Absorption fluids data survey: final report on worldwide data

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ORNL/Sub/84-47989/3
ABSORPTION FLUIDS DATA SURVEY:
FINAL REPORT ON WORLDWIDE DATA
R. A. Macriss
J. M. Gutraj
T. S. Zawacki
Date Published-February 1988
Prepared by
INSTITUTE OF GAS TECHNOLOGY
Chicago, Illinois 606 16
under
Subcontract 8 6X-4798 9 C
for the
ENERGY DIVISION
OAK RIDGE NATIONAL LABORATORY
Oak Ridge, Tennessee 37831
operated by
MARTIN MARIETTA ENERGY SYSTEMS, INC.
for the
U.S. DEPARTMENT OF ENERGY
under contract DE-AC05-840R2 1400
3 Y45b 031554? b

TABLE OF CONTENTS
Page
LIST OF FIGURES
LIST OF TABLES
SUMMARY OF RESULTS
ABSTRACT
V
vi i
i X
xiii
1.
2.
3.
4.
5.
6.
INTRODUCTION
METHOD AND SCOPE
2.1. FLUID PROPERTIES AND DATA
2.2. COARSE SCREENING OF LITERATURE DATA
DETAILED PRESENTATIONS AND TABULATIONS
3.1 . REFRIGERANTS AND ABSORBENTS
3.2. FLUIDS, PROPERTIES, AND NUMBER OF REFERENCES WITH DATA
3.3. COARSE SCREENING OF DATA FOR SELECTED FLUIDS
3.4. FINE SCREENING OF NH3-BzO DATA
3.5. GAPS IN THE DATA OF KEY FLUIDS
ACKNOWLEDGEMENTS
RE FE RENCE S
APPENDIX. FLUIDS, PROPERTIES, DATA, AND KANGE OF CONDITIONS
1
2
2
3
4
4
17
41
60
71
89
90
A- 1
iii

LIST OF FIGURES
Figure
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
Number of references for vapor-liquid equilibrium <strong>data</strong>
Number of references for crystallization temperature <strong>data</strong>
Number of references for corrosion <strong>data</strong>
Number of references for heat of mixing <strong>data</strong>
Number of references for liquid-phase density <strong>data</strong>
Number of references for vapor and liquid-phase enthalpy
<strong>data</strong>
Number of references for specific heat <strong>data</strong>
Number of references for stability <strong>data</strong>
Number of references for viscosity <strong>data</strong>
Number of references for mass and heat transfer, thermal
conductivity, and refractive index <strong>data</strong>
Number of references for flammability, toxicity, entropy,
and surface tension <strong>data</strong>
Comparison of NH3 + H20 vapor pressure-concentration <strong>data</strong>
Comparison of measured and predicted vapor composition
of the NH3 + H20 pair at 60°C
Comparison of ammonia-water enthalpy <strong>data</strong> at 60°C
Comparison of H20 + LiBr vapor pressure <strong>data</strong>
Comparison of CH30H + LiBr vapor pressure-concentrat ion
<strong>data</strong>
Comparison of CH3.0H + LiBr viscosity <strong>data</strong>
Comparison of CH30H + ZnBr2 vapor pressure-concentration
<strong>data</strong>
Page
18
26
28
29
31
33
35
36
37
39
40
43
45
47
49
51
53
54
19
Comparison of methanol + LiBr:
<strong>data</strong>
ZnBr2 (2:l) vapor pressure
55
20
21
Comparison of R22 + DMETEG vapor pressure-concentration
<strong>data</strong>
Comparison of R21 + DMETEG vapor pressure <strong>data</strong>
V
58
59

LIST OF FIGURES, Cant.
Figure
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
4@
41
42
43
44
Comparison of R22 + DMA vapor pressure <strong>data</strong>
Comparison of R25 + DkfH and 1322 + DNPI vapor pressure <strong>data</strong>
Comparison of methylamine + sodium thiocyanate vapor
pressure <strong>data</strong>
Comparison of total pressure <strong>data</strong> at 80°C
Comparison of total pressure <strong>data</strong> at 133°C
Comparison of predicted and measured relative volatilities
Comparison of measured and projected pressure at 133°C
Comparison of projected and measured relative volatilities
Cornparison of projected and measured relative volatilities
Comparison of projected and measured relative volatilities
Gaps in vapor-liquid equilibrium <strong>data</strong> for key <strong>fluids</strong>
Gaps in crystallization temperature <strong>data</strong> for key <strong>fluids</strong>
Gaps in corrosion <strong>data</strong> for key <strong>fluids</strong>
Gaps in toxicity <strong>data</strong> for key <strong>fluids</strong>
Gaps in heat and mass transfer <strong>data</strong> for key <strong>fluids</strong>
Gaps in viscosity <strong>data</strong> for key <strong>fluids</strong>
Gaps in vapor- and liquid-phase enthalpy <strong>data</strong> for key <strong>fluids</strong>
Gaps in thermal conductivity <strong>data</strong> for key <strong>fluids</strong>
Gaps in specific heat <strong>data</strong> for key <strong>fluids</strong>
Gaps in density <strong>data</strong> for key <strong>fluids</strong>
Gaps in stability <strong>data</strong> for key <strong>fluids</strong>
Gap6 in heat transfer additive <strong>data</strong> for key <strong>fluids</strong>
Gaps in corrosion inhibitor <strong>data</strong> for key <strong>fluids</strong>
Page
61
62
63
65
67
69
70
72
73
74
76
77
98
79
80
81
82
a3
84
85
86
87
88
vi

LIST OF TABLES
-- Table No.
1 Refrigerants
2 Absorbents (inorganic)
3 Absorbents (organic)
4 Absorbents (mult€component) ’
5 List of arbitrary abbreviations for organic compounds
6 Deviation of solubility <strong>data</strong> from various sources
from the <strong>final</strong> smoothed values for R22-DMETEG
Page
5
7
9
13
14
57
vi i

OF RESULTS
Over 500 different worldwide publications containing <strong>data</strong> relating to
properties of binary, ternary, and multicomponent absorption <strong>fluids</strong> were
identified. Of these, over 150 manuscripts include applications of absorption
fluid properties <strong>data</strong> toward evaluation, assessment, or design of chillers or
heat pumps but do not include actual fluid properties <strong>data</strong>.
Of the remaining
350 manuscripts, <strong>data</strong> have been extracted and catalogued from 278 manuscripts
with relevant primary source <strong>data</strong>. The publications date as far back as 1901,
but nearly 90% of the documents were published between 1960 and 1987.
texts of the 278 manuscripts are i n English, German, Japanese, Russian, or
French.
The absorption <strong>fluids</strong> covered in the 278 documents are combinations of 38
different "refrigerant" compounds and 131 single, 42 binary and 14 ternary
"absorbent" compounds.
following categories of chemical compounds:
The
Generally, the 38 refrigerants are divided among the
Refrigerants I-
Inorganic
Organic
e
@
Amines
Alcohols
Halogenated
Nydroearbons
3
35
4
5
25
1
The single absorbent compounds are generally subdivided as follows:
Absorbents
Inorganic
Organic
e
0
0
0
0
0
e
e
0
0
@
Alcohols
Ethers
Alcohol-ethers
Amides
Amines
Atnine-alcohols
Esters
Ketones
Acids
Aldehydes
Others
48
83
10
5
3
9
4
1
21
5
4
1
20
ix

The binary and ternary absorbents are various mixtures of two or more single
absorbent compounds.
In terms oE absorption fluid properties, for which <strong>data</strong> are available in
the 278 primary documents, the list below reveals that vapor-liquid
equilibrium is the predominant property, <strong>report</strong>ed in almost 60% of the
documents.
in only two documents.
Toxicity or flammability of <strong>fluids</strong>, on the other hand, is <strong>report</strong>ed
Thermodynamic, transport, and other <strong>data</strong>
*
Fluid property -
Number of references
Vapor-liquid equilibrium 180
Enthalpy 74
Specific heat 54
Viscos i-ty 47
Heat of mixing 52
Density 53
Crystallization 52
Surf ace tension
Corrosion (and inhibitors)
Thermal conductivity
Entropy
Stability
Re€ ractive index
Heat transfer
Mass transfer
Toxicity
Flammabil i ty
A list of several key absorption <strong>fluids</strong> currently of interest to
researchers of advanced absorption heat pumps is also shown below:
Key <strong>fluids</strong>
(see Table3 for abbreviations)
18
25
10
16
9
7
5
10
1
1
CW30H-LiBr-ZnBr2
TF E- NMP
TFE-DMEDEG
* A given document may contain <strong>data</strong> relating to more than one property;
therefore, the sum of the references is larger than 199.
X

NH3-NaSCN
H20-Li Br
H2O-LiBr-LiCl
H20-EiBr-LiSCN
M20-LiBr-ZnBr2
TFE-DHETEG
CH3NH2-R20-Li
RZP-DMETEG
R22-DPIEDEG
R22-DHETEG
Br
for
the
0
0
9
e
@
Coarse screening and evaluations were carried out as part of this study
selected or key absorption <strong>fluids</strong>. Several approaches were considered for
review and coarse screening of <strong>data</strong> from multiple sources. These include
Consideration of the author's statements concerning <strong>data</strong> quality;
Assessment of the measurement technique and apparatus used to develop the
<strong>data</strong>;
Consideration of a given author's reputation for measuring <strong>data</strong>, where
only one author's <strong>data</strong> were available for a fluid;
Comparison of <strong>data</strong> plots for a given fluid using <strong>data</strong> scatter and internal
consistency criteria to judge <strong>data</strong> quality and multiple-author <strong>data</strong>
agreement; and
Consideration of general trends of the plotted <strong>data</strong> as inferred from <strong>data</strong>
for similar or homologous series <strong>fluids</strong>.
The coarse screening addressed <strong>data</strong> from multiple SOUKC~S for several
different fluid systems (PIW3-R209 NZO-LiBr, CH30H-ZnBr2, C1130W-LiBr, R22-
DMETEC), covering several propertiesa The number of alternate <strong>data</strong> sources
varied from 2 to 4, and the 5 <strong>fluids</strong> shown in parenthesis are the only ones
with <strong>data</strong> from nultiple sources abstracted to date.
Data gaps for key <strong>fluids</strong> have been summarized- Unresolved or potential
conflicts in the <strong>data</strong>, lack of <strong>data</strong> for known key <strong>fluids</strong> at conditions beyond
the limits of present <strong>data</strong>, and new <strong>fluids</strong> without property <strong>data</strong> constitute
these summaries. A prioritized system to fill such gaps on a fluid-by-fluid
and property-by-property basis was devised €or quick reference.
With very few exceptions, and with emphasis on current development activities
dealing with advanced absorption heat pump concepts, almost all
candidate <strong>fluids</strong> have <strong>data</strong> gaps that need to be addressed in the near future.
Xi

ABSTRACT
Over 500 different worldwide publicattons containing <strong>data</strong> that relate to
properties of
nary, ternary, and mmlt Lcomponent. absorption <strong>fluids</strong> have been
identified; from tkeae publications
278 were selected as primary sources of
relevant <strong>data</strong>, Fluids covered include combinations oi 38 different
refrigerant compounds, as weill as of 131 single, 42 binary, and 14 ternary
absorbent compounds, Generally, t h ~ 38 refrigerants are divided among the
fall owlng categories of chemai cal compounds E inorganic 3; organic, 35
(amtnes, 4; alcohols, 5; halogenated, 25; and hydrocarbons, 1). The single
absorbent compounds generally are subdivided as follows: inorganic, 48;
organic, 83 (alcohols, 10; ethers, 5; alcohol-ethers, 3; amides, 9; amines, 4;
amine-alcohols, 1; eaters, 21; ketones, 5; acids, 4; aldehydes, 1; and others,
20). The binary and ternary absorbents are variow mixtures of two or more
single absorbent compounds e
performed.
in <strong>data</strong> are not:ed.
Coarse screening and evaluations were
Data gaps for key <strong>fluids</strong> are summarized and unresolved conflicts
Results S~QW that, with very few exceptions, all candidate
<strong>fluids</strong> for development activities dealing with advanced absorption heat pump
concepts have <strong>data</strong> gaps that: must be addressed in the near future.
xiii

Over the past 86 years9 a wealth of physical. and thermodynamic property
<strong>data</strong> has been developed for fluid systems that: are potentially applicable to
the absorption ref rigerationlheat pump eycl.e,
<strong>data</strong> is available in the literature, some <strong>data</strong> remain confined to in-house
files for various reasons, and other <strong>data</strong> are proprietary but could be made
available under certain conditione or terms.
A si nificant portion of the
Generally, published <strong>data</strong> have been generated in areas of temperature,
pressure, and composition of Interest to designers of absorption chillers or
coolers.
tions, using multieffect or multistage concepts ~
cooling.
for both space heating and
These new designs operate at temgera%urcs and pressures signifi-
cantly higher than those encountered in the conventisnal absorption caolitig
cycle.
Recent research has focused on developing efficient cycle configura-
Other new concepts are based an the addition of a third component to
the binary s~liitle~ns normally used in the conventional cyc1.e.
11% an effort to define the availability and quality of existing <strong>data</strong> and
thereby ta assist in the determination sf needs for new <strong>data</strong> useful to
advanced concepts, the Institute of Gas Technology (Tell> has performed an
extensive literature search and a coarse screening of ,?xisting U.S. and
foreign literature <strong>data</strong> to identify potential conflicts or gaps in the <strong>data</strong>
for eertaln key fluid systems.
IGT ' 8 findings
This <strong>report</strong> provides a detailed account of
The information and <strong>data</strong> rnntakned in this <strong>report</strong> are presented in a
format utilized in two earlier <strong>report</strong>s (ORNL/SUB/84-4798/1
and ORNL/SUB/84-
4798/2) that covered, in past, similar <strong>data</strong> developed in the United States and
abroad over the past 86 yearsc
1.

2. METHOD AND SCOPE
Literature searches and site visits were undertaken to identify and
obtain available publications - several dating back to 1981 - on pertinent
physical, thermodynamic, and transport properties of absorption <strong>fluids</strong>. The
bulk of references identified contain <strong>data</strong> developed mainly in the United
States, West Germany, France, Britain, Japan, and the USSR. Cross-checks of
literature searches were also made, using available published bibliographies
and literature review articles, to eliminate secondary sources €or the <strong>data</strong>
and thus include only original sources and manuscripts.
2 "1. FLUID PROPERTIES AND DATA
The properties of these <strong>fluids</strong> relate to the liquid and/or vapor state
encountered in normal operation of absorption equipment employing such <strong>fluids</strong>,
and to the crystallization boundary of the liquid phase, where applicable.
The actual <strong>data</strong> were systematically classified according to type of fluid and
property as well as to temperature, pressure, and concentration ranges over
which <strong>data</strong> were available. Data were sought for at least 17 different
properties, as follows:
Mixture properties-
1. Vapor-liquid equilibria 18. Mass transfer rate
2. Crystallization temperature 11. Heat transfer rate
3. Corrosion characteristics 12. Thermal conductivity
4. Heat of mixing 13 e Refractive index
5. Liquid-phase densities 14. Entropy
6. Vapor-liquid-phase enthalpies 15. Surface tension
7. Specific heat 16. Toxicity
8. Stability 17. Flammability
9. Viscosity
The type of available <strong>data</strong> was of importance, with raw experimental <strong>data</strong>
considered to be highly desirable for use in actual process and equipment
design and sizing and €or process design correlation development. For this
reason, raw tabulated experimental <strong>data</strong> were given the highest possible ranking,
with other forms of <strong>data</strong> following in importance, as shown below:
2

Raw expe r i mental.
e
e
Tabular
Graphical
Smoothed experIra1ental
9 Tabular
@ Graphical
Empirical polynuroial
Equations of etate
Empirical polynomiaP relationships haseel on raw or swothad experimental
<strong>data</strong> are often rep~~ted. Such correlations are at beat as good as the experi-
mental <strong>data</strong> and can help factlitate the use of the <strong>data</strong> in performance and
design calculations through automation (coilaputer software and terminals 1.
the absence of <strong>data</strong>, t-eEiablc methods 0f prediction have been sought (equa-
tions of state, generalized eorrelatfons) but are expected to possess greater
uncertainties than the previous forms sf <strong>data</strong>.
2.2. COARSE SCREENING OF LITERATURE DATA
Several approaches have been used In carrying out quality review and
coarse screening of <strong>data</strong> from multiple sources fof each of several key or
highest-priority binary <strong>fluids</strong>. These alternative approaches include
* Consideration of the author's statements concerning <strong>data</strong> quality;
In
@
Assessment of the rneasuretnent tachniqiie and apparatus used in obtaining
the <strong>data</strong>; and.
Consideration of a given aiitkl~r's reputatton for measuring dath, where
only one author's <strong>data</strong> were ava.PlabLe for a fluid.
A more reliable method used Lo compare dam from various sourcc6 fat- a
given fluid and property has been the plotting ai <strong>data</strong> on a common basis.
Such plots have also served to reveal the amarxnt of scatter or internal. con-
sistency of a given author's <strong>data</strong> and, therefore, its quality.
Another ap-
proach was based on consideration of general. trends of the plotted <strong>data</strong>, as
inferred from <strong>data</strong> for similar OF homol.ogaus series <strong>fluids</strong>.
3

3. DETAILED PRESENTATIONS AND TABULATIONS
As previously implied, this <strong>report</strong> was organized to cover the various
work elements of this study in their natural sequence.
This portion of the
<strong>report</strong> contains a listing of the refrigerants and absorbents of the absorption
<strong>fluids</strong> of this study, the results of the coarse and fine screening of <strong>data</strong> for
key <strong>fluids</strong>, a list of gaps in the <strong>data</strong> of the key <strong>fluids</strong>, and the reference
material accumulated.
The details of the range of conditions over which
property <strong>data</strong> exist for each fluid are 'given in the Appendix.
____I
3.1. REFRIGERANTS AND ABSORBENTS -
Table 1 lists the 38 refrigerants grouped into 5 distinct chemical compound
categories:
hydrocarbons.
inorganics, amines, alcohols, halogenated organics, and
For each refrigerant, Table 1 contains a compound number, chem-
ical formula and name, molecular weight, and normal boiling point (in dual
units).
Table 2 lists 48 single inorganic absorbents and a number, chemical
formula, name, and molecular weight for each.
Table 3 lists 83 single organic
absorbents grouped into 9 distinct chemical compound categories:
alcohols,
ethers, alcohot-ethers, amides, amines, amine-alcohols, esters, ketones, acids,
aldehydes, and an undefined catch-all category.
For each organic absorbent,
Table 3 contains a compound number, an arbitrary abbreviation of convenience,
chemical formula and name, molecular weight, and normal boiling point (indi-
vidual units).
Table 4 lists 56 multicomponent (binary and ternary) absorbents with access
number and chemical formula.
Table 5 is an alphabetical listing of'the
arbitrary abbreviations keyed to the chemical name of the organic compounds,
4

Table 1.
Ref rigetants
Number
Ino raanics
Chemical
formula
Name
NBP NBP
MW (OF) ("C)
--
Amines
Alcohols
8
9
10
11
12
Halogenated organics
N-3
H2O
so2
CH30H
C2H50H
C3H7 OH
C F 3 C82 OH
(CF~)~CHOH
Ammonia 17.0 -28 -33.3
Water 18.0 212 100.0
Sulfur dioxide 64.1 14 -10.0
Me t hyl ami ne 31.1 21 -6.1
Ethylamine 45.1 62 16.6
Dlme thyl amine 45.1 45 7.4
T rime thyl ami ne 59.1 38 3.5
Met hana 1 32.0 149 65.0
Ethanol 46.1 173 78.3
n-Pr opanol 60.1 207 97.2
Tr i f luo roe thanol 100.0 164 73.6
Hexafluoroisopropanol 168.0 138 59.0
13
14
15
16
17
18
19
20
21
22
23
24
25
CHFC1.2
CHF2C1
CHZC12
CH2ClF
CF3CHC12
CHC1FCC1F2
CHC 1F CF
CHF2CC1 F2
CHC 1 ZCHC 1F
CHF2CHClF
Refrigerant 11
Refrigerant 12
Refrigerant 13
Re E rig e rant 21
Refrigerant 22
Refrigerant 30
Refrigerant 31
Refrigerant 123
Refrigerant 123a
Refrigerant 124
Refrigerant 124a
Refrtgerant 131a
Refrigerant 133a
137.4
120.9
104, S
102.9
86.5
84.9
68.5
152.9
152.9
136.5
136.5
151.4
118.5
75
-21
-8 1
48
-41
104
16
82
85
10
15
185
42
23.9
-29.4
-113.8
8.9
-40.6
40.0
-8.9
27.8
29.4
-1 2.1
-9.4
85.0
5.6
5

Table 1.
(cont.)
Number
Chemical
formula
Name
NBP
MI4 (OF)
--
NBP
("C)
26
27
CHF 2CHF 2
CC1~NCC1W2
Refrigerant 134
Refrigerant 140a
102.0
133.4
49
235
94.0
112.8
28
29
30
31
CH3CF3
CH2FCH2F
CHClCHCl
CClPCClF
Re f'r i ge r an t 14 3 a
Refrigerant 152
Refrigerant 1130
Refrigerant 1112a
84.0
66.0
96.9
132.4
-5 3
86
138
66
-47.0
30.0
58.9
18.9
32
33
34
35
36
37
CC12CClH
C2F3H
C2F3C1
C3F6
CH3CF2Cl
C3HF58
Refrigerant 1120
Refrigerant 1123
Refrigerant 1 113
Refrigerant 216
Refrigerant 142
Pentafluoropropionic
acid
131.4
82.0
116.5
150.0
100.6
164.0
180
ND
-18
-2 1
ND
232
82.2
ND
-27.9
-29.4
ND
97.0
Hvd r ocarbons
38 Bexane 86.0 154
68.0
ND - Not determined.
6

Table 2.
Absorbents (inorganic)
Number -
Chemical
formula
Name
-c
- Mw
1
NH4 R r
Ammonium bromide
98.0
2
NH4I
Ammonium iodide
144.9
3
CaBr2
Calcium bromide
199.9
4
CaC 12
Calcium chloride
111.0
5
CsC2H302
Cesium acetate
192.0
6
CsBr
Cesium bromide
212.8
7
CSCl
Cesium chloride
168.4
8
C8F
Cesium fluoride
151.9
9
CsOH
Cesium hydroxide
149.9
10
CO ( SCN ) 2
Cobalt thiocyanate
175.1
11
CU ( SCN ) 2
Cupric thiocyanate
179.7
12
CuSCN
Cuprous thiocyanate
121.6
13
LiC2H302
Lithium acetate
66.0
14
LiBr
Lithium bromide
86.8
15
LIC103
Lithium chlorate
90.4
16
LiC 1
Lithium chloride
42.4
17
LiH2PO-3
Lithium hydrogen phosphite
96.1
18
LiI
Lithium iodide
133.8
19
UNO3
Lithium nitrate
68.9
20
LiN02
Lithium nitrite
52.9
21
Lias04
Lithium sulfate
109.9
22
LiRF4
Lithium tetrafluoroborate
93.7
23
LiScN
Lithium thiocyanate
, 65.0
24
LiCC13CO*
Lithium trichloroacetate
169.3
25
LiCP3 co2
Lithium trif luoroacetate
112.0
26
Ni (SCN),
Nickel thiocyanate
rJr)
27
KRr
Potassium bromide
119 .O
28
KC1
Potassium chloride
74.6
29
KF
Potassium fluoride
58.1
30
ROH
Potassium hydroxide
56.1
31
KNO3
Potassium nitrate
101 . 1
7

Table 2.
(cont.)
Chemical
Number formula Name
___I
Mw
_c_
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
RbBr
RbCl
RbF
Rb I
NaBr
NaC 1
NaOH
NaT
NaN03
Na2S04
NaSCN
H2 SO4
H20
ZnR r
ZnC12
Zn(N03 12
Zn( S CN ) 2
Rubidium bromide
Rubidium chloride
Rub id ium f luo r ide
Rubidium iodide
Sodium bromide
Sodium chloride
Sodium hydroxide
Sodium iodide
Sodium nitrate
Sodium sulfate
Sodium thiocyanate
Sulfuric acid
Water
Zinc bromide
Zinc chloride
Zinc nitrate
Zinc thiocyanate
165.4
120.9
104.5
212.4
102.9
58.4
40.c)
149.9
85.0
142,O
81.1
98.0
18.0
225.2
136.3
127.4
181.5
8

Table 3.
Absorbents (organic)
_I No. Abbrev. Chemical formula Name
Alcohols
49 1,4 BDL HOC4HsOH 1, 4-Butanediol
50 2,3 BDL CH3CHOHCHOHCH3 2, 3-Butanediol
51 EG HOC2H4OH Ethylene glycol
52 DEG (HOCHzCH2)20 Diethylene glycol
53 TEG H( oc2H4) 40H Tetraethylene glycol
54 n-HA n-C7H15OII n-Ileptyl alcohol
55 BA CgHgCH20H Benzyl alcohol
56 GYL CH2 OHCHOH CH2 OH Glycerol
57 PD HOCHz(CH2) 3CH2OH Pent anedi 01
58 HDL HOCH2(CH2)4CH2OH Hexanediol
NBP NBI
MW (OF) ("C)
-__I-
90.1 455 235.
90.1 358 181,
62.1 388 197.
194.2 622 327.1
116.2 349 176.:
108.2 402 205.(
92.1 554 290.C
104.2 463 239.4
118.2 482 250.0
Ethers
59 DMEDEG CH3(OCzH4) 2OCH3 Dimethylether diethylene glycol 134.2 324 162.2
60 DMETrEG CH3(OC2H4)30CB3 Dimethylether triethylene glycol 178.2 421 216.1
61 DMETEG CH3(OC2H4)40CH3 Dimethylether tetraethylene glycol 222.3 528 275.6
62 ETFE (C4H70)CH,OC2Hs Ethyl tetrahydro furfuryl ether 130.2 316 157.8
63 DBC C4Hg(OC2Hq) 20C4Hg Dibutyl carbitol 218.3 ND ND
A1 co hol-e thers
64 MBEDEG HOfCH2)20(CH2)20CqHg Monobutylether diethylene glycol \ 162.2 448 231.0
65 MEDEG H(OC~H,J+)~OC~H~ Monoethylether diethylene glycol 134.2 383 195.0
66 METrPG C~HS(OC~H~)~OH Monomethylether of tripropylene 220.3 ND ND
glycol
Amides
67 DMF CHON( CH3) 2 N, N - Dimethyl formamide 73.1 302 150.0
68 DMA CH-jCON( CH3) 2 N, N - Dimethyl acetamide 87.1 329 165.0
69 DMH C~H~ICON(CH~)~ N, N - Dimethyl hexanamlde 143.2 428 220.0
70 DMD CiiH23CON(CH3)2 N, N - Dimethyl dodecanamide 217.3 ND ND
71 DEF CHON(C~H~) N, N - Diethyl formamide 101.2 351 172.2
72 TMM [(CH3)2NCOCH2CONCOH3]2 N, N, N, N - Tetramethylmalonamide 158.2 ND ND
9

30. Abbrev. Chemical formula Name
I_
NBP NBP
MW (OF) ("C)
--_I_.
73 TMS (CH3) 2NCOCH2 I 2 N, N, N, N - Tetramethylsuccinamide 172.2 ND ND
74 DMAN CgHgN (CH3 2 N, N - Dimethyl aniline 121.2 381 193.9
75 HMPT [ (CH-3) 2N] 3PO Hexamethylphosphoric acid triamide 179.2 NO ND
Amines
76 QUN C9H7N
77 MCAN Cg H5CLNH2
78 AN 'gHgNH2
79 OCA C8Hl 7NH2
Ami ne-a 1 coho1
80 MEA H2NCH2CH20H
Quinoline
M-Chloro aniline
Ani 1 ine
Octylamine
129.2 465 240.5
127.6 446 230.0
93.1 363 183.9
129.3 359 181.7
Et ha ti0 1 amine 61.1 338 170.0
Esters
81 PBA
82 DMPH
83 DET
84 DBP
85 DOP
86 DDP
87 DCP
88 DBS
89 DOS
90 TAN
91 ETL
92 DE0
93 DEAP
94 DEM
95 MB
96 EB
97 PB
98 n-BB
Isobutyl acetate
Dimethyl phthalate
Diethyl phthalate
Dibutyl phthalate
Dioctyl phthalate
Didecyl phthalate
Dicapryl phthalate
Dibutyl sebacate
Dioetyl sebacate
Triacetin
Ethyl laurate
Diethyl oxalate
Diethyl adipate
Diethyl malonate
Methyl benzoate
Ethyl benzoate
Propyl benzoate
n-Butyl benzoate
116.1 244
194.2 540
222.2 576
278.3 644
390.4 ND
446.3 ND
334.3 ND
314.4 651
426.7 ND
218.2 498
222.4 523
146.1 366
202.2 473
160.2 391
136.1 384
150.2 415
164.2 448
178.2 483
118.0
282 .O
302.0
340.0
ND
ND
ND
344.0
ND
258.9
27 2.8
185.6
245 e 0
199 4
195.5
212.8
195.5
250.6
10

~ 198.4
Table 3.
(cont.)
- No. Abbrev, Chemical formula Name
-- Mw
99 TBP (C4Hg0) 3po Tri-butyl phosphate 266.3
100 MSA C6H4(0H)C02CH3 Methyl salicylate 152.2
101 BZA CgHg (CH2C02CH3) Benzyl acetate 150.2
Ketones
552 28
452 23
420 21
102 4, BLN (CH2)3CO2 4-Butyrolactone
103 NMP CtjHgNO N-Methyl-2-pyrrolidone
104 2-(OCN) CaH160 2-Oc tanone
105 2,4 PON CH3COCHZCOCH3 2-4 pentanedione
106 APN C6115COCH3 Ace t o p h e no ne
Acids
86.1
99.1
128.2
100.1
120.2
403 20t
394 201
343 172
282 13E
396 202
107 PPA
108 LLA
109 OA
110 VA
A1 de hyde s
CH3CH2COOH
Propionic acid
C18H3202
Linoleic acid
‘1 8’34’2 Oleic acid
‘gH1002
Valeric acid
74.1 287 141
280.5 ND ND
282.5 689 365
102.1 367 186
111 BAD
C7H60
Ben z a Id e hyde
106.1 353 178,
Others
I-
112 TDK
113 DWA
114 BZL
115 DMMP
116 DMSO
117 NB
118 PDS
119 oc
120 MM
121 LBS
122 UTN
Tet radecane
Dowtherm A
Benzothiazole
Dimethyl methyl phosphonate
Dimethyl sulfoxide
Nitrobenzene
Polyd ime t hyls iloxane
Octyl cyanide
N-Me thylmorphol ine
Lithium benzenesulfonate
Utropin
170.2
135.2
124.1
78.1
123.1
ND
139.2
101.2
164.1
140.0
252
446
448
175
372
411
ND
436
241
ND
ND
122”
257.
231.
79.
189.
210.
ND
224.
116.
ND
ND
11
... ~
.............................

Table 3.
(cont.)
-
Abbrev.
L DMEU C5w1 ON20
i DMPU '6*l 2N20
5 NMC C7H 13 No
6 NFM 'gHgN02
7 EC C3H403
8 PC C48703
.9 SL 'qHgS02
LO CUM c9f1802
Chemical formula
Name
MW (OF) ("C)
_I_--
1,3 Dimethyl-2-imidazolidinone 114.2 433 223.0
I'D ime t hy 1 et hy 1 enu r ea"
1,3 Dimethyl-3,4,5,6 tetrahydro- 128.2 450 232.0
2 (111)-pyrimidinone
"Dime t hylpropylenurea"
N-Methyl-E-caprolactam 101.1 ND ND
N-Formylmorpholine 115.1 471 244.0
Ethylcarbonate 88.1 460 238.0
Propylenecarbonate 102.1 467 242.7
Sulf olane 120.2 549 287.0
Dihydrocoumarin 148.2 522 272.0
11 DCN '1 9H2602 Dieumylmethane 202,3 ND ND
ND - Not determined.
12

Table 4.
Absorbents (multicomponent)
Binary
Te rna ry
-
Cherni ea1 Chemical Chemical
No. formula No. formula NO formula
___I
__I
Bi-1 LiBr: LiCl Bi-23 LiI: EG Te-1 LiBr: ZnBr2: DEG
Bi-2 LiBr: LiSCN Bi-24 LiI: ZnBr2 Te-2 LiBs: ZnBr2: EG
Xi-3 LiBr: LiClOg Bi-25 LiSCN: NaSCN Te-3 LiBr: ZnRr2: DMEDEG
Ri-4 LiRt: CsBr Bi-26 LiSCN: DMETEG Te-4 LiRr: ZnBr2: MBEDEG
Bi-5 LiBr: ZnBr2 Bi-27 LiSCN: EG Te-5 LiBr: ZnBr2: PD
Bi-6 LiBr: PEA Bi-25 LiSCN: 1, 4 BDL Te-6 LiBr: LiI: EG
Bi-7 LiBr: EG Bi-29 LiSCN: MEA Te-7 LiBr: ZnBr2: CaBr2
Bi-8 LiBr: H20 Bi-30 LISCN: DMF Te-8 LiBr: CsBt: RbBr
Bi-9 LiBr: 4, BLN Bi-31 NaSCN: NaT Te-9 LiBr: RbF: CsF
Bi-10 LiBr: LiI Bi-32 NaSCN: TEG Te-10 NaSCN: NaI: 1, 4, BDL
Bi-11 TABr: ZnC12 Bi-33 NaSCN: 1, 4 BDL Te-11 LiNO3: NaN03: KNO3
Bi-12 LiC1: LiAcetate Bi-34 NaT: 1, 4 BDL Te-12 LiC1: CaC12: ZZI(NO~)~
Bi-13 LiC1: CSCl Bi-35 NHqI: 1, 4 BDL Te-13 R22: DMETEG: RA
Bi-14 LiC1: ZnBr2 Bi-36 CsF: RbF Te-14 NaOH: KOH: CsOH
Bi-15 LiC1: ZnC12 Bi-37 DMETEG: BA
Bi.-16 LiCl: LiSCN Bi-38 DMETEG: DMF
Bi-17 LiCl: CaC12 Bi-39 R22: DMETEG
Bi-18 LiN03: H20 Bi-40 R22: DMA
Bi-19 LiNO;?: LiC103 Bi-41 H20: CrO3
Bi-20 LiN03: 1,4 BDL Bi-42 NaOH: KOH
Bi-21 LiN03: 1,6 HDL
Bi-22 CaBr2: ZnBr2
13

Table 5.
List of arbitrary abbreviations €or organic compounds
Abbreviation
AN
APN
BA
B AD
1,4 BDL
2,3 BDL
4, BLN
BZA
BZTL
CUM
DBC
D BP
DBS
DCP
D DP
DEAP
DEF
DEG
DEM
DE 0
D ET
D CM
DMA
DMAN
DMD
DMEDEG
DMETEG
DME Tr E G
DMEU
DMF
DMH
DMMP
No.
78
106
55
111
49
50
102
101
114
130
63
84
88
87
86
93
71
52
94
92
83
131
68
74
70
59
61
60
123
67
69
115
Chemical name
Aniline
Ace tophenone
Renzyl alcohol
Benzaldehyde
1, 4-Butanediol
2, 3-Butanediol
4-Butyrolactone
Benzyl acetate
Benzothiazol
Dihydrocoumarin
Dibutyl carbitol
Dibutyl phthalate
Dibutyl sebacate
Dicapryl phthalate
Didecyl phthalate
Diethyl adipate
N, N-Diethyl formamide
Diethylene glycol
Diethyl malonate
Diethyl oxalate
Diethyl phthalate
Dicumylme thane
N, N-Dimethyl acetamide
N, N-Dimethyl aniline
N, N-Dimethyl dodecanamide
Dimethylether diethylene glycol
Dimethylether tetraethylene glycol
Dimethylether triethylene glycol
Dimethylethylenurea
N, N-Dimethyl formamide
N, N-Dimethyl hexanarni.de
Dimethyl methyl phosphonate
14

Table 5.
(cant.)
Abbreviation
DMPH
DMPU
DMSO
DOP
DOS
DSJ A
EB
EC
EG
ETFE
ETL
GLY
mL
HFIP
HMPT
IBA
LBS
LLA
MB
MBEDEG
MCAN
MEA
ME DEG
METrPG
MM
MSA
n-BB
n-HA
NB
NFM
NMC
NMP
No.
82
124
116
85
89
113
96
127
51
62
91
56
58
Refrigerant
75
81
121
108
95
64
77
80
65
66
120
100
98
54
117
126
125
103
Chemical name
Dimethyl phthalate
Dimethylpropylenurea
Dimethyl sulfoxide
Dioctyl phthalate
Dioctyl sebacate
Dowtherrn A
Ethyl benzoate
Ethylenecarbonate
Ethylene glycol
Ethyl tetrahydro furfuryl ether
Ethyl laurate
Glycerol
Hexane di 01
Hexafluoroisopropanol
Hexamethylphosphoric acid triamide
Isobutyl acetate
Li thium benzenesul f ona te
Linoleic acid
Methyl benzoate
Monobutylether diethylene glycol
M-Chloro aniline
Monoe tha nolarni ne
Monoethylether diethylene glycol
Monomethylether of tripropylene glycol
N-Me thylmorpholine
Methyl salicylate
n-Bu t y 1 be nz oa t e
n-Heptyl alcohol
Nitrobenzene
N-Formylmorpholine
N-Methyl-E-caprolactam
N-Methyl-2-pyrrolidone
15

Table 5.
(cont.)
Abbreviation
OA
OC
OCA
2-( OCN)
PB
PC
PD
PDS
PFPA
2, 4 PON
PPA
QUN
SL
TAN
TBP
T 1lK
TEG
T FE
TMM
TMS
UTN
VA
No.
.~
109
119
79
104
97
128
57
118
Refrigerant
105
107
76
129
90
99
112
53
Refrigerant
72
73
122
110
Chemical name
Oleic acid
Octyl cyanide
Octylamine
2 -0 c t a none
P r o p y 1. hen z o a t e
Propylenecarbonate
Pentanediol
Polydimethylsiloxane
Pentafluoropropionic acid
2-4 Pentanedione
Propionic acid
Quino 1 ine
Sul f olane
Triaeetin
Tri-butyl phosphate
Tetradeeane
Tetraethylene glycol
T r i € luo roe t hano 1
N, N, N, N-Tetramethylmalonamide
N, N, N, N-Tetranethylsuccinami~~
Utropin
Valeric acid

3.2. FLUIDS, PROPERTIES, AND NUMBER OF REFERENCES WITH DATA
For each fluid and property addressed in this study, the availability of
<strong>data</strong> can be quickly and readily assessed in a series of triangular diagrams. In
each of these figures, the number of references for each fluid and property with
<strong>data</strong> available is placed in a grid. Blank grids in these charts represent fluid
and/or properties for which no <strong>data</strong> references have been found. Where a large
number of references are indicated in the grid for a particular fluid and
property of interest, <strong>data</strong> gaps are expected to be less critical. Where a blank
grid appears for a fluid system of high priority, a critical need is suspected.
Fig. 1 lists the <strong>fluids</strong> and the number of references with vapor-liquid
equilibrium <strong>data</strong> available for each. Fig. 2 lists the <strong>fluids</strong> and the number of
references for each fluid with <strong>data</strong> on crystallization temperature. Similarly,
Fig. 3 lists the number oE references for <strong>data</strong> on corrosion, Fig. 4 for heat of
mixing, Fig. 5 for liquid-phase density, Fig. 6 for vapor- and liquid-phase
enthalpy, Fig. 7 for specific heat, Fig. 8 for stability, Fig. 9 for viscosity,
Fig. 10 for mass and heat transfer rates, thermal conductivity, and refractive
index, and Fig. 11 for flammability, toxicity, entropy, and surface tension.
17

td
m
rl
0 m
cl:
N
N
cl:
m
N
l-i
A
ld
4
m
a
N
r-i
dc;
0
m
ri
ri
I
!%
N
8
m
52
N
n
2
U
v
z m
A
2
u
v
1.9

tu
x
..
cl
cl
la
20

REFRIGERANTS
R-133a
R-124a
R-134
R-11
R-30
R-31
R-12
R-21
R-22
R-123
R-131a
R-140a
R-1112 a
R-1120
R-1130
332
CH3NH2
: BA: DMETEG
R-22 : DMA
R-22: DMETEG
DMETEG: DMF
MCAN
NaSCN
nh41
'DL: Nal
Fig. 1.
(continued).

Y
P-
op
I--
ZZ

EB
R-133a
R-124a
R-134
R-11
R-30
R-31
R-12
R-21
R-22
R-123
R-131a
R-14Oa
tu
w
REFRIGERANTS
R-1112a
R-1120
ABSORBENTS
R-1130
502
CH3NH2
(CH3)pH
(CH313N
C3B,0H
CH3 OB
C2H501i
H2°
NH3
Fig. 1.
(continued).

NNP
R-133a
R-123a
R-134
R-152
R-12 3
R-143
R-12
R-21
h)
+%
REFRIGERANTS
R-22
TFE
AB SORBENTS
: LiBr: EG
Fig. 1.
(continued).

n
a aJ
3
c
*rl
U
CJ
W
25

k
0
w
In
a,
2
(11
&
a,
w
(11
I-a
k
a,
P
E!
?
z
26

27
.
N

t\,
a
REFRIGEWTS
R-133a
R-123a
R-13
R-152
R-1123
R-1113
R-143 .
R-12
R-21
R-22
TFE
CH3m2
C2B5NH2
C3H,0H
C2H~OH
CH30H
B20
NH3
HF '1P
Fig. 4.
Number sf references for heat of mixing <strong>data</strong>.

EFTE
R-133a
R-123a
R-134
R-152
R-123b
R-123
R-143
R-124
R-21
w
3
REFRIGERANTS
R-2 2
TFE
AB SORBENTS
CR3NH2
C2H5NH2
C3H,QM
C2H50H
CH30H
H2°
NH3
HF IP
CH3 { CH
Fig. 4.
(continued).

al
P
e
1
z
31

32
ln

LiBr: ZnEr2; EG
LiC1: CaC12Zn(N03)2
w
l?-133a
R-123a
R-134
R-152
R-123b
R-123
R-143
R-124
R-21
R-22
TFE
AB SORBENTS
Fig. 6.
Number of references for vapor and liquid-phase enthalpy <strong>data</strong>.

n
.
9
M
.d
F
34

.
Kl
+J
Kl
a
k
0
VI
(D
aJ
u
C
aJ
k
a
w
aJ
k
u-1
0
k
aJ
P
El
9
x
35

.
KJ
U
v)
a,
V
C
al
$-I
a,
w
a,
k
W
0
$4
aJ
a
36

NaSCN
--.
ETFE
TEG
NElp
R-133a
R-123a
R-134
1 1 DMETEG
1 1 DMETrEG
DMF
R-152
R-123b
R-123
R-143
R-124
R-21
W
REFRIGERANTS
R-22
TFE
ABSORBENTS
CH3NH2
C2H5m2
C3H70H
C2H50H
CH30H
CSP : RbF
Fig. 9.
Number of references for viscosity <strong>data</strong>.

LiBr
Mass Transfer Rate
Heat Transfer Rate
Br: Baysilone
r: CsF: RbF
Thermal
Conductivity
Refractive Index
Fig. 10.
Number of references for mass and heat transfer, thermal
conductivity, and refractive index <strong>data</strong>.

V
8 I
f:
w
r!E
(d
m
r i
!A
h
n
0
k
u G
w
40

I
3.3. COARSE SCREENING OF DATA FOR SELECTED FLUIDS
As mentioned earlier, large amounts of <strong>data</strong> and references for any fluid do
not always guarantee adequate coverage of <strong>data</strong> needs at a required level of
precision.
In fact, they may only denote relative importance of a given fluid
for an application and/or the existence of conflicts in important property <strong>data</strong>,
which often are difficult to measure.
In such cases, a first-order or coarse
screening and evaluation of <strong>data</strong> for key <strong>fluids</strong>, properties, and regimes is of
paramount importance.
Such screening and evaluations were carried out as part
of this study for selected or key absorption <strong>fluids</strong>.
Several approaches were considered for use in carrying out the review and
coarse screening of <strong>data</strong> from multiple sources.
These include
0 Consideration of the author's statements concerning <strong>data</strong> quality;
0 Assessment of the measurement technique and apparatus used to develop the
<strong>data</strong>;
* Consideration of a given author's reputation for measuring <strong>data</strong>, where only
one author's <strong>data</strong> were available for a fluid;
0 Comparison of <strong>data</strong> plots for a given fluid using <strong>data</strong> scatter and internal
consistency criteria to judge <strong>data</strong> quality as well as multiple-author <strong>data</strong>
agreement ; and
Consideration of general trends of the plotted <strong>data</strong> as inferred from <strong>data</strong>
for similar or homologous series <strong>fluids</strong>.
Particular emphasis was placed on screening <strong>data</strong> of <strong>fluids</strong> that were either
already in use in commercial or prototype absorption cooling equipment or
identified as potentially useful in absorption systems and subsequently
experimentally investigated.
Examples of such <strong>fluids</strong> are
0 In commercial equipment, NH3-H20, H20-LiBr
0 Identified as potentially useful for heat pumps
- Organic/<strong>fluids</strong>, R21-DMETEG, R22-DMETEG, etc.
Methanol/salt; CH30H-LiBr, CH30H-LiBr or ZnBr2, etc.
In most instances, researchers have first focused on the development of
vapor-liquid equilibrium <strong>data</strong> for these <strong>fluids</strong> and secondarily on other properties
such as enthalpy, viscosity, stability, etc. Therefore, the screening
approach selected to evaluate certain property <strong>data</strong> of the above <strong>fluids</strong> has
41

cnnslstd of the sirlc-by- side CO~I+.AL isoil of vapor ~L-~SSULC (rrxi <strong>data</strong>, qui-
libriuui vapor composition (PTxy) <strong>data</strong>, eiithalpy <strong>data</strong>, and v;scosity dara of
various <strong>fluids</strong>.
Vapor-Liquid
equilibrim -..-- (Pl-_-
s> -
The ammonia-water absorption fluid pair has b e c*zrtensively ~ ~ investigated
for many years.
tu 1932.
and Si~rnter~~ (1932) and
significant anouiit of PTxy <strong>data</strong>.
Many expeslmencal studies were condrlcted in Europe some prior
Contributors incliide Mollie: 145 (1908), Wichercr266 (19321, Cli fford
of the published <strong>data</strong> and a side-by-side comparison of the <strong>data</strong> m~asured by
several investigatorb They also presented a S P ~ of iecomrru2kaded PTxy values
based on their analysis.
(1959).
Recently, Gillespie et al. ,64 Guillevic
rn the U.S., b J i l s ~ n obtained ~ ~ ~ a
In 1966, Nacriss et al. 1’
presentxi a siirirmary
and Rizvi187 9 lEi8 obtained asad
presented PTxy <strong>data</strong> Ltiat spanned a wjder range cf pressure and teapcrature than
previously <strong>report</strong>ed. In addition to experimelital J a? several investigators
have thermodynamically analyzed historical <strong>data</strong> io Se~erininc thelr Lnte~nal
consistency.
In this section of the <strong>report</strong> a side--by-side comparison is made of selected
<strong>data</strong> sets of total pressure and vapor-liquid equilibrium to determine potcntial
conflicts. Finally, the most recent PTxy <strong>data</strong> are rompatred with computed values
in the literature developed by thermodynamic f orrnulattons .
Total pressure
The cornpariscjn of the total pressurr iw’ .sured by foiir- investi-gatots over
three diszinct %~luLion conscntrntions (5, 30, and b.c) wt 7: Nli3) is illustraced
in Fig. 12. The <strong>data</strong> sho

10,000
1,000
100
3) (50) (100)
10 I I I II I 11
3.7
3.5 3.3 3.1 2.9 2.7 2.5
Tewperature, Of1 lo3 (OC)
Fig. 12. Comparison of NH3 + H20 vapor
pressure-concentration <strong>data</strong>.
43

several directed experimental tests, in the ammonia-rich solution region,
Macriss et ale compiled a recommended set of values over the range of pressure
from 0.07 to 34.5 bar and temperature range from -50" to 215°C.
The recent <strong>data</strong> of Gillespie et were obtained for pressures up to 200
bar and temperatures up to 316°C.
at 60°C are shown in Fig. 13.
and the recommended compilation of Macriss et al.
The Gillespie et al. and Macriss et al. <strong>data</strong>
There is very good agreement between the new <strong>data</strong>
The Gillespie et al. <strong>data</strong> are
claimed to be thermodynamically consistknt and were well correlated using the
Redlich-Kister approach to fitting activity coefficient <strong>data</strong>.
Thermodynamic -- evaluations
A major thrust of U.S. and European investigations has been to thermo-
dynamically analyze historical <strong>data</strong> in order to determine the consistency of
vapor liquid equilibrium <strong>data</strong>. For example, in 1947 Scatchard et al. 196
calculated equilibrium vapor compositions that were significantly different than
measured values.
Scatchard reached this conclusion through a Gibbs-Duhem
integration, assuming water was essentially non-volatile.
More recently, Edwards4' and then Won et al.265 evaluated the thermodynamic
consistency of the tabulated values presented earlier by Macriss.
Scatchard, Won projected water vapor concentrations, in equilibrium with
ammonia-rich solutions, significantly below those given by Macriss.
researchers ~
Again, as did
European
specifically Sch~ltz'~~ and Ziegler and T r e ~ p ~ have ~ ' also thermo-
dynamically analyzed the NH3-H20 system and again concluded that the <strong>report</strong>ed
measured vapor concentrations are higher for ammonia-rich solutions than their
predictions.
The vapor-liquid equilibrium values at 60°C computed from these thermo-
dynamic formulations are also presented in Fig. 13.
It is evident that the
calculated vapor compositions are substantially lower than measured values in
the ammonia-rich solution region by as much as a factor of 2.
This pattern
appears to hold true at other temperatures in the ammonia-rich region of con-
centration.
From these comparisons, it is concluded that the thermodynamic
projections of vapor compositions (Scatchard, BogartIWon, Schultz, Ziegler and
Trepp) appear to be in error.
The specific evidence is summarized as follows
44

0.010
U
Ti
L4
+I 0.005
c,
B
d
u Ti
Ll
u
8
6"
0
U
t-l
Q)
u
Ll
0
a
(d
3
0.001
0 0.1 0.2 0.3 0.4 0.5 0.6
Liquid Water Concentration, wt. frac.
Fig. 13. Comparison Qf measured and predicted vapor
composition of the NH3 + H20 pair at 6OOC.
45

3 The new <strong>data</strong> of Gillespie et al." com are favorably with historical values
and the compilation of Macriss et al. 153
8 The Gillespie et al. <strong>data</strong> are claimed to be thermodynamically consistent
and well correlated using the Redlich-Kister approach for fitting activity
coefficients.
Enthalpy <strong>data</strong>
In the U.S. prior to 1964, tabulated values of liquid- and vapor-phase
enthalpies for the NH3-H20 fluid system were based on European experimental
studies conducted between 1929 and 1934. Specifically, Jennings and Shannon
96
in 1938 and Scatchard et
in 1947 produced enthalpy tables in systematic
increments of composition and pressure based on either interpolations of
experimental <strong>data</strong> (Jennings) or thermodynamic calculations (Scatchard).
analysis by Macriss et al. in 1964 indicated that the results derived from the
method of Scatchard were in good agreemenr. with historical <strong>data</strong> for the low-
temperature region, below 25°C.
However, Scatchard's values deviated about
15% from measured <strong>data</strong> at high temperatures and pressures.
The measurements by Macriss et al.123 involved heat capacities of four
liquid mixtures of ammonia and water containing between 0 and 40 wt % ammonia
in the pressure range of 3.5 to 34.5 bar.
An
By comparison, Scatchard's projec-
tions were consistently higher than the <strong>data</strong> of Macriss, deviating up to 15%
at high temperatures.
The differences are attributed to insufficient accuracy
of the primary <strong>data</strong> utilized in the calculations of Scatchard.
The Macriss
<strong>data</strong> were consistently lower than historical European <strong>data</strong>, but the deviations
from the latter <strong>data</strong> were smaller than those found by comparison of the
Macriss <strong>data</strong> to the Scatchard projections.
Macriss also presented tabular values of liquid- and vapor-phase
enthalpies for pressures ranging from 0.07 to 34.5 bar.
basis of the analysis by Won, 265 summarized enthalpies at pressures ranging
from 0.4 to 19.0 bar. A comparison of the Won and Macriss values at 60°C
(Fig. 14) indicates only small deviations of 1 to 2%.
The vapor-phase
enthalpy projections of Won are 1 to 2% higher than the Macriss values, but
the opposite trend is noted for the liquid-phase enthalpies.
Bogart,24 on the
In Europe, the most recent presentations of liquid- and vapor-phase
enthalpies are charts prepared by Electrol~x~~ (unpublished) and by Ziegler
and Trepp. 277
The values of the latter investigators were developed from
46

800
123
Macriss
1800
P 700
Ftrl
0 1
a3
(du
>m
a -
aJh
u a
@--I
Ft(d
3s
$ t;t 600
m w
1600
1400
r
u.
\
r
09
500
I I I I I I 1 I
- Macriss 123 0 -I
1200
180
160
3;
u
\
140 g
120
100
Weight Fraction,
NH3
Fig, 14, Comparison of ammonia-water enthalpy <strong>data</strong> at 6OOC.
47

equations of state. The liquid phase <strong>data</strong> extracted from the smoothed charts
at a temperature of 60°C are also compared in Fig. 14.
At 6OoC, the comparison indicates good agreement between the two sets of
<strong>data</strong> at all solution concentrations, i.e., 0 to 100% NH3. There is also good
agreement with the compilations of Macriss et al. and Bogart.
=:-liquid
equilibrium <strong>data</strong>
The R20-LiRr pair has been utilized in commercially available absorption
cooling machines for many years and, therefore, a relatively large number of
Sources of published <strong>data</strong> were found.
tions (1Jemura and H a ~ a b a Matsuda , ~ ~ ~ et al.
investigations by
and Usyukin.2S1
Data were found in Japanese investiga-
and Osaka Gas162) and European
A comparison of vapor pressure <strong>data</strong> from two of the Japanese investigations
and the two European sources is illustrated in Fig. 15, for a 50 wt %
solution.
LiBr
The <strong>data</strong> from three of the sources (Renz, Matsuda, and Usyukin) fall
practically on the same empirical straight line drawn through the actual
points.
The Uern~ra~~~ <strong>data</strong> fall significantly below those of the other inves-
tigators by 15 to 20%, particularly in the low-temperature region below 30°C.
Although not shown, similar behavior was noted for other compositions (20, 50 and
60 wt % LiRr) at low temperatures. Therefore, from a concensus viewpoint, the
<strong>data</strong> of Ueiniira should be excluded from consideration at temperatures below 30°C.
All <strong>data</strong> taken prior to 1928 have been assembled, evaluated, and presented
82 Tn the U.S., Pennington 165
in the International Critical Tables (TCT).
ineasured and <strong>report</strong>ed vapor pressures above solutions with concentrations ranging
from 50 to 68 wt % LiBr and temperatures from 25" to 177°C.
showed that the Pennington results deviated from those previously <strong>report</strong>ed in the
International Critical Tables, with deviations averaging more than 10% of the
pressure measured.
Sufficient experimental details were not available to
indicate which group of <strong>data</strong> is more accurate.
More recently, McNeely13'
Ellington et a1.52
evaluated all known <strong>data</strong> to present a consistent
set for inclusion in the ASHRAE Handbook of Fundamentals.
Major absorption
cooling equipment manufacturers were <strong>survey</strong>ed by McMeely to obtain proprietary or
unpublished information.
___-____--
1_1--
Based on the Pennington <strong>data</strong> and proprietary <strong>data</strong>
48

1000
100
3
El
h
a,
1-I
m
aJ
M
!a
1-I
0
2
P
10
1
3.7 3.5 3.3 3.1 2.9 2.7 2.5
Temperature, 0 K x 103 ( 0 C)
Fig. 15.
Comparison of H2Q 4- LiBr vapor pressure <strong>data</strong>.
49

supplied by Carrier Corporation, McNeely developed polynomial correlations
relating solution temperature, concentration, and vapor pressure.
Comparison of the dew points calculated from the polynomials to measured
values indicated:
8 Calculated values agreed well with the ICT <strong>data</strong> below LiBr solution concentrations
of 44 wt %. In the concentration range of 45 to 60 wt % LiBr,
the calculated dew points are 0.6 to 2.8OC lower.
0 For solution concentrations above 45 wt % LiBr, the McNeely calculated
values agreed with the Pennington <strong>data</strong> but not with the ICT compilations.
Q There is little <strong>data</strong> available above solution concentrations of 60 wt % LiBr
at atmospheric pressure (1.0 bar) to substantiate the correlations.
Recently, Herold and Moran,80 in the U.S.,
developed a method for deter-
mining various thermodynamic properties based on an expression for the Gibbs free
energy of the LiBr/H20 solution,
The vapor pressures determined by the McNeely
and Herold approaches at a 50 wt % LiBr solution are also presented in Fig. 15
and are compared with the actual experimental <strong>data</strong>, indicating good agreement.
Methanol-Salt Fluids
Methanol is a refrigerant that has been proposed as a replacement for water
to prevent system freeze-up problems and to develop air-cooled systems. Most
work has focused on methanol in combination with either LiBr or ZnBr2 or a
combination of both. In this section comparisons are made of PTX <strong>data</strong> for two
binary solutions and of viscosFty <strong>data</strong> for another solution.
CH?OH-L
-
iBr
Vapor-liquid equilibrium <strong>data</strong>
Four major sources of <strong>data</strong> were found for the CH30H-LiBr system.
One from
Europe by Renz,183 one Japanese by Uemura et a1.,245 and two from the U.S., Aker
et a1.l and Biermann. 19
The <strong>data</strong> from two investigators (Renz and Uemura) are compared in Fig. 16
for solution concentrations of 10, 30, and 50 wt % LiBr.
At solution concen-
trations below 30 wt % LiBr, there is general agreement between these two sets of
<strong>data</strong>. At the low solution concentration of 10 wt % LiBr, the Renz vapor
pressures are about 10 to 15% lower than the Uemura values at identical condi-
tions.
At solution concentrations greater than 30 wt % LiBr, the Uemura <strong>data</strong>
50

1000
100
10
1
3.7 3.5 3.3 3.1 2.9 2.7 2.5
0 -1
Temperature, K
x lo3 (OC)
Fig, 16. Comparison of CH3OH + LiBr vapor
pressure-concentration <strong>data</strong>.
51

are substantially higher than Renz's values, by up to 100 %. Deviations increase
as solution concentration increases, Superimposition of the <strong>data</strong> from the two
U.S. sources (Aker and Biermann) shows good agreement with the <strong>data</strong> of Renz.
In the previous section, where H20-LiBr
<strong>data</strong> were discussed, it was also
shown that three investigators (including Rem) produced <strong>data</strong> in general agree-
ment, while Uemura's <strong>data</strong> for that fluid pair also departed from the trend line
drawn through the other investigators <strong>data</strong>.
V i s co s i tx
CA3011-LiBr system.
of 35 wt % LiBr.
and U e m ~ r measured a ~ ~ ~ and <strong>report</strong>ed solution viscosities for the
the temperature range of 10 to 50'C.
solution concentrations.
The Uemura <strong>data</strong> are higher by one to two centipoises through
instrumentation used to obtain the primary <strong>data</strong>, KIO
which set is more accurate.
CH30H-Z nBr2
The <strong>data</strong> are compared in Fig. 17 at a solution concentration
Similar observations were made at other
Without a more careful screening of the methods and
statement can be made as to
Vapor-liquid equilibrium
Both
and Uem~ra~~l have also investigated the CH30H-ZnBr2 system.
However, contrary to the wide deviations found between them in the CH3011-LiBr
system, there is general agreement between the two sets of <strong>data</strong>, as shown in Fig.
18. Uemura's measurements are generally lower by a few percentage points at
identical conditions of temperature and pressure.
I Vapor-liquid equilibrium
A comparison of <strong>data</strong> obtained in the U.S. by Aker et al.' and Biermann" for
this system is presented in Fig. 19. At a solution concentration of 44.2 wt %
CH30H,
Aker et al.
the vapor pressures of Biermann are about 20 to 25% lower than those of
At a lower concentration, 27.8 wt % methanol, better agreement is
obtained, but the Biermann measured vapor pressures are now slightly higher (by 5
ta 10%). Again, there is no independent evidence to judge which of the two sets
might be more accurate.
52

20
183
0 Renz 245
* A Uemura
35 ut X Lib
15
PI
L)
2 10
*rl
Lo
0
0
Lo
Ti
3
5
0
0
I I I 1
20 40 60 80 100
Temperature, 0 C
Fig. 17.
Comparison of CH30H f LiBr viscosity <strong>data</strong>.
53

1000
183
0 Renz
241
A
Uemura
+f
ut % ZnBq
100
bo
m
E
10
1
3.7 3.5 3.3 3.1 2.9 2.7 2.5
Temperature, OKm1 x lo3 (OC)
Fig. 18. Comparison of CH3OH + ZnBr2 vapor
pressure-concentration <strong>data</strong>.
54

100
1
0.1
44.
0.01
0.1
2.0 1.9 1.8 1,7 1,6 1-5 1.4
Temperature, OR-'
x lo3 (OF)
Fig. 19. Comparison of methanQ1 -1. LiBr: ZnBr2
(2:l) vapor pressure <strong>data</strong>.
55

-- Organic refrigerant-absorbent <strong>fluids</strong>
Extensive investigations have been conducted to determine the usefulness of
organic <strong>fluids</strong> as refrigerants, mainly halogenated hydrocarbons, paired with
high-boiling organic absorbents such as ethers, amides, and esters.
An example
of an organic refrigerant, methylamine, paired with a solid adsorbent, sodium
thiocyanate, is also presented.
~ Refrigerants ll_l 123a, 133a-ETFE
For these <strong>fluids</strong>, the available U.S. <strong>data</strong> (Murphy 1509151) practically cover
most of the important fluid properties.
Assessment of the accuracy or precision
of the <strong>data</strong>, however, cannot be made from the available references.
R22-DMETEG
For this fluid, major U.S.
experimental investigations on vapor-liquid
equilibrium have been conducted by Mastrangelo, 132 Buclez, 35 and Albright et al .3
Macriss and Mason124 thermodynamically evaluated the available <strong>data</strong> and
produced smoothed PTX curves.
The <strong>data</strong> of Mastrangelo showed considerable
scatter around the smoothed isotherms of Albright et al., indicating poor
internal consistency.
A much smaller scatter of Albright's raw <strong>data</strong> had been
evident except for the two highest temperatures, 121" and 135°C) where there were
only a few experimental points for the entire range of concentration.
Comparison
of the scatter of the raw <strong>data</strong> from all sources, on the solubility of Refrigerant
22 in DMETEG (in the range of 25 to 121°C) are summarized in Table 6.
Sato2*')
One European (Eh~nke~~) and two Japanese sources (Oouchi11i9 and Suzuki and
were found for this pair.
The <strong>data</strong> from these three sources are com-
pared for solution concentrations of 10 and 40 wt % R22 in Fig. 20.
Throughout
the range of test temperatures, 10 to 127OC, there are no significant differences
hetween the three sources of <strong>data</strong>.
R21-DMETEG
-_^____-
The <strong>data</strong> of Bucle~,~~ Albright et a1.,3 and Mastrange10'~~ at a solution
composition of 30 mol % R21 are illustrated in Fig. 21. The agreement is good at
temperatures below 51.7OC, whereas the Mastrangelo vapor pressure <strong>data</strong> are about
5% lower than those of the others at temperatures in excess of 62.8"C.
56

Table 6.
Deviation of solubility <strong>data</strong> from various sources from
the <strong>final</strong> smoothed values for R22-DMETEG
Data of Albright et: al.3 Data of Mastrangelo 132
Temperature Number of Average Number of Average
("0 p oints deviation (%I points deviation ( X )
28.3 9 0.74 11 4.6**
55.8 9 0.22 12 0.7
85.8 9 0.55 11 0.5
110.9 9 0.13 3 3.3+
* Interpolated values.
All values of xr equal or higher than smooth curve.
All values of xr equal or lower than smooth curve.
**
t
5 7

10,000
1,000
A
1 o*
I-(
0
a
rd
3
101
47
0 Ehmke 220
A Suzuki
0 Oouchi 159
*ut X R22
I
:O)
(50) (100)
I I I
II I II
3.7 3.5 3.3 3.1 2.9 2.7 2 :5
Temperature, OK-' X lo3 (OC>
Fig. 20. Comparison of R22 3. DMETEG vapor
pressure-concentration <strong>data</strong>.
58

Temperature, 0 C
1 oc
0
20 40 60
I 50
I 1 I
1.0
10
(d
vi
v1
a
..
ClJ
k
3
u1
m
al
k
pc
0.1
1
0.1
50 1
2.0 1.9 1.8 1.7 1.6 1-5 1,4
0
Temperature, R
-1
x lo3 COP>
. -
I
3,Ol
Fig. 21.
Comparison of R21 + DMETEG vapor pressure <strong>data</strong>.
59

__I_-
R2 2 -Dm
Only a small overlap exists for the <strong>data</strong> of P~doll'~~ and Albright et al.
in the temperature range of 24 to 35OC.
ment is good at a solution concentration of 26 mol %
about 3 to 5% lower than that of Albright et al. (Fig. 22).
R21 or R22-DMH
However, within that range, the agree-
R22, with Podoll's <strong>data</strong>
The <strong>data</strong> of P ~ d o l and l ~ Biermann" ~ ~ at a solution concentration of 37 mol %
R21 are illustrated in Fig. 23.
The Biermann <strong>data</strong> exhibit a significantly
stnaller slope than the trend line drawn through Podoll's <strong>data</strong>.
At low
temperatures (50"F), deviations up to 30 to 40% occur, with the Biermann <strong>data</strong>
corresponding to higher vapor pressure values.
For the R22-DMH fluid, and at a solution concentration of 30 mol %
3
R22, the
Biermann <strong>data</strong> exhibit vapor pressures 20 to 50% larger than those of Podoll, as
shown in Fig. 23.
As was the case for the R21 + DMH fluid, the deviations are
greatest at low temperatures and the slope of the Biermann trend line is smaller.
CH3NI12-NaSCN
This fluid is an example of an organic refrigerant in combination with an
inorganic salt absorbent. Two sources of smoothed <strong>data</strong> exist for this combination,
by Rush et a1.,lg4 with tabulated values, and Biermann" in graphical
form. The comparison of the vapor pressures from the two sources at solution
concentrations of 50 and 62 wt % CH3NH2 is illustrated in Fig. 24. At both
concentrations, the Biermann pressures are significantly lower, by about 40%,
than those of Rush et al. There is no obvious reason for stating which of the
two sources contains more accurate <strong>data</strong>. The experimental procedures used by
Riemann were presented in the reference.
3.4. FINE SCREENING OF NH?-H?O DATA
I
The NH3-H20 <strong>data</strong> were selected for fine screening because the pair is used
in commercially available equipment and there is a need to provide a recommended
set of PTxy values covering a wider range of conditions (pressure, temperature,
and composition) than had been previously <strong>report</strong>ed. The important reasons for
screening are summarized as follows:
0 New <strong>data</strong> have recently appeared in the literature,
0 Discrepancies have been noted between predicted and measured PTxy <strong>data</strong>, and

Temperature, 0 C
100
0
20 40 60 80
1 I 1
I I
1.0
10
(d
*d
rn
-
a
0)
k
3
rn
rn
QI
k
Pi
0.1
1
..-.lr--...
0 PoooLL173
A AL.BR1WT3
26% R22, mol X
(50) (100) (150) (200)
0.1 I I I I
2.1
2,O 1.9 1.8 1.7 1,6 1.5
-
0.01
Temperature, OR-'
x lo3 (OF', .-,
Fig. 22.
Comparison of R22 t DMA vapor pressure <strong>data</strong>.
61

Temperature,
0
C
100
0 20 40 60 80
\ I \ I I
+
DW
1 .o
10
ni
.ri
v)
a
a,
k
3
rn cn
e,
k
PI
+
DMH
0.1
1
---..-e-
A BI
o ~ a~a-2’~
*mol
28
% REFRIGERANT
0.1
2.1
(50) (100) (158) (20’
I I I I I
2.0 1.9 1.8 1.7 1.6 1,5
0.01
Temperature, ORc1 x lo3 (OF>
Fig. 23.
Comparison of R21 -t- DPN and R22 3- DMtI vapor pressure <strong>data</strong>.
62

Temperature, 0 C
100
0
20 40 60 80
I 4 4 --. I I
0 RUSHLY4 I
------ A A BIERI'UANU~~
*ut x METHYLAMIME
1.0
10
crl
-4
v1
a
n
a,
k
3
(0
[II
a,
k
&
62*{
0.1
w
Y
(D
m
2
"
(D
0-
pl
rl
1
0.1
2.0
50 1 (1001 (150) (200>(250
1.9
-
I I 1 A
1.8 1.7 1.6 1.5 1.4
0.01
Fig. 24. Comparison of methylamine i- sodium
thiocyanate vapor pressure <strong>data</strong>,
63
. . . . . . - .

Advanced cycle calculations require accurate PTxy values beyond the range of
present compilations.
Recently four sets of PTxy equilibrium <strong>data</strong> appeared in the literature and
extended the range of pressure, temperature, and compositions previously
<strong>report</strong>ed:
8 Gillespie et presented PTxy <strong>data</strong> in the range of pressure from 0.07 to
200 bar and temperatures from 40 to 316°C over the entire liquid composition
range.
o
Guillevic68 presented <strong>data</strong> at three isotherms 130, 180, and 230°C.
@
e
Rizvi187,188 obtained and presented <strong>data</strong> in ranges similar to those shown
for Gillespie et al.
Tsiklis et al .223 presented <strong>data</strong> along eight isotherms, temperatures ranging
from 97 to 350°C and pressures from 1 to 200 bar.
In addition to <strong>data</strong>, tabular values based on thermodynamic formulations and
empirical polynomials developed from <strong>data</strong> considerations have also appeared in
the literature that facilitate cycle computations.
It is, therefore, necessary to compare and evaluate primary <strong>data</strong> sets, first
to each other and then to thermodynamic predictions and polynomial estimates.
set of recommended PTxy values can then be compiled based on the results of the
aforementioned analysis.
The evaluation process consisted of the following steps:
4 Comparison of measured total pressure <strong>data</strong> obtained by various investigators
at common temperatures to determine relative spread in the primary <strong>data</strong>
0 Comparison of measured PTxy <strong>data</strong> at common temperatures to determine spread
in primary <strong>data</strong>
A
o
Comparison of PTxy <strong>data</strong> and previous thermodynamic projections to reconcile
differences
Comparison of PTxy <strong>data</strong> and polynomial projections to determine usefulness
of current estimating techniques for cycle calculations
8 Development of extended PTxy tables based on the comparative evaluation.
-- ComEarison
~ of
Measured Total -P_ressure
To begin the analysis, total pressure <strong>data</strong> gathered by vari.ous investigators
were compared at two isotherms, 80 and 133"C, as shown i n Fig, 25.
Pressures
64

d
0
rn
4
-rl
5
0
In
U
0
-3
In
m
0
m
In
N
3
N
n
-4
3
-.I
n'
>
8
V
0
to
0
u
(D
(D
u
(d
b)
$4
3
m
rn
al
CI
p.
rl
m
U
0
u
4-1
0
c
0
m
65

were generally <strong>report</strong>ed at these temperatures, thus eliminating the need for
interpolations to reduce <strong>data</strong> to a common temperature.
The important observations made €rom scanning the <strong>data</strong> obtained by six
investigators shown in Fig. 25 are summarized as follows:
@
There is general agreement in the measured pressure between sources in the
solution concentration range of 0 to 45 mol % NH3. For example, at a
solution concentration of 15 mol % NH3, the spread in the pressure is only
about 0.2 bar compared with about 1 bar at a concentration of 40 mol % NH3.
0 The spread in the measured pressure increases as the ammonia solution
concentration increases.
@
The new <strong>data</strong> obtained by Gillespie et ad4 appear to be representative of
the total historical <strong>data</strong> set obtained by the other five investigators.
The total pressure <strong>data</strong> obtained at 133°C by three investigators (Gillespie
et al.64, Guillevic,68 and Rizvi187*188) are shown in Fig. 26.
The important
conclusions obtained from scanning this <strong>data</strong> set are summarized as follows:
0 There is general agreement between them up to a solution concentration of
50 mol % ammonia. At richer solution concentrations, the <strong>data</strong> of Rizvi are
significantly higher, by up to 10 bar, than those obtained by Gillespie and
also exhibit an unusual curvature in the range of solution concentration of
60 to 80 mol % ammonia.
e
Because of the unusual nature of the Rizvi <strong>data</strong>, a smooth curve was drawn
through the <strong>data</strong> of Gillespie et al. as representative of the PX
relationship at 133°C. The <strong>data</strong> of Gillespie et al. and Guillevic are also
in agreement up to a solution concentration of 60 mol % ammonia.
Comparison of PTxy Data
Gillespie et al.64 compared their smoothed PTxy <strong>data</strong> (in terms of relative
volatility) to those obtained by Wilson,264 Wucherer ,266 Guillevic, ' 68
Rizvi, 187,188 and the compilation of Macriss et al. 123
approach consisted of correlating the <strong>data</strong> obtained on an isotherm, using the
Redlich-Kister equation for fitting activity coefficient <strong>data</strong>.
The Gillespie et al.
The comparison
between the relative volatility of Gillespie et al. and of the other investi-
gators is summarized as follows:
e
e
Wilson, f5.7%
Wucherer , fl1.6%
0 Guillevic, f14.1% (better at low temperatures, 80-100°C)
0 Rizvi, f24.0%
66

0
rl
0
m
0
CD
0
h
N
I4
Eo
V
0
c-7
c-7
4
u m
(d
u
m
a
0
\D
0
m
0
.;t
0
m
0
N
0
4
0
67

Macriss et al., k15.3X (compilation of historical <strong>data</strong>)
8 Clifford and Hunter, &8.0%.
Comparison of PTxy Data and Thermodynamic Projections
Based 01-1 solution total pressure <strong>data</strong>, Scatchard,lg6 and
modynamic projections of PTxy values.
made ther-
They both concluded that for ammonia rich
solutions, the equilibrium water vapor concentrations projected by thermodynamic
formulations were significantly lower than <strong>report</strong>ed values (Macriss et al.) and,
therefore, the measured vapor concentrations were in error.
In an attempt to reconcile the differences, a comparison was made between
the relative volatilities, projected from thermodynamic considerations, pre-
sented by B ~ g a r and t ~ ~ to <strong>data</strong> newly obtained by Gillespie et a1.,64 as shown in
Fig. 27.
The Bogart values at low temperature (40°C) are higher by a factor of
2, than those obtained by Gillespie et al., in the ammonia-rich solution
region.
Significant deviations occur at other temperatures.
Because the Gillespie et al .64 values are thermodynamically consistent and
have been verified by comparison with experimental <strong>data</strong>, the conclusion drawn
firom the comparison is that the thermodynamic projections of Won187 are not
valid.
Comparison of PTxy Data and Polynomial - Projections
Several researchers have empirically correlated historical <strong>data</strong> to provide
polynomial relationships for PTxy values to facilitate computer cycle calcula-
tions.
Three significant efforts are summarized as follows:
?a Jain and Gableg4 presented correlations for PTxy values that only applied
within a limited range of pressures: 3,5 to 5.5 bar and 17.2 to 24.1 bar
Electrolux"
polynomials
El-Sayed and T r i b ~ presented s ~ ~ correlations that covered the pressure and
temperature range of 0.07 to 110 bar and -62 to 500°C.
The projected total pressure and PTxy values were compared with measured
<strong>data</strong> to determine the accuracy of each set of polynomials.
The total pressures projected by Electrolux and El-Sayed and Tribus are
compared with the smoothed <strong>data</strong> of Gillespie et
Agreement is quite good in the ammonia-lean region (less than 50 mol %
where deviations between them are much less than 1 bar.
68
at 133°C in Fig. 28.
However, in the
ammonia),

500
100
50
h
4J
.d
rl
.d
u rd
rl
0
3
a,
?
-4
4J
cu
4
a,
FG 10
/
\ 40°C,1040F
5
1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Water Solution Concentration, mol fraction
Fig. 27.
Comparison of predicted and measured relative volatilities.
69

0
Q \
e
2-
4
tn I
d
a
1 I I I I I I I I I i!L
0 0 0 0 0 0 0 0 0 0 0 ~
- c
c O a , a o b c o l o q - o c u -
N
0
E
2
0
t-4
t-
.b.
CY
t-
z
W
0
Z
0
a
n
a
+I
d
Cf
I-l
z
0
z
4
a -
t
c
%
a
70

ammonia-rich region, the pressures projected by the polynomials are higher by up
to 10 bars than the smoothed measured values.
The relative volatilities are compared in Figs. 29, 30, and 31.
important observations are summarized as follows :
The
Q
In a narrow region of application the Jain and Gable polynomials provide
accurate estimates of PTxy values (Fig. 29).
9 The Electrolux polynomials appear to provide reasonable PTxy estimates at
temperatures below 177OC and ammonia-lean solutions (Fig. 30).
The El-Sayed and Tribus projections appear to best fit the PTxy <strong>data</strong> in the
solution composition range of 40 to 80 mol % water. Significant deviations
occur in the very dilute ammonia or ammonia-rich solution concentration
range (Fig. 31).
Conclusions
Based on the fine screening analysis:
The recent <strong>data</strong> of Gillespie et al. were found to be consistent with
historical PTx and PTxy <strong>data</strong>. Because the Gillespie et al. <strong>data</strong> are thermodynamically
consistent and have covered ranges of temperature, pressure,
and solution concentrations heretofore not available, they are selected as
the criterion of the usefulness of other thermodynamic and empirical
estimating techniques.
Q
Comparison of thermodynamic projections of PTxy values of Won with those of
Gillespie et al. showed the Won projections to be in error for ammonia-rich
solutions.
0 Comparison of PTxy estimates from polynomial formulations showed that none
of the equations could accurately represent the entire range of PTxy <strong>data</strong>
as presented by Gillespie et al. Large discrepancies were found in both
the ammonia-rich and lean solution concentrations.
3.5. GAPS IN THE DATA OF -D KEY
FLUIDS
The results of the review and assessment of the U.S.
literature <strong>data</strong> on
absorption <strong>fluids</strong> and the identification of unresolved or potential conflicts in
the <strong>data</strong> provide the basis for the definition of gaps in the existing <strong>data</strong>
base.
Additionally, information about the current activity of researchers
involved in the development of advanced absorption heat pumps provides some
insight as to potential new regimes (temperature, pressure, or concentration)
and new <strong>fluids</strong> for which <strong>fluids</strong> property <strong>data</strong> must be known.
A rating system has been devised to be used in assessing the importance of
filling the gaps in the <strong>data</strong> in support of various efforts directed at the
identification and development of viable, practical, and commercializable
71

530
LOO
50
60°C, 140°F
80'6, 176°F
121.14'C, 250°F
10
132.74'6, 270.9
O F
176.6'C, 350°F
5
-
--
64
Gillespie
94
Jain and Gable
1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Water Solution Concentration, mol fraction
Fig. 29.
Comparison of projected and measured relative volatilities.
72

600
530
\
\
\
4OoC, 104'F
100
50
8OoC,
176'F
10
132-74OC. 270.9OF
5
475OF
1
.
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Water Solution Concentration, mol fraction
Fig, 30.
Corngarison of projected and measured relative volatilities.
73

---- 4OoC, 104'F
8OoC, 176'F
121.14'C,
250'F
176.6'C, 350°F
246.15'C,
475'F
/ / I
54
Gillespie
-- El-Sayed 53
1
0 0.1 0.7 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Water Solution Concentration, liiol fracion
1
Fig. 31.
Comparison of projected and measured relative volatilities.
74

advanced absorption heat pumps,
f hid-by-f luid basis :
This rating system addresses <strong>data</strong> gaps on a
1. Highest. Priority: Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted.
The results of the assessment of gaps in the <strong>data</strong> for each fluid in this
study, using the rating system, are presented in Figs. 32 through 44.
numbers within the grid of each of the figures relate to the level of priority
of filling the <strong>data</strong> gaps relative to a specific fluid and each property of the
fluid.
<strong>data</strong>.
A blank grid signifies that no further action is warranted regarding
The
75

1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted
REFRIGERANTS
R-21
R-22
R-123a
R-124
R-133a
CH30H
CH3W2
TFE
NM3
N2 cI
.BENTS
Fig. 32.
Gaps in vapor-liquid equilibrium <strong>data</strong> for key <strong>fluids</strong>.

ETFE
1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted
R-21
R-22
R-123a
R-124
R-133a
CH30H
REFRIGEMTS
CH3NH2
TFE
H: KOH: CsOH
AB SORBENTS
NH3
H2°
Fig. 33.
Gaps in crystallization temperature <strong>data</strong> for key <strong>fluids</strong>.

EFTE
1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted
R-21
R-22
R-123a
R-124
R-l33a
CH30H
w
03
REFRIGERANTS
cH3m2
TFE
H: KON: CsOH
A3 SORBENTS
NN3
H2°
Fig. 34.
Gaps in corrosion <strong>data</strong> for key <strong>fluids</strong>.

R-21
R-2 2
R-123a
R-124
R-133a
CH3 OH
L L
t i i i i i LiBr ~
1.
2.
3.
Blank.
Conflict Resolution or New Data Imperative
Conflict Resolution in Data Needed
New Data Desirable
No Fluids Data Action Warranted
-4
\o
REFRIGERANTS
CB3NH2
TFE
&%3
H2°
Fig. 35.
Gaps in toxicity <strong>data</strong> for key <strong>fluids</strong>.

EFTE
1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. KO Fluids Data Action Warranted
R-21
R-22
R-123a
R-124
R-133a
CH30H
00
0
REFRIGERANTS
CH3NH2
TFE
ENT S
NH3
Fig. 36.
Gaps in heat and mass transfer <strong>data</strong> for key <strong>fluids</strong>.

EFTE
1. Conflict Resolution or New Data Im .perat ive
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted
R-21
R-22
R-123a
R-133a
CH30H
REFRIGERANTS
CH3NH2
TFE
NH3
H2°
Fig. 37.
Gaps in viscosity <strong>data</strong> for key <strong>fluids</strong>.

1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted
R-21
R-22
R-123a
R-124
R-133a
CH3 OH
03
N
REFRIGERANTS
CH3NH2
TFE
AB SORBENTS
NH3
HZ O
Fig. 38.
Gaps in vapor-and liquid-phase enthalpy <strong>data</strong> for key <strong>fluids</strong>.

X
8
U
..
Om 1
x $- g
V
m
E

SFTE
1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. Xew Data Desirable
Blank. No Fluids Data Action Warranted
Br
R-21
R-22
R-123a
R-124
R-133a
CH30H
m
f-
REFRIGERANTS
CH3NH2
TFE
AB s ORBENTS
NH3
H2°
Fig. 40.
Gaps in specific heat <strong>data</strong> for key <strong>fluids</strong>.

....
r-lCJm24
d
(d
d
a
h
s
rd
N
86

1. Conflict Resolution or New Data Imperative
2. Conflict Resolution in Data Needed
3. New Data Desirable
Blank. No Fluids Data Action Warranted
03
d
REFRIGERANTS
R-21
R-22
R-123a
R-124
R-133a
CN30H
CH3NH2
TFE
NH3
H2°
Fig. 43.
Gaps in heat transfer additive <strong>data</strong> for key <strong>fluids</strong>.

k
0
w

R.C.
4. ACKNOWLEDGEMENTS
The financial support and guidance provided by Messrs. F.A.
Creswiek and
DeVault of Oak Ridge National Laboratory and Messrs. J.D. Ryan and R.J.
Fiskum of the U.S. Department of Energy are gratefully acknowledged. The
authors also wish to extend their appreciation to Professors F. Steimle -
UnPversity of Essen, K.
Stephan - University of Stuttgart, I. Borde - Ben Gurion
University, T. Uemura - KansaJ University, M.J. Cheron -French Petroleum
Institute, Mlfe. L. Rolland - Gaz de France and to all those that contributed
unpublished <strong>report</strong>s and <strong>data</strong> on absorption <strong>fluids</strong>.
grateful for the patience and diligence of our secretary, Ms.
Not the least, we are
Patricia Powell,
that prepared not only this <strong>report</strong> but also the previous two <strong>report</strong>s published
in 1986 and 1987.

I
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____I
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103

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104

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106

232. Uemura, T., "Properties of Coolant - Absorbent System Used for
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presented at 1980 Japan Refrigeration Conference (Japanese text).
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10 7

247. Uemura, T. and Hasaba, T., "Some Physical Properties of Aqueous Solution
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Refrigeration ---__I-
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___ 42, No. 471, 2, 1967 (Japanese text).
I1
258. Uemura, T., Higuchi, Y., Seki, A., and Hasaba, S., Entropy-Concentration
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10 9

272. Zellhoeffer, G. F., "Solubility of Halogenated Hydrocarbon Refrigerants
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J.
110

6. APPENDIX. FLUIDS, PROPERTIES, DATA, AND RANGE OF CONDITIONS
A- 1

~
Table A.1.0.
AMMONIA BINARY AND MULTICOMPONENT ABSORPTION FLUIDS PROPERTIES DATA
A. 1.1. VaDor-Liauid Eauilibritrm
Data Temp.
Fluid System Type Range, OC
Press. Range,
atm
Weight, %
X (R)
Y (R)
NH3 + H20 TE 6-100 0.24-1.705
0.50-18.97
6.14-90
NtI3 + H2O TE 97-147 0.899-16.3 0-25.9
0-89 . 76
NH3 + H20 GE 60-147 0.24-16.3 0-90
0-100
Ref e rence
No . Author Year Country Text
-
-
38 Clifford 1933 England Eng 1 ish
38 Clifford 1933 England English
38 Clifford 1933 England English
5; NII3 + H20 GS -1 00-1 80
w
0.02-10 0-100
0-100
38 Clifford 1933 England English
NH3 + H20 TS -8 3- 150 0.02-19 . 2 0-100
0-100
38 Clifford 1933 England English
NH3 + H2O TGE . 0-61.3
11.5-1801.6 (1)
4.21-34.75 166 Perman 1901 England English
NH3 + H20 TS 0-61.3
5-1842 (1)
0-35
166 Perman 1901 England English
NH3 + H20 TE -40-260
0.04-48.39
0-40
167 Pierre 1901 Sweden English
NH3 + H20 GE -40-175
0.2-20
0-100
266 Wucher e r 1932 Germany German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Fluid System
NH3 + H20
Data
Type
GE
Temp.
Range, "C
-20-1 40
\*!eight, %
Press. Range, x (R) - Reference
-
atm Y (R) No. Author
- Year
Country
0.2-20
Y=O-l00 266 Wucherer 1932 Germany
Text
German
NH3 i- H20
GS
-50-210
0.2-20
0-100
0- 100
2 6 6 Wuche re r
1932 Germany
German
NH3 + H20
TS
-50.5-211.4
0.1-20
0-100
266 Wucherer
1932 Germany
German
NH3 i- H20
TS
-6.2-202.7
0.2-20
Y=15-99
266 Wucherer
1932 Germany
German
NH3 + H2O
TS
NA
0.2-20
0.2-100
10.5-100
266 Wucherer
1932 Germany
German
5; NH3 + H20 GTE
1.38-120.12
758-7000 (1)
11.8-50.4
145 Mollier
1908 Germany
German
NH3 + H20
GS
20-150
0-10
0-50
145 Mollier
1908 Germany
German
NH3 + H20
GS
20-180
1-10
0-50
145 Mollier
1908 Germany
German
NW3 -+ R2O
TS
20- 150
1-10
0.15-52.7
145 ?Jollier
1908 Germany
German
NA3 + H20
TS
20-150
1.08-10.20
5-50
145 Mollier
1908 Germany
German
NH3 i- H20
CP
-70-1 75
0.01-25
NA
199 Schulz
1971 Germany
English
NH3 + H20
CP
-70-175
0.01-25
0-100
197 Schulz
1971 Germany
German
X - Liquid Phase R - Refrigerant c - ppm by weight of
Y - Vapor Phase A - Absorbent(s) ".I - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available
A
in Vapor Phase

_I
Table A.1.0.
(Cont.)
Fluid System
NH3 + H20
Data
Type
CP
Temp.
Range, OC
-40-220
Press. Range,
atm
0 . 2-so
\?eight, X
Y (R)
Y (R)
0- 100
Reference
NO Author Year Country Text
-
276 Ziegler 1982 Switzerland German
NH3 + H20
GCP
-40- 22 0
0.2-50
0-100
276 Ziegler 1982 Switzerland German
NH3 + H20
CP
-40-220
0.2-50
0- 100
277 Ziegler
1984 Switzerland English
NH3 -l- H20
CCP
-40-220
0.2-50
0-100
277 Ziegler
1984 Switzerland English
NH3 + H20
GC
-200-227
0.7-34 -47
0- 100
146 Morel 1983 France French
?
cn
NH3 + H20
NH3 + H20
GCP
P
NA
NA
NA
NA
NA
NA
59 Fischer , 1935 Germany German
50 Electrolux 1970 Sweden English
NH3 + €I20
TEG
130-230
7-72
7.2-68.5
18.6-97.3
68 Guillevic 1983 France French
NH3 + H20
TE
0-9 1
0.021-11.7
8.5-84.3
60.2-(265)'
264 Wilson 1925 U.S.A. English
NH3 + H20
TE
61-1 17
15.3-35.9
Y = 96.0-99.5
122 Macriss 1944 U.S.A. Eng l i s h
NH3 + H20
GTS
-76-243
0.069-34.5
0.0-100 .o
0.0-100.0
123 Macriss 1964 U.S.A. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mHg (2) - mbar NA - Not Available

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m
9 m
s-4 e
m m
I
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I l l
w
E-
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v
wm w
w v b
0
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2;
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m
E
z
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A- 6

Table A. 1.0, (Cont. )
Weight, %
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, OC atm Y (R) - No. Author Year Country Text
I__-
NH3 -+ H20 TEG 33-345 0.05-2 18 0.0-100.0 188 Rizvi 1987 Canada English
0.0-100 . 0
NH3 + H20 GE S 97-350 1-220 0.0-100.0 223 Tsiklis 1965 U.S.S.R. English
0.0-100 . 0
NH3 + H2O GC 0-65 0.01-30 10.0-90.0 149 Munsch 1978 Germany English
NH3 + H20 GC -125-1 75 0.1-8000 (1) 12 . 0-87.6 112 Kracek 1930 U.S.A. English
NH3 f H20 GC -23 1241 (1) 0-100 112 Kracek 1930 U.S.A. English
NH3 f H20 TC -99 . 07- 0.1-10000 (1) 0-100 112 Kracek 1930 U.S.A. English
192.78
NH3 + H20 TC -90- 180 0.31-10000 (1) 0- 100 112 Kracek NA U.S.A. English
NH3 + H20 GS 0-210 0.5-20 0-100 51 Ellerwald 1981 Germany German
NH3 + 920 TEP 50-250 1 . 09-83.5 5.84-97.25 51 Ellerwald 1981 Germany German
NH3 -t H20 PTS -34-21 1 0.5-13.6 0- 100 269 Zatorskii 1978 U.S.S.R. Russian
NH3 + H20 P -62-4 99 0.07- 109 0.0-100.0 53 El-Sayed 1985 1J.S.A. English
0 . 0-1 00 .o
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, I? - Veiqht
(1) - mmHg (2) - mbar NA - Not Available

Table A. 1.0.
(Cont.)
Fluid System
Data
__.I Type
Weight, %
Temp. Press. Range, X (R)
Range, OC atm Y (R)
-
No. Author
Reference
Year Country
__I
Text
NH3 + LiN03
TE
40-125
1-16
33.7
62
Gensch
1937
Germany
Gernan
NH3 + LiN03
TE
-10-130
0.2-13.8
32.6-100
21
Blytas
1961
U. S. A.
Eng 1 i s h
NB3 -F
NaSCN
TGE
-20-90
0.34-49.64
42.2-100.0
23
Blytas
1962
U.S.A.
English
NH3 + NaSCN
TE
25-100
1.01-29.23
34.4-53.0
189
Ro ber son
1965
U. S. A.
Eng 1 i sh
hx3 + LiSCN
GTEP
28-104
1.06-15.40
40.2-61.6
128
Macr i ss
1971
U. §.A.
English
?
03
NH3 + LiSCN
NH3 + NH4I
GE
TE
35-100
25-100
1.19-11.65
4.. 68-49.16
41.4-54.4
25.6-50.3
19
190
Biermann .
Roberson
1978
1964
U. S. A.
U. S.A.
English
English
NB3 f NH4I
TS
20-120
2.34-54.61
29.9-39.9
63
George
1965
U. S.A.
Eng 1 i s h
N H ~ + NaBr
TE
25-100
3.58-53.85
39.6-60.6
190
Rob er son
1966
U. S. A.
English
NH3 -k NH4Br
TE
25-100
2.94-52.16
31.3-51.6
190
Rob e r so n
1966
U.S.A.
English
NH3 -+ NaI
TE
25-100
3.42-57.23
37.1-63.6
190
Rober son
1966
U. S. A.
English
NH3 -+ DMETEG
TE
30-1 00
1.65-35.78
1.5-17.6
190
Robe r so n
1966
U. S.A.
Eng 1 i s h
N H ~ -k DMETrEG
TE
30-100
1.16-36.37
1.2-20.9
190
Robe 1:son
1966
u. S.A.
English
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s) M -
(1) - mmHg (2) - mbar NA -
ppm by weight of A in Vapor Phase
Mole, W - Weight
No t Avai 1 ab 1 e

Table A.1.0.
(Cont.)
?-
Weight, X
Data Temp. Press. Range, x (R) Reference
Fluid System Type_ Range, "C atm Y (R) NO Author Year Country Text
NH3 + 1, 4 - TE 30-100 0.22-25.92 2.2-26.3 190 Roberson 1966 U.S.A. Eng 1 ish
Butanediol
NH3 + 2, 3 - TE 30-100 0.54-30.13 2.6-30.6 190 Roberson 1966 U.S.A. Eng 1 ish
Butanediol
NH3 + TEG TE 30-100 0.16-38.31 1.2-30.4 190 Roberson 1966 U.S.A. English
NH3 + Polydi- GE 30 7.23-1 1.72 2.0-6.0 190 Roberson 1966 U.S.A. English
methylsiloxane
UJ NH3 + Nitro- TE 30-100 3.10-35.30 2.0-13.5 147 Morrone 1962 U.S.A. English
benzen
NH3 + Octyl- TE 30- 100 2.55-36.89 2.5-33.6 147 Morrone 1962 U.S.A. English
amine
NH3 -k DMA TE 30-100 1.79-40.75 3.2-37.8 147 Morrone 1962 U.S.A. English
I
-
NH3 + Aniline TE 30-100 2.21-21.93 5.4-38.9 147 Morrone 1962 U.S.A.
English
NH3 + H20:LiBr TGS -80-300 1-30 0-100 177 Radetmacher 1981 Germany English
(2:3) (W> GE 0-100
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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A-10

Data
Weight, %
Temp. Press. Range, X (R) Reference
NO Author Year Country Text
_L
Fluid System Type Range, OC atm Y (R)
NH3 + H20:Cr03 TE 70-260 9.9-47 .
-
84 4-45 167 Pierre 1901 Sweden English
NH3 + LiN03: TE 35 & 50
1,4 BDL (0.77:l
to 9.0:1)(W)
0.15-2.00 7.7-33.1 224 Tsimbalist 1983 U.S.S.R. English
NH3 + LiNO3:
1,6 HDL (2.7:1,
TE 35 & 50 0.15-2.00 21.9-37.4 224 Tsimbalist 1983 U.S.S.R. English
7.4: 1)(W)
NH3 + 1, 4 TE 30-100 0.93-37.58 10.4-48.9 190 Roberson 1966 U.S.A. English
? Butanediol:
i--L
P NaSCN (6.04:l)
(M)
NH3 + 1, 4
Butanedfol:
TE 30-100 1.53-39.16 12.0-40.9 190 Roberson 1966 U.S.A. Eng 1 ish
NaSCN (13.29: 1)
(M)
m3 + 1, 4
Butanediol :NaI
TE 30-100 1.08-41.78 10.4-39.3 190 Roberson 1966 U.S.A. English
(4.99:1)(M)
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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5
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r-4 f-i
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0
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0
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0
Q
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m
0 0
0 0
4 4
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0 m
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0
m
4
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9-4
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w
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w
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w
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H
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X
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ow
m .rf II
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4 c-
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mu
x 7s
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r:
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A-12

Table A.l.O.
(Cont.)
Fluid System
NH3 + H20
Weight, %
Data Temp. Press. Range, x (9) Reference
Type Range, "C atm -f (R) No. Author Year Country Text
GS -151-0 NA 0.0-1 00 .o 123 Macriss 1964 U.S.A. English
-
-
NH3 + H20
NH3 + H20
NH3 + H20
NH3 + H2O
TGE 0 - -110 1
GC -100-0 HA
GE 25-75 NA
GS 0- 130 NA
0-100 142 Mironov 1955 U.S.S.R. Eng 1 ish
0-100 112 Kracek NA U.S.A. English
25-40 27 Rokelmann 1983 Germany English
0-100 181 Renz 1978 Germany German
T-
P
NH3 + H20
N H ~ f NaSCN
NH3 + LiNO3
NH3 + LiN03
w3 + LiN03
NH3 + Licl
NH3 + Li2SO4
GE 25-75 NA 25-40 46 Ehmke 1983 Germany English
GE -90-305 NA 0.0-100 .o 23 Blytas 1962 U.S.A. English
GE 5-35 NA 28.8-38.3 225 Tsimbalist 1983 U.S.S.R. English
GS 0-80 NA 30-100 181 Renz 1978 Germany German
TE NA 0.264-0.313 15-19 13 Baldi 1971 Italy Italian
TE NA 0.251-0.574 15-23 13 Raldi 1971 Italy Italian
TE NA 0.303-0.459 15-19 13 Baldi 1971 Italy Italian
NH3 + KMO3
TE NA 0.293-0.593 15-22 13 Raldi
1971 Italy 1 t a1 ian
X - Liquid Phase R - Refrigerant c - pQm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - nmHg (2) - mbar NA - Not Available

_L
Fluid System
NH3 + KC1
Data
Type
TE
Weight, Z
Temp, Press. Range, X (R)
Range, OC atm Y (R)
NA
0.31 4-0.503
15-21
No.
13
Author
Raldi
Reference
Year Country
-
1972 Ttaly
Text
Italian
NH3 + KBr
TE
NA
0.285-0.474
14-19
13
'Baldi
1971 Italy
Italian
N H ~ + NaBr TE
NA
0.332-0.591
16-2 1
13
Baldi
1971 Italy
Italian
NH3 + NaCl
TE
NA
0.188-0.351
11-17
13
Baldi
1971 Italy
It ali an
NH3 + NaN03
TE
NA
0.312-0.359
15-16
13
Raldi
1971 Italy
Italian
NH3 + Na2SO4
TE
NA
0.351-0.359
16-17
13
Raldi
1971 Italy
Italian
NH3 f LiN03: TE
H 0 (0.73:l to GS
3 tw>
NB3 + LiNO3: GE
~~0 (2.3:1 to m)
5-35
0-60
NA
NA
0.9-29.1
10-40
225 Tsimbalist
46 Ehmke
1983 U.S.S.R.
1983 Germany
English
English
NB3 + LiN03:
1,4 BDL (0.77:1
to 9.0:1)(W)
GS
35 & 50
0,15-2
7.7-33.1
224 Tsimbalist
1983 U.S.S.R.
English
NH + LiNO3: GS
1,a HDL (2.7:1,
7.4: 1) (W)
35 6( 50
0.15-2
21.9-37.4
224 Tsirnbalist
1983 U.S.S.R.
English
x - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbentts) M -
(1) - mmHg (2) - mbar NA -
ppm by weight of A in Vapor Phase
Mole, W - Weight
Not Avallable

Table A. 1.0. (Cont. )
A.1.3.
Corrosion
Weight, %
Data Temp. Cor ro s ion X (R) Reference
Fluid System Type Range, OC Inhibitor, wt % Y (9) No. Author Year Country Text
NH3 + H2O:LiBr TE 200 None 10 67 Griess 1985 U.S.A. English
-
A.1.4.
Heat of Mixing
Weight, %
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, "C atm Y (R) NO Author Year Country Text
NH3 + H20 TE 10.5-15 1 9.5-78.8 144 Mollier 1909 Germany German
-
-
7
i--L
u-l NH3 + 1120 GE 15 1 0-60 144 Mollier 1909 Germany
German
NH3 + H20 GC 100 NA 0-100 149 Munsch 1978 Germany English
NH3 + H20 TE 12 & 10 NA 0-100 232 Uemura 1977 Japan Japanese
NH3 + H20 GTE NA NA 18.0-80.34 14 Saud 1909 France French
NH3 + H20 TE NA NA 18.0-80.34 15 Raud 1909 France French
NH3 + H-20 GS NA NA 0- 100 278 Zinner 1934 Germany
German
NH3 + H2O GCP NA NA NA 59 Fischer 1945 Germany German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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A-16

Table A.1.0.
(Cont.)
Data Temp.
Fluid System Type Range, "C
NH3 + H20: TGS 30-180
LiBr (2:3)(W)
Weight, X
Press. Range, X (R) Reference
atm Y (R) No. Author Year Country Text
NA 0-100
-
-
177 Radermacher 1981 Germany Eng 1 i eh
NA 0-100 178 Radermacher 1982 Germany German
0-25 16-100 47 Ehmke 1984 Germany German
t;
P
4 NH3 + NaSCN
GS 20-200
GE -65-100
0-2 5 16-100 47 Fhmke 1984 Germany German
NA 31.2-89.9 23 Blytas 1962 U.S.A. English
NH3 + LiSCN TE 27-138
NA 37.4-52.5 128 Macriss 1971 U.S.A. English
A. 1.6. Vapor-Liquid Enthalpies
NH3 + H20 TE -26.25 -
131.83
NH3 + H20 GS -100-200
NH3 + H20 GS -80-180
9.2-17.9
NA
NA
10-90 278 Zinner 1934 Germany German
0- 108 278 Zinnelr 1934 Germany German
0-100 278 Zinner 1934 Germany German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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A-18

Table A.1.0.
(Cont.)
Weight, X
Data Temp. Press. Range, x (R) Reference
Fluid System Type Range, 'C atm Y (R) No. Author
9-
Year Country Text
NW3 + R20 GC 150-250 4-35 8-100 51 Ellerwald 1981 Germany German
IJH3 f R20 PTS -34-21 4. 0.5-19.6 0-100 269 Zatorskii 1978 U.S.§.R, Russian
NH3 f E20 CP -5-7, 43-55 3.45-5.52, NA 94 Jain 1971 U.S.A. English
17.24-24.13
NH3 i- H20 P -62-499 0.07-lO9 0.0-100.0 53 El-Sayed 1985 U.S.A. English
0.0-100.0
NE3 4- H20: cs -20-210 1-30 0-100 179 Radermacher 1981 Germany English
3; LiAr (2:3)(~)
co
m3 -+ H20: GS -70-2 10
LiRr (2:3)(W)
1-30
-
0-1 00 178 Radermacher 1982 Germany
German
A.1.7.
Specific Heat
NH3 + H20 P NA NA
NH3 + H2O P -40-220 0.2-50
NB3 + H20 P -40-220 0.2-50
NHQ + H20 GS 10-30 NA
NA 232 Uemura 1977 Japan Japanese
0-1 00 276 Ziegler 1982 Switzerland German
0-100 277 Ziegler 1984 Switzerland English
0-100 232 Uemura 1977 Japan Japanese
X - Liquid Phase R - Ref rigerant e - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A. 1 .O.
(Cont.
Weight, %
nata Temp. Press. Range, X (R) Reference
Fluid System Type Range, *C atm
y
No. Author Year Country Text
(R) -
NH3 -+ H20: TGS 30- 150 NA
LiBr (2:3)(W) GE
-
0-100 177 Radermacher 1981 Germany Engli sh
NA
0-100 176 Radermacher 1981 Germany English
NA
0-100 178 Radermacher 1982 Germany German
NA
0-50 47 Ehmke 1984 Germany German
NA
0-50 47 Ehmke 1984 Germany
German
NR3 i LiN03:
R20 (3:l)(W)
GS
20-90 NA 10-50
32 Rokelrnann 1985 Germany English
NH3 + NaSCN TE 0-25 NA 12.3-42.6 23 Rlytas 1962 E.S.A. English
NH3 + UNO3 G SP NA NA 24-40 62 Gensch 1937 Germany German
A.1.8.
Stabilitv
NH3 + N&CN Nas. 150 NA NA 90 Macriss 1464 U.S.A.
English
X - Liquid Phase R - Refrigerant c - ppm by welght of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - rnbar NA - Not Available

Table A.1.0,
(Cont.)
A.1.9.
Viscosity
Weight, Z
Data Temp. Press. Range , x (R) Reference
Fluid System Type Range, OC atm Y (R) No * Author Year Country Text
NH3 + H20 GTS 10-149 1-20 0- 100 124 Pinevich 1948 U.S.S.R. English
-
-
NH3 + NaSCN GE -10-60 NA 35.0-100.0 23 Blytas
1962 U.S.A. English
NH3 + LiSCN TE 24-93 EA 39.0-52.0 128 Macriss 1971 U.S.A. Engl i s h
NH3 + LiNO3: GE 10-70 HA
H20 (2.3:l to a)
26.2-32.2 46 Ehmke 1983 Germany Eng 1 ish
N
r
A.l.lO. Mass Transfer Rate
NH3 + H20 GE 26
0.40-1.07
MA 36 Burnett 1970 U.S.A. English
NH3 + H20 C NA
NA
NA 163 Osipov 1972 rJ.S.S.R. English
NH3 + H20
GS
NA
0-4
0-40 163 Osipov 1972 U.S.S.R. English
NH3 + H20 GE NA
NH3 + NaSCN GE 25
10-20
1
NA 163 Osipov 1972 U.S.S.S. Eng 1 ish
40-50 104 Kashiwaga 1987 Japan Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of h in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

II_
I_
A,1.11.
Heat Transfer Rate
Weight, W
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, "C atm Y (R) No. Author Year Country Text
NH3 + H20 GS 30-36 NA NA 163 Osipov 1972 U.S.S.R. English
-
NH3 4- H20 GE NA 18-20 HA 163 Osipov 1972 U.S.S.R.
Eng 1 ish
NH3 f H20 C NA NA NA 163 Osipov 1972 U.S.S.R. Eng 1 ish
A.1.12.
Thermal Conductivlx
NH3 + H20 GS 0-60 NA 0- 100 232 Uemura .I977 Japan Japanese
N B ~ + NaSCN TE 20-69 NA 12.3-1 7 , 3 23 Rlytas I962 U.S.A. English
A.1.13.
Refractive Index
m3 + H20 GS NA 5-20 0-100 278 Zinner 1934 Germany German
A.1.14.
Entropy
'M3 + 820 CP -40- 2 20 0.2-50
NH3 4- H20 CP -40-220 0.2-50
WN3 f H20 CP NA NA
0-100 276 Ziegler 1982 Switzerland German
0-100 271 Ziegier 1984 Swftzerland English
NA 59 Fischer I935 Germany German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mHg (2) - mbar NA - Not Available

Table A.1.0.
(Cont.)
Weight, %
Data Temp. Press. Range, X (Q) Reference
Fluid System Range, OC atrn y (R) c_ No. Author - Year Country Text
NH3 + H20 P -62-499 0.07-109 0.0-100.0 53 El-Sayed
0.0-1 00.0
1985 U.S.A. English
NH3 + H20 GS - 5 0- 2 00 0 . 6-25 0-100 111 Kouremenos 1971 Greece
German
NH3 + H20 PTS -34-2 11 0.5-19.6 0-100 269 Zatorskii 1978 U.S.S.R. English
- __
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbat NA - Not Available

a,
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tr.
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A-24

~~
I_
Table A.2.0.
(Coat.)
Fluid System
Data
Type
TE
Temp.
Range, OC
25-93
Press. Range,
atm
0.002-0.26
Weight, %
X (R)
Y (R)
40 & 50
- No.
Author
58 Felli
Reference
Year Country Text
1979 Italy English
H20 + LiBr
GE
0-1 10
0.0 1-0.32
40-1 00
5% Pelli
1979 Italy English
H20 + LiBr
GC
0-180
0.01-1
0-70
186 Renz
1982 Germany English
H20 + LiBr
GS
0- 180
1-1000 (2)
30.0-100.0
218 Steimle
1981 Germany English
H20 + LiBr
GS
0-180
1-1000 (2)
30.0-100.0
219 Steimle
1981 Germany English
?
h)
H20 + LiRr
H20 + LiBr
GP
P
GTP
20-240
0-200
1-10,000 (1)
1.4-7000 (1)
38.0-45 .O
30.0-100.0
162 Osaka Gas
261 Usyuk-in
1985 Japan Japanese
1969 U.S.S.R. English
H20 + LiBr
TE
0- 100
0.0008-1.01
27.8-100.0
52 Ellington
1957 U.S.A. English
H20 + LiBr
TE
25-177
0.0010-3.61
39 6-50 3
165 Pennington
1955 U.S.A. English
H20 + LiBr
TEGP
4-182
0.001-0.85
37.7-100.0
137 McNeely
1979 U.S.A. English
H20 + LiBr
GE
28-56
0.0037-0.030
41.0-46.9
119 Ledding
1965 U.S.A. English
H20 + LiBr
GS
100
0.1-1
40- 100
46 Ehmke
1983 Germany Eng li s h
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, 'w - Weight
(1) - mmHg (2) - mbar YA - Not Available

92-V
n
+-4X
I l l
W
P
0
%-
N
r
P-
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0
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I
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0
0
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n
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9
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4
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3
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S
m
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I
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8
0
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b-.
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ul
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~ 0.02-1
Weight, X
Data Temp. Press. Range, x (R) Reference
Fluid System Type Range, '6 atm - Y (R) No. Author Year Country Text
TGE
103.9-160.6
1
46.3-87.5
-
77 Hasaba
-
1964 Japan
Japanese
GE
-10-1 10
1-1000 (1)
19.6-100.0
246 Uerniira
19 6 9 Japan
Japanese
GP
. o-100
1-100 (1)
20.0-100.0
246 Uemura
1969 Japan
Japanese
TE
26.30-35.35
22.54-23.65 (I)
5 1.6-73.0
246 Uemura
1969 Japan
Japanese
GS
20-120
0.006-2.0
15.0-50 .o
19 Biermann
1978 U.S.A.
English
GE
0-1 10
0.01-0.32
44-100
58 Felli
1979 Italy
English
TE
10-7 7
0.01-0.35
68
58 Felli
1999 Italy
English
GS
100
0.06-1
60-100
46 Ehmke
1983 Germany
Engli sh
CP
NA
NA
NA
78 Hasseler
1982 England
English
GE
0-1 10
0.01-0.32
30-100
58 Felli
1979 Italy
English
GE
0-1 10
0.0 1-0.32
50-1 00
58 Felli
1979 Italy
English
GE
0-1 10
0.01-0.32
35-100
58 Felli
1979 Italy
Eng 1 ish
GS
75-175
.0
30.0
55 Erickson
1985 U.S.A.
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmiIg (2) - mbar NA - 'Not Available

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rn
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m
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m
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0
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m
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N
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c
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0
CL'
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N
m
0
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I
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Q
A
W
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H c 3 U
a
w
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4-
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A-28

Table A.2.0.
(Cont.)
Fluid System
Data
Type
Temp.
Range, OC
-
Press. Range,
a t m
Weight, %
X (R)
Y (R)
- Reference
NO Author Year Country Text
-
H20 + DEG
GS
120
0-2
0-100
104 Klyucheva 1980 U.S.S.R. English
H20 + TEG
GE
60-160
200 & 918 (2)
0-100
200 Seher 1985 Germany German
H20 + DMF
TEP
30-150
17-760 (1)
0- 100
152 Myasnikova 1974 U.S.S.R. English
H2O + DMF
GEP
-10-40
NA
0-48
54 Ennan 1972 U.S.S.R.
Eng 1 ish
3;
N
\5,
HZ0 + PPA
GS
60-100
60-100
0.05-1.02
0.05-1.02
0.2-99.6 (M)
0.2-95.8 (M)
0.2-99.6 (M)
0.2-95.8 (M)
179 Rafflenbeul 1978 Germany German
179 Rafflenbeul 1978 Germany German
27-51
0.0028-0.010
13.8
119 Ledrling 1965 1J.S.A. English
27-43
0.011-0.028 Sat. at 2OoC 19 Biermann 1978 U.S.A. Eng 1 i s h
H*O +
LfC C13~02
GTE
27-41
0.015-0.033 Sat. at 2OoC 19 Riemann 1978 U.S.A. English
H20 + Li-
GTE
Senzenesulfonate
27-35
0.021-0.032 Sat. at 20°C 19 Biermann 1978 U.S.A. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mdg (2) - mhar NA - Not Available

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A-33
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A-34

Fluid System
H20 + LiBr:
4,BLN (20:1)(M)
H20 + LiBr:
4,BLN (20:1)(M)
H20 + Li1:EG
Data
Type
GEP
GS
GS
Weight, %
Temp. Press. Range, X (R) Reference
Range, OC atm Y (R) No. Author Year Country Text
_I
60-120 0-700 ( 1) 44.1-100.0 88 Iyoki 1984 Japan English
40-100 30-400 (1) 40.0 b 60.0 88 Iyoki 1984 Japan English
-20-160 0.5-700 (1) 10.0-100.0 157 Ono 1979 Japan English
-
~~0 + LiBr: GS
27-260 0.0013-1.33 5.0-25.0 11 Aronson 1969 U.S.A. English
u ul
€50 + NaOH: GS
KOH : C SOB
(1.67:1.5:1)(W)
50-175
0.01-1.0
30.0 55 Erickson 1985 U.S.A.
English
H20 + LiN03: GS
NaN03 :KNO
(3.05: 1.41 : 1) (W)
50-300
0.02-15
30.0-100.0 40 Davidson 1986 U.S.A.
English
H20 i- LiC1:
CaC12 : Zn(N0
(4.2 : 2.7 : 1) ?W$
GS
0-130
0.002-0.89
40-100 168 Pinchuk 1982 U.S.S.R. Russian
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.2.0.
(Cant.)
Weight, %
Data Temp. Press. Range, x (R) Reference
Fluid System Type Range, OC atm Y (R) No. Author Year Country Text
H20 + LiBr: GS 0-180
ZnBr2 : DEG
1-1000 (1)
-
-
15.0-40.0 157 Ono 1979 Japan English
H20 + LiBr: GS 0-180
ZnBr2 : EG
1-1000 (1)
15.0-40.0 157 On0 1979 Japan Engl I S h
H20 + LIRr: GS 0-180
ZnBr2:DMEDEG
1-1000 (1)
15.0-40.0 157 On0 1979 Japan English
?
w
rn
H20 + LiBr: GS 0-180
ZnBr2 :PI)
320 4- LIT: GS -20-160
LfBr :EG
1-1000 (1)
0.5-700 (1)
15.0-40.0 157 On0 1979 Japan
English
0.0-100.9 1.57 Ono 1979 Japan English
A.2.2.
Crystallization Temperature
R20 + LiRr TE -16.7-78
~~0 + LiBr GE -1 6.7-1 40
NA
NA
31.8-42.7 73 Hasaba 1960 Japan Y apanes e
24 .O-42.7 73 Hasaba 1960 Japan Japanese
H20 + LIBP GE 0-140
NA
19.2-50.0
248 Uemura 2964 Japan Japanese
H20 + LiBr GE -16.7-140
NA
19.2-50 .O 232 Uemura 1977 Japan Y apanese
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s) M -
(11 - mdg (2) - mbar NA -
ppm by welght of A in Vapor Phase
Mole, W - Weight
Not Available

Table A.2.0.
(Cant.)
Fluid System
H20 + LiBr
H20 + LiBr
H20 + LiRr
Data
2Zlz
GS
GS
GS
Weight, %
Temp. Fress. Range, X (R) Reference
Range, OC atm y (R) - No. Author - Year Country Text
-68-140 NA 24.0-100.0 121 Lower 1961 Germany German
-10-80 NA 30.0-46.0 131 Manago 1984 Japan English
-1 0-80 NA 30.0-46.0 156 Ohuchi 1985 Japan English
H20 + LiBr
GE
-73-93 NA 0.0-100.0
52 Ellington 1957 U.S.A. Engl f s h
H20 + LiBr
TE
-50-100
NA
8.2-20.2
33 Roryta
1961 U.S.A.
English
7 H20 + LiBr
w
ll
H20 + LiBr
GE
GS
15-75
4-143
NA
NA
9.2-12.1
NA
119 Ledding
11 Aronson
1965 U.S.A.
1969 U.S.A.
English
English
H20 + LiBr
TE
-72-159
NA
9.5-32.5
105 Kessis
1965 France
French
€1~0 + LiBr
GE
-.72-159
NA
0-100
105 Kessis
1965 France
French
H20 + LiRr
7%
-67.2-138
NA
25 .O-60.9
105 Kessis
1965 France
French
H20 + LiBr
GS
0-50
NA
35-100
181 Renz
1978 Germany
German
H20 + LiCl
TGE
-20- 160
NA
41.4-74.0
74 Hasaba
1964 Japan
Japanese
H20 -t- tic1
GE
-20-160
NA
40.0-65 .O
239 Uemuta
1967 Japan
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not 4vaflable

Table A.2.0.
(Cont.)
Data Temp.
Fluid System Type Range, OC
H20 + LJI TGE - 10-80
H20 + ZnBr2 GS 21
H20 4- LiSCN GS 22
R20 + LiNO3 GE 0-60
H20 -t NaOH GS 40-1 25
7 E20 9 KOH GS 20-125
W
H20 * CSF GE 6-56
R20 + CsBr GE 10-57
H20 -+ NaOH:KOH GS 30-1 10
f 1 : I >(W>
H20 -t LiBr: GE 15-65
CsBr (1:1 to
7:1)
I-120 + CsF:RbF GE -2.2-22
(1:b)
Press. Range,
atm
NA
NA
NA
NA
NA
NA
NA
HA
NA
NA
NA
Weight, X
x (R)
Reference
Y (R) No. Year Country Text
--- - Author _I_
18.9-40.1 246 Uernura 1969 Japan J a pane se
NA 11 Aronson 1969 U.S.A. English
19.0 6 AGA 1968 Y.S.A. English
30-65 225 Tsirnbaltst 1983 U.S.S.R. English
NA 55 Erickson 1985 U.S.A. English
NA
55 Erickson 1.985 U.S.A.
English
2.3-2.5 119 Ledding 1965 U.S.A. English
39.5-51.1 119 Ledding 1965 1J.S.A. English
NA 55 Erickson I985 U.S.A. English
20.9-56.0 119 Ledding 1965 U.S.A. English
2.5-4.2 119 Ledding 1965 U.S.A. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A In Vapor Fhase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - rnbar NA - Not Available

Table A.2.0.
(Cont.)
Fluid System
Data
Type
Temp.
Range, O C
Press. Range,
atm
IJeight, 2
x (R)
Y (R)
Reference
No. Author Year Country Text
-
-
H20 + LiBr:
LiSCN (0.25: 1
to 4:1)(M)
GE
-6-93
NA 25.0-47.0
127 Macriss 1970 U.S.A. English
H20 + LiBr:
LiSCN
(4:l to 1:4)(M)
GS
22-30
NA 9.7-16.2
6 AGA 1968 U.S.A. English
3;
H20 + LiRr:
LiSCN (l:l)(M)
u H20 + LiBr:
* LiSCN (1:l) (M)
GTE
GS
0.3-73.3
0-100
NA 30.0-44.0
84 Iyoki 1981 Japan 3 apane se
235 Uemura 1980 Japan Japanese
H20 + LiRr:
LiSCN (0:l to
B) (MI
GE
-10-90
NA 50.0-80.0
107 Knoche 1984 Germany
German
24-99
NA
NA
11 Aronson 1969 U.S.A.
English
10-143
NA
NA
11 Aronson 1969 U.S.A.
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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Table A.2.0.
(Cont.)
Fluid System
Data
Type
Weight, %
Temp. Press. Qanqe, x (R) Reference
Range, "C
atm
Y (R) - NO. Author Year Country Text
-10-65
NA
15.0-25.0 156 Ohuchi 1985 Japan English
10-63
NA
NA 11 Aronson 1969 U.S.A.
English
-20-65
NA
15.0-30.0 131 Manago 1984 Japan
English
10-50
NA
15.0-25.0 131 Manago 1984 Japan
English
-20-65
NA
15.0-30.0
156 Ohuchi 1985 Japan
English
29
NA
NA
11 Aronson 1969 U.S.A.
English
18-79
NA
NA
11 Aronson 1969 U.S.A.
English
H20 + LiBr:EG
( 10 : 1 ) (M)
GTE
2 1.50-74.9
NA
36.2-43.0
93 Iyoki 19 8 1 Japan
Japanese
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s) Y -
(1) - mmHg (2) - mbar NA -
p'pm by weight of
Mole, W - Weight
Not Available
A in Vapor Phase

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Table A.2.0.
(Cont.)
Weight, %
Data Temp. Pres s. Range, X (R) Reference
Fluid System Type Range, OC atm Y (R9 No. Author Year
_I
Country Text
H20 + LiBr:
ZnBr2:CaBrz
(l:l:l)(M) GS 43-100 NA NA 11 Aronson 1969 U.S.A. English
(1.2:1:0.5)(M) GS 4-27 NA NA 11 Aronson 1969 U.S.A. English
(1.2:1:0.12)(?4) GS 16 NA NA 11 Aronson 1969 U.S.A. Eng 1 ish
-
(1.2:1:0.3)(M) GS 4-60 NA NA
11 Aronson 1969 U.S.A.
English
? *
w
(1.1:1:0.27)(M) GS 43 NA
H20 + ZnBr2:
LiAr (1:i):~~
GE 0-42 NA
NA 11 Aronson ,1969 U.S.A. English
NA 157 Ono 1979 Japan English
H 0 + ZnBr2:
LjBr ( 1 : 1) :PD
GE
25-42 NA
NA 157 Ono 1979 Japan English
H20 + ZnBr2:
LiBr (1:l):
GE 32-42 NA
MBEDEG
NA 157 Ono 1979 Japan English
H20 + ZnBr2: GE 18-42 NA
LiBr (1:l):DEG
H20 + LiI: GS -20-160 0.5-700 (1)
LiRr:EG
NA 157 Ono
0.0-100.0 157 Ono
1979 Japan English
19 7 9 Japan English
X - Liquid Phase R - Re€rigerant e - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

A.2.3.
Corrosion
Weight, %
Data Temp. Corrosion
x (R) - Reference
Fluid System Type Range, "C Inhibitor, wt % Y (R) - No. Author - Year Country
Text
H20 + LiBr TE NA LiSCN 0.2 37 .o 232 Uemura 1977 Japan Japanese
LiN03
Li2WO4
0.3
0.2
Li3PO4 0.2
Li2SiF5.2I-l 0
Li6(M07024 5
0.2
.12w20 0.1
~i2~i03.11~20 0.2
LiClQ4.3Hp 0 2
NH2 CONH2 0.3
(C5H5NH)2C:NH 0.2
CgHqSC(SH):N 0.1
5 Methytbenzo
triazofe 0.2
n-octy l
Alcohol
C6H4 (CN) 2
0.1
0.2
Cobratec 99 0.1
Cobratec 100 0.1
c~H~(co~)O 0.1
NHCH:NCN:CN 0.2
X - Liquid Phase R - Refrigerant c ppm by weight of A in Vapor Phase
Y Vapor Phase A Absorbent(s) M Mole, W - Weight
(1) - mmHg (2) - mbar
NA - Not Available

Table A.2.0.
(Cont.)
Weight, X
Data Temp. Corrosion X (R) Reference
Fluid System Type Range, O C Inhibitor, wt X y (R) NO. Author Year Country Text
II
H20 + LiBr TE NA Above Inhibitors 37.0 232 Uemura 1977 Japan Japanese
+ LiOH 0.2
H20 + LiBr TE 143-182 Various Lithium 37.0-46.0 42 Dockus 1963 U.S.A. English
Salts + LiOH +
Organics 0.1-0.3
H20 + LfBr TE NA None 37.0 91 Iyoki 1978 Japan Japanese
-
~~0 + LiBr TE NA LiOH 0.2 37.0 91 Iyoki
?
* H2O + LiBt
v1
1978 Japan Japanese
GE NA LiOH
Cobrate 99
0.1-1
0.1-1
37.0 91 Iyoki 1978 Japan Japanese
Cobrate 100 0.1-1
0.3
0.2
0.2
0.2
0.2
37 .O 91 Iyoki 1978 Japan Japanese
0.1
0.2
0.2
0.3
X - Liquid Phase R - Refrigerant c - ppm by weight of A In Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

u
F:
0
A
.
V
W
0
B
aJ
I+
P
rd
P
w I * - k
N.4 NNd.-i.-iC\I c1
0-4
. e . . . .
c0 000000 0 in0
CUCCINNN.
. ... ..
,--If3
Q0000 00
w w w
E-.l U B
A-46

Table A. 2.0. (Cont . )
Veiqht, %
Data Temp. Corrosion x (R) Reference
Fluid System Type Range, 'C Inhibitor, wt X y (R) NO Author Year Country Text
LiC104.3H20 0 -2
NH2CONH2 0.3
( Cg Hg NH ) 2 c : NH 0 * 2
C~H~SC(SH):N 0.1
5 Methylbenzot
riazole 0.2
n-octylalcohol 0.1
CgHq(CN12 0.2
Cobratec 99 0.1
Cobratec 100 0.1
CgHq(C02)O 0.1
c. NfICH:NCN:CH 0.2
3;
U
H20 + LiRr
TE
-
-
NA Above Inhibitors 37.0 238 Uernura 1978 Japan
+ LiOH 0.2
Japanese
fl20 + LiBr
GE
NA None 42.0-74.0 237 Uemura 1979 Japan
J apane se
W20 + LiBr GE NA L iOH 0.2-1 37 .O 237 Uemura 1979 Japan
H20 + LiBr GE NA LiSCN 0.2
LiN03 0.3
37.0 237 Uemura 1979 Japan
L iWO4 0.2
Li3PO4 0.2
Li2SiF6.2H20 0.2
Japanese
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A In Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

(d (d
k
b-l
3
s
3
h
m
N
a,
L=l
h
m
N
m
a
N
a,
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td
s
PA
I l l
n
v
a
.
P-
c7
0
c-4
P
a,
d
P
td
E+
n
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C
F-4cJcvmCJ-i w
...... .
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I
0 N
c
Q)
2
......
de.J.-id.-iN
QOOOOO
Q
m o
m-i
E
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k
6
U
7.4
P
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a0
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04
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c
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n
e4z
A-48

Table A. 2.0. (Cont . )
IJeight, %
Data Temp . Cor r os ion x (R)
Fluid System - Type Range, "C Inhibitor, wt % Y (R)
Reference
NO Author Year Country
LI
Text
H20 + LiRr
NA
No ne 47.0
52 Sllington 1957 Y.S.A.
English
H20 + LiRr
TE 75
LiCcO 46.0
(0-2080 ppm)
39 Cohen 1966 U.S.A.
English
TE 50
12 Compounds 63.0
139 Melnik 1982 U. S.S.R.
Rus s Fan
H20 + LiBr
E 2 60
T, i 2 C r04 0.1 32.0
LiOH 0.16
67 Griess 1 9 8 5 ?J . S . A.
English
GE
NA
None
42 .O-74.0
90 Iyoki 1980 Japan
Japanese
TE
NA
None 59.7
90 Iyoki 1980 Japan
Japanese
H2O + LiCl
GTE
NA
LiOH 0.2 59.7
90 Iyoki 1980 Japan
Japanese
H2O + LiCl
GE
NA
NHCH:NCH:CH 0.2 59.7
Cobratec 99 0.1
Cobratec 100 0.1
C6H4(C02)0 0.1
CgHqSC(SR) :N 0.1
(c~H~NH)~C:NH 0.2
NH 2 CONH2 0.3
1,5 6 (MOT 024
. 1-2H20 0.1
90 Iyoki 1980 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of
Y - Vapor Phase A - Absorbent(s) M - Mole, 'CJ - Weight
(1) - mmxg (2) - mbar NA - Not Available
P L
in Vapor Phase

I__
Table A. 2.0. (Cont. )
Fluid System
Weight, %
Data Temp. Corrosion x (R)
Type .. Range, O C Inhibitor, wt % Y (R) -
Reference
No. Author Year Counrry Text
-
?
LiC104.3820 0.2
LiNOg 0.3
ti~i03.n1120 0.2
~ i ~ i ~ 6 . 2 ~ 0.22 0
Li3P04.1/2H20 0.2
L~wO~.H~O 0.2
L i S CN . H20 0.2
J320 + LiCl GE NA Above Inhibitors
+ LiOH 0.2
VI H20 + LiCl GE NA Cobratec 99 0-0.9
0
Cobratec 100 0-0.9
H20 + NH4SCN TE 24-100 None
1120 + LiBr: TE NA None
LiSCN
59.7 90 Iyoki 1980 Japan
59.7 90 Iyoki 1980 Japan
59.7 230 Uernura 1979 Japan
5.6-68.0 124 Macriss 1964 U.S.A.
52.0 89 Iyoki 1981 Japan
Japanese
Japanese
Japanese
English
Japanese
H20 + LiRr: TE NA LiOH
LiSCN
0.2
52.0 89 Iyoki
1981 Japan
Japanese
H20 -+ LiBr: GE NA None
LiSCN
52.0 89 Iyoki
1981 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase 4 - Absorbent(s) 3 - Mole, IJ - Weight
(1) - mmHg (2) - mbar N.4 - Not Available

Table A.2.0.
(Cont.)
Yeight, %
Data Temp. Corrosion X (R) Reference
Fluid System Type Range, OC - Inhibitor, wt % Y (R) i No. Author Year Country Text
0.3 52.0 89 Iyoki 1981 J apan Japanese
0.2
0.1
0.2
0.2
0.1
0.1
0.1
0.2
89 Iyoki 1981 Japan
Japanese
H20 f LiRr: GE NA Cobratec 99 0-0.8 52.0
LiSCN Cobratec 100 0-0.8
LiN03 0-0.6
89 Iyoki 198 1 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(I) - mmHg (2) - mbar NA - Not Available

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2
rd
a
rd
7
c
a
a
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m
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cd Fi
P
a to a
-I b-, r,
C
cd
a
rg
r,
c:
a
P-
a
c
a
a
p.
3 3
r-4
00
m
.I(
d
W
Q\
d
r?
U
E:
0
U
W
.
0
e4
.
P
a,
d P a
E-l
k
0
5
3
z ;I
a
k
0 m
N
3
0
.
C 0
N N
m m .
C
4-
2
0
z
0
m
N
Q
N
ln
CC)NF-4flN-+.I(r-lN4CC)”jNN
N
0 OOOOCCCOOQOCOO 0 I l l
a,
z
, . . . . . . . . . . . . .
0
0
4
V
a,
u
rd
b
P 0
V
d
a,
Lo
a
s
&
k
0
a
3
d
.li
4
4
u x z
4
z
4
Z
c z
W
w
W
E+
..
W
c3
..
k
G
*rl
IJ
A-5 2

Table A.2.0.
(Cont.)
Fluid System
Data
Type
I
Temp.
Range, "C
-
Corrosion
Inhibitor, wt %
Weight, X
X (R)
Reference
Y (R) NO Author -Year Country Text
-
TdiSiOg.nH20 0.2
LiC104.3~~0 0.2
H20 + LiBr:
LiSCN
GE
NA
Above Inhibitors
+ LiOH 0.2
52.0 230 Uemura 198 1 Japan Japanese
H20 + LiBr:
LiSCN
GE
NA
Cobratec 99 0-0.8
Cobratec 100 0-0.8
LiN03 0-0.8
52.0 230 Uemura 1981 Japan Japanese
150 & 250
Zi2MoO4
25.0 131 Manago 1984 Japan English
200 & 250
None
25.0 156 Ohuchi 1985 Japan English
50-175
None
20.0 131 Manago 1984 Japan English
200 & 250
None
20.0 131 Manago 1984 Japan English
150
None
25.0 131 Manago 1984 Japan Eng 1 ish
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Fhase A - Absorbent(s) M - Mole, W - Weight
(1) - mmRg (2) - mbar NA - Not Available

a a,
- d
cn
cn
n a, a
4 E E
-!
JI! a a
d (d (d
Ll '7 r,
C
a
rd
3
a, a
cn
cn
a, a,
d
m s
P, p.
m
R)
r, 9
d
a
E
m
a
a cn
a
a
r,
C
m
a
(d
(d (d
r, '7 '7
k
0
s
u
3
;I z
s
4
.',
m
H
m
M
n
u
C 0
u
W
8
0
4
0
.
cc)
I
hl
N
m
-3
hl
4
V Z Z
a,
c
0
z
a,
d
0
z
0
z
0
tn
d
4
z
4
z
4
z
4
z
4
z
W
c3
h
c
W
n
51:
.. d
W
h
w
W
i9 E,
A- 5 4

Table A.2.0.
(Cont.)
Data Temp.
Fluid System Type Ranpe, "C,
Weight, %
Cor ro s i on
x (R)
-L-..-.---u-w-u.-- Inhibitor, wt X Y (R)
_.
Reference
No. Author Year - Country Text
-
H20 + LiBr:
4,ELN (20:1)(M)
GE
NA
Cobratec 99 0.1-
0.8
50.3
85 Iyoki
19 8 2 Japan
Japanese
4
bl
Ll
H20 + LiBr:
4,BLN (20:1)(M)
GS
30 6 90
LiOH
Cobratec 99 + LiOH
Cobratec 100 + LiOH
50.3
85 Iyoki 1982 Japan
Japanese
H20 + LiBr:
Ethanol
(3: 1) (W)
TE
138
LiNOj
(0-300 ppm)
20.0
20 Riermann 1978 U.S.A.
English
H20 + LiBr:EG
(3:1)(W)
TE
138
LiNO3, Li2Mo04
(0-300 ppm)
20.0
20 Riermann 1978 U.S.A.
Eng 1 ish
K20 + LiBr:
ZnBr2 :EG
GE
160
None
7,3-14.2
157 Ono 1979 Japan
English
X - Liquid Phase R Refrigerant c -
Y - Vapor Phase A - Absorbent(s) M -
(1) mmHg (2) - mbar NA ppm by weight of A in Vapor Phase
Mole, W - Weight
Not Available

~ NA
A.2.4.
Heat of Mixing
Data Temp.
Fluid System Type Range, O C
H20 + LiUr GTZ 15-45
Press. Range,
atm
NA
Weight, %
X (R)
y (9)__
No. Author
I
46.1-99.7 76 Hasaba
Reference
-
Year Country Text
1961 Japan Japanese
H20 + LiBr GS 25
NA
40.0-100.0
76 Hasaba
1961 Japan Japanese
H20 + LiSr GE 15-45
NA
40.0-100.0
248 Uemura 1964 Japan English
W20 + LiRr GE 15-45
NA
40.0-100.0
232 Uemura 1977 Japan Japanese
7
H20 + LiBr GP -20-200
Ln
1120 + tiBr GTC 25
NA
NA
30.0-100.0
30.0-60.0
261 Usyukin 1969 U.S.S.R. English
170 Plank 1953 Germany German
H20 + LiUr GC 0-120
NA
30-100.0
121 Lower 1961 Germany Gernan
H20 + LIBr TC 25
NA
0.0-100.0
52 Ellington 1957 U.S.A. Engl i 8 h
H20 + LiRr TE 25
0.004-0.03
45.0-95.0
168 Pinchuk 1982 U.S.S.S. Russian
H20 C LiBr TSP 25-135
NA
35.7-40.0
136 Pfaust 1966 U.S.A. English
H29 + LiCI GTE 25
NA
56.4-69.2
253 Uemura 1965 Japan Japanese
R29 9 LiCl GS 2s
50.0-100.0
253 Uemura 1965 Japan Y apane se
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) PI - Mole, W - Weight
(2) - rnbar NA - Not Available
(1) - mmHg

Table A.2.0.
(Cont.)
Weiqht, X
Data Temp. Press. Range, x (R) Reference
- No. Author - Year Country Text
Fluid System Trpe RanE, OC atm Y (R)
H20 + LiCl GS 25 NA 50.0-100.0 239 Uemura 1967 Japan English
H20 + LiI GE 25 NA 40.0-100.0 246 Uemura 1969 Japan Japanese
H20 + H2SO4 GTC NA NA 0-100.0 170 Plank 1953 Germany German
H20 + DMF TE 20 NA 0-100.0 195 Saphon 1973 Germany
German
?
H20 + LiBr: GE 25
LiSCN (1: 1 )(M)
~1 H20 + LiBr: GS 25
LiSCN (l:l)(M)
H20 f LiRr: TS 25
LFSCN (l:l)(Pi)
H20 + LiRr: GE 25
ZnBr2 (1:2.6)(W)
H20 + LiBr: GE 25
4 ,RLN (20: 1)(M)
NA 40.0-100.0 84 Iyoki 1981 Japan Japanese
NA 30.0-100.0 235 Uemura 1980 Japan Japanese
NA 35.0-95.0 84 Iyoki 1981 Japan Japanese
NA 0.0-100.0 236 Uemura 1983 Japan Japanese
NA 41.9-100.0 234 Uemuta 1381 Japan Japanese
H26 + LiBr: TS 25 MA 42.0-96.0 87 Tyoki 1 9 8 3 Japan Japanese
4, BLN (20:1)(11)
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mHg (2) - mbar NA - Not Available

f
U
n
f
y 1-1
d rl
a
7 w
f
.d
I 4
M
z w fi
f
d
(d
d
1-1
d v)
M
tn
w " 2
Q
m
aJ
L:
(d
Q
(d
",
((I
r,
l4
Eo
m
4
I
n
u
C
0
u
.
W
.
0
hl
.
P
Q)
rl
P
(d
w
CI
0
5
3
1 4
b
Eo
?
c, 9 .
9
2 m
I I
0 0
hl (u
4 4
0 cc
03 Eo
00 hl 9
Eo
d
d
U
r-i
.?-I
%
h
H
0
m 0 0
0 .
0 In m
4 d 6
I I
I
6 U 0
. * * .
I
.
0
e m In
4 4
a!
2
c 2
m
Q
.
0 I
m
0
Q
.
. .
. .
m o
.
m 0 0
en
E o Q \
d
f A A
c o
u 4
CI
0 a
P
In In m c
N N (u
0
(c1
d
I
m
(u
VI
(3
A-5 8

Fluid System
*
Data
Temp.
Range, 'C
Press. Range,
atm
Veight, %
X (R)
Y (R)
Ref e rence
- No. Author - Year Country
Text
H20 + LiBr
GTS
0-100
NA
40.0-90.0
248
Uemura
1964
Japan
English
H20 + LfBr
TS
0-100
NA
40.0-90 .O
232
Uemura
1977
Japan
Japanese
H20 + LiBr
GS
0-100
NA
30.0-100.0
121
Lower
1961
Germany
German
H20 + LiBr
GP
20-240
NA
38 .O-45.0
162
Osaka Gas
1985
Japan
Japanese
H20 + LiBr
GE
25-80
NA
35.0-100.0
5 2
F, 11 ing t on
1957
U.S.A.
English
?
ln
H20 + LiBr
H20 + LiBr
P
TSP
0-250
25-135
0.1-15.5
SA
30.0-100.0
35.0-51 .O
80
136
Herold
Maust
,1987
1966
U.S.A.
U.S.A.
English
English
1120 + LiC1
GTE
5-90
NA
54.0-92.5
77
Hasaba
1964
Japan
Japanese
H20 + LiC1
GTS
. 5-100
NA
60.0-95.0
77
Hasaba
1964
Japan
Japanese
H20 + LiCl
GE
5-100
NA
50.0-100.0
239
Uemura
1967
Japan
English
H20 + LiCl
GS
5-100
NA
6O,O-95 .0
239
Uemura
1967
Japan
Englfsh
H20 + LiI
TE
0-80
NA
37.7-94.7
246
Uemura
1969
Japan
Japanese
H20 + LiI
GTS
0-80
NA
40.0-95.0
246
'Jemura
1969
Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Nole, b7 - Weight
(1) - mmHg (2) - mbar NA - Not Available

-5
"d
r(
bc
d
li!
9;
u?
CT)
E2
N
r.
m
7-4
aJ m
aJ
C
a
s
m
.d
-I
m
d
w
d tu tu rd
M a a
c a (0 Ki
w "-, r-,
+I
fi
m
a
tu
'7
m
cc
m
4
k
0
c u
3
d
a
C
C
w
zf
m
4
Y
0
%-
w
r-
cc
a
m
a
s
P-
k
0
p.
(d
3
E:
.d
n
u
E:
0
U
v
0
N
2
aJ
r?
P
tu
P
aJ
M
C
(d
@ E
. m
m
tn
aJ
k
P-
0
03
4.
I
0
0
2
.
.
0 0
0 0
m
I
c
e
I
c
N 0
N
a
0
0
C
d
I
4.
0
m
.
c
z
4
I l l
C
zf
I
m
m-4
I
a
0
m
03 N
I
a
I
0
N
0
0
r-4
I
0
I l l
!L
w
c3
w
H
w
CY
w
H
I%
E
+
0
N
X
oin
NE:
8U
Nc
ZN ZN
A-68

Data Temp. Press. Range,
Type Range, OC atm
~~0 + LiBr: TE 0- 100 NA
4,BLN (20:1)(M)
H20 + LiBr:EG GTE 40.04-82.32 NA
(10: l)(M)
H20 + LiRr:EG TS 20-100 NA
(10: 1)(M)
H20 + LiBr: GE 0-60 NA
ZnBr2 : EG
Weight, X
x (R)
Reference
NO. Author Year Country Text
y (R) -
-
50.4-100.0 88 Iyoki 1984 Japan English
40.3-100.0 93 Iyoki 1981 Japan Japanese
40.0-100.0 93 Ivoki 1981 Japan Japanese
15.0-80.0 157 Ono 1979 Japan English
3;
0
H20 + LiBr: GS 10-60 NA
ZnBr2 : EG
A.2.6. Vapor-Liquid-Phase Enthalpies
15.0-80 0 157 Ono 1979 Japan Eng 1 ish
H20 + LiRr GS 0-170 5-70Q (1)
H20 + LiBr GS 0- 100 5-700 (1)
H20 + LiRr GS 0- 120 5-700 (1)
H20 + LiRr GS 0-120 5-700 (1)
30.0-100.0 121 Lower 1961 Germany German
30.0-100.0 72 Sasaba 1961 Japan Japanese
30.0-100.9 248 Uemura 1964 Japan Eng 1 ish
30.0-100.0 23% Uemura 1977 Japan Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A In Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

I_
Table A.2.0.
(Cont.)
Fluid System
Data Temp. Press. Range,
Type Range, 'C atm
-
Reference
No. Author Year Countrv Text
H20 + LiBr
GP 20-240 NA
38.0-45 .O
162 Osaka

I_.
Data Temp. Press. Range,
Fluid System Type Range, OC atm -
H20 + LII GS 0-120 5-750 (1)
- NO
246
Author
Uemura
Reference
Year Country
-
1969 Japan
Text
Japanese
H20 + NaOH GS 0-120 5-700 (1)
20.0-100.0
255
Uemu ra
1966 Japan
Japane s e
H20 + H2SO4 CP NA NA
NA
78
Hasseler
1982 England
English
1120 + LiBr: GS 0-130 0.007-2.3
LiSCN
30.0-100.0
235
Uemura
1980 Japan
Japanese
K20 + LiRt: GS 0-130 0.007-0.9
LiSCN (1:1)(M)
30.0-100.0
84
Iyoki
1981 Japan
Japanese
5; m
H20 + LiBr: GS 0-250 NA
H20 + LiBr: GS 0- 120 1.3-1330 (2)
ZnBr2 ( 1 : 2.6) (W)
20.0-100.0
236
Uernura
1983 Japan
Japanese
~nC12 (1:1)(W)
20.0-40.0
131
Manago
1984 Japan
English
H20 + LiBr: GS 0-200 1-5000 (1)
ZnC12 (l:l)(w)
0.0-1 00.0
156
Ohuchi
1985 Japan
English
820 + LiBr: GP 0-200 1-so0 (1)
ZnCl2 (1:l)
0.0-100.0
162
Osaka Gas
1985 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - ?Tole, W - Weight
(1) - mmHg (2) - mbar Nh - Not Available

W aJ W
01 en m
U W al W
: s
c c:
m m
E - I Q a a
m (d (D
9 '7 +-I
k
c c, c
(D m m
a e e
m (d (d
9 c-, '9
c
m
a
m
r-,
c
a
m
c
cd (B
F
cg
r, '7
4
24
0
P.
H
ca
k
3
$
3
h
H
.rl
%
0
h c
t-4 0
W
m
a
N
N
U
m
hl
n
*I
c
0
u
W
0 0
a 0
Q C
v-4 .-i
I I
0 C
6
0
c
.
e
I
0
e
I
0
0 0
6 0
0 0
4 d
I I
0 0
6 0
,--I M
6
el
0
m
u? Q
N
r?
N
W
n
4
W
0
Q
rl
I
m
Q
F-.
N
v
I
m
.
0
n
N
U
0
0
0
r-4
I
m
0
.
0
0 4
0 z
N
I
CJ
U
0
a";
W b c
E+C
(d
#
I O 0 0 m
12 N N
1
I
I
0 0 0
CY
m
I
M
m
N
m
N
k n
- '4
l-l
A
..
+-+
00
N-i
Z-
n
d
.. ..
d
kV
pc
.rlw
..
A W
I-N
k
o m
N C
X N
A-64

Table 4.2.0.
(Cont.)
Weight, %
Data Temp. Press. Range, X (R) Ref e rence
Fluid System Type Range, OC atm
Y (R) No.
_e
Author Year
__I
Country Text
H20 + LiC1: PTE 25 0.003 45-9s 168 Pinchuk 1982 U.S.S.R. Russian
CaC12 : Zn(N0
( 4.2 : 2 . 7 : 1 )?W$
A.2.7.
Specfic T-leat
H20 + LiBr GTEP 24- 130.2 NA
33.8-89.1 71 Uemura
1960 Japan
Japanese
H20 + LiBr TE? 24-130 NA
33.8-89.1 248 IJemura
1964 Japan
English
y H20 + LiRr P NA
0
m
H20 + LiBr
GEP 20-100
NA
NA
NA 232 Uemura
40.0-90.0 155 Ogawa
197 7 J apan
1980 Japan
Japanese
Japanese
H20 + LiBr GS 0-80 NA
40.0-100.0 121 Lower
1961 Germany
German
H20 + LiBr P 0-200
GP
NA
30.0-100.0 261 Usyukin
1969 U.S.S.R.
English
H20 + LiBr GE NA NA
40.0-100.0 52 Ellington
1957 U.S.A.
Engl i 6 h
H20 + Lib P 0-250 0.1-15.5
30.0-100.0 80 Herold
1987 U.S.A.
English
H20 + LiBr TE 25 0.004-0.03
45.0-95.0 168 Pinchuk
1982 U.S.S.R.
Russian
X Liquid Phase R Refrigerant c ppm by weight of A in Vapor Phase
Y - Vapor Phase A Absorbent(s) M Mole, W - Weight
(1) - mHg
(2) - mbar NA - Not Available

99-FJ
?
N
0
n
W
P=
3
us 9
m a2
w a
l-4 CI.

Data Temv. Press. Range,
Fluid System Type Range, OC atm
H20 + LiBr: GEP 10-70
4,BLN (20:1)(M)
NA
Veight, X
X (R) - Reference
No. Author Year Coun
Y
Text
(R) - I__
50.0-100.0 234 Uemura 1981 Japan Japanese
H20 + LiRr: TEP 10-70
4,BLN (20:1)(M)
NA
so.0-100.0 87 Iyoki 1983 Japan Japanese
cn
H20 + LiBr: TEP 10-70
4,BLLN (20:1)(M)
H20 + LIBr:EG TEP 20-80
(10:l) (MI
H20 + LiBr:EC TF NA
(4.5 : 1 ) (\*I)
NA
NA
NA
50.0-100.0 88 Iyoki 1984 Japan English
50 . 0-95.0 243 Uemura 1972 Japan Japanese
55.0-75.0 20 Biermann 1978 U.S.A. Fngl i sh
H20 + LiC1: GS 0-130 0.003-0.03
CaC12:Zn(NO
(4.2 : 2 . 7 : 1 )?W?
45.0-95 0 168 Pinchuk 1982 U.S.S.R. Russian
A.2.9.
Viscosity
H20 + LiBr GTE 0-90 NA
39.3-88.6
76 Hasaba 1961 Japan
Japanese
H ~ O + LiBr TS 0-90 NA
60.0-95 0
76 Hasaba 196 1 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

I_
Table A.2.0.
(Cont.)
Fluid System
H20 f LiRr
Data
v TY Pe
GE
TS
Weight, %
Temp. Press. Range, X (R)
Range, OC atm Y (R)
5-90 NA 40.0-90.0
No.
248
Author
Uemura
Ref e rence
Year Country
-
1964 Japan
Text
English
TS
0-90 NA 40.0-95.0
232
Ueniura
1974 Japan
Japanese
GS
0- 100 NA 30.0-100.0
121
Lower
196 1 Germany
German
GP
20-80 NA 39. r3-45.0
162
Osaka Gas
1985 Japan
Japanese
GS
21-77 NA 40.8-100.0
52
Ellington
1957 1J.S.A.
English
GTE
5-90 NA 57.6-89.2
74
Hasaba
1964 Japan
Japanese
GTS
5-100 NA 60.0-95.0
74
Yasaha
1964 Japan
Japanese
TG E
60 & 80 NA 62.4-95.9
239
Uemura
1967 Japan
English
TS
5-1 00 NA 60.0-95 .0
2 39
Ue mu r a
1967 Japan
English
GTE
10-80
NA 37.7-94.7
246
Uemura
1969 Japan
Japanese
TS
10-80
NA 40.0-95.0
246
Zernura
1969 Japan
Japanese
GEP
-15-40 NA 0.0-48.0
54
Ennan
1972 U.S.S.R.
English
X - Liquid Phase TI - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Yole, W - I?eight
(1) - mnHg (2) - rnbar NA - Not Available

Table A.2.0.
(Cont.)
Data Temp. Press. Range,
Fluid System Type Range, "C atm
~~0 + Utropin GEP -10-40 NA
H2O + TEG GS 20-90 NA
Weight, Z
X (R)
Reference
NO
Y (R) -
Author Year Country Text
1_1
70.0-85 0 54 Fnnan 1972 U.S.S.R. English
0- 100 200 Seher 1985 Germany German
H20 + LiRr:
LiSCN (l:l)(M)
GTE
5-90 NA
47.3-86.5
84 Iyoki 1981 Japan Japanese
H20 + LiBr: GS 5-90
LiSCN (1: 1 )(MI
NA
NA
40.0-100.0 235 Uemura 1980 Japan Japanese
21.9-90.0 236 Uemura I983 Japan Japanese
820 + LiBr: GE 20-80 NA
~ n ~ 1(l:l)(W)
2
20.0-40.0 131 Manago 19 84 Japan English
20.0-40.0 156 Ohuchi 1985 Japan English
H20 + LiBr: GI! 20-80 NA
~ n ~ 1(1:l)
2
H20 + LiRr: TE 0-100 NA
4 ,BLN (20: I )(MI
20.0-30.0 162 Osaka Gas 1985 Japan Japanese
50.4-100.0 87 Iyoki 1983 Japan Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Ahsorbent(s1 M - Mole, W - Weight
(I) - mmHg (2) - mbar NA - Not Available

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A-70

A.2.10.
Mass Transfer Rate
Weight, %
Data Temp. Press. Ranqe, X (Q) Reference
Fluid System Type Range, "C atm
No . Author
-
Year Country Text
Y (R) -
11~0 + LiBr GE 20 Nh NA 133 Matsuda 1980 Japan Japanese
H20 + LiBr TE 27-41 0.0028-0.026 41.0-43.0 270 Zawacki
1973 U.S.A. English
H20 + LiBr TE 27-41 0.0028-0.026 40.0 271 Zawacki 1973 U.S.A. English
R20 + LiBr GE 25-49 0.0028-0.026 40.0-43.0 41 Deemer 1972 U.S.A. English
II2O + LiBr GE 25
NA 40.0 6 50.0 103 Kashiwagi .I983 Japan English
w
P H20 + LiBr GE 25 NA 40.0-80.0 101 Kashiwagi 1984 Japan Japane s e
N20 + LiBr GE 25 NA 40.0-80 -0
99 Kashiwagi 1985 Japan Japanese
A.2.11.
Heat Transfer Rate
H20 + LiBr GS 0-100 NA 30.0-100.0 121 Lower 1961 Germany German
H20 + LiBr GS 0-100 NA 40.0-100.0 121 Lower 1961 Germany German
H20 i- LiBr GS 30-120
H20 + LiBr: GS 30-120
Ray si lone
NA
NA
60.0 108 Knoche 1987 Germany Eng 1 ish
60.9 108 Knoche 1987 Germany English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in VaDor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not 8vailahle

Table A. 2.0. (Cont. )
Fluid System
--
Weight, %
Data Temp. Press. Range, x (R) Reference
Type Range, OC atin Y (R) No , Author Year Country Text
1_1
-
NA 60.0 108 Rnoche 1987 Germany English
H20 + LiBr:EG TE 56
(4.5:1) (w)
H20 + LiBr: GE NA
RbF : CsF
A,2.12.
7
4 N20 + LiBr
To
Thermal Conductivity
GTE 10-80
NA 26.9-32.4 20 Riermann 1978 U.S.A. English
NA 15.0-45.0 119 Ledding 1955 U.S.A. Enql i sh
NA 39.9-86.9 251 Uemura 1963 Japan Japanese
H20 + LiBr GTS 0- 100 NA 35.0-95.0 251 Uemura 1963 Japan Japanese
H25 + LiBr TGE 18-80
TS
NA 40 .0-90. 0
248 Uemura 1964 Japan English
w20 4- LiBr TS 0-100 NA 35 0-95.0 232 Uemura
1977 Japan
Japanese
H20 + LiBr GS 0-89 NA 40.0-100.0 121 Lower 1961 Germany
German
H20 + LiCl GTE 10-90 NA 59.4-90.0 74 Hasaba 1964 Germany Japanese
H20 -+ LiCl GTS 5-100 NA 60.0-95.0 74 Hasaba 1964 Japan
3 apanese
X - Liquld phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.2.0.
(Cant.)
Data Temp. Press. Range,
Fluid System Type Range, 'C atm
Weight, X
X (R)
Y (R)
-
No . Author
Reference
Year Country
I_
Text
H20 + LiCl TGE 20 NA
62.0-89.9
239 Uemura
1967 Japan
English
H20 + LiCl TE 10-90 NA
60.0-90.0
239 Uenura
1967 Japan
English
H20 + 'tic1 TS 5-100 NA
60.0-95 -0
239 Uemura
1967 Japan
English
A.2.13.
Refractive Index
H20 + LiBr: TGE NA HA
LiCl (2: 1 (M)
?
4 A.2.14. Entropy
w
40.0-100.0
247 !lemma
1970 Japan
Japanese
H20 + LiBr GS 0-120 2-700 (1)
30.0-100.0
248 Uemura
1964 Japan
English
H20 + LiBr GS 0-120 2-700 (1)
30.0-100.0
77 Hasaba
1964 Japan
Japanese
H20 + LiBr GS 0-120 2-700 (1)
30.0-100.0
232 Uemura
19 7 7 Japan
Japanese
11~0 + LiBr P 0-250 0.1-15.5
30.0-100.0
80 Herold
1987 U.S.A.
English
H20 + LiBr GS 0-140 0.001- 1.0
30.0-100.0
121 Lower
1961 Germany
German
H20 + LiBr GTSP 0-100 0.001-1 .o
30.0-100.0
110 Koehler
1987 U.S.A.
English
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s) M -
(1) - mmHg (2) - mbar NA -
P Pr [I by weight of A in VaDor Phase
Mo : Le, W - Weight
Nor : Available

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Table A.2.0.
(Cont.)
Fluid System
H20 + LiBr
H20 + LiRr
+ n-octanol
Weight, X
Data Temp. Press. Range, x (9) Reference
Type Range, OC atm Y (R) No. Author Year Country Text
GS 0-100 NA 40.0-100.0 121 Lower 1961 Germany German
GE 20 NA 50.0 102 Kashiwagi 1985 Japan Japanese
-
-
H20 + LiBr
+ n-octanol
GE 20 NA 50.0 100 Rashiwagi 1984 Japan
Japanese
H20 -+ LiBr
+ n-octanol
GE 20 NA 50.0 99 Kashiwagi 1985 Japan Japanese
GTE 5-90 NA 60.8-90.3 74 Hasaba 1964 Japan Japanese
GTS 5-1 00 NA 60 . 0-95 .O 74 Nasaba 1964 J aDan Japanese
Y20 + LiCl
TS 5-100 NA 60.0-95.0 239 Uemura 19 67 Japan
English
H20 4- LiI
GTE 5-80 NA 37 . 7-88.0 246 TJemura
1969 Japan Japanese
H20 + LiI
H20 + LiBr:
ZnBr2 (1:2.6)(W)
TS 0-80 NA 40.0-90.0 246 Uemura 1969 Japan Japanese
TE 20-80 NA 22.0-70 .O 236 Uemura 1983 Japan J ap anese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Ahsorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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Table A. 3.0. (Cont. )
Fluid System
CH3OH + LiBr
Data
BE
T-l%
Temp.
Range, "C
-10-170.5
Weight, %
Press. Range,
X (R)
atm
Y (R)
1.4-3070 (2) 39.7-74.7
- NO
185 Renz
Author
Ref e reme
Year Country
I__
1981 Germany
Text
English
CH3OH + LiBr
TE
-10-140
1.4-1005.8 (2) 39.7-74.7
182 Renz
1980
Germany
German
CH3OH + LiBr
GS
-20-1 60
1-3000 (2)
40-100
185 Renz
1981
Germany
English
CH3OH + LiBr
GS
-20-140
2-1000 (2)
0-1 00
182 Renz
1980
Germany
German
CH30H 3- LiBr
GE
-10-1 10
0.002-0.8
50-100
58 Felli
1979
Italy
English
4
4
CH30H + LiBr
CH3OH + LfBr
TE
GS
35-100
-20-100
0.02-0.72
0.05-1
50
20-60
58 Felli
48 Eichholz
1979
1982
Italy
Germany
English
German
CH30H + LiBr
TGEP
20-100
0.02-5
69.3-100
48 Eichholz
1982
Germany
German
CH3QH + LiBr
GE
20-100
0-4
69.3-100
48 Eichholz
1982
Germany
German
CH3OH + ZnBr2
GS
-20-110
5-1000 (2)
26-100
184 Renz
1981
Germany
German
GE
-10-110
0.006-1.6
30-100
58 Felli
1979
Italy
English
CR3OH + ZnBr2
TGEP
20-100
0.05-1
76.2-98.4
48 Eichholz
1982
Germany
German
CH30H + ZnBr2
GE
20-1 00
- 0-3.5
76.2-98.4
48 Eichholz
1982
Germany
German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absotbent(s) M - Mole, W - Weight
NA - Not Available
(1) - mmHg (2) - mbar

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Table A.3.0.
(Cont.)
?
03
Fluid System
CH30H + LiI:
ZnBr2 (2:1)(M)
CH30H + LiBr:
LiCl (0.5:1)(M)
CH3OH + LiCl:
ZnBr2 (2:1)(M)
CH3OH + H20:
LiBr
cI CH3OH + H20:
LiBr
C2H5OH + LiBr
nata
Type
TP
TE
TE
GS
GS
TE
Weight, X
Temp. Press. Range, X (R) Ref e rence
Range, O C atm Y (R) No. Author Year Country Text
20-70 30-769 (1) 56.8-85 3
-
-
244 Uemura 1972 Japan Japanese
30-89 0.039-0.786 67.8-80.0 1 4ker 1965 U.S.A. English
30-115 0.030-1.055 41 .0-71.4 1 Aker 1965 U.S.A. English
60 6 100 NA 0.0-100.0 108 Knoche 1987 Germany English
-10-120 10-1000 (2) NA 108 Knoche
1987 Germany German
35-1 14 0.011-0.903 51.9-66.6 1 Aker 1965 U.Se.4. English
C2H50H f LiRr
GE
28 0.024
Sat. at 25OC 119 Ledding 1965 U.S.A. English
C2H50H + LiBr
TGEP
20-70 26.3-475 (1) 50 5-90 0 233 Uemura 1975 Japan Japanese
C2H5OH + LiC1
GE
26 0.024 Sat. at 25°C 119 Ledding 1965 U.S.A.
English
C2H50H + LiI
TGEP
29.9-72.38 12.24-384.57 (1) 50.7-94.7
86 Iyoki 1982 Japan Japanese
X Liquid Phase R Refrigerant c ppm by weight of A in Vapor Fhase
Y Vapor Phase A - Absorbent(s) M Mole, W - Weight
(1) - mmHg (2) - mbar
NA - Not Available

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~~ ~ ~~
Table A. 3.0.
(Cont.
Fluid System
CH30H + LiBr
Data
2€!'2
TE
Temp.
Range, OC
18 & 25
Press. Range,
atm
NA
41.7 & 46.1
-
-
Reference
No. Author Year Country Text
164 Pavlopoulos 1954 Germany German
CH3OH + LiBr
GS
0-70
NA
50 & 100
181 Renz 1978 Germany German
CH30H + LiBr
TE
15.5-100
NA
40.0-59.0
183 Renz 1981 Germany
German
CH30H + LiCl
TE
18 & 25
NA
69.4 & 70.9
164 Pavlopoulos 1954 Germany German
CH30H + LiCl
GTE
0-30
NA
69.5
158 Oosaba 1950 Japan Japanese
3; CH30H + LiI
03
w
CH30H + LiI
TE
TE
-17-113
18 & 25
NA
NA
22.0-64.0
36.9 & 41.1
183 Renz . 1981 Germany German
164 Pavlopoulos 1954 Germany German
CH3OH + LiSCN
TE
9.3-90
NA
38.0-44.0
183 Renz 1981 Germany German
CH30H + ZnBr2
GTE
0-80
NA
18.9-32.9
241 Uemura 1976 Japan Japanese
CH30H + NaF
m
18 & 25
NA
99.9 & 99.9
164 Pavlopoulos 1954 Germany
German
CH30H + NaCl
TE
18 & 25
NA
98.6 & 98.7
164 Pavlopoulos 1954 Germany German
CH30H + NaBr
TE
18 & 25
NA
85.2 & 86.0
164 Pavlopoulos 1954 Germany
German
CH30H + NaI
TE
18 & 25
NA
54.6 & 58.1
164 Pavlopoulos 1954 Germany German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

a,
W
k
0
s u
3
4
z ;I
u
c
0
V
v
0
.
m
-4
aJ
r-l
P m
w
c
m
d
I
c
A-84

Table A.3.0.
(Cont.)
Data Temp. Press. Range,
Fluid System Type Range, OC atm
_c
CH30H + LiBr: GE -1 0-80
Zn'Br2 (2:1)(M)
NA
28.0-60.0
NO
_I
Author
Reference
Year Country Text
-
249 Uemura 1969 Japan 3 apanese
CH30H + H20: GS -25-60
LiBr
NA
0.0-100.0
108 Knoche 1987 Germany German
CH30H + LiI: TE -12-75
ZnBr2 (2: 1) (M)
NA
34.1-40.7
228 Uemura 1973 Japan German
CK30H + Liz: GE -10-70
3; ZnBr2 (2:1)(M)
co
cn
C2HSOH + LiRr GE 0-90
NA
NA
35.0-40.0
51.0-7 7.0
240 Uemura 1975 Japan J ap anew
233 Uemura I9 75 Japan Japanese
C2H5OH + LII GTE -17.73- NA
196.33
nC3H70H + LiRr GTE 0-40 NA
25.8-68.2
58.6
86 Iyoki 1982 Japan Japanese
158 Oosaba 1950 Japan Japanese
A.3.4.
Heat of Mixing
CH30H + LiBr GE NA NA
40 . 0-1 00.0
245 Uemura
1965 Japan
Japanese
CH30H -k LiRr TGE 25 & 40 NA
45.0-100.0
48 Eichholz
1982 Germany
Ge man
X Liquid Phase R Refrigerant c - ppm by weight of A in Vapor Phase
Y Vapor Phase A Absorbent(s) M Mole, W - Weight
(1) - mdg
(2) - mbar NA - Mot Available

QJ
u)
W
F:
m
za,
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(d
27
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(r\
.-i
m
u3
m
F-4
a,
M
m
c
pl
rd
k
3
4
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=,
(d
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7
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aJ
3
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m
N
m
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R
hl
e
0
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W
c
0
0
rl
c
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cc)
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e
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H
L n
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aJ
br
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m
o r 6
v1
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e,
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!L
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c
2 z
c
P
0
C
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0
4
0
4
w
C3
h
N
k
m
G
N
+
m
0
z
V
p7
m
m
Fi
cf
E-
F
c.
rn
13
€+
w
c9
03
c3
rn
L!J
C
k
E:
N
m
n
22
L
Fz
&
-I-
.I-
U
'd
4
+
0
X
N
f +
T.
0
z
u
m
hl
A
W
x P-1 d
N
V
A-5 6

Table A. 3.0.
(Cont.
Fluid System
CH30H + LiBr
Data
TEpe
TS
Temp.
Range, O c
5-95
Press. Range,
atm
NA
Weight, %
X (R)
Y (R)
55.0-95.0
NO.
L
245
Author
Uemura
Ref ere nc e
- Year Country
1965 Japan
Text
Japanese
CH30H + LiBr
GE
5-90
NA
41.5-100.0
185
Renz
1981
Ge rmany
English
CH30H -f LiBr
TEP
5-90
NA
42.0-89.0
183
Renz
1981
Germany
German
CH30H + LiBr
GS
10-90
NA
40.0-100.0
185
Renz
1981
Germany
German
CH30H + LiBr
GS
10-90
NA
40.0-100.0
183
Rem
1981
Germany
German
GS
10-90
NA
40.0-100.0
182
Renz
1.980
Gernany
German
TEP
20-90
NA
26.0-98.0
183
Renz
1981
Germany
German
CH30H + LiI
GS
20-1 00
NA
20.0-100.0
183
Renz
1981
Germany
German
CH30H + ZnBr2
GTE
5-60
NA
40.0-94.0
24 1
Uemura
1976
Japan
Japanese
CH30H + ZnBr2
TS
5-60
NA
40.0-95.0
24 1
Ueuura
1976
Japan
Japanese
CH30H + LiSCN
TEP
20-90
NA
44.0-98.0
183
Renz
1981
Germany
German
CH30H + LiSCN
GS
20-90
NA
40.0-100.0
183
Renz
1981
Germany
German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Hole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

UJ
aJ
M
m
a, a,
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E
m (D
a
(D
aJ
u)
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m
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c
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&
a,
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h
c
k
a,
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2
4
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m
pl
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9-i
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a
e
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4
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P
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r- R
W
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0
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c2
03
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6
0
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I
Ln
m
W
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c3
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c7
cn
c3
wv,
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X N
Q k
FlFa
x c
V N
A-88

Table A.3.0.
(Cont.)
Weight, %
Data Temp. Press. Range, x (R) Ref ere nce
-
Fluid System Type Range, OC atm y (R) No. Author Year Country Text
CH30H + LiRr GS -30-140 0.001-5 40.0-100.0 48 Eichholz 1982 Germany German
CH3OH + ZnBr2 GS 0-120 2-760 (1) 20.0-100.0 241 Uemura 1976 Japan Japanese
CH30H + LiI: GS -60-1 20 2-2000 (1) 20.0-100.0 228 TJemura 1973 Japan German
ZnBr2 (2:1)(M)
-
-
CH3OH + LiI:
ZnBr2 (2: 1 ) (M)
GS
-60-120 2-2000 (1) 30.0-100.0 240 Uemura 1975 Japan Japanese
7 CH3OH + LiBr: GS
03 ZnBrz (2:1)(M)
a
C2H50H + LiBr GS
-30-120 2-2000 (1) 15.0-100.0 249 Uemura
15169 Japan Japanese
0-120 2-760 (1) 30.0-100.0 233 Uemura 1975 Japan Japanese
-29.85- 0.1-4000 (2) 20.0-100.0 86 Iyoki 1982 Japan Japanese
130.15
54-120 1-2 0.0-100.0 34 Bosnjakovic 1931 Germany German
18-107 1.6-4 10.0-97 .O 34 Bosnjakovic 1931 Germany German
0-100 NA 0.0- 100.0 34 Bosnjakovic 1931 Germany Ge man
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mhar NA - Not Available

e
U
r:
0
U
.
v
.
0
rn
k
91
4
P
m
H
u
X
0,
H
h
k
u
c
3
0
a,u
V
c
k
a , '
k
0
5
3
81
.
2
a,
E+
d)
rn
al
G
m
a
(d
'7
c:
m
a
m
3
m
a
m
r-4
Q
k
a,
5
E!
m
4
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r.
0
03
I
0
In
Ln
-4
z
0
03
I
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4
CL
w
E+
k
'ri
I4
d-
Ec
0
T
U
m
m
.d
6"
m
p.
m
'7
F:
m
a
a
'7
m
h
m
cl
m
k
3
9
m
m
c\I
z
r-4
m
m
I
m
m
v-4 .
2
m
\D
I
In
d
!&
k?
F4
k
m
.d
I4
+
X
0
5:
U
m
N
c
u)
*vi
rl
M
d
w
h
C
m
a,
c3
E
N
00
m
cl
E
a,
N
(d
k
a,
c
I4
a,
m
9
d
0
Ln
4
.
h
W
N
a?
d
I
hl
m
I-.
4
w
CI,
k
p?
'ti
4
f
X
0
m
E
a,
v)
4
v z z
a,
vlcu
m m
c m
PIC
!L
U
I l l
A-90

Table A. 3.0. (Cont. )
Fluid System
CH30H + LiBr:
ZnBr
Data
Type
TE
Weight, %
Temp. Press. Range, X (R)
Range, OC atm Y (R)
100-200 0.1-38 (1)
28.0
- No.
Author
-
Reference
Year Country
109 Koebel 1981 Germany
Text
German
A. 3.9. Viscosity
CH30H + LiBr
TGEC
5-95
NA
49.0-100.0
245 Uemura 1965 Japan
Japanese
CH30H + LiBr
TS
5-95
NA
55.0-95.0
245 Uemura 1965 Japan
Japanese
?
a
c1
CH3OH + LiBr
CH~OH + LiBr
GE
TEP
NA
10-90
10-1050 (1)
NA
60.0-95.0
43.0-82.0
245 Uemura 1965 Japan
183 Renz 1981 Germany
Japanese
German
CH30H + LiBr
GS
10-90
NA
40.0-30.0
183 Renz 1981 Germany
German
C'd3OH + Liz
TEP
20-90
NA
26.0-58.0
183 Renz 1981 Germany
German
CH30H + LiI
GS
20-90
NA
20.0-60.0
183 Renz 1981 Germany
German
CH30H + LiSCN
TEP
20-90
NA
40.0-72.0
183 Renz 1981 Germany
German
CH3OH + LiSCN
GS
20-90
NA
40.0-80.0
183 Renz 1981 Germany
German
CH30H + ZnBr2
GTE
5-60
NA
40.0-94.0
241 'Jernura 1969 Japan
Japane s e
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s1 M -
(1) - mmHg (2) - mbar NA -
ppm by weight of A in Vapor Phase
Mole, W - Weight
Not Ava i 1 ab le

aJ
m
aJ
C
fll
a
m
c-,
tu aJ Q)
m m m
0) 0) c C 9) c:
C C (D (D C m
fll (D
(D
a a E E a E
(D (D aJ
aJ m aJ
+J +I c3 LQ 9 a
G
(D
a m
Q
m
a
m
.-I
c
tu
a
m
r,
m
\D
m
rl
3;
C
c (D
(D E
e k
m e,
9 W
m
a m
h
C
2
b
aJ
c3
4
a7
m
.-i
C
(D
a
m
c-,
m
h
a\
d
c
(D
a
m
",
k
0
c u
3
c
z 4
m
k
3
E
aJ
=,
d
e
N
0
In
m
I
0
0
4
(D m m OY
k $4 k w
3
N N 3
2
e
2
C c:
aJ 0)
e
aJ
aJ E
5 3 3
0
m
I
C
m
hl
G
ln
2 w 3
0 0 0 0 0
. . . .
a C 0 b?
m m m m
I
I
I I
0 Q 0 r-
.
Q
N
0
N
03
e
0
0
0
d
.
I
0
m
e
aJ
o m
s
P.
k
0
Q
m
P
C
'rl
c
c
z
4
z
I l l
c
u r z
n
u o
c v
mu
k C
ala
WP
0
9
1
m
0
\s,
I
m
wrom
aJPD
a?4 e
I l l
n
u
v3
E+
cn
W
N
k
m
G
N
+
z
0
m
CJ
I l l
A
x *z
A-92

Table A. 3.0.
(Cont.
Weight, %
Data Temp. Press. Range, x (R) Reference
Fluid System & Range, OC atm Y (R) No. Author Year Country Text
C2~50H + LiBr TGE 5-60 NA 60.0-95.0 233 Uemura 1975 Japan Japanese
-
-
A.3.11.
Heat Transfer Rate
CH30H + H20: GS 5-100 NA
LiBr
NA 108 Knoche 1987 Germany German
X - Liquid Phase R - Refrigerant c - ppn by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.4.0.
AMINES BINARY AND MULTICOHF'ONNENT ABSORPTION FLUIDS PROPERTIES DATA
A. 4.1. Vapor-Liquid Equilibrium
Data Temp.
Fluid System Type Range, 'C
--
CH3NH2 -+ NaSCN TEP 25- 120
Weight, %
Press. Range,
x (R)
atm
Y (R)
0.486-26.1 46.0-64.7
Reference
EO. Author Year Country Text
7
-
194 Rush
1967 U.S.A. Eng bi sh
CH3NH2 + NaSCN GS 15-95
1.38-8.27 49.6-68.5
18
Biermann
1978 U.S.A.
English
CH3NH2 -+ LiSCN TEP 26-141
0.064-13.2 43.8-79.5
126
Mac r i ss
1970 U.S.A.
English
CB3NH2 + LiSCN GS 49-142
B .38-8.2 7 48.1-62.9
18
'Bierrnann
1978 U.S.A.
English
7 CH3MB2 + LiSCN GE 20
u3
z.
CH3NH2 + LiN03 GE
20
0.9 0.65
0.9
0.45
180
180
Re nz
Re nz
1982 Germany
1982 Germany
English
English
CH3NH2 + LiSCN GS 20-60
NA
60-68
27
Bokelmann
1983 Germany
EngP is h
CK3NH2 -1- LiSCN GS 2 0-6 0
NA 60-68
46
Ehrnke
1983 Germany
Eng 1 i sh
48.3-8.27 44.0
19
Sierrnann
1978 U.S.A.
English
1.38-6.89 34.4-66.5
19 Biermann
1978 U.S.A.
English
X - Liquid Phase R - Refrigerant c - pprn by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.4.0.
(Cont.)
Weight, %
Data Temp. Press. Range, x (R) Reference
Fluid System Type Range, OC atm Y (R) No. Author Year Country Text
-
-
CH NH2 + TE 65-157 1.38-8.27 19.7-37.3 19 Riermann
Co?SCN)2
I_._
1978 U.S.A. English
CH3NH2 f CUSCN TE 63-139 1.38-8.27 21.0-40.9 19 Biermann 1978 U.S.A. English
CH NH2 +
Cuf SCN) 2
TE
50-105
4.83-8.27
39.4-51.5
19 Biermann
1978 U.S.A.
Eng 1 ish
CH3NH2 f H20
P
NA
NA
NA
257
Uemura
1967 Japan
Japanese
3;
rD
UI
CHrjNH2 f H20
CH3NH2 + H20
GS
GS
-40-1 20
-30-160
0.1-5.0
0.2-8.0
0.0-100.0
0.0-1 00.0
138
138
Mehl
Mehl
1935 Germany
1935 Germany
German
German
CH3NH2 + H20
GS
0-70
NA
0- 100
181
Renz
1978 Germany
German
CH3NH2 + EG
TE P
-10-180
0.22-10 (2)
10-40
47
Ehmke
1984 Germany
German
CH3NH2 + EG
GTS
-20-1 80
0.2-10 (2)
10-100
47
Ehmke
1984 Germany
Ge man
CH3NH2 + EG
GS
-20-180
0.2-10 (2)
10-100
31
Bokelmann
1985 Germany
German
CH~NH~ + EG
GE
40
NA
8.1-66.7
190
Roberson
1966 U.S.A.
English
CH3NH2 + EG
GS
20-60
NA
25-35
27
Bo ke lmann
1983 Germany
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.4.0.
(Cont.)
Fluid System
CH3NI-I2 + EG
CH3NH2 + TEG
CH3NH2 + TEG
CH3NH2 + TEG
CH3NH2 + TEG
Data
Type
P
GS
GE
GE
GS
GS
Weight, %
Temp. 'Press. Range, x (N Reference
Range, O C atm Y (R) No. Author Year Country Text
u_
-
20-60 NA 25-35 46 Ehmke 1983 Germany Eng 1 ish
40 & 49 NA 2.7-39.0 190 Roberson 1966 U.S.A. English
20-60 0.9 (2) 0.1-0.20 180 Renz 1982 Germany English
20-60 NA 10-15 27 Bokelmann 1983 Germany English
20-60 NA 10-15 45 Ehmke 1983 Germany Eng 1 ish
7 CH3NH2 + MEDEG G
Lo
40 NA 14.9-81.5 190 Roberson
1966 U.S.A. English
20-60 0.9 (2) 0 15-0 35 180 Renz 1982 German English
CH3NH2 + 1,4
BDL
CH3NH2 + 1,4
B DL
CH3NH2 -+ 1,4
BDL
GE
GS
GS
40 NA 5.7-58.0 190 Roberson 1966 U.S.A. English
20-60 NA 20-30 27 Bokelmann 1983 Germany Eng 1 ish
20-60 NA 20-30 46 Ehmke 1983 Germany English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbenr(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.4.0.
(Cont.)
Fluid System
CH3NH2 + (GLY)
Data
X?E
GS
Weight, X
Temp. Press. Range, X (R) Reference
Range, 'C atm Y (R) NO Author Year Country
-
-
20-60
0.9 (2)
0.15-0.40 180 Renz 1982 Germany English
Text
GS
20-60
NA
20-35 27 Sokelmann 1983 Germany English
CR3NH2 + GLY
GS
20-60
NA
20-35 46 Ehmke 1983 Germany English
GE
40
NA
2.4-35.9 190 Roberson 1966 U.S.A. English
U
CH3NH2 +
NaSCN:LiSCN
(4:1)(W)
CH3NH2 +
NaSCN :LiSCN
(1.53: 1 )(W)
TE
TE
39-136
48-148
1.38-7.58
1.38-7.58
30.6-53.4 19 Siermann 1978 U.S.A. English
26.4-54.3 19 Biermann
1978 U.S.A. Eng 1 i sh
GE
TGS
20-200
0.7-20 (2)
0- 100 177 Radermacher 1981 Germany
0-100
English
GS
-20-200
0.5-30 (2)
0-100 176 Radermacher 1981 Germany
Eng 1 ish
CH3NH2 + H20:
LiBr (2 : 3) (W)
GS
-30-300
0.5-30 (2)
0-100 178 Radermacher 1982 Germany
German
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s) M -
(1) - mmHg (2) - nbar NA -
ppm by weight of A in Vapor Phase
Mole, W - Weight
Not Available

x h 3..
d c h A 3.
d d d
m e ru m m
ru
k
E
E
W
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W a, W
c c3
a,
c3 (3
W a,
t-4 a,
-?
E!
W .9
E
s
Y
s
e
w w
0
m
c ci
n
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c
0
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r. h C 0
u
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I I I
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0 0 0 C
e -3 el e?
0
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k
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rl
,-,=
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P
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c
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k
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d
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3
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0 0 0 0 0
9 0 \o 0
I I I I I
0 Q 0 0 0
N N N N
c 0
a 0
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Fp
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+
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+
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cp)
zc
2-A
+
N
z
2
cp)O
8 x-
..
0 v3
c3 (3
A- 98

%
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FL
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5
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Weight, Z
Data Temp. Press. Range, x (R)
Fluid System Type Range, 'C atm y (a)
CH3NH2 + Y2O GS NA NA 0-60
C2H5NH2 + H20 GTE 7 & 12.4 NA 1.1-70.3
CH3NH2 + LiSCN PC 27-127 0.064-13.2 41 -8-65.7
Reference
NO Author Year Country Text
_I_
-
257 Uemura 1967 Japan Japanese
73 Hasaba 1960 Japan Japane s e
126 Macriss 1969 U.S.A. English
A.4.5.
Liquid-Phase Densities
CH3NH2 + H20 GE 0-50 NA
10-40
257 Uemura 19 67 Japan
Japanese
3; CH3NH2 + H20 GTS 0-50 NA 5-35
P
0
P CH3NH2 + LiSCN TE 31-132 NA 41.8-65 7
257 IJemura 1967 Japan
126 Macriss 1970 U.S.A.
Japanese
English
CH3NH + H 0: TGS 30-1 80 NA
LiRr ?2:3)?W)
0-100
177 Radermacher 1981 Germany
English
CH3NH + H 0: TS 30-180 NA
LiBr ?2: 3 > b
0-100
178 Radermacher 1982 Germany
German
C2H5NH2 + H20 TEP 2-55 NA 8.1-68.4
C2HgNH2 + 1120 TS 0-60 NA 5-70
C2H5NH-2 + H20 TS 2, 7, 40 NA 0-1 00
73 Hasaba 1960 Japan
73 Hasaba 1960 Japan
73 Hasaba 1960 Japan
Japanese
Japanese
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

I_
Table A.4.0.
(Cont.)
A.4.6.
Vapor-Liquid Phase Enthalpies
Weight, X
Data Temp. Press. Range, X (R) - Reference
Fluid System Type Ranqe, O C atm
No.
Year Country Text
- Y (R) - Author -
CR3NN2 + H20 GS -40-180 0.2-10 0-100 257 Uemura 1967 Japan Japanese
C2H5NH2 + 1120 GS -20-160
7-7600 (1) 0-1 00 256 TJenura 1966 Japan Jap ane s e
CH3NH + H 0: GS -30-2 10 0.4-20 (2) 0-100 177 Radermacher 1981 Germany Fnglish
LiBr ?2 : 3)?W)
5;
CH3NH -+ H 0:
LiBr ?2:3)7w)
GS -30-210 0.4-20 (2) 0-100 178 Xadermacher 1982 Germany English
F
0
A.4.7.
Specific Heat
CH3NH2 + H20 GS NA NA 0- 100 257 Uemura 1 9 6 7 Jap an 3 apane se
CH3NH2 -+ H20 10-80 NA 10-90 257 IJemura 1967 Japan Japanese
CH3NH2 + 820 GE 0-50 NA
5-30 257 Uemura 1967 Japan Japanese
CH3NHf HpO: TGS 30-150 NA
LiBr 2 3) W) GE
0-100 177 Radermacher 1981 Germany
English
0-100 178 Radermacher 1982 Germany Ge rmari
X - Liquid Phase X - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) !I - Mole, W - WeiRht
(1) - mmHg (2) - mbar NA - Vot Available

Table A.4.0.
(Cont.)
I__
Data Temp.
Fluid System Type Range, "C
CH3NH + H 0: GS 30-200
LiBr ?2:3)?W)
Weight, %
Press. Range,
X (R)
atm
Y (R)
NA 0-100
Reference
No. Author Year Country Text
I
-
176 Sadermacher 1981 Germany English
NA
8.1-68.4
73 Hasaba 1960 Japan Japanese
10-55
NA
5-70
73 Hasaba 1960 Japan Japanese
C2H5NH2 + H20 GE 25 & 40
NA
8.1-68.4
73 TIasaba 1960 Japan Japanese
A.4.9.
Viscositv
C~HI~NH~ + H20 GTE 0-50
C2H5NH2 + H20 TS 0-so
NA 5-30
0.064-13.2 41.8-65 7
NA 7.966-70.25
NA 5- 70
257 TJemura 1967 Japan Japanese
126 Macriss 1970 U.S.A. English
75 Hasaba 1961 Japan Japanese
75 Hasaba 1961 Japan Japanese
A.4.12.
Thermal Conductivity
CH3NH2 i- H20 TEP 4.8-92
CH3NH2 + H20 GE 5-40
NA 3.1-39
NA 10-35
257 Uemura 1967 Japan Japsnes e
257 Uemura 1967 Japan Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, lJ - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.4.0. (Cont. 1
Welght, %
Data Tenp. Press. Range, x (R) Reference
Fluid System Type Range, "C atm Y (R) .- NO - Author Year - Country Text
CH3NH2 + H20 TGS 5-40 NA
5-35 257 Uemura 1967 Japan Japanese
C2H5NH2 + €120 GTE 5-50 NA 9.074-48.970 251 Uemura 1963 Japan Japanese
C2H5NH2 + I120 GTS 5-60 NA 0-60 251 IJemura 1963 Japan Japanese
A.4.15.
Surface Tension
CH3NH2 + H29 GE 5-50
NA
5-38 257 Uemura 1967 Japan
Japanese
3; CFI3NH2 + A20 TGS 0-40
P
0
* CzHgNH2 + H20 TE 0-60
NA
NA
5-35 257 Uemura .19 67 Japan
8.43-58.86 75 Hasaba 1967 Japan
Japanese
Japanese
CZH5NH2 + K20 TGS 0-60
NA
5-60 75 Nasaba
19 6 1 Japan
Japanese
X - 'Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.5.0.
SULFUR DIOXIDE BINARY AND MULTICOMPONENT ABSORPTION FLUIDS PROPERTIES DATA
A. 5.1. VaDor-Liauid Eauilibrium
Data Temp.
Fluid System Type Range, OC
SO2 + DMETEG TE 25-93
so2 + DMF TE 25-93
Press. Range,
atm
0.042-20.3
0.096-18.7
Weight, %
X (R)
Reference
Y (R) -
NO Author Yeas Country
_I_
Text
5.1-78.3 4 Albright 1963 U.S.A. English
16.1-83.4 4 Albright 1963 U.S.A. English
so2 + DMA TE 25-93
0.021-14.4
7.9-7 1.2
4 Albright 1963 U.S.A. English
so2 + 2- TE 25-93
Octanone
1.14-19.4
2 3.2-74.5 4 Albright 1963 U.S.A.
English
0
wl
so2 + Ethyl TE 25-93
laurate
SO2 + Nitro- TE 25-93
benzene
1.45-19.6
1.32-19.9
16.8-61.3 4 Albsight 1963 U.S.A. English
21.2-73.7 4 Albright 1963 U.S.A. English
SO2 + n-Heptyl TE 25-93
alcohol
2.04-20.1
22.3-73.1
4 Albright 1963 U.S.A. English
A.5.4.
Heat of Mixing
so2 + DMETEG GSC 25-95
NA
0.0-100.0 4 Albright 1963 U.S.A.
Eng li s h
so2 + DMF GSC 25-95
NA
0.0- 100.0
4 Albright 1963 U.S.A.
English
so2 + DMA G SC 25-95 NA
0.0-100.0 4 Albright 1963 U.S.A.
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A.6.0.
REFRIGERANT 22 BINARY AND MULTICOMPONENT ABSORPTION FLUIDS PROPERTIES DATA
A.6.1.
Fluid System
_I
Vapor-Liquid Equilibrium
--
Data
Temp.
Range, "C
--__I
.-
Press. Range,
atm
Weight, %
X (R)
Y (R)
- No. Author
Reference -
- Year Country
Text
R22 + DXETEG
GTEP
20-90
0.08-7.65
0-23.64
2 20
Suzuki
1973
Japan
Japanese
R22 + DMETEG
TGS
-20-200
0.5-25
10-100
47
E hrnk e
1984
Germany
German
R22 + DMETEG
TEP
0-200
0.5-25
10-100
47
Ehmke
1984
Germany
German
R22 + DMETEG
GC
10-150
6.34 & 17.91
10-9 0
159
Oouchi
1985
Japan
Japanese
7
P
1122 + DMETEG
0 R22 + DMETEG
o\
GS
GC
30-100
NA
2-22
0-50
30-50
0-100
159
146
Oouchi
Morel
1985
1983
Japan
France
Japanese
French
R22 + DMETEG
TE
24-135
0.965-20.5
8.4-7 9.9
35
Buclez
1959
U.S.A.
Eng 1 ish
R22 + DMETEG
TE
38-107
0.276-1.38
a. 1-3.9
3
Al brigh t
1962
U.S.A.
English
R22 + DMETEG
GS
28-1 77
0.345-21.5
6.7-63.2
132
Mas trangelo
1959
U.S.A.
English
R22 6 DMETEG
GS
28-86
0-9.31
0.0-roo. 0
216
Sims
1972
U.S.A.
English
R22 + DMETEG
GS
-40- I80
0.63-40 .O
0.0-100.0
116
La t ys hev
1969
U.S.S.R.
Russian
R22 + DMETEG
C TS
24-121
0-31.9
0.0-100.0
124
Mac ri ss
1964
U.S.A.
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A In Vapor Phase
'I! - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - fiunHg (2) - rnbar NA - Not Available

Table A.6.0.
(Cont.)
Fluid System
Data
Type
Weight, %
Temp. Press. Range, x (R)
Range, OC atm Y (R)
No.
I
Author
Reference
Year Country
II
Text
R22 + DMETEG
GE
-110 - -30 NA
10.0-90.0
113
Kriebel
1965
Germany
German
R22 + DMETEG
GE
0- 120 1
0-23.64
220
Suzuki
1973
Japan
Japanese
R22 + DMETEG
GE
20-70 1 .0
10-30
27
Bokelmann
1983
Germany
English
R22 + DMETEG
GS
0-150
1.0
0-100
181
Renz
1978
Germany
German
R22 + DMETrEG
T EP
-20-200
0.5-25
10-100
47
Ehmke
1984
Germany
German
?
P
R22 + DMETrEG
2 R22 + DMETrEG
GS
GS
-20-200
-20-200
0.5-20
0.5-25
0-100
10-100
26
32
Boke lmann
Bokelmann
1.983
1985
Germany
Germany
Eng 1 ish
English
R22 + DMEDEG
TE
0-30
0.069-1.03
5.6-24.9
173
Pod011
1982
U.S.A.
Eng 1 ish
R22 + DMEDEG
GEP
GS
-20-200
0.1-50
14-100
8
And o
1983
Japan
Japanese
R22 + DMEDEG
GS
-20-200
0-30
10-100
8
Ando
1983 Japan
Japanese
R22 + DMEDEG
GEP
GS
-2 0-2 00
0.1-50
14-100
7
And o
1983 Japan
Japanese
R22 + DMEDEG
GS
-20-200
0-30
10-100
7
Ando
1983 Japan
Japanese
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s1 M -
(1) - mmHg (2) - mbar NA -
ppm by weight of A in Vapor Phase
Mole, W - Weight
Not Available

I_
Table A.6.0.
(Cont.1
Fluid System
R22 + DMEDEG
Data
Type
GEP
Temp.
Range, "C
II_
-20-200
Weight, %
Press. Range, X (R) Reference
atm Y (R) No. Author Year Country Text:
-
0.1-50 20-100 9 Ando 1983 Japan Japanese
R22 -k DMEDEG
GS
-20-200
0-30 10-100
9 Ando 1983 Japan Japanese
R22 + METrPG
GS
2 0- 30
0-9.31 0.0-100.0 215 Sims 1972 U.S.A. English
R22 -t IBA
GS
-70-200
0.016-20 0-100 215 Sellerio 1966 Italy German
R22 f IBA
P
NA
NA NA 250 Uemura 1968 Japan Japanese
?
I-
R22 + IBA
R22 f DMF
GS
GTEP
0-1 20
16.15-48.95
0-40,000 (1) 0-100 250 Uemura 1968 Japan Japanese
179-743 (1) 7.25-27.05 250 Uemura 1968 J apan Japanese
R22 f DMF
GS
GP
0-120
0-40,000 (1) 0- 100 250 Uemura 1968 Japan 3 apa ne s e
R22 + DMF
P
NA
NA 1-100 10 Ando
1 98 2 Japan Japanese
R22 + DMF
GS
-50-200
0.1-30 0-100 10 Ando 1982 Japan Japanese
R22 -+ DMP
TE
38-121
1.38-19.9 20.8-67.7 222 Thierne 1961 U.S.A. English
R22 + DMF
TE
38- 104
0.483-2.00 7.8-9.0 3 Albright 1962 U.S.A. English
X - Liquid Phase R - Refrigerant c - ppn by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

~
Table A.6.0.
(Cont.)
Fluid System
Data
Type
Temp.
Range, OC
-
Press. Range,
atm
Weight, %
X (R)
Y (R)
-
~~~
NO
Author
Reference
Year Country
uI_
Text
R22 + DMF
GTE
20-60
755-765 (1) 8.5-17.6
212
Seliverstov
1970 U.S.S.R.
English
R22 + DMF
TE
-20-50
740 (1) 12.9-46.8
130
Makitra
1979 U.S. S.R.
Russian
R22 + DMF
GE
20-70
1 .o 10-30
27
Bokelmann
1983 Germany
English
R22 + DEF
TE
38-104
1.79-17.1 25.8-75.7
22 2
Thieme
1961 U.S.A.
English
R22 + DMA
TE
0-30
0.103-1.10 9.4-34.1
173
Podoll
1982 U.S.A.
English
8
P
R22 + DMA
0 R22 + DMH
\o
TE
TE
20-101 0.621-19.7 25.1-73.4
0-30 0.103-1.03 7.2-23.7
3
173
A1 bright
Podoll
1962 U.S.A.
1982 U.S.A.
English
English
R22 + DMH
GS
0-150 -30-70a 22.9-50.7
18
Bi e rmann
1978 U.S.A.
Eng 1 ish
R22 + TMf
GS
0-1 50 -30-70a 2 5.0-55.0
18
B i e r mann
1978 U.S.A.
English
R22 + Dimethyl
phthalate
TGEP
20-60 754-765 (1) 5.4-1 3.8
202
Seliverstov
1964 U.S.S.R.
Eng 1 ish
R22 + Diethyl
ph t ha1 a t e
TGEP
20-60 754-755 (1) 7.8-1 7.2
202 Seliverstov
1964 U. S. S O R.
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

0
.
a
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W
d
P i-a
H
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m
n
4
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m
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ul
h
n
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c' v 0
0
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I I
c d
. .
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.
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h
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8
0
d
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Fluid System
R22 -t DMSO
R22 + TMS
Weight, X
Data Temp. Press. Range, X (R)
Reference
Type Range, "C atm y (R) -
No. Author Year Country Text
._
TEC 25-80 0.94-27.48 17-100 146 Morel 1983 France French
GS 0-150 NA 50.0-74.0 18 Biermann 1978 U.S.A. English
R22 + Pentanedione
TE 24-121 1.3 1-2 1.5 14.9-76.1 35 Ruclez
1959 U.S.A. English
R22 + Acetophenone
TE 24-107 1 . 86-17.3 14.0-62.1 35 Buclez 1959 U.S.A.
English
R22 + Renzz
aldehyde
v
R22 + Valeric
acid
R22 + Linoleic
acid
~ 2 + 2 (TAN)
TE 24-93 2.34-20.6 16.8-46.1 35 Buclez 1959 U.S.A. English
TE 24-93 2.34-19.0 14.1-62.3 35 Suclez 1959 U.S.A. English
TE 24-107 2.41-7.65 6.0-18.7 35 Buclez 1959 U.S.A. English
TE 24-121 1.72-2 1.0 9.2-53.8 172 Pluche 1959 U.S.A. English
R22 + TAN
GE 24-121
1 . 7-21 e 0 9.2-53.8 2 Albrirght 1960 1J.S.A. Engl i.sh
R22 + TAN
GTE 20-60 755-765 (1) 3.4-6.6 212 Seliverstov 1970 U.S.S.R. Fng 1 ish
X - Liquld Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Vole, W - Weight
(1) - mmg (2) - mbar NA - N or Available

n
U
C
0
U
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0
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Fu:
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4
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d
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V
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o s
A-112

Table A.6.0.
(Cont.)
Weight, X
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, O C atm Y (R) No. Author Year Country Text
R22 + NMP GE 20-70 1 .O 10-30 27 Rokelmann 1983 Germany English
R22 + Dicumyl- TGEP 20-60 754-765 (1) 5.2-1 1.8 202 Seliverstov 1964 U.S.S.R. English
methane
-
-
R22 + Oleic TGEP 20-60 754-765 (1) 7.7-12.6
acid
202 Seliverstov 1964 U.S.S.R. English
*
R22 + Methyl TGEP 20-60 754-765 (1) 5.2-1 1.8
benzoate
202 Seliverstov 1964 U.S.S.R. English
A 1222 + Propyl TGEP 2g-60 754-765 (1) 5.5-14.0 202 Seliverstov 1464 U.S.S.R. English
P
benzoate
R22 + Butyl TGEP 20-60 754-765 (1) 6.4-15.3 202 Seliverstov 1964 1J.S.S.R. Eng 1 ish
benzoate
R22 + Benzyl TGEP 20-60 754-765 (1) 5.4-1 3.2 202 Seliverstov 1964 U.S.S.R. English
acetate
R22 + Methyl TGEP 20-60 754-765 (1) 4.0-8.0 202 Seliverstov 1964 U.S.S.R. Eng 1 ish
salicylate
R22 + HMPT GE 20-70 1.0 10-30 27 Bokelmann 1983 Germany English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) W - Mole, W - Weight
(1) - mmHg (2) - mbar Nh - Not Available

Table 4.6.0.
(Cont.)
Weight, %
Data Temp. Press. Range, x (Y) Reference
Fluid System Type Range, OC atm Y (R) -. NO Author Year
I___
Country Text
R22 + ETFE GE 20-70 1 .O 10-30 27 Rokelmann 1983 Germany English
R22 + DBP:DMF GS 20 fi 80 0.5-15.0 10-50 213 Seliverstov 1970 U.S.S.R. Russian
R22 + DBP:DMF TE 20-60 NA 2.8-13.5 221 Seliverstov 1970 U.S.S.R. Russian
R22 + DBP:DMF TE 20-80 1.8-16.3 12.9-47.1 211 Seliverstov 1971 U.S.S.R. Russian
R22 -k DMETEG: TE 38-121 2.13-36.1 14.4-63.5 81 Yesselberth 1965 U.S.A. English
3;
Benzyl alcohol
(1:1)(M)
P
P
C- A.6.3. Corrosion
Weight, %
Data Temp. Corrosion x (R) Ref e rence
Fluid System Type Range, OC Inhibitor, wt % Y (R) No. Author Year Country Text
- _1___1_
--
R22 + DMETEG TE 121 NA 50.0 (Volume) 49 Eiseman 1959 U.S.A. English
R22 -+ DMETEG TE 180 WP - 0.5 WA 159 Oouchi 1985 Japan Japanese
E? - 0.5
BO - 0.5
EPC - 0.5
_AGE - 0.5
-
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - nbar NA - Not Available

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A-11.6

Table A.6.0.
(Cont.1
Weight, %
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, O C atm Y (R) NO, Author Year Country Text
R22 + DMF C NA NA NA 226 Tyagi 1976 Japan English
R22 + DMA C NA NA NA 226 Tyagi 1976 Japan English
R22 + DEF C NA NA NA 226 Tyagi 1976 Japan English
-
--
R22 + DBS GTC 22-82 NA 10-90 210 Seliverstov 1968 U.S.S.R.
English
R22 + DBS TE 22-82 NA 0-100 210 Seliverstov 1968 U.S.S.R. Eng 1 ish
?
+
P
4
R22 + DBS GS 22-82 NA 0-100 210 Seliverstov ,1968 U.S.S.R. English
R22 + DDP TC
NA
NA
NA 212 Seliverstov 1970 U.S.S.R. English
R22 + DCP TC NA
NA
NA 212 Seliverstov 1970 U.S.S.R. English
R22 + DOP TC NA NA NA 212 Seliverstov 1970 U. S. S.R. English
R22 + DOS TC NA HA NA 212 Seliverstov 1970 U.S.S.R. English
R22 + TAN TC NA NA NA 212 Seliverstov 1970 U.S.S.R. Eng 11 sh
A.6.5.
Liquid-Phase Densities
R22 + DMETEG TGE 20-90 NA 0-23.64 220 Suzuki 1973 Japan Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

0.5-25
I_
Author
Table A.5.0.
(Cont.1
Data Temp. Press. Range,
-
Fluid System Type Range, “C arm
R22 + DElETEG TGS -70-80 NA
Weight, %
x (R)
y (R)
0.0-100 .o
No.
113
Kriebel
Re f e rence -
- Year Country Text
1965 Germany German
R22 + DMETrEG GS 20-200 0-25
0-100
47
Ehmke
1984
Germany
German
R22 + DMETrEG TEP 20-90 0-25
0-100
47
Ehmke
1984
Germany
German
R22 f IBA G TE 10-80 NA
0-22.55
250
Uemura
1968
Japan
Japanese
R22 + IBA TS 10-80 NA
0-25
2 50
Uemura
1968
Japan
Japanese
?
P
R22 + DMF GTE 5-50 NA
m i--’ R22 + DMF GTS 5-50 “A
0-29.4
0-30
260
260
Uemura
Uemura
1967
1967
Japan
Japan
Japanese
Japanese
A.6.6. Vapor-Liquid-Phase ‘Enthalpies
R22 + DMETEG GS 9-200 0.5-20
0- 100
114 Latyshev
1968 U.S.S.R.
Russian
R22 + DMETEG GS -90-70 0.1-20
0- 100
113 Rriebel
1965 Germany
German
R22 + DNETEG TES 24-121 a. 38-47.3
0.0-100.0
124 Macriss
1964 U.S.A.
English
R22 -+ DMETEG GS 0-200 0.5-20
0-100
117 Latyshev
1969 U.S.S.R.
Xus s tan
R22 + DMETrEG GS 0-200 ~
0- 100
31 Bokelmann
I985 Germany
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mHg (2) - mbar NA - Not Available

Table A.6.0.
(Cant.)
Fluid System
Weight, %
Data Temp. Press. Range, x (R>
Type Range, *C atm
Y (R) NO e
I_ Author _L
Reference -
Year Country
Text
R22 + DMEDEG
GP
-40-180
0.1-50
0-100
8
Ando
1983 Japan
Japanese
R22 + DMEDEG
GP
-20-180
0.1-50
0-100
7
Ando
1983 Japan
Japanese
R22 + DMEDEG
GP
-20-200
0.1-50
0-1 00
9
Ando
1983 Japan
J ap ane s e
R22 + DMEDEG
P
NA
NA
NA
135
Mat s hush i t a
1985 Japan
English
R22 + IBA
GS
-1 5- 100
0.2-30
0-100
2 50
Uemura
1968 Japan
Japanese
4
P
P
u3
R22 + DBP
R22 + DBP
GS
GTS
0-200
20-80
0.5-20
2-14
0-100
0-50
117
207
Latyshev .
Seliverstov
1969 U.S.S.R.
1966 U.S.S.R.
Russian
Russian
R22 + DMMP
GP
0-150
0-30
0-100
268
Yaron
1985 Israel
English
R22 + DBS
GS
20-80
1-13
0-50
205
Seliverstov
1968 U.S.S.R.
Russian
R22 + DMF
GS
-1 5-100
0.5-25
0-100
250
Uemura
1968 Japan
Japanese
R22 + DMF
P
NA
NA
NA
135
Matshushi ta
1985 Japan
English
8.6.7. Specific Heat
R22 + DMETEG
GSE
20-180 ~
WA
23.39
159 Oouchi 1985 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - I.snHg (2) - mbar NA - Not Available
A in Vapor Phase

OZT-v
E
h,
+
U
;z
m
U
M
0
z z n
P
P
0
LJl
Q
I
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0
0
?
CT
0
4
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TI
(u
3
rn
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Table A.6.0.
(Cont.)
Fluid System
R22 + DMH
Data
Type
TE
Weight, %
Temp. Press. Range, X (R)
Range, O C atm Y (R)
0-25 NA 10.0-20.0
- No.
Author
173 Podoll
Reference
Year Country
II_
1982 U.S.A.
Text
English
R22 + DBP
GE
0-50 NA NA
115 Latyshev
1969 U. S.S.R.
Russian
A. 6.8. Stability
R22 + DMEDEG
GE
100-240
NA
NA
8 Ando
1983 Japan
Japanese
R22 + DMETEG
GE
100-240
NA
NA
8 Ando
1983 Japan
Japanese
3;
P
R22 + DMETEG TE
tQ w R22 + DMETEG TE
250-350
NA
NA
NA
5.0 (Volume)
NA
49 Eiseman
28 Bokelmann
1959 U.S.A.
1983 Germany
English
English
R22 + DMF
GE
100-240
NA
NA
8 Ando
198 3 Japan
Japanese
R22 + DMA
GE
100-240
NA
NA
8 Ando
1983 Japan
Japanese
A.6.9.
Viscosity
R22 + DMETEG
TGEP
20-90
NA
0-23.64
220 Suzuki
1 9 7 3 Japan
Japanese
R22 + DMETEG
CS
20-90
NA
0-80
60 Fukuda
1983 Japan
Japanese
R22 + DMETrEG
TEP
20-50
NA
0-50
47 Ehmke
1984 Germany
German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(2) - mbar NA - Not Available
(1) - mHg

Table A.6.0.
(Cont.)
Weight, %
Data Temp. Press. Range, x (R) Reference
Fluid System - Type Range, "C atm Y (R) No. Author Year Country Text
1__1
R22 +
DMETrEG GS 20-90 NA 0-50
-
47 Ehmke
1984 Germany German
1222 i- IBA GTE 10-70 NA 0-22.65 250 Uemura 1968 Japan Japanesl
R22 + IBA TS 10-70 NA 0-25 250 Uenura 1963 Japan Japanesl
?
P
N
R22 + DMF GTE 5-50 NA 0-33 260 Uemura 1967 Japan J a p a ne s 1
R22 -1- DMF GTS 5-50 NA 0-30 260 Uenura 1967 Japan Jap ane SI
A.6.11.
Heat Transfer Rate
t\) R22 + DMETEG GE 6-100 NA NA 160 Oouchi 1983 Japan Japanesl
A. 5.13. Ref ractive Index
X22 i. DMETEG TGE 25-60 NA 0-23.64 220 Suzuki 1973 Japan Japanest
R22 + IBA TGE 20 NA 0-31.25 250 IJemura 1968 Japan Japanesc
R22 f DMF TGE 20 N.4 0-38.45 260 Uemura
A.6.14.
--
Entropy
1967 Japan Japanest
822 f DBS TE 22-32 NA 10-90 210 Seliverstov 1968 U.S.S.R. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(§) :4 - Mole, W - Weight
(1) - mag (2) - nbar NA - Not Available

Table A.6.0.
(COnt.1
Weight, %
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, 'C atm Y (R) NO Author Year Co_untJy Text
R22 + DBS GS 42.5-82 NA 0- 100 210 Seliverstov 1968 U.S.S.R. English
-
-
A.6.15.
Surface Tension
R22 + DMF GTE 5-50 NA 0-31.9 260 Uemura 1967 Japan Ja pane s e
R22 + DMF GT S 5-50 NA 0-30 260 Uemura 1967 Japan Japanese
R22 + IBA GTE 30 NA 0-15.9 250 Uenura 1968 Japan Japanese
w
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mdig (2) - mbar NA - Not Available

v)
W
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(I)
rd
c
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k
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a
P
rl
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r
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l%
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in
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A-124

Table A.7.0.
(Cont.)
Fluid System
Data
Type
Weight, X
Temp. Press. Range, X (R)
Range, OC atm Y (R)
Ref e rence
No. Author Year Country
-
Text
R21 + DMF
P
NA
NA
NA
242 Uemura 1973 Japan
Japanese
R21 + DMF
PC
NA
NA
NA
12 Badarinara- 1982 England
yana
English
R21 + DEF
TE
38-121
0.896-7.03
28.1-74 . 1
222 Thieme 1961 U.S.A.
English
R21 + DFlA
TE
0-30
0.011-0.221
12.5-38.8
173 Podoll 1982 U.S.A.
English
?
P
t4
in
R21 + DMH
R21 + DMH
R21 + NMP
TE
GS
GS
0-30
0-150
0-150
0.0067-0.221
0.165-20.8
NA
6.6-30.1
23 -0-55.O
25 .O-5 1 .O
173 Podoll 1982 U.S.A.
18 Riemann 1978 1J.S.A.
18 Riermann 1978 U.S.A.
English
English
English
R21 + Diethyloxalate
TE
24-12 1
0.276-7.24
22.0-68.5
172 Pluche 1959 U.S.A.
English
R21 + Diethylma
1 o na t e
TE
24-121
0.414-7.03
30.0-66.3
172 Pluche 1959 U.S.A.
English
R21 + Diethyladipate
TE
24-121
0.276-7.10
23.2-60.7
172 Pluche 1959 U.S.A.
English
R21 + Diethyladipate
GE
24-121
0.27-7.0
23.0-6 1.0
2 Albright 1960 U.S.A.
English
X - Liquid Phase R - Refrigerant c -
Y - Vapor Phase A - Absorbent(s) M -
(1) - mmHg (2) - mbar NA -
ppm by weight of
Mole, W - Veiqht
Not Available
A . in Vapor Phase

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.
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P
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5
.
4 4
.
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4 4.
m v?
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3
4 d
In
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LT
CCI
k
0 a
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3
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u
F:
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d
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b
I
.
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CCI 4 0 P-l I-.
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I
I I I I
0 m pl m ex?
oc I-. m m C
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06 I
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b
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0
.
m
m
I
m
9
in.
0
-5
N
h
I
\Q
h
hl
0
.
m
e
I-.
I
9
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7-
8
In
I-.
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4
0
.
m
rn
m
hl
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0
03
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6
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0
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9
OI
02
c
A-126

Table A. 7.0. (Cont. )
Fluid System
Data
Type
Temp.
Range, OC
Press. Range,
atm
Reference
-
No. Author Year Country Text
R21 + Acetophenone
TE
24-121 0.276-7.58
18.5-7 1.7 35 Buclez 1959 U.S.A. English
R21 + Benzaldehyde
R21 + Ethyllaurate
TE
TE
24-121 0.276-7.79 17.7-75.1 35 Buclez 1959 U.S.A. English
38-107 0.290-1.60 11.2-24.0 3 Albright 1962 U.S.A. English
R21 + Diethyloxalate
TE
?
P
p3
., R21 + Diethyl- TE
adipate
38-107 0.234-1.48 12.8-13.4 3 Albright 1962 U.S.A. Eng 1 i s h
38-107 0.248-1.55 13.0-13.8 3 Albright 1962 U.S.A. Eng 1i s h
R21 + Nitrobenzene
GE
52 1.03-3.10 17.3-77.0 222 Thieme 1961 U.S.A. English
R21 + Aniline GE 52 1.24-3.10
21.6-81.6
222 Thieme 1961 U.S.A. Eng 1 ish
R21 + Dimethyl
aniline
GE
52 1.24-3.45
17.5-77.3
222 Thieme 1961 U.S.A. English
R21 + M-Chloro
aniline
GE
52 2.07-3.45 16.8-76.3 222 Thieme 1961 U.S.A. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHq (2) - mbar NA - Not Available

Y
V
c
QJ
c
v3
D
c c .c c
m
rl
M
d
. 4 Q
LT
.
='
m m m
*d *d -d
d r-l r-i
M b@ bo
I*!
c c c c
w w zr'r
. .
cn cn
.
G 5
. cn
.
4 c
cn
5 =,
4
hl
I-
m
I-
c\1 c\1
A
u c
0
V
v
r?
0
c\1
-1 hl
N N
N N
\o 4
4 W
k k
a, a,
4-1 rcI
a, a,
0 0
c 6
r-i &
PI 73
Y Y
N N
m
N
t-. I-
l-4 N
c
r
e
z
N
In
m
I
00
cp:
rl
cn
r--
r.
0
rl
I
90
l-7
C
c
I l l
W w I' C3
w
c3
w
b
01
P i
h
u
U
0
-44
+- v ..
I l l
n
x*;
A-128

Table A.7.0.
(Conto)
A.7.4.
Heat of Mixing
Weight, %
Data Temp. Press. Range, X (R)
Fluid System Type Range, O C atm Y (R)
R21 + DMETEG GE 3 NA 4.9-89.8
-
Reference
No. Author Year Country Text
L__
274 Zellhoeffer 1938 U.S.A. English
R21 + DMETEC C NA NA NA
226 Tyagi 19 7 6 Japan
English
R21 + DMETrEG C NA NA NA
R21 + DMEDEG TEC 25 NA 10.7-29.0
226 Tyagi 1976 Japan English
173 Podoll 1982 U.S.A. Eng 1 ish
?
P
iD
R21 + DMF GS 10
N R21 + DMF P NA
WA
NA
0- 100
NA
242 Uemura 1973 Japan Japanese
12 Badarinara- 1982 England English
yana
R21 + DMH TEC 25 NA 12.8-33.9
173 Podoll 1982 1J.S.A. Eng 1 ish
R21 + DMA TE 25 NA 10.1-19.0
173 Podoll 1982 U.S.A.
English
R21 + ETL C NA NA NA
R21 + DE0 C NA NA NA
226 Tyagi 1976 Japan Eng 1 ish
226 Tyagi 1976 Japan English
R21 + DEA C NA NA NA
226 Tyagi 19 7 6 Japan
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

Table A. 7.0. (Cont. 1
Weight, %
Data Temp. Press. Range, X (R)
Reference -
Fluid System - Type Range, OC atm Y (R) No. Author Year Country Text
R21 + DEF C NA NA NA 226 Tyagi 1975 Japan Eng 1 ish
__
-
-
A.7.5.
Liquid-Phase Densities
R21 + DMF GTE 5-80 NA 0-81.7 250 Uenura 1967 Japan Japanese
R21 + DMF GTS 5-80 NA 0-80 260 Tjemura 1967 Japan Japanese
A.7.6. Vamr-Liauid-Phase Enthaloies
?
P
R21 f DMETEG P NA NA NA 267 Yaron
,1985 Israel English
R21 -k DMETEG GP 0-150 1-26 0-1 00 267 Yaron 1985 Israel English
R21 -+ DMF GP -1 0- 120 0.01-12
0-80 12 Badarinara- 1982 England English
yana
A. 7.7 Specific Heat
R29 + DMF P NA
NA
NA 242 Uemura 197 3 Japan
Japanese
R21 + DMEDEG TE 0-25
NA
10.0-50.0 173 Podoll 1982 U.S.A.
English
R21 + DMA TE 0-25
N A
10.0-50.0 173 Podoll 1982 U.S.A.
English
X - Liquid 'Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
P - Vapor Phase A - Absorbent(s) M - Mole, 1.: - Weight
(1) - mHg (2) - mbar NA - N ot Available

Table A.7.0.
(Cont.)
Weight, %
Data Temp. Press. Range, x (R) Reference
Fluid System Type Range, OC atm y (R) No. Author - Year Country Text
LI
R21 + DMH TE 0-25 NA 10.0-50.0 173 Podoll
1982 U.S.A. English
A.7.8.
Stability
R21 + DMETEG TE , 250 NA 50.0 (Volume) 49 Eiseman 1959 U.S.A. English
A.7.9.
Viscosity
R21 + DMF GTE 5-50
NA
0-7 9 260 Uemura 19 6 7 Japan
Ja pane s e
R21 + DMF GTS 5-50
?
r
w A.7.13. Refractive Index
NA
0-80 260 Uemura . 1967 Japan
Japanese
R21 + DMF GTE 20
NA 0-74.61 260 Uemura 1967 Japan Japanese
A.7.15.
Surface Tension
NA
0-72.7 260 Uemura 1967 Japan
Japanese
R21 + DMF GTS 5-50
NA
0-70 260 Uemura 1967 Japan
Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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Table A.8.0.
(Cont.)
A.8.7.
Specific Heat
Data Temp. Press. Range,
Fluid System
-
Type Range, "C atm
R152 + DMF TEP 5-40 NA
Weight, %
X (R)
y (R)
-
Reference
No. Author Year Country Text
-
0- 1 3.45 221 Tange 19 7 4 Japan Japanese
R152 + DMF GS 0-50 NA
0-20 231 Uemura
1973 Japan Japanese
R152 + DMF P NA NA
NA
231 Uemura 1 9 7 3 Japan Japanese
A.8.9.
Viscosity
R152 + DMF GE 10-60 NA
? TS
P
W
W
R152 -t DMF GEC NA 10-2000 (1)
R152 + DMF GS 10-60 NA
0-20 221 Tange 1974 Japan Japanese
5-20 221 Tange 1974 Japan Japanese
0-20 231 Uemura 19 7 3 Japan Japanese
A.8.13.
Refractive Index
R152 + DMF GTE 20
NA
0-25
221 Tange
1974 Japan Japanese
R152 + DMF GE 20
NA
0-3 5
221 Tange
1974 Japan Japanese
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

-,
.
LJ
0
a?
-d
A-134

Table A.9.0.
REFRIGERANT 12 BINARY AND MULTICOMPONENT ABSORPTION FLUIr)S PROPERTIES DATA
A.9.1.
Vapor-Liquid Equilibrium
Data Temp.
Fluid System Type Range, 'C
R12 + DMETEG TE 38-121
R12 + DMA TE 38-121
R12 + DMF TFI -20-50
Press. Range,
3.52-41.6
4.90-36.8
740 (1)
Weight, %
X (R)
Re f e re n c e
Y (Q) NO Author Year Country Text
-
11.1-78.0 81 Hesselberth 1965 U.S.A. English
23.1-84.5 81 Hesselberth 1965 U.S.A. Eng 1 i s h
1.8-16.4 130 Makitra 1979 U.S.S.R. English
R12 + Dicumyl GTEP 20-60
methane
754-765 (1)
4.2-8. a 202 Selivers tov 1964 U. S. S. R.
English
7 R12 + Oleic GTEP 20-60
P
w
VI
acid
R12 + Methyl GTEP 20-60
benzoate
R12 + Propyl GTEP 20-60
benzoate
R12 + Butyl GTEP 20-60
benzoate
R12 + Dimethyl GTEP 20-60
phthalate
754-765 (1)
754-765 (1)
754-765 (1)
754-765 (1)
754-765 (1)
2.4-10.9 202 Seliverstov 1964 U.S. S. R. English
2.05-5.4 202 Seliverstov 1964 U.S.S.R. English
2.7-9.0 202 Seliverstov 1964 U. S. S. R. English
2.64-9.4 202 Seliverstov 1964 U.S.S.R. English
1.28-4.2 202 Seliverstov 1964 U.S.S.R. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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Ti
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A-136

Table A.9.0.
(Cont.)
Weight, Z
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, "C atm Y (R) No. Author Year Country Text
R12 + R22: TE 38-121 4.27-40.0 1.7-54.5 81 Hesselberth 1965 U.S.A. English
DMETEG:Benzyl 18.0-86.6
alcohol (1: 1) (M)
9.4. Heat of Mixing
R12 + DMF TE -20-50 740 (1) 1.8-16.4 130 Makitra 1979 U.S.S.R. qngl i s h
-
I
X - TAquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
( I) - mmHg (2) - mbar NA - Not Available

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A-138

~
Table A. 10.0.
(Cant.)
Weight, %
Data Temp. Press. Range, X (R) Reference
Fluid System Type atm Y (R) No. Author Year Country Text
R133a + DMF TE 30-70 0.8
17.0-58.9
D_
28 Bokelmann
-
1983
Germany
English
R133a + DEF TE 20-70 0.8
22.3-62.4
27 Bokelmann
1983
Ge many
English
R133a + DEF TE 20-70 0.8
22.3-62.4
28 Bobelmann
1983
Germany
Eng 1 ish
R133a + HMPT TE 30-80 0.8
23.7-43.4
27 Bokelmann
1983
Germany
English
R133a + HMPT TE 20-80 0.8
23.7-51.3
28 Bokelmann
1983
Germany
English
?
P
a
u
R133a + TBP TE 30-70 0.8
R133a + TBP
TE 30-70 0.8
16.5-38.0
16.5-38.0
27 Bokelmann
28 Bokelmann
1983
1983
Germany
Germany
English
English
A.10.4.
Heat of Mixing
R133a + NMP GS NA NA
0-100
191 Rolland
1981
France
French
A. 10.5. Liquid-Phase Densities
R133a + NMP GS 0-1 60 NA
0-100
191 Rolland
1981
France
French
R133a + ETFE TEP -60-250 NA
0.0-60.0
5 Allen
1979
U.S.A.
English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - nbar HA - Not Available

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A-140

Table A. 10.0. (Cont. )
A. 10.15. Surface Tension
Weight, %
Data Temp. Press. Range, X (R)
Reference
Fluid System Type Range, atm Y (R) No. Author Year Country Text
OC
R133a + NMP GS 0-160 NA 0-50 191 Rolland 1981 France French
A. 10.16. Toxicity
R133a + ETFE TE NA NA 0.0, 100.0 150 T4urphy 1982 U.S.A. English
A. 10.17. Flamnability
-
5;
P
CI
i-
R133a + ETFE TE 10.3-24.1
NA 0.0-100.0 150 Murphy 1.982 U.S.A. English
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(2) - mbar NA - Not Available
(1) - mmHg

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A-142

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8-144

Table A.12.0.
FLUORO-ALCOHOL BINARY AND MULT'ICOMPONENT ABSORPTION FLUIDS PROPERTIES DATA
A.12.1.
Vapor-Liquid Equilibrium
Data Temp.
Fluid System Type Range, O C
TFE + DMETEG TGE 73-1 91
TFE + DMETEG GS -10-200
Press. Range,
atm
Weight, %
X (R)
Y (R)
725 (1) 0-100
74-100
0.01-1.5 0-100
74-100
Reference
No. Author Year Country Text
_.
-
201 Seher 1983 Germany Ge rman
201 Seher 1983 Germany German
TFE + DMETEG GS -10-210
0.008-2 0-100
200 Seher
1985 Germany
Ge r ma n
TFE + DMETEG GS 15-225
0.01-1 0-100
200 Seher
,1985 Germany
German
TFE -I- DMETEG GE 40- 190
960 & 200 (2) 0-1 00
200 Seher
1985 Germany
Ge rman
TFE + DMETEG T3 20-80
0.02-0.38 2.9-57.4
27 Bokelmann
1983 Germany
English
TFE f DMETEG GS 0
65-1000 (2) 40-90
153 Nowaczyk
1885 Germany
English
TFE + DMETrEG TE 20-80
0.02 0.7-29.9
27 Bokelmann
1983 Germany
English
TFE + XMP TE 20-80
0.02-0.38 14.0-70.0
27 Bokelmann
1983 Germany
English
TFE + NMP TEP -2 0 -20 0
1-915 (2) 0-100
29 Bokelmann
1984 Germany
German
TFE + NMP GTS -20-200
1-1000 (2) 0-100
29 Rokelmann
1984 Germany
German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, kT - Weight
(1) - mdg (2) - mbar NA - Not Available

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U
F‘
Q
W
W
0
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4
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A-146

Table A.12.0.
(Cont.)
Fluid System
Data
Temp.
Range, OC
Press. Range,
atm
Weight, %
X (R)
Reference
Y (R) No. Author Year Country Text
10 UII
TFE + DMPU GS 0
65-1000 (2)
40-90 153 Nowaczyk 1986 Germany English
TEE -k DMPU GS -20-200 1-1000 (2) 20-100 153 Nowaczyk 1986 Germany English
TP3 + DMEU GS 0
65-1000 (2) 43-90 153 Nowaczyk 1986 Germany English
TFE f NMC GS 0 65-1000 (2) 40-90 153 Nowaczyk 1986 Germany Engl ish
HFIP f QUN GTE 100-200 1.6029-1.6175 24.3-71.3 55 Girsberger 1951 Switzerland German
RFIP + QUE GT E 110-190
3;
i--'
f HPIP + DMPU GS 10
I. 0940-1.0998 21.6-62.3 65 Girsberger . 1951 Switzerland German
250-1500 (2)
20-80 153 Nowaczyk 1985 Germany English
RPIP f DMEU GS 10 250-1500 (2) 20-80 153 Nowaczyk 1986 Germany English
MFIP + NMC CS 10 250-1500 (2) 20-80 153 Nowaczyk 6985 Germany English
HFIP + NFM GS 10
250-1500 (23 20-80 153 Nowaczyk 1986 Germany English
BFIP -t DMETEG GS 10 250-1500 (2) 20-80 153 Nowaczyk 1986 Germany English
HFIP f SL GS 10
250-1500 (2) 20-80 153 Nowaczyk 1986 Germany English
HFIP + PC GS 10 250-1500 (2) 20-80 153 Nowaczyk 1986 Germany English
X - Liquid Phase R - Refrigerant c - Dpm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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A-148
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Table A. 12.0. (Cont. )
A.12.4.
Heat of Mixing
Weight, %
Data Temp. Press. Ranqe, X (R) Reference
Fluid System Type Range, O C atm y (R) No. Author Year Country Text
--
TFE + DMETEG GE 20 NA 0-100 200 Seher 1985 Germany German
TFE + DMPU GS 30 NA 0-100 153 Nowaczyk 1986 Germany English
TFE + NMP ES 30 NA 0-100 153 Nowaczyk 1986 Germany English
HFIP + DMETEG GS 30 NA 0-100 153 Nowaczyk 1986 Germany English
KFIP + NFM GS 30 NA 0-100 153 Nowaezyk 1?S6 Germany Eng 1 ish
?
r
c A. 12.5. Liquid-Phase Densities
Lo
TFE + DMETEG GS 20-70 NA 0-100 208 Seher 1485 Germany German
TFE -+ DXETEG GS 0-200 NA 0-100 200 Seher 1985 Germany German
-
TPE i- NMP TEP 20-90
GS
NA 0-100 29 Bokelmann 1984 Germany German
TPE + TEG GS 20-70 NA 0-1 08 200 Seher 1955 Germany Ge rman
HFIP + QUN TE 20 NA 20-75 65 Girsberger 1951 Switzerland German
X - Liquid Phase R - Refrigerant c - ppiii by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, t,r - Veight
(1) - mmHg (2) - mbar NA - Not Available

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A-152

Table A.14.0.
REFRIGERANTS 31, 30, 11, 13, 134, 142 AND 143A BINARY AND MULTICOMPONENT
ABSORPTION FLUIDS PROPERTIES DATA
A.14.1.
Vapor-Liquid Equilibrium
Weight, %
Data Temp. Press. Range, X (R)
Fluid System Type Range, OC atm y (a)
R11 + DMETEG TE 25-121 0.345-6.07 19.8-62.8
R11 + DMETEG GE 25-1 2 I 0.34-6.1 20.0-63.0
Ref e r enc e
No. Author Year Country Text -
35 Buclez 1959 U.S.A. English
2 Albright 1960 U.S.A. English
R11 + 2- TE 25-121 0.414-5.86 27.9-71.5
oc t anone
35 Buclez
1959 U.S.A.
English
R11 + Linoleic TE 25-121 0.414-5.52 15.8-54.5
? acid
F
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i*, R11 + Diethyl TE 25-107 0.621-7.45 38.9-71.6
malonate
R11 + n-heptyl TE 38-93 0.965-5.93 44.5-77.4
alcohol
R13 + DMF TE -20-50 740 (1) 0.3-1.6
35 Suclez 1959 U.S.A. English
172 Pluche 1959 U.S.A. Eng 1 ish
172 Pluche 1959 U.S.A. English
130 Makitra 1979 U. S. S.R. English
R31 + DMETEG TE 35-177 1.52-8.96 4.7-39.8
R30 + DMETEG GS 27-177 0.138-1.31 4.1-14.1
132 Mastrangelo 1959 U.S.A.
52 Ellington 1957 U.S.A.
English
Eng 1 ish
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Ijeight
(1) - m dg (2) - mbar NA - Not Available

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A-154

Table A. 14.0.
(Cont.
Weight, %
Data Temp. Press. Range, x (R)
Reference
Fluid System Type Range, O C atm y (R) No. Author Year Country Text
R142 + Benzl TGEP 20-60 754-765 (1) 6.0-15.6 202 Seliverstov 1964 U.S.S.R. English
acetate
R142 + Dibutyl TGEP 20-60 754-765 (1) 13.8-30.5 202 Seliverstov 1964 U. S.S.R. English
sebacate
R142 + Methyl TGEP 20-60 754-765 (1) 6.0-13.6 202 Selivers tov 1964 U. S. S.R. English
salicylate
-
A.14.4.
Heat of Mixing
4 R13 + DMF TE -20-50
P
Ln
Ln
A. 14.8. Stability
R134 + NMP TE 180
R143a + NMP TE 180
740 (1)
NA
NA
0.3-1.6 130 Makitra 1979 U. S. S.R. English
NA 17 Bertocchio 1985 France French
NA 17 Bertocchio 1985 France F r e iic h
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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A-156

Table A.16.O.
OTHER BINARY AND MULTICOMPONENT ABSORPTION FLUIDS PROPERTIES DATA
A.16.1.
Vapor-Liquid Equilibrium
Weight, %
Data Temp. Press. Range, X (R) Reference
Fluid System Type Range, "C atm Y (R) No. Author Year Country Text
Hexane + TDK GTE 100-1 90 1.0352-1.0426 3.45-26.1 65 Girsberger 1951 Switzerland German
CH3CN + LiCl TE 18 & 25 NA 99.8 & 99.9 164 Pavlopoulos 1954 Germany German
-
-
C~I~CN + LiBr
TE
18 & 25
NA
91.9 & 92.4
164 Pavlopoulos 1954 Germany
German
CH3CN + LiI
TE
18 & 25
NA
39.4 & 40.5
164
Pavlopoulos
1954
Germany
German
CH~CN + NaF
?
P
-4 CH3CN + NaCI
TE
TE
18 & 25
18 ti 25
NA
NA
99.9 & 99.9
99.9 ti 99.9
164
164
Pavlopoulos
Pavlopoulos
1954
1954
Germany
Germany
German
German
CH~CN + NaBr
TE
18 & 25
NA
99.9
164
Pavlopoulos
1954
Germany
German
CH3CN + NaI
TE
18 & 25
NA
80.0 & 80.6
164
Pavlopoulos
1954
Germany
German
CH~CN + KF
TE
18 & 25
NA
99.9 & 99.9
164
Pavlopoulos
1954
Germany
German
CH3CN 3. KCI
TE
18 & 25
NA
99.9
164
Pavlopoulos
1954
Germany
German
CH~CN + KBr
TE
18 & 25
NA
99.9
164
Pavlopoulos
1954
Ge rrnany
German
CH3CN 3. KI
TE
18 & 25
NA
97.9
164
Pavlopoulos
1954
Germany
German
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s1 M - Mole, W - Weight
(1) - mHg (2) - mbar NA - Not Available

Table A.16.0.
(Cont.)
Fluid System
CK3CN i- RbCl
Data
TY Pe
TE
Temp.
Range, OC
18 & 25
Press. Range,
atm
NA
Weight, %
x (R)
-f (R)
99.9
- No. Author
164 Pavlopoulos
Reference
- Year Country Text
1954 Germany German
CH3CN -+
RbBr
TE
18 & 25
NA
99.9 & 99.9
164
Pavlopoulos
1954
Germany
German
CH3CN -k RbI
TE
18 & 25
NA
98.2 & 98.4
164
Pavlopoulos
1954
Germany
German
CH3CN -+ CSCl
TE
1-3 6 25
EA
99.9
164
Pavlopoulos
1954
Germany
Ge man
CH3CN i- CsBr
TE
18 6 25
NA
99.9 6 99.9
164
PaVloQOulOs
1954
Germany
German
?
I-
&
CMjCN f CST
CBOOH -!- LiCl
TE
TE
18 6 25
ra & 25
NA
NA
99.1 6 99.3
78.7 & 79.4
164
164
Pavlopoulos '1954
Paill 0 ~ 0 OS ~ 1
1954
Germany
Germany
Gerlo-an
German
TE
18 & 25
NA
54.3 6 55.6
164
Pavlo poul os
1954
Ge many
Ge rma~
CHOOH i- ti1
TE
18 6 25
NA
40.7 & 41.8
i 64
Pavlopsulos
1954
Ge many
Ge rman
CBOOH f NaZ1
TE
18 5 25
NA
5.2
164
Pav lo pod o s
1954
Germany
GerE3aX-I
TE
18 6 25
NA
83.8 & 83.8
I64
Pavlopoulos
4954
Germany
German
CHOOH 4- Nal
TE
18 & 25
NA
61.7 ti 62.1
164
Pavlopoulos
1954
Germany
German
CROON 9 KC1
TE
18 SI 25
NA
83.9 SI 84.0
164
Pav l o Q 0 ul 0 s
1954
Germany
German
X - Liquid Phase R - Refrigerant c - P Q ~ by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent(s) M - Mole, W - Weight
41) - mmHg (2) - mbar NA - Not Available

Data Temp.
Fluid System Type Range, "C
-
Pres s . Range,
atm
NO e
-I_
Author
Reference
Year Country Text -
CHOOH + KRr TE 18 & 25
NA
51.5 & 81.7
164 Pavlopoulos 1954 Germany German
CHOOH + KI TE 18 & 25
NA
73.9 & 74.1
164 Pavlopoulos 1954 Germany
German
CHOOJI + RbCl TE 18 & 25
NA
62.5 & 64.1
164 Pavlopoulos 1954 Germany German
CHOOH + RbBr TE ia & 25
NA
56.4 & 67.1
164 Pavlopoulos 1954 Germany German
CIIOOH + RbI TF 1% 64 25
??A
58.0 & 68.5
164 Pavlopoulos 1954 Germany
German
?
P
cn
u3
CHOOH + CsCl TE 18 & 25
CROOR + CsRr TE 18 & 25
CHOOH + CsI TE 18 & 25
NA
NA
NA
43.5 & 48.3
53.5 & 59.2
77.5 6( 78.1
164 Pavlopoulos ,1954 Germany German
154 Pavlopoulos 1954 Germany German
164 Pavlopoulos 1954 Germany Gerrcan
A.16.4.
Heat of Mixing
Benzene + TE 30
Cyclohexane
NA
16.0-81.2
217 Sosnkowska 1965 Poland English
t-Butyl Alcohol GTEP 30 & 50
+ Benzene
NA
28.6-92.6
217 Sosnkowska 1965 Poland EngiiSh
X - Liquid Phase R - Refrigerant c - ppm by weight of A in Vapor Phase
Y - Vapor Phase A - Absorbent($) M - Mole, W - Weight
(1) - mmHg (2) - mbar NA - Not Available

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A-160