Alsan RS Reiniger - Soprema

DR 

Safety data sheet 

according to 1907/2006/EC, Article 31 

Page 1/8 

Printing date 16.02.2011 Version number 11 

Revision: 07.02.2011 

* 1 Identification of the substance/mixture and of the company/undertaking 

· Product identifier 

· Trade name: Alsan RS Reiniger 

· Article number: 119-000-yyyA 

· CAS Number: 

141-78-6 

· EINECS Number: 

205-500-4 

· Index number: 

607-022-00-5 

· Registration number 01-2119475103-46 

· Relevant identified uses of the substance or mixture and uses advised against 

· Application of the substance / the preparation Cleaning agent/ Cleaner 

· Details of the supplier of the safety data sheet 

· Manufacturer/Supplier: 

Flag-Soprema UK Ltd 

Unut 640 

The Hub, 

Avenue West, 

Skyline 120 

UK-Great Notley CM77 7AA 

Tel.: +44 845 1948727 

Fax: +44 845 1948728 

www.flag-soprema.co.uk 

SOPREMA Belgium N.V. 

Bouwelven 5 

2280 Grobbendonk 

Tel.: +32 14 23 07 07 

Fax: +32 14 23 07 77 

www.sopremaalsan.be 

info@soprema.be 

· Further information obtainable from: 

Mr. Derks (Technisch Director) 

Tel.: +32 14 23 07 07 

· Emergency telephone number: 

UK - National Poisons Information Service 

Tel.: +44 191 22 5131 

Emmergency Number (24h/24h) 

Tel.: +44 870 190 67 77 

Anti Gif Centrum 

Tel.: +32 70 245 245 

2 Hazards identification 

· Classification of the substance or mixture 

· Classification according to Regulation (EC) No 1272/2008 

GHS02 flame 

Flam. Liq. 2 H225 Highly flammable liquid and vapour. 

GHS07 

Eye Irrit. 2 H319 Causes serious eye irritation. 

(Contd. on page 2) 

GB

DR 



Page 2/8 


Revision: 07.02.2011 

Trade name: Alsan RS Reiniger 

STOT SE 3 H336 May cause drowsiness or dizziness. 

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC 

Xi; Irritant 

R36: Irritating to eyes. 

F; Highly flammable 

R11: Highly flammable. 

(Contd. of page 1) 

R66-67: Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and 

dizziness. 

· Information concerning particular hazards for human and environment: 

At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent. 

· Label elements 

· Labelling according to Regulation (EC) No 1272/2008 

The substance is classified and labelled according to the CLP regulation. 

· Hazard pictograms GHS02, GHS07 

· Signal word Danger 

· Hazard-determining components of labelling: Void 

· Hazard statements 

H225 Highly flammable liquid and vapour. 

H319+EUH066 Causes serious eye irritation. Repeated exposure may cause skin dryness or cracking. 

H336 May cause drowsiness or dizziness. 

· Precautionary statements 

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse 

skin with water/shower. 

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if 

present and easy to do. Continue rinsing. 

P405 Store locked up. 

P501 Dispose of contents/container in accordance with local/regional/national/international 

regulations. 

· Other hazards 

· Results of PBT and vPvB assessment 

· PBT: Not applicable. 

· vPvB: Not applicable. 

3 Composition/information on ingredients 

· Chemical characterization: Substances 

· CAS No. Description 

141-78-6 ethyl acetate 

· Identification number(s) 

· EINECS Number: 205-500-4 

· Index number: 607-022-00-5 

4 First aid measures 

· Description of first aid measures 

· General information: Immediately remove any clothing soiled by the product. 

· After inhalation: Supply fresh air; consult doctor in case of complaints. 

· After skin contact: If skin irritation continues, consult a doctor. 

· After eye contact: 

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. 

· After swallowing: Do not induce vomiting; call for medical help immediately. 


GB

DR 



Page 3/8 


Revision: 07.02.2011 


· Information for doctor: 

· Most important symptoms and effects, both acute and delayed 

Narkose 

Headache 

Nausea 

Reizwirkung auf Haut, Augen und Atmungsorgane. 

· Indication of any immediate medical attention and special treatment needed 

No further relevant information available. 

5 Firefighting measures 

· Extinguishing media 

· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. 

· For safety reasons unsuitable extinguishing agents: Water with full jet 

· Special hazards arising from the substance or mixture 

In case of fire, the following can be released: 

Carbon monoxide (CO) 

Can form explosive gas-air mixtures. 

· Advice for firefighters 

· Protective equipment: 

Wear fully protective suit. 

Wear self-contained respiratory protective device. 

· Additional information Cool endangered receptacles with water spray. 

6 Accidental release measures 

· Personal precautions, protective equipment and emergency procedures 

Ensure adequate ventilation 

Wear protective equipment. Keep unprotected persons away. 

Keep away from ignition sources. 

· Environmental precautions: Do not allow to enter sewers/ surface or ground water. 

· Methods and material for containment and cleaning up: 

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). 

· Reference to other sections 

Es besteht Explosionsgefahr. 

See Section 7 for information on safe handling. 

See Section 8 for information on personal protection equipment. 

See Section 13 for disposal information. 

7 Handling and storage 

· Handling: 

· Precautions for safe handling Keep receptacles tightly sealed. 

· Information about fire - and explosion protection: 

Fumes can combine with air to form an explosive mixture. 

Use explosion-proof apparatus / fittings and spark-proof tools. 

Keep ignition sources away - Do not smoke. 

Protect against electrostatic charges. 

Highly volatile, flammable constituents are released during processing. 


· Conditions for safe storage, including any incompatibilities 

· Storage: 

· Requirements to be met by storerooms and receptacles: Store in a cool location. 

· Information about storage in one common storage facility: Store away from oxidizing agents. 

· Further information about storage conditions: 

Keep container tightly sealed. 

Store in cool, dry conditions in well sealed receptacles. 


GB

DR 



Page 4/8 


Revision: 07.02.2011 


· Storage class: VCI Lagerklasse 3A 

· Specific end use(s) No further relevant information available. 

8 Exposure controls/personal protection 

· Additional information about design of technical facilities: No further data; see item 7. 

· Control parameters 

· Ingredients with limit values that require monitoring at the workplace: 


WEL Short-term value: 400 ppm 

Long-term value: 200 ppm 

· Additional information: The lists valid during the making were used as basis. 


· Exposure controls 

· Personal protective equipment: 

· General protective and hygienic measures: 

Keep away from foodstuffs, beverages and feed. 

Immediately remove all soiled and contaminated clothing 

Wash hands before breaks and at the end of work. 

Avoid contact with the eyes. 

Avoid contact with the eyes and skin. 

· Respiratory protection: 

Short term filter device: 

Filter A/P2 

· Protection of hands: 

Check protective gloves prior to each use for their proper condition. 

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. 

Protective gloves 

Due to missing tests no recommendation to the glove material can be given for the product/ the 

preparation/ the chemical mixture. 

Selection of the glove material on consideration of the penetration times, rates of diffusion and the 

degradation 

· Material of gloves 

The selection of the suitable gloves does not only depend on the material, but also on further marks of 

quality and varies from manufacturer to manufacturer. 

· Penetration time of glove material 

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to 

be observed. 

Bei ersten Zeichen von Abnutzungserscheinungen sollten die Schutzhandschuhe ersetzt werden. 

Durchdringungszeit: ~ 120 min 

Empfohlene Materialstärke: ≥ 0,7 mm 

Value for the permeation: Level ≥ 4 

· For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves 

made of the following material are suitable: 

Butyl rubber, BR 

· For the permanent contact gloves made of the following materials are suitable: Butyl rubber, BR 

· Not suitable are gloves made of the following materials: 

Leather gloves 

Fluorocarbon rubber (Viton) 

Natural rubber, NR 

Nitrile rubber, NBR 

PVC gloves 


GB

DR 



Page 5/8 


Revision: 07.02.2011 


· Eye protection: 

Tightly sealed goggles 

· Body protection: 

Protective work clothing 

Solvent resistant protective clothing 

9 Physical and chemical properties 

· Information on basic physical and chemical properties 

· General Information 

· Appearance: 

Form: Fluid 

Colour: Colourless 

· Odour: Fruit-like 

· Odour threshold: Not determined. 

· pH-value at 20°C: neutral 

· Change in condition 

Melting point/Melting range: -83.57°C 

Boiling point/Boiling range: 77°C 

· Flash point: -4°C 

· Ignition temperature: 460°C 

· Decomposition temperature: Not determined. 

· Self-igniting: Not determined. 


· Danger of explosion: Product is not explosive. However, formation of explosive 

air/vapour mixtures are possible. 

· Explosion limits: 

Lower: 2.1 Vol % 

Upper: 11.5 Vol % 

· Vapour pressure at 20°C: 97 hPa 

· Density at 20°C: 0.9 g/cm³ 

· Relative density Not determined. 

· Vapour density Not determined. 

· Evaporation rate Not determined. 

· Solubility in / Miscibility with 

water at 20°C: 61 g/l 

· Segregation coefficient (n-octanol/water): 0,73 log POW 

· Viscosity: 

Dynamic at 20°C: 1 mPas 

Kinematic: Not determined. 

· Solvent content: 

Organic solvents: 100.0 % 

VOC (EC) 100.00 % 

· Other information No further relevant information available. 

GB 

(Contd. on page 6)

DR 



Page 6/8 


Revision: 07.02.2011 


10 Stability and reactivity 

· Reactivity 

· Chemical stability 

· Thermal decomposition / conditions to be avoided: 

No decomposition if used according to specifications. 

· Possibility of hazardous reactions 

Reacts violently with oxidizing agents. 

Reacts with acids, alkalis and oxidizing agents. 

· Conditions to avoid No further relevant information available. 

· Incompatible materials: No further relevant information available. 

· Hazardous decomposition products: Ethanoic acid 

* 11 Toxicological information 


· Information on toxicological effects 

· Acute toxicity: 

· LD/LC50 values relevant for classification: 


Oral LD50 5620 mg/kg (rabbit) 

Dermal LC50 >18000 mg/kg (rat) 

Inhalative LC50/4h 56 mg/l (rat) 

· Primary irritant effect: 

· on the skin: No irritant effect. 

· on the eye: Irritating effect. 

· Sensitization: No sensitizing effects known. 

· Other information (about experimental toxicology): 

Infolge des hohen Dampfdrucks wird eine gesundheitsschädliche Konzentration in der Atmluft rasch 

erreicht. Bei hohen Konzentrationen kann narkotische Wirkung auftreten. 

12 Ecological information 

· Toxicity 

· Acquatic toxicity: 


EC50/48h 717 mg/l (daphnia) 

LC50/96h 230 mg/l (oncorhynchus mykiss, regenbogenforelle) 

· Persistence and degradability Easily biodegradable 

· Behaviour in environmental systems: 

· Bioaccumulative potential Bioakkumulation möglich. 

· Mobility in soil No further relevant information available. 

· Additional ecological information: 

· General notes: 

Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water 

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage 

system. 

· Results of PBT and vPvB assessment 

· PBT: Not applicable. 

· vPvB: Not applicable. 

· Other adverse effects No further relevant information available. 

GB 

(Contd. on page 7)

DR 



Page 7/8 


Revision: 07.02.2011 


13 Disposal considerations 


· Waste treatment methods 

· Recommendation 

Must be specially treated adhering to official regulations. 

Must not be disposed together with household garbage. Do not allow product to reach sewage system. 

· Waste disposal key: 

Folgende Abfallschlüsselnummern des europäischen Abfallkatalogs (EAK) gelten als Empfehlung. Die 

Entsorgung muß mit dem örtlichen Entsorger abgestimmt werden. 

Flüssiges Produkt: 

080409* Klebstoff- und Dichtmassenabfälle, die organische Lösemittel oder andere gefährliche Stoffe 

enthalten. 

080410 Klebstoff- und Dichtmassenabfälle mit Ausnahme derjenigen, die unter 080409* fallen. 

ausgehärtetes Produkt: 

170203 Kunststoff 

· European waste catalogue 080111* (empfohlen) 

· Uncleaned packaging: 

· Recommendation: Disposal must be made according to official regulations. 

14 Transport information 

· Land transport ADR/RID (cross-border) 

· ADR/RID class: 3 Flammable liquids. 

· Danger code (Kemler): 33 

· UN-Number: 1173 

· Packaging group: II 

· Hazard label: 3 

· UN proper shipping name: 1173 ETHYL ACETATE 

· Tunnel restriction code D/E 

· Maritime transport IMDG: 

· IMDG Class: 3 

· UN Number: 1173 

· Label 3 


· EMS Number: F-E,S-D 

· Marine pollutant: No 

· Proper shipping name: ETHYL ACETATE 

· Air transport ICAO-TI and IATA-DGR: 

· ICAO/IATA Class: 3 


GB

DR 



Page 8/8 


Revision: 07.02.2011 


· UN/ID Number: 1173 

· Label 3 


· Proper shipping name: ETHYL ACETATE 

· UN "Model Regulation": UN1173, ETHYL ACETATE, 3, II 

· Special precautions for user Warning: Flammable liquids. 

· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 

15 Regulatory information 


· Safety, health and environmental regulations/legislation specific for the substance or mixture 

· National regulations: 

· Information about limitation of use: Employment restrictions concerning juveniles must be observed. 

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 

16 Other information 

This information is based on our present knowledge. However, this shall not constitute a guarantee for any 

specific product features and shall not establish a legally valid contractual relationship. 

· Department issuing MSDS: Division product safety 

· Abbreviations and acronyms: 

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the 

International Carriage of Dangerous Goods by Road) 

RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning 

the International Transport of Dangerous Goods by Rail) 

IMDG: International Maritime Code for Dangerous Goods 

IATA: International Air Transport Association 

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) 

ICAO: International Civil Aviation Organization 

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) 

GHS: Globally Harmonized System of Classification and Labelling of Chemicals 

EINECS: European Inventory of Existing Commercial Chemical Substances 

CAS: Chemical Abstracts Service (division of the American Chemical Society) 

VOC: Volatile Organic Compounds (USA, EU) 

LC50: Lethal concentration, 50 percent 

LD50: Lethal dose, 50 percent 

· * Data compared to the previous version altered. 

GB

Alsan RS Reiniger - Soprema

Create successful ePaper yourself

Delete template?

Save as template?