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References and Notes. [1] Heskins, M.; Guillet, J. E. J. Macromol. Sci., Chem. A2, 1441-1455 (1968). [2] Schild, H. G. Prog. Polym. Sci. 17, 163-249 (1992). [3] Chen, G.; Hoffman, A. S. Nature (London), 373, 49-52 (1995). [4] Hay, D. N. T.; Rickert, P. G.; Seifert, S.; Firestone, M. A. J. Am. Chem. Soc., 126, 2290-2291 (2004). [5] Xiang, G.; Norbert, K.; Heather, S. Langmuir, 25, 10271-10278 (2009). [6] Dai, X.; Zhou, F. ; Khan, N. ; Huck, W. T.S. ; Kaminski, C. F. Langmuir, 24, 13182-13185 (2008). [7]Zhou, F.; Huck, W. T. S. Phys. Chem. Chem. Phys., 8, 3815-3823 ( 2006). [8] Pyun, J.; Kowalewski, T.; Matyjaszewski, K. Macromol. Rapid Commun., 24, 1043-1059 (2003). [9] Mandal, T. K.; Fleming, M. S.; Walt, D. R. Nano Lett., 2, 3-7 (2002). [10] Sill, K.; Emrick, T. Chem. Mater., 16, 1240-1243 (2004). [11] Kickelbick, G.; Holzinger, D.; Brick, C.; Trimmel, G.; Moons, E. Chem. Mater., 14, 4382- 4389 (2002). [12] Vestal, C. R.; Zhang, Z. J. J. Am. Chem. Soc., 124, 14312-14313 (2002). [13] Kim, J.-B.; Bruening, M. L.; Baker, G. L. J Am. Chem. Soc., 122, 7616-7617 (2000). [14] Tsujii, Y.; Ohno, K.; Yamamoto, S.; Goto, A.; Fukuda, T. Adv. Polym. Sci. 197, 1-45 (2006). [15] Suzuki, A., Kobiki, Y., Jpn. J. Appl. Phys., 38, 2910-2916 (1999). 42
Chapter 3 Dominant influence of the terminal molecule of PNIPA grafted membrane obtained by Atomic Transfer Radical Polymerization 43
Page 1 and 2: Facile Approach to Synthesize Stimu
Page 3 and 4: Acknowlwdgement This dissertation w
Page 5 and 6: Chapter 1. Table of Contents 1-1. I
Page 7 and 8: 4.2.2.4.General Procedure for Synth
Page 9 and 10: Chapter 1 General Introduction 9
Page 11 and 12: The growth in industrial applicatio
Page 13 and 14: 1.3. Grafting methods. Most of thes
Page 15 and 16: 1.5. Components of ATRP. There are
Page 17 and 18: Figure 1-4:Mechanism of the Atomic
Page 19 and 20: near that of the human body, PNIPAm
Page 21 and 22: References and notes. 1. Plastiquar
Page 23 and 24: Chapter 2 Characteristics of High-D
Page 25 and 26: 2.1. INTRODUCTION. Atom transfer ra
Page 27 and 28: . Cl Si H + OH 9 + 10-undecen-1-ol
Page 29 and 30: Figure 2-3 (b): NMR spectrum of Pro
Page 31 and 32: Figure 2-4: Schematic procedure for
Page 33 and 34: 3000 2000 Wavenumber/cm -1 1000 Fig
Page 35 and 36: Figure 2-7: (a) First order kinetic
Page 37 and 38: free polymers. We performed polymer
Page 39 and 40: Figure 2-9: Contact angles of air b
Page 41: 2.4. CONCLUSION. A detailed explana
Page 45 and 46: 3.1. Introduction. Temperature resp
Page 47 and 48: and FT-IR analyses, were used as re
Page 49 and 50: azide Figure 3-2: FT-IR spectra of
Page 51 and 52: Figure 3-3: 1 H NMR spectrum of aci
Page 53 and 54: 3.3. Results and discussion. ATRP t
Page 55 and 56: temperature. 28 Electro-negativity
Page 57 and 58: Contact Angle (degree) 141 138 135
Page 59 and 60: Figure 3-7 shows equilibrium contac
Page 61 and 62: References and Notes. (1) S.A. Prok
Page 63 and 64: Chapter 4 Precise Synthesis and Phy
Page 65 and 66: 4.1. Introduction. Stimuli-sensitiv
Page 67 and 68: 4.2. Experimental Section. 4.2.1. M
Page 69 and 70: hr and at room temperature for 12 h
Page 71 and 72: chromatography with hexane/ethyl ac
Page 73 and 74: 4.2.2.4.General Procedure for Synth
Page 75 and 76: Figure 4-4. Schematic illustration
Page 77 and 78: Figure 4-5. FT-IR spectra of dried
Page 79 and 80: are necessary to achieve maximum bo
Page 81 and 82: Figure 4-1-1: XPS data of (a) C 1S
Page 83 and 84: The successful deposition of CPU-dM
Page 85 and 86: where f i is the area fraction of c
Page 87 and 88: The ATRP in this condition provides
Page 89 and 90: Figure 4-1-5: AFM image of densely
Page 91 and 92: Figure 4-1-8. Graft density of PNIP
Page 93 and 94:
Figure 4-1-7. Plots of Ld/Lc,w vers
Page 95 and 96:
Figure 4-1-9. Thickness of high den
Page 97 and 98:
Figure 4-7. a) FT-IR spectra and b)
Page 99 and 100:
Figure 4-1-10 (c): Area ratio for t
Page 101 and 102:
Area ratio 0.4 0.35 0.3 0.25 0.2 0.
Page 103 and 104:
(a) Figure 4-1-11 . Contact angle o
Page 105 and 106:
(c) Figure 4-1-11. Contact angle of
Page 107 and 108:
The temperature dependence for the
Page 109 and 110:
4.4 Conclusions. High-density therm
Page 111 and 112:
(16) Osada, Y.; Gong, J. P. Prog. P
Page 113 and 114:
2006, 22 (9), 4259-4266. L Macromol
Page 115 and 116:
(76) The Young equation, cos θ = (
Page 117 and 118:
Abstract. High-density polymer brus
Page 119 and 120:
previously grafted chain prevents l
Page 121 and 122:
5.3.1. Synthesis procedure of the A
Page 123 and 124:
5.4.1. Fourier Transform Infrared S
Page 125 and 126:
5.5. Result and discussion. Scheme
Page 127 and 128:
graft density (chain/nm 2 ) 0.8 0.6
Page 129 and 130:
Thickness (nm) 50 40 30 20 10 0 0 1
Page 131 and 132:
a nm 1μm b nm 1μm Figure 5-5. The
Page 133 and 134:
5.6. Conclusion. ATRP of PNIPA in D
Page 135 and 136:
(17) Huang, E.; Rockford, L.; Russe
Page 137:
Publications. 1. Suzuki H., Huda M.
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