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Small Angle Scattering of neutrons and xrays - NeutronXraySchool ...

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SANS <strong>of</strong> labeled<br />

stretched rubber<br />

• Stronger anisotropy at<br />

smaller q (larger distances)<br />

• Ellipse > diamond transition<br />

at large deformation<br />

• Warner-Edwards tube<br />

approach:<br />

affinely deformed Gauss chain<br />

⎧<br />

1 x<br />

r<br />

⎪<br />

2<br />

S ( q, λ) = 2N∫dx∫dx′ ∏exp<br />

⎨ ( Qμλμ) ( x−x′ ) −<br />

0 0 μ ⎪<br />

⎪⎩ ⎪⎩<br />

2<br />

d 2 2 μ<br />

μμ(1 −λμμ) 2<br />

2 6 R Rg<br />

19 Managed by UT-Battelle<br />

⎜ ( x−x′ ) ⎟⎪<br />

1−exp ⎢<br />

−<br />

⎥<br />

⎜ ⎢ 2 ⎬<br />

d ⎥ ⎟<br />

μ<br />

⎜ ⎢ ⎥⎟ ⎪<br />

⎜ 2<br />

2 6R<br />

⎟⎪<br />

⎝ ⎢⎣ g ⎥⎦⎠⎭<br />

for the U.S. Department <strong>of</strong> Energy Presentation_name<br />

Q<br />

⎛ ⎡ ⎤⎞⎫ ⎜ ⎢ ⎥⎟⎪<br />

non-affine fluctuation contribution<br />

NIST NG7 data<br />

1.5<br />

small q larger q<br />

2.0<br />

2.6<br />

29 2.9<br />

q max ~ 0.009 Å

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