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2013-2014 <strong>AP</strong> <strong>CHEM</strong>ISTRY STUDENTS<br />

There is no “required” summer assignment but I will not teach the 1 st unit (Chp 1 - Classification of matter, states<br />

of matter, scientific notation, significant figures) when school starts. If you want a little less work the first few<br />

days of school, complete the attached worksheets before school starts. A test will be given on these topics the 1 st<br />

week of school. This means that if you are solid on these concepts there is nothing to worry about this summer.<br />

If you are a little weak on these concepts you will need to spend some time before school starts reading and<br />

studying. If you want unit 2 to be a little less hectic you can use some of your summer time to start learning the<br />

common cations, anions and polyatomic ions on the last page of this handout. You will need to come by my<br />

classroom (rm 208) by Tuesday, June 4 th , to check out a book and ask any questions you might have.<br />

Have a great summer<br />

Mr. Duncan<br />

keith.duncan@ksd.org


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009, 2010. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

<strong>AP</strong> Common Ions<br />

CATIONS (+ve)<br />

ANIONS (-ve)<br />

Name<br />

Symbol/<br />

Formula<br />

Alternative*<br />

Name<br />

Symbol/<br />

Formula<br />

Alternative*<br />

Aluminum Al 3+ Bromide Br -<br />

Ammonium<br />

+<br />

NH 4 Bromate (I) BrO - (Hypobromite)<br />

Arsenic (III) As 3+ Bromate (III)<br />

-<br />

BrO 2 (Bromite)<br />

Arsenic (V) As 5+ Bromate (V)<br />

-<br />

BrO 3 (Bromate)<br />

Barium Ba 2+ Bromate (VII)<br />

-<br />

BrO 4 (Perbromate)<br />

Bismuth (III) Bi 3+ Carbonate<br />

2-<br />

CO 3<br />

Bismuth (V) Bi 5+ Chlorate (I) ClO - (Hypochlorite)<br />

Cadmium Cd 2+ Chlorate (III)<br />

-<br />

ClO 2 (Chlorite)<br />

Calcium Ca 2+ Chlorate (V)<br />

-<br />

ClO 3 (Chlorate)<br />

Chromium (II) Cr 2+ Chlorate (VII)<br />

-<br />

ClO 4 (Perchlorate)<br />

Chromium (III) Cr 3+ Chloride Cl -<br />

Cobalt (II) Co 2+ Chromate<br />

2-<br />

CrO 4<br />

Cobalt (III) Co 3+ Cyanide CN -<br />

Copper (I) Cu + (Cuprous) Dichromate<br />

2-<br />

Cr 2O 7<br />

Copper (II) Cu 2+ (Cupric) Dihydrogen Phosphate<br />

-<br />

H 2PO 4<br />

Hydrogen H + Ethanoate<br />

-<br />

C 2H 3O 2 (Acetate)<br />

Hydronium H 3O + Fluoride F -<br />

Iron (II) Fe 2+ (Ferrous) Hydride H -<br />

Iron (III) Fe 3+ (Ferric) Hydrogen Carbonate<br />

-<br />

HCO 3 (Bicarbonate)<br />

Lead (II) Pb 2+ (Plumbous) Hydrogen Oxalate<br />

-<br />

HC 2O 4 (Binoxalate)<br />

Lead (IV) Pb 4+ (Plumbic) Hydrogen Phosphate<br />

2-<br />

HPO 4<br />

Lithium Li + Hydrogen Sulfate<br />

-<br />

HSO 4 (Bisulfate)<br />

Magnesium Mg 2+ Hydrogen Sulfide HS - (Bisulfide)<br />

Manganese (II) Mn 2+ Hydrogen Sulfite<br />

-<br />

HSO 3 (Bisulfite)<br />

Manganese (IV) Mn 4+ Hydroxide OH -<br />

Mercury (I)<br />

2+<br />

Hg 2 (Mercurous) Iodate (I) IO - (Hypoiodite)<br />

Mercury (II) Hg 2+ (Mercuric) Iodate (III)<br />

-<br />

IO 2 (Iodite)<br />

Nickel (II) Ni 2+ Iodate (V)<br />

-<br />

IO 3 (Iodate)<br />

Potassium K + Iodate (VII)<br />

-<br />

IO 4 (Periodate)<br />

Silver Ag + Iodide I -<br />

Sodium Na + Manganate (VII)<br />

-<br />

MnO 4 (Permanganate)<br />

Strontium Sr 2+ Nitrate<br />

-<br />

NO 3<br />

Tin (II) Sn 2+ (Stannous) Nitride N 3-<br />

Tin (IV) Sn 4+ (Stannic) Nitrite<br />

-<br />

NO 2<br />

Zinc Zn 2+ Oxalate<br />

2-<br />

C 2O 4 (Ethandioate)<br />

Oxide O 2-<br />

Peroxide<br />

2-<br />

O 2<br />

Phosphate<br />

3-<br />

PO 4<br />

Phosphide P 3-<br />

Phosphite<br />

3-<br />

PO 3<br />

Sulfate<br />

2-<br />

SO 4<br />

Sulfide S 2-<br />

Sulfite<br />

2-<br />

SO 3<br />

Thiosulfate<br />

2-<br />

S 2O 3<br />

Thiocyanate SCN -<br />

* In the case of the cations, the alternative names are generally redundant in modern chemistry, but the anions sometimes use the alternate<br />

names. E.g. the oxyhalogen ions (bromate, chlorate, iodate etc.) are usually referred to by the alternate names, but HSO 3 - is more<br />

commonly called Hydrogen Sulfite. In each case where two names are given, the more common one used in the United States is<br />

underlined.<br />

C:\www.adriandingleschemistrypages.com\apions.doc Page 1 of 2


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009, 2010. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

POLYATOMIC IONS<br />

+2 +1 -1 -2 -3<br />

Hg 2<br />

2+<br />

NH 4<br />

+<br />

BrO -<br />

-<br />

BrO 2<br />

-<br />

BrO 3<br />

-<br />

BrO 4<br />

-<br />

C 2H 3O 2<br />

ClO -<br />

-<br />

ClO 2<br />

-<br />

ClO 3<br />

-<br />

ClO 4<br />

CN -<br />

-<br />

HCO 3<br />

-<br />

HC 2O 4<br />

-<br />

H 2PO 4<br />

HS -<br />

-<br />

HSO 3<br />

-<br />

HSO 4<br />

IO -<br />

2-<br />

CO 3<br />

2-<br />

C 2O 4<br />

2-<br />

CrO 4<br />

2-<br />

Cr 2O 7<br />

2-<br />

HPO 4<br />

2-<br />

SO 3<br />

2-<br />

SO 4<br />

2-<br />

S 2O 3<br />

-<br />

IO 2<br />

-<br />

IO 3<br />

-<br />

IO 4<br />

-<br />

MnO 4<br />

-<br />

NO 2<br />

-<br />

NO 3<br />

OH -<br />

SCN -<br />

PO 3<br />

3-<br />

PO 4<br />

3-<br />

C:\www.adriandingleschemistrypages.com\apions.doc Page 2 of 2


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

<strong>AP</strong> WORKSHEET 1a: Significant Figures<br />

1. Determine the number of significant figures in each of the following. (6)<br />

(a) 0.7680<br />

(b) 1230.00<br />

(c) 1000.01<br />

(d) 120.0<br />

(e) 1.09 x 10 4<br />

(f) 0.0080060<br />

2. Use a calculator to find the results of the following and then round the answer to the correct<br />

number of significant figures. (6)<br />

(a) 34.66 + 333.0<br />

(b) 1.23 + 9.66<br />

(c) 445 - 1.22<br />

(d) 18.2 + 1.998<br />

(e) 10.2 – 1.34<br />

(f) 100 - 23<br />

3. State the significant figure rule that is associated with “captive zeros”. (1)<br />

4. State the significant figure rule that is associated with “leading zeros”. (1)<br />

5. State the significant figure rule that is associated with “trailing zeros”. (1)<br />

6. State the significant figure rule that is associated with addition and subtraction operations. (1)<br />

7. State the significant figure rule that is associated with multiplication and division operations.<br />

(1)<br />

C:\www.adriandingleschemistrypages.com\apwsheetsnew\apwsheet01a.doc Page 1 of 2


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

8. Use a calculator to find the results of the following calculations and then round the answer to<br />

the correct number of significant figures. (6)<br />

(a) 12 x 11.45<br />

(b) (1.23 x 10 3 ) x (6.4 x 10 2 )<br />

(c) 5.233 x 6.324<br />

(d) 34 / 22<br />

(e) (1.8 x 10 5 ) / 14<br />

(f) 100.23 / 5.22<br />

9. Round each of the following to three significant figures. (6)<br />

(a) 167.789<br />

(b) 0.0000456922<br />

(c) 23.00567<br />

(d) 3.4569<br />

(e) 7903.0005<br />

(f) 11.044<br />

10. How many significant figures in each of the following? (6)<br />

(a) 654.001 nm<br />

(b) 6.02 x 10 23 particles<br />

(c) 1.0079 g<br />

(d) 13 neutrons<br />

(e) 11.22201 mg<br />

(f)<br />

0.004504 g<br />

C:\www.adriandingleschemistrypages.com\apwsheetsnew\apwsheet01a.doc Page 2 of 2


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

<strong>AP</strong> WORKSHEET 1b: Unit Conversions<br />

This worksheet utilizes the conversions given at this web site http://www.onlineconversion.com<br />

1. Perform the following conversions. In each case show the full, dimensional analysis. Source<br />

any conversion factors from the web site above. An example is given below. (6)<br />

Question: 3.00 cm to mm.<br />

Answer:<br />

3.00 cm 10 mm <br />

<br />

<br />

<br />

1 cm <br />

= 30 mm<br />

(a) 120 J to MJ<br />

(b) 3 m to cm<br />

(c) 400 miles to km<br />

(d) 25 hectares to acres<br />

(e) 34 inches to ft<br />

(f)<br />

289 s to hrs<br />

2. Perform the following conversions. In each case you do NOT need to show the full,<br />

dimensional analysis. Source any conversion factors from the web site above. (6)<br />

(a) 120000 J to kJ<br />

(b) 13 kg to lbs<br />

(c) 83.2 K to o C<br />

(d) 48 mins to ms<br />

(e) 34 o F to o C<br />

(f)<br />

13.2 kg to lbs<br />

C:\www.adriandingleschemistrypages.com\apwsheetsnew\apwsheet01b.doc Page 1 of 2


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

3. Perform the following sequences of conversions. In each case show the full, dimensional<br />

analysis. Source any conversion factors from the web site above. An example is given below.<br />

(6)<br />

Question: 3.00 cm to m VIA mm.<br />

Answer:<br />

3.00 cm 10 mm <br />

0.001 m <br />

<br />

<br />

= 0.03 m<br />

<br />

1 cm <br />

1 mm <br />

(a) 679 nm to cm VIA m<br />

(b) 23 miles to m VIA km<br />

(c) 567 feet to m VIA yd<br />

(d) 12 L to UK gal VIA mL<br />

(e) 8 MJ to J VIA kJ<br />

(f)<br />

418 s to hrs VIA min<br />

C:\www.adriandingleschemistrypages.com\apwsheetsnew\apwsheet01b.doc Page 2 of 2


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

<strong>AP</strong> WORKSHEET 1s: Matter & Measurement Summary<br />

1. Classify each of the following as either, an element, a compound or a mixture. If you<br />

classify something as a mixture then also state whether it is a homogeneous or a<br />

heterogeneous mixture. (10)<br />

(a) Helium<br />

(b) Nitrogen<br />

(c) Pure water<br />

(d) Pure table salt (sodium chloride)<br />

(e) Flat (un-carbonated) Coca-Cola<br />

(f)<br />

Air<br />

(g) Fruit cake<br />

2. Classify the following as either chemical or physical changes. (3)<br />

(a) Ice melting<br />

(b) Gasoline burning<br />

(c) Evaporation of perfume from an open bottle<br />

3. Mercury is a liquid metal that has a density of 13.58 g/mL. Calculate the volume of mercury<br />

that must be poured out in order to obtain 0.5000 g of Mercury. (2)<br />

4. Classify the following as either quantitative or qualitative observations. (4)<br />

(a) My eyes are brown<br />

(b) My neck size is 17 inches<br />

(c) My average grade last year was 79%<br />

(d) Physics is a difficult subject<br />

C:\www.adriandingleschemistrypages.com\apwsheetsnew\apwsheet01s.doc Page 1 of 3


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

5. Give an example of a natural law (other than the law of conservation of mass). (1)<br />

6. Convert these numbers to scientific notation. (2)<br />

(a) 35800000000000<br />

(b) 0.00000000821<br />

7. Round the following numbers to four figures. (6)<br />

(a) 2.16347 x 10 5<br />

(b) 4.000574 x 10 6<br />

(c) 3.682417<br />

(d) 7.2518<br />

(e) 375.6523<br />

(f) 21.860051<br />

8. Perform the following conversions. (5)<br />

(a) 0.75 kg to milligrams<br />

(b) 1500 millimeters to km<br />

(c) 2390 g to kg<br />

(d) 0.52 km to meters<br />

(e) 65 kg to g<br />

C:\www.adriandingleschemistrypages.com\apwsheetsnew\apwsheet01s.doc Page 2 of 3


© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009. All rights reserved.<br />

These materials may NOT be copied or redistributed in any way, except for individual class instruction.<br />

Revised August 2009<br />

9. Complete the following table of temperatures, performing the appropriate conversions. (18)<br />

Kelvin Fahrenheit Celsius<br />

200.<br />

23.0<br />

0.000<br />

180.<br />

45.0<br />

500.<br />

350.<br />

97.0<br />

30.0<br />

10. An experiment is performed in which the molar mass of a gas is found to be 48.45 g mol -1 .<br />

The published (actual) value is 52.98 g mol -1 . Calculate the percentage error. (2)<br />

11. Distinguish carefully between precision and accuracy. (2)<br />

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