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• application notes & technical articles<br />

Wet-Shotcrete of Refractory Castables<br />

construction & building<br />

industries<br />

mining industries<br />

In recent years, the refractory<br />

industry has focused much<br />

effort on discovering novel<br />

techniques for castable<br />

installation that combine<br />

high placing rate and low cost<br />

while maintaining final material<br />

properties.<br />

The use of versatile and automated placing<br />

methods such as pumping of self-flowing<br />

castables and shotcrete has been encouraged to<br />

replace the traditional vibration moulding<br />

technique.<br />

Based on these aspects, wet shotcrete is highly<br />

interesting from a technological standpoint,<br />

particularly for the lining of large areas and/or for<br />

the repair of damaged surfaces.<br />

The technique consists of pumping the castable<br />

from the miser to the pipeline nozzle, where<br />

high-pressure compressed air is injected so as to<br />

project the pumped castable onto the surface to<br />

• application notes & technical articles<br />

Rheological Behaviour of Automotive<br />

Paint Systems<br />

surface coatings industries<br />

Modern Characterisation<br />

Methods Show Good<br />

Correlations to Observable<br />

Effects<br />

biennial 07-08<br />

be covered. This promotes a spray flow that<br />

ensures a high installation rate and the formation<br />

of a thick layer.<br />

The difficulties involved in the shotcrete technique<br />

relate mainly to the bonding of the material on the<br />

area to be lined. The primary condition for a<br />

successful operation is that the projected material<br />

does not flow over the back lining refractory<br />

surface, and this requires a sudden loss of the<br />

castable’s fluidity. Traditionally, this effect is<br />

achieved by the controlled use of cement settling<br />

accelerators, which are also injected into the<br />

nozzle.<br />

Although they ensure the material’s cohesion,<br />

conventional accelerators such as sodium silicate<br />

and aluminium sulfate usually deteriorate the<br />

mechanical properties of castables at high<br />

temperatures. Therefore, proposals have been<br />

made for novel additives based on distinct<br />

concepts to promote the rapid reduction of<br />

castable fluidity.<br />

In most bases, material waste is generated during<br />

shotcrete application due to the so-called rebound<br />

effect. This wastage occurs when a portion of the<br />

sprayed castables, which may amount to as much<br />

as 30%, fails to adhere to the applied surface. The<br />

rebound effect, which is also enhanced by the use<br />

of accelerators, can be minimised by selecting<br />

additives that simultaneously impart adhesive and<br />

In this paper the most important measuring<br />

methods for studying the rheological behaviour of<br />

modern paint systems (oscillation tests,<br />

determination of low yield points) are described.<br />

These methods were at first used to describe the<br />

rheological/physical properties of model<br />

polyurethane micro gels. The measured values for<br />

storage modulus, phase shift and yield point in<br />

waterborne Pearle scent/coloured pigment<br />

systems were compared with flop-index values.<br />

The results show good correlations between the<br />

plastic characteristics to the castable, resulting in<br />

homogeneous and cohesive linings, even when<br />

successive layers are applied<br />

In addition to the intrinsically complex pumping<br />

operation, wet-shotcrete applications must also<br />

take into account: (a) an abrupt increase in the<br />

castable shearing rate and the injection of<br />

additives, controlled by the air rate supplied in the<br />

nozzle, and (b) the material’s adhesion and<br />

consolidation on the surface.<br />

The conventional testing techniques, however do<br />

not properly evaluate shotcrete castables, given<br />

the rheological behaviour of these castables under<br />

similar shearing conditions during their installation<br />

is not analysed. The traditional approaches focus<br />

mainly on the influence of additives on the<br />

castable’s consistency (fluidity measurements) and<br />

on post-setting properties.<br />

The main objective of the present study was to<br />

develop a novel shotcrete characterisation<br />

technique based on castable rheometry that<br />

simulates the material’s application. Commercial<br />

wet-shotcrete additives and other compounds with<br />

a high potential for this application were also<br />

evaluated using the new testing procedure.<br />

A complete copy of this article is available on<br />

request by quoting Rf-290802-BR-02.<br />

observable effect and the rheological parameters<br />

of the liquid paint.<br />

Also measurements of powder and electrode<br />

position coatings and clear coats with the<br />

oscillation technique to determine the viscositytemperature<br />

behaviour correlate well with<br />

technical properties of the final films.<br />

A complete copy of this article is available on<br />

request by quoting Rheo008TP.<br />

18 www.rheologysolutions.com

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