- Page 1 and 2: Facile Approach to Synthesize Stimu
- Page 3 and 4: Acknowlwdgement This dissertation w
- Page 5 and 6: Chapter 1. Table of Contents 1-1. I
- Page 7 and 8: 4.2.2.4.General Procedure for Synth
- Page 9 and 10: Chapter 1 General Introduction 9
- Page 11: The growth in industrial applicatio
- Page 15 and 16: 1.5. Components of ATRP. There are
- Page 17 and 18: Figure 1-4:Mechanism of the Atomic
- Page 19 and 20: near that of the human body, PNIPAm
- Page 21 and 22: References and notes. 1. Plastiquar
- Page 23 and 24: Chapter 2 Characteristics of High-D
- Page 25 and 26: 2.1. INTRODUCTION. Atom transfer ra
- Page 27 and 28: . Cl Si H + OH 9 + 10-undecen-1-ol
- Page 29 and 30: Figure 2-3 (b): NMR spectrum of Pro
- Page 31 and 32: Figure 2-4: Schematic procedure for
- Page 33 and 34: 3000 2000 Wavenumber/cm -1 1000 Fig
- Page 35 and 36: Figure 2-7: (a) First order kinetic
- Page 37 and 38: free polymers. We performed polymer
- Page 39 and 40: Figure 2-9: Contact angles of air b
- Page 41 and 42: 2.4. CONCLUSION. A detailed explana
- Page 43 and 44: Chapter 3 Dominant influence of the
- Page 45 and 46: 3.1. Introduction. Temperature resp
- Page 47 and 48: and FT-IR analyses, were used as re
- Page 49 and 50: azide Figure 3-2: FT-IR spectra of
- Page 51 and 52: Figure 3-3: 1 H NMR spectrum of aci
- Page 53 and 54: 3.3. Results and discussion. ATRP t
- Page 55 and 56: temperature. 28 Electro-negativity
- Page 57 and 58: Contact Angle (degree) 141 138 135
- Page 59 and 60: Figure 3-7 shows equilibrium contac
- Page 61 and 62: References and Notes. (1) S.A. Prok
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Chapter 4 Precise Synthesis and Phy
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4.1. Introduction. Stimuli-sensitiv
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4.2. Experimental Section. 4.2.1. M
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hr and at room temperature for 12 h
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chromatography with hexane/ethyl ac
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4.2.2.4.General Procedure for Synth
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Figure 4-4. Schematic illustration
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Figure 4-5. FT-IR spectra of dried
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are necessary to achieve maximum bo
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Figure 4-1-1: XPS data of (a) C 1S
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The successful deposition of CPU-dM
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where f i is the area fraction of c
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The ATRP in this condition provides
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Figure 4-1-5: AFM image of densely
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Figure 4-1-8. Graft density of PNIP
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Figure 4-1-7. Plots of Ld/Lc,w vers
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Figure 4-1-9. Thickness of high den
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Figure 4-7. a) FT-IR spectra and b)
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Figure 4-1-10 (c): Area ratio for t
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Area ratio 0.4 0.35 0.3 0.25 0.2 0.
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(a) Figure 4-1-11 . Contact angle o
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(c) Figure 4-1-11. Contact angle of
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The temperature dependence for the
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4.4 Conclusions. High-density therm
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(16) Osada, Y.; Gong, J. P. Prog. P
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2006, 22 (9), 4259-4266. L Macromol
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(76) The Young equation, cos θ = (
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Abstract. High-density polymer brus
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previously grafted chain prevents l
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5.3.1. Synthesis procedure of the A
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5.4.1. Fourier Transform Infrared S
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5.5. Result and discussion. Scheme
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graft density (chain/nm 2 ) 0.8 0.6
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Thickness (nm) 50 40 30 20 10 0 0 1
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a nm 1μm b nm 1μm Figure 5-5. The
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5.6. Conclusion. ATRP of PNIPA in D
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(17) Huang, E.; Rockford, L.; Russe
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Publications. 1. Suzuki H., Huda M.