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Hydro G Final report - Kildare.ie

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HYDROLOGICAL REPORT<br />

FOR LEIXLIP SPA<br />

CO. KILDARE<br />

FINAL REPORT<br />

PREPARED FOR:<br />

KILDARE COUNTY COUNCIL<br />

JULY 2008


Unit 13, Galway Technology Centre, Mervue Business Park, Galway. tel: 091 704848, fax: 091 755635<br />

Project No.: 07_136<br />

Report Title: <strong>Hydro</strong>logical Report for Leixlip Spa, Co. <strong>Kildare</strong><br />

Report Status: <strong>Final</strong> Report<br />

Date: 21/07/2008<br />

Prepared by: ___________________________<br />

Anna Kuczynska<br />

Approved by: ___________________________<br />

Dr. Pamela Bartley<br />

NOTES:<br />

All information suppl<strong>ie</strong>d by the Cl<strong>ie</strong>nt, the Cl<strong>ie</strong>nt's staff and professional advisers, local authorit<strong>ie</strong>s, other statutory<br />

bod<strong>ie</strong>s, investigation agenc<strong>ie</strong>s and other stated sources is accepted as being correct.<br />

All data and methods of analysis presented are, to the best of our knowledge, valid at the time of <strong>report</strong><br />

generation.<br />

Areas presented, off site distances and elevations are normally computed from Ordnance Survey maps and not<br />

from physical surveys. They are approximate unless otherwise stated.<br />

Project No.: 07_136 Leixlip Spa<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

PROJECT TEAM<br />

Dr. Pamela Bartley (B.Eng, M.Sc., Ph.D, MIEI) is a consultant civil engineer with over ten years<br />

f<strong>ie</strong>ld exper<strong>ie</strong>nce in hydrogeological investigations and site instrumentation. Project areas include<br />

groundwater investigations, local authority licensing of treated wastewater discharges, water<br />

resource assessment, subsoil hydrology, assessment of groundwater vulnerability, nutr<strong>ie</strong>nt impact<br />

accounting, environmental risk analysis and design of stormwater, wastewater and constructed<br />

wetland systems. Pamela is a FETAC Certif<strong>ie</strong>d Site Assessor and assists on the EPA/FAS led Site<br />

Suitability Course. She is a member of the committee of the International Association of<br />

<strong>Hydro</strong>geologists (Irish Branch) and currently holds responsibility for the organisation and<br />

management of the National Irish Annual Groundwater Conference. She completed her doctoral<br />

research (2003) at Trinity College, Dublin in conjunction with Teagasc and the EPA under National<br />

Development Plan funded research concerning groundwater vulnerability and European Directives<br />

concerning Agriculture. In conjunction with Paul Johnston of TCD, Pamela completed an assessment<br />

of Chromium levels in Irish Aquifers in the midlands for the EPA. Subsequently, Pamela completed<br />

projects concerning design and site suitability of constructed wetlands for treatment of wastewaters<br />

in conjunction with partners from TCD, GSI, EPA, NPWS and Departments of Environment and<br />

Agriculture. She has held lecturing posts at third level Irish academic institutions (WIT and CIT) and<br />

demonstrated at TCD.<br />

Anna Kuczynska (B.Eng, M.Sc.,IEMA) is a consultant environmental engineer with hydrological,<br />

hydrogeological and hydro-ecological expertise. Project areas include environmental impact<br />

assessment, risk analysis, groundwater and surface water investigations and sustainability<br />

assessments for sensitive ecological areas of groundwater dependent terrestrial ecosystems (GDTE).<br />

Since she joined <strong>Hydro</strong>-G (July 2007), she has taken responsibility for projects including hydrological<br />

and hydrogeological assessments. Before that, she worked in WS Atkins, where she was involved in<br />

a number of projects assessing impacts on soil and water environments in relation to road schemes<br />

and private developments and also undertook an assessment of the hydrological regime along the<br />

Tolka River valley. Her expertise in hydro-ecology was gained at Trinity College Dublin, where she<br />

completed her doctoral research characterising the hydrology of Pollardstown Fen (Co. <strong>Kildare</strong>) with<br />

an emphasis on protection of the habitat of the rare spec<strong>ie</strong>s of molluscs Vertigo geyeri. Throughout<br />

her work in research, she gained a broad exper<strong>ie</strong>nce in multidisciplinary and technical investigations<br />

linking hydrology, hydrogeology and ecology. During this time she worked closely with ecological<br />

and hydrogeological consultants, NPWS and academics. Her work focused on identification of<br />

environmental impacts controlled by meteorology and hydrogeology, evaluation of vulnerability, risk<br />

assessment and implementation of mitigation measures for groundwater dependent terrestrial<br />

ecosystems.<br />

Project No.: 07_136 Leixlip Spa<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

EXECUTIVE SUMMARY<br />

Leixlip Spa site in Co. <strong>Kildare</strong> is a wetland area which developed on five distinct terraces with shallow<br />

bedrock and constitutes part of the Rye Water Valley Special Area of Conservation (site code:<br />

001398). The site contains many rare and protected habitats and spec<strong>ie</strong>s including calcareous<br />

grassland and petrifying tufa springs. The ecological monitoring of the wetland suggests that the site<br />

has been drying out for the past two decades. <strong>Hydro</strong>-G was engaged by <strong>Kildare</strong> County Council to<br />

investigate and evaluate water resources within Leixlip Spa, Co. <strong>Kildare</strong> to explain these ecological<br />

changes and to a construct conceptual model of water movement throughout the site for future<br />

conservation of the site. Investigation of local water resources included identification of springs and<br />

seepages, in situ physiochemical analyses, hydrochemical analyses of selected discharge locations<br />

and flow measurements. Results facilitated identification of different groundwater discharge zones<br />

and conceptualisation of groundwater flow pathways within the site. Rev<strong>ie</strong>w of historical information<br />

revealed that parts of the site were artificially modif<strong>ie</strong>d which is likely to have impacted upon ecology<br />

of the site. This data added to the developed conceptual model.<br />

The findings of this study relate to monitoring conducted in December 2007 and January 2008, which<br />

in hydrological terms represents a recharge period. Seasonal variations may occur.<br />

The f<strong>ie</strong>ld monitoring and data analysis suggest that water at the Leixlip Spa site originates from a<br />

complex groundwater system combining two sources. The main source of water comes from a<br />

deeper, older and warmer groundwater system, discharging at the top of the first terrace through the<br />

Spa Well. The second is a more recent, shallow groundwater that flows through the karstif<strong>ie</strong>d<br />

limestone bedrock with the main groundwater discharge located in the vicinity of the fen wetland<br />

habitat (‘filtering ponds’) at the most elevated, southern terrace. Rainfall runoff also plays a part.<br />

<strong>Hydro</strong>chemical analysis suggests that groundwater discharging from the warm spring at the Spa Well<br />

is highly mineralised and is the dominant source of water within the site. It is also evident that<br />

warm water discharging from the Spa Well drains northwards and flows into and through the shallow<br />

system, resulting in water being mixed with more recently recharged water. Overland flow is also<br />

apparent. The groundwater flow in the shallow system also occurs through conduits. Due to the<br />

steep topography of the site, shallow depth of subsoil (if any) and karstic nature of bedrock,<br />

groundwater can easily discharge through rock faces and later flow over ground toward the river Rye<br />

Water. A number of discrete springs were noted at the 2nd and 3rd terraces. The physio-chemical<br />

and hydrochemical analyses revealed that the Spa Well directly influences some conduit flows that<br />

are relatively distant from the Spa Well itself and that waters on the 2nd and 3rd terraces are a<br />

mixture of the Spa Well water and the shallow system groundwater. Water flow on the 4th and 5th<br />

terraces originates mainly from surface runoff contributions from the more elevated upper terraces.<br />

<strong>Hydro</strong>chemical analysis revealed also a leakage from the canal that occurs upgrad<strong>ie</strong>nt from the<br />

wetland area at the first terrace but its contribution to overall water resources within the site is<br />

relatively small.<br />

Rev<strong>ie</strong>w of historical information revealed that the original outflow from the Spa Well was in the north<br />

westerly direction. The historical evidence suggests that the outflow was diverted towards the north<br />

easterly direction in late 1970s or early 1980s. Subsequently, water from the Spa Well discharges<br />

into the ‘filtering ponds’ area that contains the cold springs. The implication of such engineering is a<br />

limitation in water delivery to the western side of the 1st terrace manifested in drying of this wetgrassland<br />

habitat. It is also possible that diversion of the groundwater flow away from the western<br />

side of the 1st terrace occurred unintentionally during sewage works undertaken in 1980s. Analysis<br />

of water quality within the Leixlip Spa site and in the Intel drain located at the western boundary of<br />

the 1st terrace showed different hydrochemical signature in the drain than in all other samples from<br />

the Leixlip Spa site suggesting different water origin. This further supports our interpretation that<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

the Intel boundary drain does not currently act as a drainage channel drawing groundwater from the<br />

wet-grassland habitat which has been <strong>report</strong>ed to be drying out. Mitigation measures for this habitat<br />

could include reengineering of the present pipe layout to restore the original discharge from the Spa<br />

Well to the north – north westerly direction. However, this will result in reduction of groundwater<br />

flow towards the cold springs (‘filtering ponds’) and is likely to impact on the local ecology<br />

surrounding the ponds, which have adjusted to present conditions over time. Considering a probable<br />

local recharge of the cold springs, redirection of the groundwater discharge from the Spa Well might<br />

cause an increase in seasonal variation in water levels in the ‘filtering ponds’ area and subsequently<br />

could cause seasonal drying of this fen-wetland. <strong>Hydro</strong>chemical changes could also occur. Further,<br />

redirection of the outflow from the Spa Well away from the ‘filtering ponds’ will decrease a volume of<br />

water cascading to the 2nd terrace at the eastern side and this will affect distribution of water at<br />

down grad<strong>ie</strong>nt terraces. This is likely to be compensated by more water flowing on the western side<br />

but is likely to lead to habitat transformations on a local scale. The potential risks posed to the<br />

healthy existing wetland habitat on the east side of the upper terrace suggest that it does not seem<br />

prudent to interfere again with the pipe layout, from a hydrological perspective. The other potential<br />

option for the grassland habitat restoration is to reengineer the ex-parking area south to the Leixlip<br />

Spa SAC. This area currently comprises compacted soil/hard standing surface with a topographic<br />

grad<strong>ie</strong>nts towards the north and the west. Measures to harvest surface runoff water from hard<br />

standing surfaces and redirect collected water towards the western grassland habitat has potential to<br />

partially re-wet the area. These stormwater design measures are possible and require collaboration<br />

between <strong>Hydro</strong>-G and other project partners.<br />

With respect to the lowest terrace, which was <strong>report</strong>ed to be drying out, <strong>Hydro</strong>-G’s investigation has<br />

not revealed any structural changes either in local hydrology or hydrogeology. Therefore, the most<br />

probable cause of these changes is natural habitat transformation resulting from plant growth,<br />

increased evapotranspiration needs and accumulation of organic matter, which has caused an<br />

increase in ground level on this terrace. Cessation of grazing may have contributed to the vegetation<br />

overgrowth of this floodplain. Future ecological characteristics of the floodplain rely upon<br />

management strateg<strong>ie</strong>s with respect to the plant growth and accumulation of organic matter rather<br />

than management of water flows within the Leixlip Spa site.<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

TABLE OF CONTENTS<br />

1. Introduction -------------------------------------------------------------------------------------1<br />

1.1. Project Objectives ---------------------------------------------------------------------------- 1<br />

1.2. Project Methodology-------------------------------------------------------------------------- 2<br />

1.2.1. Desk Study ------------------------------------------------------------------------------- 2<br />

1.2.2. F<strong>ie</strong>ld Work -------------------------------------------------------------------------------- 2<br />

1.2.3. Reporting --------------------------------------------------------------------------------- 3<br />

2. Desk Study --------------------------------------------------------------------------------------4<br />

2.1. Environmental Settings ---------------------------------------------------------------------- 4<br />

2.1.1. Geological Settings ---------------------------------------------------------------------- 4<br />

2.2. <strong>Hydro</strong>geology --------------------------------------------------------------------------------- 4<br />

2.2.1. Aquifer Characteristics------------------------------------------------------------------- 4<br />

2.2.2. Groundwater Quality--------------------------------------------------------------------- 5<br />

2.2.3. Water Levels ----------------------------------------------------------------------------- 5<br />

2.3. Hot Springs in the <strong>Kildare</strong> Area-------------------------------------------------------------- 5<br />

2.3.1. Historical <strong>Hydro</strong>chemical Data from Leixlip Spa Well ---------------------------------- 5<br />

2.4. Groundwater Quality Monitoring within Intel Ireland Ltd.---------------------------------- 7<br />

2.5. Additional Information ----------------------------------------------------------------------- 7<br />

3. F<strong>ie</strong>ld Work Results ------------------------------------------------------------------------------8<br />

3.1. Site Observations----------------------------------------------------------------------------- 8<br />

3.2. Water Flow within the Site including Spring and Seepage Locations ---------------------- 9<br />

3.3. <strong>Hydro</strong>chemical Analyses --------------------------------------------------------------------- 10<br />

3.4. Assessment of Flow Volumes ---------------------------------------------------------------- 12<br />

4. Conceptual Model of Leixlip Spa Flow Patterns---------------------------------------------- 13<br />

5. Conclusions and Recommendations---------------------------------------------------------- 15<br />

REFERENCES---------------------------------------------------------------------------------------- 17<br />

FIGURES-------------------------------------------------------------------------------------------------------- 18<br />

Appendix A ----------------------------------------------------------------------------------------------------- 24<br />

Appendix B ----------------------------------------------------------------------------------------------------- 27<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

LIST OF FIGURES<br />

Figure 1 Location of the Leixlip Spa site, (OS LicenceEN0043207).....................................................19<br />

Figure 2 Geology in vicinity of the Leixlip Spa site. Source: www.gsi.<strong>ie</strong>..............................................20<br />

Figure 3 Location map of Intel's groundwater monitoring wells. Source: Intel Ireland..........................21<br />

Figure 4 Site location including physio-chemical monitoring points, Leixlip Spa, Co. <strong>Kildare</strong> .................22<br />

Figure 5 Layout of the drainage at Leixlip Spa. Source: <strong>Kildare</strong> County Council ..................................23<br />

LIST OF TABLES<br />

Table 1 Summary of hydrochemical analysis of the warm and the cold springs at Leixlip Louisa Bridge<br />

site, 1981-1983, from Minerex, 1983.......................................................................................6<br />

Table 2 Results of in situ survey, Leixlip Spa, 10/12/2007 ...............................................................31<br />

Table 3 Results of in situ survey, Leixlip Spa, 16/01/2008 ...............................................................31<br />

Table 4 Results of hydrochemical analysis, Leixlip Spa, 16/01/2008..................................................32<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

1. Introduction<br />

In December 2007, <strong>Hydro</strong>-G was engaged by <strong>Kildare</strong> County Council to investigate and evaluate<br />

water resources within Leixlip Spa, Co. <strong>Kildare</strong> in light of increasing concerns about the site’s<br />

ecological health and integrity.<br />

The site is located on the outskirts of Leixlip, approximately 2km west of the town, between the Intel<br />

Ireland factory and the Royal Canal. The national grid reference for the site is 299500, 236500. The<br />

location map is presented in Figure 1. The site constitutes part of the Rye Water Valley Special Area<br />

of Conservation (site code: 001398) containing protected habitats including calcareous grassland and<br />

petrifying tufa springs, as well as rare and protected spec<strong>ie</strong>s of fauna including molluscs spec<strong>ie</strong>s<br />

Vertigo moulinsiana and Vertigo angustior.<br />

Topographically, the Leixlip Spa site l<strong>ie</strong>s on number of terraces carved in limestone bedrock, which<br />

were created during construction of the Royal Canal in the 18 th century. This bedrock exposure<br />

resulted in a number of wetland habitats that developed on subsequent terraces in response to a<br />

continuous discharge of water from the bedrock. The entire area of the site is 6000m 2 ,<br />

approximately, 40m wide and 150m long with a topographic drop of 20m in a south-north direction<br />

towards the river Rye Water.<br />

In addition to its high ecological values the Leixlip Spa is known also for its archaeological features<br />

including a hexagonal well and a Roman Bath which were created in the 18 th Century following a<br />

discovery of a hot spring. The hot spring that suppl<strong>ie</strong>s water to this Bath was discovered during the<br />

construction of the Royal Canal and water from the spring is highly mineralised, specifically rich in<br />

iron, for which it gained its spa status. The original hot spring is located underneath the Royal Canal<br />

and was diverted to a man-build Spa Well of a hexagonal shape that is located at the eastern side of<br />

the entrance to the site.<br />

The ecological and archaeological features of the Leixlip Spa have been extensively investigated<br />

throughout decades and some documentation dates back as far as the 18 th century. Nevertheless, it<br />

is the site’s unique fauna and flora that have been given most attention following the implementation<br />

of the EU Habitats Directive (92/43/EEC). The site’s ecological features are <strong>report</strong>ed to have<br />

deteriorated over recent years and as the majority of the area comprises wetland habitats, there is a<br />

possibility that changes in the site’s hydrological controls merits investigation (Moorkens, Dooge,<br />

pers. comm.).<br />

1.1. Project Objectives<br />

<strong>Kildare</strong> County Council engaged <strong>Hydro</strong>-G to investigate the hydrological regime of the Leixlip Spa site<br />

and to develop a water management strategy to prevent further deterioration and to facilitate<br />

sustainable conditions.<br />

The specific objectives of the project were specif<strong>ie</strong>d by <strong>Kildare</strong> County Council, as follows:<br />

“The objective of this hydrological study is to determine the movement of water through out the site<br />

to determine how this water can be used most effic<strong>ie</strong>ntly to maintain the conservation status of the<br />

site particularily in relation to the Shining Sickle Moss (Drepanocladus vernicosus) and the semi<br />

aquatic snail spec<strong>ie</strong>s Vertigo angustior and Vertigo moulinsiana”.<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

The issues to be addressed were specif<strong>ie</strong>d as:<br />

Determine the source of water on the site and if there are other springs other than the<br />

existing spring in the Hexagonal pool on the site including the slope. Ascertain if leakage from<br />

the canal is contributing to the water feeding the site.<br />

Determine the effect of drain on the Intel side of the site is having on the site as a whole and<br />

if it contributed to the drying out of the left hand side of the site.<br />

Identify drainage pipes etc. on the site and the effect they are having on the hydrology of the<br />

site.<br />

Determine the potential for restoring the dry area (to wetland) of the site on the left hand<br />

side without impacting on the rest of the site.<br />

Determine how the water and the water movement through the site can be maximised to<br />

benefit the site as a whole.<br />

1.2. Project Methodology<br />

The project was carr<strong>ie</strong>d out in three stages, namely a desktop rev<strong>ie</strong>w, site investigation and<br />

<strong>report</strong>ing.<br />

1.2.1. Desk Study<br />

<strong>Kildare</strong> County Council provided <strong>Hydro</strong>-G with existing documentation on the ecology and the<br />

archaeology of the Leixlip Spa. In addition, a contact with Intel Ireland was facilitated by Mr. Simon<br />

Wallace (<strong>Kildare</strong> Co. Co.) which provided additional information/data on local hydrology and<br />

hydrogeology gathered in accordance with the Intel’s IPPC licence agreement, which deems Intel<br />

Ireland responsible for biannual monitoring of groundwater levels and groundwater quality within the<br />

Intel site. Intel’s IPCC licence also requires monitoring water quality in the Spa Well. Additional<br />

information was gathered during an interv<strong>ie</strong>w with Mr. Niall Meagher, a retired architect for <strong>Kildare</strong><br />

County Council who has been involved in Leixlip Spa projects and consultations with Dr. Jim Ryan<br />

and Mr. Niall Lockhard of the National Parks and Wildlife Services. A search of the Geological Survey<br />

of Ireland archives was also undertaken.<br />

1.2.2. F<strong>ie</strong>ld Work<br />

In total three site visits were undertaken.<br />

The first visit was undertaken on the 2 nd of December 2007 and involved a site meeting with<br />

ecologists Mr Declan Doogue and Mr Brendan O’Hanrahan. This meeting was facilitated by Mr. Simon<br />

Wallace (<strong>Kildare</strong> County Council). During that meeting, floristic aspects of the Spa were discussed<br />

and recent drying trends of the uppermost grassland habitat were outlined. This specifically refers to<br />

the western side of the gravel pathway which, according to Mr. Doogue, used to provide a suitable<br />

habitat for wet loving grasses and marsh orchids in the past. During this f<strong>ie</strong>ld visit, this area was<br />

<strong>report</strong>ed as ‘not wet’ in winters within the past 20 years, leading to a loss of this habitat.<br />

The second visit was carr<strong>ie</strong>d out on the 10 th of December 2007 and involved a meeting with Dr<br />

Evelyn Moorkens, malacologist, and an investigation of springs and seepages within the site. Dr<br />

Project No.: 07_136 -2-<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

Moorkens explained recent problems with Vertigo angustior habitat in the lowest terrace i.e. at the<br />

Rye River floodplain. The increasing density of grasses over the past years suggests that the site<br />

undergoes a drying trend. It has also been noted that the ground level increased due to<br />

accumulation of organic matter. The entire Leixlip Spa site was surveyed for springs and seepages<br />

and physio-chemical characteristics were measured. In total, 23 locations were surveyed. Water<br />

samples were collected from 10 no. locations. However, problems with the ionic balances obtained<br />

negated use of the initial laboratory results.<br />

During the third site visit, undertaken on the 16 th of January 2008, the in situ physio-chemical survey<br />

of springs and seepages was repeated to compare with December’s results and 8 no. water samples<br />

taken from selected locations. These were delivered to an accredited laboratory for hydrochemical<br />

analysis. Flow measurements were conducted to assess flow patterns within the site.<br />

1.2.3. Reporting<br />

A preliminary <strong>report</strong> was provided in December 2007 (Appendix A).<br />

This <strong>report</strong> presents the integrated assessment of the site’s hydrology, hydrochemistry and the<br />

emerging conceptual hydrological model for the Leixlip Spa site.<br />

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2. Desk Study<br />

2.1. Environmental Settings<br />

The Leixlip Spa site is located on the Leixlip-Maynooth local road R148, approximately 2km west of<br />

the Leixlip town centre. The R148 constitutes the site’s southern boundary and an access to the site<br />

is also provided from this road. The site is adjacent to the Intel Ireland factory, which is to the west,<br />

and the eastern boundary runs along the Royal Canal. To the north, the site is bounded by the river<br />

Rye Water. The site location map is presented in Figure 1.<br />

2.1.1. Geological Settings<br />

The bedrock geology underlying the site is discussed in the GSI publication “Geology of <strong>Kildare</strong> -<br />

Wicklow, (McConnel et al., 1994). The 1:100,000 scale bedrock geology map for the area (Sheet 16)<br />

indicates that the subject site is underlain entirely by rocks of Calp Limestone Formation (CD), which<br />

was formed during Chadian age and belongs to Lower Carboniferous system (refer to Figure 2).<br />

During the Carboniferous period, the eastern part of Ireland underwent uplift and erosion after which<br />

there was a period of subsidence in the area. Throughout this time, the sea invaded the land<br />

allowing marine sediments to accumulate across most of the Sheet 16 map, including Leixlip. The<br />

Calp Limestone is a muddy limestone and was deposited in thick sequences in turns with muds in<br />

deep sea basins with a limited fauna. It consists of dark grey, fine grained, graded limestone with<br />

interbedded black, poorly fossiliferous shales. In later periods, subsequent erosions reworked the<br />

upper end of the Calp and overlying younger limestone deposits allowing for localized karstification<br />

(in places where the rock was temporarily exposed) and/or for deposition of granite boulders within<br />

the Calp.<br />

There are number of faults in this area. These are predominantly in an east-west direction. One of<br />

these faults runs in close proximity to the site, along it’s southern boundary, Figure 2.<br />

With respect to overlying strata, the majority of this area is covered by till of sea origin and derived<br />

from limestone and overlain with Grey Brown Podzolics and Gleys (Gardiner, 1980). The GSI (GSI,<br />

2007) <strong>report</strong>s these deposits to be less than 3m deep west of Lucan village and the groundwater<br />

vulnerability rating, which classif<strong>ie</strong>s this area as ‘high’ vulnerability, suggests depths to bedrock of<br />

approximately 3 - 5m.<br />

2.2. <strong>Hydro</strong>geology<br />

2.2.1. Aquifer Characteristics<br />

According to the GSI Groundwater Body description (GSI, 2007), the Leixlip Spa Site is underlain by<br />

the Dublin Groundwater Body, which generally is low permeability and the majority of groundwater<br />

flow occurs along faults where permeability is increased by dolomitisation of the rock. The majority<br />

of flow occurs close to the surface and in isolated fractures at depths of up to 50m below ground<br />

level (bgl). Relatively low permeabilit<strong>ie</strong>s deem this bedrock to be of limited development potential<br />

and therefore the Geological Survey of Ireland classif<strong>ie</strong>d it as Locally Important aquifer, with<br />

moderate potential in local zones only. Groundwater y<strong>ie</strong>ld potential is therefore highly dependent on<br />

Project No.: 07_136 -4-<br />

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<strong>Hydro</strong>-G FINAL REPORT<br />

local fracturing of the bedrock. The general flow direction is towards the sea i.e. to the east;<br />

however, local variations, conditioned by the presence of surface water channels, are likely.<br />

2.2.2. Groundwater Quality<br />

The general water quality in this limestone aquifer suggests very hard water with total hardness<br />

between 350-480 mg/l CaCO3 and alkalinity of 300-350 mg/l CaCO3. Electric conductivit<strong>ie</strong>s are also<br />

high and can vary from 550-900 µS/cm. This water has a is calcium bicarbonate signature (GSI,<br />

2007).<br />

2.2.3. Water Levels<br />

Very little data exists on water levels in the area. The only available data were provided by Intel<br />

Ireland, which monitors groundwater levels within their site. These were not available as specific<br />

values; however, extracts from the monitoring <strong>report</strong>s provided by Intel stated that there are no<br />

trends in the groundwater level behaviour.<br />

2.3. Hot Springs in the <strong>Kildare</strong> Area<br />

A number of hot springs are <strong>report</strong>ed in the Dublin Groundwater Body, which are aligned along the<br />

Lucan – Celbridge transect. These springs were extensively stud<strong>ie</strong>d in 1983 (Minerex, 1983) and are<br />

associated with deep faults and/or synclines, which allow deeper and warmer water to surface. The<br />

temperature in these springs are <strong>report</strong>ed to range between 12.5-25 °C. Historical data from the<br />

1970’s and 1980’s (Minerex, 1983) suggest high chloride and total dissolved solids content in springs<br />

that are specifically associated with synclinal structures. The Spa Well at Leixlip Spa classif<strong>ie</strong>s as one<br />

of these springs occurring close to the Celbridge Syncline. Water signature in these springs can be<br />

mostly associated with sodium-chloride waters and is usually indicative of an older water age.<br />

Historical data (Meagher, 1976) suggest that the Leixlip Spa Well contained also large concentrations<br />

of iron, for which it was often referred to as a Chalybeate spring.<br />

An assessment of flows in these springs (Minerex, 1983) suggests normal seasonal discharge<br />

patterns with increased flows in spring and decreased in autumn which suggests groundwater flow<br />

controlled by the hydrological cycle. Similar patterns were found in the monitored spring’s<br />

temperature variations.<br />

2.3.1. Historical <strong>Hydro</strong>chemical Data from Leixlip Spa Well<br />

Burdon’s <strong>report</strong> on Irish geothermal potential (Minerex, 1983) provides a good overv<strong>ie</strong>w of the<br />

quality and annual characteristics of groundwater in the Leixlip Spa Well. The <strong>report</strong> contains<br />

information on two springs within the Leixlip Spa site, one warm (Spa Well) and one cold. The latter<br />

being sampled through a manhole, which impl<strong>ie</strong>s that the spring and its channel were modif<strong>ie</strong>d prior<br />

to the study period which was carr<strong>ie</strong>d out between 1981 and 1982. <strong>Hydro</strong>-G attempted to identify<br />

the location of the cold spring and the sampling location, however this was unsuccessful. Some later<br />

documentation, retr<strong>ie</strong>ved from the NPWS’s archive (Ecoserve, 2006), suggests a cold spring is<br />

located in an area of the two ponds on the eastern side of the upper terrace of the Leixlip Spa,<br />

approximately 50m downhill from the Spa Well.<br />

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<strong>Hydro</strong>chemistry data (Minerex, 1983) show significant differences between the warm and cold<br />

springs suggesting strongly that both springs are recharged from two different aquifers, although<br />

deeper water may be diluted with more recent recharge on its way up to the ground surface. As well<br />

as differences in water temperature, which for the warm spring ranged from 13 to 16 °C and for the<br />

cold spring it ranged from 8 to 13 °C, differences were found in electric conductivity, total dissolved<br />

solids, concentrations of chloride, sodium, sulphates, nitrates and to a lesser extent in concentrations<br />

of calcium, magnesium and bicarbonate. The warm spring water, generally, had a sodium-chloride<br />

signature with high electric conductivit<strong>ie</strong>s (EC > 1500 µS/cm) and high total dissolved solids (TDS ><br />

1000 ppm). The cold spring water had a calcium bicarbonate signature with EC varying between<br />

700-1100 µS/cm and TDS 490-770 ppm. Chloride concentrations in the warm spring were > 450<br />

mg/l while in the cold spring they were < 50 mg/l. These differences are summarised in Table 1,<br />

which shows that the two springs belong to separate groundwater systems: a deeper system<br />

represented by the warm spring and a shallow system, dependent on more recent recharge and<br />

flowing through the upper limestone aquifer, represented by the cold spring. Full datasets are<br />

available on request from <strong>Hydro</strong>-G.<br />

Table 1 Summary of hydrochemical analysis of the warm and the cold springs at Leixlip Louisa Bridge site, 1981-<br />

1983, from Minerex, 1983<br />

Parameter<br />

Summer (August 1981) Winter (March 1982)<br />

Warm Spring Cold Spring Warm Spring Cold Spring<br />

Temperature [°C] 16.5 12.3 16.2 7.8<br />

Electric Conductivity [µS/cm] 1680 700 1800 1100<br />

Total Dissolved Solids [ppm]<br />

1176 490 1260 770<br />

Calcium [mg/l] 157 117 144 250.5<br />

Magnesium [mg/l] 35.5 20.5 34 25<br />

Sodium [mg/l] 123 25 340 42<br />

Potassium [mg/l] 7.2 3.6 6.7 3.5<br />

Bicarbonate [mg/l] 212 297 324 439<br />

Sulphate [mg/l] 63 119 55.9 397<br />

Chloride [mg/l] 447 33 483 38<br />

Nitrate [mg/l] 0.89 5.76 0.86 70<br />

Iron [mg/l] 0.36 0.26 0.11 0.29<br />

More recent water quality data for the warm spring were suppl<strong>ie</strong>d to <strong>Hydro</strong>-G by Intel Ireland (Mr.<br />

Michael Cullen). These data span from 1998 until 2006 and conform with Burdon’s results, although<br />

relatively high variations in sodium, sulphate and calcium level were noted. However, the Spa Well<br />

is continuously being polluted with litter, which could affect its water quality. Nevertheless, the Intel<br />

results confirmed high temperature, EC, TDS and chloride levels in the Leixlip Spa Well (warm<br />

spring).<br />

With respect to iron concentrations, data presented by Burdon suggest relatively high concentration<br />

with comparison to the Intel data, for which only in 3 out of 8 measurements exceeded value of 0.1<br />

mg/l. Data provided by Intel are available on request from <strong>Hydro</strong>-G.<br />

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2.4. Groundwater Quality Monitoring within Intel Ireland Ltd.<br />

Extracts from the groundwater quality monitoring <strong>report</strong>s for three monitoring boreholes located<br />

within the Intel Ireland site were also provided by Intel Ireland. Two of these wells (MW13 and<br />

MW15, Figure 3) are located approximately 400m west of the Spa Well. Another well MW14 is<br />

located adjacent to the western boundary of the site (~2m from the fence). The results presented in<br />

the <strong>report</strong> from Intel suggest different water signatures in monitoring boreholes MW13-MW15 and<br />

MW14, the difference being 5-7 times higher chloride levels in MW14 than in MW13 and MW15, and<br />

subsequently higher EC levels. This suggests that MW14 is influenced by water discharging from the<br />

Spa Well. The <strong>report</strong>s states also that chloride levels increased throughout 2006-2007 monitoring<br />

period.<br />

2.5. Additional Information<br />

During the initial site visit in December 2007, Mr Simon Wallace presented a current understanding<br />

of the flow mechanism, which suggested that water from the Spa Well is directed through an<br />

underground channel to two ponds, which, in the literature (Matthews, 2007), are referred to as<br />

‘filtering ponds’. These ponds are located approximately 50m down grad<strong>ie</strong>nt from the Spa Well and<br />

their assumed function is to filter water from the Spa Well on its way the Roman Bath, built c. 100m<br />

away from the well in direction of the Rye Water river. However, other information (Ecoserve, 2006)<br />

suggests that these ‘filtering ponds’ are actually cold springs. The suggested layout of the<br />

underground channel from the Spa Well was parallel to the Royal Canal, i.e. north eastern direction<br />

(Figure 4). In addition, a sketch map (drawing) was presented by Mr. Wallace, which showed<br />

presence of a service pipe under the upper part of the site. This pipe runs in north eastern direction<br />

from the car park, towards the ‘filtering ponds’ and, approximately 20-30m down grad<strong>ie</strong>nt from the<br />

Spa Well, it sharply turn eastwards towards and under the Royal Canal (Figure 5). <strong>Hydro</strong>-G<br />

contacted Water Services in <strong>Kildare</strong> County Council to investigate precise location, depth and<br />

circumstances of laying this pipe, but no further information was available on file. The approximate<br />

time of laying the pipe is early 1980s.<br />

<strong>Hydro</strong>-G initiated also a meeting with Mr. Niall Meagher, who is a retired architect for <strong>Kildare</strong> County<br />

Council. During that meeting, a drawing from 1981 was presented that included an underground<br />

pipe suggesting a discharge of water from the Spa Well in north western direction and later, after<br />

approximately 30m from the Spa Well, the pipe turning at 90° towards north east (Figure 3).<br />

Further literature rev<strong>ie</strong>w (Minerex, 1983) confirmed that the original outlet from the Spa Well is in<br />

north western direction (Photo 1).<br />

The above information suggests that the original discharge from the Spa Well is in north western<br />

direction, directly towards the Roman Bath. It is likely also that the underground pipe from the Spa<br />

Well was diverted in north eastern direction in 1970’s or early 1980’s.<br />

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1983 2008<br />

Photo 1 Photographs of Leixlip Spa Well from 1983 (Minerex, 1983) and from 2008 (<strong>Hydro</strong>-G).<br />

3. F<strong>ie</strong>ld Work Results<br />

The f<strong>ie</strong>ld work was designed to investigate the groundwater flow pathways within the study site and<br />

was initiated with a site walkover, during which majority of springs and seepages were identif<strong>ie</strong>d.<br />

Further investigation of these springs and seepages included examination of their physio-chemical<br />

characteristics (temperature, EC, TDS, pH) and their hydrochemical signature to establish linkage<br />

between different groundwater discharge zones. Subsequently, this facilitated development of a<br />

conceptual model of the groundwater flow throughout the site. Flow measurements were taken,<br />

where possible, to assist building the conceptual groundwater flow model.<br />

3.1. Site Observations<br />

The entrance to the site leads though a hard standing area that in the past served as a car parking.<br />

This was created in 1980’s to facilitate access to the site. However, continued misuse of the parking<br />

resulted in gating access to the car park in early 1990’s. As a result, the remnant parking area<br />

comprises partially compacted soil and partially hard standing surface.<br />

Within the SAC boundary five terraces were identif<strong>ie</strong>d, whose topography steeply dips in a northern<br />

direction. This distinct topography controls water flows within the site, which, due to the cascading<br />

nature of the bedrock, tends to overflow from one terrace to another or seep from the bedrock and<br />

through the relatively shallow soil. The features of the Leixlip Spa site are presented on Figure 4. All<br />

sampling locations were numbered as presented in Figure 4 and that is how they are referred to in<br />

this text.<br />

The first terrace extends from the site entrance to the Roman Bath. There are two ponds, an Upper<br />

Pond and a Lower Pond on the eastern extent of the site half way between the Spa Well and the<br />

Roman Bath. Historical documents (Matthews, 2007) suggest that these ponds act as filters for the<br />

spring water from the Spa Well on its way to the Roman Bath. As such, these ponds are often<br />

referred to as ‘filtering ponds’. However, marshy vegetation and presence of tufaceous deposits<br />

surrounding the ponds suggests water rich in calcium bicarbonate seeping through the ground in this<br />

location. There are no bedrock exposures at this terrace and the ground looks relatively dry, i.e. free<br />

draining except for the fen-wetland pocket around the ‘filtering ponds’. Behind the western edge of<br />

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this terrace, there is a deep drop in elevation, which is a natural feature although deepening by<br />

approximately 1m did occur in 1990’s to prevent people from entering the Intel site from the Leixlip<br />

Spa site (pers. comm. with Mr Cullen, Intel Ireland). After the Roman Bath end of this terrace, the<br />

topography drops significantly.<br />

The second terrace comprises a narrow strip with water flowing overland at its eastern side. This<br />

water originates from two streams that flow out from the Lower Pond of the first terrace. Water<br />

discharges into this terrace also from the outlet from the Roman Bath. This terrace is generally wet<br />

and it is difficult to distinguish whether water comes from the overland flow only or also seeps from<br />

the ground. Large amounts of calcium carbonate (tufa, calcite) are present in numerous locations on<br />

the ground surface. Well structured calcite can be found on a slope where water cascades from the<br />

two streams formed after the Lower Pond. However, small p<strong>ie</strong>ces of tufa can be also found on the<br />

ground throughout the terrace, which suggests that water seeps also directly from the ground.<br />

Flows are relatively strong at this terrace. However, sloping topography rules out measuring of<br />

these flows.<br />

The third terrace contains a small pond surrounded by wetland vegetation. Bedrock outcrops are<br />

visible and large calcite deposits can be found in various locations, but specifically in eastern parts of<br />

the pond (referred thereafter as ‘tufa pond’). A large hole was found in the bedrock face, on the<br />

eastern side of the terrace, and a distinct water discharge was recorded in this location.<br />

The fourth terrace covers an extensive area between (and beneath) the ‘tufa pond’ and the river<br />

floodplain. This terrace is overgrown with rush-like vegetation and the ground is soft and soggy.<br />

Water movement on this terrace is through numerous small streams, which run towards the river.<br />

Two major streams were recorded, one on the eastern end and one on the western end of the<br />

terrace.<br />

The floodplain constitutes the fifth terrace. A walkover survey was conducted. Streams were<br />

identif<strong>ie</strong>d discharging into the river. No distinct springs were identif<strong>ie</strong>d. However, this terrace is<br />

overgrown with dense reed-type vegetation. Other terraces are grass-moss covered. This area was<br />

grazed historically but this practice was discontinued in the 1980’s.<br />

3.2. Water Flow within the Site including Spring and Seepage Locations<br />

The following springs and seepages were identif<strong>ie</strong>d during the <strong>Hydro</strong>-G’s site visits:<br />

1. The Spa Well – a warm spring at the most elevated, southern end of the site;<br />

2. Cold seepage springs at the east side of the first terrace (in vicinity of ‘filtering ponds’);<br />

3. Cold springs at the third terrace. There are numerous springs at this level. Distinct water<br />

discharges were identif<strong>ie</strong>d at the southern verge of the ‘tufa pond’ and through a large hole<br />

in the bedrock face (0.3m x 0.4m) at the eastern side of the rock cliff and from the ground<br />

on the western side of the site;<br />

4. No distinct seepages and springs were identif<strong>ie</strong>d at the fourth terrace. However, tufa<br />

deposition is common in a base of small streams that run on both western and eastern sides<br />

of the site. More solid deposits were identif<strong>ie</strong>d in places where the topographic grad<strong>ie</strong>nt is<br />

high and water cascades from one step to onother.<br />

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The general flow pattern noted during the site visits is that water discharges from the Spa Well<br />

(monitoring point 9, Figure 4) and drains underground in northern direction towards the two ‘filtering<br />

ponds’ (monitoring points 12-17) which create a small fen wetland on the eastern side of the first<br />

terrace. At the point where the underground drain from the Spa Well surfaces (monitoring point 8),<br />

a man made structure houses a 16” diameter pipe and a loud sound of cascading water was recorded<br />

to come from inside this pipe. A small spring (monitoring point 7) was noted immediately adjacent<br />

to the east of the 16’’ pipe (monitoring point 8). A large deposit of precipitated iron was recorded at<br />

the monitoring point 7. These two water sources (monitoring points 7 and 8) constitute a stream<br />

that flows for approximately 10 metres and then disperses into the wetland area (monitoring points<br />

12-17). There are two distinct ponds here, referred to as Upper and Lower; however, the eastern<br />

side of these ponds (at the Canal’s boundary) remains also waterlogged (monitoring point 18). From<br />

the Lower Pond water flows through a narrow stream (monitoring point 6), splits into two smaller<br />

streams (monitoring points 19 and 20) and flows over the ground into the second terrace. An<br />

underground pipe connects the Roman Bath (monitoring point 5) with either the Lower Pond directly<br />

or with the small stream discharging from it. The Roman Bath is located between (mid-way) the first<br />

and the second terrace. Water outflows from the Roman Bath into the second terrace through a<br />

sluice and then flows over ground into the third terrace. Additional groundwater sources were<br />

recorded at the third terrace and included a big opening in the rock face (monitoring point 3), which<br />

reveals the conduit nature of a very shallow bedrock with groundwater discharge into the site.<br />

Fractures are common in upper horizons of limestone bedrock and this assists discrete distribution of<br />

numerous springs at this level, which flow into and throughout a shallow ‘tufa pond’ located in the<br />

central area. From here, water flows on the surface through numerous small streams and seeps<br />

through the shallow soil. The general high topographic grad<strong>ie</strong>nt of the site extorts relatively fast flow<br />

rates and this facilitates escape of CO2 from water at all terraces, which in turns causes calcite<br />

precipitation from groundwater. It is apparent though, that although calcite precipitation occurs in<br />

the vicinity of the ‘filtering ponds’ at the first terrace, it is much more abundant at the second and<br />

third terraces where big consolidated p<strong>ie</strong>ces of tufa can be found. This is usually associated with<br />

high topographic grad<strong>ie</strong>nts. At the base of the fifth terrace, water was found in two streams at both<br />

western and eastern boundar<strong>ie</strong>s of the site (points 1 and 2). These streams discharge into the river<br />

Rye Water.<br />

3.3. <strong>Hydro</strong>chemical Analyses<br />

3.3.1. Introduction<br />

Water samples were collected from a var<strong>ie</strong>ty of monitoring locations in December 2007 and January<br />

2008. However, the 2007 sample results were compromised by laboratory equipment failure.<br />

Therefore, only the January 2008 results could be used. The parameters were chosen in order to<br />

distinguish hydrochemical signatures of analysed water samples. Eight (8 no.) water samples were<br />

collected and the parameters analysed included ions of calcium, magnesium, nitrate, sodium,<br />

potassium, sulphate, ortho-phosphate, chloride, iron (dissolved and total), carbonate, bicarbonate,<br />

alkalinity and total hardness. In addition, <strong>Hydro</strong>-G carr<strong>ie</strong>d out a physiochemical monitoring at 23<br />

locations throughout the site. Sampling locations are presented on Figure 4. The analysis was<br />

undertaken along the south - north transect. F<strong>ie</strong>ld and laboratory data as well as the full<br />

interpretation of hydrochemical analyses are presented in Appendix B. The interpretive summary is<br />

presented below.<br />

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3.3.2. <strong>Hydro</strong>chemical Interpretative Summary<br />

The physiochemical monitoring carr<strong>ie</strong>d out in situ revealed significant differences in water<br />

characteristics throughout the site during two sampling occasions (10/12/2007 & 16/01/2008) and<br />

this suggests presence of different sources of water within the site.<br />

It is evident that water temperatures decrease from the south to north direction, as does the electric<br />

conductivity. The relative increase in both water temperature and EC that was recorded in the ‘irony<br />

spring’ (monitoring point 7) suggests small leakage from the canal. In the next, further down<br />

grad<strong>ie</strong>nt sampling location, it was also noted that both the temperature and EC were higher in the<br />

Upper Pond than in the Lower. In addition, lower temperature and EC in localised places around the<br />

ponds suggest multiple sources of water at these locations, i.e cold springs which mix with warmer<br />

water coming from the Spa Well. These cold springs are likely to originate in the shallow system,<br />

which is expected to be cooler and less mineralised in comparison to water discharging from the<br />

deeper system at the Spa Well. Abundance of calcite precipitated in this area and specifically around<br />

the Lower Pond (monitoring point 18) suggests that groundwater discharges at this location.<br />

Integration of f<strong>ie</strong>ld data suggests that while the Upper Pond is fed by the Spa Well, the Lower Pond<br />

also has inputs from the shallow groundwater system.<br />

Water flow on the second terrace is by flow along the ground surface, which prevented monitoring of<br />

physio-chemical parameters.<br />

At the third terrace, there was an abundance of water flow and sources. Water was noted to enter<br />

from both overland flow and also from various sources directly in the ground and bedrock face.<br />

There were two sampling points on the fourth terrace but these were located within formed surface<br />

water channels. No direct groundwater discharge points were identif<strong>ie</strong>d.<br />

The drain on the Intel site at the western boundary of the Leixlip Spa site contains water at its<br />

northern end only, which finishes at the approximate elevation of the Roman Bath (monitoring point<br />

24). <strong>Hydro</strong>chemical data from this location suggested water originating from surface runoff.<br />

With respect to total dissolved solids (TDS), these were found generally high at all terraces ~700-<br />

1000 ppm and its distribution at different locations is similar to that of electric conductivit<strong>ie</strong>s.<br />

All the sampling locations showed alkaline conditions and were lowest in the Spa Well water.<br />

Subsequently, lower pHs were also found in places linked to the underground discharge from the Spa<br />

Well (monitoring points 8 and 11). Higher pH levels were found in places associated with cold<br />

springs and that supports the hypothesis that this water originates from the shallow system which is<br />

in contact with the alkaline bedrock. At lower terraces, the pH was generally higher.<br />

All laboratory samples collected at the Leixlip Spa site show very high mineralisation. The ionic<br />

balance analysis based on the hydrochemistry results showed that the majority of samples are of<br />

sodium-chloride (Na-Cl) signature, except for one sample – the Intel drain, which presented calcium<br />

bicarbonate character (Ca-HCO3). The sodium-chloride water signature dominates at this site<br />

because of high concentrations of chloride delivered to the site from the Spa Well. Sodium-chloride<br />

water is associated with older groundwater (Minerex, 1983). This type of water was found at<br />

monitoring locations on all terraces of the site; from the discharge drain feeding from the Spa Well to<br />

the wetland ponds area, in the Roman Bath and as far down as at the boundary between the fourth<br />

terrace and the flood plain. The fact that all samples from the Lexlip Spa site are of the same<br />

character suggests that majority of water originates from the Spa Well, although some dilution with<br />

more recent, less mineralised water is evident. This is specifically reflected in decreasing chloride<br />

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concentrations as you move in a northerly direction towards the river Rye Water. The different<br />

character of water in the Intel drain suggests that its origin is surface runoff rather than groundwater<br />

drained from the Leixlip Spa site. These findings relate to monitoring conducted in<br />

December/January, which in hydrological terms represents a recharge period. Seasonal variations<br />

may occur and can be determined by further monitoring.<br />

3.4. Assessment of Flow Volumes<br />

In addition to the hydrochemical analysis, water flow rates were assessed in three locations to<br />

evaluate quantity of water discharged into and within the site. This was carr<strong>ie</strong>d out in the stream<br />

feeding the ‘filtering ponds’ (above the Upper Pond, monitoring point 11), in the stream discharging<br />

from the ‘filtering ponds’ (below the Lower Pond, monitoring point 6) and at the entrance to the<br />

Roman Bath (monitoring point 5). Due to physical restrictions that limited conventional flow<br />

measurements, these measurements should be taken as approximate values only.<br />

In the stream feeding the ‘filtering ponds’ (monitoring point 11) the flow was determined at 9.05<br />

m 3 /hr.<br />

In the stream discharging from the ‘filtering ponds’ (monitoring point 6) the flow was measured at<br />

6.14 m 3 /hr.<br />

At the inflow to the Roman Bath (monitoring point 5) the flow was determined at 3.06 m 3 /hr.<br />

F<strong>ie</strong>ld measurement suggest that water flows in the area of the ‘filtering ponds’ are dispersed and<br />

some seepage occurs into the bedrock, reappearing at lower terraces. These flow mechanisms could<br />

contribute to the high concentrations of chloride in the Intel’s monitoring borehole MW14. Seepages<br />

and interflows in the subsoil and upper limestone move throughout the site, mix with other<br />

groundwater sources, cold springs and rainfall to create a variable habitat controlled by hydrology.<br />

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4. Conceptual Model of Leixlip Spa Flow Patterns<br />

The observed flow patterns throughout the site were detailed in Section 3.2. Based on the<br />

physiochemical monitoring, hydrochemical analyses and flow rate assessments at the Leixlip Spa<br />

site, the following model of the hydrological regime is proposed:<br />

Water at the Leixlip Spa site originates from a complex groundwater system combining two<br />

sources: a deeper, older and warmer groundwater system, discharging at the top of the first<br />

terrace through the Spa Well; and a more recent, shallow groundwater that flows through the<br />

karstif<strong>ie</strong>d limestone bedrock with the main groundwater discharge located in the vicinity of the<br />

‘filtering ponds’. Rainfall runoff also plays a part.<br />

<strong>Hydro</strong>chemical analysis suggests that groundwater discharging from the warm spring at the<br />

Spa Well is highly mineralised and is the dominant source of water within the site. It is also<br />

evident that warm water discharging from the Spa Well drains northwards and flows into and<br />

through the shallow system, resulting in water being mixed with more recently recharged water.<br />

Groundwater flow in the shallow system also travels through conduits, one of which is evident of<br />

the east side of the face of the terrace bounding the 2nd and 3rd terraces. Due to the steep<br />

topography of the site, shallow depth of subsoil (if any) and karstic nature of bedrock,<br />

groundwater can easily discharge through rock faces and later flow over ground toward the river<br />

Rye Water.<br />

The main source of water for the site is that from the warm spring known as the Spa Well.<br />

This water flows out of the well in northern direction through an underground drain. It is possible<br />

that this drain originally ran in a north westerly direction directly to the Roman Bath. However,<br />

this design was modif<strong>ie</strong>d before 1981 and the drain was diverted towards the north east direction<br />

towards the two ‘filtering ponds’.<br />

It is possible that the original positioning of the underground drain linking the Spa Well and<br />

the Roman Bath, in a north western direction, was designed to bypass the cold springs (‘filtering<br />

ponds’) to avoid mixing with cooler water discharging from the upper bedrock. However, lack of<br />

any evidence of these cold springs on the 6 inch maps, which are usually very accurate for spring<br />

discharges, suggests that the cold spring could have resulted from digging out the substrate,<br />

which subsequently enhanced seepage and created the fen wetland habitat.<br />

Site layout drawings of the 1980’s (Meagher) suggest hat the drying out of the grass wetland<br />

on the Intel side of the 1 st terrace may be attributed to repositioning of underground drains and<br />

pipes rather than construction of the drain within Intel’s boundary. Further, water quality in the<br />

Intel drain shows different hydrochemical signature than samples collected within the Leixlip Spa<br />

site suggesting that this water originates from surface runoff. Very little or no water in the drain<br />

suggests that this depression does not act as a drainage channel and as such is unlikely to draw<br />

water from the grassland <strong>report</strong>ed to be drying out.<br />

A cold spring is also located at the ‘filtering ponds’. Based on the disperse distribution of<br />

precipitated calcite at the ground surface around the cold spring, it is likely that there are many<br />

groundwater discharge points in this area, however the most pronounced is that at the northern<br />

end of the Lower Pond. Analysis of flow volumes suggested also that some seepage occurs into<br />

the bedrock in the area of the ‘filtering ponds’, reappearing at lower terraces. Seepages and<br />

interflows in the subsoil and upper limestone move throughout the site and mix with other<br />

groundwater sources, cold springs and rainfall to create a variable habitat controlled by<br />

hydrology.<br />

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There are two distinct water sources at the physical location where the drainage pipe from<br />

the Spa Well appears at ground level. Observations and f<strong>ie</strong>ld monitoring data suggest a small,<br />

but not significant, leakage from the canal.<br />

A number of discrete springs were noted at the 2 nd and 3 rd terraces. Water oozes from the<br />

ground and through the cliff face. The physio-chemical analysis suggests that this water is a<br />

mixture of the Spa Well water and the shallow system groundwater. F<strong>ie</strong>ld data suggests that the<br />

Spa Well directly influences some conduit flows that are relatively distant from the Spa Well itself.<br />

Water flow in the 4 th and 5 th terraces (floodplain) originates mainly from surface runoff<br />

contributions from the more elevated upper terraces. No springs were identif<strong>ie</strong>d within the 4th or<br />

5th terrace.<br />

F<strong>ie</strong>ld data suggest that the Intel boundary drain does not currently act as a drainage channel<br />

drawing groundwater from the wet-grassland habitat which has been <strong>report</strong>ed to be drying out.<br />

Data from a groundwater monitoring well on the Intel site suggests that water from the deeper<br />

groundwater system on the Leixlip Spa site influences hydrochemistry at that location.<br />

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5. Conclusions and Recommendations<br />

5.1 F<strong>ie</strong>ld monitoring and data analysis suggest that water at the Leixlip Spa site originates from<br />

a complex groundwater system combining two sources.<br />

5.2 The main source of water comes from a deeper, older and warmer groundwater system,<br />

discharging through the Spa Well at the top of the first, most elevated, southern<br />

terrace. The second is a more recent, shallow groundwater that flows through the<br />

karstif<strong>ie</strong>d limestone bedrock with the main groundwater discharge located in the<br />

vicinity of the ‘filtering ponds’, which are also on the first terrace. Overland flow is<br />

also apparent.<br />

5.3 The majority of groundwater discharge locations were identif<strong>ie</strong>d within the 1st terrace.<br />

However, some discrete groundwater discharges exist also at the 2nd and 3rd<br />

terraces. No springs were identif<strong>ie</strong>d within the 4th or 5th terrace (floodplain).<br />

5.4 Rev<strong>ie</strong>w of historical information revealed that the upper (1st) terrace underwent a ser<strong>ie</strong>s of<br />

modifications which are likely to have altered the original, natural groundwater<br />

pathways within the site. The original outflow from the Spa Well was in the north<br />

westerly direction. The historical evidence suggests that the outflow was diverted<br />

towards the north easterly direction in late 1970s or early 1980s. Subsequently,<br />

water from the Spa Well flows towards the cold springs (‘filtering ponds’). The<br />

implication of such engineering is limitation in water delivery to the western side of<br />

the 1st terrace manifested in drying of this wet-grassland habitat. To verify this<br />

hypothesis, further investigation is necessary and this could, for example, include<br />

geophysical or drain camera surveys that would determine the original layout of the<br />

Spa Well discharge pipe. It is also possible that diversion of the groundwater flow<br />

away from the western side of the 1st terrace occurred unintentionally during sewage<br />

works undertaken in 1980s. Knowledge of the exact location of service pipes within<br />

the upper extent of the site would also benefit the conceptualisation of groundwater<br />

flows at this location. If this hypothesis is confirmed, the subsequent mitigation<br />

measures would include reengineering the pipe layout so they could allow the Spa<br />

Well discharge to flow in north – north westerly direction. However, this will result in<br />

a reduction of groundwater flow towards the cold springs (‘filtering ponds’) and is<br />

likely to impact on the local ecology surrounding the ‘filtering ponds’ which have<br />

adjusted to present conditions over time. Considering a probable local recharge of<br />

the cold springs, redirection of the groundwater discharge from the Spa Well might<br />

cause an increase in seasonal variation in water levels in the ‘filtering ponds’ area<br />

and could cause seasonal drying of the fen wetland. <strong>Hydro</strong>chemical changes could<br />

also occur. Redirection of the outflow from the Spa Well, away from the ‘filtering<br />

ponds’, will also reduce the volume of water cascading to the second terrace at the<br />

eastern side and this will affect distribution of water at down grad<strong>ie</strong>nt terraces. This<br />

is likely to be compensated by more water flowing on the western side but is likely to<br />

lead to habitat transformations on a local scale.<br />

5.5 F<strong>ie</strong>ld data suggest that the Intel boundary drain does not currently act as a drainage<br />

channel drawing groundwater from the wet-grassland habitat which has been<br />

<strong>report</strong>ed to be drying out. Data from a groundwater monitoring well on the Intel site<br />

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suggests that water from the deeper groundwater system on the Leixlip Spa site<br />

influences hydrochemistry at that location.<br />

5.6 The re-wetting of the western side of the first terrace could be potentially ach<strong>ie</strong>ved by<br />

reengineering of the surface run-off from the area upgrad<strong>ie</strong>nt from the first terrace.<br />

This area is currently hard standing with surface runoff flowing both westwards and<br />

northwards, following the topographic grad<strong>ie</strong>nt. Rainwater is collected therefore<br />

either in the Intel drain or infiltrates into the ground at the top of the first terrace.<br />

This water could be however conserved and directed towards the western parts of<br />

the first terrace where it could seep into the, currently drying, grassland habitat.<br />

5.7 With respect to the lowest terrace, which was <strong>report</strong>ed to be drying out, the desktop rev<strong>ie</strong>w<br />

and interv<strong>ie</strong>ws undertaken during the study have not revealed any structural changes<br />

in either local hydrology or hydrogeology. Therefore, the most probable cause of<br />

these changes is natural habitat transformation resulting from plant growth,<br />

increased evapotranspiration needs and accumulation of organic matter, which<br />

subsequently resulted in increased ground level in places. Cessation of grazing may<br />

have contributed to the vegetation overgrowth of this floodplain.<br />

5.8 This study was executed in the months of December and January, which is a recharge<br />

period and groundwater levels are expected to be at their highest. Considering the<br />

complexity of the Leixlip Spa system combining two groundwater sources, one deep<br />

and one shallow, the relative contribution of water from these sources may differ<br />

seasonally and this can further affect hydrochemistry on a local scale. It is advised<br />

therefore that if it is decided to re-engineer the site in any way, the site’s<br />

hydrological characteristics when groundwater levels recede (summer) requires<br />

characterisation.<br />

5.9 With respect to the future water management strategy for the Leixlip Spa site, the evidence<br />

collected suggest that alteration of the pipe network at the first, most southern,<br />

terrace may result in significant changes to the hydrological regime of the ‘filtering<br />

ponds’, which is difficult to predict quantitatively. Considering that the habitat in the<br />

vicinity of the ‘filtering ponds’ is of high ecological value, interference with the pipe<br />

layout does not seem prudent from a hydrological perspective. A management<br />

strategy is recommended for the floodplain area; however, this should focus on<br />

controlling plant growth and restricting accumulation of the organic matter.<br />

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REFERENCES<br />

Ecoserve (2006) Development of baseline ecological dataset for selected warm springs in Ireland.<br />

www.ecoserve.<strong>ie</strong>. Source: National Parks and Wildlife Service<br />

Gardiner (1980) Ireland. General Soil Map. Second Edition. An Foras Taluntais<br />

GSI (2007) Dublin Groundwater Body. Summary of Characterization. Unpublished<br />

Matthews N. (2007) The conservation of the Spa Well, at Louisa Bridge, Leixlip, Co.Kiladare. Report<br />

to <strong>Kildare</strong> County Council.<br />

Mc Connell B., Philcox M., Sleeman A., Stanley G., Flegg A., Daly E. Warren W. (1994). Geology of<br />

<strong>Kildare</strong> - Wicklow, Sheet 16, Geological Survey of Ireland<br />

Meagher N. (1976) Leixlip Spa. Information booklet.<br />

Minerex (1983) Irish Geothermal Project. Report to Geological Survey of Ireland.<br />

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FIGURES<br />

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5 km<br />

Site Location<br />

Figure 1 Location of the Leixlip Spa site, (OS LicenceEN0043207)<br />

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5 km<br />

Site Location<br />

Figure 2 Geology in vicinity of the Leixlip Spa site. Source: www.gsi.<strong>ie</strong><br />

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Figure 3 Location map of Intel's groundwater monitoring wells. Source: Intel Ireland.<br />

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Figure 4 Site location including physio-chemical monitoring points, Leixlip Spa, Co. <strong>Kildare</strong><br />

Project No.: 07_136 -22-<br />

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EASTON<br />

LEIXLIP<br />

Figure 5 Layout of the drainage at Leixlip Spa. Source: <strong>Kildare</strong> County Council<br />

CONFEY<br />

Leixlip<br />

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Appendix A<br />

Leixlip Spa: Phase One Report<br />

Source: <strong>Hydro</strong>-G, 2007<br />

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Mr. Simon Wallace<br />

Senior Executive Parks Superintendent<br />

<strong>Kildare</strong> County Council<br />

Dear Simon<br />

Re: Preliminary <strong>report</strong> on the hydrological investigation of Leixlip Spa, Co. <strong>Kildare</strong><br />

Our Ref: 07136_Leixlip Spa_D07<br />

17 th Dec 2007<br />

This <strong>report</strong> has been prepared by <strong>Hydro</strong>-G to inform <strong>Kildare</strong> County Council on a progress of the initial assessment of<br />

hydrological requirements of the Leixlip Spa SAC (code 001398). The <strong>report</strong> outlines site visits and f<strong>ie</strong>ld work<br />

investigations carr<strong>ie</strong>d out to date. An interpretation of results will be provided at a later date when the results of the<br />

sampling regime are processed and hydrochemical results returned from the laboratory.<br />

In November 2007 <strong>Hydro</strong>-G was approached by <strong>Kildare</strong> County Council to undertake an investigation on the<br />

hydrological regime of Leixlip Spa, Co. <strong>Kildare</strong>. The site is located in Leixlip village, along the western side of the Royal<br />

Canal and between a regional road R 148 and the Rye River. The western boundary of the site is adjacent to the Intel<br />

factory. The ecological features of the site comprise a wide range of protected spec<strong>ie</strong>s and habitats including<br />

petryfying tufa springs (SAC Site Synopsis 001398) and alkaline fen habitat. These habitats rely on a stable discharge<br />

of groundwater saturated with calcite carbonate. Although it is well understood that the rare habitats and spec<strong>ie</strong>s<br />

found at the Leixlip Spa are dependent on the hydrological regime of the site, the latter is not well understood and very<br />

limited data on the site hydrology exist at present. Neither quantitative nor qualitative data are available.<br />

The site is located on a steep limestone ridge which is a remnant of a quarry created in the late 18 th century. The most<br />

prominent hydrological feature of the site is a warm spring located at the entrance to the site, east of the public<br />

pathway leading into the site. The spring was discovered in late 18 th century and merits attention due to the relatively<br />

high temperature and iron content in the water that it discharges.<br />

To date, <strong>Hydro</strong>-G conducted two site visits the first on the 2 nd and latter on the 10 th of December 2007. The purpose of<br />

these visits was to meet with ecologists involved in works on the site, namely Mr Declan Doogue, Mr Brendan<br />

O’Hanrahan and Ms Evelyn Moorkens. These site meetings facilitated greater understanding of the site’s ecology and<br />

its hydrological needs for sustaining a healthy habitat. It was established during these visits that ecological features<br />

have changed throughout the past 20-30 years of ecological monitoring. Specifically, the following two issues had<br />

been raised:<br />

• Drying of the upper zone, west of the gravel pathway. Historically this area provided a suitable habitat for wet<br />

loving grasses and marsh orchids. However Mr Declan Doogue <strong>report</strong>ed this area had not been wet in<br />

winters within the past 20 years which led to loss of this habitat.<br />

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• Deterioration of the floodplain quality. Historically, this zone provided a suitable habitat for two rare spec<strong>ie</strong>s of<br />

molluscs listed in Annex II Habitats Directive, namely Vertigo angustior and Vertigo moulinsiana. While V.<br />

moulinsiana seem to enjoy current state of the habitat, decreasing numbers of Vertigo angustior suggest and<br />

on-going unfavourable change of this habitat. Dr Evelyn Moorkens <strong>report</strong>ed increasing density of grasses<br />

which suggest that the site is undergoing a drying trend. It has also been noted that ground level has<br />

increased with obvious decomposed organic matter.<br />

A one day f<strong>ie</strong>ld investigation was carr<strong>ie</strong>d out by <strong>Hydro</strong>-G on the 10 th of December 2007. This investigation focused on<br />

identification and classification of discharge zones within the study site. The site was surveyed for physio-chemical<br />

parameters, which were recorded at 23 locations. It is apparent from this investigation that water discharges through<br />

numerous springs and seepages along the S-W transect and at all terraces. Differences in physio-chemical<br />

characteristics suggest mixing of water from possibly more than one source which will be further interpreted by detailed<br />

hydrochemical analysis. A total of 10 no. of water samples were collected and were delivered to an accredited<br />

laboratory for hydrochemical analysis. These samples are currently being analysed for major anions and cations to<br />

allow for ionic balance determination. Additionally major nutr<strong>ie</strong>nt levels will be established, including potassium,<br />

nitrates and ortho-phosphates. <strong>Hydro</strong>-G will integrate the results of the in situ physio-chemical monitoring programme<br />

with the results of the hydrochemical analyses and design the next stage of f<strong>ie</strong>ld investigations accordingly.<br />

This initial site investigation also mapped discharge locations within the site. These will be investigated again during<br />

the 2 nd site visit, planned for January 2008, to allow for quantitative analysis of flows throughout the site. It is hoped<br />

that such approach, bound with hydrochemical results will facilitate development a conceptual model of the<br />

hydrological regime within the site. This model will inform recommendations regarding future monitoring and<br />

conservation of the site.<br />

It is apparent that the site has undergone numerous modifications in the past. Modifications within the site include the<br />

installation of service pipes running through the upper part of the site and construction of a gravel access path.<br />

Modifications external, but adjacent to the Leixlip Spa site, include the construction of the Intel factory during which<br />

time large embankments and a drainage ditch were installed alongside the western boundary of the Leixlip Spa site.<br />

These events must be chronologically structured and compared with the observations of the ecologists. Thus, the<br />

January 2008 works will include liaison with the site’s ecologists, the site architect, Intel representatives, <strong>Kildare</strong><br />

County Council Water Services, GSI and NPWS.<br />

We trust that the above is to your satisfaction. Should you wish to discuss any matters please feel free to contact me<br />

directly on (091) 704841.<br />

Yours truly<br />

__________________________<br />

Ania Kuczynska B.Eng, M.Sc.<br />

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Appendix B<br />

Leixlip Spa - <strong>Hydro</strong>chemical Analysis<br />

Source: <strong>Hydro</strong>-G, 2007/2008<br />

and Complete Laboratory Solutions, Ros Muc, Co. Galway<br />

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Temperature, Electric Conductivity and Total Dissolved Solids<br />

It is evident that water temperatures decrease from the south to north direction, as does the electric<br />

conductivity. The highest temperatures and ECs were recorded in the Spa Well (monitoring point 9,<br />

T=13.5-15°C, EC = 1900-2000 µS/cm) and in the outflow from the underground drain (monitoring<br />

point 8). In the small ‘irony spring’ (monitoring point 7) both water temperature and EC were<br />

recorded at much lower levels (T = 8-10 °C, EC=~750 µS/cm), which were comparable with the<br />

Royal Canal conditions (monitoring point 10; T=5.9°C and EC= 617µS/cm; 10/12/2007) and as such<br />

suggest leakage from the canal. In the next, further down grad<strong>ie</strong>nt, location in vicinity of the<br />

‘filtering ponds’ temperatures and ECs var<strong>ie</strong>d spatially across relatively small distances and were<br />

highest in central points in both ponds and lower at more outer locations. It was also noted that<br />

both the temperature and EC were higher in the Upper Pond than in the Lower and that EC measured<br />

in the Lower Pond on the second occasion were significantly lower than the first time in December.<br />

The depth of water in these ponds was investigated to reveal that both ponds are relatively shallow<br />

with 0.45m depth in the Upper Pond and 0.25m in the Lower Pond. F<strong>ie</strong>ld investigations suggest that<br />

these ponds are underlain directly with bedrock. Lower temperature and EC in localised places<br />

suggest multiple sources of water at these locations, i.e cold springs which mix with warmer water<br />

coming from the Spa Well. These cold springs are likely to originate in the shallow system which is<br />

expected to be cooler and less mineralised in comparison to water discharging from the deeper<br />

system at the Spa Well. Abundance of calcite precipitated in this area and specifically around the<br />

Lower Pond (monitoring point 18) suggests that groundwater discharges at this location. Integration<br />

of f<strong>ie</strong>ld data suggests that while the Upper Pond is fed by the Spa Well, the Lower Pond also has<br />

inputs from the shallow groundwater system. Monitoring results down grad<strong>ie</strong>nt of the ‘filtering<br />

ponds’ show temperatures at approximate level of 8-9 °C and EC at around 1750-1850 µS/cm (lower<br />

than in the Spa Well by ~5 °C and ~200 µS/cm).<br />

Water flow on the second terrace is by flow along the ground surface. This prevented monitoring of<br />

physio-chemical parameters. There is an abundance of ad hoc streams wherever topography allows.<br />

Large depositions of calcite were noted where water drops from the first terrace into the second<br />

terrace. Increased flow velocit<strong>ie</strong>s and more dispersed nature of flow increases the release of the<br />

CO2 from the water, which facilitates higher calcite precipitation rates in this location.<br />

At the third terrace, there was an abundance of water flow and sources. It is likely that not all<br />

discharge points were identif<strong>ie</strong>d. Water was noted to enter from both overland flow and also from<br />

various sources directly in the ground and bedrock face. Discharge from the bedrock face at the<br />

eastern side of the terrace (monitoring point 3) had relatively low temperatures (7-8 °C) and high EC<br />

values at ~ 1600µS/cm. Some deposition of iron was also noted in the opening in the bedrock,<br />

suggesting high iron content in water. Two other small outflows from the base of the bedrock were<br />

also noted; one in a shallow pool of water where distinct p<strong>ie</strong>ces of tufa are present (‘tufa pond’,<br />

monitoring point 22) and the second 1m above this pool (too shallow to measure physio-chemistry).<br />

Physio-chemical characteristics of the ‘tufa pond’ were: T at 6.3 - 8.3°C and EC at ~1480 µS/cm.<br />

There were two sampling points on the fourth terrace; one on the west side (monitoring point 1) and<br />

one at the east side (monitoring point 2). On the east side, water forms a stream of 0.15m width and<br />

0.05m depth and the flow is relatively fast. Deposits of tufa are present in the bed of the stream.<br />

Measured temperatures were 5.5 - 6.8°C on the west side and 6.6 - 6.9°C on the east side. Electric<br />

conductivity averaged 1550 µS/cm.<br />

The drain on the Intel site at the western boundary of the Leixlip Spa site contains water at its<br />

northern end only, which finishes at the approximate elevation of the Roman Bath. Water in this<br />

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drain (monitoring point 24) was also sampled and showed temperature of 8.34°C and electric EC of<br />

651µS/cm suggesting water originating from surface runoff.<br />

With respect to total dissolved solids (TDS), these were found generally high at all terraces ~700-<br />

1000 ppm and its distribution at different locations is similar to that of electric conductivit<strong>ie</strong>s.<br />

pH Level<br />

All the sampling locations showed alkaline conditions ranging from 7.15 to 9.48 pH on the 10th of<br />

December 2007 and from 7.29 to 8.74 on the 16th of January 2008. In the Spa Well (monitoring<br />

point 9) the pH was recorded at 7.15 and 7.99 and was relatively low in comparison to other<br />

locations. Subsequently, lower pHs were also found in places linked to the underground discharge<br />

from the Spa Well (monitoring points 8 and 11), where they were measured at 7.27-7.75. The Royal<br />

Canal (monitoring point 10) sample showed pH of 8.25 and the ‘irony spring’ (monitoring point 7)<br />

7.29. In the ‘filtering ponds’ (monitoring points 12-17) pH tended to exceed 8 on both occasions.<br />

Similar pH was found at the entrance to the Roman Bath (point 5) where it was measured at 8.52<br />

and 8.32 respectively. Higher pH in places associated with cold springs supports the hypothesis that<br />

this water originates from the shallow system which is in contact with the alkaline bedrock. At lower<br />

terraces, the pH was generally higher, above 8.<br />

Chloride<br />

Results of the hydrochemical analysis show very high chloride levels in the majority of samples,<br />

which explains relatively high EC and TDS values measured in situ. The highest chloride levels (~350<br />

mg/l Cl) were recorded at the Spa Well (monitoring point 9) and the discharge from the Spa Well<br />

(monitoring point 8). The high chloride level in the Spa Well was expected, following the literature<br />

rev<strong>ie</strong>w. Chloride concentrations decrease in a northerly direction. Samples from the bottom of the<br />

fourth terrace have Cl concentrations of ~ 260 mg/l Cl. This suggest that water collected at down<br />

grad<strong>ie</strong>nt locations from the Spa Well represent mixing conditions of water coming from the Spa Well<br />

and from other sources (rainfall, surface runoff) that have lower chloride concentrations. Relatively<br />

low concentration of chloride was found in a sample taken from the Intel drain (monitoring point 24)<br />

and was found at 65.94 mg/l. This suggests that water gathered in the ditch collects the rainfall<br />

runoff rather than groundwater that could contribute to wetlands on the site. The high chloride<br />

concentrations within the study site, abnormal for Irish conditions, are associated with water coming<br />

from deeper, warmer rocks, where chloride dissolves from certain stratograph<strong>ie</strong>s.<br />

Sodium and Potassium<br />

Sodium concentrations on the Leixlip Spa site range from 158-203 mg/l Na and followed similar<br />

pattern to that presented by chloride, i.e. the highest concentration was found in the Spa Well<br />

(monitoring point 9) and these decrease along the south-north grad<strong>ie</strong>nt. The Intel drain had lowest<br />

sodium concentration (35 mg/l Na) which suggests that water in the Intel drain does not come from<br />

the Leixlip Spa site. Potassium concentrations were relatively stable across the Leixlip Spa site (7-10<br />

mg/l K). Significantly lower concentration of potassium was found in the Intel drain (monitoring point<br />

24, 2.8mg/l K).<br />

Calcium and Magnesium<br />

Calcium and magnesium concentrations were generally similar across the whole Leixlip Spa site. The<br />

magnesium concentration was significantly lower in the Intel drain (monitoring point 24) with<br />

comparison to other sampling points.<br />

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Iron<br />

Iron concentrations var<strong>ie</strong>d throughout the site. An exceptionally high level of 20740 µg/l Fe was<br />

recorded in the wetland area (centre of the Lower Pond, monitoring point 16). Historical data<br />

(Meagher, 1976; Matthews, 2007) suggest high iron concentrations in the Spa Well water. Other<br />

elevated iron concentrations were found in the discharge from the Spa Well (monitoring point 8 -<br />

830µg/l Fe), above the Upper Pond (monitoring point 11 - 1450 µg/l Fe) and the bedrock face<br />

(monitoring point 3 -270µg/l Fe). The iron concentration in the Spa Well was found to be 150µg/l.<br />

Big differences in iron concentrations across the site are not well understood at this stage of the<br />

investigation.<br />

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Table 2 Results of in situ survey, Leixlip Spa, 10/12/2007<br />

Monitoring<br />

Point<br />

Coordinates<br />

EC<br />

µS/cm<br />

pH<br />

-<br />

Temp<br />

ºC<br />

TDS<br />

ppm<br />

DO<br />

%<br />

DO<br />

mg/l<br />

1 N53°22.348' W006°30.362' 1594 9.48 5.51 795 91.40 11.61<br />

2 N53°22.346' W006°30.323' 1533 8.51 6.6 872 90.00 11.23<br />

3 N53°22.325' W006°30.350' 1671 8.24 8.31 835 70.80 8.29<br />

4 1742 8.90 6.3 872 85.00<br />

5 N53°22.300' W006°30.362' 1845 8.52 8.02 921 97.10 11.60<br />

6 N53°22.297' W006°30.355' 1857 8.12 7.9 928 96.10 11.32<br />

7 767 7.29 11.62 375 12.30 1.33<br />

8 2004 7.27 13.18 1006 31.10 3.63<br />

9 N52°22.249' W006°30.396' 2028 7.15 13.5 1014 23.50<br />

10 617 8.25 5.9 308 82.00 10.26<br />

11 N53°22.224' W006°30.579' 1971 7.75 12.62 985 37.00 3.97<br />

12 N53°22.282' W006°30.363' 1972 8.08 10.57 986 15.10 1.64<br />

13 1891 8.14 11.1 575 63.50 7.05<br />

14 N53°22.286' W006°30.365' 1926 8.17 10.43 965 65.80 7.13<br />

15 N53°22.291' W006°30.356' 1876 7.61 7.86 937 55.70 6.92<br />

16 N53°22.294' W006°30.354' 1811 8.11 8.01 905 8.50<br />

17 N53°22.296' W006°30.357' 1716 8.10 7 859 41.89 5.05<br />

18 1862 7.90 8.8 931 10.00 1.40<br />

19 N53°22.303' W006°30.340' 1719 8.36 7.89 860 96.40 11.48<br />

20 N53°22.305' W006°30.347' 1859 8.30 7.73 930 94.30 11.22<br />

21 1372 8.17 6.31 714 13.60 1.68<br />

22 N53°22.324' W006°30.348' 1468 8.70 6.34 754<br />

23 1680 8.36 6.04 843 82.30 10.26<br />

Table 3 Results of in situ survey, Leixlip Spa, 16/01/2008<br />

Monitoring<br />

Point<br />

Coordinates<br />

EC<br />

µS/cm<br />

pH<br />

-<br />

Temp<br />

ºC<br />

TDS<br />

ppm<br />

DO<br />

%<br />

DO<br />

mg/l<br />

1 N53°22.348' W006°30.362' 1554 7.85 6.75 777 79.1 9.46<br />

2 N53°22.346' W006°30.323' 1522 8.34 6.87 761 80.6 9.64<br />

3 N53°22.325' W006°30.350' 1530 7.84 6.81 765 63.3 7.51<br />

5 N53°22.300' W006°30.362' 1709 8.32 9.75 854 82.7 9.16<br />

6 N53°22.297' W006°30.355' 1793 8.11 8.63 1237 87.5 9.94<br />

7 728 7.29 9.91 364 15.1<br />

8 1988 7.4 11.02 952 22.4 2.22<br />

9 N52°22.249' W006°30.396' 1914 7.99 14.82 955 17.3 1.7<br />

11 N53°22.224' W006°30.579' 1856 7.52 13.74 926 24.3 2.4<br />

12 N53°22.282' W006°30.363' 1813 8.25 10.52 907<br />

14 N53°22.286' W006°30.365' 1955 8.07 9.32 977 83.5 9.23<br />

15 N53°22.291' W006°30.356' 1594 8.16 9.47 796 59.5 6.48<br />

16 N53°22.294' W006°30.354' 1416 8.27 10.08 708 82.3 9.01<br />

17 N53°22.296' W006°30.357' 724 8.74 8.74 362 64 7.22<br />

19 N53°22.303' W006°30.340' 1419 8.1 9.54 710 79.5 8.84<br />

20 N53°22.305' W006°30.347' 1662 8.18 9.58 831 82.7 9.19<br />

22 N53°22.324' W006°30.348' 1491 8.31 7.69 747 77.2 9<br />

24 N53°22.314' W006°30.395' 651 8.34 5.4 325 60.5 7.39<br />

Project No.: 07_136 -31-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Table 4 Results of hydrochemical analysis, Leixlip Spa, 16/01/2008<br />

Monitoring<br />

Point<br />

Alkalinity<br />

mg/l CaCO3<br />

Total<br />

Hardness<br />

mg/l<br />

CaCO3<br />

Ca Mg HCO3 CO3 Na K SO4<br />

Project No.: 07_136 -32-<br />

Leixlip Spa<br />

Fe<br />

(dissolved)<br />

Fe<br />

(total)<br />

mg/l mg/l mg/l mg/l mg/l mg/l mg/l µg/l µg/l mg/l<br />

2 225 350.6 94 26 245


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -33-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -34-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -35-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -36-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -37-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -38-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -39-<br />

Leixlip Spa


<strong>Hydro</strong>-G FINAL REPORT<br />

Project No.: 07_136 -40-<br />

Leixlip Spa

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