Material Safety Data Sheet - Daycon

Material Safety Data Sheet
For Compliance with OSHA 29 CFR 1910.1200 and ANSI Z400.1-1998
Product Name
RESCUE 96
Item No.
ND32930
Date of Last Revision
September 29, 2011
N/A = Not Applicable
N/R = Not Regulated
NIA = No Information Available
Product Use:
Carpet spotter/degreaser.
2. Composition/Information on Ingredients
Components C.A.S. Number Exposure Limits % (Optional)
D-Limonene (Monocyclic
Terpene Hydrocarbon
_Fatty acids, C6-10,
methyl esters
OSHA Regulatory Status
Combustible Liquid
5989-27-5 NIA N/R
68937-83-7 NIA N/R
3. Hazards Identification
Emergency Overview
Contact with eyes may cause irritation. Contact with skin may cause irritation. May cause irritation
of respiratory tract.
Routes of Exposure Signs and Symptoms Single, Repeated, or Severity (Mild,
Acute and Chronic
Lifetime Exposure
Moderate, Severe)
Health Effect(s)
Target Organ(s)
Eye
Skin
Irritant
Irritant
Single
Single or
Severe
Moderate
Dryness
Dryness
Eyes
Skin
Inhalation Inhalation of
repeated.
Single or Mild to severe Difficulty Respiratory tract
vapors or mists
of the product
may be
irritating to the
respiratory
repeated
breathing
Ingestion
system.
If ingestion of a Single Mild to severe Nausea Digestive Tract,
large amount
does occur,
seek medical
attention. Do
NOT induce
vomiting.
kidneys
Other
1. Product and Company Identification
MSDS Code Number
105-4
Distributor
Daycon Products Company, Inc.
Street Address
16001 Trade Zone Avenue
City, State, Zip Code
Upper Marlboro, MD 20774
Information Telephone Number
800-394-0019
Fax
301-218-7100
Emergency Telephone Number
800-535-5053
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Medical Conditions Aggravated by Exposure
Dermatitus, asthma
Carcinogenicity (OSHA, IARC, NTP)
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
In 2-year gavage studies, there was clear evidence of carcinogenic activity of d-limonene for male rats, as shown by
increased incidences of tubular cell hyperplasia, adenomas, and adenocarcinomas of the kidney. There was NO
evidence of carcinogenic activity of d-limonene for female rats, for male mice, or for female mice.
Potential Environmental Effects
May bio concentrate in aquatic organisms and fish. Has low mobility in soil and may rapidly volatilize in the
atmosphere. Limonene can be readily degraded in soil.
4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
Eye Flush with water for 15
minutes.
Seek medical attention if
irritation persists.
None known.
Skin Flush with water. Seek medical attention if None known.
Inhalation Remove to fresh air.
Give artificial respiration
irritation persists.
Seek medical attention. None known.
Ingestion
if not breathing.
If ingestion of a large
amount does occur,
seek medical attention.
Do NOT induce
Seek medical attention. None known.
Other
vomiting.
N/A
N/A N/A
Note to Physicians (Treatment, Testing, and Monitoring)
NIA
Flashpoint 122°F Flammable (Explosive) Limits in
Method Air
Flame Propagation or Burning Rate (for solids)
NIA
Extinguishing Media
Use water fog, dry chemical,
carbon dioxide or alcohol type
foam.
5. Fire Fighting Measures
LEL0.7% UEL 6.1%
Autoignition
Temperature
Properties Contributing to Fire Intensity
Vapors are heavier than air
and liquid will float on water.
Extinguishing Media to Avoid
NIA
NIA°F
Flammability Classification
3
MSDS 105 RESCUE 96 Page 2 138-F 2013
Other
NIA
Reactions to Extinguishing Media
NIA
Protection and Procedures for Firefighters
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protective gear.
Unusual Fire and Explosion Hazards
Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors are heavier than air and may
travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined
areas. This liquid floats on water and may travel to a source of ignition and spread fire.

6. Accidental Release Measures
Containment Techniques
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Spill/Leak Clean-up Procedures and Equipment.
Mop up or pick up with wet vac.
Evacuation Procedures
Stay out of spill. Remove all unnecessary personnel.
Special Instructions
Remove all sources of ignition. Provide ventilation
Reporting Requirements
N/R
7. Handling and Storage
Handling Practices and Warnings
Do not use near sparks or open flame. Keep container closed when not in use.
Storage Practices and Warnings
Store in cool dry area away from oxidizers and ignition sources.
Ventilation
8. Exposure Control/Personal Protection
Other Engineering Controls
Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies:
Eye/Face Wear splash proof safety goggles and face
shield.
Skin Neoprene or rubber gloves.
Inhalation
Not normally required.
General Hygiene Considerations and Work Practices
Wash hands before touching eyes, mouth or food, or smoking.
Protective Measures During Repair and Maintenance of Contaminated Equipment
Wear protective gloves and eye protection.
Other Protective Measures and Equipment
None required.
Appearance
Splash proof safety goggles and face shield.
Neoprene or rubber gloves.
NIOSH approved respirator.
9. Physical and Chemical Properties
Odor
Citrus
Clear iquid.
Normal Physical State: (Mark an X next to the ones that apply) Boiling Point 175-176 °C
x
Liquid
Solid
Specific Gravity or Density (H2O = 1)
0.8400
Vapor Pressure (mm Hg.)
1.98
Other
N/A
Gas Melting Point N/A °F
(Other) Freezing Point -74° C Decomposition
Solubility in Water
Insoluble
Vapor Density (AIR = 1)
>1
pH pH (at use dilution)
N/A N/A
Evaporation Rate (Butyl Acetate = 1)
NIA
MSDS 105 RESCUE 96 Page 3 138-F 2013

Incompatibility (Materials to Avoid)
Avoid strong oxidizing agents.
Hazardous Products Produced During Decomposition
Oxides of carbon.
Hazardous Polymerization? (Mark May Occur
an X next to the ones that apply)
Stability? (Mark an X next to the
ones that apply)
Stable
×
10. Stability and Reactivity
Will Not Occur
×
Unstable
Conditions to Avoid
N/A
Conditions to Avoid
Contact with Aluminum Chloride polymerization catalyst,
strong oxidizing agents.
11. Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic Effects, Reproductive Effects, or Structure Activity Data
For D-Limonene:
LD50/LC50:
CAS# 5989-27-5:
Draize test, rabbit, skin: 10%/24H Mild;
Oral, mouse: LD50 = 5600 mg/kg;
Oral, rat: LD50 = 4400 mg/kg;
Skin, rabbit: LD50 = >5 gm/kg; .
Carcinogenicity:CAS# 5989-27-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information available.
Teratogenicity: Not known to be teratogenic.
Reproductive Effects: See actual entry in RTECS for complete information.
Mutagenicity: d-Limonene was not mutagenic in 4 strains of S. typhimurium, did not significantly increase the
number of Tft-resistant cells in the mouse L5178Y/TK+/- assay, and did not induce chromosomal aberrations or
SCEs in cultured CHO cells.
Neurotoxicity: No information available.
12. Ecological Information
Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements
For D-Limonene:
Ecotoxicity: No data available. No information available.
Environmental: May bioconcentrate in aquatic organisms and fish. Has low mobility in soil and may rapidly
volatilize in the atmosphere. Limonene can be readily degraded in soil.
Physical: No information available.
Other: Dipentene, which is optically inactive limonene, is a marine pollutant.
13. Disposal Considerations
Regulations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US
EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators
must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Properties (Physical/Chemical) Affecting Disposal
Combustible
NOTE: State or local requirements may differ from federal regulations. Processing or using this product may make the information here inappropriate. Waste
generators are responsible for waste classification, transport, and disposal.
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Regulated for shipping? (Mark an X
next to the ones that apply)
Yes X No
Do changes in quantity, packaging, or
shipment method change product
classification?
Yes No
14. Transport Information
Proper Shipping Name
Combustible
Not Regulated for Domestic Shipments
Hazard Class
3
Packing Group
III
Identification Number
UN2319
Other
For domestic shipments, Combustible liquids shipped in non-bulk (i.e. 119 gallons or less) are exempt from shipping
papers, placarding, labeling, and marking requirements. This does not apply to shipments by vessel or aircraft.
Exception 173.150 (f).
15. Regulatory Information
Federal Regulations (OSHA, TSCA, CERCLA, FIFRA, EPCRA, CAA, CWA, SDWA, CPSA, DEA, FDA/USDA, etc.)
TSCA
CAS# 5989-27-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 5989-27-5: immediate, fire.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
State Regulations
CAS# 5989-27-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI N
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
MSDS 105 RESCUE 96 Page 5 138-F 2013

S 60 This material and its container must be disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to special instructions /safety data sheets.
WGK (Water Danger/Protection)
CAS# 5989-27-5: No information available.
Canada - DSL/NDSL
CAS# 5989-27-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 5989-27-5 is listed on the Canadian Ingredient Disclosure List.
Other
NIA
16. Other Information
Label Text, Hazard Rating Systems, Key Legend, or Other
NCPA-HMIS Rating: Health - 1 Flammability - 2 Reactivity - 0 PPE - X
NOTE: OSHA’s Hazard Communication Standard (29 CFR 1910.1200) does not require the information requested in Sections 11, 12, 13, 14, 15, and 16 for
MSDSs. If your company chooses not to fill in these sections, you may wish to enter something (like N/R for “not required” or N/A for “not applicable”) to indicate
that the field is purposely being left blank.
MSDS 105 RESCUE 96 Page 6 138-F 2013