c - Former Fort Ord - Environmental Cleanup

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""" "
~OR rcl AMERICAN EXPLOSIVES --PRIMASHEET 1000
NORTH AMERICAN EXPLOSIVES --PRIMASHEET 1000
..r7.\.TERIAL SAFETY DATA SHEET
lj ~ 137500N079933
~.J.ufacturer. s CAGE: OLHD2
Part No. Indicator: A
Part Number/Trade Name: PRlMASHEET 1000
====~~~===~. ==~ ~ ---c ~:~====~=
=======~===
General Information
===~='c Company's N~e: NORTH -=====~=~========~£='-~
AMERICAN EXPLOSIVES
Company's Street: HIGHWAY 175
Company's City: GRA:HAM
Company's State: Ki
Coropany's Country: US
Company's Zip Code: 42344
company's Emerg Ph #: 502-338-1988
Company's Info Ph #: 502-338-1988
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared; 01AUG92
Safety Data Review Date: l8NOV97
--=======~~~===~~======~
MSDS Serial Number: CFRXK i
,,==c ' ---c , ,""1- ~===========
=~============~~~=====~=~---
===~~=~~~~~==~======---~
Ingredients/Identity Information
=========~==~~~~~~===~-~===============~~===
~-oprietary; YES
~ qredient : PROPRIETARY
Ingredient Sequence Number: 01
~ ~
Proprietary: YES
Ingredient: PROPRIETARY
Ingredient Sequence Number: 02
======~~====~==== ---~--- ==...===- ===- --~--
==~=~~====~ ====-==
Physical/Chemical Characteristics
=====~~====~~~===~==~--~=========-~=~=~~~=;====~£;====~=
Appearance And Odor: OLIVE DRAB, PUTTY-LIKE MATERIAL IN SHEETS1
EXTRUDED SHAPES .
Boiling Point: NONE
Melting Point: SUPP DATA
Vapor Pressure (MM Hg/70 F) ; NONE
Vapor Density (Air=!) ; NONE
Specific Gravity: 1.48
Evaporation Rate And Ref: NONE
Solubility In Water: NONE
Percent
======0~====~-====~
Volatiles By volume:
~==~-:r=;====~===~~=;=====:~===
0.1
.-
Fire and Explosion Hazard Data
==========~===~~~~=~--- ~~~===~~--======~~==== ~
Flash Point= NONE
Lower Explosive Limit= NONE
CJ'pper E~plosive
~xtinguishing
Limit:
Media;
NONE
MEDIA SUITABLE FOR SURROUNDING FIRE (FP N) .
Special Fire Fighting Proc: USE NIOSH APPROVED SCBA & FULL PROTEi
EQUIPMENT (FP N) .EXPLOSION HAZARD EXISTS; EVACUATE PERSONNEL TO
~
PLACE; FIREMEN SHOULD NOT APPROACH FIRE .
Unusual Fire And Expl Hazrds: PBX MAY BE INITIATED BY IMPACT, ~,
---
,======,
c:ORDS
&
-:0,
~TIVE
SAFE
Page 1 of 3
---
ICTION &
S0"d .>:~L !i1!i1!i1?-?!i1-I:lr

--.
NtlR TH AMERICAN EXPLOSI YES -PRIMASHEET 1000
ELECTROSTATIC DISCHARGE. AUTOIGNITION TEMP:
===~==============::::===~===='=~~=~
565F,296C-
===========~=====~=T=:
~-
-~"..-~===--'=~'- ~--- ~-
Reactivity
~
Data
~~;
====~==:==Ja=~¥======
Stability:
Cond To
YES
Avoid (Stability) : STORAGE >170F. ANY CONDITION WHICH
I
r: CTS
SUBJ
MATERIAL TO SHEARING, GRINDING OR IMPACT .
Materials To Avoid: STRONG ACIDS; ALKALIES & OXIDANTS.
Hazarqous Decomp Products: TOXIC, AVOID INHALATION & INGESTION.
Hazardous Poly Occur: NO
I
~~n~ition~~~~-~~~:~={Poly) : NOT RELEVANT -~~ =~---I
---Health-~~~~rd Data
-F~='""~=::=-
I
~~~~~L;~OE~~~~u=e ~n BY ~F~~~~~-~~~~~~~-~~~T~-~~--
Route Of Entry -Skin: NO I
Page lot ~
Route Of Entry -Ingestion: YES
Health Haz Acute And Chronic: EYE/SKIN CONTACT & INHALATION:NOT A
ROUTE OF EXPOSURE. INGESTION:MODERATELY TOXIC IF INGESTED.
ILlKELY
Carcinogenicity- NTP: NO
Carcinogenicity- IARC: NO
Carcinogenicity- OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS .
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: INHAL;REMOVE TO FRESH AIR. SUPPORT BREA~ rHING
..;J':VE O*2/ARTF RESP) (FP N) -EYES: IMMEDIATELY FLUSH W/POTABLE WAT] ~R FOR A
~&IMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD (FP N) .SKIN: FLUSH W/COPIOUS
AMOUNTS OF WATER. CALL MD (FP N) .INGEST:ADMINISTER
===~='" --~--~ ~====~=~=~~=;:==, ===---
EPETIC. REST.'
==~=,
='=
Precautions
--
for Safe Handling and Use
=====
~NT
FEDERAL
ROUS
LlOCAL
:ROP WT
.======~~===~~===~====~====~==~======~==- ~====~===-
Respiratory Protection:
Control Measures
NIOSH APPROVED RESPIRATOR ~
APPROPRIATE FOr
EXPOSURE
OF CONCERN (FP N) .NONE.
Ventilation: NONE.
Protective Gloves: RUBBER OR POLYMERIC GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N) .
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WH: [CH MEET
~SI DESIGN CRITERIA (FP N) .
.'ork Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Suppl. Safety & Health Data: MP:SOFTENS
=""'=========~~===~=======~=~===~===~~~=~~==
AT 165F, 74C.
~
, I c-
--~---~
======1==========~
==~---=--===--=~~~-~~--=-~:~:~~:::::~~=~:::-~~-~~~~-~-
=~====~---~=====~~-~===========~~=============
000c-CO-l:JO

Page j ot j
~=~==='~-===~=--
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--===~
Disposal Data
~==============~=-~-
,==~==~='~===~========~====="
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Label
"====:;====~=
Data
~~~===~c===~~======,
Label Required: YES
Technical Review Date: 18NOV97
~~~T--~-~~~
Label Date: 07NOV97
Label.Status:
Common Name:
G
PRlMASHEET 1000
Chronic Hazard: NO
signal
Acute
Word:
Health
DANGER!
Hazard-Moderate; X
Contact Hazard-Slight: X
Fire Hazard-Slight: X
Reactivity
Special
Hazard-Severe:
Hazard Precautions:
X
EXPLOSIVE. ACUTE:INGESTION:MODERATELY TOXIC IF
INGESTED. CHRONIC=NONE LISTED BY MANUFACTURER.
Protect Eye: y
Protect Skin: Y
Protect Respiratory: y
Label N~e: NORTH AMERICAN EXPLOSIVES
Label street: HIGHWAY 175
Label Ci ty : GRAHAM
Label State: KY
Label Zip Code: 42344
Label Country~ us
i )el Emergency Number: 502-338-1988
l1.0.d 8£:S1 000c-c0-1:JO

...ID~'ffiFICA-nON ...
MSDS RECORD NUMBER: 347631
PRODUcr NA\fE(S) : SAFETY FUSE.
PRODt;cr rnE~-nFICATION : cxu 0012
...M.~TERIAL SAFETY DATA ...
H.~-\.~ SU~fM~Y (29 CFR 1910.1200)
MSDS
SAFETY FUSE
Physical Haz:lrds: Burning rni'tIU!e.
He:llth Haz:lrds: This is a packaged product that
will not result in exposure to the contents under
nor:n:ll conditions.
1. PRODUcr rnE~-nFIcA11ON
Produc: ~ame: Safety Fuse.
Produc: Class: Non-electric ignition system.
SHIPPL'iG DESCRIrnON fu"NmD NATIONS
(U.S. DOn
Shipping ~ame: Fuse, Safer:/
Shipping OassiDivision: 1.45
Produc: Identification ~o (P~): UNO105
Packing Group: II
coMPosmoN
T ex,ile carcass over-extruded with asphalt and
polyethylene, containing:
Black Powder
Aromatic Compounds
2. PHYSIC.-\L PROPERTIES
Description: Ingredients are housed in a textile
carcJSs over-extruded with asphalt and
polyethylene.
3. FIRE .-\.~D EXPLOSION DATA
Flash Point (method): Not applicable.
Autoignition Temperature: Not available.
Flammability Limits in .o1.ir (%): Not applicable.
Fixe E"{tinguishing ~edia: Fires can be controlled
with water.
Fixe Fighting Procedures: Apply water.
Other Fire or Explosion Haza.rds: Fuse can be
readily ignited by flame.
4. RE.~cm1n. DATA
Stability:
Under ~orrnal Conditions: Stable.
Under Fire Conditions: May ignite if heated.
Haz3.rdous Polymerization: Will not occur.
Condiricns to .-\void: Heat or flame that may ignite
the ?roduc:.
Mate~als to Avoid: The wJ..x covering and
P:Jge G-:.6
A
polyerhylene will, in rime, be affected by fuel oil.
Haz:1rdous Decomposirion or Combustion
Produc:s: v.:1pors i)f ~Ox, CO.
5. TOXICOLOGtC.~ .-\.~-o HE.-\LTH DATA---
Toxicological Data: This is :1 manufacrured article
and may release hazJ.rdous
producrs during burning. Ignition producrs include
NO, NO2, CO, SO2.
Recommended Exposure Limirs:
OSK~ ACGIH
PEL TLV
Nirrogen Dioxide 5 ppm-c:iling 3 ppm
Nitric Oxide 5 ppm 25 ppm
Carbon ~onoxide 50 ppm 50 ppm
Sulfur Dioxide 5 ppm 2 ppm
6. PREv"E:-.."TT"I"E ~E.-\SURES
Handling P~oc~dures and Equipment: Avoid
inhalation of smoke J.nd ."apors.
Storage TemperatUre (oq: .-'\[l1bient temperatures.
Storage RequirementS: Product should be stored in
a cool dr:;1 environment and !lot stored in close
proximity to high explosive material.
Other Prec3.utions: This product is explosive.
Meet all legal requirement for shipping and
magazlmng.
7. ENV1RON~fENT..:\L PROTEcnON DATA
Steps to be Taken in the Event of a Spill or Leak:
Pick up CJ.utiously as per normal preC:lutions taken
in handling ~xplcsives.
Environme:ltal EffectS: None.
DeJ.ctivating Chemicals: Not applicable.
Waste Disposal ~ethods: Return to supplier or
contact supplier Technical Representative to
arrange for destruction by burning.
8. ADOmONAL 11'-l"FOR.'vf.-\110N ~"D
SOL"RCES USED
1. Docume:ltation of the Threshold Limit Values
and Biolo~c3.l E"t"posure
Indices, 5th ed.. AmericJ.n Conference of
Governmental Industrial Hygienists
Inc., Cincinnati. 1986.
2. Grayson, Martin, Ed., Kirk-Othmer Concise
Encyclopecia of Chemical
T echnolog'! .3rd ed., John Wiley and Sons, New
York,1985.
C.\fS Eilvironm~ntaJ Resroration Group

ID E !';"11 F1CA 11ON
MSDS RECORD NUMBER: 347777
PRODLcr ~A."1E(S): ThT
PRODL'cr mEl'iuFICA11ON: E..""(p 0032
...~~TER1AL SAFETY DATA ...
PRODUcrIDENI1FTCATION
Product ~ ame: TNT
Chemic:Ll Name: 2,~,6- Trinitrotoluene
MSDS
Synonyms: Methyltrinitrobenzene, alpha- TNT ,
Nitropel, ~'T (TYl Flake) (Military Grade), TNT
(Flake), Triton, Trinitrotoluol, Trocyl, Tolite,
Trinitrotoluene.
Chemic:Ll Family: High E.~plosives.
Molecular Formula: (NO2)3C6H2CH3
Produc: Use: Blasting agent. Manufacture of
packaged expi(1sives and primers
( C:lSt explosive ).
REGUL.~TORY S-ECTION
Controlled ProductS Reg'Jlarions Oassific:lrion:
This product is an explosive
and is not regulated by \\t1iMIS.
OSHA Hazard Communic:lrion (29CFR
1910.1200) Classification: Irritant (eye,
skin and respiratory tract); skin sensitizer;
explosive.
U .S. DOT Oassificarion: Refer to the "Code of
Federal Reg'Jlarions."
Read the entire MSDS for the complete hazard
evaluation of this produc~.
H.~-\RDOUS !NGREDIE~lS OF PRODUcr
ACGIH
HazJrdous IngredientS %(w/w) TL V
Trinitrotoluene 98-100 0.5 mg/m3
CAS ~o. 118-96- 7
PHYsrc.o:\L PROPERTIES
Physic.11 State: Solid.
Appe.1rance and Odour: Pale yellow flakes or
priUs; pr.1ctically odourless.
Odour Tur~shold: Not J.pplic.1ble.
Boiling Range (Deg. C): Decomposes J.t 270.
Melring/fre~zing Point (Deg. C): 80.65 (pure
~l)
Vapour Pressure: 0.053 mmHg (@ 85 Deg. C).
Specific Gravity: 1.645 (crystals); 1.47 (molten)
(water = 1).
VJ.pour Density: Not available.
BuL1

,T AIJ..' U
TNT
Agency for Research on C1ncer), not regulated as carcinogens by OSK--\ (Occupational Safety and
Health Administration), and not listed as
carcinog'=:1S by NTP (National Toxicology
ProgrJIn).
Reproductive Effects: No information is available
and no adverse reproductive effects are anticipated.
Mutagenicity Data: No information is available
and no adverse mutagenic effects are anticipated.
Teratogenicity/Fetotoxicity Data: ~o information
is available and no adverse
teratogenic/embryotoxic effectS are anticipated.
Synergistic Materials: None known.
EFFEcrS OF EXPOSu"RE WHEN:
Inhaled: Product is irritating to the nose, throat and
respirJtcr:/ tract. May cause c:ntral nervous system
(~S) depression, liver damage, kidney damage
and methemoglobinemia. See "Other Health
Effects" S~ction.
In contact with the skin: This product may cause
irritation due to abrasive ac:ion. Prolonged and
repea~:d contact may lead to de:matitis. May be
absorbed through intact ski.'1. May cause skin
sensitization or other
allergic responses. S~e "Other Health Effects"
S~ction.
In contact with the eyes: This product causes
irritation, redness and pain. Prolonged and
repeated contact may cause cataracts.
Ingested: Ingestion of large amounts may cause
nausea. gastrointestinal upset and abdominal pain.
~fay cause central nervous system (CNS)
depression, liver damage, kidney damage and
methemoglobinemia. S~e "Other Health Effects"
Section.
Other Health Effects: Initial manifestation of
methemoglobinemia is cyanosis, characterized by
navy blue, almost black lips, tongue, and mucous
membranes, with skin colour being slate gray.
Further manifestation is characterized by headache,
weakness, dyspnea, dizziness, stupor, respiratory
distress and death due to anoxia.
Signs and symptoms of kidney damage generally
progress from oliguria. to blood in the urine, to
total :enal failure.
If ingested, Nitrates may be reduced to nitrites by
bacteria in the digestive tract. Signs and symptoms
of nitrite poisoning include cyanosis (due to
methemoglobin formation), nausea, dizziness and
increased heart rate.

MSDS
CNS depression is charJ.cteriz~d by heJ.dache,
dizziness, drowsiness, nausea, vomiting and
incoordination. Sl:vere overexposures may lead to
coma and possible death due to ~spiratory failure.
SensitizJ.tion is the proc:ss whereby a biologic:1l
change occurs in the individual because of
previous exp9sure to a substanc: J.nd, as a result.
the individual reacts more strongly when
subsequently exposed to the substance. Once
sensitized, an individual can ~J.ct to extremely low
airborne levels, even below the TL V, or to skin
contac:.
FIRST .-\ID PROCEDL"RES WHEN:
Inhaled: yfove victim to fresh lir. Give artificial
respiration ONL y if breathing has stopped. Give
cardiopulmonar:' resuscitation (CPR) if there is no
breathing .~'\j"D no pulse. Obtain medical attention
Il\L"£EDL-\TEL y .
In contact with the skin: Flush skin with running
water for a miDi'!lum of :?0 mi.'1utes. Start flushing
while removing contaminated ciothing. If iIritation
persistS, repeat flushing. Obtain medical attention
Il\{~£EDL-\TEL y .
In contact with the eyes: Immediately flush eyes
with running water for a minimum of 20 minutes.
Hold e:/elids open during flushing. If irritation
persistS. repeat flushing. Obtain medical attention
I~L."£EDI.-\TEL Y.
Ingested: If victim is alert and not convulsing, rinse
mouth out J.nd give 1/2 to 1 glass of water to dilute
material. DO NOT induc: vomiting. If
spontaneous vomiting occurs, have victim lean
forward with head down to avoid breathing in of
vomitus. rinse mouth and administer more water.
Obtain medical attention IM~£EDL-\TEL y .
E.merg:e:lcv Medic:ll Care: .AJcohol use may cause
-..
e:thanc:d response to effec:s of TNT exposure.
Individuals deficie:lt in glucose-6-phosphate
deh:;drogenase may be at greater risk. Medical
conditions that may be aggr~vated by exposure to
this product include cardiovascular diseases and
live:-, blood J.nd kidney disorders.
PRE\t"E~-r A TIVE ytEAS ~RES
Recommendations listed in this secrion indicate the
c:..pe of equipment which will provide protecrion
against overexposure to this product. Conditions
of use, adequacy of engine~ring or other control
me:J.Sur~s, and acrua1 exposures will dictate the
ne:d for specific protecrive devices at your
Page G-IO
Th'T lA
workplJce.
Engineering Con[rols: Local exhaust ventilation
required. if the product itSelf is handled.
Respirator'j Protection: A
NIOS~ISH.-\-approved air-purifying respirator
equipped .Nith combined dust, mist, fume/organic
vapour Cartridges for concenttadons up to 5 mglm3
Thl. An air-supplied respirJtor if concentrations
are higher or unknown.
Skin Protec:ion: Gloves and protective clothing
made from cotton should be impervious under
conditions of use. The use of cover:ills is
recommended.
Eve Pro[t:ction: SafeN g]JSses with side shields are
..recommended
to prevent eye contact.
Other Personal Protective Equipment: Locate
safet:' shower and eye'.vJSh station close to
chemical handling :lrea.
C...(5 £nvironmcntal R..storalion Group
Handling P:cc:dures and Equipment: This product
is an explosive and should only be used under the
super";ision of an.experienc:d blaster.
Stor:lge Tempe:-arure (Deg. C): See below.
StorJge RequirementS: Dry, secure magazine that
is properly grounded. Do not expose to
temperatUres above 35 Deg. C.
Other Prec:lutions: Use only with adequate
ventilation and avoid bre:lthing dusts/vapours.
Avoid contact with eyes, skin or clothing. Wash
thoroughly with soap and water after handling.
WJSh contaminated clothing thoroughly
before re-use.
E~vlRONME~l.-\L PROTEcnON DATA
Steps to be Tak:n in the Event of a Spill or Leak:
Stop Jnd contain spill. Wet spilled material and
swe:p up into strong plJStic bags or plastic
containers. K~ep the material we[. Avoid use of
me~al ~ools. Be careful to avoid shock, friction and
sparks. Nc[ify applic:lble government authority if
releJSe is .eportable or could Jdversely affect the
environment.
Environmental EffectS: Har:nful to aquatic life at
low conc:ntrations. A concentration of 1.5 mg/1.
is toxic to fish. Can be dangerous if allowed to
enter drinking water intakes. Product has an
un:lesthetic Jppe'JIlnc: and can be a nuisance.
Delctivlting Chemic:lls: ~one known.
WJSte Dispcsal ~[ethods: Do not dispose of waste
with norm.1l garbage. or to sewer systems. Bum
under supervision of an expert at a approved

explosivc burning ground or destroy, by dctonation
in borcholes, with
y~..., ,
cxplosivcs in accordance with applicable 1oc:11,
state and fcdcral regulations.
ADOmONAL INFORMA11ON AND
SOURCES USED
National Instirutc for Occupational
TNT
Safety and Health, U.S. Dept. of Health and
Human Services, CinCinnati, 1987.
U .S. Dept. of Health and Human Services,
NIOSH/OSHA Occupational Health
Guidelincs for Chemical Hazards, NIOSH, U.S.
Dept. of Labour, 1978.

..IDENTIFICA110N ...
MSDS RECORD NUMBER: 347776
PRODUcr NA."iE(S) : PEm
PRODUcr IDENnFICA-nON: E..""(p 0074
...~TERl-\L SAFETY DATA ...
PRoDucrrDE~cA110N
Product ='lame: PETN
Chemic:ll ='lame: Pencaervthricol Tetranitrate.
-
Synonyms: 1,3-Propanediol, 2,2-bis-dinitrate
( ester). Penthrite, Nitropenta,
Corpent, PETN (Cap Grade) (medium fine or
super fine).
Chemical Family: High Explosive, (Initiating
Explosive).
Molecular Formula: C(CH20NO2)4
Product Use: Manufacture of detonators,
detonating cords and primers.
REGUL.3.,.TORYSEC110N
Controlled Products Regulations Classification:
This product is an explosive
and is not regulated by \\I"HWS.
OSH..3.,. Hazard Communication (29CFR
1910.1200) Oassification: Oxidizer; skin
sensitizer; irritant ( eye, skin, respiratory tract);
explosive.
U.S. DOT Oassification: Refer to the "Code of
Federal Regulations."
Read the entire MSDS for the complete hazard
evaluation of chis product.
H.~ARDOl:;S rNGREDIE~IS OF PRODucr
ACGIH TL V
Hazardous Ingredients %(w/w)
Pentaerythitol Tetranicrate 65- is Not listed
CAS ~o. i8-11-5
PHYsrc.-\L PROPERTIES
Physical State: Solid.
Appearance and Odour: \\Iwre crystalline solid;
odourless.
Odour Threshold: Not applicable.
Boiling Range (Deg. C): Decomposes betWeen
161-233 Deg. C
Melting Freezing Point (Deg. C): 140 (min., dry
basis).
\'apour Pressure: Not JppliCJ.ble.
MSDS
PETN A
Specific Gravity: 1.773 @ 4 Deg. C/20 Deg. C
(dry basis, water = 1)
Vapour Density: Not applicable.
Bulk De~ity: 0.80-1.07 g/c:n3 (cap grade -loose
pour)
Evaporarion Rate: Not applicable.
Solubility: Very soluble in ac:tone (25 g/100 9 @
20 Deg. C); slightly soluble in alcohol and ether;
practically insoluble in water.
% Volatile by Volume: Not applicable.
pH: Not :1pplic:1.ble.
Coefficient of Water/Oil Distn"bution: Not
available.
Se:lSitivity to ~lechanica1 Impact: Dried PETN is
ver:' shock sensitive.
Rate of Burning: Not :1vailable.
Explosive Power: 591 kJ/1OO 9
Se~itivity to Static Discharge: May be detonated
by :1 :7.000 Volts or higher electric spark.
RE.-\C11vlTY DATA
Stability:
Under Normal Conditions: Stable.
Under Fire Conditions: Deflagarion @ 202 Deg. C.
Explodes @ 205-225
Deg. C, burns unconfined.
Haz3Idous Polymerization: Will not occur.
Conditions to Avoid: High temperatures, sparks,
open flames and all other sources of ignition.
Materials to Avoid: Acids, alkalis, oxidizing and
,.I .
re-uC'.ng agentS.
Haz"JIdous Decomposition or Combustion
ProductS: Thermal decomposition products are
toxic and may include hvdroc"JIbons, oxides of
..
C:1rbon and nitrogen.
FIRE .~~"D EXPLOSION DATA
F1ash Point (~ethod): Not :1pplicable.Autoignition
Temperarure: Deflagration @ 202 Deg. C.
Explodes @' 205-225 Deg. C.
F1ammability LimitS in Air (% ): tEL: Not
applic:1ble. utL: Not applicable.
Fire Extinguishing Media: See below.
Fire Fighting Procedures: DO NOT FIGlfr FIRES
L~vOL V1NG EXPLOSIVt
~l-\TER1ill. Immediately evacuate all personnel
from the area.
Other Fire or E.~plosion Hazards: PETN can be
deton:1.ted bv friction or :1 heavv blow if allowed to
..
become dry and is even more sensitive if
contaminated with grit. In the presenc~ of acid

"ISDS
(eg. Nitric), PETN may
start to decompose and could ~:tplode, especially
under confinement. A P~ fire 'Nil1 emit copious
amountS of :oxic nitrogen oxide fumes.
TOXICOlOGiC.~ .~'ffi HE~ TH OAT A
R~com:mended Exposur~ Umit: None established
for this product. See "HAZARDOUS
INGREP[E~S OF PRODUcr" Section.
Toxicologic:l.1 Oata: This product has not been
tested.
Pentae::,thritol Tetr:lnitrate LDSO ( or:1l,mouse )
= 25500 mg;kg (6)
CarC".nogerjcity Data.: Tae ingredient(s) of this
product is (are ) not classified as carcinogenic by
ACGIH (.-\merican Conference of Governmental
Industrial Hygi~nists) or lARC {International
Agenc:;. for Research on
Canc:r), not regulated as carcinogens by OSHA.
(Occupational Safety and Health Administration),
and not listed as carcinogens by NTP (National
Toxicology Program).
Reproductive Effects: No information is available
and no adverse reproductive effects are anticipated.
Mutagenicity Data: No information is available
and IlO adverse mutagenic effects are
anticipated.
Teratogenicity Data: No information is available
and no adverse teratogenic;'embryotoxic effects are
anticipated.
Synergistic ~Iaterials: None known.
EFFECTS OF EXPOSURE \\t"HEN:
Inhaled: Product is irritating to the nose, throat and
respiratory tract. May cause low blood pressure.
Se~ "Other Health Effects" Section.
In contac: with the skin: This product may cause
irritation due to abrasive action. May cause skin
sensitization or other allergic responses. See
"Other Health Effects" Section.
In contact with the ~yes: This product may cause
irritatioIl, redness and possible damage due to
abrasiveness.
Ingested: Ingestion of large amounts may cause
nausea. gastrointestinal upset and abdominal pain.
Other Health Effects: PETN is a vasodilator. It
promotes periphral pooling of the blood and
decr~ases venous r~rurn to the heart. This results
in an uveralllowering of the blood pressur~.
Sensitization is the process whereby a biological
change occurs in the individual because of
PETN ,a
previous ::cposure to J substJnce Jnd, JS J result,
the indi'/idual reacts more strongly when
subseque~tly e:cposed to the substance. Onc:
sensitized. an individual C:ln react to extremely low
airborne levels, even below [he TL V, or to skin
contact.
FIRST AID PROCEDu'RES WHE~:
Inhaled: ~ove victim to fresh air. Give artificial
respir:ll:ion ONL y if breathing has stopped. Give
QIdiopulmonar! resuscitation (CPR) if [here is no
breathing .~~"D !10 pulse. Obtain medicai Jttention
IMMED L-\ TEL y .
In contact with the skin: Flush skin with running
water for 1 minimum of ::.0 minutes. Start flushing
while removing contaminated clothing. If irritation
persists, repeat flushing. Obtain medical attention
IM~EDL-\TEL Y.
In contac: '.vith the eyes: Immediately flush eyes
~ith running water for a minimum of 20 minutes.
Hold eyelids open during flushing. If irritation
persists, repeat flushing. Obtain medical attention
Il\,IfMEDI.-\TEL Y .
Ingested: If vicrim is alen and not convulsing, rinse
mouth out and give 1/2 to 1 glass of water to dilute
material. DO NOT induc= vomiting. If
spontaneous vomiting occurs, have victim lean
forward with head down to avoid breathing in of
vomitus, rinse mouth and administer more water.
Obtain medical attention IM~fEDL~TEL y .
Emergenc:' ~edical Care: Tre:lt symptomatically.
PREVE~-r.-\ m"E YfE.-\SLRES
Recommendations listed in this section indicate the
type of equipment which will provide protection
against overexposure to this product. Conditions
of use, adequacy of engine~ring or other control
me3.SUres, and acrual exposures will dictate the
need for specific protec:ive devices at your
workplac~.
Engine~ring Controls: Loc.11, non-mechanical
exhaust ve:ltilarion ~ecommended if material itself
is manipulated.
Respiratory Protection: A
N10S~ISH.-\-approved air-purifying respirator
equipped with dust, mist, fume cartridges for
.-conc~ntrltlons
up to) mg.:m-,.
An air-5uFplied respirator if concentrations are
higher or unbown.
Skin P~otec:ion: Gloves and protective clothing
made from cotton should be used. The use of

MSDS
PETN
coveralls is recommended.
Eye Pro[ection: Saiecy glasses 'Nith side shields are
recommended to preven[ eye con[act.
Other Personal Protective Equipment: Wear an
impermeable apron and boo[s. Locate safety
shower and eyewash station close to chemical
handling area.
Handling Procedures and Equipment: This product
is an explosive and should only be used under the
supervision of an experienced person.
Storage Temperature (Deg C): See below.
Storage RequirementS: Dry, secure magazine that
is properly grounded, away from other high
explosive materials. Do not expose to
temperatures above 40 Deg. C.
Other Precautions: Meet all legal requirementS for
shipping and magazining. Government regulations
require that there be a minimum of 25% moisture
in PETN .Nhen packaged and shipped in fibreboard
boxes.
E~vlRONME~-r.-\L PROTEcnON DATA
Steps to be Taken in the Event of a Spill or Leak:
Stop and contain spill. Ensure no danger of
friction, static or heat Keep the material wet at all
times. Recover the material as well as the
contaminated soil, using an absorbant, if necessary.
Use non-sparking tools (eg. wood or brass). Notify
applicable government authority if release is
reportable or could adversely affectthe
environment.
Environmental EffectS: May be hannful to aquatic
life. Can be dangerous if allowed to enter drinkjng
water intakes. Tnis material is extremely insoluble
in water. Furthermore it is chemically stable in a
non-acidic medium.
Deactivating Chemicals: P~ destroyer (solution
containing Potassium Hydroxide, Methyl Alcohol,
Acetone and Water).
Waste Disposal ~ethods: Bum under supervision
of an expert at a approved explosive burning
ground or destroy, by detonation in boreholes, with
explosives in accordanc~ with applicable local,
state and federal regulations.
ADDmON.-\L n-."FOR~l-\TION k'ffi
.SOLRCES l!SED
1. Chemistry and T echnolog:. of Explosives, Vol.
2, T. Urbanski. (1983 repr), Pergamon Press.
2. Hawley, Gessner G., The Condensed Chemical
Dictionary , lOth ed., Van
A,
Nostrand Reinhold Co., New York, 1981.
3. Wmdholz, Martha, Ed., The Merck Index:, lOth
ed., Merck and Co. Inc., Rahway, New Jersey,
1983.
4. A..\fCp. 706-177, Engineering Design
Handbook, Properties of Explosives of Military
Interest, (1971), U.S. Army Material Command.
5. Formula Book -Explosives, C-I-L Inc.,
Explosives Research and T ccnincal
Department, Current Edition.
6. Supplier's Material Safety Data Sheets.

~l-\ TE R I A L S A F E T y D A T A SHEET
HOLSTON D&cNSE CORPOR.-o\110N
No.4133,00i7
For more information about this MSDS, dial
(615)2:+i-9111, E."(t 3302
EFFEcnVE DATE: 07/15;87
DOT No.'OOi7
L-\BEL ~A.\1E: cOl".1POSmON C-4
CHE~1ICAL NA."fE: NA
TRADE, COMMON NA.\1ES, OTHER: NA
CHEMIC.~ FOR.\1UU: c} H 6 N6 06 (RDx
only)
MOLECUL;o\R \Vr.: 222.13 (RDX only)
sEcrrON II H..'\z.-\RDOUS INGREDIENTS
OF ~1TXTURE.
cHE~acAL NA..\1ES: Cyc!otrimethylene-
trinitramine.
Common names: WEIGrrr ACGIH TL v
RDX, Cyclonite 89.9% 1.5 mg.m }TW A
Hexogen 92.0% 3.0 mg/m 3
STEI (skin)
SECTTON III PHYSIC.o\L DATA
BOILING POI~T COc ): NA
SPECIFIC GM V1TY(H O=1).- 1.7
MELTh'.'...G POI1'1-rCOd :205 with decomposition
V.A.POR PRESSURE: O
PERCE~-r VOL-\11LE: NA
V.J..POR DENSITY: NA
EV APOR.~110N RA.TE: NA
SOLu"BILITY IN W ATER: Insoluble
APPE.~'iCE AJ.'ffi ODOR: Putty like plastic,
white to off white.
SECTTON IV EIRE ..\l~ EXPLOSIVE
H.~.-\..~D DATA
FLo\SH POI~T COd: NA
FL-\.\I~LA.BLE UMn-S: NA
E."

Mouse-500 mykg, osa~ PEL -Not est.1blished
for any component in this formulation.
EFFEcrS OF EXPOSURE:
Skin and Eyes. C1n cause .1llergic skin
reaction. Can course eye irritation. Avoid
prolonged contact with skin. Avoid contact with
eyes.
INHAL-\ 11ON .~'iD INGES11ON:
Chronic exposure to RDX dust has been reported
to cause convulsions or unconsciousness.
Chronic
local and systemic effectS are not fully lmown.
Inhalation and ingestion c~ result in systemic
poisoning, usually affecting the bone marrow
(blcod-c=l1-producing system) and the liver.
Avoid inhalation and ingestion of dust.
E~RGENCY Al~"D FIRST ,@: .
~ In case of contact., flush thoroughly with
large amountS of low pressure water for at least
15 min. Remove contact lenses. Get medical
attention.
~ Wash with soap and warm running water.
Clean clothing thoroughly and dispose of shoes
contaminated with =xplosives in accordance with
explosive disposal ?rocedures. Get medical
attention for rash or irritation.
rNlL-\L~11ON: Remove to fresh air, treat any
irritation symptomatically. If breathing is
difficult, give oxygen. Get medical attention.
INGESTION: If conscious, induce vomiting
immediately by giving lor .? glasses of water
and touching back of throat with finger or blunt
objec: or by giving syrup of ipecac. Never give
anything by mouth to an unconscious person. Get
medical attention.
SEcrrON VlI SPEO.~ PROTEcnON
I!'-roR~l-\ 11ON
RESP!R.-\TORY PROTEcrrON: NA
\I'E!'-t'TIL-\TION: NA
PROTECrT\I"E GLO\l"ES: If prolonged or
repeated skin contact may occur, impervious
gloves are recommended.
EYE PROTEcrrON: Industrial safety glasses
are recommended for any type of industrial
chemical handling.
OTHER PROTEcrIVE EQUIP~1EL\4"T: For
explosive-handling worke:'S, caps and coveralls
for full body (arms & legs) protection are
recommenced. Cotton underwear, socks, and
MSDS
coL\IPOSmONC-4 /4
conducrive shoes are recommended to avoid
human static disch'JIge. A safety shower, an eye
bath, and washing facilities should be available.
As a precaution. handle only in wel1-ventilated
areas, change clothing daily, bathe at the end of
the work period, and wash hands thoroughly
after handling.
SEcnON VIII SPILL OR LE.3,.K
PROCEDURES
STEPS TO BE TAKE:.~ IN E~'\j"T
l'¥t.1.,TER1-\L IS RELEASED OR SPTT TFD:
Oean tip spills immediately using a soft bristle
brush and a conductive rubber pan or rubber
shovel. Use conductive containers and ground
all containers before transferring explosives
betWeen containers, Treat like a flammable
solvent with regard to electrostatic discharge.
Avoid pinching material. metal to metal
contract., impact with sharp objects, friction or
other situations which may initiate the explosive.
Avoid sand, glass, grit, and metal fragments
which may sensitize the explosive to impact
and/or friction. Wet with water to desensitize.
WASTE DISPOSAL MErdOD:
E."(plosives should be destroyed by open burning,
by burning in an approved incinerator, or by
chemical treatment. with caustics. The disposal
site should be located to provide. adequate
quantity-distanc: protection for adjacent.
facilities and personnel. Explosives should not be
burned In containers. The explosives should be
ignited remotely. Personnel should wear flame
resistant clothing. The disposal of explosives
should comply with all applicable federal, state,
and local regulations.
Refer to Section IV for precautions when,
burning. Store, and handle waste explosives as
Oass A explosives. Transpon in accordance
with the Depanment of Transponation
regulations for Oass A explosives. Obtain
approval from appropriate safely Agency before
disposal.
SEcrION IX SPECIAL PRECAtmONS
PREcArnoNs TO BE T.o3..KEN IN
STOR.-\GE ..\J.~"D H..\J.~"DUNG: High explosives
should be stored in approved explosives
magazines in accordance with .-\."'ICR 385-100.
Storage and handling must be carried out in
accordanc: with appropriate Safety Agency

egulations conceming quantity distance,
barricading, persoMel exposure and material
handling equipment. Recycle or dispose of used
containers in accordance. with appropriate Safety
Agency regulations. In buildings and lacations
where explosives with spark energies for
initiation not greater than 0.02 Joules are
handled, the relative humidity should be 50% or
greater.
SECfION X O111ER PRECAlJrIONS:
CAUTION, Explosives must be tested for
compatibility with any materials which they
contact. Materials include other explosives,
solvents, adhesives, metals, plastics, paints,
cleaning compound, floor and table coverings,
packing material, and other similar materials and
equipment,. Keep container closed. Wash
throughly after handling. Wash contaminated
clothing before reuse. Extreme care should be
exercised during maintenance of explosive
contaminated equipment Decontamination
procedures include washing/steaming, chemical
decontamination and thermal decontamination.
Decontamination should be performed prior to
welding, cutting or grinding metal parts.
Penetrating oil should be used liberally on nuts,
COMPOSmONC-4
bolts, and all threaded connections to aid in
descnsitizing hidden explosives prior to
disassembly. Refer to AI\1CR 385-100,
paragraph 16-18.
The notation NA is used to indicate a section or
item of information is not applicable for the
Chemical or ingredient.
Additional information about the properties of
explosives can be found in the Engineering
Design Handbook, Explosives Series, Properties
of Explosives of military interest, Army Material
Command Pamphlet 700-1 ;7.
Additional Infonnation about fire fighting
procedures; colIection and destrUction of waste;
and storage and handling precautions can be
found in the Army Safety ~anual, AImy
Materiel Command Regulation 385-100 and the
Department of Defense ContraCtor's Safety
Manual for Ammunition, Explosives and Related
Dangerous Material, DaD 4145, 26M.

~
...mE~-mICAtiON ...
MSDS RECORD NUMBER: 347637
PRODt:cr NA.~(S) : Safety Fuse Assemblies.
PRODUcr IDENnFICAtiON : CXU 0007
...~~TERLA.L SAFETY DATA ...
HAL-\..Q.D SUMMARY (29 CFR 1910.1200)
Physical Haz3.!ds: E.~losive.
Health Haz3.!ds: This is a packaged product that
will not result in exposure to the contents under
normal conditions.
1. PRODUcr IDE~-nF1CAtiON
NON;.ELECfRIC CAPS
Product ~ame: Safety Fuse .~semblies.
Product Class: ~on-electric ignition system.
SHIPPL'iG DESCRIrnON :L~-n"ED NA11ONS
('U.S. DOT)
Shipping ~ame: Detonator assemblies, non-electric
(DETONATORS, CL~S A)
Shipping Class/Division: 1.lB (E..'"(PLOSIVES,
CL~S A)
Product Indentification No (PIN): UN0360
Packing Group: II
cOMPOSmON
An aluminum shell containing:
Pentaerythritol Tetranitrate (pEW)
Le~d .~ide
Lead Styphnate
Textile c~rcl5S, over-extrUded with asphalt and
polyethylene, containing: Black Powder Aromatic
Compounds
2. PHYSIC..3..L PROPERtiES
Desc:iption: IngredientS are housed in an
aluminum shell, or textile carcass over-extruded
with asphalt and polyethylene.
3. FIRE .~~"D E-XPLOSION DATA
F1ash Point (method): Not applicable.
Autoig!rition Temperature: PETN explodes at
205-215oC
Flammability LimitS in Air (% ): Not applicable.
Fire E.xtinguishing ~edia: See below.
Fire Fighting Procedures: DO NOT FIGrrr FIRES
I~y.OL V1~G E.'"(PLOSIVE MATERIALS.
Immediately cvacuate all personnel from the area.
Other Fire or E.~plosion Hazards: High explosive
with mass detonation haz3.!d.
4. REACT1v1TY DATA
Stability: Under Normal Conditions: Can explode
on impact.
Under Fire Conditions: ~ay ignite if heated.
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Shock. impact, or heat that
may detonate the product.
Materi:lls to Avoid: The wax covering and
polyethylene will, in rime, be affected by fuel oil.
Hazardous Decomposition or Combustion
Products: Vapours of NOx, CO and lead
fumes.
5. TOXICOLOGIC.'\L ..1...'iD HE.'\L11I DATA
Toxicologic:ll Data: This is a manufactured article
and may release hazardous productS during
detonation. Detonation productS include NO,
NO2. CO, SO2 and lead fumes.
Recomme:lded E.'(posure LimitS:
OSH.~ ACGIH
PEL TLV
Nitrogen Dioxide 5 ppm-c:iling 3 ppm
Nitric Oxide 25 ppm 25 ppm
Carbon ~lonoxide 50 ppm 50 ppm
Sulphur Dioxide 5 ppm 2 ppm
Lead 0.05 mg/m3 0.15mg/m3
6. PREVE~11VE ~fEASLTRES
Handling Procedures and Equipment: All
persoMel should keep clear during detonation.
Avoid inhalation of smoke and vapours.
Storage Temperature ( oC): .Jo\mbie:lt temperatures.
Storage RequirementS: Product should be stored in
a cool dry environment and not stored in close
proximity to high explosive material.
Other Precautions: Tais product is explosive.
Meet all legal requirement for shipping and
magazining.
7. E~vlRO~~fE~l,~ PROTEcrION DATA
Steps to be Taken in tbe Event of a Spill or Leak:
Pick up cautiously as per Ilorm:ll preQutions taken
in handling explosives.
Environmental EffectS: None known.
Deacnvating Cbemic:Lls: Not applicable.
Waste Disposal ~ethods: RetUrn to supplier or
contact supplier Technic:Ll Representative to
arrange for destruction by detonation under
regulator! supervision.
§. ADOmONAL INFOR~1A11ON AJ.~
SOuRCES L'SED
1. Documentation of the Threshold Limit Values

i\'1~U~ A
i NON ELEcrRIC DETONATORS A
and Biological Exposure
Indices, Sth ed.; American Conference' -of
Govemmental Industrial HygienistS
Inc., Cincinnati, 1986.
2. Grayson, Martin, Ed., Kirk-Othmer Concise
Encyclopedia of Chemical
Technology , 3rd ed.. John ~iley and Sons, New
York. 1985.
c.\{S Environmlnl4l Restoration Group Page G.2S

~: ...IDEN1lFICA 1l0N ...
'-
MSDS RECORD NUMBER: 773649
PRODUCT NAME(S): ELECTRIC BLASTING
CAPS
DUPONT SPECIALTY ELECTRIC
DETONATORS-"E"PRODUCTS
PRODUCT IDENTIFICATION: MSDS
NU1\IIBER: CECO1127
...MATERIAL SAFETY DATA ...
Tra~e names and Synonyms
ELECTRlC BLAS11NG CAPS
E ...= Number and/or Letter Designation of
Product
PREVENTION OF ACCIDENTS fN n1E USE
OF EXPLOSIVES
The prevention of accidents in the use of
explosives is a result of careful planning and
observance of the best known practices. The
explosives user must remember they are
dealing with a powerful force and various devices
and methods have been developed to assist them
in directing this force. The user should realize this
force, ifmisdirected, may either kill or injure.
W ARNING
All explosives are dangerous and must be
carefully handled and used following approved
safety procedures either by or under the direction
of competent, experienced persons in
accordance with all applicable Federal, State and
local laws regulations and ordinances. If. after
carefully reading the" Always and Never" and
"Instructions and Warnings" leaflets inserted in
. each case of tbese products, you have any
questions or doubts as to how to use any explosive
product, do not ':lSe it before consulting your
supervisor. If your supervisor has any
questions or doubts, they should consult tbe
manufacturer before use. See" Additional
Infonnation and References" below.
ComponentS
Material CAS Number %
Pentaeryhritol
Tetranitrate (PETN) 78-11-5
Lead Azide 13424-46-9
Lead
Dinitroorthocresylate 79357-62-3
Smokeless Powder
Lead Styphnate 15245-44-0
Hexnitrostilbene (HNS II) 109-27-3
Tacot 25243-36-1
Boron 7440-42-8
Ferric Oxide 1309-37-1
Magnesium 7439-95-4
Tellurium Dioxide 7446-07-3
Cyclotrimethylenetrinitramine (RDX)
Barium Peroxide 1304-29-6
HAZARDS TDEN11FICA 110N
Potential Health Effects
121
-82
-4
DuPONT SPECIAL TY ELECTRIC
DETONATORS -tIE" PRODUCTS and
their components do not present health hazards in
normal handling and use. The components that
make up the article are contained the shell and
include explosive materials such as Tacot, Boron,
Hexnitrostibene (HNS II), Smokeless Powder,
Pentaeryhritol Tetranitrate (PETN), Lead Azide,
Magnesium, Ferric Oxide, Lead
Dinitroorthocresylate, Lead Styphnate,
Tellurium Dioxide, Cyclotrimethylenetrinitramine
(RDX), and .
Barium Peroxide. Under reasonable foreseeable
conditions of use, there is no exposure to these
materials.
Upon detonation, decomposition products
released may include Nitrogen Oxides and fumes
of Lead, Barium, Iron, Magnesium

.
,
Boron and Tellurium. These materials have the
following hazards:
Nitrogen Oxides: Are skin, eye and respiratory
system irritants.
Overexposure to Lead compounds may cause
abnormal blood forming system function with
anemia. Higher exposure may lead to abnormal
kidney function with reduced urine volume,
abnormal laboratory testS or edema; nervous
system effects.
Symptoms may include loss of appetite, anemia;
di~rbance of sleep and fatigue. Tests of some
lead compounds for mutagenic activity in
bacterial or mammalian cell cultures have
been inconclusive, with positive results in some
studies, and negative resultS in others. Some
studies suggest that lead compounds may have
developmental tox.icity at dosage levels showing
maternal toxicity; while some tests
with lead compounds in animals demonstrate
reproductive toxicity. DuPont handles lead
compounds as potential developmental toxins.
Women of childbearing potential should be
warned of the risk to the fetus in operations
involving direct exposure to lead compounds.
For exposure longer than 8 hours, the OSHA
Exposure limit is reduced by this formula:
Exposure limit (in ug/m3) = 400 /hours worked in
the day.
Tellurium Oxide has caused adverse liver and
kidney effectS in laboratory animals. Exposure
can lead to toa metallic taste in the mouth and a
garlic odor on the breath. SNdies in laborAtory
animals have shown adverse effectS to the nervous
system.
Barium salts cause muscle paralysis, alteration of
the hearts electrical activity with irregular pulse,
palpatations or inadequate circulation.
Overexposure to Magnesium by inhalation,
ingestion, or skin, or eye t:ontact may initially
include: skin irritation with discomfort or rash;
eye irritation with discomfort, tearing,
blurring of vision; irritation of mucosal surfaces;
or metal fume fever.
Overexposure to Iron Oxide by: Eye contact may
initially include; mild eye irritation with
discomfort, tearing, or blurring of vision.
Inhalation may initially include; irTitation of the
upper respiratory passages, with coughing
and discomfort; or deposition of iron in the lung
tissue resulting in discoloration but without
fibrosis or significant symptoms.
Over exposure to Boron and Boron Oxides may
cause eye, nose or throat irTitation.
Carcinogenicity Information
The following components are listed by 1ARC,
NTP , OSHA or ACGIH as carcinogens. A "P"
indicates a proposed carcinogen.
Material
Lead Azide
Lead Styphnate
FIRST AID MEASIJRES
IARC NTP OSHA ACGIH
'Get medical attention immediately if explosion
'causes physical injury .If decomposition fumes
are inhaled, remove to fresh air. If not breathing,
give artificial respiration. Ifbreathing is difficult,
give oxygen. Call a physician.
FIRE FIGHTTNG MEASURES
Flammable Properties
Detonates when exposed to heat or flame.
Fire and ExQlosion Hazards:
Hazardous gaseslvapors produced in fire are
Boron, Iron, Magnesium, Lead and Tellurium
compounds, Carbon Monoxide and Nitrogen
Oxides. Products are Class A or Class C
Explosives (DOn. Will detonate with friction,
impact, heat, tow level electrical current or
electrostatic energy. Detonation produces
shrapnel.
Extinguishing Media None
Fire Fighting Instructions
Evacuate personnel to a safe area. Do not fight
fire. Isolate area. Guard against intruders.
ACCIDENTAL RELEASE i\lfEASURES
X
X

~
Safeguards (Personnel)
NOTE: Review FIRE FIGH11NG MEASURES
and HANDLING (PERSONNEL) sections before
proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT
during clean-up.
Accidental Release Measures
Control access to area and remove sources of
friction, impact, heat, low level electrical current,
electrostatic or RF energy .Refer to
manufacturer's" Always and Never" and
"In.structions and Warnings" supplied with each
product shipment
HANDLING AND STORAGE
Handling (personnel)
Avoid breathing fumes for detonation.
Sto~ge
Refer to manufacturers ..Always and Never" and
"Instructions Warnings'. supplied with each
shipment.
~OSURE CONTROLS/PERSONAL
EROTECTTO~
Engineering Controls
Use only with adequate ventilation. Keep away
from friction impact, heat, low level electrical
current, electrostatic or RF energy. Do not
consume food, drink or tobacco in areas where
they may become contaminated with material.
Refer to the manufacturer's" Always and Never"
and "Instructions and
Warnings" supplied with each product shipment.
See also OSHA Lead S~dard 29 CFR
1910.1025.
P.ERsONAT. PROTEC11VE EOmPMENI
Eye/Face: Safety Glasses.
Additional: Cotton socks and conductive soled
shoes,floors and surfaces.
Exposure Guidelines
Exposure Lim its
DUPONT SPECIALTY
DETONA TORS -"E" PRODUCTS
ELECTRIC
PEL (OSl-L-\): Particulates (Not Otherwise
Regulated) 15 mg/m3, 8 Hr. TWA, total dust
5 mg/m3, 8 Hr. TW A, respirable dust
Other Applicable Exposure Limits
Lead Azide PEL (OSHA): 0.05 mg/m3, 8 Hr.
TW A, as pb for> 8 Hrs. exposure, limit in mg/m3
= 0.4 divided by hours worked.
n.V (ACGlli): 0.15 mg/m3, 8 Hr. TWA, as pb
Notice of Intended changes 1993-1994
Lead, elemental, and inorganic compounds as pb
0.05 mg/m3, A3 AEL .(Du Font) : "See Human
Health Effects SeCtion"
Ferric Oxide PEL (OSHA): 10 mg/m3, as Total
Particulate- 8 HrTWATLV (ACGIH) : B2, 5
ing/m3, as Fe, 8 Hr. TWA
(See Appendix B 1992-93 n. V Booklet)
AEL .(Du Font): None Established
Cyclotrimethylenetrinitramine (RDX)
PEL (OSHA): None EStablished
n.V (ACGIH): 1.5 mg/m3, 8 Hr. TWA, Skin
AEL .(Du Font): None Established
* AEL is Du Font's Acceptable Exposure Limit.
Where governmentally imposed occupational
exposure limits which are
lower than the AEL are in effect, such limits shall
Uke precedence.
PHYSICAL AND CHEMICAL PROPER11ES
Physical Data
Aluminum or Bronze shells With attached
insulated Copper or Iron leg wires.
STABILITY AND REACTMIY
Chemical Stability
Upstable with heat. Unstable with shock.
Unstable with st3.ticcharges. Detonates with
friction, low level electrical current,

electrostatic or RF energy
Incompatibility with Other Materials
Incompatible with acids and alkalies.
Decomposition
Decomposes with heat. Decomposes with shock.
Hazardous gases/vapors produced are Boron, Iron,
Magnesium, Tellurium and Lead compounds,
Carbon Monoxide and Nitrogen Oxides.
Detonation produces shrapnel.
Polymerization
Polymerization will not occur .
IQXTCOI,OGICAL TNFORMA 110N
No Information Available
ECm.OGTCAL TNFORMA 110N
No Infomlation Available
DISPOSAL CONSIDERA TTONS
Waste Disposal
Consult explosive manufacturer for
recommended methods of destroying explosive
materials. Comply with applicable Federal,
State and Local Regulations.
TRANSPORT A 11 ON mFORMA 11ON
Shipping Information
Shipping Information depends on packaging and
product characteristics. Check manuf~ctUrer or
shipper for specific inforniation.
QnIER TNFO~{A T10N
Additional Information
w ARNlNG: This product contains chemicals
known to the State ofCalifomia to cause cancer,
birth defects, or other reproductive harm. It is
obviously impossible to include warnings or
approved methods for every conceivable situation.
A list of suggestions to aid in avoiding the more
common causes of
accidents is set forth in the " Always and Never'.
and "Instructions and Warnings" included as case

.
.
inserts with the product. Additional information is
available in the
Blasters' Handbook, published by Explosives
Technology International, Inc., Ordnance Safety
Manua1, published by the U.S. Army Ordnance
Department, and the Institute of
Makers of Explosives Safety Library Publications.
Copies of
these IME publications may be obtained by
writing the Institute of Makers of Explosives,
1120 19th Street, N. W ., Suite 510, Washington,
D.C. 20036-3605, or from your explosives
supplier:
IME publication subjects:
o Storag~ Magazines
o Table of Distances
o Use and Handling of Explosives
O RF Hazards
o Destruction of Commercial Explosives
o Transportation

~
-
(
-.1
...'
~
APR.14.1997 12:OSPM
r' Ensign-Blck:ford
,~ Company
HALL I BURTON .817 783 5812 NO.564 P.5/9
Ma terl
Blasting Products Division
66d Hopme.adow Street
S~bury, Connecticut 06070 USA
(20~) 65.8-4411
Telex: 710436 5050
~==================~======= =========================
Section I
=============
===;c -- ===
Manufacturer's Name I
Emergency Telephone No.
The Ensign-Bickford Com,t any
~
I
1-203-658-4411
Address (Number,Street,Ci~
y,State,Zip Code)
660 Bopmeadow Street, 5j msbury, CT 06070
Chemical Name & Synonyms
NOT A CHEMICAL
Chemical Family
, Trade Name & Synonyms
PRIMACORD ~ DETONATING CORD
I Formula -. I C.A.S. Number
N/A
N/A
===================== -=,-====== ~~~""'-:J",,"~--~
==z==================================
===================. .== ============~
=z==
Ingredient .
Se I
====='-
PENTAERYTHRITOL
i !
TETRANITRATE
.. d
(PETN )
i
T.L.V. :
a===========~=============~
Ingredient i
~YCLOTRlMETHYLENE TRINITRAMINE (RDX)
ction II -Hazardous Ingredients 1
= = = =-3
I Percent I
Percent
P.E.L. :
;~~~;~~
=~==:================JL~=
l---~~==========
P.E.L.
===;===~======:=========
~
=======
Ingredient
Percent
~YCLOTETRAMETHYLENE TETRA~ ITRAMINE ( HMX )
T.L.V. :
--= =====-=~===2==:=2=
I ~~~:~~~~:~:~:~~~~~~
In9redient
T.L.V. : .
==-~=====~~- -.
§t ~~~L~
==========k======Z=======-========-===2===: I ;:~:~::
INITROPYRIDINE (PYX)
!Percent
================= ==============
Ii
ii
11
ii
"
'I
"
'I
I:
:1
"
P.E.L. :

~
APR.14.1997 12:05PM
".1Jd.'-d. ~11t:t: \.. L' (.JL :
I .
, M~hu f actured By:
HALL I BURTON 817 783 5812
r'l\.L!'~l,..urtIJ Ur..'J.'uNI\'J.'.LNu '-U~IJ
THE ENSIGI-BICI

. "1: ,
APR.14.1997 12:06PM
..ud.I.d. ~!I~~L rUL :
'..M~nufactured By:
HALLIBURTON -817 783 5812
r.:-..1."~'-ul\J.) U~.J.uf-,nJ...L~v l..:ut{U
THE ENSIGt-BICKFORD COMPANY
NO.564
1"age j
u====================== l===========~ ~=~==:;~:~~~=~=:=~~~~:~=~~:~
1 =~=~==== = ::
Threshold Limit Value: NOT ESTABLISHED
Eye
Contact N/A -NOT A
Skin
Contact
N/A -NOT A
Effects of Overexposure
~IKELY ROUTE OF EXPOSURE
LIKELY ROUTE OF EXPOSURE
Inhalation: N/A- NOT A ~IKELY ROUTE OF EXPOSURE
Ingestion :
Eye
Contact
Skin
Contact
.
E
m
e
r
g
e
n
c
y
a
n
N/A- NOT A ~IKELY ROUTE OF EXPOSURE
N/A
N/A
~
II d
"
I
I!
.'
Ii
I!
.
F
~
r
s
t
P.7/9
. d d .
Inhalation: IF DETONATI(
~c IN PtJMES ARE INHALED REMOVE TO FRESH
AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION,
PREFERABLY
DIFFICULT
~ :OUTH TO MOUTH. -~
GJ VE OXYGEN. CALL
IF BREATHING
A PHYSICIAN.
IS
Ingestion :
N/A
=====:~=====~===~==========~=======3=-================================
A~
P
r
o
c
e
u
r
e
s

-
-
-
PPR.14.1997 12:06PM
..:oa.t:a ~neet: ror :
:. ..".a-nufactured By:
~==============
======================
Stability: STABLE
HALLIBURTON 8177835812
Conditions to Avoid: DE~
l' Kl.!'1j\l.UrtlJ 4 u r L"u.C'I~ "J." .l~u I..Urt u
THE ENSIG~-BICKFORD COMPANY
e
"J: ~
--
se~tion VI Reactivity Dat~-
II
,.======= ====== """===
HEJ
II
I
t'IO .564 P.8/9
};'age ~
=-;;=;=======:==
;=================
~ONATING CORDS BECOME LESS STABLE WITH
~T. UNSTABLE WITH SHOCK.
I
II
Incompatability : ~N~OMPATIBLE WITH ACIDS, ALKALIES.
Hazardous Decomp. :
I
HAl ~ARDOUS GASES PRODUCED ARE NITROGEN
Products: OX! [DES.
Hazardous pqlymerization:
WILL NOT OCCUR
...
'CondJ.tJ.ons
:
to AvoJ.d: HE ~T, SHOCK. AVOID BREATHING FUMES FROM
DE rONATION.
==============~=
I---s
===========~==========================================
~============~====
================================8======~=============.=======
Steps to be Taken: R~~IEW
II
FIRE' EXPLOSION HAZARDS AND
In Case Material is: SAFETY PRECAUTIONS BEFORE PROCEEDING
Released or Spilled: W~gH CLEAN UP. USE APPROPRIATE PERSONAL
;~~~~-~i~~~~~~ ; ~~;~~;:;;-;~~~~~;~~;~;;;;~~;~;~;-
Me thad: RE,~OMMENDED METHODS FOR DESTROY ING
EXPLOSIVE MATERIALS. .
=================~====
==========================-============~

~
APR.14. 1997 12:07PM
.r.o.ua...a ~neet. tor:
r~anufactured By:
Respiratory
Protection
~
HALLIBURTON 8177835812
1
1'r

v
.
.
APR.14. 1997
-12:02PM
HALL I rBURTON
HALL I BURTON 817 783 5812.
~ :
NO.564 P.2/9
HA LLIBURTON ENERGY SERVICES
-
Explosiv~ Products Cf""tr / B~J2 Sourh I JSW I Al,,~r~do. Tt.T.JS 76009-9775/ Ttl: BI7-78J-5 1111 F..%: 8,7-7BJ-S81 2
PRODUCT ID~FlCA~IOX
.XAT&RIAL 8A7BTY DATA SHII~
!i
PRODUCT KAKK .8KAP8D ~CaARG. P~ODOcr.
TRADE NJ\Ja.S ANS SYNO!fr!MS
..Ti.ioD Dat.. '12'1'.
Tublng CUtter., Drill Pipe CUtter., Casing Cutter.,
Big Bole charges~ De.p Penetratlng Charg8s, Grav.l
Pack Charge., DY~A-Strip Charges, DYNA-Cap Charge.,
DYNA-Jet Charge.' SSB Charges, Sidewinder Charge.,
GSC Charges, JunJ Shot Charg.., Linear ShAped Charge., (LSC)
Flexlble Linear ihaped Ch&rge. (rLSC)
MAN tI F A CTtJRE R : H. llliburton Energy Servic..
Ij ~~lo.ive Product. Center
8~ ,32 South 1-35 W
A: v&rado, 'l'exas.76009-9775
PRODUCT INJ'ORHATION p ~ONEI (817) 783-5111
EMERGENCY PHONE I
(817) 783-5111
TRANSPORTATIOK EMERGENCY J,HONE:
mFO'IRAC: (100) 535-'Q53 U.S. ct CANADA
**********.**.**.********. ***..*.*****..**..********** *****.**.*..*.
B:A%ARDOUS ~8
ExpOsure Limits
CHEMICAL ii n.Y HIt
Cyclotrimethy18n8trin:l.tramin8 (RDX) 1.Smg!K] 1.5 mg/MJ
Cyclot.tramethyl.nete,tr&nitramin. (HKX) NE NE
Hexanitro.tilben. (HN'S) NE NE
2,6-bi. (PicrylAmino)~3,5-dinitropyridine (pyX) HE HZ
Nonanitroterphenyl (NONA) NE NE
Deeen.itizinq
Iron
Wax I!
,.
!i
NE
S mq!KJ
NE
10 mq/KJ
CoppGr
Tin
r
I
1 mq/KJ
2 mq!HJ
1 mg/KJ
2 Dlg/H)
Aluminum
Corrosion itesietant S :eel
5 mg!HJ
HZ
NE
NE
Lead 0.15 mg!H' 50 g!HJ
Antimony 0.5 Dlq!HJ 0.5 q!HJ
NE -Not Established
*************.***.***...*.
.*********.****.*****..****..*******.**.****.*
PB:YSICAL DAn
Packed
*****************.*.*.**.~
powder charge. !(.nc&8ed
.***
in
*.*.*
metal c&.inq).
*..*.*****.**..**.*****.****
B:A I A.RDO U 8 R.:EA cr I V:I n I
INSTABILIrYI Hay de
level electrIcal curr4
INCOMPArI:BILlryl Aclc
HAZARD DBCOKPOSlrION~
produc&d may contain
may -180 be produced.
POLYHXRIZArIONI Pol~
*.**,*.******.*******.*.**
l'IU AJm BXPLOBION' DATA
P'LASHPOIHTI N/A
EXTINGUZS~NG MEDIA:
'!
None
:onate
~nt .
with friction, J.mp..ct, heat, -"and
low
I. and aklali8.
Detonation may product shrapnel. Gases
!&rbon
I
monoxide and nitrogen oxide. Lead fumes
:erlzatlon will not. occur..
t****************..*******..******..****...**.
I;
"
~
SPECIAL rIg FIGH'l'INQ' PROCEDURESr DO KOT tight tire. I.olate
\
area. Evacuate per.o~n81 I to a safe area. Guard I.galn.t intruder..
Allow tire to burn it~.lf out.

:. .APR .14 .1997
,--
12:03PM HALLIBURTON " 8177835812
:!
.
f'IO.S64 P.3/9

,.: APR.14.1997
.'. .
12: 04PM
SPILL OR LUX P~OCXDUUIJ
HALL I BURTON 817 783 5812
f'K) .564 P.4/9
n .
U.8 appropriat. prot,lctive equlpuent. I.olat. area and remov.
.ources of trictlon, [impact, heat, low level electrical current,
8lectroetatic or RP' .Inerqy. only competent, experienced person.
.hould be involved ii clean up procedures. Sweep up with non-
.pa.rk.ln9 tool. and rerrov8.
WAS'l'B DISPOSAL
Di8posal ot in complil nc. with applicable Federal Regulation. under
th. authority ot the Resource Conservation and Recovery Act (40
CFR, parte 260-271). I
* ***..**.**...1 .*.**********************.*****.*..*.* *.
SPBCIAL P~OTScrIO. IXFORKA~
VENTILATIONr
RESPIRATORY:
BYE:
Use onlv
NIOSH/HI
Safety glasses o
GLOVES: Normal work a
..*.*****...****.*.**.***.i
SPECIAL PR.ECAtrrIONS
LOves.
***.**.*..***.*..**.***** ***...*****'
~eep away frOC\ frictJjon, impact and heat. Do Not consume food,
drink or tobacco in a~848 where they may become contaminAted with
these mAteriAls.
STORAGE CONDITIONS
Refer to manufacturer
storage conditions.
* * *...*.*.*.**.j
recommendations and warning for proper
It.*t*.** ***..*.*..*.***.****.*****
THE INFORMATION WHICH Isi CONTAINED IN THIS DOCUKENT IS BASED UPON
AVAILABLE
OBTAINED
DATA AND SELIZVEj , TO BE
rROH VARIOUS : ~OURCES,
CORRECT.
INCLUDING
HOWEVER, AS suCH BAS
TH! KANUrACTURER
BEEN
AND
INDEPENDENT LABORATORIES, 1Ir
IS GIVEN WITHOUT WARRANTY OR UPR.KSENTATION
THAT IT IS COMPLETE, ACCl ~TE AND CAN BE RELIXD UPON. HALLIBURTON
ENERGY SERVICES HAS NOT AT~ 'IMP'l'ED TO CONCEAL IN ANY WAY THE DELETERIOUS
ASPECTS or THE PRODUCT LIS7 :ID KERZIN, BUT MAKBS NO WARRANTY AS TO SUCH .
FURTHER, AS HALLIBURTOK Eli ERGY SERVICES CANNOT ANTICIPAT~ NOR CONTROL
THE KANY SITUATIONS IN WHICH
THE LISTED PRODUCT OR THIS IN!'0RMAT:tON KAY
BZ USED BY OUR CUSTOMER, THERE IS NO GUAIWlT.EB THAr r~ fmALTH AND
SArETY PRECAUTIONS SUGGESTS)
WILL 81 PROPER UNDER ALL CONDITIONS. IT IS
THE SOLE RESPONSIBILITY or EACH USER OF TRI LISTED PRODUCT TO DBTERHIHE
AND COKPLY WITH TRX p.EQOIro KENTS or ALL APPLICABLE LAWS AND REGttLATIONS
REGARDING ITS USE. THIS IN ~ORKArION
SArETY TO PERSONS AND PROP~RTY
.ANY
IS GIVEN SOLEL~ FOR THE PURPOSES
OTHER US! OF THIS INFORMATION'
OF
IS
EXPRESSLY
SERVICES.
PROHIBITED. GO\'~RNKENT
REGULATIONS DEPARTMENT, HALLIBURTON

.
s~ o~ W'iE'1'J:r'f;
Still 'r"""-Cit:l e Erqine o il
.,
MATrn.IAL SAr~ ~ Srtt.t;.l'
~te. 15..51-1ed: l0/3i/90
~ [Ste: 05/04/88
~an:i oil ~ P.O. 8:D{. BO9B ~~rt, lA 7UOa
A. =nDI~OO AND :EMER::;E:NC'.i ~~C3:i
Pro aJcr' N]I.ME .
Stihl ~ e E:r"q ine o il
amfiCAL~
~t:roleL:rln IlJbric::atin; oil
prowcr CDDE
CASN(n-mEP.
~wcr APPF.A!W'cr AND OOOR
[:Sl::"k ~d Green Liquid: ]JIImt:Jnia Qjor
~ Ci n:IEmCt'E NtJMEER.
.(318)-687-8000
B.
ca=!ENIS AND r~ INFO~ON
~ CJ..S NO .OF
~
lubricating oil 64742-54-7 or 64742-65-0 .
Base Stocks and 64742-57-0 or 64742-62-7
Proprietazy 1IcHi ti yes Mixb.l1:'e.
Mineral Spirits .8052-41-3
See se:::tion E for Health arrl F.aza.td InfODration
H1I.zARr:x::xjS ~ mE2'mF!CATION sySI'.EH (HMIS)
Health FlaIm'ability Reactivity
1 2 O
== LIMrr FOR 'IOrAL proI:IJcr
.100 ~ (570 ngiIn3) £or an
8-ho.Jr wrkday.
~exMi.xbIre
.CAS ~ Not J\pplicable
A..'CFro~
a;;.NCE1'1'TRAITON
Grea ter than 8 S ~
less than 1. O ~
Less than .1 O %
Haz ard Ra tin;s .
0- Least 3 :-High
l-Slight 4-ET.~e
2 -tfcrl era te
FAsIS
~~I'errled by West1arx3. for light
h~n fraction present in
prt:duct .
c. ~ ro.JI':ES OF Em'R'i AND ~CY AND FIRST
AID~
EYE ~cr
If splashed into the eyes,o flush with. cle2.= '..'ater for 15 mirnIt.es
or until irritation su ""'sides .If irritation ~ists, call a

u --"
,;. .: :.
-.:..,::
p,"~~
; 0. ,. SIaN'
~";: ~oo
:~.~;~
~~;:
rl
.
,
:~
~
-
.;..,;; .
4;:~..~
~.;:;';:
Page 2 stihl ~cle Erqine oil
: , ..
In. case of skin .contact , reIt'OVe any conta."nlna.terl clothi.r1:J an::i W'a.sh
skin tllort:U;hly with soap arrl wt2;r .
Vap:Jr pres.surQ is very lcy..r. .Vap:Jr inhalation urxjer ambient
o;:)r:x:litions is nonrally not a problem. It" OV~~Ie. by.va~r fratt hat
prt::duct, ilme:liately relIDVe from ~~e. arxi call a physician. If
brea~ is i=e;ular or has stCPIBi, start ~tation; odmjnister
oxygen, if available. If cver!?-~ to oil tnist, re!IDVe frcm further
~ until exCESSive oil Inist corrlition subsides.
~' l.'.J.oo
~tely.
D.
I.f
iIq ested , 00 NOr irrluce v cxni tirXJ ; call a, physician
n:RE AND EXProsION fP.ZARD rnroPloro'ION
flASH ro mr ( Mnm-!.ni )
175+ (B'fCC)
Afjro I GNITI ON ~
Greater than 500. F
'l'OO'I~ FIRE fro~CI'ION ASSo:D.:rION (NFPA) -HAZARD Imlrn"ICATION
Health FlaImBbility p.e.activity EA.SIS
1 2 O F.B::Xmrerrle:ibyWestlarrl
l.wrn~ rnEX:JI.IJrIONS
Use p~ with c2.ution
static electricity , arrl Of:EI1 f1.C.Ire.
arourrl heat,
sparks 1 pilot lights
FIA!-2'!ABIE OR EXPlCSIVE I.1:MrIS (APFro~ ~ BY VOIIlME m AIR)
E.stiJta tm val u es : Ia..r er F 1 alm'ab 1 e Limi t a. 9 ~ Up r:e-r F 1 aIrIIrab 1 e
Limit 7%
MEDIA AND FmE FI~G PRX:EnJl'ES
~, water spray (fog) , dry d1emical, carron dioxide ard
vap:::>rizi:rq liquid typa ~ agents tray all k;e suita;ble for
~ fire imrolvirq this type of prcduct, depeniiI'J on size
or IXItential size 0! fi.t:-e arrl ci=nstances rela~ to the si'bJation.
Plan fixe protection ard respJnse sb:ats;y thJ:""9h o::>ns1lltation with
lo::al .fire protection authorities or appropriate specialtists.
'nle follOO.rq p1.-o::::ed-lJre5 for this type of p'tr:!uct are ~-~ on
the r~l1~tions in the National Fire Prct:e::tion Asscciation's
"Fire Protect:ion Guide an HazaI:dous Materials". Eighth Edition
(1984):
Use ~ter spray, drj d1ernical, foam, or carl:cn dioxide. Water or
foam 1Iay cai1se f=thjn;. Use W'ater to .keep !~ o:mtainers
o:x:)l. Water spray nay 1:e -u.se:i to flush .spills a'.,'ay fran eX!=\Jres .
Mi.n.il!lize b.reathi.toq gases, vap:Jr, fuItes or dea:3l~ition prt:rluctS. Use
suppliOO-air brea~ equipIrent for enclosei or ~ine;i Sp3CE.5 or as
~...\ :-~ ~~~ .

Page 3
0, "-'.;-
Stihl ~le ErXjine oi:t"'
DEm-m::smCt{ ~aJCI$ tJNm:R ~ CI)NDITIONS
F\JrIes, SltCke, ~~n ~noxide, sulfur oxides, aldehydes arrl other
a~~~ition prc:x:lucts, in the case of i11complete c::=:i1b.lSion.
~ -~
tlEMpIYII ~ ~G
It~l~ o:Jntair,ers retain residue (1i~d a.rrl/or va~r) an::1 can
k:e d:arqero.JS. 00 NOr PRESSURIZE, aJr, WEr.D, ~, SQU)ER, mIIL,
GP,Dm OR ~E stJai ~ 'ro HEAT, ~,. SPAP.I

-
-
-
Page 4
B:)~ ~
Not f);~
SPECIFIC ~vrl"f
0.8810
VAroR ~
less than 5 "nm Hg @ 20 C
VAroR WtSrIY (AIR = 1;
Grea tar than S
J.D LEaJIAR WEI Qfi1
N at re taz1niJ1ed PERCENrVOIATn.EBYVOIIJME
8.0
PI
Essential1 y N eutral
roJR, ~ OR MELTING romr
-20 F ~ ~int by ~ r:s7
VIS~I'lY.
74.43 CSt @ 40 C
EVAroRATE P.A!'E @ 1 A'IM .AND
25 C (77 F) (n-a:JIYL ACEmTE
= 1)
0.2
SOIlJBII.nY m ~ @ A:IM.
AND 25 C (77F} t
Negligible: less than 0.1%
'n1is p:rOOuct is stable arxi will not react violently with j.,'at.er.
HazardO.1S pclYIrerization will not ~.1r .Avoid CXJntact with ~
CDddants sud1 as liquid dllorine, ~trate:i oxYgen, so::lium
hyp:dllorite or calci1.nn hYlXX=hylorite.
H. ~ DmJ~ON
tray

Page. 5
~ QJANrrr't ( ~ ) I EP A RmJIA1'r ON 4 O QR 3 O 2
Hat applicable
EPA ~ crASSnICATION QJDE :
~ QlrCnic Fire
Hazard Hazard Hazard
Pl:ESSUJ;."e
?.aza:r;d
R-ea cti v e
H.aza.rd
Not .
]l..pplicable
XXX
~oo
Use lo::al eXhaust to capture vafX:>r, mists or ~ , if
~5.S2-ry .Provide ventilation sufficient to prevent ex~
r~erl ~ lOOt or bui1dut:! of explosive a:Jrx:.entrations. of
\rap:Jr
lights
in
.
air .Use explosion-prtXJf
-.
ecJ:.liPient. No STXJkiI);f or 0t:er1
RESpD'A:It>RY P-~CI'ION
Use supplie:i-air
spaces , if neeje:i .
:f'~1~CI'IVE GlOVES
Use d1 emi ca.l- res istant
~ted skin CI;)ntact.
respiratoI:Y protection in confine:j or enclose::i
EYE !roJ.:l:.U'J:OO
Use. splash gc:x;gles or face shield 'ww'hen eye ront..!l.--t: my ~..lr .
~ IP.A CI'I Q:s ~ ~ CIJNrro rs
Xeep 0:Jnt.ai.l"1er:s" ard storage cx:>nt.ainers close:l w"hen not in use.
nJ not store ooar heat,. sp3.rks, flCIre or strorx; oxidants.
.
~ fffGmrE ..
Hinimize breath.ing vapJr, mist or fures. Avoid prolorged or
re~terl a::Int.act ~th skin. Rem:Jve O:Intamimterl clotlUn;; laurrler or
dry-clean 1::efore :reuse. R.errove contaminate;:i shCES ard thoroughly
cl~ before ~c;.e; di.sc:a...""d if oi J ~\r~ ,..., , ,

Page 6 stih.l 'I\.'O-Cycle Er%Jihe. O~
af'!;:.er aJ!1tac:t, OOfore b~ arrl ~i..arrl ato erd of ~'Ork ~ic:xi.
Prt:rluc:t is 1:'1aa.dily rem:JVe:i f!:on s3dn by '.,laterles.s harrl cleaners
follC1..'e:;i by washin; tbom.1ghly with soap arx:l water .
J . 'rnANSroRrATIOO~ON
TP.ANS roRrATI Qi IN crrJfJ::rr rnFO ~ ON
For further infonration relative to spills rc-5u.ltjiq from
b:ans!X)rl:ation incidents, refer tD lat2St ~ of
~tati6n E}oorgerq ReSp:Jnse GUid~~k for HazazdOJS Materials
Ircidents. ror p 5800.3.
001' = CATI 00 NUMBER
Not ~licable
'The info:cration arrl ~::aciiIerdations contained herein are, to the
best of Westlarrl's Jrt, IA 7ll48
(318)-688-1300.
FOR amEP. Imrocr INro~ON ~cr:
5F=ial ty o i1 0:2l'f'&zTf I Inc .
2740 Valleyvie'..r Dr .
ShrevefX:)rt, IA 71148
(318)-687-8000

.
-
.
1 DUPO 50
E. I. du Pont de Nemours and Company
UNLEADED GASOLINE
MSDS NUMBER: 34310019-40 ISSUE DATE: 95/01/13 PAGE
'I a ~
, , , , ':; .UNLEADED GASOLINE i
34310019 Revised 19-NOV-1994 Printe!d 13-JAN-1995
CHEMICAL PRODUCT/COMPANY IDENTIFICATION
Material Identification
Corporate MSDS Number : DUOOlO44
Tradenames and Synonyms
AUTOMOTIVE UNLEADED GASOLINE
PETROL
MOTOR SPIRITS
GASOLINE -UNLEADED
CCO379
Company Identification
MANUFACTURER/DISTRIBUTOR
PHONE NUMBERS
Transport ~ergency
Medical ~ergency
PURCHASED MATERIAL
: CHEMTREC: 1-800-424-9300
: 1-800-441-3637
COMPOSITION/INFORMATION ON.INGREDIENTS
Components
Material
GASOLINE
*BENZENE
*ETHYLBENZENE
*CUMENE
*PSEUDOCUMENE
*METHYL T-BUTYL ETHER
*XYLENES
*TOLUENE
CAS Number
8006-61-9
71-43-2
100-41-4
98-82-8
95-63-6
1634-04-4
1330-20-7
108-88-3
100
~ .
,~
O.~-4.9
-2
-I
-2

1 DUPO 50
E. I. du Pont de Nemours and Company
UNlEADED GASOlINE
MSDS NUMBER: 34310019-40
Components (Remarks)
ISSUE DATE: 95/01/13 PAGE 2
Components listed above are typical for Conoco produged
gasoline. Gasoline is a variable complex mixture of
components, principally hydrocarbons, blended to
performance, rather than chemical, specifications. It I may
contain various proprietary additives.
This MSOS does not cover leaded gasoline.
HAZARDS IDENTIFICATION
Potential Health E~~ects
Primary Routes of Exposure/Entry: Skin. Inhalation.
Signs and Symptoms of Exposure/Medical Conditons Aggravated
by Exposure: A few studies have indicated that workers
exposed many years to high concentrations of benzene have a
slightly higher incidence of leukemia. Benzene can a1so be
toxic to the blood and blood-forming tissues.
Studies with mice or rats have shown that some petroleum
distillates have caused either damage or tumors of the
kidneys or tumors of the liver. However, kidney effects
were not seen in similar studies involving guinea pig~, dogs
or monkeys. .Also, the significance of the liver tumo~s in
rodents is highly speculative.
Mouse skin painting studies have shown that petroleum middle
distillates (boiling range of 100-700 deg F; naphtha, jet
fuel, diesel fuel, kerosene, etc.) can cause skin cancer
when repeatedly applied and never washed from the animal's
skin. The relative significance of this to human health is
uncertain since the petroleum distillates were not washed
from the skin and resulting skin effects (irritation, cell
damage, etc.) may playa role in the tumorigenic response.
A ~ew studies have shown that washing the animal's skin with
soap and water between treatments greatly reduces the
carcinogenic effect of some petroleum oils.
The product contains petroleum hydrocarbons which may cause
irritation to eyes, skin and lungs a~ter prolonged or
repeated exposure. Extreme exposure or aspiration into the
lungs may cause pneumonia. Overexposure may cause weakness,
headache, nausea, con~usion, blurred vision, drowsiness and
other nervous system e~~ects; greater exposure may cause
dizziness. slurred speech, ~lushed ~ace, unconsciousness or
convulsions.

1 DUPo 50
E. I. du Pont de Nemours and Company
UNLEADED GASOLINE
MSDS NUMBER. 3431001940
Carcinogenicity Infonmation
ISSUE DATE: 95/01/13
The following components are listed by IARC, NTP, OSHA °lr ACGIH as
carcinogens. A -P" indicates a proposed carcinogen. I
Material
GASOLINE
BENZENE
FIRST AID MEASURES
First Aid
INHALATION
IT inhaled, remove to Tresh air. IT not breathing, give
,
IARC NTP OSHA ACGIH
X
X ix X X
artiTicial respiration. IT breathing is diTTicult, give oxygen
Call a physi ci an .
SKIN CONTACT
In case of contact, immediately wash skin with soap and water.
Wash contaminated clothing before reuse.
If irritation develops. consult a physician
EYE CONTACT
In case of contact. immediately flush eyes with Plentylof water
for at least 15 minutes. Call a physician. I
INGESTION
If swallowed. do not induce vomiting. Immediately give 2 glasses
of water. Never give anything by mouth to an unconscious person.
Call a physician.
Notes to Physicians
Activated charcoal mixture may be administered. To prepare
activated charcoal mixture, suspend 50 grams activated charcoal in
400 mL w~ter and mix thoroughly. Administer 5 mL/kg, qr 350 ml
for an average adult. i
Minute amounts aspirated into the lungs during ingestion
or vomiting may cause mild to severe pulmonary injury and
possibly death.
t
PAGE 3

-
1 DUPO 50
E. I. du Pont de N~ours and Company
UNlEADED GASOlINE
MSDS NUMBER: 34310019-40 ISSUE DATE: 95/01/13 PAGE
FIRE FIGHTING MEASURES
Flammable Properties
Flash Point
Method
Flarm1able limits in Air
LEL
UEL
: As low as -50 F
: TCC
% by Volume
: < 1
: 8
Flammable liquid. Vapor fonms explosive mixture with air. Vapors
or gases may travel considerable distances to ignitionj source and
flash back.
NFPA Classification : Class IA Flammable Liquid.
Hazardous gases/vapors produced in fire are carbon-",onoxide
Extinguishing Media
Foam Dry Chemical. CO2
Fire Fighting Instructions
Keep personnel removed and upwind o~ ~ire. Wear sel~-~ontained
breathing apparatus. Wear full protective equipment. Shut o~~
source of fuel, i~ possible and without risk. Cool ta~k/container
with water spray. I
Special Fire Fighting Procedures: Water may be ineffective
to extinguish, but water should be used to keep fire-exposed
containers cool. If a leak or spill has not ignited, use
water spray to disperse the vapors and to protect personnel
attempting to stop a leak. Water spray may be used to flush
spills away from areas of potential ignition. 1
Unusual Fire and Explosion Hazards: Highly Flammable.
Products of combustion may contain carbon monoxide, carbon
dioxide and other toxic materials. Do not enter enclosed or
con~ined space without proper protective equipment including
respiratory protection. !
ACCIDENTAL RELEASE MEASURES
Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING {PERSONNEL)
sections before proceeding with clean-up. Use appropri.te
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Evacuate personnel, thoroughly ventilate area, use Self 1
breathing apparatus.
I
contained
4

1 "OUPO 50
E. I. du Pont de Nemours and Company
I UNLEADED GASOLINE
MSDS NUMBER: 34310019-40
Initial Containment
ISSUE DATE: 95/01/13
Remove source of heat, sparks, flame, impact, friction or
electricity. Dike spill. Prevent material from entering sewers,
waterways, or low areas.
Accidental Release Measures
Several components o~ gasoline are subject to the Superfund
reportable discharge requirements if spilled. Concentrations
of gasoline components with a Superfund Reportable Quantity
(RQ) will depend on vendor formulations.
HANDLING AND STORAGE
Handling (Personnel}
Avoid breathing vapors or mist. Avoid contact with .ey~s. skin
clothing. Wash thoroughly after handling.
For use as a motor fuel only. Do not use as a cleaning
solvent, or thinner, or for other non-motor fuel uses.
Handling (Physical Aspects)
Storage
Ground container when pouring. Use of non-sparking and
explosion-proof equipment may be necessary depending on! type of
operation. Keep away from heat, sparks and flames. I
Keep container in a cool place. Do NOT expose to direct sunlight.
Store in a well ventilated place. Keep container tightly closed.
Store in accordance with National Fire Protection Association
reconTnendations.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls
Keep container tightly closed.
Use ventilation that is adequate to keep employee exposure
to airborne concentrations below exposure limits.
PAGE 5
or

-
1 DUPO SO
E. I. du Pont de Nemours and Company
NLEADED GASOlINE
I MSDS NUMBER: 34310019-40
Personal Protective Equipment
EYE/FACE PROTECTION
ISSUE DATE: 95/01/13 PAGE 6
Wear safety glasses. Wear coverall chemical splash goggles
and face shield when the possibility exists for eye and face
contact due to splashing or spraying of material.
RESPIRATORS
A NrOSH/MSHA approved air purifying respirator with a
organic vapor cartridge or canister may be permissible ~nder
certain circumstances where airborne concentrations are
expected to exceed exposure limits. Protection prov;de~ by
air purifying respirators is limited. Use a positive
pressure air supplied respirator if there is any potential
for an uncontrolled release, exposure levels are not known,
or any other circumstances where air pur;f"ying respirators
may not provide adequate protection. .!
PROTECTIVE CLOTHING
Wear impervious clothing, such as gloves, apron, boots Or
whole bodysuit as appropriate. Conoco recommends NBR o
Neoprene impervious clothing.
# Exposure Guidelines
Applicable Exposure Limits
GASOLINE
PEL (OSHA}
TLV (ACGIH)
AEL * (DU Pant)
BENZENE
PEL (OSHA)
TLV
(ACGIH)
AEL * (Du Pant)
ETHYLBENZENE
PEL (OSHA)
TLV (ACGIH)
AEL * (Du Pant)
CUMENE
: None Established
: 300 ppm. 890 mg/m3. 8 Hr. TW~
STEL 500 ppm, 1.480 mg/m3 I'
: None Established {
: 1 pprn, B Hr. TWA ~'7
5 pprn, STEL ..;" ~\"
0.5 pprn, Action Level
: 10 pprn, A2, 32 mg/m3, A2, B Mr. TWA
Notice o~ Intended Changes (1994-1995)
0.3 pprn, 0.96 mg/m3, B Hr. rWA, Skin, A1
: 1 pprn, B & 12 Hr. TWA I
5 ppm, 15 mi nute TWA ':f .
: 100 ppm. 435 mg/m3. 8 Hr
: 100 ppm, 434 mg/m3. 8 Hr
STEL 125 PPm. 543 mg/m3
: None Established
,-
I
r
TWA
TWA

~
1 -DUPO 50
E. I. du Pont de Nemours and Company
UNLEADED GASOLINE
MSDS NUMBER: 3431001940
-I
PEL (OSHA) :
ISSUE DATE:
50 ppm, 245
95/01/13
mg/m3, 8 Hr.
I
.i
TW~, Skin
TLV (ACGIH) : 50 ppm, 246 mg/m3, 8 Hr. TW~, Skin
AEL * (au Pont) : None Established I
PSEUDOCUMENE
PEL (OSHA)
TLV (ACGIH)
AEL * (Du Pant)
METHYL T-BUTYL ETHER
PEL (OSHA)
TLV (ACGIH)
AEL * (au Pant)
WEEL (AIHA)
XYLENES
PEL (OSHA)
TLV (ACGIH)
AEL * (Du Pont)
TOLUENE
PEL (OSHA)
TLV (ACGIH)
AEL * (Du Pant)
: 25 ppm. 125 mg/m3. 8 Hr. TWA
25 ppm. 123 mg/m3. 8 Hr. TW~
: None Established
: None Established I
: 40 ppm. 144 mg/m3. 8 Hr. TW~
Notice o~ Intended Changes (1994-1995)
40 ppm. 144 mg/m3. 8 Hr. TWA, A3
: None Established
: 100 ppm. 8 Hr. TWA
: 100 ppm. 435 mg/m3. 8 Hr. TWA
: STEL 100 ppm. 150 434 PPm. mg/m3. 651 mg/m3 8 Hr.. JA
: 100 ppm. 8 Hr. T'w'A
150 ppm. 15 mi nute T'w'A t,~~~
: 200
300
ppm.
ppm.
8 Hr. TWA
Ce; 1; ng
;1CC{
,"C ~
,"
500 ppm -10 M;n. Max.
: 50 ppm. 188 mg/m3. 8 Hr. TW , .Skin
: 50 ppm. 8 & 12 Hr. TWA
* AEL is Du Pont's Acceptable Exposure Limit. Where !
governmentally imposed occupational exposure limits which are
I
lower than the AEL are in effect, such limits shall ta~e
precedence. I
Poi,
ressl
Specific Gravity
It
Ire
iles
i ty .
n Water
: 29-225 C (84-437 F)
: 275-475 m11 Hg @ 20 C (68 F)
: 100% by Volume
: May be slightly soluble
: Gasoline
: Liquid
: Red-dyed, pink, or colorle light
yellow
: 0.70-0.77 (H20=1)
PAGE 7

1 DUPO 50
E. I. dlJ Pont de Nemours and Company
UNlEADED GASOlINE
I1SDS NUMBER: 3431001940
Physical Hazards
ISSUE DATE: 95/01/13
Physical and Flammable properties are typical of conoc
products; data reported above may vary slightly for
other vendors' products. ,:
,
STABILITY AND REACTIVITY
Chemical Stability
Stable at nonna
temperatures and storage conditions
Avoid contact with strong oxidants such as chlorine.
concentrated oxygen, or hypochlorites. Keep from heat
flame and other ignition sources.
Decomposition
Hazardous gases/vapors produced are carbon monoxide from
incomplete oxidation.
Polymerization
Polymerization will not occur
DISPOSAL CONSIDERATIONS
Waste Disposal
Treatment. storage. transportation. and disposal must be in
accordance with applicable Federal. State/Provincial. and Local
regulations. Do not ~lush to sur~ace water or sanitary sewer
system. I
Recycle as much of the recoverable product as possible.
CERCLA RQ -METHYL TERT-BUTYL ETHER = 1 LB
TRANSPORTATION INFORMATION
Shipping Information
DOT
Proper Sh;pping Name
Hazard Class
I.D. No. (UN/NA)
DOT Label (s)
DOT Placard
DOT/IMO
Proper Shipping Name
: GASOLINE
: FLA~BLE LIQUID
: UN12O3
: FLAMMABLE LIQUID
: FLAMMABLE
: GASOLINE OR MOTOR SPIRIT
~
PAGE 8

1 DUPo 50
E. I. du Pont de Nemours and Company
'JNLEADED GASOLINE
I ~DS NUMBER: 34310019-40 ISSUE DATE: 95/01/13
~ Hazard Class: 3 (IMO 3.1)
...UN No. : UN12D3
DOT/IMO Label: FLAMMABLE LIQUID
Packing Group: II
REGULATORY INFORMATION
U.S. Federal Regulations
TSCA Inventory Status : Reported/Included.
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute: Yes
Chronic: Yes
Fi re: Yes
Reactivity: No
Pressure: No
OTHER INFORMATION
NFPA, NPCA-HMIS
NFPA Rating
Health
Flarrrnability
Reactivity
: 1
: 3
: 0
The data in this Material Safety Data Sheet relates onlyl to the
speci~ic material designated herein and does not relate to use in
combination with any other material or in any process. I
Responsibility ~or MSDS : Du Pont
Address: Corporate MSDS O~~ice -HR
Telephone: 302-992-6704
# Indicates updated section.
Barley Mill Plaza, P14-2150
Wilmington, DE 19880-0014
End of MSDS
PAGE 9

MATERIAL SAFETY DATA SHEET
GENIUM PUBLISHING CORPORATION
1145 CATAL YN STREET
SCHENECTADY. NY 12303.18,j6 USA
(5 18) 377.8855
SECTION I. MATERIAL IDENTIFICATION
CEHIUM P\lIUSHIHC COR~.
NO.
469
FUEL OIL NO. Z
Date
Occober 1981
HATERIAL NAME: FUEL OIL NO. Z
! DESCRIPTION: ~ture of pecroleum hydrocarbons; a distillace oil of low sulfur contenc.
OTHER DESIGNATIONS: ASTM D396, CE Material D27B1A, CAS 1068" 476 302
MANUFACTURER: Available from many suppliers, includ1n~:
SECT[ON II, INGREDIENTS AND HAZARDS x HAZARD D.Ai"A
Fuel Oil No.2
C~mpl~:< cix~ure of pur~ffinic, olefini~, n3phcheni~,
and a~l'macic hydro~arbo"s
Sulfu~ conce"c
u",nzcn~**
*Cu~r~n~ n$!i,\ st.~nd~rd and ACCrH (1981) TLV
**.\ iuw benzcnc 1~\'~1 r~du~es carcinugenic risk
oils ~r~ ex~pceJ und~r che benzene scandard
l~9 CfR 19l0.l0Z8)
::ECTION .PHYSICAL DATA
App~arance and Odor:
Ca 340-675
negligible
2.0-3.6
Fu~l

~
No. 469
Inhalation of excessive concentrations of vapor or mist can be irritating to the respi- .
ratory passages and can cause the folloying symptoms: headache. dizziness. nausea, I
l.
vo~iting, and loss of coordination. Prolonged or repeated skin contact may cause irri~
tation of the hair follicles and block the sebaceous glands. This produces a rash of
acne pimples and spots, usually on the arms and legs. (Good personal hygiene Yill pre "
vent this).
Chemical pneumonitis may result yhen ingescion occurs and oil is aspirated in the lungs
FI~U~: .Eye COntact: Flush thor~ughly Yith running yater for 15 min. includiDg under eyelids.
$~n Contact: Remove contaminated clothing. Wipe ex~ess oil off vith a dry cloth. Was
affecced area yell yith soap and Yacer.
Inhalation: Remove to fresh air. Restore and/or support bre~thing as required.
Ingestion: Do noc induce vomiting.
Seek medical assistan~e for further treatment. observation and supporc.
SECTION VII. SPILL~ LEAK~ AND DISPOSAL PROCEDURES
oNotify safety personnel of leaks or spills. ~ove sources of heat or ignition.
...i ovide adequate ventilation. Clean-up personnel to use protection against .
,.., liquid contact and vapor or mist inhalation. Contain spill by diking. Small spills ca~
I be contained by using absorbants, such as rags, straw, polyurethane foam, activated ,
(.' .carbon, and sand. Clean up spills promptly to reduce fire or vapor hazards. .
.!SPOSAL: May be disposed of by a licensed waste disposal company, or by controlled in- .
cineration or burial in an approved landfill.
Follow Federal, State and Local regulations. Repor~ large oil spills.
SECTION VIII. SPECIAL PROTECTION INFORMATION
Provide adequate ventilation where operatin~ conditions (heating or spraying) may create
excessive vapor~ or mists. Use explosion proof equipment. Provide approved respirato~~
apparatus for nonroutine or emergency use. Use an approved filter & vapor res,pirator I
when vapor/mist concentrat~ons are high. Wear protective rubber gloves and chemical I
safety glasses where contact vith liquid or high mist conc. mayoccur. Additional
suitable protective clothing may be required depending on working conditions. An eyewash
fountain and vashing facilities to be readily available near handling and use
areas.
Launder soiled or contaminated clothing before reuse (at least veekly laundering of
work clothes. is recommended) .
SECTION IX. SPECIA~ PRECAUTIONS AND COMMENTS
Store in closed c.ontainers in a cool. dry, well-vent:iJ.at:ea area avay rrom sourc.es ot
I open flame, heat. strong oxidizing agents. and ignition. Protect containers from
~ physic.al damage. Use non sparking tools and explosion-proof electrical equipment.
~ Prevent static. elec.tric. sparks .
."'VOid prolonged skin .c.ontac.t and breathing' of vapors or mists-
' smoking in areas of use. Folloy good hygienic practice in the use of this material.
Do not wear oil c.oncaminated clothing. Do not put oily rags into pockets. Wash exposed
skin areas several times a day with soap and varm vater vhen working Yith this
material. DOT Classific.acion: COMBUSTIBLE
~ATA SOURCE(S) CODE: 1,6,7,12
-APPROVALS:
HIS
CRO
~ ..10 ~ --~.O' "7 -0'-- , --~ --.,
"",." .,~ r ~ "M 0 ~ .-~.00'- 7
--
Industr;"l Hvaip:ne I"
J
I
it
1.
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~."'
"
~
~-

5t'EC!A!.~ on. ~]..N"i
Stihl .r::hain arrl .~
A.
-:""-&:..-
~ SAFf:IY. ~ ~ .
ra.te. Issuerl: 10/31/90
SIJper-'~ ~t.e: 05/04/88
~ oil ~ P.o. B:Jx SO98 ~,IA 71l.08
IDENr!nCAT.!OO ].lm ~C'i ~
mJrocr !-WiE
Stihl C1a.in arrl :ea.r lubricant
Q1EMICAL~
Petrolel.D ~catin; oil
IR)rIJCr ~CE AND OOOR
Cl. ear arxi Bright
Mild Blarrl Petroleum Qjcr
~Cf ~ NUMEm
(318)-687-8000
IB. ~AND~~OO
~wcr CI)I:lE
a.s~
~ CAS NO .OF
cn1Ea!E!!IS
IIJbricatin; oil. B3.se S~ 64742-52-5 an:i
64742-53-6
~lex M1xb:e
CAS NI~r .Not At:t:Jlicable
'APfroXIM1'.TE
~=oo
Greater than 9 5 %
Addi ti ve Package Less than S %
See section E f"or Health arrl Hazard InfODIaticn
HAZARIXXJS HI\=rJ\IS ImrrIFICATION SYSmi (1mS)
Health ~ility Reactivity
1. 1 O
~ L1M:tT roR 'rorAL ~00Cl'
S nqj~ for oil mist in air
MSIS
Hazard Ra tin;s
0- least 3 -High
1-5light 4-~tI:ar.e
2~te
CSf!A. Regu1atior1 29 Q'R 1.910.1.000
c. ~ R:x]rES OF mmi' AND ~cr AND i'I:FSr
AID m:::I~I,j~
EYEa:NrAcr
I f sp , ~ shei intD the eyes , f1 ush ~ th cl. ear 1!"a ter f or l5 mi!l1.Ites
or until
.I
irri taticn .StJhsides .If i.rri taticn P'rSists ' C2li a
rl1Y:sl.ciaI1. I

Page 2
stihl a-.ain arrl ~ -
SI

.
Pal; e. 3 ~ ~ Q1ain ard .Bar
~rl:.r(]:1 IroroCIS. UNm>. FIRE mmITl:a5 .
.~ , Sl%XJke. , C3rl:x:Jn .."."a.;.. ; ~ 00.des , aldehydes ard other
d~-:.:-i,~T-~itia1 prcxnJCts, in the case of in:x:::mplete ~.1Sion.
'1n1PI"i" ~~
, ~ t =tajJ1QrS rEta.in res idue ( liquid ard/ or ~ ) a!':d ca.n
~ darJ:J~. ro ~ PRESSURIZE, a7r, WE:rD, ~, roL"ER, rP.n.L,
GRI2-lD OR ~ SUa! ~ 'IO HE1'.T , FI.AME: , SPAPJ(S , ~c
EU:cmICI'IY , 00. ~ ~ OF IQm'IOO : 'IHF:'i ~ ~DE .AND ~
~ OR ~. {):) rDt a~ tc clean sin::e residue is diffiOl1t
to reIIr:Y-..e .I~I dr\ms sha.l1d re O:%!tJle:tely drai.rm , prct:erly
burx.;e:i arrl l=~!:1y retm:rs1 to a dI:\D %:~M~. All other
~ shoJ1.d 00 ~ of in .an erNll:cr1I2ntal1y sa.fe ~ arrl.
in ac::x)rdarx:::e .-ith gaveI:Imexltal ~ticns. Fcr wrk on tanks refer
tc ~~tia'B1 Sa:fety arrl Health }o,.jn1st;raticn I:93U1aticns. M51
Z49.1 an:i other gov=-ntal arxi ~ refererx:es pertainin; tc
cleanirq, rep3iriIx;", weldirq, ar other =teI!p1.ate:i cperations.
E. HEAImi AND lOOARD ~ ON
VAR:[ABn.rI'\r~nwlVn:I11-.I.S .
Health st:lnies have sho..m that many ~troleum hyd:~ arrl
synthetic l.ubric::ants ~ !"tential .hI.man heal th risks ...'tridl Day vary
fran t:eI:sar1 to t:erSCI1. As a pra:2.ution, ~ to liquids, vaE=Ors,
IIJ.ists or fuIIes ~d k:e minimized .
m"F.crs OF a=JRE (SIQ5 AND SYMPm'1S OF ~0Rt:)
Prolarx;e:i or ret:eated skin contact nay cause skin iI:ritation
NA:ruF.F. OF H1-.z.ARD AND roXICI'I"i ~ON
In ~I:~ with the aJrI:ent ~ Hazard r~mication Starrlard
c:ri teria , this prt:rluct dces rot ~ a carx:er hazard wamh,. .'n1is
is b:cause the pz:muct .is fonm11~tej f:ran base sto=ks .-.'hid1 are
severely hydt:Ct:r~t.ed, severely solvent extracta:i, arD/or prc",~~~ by
mild hj'drtJtJ:ea~ arrl extractia'1. Alternatively. it my a::1Sist of
~~~ mt ctherJise aff~ :by ~ criteria, sud1 as vacuum
distill a tes or synthetically deri va:i Ita. ter ia1s , am as sud1 is mt
d1aracterizm :by OlD:"r:?I:lt ~ cl~~5ification criteria.
Prolorx;w or !:E[:eated skin ~ltact ~th this pra!uct terx!s ~
renD\7e sk;in oils p:ssibly leadino to irritation am np~titis.
Ha..t'ev' er I ~ -~ an h1.men e>q:eri ~ arxi ava i 1 ~ b 1 e toxiro 1 ogi ca1 data I
this p%:murt is jt:k:Jge:l to ~ neither a "u..I.1.I:C:Sive" ~ an "irritant"
by a>11A c:ci tEri.a ...
Q)rttiIU]OJS
aninal tests .
CX)rIt,act with use:i 1IrJtor oil has ~11~ skin carx::er ill
Prcrluct ~ctin; the eyes nay cause eye i:rritaticn.
cl

8
.
8
Page 4
Stihl Q:1a.in am .Pi!r
) Prt:dI.x:t has a lC7.J o~.~~'"-~~.~ arxi ~~, t~-cl'.tY, nIt
mir!%Jte .~ aspiraterl into the Itln3S dJ.rriIf:J irl3esticn or vt:mitirJ:J
Iray ~11se tnild to severe p1L~ injury ard p:::ssibly death.
'nlis pran%:t is j~ to have an aaIte oral IISO (rat) greater
than 5 g/}t:q of b::dy "-'eight, an:l an aaIte. dI"~l ~O (t"arLJit) greater
than J .1.6 g/kq of b:::rly ~ight.
W.E-EXISI:nC MEDICAL ~CNS ;!Ua! MAY BE ~~ BY =-
Nore. ~
F. mYSIC1\L ~
.'n1e foll~ dat:a are ~te or ~il:2,l values arrl shci1ld
oot t:e usa:i for pre::ise design FUrIX2Se5 .
..,
00 n.m:; ~
Not~t.=.jz8i
SPEcrF:r c Gt

pages ~ ~ QJain an:l Bar
s- ~ 'IO EE TAKEN IN CASE !!An7!IAr. ~ ~ SPn J' m .
:RB:XJIJer free P=!1JI:t .}di sam , ~ , cr cther sui tabl e
~~~,1i-~lt to spill area. Minimi ?'~ skin a::lt:act. ~ ~ 0It of
sewers arD 'w'a.~ by djkjn; cr ~ .M\rise authcrities
if ~ has entere:i or m:y enter ~ , 'w-a~ , or ~i ve
lan:i ~ .Assure c:::'1f aImi ty 'Wi th ~ ' ] ~ 1 e 9C\r ~ ~ ~ tal
rs;u1.aticns.
~ ~ (ro;) , EPA ~ai 40 c:rn 302
Not ~wlic:able
'roXIC am-n:CAL 'RErEA5E ~.~, n'A mI:;JiATICN 40 CFR.i372
Not awl ;~.."e i
E:PA }mzAP.D =D.TI(J:.f axE:
w.%te~Fire
Haza:rdHazamHaz.am
I. ~11:~!~1-CN .AND ~~
pz-~
Ha%a:rd
P.eactive
Hazam
Not
Awlif:abl.e
xxx
vn==CN i
Use. lcx=al ~ tc capb.n"e vaFrJr , mists ar ~ , i.f
F.:..-~~ry. ~ venti1aticn su:f.ficient tc prevenI: e:I-c--~iT'x;
:to:~I'.'~'''rle:i ~:rre l.i:mit or WildlJp of ~-..,-1csive. ~ticns of
Vap:Ir
lights.
in
: .
air .Use. exp 1 cs i or- rpz-- w .f equi prent .No SD:3kin; or ~
RES I;' IRATORY Im ~ r .~l ~
Use ~ied-air
S'p3ces , if ~~ .
From::r'LVE Gr.a.lES
Use ~ ; ~ , -res istant
~ ta:l skin 0:: 1 t:act:: .
resp ira tory prote:ti an in az1fined or el'x=l csal
gloves, if ~e:i, to avoid pro:J.Or'X3'E!d or
I
~ Iro~~CN i
Use splash 9tX]g1~ orface shield W'ben eye ~, :ay cx:z=tt'.
~ mJ~..lVE ~
Use. d1an ; ~ 1 -~ istant apt or lor other ~ cl cthirx; , if
~~, to avoid =taminatirq re;ular clcthin; ~~ t'Y'W,1" result in
pro 1 0fX3e:i or ret::ea ted skin cx:: 1 tact .
"mK ~CES~ ~I.S
}r.eep ~ arrl storage. ~ cl~ ~ mt in use.
t):) ~ stare rear heat, ~, f1~Ire or ~t:I:~~ ~.
F=a{AI.}fiGmiE I
Minimize breathirq ~ , 1nist or fuIr.es .AVbid prolorqs:i or
~ te:l ~ 1 tact 'w'i th sJdn .P2IcoJe cn 1 i:amina tsi cl othiJ'X1 : 1aurrler or
drj -cl ean t:e:f cre ra.1se .~ o:I1tamil1atm shces arrl t1=u;h1 y
clean 1:efore ra1se.; dL~rd if oil~. Cl~ skin t1=u;h1y

8
t;:
?age 6 Stihl C'1ain arrl B?r
a.fter ..c:aItact , k:e.f cre ~ .w: ~ , .ard a t erd of 'w'C rk I:'e-rii;:d .
Prt:rluct is readily ~ fra!l skin by 'w'aterless harxi cleare:rs
f olJ, ~ by wshirq ~ y 0Ji th soap an:i \o'a te.r .I
J'. ~roR:rATICN ~Ctl
'IF.ANSroRrATIa1 ~Cmfl;lr ~a1
For further infO2:JrJaticn relative to spills resulti.rq frau
~tion i=idents, refer to latest ~ .of
Trans ~ 4 ta ticn
Irx::ident.s. ror
E%I:ex:g erx:y
P 5800.3.
P.esp:Jr 1se. Q 1 i n P ~ ~ f or ImmdaJS
.
Ma teria1s
oorImrm:Ic:ATIr21~
Not ~licab' e
'n1e inf crII2. ti on arrl .L. ~ erda ti ons c=:z 1 t:airm herein are , to the
t:est of ~an:i's krx:1..ile=X;e arrl OOlief, aO='-Irate ard reliable as of
the ac:cJracy date or issued. reliability, Westlarrl am Westlarrl. d~ rot shall W'aIrant ~ te or liable guarantee for any thei:r lcss
or danag e aris iD:I C2.It o f the use ~ f .
'n1e infornation arrl re:I'~'~rrlatians are offered for the user's
consideration ar:rl examinaticn, arrl it is the user's ~ibility to
satisfy itself that they are suitable arrl ~lete for its ~c.1lar
use.
'n1e DNirUlmE11t:.al Il1fOI::ra.tion ircltrla:i urDer ~CIl H here:Jf as
wl1 as the HazardOJS Materials Identification System (!i'aS) arrl
National Fire PJ:utection As.scciation (NFPA) ratin;s have b:!en iIx:l\rle:i
by Westlarrl oil ~ , Irx:. , 1n oI:der to provide additional health
an:i hazard classification info:cration. 'n1e ratirqs re:lx,"lerrle:i are
b::.-~ ~ the criteria suppli~ by the deve1~ of these rati1'q
syst.eIt5 , tCXJether with westlarrl's intu.,retation of the aV'ailable
data.
FOR AOOrnCtu..L ~ON ON ~ EFFECIS a:1:rD.crf
Westlard. oil ~ , ~. """
2740 v.iUeyvier.,t Dr. ~ 1
Shrev~:1;.t, !A 711.48 { .
(J18) -6Bs..:lJOO ..'~.
FOR onw. ffi:)rocr ~ON Q:!-lrAcr :
~i.a1ty oil ~ , Irx:.
2740 Valleyvie:.1 Dr.
Shre\.-~rt, lA 7ll48
(318)-681-8000
rL
I

I. PRODUCT IDENTIFICATION
II. HAZARDOUS INGREDIENTS
Chemical Name
Aliphatic Petroleum Distillates
Petroleum Base Oil
Non-hazardous Ingredients
III. PHYSICAL DATA
Boiling Point:
Vapor Density (air = 1 ):
Solubility in Water:
Specific Gravity (H2O = 1 )
Percent Volatile (volume)
IV. FIRE AND EXPLOSION
CAS Number
80~2-41.3
64742-65-0
300°F (minimum)
Greater than 1
Insoluble
.800 @ 70°F
74%
%
I')
.-70 -
> 20
< 10
Evaporation Rate:
Vapor Pressure:
Appearance:
Odor: ,
VOC: 1
SHEET
Exposure Umlt .
ACGIH/OSHA
100 ppm PEL
5 mg/MJ TWA (mist)
Not determined
Not determined
.Cloudy light amber
Characteristic odor
568 grams per liter
v. HEALTH HAZARD I
Threshold Limit Value
Aliphatic Petroleum Distillates
OF ENTRY
(Stoddard solvent) lowest TLV (ACGIH 100 pp 1.)
Symptoms of Overexposure. .
Inhalation (Breathing): May cause anesthesia, headache, dizziness, nausea ~nd upper respiratory irritation.
Skin Contact: May cause drying of skin and or irritation.
Eye Contact: May cause irritation. tear\ng and redness. ..
Ingestion (Swallowed): May cause irritation. nausea, vomiting and diarrhea. ..: , .' .
First Aid Emergency Procedures, -., ,- ..-, .,
Ingestion (Swallowed): Do not induce vomiting. seek medical attention.
..,
' l
, .-.' .
Eye Contact: Immediately flush eyes with large amounts of water fcpr 15 minutes.
Skin Contact: Wash with soap and water. 1
Inhalation (Breathing): Remove to fresh air. Give artificial respiration if nece~sary. If breathing is difficult, give
DANGER!
Aspiration Hazard
Suspected Cancer Agent
v,," ' ,-
oxygen.
If swallowed can enter lungs and may cause chemic~1 pneumonitis. Do not induce
vomiting. Call Physician immediately. ~ l
"",.:.j
I

-
8
VI. REACTIVITY DATA
Stability:
Conditions to avoid:
Stable
NA .--1
x Unstable.
Incompatability:
Strong oxidizing materials !
Hazardous decomposition products: Thermal decomposition
and/or carbon dioxide.
may y~ld
I
carbon monoxide
~...
Hazardous polymerization:
VII. SPILL OR LEAK PROCEDURES
VIII. SPECIAL HANDLING INFORMATION
Ventilation:
Respirato'ry' Protection:
Protective Gloves:
Eye Protection:
Other Protective Equipment
IX. SPECIAL PRECAUTIONS
May occur :'t","! Will not occur X
.
Sufficient to keep solvent vapor less than TlV.
Advised
Advised
when concentratio'ns exceed TLV.
to prevent possible skin irritation.
\
!
.
, ,
Approved eye protection to safeguard agai.nst ~tentia} eye contact,
irritation or injury. !
None required. d
Keep from open flame, do not take internally. Avoid excessive inhalation of spr~y particles. Keep from children.
x. TRANSPORTATION DATA
Domestic Surlace
Description:
Hazard Class:
ID No.:
Packaging Group:
Label Required:
Domestic Air
Description:
Hazard Class:
Label Required:
-
Petroleum Distillates N.O.S.
Combustible liquid
UN 1268
III
NONE. for containers less than 100 Gallons
Petroleum Distillates N.O.S. (Stoddard Solvent)
3 UN 1268 PGIII
Flammable Liquid
XI. REGULATORY INFORMATION
All ingredients for this product are listed on the TSCA inventory.
SARA Title III chemicals: None
California Prop 65 chemicals: None
CERCLA reportable quantity: None
RCRA hazardous waste no: DO()1 (ignitable)
',- =VISION DATE: October 1993
".
NA = Not applicable
NDA = No data available
TITLE: Technical Director
SUPERSEDES: Auoust 1992
< = Less ,than
> = More thari -

-
MAteriAl Name
Quaker State HD lOW Motor Oil
MATERIAL SAFETY
DATA SHEET
Chemical Name: Petroleum distillate mixture I
Internal Part No.: Order Nos. 03408 (5 gallon); 03~lO
bulk I
j
Page: 1
I Issue Date: 11/04/1994
M$DS No.: 05-021
Manufacturer Information
Quaker State Corporation
P.O. Box 989
Oil City, Pennsylvania 16301
Supplier
None
PHONE t:
EMERGENCY t:
Information
PHONE I: (814)676-7676
EMERGENCY I: (814)676-7676
Mfg. Part tNA Sup. Part tNA
Synonyms : Motor Oil
CAS I
64742-65-0
68649-42-3
84605-20-9
Components
55 gallon); 03419
Component Information/Information on Non-Hazardous Components
This product is not considered a hazardous product under 29 CFR
1910.1200 (Hazard Communication). All mineral oils used in this
product have been severely hydrotreated and/or solvent refined.
Section 3- HAZARDS IDENTIFICATION
Emergency OVerview
This product is a viscous amber liquid. It will burn at elevated
temperatures (above 400 F). Addition of water or foam to the fire may
cause frothing. Use dry chemical or carbon dioxide for small fires,
water spray or foam for large fires.
Label Information
WARNING: Continuous contact with used motor oil has caused skin
cancer in animal tests. Avoid prolonged contact. Wash skin with soap
and water. Launder or discard soiled clothes.
.Potential Heal th Effects. i,!;c
Ey;~iS product may cause irritation to the eyes. :1;
Skin I
Prolonged or repeated contact with skin may cause 'mild irritation and
possibly dermatitis. symptoms may include redness, edema, drying,
defatting and cracking of the skin.
Ingestion i
Low toxicity. Swallowing may cause stomach cramps ;and diarrhea.
Pulmonary aspiration hazard if swallowed. i
\ Val
80-95
1-2
1-5

'i
MAteriAl Name
Quaker State HD lOW Motor Oil
MATERIAL SAFETY
DATA SHEET
I Page: 2
Issue Date: 11/04/1994
Msbs No.: 05-021
InhAlAtion
Negligible hazard at room temperature {up to 95 degrees F). High
temperatures or mechanical action may form mists pr fumes. Inhalation
of oil mists or fumes can cause irritation of thel nose, throat and
upper respiratory tract. Y",cC.
Eyes
Flush eyes with large amounts of water for 15 min~tes. If eyes become
inflamed, seek medical advice.
Skin I
Remove contaminated clothing. Wash affected area ,ith mild soap and
water. Launder contaminated clothing before reuse~ If leather articles
become saturated they should be discarded.
Ingestion
Do not induce vomiting unless instructed to
I
do so by a physician. Call
your
Inhalation
local poison control center or get medical attention.
Remove to fresh air. If not breathing, give mouthito mouth
resuscitation.
physician.
If breathing is difficult, give o1 gen. Call a
Notes to Physician i
This material, if aspirated into the lungs, may cause chemical
pneumonitis; treat the affected person appropriately.
Section S -FIRE FIGHTING MEASURES
General Fire Hazards
This product is combustible at high temperatures. I
Hazardous Combustion Products !
Carbon dioxide, carbon monoxide, oxides of sodium, 1 calcium, magnesium,
phosphorus, and zinc.
Extinguishing Media I
Dry chemical or carbon dioxide for small fires. .W~ter spray or foam
for large fires.
Fire Fighting Equipment/Instructions
I
Wear full set of protective equipment including chemical goggles and
gloves. Use water spray to cool fire-exposed containers and as a
protective screen. Do not point solid water stream directly into
burning oil to avoid spreading.
Continued on next page...

Material Name
Quaker State HD lOW Motor Oil
MATERI-AL SAFETY
DATA SHEET
Page: 3
Issue Date: 11/04/1994
MS,DS No. : 05-021
this is without risK.
Clean-Up Procedures
Wear 'appropriate protective equipment and clothing during clean-up.
Absorb with inert absorbent such as dry clay, sand or diatomaceous
earth, commercial sorbents, or recover using pumps~ Scoop up used
absorbent into drums. Do not allow the spilled product to enter public
drainage systems or open water courses. Surfaces ~ay become slippery
after spillage.
Evacuation Procedures 1
Persons not wearing protective equipment should br excluded from area
of spill until clean-up has been completed. r
Exposure Guidelines \
A. General PI;oduct Information
If 011 mists are generated, observe the OSHA exposure limit of 5
mg/m3. Protect from skin and eye contact. !
B. Component Exposure Limits
No ACGIH, NIOSH or OSHA exposure guidelines 11ste4 for this product's
Engineering components. Ctrl.: Use general ventilatlon. Use in 4 well-vent1lated area
PERSONAL PROTECTIVE EQUIPMENT i
Eye/Face: Wear safety glasses; chemical gogglesl(if splashing 1s
poss1ble) .i

MAteriAl Name
Quaker State HD lOW Motor Oil
MATER+AL SAFETY
DATA SHEET
Page: 4
Issue Date: 11/04/1994
M$DS No.: 05-021
Skin: Use impervious gloves for prolonged contact or any contact
with used oil. The use of neoprene gloves is recommended.
Respiratory: Normally not necessary. If mist is generated (heating,
spraying) and engineering controls are not sufficient, wear
approved organic vapor respirator suitable for oil mist.
General: Use good hygiene when handling petror,eum product.
-
Appearance: Light amber
Physical State: Liquid
Vapor Pressure: Negligible
Boiling Point: Not determined
Melting Point: Not determined
Specific Gravity: 0.87 to 0.88
Softening Point: Not determined
Viscosity: approx. 210 SUS @
loo F
Percent Volatile: Negligible
Additional Properties
None
Odor ,,;;f\ : Mild hydrocarbon
pH : Not applicable
Vapor Density: Not determined
Freezing Point: Not determined
Solubility (H20): Negligible "in water
Particle Size: Not applicable
Evaporation Rate: Not determined
Bulk Density, : Not determined
Molecular Weight: Mixture
Hazardous Decomposition Produc~s
At thermal decomposition temperatures carbon diox~de, carbon monoxide,
oxides of calcium, magnesium, phosphorus, and zinq.
Hazardous polymerization I
Hazardous polymerization will not occur. ~'-'- ~ ;~:;
and fibrosis 1n the ~ung. ;
B. Component LDSO/LCSO ,'i:
Epidemiology ;':
No data available for product.
Carcinogenicity
A. General Product/Component Information
t;;~
,,'
.
No data available on the product as a whole. Note ~hat USED oils tend
to contain higher amounts of the cancer-caus1ng aromat1cs, which have
been linked to scrotal and lung cancer in humans. I
B. Component
None of this
Carcinogenicity Listings
product's components are listed by AC ~ IH, IARC, NIOsH,
NTP or OsHA. .
Teratogenicity/Reproductive Effects I
No data available for the product as a whole. Rev1~w of information on
'..'.'m,",n.'",.'+-.'. '..1,..-~~~ '
1

,~
Material Name
Quaker State HD lOW Motor 011
MATERIAL SAFETY
DATA SHEET
r Page: 5
J Issue Date: 11/04/1994
l'tSDS No.: 05-021
Neurotoxicity
No data available on this product as a whole. Excessive exposure to
the oil mist and vapors may cause respiratory t~act irritation.
Mutagenicity
No data available on this product as a whole. Re~iew of information on
components
effects.
indicates no components at greater th~n 1.0' have mutagenic
Other Information
Persons
product.
with skin or respiratory conditions may r e more sensitive to
Ecotoxicity
No information is available on ecotoxicity of thfs product. Keep
product out of sewers and waterways. ,
Environmental Fate -b J
No information is available. ;t,
Section 13- DISPOSAL CONSIDERATIONS
us EPA Waste Nwnber , Descriptions ,:r
A. General Product Information I
Product as shipped does not meet the definition Qr characteristics of
a hazardous waste. User must test waste using methods described in 40
CFR Part 261 to determine if it meets applicable idefinitions of
hazardous wastes.
B. Component Waste Nwnbers
No EPA Waste Numbers are applicable for this pro uct's components.
Disposal Instructions l'
Used oil can be returned to a collection center r provided to a
licensed recycler. All wastes must be handled in accordance with
local, state and federal regulations. i
Section 14- TRANSPORTATION INFORMATION
DOT Information
Shipping Name: Not regulated as a hazardous material
Hazard Class: None l
Packing UN/NA Group: t: None ('{ > j
Label(s) Required ~
Additional Shipping InformAtion
International Transportation Regulations
Not regulated as dangerous goods.
us Federal Regulations "~'
A. General Product Information
~
All components of this product are listed on the .5. EPA TSCA
Inventory. "'
J

-
Material Name
Quaker State HD lOW Motor Oil
MATERIAL SAFETY
DATA SHEET
I PAge: 6
~ Issue DAte: 11/04/1994
M~D5 No.: 05-021
B. Component Information
None of this product's components are listed under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) or CERCLA
(40CFR 302.4) .J
State Regulations ;,,1
A. General Product Information
No components require labeling under California ~roposition 65.
B. Component Information
None of this product's components are listed on ~he state lists from
CA, FL, MA, MN, NJ, or PA. ,
Other Regulations
A. General Product Information
This product is not considered a controlled prod ct under the Canadian
Controlled Products Act.
B. Component Information
None of this product's components are listed on he Canadian
Controlled Product Ingredient Disclosure List .-.,J
Section 16 -OTHER INFORMATION
Other Information ,
This information is, to the best of Quaker State Corporation's
knowledge and belief, accurate and reliable. How~ver, no
representation, warranty, or guarantee is made to its accuracy,
reliability, or completeness. It is the user's responsibility to
satisfy himself as to the suitableness and completeness of such
information for his own particular use. i
Information Preparation: 11/04/94 r
Key/Legend i
NA = Not Applicable; ND = Not Determined; Y = Ye~; N = No
Contact Person: D. w. Cralley -Corporate Phone: (814)676-7676
Manager, Health and Safety 1
End of MSDS IQS-O21

MSDS
HYDRAULIC FLUID A\
mENnFICA-noN ... PEL (1W A); (3) ACGIH STEL; (4) OSHA
MSDS RECORD NUMBER: 480541
PRODUcr NAJ.\1E(S): HYDR.AUUC FLUID
DATE OF MSDS : 1991-07-15
E~(ERGE.:.'iCY TELEPHONE NO.:
303-623-5716800-424-9300 (~VrrREq
...~L-\~~ SAFETY DATA ...
i\'L;\TERI..-\L SAFETY DATA SHEET
30i-i66 REV. C
Issued: 8-30-91 Supersedes Rev ., Dated:
6-18-86
SECI1ON I -PRODUcr mENTmCA 11ON
A~D USE
PROD{JCT ID&~"11FIER HYDRAUUC
FLulD
PROD{;CT ID&'ffiFICATION NUIvIBER
(PIN) UN
PRODUCT USE Hydraulic fluid used in
hydraulic motors and hydraulic power
supplies.
CHE~CAL NAJ.\I[E AL~"D SYNONYMS
Industrial oils
cHE~ac.~ FALVIIL Y Pctroleum hydrocarbons
SEcnON II -HALA.RDOUS INGREDIENTS
HAz..3..RDOUS INGREDIENTS & CAS #
% BY V/EIGHr EXPOSLTR£ liMITS
Petroleum hydrocarbon industrial mixture
100 NE
oil (C.o1.S# Unavailable)
LD50 (SPECIES & ROu-rE): ~c
LC50 (SPECIES): NE
Oil mist, if generated (mineral)
5 mg.im3 (1, 2)
(CAS# 64742-65-0)
10 mg.im3 (3)
LD50 (SPECIES & ROL-rE): r-..c
LC50 (SPECIES): NE
Sara (.;10 CFR 37:.), Title III, Section 313
Reportable Chemicals: None
Produc: does no[ mee[ classification criteria of
\\-1IMIS and is not 3. controlled
STEt; (5) MFR.iSUPPLIERTLV; c=Cciling
value LDSO Values are via Oral Route unless
otherwise indic:lted.
SEcnON ill -PHYSIC.o\L DATA
PHYSICAL STATE Liquid
v APOR PRESSURE (mm Hg) NE
VAPOR Dfu'\j"51TY (Air=l) >1
% VOL-\11LE AT ROOM TE.'\-{P .DEG C
Negligible
EVAPORATION RATE (N-BuTYL
ACETATE= 1)

Acute aspiration of large amountS ofoi11adcn
material may p~cc a serious aspiration
pneumonia. Repeated aspiration of small
quantitics of mineral oil can produce chronic
inflammation of the lung.
MSDS
HYD RA VU C FLUID
\,

MATERIAL SAFETY DATA SHEET
roduct Name: Poison Oak-N-Ivy ARMOR
1'ec Laboratories, Inc.
Page lor 4
Issue Date: 09/08/93
.*'**...*' *** **..**.*...*.*..* * ****** ***.*..**.*.
*A..*..**.**.**.- SECTIOR I -COMPARY ABD PRODUCT IBFORMATIOR **.. .
,* *..***.*..*..**.** **-.*.*...*.*.*..*.**..*.*.*.* * *-
MANUFACTURER:
Tec Laboratories, Inc.
P. 0. Box 1958
Albany, OR 97321
EMERGENCY TELEPHONE NUMBERS:
(503) 926-4577
(503) 926-0769
PRODUCT NAME :
Poison Oak-N-Ivy ARMOR
r
CHE.'of!CAL FAJ.'t!ILY:
Lotion
CAS NUMBER :
Not available for this mixture
PRODUCT DESCRIPTION:
Lotion for conditioning skin before
exposure to poison oak, ivy and
sumac.
4.'**************.**...*.*****************..***.********.****.*.*.**.************.
,*'*.~***************.* SECTION II -RA7~RDOUS IXGR!DIEBTS ****************.*..***.
,.."*'******************************************************************.******.***z
PERCENT BY
,.:;AS # CHEMICAL NAME WEIGHT T!.V ACGIH
--
**********NO HAZARDOUS INGRED!~~TS*********
HAZARD SuMM.~?:l
Ratinq De:initions
Health O
Fire 1
ReactivityO
0- least
1- slight
2- moderate
3- high
4- extreme
**************.**** *******.******.**.********a*****************.********.***%
************.*..*..********** SECTION III -COMPOSITION *.*.*.***.**************%
~**********.*******.**.****************.*************.************************..%
CAS # CHEMICAL NAME PERCENT BY WEIGH!
---
125643-43-8
8042-47-5
8021-89-3
1337-33-3
8006-90-4
88-04-0
P=oprietar"{ infor~ation
Tricaprylyl citrate (trioctyl citrate)
f.-lhite mineral oil
Bleached beeswax
Monostearyl citrate
Triple distilled pepper~i~t oi~
Chloroxylenol
PI*
II
II
II
II
n

Product Name: Poison Oak-N-Ivy ARMOR
Tec Laboratories, Inc.
Page 2 of 4
Issue Date: 09/08/93
*** *.*..**.**.**.*.**..***** ** *.***
.* * * SECTIOB IV -BEALTH BA7~RD ARD i:~~ AID IKFORMATIOR * * ..* * .* .* ~
*..* *.**..*...*.***..***..**..*.***...* *...**.* ***.*~
OCCUPATIONAL EXPOSURE LIMIT: Not established
CARCINOGENICITY: Not listed by NTP, IARC or OSHA
PRIMARY ROUTES OF ENTRY: Skin, eyes
SYMPTOMS .AND EFFECTS ROUTE OF EMERGENCY AND FIRST AID
.OF OVEREXPOSURE ENTRY PROCEDURES
Product 1s unlikely to produce
eye irritation or corneal
injury.
Product is non-irritant under
normal use. Repeated, longterm
exposure may cause minor
irritation.
Low vapor pressure makes
inhalation hazard unlikely.
Ingestion is relatively nontoxic
unless aspiration occurs.
This product may have laxative
properties and may result in
abdominal cramps and diarrhea.
EYES If eyes become irritated,
flush eyes with large amounts
of water until irritation
subsides. If product is hot,
treat for thermal burns and
get medical attention
imJnediately.
SKIN
Discontinue use and wash
affected skin with soap and
water. Remove contaminatf
clothing. If a rash or
other symptoms develop, g~
medical attention.
INHALATION Remove to fresh room temperature
air.
INGEStION DO NOT INDUCE VOMITING.
Give large quantities of
water to dilute. Never
give anything by mouth to
an unconscious person. Call
a physician.
NOTE TO PHYSICIAN: There is no specific antidote. Treatment of overexposure
should by directed at the control of symptoms and the clinical condition.
,
\

Product Name: Poison Oak-N-!-r/ ARMOR
Tec Laboratories, Inc.
Page 3 of 4
Issue Date: 09/08/93
***..*.*****..*.****.***888.** *.8..*a **...********...
-..* ..* *... SECTIOR V *.** -PERSORAL *.** PROTECTIOR *** IBFORMATIOR *8**.**8*.*** *.*
*..*.**..&
EYE PROTECTION:
goggles.
--WHEN HANDLING BUL~ QUANTITIES--
OSHA approved plastic face shi~ld or splash-proof safety
PROTECTIVE CLOTHING: No skin protection is required for single, short
duration exposures. For prolonged or repeated exposures, use impervious
clothing (boots, gloves, aprons, etc.) over parts of the body subject to
exposure. If handling hot material, use insulated protective clothing.
VENTILATION: If vapor or mist is generated when the material is heated or
handled, adequate ventilation in accordance with good engineering practice
must be provided to maintain concentrations below the specified exposure or
flammable limits.
RESPIRATORY PROTECTION: Not required in under conditions of normal use. If
vapor or mist is generated when the material is heated or handled, use an
organic vapor respirator with a dust and mist filter. All respirators mus~
be NIOSH certified. Do not use compressed oxygen in hydrocarbon atmospheres
--WHEN USING PRODUCT ACCORDING TO DIRECTIONS FOR USE--
EYE PROTECTION: Avoid applying product in eyes.
PROTECTIVE CLOTHING: None required for normal us~.
VENTILAT!ON: Nor~al room ventilation is satis:actory.
RESPIRATORY PROTECTION:
None required for normal use.
.*************************************** ****.******************************.&S
* * * * * * * * * .* * * * SECTIOH VI -STORACZ AHD SPECIAL BAHDLIHG IHFO~IOH * * * * * * * * * .* & ~
****.******************.***.***************.*.**.**...*************************.c~
Avoid contact with eyes and mucous membranes.
Do not tranfer to unmarked bottles.
Store at room temperature.
****-**--**--*--****--*****-*************-***********-**********************-***.
$**-*** -* ** ** * * ** SECTION VII -SPILL OR LEAK RESPONSE IHFORMATIOH ** cc**** * * ** * ~
.***c*****-**-********-*****************c***************************************s
PRECAUTIONS IN CASE OF SPILLS OR LEAKS:
d .,
.lsposa
Dike and absorb material for
WASTE DISPOSAL METHOD: Sanitary landfill or incineration according to local
state and federal regulations for non-hazardous substances.
RC~0\/CERCLA HAZAR!JOUS WASTE: This product contains no hazardous waste

.Product Name: Poison Oak-N-I~1 ARMOR Page' of 4
Tec Laboratories, Inc. Issue Date: 09/08/93
~
..
* **,
.* SECTIOR VIII -I'IRE un EXPLOSION A'A7~RD IBP'ORMA'1"IOrr * * ..~
-** *..* * !
FLASH POINT (open cup): greater than 300°E'
FLAMMABLE LIMITS: unknown
(in air, % by volume)
EXTINGUISHING MEDIA: Foam, dry chemical, or carbon dioxide
UNUSUAL FIRE AND EXPLOSION HAZARDS :
burning.
SPECIAL FIRE FIGHTING PROCEDURES:
Treat as an oil fire.
None, except smoke may be generated whe~
Keep away from surfaces above 260°F.
******-*-*-***...***8***.**.******************8* **.*****-****-****.*******..
*********************** SEC'rIOH IX -REACTIVITY rBFORMA'1'IOH ***************-***a.
********************************************************************************a
STABILITY: Stable
INCOMPATIBILITY (MATERIALS TO AVOID): None
HAZARDOUS DECOMPOSITION PRODUCTS: Unk.iOwn
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: None
***********.****.*..*************************..********************.********.**a.
********aaaa*a.***.****a**** SECTIOH X -PHYSICAL DA%A ******a.***************aa.
********a**..*..*.****.***.****************.******.************.*****.********.aa
APPEARANCE: Yellowish-white o~ly liquid
ODOR: Peppermint
SOLUBILITY IN WATER (% by weight): insoluble
SPECIFIC GRAVITY: 0.913 ~ 25° C
BOILING POINT: above 300°F
WEIGHT PER GALLON: 7.62 Ibs/gal
VISCOSITY: 3- 10 cps
AUTO IGNITION TEMPERATURE: not established
,

MATERIAL
SAFETY DATA SHEET
oduct Name: Tecnu- Poison Oak-N-Ivy Cleansing Treatment Page 1 of 4
Tec Laboratories, Inc. Issue Date: 09/07/93
.~ SECT~OB I -COMPARY ABD PRODUCT IBFORMAT~O. a
MANUFACTURER:
Tec taboratories, Inc.
P. 0. Box 1958
Albany, OR 97321
EMERGE~CY TELEPHONE NUMBERS:
(503) 926-4577
PRODUCT NAME:
Tecnua Poison Oak-N-I~1 Cleansing
Treat:nent
CHE~ICAt FA.~ItY:
Detergent
888 &.
(503) 926-0769 CAS NUMBER:
Not available for this mixture
PRODUCT DEsCRI?TION:
Cleanse~ for removal of poison
plant oils.
.**.*.*...* * ** *.* * * * *..*a-z
*** *...* SECTION II -RA7~RDOUS INGREDrEHTS *...**.*..*****.*..***-.
*******.*** *.*******.***...*.***.***.*aa*a.a..a**..****.*..**.***.*...* PERCE~T BY OSHA ACGIH
CAS # CHEMICAL NAME WEIGHT PEL TLV
"
NO HAZARDOaS INGREDIENTS
HAZ"~D SUMMAR"{
Ratinq Defin.i-=ions
Health O
Fire 2
ReactivityO
0- least
1- slight
2- moderate
3- high
4- ex-:reme
**.8.8 *...*.* *88.8*...*** *.* SECTION *******..** III -COMPOSITION 8.88.*..888..*..**
** 8 ****.8.*..
.aaa***aa.8 a * * t 88
CAS # CHE~rCAL NAME PERCENT BY WE!GH7
~
1132-18-5
6471-65-7
57-55-6
61790-12-3
9036-19-5
N/A
25322-68-3
.PI = Proprietary information
Water
Deodorized mineral spirits
Propylene glycol
Octylpheno~l-po 1 yetho:

Product Name: Tecnu.Poison Oak-N-Ivy Cleansing Treatment
Tec Laboratories, Inc.
Page 2 ,..~ .:.
Issue Date: 09/t -}:
SECTIOR IV -HEALTH RA7~RD ARD ~IRST AID rKFORMAT~O. & .
OCCUPATIONAL EXPOSURE LIMIT: Not established
CARCINOGENICITY: Not listed by NTP, IARC or OSHA
PRIMARY ROUTES OF ENTRY: Skin, eyes
SYMPTOMS AND E:~ECTS ROUTE OF EMERGENCY AND FIRST AID
OF OVEREXPOSURE ENTRY
.
PROCEDURES
Causes to moderate to extreme
irritation, with possible
corneal injury
E:

Produc~ Name: Tecnu--Poison Oak-N-I~1 Cleansing Treat~ent
Tec Laboratories, Inc.
EYE PROTECTION:
Page 3 of
Issue Date: 09/01/9
SEC"rIOR V -PERSORAL PROT!C'TIOR IB!'ORMATIOR * * * ..* c
--WHEN HANDLING BULK QUANTITIES--
OSHA approved monogoggles or face shield.
PROTECTIVE CLOTHING: Wear rubber gloves. To avoid excessive exposure, wear
impervious boots and clothing.
VENTILATION: Normal room ventilation should be satisfactory.
RESPIRATORY PROTECTION: Not necessary
.-WHEN USING PRODUCT ACCORDING TO DIRECTIONS FOR USE--
EYE PROTECTION: Avoid applying product in and a=o~~d eyes.
PROTECTIVE CLOTHING: None required for normal use.
VENTILATION: Nor~al room ventilation is satistactory
RESPIRATORY PROTECTION:
None required for normal use
4***************************...*..**..*...*****~...**.***.*..***.***...***.&a.
..~ * * * * * * * * .* * SECTIO. VI -STORAGE AHD SPECIAL HAHDLIKG INFORMATIOH * * * * * * * * * ..z
**.*********..*.*.**.**.****.******.****.* * ******.**.&a*.**.*.*.**a*aa.z&
Keep away from heat, spa=ks, and flame.
room temperature.
Avoid contact with eyes. Store at
* s.*..*aa.*.* **...**.**..**..**.**.* * **.*..** az
...s.. S~IOH VII -SPILL OR LZAX RESPOBSE IBFORMATIOH a
s * ~.a.~~.a ** * * z.
P~ECAUTIONs IN CASE OF SPILLS OR LEAKS: Material is not considered toxic.
Absorb w:~~ dry sand or oil absorbents. All ma~er:.als are bio-degradable.
Clean spill area with detergent solution and flush down sewe~ with wa~er.
WASTE DIS?OSAL METHOD: Waste materials should be dumped or buried in an
approved industrial waste landfill. La:-ge quantities.may be disposed of by
lnclne:-a-1On.
RCRA/CERCtA HAZARDOUS WASTE: This produc~ contains no hazardous waste.

P~oduct Name: Tecnu Poison Oak-N-I~/ Cleansing Treat~ent
Tec Laboratories, Inc.
Page 40:
Issue Date: 09/07/3
.
SECTIOK VIII -PIRE ABD EXPLOSIOH *.* * HA~ARD * ** rHPORM&%IO.
,
FLASH POINT (open cup): 158°F
FLAMMABLE LIMITS: unknown
{in air, , by volume)
EXTINGUISHING MEDIA:
for small fires.
Foam for large fires; carbon dioxide or dry chemical
U~IUSUAL FIRE AND EXPLOSION HAZARDS : Smoke may be generated when burning.
SPECIAL FIRE FIGHTING PROCEDURES: Keep away from heat or hot surfaces abot;~
150°F. Above 150°F, treat vapors as you would odorless spirits. Treat as c::
fire.
* a...* *** * a ~.aa.
STABItI'l'Y: Stable
SECTION IX -REACTIVITY IBFORMATIOR aa.
* * *...* ~ * * *az.
INCOMPATIBILITY (MATERIALS TO AVOID}: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: None
Warl mixed alkanes at high temperatureJ.
************ *.****************.***.*.*...*.**.*.**.******...**..*.*****a.--
**.*a* *.*...**.**.***** SECTION X -PHYSICAL DATA *a***.a*.a.**a**a***a*.--
*a*a**.*a***.*****.*********..a**.**a ** *...*...***a**.a********.***
APPEARANCE: Creamy white, slightly viscous
ODOR: Lavender
SO!.'JB!LIn IN .WATER (~ by. weigh"=) : 100%
5?ECIFIC GRAVITY: 1.0 ~ 25°C
BOILING POINT: 164°F
WE!GRT PER GA:~ON: 8.35#
VISCOS::r"{ : 1,200- 1,700
AUTO IGN!TION TE~PERATURE: unk:1own \

MATERIAL SAFETY DATA SHEET
Jd~ct Na~e: Clea:ly Cala-Ge1~m
Tec Laboratories, Inc.
Pa

P~oduct Name: Clearly Cala-Gel~-
Tec Laboratories, Inc.
?ag~ 2 of. 4
Issue Date: 08/30/9-:
.*..c ' w a a.a.., , a a~.~.
SECTIOH IV -HEALTH HAZARD AKD P!RST AID INPORKATIOK ~ ..., ..,
a ~..
OCCUPATIONAL EXPOSURE LIMIT: Not established
CARC:NOG~NICIrY: Not listed by NTP, IARC or OSaA
PRIMARY ROOT!S OF ENTRY: Skin, eyes, ingestion
S.lMP~OMs AND E!FEC7s ROUTE 0! E~ERGE~CY AND F=RsT A:D
OF OV::RE:

P~oduct Name: Clearly Cala-Gel~-
Tec Laboratories, Inc.
~
Page 3 of 4
Issue Date: 08/30,/93
.c c ~..c ~..~...~...~ c ~ c..t*~
SZCTIOH V -PERSONAL PROTECTION ~O~~TIOB ~. c
tt...~~ ~ tw..w..~ c.~~
--WHE~ HANDLING Bat:< QUAN7rTIES--
EYE PROTECTION: OSHA approved monogog;les or face shielc.
PROTECTI~IE CLOTHING: Wea~ r'lbber gloves .
impervious boots and clothing.
VENTILATION Gene~al mechanical
RESP!RATORY PROTECT~O~I: Not required in mos~ cond:tions
~o a~loid excessi.~e exposure, wea~
t ., +0. h ' d b t .~ -
room Ven.l..a,-:On S.OU- e sa..ls..ac,-o:-y
-wnE~r USING ?RODUC': ACCORDING TO DIRECT:ONS FOR OSE--
E.fE PROTECTION : Do not apply product in an~ a=o~~~ eyes .
PROTECTIVE CLOTHIYG: None required for nor~al use.
V'E:N'rItA'rION Nor~al room ventilation is satis=actory.
~ESPIRATORY PROTECTION None required for normal use
***.**************~***x*~*~*****************~**.******~¥**~**..************xa~
* * * * * * * ,. .* ~ ,. * :R SECTION VI -STORAGE AND SPECIAL RA2mLI'NG INFOR..~'l'IOK * * * * ~ ,. .~ ¥ ...8 ~
* * * * * .* * * ..,. ..t * * * * * * * * * X'C * .* .* ..k * ,. :C * .t * ~ "' ~ ..* * * ~ .* * * .* ~ * * * ..* * * .* * .* * * * * * * .* * X * x. .
Avoid con~act w:t~ ey~s a~~ mu~ous me~b~ar~es
s -~~~ a -~ OO -~ em - e - a - u -~
~- ...".~..
*****...~ ~.aaa..aa.a.**~~...** **aa.a.~..**..*.ta.;.x *..*~..*.*~~.*..~-
:« .* ...~ ..~ * ~ ~ .1. * .SEc-rIOH VII SPILL OR tEAX RESPONSE L1iFOR.~TION .* * * * * * "'
..*...~.t*.t..~.~~~ a~...~.~ a...~~ ~..~a a.x.~.a..* a ~w.
o~-: C . U"T'~ ON~ I 'f C' S -: 0 -. S ~-~.. S OR ~=.v S .J- ~, : i ... r .' T:',. s ~
.;'.- t'\ .-1... .'t n.. .: : l'\."' .--0 ,. -S v;-' .~- s ;.~...e. .
a-~ a ...':- I. \. 01 0..'-. 1 0 .: .Ja-o- (n. 0 - wa -~.. wc -'.- ~o S -.~ O ~: ,!,.-~
a~d flush I. dc~~ I. sewe= -~. or di~

P~oduct Name: Clearly Cala-Gel~M
Tec Laboratories, In~..
Page 4 of 4
:ssue Date: 08/30/9~
SECTIOH VIII * -PIRE AHD EXPLOSION BAZARD IHFORMATIOH * *.*
~ .* ..-
FLASH POINT {closed cup): not applicable
FLAMMABLE LIMITS: not applicable
(in air, % by volume)
E:{7I~GaISHING MEDIA : not applicabie; non-flammable Mate~ial
VNUSUAL F:RE ~~D EX?LOSION HAZARDS: None
S?ECIAt FIRZ F:GHTING P~OCEDURES: Not ap~l.:cable
** * t..
.:a:a 8.* *&.***.***** ,.*,.*****.**, **, **.'.*.* *.**"'.*.*.*.~*~:«:c4~
* * ,. ,. ...* .,. * :. * *:w ,. :Ra a. *. * SEC"1"IOH' IX -REAC"l'IVI"l"Y 11fFO~.A':ION ~* * ~ :k* =- ." :J:J .* * ,. * .* ,. .c ..
.**..*~*~*,.,.~**.*.*****..*~*..**.*******.~***~.****..*~**$*¥~¥.,.*********¥..*.*.~~
STABIr.ITY: Stable.
INCOM?A!:3:~ITY (MAT~RIALS TO A.JOID) : Nor.e
RAZARDOUS ~ECO~!?OS :7IO~; PRODijC7S : None
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: None
*..*:W*:W~..***:W.*..~*.*.*...*' *.:~.*.**...':1:a..:I:a~~,...* ~*..*,**:tS:a$4..C.~~.
** * *..*.**.. SECTION X -PHYSICAL DATA *.*:W*...*.~*.**~**.« ~~.
*.**.** *..:W*...*...**.**...**.:W**~**...*.*.****...******..*..~..~*.* ~c
A?PEARANCE: Clear, colorless viscous l!quid
ODOR: M.ec::.cinalodor
SOL"JBItI':'Y IY WA':'=.R ( % by weigh t ).: 100%
SPECrFIC GRAVr7Y: 0.97! 25: C
BCILI~G ?OIY7: 2123 F
WE:GH~ P~R GAt~ON:8.3435~igal
VISCOSIT.{ : 17,OCO -40,OCO cps
AUTO IGN:~:ON rEMPERATURE: N,:A
,

~EcnON t. CHEYfIC.,.\L
rnE~-nFICA11ON
INSEcr REPELLENT
CHE~~rO RECORD NU~mER : 333
CCOHS CHEWC.-\L NA.'v1E : Pcrmcthrin
MSDS
INSECT REPELLE."c'T
S y N O N y M S
3-(2.2- D ichlo rocthcn yl )- 7.,2 .dimcth y lcyclopropa
ncc:lrboxytic lcid, (3-phenoX"fphcnyl)mcthyl ester
3-Phenoxybenzyl
( 1 RS )-cis. tr3,ns- 3 -(7.,2 -dichlorovinyl)- 2,2 -dimeth
ylc:'c!opropanec:lrboxylate P~rmethrine
TR.-illE NA."'1E(S) :
Ambush
Ec..iban
Pounc:
SEcnON :.. DESCRIP11ON
APPE.-\...I

MA TERL~S .~o inforrna~ion available.
POTENT1.--\L FOR ACCUMUL~ TION :
Animal studies indicate rapid breakdown and
excretion of this p~throid. Thus, the potential for
accumulation in humans is considered to be low.
SEcnON ~. FIRST .W ~E-\SURES
INRA.L\TION : If symptoms are experienced.
remove source of contamination or move victim to
fresh air. Obtain medical advice immediately.
SKIi'I" CO~lACT : Symptoms of skin contact are
delayed. Therefore, if contact occurs, rem.ove
contaminated clothing, shoes and leather goods
(e.g. watchbands, belts).
Gently blot or brush away exc:ss chemical quickly.
Wash gently and thoroughly with water and
non-abrasive soap. If symptoms occur, obtain
wedical attention immediately. Completely
decontaminate clothing, shoes
and leather goods before reuse, or discard.
EYE CO~lACT : Gently blot or brush away
exc:ss chemical quickly. Immediately flush the
contaminated eye(s) with lukewann, gently
flowing water for 20 minutes, by the clock, holding
the eyelid(s) open. If irritation persists, obtain
medical advice immediately.
INGESTION: Have victim rinse mouth
thoroughly with water. DO NOT lrII"DUCE
VOMmNG. Have victim drink 240 to 300 mL (8
to 10 oz.) of water. If vomiting occurs
naturally, rinse mouth and repeat administration of
water. Obtain medic:11 attention immediately.
FIRST .AJD COMMENTS: Consult a physician
and/or the nearest Poison Control Center for all
exposures except minor instances of inhalation or
skin contact. All first aid procedures should be
periodic:illy reviewed by a physician familiar with
the material and its conditions of use in the
workplace. ~: Other ingredients in perrnethrin
formulations may cause toxic effects and require
specific first aid measures.
NOTE TO PHYSICIAl"iS : Studies with
permethrin showed that topical Vitamin E acetate
(dl-alpha tocopheryl ac:ta.te) reduced or eliminated
the sensations from skin contact. Mephenesin (a
muscle rela.~ant) has been proposed for use in
treatment of pyrethroid poisoning. In testS with ratS
rec:iving lethal doses of the pyrethroids cismethrin
and deltame~hrin. all anim:11s survived when
treated with mephenesin.
rvl~U~
INSECT REPELLE.'iT lA
SEcnON 5. ARE FIGfmNG ~.1,.SURES
FL-\SH POr:-..l : No information available.
Probably cJ.n burn only if strongly heated.
LOWER FL-\.\f~l-\BLE (EXPLOSIVE) U?-IaT
(LFL LEL) : Not available
UPPER FL\.\1~LE (E""

supplier for advice.
SECTION 8. EXPOSURE
MSDS
L~SECT REPELLE~'T
COr-.-rROLS;PERSONAL PROTECTION
B&SPIR..3.. TORY PROTECrtON GulDELINES
:No specific guidelines are available. Contact
manufacturer or supplier for advice. The NIOSH
recommendations for PYRETHRUM may be
applicable. See
CHE~1L~'FO record number 311 (pyrethrins) for
details.
EYE:F ..3..CE PROTECTlON : No specific
requirement, but it is good practice to wear
chemic:1l safety goggles. During pesticide
application, a full-face shield may also be
required to ensure adequate protection.
.SKIN PROTECTlON : No specific requirement,
but it is good practice to prevent skin contact.
During pesticide application, this will require the
use of impervious gloves, overalls, bootS and/or
other resistant protective clothing.
RESIST..3 'iCE OF M.3..TERIALS FOR
~ROTEcrIV"E CLOTHING: No specific
infonnation is available. Contact
manufacturerisupplier for advice. Polyvinyl
alcohol (pV A) provides. good rcsistance to
p:-Tethrins and rclated materials (higher monobasic
carboxylic esters). Consider solvent base when
selecting rcsistant materials for pyrethroid
formulations. NOTE: Resistancc of specific
materials can vary from product to product.
Evaluate resistance under conditions of use and
maintain clothing carefully.
SEcnON 9. PHYSIC.~ .A.J'iD CHEMICAL
PROPERTIES
MELTING POI~-r: 34-35 deg C (pure)
BOILING POI~"T: Very high (approximately 200
deg C at 0.008 mID Hg); probably decomposes on
heating.
REL~TIVE DE.'-i"SrrY (SPEOFIC GRA. V1TY) :
1.19-1.27 at 20 deg C (water = 1)
SOLUBILrrY IN WATER: Practically insoluble
(0.:. mg.'l. at 20 deg C)
SOLUBILrrY li'i OTHER UQtnDS :
Readily soluble in common organic solvcnts such
as alcohols, ac:tone, ether, chloroform, methylene
chloride, xylene: moderately soluble in ethylene
glycol.
1,.PO~R DE~SITY: Not applicable
V.-\POl:R PRESSURE: Very low (3.4 x 10(-7)
P:zge G.J4
--
mm Hg at :?5 deg C)
C.\-(S EnvironmenlDl Restonuion Group
A
SATUR..-\TION VAPOUR CONCE~~TION
: Not applicable
EVAPORATION R.-\TE : Practically zero.
pH V ALUE: Not available
CRITICAL TEMPERA Th"RE: Not applicable
COEFFICIENT OF OIL/WATER
DISTRIBlJ-nON (P .UTITION COEFFICIENI)
: Log P(oct) = 6.5. Also reponed as 3.48.
SEcnON 10. ST.~ILrrY Al~"D REA..crMrY
ST.-\BU..IrY : Stable to heat (more than 2 years at
50 deg C).(:) Relatively stable in
sunlight.(l i) More stable in acid than alkaline
media with optimum stability at about pH 4.(2)
HALA..RDOUS POL Y~RIZ.0'\TION : Does not
ocC'Jr
HALUDOUS DECOMPOSmoJl," PRODUCTS
: None known
INCOMP ATIBILrrY -?-IL.\,TERLA.l.S TO A VOID
: STRONG OXIDIZING AGE:.~lS -May increase
the risk of fire. STRONG BASES -Cause
decomposition of material.
CALCIu1'Y1 ~1TR.A..TE
CORROSIVTIY TO MET.,a.LS : Not corrosive to
aluminum.
ST.~IUTY AND REAcrr'IITIY COMMENTS
:Petmethrin is more stable to sunlight than natural
pyrethrins, but some degradation does occur .
SEcnON 13. DISPOSAL cONSmERATIONS
Pyrethroids are highly toxic to fish. Do not release
to 'W.ater. Disposal by controlled incineration or
seC'Jre landfill may be acceptable. Treat with alkali
(lime) before landfilling. Decontamination of
waste material should only be done by
specially-tr:lined personnel using appropriate
facilities and protec:ive equipment. Incineration
must be C:lIried out in approved fac'"Jities equipped
with adequate emission con~ol devices. Comply
with applicable federal, state and local government
regulations regarding disposal.

I.. £DE~-nFTCA110N ...
MSDS RECORD NUMBER: 668986
PRODUcr ~A.~(S): DEEP WOODS OFF
PU1\rIP SPR.-\ Y
MATERL-\L SAFETY DATA SHEET
\VH1\11IS S~ria1 No: 8 Issued: 1993-04-26
Supersedes: 1993-01-27
PRODUcr IDENnFICA11ON
PRODuCT ~A.\1E: DEEP WOODS OFF! PUMP
SPR..-\Y
PRODUcr USE: HOUSEHOLD INSECT
REPE~~"T
HMIS R.-\T[';O
~-\Lm: 2
FL\.\1~ILrrY: 3
RE.-\CTIv1TY:O
SPECL-\L W.-\R. ~h'lO:
INGREDIE~"T I1'-1"FOR.\1A11ON
WEIGHT o/c CAS INGREDIE..'l"r
25 13..:.-62-3 DIETrlYLTOLU~\1IDE
LD50: 1,950 ~0,'KO (ORAL -RAT)
EXP. UMlTS: NOT ESTABUSHED
15- 40 64-17-5 ETHANOL
LD50: 7 ,060 ~0/'KO (OR.-\L -RAT)
EXP .LIMITS: 1000 PP~I (TL V- TW A ACGIH)
PHYSIC.~ DATA
PHYSIC.-\L STATE: UQt.1D
ODOU&'A?PE.-\R..-\.'lCE: CLEAR,
COLOURLESS LIQUID WITH
CH.-\RAcrERIS11C FLOR.-\L ODOUR
ODOUR THRESHOLD: NOT A V .~LABLE
SPEOFIC OR.-\ VITY: 0.923 CVi.ATER = 1.0)
V ..1.POUR PRESSURE (~fM HO): NOT
AVAlUBLE
V APOt:R DENSITY (.-\IR=1.0): NOT
A V .-\ILIo\B LE
WATER SOLL'BILrrY: DISPERSIBLE
EV.-\POR.-\l1ON R.-\TE: NOTAVAIL.1..BLE
(Bu-rYL ACETATE = 1.0)
BOILING PO~"T (DEG q: 75
FREEZING POil'l"T (DEO C): NOT
A V ..1JLIo\B LE PH: 7 .5
COEF. WATER.:OIL: NOTAV.~L.
FIRE .-1...',"D EXPLOSION 11'-1"FORMA11ON
FL-\SH POI~"T (DEO C): 25 (TCC)
FL~\I~L-\3LE U~fITS: ~OT A V ..1JL-\BLE
Au"TO-IG~mON
APPU C..3.,B LE
TE~IP (DEG C): NOT
1..'1...:JJ.Ju
DEEP WOODS OFF
FL-\.\~l-1.BILrrY CL-\SSIFICA11ON
FL~~LE UQl;lD
E.mNGT..:1SHI'i"G MEDIA: CARBON
D[OXIDE. FOA.\I. DRY CHE.'vfICAL,
" ALCOHOL" FOA..\1.
SPECIAL FIREFIGrmNG PROCEDURES :
N O R. \1AL FIRE FIG HfnIf G P R OCED URE MA Y
BE USED. COOL .A.J.~ USE CAt.mON WHEN
APPROACH1NG CONTAINE.~.
FIRE FIGHTERS SHOULD \VE.~.R SCBA AND
PROTEcrIVE CLOTHING.
E."'

MSDS
INGESTION: DILtJrE WrnIl -2 GLASSES
OF ~LK. SEEK MEDICAL AID.
REACIlVITY DATA
ST.-\BlLITY : STABLE
CONDmONS TO A VOID : E-XCESSIVE HEAT.
INCOMPA1lBIUrY : AVOID PLAS11c,
RUBBER AND OXIDIZERS.
H..:\ZA.,RDOUS DECOMPOSmON PRODUcrS
: ~~ ~"(POSED TO FIRE. PRODUCES
NOR."fAL COMBUS11ON PRODUcrS.
HAZARD O U S P O L YMERIZA -n o N : WILL
NOT OCCUR.
CONDmONS TO A VOID :NOT APPUCABLE
PREVE~-nVE ME.~SURES
STEPS TO BETA1

1.
MATERI.L\L SAFETY D.;\T.-\ SHEET
~S No: 3a6
o R.THO@ DiaziDon PLL'S@ Insect Spray
SOL~
2.
3.
CHE~CAL PRODUCT AND CO1\01P..\NY IDENTIFICATION
Product [denti.;cr: OR'rHO@ DiaziD011 PLUS@ In.scct Spny
Product Dac.."'iploioll: Insecticide
MANUFACTURER:
The SOLARIS Group
0! ~fODsallto CoJmpany
P.O. Box 5008
5a.n R.u::OD., CA 94583-0808
EPA Re;. No.: 239-236"C PI"."; 6019
COMPOSITION/INFORM..\TION Oi"" Il"'iGREDIENTS
Diui:lon, Dieth'! 1- Isc propy lemthylpyrimidinyl- ?h08phorothio&t~
INERT INCRED(E:-;TS
24 HR. EMERGENCY TELEPHONE
NU MB ERS :
Emerg~ncy Phon~ 800-454-2333
wt.%
25
-i4.9IJ
CAS R~try #
333-41-5
~Inert IngrcdieQ~" is ~ terIU df:rtnC(} by the U.S. En\.ironm~nt.;;.1 ?rotectiol\ Ag~ncy under the f~ucr.,j
lnaec:icide. Fungicide, and Rodenticide Act (10 crR 158.1531. It refers !.0 &ny subltuce, of.her thar
&11 a-ctive in,redient, whic.'1 is iDtentioDa1ly added 1.0 :\ pesticidc product. Some inert. ingr~ients ma)
be hazard~ chemicals, u defined by the Federal OSHA Hazard Commlmic.atioD. St.anda.rd (29 Cf~.
1910.1200). The ha:a:d& 3SS.,")\:iat.ed with these inert illgredienls have beetl inclu'led in thi5 document.
H..\ZARDS mENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE:
Light OIrnb~r liquid
I~iMED(,\7E CONCERNS:
-CAUSr:S ~ODER.~r:: EY~: lNJUa.y
-HAR:..lfUt IF S"v"ALLO\VED. I:"lI(ALED OR AASOHBEO THROtGa THE SK1'l
-I\VOID BREATIJ1NG SPR.r\'{ MIS'f
-DO NOT GET IN E1'ES. ON SKIN, OR ON Ct.OTIll:'iG
-COMBUSTIBLE
-KEEP OUT OF REACH OF C1IILDRE~
POTE:-lTIAL HEALTH EFFECTS
p-c-. 1 of ,
DATE PRE?\RED: IJT/"le/t99$
EYES:
The unc.!jl:J~d ?roduct is :lloderately irr:tating to ~ht! eyes. Eye contact. :n!.y include discomfort,
te&:ing, swellin" ~dD.~.. and Dlu::ed vision. S~ Tc.xiccicgica.l Infcr:tlati~n, ~ttion 11.
SOLA-oO-OO15.02

1 S
MSDS ~: 3&96
ORTHO@ DitlzinoD PLUS@ Insect Spray
SKIN:
The undilu~d produc~ is considc:red 3. moderat.t skin ir.;l.allt.l.hp;rtfore contact with lht: skin can
~&QIe prolon&ed (days) injury to the' affected area. The dCgTee o(injury win depend on the amount
of ma.l.cria.l that beL1 on the skin a.l1d ~h.e speed and lhoroughncss of thr. first aid treatment. Skin
iml.alion :::ay includr. redn88, itching ~d sweilil1'. Thit sub.~an~ is considered slightly toxic
to internal Or&ans if :lbsorbed lhroQ&h the skin. Sr.e Toxicolo&ical IDro~tioD., sedio[l 11.
L"iG~TlON:
This ,ubstaJlce :s slightly toxic to internaJ orxans if Jwallcwed. The de~ of injury win depend
on ~he &n'.cun~ absorbed from the gut. Because of lne row viscosity of this 3ubsta.nce, it can
direc..!y e:tt~ :he lungs ifit i. swa11ow~d (thi., it ~a1led aapira.ticn). Thia all oct'Jr dur.inl the Kt
or 5w&ilowin~ or when vomiting the ~u'0&~nce. Qncc in tht: lungs, the substance is very difficult
to rc~ove md ,=an C3U.~ !~V~ injury to the lun~ and de&Lh. Read the Taxicologicallnformation
secLion (11) of ~hia documc~~ for more information.
I:-t"HALATIO~:
Breathing the V3por may be irritating to lhe ~piral.0ry tract. If inhaled. this Iubat.&nce i!
conaidc:e.i ?rsc..~cally D.on-taxic ~o int:rna.l org3.11S. ~~d ..ne Toxicolo,ical Iarorma.lioa 3ection
(11) ,Jf t1iis document Cor mo~ in£orma.ticn.
TARGET ORGA:.{S:
DiaziDon is !."1 iAhibitor or ..bc cholin~tl:ra5e ~1U'lme, round in nervoU:i tissue. red blood celts, a.nci
plasma..
COM)tENTS HEALTH:
Depending upon the l"..Xtenl. &!\d dqr~ of I)vC!exposure LO tobe produd, signs 3.nd symptoms o .
cholincste~ase inhibition I:an result. r.,Uo".ing cither inge3tion, .,kin contact or innalation ~;
of e.xpOl1.l:e. Signs and symptoms or cholil1csL~aae inhibition C4D also ~ult from cither acut('
(one time), sub chronic (repealed short-term) and chronic {daily liie-time) ov~rexpos11re to th(!
product.
Signs and sYI:lPtoms or ~olinesterase inhibittcn usually occur wi,hin 12 !lours f'ollowing over.
expOSI1~. These effects may include. but may I1oL be limited to, headache. dh%incs. ~aknes,
naU5e&, vomi\i:1g, diarrhea. CQnstric:ion of :he ?upil or the eye, blurred or dark yiaion, exCe38iVI:
salivation or na.sal discharge, prorux sweaLing ud abdominal cramps.lDcontinence, unconscious.
neIl. convulsions and bre3.lhing diffic'Jlties ue indicative of ~yete poi~ning. In Wltreatcd 3eVU':
poiscDing. death i3 due to ~plr~tory rai.lurl: or cardiac urest.
This ?roJuct llsoconLains 3. ppctroleum JistillaLe. Dcpi'nding upon the de~t~ or .'verexposure, th ~
sysumic tcxiC1ty of Lhe prcduct may OC or I~ concern than the potential dimcal complic~ion.s
~ha.t ::an ~esult from JSpira.tion of the petroleum dislilla.Lc: into the lunp if tbc ~rod\lct is either
~1~ or vomited.
c- % 01 )
-DATE PREPARED: 01/~/l~

4.
5.
FIRST A.1D MEASu~S
MSDS No: 389!)
OR.THO@ Diaz.inon PLUS@ rn.ect Spray
EYES:
flush ey~ :mmedi&t~ly with fresh water for ~ \ei\St I.) Inil\ul.es whi1~ holdin, the eyelids open.
Remove con~t len3e3 if worn. Call" physician.
SKI:of:
~ove contami.-l.tcd clol.hin&. W~h SkUI thorou&hly wil.h soa.p and wa.tc:. See '1 doctor ir i1ny
si&DS or sym?torr..1 described in this doc:um~nt OC:C'Jr. Dixard CQIlLaminatcd noD-w&terproof sh~
aud boot.l. Wa.sh CQntaminl\Led dothin&.
I~GESTIO.'i" :
If sw:illowed, immediately tetCi'honc a poison ~ontrol center. emerg~ncy '.rc&tmel1t center or a.
ph)'Stca.n for advic~. DO ~OT make person ..onlit ulll~ dircctcrl to do SO by meciicaJ p~onDel.
[!mdicai ldvice cannot b~ obtained. then imnl!dia1ei"! '.6ke person a.nd product :ODtainer, with
l&bei. tQ an em~:~ency ~atmeQ.t center.
I~HALATIO.'{:
If mpira.tory discomfort or irritaticn oe~urs. mOVf! lhe pe~n to r~h m.
d~omfor~ or irri~ion ecntinues.
See a. doctor n'
NOTES TO PHYSIC1..\N:
This material conta.ins 3.l:holine5terase inhibitor. &feasut\!ment of blood cholinl!Ste:a.se activit:.
lI1&y be useful in monitoring e.xp~ure. If signs or dtolil;atc:;I5e inhibition ~ppea.r. atropino!
sulfate is 3ntidota.l. 2-PA~ (PR.O'rOP..\~{) is a~ anr.idotal ud may be used in :onjuncticlL
with Itropine but 3hould not be UIc:d alone. T11j:; m:lteri.I conta-ins light h:-.droca.rbon liquid an.1
&II ;l5pir.ltion hazard may exist.
ADDmONAL INFOR.\fATIO:-1:
In case of medical emcrgencies involving this j)rod~tt, tall day or night. (800} 45i-2022 Olt
(800) 454-2333.
FIRE FIGHTL.~G MEASURES
Fl~bpoin~ a.nd Method: 15::0 F TAG CC
E.'tTl~C{;ISHl.\"G MEDIA:
CO'Z. dry chemical. roam .\nd water t'o!-
p-C.. 30( ,
HAZARDOUS COMBUSTION PRODUCTS:
Norma1.:ombu:Jtion forms carbon dioxide. watt;r vapor alld nlay produce oxides of sulfur I nittOg~n
and phospQoroua. Incomplete :cmbasticn can produce c3.lbon mon~ide.
OATE PREPARED: 0112811995

6.
O~HO@ DiAzinon PLUS~ Inaect Spray
nRE FIGHTI~G PROCEDURES:
Liquid evaporaLes 8Ad forms va.pot (rl&m~) \vhici1 C:1Q caLcb fire and burn with explosive "'ol~nce.
InyWble vapor spreads euily and can be set 011 fire by many ~urc=s such as pi)o~ lipt3, ~d~
equipm!Dt, and elecuica1 motolS and .iwitches. Fire hazard is greaLer as liquid ~mperaLure rises
a.bovl'. 85 f .
Products of combustiol1 frorn fi~ involving thi.l :n&Le:ial :nay be taxic. Avoid breathin& smoke
and mi"t8. Avoid per1QlU1Cl ~d equipment conUct with rallol1t a.nd runoff. .\fiaimize the amount
of water used for fire fighting. Do DOt ~nter ~7 enclosed area without run protectiw equipment,
including self-