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<strong>Food</strong><br />

Abbreviation: <strong>Food</strong><br />

Print: ISSN 1749-7140<br />

Frequency and Peer status: Biannual, Peer reviewed<br />

Scope and target readership: <strong>Food</strong> accepts original papers that apply, at the molecular and microstructural level, to science, engineering,<br />

technology, biochemistry, engineering, practical and applied, to further the improvement of human nutrition. Pure research aimed at<br />

improving technical processes, through raw material processing to food, novel processing methods, automation, quality control and<br />

assurance, microbiological safety issues, advances in preservation and packaging technologies and sensory analysis in order to increase<br />

consumer acceptance and satisfaction are also welcome contributions. Papers may also include aspects on physical properties, quality<br />

assurance, safety, storage, distribution, marketing and use.<br />

<strong>Food</strong> is designed for professional nutritionists and dieticians, researchers, scholars and regulatory bodies.<br />

Some of the detailed topics in <strong>Food</strong> may include, among others:<br />

1) Agrochemical effects on foods;<br />

2) Chemistry, analysis, methodology and analysis (development and evaluation, novel techniques, automation or on-line procedures for process<br />

control, methods for food adulterants, aspects of quality assurance including the preparation and characterization of reference materials);<br />

3) Economic and regulatory policies, their effects on safety and quality assessment, processing and preservation;<br />

4) Manufacture, storage and marketing;<br />

5) Measurement of micronutrients, macronutrients, additives and contaminants in foodstuffs and biological samples;<br />

6) Microbiology: novel methods of detecting microorganisms in foods (sensory, nutritional and physiological aspects); genetics and<br />

biochemistry of microorganisms that are either used to make foods or that represent safety problems;<br />

7) Pharmacological properties of ingredients (emphasizing content of bioactive ingredients);<br />

8) Physico-chemical properties or changes to products that result in longer preservation, applied to transportation and shelf-life;<br />

9) Preservatives, packaging systems, potential hazards of new formulations;<br />

10) Processing, stability and stabilization, improvement in quality and properties;<br />

11) Regulation of growth and toxin production in both model systems and complex food substrates;<br />

12) Structural changes in molecules during processing and storage;<br />

13) Toxicology and effects on specific organ systems, immune functions, carcinogenesis and teratogenesis;<br />

Although not explicit in the title, research pertaining to drinks and beverages will also be accepted.<br />

Editor-in-Chief<br />

Jaime A. Teixeira da Silva, Kagawa University, Japan<br />

Technical Editor<br />

Kasumi Shima, Japan<br />

Statistics Advisor<br />

Marcin Kozak, Warsaw University of Life <strong>Science</strong>s, Poland<br />

Editorial Board and Advisory Panels (Listed alphabetically)<br />

Emmanuel Ohene Afoakwa, University of Ghana, Ghana<br />

Dulce Antunes, University of Algarve, Portugal<br />

Noureddine Benkeblia, The University of the West Indies, Jamaica<br />

Maira Bes-Rastrollo, University of Navarra, Spain<br />

Pedro Bouchon, Pontificia Universidad Católica de Chile, Chile<br />

Sashi Kanta Dash, Orissa University of Agriculture & Technology,<br />

India<br />

Maria Grazia D'Egidio, Research Institute for Cereal Cultivation,<br />

Italy<br />

Moutairou Egounlety, Université d'Abomey-Calavi, Benin<br />

Fatma Mohy El-Din, Purdue University, USA<br />

Hany A. El-Shemy, Southern Illinois University at Carbondale, USA<br />

Manuel Fernandes-Ferreira, Universidade do Minho, Portugal<br />

Robert D. Hancock, Scottish Crop Research Institute, UK<br />

Parigi Ramesh Kumar, Central <strong>Food</strong> Technological Research Institute,<br />

India<br />

Alberto Edel León, Universidad Nacional de Cordoba, Argentina<br />

Xinxian Li, Aohata Corp., Japan<br />

Sean Liu, Rutgers, The State University of New Jersey, USA<br />

Tezira A. Lore, International Livestock Research Institute, Kenya<br />

Barakat S. M. Mahmoud, Mississippi State University, USA<br />

Silvia Valtueña Martínez, European <strong>Food</strong> Safety Authority, Italy<br />

Elena Palacios Mechetnov, CIBNOR, Mexico<br />

Hari Niwas Mishra, Indian Institute of Technology Kharagpur, India<br />

Takahiro Noda, National Agricultural Research Center for Hokkaido<br />

Region, Japan<br />

Zuleat Millicent Ofuya, University of Port Harcourt, Nigeria<br />

Philippa C. Ojimelukwe, Michael Okpara University of Agriculture,<br />

Nigeria<br />

P. Ponmurugan, K. S. Rangasamy College of Technology, India<br />

Jamuna Prakash, University of Mysore, India<br />

Sudip K. Rakshit, Asian Institute of Technology, Thailand<br />

Chandi Charan Rath, North Orissa University, India<br />

Alberto Ritieni, University of Naples Federico II, Italy<br />

Sabuj Sahoo, Utkal University, India<br />

Jürgen Schrezenmeir, Federal Research Centre for Nutrition and <strong>Food</strong>,<br />

Germany<br />

Perumal Siddhuraju, Bharathiar University, India<br />

Mike Sissons, Tamworth Agricultural Institute, Australia<br />

Iryna Smetanska, Institute for Vegetable and Ornamental Crops,<br />

Germany<br />

Klára Szentmihályi, Hungarian Academy of <strong>Science</strong>s, Hungary<br />

Rong Tsao, Agriculture & Agri-<strong>Food</strong> Canada, Canada<br />

Daniel Valero, University Miguel Hernandez, Spain<br />

Supayang P. Voravuthikunchai, Prince of Songkla University,<br />

Thailand<br />

Anand K. Yadav, Fort Valley State University, USA<br />

Nigel Yee, Unitec, New Zealand<br />

Lina Yonekura, National <strong>Food</strong> and Agricultural Research<br />

Organization, Japan


<strong>Global</strong> <strong>Science</strong> <strong>Books</strong>, Ltd.<br />

Editorial Office<br />

Miki cho Post Office, Kagawa ken, Kita gun<br />

Miki cho, Ikenobe 3011-2, P.O. Box 7<br />

761-0799, Japan<br />

®<br />

Head Office: Isleworth, United Kingdom<br />

Accounting: Lagos, Portugal<br />

GSB homepage: www.globalsciencebooks.info<br />

Journals web-page: http://www.globalsciencebooks.info/Journals/GSBJournals.html<br />

FOOD web-page: http://www.globalsciencebooks.info/Journals/<strong>Food</strong>.html<br />

GSB Japan web-page: http://www17.plala.or.jp/gsbjapan<br />

GSB is a trademark of <strong>Global</strong> <strong>Science</strong> <strong>Books</strong>, Ltd.<br />

<strong>Food</strong> ©2009 <strong>Global</strong> <strong>Science</strong> <strong>Books</strong>, Ltd.<br />

All rights reserved. No parts of this journal may be reproduced, stored in a retrieval system or transmitted in any form or by<br />

any means, electronic, mechanical, photocopying, microfilming, recording, or otherwise without written permission from<br />

<strong>Global</strong> <strong>Science</strong> <strong>Books</strong>, Ltd.<br />

For additional copies, photocopies, bulk orders, or copyright permissions, please refer requests in writing to the above<br />

address, or apply online.<br />

Guest Editors<br />

Dr. Nigel Yee<br />

Prof. William T. Bussell<br />

Unitec New Zealand<br />

In co-operation with<br />

Unitec New Zealand<br />

Cover photos: Top two rows: Structures of hydroxycinnamic acids (top row) and hydroxybenzoic acids (bottom row) found<br />

in potato peels (Schieber and Saldaña, pp 23-29). Bottom, left: The ratio of OSWV peak current for electrodes modified<br />

with receptor 1(A), receptor 2 (B) and receptor 3 (C) in the presence of different concentrations of AAc (I p ) to that in the<br />

absence of AAc (I p,0 ) as a function of the AAc concentration; Bottom, right: Corey-Pauling-Koltun atomic model of<br />

complex that forms between tetralactam and acrylate (Krajewska et al., pp 113-120).<br />

Disclaimers: All comments, conclusions, opinions, and recommendations are those of the author(s), and do not necessarily<br />

reflect the views of the publisher, or the Editor(s). GSB does not specifically endorse any product mentioned in any<br />

manuscript, and accepts product descriptions and details to be an integral part of the scientific content.<br />

Printed in Japan on acid-free paper.<br />

Published: June, 2009.


The Guest Editors<br />

Dr. Nigel Yee. I graduated B-Tech (Hon) with a major in Engineering and Automation in<br />

1995, and was awarded M-Tech (Hon) in 1996 from Massey University, New Zealand. I<br />

then commenced employment with Casa Herrera Inc. in Los Angeles as an Engineer<br />

designing production lines for snack foods based on potato, corn and wheat. In mid 1998 I<br />

returned to New Zealand and completed a PhD in 2004, in Electrical and Electronic<br />

Engineering at The University of Auckland, New Zealand, focusing on measurement of<br />

moisture levels in potato chips using near infrared electromagnetic spectrum. I have<br />

previously held the position as Honorary Research Fellow of the Faculty of Engineering,<br />

The University of Auckland and I am currently a member of Faculty at Unitec, Institute of<br />

Technology New Zealand.<br />

Prof. William T. Bussell. I graduated BSc (NZ) majoring in Botany in 1960 and was<br />

awarded MSc (NZ) in 1962 and PhD (Otago) 1966 (both in Botany). The main positions<br />

during my career have been first at Horticultural Research Centre, Ministry of Agriculture<br />

and Fisheries, Levin, New Zealand from 1967 to 1988, second at School of Agriculture,<br />

University of the South Pacific, Apia, Western Samoa (1991-1994) and third at Unitec New<br />

Zealand (since 1996). My research has centred on agronomic and environmental studies of a<br />

wide range of vegetable crops grown both outdoors and in greenhouses and has always been<br />

influenced by industry needs. This work has resulted in about 150 publications comprising<br />

refereed scientific and conference papers, industry journal articles, and reports. I have<br />

refereed many papers for agricultural and horticultural science journals in New Zealand and<br />

Australia. I have worked intermittently on root and tuber crops, beginning with carrot in<br />

1968, parsnip (1972), potato (1979) and taro (1992). There have been 17 publications on<br />

these crops from 1969 to 2007.<br />

FOREWORD: THE UBIQUITOUS POTATO<br />

The year 2008 was the United Nations International Year of the Potato. These two special issues of the journal FOOD,<br />

dedicated to important aspects of current research on the potato (Solanum tuberosum L), celebrates this unique event. The<br />

material is from respected authors and so we hope that researchers, experts and readers interested in developments in a wide<br />

range of current and very active aspects of potato research find this work useful and stimulating.<br />

This work comprises 30 papers which are not exactly categorized into separate themes because some cover a number<br />

of different themes. Instead the work’s first papers broadly discuss physical and chemical properties and the measurement of<br />

these properties in the raw and processed potato tuber. Studies relating to the chemical composition and physical structure of<br />

different cultivars from the unprocessed and processed potato tubers are presented. The knowledge of the chemical<br />

composition, molecular and macromolecular structure and how this changes when chemical and physical stimulus are<br />

applied to the tuber have led to the development of methods for extraction of chemical components from the potato, thus it<br />

is apt that papers detailing developments in the area of extraction methods are presented at this point. The knowledge of<br />

how to extract desired chemical components leads to another active area of research, namely the utilisation of chemical<br />

constituent components extracted from the potato in other applications and papers detailing the use of potato tuber extracts<br />

are presented. The effects on human health and nutrition of chemical components within the potato is a research area where<br />

increasing knowledge of the effects of chemicals on human metabolism has lead to the development of both improved diets<br />

and means to reduce the risk of disease. A group of papers specifically related to human health are presented that share this<br />

theme. The last papers cover two themes. The first is use of and how to reduce chemical components considered to be waste<br />

products from potato processing and the second is acrylamide. Acrylamide is considered to pose a risk to human health and<br />

papers describing methods to reduce levels in fried potato products are presented.<br />

We thank all authors for their contributions to this volume and hope that future work will be able to be published in<br />

future special issues of FOOD.<br />

Nigel Yee and William T. Bussell


SPECIAL ISSUE: CONTENTS<br />

Miquel Nofrarías, Daniel Martínez-Puig, José F. Pérez (Spain) Potential Health Benefits of Potato Starch<br />

Daisuke Ichiura, Aki Naemura, Mayumi Ura, Motoyuki Mori, Junichiro Yamamoto (Japan) Anti-Thrombotic Effect of<br />

Potato in Animal Experiments<br />

Zenon Zduńczyk, Iwona Kosieradzka (Poland) Nutritional Properties of Tubers of Genetically Modified Potatoes Cultivated<br />

in Poland - A Review<br />

Andreas Schieber, Marleny D. Aranda Saldaña (Canada) Potato Peels: A Source of Nutritionally and Pharmacologically<br />

Interesting Compounds – A Review<br />

Enrico Finotti, Enrico Bersani, Vittorio Vivanti (Italy), Mendel Friedman (USA) Application of a Functional Mathematical<br />

Index to the Evaluation of the Nutritional Quality of Potatoes<br />

Justina Catarino, Elsa Mendonça, Ana Picado, Paulo Partidário, João Nobre da Costa (Portugal) Eco-Efficiency in a<br />

Crispy Chips Industry<br />

Elizabeth Troncoso, Rommy Zúñiga, Cristián Ramírez, Javier Parada, Juan Carlos Germain (Chile) Microstructure of<br />

Potato Products: Effect on Physico-Chemical Properties and Nutrient Bioavailability<br />

María Dolores Alvarez, Cristina Fernández, Wenceslao Canet (Spain) Oscillatory Properties of Fresh and Frozen/Thawed<br />

Mashed Potatoes as Modified by Mixtures of Amidated Low-Methoxyl Pectin and Xanthan Gum<br />

Frédéric Mestdagh, Carlos Van Peteghem, Bruno De Meulenaer (Belgium) A Farm-to-Fork Approach to Lower Acrylamide<br />

in Fried Potatoes<br />

Nigel P. Brunton, Ronan Gormley, Martina Sinn, Francis Butler, Enda Cummins, Michael O’Keeffe (Ireland) Effect of<br />

Pre-Treatments, Frying Temperature and Oven Re-Heating on the Acrylamide Content and Quality Characteristics of French<br />

Fries from ‘Rooster’ Potato Tubers<br />

Franco Pedreschi, Rommy N. Zuñiga (Chile) Acrylamide and Oil Reduction in Fried Potatoes: A Review<br />

Agnieszka Kita, Grażyna Lisińska, Agnieszka Tajner-Czopek, Anna Pęksa, Elżbieta Rytel (Poland) The Properties of<br />

Potato Snacks Influenced by the Frying Medium<br />

Grażyna Lisińska, Anna Pęksa, Agnieszka Kita, Elżbieta Rytel, Agnieszka Tajner-Czopek (Poland) The Quality of Potato<br />

for Processing and Consumption<br />

Ramesh Y. Avula, Rakesh K. Singh (USA) Functional Properties of Potato Flour and its Role in Product Development – A<br />

Review<br />

Agnieszka Krajewska, Jerzy Radecki, Hanna Radecka (Poland) Sensors and Biosensors for Determination of Acrylamide<br />

and Acrylic Acid in Potato <strong>Food</strong> Products<br />

1<br />

8<br />

13<br />

23<br />

30<br />

37<br />

41<br />

55<br />

66<br />

76<br />

82<br />

93<br />

99<br />

105<br />

113


<strong>Food</strong><br />

SPECIAL ISSUES: POTATO: FOOD, NUTRITION AND HEALTH (Guest Editors: Nigel Yee, William Bussell (Unitec, New<br />

Zealand)) ~ April, 2009<br />

Special Issue 2<br />

Miquel Nofrarías, Daniel Martínez-Puig, José F. Pérez (Spain) Potential Health Benefits of Potato Starch (pp 1-7)<br />

ABSTRACT<br />

Invited Mini-Review: Starch is considered a major source of available energy in the human diet. In potato, starch content<br />

varies from 70 to 90% on a dry matter basis depending on the botanical variety. The traditional view of starch digestion is that to<br />

a large extent starch is rapidly digested. However, a variable fraction of ingested starch can escape digestion in the foregut, and<br />

ferment later in the hindgut (RS, resistant starch). Raw potato starch is largely considered as a high RS ingredient. However,<br />

potato is mostly consumed processed, which gelatinizes starch at different extents, and this will have an effect on the<br />

composition and nutritional values (glycemic index and RS content). In general, processed potato has high levels of digestible<br />

starch, although the values may decrease with an increased time of storage after cooking. RS is becoming more desirable in<br />

the human diet because of its relevance to health, on the prevention and control of some digestive and metabolic disorders. RS<br />

intake, in substitution to digestible starch, seems to decrease postprandial glycemic and insulinemic responses, improve whole<br />

body insulin sensitivity, increase satiety, lower plasma cholesterol and triglyceride concentrations, and reduce fat storage. RS<br />

has also been associated with protective effects on chronic colonic diseases, including reduction of colon cancer risk and in the<br />

treatment of bowel inflammatory conditions. In summary, this review presents the current understanding of potato starch and<br />

potential health benefits which are likely to be associated with intake of resistant potato starch.<br />

Daisuke Ichiura, Aki Naemura, Mayumi Ura, Motoyuki Mori, Junichiro Yamamoto (Japan) Anti-Thrombotic Effect of Potato<br />

in Animal Experiments (pp 8-12)<br />

ABSTRACT<br />

Original Research Paper: Prevention of atherothrombotic diseases is an important and urgent social task in the developed<br />

world. Inappropriate diet plays a causative role in the development and clinical outcome of thrombotic diseases. We have been<br />

testing fruits and vegetables and found that some varieties have a significant anti-thrombotic effect. The present study aimed to<br />

test twenty potato varieties using in vitro test (<strong>Global</strong> Thrombosis Test-GTT) and animal models of thrombosis (laser-induced<br />

thrombosis in the carotid artery of mice). Potato varieties Touya (yellow), Hokkaikogane (yellow) and Star ruby (yellow) showed<br />

heat-resistant anti-thrombotic effects. Including these varieties in daily diet may be beneficial in thrombosis prevention.<br />

Zenon Zduńczyk, Iwona Kosieradzka (Poland) Nutritional Properties of Tubers of Genetically Modified Potatoes Cultivated in<br />

Poland - A Review (pp 13-22)<br />

ABSTRACT<br />

Invited Mini-Review: This review addresses in vivo experiments concerning nutritional and health properties of tubers of<br />

transgenic potatoes cultivated in a field experiment in Poland. Genetic modification was conducted with three aims: (1) to<br />

improve resistance to a necrotic strain of Potato virus Y (transgenic lines with a truncated gene coding PVY N polymerase in the<br />

sense or antisense orientation and lines with a non-translated region of the PVY N genome in the sense or antisense orientation),<br />

(2) to modulate the content of flavonoids through overexpression of 14-3-3 protein from Cucurbita pepo or to repress the gene<br />

encoding protein ADP-ribosylation factor, and (3) to enhance flavonoids synthesis through overexpression of the enzymes of<br />

the flavonoid synthesis pathway, i.e. chalcone synthase, chalcone isomerase and dihydroflavonol dehydrogenase. Special<br />

attention is focused on differentiated chemical composition and nutritional properties of diets. Investigations were conducted on<br />

rats fed for 3-5 weeks diets with a high content (20-40%) of autoclaved and dried potato tubers. The in vivo experiments<br />

indicate that tubers of genetically modified potato are a substantial and nutritional equivalent to the non-transgenic cultivars,<br />

although some indices of the physiological response of animals pointed to the need for conducting longer investigations.<br />

Andreas Schieber, Marleny D. Aranda Saldaña (Canada) Potato Peels: A Source of Nutritionally and Pharmacologically<br />

Interesting Compounds – A Review (pp 23-29)


ABSTRACT<br />

Invited Mini-Review: In October 2007, the United Nations declared 2008 as The Year of the Potato, highlighting the<br />

importance of this crop as a staple food in human nutrition. While fresh potato consumption is decreasing in many countries,<br />

more potatoes are currently processed into value-added products to meet the demand especially from the fast food and<br />

convenience food industries. Potatoes are usually peeled during processing, either by steam, lye or abrasive peeling,<br />

depending on the type of product. As a consequence, large quantities of peels are generated which represent a severe disposal<br />

problem to the industry, especially with the increasing awareness and aims of minimising environmental impact and<br />

sustainability. However, potato peels contain a number of nutritionally and pharmacologically interesting compounds such as<br />

polyphenols and glycoalkaloids, which may be recovered and used as natural antioxidants and precursors for steroid hormones,<br />

respectively. Furthermore, applications of the dietary fibre fraction have been described. This review summarizes the available<br />

literature on potato peel utilization, focusing on the above mentioned constituents, and highlights the potential of an important<br />

by-product of the food industry as a source of valuable compounds.<br />

Enrico Finotti, Enrico Bersani, Vittorio Vivanti (Italy), Mendel Friedman (USA) Application of a Functional Mathematical<br />

Index to the Evaluation of the Nutritional Quality of Potatoes (pp 30-36)<br />

ABSTRACT<br />

Original Research Paper: This paper describes the derivation and application of a new functional mathematical index that was<br />

used to evaluate the nutritional, safety, and processing quality aspects of potatoes. The index introduces the concept of an<br />

“optimal potato”, using appropriate distance and N-dimensional parameter space models. Although the index may not be a<br />

unique answer to the need for defining a “quality potato index”, the results of the present study show that it presents an<br />

approach that can be used to establish whether a specific potato variety or processed potato product can be considered of high,<br />

medium, or low nutritional quality. The main goal of the index is to link composition and chemical quality to factors that govern<br />

growth, production, distribution, and processing of potatoes and potato products for commercial use. In addition, it is expected<br />

that the index will be a useful parameter that can detect critical points (harvest time, storage conditions, treatment processes)<br />

as affected by variety and composition during the entire growth, production, and distribution cycle of potatoes, and thus<br />

suggests new ways to increase the value of potatoes for the human diet. The index is intended to complement and extend<br />

methods for nutritional quality and safety of potato proteins.<br />

Justina Catarino, Elsa Mendonça, Ana Picado, Paulo Partidário, João Nobre da Costa (Portugal) Eco-Efficiency in a<br />

Crispy Chips Industry (pp 37-40)<br />

ABSTRACT<br />

Research Note: Combining economical and environmental efficiencies, eco-efficiency within production processes is a key<br />

path where there is a simultaneous focus on waste prevention and on the improvement of resource productivity – by producing<br />

more with less, towards sustainable production. To achieve such a goal, a Portuguese crispy chips company implemented a<br />

cleaner production approach. That process included the company’s background information, a global inventory based on<br />

manufacturing diagrams, materials accounting, mass balances for the more representative materials, a synthesis of the<br />

production process eco-inefficiencies and its environmental impacts, an identification of ideas to improve the eco-efficiency in<br />

the field, and finally a feasibility analysis regarding technical, environmental and economical aspects. Results show that 75% of<br />

the starch input was converted into the final product, and that 80% of the by-products and wastes were generated before the<br />

frying process. It was also found that water utilization was closely related to the starch path. After a creativity phase where<br />

improvement ideas were generated and a feasibility analysis was done, some solutions were implemented. The implementation<br />

of improvement solutions resulted in an increase in business productivity that enabled the reduction of energy consumption,<br />

water and chemicals inputs, and the volume of sludge. In conclusion, eco-efficiency showed to be of major value to this industry,<br />

converting process inefficiencies into economic opportunities with simultaneous environmental benefits, thus fulfilling the<br />

industry’s objectives towards the challenge of sustainable development.<br />

Elizabeth Troncoso, Rommy Zúñiga, Cristián Ramírez, Javier Parada, Juan Carlos Germain (Chile) Microstructure of<br />

Potato Products: Effect on Physico-Chemical Properties and Nutrient Bioavailability (pp 41-54)<br />

ABSTRACT


Invited Review: Understanding the microstructural changes of raw potato during processing is critical if food properties want to<br />

be controlled properly, because there is a causal connection between structure and functionality. Major structural elements<br />

contributing to potato products identity and quality are plant cells, cell walls and starch granules. During processing, which can<br />

be viewed as a series of restructuring and reassembling operations, these elements are modified, which generates changes on<br />

the product properties. For example, texture is a sensory attribute of uppermost importance for the preference of potato<br />

products. The abundance of starch inside the cells, and the shape and size of starch granules modified during different<br />

processing, have been reported as important factors for the final texture, as well as the structure of the cell wall polymers. Thus,<br />

microscopy techniques for examining food microstructure are necessary to understand structure-property relationships and<br />

their effects on chemical stability, physical properties and nutrient bioavailability of potato products. Image processing and<br />

image analysis techniques provide the required quantitative data for the analysis and design of food microstructure. In addition,<br />

it is necessary to improve the quality of existing foods and to create new products that satisfy consumer’s demands of healthy<br />

foods, which will be based on interventions at the microscopic level.<br />

María Dolores Alvarez, Cristina Fernández, Wenceslao Canet (Spain) Oscillatory Properties of Fresh and Frozen/Thawed<br />

Mashed Potatoes as Modified by Mixtures of Amidated Low-Methoxyl Pectin and Xanthan Gum (pp 55-65)<br />

ABSTRACT<br />

Original Research Paper: Freezing and thawing of mashed potatoes has a detrimental effect on their physical and<br />

water-holding properties. This study deals with the ability of mixtures of amidated low-methoxyl (ALM) pectin and xanthan gum<br />

(XG) to ameliorate these effects in fresh (F) and frozen/thawed (F/T) mashed potatoes. Viscoelastic properties were monitored<br />

by oscillatory measurements. A parameter that characterizes the fluid behaviour for the nonlinear viscoelastic range (α, fluid-like<br />

relative angle) was also determined. The effect of ALM and XG concentration on the dynamic rheological parameters was<br />

studied using response surface methodology (RSM). A central composite rotatable experimental design was used with ALM<br />

concentration ranging between 1.5 and 4.5 g kg -1 and XG concentration ranging between 0.5 and 2.5 g kg -1 as independent<br />

variables. The effects were highly dependent on the levels of ALM and XG added, although the effect of XG concentration on<br />

the oscillatory measurements was more significant. When comparing the effect of processing on a particular formulation,<br />

although F samples presented a spongier, more rigid structure over the linear viscoelastic range (higher elastic modulus values<br />

(G’)) than their F/T counterparts, they were more fluid-like after breakdown. For F mashed potatoes, the optimum condition for α<br />

showing maximum fluid-like character after breakdown was found at 3.32 g kg -1 ALM pectin and 1.65 g kg -1 XG, whereas the<br />

response surface for α was saddle-shaped after freezing and thawing. For F/T mashed potatoes, the optimum condition for δ<br />

showing maximum structural weakening in the linear viscoelastic range was found at 3.06 g kg -1 ALM pectin and 2.38 g kg -1 XG.<br />

In spite of the fact that no enhancement of oscillatory properties was observed, this approach may have potential for designing<br />

F and F/T mashed potatoes with specified dynamic properties.<br />

Frédéric Mestdagh, Carlos Van Peteghem, Bruno De Meulenaer (Belgium) A Farm-to-Fork Approach to Lower Acrylamide<br />

in Fried Potatoes (pp 66-75)<br />

ABSTRACT<br />

Invited Review: Acrylamide is a probable human carcinogen, which is formed during frying or baking of carbohydrate-rich<br />

foodstuffs, such as potatoes. The presence of this heat-induced contaminant in a wide range of daily consumed foodstuffs<br />

sparked international research, focusing on analysis, occurrence and formation in food as well as on toxicological aspects. This<br />

review summarizes the state-of-the-art knowledge about the formation mechanisms of acrylamide and several key factors<br />

influencing its generation in fried potato products. Based on the knowledge gathered, suggestions are given to lower the<br />

acrylamide content in the final product as much as possible. For this, a farm-to-fork approach is followed starting from the<br />

agricultural practice, through several food-processing possibilities on industrial and home-cooking level. Furthermore, the<br />

dietary acrylamide exposure is investigated as well as the importance of canteen food.<br />

Nigel P. Brunton, Ronan Gormley, Martina Sinn, Francis Butler, Enda Cummins, Michael O’Keeffe (Ireland) Effect of<br />

Pre-Treatments, Frying Temperature and Oven Re-Heating on the Acrylamide Content and Quality Characteristics of French<br />

Fries from ‘Rooster’ Potato Tubers (pp 76-81)<br />

ABSTRACT<br />

Original Research Paper: Acrylamide levels in food, and especially in potato products, are perceived world wide as a potential


public health problem. The current trials on ‘Rooster’ potato tubers purchased (as ware samples) in a supermarket and fried<br />

under domestic conditions showed that soaking (citric acid vs. water) and pre-treatments such as blanching in water and<br />

pre-frying in oil were useful for lowering the content of acrylamide precursors (reducing sugars and asparagine) in potato tuber<br />

strips and also the acrylamide content in the corresponding French fried samples. However, this effect was small relative to that<br />

of frying temperature where an increase in acrylamide content from 243 (150°C/6 min) to 761 µg/g (190°C/6 min) was<br />

demonstrated in French fries. Oven-reheating (convection vs. microwave) of fully fried samples had no effect on acrylamide<br />

content. Soaking, blanching, frying and re-heating treatments had an effect on fry colour and on textural properties. However,<br />

the extent of the effects was generally small for the latter. A sensory panel indicated that Hunter values in the ranges 68-70 L or<br />

2.8-3.0 L/b represented ideal French fry colour.<br />

Franco Pedreschi, Rommy N. Zuñiga (Chile) Acrylamide and Oil Reduction in Fried Potatoes: A Review (pp 82-92)<br />

ABSTRACT<br />

Invited Review: Potato is the raw food material that has been used the most in frying operations due to the high demand of<br />

consumers all over the world. Detection of high concentrations of acrylamide in heated starch rich foodstuffs, such as potato, by<br />

the Swedish National <strong>Food</strong> Administration in April 2002 attained public concern because this product is a suspected human<br />

carcinogen. Maillard reaction is suggested as the major mechanism of acrylamide formation in fried potatoes. The precursors of<br />

this reaction for fried potatoes are glucose, fructose and asparagine. So, several methods based in diminishing or eliminating<br />

acrylamide precursors have been implemented. On the, other hand, other reduction methods of acrylamide focus principally in<br />

the process parameters such as vacuum frying or conventional frying at low temperatures. Post-frying techniques could<br />

eventually be implemented to diminish acrylamide formation as well. But the major challenge is to reduce as much as possible<br />

acrylamide levels in fried potatoes but maintaining intact their sensorial properties and low oil content. Typical final oil content of<br />

potato chips and French fries are ~35% and ~15% by weight, respectively. Some of the principal factors that affect oil<br />

absorption in fried potato products are process parameters (temperature, pressure and frying time), deterioration degree of the<br />

frying oil, food geometry and pre-treatments (e.g. drying, solute impregnation, edible film coatings). Recently, much attention<br />

has been given to the use of vacuum frying which may be an option to produce fried potatoes with low oil content. Reducing<br />

acrylamide and oil content while maintaining product quality (flavor, color, texture, safety, etc.) in commercial fried potato<br />

production is a crucial challenge for the food industry.<br />

Agnieszka Kita, Grażyna Lisińska, Agnieszka Tajner-Czopek, Anna Pęksa, Elżbieta Rytel (Poland) The Properties of<br />

Potato Snacks Influenced by the Frying Medium (pp 93-98)<br />

ABSTRACT<br />

Invited Mini-Review: Potato products, such as French fries and chips are very popular due to their flavour, aroma and other<br />

sensory properties, which to a large extent depend on the frying process affecting the colour, taste and texture of the product.<br />

The oil used for frying is absorbed by the product and thus becomes its ingredient, which plays a significant qualitative role. The<br />

quantity of the absorbed fat is found within the range of 20-45% and its impact on the properties of the product is enormous.<br />

The type and quality of the frying medium influence the fat content and texture of the finished product. Besides, the parameters<br />

of the frying process and the type of oil influence the formation of acrylamide in subsequent products, which has an adverse<br />

effect on their quality. The type and the quality of the frying medium also affect the shelf-life of potato products. The changes<br />

due to storage are primarily connected with fat degradation, reducing flavour and odor of potato products (French fries and<br />

chips) as well as their moisture content, affecting the texture.<br />

Grażyna Lisińska, Anna Pęksa, Agnieszka Kita, Elżbieta Rytel, Agnieszka Tajner-Czopek (Poland) The Quality of Potato<br />

for Processing and Consumption (pp 99-104)<br />

ABSTRACT<br />

Invited Mini-Review: Potatoes are destined both for cooking in households and for food processing (chips, French fries,<br />

dehydrated products) as well as starch and alcohol production. The requirements of industries, regarding the chemical<br />

composition and quality of raw material vary, depending on the destination of the finished product. The technological value of<br />

potato is determined by a variety of features required by a particular industry. The properties and components of potato tubers<br />

affect the technological process, the yield and quality of the finished product. The nutritive value depends on the chemical<br />

composition of the product, including the presence of toxic compounds hazardous to human health. Potato cultivars have a


great impact both on the technological value of potato destined for industrial use and on the quality of potatoes destined for<br />

human consumption. However, a number of factors determining the technological value of potato tubers can be influenced by<br />

human actions (fertilization, use of pesticides, planting and harvest dates, irrigation, storage conditions, etc.) and the<br />

environment (location of the field, weather and soil conditions).<br />

Ramesh Y. Avula, Rakesh K. Singh (USA) Functional Properties of Potato Flour and its Role in Product Development – A<br />

Review (pp 105-112)<br />

ABSTRACT<br />

Invited Mini-Review: Potato flour is a viable value added product due to its versatility in function as a thickener and color or<br />

flavor improver. It is used in bakery products, sauces, gravy, extruded products or fabricated snacks and also in dry soup mixes.<br />

Potato flour is prepared by drying the peeled slices in a hot air drier or by drying the cooked mash in a drum drier into flakes<br />

followed by grinding and sieving. The severity of heat treatment during the drying process influences the changes/degradations<br />

of starch and properties of flour. Flour properties can also be modified by chemical and enzymatic treatments and the properties<br />

such as paste viscosity, dough rheology, gel forming properties, swelling ability are important in determining suitability of flour in<br />

food formulations. The high stability of drum dried and hot air dried flours during heating and cooling processes demonstrates<br />

their possible use in products requiring sterilization such as baby food. Enzyme modified flours with high paste viscosities act as<br />

good thickeners. The functional properties of potato flour made by different processes involving physical, chemical or enzymatic<br />

treatments are discussed.<br />

Agnieszka Krajewska, Jerzy Radecki, Hanna Radecka (Poland) Sensors and Biosensors for Determination of Acrylamide<br />

and Acrylic Acid in Potato <strong>Food</strong> Products (pp 113-120)<br />

ABSTRACT<br />

Invited Review: The presence of toxic acrylamide in a wide range of food products such as potato crisps, French fries or bread<br />

was confirmed by Swedish scientists from Stockholm University. The neurotoxity, and possible carcinogenicity, of this<br />

compound and its metabolites imposes a duty to control them by quantitative and qualitative assays. Acrylamide forms an<br />

adduct with hemoglobin (Hb) as a result of the reaction with the α-NH 2 group of the N-terminal valine of Hb. This interaction is<br />

the basis of a new voltammetric biosensor to detect acrylamide. The biosensor was constructed using a carbon-paste electrode<br />

modified with hemoglobin (Hb), which contains four prosthetic heme-Fe(III) groups. Such an electrode displays a reversible<br />

reduction/oxidation process of Hb-Fe(III)/Hb-Fe(II). Interaction between Hb and acrylamide was observed through a decrease<br />

of the Hb-Fe(III) reduction peak current. Exposing acrylamide to pH extremes results in its hydrolysis to acrylic acid. Apart from<br />

natural host molecules, synthetic receptors such as tetralactam or macrocyclic polyamine derivatives were applied as active<br />

elements of sensors for voltammetric detection of acrylic acid. The synthetic host molecules were immobilized on an electrode<br />

surface by covalent Au-S bond or by an embedment method into the thiol layer via hydrophobic and van der Waals interactions.<br />

The applicability of sensors was proved by a validation procedure made in the matrix obtained by water extraction of potato<br />

chips. The proposed sensor parameters such as sensitivity, selectivity, wide dynamic range, simplicity of sample preparation, in<br />

comparison to those presented by others in already reported methods, will be discussed.

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