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Jonathan Bricker - US Nuclear Waste Technical Review Board

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Progress of the High Level <strong>Waste</strong> Program at the<br />

Defense <strong>Waste</strong> Processing Facility<br />

<strong>Jonathan</strong> M. <strong>Bricker</strong>, PEM<br />

DWPF Process Improvement<br />

<strong>Nuclear</strong> <strong>Waste</strong> <strong>Technical</strong> <strong>Review</strong> <strong>Board</strong>: Spring 2013 Meeting<br />

Richland, WA<br />

April 16, 2013


DWPF Progress<br />

– 4.0 million gallons HLW treated<br />

– 14 million pounds of glass produced representing 50 million curies<br />

– 3600+ canisters filled (7500+ planned)<br />

– Currently processing Sludge Batch 7; Sludge Batch 8 to start May 2013 (18 batches planned)<br />

– Production performance for FY13 currently below target<br />

Canisters<br />

<strong>Waste</strong> Loading<br />

Number of Discrete Canisters Produced<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

264<br />

275<br />

225<br />

196<br />

192<br />

38.3%<br />

36.5%<br />

33.3%<br />

33.0%<br />

30.7%<br />

FY08 FY09 FY10 FY11 FY12<br />

Fiscal Year<br />

2


DWPF Overview<br />

Modular Caustic Side<br />

Solvent Extraction Unit<br />

(Strip Effluent, Cs-137<br />

stream)<br />

Actinide Removal<br />

Product<br />

Nitric Acid,<br />

Formic Acid,<br />

and Antifoam<br />

Additions<br />

Antifoam Additions,<br />

Decon Frit Water<br />

Additions, and Frit<br />

Additions<br />

H- Tank Farm<br />

<strong>Waste</strong> Acceptance<br />

Items/Activities<br />

Sludge Receipt<br />

and Adjustment<br />

Tank<br />

Slurry Mix<br />

Evaporator<br />

SAMPLE<br />

ANALYSIS<br />

HOLD POINT-<br />

GLASS<br />

ACCEPTABLE?<br />

Melter<br />

Feed<br />

Tank<br />

Melter<br />

Process works to produce highly durable borosilicate wasteform.<br />

3


Recent Improvements<br />

• Extensive improvements made to increase waste throughput<br />

– Reduction in cycle time of melter feed preparation cycle (e.g. analytical improvements)<br />

– Melter bubbler installation to increase melt rate<br />

– Increase in waste loadings due to “tailoring” frit (i.e. more waste in each can)<br />

400<br />

Goal is to maximize<br />

waste throughput to<br />

reduce environmental risk.<br />

Canisters Per Year<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

Recent<br />

Improvements<br />

Original<br />

Capacity<br />

Melter<br />

Bubblers<br />

Original<br />

Capacity<br />

50<br />

0<br />

DWPF Batch Prep<br />

DWPF Melter<br />

4


Challenges and Future Work<br />

• Growing need to provide flexibility to accommodate variability in<br />

SRR System Plan (e.g. waste feed compositions, input streams)<br />

– Understand and expand operating windows (simplify process to improve throughput)<br />

– Optimize processing windows for future waste compositions (higher waste loadings)<br />

– Addressing demand for higher process/equipment reliability due to closely Long-term coupled<br />

operations and increased activity in Tank Closure efforts and salt waste Improvements processing<br />

• Alternate Reductant<br />

• Dry Frit<br />

• System Reliability<br />

Goal is to position<br />

facility for continuous<br />

success.<br />

Canisters Per Year<br />

400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

Melter<br />

Bubblers<br />

Planned<br />

Improvements<br />

Recent<br />

Improvements<br />

Original<br />

Capacity<br />

Short-term<br />

Improvements<br />

Melter<br />

Bubblers<br />

Original<br />

Capacity<br />

0<br />

DWPF Batch Prep<br />

DWPF Melter<br />

5


Lessons Learned<br />

• Lessons learned over 18 years of operation<br />

– Efficiency of waste qualification program<br />

– Success of statistical process control (versus product quality control) methodology<br />

– Decontamination features provide ability to perform hands-on work on critical<br />

equipment<br />

– Utility of maintaining research facilities and expertise throughout the DWPF production<br />

life to address immediate issues as well as forward-looking improvements<br />

– Synergizing ideas from multiple technology organizations<br />

– Continuous improvement required to accommodate changes in SRR System Plan<br />

– Understanding impacts of changes in processes on the physical properties of material<br />

– Volume management critical to vitrification production performance<br />

6

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