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K2 - Dhm.ie

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<strong>K2</strong><br />

FOR USE ONLY AS AN<br />

AGRICULTURAL PLANT GROWTH REGULATOR<br />

<strong>K2</strong> is a high concentration chlormequat based plant growth regulator for use in Cereals and<br />

certain ornamentals.<br />

PACK SIZE<br />

5 LITRES


<strong>K2</strong><br />

GENERAL COMMENTS : ‘The effects of <strong>K2</strong> on plant growth can result in y<strong>ie</strong>ld increase and a<br />

reduction in early lodging from a spring application. This control of lodging is more consistent in wheat<br />

than in barley.’<br />

TIME OF APPLICATION TO AUTUMN SOWN CROPS (WHEAT AND BARLEY)<br />

Apply <strong>K2</strong> during tillering, but not later than leaf sheath erect stage (when the leaf sheaths on half of the<br />

main shoots have reached 5cm (2") measured from ground level to the base of the uppermost leaf blade)<br />

but before the first node is detectable (Zadoks 31). This is likely to be between mid-February and mid-<br />

April. Best results have been obtained from applications made before the end of March in all autumn<br />

sown crops.<br />

TIME OF APPLICATION TO SPRING SOWN CROPS (WHEAT ONLY)<br />

Apply <strong>K2</strong> during tillering, but before the first node is detectable on half of the main stems. This will<br />

usually mean treating the crop between 15 and 35 days after 50% emergence, especially in late drilled<br />

spring crops.<br />

RATE OF APPLICATION<br />

WINTER WHEAT Apply <strong>K2</strong> at 1.0 litres per hectare (0.7 pints per acre)<br />

SPRING WHEAT Apply <strong>K2</strong> at 0.9 litres per hectare (0.64 pints per acre)<br />

WINTER BARLEY Apply <strong>K2</strong> at 1.25 litres per hectare (0.9 pints per acre)<br />

APPLICATION VOLUME<br />

Apply the recommended rate of <strong>K2</strong> in at least 200 litres of water per hectare (18 gallons per acre).<br />

MIXING<br />

Shake well before use. Add <strong>K2</strong> to a half-filled tank. Top up tank to the required volume and ensure<br />

thorough mixing before and during spraying.<br />

CAUTION<br />

Do not use in tank mixture with liquid nitrogen fertiliser.<br />

APPLICATION CONDITIONS<br />

Do not apply <strong>K2</strong> to crops under stress from waterlogging, drought, or nutr<strong>ie</strong>nt defic<strong>ie</strong>ncy. In hot, dry<br />

weather a better result might be obtained from application in the early morning or evening.<br />

CAUTION<br />

Although <strong>K2</strong> may be used under normal seasonal temperature (down to 1° C) and ground conditions, it<br />

should not be sprayed onto plants covered with frost and requires two hours before rain or frost occurs<br />

for a good effect to be obtained. Do not allow <strong>K2</strong> to drift onto neighbouring crops.<br />

UNDERSOWN CROPS<br />

<strong>K2</strong> may be used on crops undersown with clovers and grasses.<br />

VARIETAL RESTRICTIONS<br />

There are no var<strong>ie</strong>tal restrictions on the use of <strong>K2</strong><br />

SEED CROPS<br />

<strong>K2</strong> may be used on all var<strong>ie</strong>t<strong>ie</strong>s of wheat and barley grown under the Seed Certification Scheme but<br />

growers are advised to consult the guidelines laid down in the Seed Certification Scheme’s<br />

“Certification of Seed of Wheat, Barley and Oats”.


<strong>K2</strong><br />

USE OF STRAW<br />

There are no restrictions on the use of straw from crops treated with <strong>K2</strong>.<br />

COMPATIBILITY<br />

Herbicides - Provided that all product recommendations are followed, <strong>K2</strong> is compatible with<br />

the following products: amidosulfuron (MAFF 07318), benazolin + bromoxynil + ioxynil<br />

(MAFF 07243), benazolin + 2,4-DB + MCPA (MAFF 05623), benazolin + 2, 4-DB + MCPA<br />

(MAFF 07841), bentazone + MCPA + MCPB (MAFF 00028), bromoxynil + fluroxypyr (MAFF<br />

01587), bromoxynil + fluroxypyr + ioxynil (MAFF 05173), bromoxynil + ioxynil (MAFF<br />

07313), bromoxynil + ioxynil (MAFF 06201), bromoxynil + ioxynil + mecoprop-P (MAFF<br />

08150), bromoxynil + ioxynil + triasulfuron (MAFF 06117), chlorotoluron (MAFF 05779),<br />

chlorotoluron (MAFF 03059), clodinafop-propargyl (MAFF 07763), clodinafop-propargyl +<br />

diflufenican (MAFF 08128), clodinafop-propargyl + trifluiralin (MAFF 08030), clopyralid<br />

(MAFF 05578), clopyralid + fluroxypyr + ioxynil (05185), cyanazine (MAFF 07009), 2, 4-D<br />

(MAFF 01391), 2 4-D (MAFF 01393), 2 4-D (MAFF 07699), 2, 4-D (MAFF 08050),<br />

dichlorprop (MAFF 01394), diclofop-methyl (MAFF 07323), diclofop-methyl + fenoxaprop-Pethyl<br />

(MAFF 07337), difenzoquat (MAFF 03241), diflufenican + isoproturon (MAFF 06200),<br />

diflufenican + isoproturon (MAFF 06491), fenoxaprop-ethyl (MAFF 07308), fenoxaprop-P-ethyl<br />

(MAFF 07309), fenoxaprop-P-ethyl + isoproturon (MAFF 07332), flamprop-M-isopropyl<br />

(MAFF 07005), fluroxypyr (MAFF 05496), imazamethabenz-methyl (MAFF 03737),<br />

isoproturon (MAFF 08100), isoproturon (MAFF 06172), isoproturon (MAFF 07695),<br />

isoproturon + pendimethalin (MAFF 03687), linuron (MAFF 07862), MCPA (MAFF 00209),<br />

MCPA (MAFF 07717), MCPA (MAFF 08100), MCPB (MAFF 07522), mecoprop (MAFF<br />

02918), mecoprop (MAFF 06037), mecoprop-P (MAFF 05889), methabenzthiazuron (MAFF<br />

02169), metoxuron (MAFF 00754), metsulfuron-methyl (MAFF 02977), metsulfuron-methyl +<br />

thifensulfuron-methyl (MAFF 03990), pendimethalin (MAFF 08152), pendimethalin (MAFF<br />

04183), thifensulfuron-methyl + tribenuron-methyl (MAFF 07795), tralkoxydim (MAFF 06675),<br />

triasulfuron (MAFF 05993), tribenuron-methyl (MAFF 06270), trifluralin (MAFF 05313),<br />

trinexapac-ethyl (MAFF 07830).


<strong>K2</strong><br />

Fungicides - Provided that all product recommendation are followed, <strong>K2</strong> is compatible with<br />

the following products: azoxystrobin(MAFF 08517), benomyl (MAFF 00229), bromuconazole<br />

(MAFF 08268), carbendazim (MAFF 03848), carbendazim (MAFF 07315), carbendazim (MAFF<br />

02752), carbendazim + chlorothalonil (MAFF 05119), carbendazim + flutriafol (MAFF 06659),<br />

carbendazim + prochloraz (MAFF 07225), carbendazim + propiconazole (MAFF 01050),<br />

carbendazim + propiconazole (MAFF 04968), chlorothalonil (MAFF 05544), chlorothalonil<br />

(MAFF 08366), cyproconazole (MAFF 05065), cyproconazole (MAFF 08354), cyproxonazole +<br />

prochloraz (MAFF 07431), cyproconazole + quinoxyfen (MAFF 08960), cyprodinil (MAFF<br />

08764), epoxiconazole (MAFF 07236), epoxiconazole + fenpropimorph (MAFF 07362),<br />

epoxiconazole + kresoxim-methyl (MAFF 08889), epoxiconazole + kresoxim-methyl +<br />

fenpropimorph (MAFF 08886), epoxiconazole + tridemorph (MAFF 07363), fenpropidin (MAFF<br />

06693), fenpropidin (MAFF 07933), fenpropimorph (MAFF 00578), fenpropimorph (MAFF<br />

06943), fenpropimorph + flusilazole (MAFF 06783), fenpropimorph + kresoxim-methyl (MAFF<br />

08362), fenpropimorph + propiconazole (MAFF 05715), fenpropimorph + quinoxyfen (MAFF<br />

08241), flusilazole (MAFF 08237), iprodione (MAFF 06328), mancozeb (MAFF 04255),<br />

mancozeb (MAFF 06320), maneb (MAFF 01276), nuarimol (MAFF 05502), prochloraz (MAFF<br />

07287), propiconazole (MAFF 02138), propiconazole (MAFF 06747), quinoxyfen (MAFF<br />

08279), sulfur (MAFF 05572), sulfur (MAFF 04707), sulfur (MAFF 04050), tebuconazole<br />

(MAFF 08691), tebuconazole + triadimenol (MAFF 06387), tebuconazole + tridemorph (MAFF<br />

06468), triadimefon (MAFF 00221), triadimenol (MAFF 02672), triadimenol + tridemorph<br />

(MAFF 08361), tridemorph (MAFF 00369).<br />

Insecticides - Provided that all product recommendations are followed, <strong>K2</strong> is compatible with<br />

the following products: chlorpyrifos (MAFF 01992), chlorpyrifos (MAFF 07815), cypermethrin<br />

(MAFF 06632), cypermethrin (MAFF 04119), cypermethrin (MAFF 07680), deltamethrin<br />

(MAFF 01712), demeton-S-methyl (MAFF 08017), dimethoate (MAFF 00199), dimethoate<br />

(MAFF 01527), dimethoate (MAFF 07351), lambda-cyhalothrin (MAFF 06434), pirimicarb<br />

(MAFF 06633), pirimicarb (MAFF 06922).<br />

Adjuvants – SPRAYSEAL<br />

Foliar Fertiliser - When using <strong>K2</strong> with a foliar fertiliser thoroughly mix the <strong>K2</strong> before adding<br />

foliar fertiliser to the spray tank.


<strong>K2</strong><br />

SAFETY DATA SHEET<br />

1. Identification of the substance/preparation and of the<br />

company/undertaking.<br />

PRODUCT NAME<br />

COMPANY<br />

Eastleigh,<br />

<strong>K2</strong><br />

Mandops (UK) Limited, 36 Leigh Road,<br />

Hampshire, SO50 9DT<br />

Tel: 01703 641826<br />

Fax: 01703 629106<br />

2. Composition/information on ingred<strong>ie</strong>nts<br />

ACTIVE INGREDIENT Chlormequat (620 g/litre aqueous solution)<br />

(2-chloroethyltrimethylammonium chloride)<br />

CAS NO [999-81-5]<br />

EC NO 213-666-4<br />

EC SYMBOL LETTER<br />

Xn<br />

3. Hazards identification<br />

FIRE<br />

HEALTH<br />

ENVIRONMENT<br />

Does not present a fire hazard.<br />

Harmful in contact with skin and if swallowed.<br />

None reported.<br />

4. First aid measures<br />

EYES<br />

SKIN<br />

persists.<br />

INGESTION<br />

Keeping eyelids open, irrigate well with eye wash<br />

solution or copious amounts of water without delay.<br />

Obtain medical attention at once.<br />

Remove contaminated clothing and wash skin well<br />

with soap and water.<br />

Obtain medical attention if irritation occurs and<br />

Do not induce vomiting. Wash out mouth with water<br />

and give water (0.25 litres) to drink. Keep pat<strong>ie</strong>nt at<br />

rest and obtain medical attention at once.


<strong>K2</strong><br />

SAFETY DATA SHEET cont..<br />

5. Fire-fighting measures<br />

EXPOSURE HAZARD<br />

SUITABLE EXTINGUISHERS<br />

OTHER ADVICE<br />

If involved in a fire, it will emit fumes containing toxic<br />

nitrogen and chlorine compounds.<br />

Firefighting personnel should wear standard chemicalresistant<br />

protective suit and self-contained breathing<br />

apparatus.<br />

Product is not combustible. Fight fire with carbon dioxide,<br />

foam or water spray, as suitable for other, combustible,<br />

materials involved .<br />

If without risk, remove unopened packages from exposure to fire.<br />

Otherwise spray unopened containers with water to keep cool.<br />

Do not let fire-fighting water contaminate drains or watercourses.<br />

6. Accidental release measures<br />

PERSONAL PRECAUTIONS<br />

ENVIRONMENTAL PRECAUTIONS<br />

OTHER PRECAUTIONS<br />

CLEAN-UP METHODS<br />

Wear protective equipment described in Section 8. Do<br />

not eat drink or smoke. Avoid contact with chemical.<br />

Prevent spillages from entering drains or sewers (inform<br />

local water authority if this occurs), or rivers or other<br />

watercourses (inform National Rivers Authority if this<br />

occurs).<br />

Cordon off area. Keep people and animals away.<br />

Absorb/contain liquid spillages in sand, earth or<br />

propr<strong>ie</strong>tary absorbent, shovel up and place in plastic<br />

drums for subsequent safe disposal (see Section 13).<br />

7. Handling and storage<br />

HANDLING<br />

STORAGE<br />

No special precautions are necessary if unopened packs are handled with<br />

care. When handling in a usage context, refer to usage instructions. When<br />

handling in a spillage context, refer to Sections 3, 6 and 8. In all cases,<br />

before attempting to handle packages manually, refer to assessments made<br />

under the Manual Handling Regulations. Wash hands thoroughly before<br />

eating, drinking or smoking and after work.<br />

No special precautions required. Pesticides should be stored in a locked<br />

designated pesticide store, away from children, animals, food, drink, animal<br />

feeding stuffs and other chemicals. Rotate stock and examine regularly for<br />

leakages.<br />

8. Exposure controls/personal protection<br />

ENGINEERING CONTROLS<br />

Wherever possible, exposure should be eliminated or minimised<br />

using appropriate engineering controls such as physical<br />

containment and good ventilation.


<strong>K2</strong><br />

SAFETY DATA SHEET cont..2<br />

UK EH40 OCCUPATIONAL<br />

EXPOSURE STANDARDS Product - none.<br />

RESPIRATORY<br />

HAND<br />

EYE<br />

SKIN<br />

None required when handling the concentrate.<br />

Plastic or rubber gloves or gauntlets.<br />

Goggles, with side protection, or visor.<br />

Chemical resistant non-adsorbent overalls and rubber or PVC wellington boots.<br />

NOTE<br />

If possible decontaminate protective clothing before removal. Some of the above protective<br />

equipment may be inappropriate when small quantit<strong>ie</strong>s of product are involved. Obtain expert advice before disregarding.<br />

9. Physical and chemical propert<strong>ie</strong>s<br />

APPEARANCE<br />

ODOUR<br />

Yellow-brown liquid<br />

Strong fishy<br />

DECOMPOSITION TEMP 200°C<br />

BOILING TEMPERATURE 100°C<br />

VAPOUR PRESSURE<br />

Aqueous, similar to water.<br />

DENSITY (g/ml) 1.136<br />

SOLUBILITY IN WATER<br />

PARTITION COEFFICIENT<br />

POUR POINT<br />

Miscible<br />

N/A<br />

N/A<br />

AUTOIGNITION<br />

TEMPERATURE<br />

Not<br />

combustible<br />

VISCOSITY (mPa @ 20°C) Not known<br />

pH 6.5-7.5<br />

EXPLOSION POTENTIAL No<br />

OXIDISING POTENTIAL<br />

FLASH POINT (°C)<br />

No<br />

Probably none<br />

10. Stability and reactivity<br />

CONDITIONS TO AVOID<br />

MATERIALS TO AVOID<br />

None known under normal conditions of use. Avoid frost (for technical<br />

reasons).<br />

Concentrate is corrosive to unprotected metals. Avoid materials which react<br />

with water.<br />

HAZARDOUS DECOMPOSITION PRODUCTS None - product is stable (but see Section 5).


<strong>K2</strong><br />

SAFETY DATA SHEET cont..3<br />

11. Toxicological information<br />

ACUTE TOXICITY<br />

RAT ORAL LD 50<br />

RAT DERMAL LD 50<br />

RAT INHALATION LC 50<br />

670 mg/kg<br />

> 6,500 mg/kg (calculated)<br />

> 5 mg/litre (calculated)<br />

The median LD 50 for a person weighing 70 kg is calculated to be 52.5 ml.<br />

ACUTE EXPOSURE EFFECTS<br />

INHALATION<br />

EYES<br />

SKIN<br />

INGESTION<br />

Not Known<br />

May cause slight irritation<br />

May cause slight irritation<br />

Possible headache, giddiness, nausea, muscular twitching,<br />

sweating and incontinence.<br />

CHRONIC TOXICITY<br />

CARCINOGENICITY Chlormequat chloride is not reported to be carcinogenic.<br />

MUTAGENICITY<br />

Chlormequat chloride is not reported to be mutagenic.<br />

REPROTOXICITY Chlormequat chloride is not reported to be reprotoxic.<br />

OTHER<br />

No data<br />

12. Ecological information<br />

ACUTE TOXICITY<br />

96 hr LC 50 rainbow trout Not known<br />

72 hr LC 50 carp > 1000 mg/litre (chlormequat chloride)<br />

48 hr LC 50 daphnia magna 16.9 mg/litre (chlormequat chloride)<br />

LD 50 quail<br />

555 mg/kg (chlormequat chloride)<br />

DEGRADATION<br />

SOIL DT 50 (days)<br />

13. Disposal considerations<br />

No data, but chlormequat chloride rapidly degrades in soil.<br />

PRODUCT<br />

PACKAGING<br />

Dispose of at a licensed waste disposal site capable of accepting pesticides,<br />

in compliance with the Special Wastes and Duty of Care Regulations. The<br />

preferred method of disposal at such facilit<strong>ie</strong>s is incineration at above<br />

1,000°C with a minimum residence time of 3 seconds, with off-gas<br />

scrubbing.<br />

Uncontaminated outer packaging may be disposed of at an approved landfill<br />

site or by incineration. Contaminated or inner packaging should be disposed<br />

of as for product above.


<strong>K2</strong><br />

SAFETY DATA SHEET cont..4<br />

14. Transport information<br />

Note<br />

UN particulars may not apply to all modes of transport - see individual modes below. Some of the<br />

following particulars may not apply to small (<strong>ie</strong> exempt or limited) quantit<strong>ie</strong>s - see transport rules.<br />

UN-No 1760 IMDG class As for UN<br />

UN Class 8 IATA/ICAO Particulars As for UN<br />

UN Packing Group iii CDG-CPL Emergency<br />

UN Danger Sign Corrosive Substance symbol Action Code N/A<br />

UN Subsidiary Hazard Sign None Other particulars As for UN<br />

ADR/RID - Classification 66c<br />

- Other particulars As for UN<br />

15. Regulatory information<br />

LABEL NAME<br />

PF801 (contains 620 g/l chlormequat chloride)<br />

CLASSIFICATION<br />

Harmful<br />

RISK SYMBOL<br />

Xn<br />

RISK PHRASES<br />

(R21/22) Harmful in contact with skin and if swallowed.<br />

SAFETY PHRASES<br />

‘CHIP’ Regulations Not applicable<br />

‘COP’ Regulations<br />

Wear suitable protective gloves when handling the concentrate<br />

When using do not eat, drink or smoke<br />

Wash concentrate from skin or eyes immediately<br />

Do not breathe spray<br />

Wash hands and exposed skin before meals and after work<br />

Keep away from food, drink and animal feeding stuffs<br />

Keep out of reach of children<br />

Do not contaminate surface waters or ditches with chemical or<br />

used container<br />

Keep in original container, tightly closed, in a safe place<br />

Wash out container thoroughly, empty washings into spray<br />

tank and dispose of safely<br />

Do not reuse container for any purpose<br />

If you feel unwell, seek medical advice (show label where<br />

possible)<br />

16. Other information<br />

THIS MATERIAL IS USED FOR<br />

SOURCES OF DATA<br />

Agricultural plant growth regulator<br />

Raw material suppl<strong>ie</strong>rs’ safety data sheets and company in-house<br />

data<br />

This Safety Data Sheet is VERSION 2. Prepared by: PH on 05.09.97<br />

Mandops have taken care to ensure the accuracy of the information given herein and provide this Safety Data<br />

Sheet as required by Directives 91/155/EEC and 93/112/EC but give no warranty as to accuracy or<br />

completeness. Since the conditions of use of this product vary, and are not within the control of Mandops, the<br />

obligation to ensure safety rests with the user.


<strong>K2</strong><br />

STATUTORY CONDITIONS RELATING TO USE<br />

FOR USE ONLY AS AN AGRICULTURAL PLANT GROWTH REGULATOR<br />

One application only is permitted per crop.<br />

CROP<br />

WINTER WHEAT<br />

SPRING WHEAT<br />

WINTER BARLEY<br />

Latest time of application:<br />

MAXIMUM INDIVIDUAL DOSE<br />

1.8 litre per hectare<br />

0.9 litres per hectare<br />

2.3 litres per hectare<br />

Before first node detectable stage.<br />

Engineering control of operator exposure must be used where reasonably practicable in addition to<br />

the following protective equipment:<br />

WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate.<br />

However, engineering controls may replace personal protective equipment if a COSSH assessment<br />

shows that they provide an equal or higher standard of protection.<br />

DO NOT RE-USE CONTAINER for any purpose.<br />

READ ALL PRECAUTIONS BEFORE USE.


<strong>K2</strong><br />

HARMFUL IN SWALLOWED<br />

HARMFUL<br />

PRECAUTIONS<br />

DIRECTIONS FOR USE<br />

For detailed instructions see attached leaflet. Read this before use.<br />

PRECAUTIONS<br />

WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate.<br />

WHEN USING DO NOT EAT, DRINK OR SMOKE<br />

WASH CONCENTRATE from skin or eyes immediately<br />

DO NOT BREATHE SPRAY<br />

WASH HANDS AND EXPOSED SKIN before meals and after work<br />

DO NOT CONTAMINATE SURFACE WATERS OR DITCHES with chemical or used<br />

container.<br />

KEEP IN ORIGINAL CONTAINER, tightly closed in a safe place<br />

WASH OUT CONTAINER THOROUGHLY, empty washings into spray tank and dispose<br />

of safely.<br />

DO NOT REUSE CONTAINER for any purpose.<br />

KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.<br />

KEEP OUT OF REACH OF CHILDREN<br />

IF YOU FEEL UNWELL, seek medical advise (show the label where possible).<br />

IMPORTANT<br />

The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of<br />

this product at work.<br />

READ THE LABEL BEFORE YOU BUY, USE PESTICIDES SAFELY.

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