MSDS_8172_SCHWEGO® ANTIHAUT 8172_EN - Gerstaecker.at

Material Safety Data Sheet 

according to Regulation (EC) No. 1907/2006 

Product name : SCHWEGO ® ANTIHAUT 8172 

Revision : 19.07.2011 Version (Revision) : 2.0.0 (1.0.1) 

Print date : 24.08.2011 Supersedes date : 19.07.2011 

1. Identification of the substance/mixture and of the company/undertaking 

1.1 Product identifier 

SCHWEGO ® ANTIHAUT 8172 (8172) 

1.2 Relevant identified uses of the substance or mixture and uses advised against 

Printing chemical for industrial and/or professional use 

1.3 Details of the supplier of the safety data sheet 

Manufacturer/Supplier 

Bernd Schwegmann GmbH & Co. KG 

Street/P.O.Box 

Wernher-von-Braun-Str. 14 

Country code/Postal code/Town/City 

D-53501 Grafschaft-Gelsdorf 

Telephone / Telefax 

+49 22 25 / 92 26-0 / +49 22 25 / 92 26-33 

Contact person Material Safety Data Sheet 

E-Mail: MSDS@SchwegmannNet.de 

1.4 Emergency telephone number 

+49 61 31 / 19 24 0 (Poison Control Center Mainz, 24 h in English and German) 

2. Hazards identification 

2.1 Classification of the substance or mixture 

Directive 67/548/EEC or 1999/45/EC 

Extremely flammable. · Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · 

Irritating to skin. · Vapours may cause drowsiness and dizziness. 

F+ ; R 12 · N ; R 51/53 · Xi ; R 38 · R 67 

2.2 Label elements 

Directive 67/548/EEC or 1999/45/EC 

Danger symbol and danger designation 

F+ ; Extremely flammable 

Xi ; Irritant 

N ; Dangerous for the environment 

R-phrases 

12 Extremely flammable. 

51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

38 Irritating to skin. 

67 Vapours may cause drowsiness and dizziness. 

S-phrases 

51 Use only in well-ventilated areas. 

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 

16 Keep away from sources of ignition - No smoking. 

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( EN / D )






23 Do not breathe gas/fumes/vapour/spray 

Special designation for certain mixtures 

56 Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50 °C. 

57 Do not pierce or burn, even after use. 

58 Do not spray on a naked flame or any incandescent material. 

2.3 Other hazards 

According to our data the mixture does not meet the criteria for PBT or vPvB. 

2.4 Additional information 

Danger of bursting and explosion by pressure increase. 

3. Composition/information on ingredients 

3.2 Mixtures 

Chemical characterization 

Aerosol tin (500 mL) with compressed hydrocarbon gas and a solution of an active material 

Hazardous components 

PROPANE/BUTANE HYDROCARBON MIXTURE ; EC-No. : 270-990-9; CAS-No. : 68512-91-4 

Percentage : 35 - 50 % 

Classification 67/548/EEC : F+ ; R12 

NAPHTHA (PETROLEUM C6 - C8), HYDROTREATED LIGHT (BENZENE < 0,1 %) ; Registration number (EC) : 01-2119475514- 

35 ; EC-No. : 921-024-6; CAS-No. : 64742-49-0 


Classification 67/548/EEC : F ; R11 N ; R51/53 Xn ; R65 Xi ; R38 R67 

Classification 1272/2008 (GHS) : Flam. Liq. 2 ; H225 Asp. Tox. 1 ; H304 Skin Irrit. 2 ; H315 STOT SE 3 ; H336 

Aquatic Chronic 2 ; H411 

N-HEXANE ; EC-No. : 203-777-6; CAS-No. : 110-54-3 


Classification 67/548/EEC : F ; R11 Repr. Cat.3 ; R62 N ; R51/53 Xn ; R48/20 Xn ; R65 Xi ; R38 R67 

Classification 1272/2008 (GHS) : Flam. Liq. 2 ; H225 Asp. Tox. 1 ; H304 Repr. 2 ; H361.F2D0 STOT RE 2 ; H373 Skin 

Irrit. 2 ; H315 STOT SE 3 ; H336 Aquatic Chronic 2 ; H411 

For the wording of the listed risk phrases refer to section 16. 

Additional information 

Materials that are listed in the so-called "candidate list of substances of very high concern (SVHC) for authorisation", issued by 

the ECHA, are not intentionally any part of this product. It is therefore not to be expected that such materials are present in 

quantities > = 0.1% in the product. 

4. First-aid measures 

4.1 Description of first aid measures 

General: 

Immediately remove all contaminated clothing. 

In all cases of doubt, or when symptoms persist, seek medical attention. 

After inhalation: 

Remove concerned person out of danger area. 

Let in fresh air. 

Call a doctor, should the air passages be affected. 

After skin contact: 

Wash away with soap and water and rinse. 

After eye contact: 

Remove contact lenses, keep eyelids open. Flush with plenty of water (10 - 15 min.). 

Protect unaffected eye. 

After ingestion: 

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After first aid treatment immediately seek medical advice. 

4.2 Most important symptoms and effects, both acute and delayed 

None known. 

4.3 Indication of any immediate medical attention and special treatment needed 

No data available. 

5. Fire-fighting measures 

5.1 Extinguishing media 

Suitable extinguishing media 

Foam, CO2, powder extinguisher. 

Water haze. Water spray jet. 

Unsuitable extinguishing media 

Waterjet. 

5.2 Special hazards arising from the substance or mixture 

In case of fire toxic gases may be formed: Carbon monoxide. 

5.3 Advice for firefighters 

When extinguishing fires, use breathing apparatus with an independent source of air. 

5.4 Additional information 

Cool endangered containers with water in case of fire. 

Under extreme heating in closed containers decomposition Pressure formation and bursting of containers possible. 

Adapt extinguishing measures to suit the environment. 

6. Accidental release measures 

6.1 Personal precautions, protective equipment and emergency procedures 

Advice for non-emergency personnel: Avoid substance contact. Do not breathe vapours, aerosols. Ensure adequate ventilation. 

Evacuate the danger area, observe emergency procedures, consult an expert. 

Advice for emergency responders: Protective equipment see section 8. 

6.2 Environmental precautions 

Do not allow discharge into bodies of water, the soil or the sewage system. 

6.3 Methods and material for containment and cleaning up 

Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and 

place in container for disposal according to local regulations (see section 13). Remove according to regulations. 

6.4 Reference to other sections 

Refer to protective measures listed in sections 7 and 8. 

7. Handling and storage 

7.1 Precautions for safe handling 

Information for safe handling 

Normal precautions taken when handling chemicals should be observed. 

Do not eat or drink during work - no smoking. 

Wash hands after use. 

Information about protection against explosions and fires 

Keep away from ignition sources and provide for good ventilation. 

Ignition group : 

Flammable class : 

T2 

C 

7.2 Conditions for safe storage, including any incompatibilities 

Requirements to be met by storerooms and containers 

Prevent heating about 50 ° C. Keep German Technical Rule for Hazardous Substances (TRGS) 510 "Storage of hazardous 

Page : 3 / 9 







substances in non-stationary containers". 

Always keep in containers of same material as the original one. See also instructions on the label. Avoid heating and direct 

sunlight. 

Information about separation of incompatible products 

Keep away from strong oxidising agents. 

Further information about storage conditions 

Storage class (LGK) : 

2B 

7.3 Specific end use(s) 

Aerosol products for offset printing 

For further information refer to our technical data sheet. 

8. Exposure controls/personal protection 

8.1 Control parameters 

NAPHTHA (PETROLEUM C6 - C8), HYDROTREATED LIGHT (BENZENE < 0,1 %) ; CAS-No. : 64742-49-0 

Specification : TRGS 900 - maximum limit in the atmosphere at the workplace ( D ) 

Parameter : 

(RCP-Method) 

Value : 1500 mg/m 3 

Category : 

2(II) 

Remarks : 

AGS 

Version date : 27.12.2007 

N-HEXANE ; CAS-No. : 110-54-3 


Value : 50 ppm / 180 mg/m 3 


8(II) 

Remarks : 

Y 


Specification : TRGS 903 - biological maximum limits ( D ) 

Parameter : 

2,5-Hexandione / urine / end of exposure or shift 

Value : 

5 mg/l 


CALCULATED EXPOSURE VALUE FOR THE MENITONED MIXTURE OF HYDRO CARBONS ACCORDING TO GERMAN 

REGULATORIES 


Parameter : 

(RCP-Method) 

Value : 1400 mg/m 3 


2(II) 

Remarks : 

AGS 


8.2 Exposure controls 

Recommended analysis methods for workplace readings: See the series of publications by the German Federal Institute for 

Occupational Safety and Medicine (Bundesanstalt für Arbeitsschutz und Arbeitsmedizin - BAuA) 1 

Personal protective equipment 

Respiratory protection 

Provide for good ventilation. Personal breathing equipment generally not required. With insufficient ventilation, to strong 

unpleasant odours or when aerosols or vapour are present, use an EN 141 certified breathing apparatus. Filter: Filter model 

A1. Can be used up to a maximum concentration of 1000 ppm. 

Hand protection 

Avoid contact with the skin and mouth. 

Chemical-resistent protective gloves according EN 374 must be worn. 

Protective gloves (nitril rubber). 

Thick (mm): 0,2 

Penetration time (s): > 3600 (LEVEL 2) (Literature value) 

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Eye protection 

Use safety goggles with side protection, which comply with EN 166:2001. 

Environmental precautions 

Refer to protective measures listed in section 6. 

9. Physical and chemical properties 

9.1 Information on basic physical and chemical properties 

Image 

Form : 

Colour : 

Odour : 

Relevant safety data 

Aerosol tin (500 mL) with compressed hydrocarbon gas and a solution of an active material 

Colourless. 

Characteristic. 

Melting point / range : no data available literature 

Boiling point / range : ( 1013 hPa ) < -10 °C literature 

Flash point : ca. -80 °C ISO 1523 

Ignition temperature : ca. 365 °C DIN 51794 

Lower explosion limit : 1,5 % b.v. literature 

Upper explosion limit : 10,9 % b.v. literature 

Vapour pressure: ( 20 °C ) 1200 - 7500 mbar DIN EN 12 

Density : ( 20 °C ) 0,5 - 0,58 g/cm 3 DIN EN ISO 2811-1 

Solubility in water : ( 20 °C ) < 0 g/l (calculated) 

Content VOC (EU): 44,5 % (calculated) 

9.2 Other information 

Determined internal pressure: 4,8 bar / 50° C 

500 mL = 0,334 kg 

The VOC concentration was calculated using the difference method according to ISO 11890-1. 

The physical specifications are approximate values and refer to the used safety relevant component (aerosol). 

Additional physico-chemical data is unavailable. 

10. Stability and reactivity 

10.1 Reactivity 

There are no data available on the product itself. 

10.2 Chemical stability 

The product is chemically stable under normal ambient conditions (20° C room temperature). 

10.3 Possibility of hazardous reactions 


10.4 Conditions to avoid 

Avoid heating over 50°C. 

Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been 

excluded. 

10.5 Incompatible materials 

Reaction with oxidizing agents possible. 

10.6 Hazardous decomposition products 

Flammable gases / vapours. 

Certain vapours form explosive mixtures with air. 

11. Toxicological information 

11.1 Information on toxicological effects 

Acute toxicity, skin irritation, mucous membrane irritation, genetic altering potential and skin sensitivity will be assessed by the 

Page : 5 / 9 







manufacturer based on the available component data. 

11.2 Experience on practice 

No data available. 

11.3 Additional toxicological information 

The product was classified in toxicological terms on the basis of the results of the calculation procedure outlined within General 

Directive on Preparations (1999/45/EC). 

12. Ecological information 

12.1 Toxicity 


12.2 Persistence and degradability 


12.3 Bioaccumulative potential 


12.4 Mobility in soil 


12.5 Results of PBT and vPvB assessment 

According to our data the product does not contain PBT-substances. 

12.6 Other adverse effects 


13. Disposal considerations 

13.1 Waste treatment methods 

In accordance with local official regulations. Remove in accordance with regulations. 

Recommendation 

Precise waste material code to be agreed upon with waste disposer. 

Waste key 

EAK-Code: 16 05 04 

Contaminated packaging 

Emptied botteles: EAV-Code: 15 01 10 

14. Transport information 

14.1 UN number 

1950 

14.2 UN proper shipping name 

ADR/RID 

AEROSOLS 

IMDG-Code 

AEROSOLS 

ICAO-TI / IATA-DGR 

AEROSOLS, FLAMMABLE 

14.3 Transport hazard class(es) 

ADR/RID 

Transport hazard class(es) 2 

Classification-Code : 

5F 

Tunnel restriction code : D 

Special provisions : LQ 2 

Label : 

2.1 / N 

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IMDG-Code 

Transport hazard class(es) 2.1 

EmS number : 

F-D / S-U 

Special provisions : 

LQ 1 l 

Label : 

2.1 / N 

ICAO-TI / IATA-DGR 

Transport hazard class(es) 2.1 

Label : 2.1 

14.4 Packing group 

ADR/RID : --- 

IMDG-Code : 

ICAO-TI / IATA-DGR : 

14.5 Environmental hazards 

ADR/RID : N 

IMDG-Code : P 

ICAO-TI / IATA-DGR : N 

14.6 Special precautions for user 

Refer to protective measures listed in sections 7 and 8. 

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 

Sold in packaging approved or suitable for transport. 

14.8 Remarks 

To 14.3: Label "N": The special marking for packagings with contents of > 5 L the "environmentally hazardous substance mark" 

(new marine pollutant mark) is required. 

To 14.5: N = ENVIRONMENTALLY HAZARDOUS / P = MARINE POLLUTANT 

15. Regulatory information 

Safety, health and environmental regulations/legislation specific for the substance or 

15.1 

mixture 

National regulatory information 

Water pollution classification 

Class : 1 according VwVwS 

15.2 Chemical safety assessment 

A chemical safety assessment has not been carried out for this product (mixture). 

16. Other information 

Literature: 

1 http://www.baua.de 

2 http://www.arbeitssicherheit.de 

The details in this material safety data sheet satisfy national and EC legislation. 

Information relating to the classification and labelling under Regulation (EC) No 

1272/2008 (GHS) 

Classification 

Extremely flammable aerosol. · Causes skin irritation. · May cause drowsiness or dizziness. · Toxic to aquatic life with long 

lasting effects. 

Aquatic Chronic 2 ; H411 · Skin Irrit. 2 ; H315 · Flam. Aerosol 1 ; H222 · STOT SE 3 ; H336 

Label elements 

Hazard pictograms 

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Flame (GHS02) · Environment (GHS09) · Exclamation mark (GHS07) 

Signal word 

Danger 

Hazard statements 

H222 

Extremely flammable aerosol. 

H315 

Causes skin irritation. 

H336 

May cause drowsiness or dizziness. 

H411 

Toxic to aquatic life with long lasting effects. 

Precautionary statements 

P210 

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. 

P211 

Do not spray on an open flame or other ignition source. 

P312 

Call a POISON CENTER or doctor/physician if you feel unwell. 

P332/313 If skin irritation occurs: Get medical advice/attention. 

P403/233 Store in a well-ventilated place. Keep container tightly closed. 

P501 

Dispose of contents/container: Remove in accordance with local official regulations. 

Special rules for supplemental label elements for certain mixtures 

O210 

Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50 °C. 

Do not pierce or burn, even after use. 

O211 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - 

No smoking. 

Further information 

Key or legend to abbreviations and acronyms used in the safety data sheet: 

TRGS: Technical Rules of Hazardous Substances 

RCP: Reciprocal calculation-based procedure 

VOC: Volatile Organic Compounds 

ISO: International Standards Organization 

EN: European Standard 

LGK: German storage class 

ADR: Accord européen relatif au transport international des marchandises Dangereuses par Route (European Agreement 

concerning the International Carriage of Dangerous Goods by Road) 

RID: Règlement concernant le transport international ferroviaire des marchandises dangereuses (Regulations concerning the 

International Carriage of Dangerous Goods by Rail) 

IMDG-Code: International Maritime Code for Dangerous Goods 

GGVSee: German Carriage of Dangerous Goods by Sea Ordinance 

GGVSEB: German Carriage of Dangerous Goods b road, rail and inland waterways 

ICAO-TI: International Civil Aviation Organization-Technical Instructions 

IATA-DGR: International Air Transport Association-Dangerous Goods Regulations 

WGK: German Water pollution classification 

VbF: German Ordinance on Flammable Liquids 

BetrSichV: German Ordinance on Industrial Safety and Health 

GefStoffV: German Hazardous Substances Ordinance 

PBT: Persistent, Bioaccumulative and Toxic 

vPvB: very Persistent, very Bioaccumulative 

CAS: Chemical Abstracts Service 

VwVwS: German Administrative Regulation on the Classification of Substances hazardous to waters into Water Hazard Classes 

EG/EU: European Union 

UN: United Nations 

Relevant changes 

02. Hazards identification · 02.2 S-phrases · 03. Composition/information on ingredients · 04. First-aid measures · 06. 

Accidental release measures · 07. Handling and storage · 08.1 Control parameters · 09. Physical and chemical properties · 10. 

Stability and reactivity · 11. Toxicological information · 13. Disposal considerations · 14. Transport information · 15. Regulatory 

information · 16. Other information 

R-Phrases of components 

11 Highly flammable. 

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12 Extremely flammable. 

38 Irritating to skin. 

48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. 

51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

62 Possible risk of impaired fertility. 

65 Harmful: may cause lung damage if swallowed. 

67 Vapours may cause drowsiness and dizziness. 

GHS Hazard statements of components 

H222 

Extremely flammable aerosol. 

H225 

Highly flammable liquid and vapour. 

H304 

May be fatal if swallowed and enters airways. 

H315 

Causes skin irritation. 

H336 

May cause drowsiness or dizziness. 

H361.F2D0 

Suspected of damaging fertility. 

H373 

May cause damage to organs through prolonged or repeated exposure. 

H411 

Toxic to aquatic life with long lasting effects. 

Contact 

Dipl.-Chem. (FH) Gabriele Janssen · Tel. +49 (0) 22 25 / 92 26-12, Fax -48 

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and 

shall not establish a legally valid contractual relationship. 

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MSDS_8172_SCHWEGO® ANTIHAUT 8172_EN - Gerstaecker.at

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