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A-Z Analysis for Industry - Filter

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INFORMATION<br />

ANALYSIS FOR INDUSTRY<br />

A-Z <strong>Analysis</strong> <strong>for</strong> <strong>Industry</strong><br />

Laboratory and Continuous Monitoring Solutions


2<br />

<strong>Analysis</strong> <strong>for</strong> industrial production and<br />

wastewater treatment<br />

The control of industrial production processes is subject to close scrutiny. Production<br />

plants, customers and legislators need verifi able data on product quality, energy<br />

consumption and operating procedures. HACH LANGE offers laboratory and continuous<br />

monitoring solutions <strong>for</strong> each stage of the water cycles associated with production<br />

processes. Whatever your analytical requirements; complex sample matricies,<br />

ultra low, high loads and harsh conditions, our products and services ensure<br />

your systems keep running effectively and effi ciently.<br />

Key brands under one roof:<br />

HACH, LANGE, ORBISPHERE, POLYMETRON,<br />

RADIOMETER ANALYTICAL, BUHLER, SIGMA,<br />

HIAC, MET ONE, GLI, ZULLIG, ASTRO, LACHAT,<br />

ANATEL, CONTRONIC, EVITA,<br />

PACIFIC SCIENTIFIC and partnership with<br />

SIEMENS.<br />

www.hach-lange.com<br />

Beverage<br />

2<br />

Production all branches Water conditioning and<br />

“We have to rely on our data, <strong>for</strong> sure! That’s<br />

why we are trying to eliminate all error<br />

sources in our analysis. From sample taking<br />

to QA. HACH LANGE support is excellent.<br />

Especially their technical advice and<br />

workshops, which provide lots of practical<br />

advice.”<br />

Raw<br />

materials<br />

treatment all branches


Paper<br />

3<br />

Chemical <strong>Industry</strong>,<br />

Pharma<br />

4<br />

1<br />

Power<br />

“I have to keep our systems running, which is<br />

not always that easy because of production and<br />

weather conditions etc. So I need devices which<br />

can stand up to anything! They should be low<br />

wear and tear and easy to maintain. Fortunately<br />

HACH LANGE instruments provide this! They<br />

offer real support, are close by and know our<br />

special circumstances very well.”<br />

Electroplating<br />

5<br />

6<br />

Neutralisation<br />

INDUSTRY_APPLICATIONS<br />

7<br />

Biological Waste Water<br />

Treatment<br />

“As a plant manager, I am responsible <strong>for</strong> the<br />

optimisation of our water treatment processes.<br />

Increasing its effectiveness continously,<br />

while decreasing the costs. This is an ongoing<br />

challenge, which needs hi-end technologies and<br />

solutions. So, I appreciate the cooperation from<br />

HACH LANGE, who know my business.”<br />

3


4<br />

ORBISPHERE G1200 luminescent<br />

dissolved oxygen sensor<br />

Power plant reliability even with ultra<br />

low loads<br />

Providing electricity depends on stable running processes. They must be monitored closely in order to<br />

avoid any interferences with the operation of the plant. Whether fossil fuel, nuclear or combined cycle,<br />

HACH LANGE solutions are trusted to control critical operating parameters.<br />

Power Plant analyses: where, how, and why<br />

www.hach-lange.com<br />

POLYMETRON 9123<br />

conductivity and calculated pH<br />

POLYMETRON 9210<br />

silica analyser<br />

Parameter* Why analyse? 1 2 3 4 5 6<br />

Ammonium Ammonium is used <strong>for</strong> pH adjustment. •<br />

Chlorine dioxide Monitoring disinfectants minimises costs of biocide dosing. •<br />

Chlorine total / free Monitoring disinfectants allows cost control of biocide dosing. •<br />

Conductivity Salts cause deposits in tubes, heat exchangers, boilers and turbines. • • • • • •<br />

Hardness Hardness drives costs of fresh water intake. •<br />

Hydrazine Monitoring avoids overdosing of oxygen scavengers. • •<br />

Hydrogen/Helium H 2: indicates explosive oxyhydrogen; He: indicates negative infl uence of H2 •<br />

Oxygen Oxygen is major source of corrosion in water. •<br />

Oxygen Oxygen is major source of corrosion in water. •<br />

P+M value (alkalinity) Alkalinity of circulated water impacts calcium deposits. • •<br />

pH value Low pH of water correlates with corrosion. • • • • •<br />

Phosphate Phosphate inhibits tube corrosion. •<br />

Phosphate/P pentoxide Phosphate inhibits tube corrosion. • •<br />

Silica Silica precipitates damage to turbines and tubes. • • • •<br />

Sodium Sodium indicates effi ciency losses of ion exchangers. • • • •<br />

TOC Non-ionic inorganic compounds lead to deposits in pipes. • •<br />

Turbidity Turbidity measures effectiveness of fi ltration and microbiological quality. • • • •


Fresh Water<br />

1 WATER INTAKE<br />

Conductivity<br />

pH value<br />

TOC<br />

Turbidity<br />

1<br />

6 STEAM + CONDENSATES<br />

Conductivity<br />

Hydrazine<br />

pH value<br />

Silica<br />

Sodium<br />

TOC<br />

2 DEMINERALISATION<br />

WATER PLANT<br />

Conductivity<br />

Silica<br />

Sodium<br />

Turbidity<br />

Multilayer<br />

fi lter<br />

Condensate<br />

polishing plant<br />

Cation<br />

exchanger<br />

Range Product Solutions*<br />

6<br />

2<br />

Anion<br />

exchanger<br />

Condensate<br />

Heat<br />

exchanger<br />

Cooling water<br />

Fresh Water<br />

Mixed bed<br />

resin<br />

3 MAKE-UP / FEED WATER<br />

Ammonium<br />

Conductivity<br />

Hydrazine<br />

Oxygen<br />

P + M value<br />

Turbine<br />

pH value<br />

Phosphate<br />

Silica<br />

Sodium<br />

Cooling<br />

tower<br />

POWER 1<br />

Boiler / Reactor<br />

Waste Water<br />

0.01–1,000 mg/l NH4<br />

AMTAX sc / NH4D sc / ISE: ammonium sensors; POLYMETRON 8810 titrator<br />

0.01–2 mg/l Chlorine dioxide 9187 sc amperometric chlorine dioxide sensor<br />

5<br />

3<br />

5 COOLING WATER LOOP<br />

4<br />

Chlorine dioxide<br />

Chlorine<br />

Conductivity<br />

Hardness<br />

pH value<br />

Silica<br />

Sodium<br />

Turbidity<br />

5<br />

4 BOILER / REACTOR<br />

Helium (nuclear)<br />

Hydrogen (nuclear)<br />

4<br />

4<br />

Conductivity<br />

Silica<br />

Sodium<br />

P + M value<br />

pH value<br />

Phosphate<br />

Phosphorus pentoxide<br />

Turbidity<br />

0.03–20 mg/l CL17 / CHLOROMAT 9184 sc: photometric or amperometric chlorine sensors<br />

0.01 µS/cm – 10,000 mS/cm POLYMETRON / HACH: conductive and inductive sensors<br />

0.05–1,000 mg/l CaCO3<br />

APA6000 / SP510 / Polymetron 8810 titrator: hardness analysers<br />

0–500 ppb POLYMETRON 9186 oxygen scavenger analyser<br />

0–100 % ORBISPHERE 31280 H2 / He gas analyser<br />

0–80,000 ppm POLYMETRON 9183 / 9182: oxygen analysers or electrochemical sensors<br />

0–20,000 ppb ORBISPHERE G1100 / G1200 / 3650: luminescent or electrochemical oxygen sensors, also portable<br />

0–1,000 mg/l CaCO3 (Total alkalinity) APA6000 P+M analyser, POLYMETRON 8810 titrator<br />

7.5–10.5; 0–14 POLYMETRON 9123 Conductivity and calculated pH, POLYMETRON pH sensors<br />

0.05–50 mg/l PO4-P PHOSPHAX sc / POLYMETRON 9211: phosphate analysers<br />

0.01–5 mg/l PO4-P, ortho and total PHOSPHAX sigma photometric phosphate analyser<br />

0–5,000 ppb POLYMETRON 9210 silica analyser<br />

0.01–20 ppm POLYMETRON 9240 / 9245: sodium multi-/single channel analysers<br />

0.01–20,000 mg/l ANATEL A4000 / TOCTAC / ASTRO UV: TOC analysers with different sample treatment<br />

0.0001–9,999 FNU COSMOS 25 HT, SOLITAX sc / SS7 sc / ULTRATURB plus sc / 1720E sc / FT 660 sc: IR and white-light turbidity sensors<br />

* For more products and parameters see appendix table!


6<br />

Water and product quality <strong>for</strong> the<br />

beverage industry<br />

Nowhere is product quality more closely focused than in the area of food and drink. This is another<br />

reason why raw materials, intermediate and fi nished products have to be seamlessly monitored.<br />

HACH LANGE has made-to-measure solutions <strong>for</strong> specifi c sectors.<br />

www.hach-lange.com<br />

ORBISPHERE 3658 portable<br />

carbon dioxide analyser<br />

Beverage industry analyses: where, how, and why<br />

COSMOS XL turbidity sensor with<br />

special design <strong>for</strong> beverage<br />

ORBISPHERE M1100 luminescent<br />

dissolved oxigen sensor<br />

ORBISPHERE 6110 total<br />

package analyser <strong>for</strong> oxygen<br />

and carbon dioxide<br />

Parameter* Why analyse? 1 2 3a 3b 3c 3d 4 5 6<br />

Brix/Diet Brix, Diet, CO2, O2, and temperature control fi nal quality of soft drinks. •<br />

Carbon dioxide Carbon dioxide measurement indicates fi nal product quality. • • • • •<br />

Chlorine total, free Monitoring disinfectants allows cost control of biocide dosing. • •<br />

Conductivity Conductivity measures water and product quality. • • • •<br />

Hardness Hardness drives costs of raw water intake. • •<br />

MEBAK parameter MEBAK parameters lab analysis <strong>for</strong> beer quality. •<br />

Nitrate Nitrate indicates water and product quality. •<br />

Nitrogen Dissolved nitrogen monitors fi nal product quality. • •<br />

Oxygen Monitoring oxygen controls corrosion, process effi ciency and product quality. • • • • • •<br />

Oxygen +<br />

Carbon dioxide<br />

Final package analysis controls beer quality and fi ller. •<br />

Ozone Ozone analysis ensures disinfection levels in beverages. •<br />

P+M value (alkalinity) Alkalinity indicates water and product quality. •<br />

pH value pH value indicates water and product quality. • • • •<br />

Turbidity Turbidity measures effectiveness of fi ltration and microbiological quality. • • • • • •


Fresh Water<br />

1 WATER<br />

CONDITIONING<br />

Chlorine<br />

Conductivity<br />

Hardness<br />

Iron *<br />

Manganese *<br />

Nitrate<br />

pH value<br />

Turbidity<br />

1<br />

2 BOILER HOUSE<br />

Conductivity<br />

Hardness<br />

Oxygen<br />

pH value<br />

P + M value<br />

Turbidity<br />

5 BOTTLE RINSING<br />

Chlorine<br />

Conductivity<br />

pH value<br />

Turbidity<br />

Range Product Solutions*<br />

2<br />

5<br />

3a BEER PRODUCTION<br />

Conductivity<br />

MEBAK parameters<br />

Oxygen<br />

pH value<br />

Turbidity<br />

3a<br />

3b WINE PRODUCTION 3c SOFT DRINK PRODUCTION<br />

wine<br />

beer<br />

Oxygen<br />

Turbidity<br />

3b<br />

Wine<br />

Deaerated<br />

water<br />

tank<br />

Filtration<br />

3c<br />

3c<br />

6<br />

Waste Water<br />

BEVERAGE 2<br />

Oxygen<br />

3c<br />

Softdrink<br />

3d<br />

Mineral<br />

water<br />

Bright<br />

beer<br />

tank<br />

Carbon dioxide<br />

Oxygen<br />

Carbon dioxide<br />

6 FILLING<br />

4<br />

3d MINERAL WATER<br />

PRODUCTION<br />

Carbon dioxide<br />

Oxygen<br />

Ozone<br />

3a<br />

4 PRE FILLING<br />

Brix / Diet<br />

Carbon dioxide<br />

Nitrogen<br />

Oxygen<br />

Turbidity<br />

0–20° Brix; 0–200 % Diet ORBISPHERE 3624 in-line analyser<br />

0–15 g/kg ORBISPHERE thermal conductivity analyser, portable<br />

0.03–20 mg/l HOCl CL17 / CHLOROMAT 9184 sc: photometric or amperometric chlorine sensors<br />

0.01 µS/cm – 10,000 mS/cm POLYMETRON / HACH: conductive and inductive sensors<br />

0.05–1,000 mg/l CaCO3<br />

APA6000 / SP510: hardness analysers<br />

DR 5000 UV/VIS spectrophotometer and MEBAK cuvette tests<br />

0.1–100 mg/l NO3-N NITRATAX plus sc UV sensor<br />

0–350 ppm ORBISPHERE 315xx / 3654: portable gas analysers<br />

0–80,000 ppb ORBISPHERE A1100 / M1100: electrochemical or luminescent oxygen sensors<br />

1 ppb – 20 ppm O2<br />

0–10 g/kg CO2<br />

ORBISPHERE 3625 / 6110: total package analysers<br />

5 ppb – 200 ppm ORBISPHERE 313xx electrochemical sensor<br />

10–4,000 mg/l CaCO3 APA6000 P + M analyser<br />

0–14 POLYMETRON 8362 / 1200-S sc / pHD-S sc: pH sensors<br />

0.0001–9,999 FNU COSMOS 25 Vari XL / SOLITAX sc / SS7 sc / ULTRARURB plus sc / 1720E sc / FT 660 sc: IR and white-light<br />

turbidity sensors<br />

* For more products and parameters see appendix table!<br />

7<br />

Carbon dioxide<br />

Nitrogen<br />

Oxygen


8<br />

Paper production:<br />

Accuracy even with high loads<br />

Measure solids and turbidity<br />

independently of colour<br />

The solids content of the white water<br />

box and the fl ow box have the highest<br />

priority. The rugged SOLITAX sc probe<br />

provides colour-independent and<br />

precise results <strong>for</strong> this application.<br />

With a measuring range of 0.001 to<br />

4,000 FNU, or 0.001 to 500 g/l,<br />

it is suitable <strong>for</strong> all stations. It can<br />

be installed inline, in a bypass or<br />

immersed.<br />

Organic components<br />

Organic loads are continuously<br />

determined in-process via TOC or<br />

spectral absorption coeffi cients.<br />

Alternatively, samples are taken and<br />

analysed in the laboratory, using the<br />

TOC analyser or the COD cuvette test.<br />

The latter uses far smaller amounts of<br />

reagents than the old standard method<br />

and is especially safe in terms of<br />

handling.<br />

For F the h llowest and d the h hi highest h solids lid<br />

concentrations: SOLITAX sc probes<br />

Water plays a crucial role in the production of paper and board. During the production process, it comes<br />

into contact with many fi llers and auxiliaries. Only continuous monitoring ensures optimal product quality<br />

and minimal environmental pollution.<br />

www.hach-lange.com<br />

HQD: portable measuring instrument<br />

<strong>for</strong> pH, O 2 and conductivity<br />

Flexibility <strong>for</strong> pH and O2<br />

pH and oxygen are important <strong>for</strong><br />

economic production. Permanently<br />

installed or portable instruments<br />

can be used to measure them. The<br />

innovative LDO oxygen sensor has<br />

proved extremely effective <strong>for</strong> both<br />

parameters. The optical measurement<br />

method is precalibrated <strong>for</strong> longterm<br />

use and needs no electrolyte<br />

membrane replacement. Just change<br />

the sensor cap every one or two years<br />

– it’s that simple!


Fresh Water<br />

Acid capacity<br />

Alkalinity<br />

Ammonium<br />

COD<br />

Conductivity<br />

Copper<br />

Chloride<br />

Chlorine<br />

DEHA<br />

Hardness<br />

Hydrazine<br />

Iron<br />

Molybdenum<br />

Fresh Water tank<br />

Hardness<br />

Iron<br />

Manganese<br />

pH<br />

Nitrite<br />

Oxygen<br />

pH<br />

Phosphonate<br />

Phosphorus<br />

SAC<br />

Silica<br />

Sodium<br />

Sulphite<br />

TOC<br />

Toxicity<br />

Turbidity<br />

Accurate starch determination<br />

The cuvette test determines soluble<br />

starch in the measuring range from<br />

2 to 150 mg/l. This simply involves<br />

pipetting 2 vml sample into the cuvette,<br />

then waiting <strong>for</strong> just ten minutes<br />

until the evaluation is carried out<br />

automatically in the photometer.<br />

HACH LANGE provides a service to<br />

collect and recycle used cuvettes.<br />

The HACH LANGE Environment Centre<br />

has been a certifi ed disposal facility <strong>for</strong><br />

ten years!<br />

Power station<br />

Mixing box<br />

White Water box<br />

Oxygen<br />

Hardness<br />

pH<br />

For precise routine checks<br />

The REFO 60 is designed <strong>for</strong> objective<br />

gloss measurement of raw paper and<br />

board during the production process.<br />

With its handy size and a weight of<br />

less than 500 g, it is the ideal product<br />

in all areas of production. Automatic<br />

calibration to the black glass standard<br />

in accordance with ISO 2813 is<br />

initiated by pressing a button.<br />

Energy<br />

AOX<br />

COD<br />

Conductivity<br />

Chloride<br />

Microbial contamination<br />

Solids<br />

Starch<br />

Sulphate<br />

PAPER 3<br />

Paper machine<br />

Industrial Waste Water plant<br />

Total chlorine analyser<br />

Gloss<br />

9


10<br />

ORBISPHERE 3650 EX portable<br />

electrochemical sensor <strong>for</strong> oxygen<br />

and hydrogen measurements<br />

Broad range of solutions <strong>for</strong> complex<br />

requirements in the chemical industry<br />

There is an enormous variety of raw, intermediate and fi nished chemical products. Every plant has its own<br />

specifi c analysis methods <strong>for</strong> quality control. HACH LANGE offers specifi c measuring systems, which are<br />

easy to operate and provide reliable results. Controllers and sensors <strong>for</strong> continuous monitoring <strong>for</strong>m the<br />

basis of safe and reliable operation, even in explosion risk areas.<br />

Everything <strong>for</strong> liquid analysis<br />

Liquid level, fl ow, pressure,<br />

temperature, pH, conductivity, redox<br />

potential etc. HACH LANGE offers<br />

a very wide range of parameters,<br />

materials and fi ttings. Controllers<br />

and transmitters with two and fourwire<br />

technology can be integrated<br />

into existing bus systems. Access<br />

is restricted to authorised users <strong>for</strong><br />

maximum security.<br />

www.hach-lange.com<br />

Detect oil in and on water<br />

immediately<br />

UV fl uorescence is a sensitive method<br />

<strong>for</strong> detecting polycyclic aromatic<br />

hydrocarbons (PAH) in water. The<br />

ENVIROFLU-HC probe is an immersible<br />

UV fl uorometer. It is installed in pipes and<br />

sewers <strong>for</strong> monitoring, in combination<br />

with alarm systems.<br />

SI 792 EX 2-wire transmitter<br />

compatible with HART, PROFIBUS<br />

PA and FIELDBUS FOUNDATION in<br />

combination with pH sensors<br />

ORBISPHERE 311XX<br />

electrochemical<br />

sensor <strong>for</strong> oxygen<br />

measurements<br />

COSMOS EX turbidity<br />

and suspended solids<br />

measurement in<br />

Ex-zone 1<br />

Colour in liquids<br />

LICO 500 is ideal <strong>for</strong> determining<br />

colour in liquids. Results can be<br />

expressed in 24 international colour<br />

scales, including Hazen and Gardner.<br />

TITRALAB titrators are precise,<br />

upgradable systems with automatic<br />

reliable reagent traceability in<br />

con<strong>for</strong>mity with GLP. Intuitive operation<br />

with self-explanatory menus on the<br />

large display enables work to be<br />

carried out quickly and accurately.


Raw materials<br />

checks<br />

Fresh Water<br />

Complete solutions <strong>for</strong> turbidity,<br />

solids, particles, sludge<br />

From ultraclear to murky fl uids: process<br />

probes and turbidimeters monitor<br />

fi ltration processes and detect product<br />

intrusions into process water fl ows. In<br />

the laboratory, the 2100 AN turbidimeter<br />

satisfi es the requirements of the various<br />

European pharmacopoeias and ISO<br />

standards. The perfectly matched<br />

accessory: STABL CAL is a stabilised,<br />

ready-to-use <strong>for</strong>mazin standard available<br />

in a variety of concentrations.<br />

Production<br />

checks<br />

Ultraclear water Clear water Sludge<br />

ARTI – Particle counter<br />

CHEMICAL INDUSTRY, PHARMA 4<br />

Outgoing goods<br />

checks<br />

FILTERTRAK 660 sc – Turbidity<br />

ULTRATURB plus sc – Turbidity<br />

1720 E sc – Turbidity<br />

Plastics<br />

HIAC PODS portable oil<br />

diagnostic system according<br />

ISO 11171 standards<br />

2100 series laboratory turbidimeters – Turbidity<br />

SOLITAX sc – Turbidity and solids concentration<br />

Main use <strong>for</strong> various laboratory and process instruments<br />

Drugs<br />

Dyes<br />

Waste Water<br />

SURFACE SCATTER 7 sc – Turbidity<br />

SONATAX sc – Sludge level<br />

Petrol<br />

SURFACE SCATTER 7 sc <strong>for</strong><br />

measurements of middle and<br />

high range turbidity<br />

11


12<br />

Sample preparation with thermostat and CRACK SET<br />

From sample preparation to AQA in<br />

electroplating plants<br />

In recent years, considerable ef<strong>for</strong>ts have been made to reduce water consumption in electroplating<br />

plants. Operational analysis has made a considerable contribution, enabling bath service life to be<br />

extended and rinse steps to be made more effi cient.<br />

Sample preparation<br />

Accurate analysis results start with<br />

correct sample preparation. In an<br />

industry that makes use of a wide<br />

variety of additives and complexing<br />

agents, this is essential. The<br />

CRACK SET reliably digests complex<br />

metal compounds, making the metals<br />

accessible <strong>for</strong> analysis.<br />

www.hach-lange.com<br />

Cuvette test <strong>for</strong> surfactants<br />

Metal and bath analysis<br />

Tests have been developed specifi cally<br />

<strong>for</strong> the high concentrations in acidic<br />

copper, nickel and chromium baths.<br />

Pipette, mix the cuvette contents<br />

and evaluate in the photometer. The<br />

LANGE cuvette tests offer maximum<br />

safety, even <strong>for</strong> inexperienced users.<br />

Even a complex but important<br />

parameter such as surfactants poses<br />

no problems.<br />

Portable DR 2800 spectrophotometer<br />

with touchscreen<br />

Confi dence in your results<br />

Analytical quality assurance can be<br />

used to verify obtained analysis results<br />

are correct. Alongside the simplest<br />

verifi cation method you can check<br />

the quality of your analysis with the<br />

ADDISTA, AQA system. It consists<br />

of a standard and a spiking solution<br />

together with a round robin test<br />

solution.


5<br />

ELECTROPLATING<br />

Bath analysis<br />

Conductivity<br />

Immersion baths<br />

Neutralisation units:<br />

Effective process stabilisation<br />

The electroplating sector is not the only one in which neutralisation is carried out at the end of the<br />

production process. Many indirect dischargers, such as milk processing plants, breweries, abattoirs<br />

and chemical plants, treat their wastewater be<strong>for</strong>e discharging it. Direct dischargers use neutralisation<br />

to stabilise their industrial wastewater plant process.<br />

Mobile checks with rugged<br />

electrodes<br />

HQ30D is the handy solution <strong>for</strong><br />

fast and reliable monitoring of pH<br />

and conductivity at a wide range of<br />

locations in production plants. Simple<br />

but clever INTELLICAL ® electrodes<br />

record their own calibration data. This<br />

saves time and provides assurance.<br />

The calibrated electrodes can be<br />

replaced at any time in the fi eld, and<br />

can be connected to other HQD<br />

instruments without losing any data!<br />

Rinse baths<br />

Detoxifi cation<br />

Cost effective<br />

Up to eight sensors, e.g. <strong>for</strong> pH,<br />

redox potential and conductivity, can<br />

be connected to the SC controllers.<br />

Control algorithms, which are used <strong>for</strong><br />

effi cient control of the addition of acid<br />

and alkali, are preconfi gured in the<br />

controller. The fast response time of<br />

the sensors ensures stable operation.<br />

NEUTRALISATION 6<br />

Neutralisation<br />

Redox<br />

Conductivity<br />

pH<br />

Redox<br />

AOX<br />

Arsenic<br />

Barium<br />

Cadmium<br />

Cobalt<br />

Copper<br />

Specialist <strong>for</strong> electrochemistry: SI 792<br />

transmitter with pH and conductivity<br />

sensors<br />

13<br />

Waste Water<br />

plant<br />

Cyanide<br />

Chromium<br />

Chromium(VI)<br />

Free chlorine<br />

Lead<br />

Mercury<br />

Nickel<br />

Selenium<br />

Silver<br />

Sulphide<br />

Tin<br />

Zinc


14<br />

Cost effective analysers<br />

The SC 1000 controller is suitable <strong>for</strong><br />

networks and stand-alone solutions.<br />

Up to eight sensors can be connected<br />

to each module, and several modules<br />

can be linked in a network. Existing<br />

measurement signals can be<br />

integrated. Control is effected through<br />

bus systems (e.g. PROFIBUS DP,<br />

MODBUS). The system can be<br />

extended at any time.<br />

Measure oxygen with LDO:<br />

no maintenance required<br />

The optical measurement principle of<br />

the LDO oxygen sensor guarantees<br />

precise measured values over a long<br />

service life. No calibration is needed,<br />

no membranes or electrolytes need<br />

to be replaced. Simply changing the<br />

sensor cap every two years is suffi cient<br />

to ensure that the sensor continues<br />

to operate reliably and drift-free. LDO<br />

sensors are also available <strong>for</strong> portable<br />

HQD instruments.<br />

Add up to eight sensors: SC 1000 controller<br />

Wastewater treatment <strong>for</strong> assurance of<br />

processes and consent limits<br />

The end result is crucial. Nowhere is this more true than in the case of wastewater, as every failure to comply<br />

with legal limit values comes at a high price. Many years of experience ensure HACH LANGE probes and<br />

analysers can satisfy the high demands associated with salt load, organic components and pH.<br />

www.hach-lange.com<br />

NH4 ISE + NO3 ISE<br />

Stable nitrifi cation, stable<br />

outfl ow values<br />

Nutrient loads that fl uctuate widely<br />

from batch to batch are an obstacle<br />

to effi cient wastewater treatment.<br />

The ion-selective NH4D sc electrode<br />

effectively monitors and regulates the<br />

addition of oxygen to the aeration tank.<br />

Highly precise analysers check that the<br />

limit values <strong>for</strong> nitrogen and phosphate<br />

are not exceeded in the outfl ow of<br />

industrial wastewater treatment plants.


Industrial<br />

infl ow<br />

Laboratory / Control<br />

Sampler<br />

Unique linkage of laboratory and<br />

process analysis<br />

The DR 3800 sc spectrophotometer<br />

brings together measured values<br />

from laboratory and process analysis.<br />

The colour display combines the<br />

measurement result of a 24 hour<br />

mixed sample and the associated<br />

time curve of the online sensor. The<br />

DR 3800 sc can also measure all<br />

important wastewater parameters,<br />

using preprogrammed, plant-specifi c<br />

methods, which can be easily<br />

upgraded.<br />

Aeration<br />

Conductivity<br />

Flow<br />

pH<br />

SAC<br />

TOC<br />

BIOLOGICAL WASTEWATER TREATMENT 7<br />

Aeration<br />

Sludge level<br />

Conductivity<br />

Nitrate<br />

Qxygen<br />

pH<br />

SAC<br />

Turbidity<br />

Water quality station<br />

Pre-dosed cuvette tests <strong>for</strong> safe<br />

handling<br />

The cuvettes contain exact amounts of<br />

ready-to-use reagents and the results<br />

are automatically calculated. Barcodes<br />

identify the cuvettes and<br />

10-measurements are taken per<br />

cuvette rotation to exclude any errors<br />

caused by surface smears, etc. Users<br />

are not required to carry out any<br />

calibration! The closed system ensures<br />

the highest levels of safety <strong>for</strong> both the<br />

analyst and their surroundings, even<br />

under the most diffi cult conditions.<br />

Final sedimentation<br />

Acid capacity<br />

Ammonium<br />

Nitrate<br />

Organic acids<br />

Oxygen<br />

pH<br />

Phosphate, ortho<br />

Solids<br />

Solids<br />

Sludge level<br />

Outfl ow<br />

Sampler<br />

Phosphate Analyser according<br />

yellow-method<br />

15<br />

Ammonium<br />

Conductivity<br />

Flow<br />

Nitrate<br />

Organic acids<br />

pH<br />

Phosphate, ortho<br />

Phosphate, total<br />

SAC<br />

TOC<br />

Turbidity


Parameter Range Product Product description<br />

Flow 0–100 / 0–500 m³/h<br />

0–25,000 m³/h<br />

SITRANS FM MAG 1100F/<br />

MAG3100/MAG5100W SITRANS<br />

FU; SITRANS FU SONO<br />

Magnetic inductive supersonic clamp on,<br />

supersonic matrix contact<br />

Fluoride 0.02–2 mg/l Reagent / LCK, RS, AV (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Formaldehyde 0.003–10 mg/l Reagent test / LCK, PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Hardness 0.05–1,000 mg/l CaCO3 APA6000/ PM 8810 Colorimetry<br />

Hardness, Ca+Mg 0.1–100 mg/l Ca Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Hardness, Ca+Mg 0.15–50 mg/l Mg Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Hardness, Ca+Mg 0.001–4.00 mg/l CaCO3 Reagent / RL (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Hydrazine 0.004–2 mg/l Reagent / LCW, RS, AV<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Hydrazine 0.2–500 ppb Hydrazin Hydrastat 9186 Triple electrode system<br />

Hydrogen 0–10 ppm ORBISPHERE 312XX, 3654 Electrochemical sensor, portable analyser<br />

Hydrogen peroxide 50–150 mg/l Digital titrator Titration test by hand<br />

Hydrogen peroxide 1–10 g/l Reagent / LCW (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Hydrogen/Helium 0–100% ORBISPHERE 31280 Thermal conductivity sensor<br />

Iodine 0.07–7 mg/l Reagent / PP, AV (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Iron 0.005–6 mg/l Reagent / LCW, LCK, PP, RS, RL,<br />

AV (DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Iron II 0.02–3 mg/l Reagent / PP, AV (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Iron II/III 0.2–6 mg/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Lead 0–2 mg/l Reagent test / LCK, RS (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Level 0–100 m SITRANS LR 200, 250/260,<br />

400/460 LU/MultiRanger +<br />

Echomax SITRANS LG 200<br />

Manganese 0.007–20 mg/l Reagent test / LCW, PP<br />

(DR Series)<br />

Radar 6 GHz Puls, 25 GHz Puls, Radar 24 GHz<br />

FMCW supersonic microwave<br />

Photometric test (UV/VIS spectrophotometer)<br />

MEBAK parameters Reagent test / LCK (DR Series) UV/VIS spectrophotometer with special<br />

software <strong>for</strong> MEBAK parameters<br />

Menthol in distillate 0.5–15 mg / 100 ml Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Mercury 0.0001–0.0025 mg/l Reagent test / RS (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Microbiology Total microorganism count,<br />

yeasts, moulds, slime-<strong>for</strong>ming<br />

bacteria, E. coli, total coli<strong>for</strong>ms,<br />

Pseudomonas<br />

Diverse microbiological tests<br />

Molybdenum/Molybdate 0.02–300 mg/l Reagent test / LCK, PP, AV<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Nickel 0.007–6 mg/l Reagent test / LCK, PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Nickel baths, acidic 5–120 g/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Nitrate 0.01–30 mg/l NO3-N Reagent test / LCK, PP, TNT, AV<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Nitrate 0.1–100 mg/l NO3-N NITRATAX plus sc, Optical nitrate sensor<br />

Nitrite 0.0015–250 NO2-N Reagent test / LCK, PP, TNT, AV<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Nitrogen 0–350 ppm ORBISPHERE 315xx, 3654 Nitrogen TC sensor; Nitrogen portable gas<br />

analyser<br />

Nitrogen, tot., TN 1–100 mg/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Nitrogen, total, inorganic 0.2–25 mg/l Reagent test / TNT (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Nitrogen, total, Kjeldahl 1–150 mg/l Reagent test / PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Organic acids 27–2,800 mg/l Reagent test / LCK, RS (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

ORP ±2,000 mV ECO700 ORP [ECO10 ORP] ORP electrode (ORP meter)<br />

ORP ±1,500 mV 1200-S sc, pHD-S sc,<br />

SI 794 / 8351<br />

Blue: laboratory analysis<br />

Red: process measurement technology<br />

Please note: the measuring ranges can vary from instrument to instrument!<br />

ORP process electrodes in combination with<br />

SC controller<br />

17


18<br />

Parameters, measuring ranges and product solutions<br />

Parameter Range Product Product description<br />

Oxygen 0–80,000 ppb ORBISPHERE A1100; M1100;<br />

3650<br />

Oxygen sensor (EC); Luminescent oxygen<br />

sensor; Oxygen portable analyser (reference in<br />

beverage)<br />

Oxygen 0.006–15 mg/l Reagent test / AV (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Oxygen 0–20 mg/l, 0–60 mg/l INTELLICAL ® LDO; INTELLICAL ®<br />

LBOD (HQD30D; HQD40D);<br />

ECO901 oxi (ECO30 oxi)<br />

O2 electrodes (meter)<br />

Oxygen 0–1,000 ppb LANGE LDO sc, 5740 sc, SI 792, LDO: optical luminescent sensor, 5740: Ni/Pb<br />

SI 794, OXISTAT<br />

galvanic sensor, sensors in combination with<br />

controller, OXISTAT: amperometric<br />

measurement<br />

Oxygen 0–80,000 ppm POLYMETRON 9183; 9182 Oxygen Analyser, EC-sensor<br />

Oxygen 0–20,000 ppb ORBISPHERE G1100; G1200; Oxygen luminescent sensor, G1200 nuclear<br />

3650; A1100<br />

application; O2 and H2 Portable analyser;<br />

Oxygen EC sensor<br />

Oxygen + Carbon dioxide 1 ppb – 20 ppm O2 ORBISPHERE 3625 Package analyser <strong>for</strong> breweries lab: quality<br />

0–10 g/kg CO2 control and fi ller troubleshooting<br />

Oxygen scavenger 0.0005–0,6 mg/l DEHA Reagent test / PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Oxygen scavenger 0–500 ppb POLYMETRON 9186 Oxygen Scavenger analyser via hydrazine and<br />

carbohydrazide detection<br />

Ozone 5 ppb – 200 ppm ORBISPHERE 313xx O3 (EC) Sensor. Large range due to 2 different<br />

membranes<br />

Ozone 0.01–3.8 mg/l Reagent test / LCK, AV (DR<br />

Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Ozone 0.005–2 mg/l OZONMAT 9185 Amperometric sensor<br />

P + M value (alkalinity) 10–4,000 mg/l CaCO3 Digital titrator Titration test by hand<br />

P + M value (alkalinity) 10–1,000 mg/l CaCO3 APA6000 Colorimetric and titrimetric measurement<br />

Particle counters 1–100 µm ARTI WPC 21, 22 Particle counter<br />

PCB 1, 5, 10, 50 ppm threshold<br />

value<br />

Reagent test / IM (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

pH value 7.5–10.5 POLYMETRON 9123 pH Calculator; pH calculation via differential<br />

conductivity<br />

pH value 0–14 POLYMETRON 8362 pH Pure water sensor<br />

pH value 0–14 INTELLICAL ® pHC (HQ11D;<br />

HQ30D; HQ40D); ECO501 pH;<br />

ECO502 pH, ECO801 multi<br />

(ECO10 pH; ECO40 multi)<br />

pH electrode (meter)<br />

pH value 0–14 8362, 1200-S sc, pHD-S sc pH process electrode and SC contoller<br />

pH / ORP value 0–14 POLYMETRON 8350/51 pH/redox combination probes<br />

Phenol 0.002–200 mg/l Reagent test / LCK, PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Phosphate 0.05–50 mg/l PO4-P PHOSPHAX sc Photometric phosphate analyser<br />

Phosphate 0–50,000 ppb POLYMETRON 9211 Phosphate multi-channel analyser (1-6)<br />

Phosphate, ortho + total 0.01–20 mg/l PO4-P Reagent test / LCK, TNT<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Phosphate, ortho + total 0.01–5 mg/l PO4-P PHOSPHAX sigma Photometric phosphate analyser including<br />

sample digestion<br />

Phosphonates 0.02–125 mg/l Reagent test / PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Phosphorus, ortho 0.02–100 mg/l PO4 Reagent test / LCK, RL, RS, AV,<br />

TNT, PP (DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Phosphorus, total 0.06–100 mg/l PO4 Reagent test / TNT (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Photometric iodine sample Iodine value >0.2 Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Potassium 0.1–50 mg/l Reagent test / LCK, PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Pressure 0–40 / 0–400 / 0–700 bar SITRANS P compact/P300/DSIII Relative-/ absolute-/ and differential pressure<br />

Reducing agents <strong>for</strong> boiler water 0.02–1 mg/l DEHA Reagent / LCW (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

SAC254 0.01–3,000/m UVAS sc Optical measurement of solved organic<br />

compounds, TOC/COD-correlation possible<br />

Salinity 0–100 ppt Digital titrator Titration test by hand<br />

Sampler Mobile and stationary BÜHLER 4010, SIGMA SD 900,<br />

SIGMA 900<br />

Automatic sampler (mobile and stationary)<br />

Selenium 0.01–1 mg/l Reagent test / RS (DR Series) Photometric test (UV/VIS spectrophotometer)


Parameter Range Product Product description<br />

Silica 0–5,000 ppb POLYMETRON 9210 Silica analyser<br />

Silica 0.003–100 mg/l SiO2 Reagent test / LCW, PP, RL<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Silica 0–1,000 ppb SiO2 SILCOSTAT 9210 Photometric<br />

Silver 0.005–2,500 mg/l Reagent test / LCK, PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Sludge activity 5–200 µg Formazan Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Sludge level 0.2–12 m SONATAX sc Ultrasonic sluge level detection<br />

Sodium 0.01–20 ppm POLYMETRON 9240; 9245 Sodium multi- and single-channel analyser<br />

Sodium 0.0001–10,000 mg/l SODIMAT 9073 Autoscan analyser<br />

Solids 0.001–500 g/l TS SOLITAX sc Infrared duo straylight photometer<br />

Starch 2–150 mg/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Sulphate 2–900 mg/l Reagent test / LCK, PP and AV<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Sulphide 0.005–2 mg/l Reagent / LCK, LCW, RS<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Sulphite 0.1–5 mg/l Reagent test / LCW, HPT<br />

(DR Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

Surfactants, anionic 0.002–2 mg/l Reagent test / LCK, RS (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Surfactants, cationic 0.2–2 mg/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Surfactants, nonionic 0.2–20,000 mg/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Tannin and lignin 0.1–9.0 mg/l Reagent test / RS (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Temperature 0–1,250 °C SITRANS T (TH200/300/400) Resistance thermometer, thermocouple<br />

Tin 0.1–2 mg/l Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

TOC 0–50 ppm ANATEL A4000/ ASTRO TOC TOC analyser<br />

TOC 0.3–3,000 mg/l Reagent test / LCK, TNT (DR<br />

Series)<br />

Photometric test (UV/VIS spectrophotometer)<br />

TOC 0.01–20,000 mg/l TOCTAC, Astro UV TOC analyser, TOC analyser with UV digestion<br />

Tolyltriazole 1–20 mg/l Reagent test / PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Toxicity 0–100% Inhibition Reagent test / PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

TPH in water Threshold 2–200 mg/l Reagent test / IM (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Turbidity 0.001–1,000 FNU 2100N IS, AN IS, 2100P ISO Turbidimeter<br />

Turbidity 0.0001–9,999 FNU COSMOS-25, HT, VARI, XL;<br />

SOLITAX sc, SURFACE SCATTER<br />

SS7 sc, ULTRATURB sc,<br />

1720E sc, FT 660 sc<br />

Sensor <strong>for</strong> turbidity (nephelometry)<br />

Vicinal diketones 0.015–0.5 mg/kg Diacetyl Reagent test / LCK (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

Water determination, Karl Fischer 0.1–100 % TITRALAB 980 Automatic titration<br />

Zinc 0.01–6 mg/l Reagent test / LCK, PP (DR Series) Photometric test (UV/VIS spectrophotometer)<br />

LCK ➔ LANGE cuvette test HPT ➔ HACH pipette test RS ➔ Reagent solution<br />

LCW ➔ LANGE pipette test PP ➔ Powder Pillow test IM ➔ Immunoassay<br />

TNT ➔ TEST‘N‘TUBE AV ➔ ACCUVAC RL ➔ Rapid-Liquid-System<br />

Blue: laboratory analysis<br />

Red: process measurement technology<br />

Please note: the measuring ranges can vary from instrument to instrument<br />

For in<strong>for</strong>mation and advice, just call us!<br />

UK: (0161) 872 14 87<br />

IRELAND: (01) 460 25 22<br />

www.hach-lange.com<br />

19


INDUSTRY_SERVICES<br />

Wide range of service solutions<br />

to suit your needs<br />

75 years of analytical quality<br />

Made-to-measure solutions <strong>for</strong><br />

customers have been a HACH LANGE<br />

priority <strong>for</strong> 75 years. Customer<br />

requirements and wishes have been a<br />

crucial infl uence on the development of<br />

new products and services. The focus<br />

is on simple operation, the highest<br />

levels of user safety and reliable<br />

analysis results.<br />

What level of service would you<br />

like?<br />

You can choose the type and scope of<br />

service. Our qualifi ed technicians are<br />

close at hand wherever you are.<br />

The purchase of your instrument is<br />

followed by careful commissioning,<br />

with training <strong>for</strong> your employees.<br />

You then select a service package<br />

appropriate to your needs. The options<br />

range from a simple one-off inspection<br />

without a contract to an all-inclusive<br />

package with remote maintenance<br />

(24/7), on-site-service and an extended<br />

warranty period of 5 years.<br />

Key brands under one roof<br />

HACH, LANGE, SIGMA, PACIFIC SCIENTIFIC, CONTRONIC, RADIOMETER<br />

ANALYTICAL, BÜHLER MONTEC, ORBISPHERE, POLYMETRON, ASTRO,<br />

LACHAT, ANATEL, MET ONE, HIAC, GLI, EVITA, ZÜLLIG<br />

and Partnership with SIEMENS.<br />

HACH LANGE – the specialists <strong>for</strong> water analysis<br />

Everything from<br />

a single supplier<br />

Whether fi eld or laboratory analysis,<br />

samplers or process measurement<br />

technology, HACH LANGE stands <strong>for</strong><br />

the total spectrum of water analysis.<br />

From visual methods to comprehensive<br />

systems of reagents, mesurement<br />

technology and accessories.<br />

HACH LANGE Services<br />

Contact us to place an order,<br />

request in<strong>for</strong>mation or receive<br />

technical support.<br />

On site technical support.<br />

Service packages and extended<br />

warranty up to 5 years.<br />

Seminars and workshops:<br />

Practical and hands on training.<br />

For every application Parameters from A to Z<br />

Solutions from HACH LANGE are<br />

tailor-made <strong>for</strong> wastewater, drinking<br />

water or process water – <strong>for</strong> reliable<br />

control of operational processes<br />

and monitoring of legally prescribed<br />

limit values.<br />

From Ammonium to Zinc – consistently<br />

user friendly and proven in<br />

daily practice. Regulatory bodies<br />

and industry know they can rely on<br />

HACH LANGE solutions <strong>for</strong> everything<br />

from sample preparation to<br />

quality control.<br />

DOC030.52.10004.Apr09

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