PS-PLLA - Www2.che.nthu.edu.tw

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Proposed Mechanism Solvent evaporation d funnel effect Step 1: well-ordered microphase separation Step 2: solvent permeate through specific microdomain fs 41
Definition of Solvent Solvent Molar volume χ PS-solvent PLLA-solvent δ solvent (MPa) 0.5 Vapor Pressure (mmHg) Chlorobenzene 102.1 0.36 0.62 19.6 12 benzene 89.4 0.34 0.81 18.6 70 THF 81.7 0.35 0.6 19.4 176 1,1,2-trichloroethane 100.4 0.36 < 0.5 19.6 17.1 1,2-dichloroethane 79.2 0.42 0.44 20.4 61 chloroform 80.7 0.34 < 0.5 19 159.6 χ = χ H + χ S = V i (δ i –δ j ) 2 /RT + 0.34 χ PS-solvent < 0.5 and χ PLLA-solvent >0.5 PS selective solvent χ PS-solvent < 0.5 and χ PLLA-solvent
Page 1 and 2: Block Copolymer Thin Films
Page 3 and 4: Thickness Effect while t is small f
Page 6 and 7: Phase diagram of thin film morpholo
Page 9 and 10: Surface Tension @
Page 11 and 12: Grain boundary problem for thicker
Page 13 and 14: Electric field-Induced Orientation
Page 15 and 16: Shear-induced Orientation PS-PEP Cy
Page 17: Grephoepitaxy-induced Orientation C
Page 21 and 22: Evaporation-induced Orientation Spi
Page 23 and 24: FESEM micrographs of hydrolyzed PS-
Page 25 and 26: Tunable dimensions of nanostructure
Page 27: Spin-coated PS-PLLA thin films Perp
Page 31 and 32: Evaporation Rate Effect Selective s
Page 33 and 34: Solution Casting Neutral solvent Cr
Page 35 and 36: Molecular Weight Effect Selective S
Page 37 and 38: Tg Effect Side view image of FESEM
Page 39 and 40: Substrate Effect Glass slide Carbon
Page 41 and 42: Proposed Mechanism Segregation stre
Page 43 and 44: Nanopatterning for Lamellar Nanostr
Page 45 and 46: Crystallizable solvent T max =150 o
Page 47 and 48: Strongly Segregated PS-PLLA Quench
Page 49 and 50: Crystallization-Induced Orientation
Page 51 and 52: Lattice Matching PLLA -PCL 0.514 nm
Page 53 and 54: Mechanisms 1.Homogeneous mixture of
Page 56 and 57: Methods for Nanopatterning Photoli
Page 58 and 59: Soft Lithography Whitesides, G. M.
Page 60 and 61: Scanning Probe Lithography Atomic f
Page 62 and 63: Advantages and Disadvantages Electr
Page 64 and 65: Nanopatterning from Degradable BCPs
Page 66 and 67: Nanopatterning from Degradable BCPs
Page 68 and 69: Synthetic routes of PS-PLLA block c
Page 70: Nanotemplate (i.e., Nanoreactor) A
Page 73 and 74: Pore-filling for Nanotemplates Capi
Page 75 and 76: TEM : Air-block releasing Nanoporou
Page 77 and 78: TEM : directed capillary force (met
Page 79 and 80:
Confocal Microscopy Observation CdS
Page 81 and 82:
Double-length-Scale Patterns (a) Co
Page 83 and 84:
FESEM images of CNTs grown from PS/
Page 85 and 86:
Lighting DTC Phosphor (CRT) Ni on D
Page 87 and 88:
Pore-filling for Sirolimus Capillar
Page 89 and 90:
Accumulative Accumulative release r
Page 91 and 92:
Nanoscale Spatial Effect PY/CM thin
Page 93:
Chain Alignment Mechanism Solventan
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PS-PLLA - Www2.che.nthu.edu.tw

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