Luis Fernando Piedra-Garza - Jacobs University

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4.2.4 Single Crystal X-ray Diffraction 103 4.2.5 Solution Studies (Nuclear Magnetic Resonance) 109 4.3 Conclusions 113 4.4 References 114 Chapter V. 2-D Assemblies of Diethyltin Functionalized Heteropolytungstates 5.1 2-D Assemblies of Diethyltin Functionalized [A-α-XW 9 O 34 ] n- (X = P V , As V ) Keggin Polytungstates 115 5.1.1 Synthetic Procedure 116 5.1.2 FT-Infrared Spectroscopy 117 5.1.3 Thermogravimetry 118 5.1.4 Single Crystal X-ray Diffraction 120 5.1.5 Conclusions 125 5.2 References 126 xiv
Chapter VI. 1-D Assemblies of Diorganotin Functionalized Heteroand Isopolytungstates 6.1 The [{Sn(C 2 H 5 ) 2 } 6 (H 2 O) 6 (B-β-XW 9 O 33 ) 2 ] 6- (X = Sb III , As III ) Lone-Pair Polyoxotungstate Dimer and its 1-D Architecture in the Solid State 127 6.1.1 Synthetic Procedure 128 6.1.2 FT-Infrared Spectroscopy 129 6.1.3 Thermogravimetry 130 6.1.4 Single Crystal X-ray Diffraction 132 6.2 A Lone-Pair Tungstoarsenate [{Sn(C 2 H 5 ) 2 } 3 (H 2 O) 2 (B-β-AsW 9 O 33 )] 3- and its 1-Dimensional Arrangement through Diethyltin Bridges 138 6.2.1 Synthetic Procedure 138 6.2.2 FT-Infrared Spectroscopy 139 6.2.3 Thermogravimetry 140 6.2.4 Single Crystal X-ray Diffraction 141 6.3 The Dimethyltin Functionalized Eicosatungstodiphosphate Polyanion: [{Sn(CH 3 ) 2 (H 2 O)} 2 (P 2 W 20 O 70 K(H 2 O) 2 )] 5- 146 6.3.1 Synthetic Procedure 146 6.3.2 FT-Infrared Spectroscopy 147 6.3.3 Thermogravimetry 148 6.3.4 Single Crystal X-ray Diffraction 149 6.4 The Diethyltin Functionalized Hexatungstate Isopolyanion: [{Sn(C 2 H 3 ) 2 } 2 (W 6 O 22 )] 4- 153 6.4.1 Synthetic Procedure 153 6.4.2 FT-Infrared Spectroscopy 154 6.4.3 Thermogravimetry 155 6.4.4 Single Crystal X-ray Diffraction 156 xv
Page 1 and 2: Hybrid Organic-Inorganic Polyoxotun
Page 3 and 4: Acknowledgments The amount of peopl
Page 5 and 6: Short Abstract The present work sum
Page 7 and 8: The next chapter describes the gene
Page 9 and 10: one equivalent of diethyltindichlor
Page 11 and 12: Index Acknowledgments Short Abstrac
Page 13 and 14: Chapter II. Analytical Techniques u
Page 15: Chapter III. General Introduction o
Page 19 and 20: 7.3.4 Single Crystal X-ray Diffract
Page 21 and 22: List of Figures/Schemes Figure 1.1
Page 23 and 24: Figure 4.5 Combined polyhedral/ball
Page 25 and 26: Figure 6.10 Combined polyhedral/bal
Page 27 and 28: Figure 9.3 Combined polyhedral/ball
Page 29 and 30: Table 6.6 Selected Bond Lengths (Å
Page 31 and 32: Chapter I. Iso- and Heteropolyoxome
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Chapter I. Iso- and Heteropolyoxome
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Luis Fernando Piedra-Garza - Jacobs University

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