Luis Fernando Piedra-Garza - Jacobs University

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Chapter IX. Structures without Organometallic Moieties attached to the POM Framework 9.1 The Chiral Sandwich-Type [Sb 3 III (A-α-PW 9 O 34 ) 2 ] 9- Lone-Pair containing Polyanion 207 9.1.1 Synthetic Procedure 208 9.1.2 FT-Infrared Spectroscopy 209 9.1.3 Thermogravimetry 210 9.1.4 Single Crystal X-ray Diffraction 211 9.2 A Novel [H 3 Se 2 W 22 O 74 (H 2 O) 7 ] 5- Plenary Polyoxodiselenotungstate 215 9.2.1 Synthetic Procedure 216 9.2.2 FT-Infrared Spectroscopy 216 9.2.3 Single Crystal X-ray Diffraction 217 9.3 Conclusions 220 9.4 References 221 Appendix A. Published Articles B. Submitted and Accepted Articles (stand: June 2009) C. Compact Disc with crystallographic information (cif files) of structures 1 to 17 xviii
List of Figures/Schemes Figure 1.1 The Anderson-Evans heptamolybdate anion [Mo 7 O 24 ] 6- 7 Figure 1.2 The Lindqvist hexatungstate anion [W 6 O 19 ] 2- 9 Figure 1.3 The [XM 12 O 42 ] n- Keggin structure in polyhedral representation: four corner shared {M 3 O 13 } triads (depicted in different colours) wrapping the central [XO 4 ] tetrahedron 10 Figure 1.4 The five Baker-Figgis isomers of the Keggin polyanion 13 Figure 1.5 The mono- and trilacunary species derived from the [α-XM 12 O 40 ] n- Keggin heteropolyanion 14 Figure 1.6 The three monolacunary species derived from the [β-XM 12 O 40 ] n- Keggin heteropolyanion 15 Figure 1.7 Trilacunary species derived from the [β-XM 12 O 40 ] n- Keggin heteropolyanion 16 Figure 1.8 [γ-XM 10 O 36 ] m- . The only lacunary specie derived from the [γ-XM 12 O 40 ] n- Keggin heteropolyanion 17 Figure 1.9 The Wells-Dawson [α-X 2 W 18 O 62 ] 6- (X = P V , As V ) heteropolyanion 18 Figure 1.10 Monolacunary species of the Wells-Dawson polyanion (a) [α 1 -X 2 W 17 O 61 ] 10- , (b) [α 2 -X 2 W 17 O 61 ] 10- 19 Figure 1.11 Tri- and Hexalacunary species of the Wells-Dawson polyanion (a) [P 2 W 15 O 56 ] 12- , (b) [H 2 P 2 W 12 O 48 ] 12- 20 xix
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Chapter I. Iso- and Heteropolyoxome
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Luis Fernando Piedra-Garza - Jacobs University

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