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Full Lesson Plan - School of Arts & Sciences

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Bill Wagenborg<br />

Chemistry <strong>Lesson</strong> <strong>Plan</strong><br />

March 2007<br />

<strong>Lesson</strong> Title: Understanding Charles’ Law<br />

Grade Level: 8<br />

Time Frame: 1-2 (45 Minute) Classes<br />

Goals/Objectives: The Students Will Be Able To:<br />

- follow a sequenced plan <strong>of</strong> instructions<br />

- describe changes to gases caused by the addition and<br />

absence <strong>of</strong> heat(rise and fall in temperature)<br />

- use process skills to make inferences and predictions<br />

using collected information<br />

- explain the concepts involved in Charles’ Law through<br />

discussion and written words<br />

Pennsylvania Standards:<br />

3.1.10 E: Describe patterns in nature, physical and man made<br />

systems.<br />

3.2.10 B: Apply process knowledge and organize scientific and<br />

technological phenomena in varied ways.<br />

Opening (Attention Grabber)<br />

Materials: Empty Soda Can, Hot Plate, 1 Liter Beaker, Tongs, Tap Water<br />

Teacher Action:<br />

1.Fill up the beaker with room temperature water.<br />

2.Place just enough water in the soda can to cover the bottom.<br />

3.Turn the hot plate on, place the soda can on top and heat the can until the<br />

water begins to boil. (You should see steam flowing from the top <strong>of</strong> the<br />

can)<br />

4.Using the tongs, grab the can at the bottom and quickly place the top<br />

portion <strong>of</strong> it in the beaker upside down. (The sides <strong>of</strong> the can will crush<br />

inward)<br />

5. Allow students to hypothesize why this occurred and explain that today<br />

they will be doing a lab that may help them understand what happened.<br />

***Caution: Before doing this demonstration inspect the beaker for any cracks<br />

and make sure the students are not extremely close. The force <strong>of</strong> the can crushing in a<br />

beaker with a tiny crack can cause the beaker to break. (This happened to me before<br />

when I was testing it before class. I reinforce the top <strong>of</strong> beaker I use with duct tape before<br />

doing this demonstration in order to prevent any accidents)<br />

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Materials For <strong>Lesson</strong>:<br />

For Each Group:<br />

2 balloons (be mindful <strong>of</strong> student allergies when choosing the type)<br />

2 250 ml beakers<br />

2 thermometers<br />

2 aluminum pie pans (6-12 inches)<br />

For The Class:<br />

Crushed ice<br />

Tap water<br />

Hot Plate(s)<br />

Pre-Class Questions:<br />

What do you think will happen to a balloon if you heat it? Why?<br />

What if you cool it? Why?<br />

Draw a picture <strong>of</strong> what the gas might look like inside the balloon for each<br />

instance.<br />

<strong>Lesson</strong>:<br />

Part A<br />

The students are broken up into groups and each group will blow up a balloon in a<br />

250 ml beaker. The balloon should fit firmly against the insides <strong>of</strong> the beaker.<br />

They will then place the beaker in an aluminum pie shaped container. This<br />

container will be a water bath filled with room temperature water. Using a<br />

thermometer, the students will take and record the temperature <strong>of</strong> the water and<br />

observe the balloon. They will make a drawing <strong>of</strong> what they think the gas looks<br />

like inside the balloon.<br />

The students will then place the container with the beaker in it, on a hot plate and<br />

heat the water. (We do not have any Bunsen burners or access to gas for that<br />

matter). They will take the temperature <strong>of</strong> the water at equal intervals (every 30<br />

seconds for 5 minutes) and observe what happens to the balloon in the beaker<br />

until the water begins to boil.<br />

The students will be recording all <strong>of</strong> the information and observations in their lab<br />

journals. They also will draw a picture <strong>of</strong> what they think the gas inside the<br />

balloon looks like after the five minutes <strong>of</strong> heating. They will compare this to<br />

their drawing <strong>of</strong> the gas before they added heat to the balloon and the prediction<br />

they made in their pre-class drawing <strong>of</strong> a heated balloon.<br />

Part B<br />

The students will blow up another balloon inside a second 250 ml beaker and<br />

again place it in a room temperature water bath in an aluminum pie plate. They<br />

will record the temperature and observe the balloon’s size in the beaker. They will<br />

make a drawing <strong>of</strong> what they think the gas looks like inside the balloon.<br />

2


Assessments:<br />

The students will then begin to fill the water bath with crushed ice. They will<br />

record the temperature, observe the balloon and add more ice. All will be done<br />

over equal time intervals (30 seconds for 5 minutes).<br />

As they did in part a, they will record all information in their lab journals. They<br />

also will draw a picture <strong>of</strong> what they think the gas inside the balloon looks like<br />

after the five minutes <strong>of</strong> cooling. They will compare this to the drawing they<br />

made <strong>of</strong> the gas before they added the ice and to their pre-class drawing <strong>of</strong> a<br />

cooled balloon.<br />

After the lab (that day if time permits or the following class), we will have<br />

a discussion about what the students observed and what they think may have<br />

caused their results. They will also record their thoughts and experiences with this<br />

lab in their lab journals. I will serve as a moderator/guide and not an answer<br />

person. I want to see what their thoughts are and that they arrived at their<br />

conclusions on their own.<br />

1. The students will be given follow up questions dealing with their lab that<br />

will be used as an assessment. The questions will be phrased in a way where<br />

I will be able to see if they understand why the balloon increased in size in<br />

the hot water and decreased in size for the cold. I want to make sure that<br />

they realize that the volume <strong>of</strong> the gas inside the balloon is increasing and<br />

decreasing.<br />

For example:<br />

• Were your predictions from the pre-class correct? Explain<br />

• Based on your observations, what happens to a balloon<br />

when heated and when cooled?<br />

• What affect does the temperature have that causes the<br />

balloon to act this way?<br />

• Using this lab and what we learned about Boyle’s Law in<br />

our previous unit as a basis, explain why the soda can got<br />

crushed in our opening activity?(If Boyle’s Law is taught<br />

after Charles Law you can just focus on their<br />

explanations from the temperature and volume viewpoint<br />

now, and readdress the pressure at a later point)<br />

2. They will also be given a question on their unit test that takes Charles’ Law<br />

and puts in a “real world” context.<br />

For example:<br />

• Why do the tires on your car appear to be deflated in the morning<br />

after a cold night? How does this show Charles’ Law?<br />

Or<br />

3


• You are a manager <strong>of</strong> a party store. It is a cold day and a person<br />

just buys a bunch <strong>of</strong> balloons before leaving the store. She returns<br />

minutes later complaining that her balloons are deflated. Using<br />

what you have learned about Charles’ Law, give your response to<br />

the customer.<br />

Story <strong>of</strong> Charles Law (See Page 7): During the following class or lab wrap up session,<br />

the students will hear the story <strong>of</strong> how Charles Law came about and how it relates to<br />

balloons. It provides the students with a connection between a science law and a real<br />

world application.<br />

4


Story <strong>of</strong> Charles’ Law<br />

To begin the story <strong>of</strong> Charles law, we should first look at the early<br />

attempts <strong>of</strong> discovery by Robert Boyle and Guilliame Amonton. In 1622<br />

Boyle had published his work on the inverse relationship between a gas’<br />

pressure and volume, a law that would later bear his name. He was aware <strong>of</strong><br />

the increase in volume <strong>of</strong> a gas when heated, but a temperature scale did not<br />

exist then. In the early 1700’s Amonton did many experiments involving a<br />

gas’ volume and its temperature, but like Boyle a temperature scale did not<br />

exist. (Thall, n.d.)<br />

So we can now look at the gentleman who the law is named after.<br />

Jacques Charles was a Frenchman who early on in his life had very little<br />

science education. While working in a Paris Government Office he had a<br />

chance encounter with the American Ambassador to France, Benjamin<br />

Franklin. After hearing <strong>of</strong> Franklin’s experiments and scientific ideas,<br />

Charles decided to teach himself some science. This self teaching eventually<br />

led to public lectures and then to the Academy <strong>of</strong> Science, where he began to<br />

develop a respectable reputation. (Ellyard, 2005)<br />

It was here in 1783 that the Montg<strong>of</strong>ier brothers asked Jacques<br />

to look at their new mode <strong>of</strong> travel, the hot air balloon. After careful<br />

scrutiny, Charles stated that he believed that for the safest and surest form <strong>of</strong><br />

travel the balloon should be filled with” a very light flammable air<br />

(hydrogen) rather than heating the air over fire.”(Ellyard, 2005) In August <strong>of</strong><br />

that year he but his theories to the test. He got his first balloon and filled it<br />

with hydrogen by pouring sulfuric acid over scrap iron (later zinc). He went<br />

to a field, where the Eiffel tower now stands, and sent his balloon up 10 km.<br />

After more trials he soon started to notice that the balloon’s volume would<br />

expand as the balloon went up into lower air pressure. This was not anything<br />

new; it was simply proving Boyle’s Law from 1659. More importantly he<br />

saw a connection between heating the gas and the gas’ volume. (Ellyard,<br />

2005)<br />

In 1787 Charles decided to investigate this relationship further. He<br />

went out and got a J-shaped glass tube that Robert Boyle had used in his<br />

study <strong>of</strong> gases. He placed the tube in a water bath so he could manipulate the<br />

temperature <strong>of</strong> the gas. He held the pressure <strong>of</strong> the trapped gas bubble steady<br />

by “keeping a constant difference between mercury levels in the two arms <strong>of</strong><br />

the tube,” (Ellyard, 2005) This would make pressure a non factor in his<br />

experiments. He then went about changes the temperature <strong>of</strong> the water bath<br />

and observing the effect on the trapped gas bubble. His results showed that<br />

5


the volume <strong>of</strong> the gas rose with an increase in temperature and fell with a<br />

decrease in temperature, (Ellyard, 2005)<br />

This relationship was dubbed Charles’ Law. This may not be fair for<br />

two reasons. First Charles was not the first to discover this relationship.<br />

Gulilliame Amontons had done so in 1702, but Charles’ apparatus was better<br />

and he had more precise measurements. Secondly Charles never published<br />

his work on the relationship between a gas’ volume and its temperature. That<br />

distinction would go to Gay Lussac. (Ellyard, 2005)<br />

After the French Revolution, fourteen year old Joseph Gay-Lussac<br />

went to Paris. It was here that he received private lessons and attended<br />

boarding school. He eventually became an assistant to French chemist<br />

Claude Louis Berthollet who trained him in chemical research. During the<br />

winter <strong>of</strong> 1801-1802, twenty-four year old Gay-Lussac was encouraged by<br />

Berthollet to conduct research on the expansion properties <strong>of</strong> gases. (Green,<br />

Peterson, 1992)<br />

Gay-Lussac wanted to get results that were more accurate than those<br />

obtained by Charles and others. In his experiments he “excluded water<br />

vapors from his apparatus and made sure that the gases themselves were free<br />

<strong>of</strong> moisture.” He concluded that “equal volumes <strong>of</strong> gases expand equally<br />

with the same increase in temperature.”(Lussac, 1802)<br />

There were some differences between his results and Jacques Charles.<br />

First <strong>of</strong> all, Gay-Lussac published his results while Charles did not. Gay-<br />

Lussac also measured the coefficient <strong>of</strong> expansion while Charles did not.<br />

Charles only investigated oxygen, carbon dioxide, nitrogen and air.Gay-<br />

Lussac’s results worked for all gases. Finally, because Charles had water in<br />

his apparatus, his results showed an unequal expansion for the gases that<br />

were water soluble. Gay-Lussac had obtained more accurate results and<br />

published them yet the law is still more commonly referred to as Charles’<br />

Law than Gay-Lussac’s Law. (Green, Peterson, 1992)<br />

Like Charles before him, Gay-Lussac was an avid balloonist. In 1804<br />

he flew to an altitude <strong>of</strong> 23,000 feet which was a record that stood for half <strong>of</strong><br />

a century. Eventually as, Charles predicted, hot air balloons were replaced<br />

by hydrogen filled and later helium filled balloons. In the 1960’s hot air<br />

ballooning became popular again as a sport. (Reese, 2004)<br />

Charles and Gay-Lussac’s results helped other scientists discover the<br />

absolute zero temperature <strong>of</strong> a gas. This is done by locating the theoretical<br />

temperature in which gas has a volume <strong>of</strong> zero. (Ellyard, 2005) This is the<br />

coldest temperature possible. It has never been achieved because gas<br />

liquefies before reaching this temperature and is no longer subject to the gas<br />

laws. (McGrath, 2005)<br />

6


References<br />

Ellyard, David (2005)<br />

Who Discovered What When.<br />

Sydney: Reed New Holland.<br />

Gay-Lussac, Joseph (1802)<br />

Annales de Chimie 43, 137 (1802) [reprinted in William Francis<br />

Magie, ed., A Source Book in Physics (New York: McGraw-Hill,<br />

1935)]. First Section. Retrieved February 19,2007 from<br />

http://web.lemoyne.edu/~giunta/gaygas.html<br />

Green. Jeffery M., Peterson, Andy (1992)<br />

Gay-Lussac-Scientist. Retrieved February 19,2007 from<br />

http://www.woodrow.org/teachers/ci/1992/Gay-Lussac.html<br />

McGrath, Kimberly (ed.) (2005)<br />

World <strong>of</strong> Physics. Farmington, Michigan:<br />

Thomas Gale Publishing. Retrieved February 19, 2007 from<br />

http://www.bookrags.com/research/charles-law-wop/<br />

Reese, K.M. (2004)<br />

Gay-Lussac, Balloon Pioneer. Chemical Engineering News.<br />

Volume 82(25) Pg 56<br />

Thall, Edwin (n.d)<br />

Thall’s History <strong>of</strong> Gas Laws. Retrieved February 19,2007 from<br />

http://mooni.fccj.org/~ethall/gaslaw/gaslaw.htm<br />

*Soda can demonstration and balloon lab based on those found in The<br />

<strong>School</strong> District <strong>of</strong> Philadelphia’s 8 th Grade Science Textbook.<br />

Holt Science and Technology: Introduction to Matter (2005)<br />

Holt, Reinhart and Winston: Austin Texas.<br />

* All photos are the property <strong>of</strong> William J. Wagenborg Jr. and may not<br />

be used by anyone in any way.<br />

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Pictures To Be Used For <strong>Lesson</strong><br />

Jacques Charles<br />

(http://dbhs.wvusd.k12.ca.us/webdocs/GasLaw/Gas-Charles.html<br />

Joseph Gay-Lussac<br />

(http://dbhs.wvusd.k12.ca.us/webdocs/Gallery/Gallery6.html)<br />

http://discover.edventures.com<br />

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More Links<br />

These are links to some Charles’ Law graphics.<br />

http://www.1728.com/charles.htm<br />

http://exploration.grc.nasa.gov/education/rocket/glussac.html<br />

http://www.chem.iastate.edu/group/Greenbowe/sections/projectfolder/flashfiles/gaslaw/c<br />

harles_law.html<br />

These are links to more information on hot air ballooning.<br />

http://www.planoballoonfest.org/balloon_history.html<br />

http://www.nationalballoonmuseum.com/exhibits.cfm?exhibitid=18<br />

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