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22. Chung, J. E.; Yokoyama, M.; Yamato, M.; Aoyagi, T.; Sakurai, Y.; Okano, Journal of Controlled Release, 1999, 62, 115–127. 23. Hu Yan and Kaoru Tsujii. ―Potential application of poly(N-isopropylacrylamide) gel containing polymeric micelles to drug delivery systems‖ Colloids and Surfaces B: Biointerfaces. 2005, 46, 142–146. 24. Antunes F. , Gentile L. , Tavano L. , Oliviero Rossi C. , " Rheological characterization of the thermal gelation of poly(N-isopropylacrylamide) and poly(N-isopropylacrylamide)co- Acrylic Acid". Applied Rheology, 2009, Vol. 19, n. 4, pp. 42064-42069. 25. Wang, S. Q.; Zhu, Y. X. Langmuir 2009, 25 (23), 13448–13455. 26. Teodorescu, M.; Matyjaszewski, K. Macromolecules 1999, 32 (15), 4826–4831. 27. Rademacher, J. T.; Baum, R.; Pallack, M. E.; Brittain, W. J.; Simonsick, W. J. Macromolecules 2000, 33 (2), 284–288. 28. Bontempo, D.; Li, R. C.; Ly, T.; Brubaker, C. E.; Maynard, H. D. Chem. Commun. 2005, No. 37, 4702–4704. 29. Xu, J.; Ye, J.; Liu, S. Y. Macromolecules 2007, 40 (25), 9103–9110. 30. Masci, G.; Giacomelli, L.; Crescenzi, V. Macromol. Rapid Commun. 2004, 25 (4), 559–564. 31. Millard, P.-E.;Mougin, N. C.;B€oker,A.;M€uller,A.H.E. Controlled/ Living Radical Polymerization: Progress in ATRP; Matyjaszewski, K., Ed.; ACS Symposum Series; American Chemical Society: Washington, DC, 2009; pp 127-137. 32. Jonas, A. M.; Glinel, K.; Oren, R.; Nysten, B.; Huck, W. T. S. 22
Chapter 2 Characteristics of High-Density Poly(N-isopropylacrylamide) (PNIPA) Brushes on Silicon Surface by Atom Transfer Radical Polymerization 23
Page 1 and 2: Facile Approach to Synthesize Stimu
Page 3 and 4: Acknowlwdgement This dissertation w
Page 5 and 6: Chapter 1. Table of Contents 1-1. I
Page 7 and 8: 4.2.2.4.General Procedure for Synth
Page 9 and 10: Chapter 1 General Introduction 9
Page 11 and 12: The growth in industrial applicatio
Page 13 and 14: 1.3. Grafting methods. Most of thes
Page 15 and 16: 1.5. Components of ATRP. There are
Page 17 and 18: Figure 1-4:Mechanism of the Atomic
Page 19 and 20: near that of the human body, PNIPAm
Page 21: References and notes. 1. Plastiquar
Page 25 and 26: 2.1. INTRODUCTION. Atom transfer ra
Page 27 and 28: . Cl Si H + OH 9 + 10-undecen-1-ol
Page 29 and 30: Figure 2-3 (b): NMR spectrum of Pro
Page 31 and 32: Figure 2-4: Schematic procedure for
Page 33 and 34: 3000 2000 Wavenumber/cm -1 1000 Fig
Page 35 and 36: Figure 2-7: (a) First order kinetic
Page 37 and 38: free polymers. We performed polymer
Page 39 and 40: Figure 2-9: Contact angles of air b
Page 41 and 42: 2.4. CONCLUSION. A detailed explana
Page 43 and 44: Chapter 3 Dominant influence of the
Page 45 and 46: 3.1. Introduction. Temperature resp
Page 47 and 48: and FT-IR analyses, were used as re
Page 49 and 50: azide Figure 3-2: FT-IR spectra of
Page 51 and 52: Figure 3-3: 1 H NMR spectrum of aci
Page 53 and 54: 3.3. Results and discussion. ATRP t
Page 55 and 56: temperature. 28 Electro-negativity
Page 57 and 58: Contact Angle (degree) 141 138 135
Page 59 and 60: Figure 3-7 shows equilibrium contac
Page 61 and 62: References and Notes. (1) S.A. Prok
Page 63 and 64: Chapter 4 Precise Synthesis and Phy
Page 65 and 66: 4.1. Introduction. Stimuli-sensitiv
Page 67 and 68: 4.2. Experimental Section. 4.2.1. M
Page 69 and 70: hr and at room temperature for 12 h
Page 71 and 72: chromatography with hexane/ethyl ac
Page 73 and 74:
4.2.2.4.General Procedure for Synth
Page 75 and 76:
Figure 4-4. Schematic illustration
Page 77 and 78:
Figure 4-5. FT-IR spectra of dried
Page 79 and 80:
are necessary to achieve maximum bo
Page 81 and 82:
Figure 4-1-1: XPS data of (a) C 1S
Page 83 and 84:
The successful deposition of CPU-dM
Page 85 and 86:
where f i is the area fraction of c
Page 87 and 88:
The ATRP in this condition provides
Page 89 and 90:
Figure 4-1-5: AFM image of densely
Page 91 and 92:
Figure 4-1-8. Graft density of PNIP
Page 93 and 94:
Figure 4-1-7. Plots of Ld/Lc,w vers
Page 95 and 96:
Figure 4-1-9. Thickness of high den
Page 97 and 98:
Figure 4-7. a) FT-IR spectra and b)
Page 99 and 100:
Figure 4-1-10 (c): Area ratio for t
Page 101 and 102:
Area ratio 0.4 0.35 0.3 0.25 0.2 0.
Page 103 and 104:
(a) Figure 4-1-11 . Contact angle o
Page 105 and 106:
(c) Figure 4-1-11. Contact angle of
Page 107 and 108:
The temperature dependence for the
Page 109 and 110:
4.4 Conclusions. High-density therm
Page 111 and 112:
(16) Osada, Y.; Gong, J. P. Prog. P
Page 113 and 114:
2006, 22 (9), 4259-4266. L Macromol
Page 115 and 116:
(76) The Young equation, cos θ = (
Page 117 and 118:
Abstract. High-density polymer brus
Page 119 and 120:
previously grafted chain prevents l
Page 121 and 122:
5.3.1. Synthesis procedure of the A
Page 123 and 124:
5.4.1. Fourier Transform Infrared S
Page 125 and 126:
5.5. Result and discussion. Scheme
Page 127 and 128:
graft density (chain/nm 2 ) 0.8 0.6
Page 129 and 130:
Thickness (nm) 50 40 30 20 10 0 0 1
Page 131 and 132:
a nm 1μm b nm 1μm Figure 5-5. The
Page 133 and 134:
5.6. Conclusion. ATRP of PNIPA in D
Page 135 and 136:
(17) Huang, E.; Rockford, L.; Russe
Page 137:
Publications. 1. Suzuki H., Huda M.
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