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PS-PLLA - Www2.che.nthu.edu.tw

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<strong>PS</strong> <strong>PLLA</strong><br />

Hydrophilic substrate<br />

Spin coating at room temperature<br />

D <strong>PS</strong> (glass state) = D <strong>PLLA</strong> (glass state)<br />

S <strong>PS</strong>-<strong>PS</strong> selective solvnet > S <strong>PLLA</strong>-<strong>PS</strong>-selective solvent<br />

Permeation<br />

Diffusivity & Solubility<br />

Kinetic control & Dynamic control<br />

<strong>PS</strong> <strong>PLLA</strong><br />

Hydrophilic substrate<br />

Spin coating at 50 O C<br />

D <strong>PS</strong> (glass state) S <strong>PLLA</strong>-<strong>PS</strong>-selective solvent<br />

Permeation (P=DXS)<br />

Diffusivity (D) ~ T g<br />

Solubility (S)<br />

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