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Chair of Sanitary Engineering and Water Recycling<br />

AQUA-Study Award<br />

Dipl.-Ing. Asya Drenkova-Tuhtan, M.Sc., from<br />

Bulgaria graduated from the master program<br />

Water Resources Engineering and Management<br />

(WAREM) and is now a researcher at the Chair of<br />

Sanitary Engineering and Water Recycling. She<br />

has been awarded with the AQUA-Study Award<br />

2011 from the Fo<strong>und</strong>ation AQUA of the Faculty of<br />

Civil- and Environmental Engineering of the University<br />

of Stuttgart.<br />

The AQUA Fo<strong>und</strong>ation annually awards a prize to a student<br />

of the water-related subjects at the Faculty of Civil-<br />

and Environmental Engineering at the University of<br />

Stuttgart. The award recognizes outstanding academic<br />

achievement, meaning excellent diploma, master and<br />

doctoral theses, as well as student commitment. The<br />

AQUA-Study Award 2011 was awarded to Ms. Asya<br />

Drenkova-Tuhtan in recognition of her outstanding<br />

academic achievements and her master thesis „Application<br />

of Zero-Valent Iron Nanoparticles in Wastewater<br />

Treatment“. At a high scientific level and with great<br />

commitment, she has made an innovative contribution<br />

to the municipal wastewater treatment.<br />

With the aim to investigate the applications of zerovalent<br />

nano-iron as a sorbent and a reducing agent<br />

in the municipal wastewater treatment, laboratory<br />

tests have been conducted to determine to what extent<br />

poorly biodegradable pollutants in wastewater can<br />

be converted or eliminated by nZVI (nanoscale zerovalent<br />

iron). For the examined pollutants the conventional<br />

wastewater treatment shows no or nearly no<br />

effect. Furthermore, the suitability of the iron nanoparticles<br />

as an alternative to eliminate phosphate was<br />

investigated. The kinetics and other parameters were<br />

determined until optimal conditions and a phosphate<br />

elimination of> 95% were achieved. Three different<br />

commercial nZVI products were analyzed and compared.<br />

In addition, the potential of nZVI for the elimination<br />

of 9 frequent micropollutants in the domestic<br />

wastewater at different pH values was investigated as<br />

well as, the efficiency of nZVI to bind some selected<br />

heavy metals. The achieved elimination rate was very<br />

high (> 90%), particularly for heavy metals and some<br />

organic micropollutants. Furthermore, the separation<br />

of the nanoparticles by means of sedimentation,<br />

filtration, and magnetic separation was investigated.<br />

The AQUA - Study Award 2010 was awarded to<br />

Karen Mouarkech, from Lebanon and a graduate<br />

of the master program Air Quality Control, Solid<br />

Waste and Waste Water Process Engineering<br />

(WASTE), in recognition of her outstanding academic<br />

achievements and her master thesis „Determination<br />

of suitable substrates originating<br />

from wastewater treatment processes for biological<br />

hydrogen production by dark fermentation<br />

at various process conditions.“<br />

With a high degree of initiative and systematic work,<br />

she has mastered the complex issue that requires both<br />

a broad basic knowledge and a deeper <strong>und</strong>erstanding<br />

of anaerobic treatment processes.<br />

Abstract of the Master Thesis:<br />

Hydrogen fuel is an environmentally friendly gas. The<br />

production of hydrogen from substances derived from<br />

wastewater treatment is therefore a sustainable process.<br />

Therefore, various substrates (primary sludge,<br />

secondary sludge, wastewater from the sugar production,<br />

wastewater from the beer production) were<br />

examined with regard to the possible production of<br />

hydrogen. Experiments with primary and secondary<br />

sludge were done in a 4-liter experimental reactor at a<br />

temperature of 35°C, at different pH values, and different<br />

„Food to Microorganism Ratios“ (F: M). This way<br />

methane was produced. The sludge was pretreated by<br />

heating and acidification which inhibited the methanogenesis<br />

and a minimal amount of hydrogen could<br />

be produced. In general, it was fo<strong>und</strong> that an acidic<br />

medium is required for the highest hydrogen production.<br />

With wastewater from the sugar production the<br />

highest hydrogen production was achieved. Further investigations<br />

will be carried out.<br />

In 2010 and 2011, two students were awarded.<br />

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