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1) In which compound does chlorine have the highest oxidation ...

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Name: ____________________________________________<br />

1) <strong>In</strong> <strong>which</strong> <strong>compound</strong> <strong>does</strong> <strong>chlorine</strong> <strong>have</strong> <strong>the</strong> <strong>highest</strong><br />

<strong>oxidation</strong> number?<br />

A) NaClO 3<br />

C) NaClO 4<br />

B) NaClO<br />

D) NaClO 2<br />

2) <strong>In</strong> <strong>which</strong> substance <strong>does</strong> <strong>chlorine</strong> <strong>have</strong> an <strong>oxidation</strong> number<br />

of +1?<br />

A) Cl 2<br />

B) HCl<br />

C) HClO 2<br />

D) HClO<br />

3) What is <strong>the</strong> <strong>oxidation</strong> number assigned to manganese in<br />

KMnO 4<br />

?<br />

A) +4<br />

B) +3<br />

C) +7<br />

D) +2<br />

4) What is <strong>the</strong> <strong>oxidation</strong> state of nitrogen in NaNO 2<br />

?<br />

A) +1<br />

B) +2<br />

C) +3<br />

D) +4<br />

5) The transfer of <strong>which</strong> particle is required for a redox reaction<br />

to occur?<br />

A) electron<br />

B) ion<br />

6) Given <strong>the</strong> redox reaction:<br />

Cr 3+ + Al ‚ Cr + Al 3+<br />

C) neutron<br />

D) proton<br />

As <strong>the</strong> reaction takes place, <strong>the</strong>re is a transfer of<br />

A) protons from Al to Cr 3+<br />

B) electrons from Al to Cr 3+<br />

C) protons from Cr 3+ to Al<br />

D) electrons from Cr 3+ to Al<br />

7) Which reaction is an example of an <strong>oxidation</strong>-reduction<br />

reaction?<br />

A) 2KOH + H 2 SO 4<br />

‚ K 2 SO 4 + 2H 2 O<br />

B) Cu + 2AgNO 3<br />

‚ Cu(NO 3 ) 2 + 2Ag<br />

C) AgNO 3 + KI ‚ AgI + KNO 3<br />

D) Ba(OH) 2 + 2HCl ‚ BaCl 2 + 2H 2 O<br />

8) As a Ca atom undergoes <strong>oxidation</strong> to Ca 2+ , <strong>the</strong> number of<br />

neutrons in its nucleus<br />

A) increases<br />

C) remains <strong>the</strong> same<br />

B) decreases<br />

9) Given <strong>the</strong> reaction:<br />

Mg + CuSO 4<br />

‚ MgSO 4 + Cu<br />

Which equation represents <strong>the</strong> <strong>oxidation</strong> that takes place?<br />

A) Mg 2+ + 2e - ‚ Mg C) Cu ‚ Cu 2+ + 2e -<br />

B) Mg ‚ Mg 2+ + 2e - D) Cu 2+ + 2e - ‚ Cu<br />

D) Al 3+ B) Fe<br />

6118 - 1 - Page 1<br />

10) Given <strong>the</strong> reaction:<br />

Mg(s) + 2H + (aq) + 2Cl - (aq) ‚<br />

Mg 2+ (aq) + 2Cl - (aq) + H 2 (g)<br />

Which species undergoes <strong>oxidation</strong>?<br />

A) H + (aq)<br />

C) Mg(s)<br />

B) H 2 (g)<br />

D) Cl - (aq)<br />

11) Given <strong>the</strong> balanced ionic equation:<br />

Zn(s) + Cu 2+ (aq) ‚ Zn 2+ (aq) + Cu(s)<br />

Which equation represents <strong>the</strong> <strong>oxidation</strong> half-reaction?<br />

A) Zn(s) + 2e - ‚ Zn 2+ (aq)<br />

B) Cu 2+ (aq) + 2e - ‚ Cu(s)<br />

C) Cu 2+ (aq) ‚ Cu(s) + 2e -<br />

D) Zn(s) ‚ Zn 2+ (aq) + 2e -<br />

12) Given <strong>the</strong> reaction:<br />

Zn(s) + 2HCl(aq) ‚ ZnCl 2 (aq) + H 2 (g)<br />

Which statement correctly describes what occurs when this<br />

reaction takes place in a closed system?<br />

A) There is a net loss of mass.<br />

B) Atoms of Zn(s) gain electrons and are reduced.<br />

C) Atoms of Zn(s) lose electrons and are oxidized.<br />

D) There is a net gain of mass.<br />

13) <strong>In</strong> an <strong>oxidation</strong>-reduction reaction, reduction is defined as<br />

<strong>the</strong><br />

A) gain of electrons<br />

C) gain of protons<br />

B) loss of protons<br />

D) loss of electrons<br />

14) <strong>In</strong> any redox reaction, <strong>the</strong> substance that undergoes<br />

reduction will<br />

A) gain electrons and <strong>have</strong> an increase in <strong>oxidation</strong><br />

number<br />

B) lose electrons and <strong>have</strong> a decrease in <strong>oxidation</strong> number<br />

C) gain electrons and <strong>have</strong> a decrease in <strong>oxidation</strong> number<br />

D) lose electrons and <strong>have</strong> an increase in <strong>oxidation</strong> number<br />

15) Given <strong>the</strong> reaction:<br />

2Al(s) + Fe 2 O 3 (s) Al 2 O 3 (s) + 2Fe(s)<br />

Which species undergoes reduction?<br />

A) Fe 3+<br />

C) Al


16) Which change in <strong>oxidation</strong> number indicates <strong>oxidation</strong>?<br />

A) +2 to -3<br />

B) -1 to -2<br />

C) +3 to +2<br />

D) -1 to +2<br />

17) According to <strong>the</strong> Activity Series chemistry reference table,<br />

<strong>which</strong> of <strong>the</strong>se metals will react most readily with 1.0 M HCl<br />

to produce H 2<br />

(g)?<br />

A) Zn<br />

B) K<br />

C) Ca<br />

D) Mg<br />

18) Which metal reacts spontaneously with a solution<br />

containing zinc ions?<br />

A) silver<br />

B) nickel<br />

C) copper<br />

D) magnesium<br />

C) Fe ‚ Fe 2+ + 2e -<br />

19) <strong>In</strong> a redox reaction, how <strong>does</strong> <strong>the</strong> total number of electrons<br />

lost by <strong>the</strong> oxidized substance compare to <strong>the</strong> total number<br />

of electrons gained by <strong>the</strong> reduced substance?<br />

A) The number lost is always greater than <strong>the</strong> number<br />

gained.<br />

B) The number lost is always equal to <strong>the</strong> number gained.<br />

C) The number lost is sometimes equal to <strong>the</strong> number<br />

gained.<br />

D) The number lost is sometimes less than <strong>the</strong> number<br />

gained.<br />

20) Which equation shows conservation of charge?<br />

A) Fe + 2e - ‚ Fe 3+<br />

B) Fe ‚ Fe 2+ + e - D) Fe + 2e - ‚ Fe 2+<br />

21) Which equation shows conservation of both mass and<br />

charge?<br />

A) Ni + Pb 2+ ‚ Ni 2+ + Pb<br />

B) Cl 2 + Br - ‚ Cl - + Br 2<br />

C) Cu + 2Ag + ‚ Cu 2+ + Ag<br />

D) Zn + Cr 3+ ‚ Zn 2+ + Cr<br />

22) A voltaic cell spontaneously converts<br />

A) chemical energy to electrical energy<br />

B) electrical energy to nuclear energy<br />

C) electrical energy to chemical energy<br />

D) nuclear energy to electrical energy<br />

23) Which statement is true for any electrochemical cell?<br />

A) Reduction occurs at both <strong>the</strong> anode and <strong>the</strong> cathode.<br />

B) Oxidation occurs at both <strong>the</strong> anode and <strong>the</strong> cathode.<br />

C) Oxidation occurs at <strong>the</strong> anode, only.<br />

D) Reduction occurs at <strong>the</strong> anode, only.<br />

24) A diagram of a chemical cell and an equation are shown<br />

below.<br />

When <strong>the</strong> switch is closed, electrons will flow from<br />

A) <strong>the</strong> Pb 2+ (aq) to <strong>the</strong> Pb(s)<br />

B) <strong>the</strong> Cu 2+ (aq) to <strong>the</strong> Cu(s)<br />

C) <strong>the</strong> Cu(s) to <strong>the</strong> Pb(s)<br />

D) <strong>the</strong> Pb(s) to <strong>the</strong> Cu(s)<br />

25) All organic <strong>compound</strong>s must contain <strong>the</strong> element<br />

A) nitrogen<br />

B) carbon<br />

C) phosphorus<br />

D) oxygen<br />

26) Which element must be present in an organic <strong>compound</strong>?<br />

A) oxygen<br />

B) hydrogen<br />

C) nitrogen<br />

D) carbon<br />

27) Which element has atoms that can bond with each o<strong>the</strong>r to<br />

form long chains or rings?<br />

A) nitrogen<br />

B) fluorine<br />

C) oxygen<br />

D) carbon<br />

28) An unknown substance, liquid X, is tested in <strong>the</strong> laboratory.<br />

The chemical and physical test results are listed below.<br />

d Nonconductor of electricity<br />

d <strong>In</strong>soluble in water<br />

d Soluble in hexane<br />

d Low melting point as a solid<br />

d Combustion produces only CO 2 and H 2 O<br />

6118 - 1 - Page 2<br />

Based on <strong>the</strong>se results, a student should conclude that<br />

liquid X is<br />

A) covalent and organic<br />

B) ionic and organic<br />

C) covalent and inorganic<br />

D) ionic and inorganic


29) Which structural formula is incorrect?<br />

A)<br />

6118 - 1 - Page 3<br />

34) What is <strong>the</strong> IUPAC name of <strong>the</strong> <strong>compound</strong> having <strong>the</strong><br />

following structural formula?<br />

B)<br />

A) 3-pentene<br />

B) 3-pentyne<br />

C) 2-pentene<br />

D) 2-pentyne<br />

35) Which structural formula correctly represents a<br />

hydrocarbon molecule?<br />

C)<br />

A)<br />

C)<br />

D)<br />

B)<br />

D)<br />

30) Molecules of 2-methyl butane and 2,2-dimethyl propane<br />

<strong>have</strong> different<br />

A) numbers of covalent bonds<br />

B) molecular formulas<br />

C) structural formulas<br />

D) numbers of carbon atoms<br />

31) Which <strong>compound</strong> is classified as a hydrocarbon?<br />

A) chloroethane<br />

B) ethanol<br />

32) Which formula represents a hydrocarbon?<br />

C) ethanoic acid<br />

D) ethane<br />

36) The empirical formula of a <strong>compound</strong> is CH 2 . Which<br />

molecular formula is correctly paired with a structural<br />

formula for this <strong>compound</strong>?<br />

A) C 2 H 4 ,<br />

B) C 3 H 8 ,<br />

A) CH 3 CH 2 CH 2 CH 3<br />

B) CH 3 CH 2 COOCH 3<br />

C) CH 3 CH 2 CH 2 CHO<br />

D) CH 3 CH 2 CH 2 COOH<br />

C) C 3 H 8 ,<br />

33) Given <strong>the</strong> structural formula:<br />

D) C 2 H 4 ,<br />

What is <strong>the</strong> IUPAC name of this <strong>compound</strong>?<br />

A) propene<br />

B) propanone<br />

C) propane<br />

D) propanal<br />

37) Given <strong>the</strong> reaction: 4Al(s) + 3O 2<br />

(g) ‚ 2Al 2<br />

O 3<br />

(s)<br />

(a)<br />

Write <strong>the</strong> balanced <strong>oxidation</strong> half-reaction for this<br />

<strong>oxidation</strong>-reduction reaction.<br />

(b) What is <strong>the</strong> <strong>oxidation</strong> number of oxygen in Al 2 O 3 ?


Questions 38 and 39 refer to <strong>the</strong> following:<br />

The equation below represents an unbalanced redox reaction.<br />

__Cu(s) + __AgNO 3<br />

(aq) ‚ __Cu(NO 3<br />

) 2<br />

(aq) + __Ag(s)<br />

38) Write <strong>the</strong> reduction half-reaction for <strong>the</strong> given redox<br />

reaction.<br />

39) Balance <strong>the</strong> given redox equation using <strong>the</strong> smallest wholenumber<br />

coefficients.<br />

Questions 40 and 41 refer to <strong>the</strong> following:<br />

6118 - 1 - Page 4<br />

42) On <strong>the</strong> given diagram, indicate with one or more arrows <strong>the</strong><br />

direction of electron flow through <strong>the</strong> wire.<br />

43) Write an equation for <strong>the</strong> half-reaction that occurs at <strong>the</strong><br />

zinc electrode in <strong>the</strong> given diagram.<br />

44) Explain <strong>the</strong> function of <strong>the</strong> salt bridge in <strong>the</strong> given diagram.<br />

Questions 45 and 46 refer to <strong>the</strong> following:<br />

The diagram below represents a voltaic cell and a balanced ionic<br />

equation.<br />

The redox reaction below occurs spontaneously in an<br />

electrochemical cell.<br />

Zn + Cr 3+ ‚ Zn 2+ + Cr<br />

40) Which species loses electrons and <strong>which</strong> species gains<br />

electrons?<br />

41) State what happens to <strong>the</strong> number of protons in a Zn atom<br />

when it changes to Zn 2+ as <strong>the</strong> redox reaction occurs.<br />

Questions 42 through 44 refer to <strong>the</strong> following:<br />

45) What is <strong>the</strong> total number of moles of electrons needed to<br />

completely reduce 6.0 moles of Ni 2+ (aq) ions in <strong>the</strong> ionic<br />

equation shown?<br />

46) Identify one metal from <strong>the</strong> Activity Series chemistry<br />

reference table that is more easily oxidized than Mg(s).<br />

47) How is <strong>the</strong> bonding between carbon atoms different in<br />

unsaturated hydrocarbons and saturated hydrocarbons?<br />

48) Identify <strong>the</strong> homologous series of hydrocarbons to <strong>which</strong><br />

CH 3 CHCH 2 belongs.

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