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1<br />

I<br />

<strong>Resource</strong> Conservation <strong>and</strong> Recovery Act<br />

Facility Investigation/Remedid Investigation<br />

Report for'>Waste Area Groupings 1 <strong>and</strong> 7<br />

at Paduchh Gaseous Diffwion Plant<br />

Paducah, Kentucky<br />

<strong>Volume</strong> <strong>4.</strong> <strong>Appendixes</strong> L, <strong>Section</strong> <strong>L.7</strong>, <strong>and</strong> M<br />

CLEARED FOR PUBLIC RELEASE


DOE/OR/07- 1404&D 1<br />

KY/EM-lOl&Dl<br />

Energy Systems Environmental Restoration Program<br />

PGDP Environmental Restoration Program<br />

<strong>Resource</strong> Conservation <strong>and</strong> Recovery Act<br />

Facility Investigation/Remedial Investigation<br />

Report for Waste Area Groupings 1 <strong>and</strong> 7<br />

at Paducah Gaseous Diffusion Plant<br />

Paduca h , Kentucky<br />

<strong>Volume</strong> <strong>4.</strong> <strong>Appendixes</strong> L, <strong>Section</strong>s <strong>L.7</strong>, <strong>and</strong> M<br />

Date Issued-November 1995<br />

Prepared by<br />

Environmental Restoration Division<br />

Lockheed Martin Energy Systems, Inc.<br />

Paducah, Kentucky<br />

<strong>and</strong><br />

Risk Analysis <strong>Section</strong><br />

Health Sciences Research Division<br />

Oak Ridge National Laboratory<br />

Lockheed Martin Energy Systems, Inc.<br />

Oak Ridge, Tennessee<br />

<strong>and</strong><br />

CDM Federal Programs Corporation<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

U.S. Department of Energy<br />

Office of Environmental Restoration <strong>and</strong> Waste Management<br />

PADUCAH GASEOUS DIFFUSION PLANT<br />

Paducah, Kentucky 42002<br />

by<br />

LOCKHEED MARTIN ENERGY SYSTEMS, INC.<br />

for the<br />

U.S. DEPARTMENT OF ENERGY<br />

under contract DE-AC05-760R00001


Appendix <strong>L.7</strong><br />

Chronic Hazard Index Estimates <strong>and</strong> Cancer Risk Estimates for Adults<br />

<strong>and</strong> Children


THIS PAGE LEFT BLANK


Hazard Index Estimates<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 1, SWMU lOOc, RGW-Residential Dermal Contact with Water<br />

Aluminum<br />

4s<br />

Barium 5.52E-05 <strong>4.</strong>90E-03 9 1.13E-02<br />

Manganese 5.09E-04 2.00E-04 38 2.54E+00<br />

Methylene Chloride 1.80E-06 5.70E-02 41 3.15E-05<br />

bis(2-Ethylhexy1)phthalate 3.75E-06 3.8OE-03 15 9.86E-04<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

2.56E+00<br />

WAG 1. SWMU 1OOc. RGW-Residential Ingestion of Water<br />

Alummum<br />

3.64E-01<br />

Barium 1.88E-02 7.00E-02 a 2.68E-01<br />

Manganese 1.73E-01 5.00E-03 a 3.46E+01<br />

Methylene Chloride<br />

1.37E-04 6.00E-02 a 2.28E-03<br />

bis(2-Ethylhexy1)phthalate 5.48E-05 2.00E-02 a 2.74E-03<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

3.49E+01<br />

WAG 1, SWMU lOOc, RGW-Residential Inhalation of Water<br />

Aluminum<br />

Barium 1.43E-04 b,c<br />

Manganese 1.43E-05 a<br />

Methylene Chloride 7.13E-06 8.57E-01 b 8.32E-06<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

8.32E-06<br />

WAG 1, SWMU lOOc, RSO-Residential Dermal Contact with Soil<br />

Aluminum 3.55E-02 4s<br />

Arsenic 2.12E-05 1.23E-04 8 1.73E-01<br />

Beryllium 1.90E-06 5.00E-05 13, 1 3.79E-02<br />

Cobalt 3.00E-05 26<br />

Lead <strong>4.</strong>39E-05 26<br />

Sodium<br />

1.42E-03<br />

Thallium 2.42E-07 52<br />

2-Methylnaphthalene 2.23E-06 43<br />

3-Nitroaniline<br />

5.47E-07<br />

Endosulfan Sulfate<br />

7.45E-09<br />

Endrin Ketone<br />

7.69E-09<br />

Naphthalene 1.35E-06 43<br />

Phenanthrene 3.71E-06 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

2.10E-01<br />

WAG 1. S WMU 1 OOc, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

6.34E-03<br />

Arsenic<br />

3.79E-06 3.00E-04 a 1.26E-02<br />

Beryllium 3.39E-07 5.00E-03 a 6.77E-05<br />

Cobalt<br />

5.35E-06<br />

Lead<br />

7.84E-06<br />

Sodium<br />

2.53E-04<br />

Thallium<br />

<strong>4.</strong>32E-08<br />

2-Methylnaphthalene<br />

2.00E-07<br />

3-Nitroaniline<br />

<strong>4.</strong>88E-08<br />

Endosulfan Sulfate<br />

6.66E-10<br />

Endrin Ketone 6.87E- 10<br />

Naphthalene 1.21E-07 e<br />

Phenanthrene<br />

3.31E-07<br />

Gross Alpha<br />

Gross Beta<br />

Page 1 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS<br />

Neptunium-237<br />

CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

1.27E-02<br />

WAG 1, SWMU lOOc, RSO-Residential Ingestion of Soil for Child<br />

Aluminum<br />

5.92E-02<br />

Arsenic<br />

3.54E-05 3.00E-04 a 1.18E-01<br />

Beryllium<br />

3.16E-06 5.00E-03 a 6.32E-04<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

5.00E-05<br />

7.31E-05<br />

2.36E-03<br />

<strong>4.</strong>03E-07<br />

1.86E-06<br />

<strong>4.</strong>56E-07<br />

6.21E-09<br />

6.41E-09<br />

1.13E-06<br />

e<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-23 8<br />

3.09E-06<br />

Pathway Total 1.19E-0 1<br />

WAG 1, SWMU lOOc, RSO-Residential Ingestion of Vegetables<br />

Aluminum<br />

Arsenic <strong>4.</strong>55E-06 3.OOE-04 a 1.52E-02<br />

Barium 1.05E-01 7.00E-02 a 1.49E+00<br />

Beryllium 1.27E-07 5.OOE-03 a 2.55E-05<br />

Cobalt<br />

Lead<br />

5.02E-06<br />

Manganese 1.04E+00 5.00E-03 a 2.07E4-02<br />

Sodium<br />

Thallium<br />

3.47E-09<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Methylene Chloride<br />

1.01E-03 6.00E-02 a 1.69E-02<br />

Naphthalene<br />

1.27E-05<br />

e<br />

Phenanthrene<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

6.79E-06<br />

5.56E-04 2.00E-02 a 2.78E-02<br />

Pathway Total<br />

2.09E4-02<br />

WAG 1, SWMU lOOc, RSO-Residential Inhalation of Soil<br />

Aluminum<br />

2.96E-07<br />

Arsenic<br />

1.77E-10<br />

Beryllium<br />

1.58E-11<br />

Cobalt<br />

2.50E-10<br />

Lead 3.66E- 10<br />

Sodium<br />

1.18E-08<br />

Thallium<br />

2.01E-12<br />

2-Methylnaphthalene 9.31E-12<br />

3-Nitroaniline<br />

2.28E-12<br />

Endosulfan Sulfate<br />

3.11E-14<br />

Endrin Ketone<br />

3.21E-14<br />

Naphthalene<br />

5.63E-12<br />

Phenanthrene<br />

1.55E-11<br />

Gross Alpha<br />

Page 2 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

2.46E+02<br />

WAG 1, SWMU 136, RGW-Residential Dermal Contact with Water<br />

Barium 2.66E-05 <strong>4.</strong>90E-03 9 5.42E-03<br />

Manganese <strong>4.</strong>50E-04 2.00E-04 38 2.25E+00<br />

Trichloroethene 1.39E-04 57<br />

bis(2-Ethylhexy1)phthalate 1.87E-06 3.80E-03 15 <strong>4.</strong>93E-04<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

2.26E+00<br />

WAG 1, SWMU 136. RGW-Residential Ingestion of Water<br />

Barium 9.04E-03 7.00E-02 a 1.29E-01<br />

Manganese 1.53E-01 5.00E-03 a 3.06E+01<br />

Trichloroethene 3.01E-03<br />

bis(2-Ethylhexy1)phthalate 2.74E-05 2.00E-02 a 1.37E-03<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total 3.08E+O 1<br />

WAG 1, SWMU 136, RGW-Residential Inhalation of Water<br />

Barium 1.43E-04 b,c<br />

Manganese 1.43E-05 a<br />

Trichloroethene<br />

1.57E-04<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

WAG 1, SWMU 136, RSO-Residential Dermal Contact with Soil<br />

Aluminum 1.49E-03 435<br />

Arsenic 5.36E-07 1.23E-04 8 <strong>4.</strong>36E-03<br />

Beryllium 6.70E-08 5.OOE-05 13, 1 1.34E-03<br />

Cobalt 1.54E-06 26<br />

Lead l.lSE-06 26<br />

Sodium<br />

<strong>4.</strong>19E-05<br />

Sulfate<br />

1.31E-04<br />

Thallium 9.03E-09 52<br />

1.1,l -Trichloroethane 1.25E-08 55<br />

1.1 -Dichloroethene 8.1 1E-09 9.00E-03 31 9.0 IE-07<br />

Benzo(a)anthracene 5.87E-08 2<br />

Benzo(a)pyrene 6.26E-08 2<br />

Benzo(b)fluoranthene 6.56E-08 2<br />

Benzo(g,h,i)perylene 5.53E-08 2<br />

Dibenzo(qh)anthracene 2.19E-08 2<br />

Indeno( 1,2,3-cd)pyrene 5.66E-08 2<br />

Phenanthrene 2.13E-08 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

5.70E-03<br />

WAG 1. SWMU 136, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

2.66E-04<br />

Arsenic 9.58E-08 3.00E-04 a 3.19E-04<br />

Beryllium 1.20E-08 5.OOE-03 a 2.39E-06<br />

Cobalt<br />

2.74E-07<br />

Lead<br />

2.05E-07<br />

Sodium<br />

7.48E-06<br />

Sulfate<br />

2.34E-05<br />

Thallium 1.61 E-09<br />

1.1,l -Trichloroethane <strong>4.</strong>46E-10 e<br />

1,l-Dichloroethene 2.90E-10 9.00E-03 a 3.22E-08<br />

Page 3 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Benz0la)anthracene .,<br />

5.24E-09<br />

Benzo(a)pyrene<br />

5.59E-09<br />

Benzo(b)fluoranthene<br />

5.86E-09<br />

Benzo(g,h,i)perylene<br />

<strong>4.</strong>94E-09<br />

Dibenzo(a,h)anthracene 1.95E-09<br />

Indeno( 1,2,3-cd)pyrene 5.05E-09<br />

Phenanthrene<br />

1.90E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.22E-04<br />

WAG 1, SWMU 136, RSO-Residential Ingestion of Soil for Child<br />

Aluminum<br />

2.49E-03<br />

Arsenic<br />

8.94E-07 3.00E-04 a 2.98E-03<br />

Beryllium<br />

1.12E-07 5.00E-03 a 2.23E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1,1, I-Trichloroethane<br />

1, I-Dichloroethene<br />

2.56E-06<br />

1.91E-06<br />

6.98E-05<br />

2.19E-04<br />

1.50E-08<br />

<strong>4.</strong>16E-09<br />

2.70E-09 9.00E-03<br />

e<br />

a 3.00E-07<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

<strong>4.</strong>89E-08<br />

5.22E-08<br />

5.47E-08<br />

<strong>4.</strong>61E-08<br />

1.82508<br />

<strong>4.</strong>72E-08<br />

1.78E-08<br />

Pathway Total<br />

3.00E-03<br />

WAG 1, SWMU 136, RSO-Residential Ingestion of Vegetables<br />

Aluminum<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Manganese<br />

Sodium<br />

Sulfate<br />

Thallium<br />

l,l,l-Trichloroethane<br />

1,l -Dichloroethene<br />

Benzo(a)anbene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Trichloroethene<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

1.15E-07<br />

5.03E-02<br />

<strong>4.</strong>50E-09<br />

1.3 1E-07<br />

9.16E-0 1<br />

1.30E- 10<br />

1.24507<br />

1.94E-07<br />

2.36E-08<br />

1.36E-08<br />

1.42E-08<br />

8.66E-09<br />

6.85E-09<br />

3.90E-08<br />

2.78E-04<br />

3.00E-04 a 3.83E-04<br />

7.00E-02 a 7.18E-0 1<br />

5.OOE-03 a 9.00E-07<br />

5.00E-03 a 1.83E+02<br />

9.00E-03<br />

2.OOE-02<br />

WAG 1, SWMU 136, RSO-Residential Inhalation of Soil<br />

Aluminum<br />

1.24E-08<br />

Arsenic<br />

<strong>4.</strong>47E-12<br />

Beyllium<br />

5.58E-13<br />

Page 4 of 53<br />

e<br />

a<br />

a<br />

2.15E-05<br />

1.39E-02<br />

1.84EM2


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Cobalt<br />

1.28E-11<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

l,l,l-Trichloroethane<br />

9.55E-12<br />

3.49E- 10<br />

1.09E-09<br />

7.53E-14<br />

5.32E-09<br />

e<br />

1, I-Dichloroethene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

9.18E-09<br />

2.45E-13<br />

2.61E-13<br />

2.73E-13<br />

2.31E-13<br />

9.12E- 14<br />

2.36E-13<br />

8.89E- 14<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

2.17E+02<br />

WAG 1, SWMU 38c, RGW-Residential Dermal Contact with Water<br />

Barium 2.34E-05 <strong>4.</strong>90E-03 9 <strong>4.</strong>78E-03<br />

Manganese 2.27E-04 2.00E-04 38 1.13E+00<br />

Methylene Chloride <strong>4.</strong>67E-05 5.70E-02 41 8.19E-04<br />

Gross Beta<br />

Pathway Total<br />

1.14E+00<br />

WAG 1, SWMU 38c, RGW-Residential Ingestion of Water<br />

Barium 7.97E-03 7.00E-02 a 1.14E-01<br />

Manganese 7.73E-02 5.OOE-03 a 1.55E+01<br />

Methylene Chloride 3.56E-03 6.00E-02 a 5.94E-02<br />

Gross Beta<br />

Manganese 1.43E-05 a<br />

Methylene Chloride 1.86E-04 8.57E-01 b 2.16E-04<br />

Gross Beta<br />

Pathway Total<br />

2.16E-04<br />

WAG 1, SWMU 38c, RSO-Residential Dermal Contact with Soil<br />

Aluminum 6.98E-02 4s<br />

Arsenic<br />

<strong>4.</strong>49E-05 1.23E-04 8 3.65E-01<br />

Beryllium<br />

<strong>4.</strong>18E-06 5.00E-05 13, 1 8.36E-02<br />

Cobalt<br />

Lead<br />

Sodium<br />

'Ihallium<br />

2-Hexanone<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

Benzo( a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

7.22E-05<br />

1.06E-04<br />

1.52E-03<br />

9.10507<br />

3.84E-07<br />

6.11E-07<br />

2.30E-06<br />

1.99E-06<br />

2.92E-06<br />

3.88E-06<br />

26<br />

26<br />

52<br />

36<br />

46<br />

2<br />

2<br />

2<br />

2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thonum-228<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total 4 .. 49E-0 ..- . 1 .<br />

WAG 1, SWMU 38c, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

1.25E-02<br />

Arsenic 8.02E-06 3.00E-04 a 2.67E-02<br />

Bervllium 7.46E-07 5.00E-03 a 1.49E-04<br />

Cobalt<br />

1.29E-05<br />

Page 5 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

I<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Lead<br />

1.89E-05<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

2.72E-04<br />

1.62E-07<br />

1.37E-08<br />

5.46E-08<br />

2.05E-07<br />

1.78E-07<br />

2.60E-07<br />

3.46E-07<br />

Arsenic<br />

Beryllium<br />

Cobah<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

7.49E-05 3.00E-04 a 2.50E-01<br />

6.96E-06 5.00E-03 a 1.39E-03<br />

1.20E-04<br />

1.76E-04<br />

2.54E-03<br />

1.52E-06<br />

1.28E-07<br />

5.09E-07<br />

1.92E-06<br />

1.66E-06<br />

2.43E-06<br />

3.23E-06<br />

Pathway Total 2.5 1 E-0 1<br />

WAG 1, SWMU 38c, RSO-Residential Ingestion of Vegetables<br />

Aluminum<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Manganese<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Methvlene Chloride<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

9.63E-06<br />

<strong>4.</strong>43502<br />

2.81E-07<br />

1.2 1E-05<br />

<strong>4.</strong>62E-0 1<br />

1.31E-08<br />

3.12E-08<br />

9.23E-07<br />

<strong>4.</strong>33E-07<br />

6.33E-07<br />

2.63E-02<br />

7.10E-06<br />

WAG 1, SWMU 38c, RSO-Residentlal Inhahon of Soil<br />

Aluminum 5 82E-07<br />

3.00E-04 a 3.21E-02<br />

7.00E-02 a 6.33E-01<br />

5.00E-03 a 5.62E-05<br />

5.00E-03 a 9.24E+01<br />

6.00E-02 a <strong>4.</strong>39E-01<br />

9.35E+01<br />

Page 6 of 53<br />

!


~<br />

Hazard Index Estimates (continued)<br />

'<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Arsenic<br />

3.74E-10<br />

Beryllium<br />

3.48E-11<br />

Cobalt 6.OZE- 10<br />

Lead 8.82E- 10<br />

Sodium<br />

1.27E-08<br />

Thallium<br />

7.58E-12<br />

2-Hexanone<br />

6.39E-13<br />

Aroclor- I260<br />

2.55E-12<br />

Benzo(a)anthracene<br />

9.59E-12<br />

Benzo( a)pyrene<br />

8.31E-12<br />

Benzo(b)fluoranthene 1.21E-11<br />

Phenanthrene 1.62E- 11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total 1.11E+02<br />

WAG 7, SWMU 130, RSO-Residential Dermal Contact with Soil<br />

Lead 5.76E-07 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7. SWMU 130, RSO-Residential Ingestion of Soil for Adult<br />

Lead<br />

1.03E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, RSO-Residential Ingestion of Soil for Child<br />

Lead<br />

9.59E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, RSO-Residential Ingestion of Vegetables<br />

Lead<br />

6.58E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, RSO-Residential Inhalation of Soil<br />

Lead<br />

<strong>4.</strong>80E-12<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7. SWMU 131, RSO-Residential Dermal Contact with Soil<br />

Lead 1.1 OE-07 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav . ~-. Total<br />

WAG 7, SWMU 131, RSO-Residential Ingeshon of Soil for Adult<br />

Lead<br />

1.96E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

-<br />

Page 7 of 53


Hazard Index Estimates (continued)<br />

~~<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 7, SWMU 131, RSO-Residential Ingestion of Soil for Child<br />

Lead<br />

1.83E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 131, RSO-Residential Ingestion of Vegetables<br />

Lead<br />

1.26E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7. SWMU 131. RSO-Residential Inhalation of Soil<br />

Lead 9.16513<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7, SWMU 132, RSO-Residential Dermal Contact with Soil<br />

Lead 9.00E-06 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, RSO-Residential Ingestion of Soil for Adult<br />

Lead 1.61E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, RSO-Residential Ingestion of Soil for Child<br />

Lead<br />

1.50E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, RSO-Residential Ingestion of Vegetables<br />

Lead<br />

1.03E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, RSO-Residential Inhalation of Soil<br />

Lead<br />

7.50E-11<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7, SWMU 133, RSO-Residential Dermal Contact with Soil<br />

Lead 1.04E-05 26<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

7.5SE-08<br />

5.66E-07<br />

<strong>4.</strong>26E-07<br />

<strong>4.</strong>58E-07<br />

2.53E-07<br />

3.82E-07<br />

3.12E-08<br />

2.09E-07<br />

5.12E-07<br />

Page 8 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

EXPOSURE<br />

PATHWAY<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Uranrum-238<br />

Pathway Total<br />

WAG 7, SWMU 133, RSO-Residential Ingestion of Soil for Adult<br />

Lead<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo( a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.86E-06<br />

6.74E-09<br />

5.05E-08<br />

3.80E-08<br />

<strong>4.</strong>09E-08<br />

2.26E-08<br />

3.41E-08<br />

2.79E-09<br />

1.87E-08<br />

<strong>4.</strong>57E-08<br />

Pathway Total<br />

WAG 7, SWMU 133, RSO-Residential Ingestion of Soil for Child<br />

Lead 1.746-05<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

6.29E-08<br />

<strong>4.</strong>72E-07<br />

3.55E-07<br />

3.82E-07<br />

2.11E-07<br />

3.19E-07<br />

2.60E-08<br />

1.75E-07<br />

<strong>4.</strong>27E-07<br />

WAG 7, SWMU 133, RSO-Residential Ingestion of Vegetables<br />

Lead<br />

1.19E-06<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

2.27E-07<br />

Benzo(a)pyrene<br />

9.24E-08<br />

Benzo(b)fluoranthene<br />

9.94E-08<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

8.30E-08<br />

Dibenzo(a,h)anthracene 1.24E-08<br />

Indeno( 1,2,3-cd)pyrene 2.54E-08<br />

Phenanthrene<br />

9.37E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 8<br />

Pathwav Total<br />

WAG 7, SWMU 133, RSO-Residential Inhalation of Soil<br />

Lead<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(ah)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

8.70E-11<br />

3.15E-13<br />

2.36E-12<br />

1.77E- 12<br />

1.91E-12<br />

1.05E-12<br />

1.59E- 12<br />

1.30E-13<br />

8.73E-13<br />

2.13E-12<br />

Page 9 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 7, SWMU 134, RSO-Residential Dermal Contact with Soil<br />

Lead 1.68E-06 26<br />

Benzo( a)anthracene<br />

1.93E-08<br />

Benzo(a)pyrene<br />

1.80E-08<br />

Benzo@)fluoranthene<br />

2.69E-08<br />

Benzo(g,h,i)perylene<br />

9.54E-09<br />

Phenanthrene<br />

<strong>4.</strong>33E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, RSO-Residential Ingestion of Soil for Adult<br />

Lead<br />

2.99E-07<br />

Benzo(a)anthracene<br />

1.73E-09<br />

Benzo(a)pyrene 1.61E-09<br />

Benzo(b)fluoranthene<br />

2.40E-09<br />

Benzo(g,h,i)perylene<br />

8.52E-10<br />

Phenanthrene<br />

3.87E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, RSO-Residential Ingestion of Soil for Child<br />

Lead<br />

2.79E-06<br />

Benzo(a)anthracene<br />

1.61E-08<br />

Benzo(a)pyrene<br />

1.50E-08<br />

Benzo(b)fluoranthene<br />

2.24E-08<br />

Benzo(g,h,i)perylene<br />

7.95E-09<br />

Phenanthrene 3.61E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, RSO-Residential Ingestion of Vegetables<br />

Lead<br />

1.92E-07<br />

Benzo(a)anthracene<br />

7.75E-09<br />

Benzo(a)pyrene<br />

3.92E-09<br />

Benzo(b)fluoranthene<br />

5.84E-09<br />

Benzo(g,h,i)perylene<br />

Phenanthrene<br />

7.93E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, RSO-Residential Inhalation of Soil<br />

Lead 1.40E- 11<br />

Benzo(a)anthracene<br />

8.06E-14<br />

Benzo(a)pyrene<br />

7.52E-14<br />

Benzo@)fluoranthene 1.12E- 13<br />

Benzo(g,h,i)perylene 3.97E- 14<br />

Phenanthrene 1.81 E- 13<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 8b, RGW-Residential Dermal Contact with Water<br />

Aluminum 43<br />

Beryllium <strong>4.</strong>25E-06 5.00E-05 13, 1 8.51E-02<br />

Cobalt 26<br />

Iron 26<br />

Manganese 2.01E-03 2.00E-04 38 1 .O 1E+O 1<br />

Nickel 5.26E-05 5.40E-03 44 9.75E-03<br />

Page 10 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,l -Dichloroethene 7.12E-06 9.00E-03 31 7.9 IE-04<br />

1,2-Dichloroethene 1.31E-05 9.00E-03 1.46E-03<br />

Phenanthrene 2.20E-05 2<br />

Trichloroethene 6.74E-06 57<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

1.02E+01<br />

WAG 7, SWMU 8b, RGW-Residential Ingestion of Water<br />

Aluminum<br />

1.32E+00<br />

Beryllium<br />

1.45E-03 5.00E-03 a 2.90E-01<br />

Cobalt<br />

Iron<br />

Manganese<br />

2.34E-02<br />

3.37E+01<br />

6.85E-01 5.OOE-03 a 1.37E+02<br />

Nickel<br />

1.79E-02 2.00E-02 a 8.96E-01<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,l -Dichloroethene<br />

1.38E+01<br />

3.29E-01<br />

2.18E+01<br />

6.58E-02<br />

2.66E-04 9.00E-03 a 2.95E-02<br />

1,2-Dichloroethene<br />

<strong>4.</strong>18E-03 9.00E-03 b <strong>4.</strong>65E-01<br />

Phenanthrene<br />

Trichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thonum-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

2.74E-05<br />

1.46E-04<br />

Pathway Total<br />

1.39E+02<br />

WAG 7, SWMU 8b, RGW-Residential Inhalation of Water<br />

Aluminum<br />

Beryllium<br />

Cobalt<br />

Iron<br />

Manganese<br />

1.43E-05 a<br />

Nickel<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1, I-Dichloroethene<br />

1.38E-05<br />

1.2-Dichloroethene<br />

Phenanthrene<br />

Trichloroethene<br />

7.60E-06<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7. SWMU 8b. RSO-Residential Dermal Contact with Soil<br />

Page 11 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Aluminum 8.33E-02 <strong>4.</strong>5<br />

Arsenic<br />

3.11E-05 1.23E-04 8 2.52E-0 1<br />

Beryllium<br />

5.34E-06 5.00E-05 13, 1 1.07E-01<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

5.93E-05<br />

7.64E-05<br />

<strong>4.</strong>37E-04<br />

8.33E-04<br />

1.19E-06<br />

1.84E-06<br />

<strong>4.</strong>39E-07<br />

2.65E-06<br />

3.85E-06<br />

<strong>4.</strong>36E-06<br />

3.78E-06<br />

3.53E-06<br />

3.86E-06<br />

3.52E-06<br />

26<br />

26<br />

52<br />

43<br />

46<br />

2<br />

2<br />

2<br />

2<br />

43<br />

2<br />

Arsenic 5.54E-06 3.00E-04 a 1.85E-02<br />

Beryllium 9.54E-07 5.OOE-03 a 1.91E-04<br />

Cobalt<br />

1.06E-05<br />

Lead<br />

1.36E-05<br />

Phosphate (ortho)<br />

7.81E-05<br />

Sodium<br />

1.49E-04<br />

Thallium<br />

2.12E-07<br />

2-Methylnaphthalene<br />

1.64E-07<br />

Aroclor-1260<br />

3.92E-08<br />

Benzo(a)anthracene<br />

2.37E-07<br />

Benzo(a)pyrene<br />

3.44E-07<br />

Benzo(b)fluoranthene<br />

3.89E-07<br />

Dibenzofuran<br />

3.37E-07<br />

Indeno( 1,2,3-cd)pyrene 3.15E-07<br />

Naphthalene<br />

3.45E-07<br />

e<br />

Phenanthrene<br />

3.14E-07<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

WAG 7. SWMU 8b, RSO-Residential Ingestion of Soil for Child<br />

Aluminum 1.39E-01<br />

Arsenic 5.18E-OS 3.00E-04 a 1.73E-01<br />

Beryllium 8.90E-06 5.00E-03 a 1.78E-03<br />

Cobalt<br />

9.88E-05<br />

Lead<br />

1.27E-04<br />

Phosphate (ortho)<br />

7.29E-04<br />

Sodium<br />

1.39E-03<br />

Thallium<br />

1.98E-06<br />

2-Methylnaphthalene<br />

1.53E-06<br />

Aroclor-1260<br />

3.66E-07<br />

Benzo(a)anthmcene<br />

2.21E-06<br />

1.87E-02<br />

Page 12 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Benzo(a)pyrene<br />

3.21E-06<br />

Benzo(b)fluoranthene<br />

3.63E-06<br />

Dibenzofuran<br />

3.15E-06<br />

Indeno( 1,2,3-cd)pyrene 2.94E-06<br />

Naphthalene<br />

3.22E-06<br />

e<br />

Phenanthrene<br />

2.93E-06<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-23 5<br />

Uranium-238<br />

Pathwav Total 1.74E-01<br />

WAG 7, SWMU 8b, RSO-Residential Ingestion of Vegetables<br />

Aluminum<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Iron<br />

Lead<br />

8.74E-06<br />

Manganese <strong>4.</strong>09E+00 5.00E-03<br />

Nickel 1.00E-01 2.00E-02<br />

Phosphate (ortho)<br />

Silica<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Sulfide<br />

Thallium<br />

1,1 -Dichloroethene<br />

1.70E-08<br />

1.71E-03 9.00E-03<br />

1,2-Dichloroethene<br />

<strong>4.</strong>64E-02 9.00E-03<br />

2-Methylnaphthalene<br />

Aroclor- 1260<br />

Benzo( a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

Trichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium228<br />

Thorium-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

2.24E-08<br />

1.06E-06<br />

8.37E-07<br />

9.47E-07<br />

<strong>4.</strong>27E-07<br />

3.63E-05<br />

1.59E-04<br />

R’AG 7. SWMU 8b, RSO-Residential Inhalation of Soil<br />

Aluminum<br />

6.95E-07<br />

Arsenic<br />

2.59E-10<br />

Beryllium<br />

<strong>4.</strong>45E-11<br />

Cobalt<br />

<strong>4.</strong>94E-10<br />

Lead<br />

6.37E-I0<br />

Phosphate (ortho)<br />

3.64E-09<br />

Sodium 6.95509<br />

Thallium<br />

9.88E-12<br />

2-Methvlnaphthalene<br />

7.67E-12<br />

Aroclor-1260 1.83E- 12<br />

Benzo( a)anthracene<br />

1.lOE-I1<br />

6.66E-06 3.00E-04 a 2.22E-02<br />

8.04E-03 5.00E-03 a 1.61E+00<br />

Page 13 of 53<br />

a<br />

a<br />

a<br />

b<br />

e<br />

8.19E+02<br />

5.02E+00<br />

1.90E-01<br />

5.15E+00<br />

8.31E+02


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Benzo(a)pyrene<br />

1.6lE-11<br />

Benzo(b)fluoranthene 1.82E- 11<br />

Dibenzofuran 1.57E- 11<br />

Indeno( 1,2,3-cd)pyrene 1.47E-11<br />

Naphthalene 1.61E- 11<br />

Phenanthrene<br />

1.47E-11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

9.80E+02<br />

WAG 1, SWMU 100% CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 7.30E-03 4s<br />

Arsenic<br />

3.38E-06 1.23E-04 8 2.75E-02<br />

Beryllium<br />

<strong>4.</strong>92E-07 5.00E-05 13, 1 9.85E-03<br />

Cobalt<br />

9.73E-06 26<br />

Lead<br />

6.82E-06 26<br />

Sodium<br />

8.01E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.73E-02<br />

WAG 1, SWMU 100% CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Cadmium 5.00E-04 a<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100% CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

7.52E-04<br />

Arsenic 3.49E-07 3.00E-04 a 1.16E-03<br />

Beryllium 5.08E-08 5.00E-03 a 1.OZE-05<br />

Cobalt<br />

1.00E-06<br />

Lead<br />

7.03E-07<br />

Sodium<br />

8.26E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.17E-03<br />

WAG 1, SWMU 100% CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

7.02E-03<br />

Arsenic 3.25E-06 3.00E-04 a 1.08E-02<br />

Beryllium <strong>4.</strong>74E-07 5.OOE-03 a 9.47E-05<br />

Cobalt<br />

9.36E-06<br />

Lead<br />

6.56E-06<br />

Sodium<br />

7.71E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.09E-02<br />

WAG 1, SWMU 100% CSE-Recreational Inhalation of Sediment<br />

Aluminurn<br />

3.51E-08<br />

Arsenic<br />

1.63E-11<br />

Beryllium<br />

2.37E-12<br />

Page 14 of 53


Hazard Index Estimates (continued)<br />

I'U 1AL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Cobalt<br />

<strong>4.</strong>68E-11<br />

Lead<br />

Sodium<br />

3.28E-11<br />

3.85E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100% CSW-Recreational Dermal Contact with Water<br />

Aluminum 4,5<br />

Cadmium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

8.82E-07 5.00E-06 16, 1 1.76E-01<br />

26<br />

1.03E-06 26<br />

Pathway Total 1.76E-0 1<br />

WAG 1, SWMU 100% RGW-Recreational Ingestion of Fish<br />

Aluminum<br />

Cadmium<br />

5.00E-04 a<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 1, SWMU 100b, CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 5.68E-03 495<br />

Arsenic<br />

3.08E-06 1.23E-04 8 2.5lE-02<br />

Beryllium<br />

3.80E-07 5.OOE-05 13, 1 7.59E-03<br />

Cobalt<br />

<strong>4.</strong>92E-06 26<br />

Lead<br />

5.99E-06 26<br />

Sodium<br />

7.47E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100b, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Arsenic 3.00E-04 a<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

N'AG 1. SWMU 100b, CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

5.86E-04<br />

3.18E-07 3.00E-04 a 1.06E-03<br />

3.91E-08 5.00E-03 a 7.83E-06<br />

5.08E-07<br />

6.18E-07<br />

7.71E-06<br />

Page 15 of 53<br />

3.27E-02<br />

2.25E-01


Hazard Index Estimates (continued)<br />

IUIAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIEhT INDEX INDEX<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100b. CSE-Recreauonal Ingestion of Sediment for Child<br />

1.07E-03<br />

Aluminum<br />

5.47E-03<br />

Arsenic 2.97E-06 3.00E-04 a 9.89E-03<br />

Beryllium 3.65E-07 5.OOE-03 a 7.3 1E-05<br />

Cobalt<br />

<strong>4.</strong>74E-06<br />

Lead<br />

5.76E-06<br />

Sodium<br />

7.19E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 5<br />

Uranium-238<br />

Pathway Total<br />

9.97E-03<br />

WAG 1, SWMU 100b, CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

2.73E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodiuh<br />

1.48E-11<br />

1.83E- 12<br />

2.37E-11<br />

2.88E-11<br />

3.60E- 10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100b, CSW-Recreational Dermal Contact with Water<br />

Alummum<br />

4s<br />

Arsenic<br />

9.29E-08 1.23E-04 8 7.55E-04<br />

Lead<br />

1.80E-06 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

7.55E-04<br />

WAG 1, SWMU 100b, RGW-Recreational Ingestion of Fish<br />

Aluminum<br />

Arsenic 3.00E-04 a<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

<strong>4.</strong>34E-02<br />

WAG 1. SWMU IOOc, CSE-Recreational Ingestion of Deer<br />

Alummum<br />

Arsenic 5.45E-11 3.00E-04 a 1.82E-07<br />

Beryllium 1.64E-12 5.00E-03 a 3.27E-10<br />

Cobalt<br />

Lead<br />

2.01E-11<br />

Sodium<br />

Thallium 9.706-12<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin ketone<br />

Naphthalene 7.91 E- 13 e<br />

Phenanthrene<br />

8.23E-12<br />

Page 16 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

l.82E-07<br />

SWMU Total<br />

1.82E-07<br />

WAG 1, SWMU 136, CSE-Recreahonal Ingestion of Deer<br />

Aluminum<br />

Arsenic<br />

1.38E- 12 3.00E-04 a <strong>4.</strong>59E-09<br />

Beryllium<br />

5.77E- 14 5.00E-03 a 1.15E-I1<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

I,l,l-Trichloroethane<br />

1,1 -Dichloroethene<br />

5.25E-13<br />

3.62E- 13<br />

1.41E- 15<br />

<strong>4.</strong>77E-16 9.00E-03<br />

e<br />

a 5.30E-14<br />

Benzo(a)anthracene<br />

Benzo(a)p yrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(4h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

6.20E-13<br />

1.44E-12<br />

1.5 1 E- 12<br />

2.35E-13<br />

2.97E- 12<br />

<strong>4.</strong>74E-14<br />

Pathway Total<br />

<strong>4.</strong>61E-09<br />

SWMUTO~~~<br />

<strong>4.</strong>61E-09<br />

WAG 1, SWMU 38% CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 2.73E-03 4s<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Vanadium<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

9.49E-07 5.00E-05 13, 1 1.90E-02<br />

5.99E-06 26<br />

5.46E-06 26<br />

2.46E-05<br />

5.77E-05 7.00E-05 58, 5 8.24E-01<br />

1.19E-07 2<br />

Lead<br />

Sodium<br />

Chloroform<br />

1.00E-02 a<br />

bis(2-Ethylhexy1)phthalate<br />

2.00E-02 a<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

WAG 1. SWMU 38% CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

2.8 IE-04<br />

Beryllium 9.78E-08 5.00E-03 a 1.96E-05<br />

Cobalt<br />

6.18E-07<br />

Lead<br />

5.63E-07<br />

Sodium 2.54E-06<br />

Vanadium 5.94E-06 7.00E-03 b 8.49E-04<br />

Phenanthrene<br />

6.12E-09<br />

Gross Alpha<br />

Gross Beta<br />

Page 17 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD<br />

~~<br />

HAZARD<br />

ANALYSIS<br />

CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Pathway Total<br />

8.69E-04<br />

WAG 1, SWMU 38% CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

2.63E-03<br />

Beryllium<br />

9.13E-07 5.00E-03 a 1.83E-04<br />

Cobalt<br />

Lead<br />

Sodium<br />

Vanadium<br />

5.76E-06<br />

5.25E-06<br />

2.37E-05<br />

5.55E-05 7.00E-03 b 7.93E-03<br />

Phenanthrene<br />

5.71E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total 8.11E-03<br />

WAG 1. SWMU 38% CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

1.31E-08<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Vanadium<br />

Phenanthrene<br />

<strong>4.</strong>57E- 12<br />

2.88E-11<br />

2.63E-11<br />

1.18E-10<br />

2.77E- 10<br />

2.85E-13<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38% CSW-Recreational Dermal Contact with Water<br />

Arsenic 7.30E-08 1.23E-04 8 5.93E-04<br />

Lead 3.78E-07 26<br />

Sodium<br />

Chloroform 2.37E-06 2.00E-03 24 1.18E-03<br />

bis(2-Ethylhexy1)phthalate 3.09E-06 3.80E-03 15 8.13E-04<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38q RGW-Recreational Ingestion of Fish<br />

2.59E-03<br />

Arsenic 3.00E-04 a<br />

Lead<br />

Sodium<br />

Chloroform<br />

1.00E-02 a<br />

bis(2-Ethylhexy1)phthalate<br />

2.00E-02 a<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU- Total<br />

8.53E-01<br />

WAG 1. SWMU 38b, CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 5.27E-03 <strong>4.</strong>5<br />

Arsenic<br />

2.14E-06 1.23E-04 8 1.74E-02<br />

Beryllium<br />

2.79E-07 5.00E-05 13, 1 5.58E-03<br />

Cobalt<br />

3.97E-06 26<br />

Lead<br />

1.08E-05 26<br />

Sodium<br />

<strong>4.</strong>18E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

2.29E-02<br />

WAG 1, SWMU 38b, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Page 18 of 53


Hazard Index Estimates (continued)<br />

IWlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

WAG 1. SWMU 38b, CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum 5.43 E-04<br />

Arsenic 2.20E-07 3.00E-04 a 7.34E-04<br />

Beryllium 2.87E-08 5.00E-03 a 5.75E-06<br />

Cobalt<br />

<strong>4.</strong>10E-07<br />

Lead<br />

l.llE-06<br />

Sodium<br />

<strong>4.</strong>31E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

7.40E-04<br />

WAG 1, SWMU 38b, CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

5.07E-03<br />

Arsenic 2.05E-06 3.00E-04 a 6.85E-03<br />

Beryllium 2.68E-07 5.00E-03 a 5.37E-05<br />

Cobalt<br />

3.82E-06<br />

Lead<br />

1.04E-05<br />

Sodium<br />

<strong>4.</strong>02E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

6.90E-03<br />

WAG 1, SWMU 38b, CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

2.54E-08<br />

Arsenic<br />

1.03E-11<br />

Beryllium 1.34E- 12<br />

Cobalt<br />

1.9lE-11<br />

Lead<br />

5.20E-11<br />

Sodium<br />

2.01E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38b, CSW-Recreational Dermal Contact with Water<br />

Aluminum 495<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

WAG 1. SWMU 38b, RGW-Recreational Ingestion of Fish<br />

Aluminum<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

2.98E-02<br />

WAG 1, SWMU 38c, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Arsenic 2.12E-IO 3.00E-04 a 7.08E-07<br />

Beryllium 6.63E-12 5.00E-03 a 1.33E-09<br />

Page 19 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Lead<br />

8.91E-11<br />

Sodium<br />

Thallium<br />

6.72E-11<br />

2-Hexanone<br />

Aroclor- 1260 2.24E- 10<br />

Benzo(a)anthracene <strong>4.</strong>47E- 11<br />

Benzo(a)p yrene<br />

8.46E-11<br />

Benzo(h)fluoranthene<br />

1.24E-10<br />

Phenanthrene<br />

1.59E-11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

7.10E-07<br />

S WMU Total<br />

7.10E-07<br />

WAG 7, SWMU 130, CSE-Recreational Ingestion of Deer<br />

Lead<br />

2.63E-13<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7. SWMU 131, CSE-Recreational Ingestion of Deer<br />

Lead 5.03E- 14<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7. SWMU 132, CSE-Recreational Ingestion of Deer<br />

Lead<br />

<strong>4.</strong>12E-12<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

R’AG 7, SWMU 133, CSE-Recreational Ingestion of Deer<br />

Lead<br />

<strong>4.</strong>78E-12<br />

Acenaphthylene<br />

Benzo( a)anthracene<br />

5.98E-12<br />

Benzo( a)pyrene<br />

9.80E-12<br />

Benzo(h)fluoranthene<br />

1.06E-11<br />

Benzo( g.h,i)perylene<br />

Benzo(k)fluoranthene<br />

8.81E-12<br />

Dihenzo(a,h)anthracene<br />

3.35E-13<br />

Indeno( 1,2.3-cd)pyrene 1.10E-11<br />

Phenanthrene<br />

1.14E-12<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7. SWMU 134, CSE-Recreational Ingestion of Deer<br />

Lead<br />

7.67E-13<br />

Benzo(a)anthracene 2.04E- 13<br />

Benzo( a)pyrene<br />

<strong>4.</strong>16E-13<br />

Benzo(b)fluoranthene<br />

6.20E-13<br />

Benzo( g.h,i)perylene<br />

Phenanthrene<br />

9.62E-14<br />

Gross Alpha<br />

Gross Beta<br />

Page 20 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 8% CSE-Recreational Dermal Contact with Sedunent<br />

Alummum 2.38E-03 4,5<br />

Arsenic<br />

5.05E-06 1.23E-04 8 <strong>4.</strong>10E-02<br />

Beryllium<br />

5.33E-07 5.OOE-05 13, 1 1.07E-02<br />

Cobalt<br />

9.03E-06 26<br />

Lead<br />

6.77E-06 26<br />

Sodium<br />

7.88E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

5.17E-02<br />

WAG 7, SWMU 8a, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Cobalt<br />

Iron<br />

Lead<br />

Manganese<br />

Nickel<br />

Phosphate (oriho)<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

Tungsten<br />

Vanadium<br />

Zirconium<br />

1,l -Dichloroethene<br />

1,2-Dichioroethene<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anihracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Methylene Chloride<br />

Naphthalene<br />

Phenanthrene<br />

Trichloroethene<br />

his(2-Ethylhexy1)phthalate<br />

cis- 1,2-Dichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

3.46E-09<br />

3.51E-09<br />

3.07E-07<br />

7.95E-08<br />

1.84E-09<br />

<strong>4.</strong>38E-06<br />

6.80E-05<br />

8.22E-06<br />

5.31E-05<br />

<strong>4.</strong>45E-06<br />

1.45E-11<br />

6.60E-12<br />

3.85E-09<br />

1.23E-09<br />

3.91E-09<br />

<strong>4.</strong>42E-09<br />

8.16E-09<br />

9.96E-11<br />

3.44E-10<br />

3.26E-13<br />

8.38E-12<br />

<strong>4.</strong>00E-04<br />

3.00E-04<br />

7.00E-02<br />

5.OOE-03<br />

5.OOE-04<br />

5.00E-03<br />

2.00E-02<br />

7.00E-03<br />

9.00E-03<br />

9.00E-03<br />

6.00E-02<br />

2.00E-02<br />

1.00E-02<br />

a<br />

a<br />

a<br />

a<br />

a<br />

a<br />

a<br />

b<br />

a<br />

b<br />

a<br />

e<br />

8.64E-06<br />

1.17E-05<br />

<strong>4.</strong>39E-06<br />

1.59E-05<br />

3.67E-06<br />

1.36E-02<br />

<strong>4.</strong>11E-04<br />

6.36E-04<br />

1.61E-09<br />

7.34E-10<br />

a 1.63E-11<br />

b 8.38E- 10<br />

WAG 7, SWMU 8a, CSE-RecreAonal Ingesbon of Sedunent for Adult<br />

Alummum<br />

2.46E-04<br />

Arsenic 5.20E-07 3.00E-04 a 173E-03<br />

Page21 of53<br />

1.47E-02


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Beryllium 5.49E-08 5.OOE-03 a 1.10E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

9.31E-07<br />

6.98E-07<br />

8.12E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.75E-03<br />

WAG 7, SWMU 8a, CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

2.29E-03<br />

Arsenic <strong>4.</strong>86E-06 3.00E-04 a 1.62E-02<br />

Beryllium 5.12E-07 5.00E-03 a 1 .O2E-04<br />

Cobalt<br />

8.69E-06<br />

Lead<br />

6.51E-06<br />

Sodium<br />

7.58E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.63E-02<br />

WAG 7. SWMU 8a, CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

1.15E-08<br />

Arsenic<br />

2.43E-11<br />

Beryllium<br />

2.56E-12<br />

Cobalt<br />

<strong>4.</strong>34E-11<br />

Lead 3.26511<br />

Sodium 3.79E- 10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 8% CSW-Recreational Dermal Contact with Water<br />

Aluminum <strong>4.</strong>5<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Cobalt<br />

Iron<br />

Lead<br />

Manganese<br />

Nickel<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Tantalum<br />

lkallium<br />

Tungsten<br />

Vanadium<br />

Zirconium<br />

1,l -Dichloroethene<br />

1,2-Dichloroethene<br />

Methylene Chloride<br />

Trichloroethene<br />

bis(2-Ethy1hexyl)phthalate<br />

cis- 1.2-Dichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Xeptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-238<br />

1.24E-06<br />

7.46E-08<br />

2.80506<br />

2.08E-07<br />

1.59E-07<br />

2.3 1E-05<br />

1.16E-03<br />

3.31E-06<br />

3.58E-05<br />

1.59E-07<br />

1.95E-07<br />

8.44E-07<br />

1.09E-07<br />

1.54E-07<br />

1.43E-06<br />

8.00E-06 7<br />

1.23E-04 8<br />

<strong>4.</strong>90E-03 9<br />

5.00E-05 13, 1<br />

5.00E-06 16, 1<br />

26<br />

26<br />

26<br />

2.00E-04 38<br />

5.40E-03 44<br />

52<br />

7.00E-05 58, 5<br />

12<br />

9.00E-03 31<br />

9.00E-03<br />

5.70E-02 41<br />

57<br />

3.80E-03 15<br />

1 .OOE-02 83<br />

Page 22 of 53<br />

1.55E-01<br />

6.07E-04<br />

5.71E-04<br />

<strong>4.</strong>1 5E-03<br />

3.19E-02<br />

5.82E+00<br />

6.14E-04<br />

5.12E-0 1<br />

1.77E-05<br />

2.17E-05<br />

1.48E-05<br />

<strong>4.</strong>06E-05<br />

1.43E-04


Hazard Index Estimates (continued)<br />

-<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Pathway Total<br />

6.52E-tOO<br />

WAG 7, SWMU 8% RGW-Recreational Ingestion of Fish<br />

Aluminum<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Cobalt<br />

Iron<br />

Lead<br />

Manganese<br />

Nickel<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

Tungsten<br />

Vanadium<br />

Zirconium<br />

1, I-Dichloroethene<br />

1,2-DichIoroethene<br />

Methylene Chloride<br />

1.71E-04<br />

1.20E-05<br />

<strong>4.</strong>82E-05<br />

1.04E-04<br />

5.66E-01<br />

1.27E-03<br />

5.1 IE-04<br />

1.75E-06<br />

<strong>4.</strong>00E-04<br />

3.00E-04<br />

7.00E-02<br />

5.00E-03<br />

5.00E-04<br />

5.00E-03<br />

2.00E-02<br />

7.00E-03<br />

9.00E-03<br />

9.00E-03<br />

6.00E-02<br />

a<br />

a<br />

a<br />

a<br />

a<br />

a<br />

a<br />

b<br />

a<br />

b<br />

a<br />

<strong>4.</strong>27E-01<br />

<strong>4.</strong>01E-02<br />

9.64E-02<br />

1.13E+02<br />

7.30E-02<br />

2.91E-05<br />

Trichloroethene<br />

bis(2-Ethylhexy1)phthalate<br />

cis- 1,2-Dichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-238<br />

2.00E-02<br />

1.00E-02<br />

a<br />

b<br />

Pathway Total<br />

1.14E+02<br />

SWMU Total<br />

1.20E+02<br />

WAG 1, SWMU 100% ESE-Excavation Dermal Contact with Sediment<br />

Aluminum 2.89E-03 4s<br />

Arsenic 1.34E-06 1.23E-04 8 1.09E-02<br />

Beryllium 1.95E-07 5.00E-05 13, 1 3.90E-03<br />

Cobalt 3.85E-06 26<br />

Lead 2.70E-06 26<br />

Sodium<br />

3.17E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.48E-02<br />

WAG 1, SWMU 100% ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

<strong>4.</strong>62E-03<br />

2.14E-06 3.00E-04 a 7.14E-03<br />

3.12E-07 5.00E-03 a 6.24E-05<br />

6.16E-06<br />

<strong>4.</strong>32E-06<br />

5.07E-05<br />

Pathway Total<br />

WAG 1. SWMU 100% ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

7.01E-08<br />

Arsenic<br />

3.25E-11<br />

Beryllium<br />

<strong>4.</strong>73E-12<br />

Cohalt<br />

9.35E-11<br />

Page 23 of 53<br />

7.20E-03


Hazard Index Estimates (continued)<br />

I u I'AL<br />

PATHWAY EXPOSURE<br />

REFERENCE FWD HAZARD HAZARD HAZARD<br />

ANALYSIS<br />

Lead<br />

CDI<br />

6.56E-11<br />

DOSE SOURCE QUOTIENT INDEX INDEX<br />

Sodium<br />

7.70E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU-Total<br />

2.20E-02<br />

WAG 1, SWMU 100b, ESE-Excavation Dermal Contact with Sediment<br />

Aluminum 2.25E-03 4s<br />

Arsenic 1.22E-06 1.23E-04 8 9.93E-03<br />

Beryllium 1.50E-07 5.00E-05 13, 1 3.01E-03<br />

Cobalt 1.95E-06 26<br />

Lead 2.37E-06 26<br />

Sodium<br />

2.96E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-23 8<br />

Pathway Total<br />

1.29E-02<br />

WAG 1, SWMU 100b, ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

3.60E-03<br />

Arsenic<br />

1.95E-06 3.00E-04 a 6.51E-03<br />

Beryllium<br />

2.40E-07 5.OOE-03 a <strong>4.</strong>81E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

3.12E-06<br />

3.79E-06<br />

<strong>4.</strong>73E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

6.56E-03<br />

WAG 1, SWMU 100b, ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

5.46E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

2.96E-11<br />

3.65E-12<br />

<strong>4.</strong>73E-11<br />

5.76E-11<br />

7.18E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 1, SWMU IOOc, ESO-Excavation Dermal Contact with Soil<br />

1.95E-02<br />

Aluminum<br />

Arsenic<br />

2.47E-03<br />

1.48E-06 1.23E-04<br />

4s<br />

8 1.20E-02<br />

Beryllium<br />

1.32E-07 5.00E-05 13, 1 2.64E-03<br />

Cobalt<br />

2.09E-06 26<br />

Lead<br />

3.05E-06 26<br />

Sodium<br />

Thallium<br />

9.86E-05<br />

1.68E-08 52<br />

2-Methylnaphthalene<br />

1 S5E-07 43<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

Phenanthrene<br />

3.80E-08<br />

5.19E-10<br />

5.35E- 10<br />

9.39E-08<br />

2.58E-07<br />

43<br />

2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thonum-228<br />

Uranium-238<br />

Page 24 of 53


Hazard Index Estimates (continued)<br />

IUIAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Pathway Total<br />

1.46E-02<br />

WAG 1, SWMU lOOc, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

3.95E-03<br />

Arsenic<br />

2.36E-06 3.00E-04 a 7.87E-03<br />

Beryllium<br />

2.1 1E-07 5.00E-03 a <strong>4.</strong>22E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

3.34E-06<br />

<strong>4.</strong>88E-06<br />

1 S8E-04<br />

2.69E-08<br />

1.24E-07<br />

3.04E-08<br />

<strong>4.</strong>15E- 10<br />

<strong>4.</strong>28E-10<br />

7.51E-08<br />

e<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

2.06E-07<br />

' Pathway Total<br />

7.92E-03<br />

WAG 1, SWMU lOOc, ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

6.OOE-08<br />

Arsenic<br />

3.58E-11<br />

Beryllium<br />

3.20E-12<br />

Cobalt<br />

5.06E-11<br />

Lead<br />

7.41E-11<br />

Sodium<br />

2.39E-09<br />

Thallium<br />

<strong>4.</strong>08E-13<br />

2-Methylnaphthalene<br />

1.89E-12<br />

3-Nitroaniline <strong>4.</strong>62E- 13<br />

Endosulfan Sulfate<br />

6.29E-15<br />

Endrin Ketone<br />

6.50E-15<br />

Naphthalene 1.14E- 12<br />

Phenanthrene<br />

3.13E-12<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

2.26E-02<br />

WAG 1. SWMU 136, ESO-Excavation Dermal Contact with Soil<br />

Aluminum 2.59E-03 4s<br />

Arsenic 9.33E-07 1.23E-04 8 7.58E-03<br />

Beryllium 1.16E-07 5.00E-05 13, 1 2.33E-03<br />

Cobalt<br />

2.67E-06<br />

26<br />

Lead<br />

1.99E-06<br />

26<br />

Sodium<br />

7.29E-05<br />

Sulfate<br />

2.28E-04<br />

Thallium 1.57E-08 52<br />

1,l. 1 -Trichloroethane 2.17E-08 55<br />

1,l -Dichloroethene 1.41E-08 9.00E-03 31 1.57E-06<br />

Benzo(a)anthracene 1 .OZE-07 2<br />

Benzo(a)pyrene 1.09E-07 2<br />

Benzo(b)fluoranthene 1.14E-07 2<br />

Benzo(g,h,i)perylene 9.62E-08 2<br />

Dibenzo(a,h)anthracene 3.80E-08 2<br />

Indeno( 1,2,3-cd)pyrene 9.84E-08 2<br />

Phenanthrene 3.71E-08 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Page 25 of 53


Hazard Index Estimates (continued)<br />

lUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Pathway Total<br />

9.91E-03<br />

WAG 1. SWMU 136. ESO-Excavation Ineestion of Soil<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1.1,1 -Trichloroethane<br />

1,l-Dichloroethene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.49E-06 3.00E-04 a <strong>4.</strong>97E-03<br />

1.86E-07 5.00E-03 a 3.73E-05<br />

<strong>4.</strong>27E-06<br />

3.19E-06<br />

1.17E-04<br />

3.65E-04<br />

2.5 1E-08<br />

6.95E-09<br />

e<br />

<strong>4.</strong>51E-09 9.00E-03 a 5.01E-07<br />

8.17E-08<br />

8.71E-08<br />

9.13E-08<br />

7.70E-08<br />

3.04E-08<br />

7.87E-08<br />

2.97E-08<br />

Pathway Total 5.01E-03<br />

WAG 1, SWMU 136, ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

6.30E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

?ballium<br />

1,l. 1 -Trichloroethane<br />

1,l -Dichloroethene<br />

Benzo( a)anthracene<br />

Benzo(a)p yrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.26E-11<br />

2.83E-12<br />

6.48E- 11<br />

<strong>4.</strong>84E-11<br />

1.77E-09<br />

5.54E-09<br />

3.81E- 13<br />

2.70E-08<br />

<strong>4.</strong>65E-08<br />

1.24E-12<br />

1.32E-12<br />

1.38E- 12<br />

1.17E- 12<br />

<strong>4.</strong>62E-13<br />

1.19E- 12<br />

<strong>4.</strong>50E- 13<br />

e<br />

Beryllium 3.76E-07 5.00E-05 13, 1 7.51E-03<br />

Cobalt 2.37E-06 26<br />

Lead 2.16E-06 26<br />

Sodium<br />

9.75E-06<br />

Vanadium 2.28E-05 7.00E-05 58, 5 3.26E-01<br />

Phenanthrene <strong>4.</strong>70E-08 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

U'AG 1. SWMU 38% ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

1.73E-03<br />

Beryllium 6.01E-07 5.OOE-03 a 1.20E-04<br />

Cobalt<br />

3.79E-06<br />

Lead<br />

3.46E-06<br />

3.34E-01<br />

Page 26 of 53


~~ ~<br />

Hazard Index Estimates (continued)<br />

I'Ul'AL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Sodium<br />

1.56E-05<br />

Vanadium<br />

3.65E-05 7.00E-03 b 5.22E-03<br />

Phenanthrene<br />

3.76E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

5.34E-03<br />

WAG 1, SWMU 38% ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Vanadium<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.62E-08<br />

9.12E-12<br />

5.76E-11<br />

5.24E-11<br />

2.37E-10<br />

5.54E-10<br />

5.70E- 13<br />

S WMU Total 3.39E-0 1<br />

WAG 1, SWMU 38b, ESE-Excavation Dermal Contact with Sediment<br />

Aluminum 2.09E-03 4s<br />

Arsenic 8.45E-07 1.23E-04 8 6.87E-03<br />

Beryllium l.lOE-07 5.00E-05 13, 1 2.21E-03<br />

Cobalt 1.57E-06 26<br />

Lead <strong>4.</strong>27E-06 26<br />

Sodium<br />

1.65E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

9.08E-03<br />

WAG 1, SWMU 38b, ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

3.34E-03<br />

Arsenic<br />

1.35E-06 3.00E-04 a <strong>4.</strong>5 IE-03<br />

Beryllium<br />

1.77E-07 5.00E-03 a 3.53E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

2.52E-06<br />

6.84E-06<br />

2.65E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total <strong>4.</strong>546-03<br />

WAG 1, SWMU 38b, ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

5.06E-08<br />

Arsenic<br />

2.05E-11<br />

Beryllium<br />

2.68E-12<br />

Cobalt<br />

3.82E-11<br />

Lead 1.04E- 10<br />

Sodium <strong>4.</strong>0 1E- 10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 8<br />

Pathway Total<br />

SWMU Total<br />

1.36E-02<br />

WAG 1, SWMU 38c, ESO-Excavation Dermal Contact with Soil<br />

Aluminum 2.14E-03 4s<br />

Arsenic<br />

1.38E-06 3.23E-04 8 l.12E-02<br />

Beryllium<br />

1.28E-07 5.00E-05 13, 1 2.56E-03<br />

Cobalt<br />

2.21E-06 26<br />

Lead<br />

3.24E-06 26<br />

Sodium<br />

Thallium<br />

<strong>4.</strong>66E-05<br />

2.78E-08 52<br />

2-Hexanone<br />

1.17E-08 36<br />

Page 27 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Ar0clor-126O 1.87E-08 46<br />

Benzo(a)anthracene<br />

7.05E-08<br />

Benzo(a)pyrene 6.11E-08<br />

Benzo(b)fluoranthene<br />

8.92E-08<br />

Phenanthrene<br />

1.19E-07<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-23 7<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.37E-02<br />

WAG 1, SWMU 38c, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

3.42E-03<br />

Arsenic 2.20E-06 3.00E-04 a 7.33E-03<br />

Beryllium 2.05E-07 5.00E-03 a <strong>4.</strong>09E-05<br />

Cobalt<br />

3.54E-06<br />

Lead<br />

5.18E-06<br />

Sodium<br />

7.46E-05<br />

Thallium<br />

<strong>4.</strong>46E-08<br />

2-Hexanone<br />

3.76E-09<br />

Aroclor- 1260<br />

1.5OE-08<br />

Benzo(a)anthracene 5.64E08<br />

Benzo(a)pyrene<br />

<strong>4.</strong>88E-08<br />

Benzo(b)fluoranthene<br />

7.14E-08<br />

Phenanthrene<br />

9.50E-08<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-23 8<br />

Pathway Total<br />

7.38E-03<br />

WAG 1, SWMU 38c, ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

5.19E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

3.34E-11<br />

3.1 OE- 12<br />

5.37E-11<br />

7.86E-11<br />

1.13E-09<br />

6.76E-13<br />

5.70E- 14<br />

2.27E-13<br />

8.55E-13<br />

7.41 E- 13<br />

1.08E-12<br />

1.44E- 12<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWW-Total 2.1 1E-02<br />

WAG 7, SWMU 130, ESO-Excavation Dermal Contact with Soil<br />

Lead 2.65E-06 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, ESO-Excavation Ingestion of Soil<br />

1 asd 4 25F-06<br />

Page 28 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, ESO-Excavation Inhalation of Soil<br />

Lead 6.44E- 11<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 131, ESO-Excavation Dermal Contact with Soil<br />

Lead <strong>4.</strong>67E-06 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 131, ESO-Excavation Ingestion of Soil<br />

Lead<br />

7.48E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 131, ESO-Excavation Inhalation of Soil<br />

Lead<br />

1.13E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7. SWMU 132, ESO-Excavation Dermal Contact with Soil<br />

Lead 2.75E-05 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, ESO-Excavation Ingestion of Soil<br />

Lead<br />

<strong>4.</strong>41E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, ESO-Excavation Inhalation of Soil<br />

Lead<br />

6.69E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU- Total<br />

WAG 7, 7. SWMU 133, 133. ESO-Excavation Dermal Contact with Soil<br />

Lead 3.80E-05 26<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo( g.h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

2.75E-07<br />

2.06E-06<br />

1.55E-06<br />

1.67E-06<br />

9.21E-07<br />

1.39E-06<br />

1.14E-07<br />

7.63E-07<br />

1.87E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Page 29 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Pathway Total<br />

WAG 7, SWMU 133, ESO-Excavation Ingestion of Soil<br />

Lead<br />

6.09E-05<br />

Acenaphthylene<br />

2.20E-07<br />

Benzo(a)anthracene<br />

1.65E-06<br />

Benzo(a)pyrene<br />

1.24E-06<br />

Benzo(b)fluoranthene<br />

1.34E-06<br />

Benzo(g,h,i)perylene<br />

7.37E-07<br />

Benzo(k)fluoranthene 1 .I 1E-06<br />

Dibenzo(a,h)anthracene 9.10E-08<br />

Indene( 1,2,3-cd)pyrene 6.11E-07<br />

Phenanthrene<br />

1.49E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 133, ESO-Excavation Inhalation of Soil<br />

Lead<br />

9.23E-10<br />

Acenaphthylene<br />

3.34E-12<br />

Benzo(a)anthracene<br />

2.50E-11<br />

Benzo(a)pyrene<br />

1.88E-11<br />

Benzo(b)fluoranthene<br />

2.03E-11<br />

Benzo(g,h,i)perylene 1.12E- 11<br />

Benzo(k)fluoranthene<br />

1.69E-11<br />

Dibenzo(a,h)anthracene 1.38E- 12<br />

Indeno( 1,2,3-cd)pyrene 9.26E-12<br />

Phenanthrene<br />

2.26E-11<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7, SWMU 134, ESO-Excavation Demal Contact with Soil<br />

Lead 6.1 1E-06 26<br />

Benzo(a)anthracene<br />

7.05E-08<br />

Benzo(a)pyrene<br />

6.58E-08<br />

Benzo(b)fluoranthene<br />

9.81E-08<br />

Benzo(g,h,i)perylene<br />

3.48E-08<br />

Phenanthrene<br />

1.58E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, ESO-Excavation Ingestion of Soil<br />

Lead<br />

9.77E-06<br />

Benzo(a)anthracene<br />

5.64E-08<br />

Benzo(a)pyrene<br />

5.26E-08<br />

Benzo(b)fluoranthene<br />

7.85E-08<br />

Benzo(g,h,i)perylene<br />

2.78E-08<br />

Phenanthrene<br />

1.26E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7, SWMU 134, ESO-Excavation Inhalation of Soil<br />

Lead 1.48E- 10<br />

Benzo( a)anthracene<br />

8.55E-13<br />

Benzo(a)pyrene<br />

7.98E-13<br />

Benzo(b)fluoranthene<br />

1.19E-12<br />

Benzo(g,h,i)perylene <strong>4.</strong>22E- 13<br />

Phenanthrene<br />

1.92E-12<br />

Gross Alpha<br />

Gross Beta<br />

Page 30 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX R\IDEX<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 8b, ESO-Excavation Dermal Contact with Soil<br />

Aluminum 2.55E-03 4s<br />

Arsenic 9.51E-07 1.23E-04 8 7.73E-03<br />

Beryllium 1.63E-07 5.00E-05 13, 1 3.27E-03<br />

Cobalt 1.81E-06 26<br />

Lead 2.34E-06 26<br />

Phosphate (ortho)<br />

1.34E-05<br />

Sodium<br />

2.55E-05<br />

Thallium 3.63E-08 52<br />

2-Methylnaphthalene 5.64E-08 43<br />

Aroclor-1260 1.34E-08 46<br />

Benzo( a)anthracene 8.11E-08 2<br />

Benzo(a)pyrene 1.18E-07 2<br />

Benzo(b)fluoranthene 1.33E-07 2<br />

Dihenzohran<br />

1.16E-07<br />

Indeno( 1,2,3-cd)pyrene 1.08E-07 2<br />

Naphthalene 1.18E-07 43<br />

Phenanthrene 1.08E-07 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thonum-228<br />

Thonum-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

l.lOE-02<br />

WAG 7, SWMU 8h, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

<strong>4.</strong>08E-03<br />

Arsenic 1.52E-06 3.00E-04 a 5.07E-03<br />

Beryllium 2.62E-07 5.00E-03 a 5.23E-05<br />

Cobalt<br />

2.90E-06<br />

Lead<br />

3.74E-06<br />

Phosphate (ortho)<br />

2.14E-05<br />

Sodium <strong>4.</strong>08B05<br />

Thallium 5.81 E-08<br />

2-Methylnaphthalene<br />

<strong>4.</strong>51E-08<br />

Aroclor- 1260<br />

1.07E-08<br />

Benzo(a)anthracene<br />

6.49E-08<br />

Benzo(a)p yrene<br />

9.44E-08<br />

Benzo(h)fluoranthene<br />

1.07E-07<br />

Dibenzofuran<br />

9.25E-08<br />

Indeno( 1,2,3-cd)pyrene 8.64E-08<br />

Naphthalene<br />

9.46E-08<br />

e<br />

Phenanthrene<br />

8.62E-08<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

Arsenic<br />

2.31E-11<br />

Beryllium<br />

3.97E-12<br />

Cobalt <strong>4.</strong>40E- 11<br />

Lead<br />

5.68E-11<br />

Phosphate (ortho)<br />

3.25E-10<br />

Sodium<br />

6.19E-10<br />

Page 31 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Thallium<br />

8.81E-13<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

6.84E- 13<br />

1.63E-13<br />

9.85E-13<br />

1.43E-12<br />

1.62E-12<br />

1.40E- 12<br />

1.31E-12<br />

1.43E-12<br />

1.31E-12<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S W MU Total<br />

1.61E-02<br />

WAG 1, SWMU 100% ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 2.01E-03 4s<br />

Arsenic 9.30E-07 1.23E-04 8 7.56E-03<br />

Beryllium 1.35E-07 5.00E-05 13, 1 2.71E-03<br />

Cobalt 2.68E-06 26<br />

Lead 1.88E-06 26<br />

Sodium<br />

2.20E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.03E-02<br />

WAG 1, SWMU 100% ISE-Current Industrial Ingestion of Sediment<br />

Aluminurn<br />

1.96E-03<br />

Arsenic<br />

9.06E-07 3.00E-04 a 3.02E-03<br />

Beryllium<br />

1.32E-07 5.00E-03 a 2.64E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

2.61E-06<br />

1.83E-06<br />

2.15505<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.05E-03<br />

WAG 1, SWMU 100% ISE-Current Industrial Inhalation of Sediment<br />

Aluminum<br />

1.83E-07<br />

Arsenic<br />

8.46E-11<br />

Beryllium<br />

1.23E-11<br />

Cobalt<br />

2.43E-10<br />

Lead<br />

1.71E-10<br />

Sodium<br />

2.00E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100% ISW-Current Industrial Dermal Contact with Water<br />

Aluminum 495<br />

Cadmium 1.04506 5.00E-06 16, 1 2.08E-01<br />

Cobalt 26<br />

Lead 1.22E-06 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

2.08E-01<br />

Page 32 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

S WMU Total 2.22E-0 1<br />

WAG 1, SWMU 100b, ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 1.56E-03 4,5<br />

Arsenic<br />

8.49E-07 1.23E-04 8 6.90E-03<br />

Beryllium<br />

1.04E-07 5.00E-05 13, 1 2.09E-03<br />

Cobalt<br />

1.35E-06 26<br />

Lead<br />

1.65E-06 26<br />

Sodium<br />

2.06E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

8.99E-03<br />

WAG 1, SWMU 100h, ISE-Current Industrial Ingestion of Sediment<br />

Aluminum<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

1.52E-03<br />

8.27E-07 3.00E-04 a 2.76E-03<br />

1.02E-07 5.00E-03 a 2.04E-05<br />

1.32E-06<br />

1.61E-06<br />

2.00E-05<br />

Pathway Total<br />

WAG 1, SWMU 100b, ISE-Current Industrial Inhalation of Sediment<br />

Aluminum<br />

1.42E-07<br />

Arsenic 7.72E- 11<br />

Beryllium 9.50E- 12<br />

Cobalt 1.23E- 10<br />

Lead 1. SOE- 10<br />

Sodium<br />

1.87E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-23 8<br />

Pathway Total<br />

WAG 1, SWMU 100b, ISW-Current Industrial Dermal Contact with Water<br />

Aluminum 4,5<br />

Arsenic l.lOE-07 1.23E-04 8 8.92E-04<br />

Lead 2.12E-06 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 1. SWMU lOOc, ISO-Current Industrial Dermal Contact with Soil<br />

Aluminum 9.05E-04 4,5<br />

Arsenic 6.22E-07 1.23E-04 8 5.06E-03<br />

Beryllium <strong>4.</strong>80E-08 5.00E-05 13, 1 9.60E-04<br />

Cohalt 7.23E-07 26<br />

Lead 1.93E-06 26<br />

Sodium<br />

1.70E-05<br />

3-Nitroaniline<br />

1.79E-08<br />

Gross Alpha<br />

Gross Beta<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

Page 33 of 53<br />

2.78E-03<br />

8.92E-04<br />

6.02E-03<br />

1.27E-02


Hazard Index Estimates (continued)<br />

IUlAL<br />

EXPOSURE<br />

PATHWAY<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 1, SWMU IOOc, ISO-Current Industrial Ingestion of Soil<br />

Aluminum 8.81E-04<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

3-Nitroaniline<br />

Gross Alpha<br />

Gross Beta<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

6.06E-07 3.00E-04 a 2.02E-03<br />

<strong>4.</strong>68E-08 5.00E-03 a 9.35E-06<br />

7.04E-07<br />

1.88E-06<br />

1.65E-05<br />

8.72E-09<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sod&<br />

3-Nitroaniline<br />

5.66E-11<br />

<strong>4.</strong>36E-12<br />

6.57E-11<br />

1.75E-I0<br />

1.54E-09<br />

8.14E- 13<br />

Gross Alpha<br />

Gross Beta<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 1, SWMU 136, ISO-Current Industrial Dermal Contact with Soil<br />

Aluminum 3.2OE-05 4s<br />

Arsenic<br />

2.70E-08 1.23E-04 8 2.19E-04<br />

Beryllium<br />

1.90E-09 5.00E-05 13, 1 3.80E-05<br />

Cobalt<br />

Lead<br />

1.19E-07<br />

2.87E-08<br />

26<br />

26<br />

Sodium<br />

3.83E-07<br />

Sulfate<br />

<strong>4.</strong>30E-06<br />

Thallium<br />

6.19E-10<br />

52<br />

Benzo(a)anthracene<br />

3.36E-09<br />

2<br />

Benzo(a)pyrene<br />

<strong>4.</strong>60E-09<br />

2<br />

Benzo(b)fluoranthene<br />

5.66E-09<br />

2<br />

Benzo( g,h,i)perylene<br />

2.39E-09<br />

2<br />

Dibenzo(qh)anthracene 7.16E-10<br />

2<br />

Indeno( 1,2,3-cd)pyrene 2.74E-09<br />

2<br />

Phenanthrene<br />

6.98E-10<br />

2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

8.05E-03<br />

Arsenic 2.63E-08 3.00E-04 a 8.75E-05<br />

Beryllium 1.85E-09 5.00E-03 a 3.70E-07<br />

Cobalt<br />

1.16E-07<br />

Lead<br />

2.80E-08<br />

Sodium<br />

3.73E-07<br />

Sulfate<br />

<strong>4.</strong>18E-06<br />

Thallium<br />

6.03E-10<br />

Benzo(a)anthracene<br />

1.64E-09<br />

Benzo(a)pyrene<br />

2.24E-09<br />

Benzo(b)fluoranthene<br />

2.76E-09<br />

Benzo(g,h,i)perylene<br />

1.16E-09<br />

Dibenzo( ah)anthracene 3.49E- 10<br />

Page 34 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Indeno( 1,2,3-cd)pyrene 1.33E-09<br />

Phenanthrene 3.40E- 10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

8.79E-05<br />

WAG 1, SWMU 136, ISO-Current Industrial Inhalation of Soil<br />

Aluminum 2.91E-09<br />

Arsenic<br />

2.45E-12<br />

Beryllium<br />

1.73E-13<br />

Cobalt<br />

1.09E-11<br />

Lead<br />

2.61E-12<br />

Sodium<br />

3.48E-11<br />

Sulfate 3.91E- 10<br />

Thallium<br />

5.63E-14<br />

Benzo( a)anthracene<br />

1.53E-13<br />

Benzo(a)pyrene<br />

2.09E-13<br />

Benzo(b)fluoranthene<br />

2.57E-13<br />

Benzo(g,h,i)perylene<br />

1.09E-13<br />

Dibenzo(qh)anthracene 3.26E-14<br />

' Indeno( 1,2,3-cd)pyrene 1.25E-13<br />

Phenanthrene<br />

3.18E-14<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

3.45E-04<br />

WAG 1, SWMU 38% ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 7.51E-04 4s<br />

Beryllium 2.61E-07 5.00E-05 13, 1 5.22E-03<br />

Cobalt 1.65E-06 26<br />

Lead 1.50E-06 26<br />

Sodium<br />

6.77E-06<br />

Vanadium 1.59E-05 7.00E-05 58, 5 2.27E-01<br />

Phenanthrene 3.26E-08 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total 2.32E-0 1<br />

WAG 1, SWMU 38% ISE-Current Industrial Ingestion of Sediment<br />

Aluminum 7.31E-04<br />

Beryllium 2.54E-07 5.OOE-03 a 5.09E-05<br />

Cobalt<br />

1.61E-06<br />

Lead<br />

1.46E-06<br />

Sodium<br />

6.60E-06<br />

Vanadium 1.55E-05 7.00E-03 b 2.2 IE-03<br />

Phenanthrene<br />

1.59E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.26E-03<br />

WAG 1. SWMU 38% ISE-Current Industrial Inhalation of Sediment<br />

Aluminum<br />

6.83E-08<br />

Beryllium<br />

2.38E-11<br />

Cobalt<br />

1.50E-I0<br />

Lead<br />

1.37E-10<br />

Sodium 6.16E- 10<br />

Vanadium<br />

1.44E-09<br />

Phenanthrene<br />

1.48E-12<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

Page 35 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 1, SWMU 38% ISW-Current Industrial Dermal Contact with Water<br />

Arsenic 8.62E-08 1.23E-04 8 7.01E-04<br />

Lead <strong>4.</strong>47E-07 26<br />

Sodium<br />

Chloroform 2.80E-06 2.00E-03 24 1.40E-03<br />

bis(2-Ethylhexy1)phthalate 3.65E-06 3.80E-03 15 9.60E-04<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.06E-03<br />

S WMU Total<br />

2.37E-01<br />

WAG 1, SWMU 38b, ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 1.45E-03 475<br />

Arsenic<br />

5.88E-07 1.23E-04 8 <strong>4.</strong>78E-03<br />

Beryllium<br />

7.67E-08 5.00E-05 13, 1 1 S3E-03<br />

Cobalt<br />

1.09E-06 26<br />

Lead<br />

2.97E-06 26<br />

Sodium<br />

1.15E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total 6.31E-03<br />

WAG 1, SWMU 38b, ISE-Current Industrial Ingestion of Sediment<br />

Aluminum 1.41E-03<br />

Arsenic<br />

5.72E-07 3.00E-04 a 1.91E-03<br />

Beryllium<br />

7.47E-08 5.00E-03 a 1.49E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

1.07E-06<br />

2.89E-06<br />

1.12E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.92E-03<br />

WAG 1, SWMU 38b, ISE-Current Industrial Inhalation of Sediment<br />

Aluminum<br />

1.32E-07<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

5.34E-11<br />

6.98E-12<br />

9.95E- 11<br />

2.70E-10<br />

1.05E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38b, ISW-Current Industrial Dermal Contact with Water<br />

Aluminum <strong>4.</strong>5<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

8.24E-03<br />

WAG 1, SWMU 38c, ISO-Current Industrial Dermal Contact with Soil<br />

Alummum 5.42E-03 4s<br />

Arsenic 3.18E-06 1.23E-04 8 2.59E-02<br />

Beryllium 2.65E-07 5.00E-05 13, 1 5.30E-03<br />

Cobalt <strong>4.</strong>91E-06 26<br />

Lead 9.68E-06 26<br />

Sodium<br />

<strong>4.</strong>35E-05<br />

Aroclor-1260 <strong>4.</strong>36E-08 46<br />

Page 36 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Benzo(a)anthracene 1.39E-07 2<br />

Benzo(a)pyrene<br />

1.20E-07<br />

2<br />

Benzo(b)fluoranthene<br />

1.76E-07<br />

2<br />

Phenanthrene<br />

2.46E-07<br />

2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-23 5<br />

Uranium-238<br />

Pathway Total<br />

3.12E-02<br />

WAG 1, SWMU 38c, ISO-Current Industrial Ingestion of Soil<br />

Aluminum<br />

5.28E-03<br />

Arsenic 3.10E-06 3.00E-04 a 1.03E-02<br />

Beryllium 2.58E-07 5.OOE-03 a 5.16E-05<br />

Cobalt<br />

<strong>4.</strong>78E-06<br />

Lead<br />

9.42E-06<br />

Sodium<br />

<strong>4.</strong>23E-05<br />

Aroclor- 1260<br />

2.12E-08<br />

Benzo(a)anthracene<br />

6.75E-08<br />

Benzo(a)pyrene<br />

5.85E-08<br />

Benzo(b)fluoranthene<br />

8.5SE-08<br />

Phenanthrene<br />

1.20E-07<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.04E-02<br />

WAG 1, SWMU 38c, ISO-Current Industrial Inhalation of Soil<br />

Aluminum<br />

<strong>4.</strong>93E-07<br />

Arsenic 2.89E- 10<br />

Beryllium<br />

2.41E-11<br />

Cobalt<br />

<strong>4.</strong>46E-10<br />

Lead 8.80E- 10<br />

Sodium<br />

3.95E-09<br />

Aroclor-1260<br />

1.98E-12<br />

Benzo(a)anthracene<br />

6.30E-12<br />

Benzo(a)p yrene 5.46E- 12<br />

Benzo(b)fluoranthene<br />

7.98E-12<br />

Phenanthrene<br />

1.12E-11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

<strong>4.</strong>1 SE-02<br />

WAG 7, SWMU 132, ISO-Current Industrial Dermal Contact with Soil<br />

Lead 3.47E-07 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7. SWMU 132, ISO-Current Industnal Ingesbon of Soil<br />

Lead<br />

3.38E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, ISO-Current Industrial Inhalation of Soil<br />

Page 37 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE FWD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Lead<br />

3.15E-11<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 7, SWMU 133, ISO-Current Industrial Dermal Contact with Soil<br />

Lead 3.42E-07 26<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)flporanthene<br />

Dibenzo(dh)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

2.78E-09<br />

2.19E-08<br />

1.65E-08<br />

1.77E-08<br />

9.70E-09<br />

1.48E-08<br />

1.05E-09<br />

8.02E-09<br />

1.98E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 133, ISO-Current Industrial Ingestion of Soil<br />

Lead<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(qh)anthracene<br />

Indene( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

3.33E-07<br />

1.36E-09<br />

1.07E-08<br />

8.01E-09<br />

8.63E-09<br />

<strong>4.</strong>73E-09<br />

7.19E-09<br />

5.14E- 10<br />

3.90E-09<br />

9.66E-09<br />

Pathway Total<br />

WAG 7, SWMU 133, ISO-Current Industrial Inhalation of Soil<br />

Lead 3.11E-11<br />

Acenaphth ylene 1.27E- 13<br />

Benzo(a)anthracene<br />

9.98E-13<br />

Benzo(a)pyrene<br />

7.48E-13<br />

Benzo(b)fluoranthene<br />

8.06E-13<br />

Benzo(g,h,i)perylene<br />

<strong>4.</strong>41E-13<br />

Benzo(k)fluoranthene<br />

6.71E-13<br />

Dibenzo(qh)anthracene <strong>4.</strong>8OE-14<br />

Indeno( 1,2,3-cd)pyrene 3.64E- 13<br />

Phenanthrene<br />

9.02E-13<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 134, ISO-Current Industrial Dermal Contact with Soil<br />

Lead 3.16E-08 26<br />

Benzo(a)anthracene 5.9 1E- 10 2<br />

Benzo(a)pyrene 5.9 1 E- 10 2<br />

Benzo(b)fluoranthene 8.86E- 10 2<br />

Benzo(g,h,i)perylene 3.04E- 10 2<br />

Phenanthrene l.lOE-09 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

Page 38 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 7, SWMU 134, ISO-Current Industrial Ingestion of Soil<br />

Lead<br />

3.08E-08<br />

Benzo(a)anthracene 2.88E- 10<br />

Benzo( a)pyrene 2.88E- 10<br />

Benzo(b)fluoranthene<br />

<strong>4.</strong>32E-10<br />

Benzo(g,h,i)perylene<br />

1.48E-10<br />

Phenanthrene<br />

5.34E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, ISO-Current Industrial Inhalation of Soil<br />

Lead<br />

2.88E-12<br />

Benzo(a)anthracene<br />

2.69E-14<br />

Benzo(a)pyrene 2.69E- 14<br />

Benzo(b)fluoranthene<br />

<strong>4.</strong>03E-14<br />

Benzo(g,h,i)perylene 1.38E- 14<br />

Phenanthrene<br />

<strong>4.</strong>99E-14<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 8% ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 6.56E-04 4,5<br />

Arsenic 1.39E-06 1.23E-04 8 1.13E-02<br />

Beryllium 1.47E-07 5.00E-05 13, 1 2.93E-03<br />

Cobalt 2.48E-06 26<br />

Lead 1.86E-06 26<br />

Sodium<br />

2.17E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.42E-02<br />

WAG 7, SWMU 8% ISE-Current Industrial Ingestion of Sediment<br />

Aluminum<br />

6.39E-04<br />

Arsenic<br />

1.35E-06 3.00E-04 a <strong>4.</strong>51E-03<br />

Beryllium<br />

1.43E-07 5.00E-03 a 2.85E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

2.42E-06<br />

1.8 IE-06<br />

2.11E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

<strong>4.</strong>54E-03<br />

WAG 7. SWMU 8% ISE-Current Industrial Inhalation of Sediment<br />

Aluminum<br />

5.96E-08<br />

Arsenic 1.26E- 10<br />

Beryllium<br />

1.33E-11<br />

Cobalt<br />

2.26E-10<br />

Lead<br />

1.69E-10<br />

Sodium<br />

1.97E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 8% ISW-Current Industrial Dermal Contact with Water<br />

Aluminum 4,5<br />

Antimony<br />

1.32E-06 8.00E-06 7 1.65E-01<br />

Arsenic<br />

9.28E-08 1.23E-04 8 7.55E-04<br />

Cadmium<br />

1.86E-07 5.00E-06 16, 1 3.72E-02<br />

Lead<br />

2.66E-07 26<br />

Manganese<br />

1.09E-03 2.00E-04 38 5.46E+OO<br />

Page 39 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS<br />

Silicon<br />

CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Sodium<br />

Sulfate<br />

Thallium 52<br />

Vanadium 3.95E-05 7.00E-OS 58, 5 5.64E-01<br />

Methylene Chloride 1.05E-06 5.70E-02 41 1.84E-05<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

6.23E+00<br />

S WMU Total<br />

WAG 7, SWMU 8b, ISO-Current Industrial Dermal Contact with Soil<br />

6.25E+00<br />

Aluminum 3.52E-03 <strong>4.</strong>5<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo( a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Dibenzoh<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

7honum-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

1.90E-06<br />

3.55E-07<br />

<strong>4.</strong>83E-06<br />

5.92E-06<br />

2.86E-05<br />

3.18E-05<br />

6.93E-08<br />

1.21E-07<br />

7.63E-08<br />

3.12E-07<br />

2.96E-07<br />

3.77E-07<br />

2.77E-07<br />

2.31E-07<br />

2.99E-07<br />

9.83E-07<br />

1.23E-04 8<br />

52<br />

43<br />

46<br />

2<br />

2<br />

2<br />

2<br />

43<br />

2<br />

Pathway Total<br />

WAG 7, SWMU 8b, ISO-Current Industrial Ingestion of Soil<br />

Aluminum 3.43503<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo( a)pyrene<br />

Benzo(b)fluoranthene<br />

Dibenzofuran<br />

Indene( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thonum-230<br />

Uranium-234<br />

Uranium-23 5<br />

Uranium-238<br />

1.54E-02<br />

5.OOE-05 13, 1 7.09E-03<br />

26<br />

26<br />

1.85E-06 3.00E-04 a 6.17E-03<br />

3.45507 5.00E-03 a 6.91E-OS<br />

<strong>4.</strong>70E-06<br />

5.77E-06<br />

2.79E-05<br />

3.09E-05<br />

6.75E-08<br />

5.87E-08<br />

3.72E-08<br />

1.52E-07<br />

1.44E-07<br />

1.84E-07<br />

1.3SE-07<br />

1.13E-07<br />

1.45E-07<br />

<strong>4.</strong>79E-07<br />

e<br />

Pathway Total<br />

WAG 7. SWMU 8b, ISO-Current Industrial Inhalation of Soil<br />

Page 40 of 53<br />

2.25E-02<br />

6.24E-03


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Aluminum<br />

3.20E-07<br />

Arsenic 1.73E- 10<br />

Beryllium<br />

3.22E-11<br />

Cobalt<br />

<strong>4.</strong>39E-10<br />

Lead 5.39E- 10<br />

Phosphate (ortho)<br />

2.60E-09<br />

Sodium<br />

2.89E-09<br />

Thallium<br />

6.30E-12<br />

2-Methylnaphthalene 5.48E- 12<br />

Aroclor-1260 3.47E- 12<br />

Benzo( a)anthracene 1.42E- 11<br />

Benzo(a)p yrene<br />

1.35E-11<br />

Benzo(b)fluoranthene<br />

1.72E-11<br />

Dibenzohran<br />

1.26E-11<br />

Indeno( 1,2,3-cd)pyrene 1.05E-11<br />

Naphthalene<br />

1.36E-11<br />

Phenanthrene<br />

<strong>4.</strong>47E-11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

2.88E-02<br />

WAG 1. SWMU 100% FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 6.52E-03 4s<br />

Arsenic<br />

3.02E-06 1.23E-04 8 2.46E-02<br />

Beryllium<br />

<strong>4.</strong>40E-07 5.OOE-05 13, 1 8.80E-03<br />

Cobalt<br />

8.69E-06 26<br />

Lead<br />

6.1 OE-06 26<br />

Sodium<br />

7.16E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

3.34E-02<br />

WAG 1, SWMU 100% FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

1.96E-03<br />

Arsenic 9.06E-07 3.00E-04 a 3.02E-03<br />

Beryllium 1.32E-07 5.00E-03 a 2.64E-05<br />

Cobalt<br />

2.61E-06<br />

Lead<br />

1.83E-06<br />

Sodium<br />

2.15E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.05E-03<br />

WAG I. SWMU IOOa, FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

1.83E-07<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

8.46E-11<br />

1.23E- 11<br />

2.43E-10<br />

1.71E-10<br />

2.00E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Path wav Total<br />

U’AG I. SWMU 100% FSW-Future Industnal Dermal Contact with Surfacewater<br />

Alummum<br />

Cadmium<br />

Cobalt<br />

4s<br />

3.38E-06 5.00E-06 16, 1 6.77E-0 1<br />

26<br />

Page41 of53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Lead 3.97E-06 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

6.77E-01<br />

S WMU Total<br />

7.13E-01<br />

WAG 1, SWMU 100b, FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 5.08E-03 4s<br />

Arsenic 2.76E-06 1.23E-04 8 2.24E-02<br />

Beryllium 3.39E-07 5.00E-OS 13, 1 6.78E-03<br />

Cobalt <strong>4.</strong>40E-06 26<br />

Lead 5.35E-06 26<br />

Sodium<br />

6.68s-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

2.92E-02<br />

WAG 1, SWMU IOOb, FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

1.52E-03<br />

Arsenic<br />

8.27E-07 3.00E-04 a 2.76E-03<br />

Beryllium<br />

1.02E-07 5.00E-03 a 2.04E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

1.32E-06<br />

1.61E-06<br />

2.00E-05<br />

Arsenic 7.72E11<br />

Beryllium<br />

9.50E-12<br />

Cobalt<br />

1.23E-10<br />

Lead 1 SOE- 10<br />

Sodium<br />

1.87E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU IOOb, FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum<br />

4s<br />

Arsenic<br />

3.56E-07 1.23E-04 8 2.90E-03<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

6.89E-06 26<br />

S WMU Total<br />

WAG 1, SWMU IOOc, FGW-Future Industrial Dermal Contact with Groundwater<br />

Aluminum 495<br />

Barium 3.94E-OS <strong>4.</strong>90E-03 9 8.OSE-03<br />

Manganese 3.63E-04 2.00E-04 38 1.82E+00<br />

Methylene Chloride 1.28E-06 5.70E-02 41 2.25E-05<br />

bis(2-Ethylhexy1)phthalate 2.68E-06 3.80B03 15 7.04E-04<br />

Gross Alpha<br />

Page 42 of 53<br />

2.9OE-03<br />

3.49E-02


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Gross Beta<br />

Pathway Total<br />

1.83E+00<br />

WAG 1, SWMU IOOc, FGW-Future Industrial Ingesaon of Groundwater<br />

Aluminum<br />

1.30E-01<br />

Barium 6.71E-03 7.00E-02 a 9.59E-02<br />

Manganese 6.18E-02 5.00E-03 a 1.24E+O 1<br />

Methylene Chloride <strong>4.</strong>89E-05 6.00E-02 a 8.15E-04<br />

bis(2-Ethylhexy1)phthalate 1.96E-05 2.00E-02 a 9.78E-04<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

1.25E+01<br />

WAG 1, SWMU lOOc, FGW-Future Industrial Inhalation of Groundwater<br />

Aluminum<br />

Barium 1.43E-04 b,c<br />

Manganese 1.43E-05 a<br />

Methylene Chloride 5.10E-06 8.57E-01 b 5.95E-06<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

5.95E-06<br />

WAG 1, SWMU lOOc, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 3.78E-03 4s<br />

Arsenic 2.26506 1.23E-04 8 1.83E-02<br />

Beryllium 2.02E-07 5.00E-05 13, 1 <strong>4.</strong>03E-03<br />

Cobalt 3.19E-06 26<br />

Lead <strong>4.</strong>66E-06 26<br />

Sodium 1.51 E-04<br />

Thallium 2.57E-08 52<br />

2-Methylnaphthalene 2.38E-07 43<br />

3-Nitroaniline<br />

5.8 IE-08<br />

Endosulfan Sulfate<br />

7.92E-10<br />

Endrin Ketone 8.18E- 10<br />

Naphthalene 1.44E-07 43<br />

Phenanthrene 3.94E-07 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

2.24E-02<br />

WAG 1. SWMU lOOc, FSO-Future Industrial Ingestion of Soil<br />

Aluminum<br />

1.13E-03<br />

Arsenic 6.77E-07 3.00E-04 a 2.26E-03<br />

Beryllium 6.05E-08 5.00E-03 a 1.21E-05<br />

Cobalt<br />

9.56E-07<br />

Lead<br />

1.40E-06<br />

Sodium<br />

<strong>4.</strong>52E-05<br />

Thallium<br />

7.71E-09<br />

2-Methylnaphthalene<br />

3.56E-08<br />

3-Nitroaniline<br />

8.72E-09<br />

Endosulfan Sulfate 1.19E- 10<br />

Endrin Ketone<br />

1.23E-10<br />

Naphthalene<br />

2.15E-08<br />

e<br />

Phenanthrene<br />

5.91E-08<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

2.27E-03<br />

WAG 1, SWMU lOOc, FSO-Future Industrial Inhalation of Soil<br />

Aluminum<br />

1.06E-07<br />

Page 43 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Beryllium<br />

5.65E-12<br />

cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

Phenanthrene<br />

8.92E-11<br />

1.31E- 10<br />

<strong>4.</strong>22E-09<br />

7.19E- 13<br />

3.33E-12<br />

8.14E- 13<br />

1.1 IE-14<br />

1.15E-14<br />

2.01E-12<br />

5.52E-12<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total 1.43E+O 1<br />

WAG 1, SWMU 136, FGW-Future Industrial Dermal Contact with Groundwater<br />

Barium 1.90E-05 <strong>4.</strong>90E-03 9 3.87E-03<br />

Manianese 3.21E-04 2.00E-04 38 1.61E+00<br />

Trichloroethene 9.95E-05 57<br />

bis(2-Ethylhexy1)phthalate 1.34B06 3.80E-03 15 3.52E-04<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

1.61E+00<br />

WAG 1, SWMU 136, FGW-Future Industrial Ingestion of Groundwater<br />

Barium 3.23E-03 7.00E-02 a <strong>4.</strong>6 1 E-02<br />

Manganese 5.47E-02 5.00E-03 a 1.09E+01<br />

Trichloroethene<br />

1.08E-03<br />

bis(2-Ethylhexy1)phthalate 9.78E-06 2.00E-02 a <strong>4.</strong>89E-04<br />

Gross Alpha<br />

Gross Beta<br />

Manganese 1.43E-05 a<br />

Trichloroethene<br />

1.12E-04<br />

bis(2-Ethylhexyl)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

WAG 1, SWMU 136, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 1.59E-04 4s<br />

Arsenic<br />

5.70E-08 1.23E-04<br />

Beryllium<br />

7.12E-09 5.00E-05<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1.1.1 -Trichloroethane<br />

1,1 -Dichloroethene<br />

1.63E-07<br />

1.22E-07<br />

<strong>4.</strong>45E-06<br />

1.39E-05<br />

9.60E- IO<br />

1.33E-09<br />

8.62E-10 9.00E-03<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indene( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

6.24E-09<br />

6.66E-09<br />

6.97E-09<br />

5.88E-09<br />

2.32E-09<br />

6.02E-09<br />

2.27E-09<br />

8 <strong>4.</strong>63E-04<br />

13, 1 1.42E-04<br />

26<br />

26<br />

52<br />

55<br />

31 9.57E-08<br />

2<br />

2<br />

2<br />

2<br />

2<br />

2<br />

2<br />

Page 44 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1,1,1 -Trichloroethane<br />

1,l-Dichloroethene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indene( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.71E-08 3.00E-04 a 5.70E-05<br />

2.14E-09 5.00E-03 a <strong>4.</strong>27E-07<br />

<strong>4.</strong>90E-08<br />

3.66E-08<br />

1.34E-06<br />

<strong>4.</strong>18E-06<br />

2.88E-10<br />

7.97E-11<br />

5.17E-11<br />

9.37E- 10<br />

9.98E-10<br />

1.05E-09<br />

8.82E-10<br />

3.49E- 10<br />

9.02E-10<br />

3.40E- 10<br />

9.00E-03<br />

e<br />

a<br />

5.74E-09<br />

Arsenic<br />

1.60E-12<br />

Beryllium<br />

1.99E-13<br />

Cobalt <strong>4.</strong>57E- 12<br />

Lead<br />

3.41E-12<br />

Sodium<br />

1.25E-IO<br />

Sulfate 3.91E-10<br />

lhallium<br />

2.69E-14<br />

l,l,l-Trichloroethane<br />

1.9OE-09<br />

e<br />

1,l -DichIoroethene 3.28E-09<br />

Benzo(a)anihracene 8.74E- 14<br />

Benzo(a)pyrene<br />

9.32E-14<br />

Benzo(b)fluoranthene<br />

9.76E-14<br />

Benzo(g,h,i)perylene<br />

8.23E-14<br />

Dibenzo(a,h)anthracene 3.26E- 14<br />

Indene( 1,2,3-cd)pyrene 8.42E-14<br />

Phenanthrene<br />

3.18E-14<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 1, SWMU 38% FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 2.44E-03 4,5<br />

Beryllium 8.48E-07 5.00E-05 13, 1 1.70E-02<br />

Cobalt 5.35E-06 26<br />

Lead <strong>4.</strong>88E-06 26<br />

Sodium<br />

2.20E-05<br />

Vanadium 5.15E-05 7.00E-05 58, 5 7.36E-01<br />

Phenanthrene 1.06E-07 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38a, FSE-Future Industrial Ingestion of Sediment<br />

Aluminum 7.31E-04<br />

Beryllium<br />

2.54E-07 5.00E-03 a 5.09E-05<br />

Cobalt<br />

1.61E-06<br />

Lead<br />

1.46E-06<br />

Page 45 of 53<br />

7.53E-01<br />

1.26E+01


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Sodium<br />

6.60E-06<br />

Vanadium 1.55E-05 7.00E-03 b 2.21E-03<br />

Phenanthrene<br />

1.59E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.26E-03<br />

WAG 1, SWMU 38% FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

6.83E-08<br />

Beryllium<br />

2.38E-11<br />

Cobalt 1 SOE- 10<br />

Lead 1.37E- 10<br />

Sodium<br />

6.16E-10<br />

Vanadium<br />

1.44E-09<br />

Phenanthrene<br />

1.48E-12<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38% FSW-Future Industrial Dermal Contact with Surfacewater<br />

Arsenic 2.80E-07 1.23E-04 8 2.28E-03<br />

Lead 1.45E-06 26<br />

Sodium<br />

Chloroform 9.08E-06 2.00E-03 24 <strong>4.</strong>54E-03<br />

bis(2-Ethylhexy1)phihalate 1.18E-05 3.80E-03 15 3.12E-03<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

9.93E-03<br />

SWMU Total 7.65E-01<br />

WAG 1, SWMU 38b, FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum <strong>4.</strong>71E-03 4s<br />

Arsenic 1.91E-06 1.23E-04 8 1.55E-02<br />

Beryllium 2.49E-07 5.00E-05 13, 1 <strong>4.</strong>98E-03<br />

Cobalt 3.55E-06 26<br />

Lead 9.65E-06 26<br />

Sodium<br />

3.73E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.05E-02<br />

WAG 1, SWMU 38b, FSE-Future Industrial Ingestion of Sediment<br />

Aluminum 1.41 E-03<br />

Arsenic 5.72E-07 3.00E-04 a 1.91E-03<br />

Beryllium 7.47E-08 5.00E-03 a 1.49E-05<br />

Cobalt<br />

1.07E-06<br />

Lead<br />

2.89E-06<br />

Sodium<br />

1.12E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

1.92E-03<br />

WAG 1, SWMU 38b, FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

1.32E-07<br />

Arsenic 5.34E-I 1<br />

Beryllium<br />

6.98E-12<br />

Cobalt<br />

9.95E-11<br />

Lead<br />

2.70E-10<br />

Sodium<br />

1.05E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Page 46 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

WAG 1, SWMU 38b, FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum 4,5<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

2.24E-02<br />

WAG 1, SWMU 38c, FGW-Future Industrial Dermal Contact with Groundwater<br />

Barium 1.67E-05 <strong>4.</strong>90E-03 9 3.41 E-03<br />

Manganese<br />

1.62E-04 2.00E-04 38 8.11E-01<br />

Methylene Chloride<br />

3.34E-05 5.70E-02 41 5.85E-04<br />

Gross Beta<br />

Pathway Total 8.15E-0 1<br />

WAG 1, SWMU 38c, FGW-Future Industrial Ingestion of Groundwater<br />

Barium 2.85E-03 7.00E-02 a <strong>4.</strong>07E-02<br />

Manganese 2.76E-02 5.OOE-03 a 5.52E+00<br />

Methylene Chloride 1.27E-03 6.00E-02 a 2.12E-02<br />

Gross Beta<br />

Pathway Total<br />

5.58E+00<br />

WAG 1, SWMU 38c, FGW-Future Industrial Inhalation of Groundwater<br />

Barium 1.43E-04 b,c<br />

Manganese 1.43E-05 a<br />

Methylene Chloride 1.33E-04 8.57E-01 b 1.55E-04<br />

Gross Beta<br />

Pathway Total<br />

1 .%E-04<br />

WAG 1, SWMU 38c, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 1.37E-02 4s<br />

Arsenic<br />

8.79E-06 1.23E-04 8 7.14E-02<br />

Beryllium<br />

8.17E-07 5.00E-05 13, 1 1.63E-02<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

1.41E-OS<br />

2.07E-05<br />

2.98E-04<br />

1.78E-07<br />

7.50E-08<br />

1.20E-07<br />

<strong>4.</strong>50E-07<br />

3.90E-07<br />

5.70E-07<br />

7.59E-07<br />

26<br />

26<br />

52<br />

36<br />

46<br />

2<br />

2<br />

2<br />

2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

8.78E-02<br />

WAG 1, SWMU 38c, FSO-Future Industrial Ingestion of Soil<br />

Aluminum<br />

<strong>4.</strong>10E-03<br />

Arsenic 2.64E-06 3.00E-04 a 8.79E-03<br />

Beryllium 2.45E-07 5.00E-03 a <strong>4.</strong>90E-05<br />

Cobalt<br />

<strong>4.</strong>24E-06<br />

Lead<br />

6.21E-06<br />

Sodium<br />

8.94E-05<br />

Thallium<br />

5.34E-08<br />

2-Hexanone<br />

<strong>4.</strong>50E-09<br />

Aroclor- 1260<br />

1.79E-08<br />

Benzo( a)anthracene<br />

6.75E-08<br />

Benzo(a)pyrene<br />

5.85E-08<br />

Benzo@)fluoranthene<br />

8.55E-08<br />

Page 47 of 53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Phenanthrene<br />

1.14E-07<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

llonum-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

8.84E-03<br />

WAG 1, SWMU 38c, FSO-Future Industrial Inhalation of Soil<br />

Aluminum<br />

3.83E-07<br />

Arsenic<br />

2.46E-10<br />

Beryllium<br />

2.29E-11<br />

Cobalt 3.96E- 10<br />

Lead<br />

5.79E-10<br />

Sodium<br />

8.34E-09<br />

Thallium<br />

<strong>4.</strong>98E-12<br />

2-Hexanone <strong>4.</strong>20E- 13<br />

Aroclor-1260<br />

1.67E-I2<br />

Benzo(a)anthracene<br />

6.30E-12<br />

Benzo(a)pyrene<br />

5.46E-12<br />

Benzo(b)fluoranthene 7.98512<br />

Phenanthrene<br />

1.06E-11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

6.49E+00<br />

WAG 7, SWMU 130, FSO-Future Industrial Dermal Contactwith Soil<br />

Lead 6.12E-08 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 8<br />

Pathwav Total<br />

WAG 7. SWMU 130, FSO-Future Industrial Ingestion of Soil<br />

Lead<br />

1.84E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7. SWMU 130. FSO-Future Industrial Inhalation of Soil<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7. SWMU 131, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 1.17E-08 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7, SWMU 131, FSO-Future Industrial Ingestion of Soil<br />

Lead<br />

3.50E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7. SWMU 131, FSO-Future Industrial Inhalation of Soil<br />

Lead<br />

3.27E-13<br />

Page 48 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 132, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 9.56E-07 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, FSO-Future Industrial Ingestion of Soil<br />

Lead<br />

2.87E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, FSO-Future Industrial Inhalation of Soil<br />

Lead<br />

2.68E-11<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 133, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 1.11E-06 26<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

8.02E-09<br />

6.02E-08<br />

<strong>4.</strong>52E-08<br />

<strong>4.</strong>87E-08<br />

2.69E-08<br />

<strong>4.</strong>06E-08<br />

3.32E-09<br />

2.23E-08<br />

5.44E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 133, FSO-Future Industrial Ingestion of Soil<br />

Lead<br />

3.33E-07<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.20E-09<br />

9.02E-09<br />

6.78E-09<br />

7.30E-09<br />

<strong>4.</strong>03E-09<br />

6.10E-09<br />

<strong>4.</strong>98E-10<br />

3.34E-09<br />

8.16E-09<br />

WAG 7, SWMU 133, FSO-Future Industrial Inhalation of Soil<br />

Lead<br />

3.11E-11<br />

Acenaphthylene<br />

1.lZE-13<br />

Benzo(a)anthracene<br />

8.42E-13<br />

Benzo( alp yrene<br />

6.33E-13<br />

Benzo(b)fluoranthene 6.82E- 13<br />

Benzo(g,h,i)perylene 3.76E- 13<br />

Benzo(k)fluoranthene 5.69E- 13<br />

Dibenzo(ah)anthracene <strong>4.</strong>65E-14<br />

Page 49 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Indene( 1,2,3-cd)pyrene<br />

__-<br />

3.12E-13<br />

Phenanthrene 7.62E- 13<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 134, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 1.78E-07 26<br />

Benzo(a)anthracene<br />

2.05E-09<br />

Benzo(a)pyrene<br />

1.92E-09<br />

Benzo(b)fluoranthene<br />

2.86E-09<br />

Benzo(g,h,i)perylene 1 .O 1E-09<br />

Phenanthrene<br />

<strong>4.</strong>60E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, FSO-Future Industrial Ingestion of Soil<br />

Lead<br />

5.34E-08<br />

Benzo(a)anthracene 3.08E- 10<br />

Benzo(a)pyrene 2.88E- 10<br />

Benzo@)fluoranthene<br />

<strong>4.</strong>29E-10<br />

Benzo(g,h,i)perylene<br />

1.52E-10<br />

Phenanthrene<br />

6.91E-10<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, FSO-Future Industrial Inhalation of Soil<br />

Lead <strong>4.</strong>99E- 12<br />

Benzo(a)anthracene<br />

2.88E-14<br />

Benzo(a)pyrene<br />

2.69E-14<br />

Benzo@)fluoranthene <strong>4.</strong>0 1E-14<br />

Benzo(g,h,i)perylene<br />

1.42E-14<br />

Phenanthrene<br />

6.45E-14<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 8% FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 2.13E-03 <strong>4.</strong>5<br />

Arsenic<br />

<strong>4.</strong>51E-06 1.23E-04 8 3.67E-02<br />

Beryllium<br />

<strong>4.</strong>76E-07 5.00E-05 13, 1 9.52E-03<br />

Cobalt<br />

8.07E-06 26<br />

Lead<br />

6.05E-06 26<br />

Sodium<br />

7.04E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

<strong>4.</strong>62E-02<br />

WAG 7, SWMU 8% FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

6.39E-04<br />

1.35E-06 3.00E-04 a <strong>4.</strong>51E-03<br />

1.43E-07 5.OOE-03 a 2.85E-05<br />

2.42E-06<br />

1.81E-06<br />

2.1 1E-05<br />

Page 50 of 53<br />

<strong>4.</strong>54E-03


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTENT INDEX INDEX<br />

WAG 7, SWMU 8% FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

5.96E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

1.26E-10<br />

1.33E-11<br />

2.26E-10<br />

1.69E-10<br />

1.97E-09<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 8% FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum<br />

4s<br />

Antimony<br />

<strong>4.</strong>28E-06 8.00E-06 7 5.35E-0 1<br />

Arsenic<br />

3.01E-07 1.23E-04 8 2.45E-03<br />

Cadmium<br />

6.04E-07 5.00E-06 16, 1 1.21E-01<br />

Lead<br />

8.65E-07 26<br />

Manganese<br />

3.55E-03 2.00E-04 38 1.77E+01<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Thallium<br />

52<br />

Vanadium<br />

1.28E-04 7.00E-05 58, 5 1.83E+00<br />

Methylene Chloride<br />

3.41E-06 5.70E-02 41 5.98E-05<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

2.02EM1<br />

S WMU Total<br />

2.03E+01<br />

WAG 7, SWMU 8b, FGW-Future Industrial Dermal Contact with Groundwater<br />

Aluminum<br />

4s<br />

Beryllium<br />

3.04E-06 5.OOE-05 13, 1 6.08E-02<br />

Cobalt<br />

Iron<br />

26<br />

26<br />

Manganese<br />

1.44E-03 2.00E-04 38 7.18E+00<br />

Nickel<br />

3.76E-05 5.40s-03 44 6.96E-03<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,1 -Dichloroethene 5.09E-06 9.00E-03 31 5.65E-04<br />

1,2-Dichloroethene<br />

9.39E-06 9.00E-03<br />

1.04E-03<br />

Phenanthrene<br />

1.57E-05<br />

2<br />

Trichloroethene<br />

<strong>4.</strong>82E-06<br />

57<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

7.25E+00<br />

WAG 7, SWMU 8b, FGW-Future Industrial Ingestion of Groundwater<br />

Aluminum<br />

<strong>4.</strong>73E-01<br />

Beryllium 5.17E-04 5.OOE-03 a 1.03E-01<br />

Cobalt<br />

8.35E-03<br />

Iron 1.20E+O 1<br />

Manganese 2.44E-01 5.00E-03 a <strong>4.</strong>89E+01<br />

Nickel 6.40E-03 2.00E-02 a 3.20E-01<br />

Silica<br />

<strong>4.</strong>91EM0<br />

Silicon 1.17E-0 1<br />

Sulfate<br />

7.79EMO<br />

Sulfide<br />

2.35E-02<br />

1.1-Dichloroethene 9.49E-05 9.00E-03 a 1.05E-02<br />

Page 51 of53


Hazard Index Estimates (continued)<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

1.2-Dichloroethene 1.49E-03 9.00E-03 b 1.66E-01<br />

Phenanthrene<br />

9.78E-06<br />

Trichloroethene<br />

5.2 IE-05<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total <strong>4.</strong>95E+01<br />

WAG 7, SWMU 8b, FGW-Future Industrial Inhalation of Groundwater<br />

Aluminum<br />

Beryllium<br />

Cobalt<br />

Iron<br />

Manganese<br />

1.43E-05 a<br />

Nickel<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,l-Dichloroethene<br />

9.89E-06<br />

1,2-DichIoroethene<br />

Phenanthrene<br />

Trichloroethene<br />

5.43E-06<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 8b, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 1.77E-02 4s<br />

Arsenic 6.60E-06 1.23E-04 8 5.37E-02<br />

Beryllium 1.14E-06 5.00E-05 13, 1 2.27E-02<br />

Cobalt 1.26E-05 26<br />

Lead 1.623-05 26<br />

Phosphate (ortho)<br />

9.30E-05<br />

Sodium<br />

1.77E-04<br />

Thallium 2.52E-07 52<br />

2-Methylnaphthalene 3.91E-07 43<br />

Aroclor-1260 9.33E-08 46<br />

Benzo( a)anthracene 5.63E-07 2<br />

Benzo( a)pyrene 8.19E-07 2<br />

Benzo(b)fluoranthene 9.27E-07 2<br />

Dibenzohran<br />

8.03E-07<br />

Indene( 1,2,3-cd)pyrene 7.50E-07 2<br />

Naphthalene 8.21E-07 43<br />

Phenanthrene 7.48E-07 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

ThOnUm-228<br />

ThOriUm-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

7.64E-02<br />

WAG 7, SWMU 8b, FSO-Future Industrial Ingestion of Soil<br />

Aluminum<br />

5.31E-03<br />

Arsenic 1.98E-06 3.00E-04 a 6.60E-03<br />

Page 52 of 53


Hazard Index Estimates (continued)<br />

IUlAL<br />

PATHWAY EXPOSURE<br />

REFERENCE RFD HAZARD HAZARD HAZARD<br />

ANALYSIS CDI DOSE SOURCE QUOTIENT INDEX INDEX<br />

Bervllium 3.41E-07 5.OOE-03 a 6.81E-05<br />

cobalt<br />

Lead<br />

Phosphate (oriho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo( a)anthracene<br />

Benzo( a)pyrene<br />

Benzo(h)fluoranthene<br />

Dibenzofuran<br />

Indene( 1,2,3-cd)pyrene<br />

Naphthalene<br />

3.78E-06<br />

<strong>4.</strong>87E-06<br />

2.79E-05<br />

5.32E-05<br />

7.56E-08<br />

5.87E-08<br />

1.40E-08<br />

8.45E-08<br />

1.23E-07<br />

1.39E-07<br />

1.20E-07<br />

1.13E-07<br />

1.23E-07<br />

e<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

' Uranium-235<br />

Uranium-238<br />

1.12E-07<br />

Pathway Total<br />

6.67E-03<br />

WAG 7, SWMU 8b, FSO-Future Industrial Inhalation of Soil<br />

Aluminum<br />

<strong>4.</strong>96E-07<br />

Arsenic<br />

1.85E-10<br />

Beryllium<br />

3.18E-11<br />

Cobalt<br />

3.53E-10<br />

Lead <strong>4.</strong>5 5E- 10<br />

Phosphate (ortho)<br />

2.6OE-09<br />

Sodium<br />

<strong>4.</strong>96E-09<br />

Thallium<br />

7.06E-12<br />

2-Methylnaphthalene 5.48E- 12<br />

Aroclor- 1260 1.31E-12<br />

Benzo(a)anthracene<br />

7.89E-12<br />

Benzo(a)p yrene<br />

1.15E-11<br />

Benzo(b)fluoranthene 1.30E- 11<br />

Dibenzofuran 1.12E- 11<br />

Indene( 1,2,3-cd)pyrene 1.05E-11<br />

Naphthalene<br />

1.15E-11<br />

Phenanthrene<br />

1.05E-11<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total 5.68E+01<br />

Page 53 of 53


THIS PAGE LEFT BLANK


Excess Lifetime Cancer Risks<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

WAG 1. SWMU IOOc, RGW-Residential Dermal Contact with Water<br />

Aluminum <strong>4.</strong>5<br />

Barium 3.15E-05 NA 9<br />

Manganese 2.9 IE-04 D 38<br />

Methylene Chloride 1.03E-06 7.89E-03 B2 41 8.10E-09<br />

bis(2-Ethylhexyl)phthalate 2.14E-06 7.37E-02 B2 15 1.58E-07<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

1.66E-07<br />

WAG 1, SWMU lOOc, RGW-Residential Ingestion of Water<br />

Aluminum<br />

2.08E-01<br />

Barium 1.07E-02 NA<br />

Manganese 9.89E-02 D<br />

Methylene Chloride 7.83E-05 7.50E-03 B2 a 5.87E-07<br />

bis(2-Ethylhexy1)phthalate 3.13E-05 1.40E-02 B2 a <strong>4.</strong>38E-07<br />

Gross Alpha<br />

1.19E+05<br />

Gross Beta<br />

2.06E+05<br />

Pathway Total<br />

1.03E-06<br />

WAG 1, SWMU IOOc, RGW-Residential Inhalation of Water<br />

Aluminum<br />

Barium<br />

Manganese<br />

Methylene Chloride<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

<strong>4.</strong>08E-06<br />

NA<br />

D<br />

B2<br />

B2<br />

Arsenic 1.21E-05 3.66E+00 A 8 <strong>4.</strong>44E-05<br />

Beryllium 1.08E-06 <strong>4.</strong>30E+02 B2 13, 1 <strong>4.</strong>66E-04<br />

Cobalt 1.7 IE-05 26<br />

Lead 2.5 1 E-05 B2 26<br />

Sodium<br />

8.10E-04<br />

Thallium 1.38E-07 NA 52<br />

2-Methylnaphthalene 1.28E-06 43<br />

3-Nitroaniline<br />

3.12E-07<br />

Endosulfan Sulfate <strong>4.</strong>26E-09<br />

Endrin Ketone<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

<strong>4.</strong>40E-09<br />

7.72E-07<br />

2.12E-06<br />

D 43<br />

D 2<br />

Pathway Total<br />

WAG 1. SWMU lOOc, RSO-Residential External Exposure to Soil<br />

Aluminum<br />

h<br />

Arsenic A h<br />

Beryllium B2 h<br />

Cobalt<br />

b<br />

Lead B2 b<br />

Sodium<br />

b<br />

Thallium NA b<br />

2-Methylnaphthalene<br />

b<br />

3-Nitroaniline<br />

b<br />

Endosulfan Sulfate<br />

b<br />

Endrin Ketone<br />

b<br />

Naphthalene<br />

D<br />

h<br />

Phenanthrene<br />

D<br />

b<br />

Gross Alpha 1.92E+02 b<br />

Gross Beta 3.05E+02 h<br />

Neptunium-237 2.03E+00 <strong>4.</strong>62E-07 h 9.36E-07<br />

5.10E-04<br />

Page 1 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

ThoriUm-228 1.78E+01 9.94E-07 b 1.776-05<br />

Uranium-238 1.74E+01 5.25E-08 b 9.16E-07<br />

Pathway Total<br />

1.96E-05<br />

WAG 1, SWMU lOOc, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

8.15E-03<br />

Arsenic<br />

<strong>4.</strong>87E-06 1.50E+00<br />

Beryllium<br />

<strong>4.</strong>35E-07 <strong>4.</strong>30E+00<br />

Cobalt<br />

6.88E-06<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

1.OlE-05<br />

3.25E-04<br />

5.55E-08<br />

2.57E-07<br />

6.28E-08<br />

8.56510<br />

8.83E-10<br />

1 S5E-07<br />

<strong>4.</strong>26E-07<br />

1.01E+04<br />

1.60E+04<br />

B2<br />

NA<br />

D<br />

D<br />

Neptunium-237<br />

1.06E+02 3.00E-10<br />

Thorium-228<br />

9.35E+02 2.31E-10<br />

Uranium-238<br />

9.15E+02 6.20E-11<br />

Pathway Total<br />

WAG 1, SWMU lOOc, RSO-Residential Ingestion of Soil for Child<br />

Aluminum<br />

8.15E-03<br />

Arsenic<br />

<strong>4.</strong>87E-06 1.50E+00<br />

Beryllium<br />

<strong>4.</strong>35507 <strong>4.</strong>30E+00<br />

Cobalt<br />

6.88506<br />

Lead<br />

1.OlE-05<br />

BZ<br />

Sodium<br />

3.25504<br />

Thallium<br />

5.55E-08<br />

NA<br />

2-Methylnaphthalene 2.57E-07<br />

3-Nitroaniline<br />

6.28E08<br />

Endosulfan Sulfate 8.56510<br />

Endrin Ketone<br />

8.83E-10<br />

Naphthalene<br />

1 .ME-07<br />

D<br />

Phenanthrene<br />

<strong>4.</strong>26E-07<br />

D<br />

Gross Alpha<br />

1 .O 1E+04<br />

Gross Beta<br />

1.60E+04<br />

Neptunium-237<br />

1.06E+02 3.00E-10<br />

Ihonum-228<br />

9.35E+02 2.31E-10<br />

Uranium-238<br />

9.15E+02 6.20E-11<br />

A a 7.31E-06<br />

B2 a 1.87E-06<br />

3.19E-08<br />

2.16E-07<br />

5.67E-08<br />

A a 7.31E-06<br />

B2 a 1.87E-06<br />

3.19E-08<br />

2.16E-07<br />

5.67E-08<br />

9.49E-06<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Manganese<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Methylene Chloride<br />

Naphthalene<br />

Phenanthrene<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Bcta<br />

2.60E-06<br />

7.28E-08<br />

2.87E-06<br />

1.98E-09<br />

5.78E-04<br />

7.24E-06<br />

3.88506<br />

3.18E-04<br />

1.50E+00<br />

<strong>4.</strong>30E+00<br />

7.50E-03<br />

1.4OE-02<br />

A a 3.90E-06<br />

NA<br />

BZ a 3.13E-07<br />

B2<br />

D<br />

NA<br />

BZ a <strong>4.</strong>34E-06<br />

D<br />

D<br />

B2 a <strong>4.</strong>45E-06<br />

Neptunium-237 2.96E+03 3.00E-10 8.88E-07<br />

Page 2 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Thorium-228 6.01E+04 2.31E-10 3.39E-05<br />

Uranium-238 1.63E+03 6.20E-11 1.01E-07<br />

Pathway Total<br />

2.79E-05<br />

WAG 1, SWMU IOOc, RSO-Residential Inhalation of Soil<br />

Aluminum<br />

1.69E-07<br />

Arsenic 1 .O 1E- 10 5.OOE+O 1 A h 5.05E-09<br />

Beryllium 9.03E-12 8.40E+00 B2 h 7.59E-11<br />

Cobalt 1.43E- 10<br />

Lead 2.09E-10 B2<br />

Sodium<br />

6.75E-09<br />

Thallium 1.15E- 12 NA<br />

2-Methylnaphthalene 5.32E- 12<br />

3-Nitroaniline 1.30E- 12<br />

Endosulfan Sulfate<br />

1.78E-14<br />

Endrin Ketone<br />

1.83E-14<br />

Naphthalene 3.22E- 12 D<br />

Phenanthrene 8.83E-12 D<br />

Gross Alpha<br />

<strong>4.</strong>10E-01<br />

Gross Beta 6.49E-01<br />

Neptunium-237 <strong>4.</strong>31E-03 3.45E-08<br />

1.49E-10<br />

Thorium-228 3.80E-02 9.68E-08 3.68E-09<br />

Uranium-238 3.72E-02 1.24E-08 <strong>4.</strong>61E- 10<br />

Pathway Total<br />

9.42E-09<br />

SWMU Total<br />

5.68E-04<br />

WAG 1, SWMU 136, RGW-Residential Dermal Contact with Water<br />

Barium 1.52E-05 NA 9<br />

Manganese 2.57E-04 D 38<br />

Trichloroethene 7.96E-05 7.33E-02 NA 57 5.83E-06<br />

his(2-Ethylhexy1)phthalate 1.07E-06 7.37E-02 B2 15 7.89E-08<br />

Gross Alpha<br />

Gross Beta<br />

Pathwav Total<br />

5.9 IE-06<br />

WAG 1. SWMU 136, RGW-Residential Ingestion of Water<br />

Barium 5.17E-03 NA<br />

Manganese 8.75E-02 D<br />

Trichloroethene 1.72E-03 1.1 OE-02 NA e 1.89E-05<br />

his(2-Ethylhexy1)phthalate 1.57E-05 1.40E-02 BZ a 2.19E-07<br />

Gross Alpha 8.71E+04<br />

Gross Beta<br />

2.24E+05<br />

Pathway Total<br />

1.92E-05<br />

WAG 1, SWMU 136, RGW-Residential Inhalahon of Water<br />

Banum<br />

NA<br />

Manganese<br />

D<br />

Trichloroethene 8.97E-05 6.OOE-03 NA e 5.38507<br />

his(2-Ethylhexy1)phthalate<br />

B2<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

5.38E-07<br />

WAG 1. SWMU 136, RSO-Residential Dermal Contact with Soil<br />

Aluminum 8.52E-04 495<br />

Arsenic 3.06E-07 3.66E+00 A 8 l.lZE-06<br />

Beryllium 3.83E-08 <strong>4.</strong>30E+02 BZ 13, 1 1.65E-05<br />

Cobalt 8.78E-07 26<br />

Lead 6.55E-07 BZ 26<br />

Sodium<br />

2.39E-05<br />

Sulfate<br />

7.50E-05<br />

Thallium 5.16E-09 NA 52<br />

l.l,l-Trichloroethane 7.14E-09 D 55<br />

1.1 -Dichloroethene <strong>4.</strong>63E-09 6.00E-01 C 31 2.78E-09<br />

Benzo(a)anthracene 3.36E-08 2.35E+00 BZ 2 7.90E-08<br />

Benzo( a)pvrene 3.58E-08 2.35E+01 B2 2 8.43E-07<br />

Benzo(h)fluoranthene 3.75E-08 2.35EMO BZ 2 8.82E-08<br />

Benzo(g,h,i)perylene 3.16E-08 D 2<br />

Dihenzo(ah)anthracene 1.25E-08 2.35E+01 BZ 2 2.94E-07<br />

Page 3 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Indeno( 1,2,3-cd)pyrene 3.23E-08 2.35E+00 B2 2 7.61E-08<br />

Phenanthrene<br />

1.22E-08<br />

D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.90E-05<br />

WAG 1, SWMU 136, RSO-Residential External Exposure to Soil<br />

Aluminum<br />

h<br />

Arsenic A b<br />

Beryllium B2 b<br />

Cobalt<br />

h<br />

Lead B2 b<br />

Sodium<br />

h<br />

Sulfate<br />

h<br />

Thallium NA h<br />

1,1, I-Trichloroethane D b<br />

1,1 -Dichloroethene C h<br />

Benzo(a)anthracene B2 b<br />

Benzo(a)pyrene B2 h<br />

Benzo(h)fluoranthene B2 b<br />

Benzo(g,h,i)perylene D b<br />

Dibenzo(a,h)anthracene B2 h<br />

Indeno( 1,2,3-cd)pyrene B2 b<br />

Phenanthrene D h<br />

Gross Alpha 5.52E+00 h<br />

Gross Beta 8.04E+OO b<br />

Uranium-238 <strong>4.</strong>36E-01 5.25E-08 h 2.29E-08<br />

Pathway Total<br />

2.29E-08<br />

WAG 1, SWMU 136, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

3.42E-04<br />

Arsenic<br />

1.23E-07 1.50E+00 A a 1.85E-07<br />

Beryllium<br />

1.54E-08 <strong>4.</strong>30E+00 B2 a 6.61E-08<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1 , 1,1 -Trichloroethane<br />

1.1 -Dichloroethene<br />

3.53E-07<br />

2.63E-07<br />

9.62E-06<br />

3.01E-05<br />

2.07E-09<br />

5.74E-10<br />

3.72E-10 6.00E-01<br />

BZ<br />

NA<br />

D<br />

C a 2.23E-10<br />

Benzo(a)anthracene 6.74E-09 7.30E-01 B2<br />

<strong>4.</strong>92E-09<br />

Benzo(a)pyrene<br />

7.19E-09 7.30E+00 B2 a 5.25E-08<br />

Benzo(b)fluoranthene 7.53E-09 7.30E-01 B2<br />

5.50E-09<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

6.35E-09<br />

2.51E-09 7.30E+00<br />

D<br />

B2<br />

1.83E-08<br />

Indeno( 1,2,3-cd)pyrene 6.50E-09 7.30501 B2<br />

<strong>4.</strong>74E-09<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

2.49509<br />

2.90E+02<br />

<strong>4.</strong>22E+02<br />

2.29EM1 6.20E-11<br />

D<br />

1.42E-09<br />

Pathway Total<br />

3.38E-07<br />

WAG 1, SWMU 136, RSO-Residential Ingestion of Soil for Child<br />

Alummum<br />

3.42E-04<br />

Arsenic 1.23E-07 1.50E+00 A a 1.85E-07<br />

Beryllium 1.54E-08 <strong>4.</strong>30E+00 B2 a 6.61E-08<br />

Cobalt<br />

3.53E-07<br />

Lead 2.63E-07 B2<br />

Sodium<br />

9.62E-06<br />

Sulfate<br />

3.01E-05<br />

Thallium 2.07E-09 NA<br />

1,I.l -Trichloroethane 5.74E- 10 D<br />

1.1 -Dichloroethene 3.72E-10 6.00E-01 C a 2.23E-10<br />

Benzo(a)anthracene 6.74E-09 7.30E-01 B2 <strong>4.</strong>92E-09<br />

Benzo(a)pyrene 7.19E-09 7.30EM0 B2 a 5.25E-08<br />

Benzo(b)fluoranthene 7.53E-09 7.30E-01 B2 5.50E-09<br />

Page 4 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Benzo(g,h,i)perylene 6.35E-09 D<br />

Dibenzo(a,h)anthracene 2.51E-09 7.30E+00 BZ 1.83E-08<br />

Indeno(l,2,3-cd)pyrene 6.50E-09 7.30E-01 BZ <strong>4.</strong>74E-09<br />

Phenanthrene 2.45E-09 D<br />

Gross Alpha<br />

2.90E+02<br />

Gross Beta<br />

<strong>4.</strong>22E+02<br />

Uranium-238 2.29E+01 6.20E-11 1.42E-09<br />

Pathway Total 3.38E-07<br />

WAG 1, SWMU 136, RSO-Residential Ingestion of Vegetables<br />

Aluminum<br />

Arsenic<br />

6.57E-08<br />

1.50Et00 A a 9.85E-OX<br />

Barium<br />

Beryllium<br />

2.57E-09 <strong>4.</strong>30E+00<br />

NA<br />

B2 a 1.1 IE-08<br />

Cobalt<br />

Lead<br />

Manganese<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1,1,1 -Trichloroethane<br />

1,l -Dichloroethene<br />

7.49E-08<br />

7.42E- 11<br />

7.09E-08<br />

1.11E-07<br />

6.00E-01<br />

B2<br />

D<br />

NA<br />

D<br />

C a 6.64E-08<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indene( 1,2,3-cd)pyrene<br />

1.35E-08<br />

7.77E-09<br />

8.14E-09<br />

<strong>4.</strong>95E-09<br />

3.92E-09<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

BZ<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

a<br />

9.83E-09<br />

5.67E-08<br />

5.94E-09<br />

3.61E-08<br />

2.86E-09<br />

Phenanthrene<br />

Tnchloroethene<br />

2.23E-08<br />

1.03E-02 1.1OE-02<br />

D<br />

NA e 1.13E-04<br />

bis(2-Ethylhexy1)phthalate<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 8<br />

1.59E-04<br />

<strong>4.</strong>08E+01<br />

1.40E-02<br />

6.20E-11<br />

B2 a 2.22E-06<br />

2.53E-09<br />

Pathway Total<br />

1.16E-04<br />

WAG 1, SWMU 136, RSO-Residential Inhalation of Soil<br />

Aluminum 7.11E-09<br />

Arsenic 2.55E-12 5.00E+01 A b 1.28E- 10<br />

Beryllium 3.19E-13 8.40E+00 B2 b 2.68E-12<br />

Cobalt<br />

7.32E-12<br />

Lead 5.46E-12 B2<br />

Sodium<br />

2.00E-10<br />

Sulfate<br />

6.25E-10<br />

Thallium <strong>4.</strong>30E- 14 NA<br />

I,], 1 -Trichloroethane 3.04E-09 D<br />

1, I -Dichloroethene 5.24E-09 1.20E+00 C b 6.29E-09<br />

Benzo(a)anthracene 1.40E-13 BZ<br />

Benzo(a)pyrene 1.49E-13 B2<br />

Benzo(b)fluoranthene 1.56E- 13 B2<br />

Benzo(g,h,i)perylene 1.32E-13 D<br />

Dibenzo(a,h)anthracene 5.21E-I4 B2<br />

Indeno( I ,2,3-cd)pyrene 1.35E-13 B2<br />

Phenanthrene 5.08E-34 D<br />

Gross Alpha<br />

1.18E-02<br />

Gross Beta<br />

1.71E-02<br />

Uranium-238 9.28E-04 1.24E-08 1.15E-11<br />

Pathway Total<br />

6.44E-09<br />

S WMU Total<br />

1.61E-04<br />

WAG 1. SWMU 38c, RGW-Residential Dermal Contact with Water<br />

Barium 1.34E-05 NA 9<br />

Manganese 1.30E-04 D 38<br />

Methylene Chloride 2.67E-05 7.89E-03 B2 41 2.11E-07<br />

Gross Beta<br />

Pathway Total 2.11E-07<br />

R’AG 1. SWMU 38c, RGW-Residential Ingestion of Water<br />

Page 5 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Bmum <strong>4.</strong>56E-03 NA<br />

Manganese <strong>4.</strong>41E-02 D<br />

Methylene Chloride 2.04E-03 7.50E-03 B2 a 1.53E-05<br />

Gross Beta<br />

1.08E+05<br />

Pathway Total<br />

1.53E-05<br />

WAG 1, SWMU 38c, RGW-Residential Inhalation of Water<br />

Barium<br />

NA<br />

Manganese<br />

D<br />

Methylene Chloride 1.06E-04 B2<br />

Gross Beta<br />

Pathway Total<br />

WAG 1, SWMU 38c, RSO-Residential Dermal Contact with Soil<br />

Aluminum 3.99E-02 4s<br />

Arsenic<br />

2.57E-05 3.66E+00 A 8 9.39E-05<br />

Beryllium<br />

2.39E-06 <strong>4.</strong>30E+02 B2 13, 1 1.03E-03<br />

Cobalt<br />

<strong>4.</strong>13E-05<br />

26<br />

Lead<br />

6.OSE-05<br />

B2 26<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

8.70E-04<br />

5.20E-07<br />

2.19E-07<br />

NA 52<br />

36<br />

Aroclor-1260<br />

3.49E-07 8.56E+00 B2 46 2.99E-06<br />

Benzo(a)anthracene 1.32E-06 2.35E+00 B2 2 3.10E-06<br />

Benzo(a)pyrene<br />

1.14E-06 2.35E+01 B2 2 2.68E-05<br />

Benzo(b)fluoranthene 1.67E-06 2.35E+00 B2 2 3.92E-06<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

2.22E-06<br />

D 2<br />

Pathwav Total<br />

1.16E-03<br />

WAG 1, SWMC' 38c, RSO-Residenhal External Exposure to Soil<br />

Alummum<br />

b<br />

Arsenic<br />

A<br />

h<br />

Beryllium<br />

Cobalt<br />

B2<br />

h<br />

h<br />

Lead<br />

Sodium<br />

B2 h<br />

b<br />

Thallium<br />

NA b<br />

?-Hexanone<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

Benzo( a)pyrene<br />

Benzo@)fluoranthene<br />

Phenanthrene<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

h<br />

h<br />

h<br />

b<br />

h<br />

h<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

<strong>4.</strong>63E+02<br />

6.39E+02<br />

<strong>4.</strong>06E+01 <strong>4.</strong>62E-07<br />

h<br />

b<br />

b 1.88E-05<br />

Thorium-228<br />

3.41E+01 9.94E-07<br />

b 3.39E-05<br />

Uranium-235<br />

7.42E+00 2.65E-07<br />

b 1.97E-06<br />

Uranium-238<br />

1.31E+02 5.25E-08<br />

b 6.89E-06<br />

Pathwav Total<br />

6. ISE-05<br />

WAG 1, SWMU 38c, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

1.60E-02<br />

Arsenic 1.03E-05 1.50E+00 A a 1.55E-05<br />

Beryllium 9.59E-07 <strong>4.</strong>30E+00 B2 a <strong>4.</strong>12E-06<br />

Cobalt<br />

1.66E-05<br />

Lead 2.43E-05 B2<br />

Sodium<br />

3.50E-04<br />

Thallium 2.09E-07 NA<br />

2-Hexanone<br />

1.76E-08<br />

Aroclor- 1260 7.02E-08 7.70E+00 B2 5.40E-07<br />

Benzo( a)anthracene 2.64E-07 7.30E-01 B2 1.93E-07<br />

Page 6 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Benzo(a)p yrene 2.29E-07 7.30E+00 B2 a 1.67E-06<br />

Benzo(b)fluoranthene 3.35E-07 7.30E-01 B2 2.44E-07<br />

Phenanthrene <strong>4.</strong>45E-07 D<br />

Gross Alpha<br />

2.43E+04<br />

Gross Beta<br />

3.35E+04<br />

Neptunium-237 2.13E+03 3.00E-10 6.39E-07<br />

Thorium-228 1.79E+03 2.31E-10 <strong>4.</strong>14E-07<br />

Uranium-235 3.89E+02 <strong>4.</strong>70E-11 1.83E-08<br />

Uranium-238 6.88E+03 6.20E-11 <strong>4.</strong>27E-07<br />

Pathway Total<br />

2.37E-05<br />

WAG 1, SWMU 38c, RSO-Residential Ingestion of Soil for Child<br />

Aluminum<br />

1.60E-02<br />

Arsenic<br />

1.03E-05 1.50E+00 A a 1 S5E-05<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

9.59E-07<br />

1.66E-05<br />

2.43E-05<br />

3.50E-04<br />

2.09E-07<br />

1.76E-08<br />

7.02E-08<br />

2.64E-07<br />

<strong>4.</strong>30E+00<br />

7.70E+00<br />

7.30E-01<br />

B2<br />

B2<br />

NA<br />

B2<br />

B2<br />

a <strong>4.</strong>12E-06<br />

5.40E-07<br />

1.93E-07<br />

Benzo( a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

2.29E-07<br />

3.35E-07<br />

<strong>4.</strong>45E-07<br />

2.43E+04<br />

3.35E+04<br />

2.13E+03<br />

1.79E+03<br />

3.89E+02<br />

6.88E+03<br />

7.30E+00<br />

7.30E-01<br />

3.00E-10<br />

2.31E-10<br />

<strong>4.</strong>70E- 11<br />

6.20E-11<br />

B2<br />

B2<br />

D<br />

a 1.67E-06<br />

2.44E-07<br />

6.39E-07<br />

<strong>4.</strong>14E-07<br />

1.83E-08<br />

<strong>4.</strong>27E-07<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Manganese<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo( a)pyrene<br />

Benzo(b)fluoranthene<br />

Methylene Chloride<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

5.50E-06<br />

1.60E-07<br />

6.91E-06<br />

7.47E-09<br />

1.78E-08<br />

5.27E-07<br />

2.48E-07<br />

3.62E-07<br />

1.50E-02<br />

<strong>4.</strong>06E-06<br />

7.70E+00<br />

7.30E-0 1<br />

7.30E+00<br />

7.30E-01<br />

7.50E-03<br />

3.00E-10<br />

2.31E-10<br />

<strong>4.</strong>70E-11<br />

6.20E-11<br />

A<br />

NA<br />

B2<br />

B2<br />

D<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

a<br />

a<br />

a<br />

a<br />

8.25E-06<br />

6.90E-07<br />

1.37E-07<br />

3.85E-07<br />

1.8lE-06<br />

2.64E-07<br />

1.13E-04<br />

1.78E-05<br />

2.666-05<br />

3.18E-08<br />

7.6 1 E-07<br />

WAG 1, SWMU 38c, RSO-Residential Inhalation of Soil<br />

Aluminum<br />

3.33E-07<br />

Arsenic 2.14E-IO 5.00E+01 A b 1.07E-08<br />

Beryllium 1.99E- 11 8.40E+00 B2 h 1.67E-IO<br />

Cobalt 3.44E- 10<br />

Lead 5.04E- 10 B2<br />

Sodium<br />

7.25E-09<br />

Thallium <strong>4.</strong>33E-12 NA<br />

2-Hexanone<br />

3.65E-13<br />

1.69E-04<br />

Page 7 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Aroclor-1260 1.46E-12 B2<br />

Benzo(a)anthracene 5.48E- 12 B2<br />

Benzo(a)pyrene <strong>4.</strong>75E-12 B2<br />

Benzo(b)fluoranthene 6.94E-12 B2<br />

Phenanthrene 9.24E- 12 D<br />

Gross Alpha<br />

9.86E-01<br />

Gross Beta<br />

1.36E+00<br />

Neptunium-237 8.65E-02 3.45E-08 2.98E-09<br />

'Ihorium-228 7.27E-02 9.68E-08 7.03E-09<br />

Uranium-235 1.58E-02 1.30E-08 2.05E-10<br />

Uranium-238 2.79E-01 1.24E-08 3.46E-09<br />

Pathway Total<br />

2.46E-08<br />

SWMU Total<br />

1.43E-03<br />

WAG 7, SWMU 130, RSO-Residential Demal Contact with Soil<br />

Lead 3.29E-07 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, RSO-Residential External Exposure to Soil<br />

Lead B2 b<br />

Gross Alpha<br />

1.35E+00<br />

b<br />

Gross Beta<br />

3.42E+00<br />

b<br />

Uranium-23 8 2.08E-01 5.25E-08<br />

b 1.09E-08<br />

Pathway Total<br />

1.09E-08<br />

WAG 7, SWMU 130, RSO-Residential Ingestion of Soil for Adult<br />

Lead 1.323-07 B2<br />

Gross Alpha<br />

7.08E+01<br />

Gross Beta<br />

1.80E+02<br />

Uranium-238 1.09E+01 6.20E-11<br />

6.76E- 10<br />

Pathway Total<br />

6.76E-10<br />

WAG 7, SWMU 130, RSO-Residential Ingestion of Soil for Child<br />

Lead 1.32E-07 B2<br />

Gross Alpha 7.08EM 1<br />

Gross Beta<br />

1.80E+02<br />

Uranium-238 1.09E+01 6.20E-11 6.76E- 10<br />

Pathway Total<br />

6.76E-10<br />

WAG 7, SWMU 130, RSO-Residential Ingestion of Vegetables<br />

Lead 3.76E-08 B2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 1.94E+O 1 6.20E- 11 1.21E-09<br />

Pathway Total<br />

1.21E-09<br />

WAG 7, SWMU 130, RSO-Residential Inhalation of Soil<br />

Lead 2.74E- 12 B2<br />

Gross Alpha<br />

Gross Beta<br />

2.87E-03<br />

7.29E-03<br />

Uranium-238<br />

<strong>4.</strong>43E-04 1.24E-08 5.49B 12<br />

Pathway Total<br />

5.49E-12<br />

SWMU Total<br />

1.28E-08<br />

WAG 7, SWMU 131, RSO-Residenbal Dermal Contact with Soil<br />

Lead 6.28E-08 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 131, RSO-Residential External Exposure to Soil<br />

Lead B2 b<br />

Gross Alpha 2.76E-01 b<br />

Gross Beta 4 07E-01 b<br />

Uranium-238 2.56E-02 5.25E-08 b 1.35E-09<br />

Pathwav Total<br />

1.35E-09<br />

WAG 7, SWMU 131, RSO-Residenbal Ingestion of Soil for Adult<br />

Lead 2.52E-08 B2<br />

Page 8 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Alpha<br />

1.45E+01<br />

Gross Beta<br />

2.13E+01<br />

Uranium-238 1.34E+00 6.20E-11 8.34E-11<br />

Gross Alpha 1.45E+O 1<br />

Gross Beta<br />

2.13E+01<br />

Uranium-238 1.34E+00 6.20E-11 8.34E-11<br />

Pathway Total<br />

WAG 7, SWMU 131, RSO-Residential Ingestion of Vegetables<br />

Lead 7.18E-09 B2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 2,40E+00 6.20E-11 1.49E-10<br />

8.34E-11<br />

Lead<br />

5.24E-13<br />

Gross Alpha<br />

5.88E-04<br />

Gross Beta<br />

8.66E-04<br />

Uranium-238 5.46E-05 1.24E-08<br />

6.77E-13<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 132, RSO-Residential Dermal Contact with Soil<br />

Lead 5.14E-06 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, RSO-Residential External Exposure to Soil<br />

Lead BZ b<br />

Gross Alpha 3.76E+00 b<br />

Gross Beta 6.56E+00 b<br />

Uranium-238 <strong>4.</strong>44E-01 5.25E-08 b 2.33E-08<br />

Pathway Total<br />

WAG 7. SWMU 132, RSO-Residential Ingestion of Soil for Adult<br />

Lead 2.07E-06 B2<br />

Gross Alpha<br />

1.97E+02<br />

Gross Beta<br />

3.44E+02<br />

Uranium-238<br />

2.33E+01 6.20E-11 1.44E-09<br />

Pathway Total<br />

WAG 7. SWMU 132, RSO-Residential Ingestion of Soil for Child<br />

Lead 2.07E-06 B2<br />

Gross Alpha<br />

1.97E+02<br />

Gross Beta<br />

3.44Ei-02<br />

Uranium-238 2.33E+01 6.20E-11 1.44E-09<br />

Pathwav Total<br />

U'AG 7. SWMU 132, RSO-Residential Ingestion of Vegetables<br />

Lead 5.88E-07 B2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 <strong>4.</strong>15E+01 6.20E-11 2.57E-09<br />

Pathway Total<br />

WAG 7, SWMU 132, RSO-Residenhal Inhalation of Soil<br />

Lead <strong>4.</strong>29E-11 BZ<br />

Gross Alpha<br />

8.01E-03<br />

Gross Beta<br />

1.40E-02<br />

Uranium-238 9.45E-04 1.24E-08 1.17E- 11<br />

Pathway Total<br />

S WMU Total<br />

WAG 7. SWMU 133. RSO-Residential Dermal Contact with Soil<br />

Lead 5.97E-06 B2 26<br />

Acenaphthylene <strong>4.</strong>3 1E-08 2<br />

Benzo( a)anthracene 3.23E-07 2.35E+00 B2 2 7.62E-07<br />

Page 9 of 64<br />

6.77E- 13<br />

2.33E-08<br />

1.44E-09<br />

1.44E-09<br />

2.57E-09<br />

1.17E-11<br />

1.58E-09<br />

2.73E-08


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Benzo(a)p yrene 2.43E-07 2.35E+01 B2 2 5.73E-06<br />

Benzo(b)fluoranthene 2.62E-07 2.35E+00 B2 2 6.36E-07<br />

Benzo( g,h,i)perylene 1.44E-07 D 2<br />

Benzo(k)fluoranthene 2.18E-07 2.35E-01 B2 2 5.14E-08<br />

Dibenzo(a,h)anthracene 1.78E-08 2.35E+01 B2 2 <strong>4.</strong>20E-07<br />

Indeno( 1,2,3-cd)pyrene 1.20E-07 2.35E+00 B2 2 2.82E-07<br />

Phenanthrene 2.93E-07 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

7.86E-06<br />

WAG 7, SWMU 133, RSO-Residential External Exposure to Soil<br />

Lead B2 b<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo( a)p yrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

B2<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

B2<br />

D<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

5.00E+00<br />

5.86Bi-00<br />

3.95E-01 5.25E-08<br />

b<br />

b<br />

b 2.07E-08<br />

Pathway Total 2.07E-08<br />

WAG 7, SWMU 133, RSO-Residential Ingestion of Soil for Adult<br />

Lead 2.40E-06 B2<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

8.66E-09<br />

6.50E-08 7.30E-01 B2<br />

<strong>4.</strong>74E-08<br />

Benzo(a)pyrene<br />

<strong>4.</strong>88E-08 7.30E+00 B2 a 3.57E-07<br />

Benzo(b)fluoranthene 5.266-08 7.30E-01 B2<br />

3.84E-08<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

2.90E-08<br />

<strong>4.</strong>39E-08 7.30E-02<br />

D<br />

B2<br />

3.20E-09<br />

Dibenzo(a,h)anthracene 3.58E-09 7.30E+00 B2<br />

2.62E-08<br />

Indene( 1,2,3-cd)pyrene 2.40E-08 7.30E-01 B2<br />

1.76E-08<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

5.88E-08<br />

2.62E+02<br />

3.07E+02<br />

2.07E+01 6.20E-11<br />

D<br />

1.28E-09<br />

Pathway Total<br />

<strong>4.</strong>91E-07<br />

WAG 7, SWMU 133, RSO-Residential Ingestion of Soil for Child<br />

Lead 2.40E-06 B2<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

8.66E-09<br />

6.50E-08 7.30E-01 B2<br />

<strong>4.</strong>74E-08<br />

Benzo(a)pyrene<br />

<strong>4.</strong>88E-08 7.30E+00 B2 a 3.57E-07<br />

Benzo(b)fluoranthene 5.26E-08 7.30E-01 B2<br />

3.84E-08<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

2.90E-08<br />

<strong>4.</strong>39E-08 7.30E-02<br />

D<br />

B2<br />

3.20E-09<br />

Dibenzo(a,h)anthracene 3.58E-09 7.30E+00 B2<br />

2.62E-08<br />

Indeno( 1,2,3-cd)pyrene 2.40E-08 7.30E-01 B2<br />

1.76E-08<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

5.88E-08<br />

2.62E+02<br />

3.07E+02<br />

2.07E+01 6.20E-11<br />

D<br />

1.28E-09<br />

Pathway Total<br />

<strong>4.</strong>91E-07<br />

WAG 7, SWMU 133, RSO-Residential Ingestion of Vegetables<br />

Lead 6.82E-07 B2<br />

Acenaphthylene<br />

Benzo(a)anthracene 1.30E-07 7.30E-01 B2 9.47E-08<br />

Benzo(a)pyrene 5.28E-08 7.30E+00 B2 a 3.85E-07<br />

Benzo(b)fluoranthene 5.68E-08 7.30E-01 B2 <strong>4.</strong>15E-08<br />

Benzo(g,h,i)perylene<br />

D<br />

Benzo(k)fluoranthene <strong>4.</strong>74E-08 7.306-02 B2 3.46E-09<br />

Page 10 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Dibenzo(a,h)anthracene 7.06649 7.30E+00 B2 5.16E-08<br />

Indeno( 1,2,3-cd)pyrene 1.45E-08 7.30E-01 B2 1.06E-08<br />

Phenanthrene 5.35E-07 D<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 3.69E+01 6.20E-11 2.29E-09<br />

Pathway Total<br />

5.90E-07<br />

WAG 7, SWMU 133, RSO-Residential Inhalation of Soil<br />

Lead <strong>4.</strong>97E-11 B2<br />

Acenaphth ylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.80E-13<br />

1.35E-12<br />

1.OlE-12<br />

1 a9E-12<br />

6.02E-13<br />

9.1 1E-13<br />

7.44E- 14<br />

<strong>4.</strong>99E-13<br />

1.22E-12<br />

1.06E-02<br />

1.25E-02<br />

8.41E-04<br />

1.24E-08<br />

B2<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

B2<br />

D<br />

1.04E- 1 1<br />

S WMU- Total<br />

WAG 7, SWMU 134, RSO-Residential Dermal Contact with Soil<br />

Lead 9.57E-07 B2 26<br />

Benzo(a)anthracene 1.lOE-08 2.35E+00 B2 2 2.60E-08<br />

Benzo(a)pyrene 1.03E-08 2.35E+01 B2 2 2.43E-07<br />

Benzo(b)fluoranthene 1.54E-08 2.35E+00 B2 2 3.62E-08<br />

Benzo(g,h,i)perylene 5.45E-09 D 2<br />

Phenanthrene 2.48E-08 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 134, RSO-Residential External Exposure to Soil<br />

Lead B2 b<br />

Benzo(a)anthracene<br />

B2<br />

b<br />

Benzo(a)pyrene<br />

B2 b<br />

Benzo(b)fluoranthene<br />

B2 b<br />

Benzo(g,h,i)perylene<br />

D<br />

h<br />

Phenanthrene<br />

D b<br />

Gross Alpha<br />

3.83E+00<br />

b<br />

Gross Beta<br />

<strong>4.</strong>33E+00<br />

b<br />

Uranium-238<br />

2.94E-01 5.2SE-08<br />

b 1.54E-08<br />

Pathway Total<br />

WAG 7. SWMU 134, RSO-Residential Ingestion of Soil for Adult<br />

Lead 3.85E-07 B2<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo( g,h,i)perylene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.09E-09<br />

<strong>4.</strong>97E-09<br />

D<br />

D<br />

2.22E-09 7.30E-01 B2 1.62E-09<br />

2.07E-09 7.30E+00 B2 a 1.51 E-08<br />

3.09E-09 7.30E-01 B2 2.26E-09<br />

2.01E+02<br />

2.27E+02<br />

1.54E+01 6.20E-11 9.56E-10<br />

Pathway Total<br />

WAG 7, SWMU 134, RSO-Residential Ingestion of Soil for Child<br />

Lead 3.85E-07 B2<br />

Benzo(a)anthracene 2.22E-09 7.30E-01 B2 1.62E-09<br />

Benzo(a)pyrene 2.07E-09 7.30E+00 B2 a 1.51E-08<br />

Benzo(b)fluoranthene 3.09E-09 7.30E-01 B2<br />

2.26E-09<br />

Benzo(g,h,i)perylene 1.09E-09 D<br />

Phenanthrene <strong>4.</strong>97E-09 D<br />

1.04E-11<br />

3.05E-07<br />

1.54E-08<br />

2.00E-08<br />

8.96E-06<br />

Page 11 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Beta<br />

2.27E+02<br />

Uranium-238 1.54E+01 6.20E-11 9.56E-10<br />

Pathway Total<br />

2.00E-08<br />

WAG 7, SWMU 134, RSO-Residential Ingestion of Vegetables<br />

Lead 1.09E-07 B2<br />

Benzo( a)anthracene <strong>4.</strong>43E-09 7.30E-01 B2 3.23E-09<br />

Benzo(a)pyrene 2.24E-09 7.30E+00 B2 a 1.63E-08<br />

Benzo(b)fluoranthene 3.34E-09 7.30E-01 B2 2.44E-09<br />

Benzo(g,h,i)perylene<br />

D<br />

Phenanthrene <strong>4.</strong>53E-08 D<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 8 2.75E+01 6.20E-11 1.70E-09<br />

Pathway Total 2.378-08<br />

WAG 7, SWMU 134, RSO-Residential Inhalation of Soil<br />

Lead 7.98E- 12 B2<br />

Benzo(a)anthracene <strong>4.</strong>60E-14<br />

B2<br />

Benzo( a)pyrene<br />

<strong>4.</strong>30E-14<br />

B2<br />

Benzo(b)fluoranthene 6.41E-14<br />

B2<br />

Benzo(g,h,i)perylene 2.27E-14<br />

D<br />

Phenanthrene<br />

1.03E- 13<br />

D<br />

Gross Alpha<br />

Gross Beta<br />

8.16E-03<br />

9.22E-03<br />

Uranium-238<br />

6.26E-04 1.24E-08<br />

7.76E-12<br />

Pathwav Total<br />

7.76E- 12<br />

S WMU Total<br />

3.64E-07<br />

WAG 7. SWMU 8b. RGW-Residential Dermal Contact with Water<br />

Aluminum<br />

Beryllium<br />

2.43E-06<br />

Cobalt<br />

Iron<br />

Manganese<br />

1.15E-03<br />

Nickel 3.01E-05<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,1 -Dichloroethene <strong>4.</strong>07E-06<br />

1.2-Dichloroethene<br />

Phenanthrene<br />

Trichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

7.51E-06<br />

1.26E-05<br />

3.85E-06<br />

<strong>4.</strong>30E+02<br />

6.00E-01<br />

7.33E-02<br />

4,5<br />

B2 13, 1<br />

26<br />

26<br />

D 38<br />

NA 44<br />

C 31<br />

NA<br />

D 2<br />

NA 57<br />

1.05E-03<br />

2.44E-06<br />

2.83E-07<br />

Pathway Total<br />

WAG 7, SWMU 8b, RGW-Residential Ingestion of Water<br />

Aluminum<br />

7.56E-01<br />

Beryllium 8.28E-04 <strong>4.</strong>30E+00 B2 a 3.56E-03<br />

Cobalt<br />

1.34E-02<br />

Iron 1.93Ei-O 1<br />

Manganese 3.9 1E-01 D<br />

Nickel 1.OZE-02 NA<br />

Silica<br />

7.86E+00<br />

Silicon<br />

1.88E-01<br />

Sulfate<br />

1.25E+01<br />

Sulfide<br />

3.76E-02<br />

1.1-Dichloroethene 1.52E-04 6.00E-01 C a 9.12E-05<br />

I ,2-Dichloroethene 2.39E-03 NA<br />

Phenanthrene 1.57E-05 D<br />

Trichloroethene 8.34E-05 1.1OE-02 NA e 9.17E-07<br />

Page 12 of 64<br />

1.05E-03


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Abha<br />

<strong>4.</strong>28E+05<br />

Gross Beta<br />

2.23E+06<br />

Neptunium-237 6.64E+04 3.00E-10<br />

1.99E-05<br />

Thorium-228 2.18E+04 2.31E-10<br />

5.05E-06<br />

Uranium-234 3.72E+05 <strong>4.</strong>44E-11<br />

1.65E-05<br />

Uranium-23 5 3.12E+04 <strong>4.</strong>70E-11<br />

1.47E-06<br />

Uranium-238 7.83E+05 6.20E-11<br />

<strong>4.</strong>86E-05<br />

Beryllium<br />

Cobalt<br />

Iron<br />

Manganese<br />

Nickel<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1, I-Dichloroethene 7.9 1E-06<br />

1,2-Dichloroethene<br />

Phenanthrene<br />

Trichloroethene<br />

<strong>4.</strong>34E-06<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

8.40E+00<br />

1.20E+00<br />

6.00E-03<br />

3.45E-08<br />

9.68E-08<br />

1.40E-08<br />

1.30E-08<br />

1.24E-08<br />

B2<br />

D<br />

NA<br />

h<br />

C b 9.49E-06<br />

NA<br />

D<br />

NA e 2.61E-08<br />

WAG 7, SWMU 8h, RSO-Residential Dermal Contact with Soil<br />

Aluminum <strong>4.</strong>76E-02 4,5<br />

Arsenic 1.77E-05 3.66E+00 A 8 6.49E-05<br />

Beryllium 3.05E-06 <strong>4.</strong>30E+02 B2 13, 1 1.31E-03<br />

Cobalt 3.39E-05 26<br />

Lead <strong>4.</strong>37E-05 B2 26<br />

Phosphate (ortho)<br />

2.50E-04<br />

Sodium<br />

<strong>4.</strong>76E-04<br />

Thallium 6.78E-07 NA 52<br />

2-Methylnaphthalene 1.05E-06 43<br />

Aroclor- 1260 2.51E-07 8.56E+00 B2 46 2.14E-06<br />

Benzo(a)anthracene 1.51E-06 2.35E+00 B2 2 3.57E-06<br />

Benzo(a)pyrene 2.20E-06 2.35E+01 B2 2 5.19E-05<br />

Benzo(b)fluoranthene 2.49E-06 2.35E+00 B2 2 5.87E-06<br />

Dibenzofuran<br />

2.16E-06<br />

Indeno(l,2,3-cd)pyrene 2.02E-06 2.35E+00 B2 2 <strong>4.</strong>75E-06<br />

Naphthalene 2.21E-06 D 43<br />

Phenanthrene 2.01E-06 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium235<br />

Uranium-238<br />

Pathwav Total<br />

WAG 7. SWMU 8b. RSO-Residential External Exposure to Soil<br />

Aluminum<br />

h<br />

Arsenic A h<br />

Beryllium B2 h<br />

Cobalt<br />

h<br />

Lead B2 h<br />

Phosphate (ortho)<br />

h<br />

9.52E-06<br />

1.45E-03<br />

Page 13 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Sodium<br />

b<br />

Thallium NA b<br />

2-Methylnaphthalene<br />

b<br />

Aroclor- 1260 B2 b<br />

Benzo(a)anthracene B2 b<br />

Benzo(a)pyrene B2 b<br />

Benzo(b)fluoranthene B2 b<br />

Dibenzofuran<br />

b<br />

Indeno( 1,2,3-cd)pyrene B2 b<br />

Naphthalene D b<br />

Phenanthrene D b<br />

Gross Alpha 3.22E+02 b<br />

Gross Beta 5.41 E+02 b<br />

Neptunium-237 6.14E+01 <strong>4.</strong>62E-07 b 2.84E-05<br />

Thorium-228 3.44E+01 9.94E-07 b 3.42E-05<br />

Thorium-230 1.60E+04 <strong>4.</strong>40E-11 b 7.02E-07<br />

Uranium-235 5.92E+00 2.65E-07 h 1.57E-06<br />

Uranium-238 1.16E+02 5.25E-08 b 6.11E-06<br />

Pathway Total<br />

7.09E-05<br />

WAG 7, SWMU 8b, RSO-Residential Ingestion of Soil for Adult<br />

Aluminum<br />

1.91E-02<br />

Arsenic 7.13E-06 1.50E+00 A a 1.07E-05<br />

Beryllium 1.23E-06 <strong>4.</strong>30E+00 B2 a 5.27E-06<br />

Cobalt<br />

1.36E-05<br />

Lead 1.75E-05 B2<br />

Phosphate (ortho)<br />

1.00E-04<br />

Sodium<br />

1.91E-04<br />

Thallium 2.72E-07 NA<br />

2-Methylnaphthalene 2.11E-07<br />

Aroclor-1260 5.04E-08 7.70E+00 B2<br />

3.88E-07<br />

Benzo(a)anthracene 3.04E-07 7.30E-01 B2<br />

2.22E-07<br />

Benzo(a)p yrene <strong>4.</strong>42E-07 7.30E+00 B2 a 3.23E-06<br />

Benzo(b)fluoranthene 5.00E-07 7.30E-01 B2<br />

3.65E-07<br />

Dibenzofuran<br />

<strong>4.</strong>34E-07<br />

Indene( 1,2,3-cd)pyrene <strong>4.</strong>05E-07 7.30E-0 1 B2<br />

2.96E-07<br />

Naphthalene <strong>4.</strong>43E-07 D<br />

Phenanthrene <strong>4.</strong>04E-07 D<br />

Gross Alpha<br />

1.69E+04<br />

Gross Beta<br />

2.84E+04<br />

Neptunium-237 3.22E+03 3.00E-10 9.66E-07<br />

Thorium-228 1.80E+03 2.31E-10 <strong>4.</strong>17E-07<br />

Thorium-230 8.37E+05 3.75E-11 3.14E-05<br />

Uranium-23 5 3.11E+02 <strong>4.</strong>70E-11 1.46E-08<br />

Uranium-238 6.10EM3 6.20E-I 1 3.78E-07<br />

Pathway Total<br />

5.36E-05<br />

WAG 7. SWMU 8b. RSO-Residential Ineestion of Soil for Child<br />

Arsenic 7.13E-06 1.50E+00 A a 1.07E-05<br />

Beryllium 1.23E-06 <strong>4.</strong>30E+00 B2 a 5.27E-06<br />

Cobalt<br />

1.36E-05<br />

Lead 1.75E-05 B2<br />

Phosphate (ortho)<br />

1.00E-04<br />

Sodium<br />

1.91E-04<br />

Thallium 2.72E-07 NA<br />

2-Methylnaphthalene 2.11E-07<br />

Aroclor-1260 5.04E-08 7.70E+00 B2 3.88E-07<br />

Benzo(a)anthracene 3.04E-07 7.30E-01 B2 2.22E-07<br />

Benzo(a)pyrene <strong>4.</strong>42E-07 7.30E+00 B2 a 3.23E-06<br />

Benzo(b)fluoranthene 5.00E-07 7.30E-01 B2 3.65E-07<br />

Dibenzofuran<br />

<strong>4.</strong>34E-07<br />

Indeno( 1.2.3-cd)pyrene <strong>4.</strong>05E-07 7.30E-01 B2<br />

2.96E-07<br />

Naphthalene <strong>4.</strong>43E-07 D<br />

Phenanthrene <strong>4.</strong>04E-07 D<br />

Gross Alpha<br />

1.69E+04<br />

Page 14 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Beta<br />

2.84E+04<br />

Neptunium-237 3.22E+03 3.00E-10<br />

9.66E-07<br />

Thorium-228 1.80E+03 2.3 1E- 10<br />

<strong>4.</strong>17E-07<br />

Thorium-230 8.37E+05 3.75E-11<br />

3.14E-05<br />

Uranium-235 3.11E+02 <strong>4.</strong>70E-11<br />

1.46E-08<br />

Uranium-238 6.10E+03 6.20E-11<br />

3.78E-07<br />

Pathway Total<br />

5.36E-05<br />

WAG 7, SWMU 8b, RSO-Residential Ingestion of Vegetables<br />

Aluminum<br />

Arsenic<br />

3.80E-06 1.50E+00<br />

Beryllium<br />

<strong>4.</strong>59E-03 <strong>4.</strong>30E+00<br />

Cobalt<br />

Iron<br />

Lead<br />

Manganese<br />

Nickel<br />

Phosphate (ortho)<br />

Silica<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Sulfide<br />

Thallium<br />

1,l -Dichloroethene<br />

<strong>4.</strong>99E-06<br />

9.74E-09<br />

9.79E-04 6.00E-01<br />

1,2-Dichloroethene<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

1.28E-08 7.70E+00<br />

Benzo(a)anthracene 6.07E-07 7.30E-01<br />

Benzo(a)pyrene<br />

<strong>4.</strong>78E-07 7.30E+00<br />

Benzo(b)fluoranthene 5.41E-07 7.30E-01<br />

Dibenzofuran<br />

Indeno(l,2,3-cd)pyrene 2.44E-07 7.30E-01<br />

Naphthalene<br />

Phenanthrene<br />

Trichloroethene<br />

2.07E-05<br />

9.1 OE-05<br />

<strong>4.</strong>99E-04 1.10E-02<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

<strong>4.</strong>61E+05 3.00E-10<br />

Thorium-228<br />

2.35E+05 2.31E-10<br />

Thorium-230<br />

2,92E+O5 3.75E-11<br />

Uranium-234<br />

2.06E+06 <strong>4.</strong>44E-11<br />

Uranium-235<br />

1.74E+O5 <strong>4.</strong>70E-11<br />

Uranium-238<br />

Pathwav Total<br />

<strong>4.</strong>36E+06 6.20E-11<br />

A a 5.71E-06<br />

B2 a 1.98E-02<br />

B2<br />

D<br />

NA<br />

NA<br />

C<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

D<br />

NA<br />

a<br />

a<br />

e<br />

5.88E-04<br />

9.85E-08<br />

<strong>4.</strong>43E-07<br />

3.49E-06<br />

3.95E-07<br />

1.78E-07<br />

5.49E-06<br />

1.38E-04<br />

5.43E-05<br />

1.09E-05<br />

9.16E-05<br />

8.16E-06<br />

2.70E-04<br />

WAG 7, SWMU 8b, RSO-Residential Inhalation of Soil<br />

Aluminum<br />

3.97E-07<br />

Arsenic 1.48E-10 5.00E+01 A b 7.40E-09<br />

Beryllium 2.54E-11 8.40E+00 B2 b 2.14E- 10<br />

Cohalt 2.82E- 10<br />

Lead 3.64E- 10 B2<br />

Phosphate (ortho)<br />

2.08E-09<br />

Sodium<br />

3.97E-09<br />

Thallium 5.65E-12 NA<br />

2-Methvlnaphthalene <strong>4.</strong>38E- 12<br />

Aroclor- 1260 1.04E- 12 B2<br />

Benzo(a)anthracene 6.3 1E- 12 B2<br />

Benzo(a)pyrene 9.18E-12 B2<br />

Benzo(b)fluoranthene 1.04E-11 B2<br />

Dibenzofuran 9.00E- 12<br />

Indeno( 1,2,3-cd)pyrene 8.40E-12 B2<br />

Naphthalene 9.20E-12 D<br />

Phenanthrene 8.38E- 12 D<br />

Gross Alpha<br />

6.87E-01<br />

Gross Beta<br />

1,15E+00<br />

Page 15 of 64<br />

2.09E-02


~~<br />

Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Neptunium-237 1.31E-01 3.45E-08 <strong>4.</strong>51E-09<br />

Thorium-228 7.32E-02 9.68E-08 7.09E-09<br />

Thorium-230 3.40E+01 1.72E-08 5.85E-07<br />

Uranium-235 1.26E-02 1.30E-08 1.64E- 10<br />

Uranium-238 2.48E-01 1.24E-08 3.076-09<br />

Pathway Total<br />

6.07E-07<br />

Arsenic 1.93E-06 3.66E+00 A 8 7.07E-06<br />

Beryllium 2.81E-07 <strong>4.</strong>30E+02 B2 13, 1 1.21E-04<br />

Cobalt 5.56E-06 26<br />

Lead 3.90E-06 B2 26<br />

Sodium<br />

<strong>4.</strong>58E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

1.25E+01<br />

Gross Beta<br />

2.56E+01<br />

Uranium-238<br />

1.74E+00 5.25E-08<br />

Pathway Total<br />

WAG 1, SWMU 100% CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Cadmium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234 <strong>4.</strong>44E- 11<br />

Uranium-238<br />

6.20E-11<br />

Pathway Total<br />

A<br />

B2<br />

B2<br />

B1<br />

B2<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

9.13E-08<br />

WAG 1, SWMU 100% CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

9.67E-04<br />

Arsenic <strong>4.</strong>48E-07 1.50E+00 A a 6.72E-07<br />

Beryllium 6.53E-08 <strong>4.</strong>30E+00 BZ a 2.81E-07<br />

Cobalt<br />

1.29E-06<br />

Lead 9.04E-07 BZ<br />

Sodium<br />

1.06E-05<br />

Gross Alpha<br />

6.56E+02<br />

Gross Beta<br />

1.34E+03<br />

Uranium-238 9.13E+01 6.20E-11 5.66E-09<br />

Pathway Total<br />

WAG 1, SWMU 100% CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

9.67E-04<br />

Arsenic<br />

<strong>4.</strong>48E-07 1.50E+00 A a 6.72E-07<br />

Beqllium<br />

6.53E-08 <strong>4.</strong>30E+00 BZ a 2.81E-07<br />

Cobalt<br />

1.29E-06<br />

Lead<br />

9.04E-07<br />

BZ<br />

Sodium<br />

1.06E-05<br />

Gross Alpha<br />

6.56E+02<br />

Gross Beta<br />

1.34E+03<br />

Uranium-238<br />

9.13E+01 6.20E-11 5.66E-09<br />

Pathway Total<br />

WAG 1. SWMU lOOa CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

2.01E-08<br />

9.13E-08<br />

9.59E-07<br />

9.59E-07<br />

Page 16 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Arsenic 9.30E-12 5.OOE+01 A b <strong>4.</strong>65E-10<br />

Beryllium 1.35E-12 8.40E+00 B2 b 1.14E-11<br />

Cobalt<br />

2.68E-11<br />

Lead 1.88E-11 B2<br />

Sodium<br />

2.20E-10<br />

Gross Alpha<br />

2.66E-02<br />

Gross Beta<br />

5.46E-02<br />

Uranium-238 3.71E-03 1.24E-08 <strong>4.</strong>59E-11<br />

Pathway Total<br />

5.22E-10<br />

WAG 1, SWMU IOOa, CSW-Recreational Dermal Contact with Water<br />

Aluminum 4,5<br />

Cadmium 5.04E-07 B1 16, 1<br />

Cobalt 26<br />

Lead 5.91 E-07 B2 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100% RGW-Recreational Ingestion ofFish<br />

Aluminum<br />

Cadmium<br />

B1<br />

Cobalt<br />

Lead<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

<strong>4.</strong>44E-11<br />

6.20E-11<br />

Pathway Total<br />

S WMU Total<br />

1.29E-04<br />

WAG 1, SWMU 100b, CSE-Recreational Demal Contact with Sediment<br />

Alummum 3.25E-03 4s<br />

Arsenic 1.76E-06 3.66E+00 A 8 6.45E-06<br />

Beryllium 2.17E-07 <strong>4.</strong>30E+02 B2 13, 1 9.33E-05<br />

Cobalt 2.81E-06 26<br />

Lead 3.42E-06 B2 26<br />

Sodium<br />

<strong>4.</strong>27E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 5<br />

Uranium-238<br />

Pathway Total<br />

9.97E-05<br />

WAG 1, S WMU 1 OOb, CSE-Recreational External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic<br />

A b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

Sodium<br />

B2 b<br />

b<br />

Gross Alpha<br />

1.96E+01<br />

b<br />

Gross Beta<br />

3.15E+OI<br />

b<br />

Uranium-235<br />

1.85E+00 2.65E-07 b <strong>4.</strong>90E-07<br />

Uranium-238<br />

5.59E+00 5.25E-08 b 2.93E-07<br />

Pathway Total<br />

7.83E-07<br />

WAG 1. SWMU 100b, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Arsenic 1.50E+00 A a<br />

Lead<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234 <strong>4.</strong>44E- 11<br />

Page 17 of 64


Excess Lifetime Cancer Risks (continued)<br />

AN-<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Uranium-235<br />

<strong>4.</strong>70E-11<br />

Uranium-238<br />

6.20E-11<br />

Pathway Total<br />

WAG 1, SWMU 100h, CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

7.53E-04<br />

Arsenic<br />

<strong>4.</strong>09E-07 1.50E+00 A a 6.13E-07<br />

Beryllium<br />

5.03E-08 <strong>4.</strong>30E+00 B2 a 2.16E-07<br />

Cobalt<br />

Lead<br />

6.53E-07<br />

7.94E-07<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

9.91E-06<br />

1.03E+03<br />

1.65E+03<br />

9.70E+01 <strong>4.</strong>70E-11 <strong>4.</strong>56E-09<br />

Uranium-238<br />

2.93E+02 6.20E-11 1.82E-08<br />

Pathwav Total<br />

8.52E-07<br />

WAG 1, SWMU IOOb, CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

7.53E-04<br />

Arsenic <strong>4.</strong>09E-07 1.50E+00 A a 6.13E-07<br />

Beryllium 5.03E-08 <strong>4.</strong>30E+00 B2 a 2.16E-07<br />

Cobalt<br />

6.53E-07<br />

Lead 7.94E-07 B2<br />

Sodih<br />

9.91E-06<br />

Gross Alpha<br />

1.03E+03<br />

Gross Beta<br />

1.65E+03<br />

Uranium-23 5 9.70E+01 <strong>4.</strong>70E-11 <strong>4.</strong>56E-09<br />

Uranium-238 2.93E+02 6.20E-11 1.82E-08<br />

Pathway Total<br />

8.52E-07<br />

WAG 1, SWMU IOOb, CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

1.56E-08<br />

Arsenic<br />

8.48E-12 5.OOE+01 A b <strong>4.</strong>24E-10<br />

Beryllium<br />

1.04E-12 8.40E+00 B2 h 8.77E-12<br />

Cobalt<br />

Lead<br />

1.35E-11<br />

1.6SE-11<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

2.06E-10<br />

<strong>4.</strong>17E-02<br />

6.71E-02<br />

3.94E-03 1.30E-08 5.12E-I1<br />

Uranium-238<br />

1.19E-02 1.24E-08 1.48E- 10<br />

Pathway Total 6 32E-10<br />

WAG 1, SWMU 100b, CSW-Recreahonal Dermal Contact with Water<br />

Alummum<br />

4s<br />

Arsenic 5 31E-08 3 66E+00 A 8 194E-07<br />

Lead 103E-06 B2 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.94E-07<br />

Q'AG 1, SWMU 100b. RGW-Recreahonal Ingeshon of Fish<br />

Alummum<br />

Arsenic<br />

1.50E+00 A a<br />

Lead<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

<strong>4.</strong>44E- 11<br />

<strong>4.</strong>70E-11<br />

6.20E-11<br />

Page 18 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Arsenic 3.12E-11 1.50E+00 A a <strong>4.</strong>68E-11<br />

Beryllium 9.34E-13 <strong>4.</strong>30E+00 B2 a <strong>4.</strong>02E- 12<br />

Cobalt<br />

Lead 1. ME-1 1 B2<br />

Sodium<br />

Thallium 5.54E-12 NA<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene <strong>4.</strong>52E- 13 D<br />

Phenanthrene <strong>4.</strong>71E- 12 D<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237 <strong>4.</strong>74E-08 3.00E-10 1.42E- 17<br />

Thorium-228 3.63E-03 2.31E-10 8.39E-13<br />

Uranium-238 <strong>4.</strong>52E-08 6.20E-11 2.80E-18<br />

Pathway Total<br />

5.16E-11<br />

S WMU Total<br />

5.16E-11<br />

WAG 1, SWMU 136, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Arsenic<br />

7.88E-13 1.50E+00 A a 1.18E-12<br />

Beryllium<br />

3.30E-14 <strong>4.</strong>30E+00 B2 a 1.42E-13<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

1,1,1 -Trichloroethane<br />

1,1 -Dichloroethene<br />

3.00E- 13<br />

2.07E- 13<br />

8.04E-16<br />

2.73E-16 6.00E-01<br />

B2<br />

NA<br />

D<br />

C a 1.64E- 16<br />

Benzo(a)anthracene 3.55E-13 7.30E-01 B2<br />

2.59E-13<br />

Benzo(a)pyrene<br />

8.24E-13 7.30E+00 B2 a 6.02E-12<br />

Benzo(b)fluoranthene 8.63E-13 7.30E-01 B2<br />

6.30E-13<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene 1.34E-13 7.30E+00<br />

D<br />

B2<br />

9.79E- 13<br />

Indeno( 1,2,3-cd)pyrene 1.70E-12 7.30E-01 B2<br />

1.24E- 12<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

2.71E- 14<br />

7.05E-10 6.20E-11<br />

D<br />

<strong>4.</strong>37E-20<br />

Pathway Total<br />

1.04E-11<br />

SWMU Total 1.04E- 11<br />

WAG I, SWMU 38% CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 1.56E-03 <strong>4.</strong>5<br />

Beryllium 5.42E-07 <strong>4.</strong>30E+02 B2 13, 1 2.33E-04<br />

Cobalt 3.42E-06 26<br />

Lead 3.12E-06 B2 26<br />

Sodium<br />

1.41E-05<br />

Vanadium 3.29E-05 NA 58, 5<br />

Phenanthrene 6.78E-08 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.33E-04<br />

WAG 1, SWMU 38a, CSE-Recreational External Exposure to Sediment<br />

Aluminum<br />

b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

Sodium<br />

B2 b<br />

b<br />

Vanadium<br />

NA b<br />

Phenanthrene<br />

D b<br />

Gross Alpha<br />

1.14Ei-01<br />

b<br />

Gross Beta<br />

1.49E+O 1<br />

b


Excess Lifetime Cancer Risks (continued)<br />

Y '1'6 '1'0 I'AL I'U'IAL<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Uranium-238 3.58E+00 5.25E-08<br />

b 1.88E-07<br />

Pathway Total<br />

1.88E-07<br />

WAG 1, SWMU 38% CSE-Recreational Ingestion of Deer<br />

Arsenic 1.50E+00 A a<br />

Lead<br />

B2<br />

Sodium<br />

Chloroform 6.10E-03 B2 a<br />

bis(2-Ethylhexy1)phthalate 1.40E-02 B2 a<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

6.20E-11<br />

Pathway Total<br />

WAG 1, SWMU 38% CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

3.62E-04<br />

Beryllium 1.26E-07 <strong>4.</strong>30E+00 B2 a 5.41E-07<br />

Cobalt<br />

7.94E-07<br />

Lead 7.23E-07 B2<br />

Sodium<br />

3.26E-06<br />

Vanadium 7.64E-06 NA<br />

Phenanthrene 7.86E-09 D<br />

Gross Alpha<br />

5.99E+02<br />

Gross Beta<br />

7.83E+02<br />

Uranium-238 1.88E+02 6.20E-11 1.16E-08<br />

Pathway Total<br />

5.53E-07<br />

WAG 1, SWMU 38% CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

3.62E-04<br />

Beryllium 1.26E-07 <strong>4.</strong>30E+00 B2 a 5.41 E-07<br />

Cobalt<br />

7.94E-07<br />

Lead 7.23E-07 B2<br />

Sodium<br />

3.26E-06<br />

Vanadium 7.64E-06 NA<br />

Phenanthrene 7.86E-09 D<br />

Gross Alpha<br />

5.99E+02<br />

Gross Beta<br />

7.83E+02<br />

Uranium-238 1.88E+02 6.20E-11 1.16E-08<br />

Pathway Total<br />

5.53E-07<br />

WAG 1, SWMU 38% CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

7.50E-09<br />

Beryllium<br />

2.6lE-12 8.40E+00 B2 h 2.19E-11<br />

Cobalt<br />

Lead<br />

1.65E-11<br />

1.50E-11<br />

B2<br />

Sodium<br />

Vanadium<br />

6.77E-11<br />

1.59E- 10<br />

NA<br />

Phenanthrene<br />

1.63E- 13<br />

D<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

2.43E-02<br />

3.18E-02<br />

7.61E-03 1.24E-08 9.44E-11<br />

~ ~.<br />

Pathway Total<br />

1.16E-10<br />

WAG 1. SWMU 38% CSW-Recreational Dermal Contact with Water<br />

Arsenic <strong>4.</strong>17E-08 3.66E+00 A 8 1.53E-07<br />

Lead 2.16E-07 B2 26<br />

Sodium<br />

Chloroform 1.35E-06 3.05E-02 B2 24 <strong>4.</strong>13E-08<br />

bis(2-Ethylhexy1)phthalate 1.76E-06 7.37E-02 B2 I5 1.30E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.24E-07<br />

K'AG 1, SWMU 38% RGW-Recreational Ingestion of Fish<br />

Arsenic 1.50E+00 A a<br />

Lead<br />

B2<br />

Sodium<br />

Chloroform 6.10E-03 B2 a<br />

bis(2-Ethvlhexyl)phth~atr 1.40E-02 B2 a<br />

Page 20 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

6.20E-11<br />

Pathway Total<br />

SWN-Total<br />

2.34E-04<br />

WAG 1, SWMU 38b, CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 3.0 1E-03 4s<br />

Arsenic 1.22E-06 3.66E+00 A 8 <strong>4.</strong>46E-06<br />

Beryllium 1.59E-07 <strong>4.</strong>30E+02 B2 13, 1 6.85E-05<br />

Cobalt 2.27E-06 26<br />

Lead 6.17E-06 B2 26<br />

Sodium<br />

2.39E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

7.30E-05<br />

WAG 1, SWMU 38b, CSE-Recreational External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic<br />

A b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

Sodium<br />

B2 b<br />

b<br />

Gross Alpha<br />

1.36E+O 1<br />

b<br />

Gross Beta<br />

2.88E+01<br />

b<br />

Uranium-238<br />

2.84E+00 5.25E-08 b 1.49E-07<br />

Pathway Total<br />

1.49E-07<br />

WAG 1, SWMU 38b, CSE-Recreational Ingestion of Deer<br />

Aluminum<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

3.00E- 10<br />

2.95E-10<br />

<strong>4.</strong>44E- 1 1<br />

6.20E-11<br />

Pathway Total<br />

WAG 1, SWMU 38b, CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

6.98E-04<br />

Arsenic 2.83E-07 1.50E+00 A a <strong>4.</strong>25E-07<br />

Beryllium 3.70E-08 <strong>4.</strong>30E+00 B2 a 1.59E-07<br />

Cobalt<br />

5.27E-07<br />

Lead 1.43E-06 B2<br />

Sodium<br />

5.54E-06<br />

Gross Alpha<br />

7.12E+02<br />

Gross Beta 1.51E+03<br />

Uranium-238 1.49E+02 6.20E- 11 9.22E-09<br />

Pathway Total<br />

WAG 1, SWMU 38b, CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

6.98E-04<br />

Arsenic 2.83E-07 1.50E+00 A a <strong>4.</strong>25E-07<br />

Beryllium 3.70E-08 <strong>4.</strong>30E+00 B2 a 1.59E-07<br />

Cobalt<br />

5.27E-07<br />

Lead 1.43E-06 B2<br />

Sodium<br />

5.54E-06<br />

Gross Alpha<br />

7.12E+02<br />

Gross Beta 1.51E+03<br />

Uranium-238 1.49E+02 6.20E-11 9.22E-09<br />

Pathway Total<br />

WAG 1. SWMU 38b, CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

1.45E-08<br />

Arsenic<br />

5.87E-12 S.OOE+O 1 A b 2.94E-10<br />

Beryllium<br />

7.67E-13 8.40E+00 B2 b 6.44E- 12<br />

5.93E-07<br />

5.93E-07<br />

Page 21 of64


Excess Lifetime Cancer Risks (continued)<br />

A N m T o r -<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 2.97E-11 B2<br />

Sodium 1.15E- 10<br />

Gross Alpha<br />

2.89E-02<br />

Gross Beta<br />

6.13E-02<br />

Uranium-238 6.04E-03 1.24E-08 7.49E- 11<br />

Pathway Total<br />

3.75E-10<br />

WAG 1, SWMU 38b, CSW-Recreational Dermal Contact with Water<br />

Aluminum<br />

4s<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

WAG 1. SWMU 38b. RGW-Recreational Ineestion of Fish<br />

Aluminum<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-23 8<br />

3.00E- 10<br />

2.95E-10<br />

<strong>4.</strong>44E- 11<br />

6.20E-11<br />

Pathway Total<br />

S WMU Total<br />

7.37E-05<br />

WAG 1, SWMU 38c, CSE-Recreational Ingestion of Deer<br />

Alummum<br />

Arsenic<br />

Beyllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo( a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWhKJ Total<br />

1.2 1E- 10<br />

3.79E- 12<br />

5.09E-11<br />

3.84E-11<br />

1.28E-10<br />

2.56E-11<br />

<strong>4.</strong>83E-11<br />

7.06E- 1 1<br />

9.06E-12<br />

1.54E-05<br />

1.08E-02<br />

6.28E-09<br />

2.07E-06<br />

1.50E+00<br />

<strong>4.</strong>30E+00<br />

7.70E+00<br />

7.30E-01<br />

7.30E+00<br />

7.3OE-01<br />

3.00E- IO<br />

2.3 1E- 10<br />

<strong>4.</strong>70E- 1 1<br />

6.20E-11<br />

A<br />

B2<br />

B2<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

R’AG 7. SWMU 130, CSE-Recreational Ingestion of Deer<br />

Lead 1.51E- 13 B2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 <strong>4.</strong>25E-10 6.20E-11<br />

Pathway Total<br />

S WMU Total<br />

R’AG 7, SWMU 131, CSE-Recreabonal Ingestion of Deer<br />

Lead 2.87E- 14 B2<br />

Gross Alpha<br />

Gross Beta<br />

a<br />

a<br />

a<br />

1.82E-10<br />

1.63E-11<br />

9.88E- 10<br />

1.87E-11<br />

3.53E-10<br />

5.15E- 11<br />

<strong>4.</strong>62E- 15<br />

2.49E-12<br />

2.95E-19<br />

1.28E-16<br />

2.63E-20<br />

Uranium-238 5.96E-11 6.20E-11 3.69E-21<br />

Pathway Total<br />

SWMU Total<br />

WAG 7. SR’MU 132. CSE-Recreabonal Ingestion of Deer<br />

Page 22 of 64<br />

1.61E-09<br />

2.63E-20<br />

3.69E-21<br />

1.61E-09<br />

2.63E-20<br />

3.69E-21


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 2.35E-12 BZ<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 1.29E-09 6.20E- 11 7.98E-20<br />

Pathway Total<br />

7.98E-20<br />

S WMU Total<br />

7.98E-20<br />

WAG 7, SWMU 133, CSE-Recreational Ingestion of Deer<br />

Lead 2.73E-12 BZ<br />

Acenaphthylene<br />

Benzo(a)anthracene 3.42E-12 7.30E-01<br />

2.49E- 12<br />

Benzo( a)pyrene<br />

5.60E-12 7.30E+00<br />

a <strong>4.</strong>09E-11<br />

Benzo(b)fluoranthene 6.03E-12 7.30E-01<br />

<strong>4.</strong>40E-12<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene 5.03E-12 7.30E-02<br />

3.67E- 13<br />

Dibenzo(a,h)anthracene 1.91E-13 7.30E+00<br />

1.40E-12<br />

Indeno( 1,2,3-cd)pyrene 6.29E-12 7.30E-01<br />

<strong>4.</strong>59E- 12<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

6.50E-13<br />

1.21E-09 6.20E-11<br />

7.51E-20<br />

Pathway Total<br />

5.41E-11<br />

SWMU-Total<br />

5.41E-11<br />

WAG 7, SWMU 134, CSE-Recreational Ingestion of Deer<br />

Lead <strong>4.</strong>38E-13 B2<br />

Benzo(a)anthracene 1.17E-13 7.30E-01 B2 8.52E-14<br />

Benzo(a)pyrene 2.38E-13 7.30E+00 B2 a 1.73E- 12<br />

Benzo(b)fluoranthene 3.54E-13 7.30E-01 B2 2.59E-13<br />

Benzo(g,h,i)perylene<br />

D<br />

Phenanthrene 5.50E-14 D<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238 6.71510 6.20E-11 <strong>4.</strong>16E-20<br />

Pathway Total 2.08E- 12<br />

SWMU Total 2.08E- 12<br />

WAG 7, SWMU 8% CSE-Recreational Dermal Contact with Sediment<br />

Aluminum 1.36E-03 4s<br />

Arsenic 2.88E-06 3.66E+00 A 8 1.06E-05<br />

Beryllium 3.04E-07 <strong>4.</strong>30E+02 BZ 13, 1 1.31E-04<br />

Cobalt 5.16E-06 26<br />

Lead 3.87E-06 BZ 26<br />

Sodium<br />

<strong>4.</strong>50E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.41E-04<br />

WAG 7. SWMU 8a CSE-Recreational External Emosure to Sediment<br />

Aluminum<br />

b<br />

Arsenic<br />

A b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

Sodium<br />

B2 b<br />

b<br />

Gross Alpha<br />

9.64E+00<br />

b<br />

Gross Beta<br />

1.59E+01<br />

b<br />

Uranium-238<br />

1.16E+00 5.25E-08 b 6.06E-08<br />

Pathway Total<br />

6.06E-08<br />

WAG 7, SWMU 8% CSE-Recreational Ingestion of Deer<br />

Aluminurn<br />

Antimony<br />

NA<br />

Arsenic 2.01E-09 1.50E+00 A a 3.0 1E-09<br />

Barium<br />

NA<br />

Beryllium <strong>4.</strong>54E-08 <strong>4.</strong>30E+00 BZ a 1.95E-07<br />

Cadmium<br />

B1<br />

Cobalt<br />

Page 23 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Iron<br />

Lead<br />

Manganese<br />

Nickel<br />

Phosphate (ortho)<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

Tungsten<br />

Vanadium<br />

Zirconium<br />

2.50E-06<br />

3.03E-05<br />

B2<br />

D<br />

NA<br />

NA<br />

NA<br />

1,l-Dichloroethene<br />

1,2-Dichloroethene<br />

2-Methylnaphthalene<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Methylene Chloride<br />

Naphthalene<br />

Phenanthrene<br />

Trichloroethene<br />

bis(2-Ethylhexy1)phthalate<br />

cis- 1,2-Dichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

8.28E-12<br />

2.20E-09<br />

7.04E-10<br />

2.23E-09<br />

2.52E-09<br />

<strong>4.</strong>66E-09<br />

5.69E-11<br />

1.96E-10<br />

1.14E-I1<br />

1.86E- 13<br />

1.02E-03<br />

2.80E-01<br />

9.64E-03<br />

3.75E+00<br />

9.55E-08<br />

2.71E-04<br />

6.00E-01<br />

7.70E+00<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

7.30E-01<br />

7.50E-03<br />

1.1 OE-02<br />

1.40E-02<br />

3.00E- 10<br />

2.3 1E-10<br />

3.75E-11<br />

<strong>4.</strong>44E-11<br />

<strong>4.</strong>70E-11<br />

6.20E-11<br />

C<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

D<br />

NA<br />

B2<br />

D<br />

a<br />

a<br />

a<br />

e<br />

a<br />

<strong>4.</strong>97E-12<br />

1.70E-08<br />

5.14E- 10<br />

1.63E-08<br />

1.84E-09<br />

3.40E-09<br />

1.26E-13<br />

2.6 1 E- 15<br />

3.05E-13<br />

6.48E-11<br />

3.62E- 13<br />

1.67E- 10<br />

<strong>4.</strong>49E-18<br />

1.68E-14<br />

Pathwav Total<br />

2.37E-07<br />

WAG 7, SWMU 8% CSE-Recreational Ingestion of Sediment for Adult<br />

Aluminum<br />

3.16E-04<br />

Arsenic<br />

6.69E-07 1.50E+00 A a 1.00E-06<br />

Beryllium<br />

7.06E-08 <strong>4.</strong>30E+00 B2 a 3.04E-07<br />

Cobalt<br />

Lead<br />

1.20E-06<br />

8.97E-07<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.04E-05<br />

5.06E+02<br />

8.34E+02<br />

6.06E+01 6.20E-11 3.76E-09<br />

Pathway Total 1.31E-06<br />

WAG 7, SWMU 8% CSE-Recreational Ingestion of Sediment for Child<br />

Aluminum<br />

3.16E-04<br />

Arsenic 6.69E-07 1.50E+00 A a 1.00E-06<br />

Beryllium 7.06E-08 <strong>4.</strong>30E+00 B2 a 3.04E-07<br />

Cobalt<br />

1.20E-06<br />

Lead 8.97E-07 B2<br />

Sodium<br />

1.04E-05<br />

Gross Alpha<br />

5.06E+02<br />

Gross Beta<br />

8.34E+02<br />

Uranium-238 6.06E+01 6.20E-11 3.76E-09<br />

Pathway Total 1.31E-06<br />

WAG 7. SWMU 8a CSE-Recreational Inhalation of Sediment<br />

Aluminum<br />

6.55E-09<br />

Arsenic 1.39E-11 5.OOE+01 A h 6.94E- 10<br />

Beryllium 1.46E-12 8.40E+00 B2 h 1.23E-11<br />

Page 24 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Cobalt<br />

2.48E-11<br />

Lead 1.86E-11 B2<br />

Sodium<br />

2.17E-10<br />

Gross Alpha<br />

2.05E-02<br />

Gross Beta<br />

3.38E-02<br />

Uranium-238 2.46E-03 1.24E-08 3.05E-11<br />

Pathway Total 7.37E- 10<br />

WAG 7, SWMU 8% CSW-Recreational Dermal Contact with Water<br />

Aluminum<br />

4s<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Cobalt<br />

Iron<br />

Lead<br />

Manganese<br />

Nickel<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

Tungsten<br />

Vanadium<br />

Zirconium<br />

1,l-Dichloroethene<br />

1,2-Dichloroethene<br />

Methylene Chloride<br />

Trichloroethene<br />

bis(2-Ethylhexy1)phthalate<br />

7.09E-07<br />

<strong>4.</strong>27E-08<br />

1.60E-06<br />

1.19E-07<br />

9.1 IE-08<br />

1.32E-05<br />

6.65E-04<br />

1.89E-06<br />

2.05E-05<br />

9.11E-08<br />

1.12E-07<br />

<strong>4.</strong>82E-07<br />

6.26E-08<br />

8.826-08<br />

3.66E+00<br />

<strong>4.</strong>30E+02<br />

6.00E-01<br />

7.89E-03<br />

7.33E-02<br />

7.37E-02<br />

NA<br />

A<br />

NA<br />

B2<br />

B1<br />

B2<br />

D<br />

NA<br />

NA<br />

NA<br />

C<br />

NA<br />

B2<br />

NA<br />

B2<br />

7<br />

8<br />

9<br />

13, 1<br />

16, 1<br />

26<br />

26<br />

26<br />

38<br />

44<br />

52<br />

58, 5<br />

12<br />

31<br />

41<br />

57<br />

15<br />

1.56E-07<br />

5.10E-05<br />

5.46E-08<br />

3.81E-09<br />

<strong>4.</strong>59E-09<br />

6.50E-09<br />

cis- 1,2-Dichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-238<br />

8.15E-07<br />

D 83<br />

Pathway Total<br />

5.12E-OS<br />

WAG 7, SWMU 8% RGW-Recreational Ingestion of Fish<br />

Aluminum<br />

Antimony<br />

9.75E-05<br />

Arsenic<br />

Barium<br />

Bevllium<br />

Cadmium<br />

2.75E-05<br />

Cobalt<br />

Iron<br />

Lead<br />

5.9 IE-05<br />

Manganese<br />

3.23E-01<br />

Nickel<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

7.25E-04<br />

Tungsten<br />

Vanadium<br />

2.92E-04<br />

Zirconium<br />

1.1-Dichloroethene<br />

NA<br />

6.87E-06 1.50E+00 A a 1.03E-05<br />

NA<br />

<strong>4.</strong>30E+00 B2 a<br />

B1<br />

B2<br />

D<br />

NA<br />

NA<br />

NA<br />

6.00E-01 C a<br />

Page 25 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Methylene Chloride 9.98E-07 7.50E-03 B2 a 7.486-09<br />

Trichloroethene 1.1OE-02 NA e<br />

bis(2-Ethylhexy1)phthalate 1.40E-02 B2 a<br />

cis- 1,2-Dichloroethene<br />

D<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

3.00E-IO<br />

Thorium-228<br />

2.31E-10<br />

Uranium-234<br />

<strong>4.</strong>44E-11<br />

Uranium-238<br />

6.20E-11<br />

Pathway Total<br />

1.03E-05<br />

SWMU Total<br />

2.05E-04<br />

WAG 1, SWMU lOOa ESE-Excavation Dermal Contact with Sediment<br />

Aluminum <strong>4.</strong>13E-05 4s<br />

Arsenic 1.91E-OS 3.66E+00 A 8 7.00E-08<br />

Beryllium 2.78E-09 <strong>4.</strong>30E+02 B2 13, 1 1.20E-06<br />

Cobalt 5.5OE-08 26<br />

Lead 3.86E-08 B2 26<br />

Sodium<br />

<strong>4.</strong>53E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.27E-06<br />

WAG 1. SWMU lOOa ESE-Excavation External ExDosure to Sediment<br />

Aluminum<br />

Arsenic<br />

A b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

Sodium<br />

B2 b<br />

b<br />

Gross Alpha<br />

1.33E-01<br />

b<br />

Gross Beta<br />

2.73E-01<br />

b<br />

Uranium-238<br />

1.86E-02 5.25E-08 b 9.74E- 10<br />

Pathway Total 9.74E- 10<br />

WAG 1, SWMU 100% ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

6.60E-05<br />

Arsenic 3.06E-08 1.50E+00 A a <strong>4.</strong>59E-OX<br />

Beryllium <strong>4.</strong>46E-09 <strong>4.</strong>30E+00 B2 a 1.92E-08<br />

Cobalt<br />

8.80E-08<br />

Lead 6.17E-08 B2<br />

Sodium<br />

7.25E-07<br />

Gross Alpha<br />

8.76EM1<br />

Gross Beta<br />

1.80EM2<br />

Uranium-238 1.22EM1 6.20E-11 7.56E- 10<br />

Pathway Total<br />

6.58E-08<br />

WAG 1, SWMU 100% ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

1.00E-09<br />

Arsenic<br />

<strong>4.</strong>64E-13 5.OOE+01 A b 2.32E-11<br />

Beryllium<br />

6.76E-14 8.40E+00 B2 b 5.68E-13<br />

Cobalt<br />

Lead<br />

1.34E-12<br />

9.36E- 13<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.1OE- 11<br />

1.33E-03<br />

2.72E-03<br />

1.85E-04 1.24E-08 2.29E-12<br />

Pathway Total<br />

2.61E-11<br />

Arsenic 1.74E-08 3.66EM0 A 8 6.38E-08<br />

Beryllium 2.15E-09 <strong>4.</strong>30E+02 B2 13, 1 9.23E-07<br />

Cobalt 2.78E-08 26<br />

Lead 3.39E-08 B2 26<br />

Sodium<br />

<strong>4.</strong>23E-07<br />

Page 26 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

9.87E-07<br />

WAG 1, SWMU 100b, ESE-Excavation External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic<br />

A b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

Sodium<br />

B2<br />

h<br />

b<br />

Gross Alpha<br />

2.09E-01<br />

b<br />

Gross Beta<br />

3.36E-01<br />

b<br />

Uranium-235<br />

1.97E-02 2.65E-07 b 5.23E-09<br />

Uranium-238<br />

5.96E-02 5.25E-08 b 3.13E-09<br />

Pathway Total<br />

8.36E-09<br />

WAG 1, SWMU 100b, ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

5.14E-05<br />

Arsenic<br />

2.79E-08 1.5OE+00 A a <strong>4.</strong>19E-08<br />

Beryllium<br />

3.44E-09 <strong>4.</strong>30E+00 B2 a 1.48E-08<br />

Cobalt<br />

Lead<br />

<strong>4.</strong>46E-08<br />

5.42E-08<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

6.76E-07<br />

1.37E+02<br />

2.21E+02<br />

1.30E+01 <strong>4.</strong>70E-11 6.09E-10<br />

Uranium-238<br />

3.92E+01 6.20E-11 2.43E-09<br />

Pathway Total<br />

5.97E-08<br />

WAG 1, SWMU IOOb, ESE-Excavation Inhalation of Sediment<br />

Aluminum 7.80E- 10<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

<strong>4.</strong>23E-13 5.00E+01 A b 2.12E-11<br />

5.21E-14 8.40E+00 B2 b <strong>4.</strong>38E- 13<br />

6.76E-13<br />

8.22E-13<br />

B2<br />

1.03E- 11<br />

2.08E-03<br />

3.35E-03<br />

1.97E-04 1.30E-08 2.56E-12<br />

5.94E-04 1.24E-08 7.37E-12<br />

WAG 1, SWMU lOOc, ESO-Excavation Dermal Contact with Soil<br />

Alummum 3.53E-05 45<br />

Arsenic<br />

2.1 1E-08 3.66E+00 A<br />

Beryllium<br />

1.88E-09 <strong>4.</strong>30E+02 B2<br />

Cobalt<br />

Lead<br />

2.98E-08<br />

<strong>4.</strong>36E-08<br />

B2<br />

Sodium<br />

1.41 E-06<br />

Thallium<br />

2.40E-IO<br />

NA 52<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

2.22E-09<br />

5.43E-IO<br />

7.41E-12<br />

7.65E-12<br />

1.34E-09<br />

D<br />

43<br />

43<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

3.69E-09<br />

D 2<br />

Pathwav Total<br />

WAG 1, SWMU IOOc, ESO-Excavation External Exposure to Soil<br />

8 7.72E-08<br />

13, 1 8.10E-07<br />

26<br />

26<br />

3.15E-11<br />

8.88E-07<br />

1.06E-06<br />

Page 27 of 64


~<br />

Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Arsenic A b<br />

Beryllium B2 b<br />

Cobalt<br />

b<br />

Lead B2 b<br />

Sodium<br />

b<br />

Thallium NA b<br />

2-Methvlnaphthalene<br />

b<br />

3-Nitroaniline<br />

b<br />

Endosulfan Sulfate<br />

b<br />

Endrin Ketone<br />

b<br />

Naphthalene D b<br />

Phenanthrene D b<br />

Gross Alpha 2.08E-01 b<br />

Gross Beta 3.30E-01 b<br />

Neptunium-237 2.19E-03 <strong>4.</strong>62E-07 b 1.01E-09<br />

Thorium-228 1.93E-02 9.94E-07 b 1.92E-08<br />

Uranium-238 1.89E-02 5.25E-08 b 9.91 E- 10<br />

Pathway Total<br />

2.12E-08<br />

WAG 1. SWMU IOOc, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

5.65E-05<br />

Arsenic 3.37E-08 1.50E+00 A a 5.06E-08<br />

Beryllium 3.02E-09 <strong>4.</strong>30E+00 B2 a 1.30E-08<br />

Cobalt<br />

<strong>4.</strong>77E-08<br />

Lead 6.98E-08 B2<br />

Sodium<br />

2.25E-06<br />

Thallium 3.84E- 10 NA<br />

2-Methylnaphthalene 1.78E-09<br />

3-Nitroaniline<br />

<strong>4.</strong>35E-10<br />

Endosulfan Sulfate 5.93E-12<br />

Endrin Ketone 6.12E- 12<br />

Naphthalene<br />

1.07E-09<br />

D<br />

Phenanthrene<br />

2.95E-09<br />

D<br />

Gross Alpha<br />

1.37E+02<br />

Gross Beta<br />

2.17E+02<br />

Neptunium-237 1.44E+00 3.00E-10 <strong>4.</strong>32E-10<br />

Thorium-228 1.27E+01 2.31E-10 2.93E-09<br />

Uranium-238 1.24E+O 1 6.20E- 11 7.69E-10<br />

Pathwav Total<br />

6.77E-08<br />

WAG 1, SWMU lOOc, ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

8.57E-10<br />

Arsenic<br />

5.12E-13 5.00E+01 A b 2.56E-11<br />

Beryllium<br />

<strong>4.</strong>57E-14 8.40E+00 B2 b 3.84E- 13<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

7.23E-13<br />

1.06E-12<br />

3.42E-11<br />

5.83E- 15<br />

2.70E- 14<br />

6.6OE-15<br />

8.99E- 17<br />

9.28E-17<br />

1.63E- 14<br />

<strong>4.</strong>47E- 14<br />

2.08E-03<br />

3.29E-03<br />

2.18E-05 3.45E-08<br />

B2<br />

NA<br />

D<br />

D<br />

7.54E-13<br />

Thorium-228<br />

3.92E-04 9.68E-08<br />

1.86E- 11<br />

Uranium-238<br />

1.88E-04 1.24E-08<br />

2.33E-12<br />

Pathway Total<br />

<strong>4.</strong>77E-11<br />

SWMU Total<br />

9.77s-07<br />

WAG 1. SWMU 136, ESO-Excavation Dermal Contact with Soil<br />

A I u m m u m 3.71E-05 4s<br />

Arsenic 1.33E-08 3.66E+00 A 8 <strong>4.</strong>87E-08<br />

Beryllium 1.66E-09 <strong>4.</strong>30E+02 B2 13, 1 7.16E-07<br />

Cobalt 3.82E-08 16<br />

Page 28 of 64


Excess Lifetime Cancer Risks (continued)<br />

AN-<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 2.85E-08 B2 26<br />

Sodium<br />

Sulfate<br />

Thallium<br />

I,], I-Trichloroethane<br />

I.04E-06<br />

3.26E-06<br />

2.24E-10<br />

3.10E- 10<br />

NA<br />

D<br />

52<br />

55<br />

1,1 -Dichloroethene 2.01E-10 6.00E-01 C 31 1.21E- 10<br />

Benzo(a)anthracene 1.46E-09 2.35E+00 B2 2 3.44E-09<br />

Benzo(a)pyrene<br />

1 S6E-09 2.35E+01 B2<br />

2 3.66E-08<br />

Benzo(b)fluoranthene 1.63E-09 2.35E+00 B2 2 3.84E-09<br />

Benzo(g,h,i)perylene 1.37E-09<br />

D 2<br />

Dihenzo(qh)anthracene 5.43E-10 2.35E+01 B2 2 1.28E-08<br />

Indeno( 1,2,3-cd)pyrene 1.41E-09 2.35E+00 B2 2 3.31 E-09<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

5.30E- 10<br />

D<br />

2<br />

Pathway Total<br />

WAG 1. SWMU 136. ESO-Excavation External Exoosure to Soil<br />

8.24E-07<br />

Aluminum<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

I,],]-Trichloroethane<br />

1 ,I-Dichloroethene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indene( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

A<br />

B2<br />

BZ<br />

NA<br />

D<br />

C<br />

B2<br />

B2<br />

BZ<br />

D<br />

B2<br />

BZ<br />

D<br />

b<br />

b<br />

b<br />

h<br />

h<br />

h<br />

h<br />

h<br />

b<br />

b<br />

b<br />

h<br />

h<br />

h<br />

b<br />

b<br />

h<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.49E-01<br />

2.18E-01<br />

1.18E-02 5.25E-08<br />

b<br />

b<br />

h 6.19E- 10<br />

Pathway Total 6.19E- 10<br />

WAG 1, SWMU 136, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

5.93E-05<br />

2.13E-08 I.50E+00 A a 3.20E-08<br />

2.66E-09 <strong>4.</strong>30E+00 B2 a 1.14E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

I,],]-Trichloroethane<br />

I,l-Dichloroethene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dihenzo(ah)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

6.11E-08<br />

<strong>4.</strong>56E-08<br />

1.67E-06<br />

5.22E-06<br />

3.59E-10<br />

9.93E-11<br />

6.45E-11<br />

1.17E-09<br />

1.24E-09<br />

1.30E-09<br />

l.lOE-09<br />

<strong>4.</strong>35E-10<br />

1.12E-09<br />

<strong>4.</strong>24E-10<br />

9.82E+01<br />

1.43E+02<br />

7.75E+00<br />

6.00E-01<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

B2<br />

NA<br />

D<br />

C<br />

B2<br />

BZ<br />

B2<br />

D<br />

B2<br />

BZ<br />

D<br />

a<br />

a<br />

3.87E-11<br />

8.52E-10<br />

9.09E-09<br />

9.52E-10<br />

3.17E-09<br />

8.21E-10<br />

6.20E-11<br />

<strong>4.</strong>80E- 10<br />

Pathwav Total<br />

WAG 1. SWMU 136. ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

9.00E-10<br />

Arsenic 3.23E-13 5.00E+01 A h 1.62E-11<br />

Page 29 of 64<br />

5.88E-08


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Beryllium <strong>4.</strong>04E-14 8.40E+00 B2 h 3.39E- 13<br />

Cobalt<br />

9.26E-13<br />

Lead 6.91E-13 B2<br />

Sodium<br />

2.53E-11<br />

Sulfate<br />

7.92E-11<br />

'Ihallium 5.45E-15 NA<br />

l,l,l-Trichloroethane 3.85E- 10 D<br />

1,l-Dichloroethene 6.64E-10 1.20E+00 C h 7.97E-10<br />

Benzo(a)anthracene 1.77E-14 B2<br />

Benzo(a)pyrene 1.89E- 14 B2<br />

Benzo(h)fluoranthene 1.98E- 14 B2<br />

Benzo(g,h,i)perylene 1.67E-14 D<br />

Dihenzo(qh)anthracene 6.60E-15 B2<br />

Indene( 1,2,3-cd)pyrene 1.71E- 14 B2<br />

Phenanthrene 6.43E-15 D<br />

Gross Alpha<br />

1.49E-03<br />

Gross Beta 2.1%-03<br />

Uranium-238 1.18E-04 1.24E-08 1.46E- 12<br />

Pathway Total<br />

8.15E-10<br />

SWMU Total<br />

8.85E-07<br />

WAG 1, SWMU 38q ESE-Excavation Dermal Contact with Sediment<br />

Aluminum 1.54E-05 <strong>4.</strong>5<br />

Beryllium 5.37E-09 <strong>4.</strong>30E42 B2 13, 1 2.31E-06<br />

Cobalt 3.39E-08 26<br />

Lead 3.09E-08 B2 26<br />

Sodium<br />

1.39E-07<br />

Vanadium 3.26E-07 NA 58, 5<br />

Phenanthrene 6.71E-10 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38% ESE-Excavation External Exposure to Sediment<br />

2.31E-06<br />

Aluminum<br />

b<br />

Beryllium<br />

Cobalt<br />

B2<br />

h<br />

h<br />

Lead<br />

Sodium<br />

B2 h<br />

h<br />

Vanadium<br />

NA b<br />

Phenanthrene<br />

D b<br />

Gross Alpha<br />

Gross Beta<br />

1.22E-01<br />

1.59E-01<br />

h<br />

h<br />

Uranium-238 3.81E-02 5.25E-08 b<br />

~<br />

2.OOE-09 _.<br />

Pathway Total<br />

WAG 1, SWMU 38% ESE-Excavation Ingestion of Sediment<br />

2.00E-09<br />

Aluminum<br />

2.47E-05<br />

Beryllium 8.59E-09 <strong>4.</strong>30E+00 B2 a 3.69E-08<br />

Cobalt<br />

5.42E-08<br />

Lead <strong>4.</strong>94E-08 B2<br />

Sodium<br />

2.23E-07<br />

Vanadium 5.22E-07 NA<br />

Phenanthrene 5.37E-10 D<br />

Gross Alpha 8.00E41<br />

Gross Beta<br />

1.05E+02<br />

Uranium-238 2.51EMl 6.20E-11 1 SSE-09<br />

Pathway Total<br />

3.85E-08<br />

WAG 1, SWMU 38% ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

3.75E-10<br />

Beryllium 1.30E-13 8.40E+00 B2 h 1.09E-12<br />

Cobalt<br />

8.22E-13<br />

Lead 7.49E-13 B2<br />

Sodium<br />

3.38E-12<br />

Vanadium 7.92E-12 NA<br />

Phenanthrene 8.14E-15 D<br />

Page 30 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Alpha 1.21E-03<br />

Gross Beta<br />

1.59E-03<br />

Uranium-238 3.80E-04 1.24E-08<br />

<strong>4.</strong>71E-12<br />

Pathway Total<br />

5.81E- 12<br />

Arsenic 1.21E-08 3.66E+00 A 8 <strong>4.</strong>42E-08<br />

Beryllium 1.58E-09 <strong>4.</strong>30E+02 BZ 13. 1 6.78E-07<br />

Cobalt 2.25E-08 26<br />

Lead 6.11E-08 B2 26<br />

Sodium<br />

2.36E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38b, ESE-Excavation External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Beryllium BZ b<br />

Cobalt<br />

b<br />

Lead B2 b<br />

Sodium<br />

b<br />

Gross Alpha 1.45E-0 1 b<br />

Gross Beta 3.07E-01 b<br />

Uranium-238 3.02E-02 5.25E-08 b 1.59E-09<br />

Pathway Total<br />

WAG 1, SWMU 38b, ESE-Excavation Ingestion of Sediment<br />

Aluminum<br />

<strong>4.</strong>77E-05<br />

Arsenic 1.93E-08 1.50E+00 A a 2.90E-08<br />

Beryllium 2.52E-09 <strong>4.</strong>30E+00 B2 a 1.08E-08<br />

Cobalt<br />

3.60E-08<br />

Lead 9.77E-08 BZ<br />

Sodium<br />

3.78E-07<br />

Gross Alpha<br />

9.50E+01<br />

Gross Beta<br />

2.02E+02<br />

Uranium-238 1.99E+01 6.20E-11 1.23E-09<br />

Pathway Total<br />

WAG 1, SWMU 38b, ESE-Excavation Inhalation of Sediment<br />

Aluminum<br />

7.23E-10<br />

Arsenic 2.93E-13 5.00E+01 A b 1.47E- 11<br />

Beryllium 3.83E-14 8.40E+00 B2 b 3.21E-13<br />

Cobalt 5.46E- 13<br />

Lead 1.48E-12 BZ<br />

Sodium<br />

5.73E-12<br />

Gross Alpha<br />

1.44E-03<br />

Gross Beta<br />

3.06E-03<br />

Uranium-238 3.01E-04 1.24E-08 3.74E- 12<br />

Pathway Total<br />

S WMU Total<br />

N’AG 1. SWMU 38c, ESO-Excavation Dermal Contact with Soil<br />

Aluminum 3.05E-05 <strong>4.</strong>5<br />

Arsenic<br />

1.96E-08 3.66E+00 A 8 7.19E-08<br />

Beryllium<br />

1.83E-09 <strong>4.</strong>30E+02 B2 13, 1 7.86E-07<br />

Cobalt<br />

3.16E-08<br />

26<br />

Lead<br />

<strong>4.</strong>63E-08<br />

B2 26<br />

Sodium<br />

6.66E-07<br />

Thallium<br />

3.98E-10<br />

NA<br />

52<br />

2-Hexanone<br />

1.68E-10<br />

36<br />

Aroclor-1260<br />

2.67E-10 8.56E+00 BZ 46 2.29E-09<br />

Benzo(a)anthracene 1.01E-09 2.35E+00 BZ 2 2.37E-09<br />

Benzo(a)p yrene<br />

8.72E-10 2.35E+01 BZ 2 2.05E-08<br />

Benzo(b)fluoranthene 1.27E-09 2.35E+00 B2 2 3.00E-09<br />

Phenanthrene 1.70E-09 D 2<br />

Page 31 of 64<br />

7.22E-07<br />

1.59E-09<br />

<strong>4.</strong>11E-08<br />

1.87E-11<br />

7.65E-07


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

8.86E-07<br />

WAG 1, SWMU 38c, ESO-Excavation External Exposure to Soil<br />

Aluminum<br />

h<br />

Arsenic A b<br />

Beryllium B2 h<br />

Cobalt<br />

h<br />

Lead B2 b<br />

Sodium<br />

h<br />

Thallium NA b<br />

2-Hexanone<br />

b<br />

Aroclor- 1260 B2 h<br />

Benzo(a)anthracene B2 b<br />

Benzo(a)pyrene B2 h<br />

Benzo(h)fluoranthene B2 b<br />

Phenanthrene D b<br />

Gross Alpha 2.20E-01 h<br />

Gross Beta 3.04E-01 h<br />

Neptunium-237 1.93E-02 <strong>4.</strong>62E-07 h 8.93E-09<br />

Thorium-228 1.62E-02 9.94E-07 b 1.62E-08<br />

Uranium-235 3.53E-03 2.65E-07 h 9.37E-10<br />

Uranium-238 6.25E-02 5.25E-08 b 3.28E-09<br />

Pathway Total<br />

2.93E-08<br />

WAG 1, SWMU 38c, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

<strong>4.</strong>89E-05<br />

Arsenic 3.14E-08 1.50E+00 A a <strong>4.</strong>72E-08<br />

Beryllium 2.92E-09 <strong>4.</strong>30E+00 B2 a 1.268-08<br />

Cobalt<br />

5.05E-08<br />

Lead 7.40E-08 B2<br />

Sodium<br />

1.07E-06<br />

Thallium 6.36E- 10 NA<br />

2-Hexanone<br />

5.37E-11<br />

Aroclor-1260 2.14E-10 7.70E+00 B2 1.65E-09<br />

Benzo(a)anthracene 8.05E-10 7.30E-01 B2 5.88E-10<br />

Benzo(a)pyrene 6.98E-10 7.3OE+OO B2 a 5.09E-09<br />

Benzo(b)fluoranthene 1.02E-09 7.30E-01 B2 7.44E- 10<br />

Phenanthrene 1.36E-09 D<br />

Gross Alpha<br />

1.45E+02<br />

Gross Beta<br />

2.00E+02<br />

Neptunium-237 1.27E+O 1 3.00E- 10 3.81E-09<br />

Thorium-228 1.07E+01 2.31E-10 2.47E-09<br />

Uranium-235 2.32E+00 <strong>4.</strong>70E-11 1.09E-10<br />

Uranium-238 <strong>4.</strong>10E+01 6.20E-11 2.548-09<br />

Pathway Total<br />

7.67E-08<br />

WAG 1, SWMU 38c, ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

7.41E-10<br />

Arsenic<br />

<strong>4.</strong>77E-13 5.00E+01 A h 2.38E-11<br />

Beryllium<br />

<strong>4.</strong>43E-34 8.40E+00 B2 h 3.73E-13<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Phenanthrene<br />

7.67E-13<br />

1.12E- 12<br />

1.62E-11<br />

9.66E- 15<br />

8.14E-16<br />

3.24E-15<br />

1.22E-14<br />

1.06E-14<br />

1.55E-14<br />

2.06E-14<br />

B2<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

Gross Alpha<br />

2.20E-03<br />

Page 32 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Beta<br />

3.03E-03<br />

Neptunium-237 1.93E-04 3.45E-08<br />

6.65E-12<br />

Thorium-228 1.62E-04 9.68E-08<br />

1.57E-11<br />

Uranium-235 3.52E-05 1.30E-08<br />

<strong>4.</strong>58E- 13<br />

Uranium-238 6.23E-04 1.24E-08<br />

7.72E-12<br />

Pathwav Total<br />

5.47E-11<br />

SWMU Total<br />

9.92E-07<br />

WAG 7, SWMU 130, ESO-Excavation Dermal Contact with Soil<br />

Lead 3.79E-08 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130, ESO-Excavation External Exposure to Soil<br />

Lead BZ b<br />

Gross Alpha 9.67E-02 h<br />

Gross Beta 2.45E-01 b<br />

Uranium-238 1.49E-02 5.25E-08 b 7.82E-10<br />

Pathway Total<br />

7.82E-10<br />

WAG 7, SWMU 130, ESO-Excavation Ingestion of Soil<br />

Lead 6.07E-08 B2<br />

Gross Alpha<br />

6.36E+01<br />

Gross Beta<br />

1.61E+02<br />

Uranium-238 9.79E+00 6.20E-11 6.07E-10<br />

Pathway Total<br />

6.07E-10<br />

WAG 7, SWMU 130, ESO-Excavation Inhalation of Soil<br />

Lead 9.20E-13 BZ<br />

Gross Alpha<br />

9.64E-04<br />

Gross Beta<br />

2.45E-03<br />

Uranium-238 1.49E-04 1.24E-08 1.84E- 12<br />

Pathway Total 1.84E- 12<br />

SWMU Total<br />

1.39E-09<br />

WAG 7, SWMU 131, ESO-Excavation Dermal Contact with Soil<br />

Lead 6.68E-08 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 131, ESO-Excavation External Exposure to Soil<br />

Lead BZ b<br />

Gross Alpha<br />

1.83E-01<br />

h<br />

Gross Beta<br />

2.69E-01<br />

b<br />

Uranium-238 1.69E-02 5.25E-08<br />

b 8.90E- 10<br />

Pathway Total<br />

8.90E-10<br />

WAG 7, SWMU 131, ESO-Excavation Ingestion of Soil<br />

Lead 1.07E-07 B2<br />

Gross Alpha<br />

1.20E+02<br />

Gross Beta<br />

1.77E+02<br />

Uranium-238 l.llE+Ol 6.20E-11 6.90E-10<br />

Lead<br />

1.62E-12<br />

Gross Alpha<br />

1.82E-03<br />

Gross Beta<br />

2.68E-03<br />

Uranium-238 1.69E-04 1.24E-08<br />

Pathwav Total<br />

SWMU Total<br />

WAG 7, SWMU 132, ESO-Excavation Dermal Contact with Soil<br />

Lead 3.93E-07 BZ 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7. SWMU 132. ESO-Excavation External Exposure to Sod<br />

2.09E- 12<br />

2.09E-12<br />

1.58E-09<br />

Page 33 of 64


~<br />

Excess Lifetime Cancer Risks (continued)<br />

I.UIAL IOTAL<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead B2 b<br />

Gross Alpha 1.79E-01<br />

b<br />

Gross Beta 3.12E-01<br />

h<br />

Uranium-238 2.11E-02 5.25E-08<br />

b l.llE-09<br />

Pathway Total 1.11E-09<br />

WAG 7, SWMU 132, ESO-Excavation Ingestion of Soil<br />

Lead 6.30E-07 B2<br />

Gross Alpha<br />

1.18E+02<br />

Gross Beta<br />

2.05E+02<br />

Uranium-23 8 1.39E+01 6.20E-11 8.61 E- 10<br />

Pathway Total 8.61E- 10<br />

WAG 7, SWMU 132, ESO-Excavation Inhalation of Soil<br />

Lead 9.55E-12 BZ<br />

Gross Alpha<br />

1.79E-03<br />

Gross Beta<br />

3.11E-03<br />

Uranium-238 2.11E-04 1.24E-08 2.61E-12<br />

Pathway Total<br />

2.61E-12<br />

SWMU Total<br />

1.97E-09<br />

WAG 7, SWMU 133, ESO-Excavation Dermal Contact with Soil<br />

Lead 5.43E-07 BZ 26<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

3.93E-09<br />

2.95E-08 2.35E+00 BZ<br />

2<br />

2 6.94E-08<br />

Benzo(a)p yrene<br />

2.22E-08 2.35E+01 BZ 2 5.22E-07<br />

Benzo@)fluoranthene 2.38E-08 2.35E+00 B2 2 5.6 1E-08<br />

Benzo(g,h,i)perylene 1.32E-08<br />

D 2<br />

Benzo(k)fluoranthene 1.99E-08 2.35E-01 B2 2 <strong>4.</strong>69E-09<br />

Dibenzo(a,h)anthracene 1.63E-09 2.35E+01 BZ 2 3.83E-08<br />

Indene( 1,2,3-cd)pyrene 1.09E-08 2.35E+00 BZ 2 2.57E-08<br />

Phenanthrene<br />

2.67E-08<br />

D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

7.16E-07<br />

WAG 7, SWMU 133, ESO-Excavation External Exposure to Soil<br />

Lead B2 b<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

Indene( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

BZ<br />

B2<br />

B2<br />

D<br />

BZ<br />

B2<br />

BZ<br />

D<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

2.83501<br />

3.32E-01<br />

2.24E-02 5.25E-08<br />

b<br />

b<br />

b 1.18E-09<br />

Pathway Total<br />

1.18E-09<br />

WAG 7. SWMU 133. ESO-Excavation Ingestion of Soil<br />

Lead 8.70E-07 B2<br />

Acenaphthylene<br />

3.14E-09<br />

Benzo(a)anthracene 2.36E-08 7.30E-01 B2 1.72E-08<br />

Benzo(a)pyrene 1.77E-08 7.30E+00 BZ a 1.29E-07<br />

Benzo(b)fluoranthene 1.91E-08 7.30E-01 B2 1.39E-08<br />

Benzo(g,h,i)perylene 1.05E-08 D<br />

Benzo(k)fluoranthene 1.59E-08 7.30E-02 B2 1.16E-09<br />

Dibenzo(qh)anthracene 1.30E-09 7.30EM0 B2 9.49E-09<br />

Indene( 1,2,3-cd)pyrene 8.72E-09 7.30E-0 1 BZ 6.37E-09<br />

Phenanthrene 2.13E-08 D<br />

Gross Alpha<br />

1.86E+02<br />

Gross Beta<br />

2.18E+02<br />

Uranium-238 1.47EM1 6.20E-11 9.12E- LO<br />

Pathway Total<br />

1.78E-07<br />

WAG 7, SWMU 133, ESO-Excavation Inhalabon of Soil<br />

Page 34 of 64


Excess Lifetime Cancer Risks (continued)<br />

A N m 'IO'IAL IO'I'AL<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 1.32E- 11 B2<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dihenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

<strong>4.</strong>77E-14<br />

3.58E- 13<br />

2.69E-13<br />

2.89E- 13<br />

1.60E- 13<br />

2.42E- 13<br />

1.97E-14<br />

1.32E- 13<br />

3.23E-13<br />

2.83E-03<br />

3.31E-03<br />

2.23E-04<br />

B2<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

B2<br />

D<br />

1.24E-08<br />

2.77E- 12<br />

2.77E- 12<br />

SWMU Total<br />

8.95E-07<br />

WAG 7, SWMU 134, ESO-Excavation Dermal Contact with Soil<br />

Lead 8.72E-08 B2 26<br />

Benzo( a)anthracene 1.01E-09 2.35E+00 B2 2 2.37E-09<br />

Benzo(a)pyrene 9.39E-10 2.35E+01 B2 2 2.21E-08<br />

Benzo(h)fluoranthene 1.40E-09 2.35E+00 B2 2 3.30E-09<br />

Benzo(g,h,i)perylene <strong>4.</strong>97E-10 D 2<br />

Phenanthrene 2.26E-09 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.78E-08<br />

WAG 7. SWMU 13<strong>4.</strong> ESO-Excavation External Emosure to Soil<br />

Benzo(a)anthracene<br />

Benzo(a)p yrene<br />

Benzo(b)fluoranthene<br />

Benzo(g.h,i)perylene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.17E-0 1<br />

2.45E-01<br />

1.67E-02<br />

5.25E-08<br />

B2<br />

B2<br />

B2<br />

D<br />

D<br />

WAG 7, SWMU 134, ESO-Excavation Ingestion of Soil<br />

Lead 1.40E-07 B2<br />

Benzo(a)anthracene<br />

Benzo( a)p yrene<br />

Benzo(h)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

3.97E-10<br />

1.80E-09<br />

1.43E+02<br />

1.61E+02<br />

D<br />

D<br />

Uranium-238<br />

1.09E+01 6.20E-11<br />

h<br />

h<br />

b<br />

b<br />

h<br />

h<br />

b<br />

h<br />

8.75E-10<br />

8.05E-10 7.30E-01 B2 5.88E-10<br />

7.51E-10 7.30E+00 B2 a 5.49E-09<br />

l.12E-09 7.30E-01 B2 8.18E-10<br />

8.75E-10<br />

6.79E- 10<br />

Pathway Total<br />

7.57E-09<br />

WAG 7, SWMU 134, ESO-Excavation Inhalation of Soil<br />

Lead 2.12E-12 B2<br />

Benzo( a)anthracene 1.22E-14 B2<br />

Benzo(a)pyrene 1.14E- 14 B2<br />

Benzo@)fluoranthene 1.70E-14 B2<br />

Benzo( g,h,i)perylene 6.03E-15 D<br />

Phenanthrene 2.74E- 14 D<br />

Gross Alpha<br />

2.16E-03<br />

Gross Beta<br />

2.45E-03<br />

Uranium-238 1.66E-04 1.24E-08 2.06E-12<br />

Pathway Total 2.06E- 12<br />

SWMU Total<br />

WAG 7, SWMU 8b, ESO-Excavation Dermal Contact with Soil<br />

Aluminum 3.64E-05 4s<br />

Arsenic 1.36E-08 3.66E+00 A 8 <strong>4.</strong>97E-08<br />

Bervllium 2.34E-09 <strong>4.</strong>30E+02 B2 13. 1 1.00E-06<br />

3.62E-08<br />

Page 35 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Cobalt 2.59E-08 26<br />

Lead<br />

3.34E-08<br />

B2 26<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

1.91E-07<br />

3.64E-07<br />

5.19E- 10<br />

8.05E-10<br />

NA 52<br />

43<br />

Aroclor-1260<br />

1.92E-10 8.56E+00 B2 46 1.64E-09<br />

Benzo(a)anthracene 1.16E-09 2.35E+00 B2 2 2.73E-09<br />

Benzo(a)pyrene<br />

1.69E-09 2.35E+01 B2 2 3.97E-08<br />

Benzo(b)fluoranthene 1.91E-09 2.35E+00 B2 2 <strong>4.</strong>49E-09<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

1.65E-09<br />

1.54E-09 2.35E+00 B2 2 3.63E-09<br />

Naphthalene<br />

1.69E-09<br />

D 43<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

llorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

1.54E-09<br />

D 2<br />

Padway TO~~I 1.llE-06<br />

~~<br />

WAG 7, SWMU 8b, ESO-Excavation External Exposure to Soil<br />

Aluminum<br />

b<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

A<br />

B2<br />

B2<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

D<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

1.54E-01<br />

2.58E-01<br />

2.92E-02 <strong>4.</strong>62E-07<br />

b<br />

b<br />

b 1.35E-08<br />

Thorium-228<br />

1.64E-02 9.94E-07<br />

b 1.63E-08<br />

Thorium-230<br />

7.60E+00 <strong>4.</strong>40E-11<br />

b 3.34E- 10<br />

Uranium-235<br />

2.82E-03 2.65E-07<br />

b 7.47E-10<br />

Uranium-238<br />

5.54E-02 5.25E-08<br />

b 2.91E-09<br />

Pathway Total<br />

3.38E-08<br />

WAG 7, SWMU 8b, ESO-Excavation Ingestion of Soil<br />

Aluminum<br />

5.83E-05<br />

Arsenic 2.17E-08 1.50E+00 A a 3.26E-08<br />

Beryllium 3.74E-09 <strong>4.</strong>30E+00 B2 a 1.61E-08<br />

Cobalt<br />

<strong>4.</strong>15E-08<br />

Lead 5.35E-08 B2<br />

Phosphate (ortho)<br />

3.06E-07<br />

Sodium<br />

5.83E-07<br />

Thallium 8.30E-10 NA<br />

2-Methylnaphthalene 6.44E-10<br />

Aroclor-1260 1.53E-10 7.70E+00 B2 1.18E-09<br />

Benzo(a)anthracene 9.27E-10 7.30E-01 B2 6.77E-10<br />

Benzo(a)pyrene 1.3SE-09 7.30E+00 B2 a 9.84E-09<br />

Benzo(b)fluoranthene 1.52E-09 7.30E-01 B2 1.1 IE-09<br />

Dibenzohran<br />

1.32E-09<br />

Indene( 1,2,3-cd)pyrene 1.23E-09 7.30E-01 B2 9.01E-10<br />

Page 36 of 64


~~~ ~ ~<br />

Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Naphthalene 1.35E-09 D<br />

Phenanthrene 1.23E-09 D<br />

Gross Alpha<br />

1.01E+02<br />

Gross Beta<br />

1.69E+02<br />

Neptunium-237 1.92E+O 1 3.00E- 10 5.76E-09<br />

Thorium-228 1.08E+O 1 2.3 1E-10 2.48E-09<br />

Thorium-230 <strong>4.</strong>99E+03 3.75E-11 1.87E-07<br />

Uranium-235 1.85E+00 <strong>4.</strong>70E-11 8.71E-11<br />

Uranium-238 3.64E+01 6.20E-11<br />

2.26E-09<br />

Pathway Total<br />

2.60E-07<br />

Q'AG 7, SWMU 8b, ESO-Excavation Inhalation of Soil<br />

Aluminum<br />

8.85E-10<br />

Arsenic<br />

3.30E-13 5.00E+01 A b 1.65E-11<br />

Beryllium<br />

5.67E-14 8.40E+00 B2 b <strong>4.</strong>76E-13<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

' Benzo(a)anthracene<br />

Benzo(a)p yrene<br />

Benzo@)fluoranthene<br />

Dibenzofuran<br />

Indene( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

6.29E- 13<br />

8.11E- 13<br />

<strong>4.</strong>64E- 12<br />

8.85E- 12<br />

1.26E-14<br />

9.77E-15<br />

2.33E-15<br />

1.41E-14<br />

2.05E-14<br />

2.31E-14<br />

2.01E-14<br />

1.87E-14<br />

2.OSE-14<br />

1.87E- 14<br />

1.53E-03<br />

2.57E-03<br />

2.91E-04 3.45E-08<br />

BZ<br />

NA<br />

B2<br />

BZ<br />

BZ<br />

BZ<br />

BZ<br />

D<br />

D<br />

1 .OOE- 11<br />

Thorium-228<br />

1.63E-04 9.68E-08<br />

1.58E-11<br />

Thonum-230<br />

7.57E-02 1.72E-08<br />

1.30E-09<br />

Uranium-235<br />

2.81E-05 1.30E-08<br />

3.65E-13<br />

Uranium-238<br />

5.52E-04 1.24E-08<br />

6.85E-12<br />

Pathway Total<br />

1.35E-09<br />

SWMU Total<br />

1.40E-06<br />

WAG 1. SWMU lOOa ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 7.17E-04 4,5<br />

Arsenic 3.32E-07 3.66E+00 A 8 1.22E-06<br />

Beryllium <strong>4.</strong>84E-08 <strong>4.</strong>30E+02 B2 13, 1 2.08E-OS<br />

Cobalt 9.56E-07 26<br />

Lead 6.70E-07 B2 26<br />

Sodium<br />

7.87E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.20E-05<br />

WAG 1, SWMU 100% ISE-Current Industrial External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic<br />

A<br />

b<br />

Beryllium<br />

B2 b<br />

Cobalt<br />

b<br />

Lead<br />

BZ b<br />

Sodium<br />

b<br />

Gross Alpha<br />

1.35E+01<br />

b<br />

Gross Beta<br />

2.78E+01<br />

b<br />

Liranium-238<br />

1.88E+00 5.2SE-08 b 9.89E-08<br />

Pathway Total<br />

9.89E-08<br />

a'AG 1. SWMU 100% ISE-Current Industrial Ingestion of Sedment<br />

Aluminum<br />

6.98E-04<br />

Arsenic<br />

3.24E-07 1.50E+00 A a <strong>4.</strong>86E-07<br />

Beryllium<br />

<strong>4.</strong>71E-08 <strong>4.</strong>30E+00 B2 a 2.03E-07<br />

Cobalt 9.31E-07<br />

Page 37 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 6.53E-07 B2<br />

Sodium<br />

7.67E-06<br />

Gross Alpha<br />

3.57E+02<br />

Gross Beta<br />

7.30E+02<br />

Uranium-238 <strong>4.</strong>96E+01 6.20E-11 3.08E-09<br />

Pathway Total 6.91E-07<br />

WAG 1, SWMU 100% ISE-Current Industrial Inhalation of Sediment<br />

Alummum<br />

6.52E-08<br />

Arsenic 3.OZE-11 5.00E+01 A b 1.51E-09<br />

Beryllium <strong>4.</strong>40E-12 8.40E+00 B2 b 3.70E-11<br />

Cobalt<br />

8.69E-11<br />

Lead 6.10E-11 B2<br />

Sodium 7.16E- 10<br />

Gross Alpha<br />

8.66E-02<br />

Gross Beta 1.77E-01<br />

Uranium-238 1.20E-02 1.24E-08 1.49E- 10<br />

Pathway Total<br />

1.70E-09<br />

WAG I. SWMU 100% ISW-Current Industrial Dermal Contact with Water<br />

Aluminum<br />

4s<br />

Cadmium<br />

Cobalt<br />

3.72E-07<br />

B1 16, 1<br />

26<br />

Lead<br />

<strong>4.</strong>37E-07<br />

B2 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

2.28E-05<br />

WAG 1, SWMU IOOb, ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 5 S9E-04 4,5<br />

Arsenic<br />

3.03E-07 3.66E+00 A 8 l.llE-06<br />

Beryllium<br />

3.73E-08 <strong>4.</strong>30E+02 B2 13, 1 1.60E-05<br />

Cobalt<br />

<strong>4.</strong>84E-07 26<br />

Lead<br />

5.89E-07 B2 26<br />

Sodium<br />

7.35E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.72E-05<br />

WAG 1, SWMU 100b, ISE-Current Industrial External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Beryllium B2 h<br />

Cobalt<br />

b<br />

Lead BZ b<br />

Sodium<br />

b<br />

Gross Alpha 2.12E+O 1 h<br />

Gross Beta 3.41E+01 b<br />

Uranium-235 2.00E+00 2.65E-07 b 5.31E-07<br />

Uranium-238 6.05E+00 5.25E-08 b 3.18E-07<br />

Pathway Total<br />

8.49E-07<br />

WAG 1, SWMU 100b, ISE-Current Industrial Ingestion of Sediment<br />

Alummum<br />

5.44E-04<br />

Arsenic 2.95E-07 1.50E+00 A a <strong>4.</strong>43E-07<br />

Beryllium 3.63E-08 <strong>4.</strong>30E+00 B2 a 1.56E-07<br />

Cobalt <strong>4.</strong>71 E-07<br />

Lead 5.74E-07 B2<br />

Sodium<br />

7.16E-06<br />

Gross Alpha<br />

5.59E+02<br />

Gross Beta<br />

8.98E+02<br />

Uranium-235 5.27E+O 1 <strong>4.</strong>70E- 11<br />

2.48E-09<br />

Uranium-238 1.59E+02 6.20E-11 9.88E-09<br />

Page 38 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Pathway Total<br />

6.12E-07<br />

WAG 1, SWMU 100b, ISE-Current Industrial Inhalation ofsediment<br />

Aluminum<br />

5.08E-08<br />

Arsenic<br />

2.76E-11 5.00E+01 A b 1.38E-09<br />

Beryllium<br />

3.39E-12 8.40E+00 B2 b 2.85E-11<br />

Cobalt<br />

Lead<br />

<strong>4.</strong>40E-11<br />

5.35E-11<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

6.68E-10<br />

1.36E-01<br />

2.18E-01<br />

1.28E-02 1.30E-08 1.66E- 10<br />

Uranium-238<br />

3.87E-02 1.24E-08 <strong>4.</strong>80E- 10<br />

Pathway Total<br />

2.05E-09<br />

WAG 1, SWMU lob, ISW-Current Industrial Dermal Contact with Water<br />

Aluminum 4,5<br />

Arsenic 3.92E-08 3.66E+00 A 8 1.43E-07<br />

Lead 7.58E-07 B2 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.43E-07<br />

S WMU Total<br />

1.88E-05<br />

WAG 1, SWMU lOOc, ISO-Current Industrial Dermal Contact with Soil<br />

Aluminum 3.23E-04 4,5<br />

Arsenic 2.22E-07 3.66E+00 A 8 8.13E-07<br />

Beryllium 1.71E-08 <strong>4.</strong>30E+02 B2 13, 1 7.37E-06<br />

Cobalt 2.58E-07 26<br />

Lead 6.88E-07 B2 26<br />

Sodium<br />

6.07E-06<br />

3-Nitroaniline<br />

6.39E-09<br />

Gross Alpha<br />

Gross Beta<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

3-Nitroaniline<br />

Gross Alpha<br />

Gross Beta<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.32E+01<br />

2.07E+01<br />

1.19E+00<br />

<strong>4.</strong>27E-01<br />

1.79E+00<br />

9.94E-07<br />

2.65E-07<br />

5.2fE-08<br />

A<br />

B2<br />

B2<br />

b<br />

b<br />

b<br />

b<br />

b<br />

ti<br />

b<br />

b<br />

b<br />

b<br />

b<br />

1.18E-06<br />

1.13E-07<br />

9.40E-08<br />

WAG 1, SWMU IOOc, ISO-Current Industrial Ingestion of Soil<br />

Aluminum<br />

3.15E-04<br />

Arsenic 2.16E-07 1.50E+00 A a 3.25E-07<br />

Beryllium 1.67E-08 <strong>4.</strong>30E+00 B2 a 7.18E-08<br />

Cobalt 2.51E-07<br />

Lead 6.71E-07 B2<br />

Sodium<br />

5.9 IE-06<br />

3-Nitroaniline<br />

3.11E-09<br />

Gross Alpha<br />

9.02E+02<br />

Gross Beta<br />

1.41E+03<br />

Thorium-228 8.11E+01 2.31E-10 1.87E-08<br />

1.39E-06<br />

Page 39 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Uranium-235 2.92E+01 <strong>4.</strong>70E-11 1.37E-09<br />

Uranium-238 1.23E+02 6.20E-11 7.60E-09<br />

Pathway Total<br />

<strong>4.</strong>24E-07<br />

WAG 1, SWMU lOOc, ISO-Current Industrial Inhalation of Soil<br />

Aluminum<br />

2.94E-08<br />

Arsenic<br />

2.02E-11 5.00E+01 A h 1 .O 1E-09<br />

Beryllium<br />

1.56E-12 8.40E+00 B2 h 1.31E-11<br />

Cobalt<br />

Lead<br />

2.35E-11<br />

6.26E-11<br />

B2<br />

Sodium<br />

3-Nitroaniline<br />

Gross Alpha<br />

Gross Beta<br />

Thonum-228<br />

5.52E- 10<br />

2.91E-13<br />

8.42E-02<br />

1.32E-01<br />

7.57E-03 9.68E-08 7.33E-10<br />

Uranium-23 5<br />

2.73E-03 1.30E-08 3.55E-11<br />

Uranium-23 8<br />

1.14E-02 1.24E-08 1.42E- 10<br />

Pathway Total<br />

1.93E-09<br />

S WMU Total<br />

1 .OOE-05<br />

WAG 1, SWMU 136, ISO-Current Industrial Dermal Contact with Soil<br />

Aluminum 1.14E-05 <strong>4.</strong>5<br />

Arsenic 9.63E-09 3.66E+00 A 8 3.52E-08<br />

Beryllium 6.79E-10 <strong>4.</strong>30E+02 B2 13, 1 2.92E-07<br />

Cobalt <strong>4.</strong>26E-08 26<br />

Lead 1.03E-08 B2 26<br />

Sodium<br />

1.37E-07<br />

Sulfate<br />

1.53E-06<br />

Thallium 2.2 1E- 10 NA 52<br />

Benzo(a)anthracene 1.20E-09 2.35E+00 B2 2 2.83E-09<br />

Benzo(a)pyrene 1.64E-09 2.35E+01 B2 2 3.87E-08<br />

Benzo@)fluoranthene 2.02E-09 2.35E+00 B2 2 <strong>4.</strong>76E-09<br />

Benzo(g,h,i)perylene 8.52E-10 D 2<br />

Dibenzo(a,h)anthracene 2.56E-10 2.35E+01 B2 2 6.02E-09<br />

Indeno(l,2,3-cd)pyrene 9.79E-10 2.35E+00 B2 2 2.30E-09<br />

Phenanthrene 2.49E-10 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

3.82E-07<br />

WAG 1, SWMU 136, ISO-Current Industrial External Exposure to Soil<br />

Aluminum<br />

b<br />

Arsenic A h<br />

Beryllium B2 h<br />

Cobalt<br />

h<br />

Lead B2 h<br />

Sodium<br />

b<br />

Sulfate<br />

h<br />

Thallium NA h<br />

Benzo(a)anthracene B2 h<br />

Benzo( a)pyrene B2 h<br />

Benzo(b)fluoranthene B2 b<br />

Benzo(g,h,i)perylene D h<br />

Dibenzo(a,h)anthracene B2 h<br />

Indene( 1,2,3-cd)pyrene B2 h<br />

Phenanthrene D h<br />

Gross Alpha 2.26E-0 1 h<br />

Gross Beta 2.58E-01 b<br />

Uranium-238 3.50E-02 5.25E-08 h 1.84E-09<br />

Pathwav Total<br />

1.84E-09<br />

WAG 1, SWMU 136, ISO-Current Industrial Ingestion of Soil<br />

Aluminum 1.11E-05<br />

Arsenic 9.38E-09 1.50E+00 A a 1.41E-08<br />

Beryllium 6.61E-10 <strong>4.</strong>30E+00 B2 a 2.84509<br />

Cobalt<br />

<strong>4.</strong>15E-08<br />

Page 40 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Sodium<br />

1.33E-07<br />

Sulfate<br />

Thallium<br />

1.49E-06<br />

2.15E-10<br />

NA<br />

Benzo(a)anthracene 5.84E-10 7.30E-01 B2<br />

<strong>4.</strong>27E-10<br />

Benzo(a)pyrene<br />

8.00E-10 7.30E+00 B2 a 5.84E-09<br />

Benzo(h)fluoranthene 9.84E-10 7.30E-01 B2<br />

7.18E-10<br />

Benzo(g,h,i)perylene<br />

Dihenzo(qh)anthracene<br />

<strong>4.</strong>15E-IO<br />

1.25E-10 7.30E+00<br />

D<br />

B2<br />

9.09E-10<br />

Indeno( 1,2,3-cd)pyrene <strong>4.</strong>77E-10 7.30E-01 B2<br />

3.48E-10<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

1.2 IE- 10<br />

1.55E+O 1<br />

1.77E+O 1<br />

2.39E+00 6.20E-11<br />

D<br />

1.48E-10<br />

Pathway Total<br />

2.53E-08<br />

WAG 1, SWMU 136, ISO-Current Industrial Inhalation ofsoil<br />

Aluminum<br />

1.04E-09<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dihenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

8.76E-13<br />

6.17E-14<br />

3.88E- 12<br />

9.33E-13<br />

1.24E-11<br />

1.40E-10<br />

2.01E-14<br />

5.45E- 14<br />

7.46E- 14<br />

9.19E- 14<br />

3.88E- 14<br />

1.16E- 14<br />

<strong>4.</strong>45E-14<br />

1.13E- 14<br />

1.45E-03<br />

1.65E-03<br />

2.23E-04<br />

5.00E+01<br />

8.40E+00<br />

1.24E-08<br />

A h <strong>4.</strong>38E-11<br />

B2 h 5.19E- 13<br />

B2<br />

NA<br />

B2<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

D<br />

2.77E-12<br />

S WMU Total<br />

WAG 1, SWMU 38% ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 2.68E-04 4,5<br />

Beryllium 9.33E-08 <strong>4.</strong>30E+02 B2 13, 1 <strong>4.</strong>01E-05<br />

Cobalt 5.89E-07 26<br />

Lead 5.36E-07 B2 26<br />

Sodium<br />

2.42E-06<br />

Vanadium 5.67E-06 NA 58, 5<br />

Phenanthrene 1.17E-08 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1. SWMU 38% ISE-Current Industrial External Exposure to Sediment<br />

Aluminum<br />

h<br />

Beryllium B2 h<br />

Cobalt<br />

h<br />

Lead B2 h<br />

Sodium<br />

h<br />

Vanadium NA h<br />

Phenanthrene D h<br />

Gross Alpha 1.24E+O 1 h<br />

Gross Beta 1.62E+O 1 h<br />

Uranium-238 3.87E+00 5.25E-08 h 2.03E-07<br />

Pathway Total<br />

M'AG 1. SWMU 38% ISE-Current Industrial Ingestion of Sediment<br />

Aluminum<br />

2.61E-04<br />

Beqllium 9.09E-08 <strong>4.</strong>30E+00 B2 a 3.91E-07<br />

Cobalt<br />

5.74E-07<br />

<strong>4.</strong>71E-11<br />

<strong>4.</strong>01E-05<br />

2.03E-07<br />

<strong>4.</strong>09E-07<br />

Page41 of64


Excess Lifetime Cancer Risks (continued)<br />

W I i 7 7 T i - i -<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Sodium<br />

2.36E-06<br />

Vanadium 5.52E-06 NA<br />

Phenanthrene 5.68E-09 D<br />

Gross Alpha<br />

3.25E+02<br />

Gross Beta<br />

<strong>4.</strong>26E+02<br />

Uranium-238 1.02E+02 6.20E-11 6.32E-09<br />

Pathway Total<br />

3.97E-07<br />

WAG 1, SWMU 38% ISE-Current Industrial Inhalation of Sediment<br />

Aluminum<br />

2.44E-08<br />

Beryllium<br />

8.48E-12 8.40E+00 B2 h 7.13E-11<br />

Cobalt<br />

Lead<br />

5.35E-11<br />

<strong>4.</strong>88E-11<br />

B2<br />

Sodium<br />

Vanadium<br />

2.20E-10<br />

5.15E- 10<br />

NA<br />

Phenanthrene<br />

5.30E- 13<br />

D<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

7.90E-02<br />

1.03E-0 1<br />

2.47E-02 1.24E-08 3.07E- 10<br />

Lead 1.60E-07 B2 26<br />

Sodium<br />

Chloroform 9.98E-07 3.05E-02 B2 24 3.OSE-08<br />

bis(2-Ethylhexy1)phthalate 1.30E-06 7.37E-02 B2 15 9.60E-08<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

SWMU Total<br />

WAG 1, SWMU 38b, ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 5.18E-04 495<br />

Arsenic 2.10E-07 3.66E+00 A 8 7.68E-07<br />

Beryllium 2.74E-08 <strong>4.</strong>30E+02 B2 13, 1 1.18E-05<br />

Cobalt 3.91E-07 26<br />

Lead 1.06E-06 B2 26<br />

Sodium<br />

<strong>4.</strong>10E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38b, ISE-Current Industrial External Exposure to Sediment<br />

Aluminum<br />

h<br />

Arsenic A h<br />

Beryllium B2 b<br />

Cobalt<br />

h<br />

Lead B2 b<br />

Sodium<br />

b<br />

Gross Alpha 1.47E+O 1 h<br />

Gross Beta 3.12E+O 1 b<br />

Uranium-238 3.07E+OO 5.25E-08 b 1.61E-07<br />

Pathway Total<br />

WAG 1. SWMU 38h, ISE-Current Industrial Ingestion of Sediment<br />

Aluminum<br />

5.04E-04<br />

Arsenic 2.04E-07 1.50E+00 A a 3.07E-07<br />

Beryllium 2.67E-08 <strong>4.</strong>30E+00 B2 a 1.15E-07<br />

Cobalt<br />

3.80E-07<br />

Lead 1.03E-06 B2<br />

Sodium<br />

<strong>4.</strong>00E-06<br />

Gross Alpha<br />

3.87E+02<br />

Gross Beta<br />

8.20E+02<br />

Uranium-238 8.09E+O 1 6.20E- 11 5.01E-09<br />

Pathway Total<br />

WAG 1, SWMLJ 38b, ISE-Current Industrial Inhalation of Sediment<br />

Page 42 of 64<br />

2.39E-07<br />

1.26E-05<br />

1.61E-07<br />

<strong>4.</strong>26E-07<br />

<strong>4.</strong>10E-05


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Aluminum<br />

<strong>4.</strong>71E-08<br />

Arsenic<br />

1.91E- 11 5.00E+O 1 A h 9.54E- 10<br />

Beryllium<br />

2.49E-12 8.40E+00 B2 b 2.09E-11<br />

Cobalt<br />

Lead<br />

3.55E-11<br />

9.65E-11<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

3.73E- 10<br />

9.39E-02<br />

1.99E-01<br />

1.96E-02 1.24E-08 2.43E-10<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

WAG 1, SWMU 38c, ISO-Current Industrial Dermal Contact with Soil<br />

Aluminum 1.94E-03 <strong>4.</strong>5<br />

Arsenic<br />

1.14E-06 3.66E+00 A<br />

Beryllium<br />

9.46E-08 <strong>4.</strong>30E+02 B2<br />

Cobalt<br />

Lead<br />

Sodium<br />

Aroclor-1260<br />

1.75E-06<br />

3.46E-06<br />

1.55E-05<br />

1.56E-08 8.56E+00<br />

B2<br />

B2<br />

Benzo(a)anthracene <strong>4.</strong>95E-08 2.35E+00 B2<br />

Benzo(a)p yrene<br />

<strong>4.</strong>29E-08 2.35E+01 B2<br />

Benzo(b)fluoranthene 6.27E-08 2.35E+00 B2<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

8.77E-08<br />

D<br />

Pathway Total<br />

WAG 1, SWMU 38c, ISO-Current Industrial External Exposure to Soil<br />

Alummum<br />

Arsenic<br />

A<br />

Beryllium<br />

B2<br />

Cobalt<br />

Lead<br />

B2<br />

Sodium<br />

Aroclor- 1260<br />

B2<br />

Benzo(a)anthracene<br />

B2<br />

Benzo( a)pyrene<br />

B2<br />

Benzo(h)fluoranthene<br />

B2<br />

Phenanthrene<br />

D<br />

Gross Alpha<br />

8.53E+O 1<br />

Gross Beta<br />

1.27E+02<br />

Neptunium-237<br />

5.80E+00 <strong>4.</strong>62E-07<br />

Thorium-228<br />

5.08E+00 9.94E-07<br />

Uranium-235<br />

<strong>4.</strong>69E+00 2.65E-07<br />

Uranium-238<br />

5.77E+01 5.25E-08<br />

Pathway Total<br />

U’AG 1. SWMU 38c, ISO-Current Industrial Ingestion of Soil<br />

Aluminum<br />

1.89E-03<br />

8 <strong>4.</strong>16E-06<br />

13, 1 <strong>4.</strong>07E-05<br />

26<br />

26<br />

46 1.33E-07<br />

2 1.17E-07<br />

2 1.01E-06<br />

2 1.48E-07<br />

2<br />

b<br />

h<br />

h<br />

b<br />

h<br />

b<br />

h<br />

h<br />

b<br />

b<br />

b<br />

h<br />

h<br />

h<br />

b<br />

h<br />

h<br />

2.68E-06<br />

5.05E-06<br />

1.24E-06<br />

3.03E-06<br />

Arsenic l.llE-06 1.50E+00 A a 1.66E-06<br />

Ben.llium 9.21E-08 <strong>4.</strong>30E+00 B2 a 3.96E-07<br />

Cobalt<br />

1.71E-06<br />

Page 43 of 64<br />

<strong>4.</strong>62E-05<br />

1.20E-05<br />

1.3 IE-05


~~<br />

Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 3.37E-06 B2<br />

Sodium<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

1.5 1E-05<br />

7.58E-09<br />

2.41E-08<br />

2.09E-08<br />

3.05E-08<br />

<strong>4.</strong>27E-08<br />

5.84E+03<br />

8.71E+03<br />

3.97E+02<br />

3.48E+02<br />

3.2 lE+OZ<br />

3.95E+03<br />

7.70E+00<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

3.00E- 10<br />

2.31E-10<br />

<strong>4.</strong>70E- 1 1<br />

6.20E-11<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

a<br />

5.83E-08<br />

1.76E-08<br />

1.53E-07<br />

2.23E-08<br />

1.19E-07<br />

8.04E-08<br />

1.5 1 E-08<br />

2.45E-07<br />

WAG 1, SWMU 38c, ISO-Current Industrial Inhalation of Soil<br />

Aluminum<br />

1.76E-07<br />

Arsenic 1.03E- 10 S.OOE+O 1 A b 5.17E-09<br />

Beryllium 8.60E-12 8.40E+00 B2 b 7.22E- 11<br />

Cobalt 1.59E- 10<br />

Lead 3.14E- 10 B2<br />

Sodium 1.41 E-09<br />

Aroclor- 1260 7.07E-13 B2<br />

Benzo(a)anthracene 2.25E-12 B2<br />

Benzo(a)pyrene 1.95E-12 B2<br />

Benzo(b)fluoranthene 2.85E-12 B2<br />

Phenanthrene 3.99E- 12 D<br />

Gross Alpha<br />

5.45E-01<br />

Gross Beta<br />

8.13E-01<br />

Neptunium-237 3.70E-02 3.45E-08 1.28E-09<br />

Thorium-228 3.25E-02 9.68E-08 3.14E-09<br />

Uranium-235 2.99E-02 1.30E-08 3.89E-10<br />

Uranium-238 3.69E-0 1 1.24E-08 <strong>4.</strong>57E-09<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 132, ISO-Current Industrial Dermal Contact with Soil<br />

Lead 1.24E-07 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7. SWMU 132, ISO-Current Industrial External Exposure to Soil<br />

Lead B2 b<br />

Gross Alpha 2.24E-01 b<br />

Gross Beta <strong>4.</strong>29E-01 b<br />

Uranium-238 3.42E-02 5.25E-08 b 1.80E-09<br />

Pathway Total<br />

WAG 7, SWMU 132, ISO-Current Industrial Ingestion of Soil<br />

Lead 1.21E-07 B2<br />

Gross Alpha<br />

1.54E+01<br />

Gross Beta<br />

2.94E+01<br />

Uranium-238 2.34E+00 6.20E-11 1.45E-10<br />

Pathway Total<br />

WAG 7, SWMU 132,ISO-Current Industrial Inhalation of Soil<br />

Lead 1.13E-I1 B2<br />

Gross Alpha<br />

1.43E-03<br />

Gross Beta<br />

2.74E-03<br />

Uranium-238 2.19E-04 1.24E-08<br />

2.71E-12<br />

Pathwav Total<br />

S WMU Total<br />

WAG 7. SWMU 133, ISO-Current Industrial Dermal Contact with Soil<br />

Lead 1.22E-07 B2 26<br />

Acenaphthylene 9.95E-10 2<br />

Benzo(a)anthracene 7.84509 2.35E+00 B2 2 l.85E-08<br />

Benzo(a)pyrene 5.88E-09 2.3SE+01 B2 2 1.38E-07<br />

Page 44 of 64<br />

2.77E-06<br />

1.46E-08<br />

1.80E-09<br />

1.45E-10<br />

2.71E- 12<br />

6.10E-OS<br />

1.95E-09


~~ ~~~<br />

Excess Lifetime Cancer Risks (continued)<br />

Y'IE 'IUIAL<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Benzo(b)fluoranthene ., 6.33E-09 2.35E+00 B2 2 1.49E-08<br />

~<br />

Benzo(g,h,i)perylene 3.47E-09 D 2<br />

Benzo(k)fluoranthene 5.27E-09 2.35E-01 B2 2 1.24E-09<br />

Dibenzo(a,h)anthracene 3.77E-10 2.35E+01 B2 2 8.87E-09<br />

Indeno(l,2,3-cd)pyrene 2.86E-09 2.35E+00 B2 2 6.74E-09<br />

Phenanthrene 7.08E-09 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.89E-07<br />

WAG 7, SWMU 133, ISO-Current Industrial External Exposure to Soil<br />

Lead B2 b<br />

Acenaphthy lene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo( g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(a,h)anthracene<br />

lndeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

B2<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

B2<br />

D<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

h<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

2.42E-01<br />

3.15E-0 1<br />

3.05E-02 5.25E-08<br />

b<br />

b<br />

b 1.60E-09<br />

Pathway Total<br />

1.60E-09<br />

WAG 7, SWMU 133, ISO-Current Industrial Ingestion of Soil<br />

Lead 1.19E-07 B2<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

<strong>4.</strong>84E- 10<br />

3.82E-09 7.30E-01 B2<br />

2.79E-09<br />

Benzo( a)pyrene<br />

2.86E-09 7.30E+00 B2 a 2.09E-08<br />

Benzo(b)fluoranthene 3.08E-09 7.30E-01 B2<br />

2.2SE-09<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

1.69E-09<br />

2.57E-09 7.30E-02<br />

D<br />

B2<br />

1.88E-I0<br />

Dibenzo(a,h)anthracene 1.83E-10 7.30E+00 B2<br />

1.34E-09<br />

Indeno( 1,2,3-cd)pyrene 1.39E-09 7.30E-01 B2<br />

1.02E-09<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

3.4SE-09<br />

1.65E+01<br />

2.1 SE+O 1<br />

2.09E+00 6.20E-11<br />

D<br />

1.29E-10<br />

Pathway Total<br />

2.86E-08<br />

WAG 7, SWMU 133, ISO-Current Industrial Inhalation of Soil<br />

Lead 1.11E-11 B2<br />

Acenaphthylene <strong>4.</strong>52E- 14<br />

Benzo(a)anthracene 3 S6E- 13 B2<br />

Benzo(a)pyrene 2.67E-13 B2<br />

Benzo@)fluoranthene 2.88E-13 B2<br />

Benzo(g,h,i)perylene 1.58E- 13 D<br />

Benzo(k)fluoranthene 2.40E-13 B2<br />

Dibenzo(a,h)anthracene 1.71 E- 14 B2<br />

lndeno( 1,2,3-cd)pyrene 1.30E-I3 B2<br />

Phenanthrene 3.22E- 13 D<br />

Gross Alpha<br />

1.54E-03<br />

Gross Beta<br />

2.0 IE-03<br />

Uranium-238 1.95E-04 1.24E-08<br />

2.42E-12<br />

Pathway Total<br />

2.42E- 12<br />

S WMU Total<br />

2.19E-07<br />

WAG 7. SWMU 13<strong>4.</strong> ISO-Current Industrial Dermal Contact with Soil<br />

Lead 1.13E-08 B2 26<br />

Benzo( a)anthracene 2.11E-10 2.35E+00 B2 2 <strong>4.</strong>97E- 10<br />

Benzo(a)pyrene 2.11E-10 2.35E+01 B2 2 <strong>4.</strong>97E-09<br />

Benzo(b)fluoranthene 3.16E-10 2.35E+00 B2 2 7.4SE- 10<br />

Benzo(g,h,i)perylene 1.08E-10 D 2<br />

Phenanthrene 3.92E-10 D 2<br />

Gross Alpha<br />

Page 45 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

6.21E-09<br />

WAG 7, SWMU 134, ISO-Current Industrial External Exposure to Soil<br />

Lead B2 b<br />

Benzo( a)anthracene B2 b<br />

Benzo(a)pyrene B2 b<br />

Benzo(b)fluoranthene B2 h<br />

Benzo(g,h,i)perylene D b<br />

Phenanthrene D b<br />

Gross Alpha 1.49E-01 b<br />

Gross Beta 3.11E-01 b<br />

Uranium-238 2.19E-02 5.25E-08 b 1.15E-09<br />

Pathway Total<br />

1.15E-09<br />

WAG 7, SWMU 134, ISO-Current Industrial Ingestion of Soil<br />

Lead 1.lOE-08 B2<br />

Benzo(a)anthracene 1.03E-10 7.30E-01 B2 7.50E-11<br />

Benzo(a)pyrene 1.03E-10 7.30E+00 B2 a 7.50E-10<br />

Benzo(b)fluoranthene 1.54E-10 7.30E-01 B2 1.13E- 10<br />

Benzo(g,h,i)perylene 5.28E-11 D<br />

Phenanthrene 1.9 1E- 10 D<br />

Gros’s Alpha<br />

1.02E+01<br />

Gross Beta<br />

2.13E+01<br />

Uranium-238 1.50E+00 6.20E-11 9.28E-11<br />

Pathway Total<br />

1.03E-09<br />

WAG 7, SWMU 134, ISO-Current Industrial Inhalation of Soil<br />

Lead 1.03E- 12 B2<br />

Benzo(a)anthracene 9.59E-15 B2<br />

Benzo(a)pyrene 9.59E-15 B2<br />

Benzo(b)fluoranthene 1.44E-14 B2<br />

Benzo(g,h,i)perylene <strong>4.</strong>93E-15 D<br />

Phenanthrene 1.78E-14 D<br />

Gross Alpha<br />

9.53E-04<br />

Gross Beta<br />

1.99E-03<br />

Uranium-238 1.40E-04 1.24E-08 1.73E- 12<br />

Pathway Total<br />

1.73E-12<br />

S WMU Total<br />

8.39E-09<br />

WAG 7. SWMU 8% ISE-Current Industrial Dermal Contact with Sediment<br />

Aluminum 2.34E-04 <strong>4.</strong>5<br />

Arsenic<br />

<strong>4.</strong>96E-07 3.66E+00 A 8 1.81E-06<br />

Beryllium<br />

5.23E-08 <strong>4.</strong>30E+02 B2 13, 1 2.25E-05<br />

Cobalt<br />

8.87E-07 26<br />

Lead<br />

6.65E-07 B2 26<br />

Sodium<br />

7.74E-06<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.43E-05<br />

WAG 7, SWMU 8% ISE-Current Industrial External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic<br />

A<br />

b<br />

Beryllium<br />

Cobalt<br />

€32 b<br />

b<br />

Lead<br />

Sodium<br />

B2 b<br />

b<br />

Gross Alpha<br />

1.04E+O 1<br />

b<br />

Gross Beta<br />

1.72E+O 1<br />

b<br />

Uranium-238<br />

1.25E+00 5.25E-08 b 6.57E-08<br />

Pathway Total<br />

6.57E-08<br />

WAG 7. SWMU 8% ISE-Current Industrial Ingestion of Sediment<br />

A I u m 111 u m<br />

2.28E-04<br />

Arsenic <strong>4.</strong>83E-07 1.50E+00 A a 7.25E-07<br />

Beryllium 5.10E-08 <strong>4.</strong>30E+00 B2 a 2.19E-07<br />

Cobalt<br />

8.64E-07<br />

Page 46 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Lead 6.48E-07 B2<br />

Sodium<br />

7.54E-06<br />

Gross Alpha<br />

2.75E+02<br />

Gross Beta<br />

<strong>4.</strong>53E+02<br />

Uranium-23 8 3.29E+01 6.20E-11 2.04E-09<br />

Pathway Total<br />

9.46E-07<br />

WAG 7, SWMU 8% ISE-Current Industrial Inhalation of Sedlment<br />

Aluminum<br />

2.13E-08<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

<strong>4.</strong>51E-11<br />

<strong>4.</strong>76E-12<br />

8.07E-11<br />

6.05E-11<br />

7.04E- 10<br />

6.67E-02<br />

l.lOE-01<br />

8.00E-03<br />

5.00E+01<br />

8.40E+00<br />

1.24E-08<br />

A<br />

B2<br />

B2<br />

b<br />

b<br />

2.26E-09<br />

<strong>4.</strong>00E-11<br />

9.91E-11<br />

Pathway Total<br />

- 2 .- 79E-09 .- .<br />

WAG 7, SWMU 8a, ISW-Current Industrial Dermal Contact with Water<br />

Aluminum 45<br />

Antimony<br />

<strong>4.</strong>71E-07<br />

NA<br />

Arsenic<br />

3.31E-08 3.66E+00 A<br />

Cadmium<br />

6.65E-08<br />

B1<br />

Lead<br />

9.52E-08<br />

B2<br />

Manganese<br />

3.90E-04<br />

D<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Thallium<br />

NA<br />

Vanadium<br />

1.41E-05<br />

NA<br />

Methylene Chloride 3.75E-07 7.89E-03 B2<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

S WMU Total<br />

WAG 7, SWMU 8b, ISO-Current Industrial Dermal Contact with Soil<br />

Aluminum 1.26E-03 43<br />

Arsenic<br />

6.78E-07 3.66E+00 A 8<br />

Beryllium<br />

1.27E-07 <strong>4.</strong>30E+02 B2 13, 1<br />

Cobalt<br />

1.72E-06<br />

26<br />

Lead<br />

2.12E-06<br />

B2 26<br />

Phosphate (ortho)<br />

1.OZE-05<br />

Sodium<br />

1.13E-05<br />

Thallium<br />

2.48E-08<br />

NA 52<br />

2-Methylnaphthalene <strong>4.</strong>3 1E-08<br />

43<br />

Aroclor- 1260<br />

2.73E-08 8.56E+00 B2 46<br />

Benzo( a)anthracene l.llE-07 2.35E+00 B2 2<br />

Benzo(a)pyrene<br />

1.06E-07 2,35E+01 B2 2<br />

Benzo(h)fluoranthene 1.35E-07 2.35E+00 B2 2<br />

Dibenzofuran<br />

9.89E-08<br />

Indeno( 1,2,3-cd)pyrene 8.25E-08 2.35E+00 B2 2<br />

Naphthalene<br />

1.07E-07<br />

D 43<br />

Phenanthrene<br />

3.51E-07<br />

D 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 8b, ISO-Current Industrial External Exposure to Soil<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Bepllium B2 h<br />

Page 47 of 64<br />

7<br />

8 1.21E-07<br />

16, 1<br />

26<br />

38<br />

52<br />

58, 5<br />

41 2.96E-09<br />

2.48E-06<br />

5.45E-05<br />

2.33E-07<br />

2.62E-07<br />

2.49E-06<br />

3.17E-07<br />

1.94E-07<br />

1.24E-07<br />

6.04E-05<br />

2.55E-05


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Cobalt<br />

h<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(h)fluoranthene<br />

Dibenzofuran<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

B2<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

D<br />

h<br />

h<br />

h<br />

h<br />

h<br />

b<br />

h<br />

b<br />

h<br />

h<br />

b<br />

h<br />

h<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

<strong>4.</strong>52E+01<br />

8.35E+01<br />

9.13E+00 <strong>4.</strong>62E-07<br />

b<br />

b<br />

b <strong>4.</strong>22E-06<br />

Thonum-230<br />

2.37E+03 <strong>4.</strong>40E-11<br />

b 1.04E-07<br />

Uranium-234<br />

1.71E+02 2.14E-11<br />

b 3.66E-09<br />

Uranium-235<br />

3.80E+00 2.65E-07<br />

h 1.01E-06<br />

Uranium-238<br />

2.40E+02 5.25E-08<br />

b 1.26E-05<br />

Pathwav Total<br />

1.79E-05<br />

WAG 7, SWMU 8b, ISO-Current Industrial Ingestion of Soil<br />

Aluminum<br />

1.22E-03<br />

Arsenic 6.61E-07 1.50E+OO A a 9.9 1 E-07<br />

Beryllium 1.23E-07 <strong>4.</strong>30E+00 B2 a 5.30E-07<br />

Cobalt<br />

1.68E-06<br />

Lead 2.06E-06 B2<br />

Phosphate (ortho)<br />

9.96E-06<br />

Sodium<br />

1.1OE-05<br />

Thallium 2.41E-08 NA<br />

2-Methylnaphthalene 2.10E-08<br />

Aroclor-1260 1.33E-08 7.70E+00 B2<br />

Benzo(a)anthracene 5.42E-08 7.30E-01 B2<br />

Benzo(a)pyrene 5.16E-08 7.30E+00 B2<br />

Benzo(b)fluoranthene 6.56E-08 7.30E-01 B2<br />

Dibenzofuran<br />

<strong>4.</strong>82E-08<br />

Indene( 1,2,3-cd)pyrene <strong>4.</strong>02E-08 7.30E-01 B2<br />

Naphthalene 5.20E-08 D<br />

Phenanthrene 1.71 E-07 D<br />

1 .O2E-07<br />

3.96E-08<br />

3.76E-07<br />

<strong>4.</strong>79E-08<br />

Gross Alpha<br />

3.1 OE+03<br />

Gross Beta 5.71 E+03<br />

Neptunium-237 6.25E+02 3.00E-10 1.88E-07<br />

Thonum-230 1.63E+OS 3.75E-11 6.09E-06<br />

Uranium-234 1.17E+04 <strong>4.</strong>44E- 11 5.19E-07<br />

Uranium-235 2.60E+02 <strong>4.</strong>70E-11 1.22E-08<br />

Uranium-238 1.64E+O4 6.20E- 11 1.02E-06<br />

Pathway Total<br />

WAG 7. SWMU 8h. ISO-Current Industrial Inhalation of Soil<br />

a<br />

2.93E-08<br />

Arsenic 6.17E-11 5.00E+01 A h 3.08E-09<br />

Beryllium 1.15E-11 8.40E+00 B2 h 9.67E-11<br />

Cobalt 1.57E- 10<br />

Lead 1.92E- 10 B2<br />

Phosphate (ortho) 9.30E- 10<br />

Sodium<br />

1.03E-09<br />

Thallium 2.25E-12 NA<br />

2-Methylnaphthalene 1.96E-12<br />

Aroclor- 1260 1.24E- 12 B2<br />

Benzo(a)anthracene 5.06E-12 B2<br />

Benzo(a)pyrene <strong>4.</strong>8 1E- 12 B2<br />

Benzo(b)fluoranthene 6.13E-12 B2<br />

Dibenzofuran <strong>4.</strong>5OE- 12<br />

Indeno( 1,2,3-cd)pyrene 3.75E-12 B2<br />

Page 48 of 64<br />

9.95E-06


Excess Lifetime Cancer Risks (continued)<br />

ANALYTE ,-<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Naphthalene <strong>4.</strong>85E- 12 D<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-230<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

1.60E-11<br />

2.89E-01<br />

5.33E-01<br />

5.84E-02<br />

1.52E+01<br />

1.09E+O0<br />

2.43E-02<br />

1.53E+00<br />

3.45E-08<br />

1.72E-08<br />

1.40E-08<br />

1.30E-08<br />

1.24E-08<br />

D<br />

2.0 1E-09<br />

2.6 1E-07<br />

1.53E-08<br />

3.16E- 10<br />

1.90E-08<br />

WAG 1, SWMU 100% FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 2.33E-03 4,5<br />

Arsenic 1.08E-06 3.66E+00 A 8 3.95E-06<br />

Beryllium 1.57E-07 <strong>4.</strong>30E+02 B2 13, 1 6.76E-05<br />

Cobalt 3.10E-06 26<br />

Lead 2.18E-06 B2 26<br />

Sodium<br />

2.56E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 100% FSE-Future Industrial External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Beryllium B2 b<br />

Cobalt<br />

b<br />

Lad B2 b<br />

Sodium<br />

b<br />

Gross Alpha 1.35E+O 1 b<br />

Gross Beta 2.78E+O 1 b<br />

Uranium238 1.88E+00 5.25E-08 b 9.89E-08<br />

Pathway Total<br />

WAG 1, SWMU 100% FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

6.98E-04<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

3.24E-07 1.50E+00 A a <strong>4.</strong>86E-07<br />

<strong>4.</strong>71E-08 <strong>4.</strong>30E+00 B2 a 2.03E-07<br />

9.3 1E-07<br />

6.53E-07<br />

B2<br />

7.67E-06<br />

9.27EM2<br />

1.90E+03<br />

1.29E+02 6.20E-11 8.00E-09<br />

3.01E-07<br />

7.15E-05<br />

9.89E-08<br />

8.86E-05<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

3.02E-11 5.00E+01 A b 1.51E-09<br />

<strong>4.</strong>40E-12 8.40E+00 B2 b 3.70E-11<br />

8.69E-11<br />

6.10E-11<br />

B2<br />

7.16E-10<br />

8.66E-02<br />

1.77E-01<br />

1.20E-02 1.24E-08 1.49E- 10<br />

Pathway Total<br />

WAG 1, SWMU 100% FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum 475<br />

Cadmium 1.21E-06 B1 16, 1<br />

Cobalt 26<br />

Lead 1.42E-06 B2 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

1.70E-09<br />

Page 49 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLQPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Uranium-238<br />

Pathway Total<br />

S W MU Total<br />

7.23E-05<br />

WAG 1, SWMU 100b, FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 1.81E-03 4,5<br />

Arsenic 9.84E-07 3.66E+00 A 8 3.60E-06<br />

Beryllium 1.21E-07 <strong>4.</strong>30E+02 B2 13, 1 5.21E-05<br />

Cobalt 1.57E-06 26<br />

Lead 1.91E-06 B2 26<br />

Sodium<br />

2.39E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

5.57E-05<br />

WAG 1, SWMU 100b, FSE-Future Industrial External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Beryllium B2 b<br />

Cobalt<br />

b<br />

Lead B2 b<br />

Sodium<br />

b<br />

Gross Alpha 2.12E+01 b<br />

Gross Beta 3.41E+01 b<br />

Uranium23 5 2.00E+00 2.65E-07 b 5.31E-07<br />

Uranium-238 6.05E+00 5.25E-08 b 3.18E-07<br />

Pathway Total<br />

8.49E-07<br />

WAG 1, SWMU 100b, FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

5.44E-04<br />

Arsenic 2.95E-07 1.50E+00 A a <strong>4.</strong>43E-07<br />

Beryllium 3.63E-08 <strong>4.</strong>30E+00 B2 a 1.56E-07<br />

Cobalt<br />

<strong>4.</strong>71E-07<br />

Lead 5.74E-07 B2<br />

Sodium<br />

7.16E-06<br />

Gross Alpha<br />

1.45E+03<br />

Gross Beta<br />

2.34E+03<br />

Uranium-235 1.37E+02 <strong>4.</strong>70E- 11 6.44E-09<br />

Uranium-238 <strong>4.</strong>14E+02 6.20E-11 2.57E-08<br />

Pathway Total<br />

6.31E-07<br />

WAG 1, SWMU IOOb, FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

5.08E-08<br />

Arsenic<br />

2.76E-11 5.00E+01 A b 1.38E-09<br />

Beryllium<br />

3.39E-12 8.40E+00 B2 b 2.85E-11<br />

Cobalt<br />

Lead<br />

<strong>4.</strong>40E-11<br />

5.35E-11<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-235<br />

6.68E-10<br />

1.36E-01<br />

2.18E-01<br />

1.28E-02 1.30E-08 1.66E-10<br />

Uranium-238<br />

3.87E-02 1.24E-08 <strong>4.</strong>80E- 10<br />

Pathway Total<br />

2 -. 135~49 -.- - -<br />

WAG 1. SWhfLJ IOOb, FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum <strong>4.</strong>5<br />

Arsenic<br />

1.27E-07 3.66E+00 A 8 <strong>4.</strong>65E-07<br />

Lead<br />

2.46E-06 B2 26<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

<strong>4.</strong>65E-07<br />

SWLIUTotal<br />

5.76E-05<br />

M’AG 1. SWMU 1OOc. FGW-Future Industrial Dermal Contact with Groundwater<br />

Page 50 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Aluminum<br />

4s<br />

Barium 1.41E-05 NA 9<br />

Manganese 1.30E-04 D 38<br />

Methylene Chloride <strong>4.</strong>58E-07 7.89E-03 B2 41 3.62E-09<br />

bis(2-Ethylhexyllphthalate 9.55E-07 7.37E-02 B2 15 7.04E-08<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

7.40E-08<br />

WAG 1, SWMU lOOc, FGW-Future Industrial Ingestion of Groundwater<br />

Aluminum<br />

<strong>4.</strong>65E-02<br />

Barium 2.40E-03 NA<br />

Manganese 2.21E-02 D<br />

Methylene Chloride 1.75E-05 7.50E-03 B2 a 1.31E-07<br />

bis(2-Ethylhexy1)phthalate 6.99E-06 1.40E-02 B2 a 9.78E-08<br />

Gross Alpha<br />

2.65E+04<br />

Gross Beta<br />

<strong>4.</strong>60E+04<br />

Pathway Total<br />

2.29E-07<br />

WAG 1, SWMU lOOc, FGW-Future Industrial Inhalation of Groundwater<br />

Aluminum<br />

Barium<br />

NA<br />

Manganese<br />

D<br />

Methylene Chloride l.82E-06 B2<br />

bis(2-Ethylhexy1)phthalate<br />

B2<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

WAG 1, SWMU lOOc, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 1.35E-03 43<br />

Arsenic 8.06B07 3.66E+00 A 8 2.95E-06<br />

Beryllium 7.20E-08 <strong>4.</strong>30E+02 B2 13, 1 3.10E-05<br />

Cobalt 1.14E-06 26<br />

Lead 1.67E-06 B2 26<br />

Sodium<br />

5.38E-05<br />

Thallium 9.17E-09 NA 52<br />

2-Methy Inaphthalene 8.48E-08 43<br />

3-Nitroaniline<br />

2.08E-08<br />

Endosulfan Sulfate 2.83E-10<br />

Endrin Ketone<br />

2.92E-10<br />

Naphthalene 5.13E-08 D 43<br />

Phenanthrene 1.41E-07 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

Pathway Total<br />

3.39E-05<br />

WAG 1, SWMU lOOc, FSO-Future Industrial External Exposure to Soil<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Beryllium B2 b<br />

Cobalt<br />

b<br />

Lead BZ b<br />

Sodium<br />

b<br />

Thallium NA b<br />

?.-Methylnaphthalene<br />

b<br />

3-Nitroaniline<br />

b<br />

Endosulfan Sulfate<br />

b<br />

Endrin Ketone<br />

b<br />

Naphthalene D b<br />

Phenanthrene<br />

D b<br />

Gross Alpha<br />

1.43E41 b<br />

Gross Beta 2.27E41 b<br />

Neptunium-237<br />

1.5 1E-01 <strong>4.</strong>62E-07 b 6.96E-08<br />

'Ihorium-228<br />

1.33E40 9.94E-07 b 1.32E-06<br />

Page 51 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Uranium-238 1.30E+00 5.25E-08 b 6.81E-08<br />

Pathway Total<br />

1.46E-06<br />

WAG 1, SWMU IOOc, FSO-Future Industrial Ingestion of Soil<br />

Aluminum<br />

<strong>4.</strong>04E-04<br />

Arsenic<br />

2.42E-07 1.50E+00 A a 3.63E-07<br />

Beryllium<br />

2.16E-08 <strong>4.</strong>30E+00 B2 a 9.29E-08<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

3-Nitroaniline<br />

Endosulfan Sulfate<br />

Endrin Ketone<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-238<br />

3.41 E-07<br />

5.00E-07<br />

1.61E-05<br />

2.75E-09<br />

1.27E-08<br />

3.11E-09<br />

<strong>4.</strong>24E-11<br />

<strong>4.</strong>38E- 11<br />

7.69E-09<br />

2.11E-08<br />

9.80E+02<br />

1.55E+03<br />

1.03E+01<br />

9.08E+01<br />

8.88E+01<br />

3.00E-10<br />

2.3 1E-10<br />

6.20E-11<br />

B2<br />

NA<br />

D<br />

D<br />

3.09E-09<br />

2.10E-08<br />

5.51E-09<br />

Pathwav Total<br />

<strong>4.</strong>85E-07<br />

WAG 1, SWMU lOOc, FSO-Future Industrial Inhalation of Soil<br />

Aluminum<br />

3.78E-08<br />

Arsenic 2.26E-I 1 5.00E+01 A b 1.13E-09<br />

Beryllium 2.02E-12 8.40E+00 B2 b 1.69E-11<br />

Cobalt<br />

3.19E-11<br />

Lead <strong>4.</strong>67E-11 B2<br />

Sodium 1.51E-09<br />

Thallium 2.57E-13 NA<br />

2-Methylnaphthalene 1.19E- 12<br />

3-Nitroaniline<br />

2.91E-13<br />

Endosulfan Sulfate 3.96E- 15<br />

Endrin Ketone <strong>4.</strong>09E- 15<br />

Naphthalene 7.18E- 13<br />

Phenanthrene<br />

1.97E-12<br />

Gross Alpha 9.15E-02<br />

Gross Beta 1.45E-01<br />

Neptunium-237 9.63E-04 3.45E-08 3.32E-11<br />

Thorium-228 8.48E-03 9.68E-08 8.2OE- 10<br />

Uranium-238 8.29E-03 1.24E-08 1.03E-10<br />

Pathway Total<br />

SWMU Total<br />

WAG 1, SWMU 136, FGW-Future Industrial Dermal Contact with Groundwater<br />

Barium 6.78E-06 NA 9<br />

Manganese 1.15E-04 D 38<br />

Trichloroethene 3.55E-05 7.33E-02 NA 57 2.60E-06<br />

bis(2-Ethylhexy1)phthalate <strong>4.</strong>78E-07 7.37E-02 B2 I5 3.52E-08<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

WAG 1. SWMU 136, FGW-Future Industrial Ingestion ofGroundwater<br />

Banum 1.15E-03 NA<br />

Manganese 1.95E-02 D<br />

Trichloroethene 3.84E-04 1.1OE-02 NA e <strong>4.</strong>23E-06<br />

bis(2-Ethylhexy1)phthalate 3.49E-06 1.40E-02 B2 a <strong>4.</strong>89E-08<br />

Gross Alpha<br />

1.94E+04<br />

Gross Beta<br />

5.00E+04<br />

Pathway Total<br />

WAG 1. SWMU 136, FGW-Future Industrial Inhalation of Groundwater<br />

Barium<br />

NA<br />

Manganese<br />

D<br />

Trichloroethene <strong>4.</strong>00E-05 6.00E-03 NA e 2.40E-07<br />

bis(2-Ethylhexy1)phthalate<br />

B2<br />

D<br />

D<br />

Page 52 of 64<br />

2.1 OE-09<br />

2.64E-06<br />

<strong>4.</strong>28E-06<br />

3.61E-05


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

2.40E-07<br />

WAG 1, SWMU 136, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 5.66E-05 <strong>4.</strong>5<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

l,l,l-Trichloroethane<br />

1, I-Dichloroethene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-23 8<br />

2.04E-08<br />

2.54E-09<br />

5.83E-08<br />

<strong>4.</strong>35E-08<br />

1.59E-06<br />

<strong>4.</strong>98E-06<br />

3.43E-10<br />

<strong>4.</strong>74E-10<br />

3.08E- 10<br />

2.23E-09<br />

2.38E-09<br />

2.49E-09<br />

2.10E-09<br />

8.30E-10<br />

2.15E-09<br />

8.10E- 10<br />

6.00E-01<br />

2.35E+00<br />

2.35E+01<br />

2.35E+00<br />

A<br />

B2<br />

BZ<br />

NA<br />

D<br />

C<br />

B2<br />

B2<br />

BZ<br />

D<br />

BZ<br />

B2<br />

D<br />

8<br />

13, 1<br />

26<br />

26<br />

52<br />

55<br />

31<br />

2<br />

2<br />

2<br />

2<br />

2<br />

2<br />

2<br />

7.45E-08<br />

1.09E-06<br />

1.85E-10<br />

5.25E-09<br />

5.60E-08<br />

5.86E-09<br />

1.96E-08<br />

5.06E-09<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Sulfate<br />

Thallium<br />

l,l,l-Trichloroethane<br />

1,1 -Dichloroethene<br />

Benzo( a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo( g,h,i)perylene<br />

Dibenzo(a,h)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

<strong>4.</strong>1 1E-0 1<br />

5.98E-01<br />

3.24E-02<br />

5.25E-08<br />

A<br />

BZ<br />

B2<br />

NA<br />

D<br />

C<br />

BZ<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

D<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

1.70E-09<br />

Arsenic 6.11E-09 1.50E+00 A a 9.16E-09<br />

Beryllium 7.63E-10 <strong>4.</strong>30E+00 BZ a 3.28E-09<br />

Cobalt<br />

1.75E-08<br />

Lead 1.31E-08 B2<br />

Sodium<br />

<strong>4.</strong>77E-07<br />

Sulfate<br />

1.49E-06<br />

Thallium 1.03E- 10 NA<br />

1,1,1 -Trichloroethane 2.85E-11 D<br />

1,1 -Dichloroethene 1.85E-11 6.00E-01 C a 1.11E- 11<br />

Benzo(a)anthracene 3.34E-10 7.30E-01 BZ 2.44E- 10<br />

Benzo(a)pyrene 3.57E-10 7.30E+00 B2 a 2.60E-09<br />

Benzo(b)fluoranthene 3.73E-10 7.3OE-01 B2<br />

2.73E- 10<br />

Benzo(g,h,i)perylene 3.15E-10 D<br />

Dibenzo(a,h)anthracene 1.25E-10 7.30E+00 B2 9.09E-10<br />

Indeno( 1,2,3-cd)pyrene 3.22E-10 7.3OE-01 BZ 2.35E-10<br />

Page 53 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Phenanthrene 1.21E-10 D<br />

Gross Alpha 2.81E+O 1<br />

Gross Beta <strong>4.</strong>09E+O 1<br />

Uranium-238 2.22E+00 6.20E-11 1.38E- 10<br />

Pathway Total<br />

WAG 1, SWMU 136, FSO-Future Industrial Inhalation of Soil<br />

1.69E-08<br />

Aluminum<br />

1.59E-09<br />

Arsenic 5.70E-13 5.00E+01 A b 2.85E-11<br />

Beryllium 7.12E-14 8.40E+00 B2 b 5.98E-13<br />

Cobalt 1.63E- 12<br />

Lead 1.22E-12 B2<br />

Sodium<br />

<strong>4.</strong>45E-11<br />

Sulfate<br />

1.40E-10<br />

Thallium 9.60E-15 NA<br />

I,], 1 -Trichloroethane 6.79E-10 D<br />

1,l-Dichloroethene 1.17E-09 1.20E+00 C b 1.40E-09<br />

Benzo(a)anthracene 3.12E- 14 B2<br />

Benzo(a)pyrene 3.33E-14 B2<br />

Benzo(b)fluoranthene 3.49E- 14 B2<br />

Benzo(g,h,i)perylene 2.94E-14 D<br />

Dibenzo(a,h)anthracene 1.16E-14 B2<br />

Indeno( 1,2,3-cd)pyrene 3.01E-14 B2<br />

Phenanthrene 1.13E-14 D<br />

Gross Alpha<br />

2.62E-03<br />

Gross Beta<br />

3.82E-03<br />

Uranium-238 2.07E-04 1.24E-08<br />

2.57E- 12<br />

Pathway Total<br />

S WMU Total<br />

1.44E-09<br />

8.44E-06<br />

WAG 1, SWMU 38a, FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 8.71E-04 4s<br />

Beryllium 3.03E-07 <strong>4.</strong>30E+02 B2 13, 1 1.30E-04<br />

Cobalt 1.91E-06 26<br />

Lead 1.74E-06 B2 26<br />

Sodium<br />

7.86E-06<br />

Vanadium 1.84E-05 NA 58, 5<br />

Phenanthrene 3.79E-08 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 1, SWMU 38% FSE-Future Industrial External Exposure to Sediment<br />

1.30E-04<br />

Aluminum<br />

b<br />

Beryllium<br />

B2 b<br />

Cobalt<br />

b<br />

Lead B2 b<br />

Sodium<br />

b<br />

Vanadium NA b<br />

Phenanthrene D b<br />

Gross Alpha 1.24E+01 b<br />

Gross Beta 1.62E+O 1 b<br />

Uranium-238 3.87E+00 5.25E-08 b 2.03E-07<br />

Pathway Total<br />

WAG 1, SWMU 38% FSE-Future Industrial Ingestion of Sediment<br />

2.03E-07<br />

Aluminum<br />

2.61E-04<br />

Beryllium<br />

9.09E-08 <strong>4.</strong>30E+00 B2 a 3.91E-07<br />

Cobalt<br />

5.74E-07<br />

Lead<br />

5.22E-07<br />

B2<br />

Sodium<br />

2.36E-06<br />

Vanadium<br />

5.52E-06<br />

NA<br />

Phenanthrene<br />

5.68E-09<br />

D<br />

Gross Alpha<br />

8.46E+02<br />

Gross Beta<br />

l.llE+03<br />

Uranium-238<br />

2.65E+02 6.20E-I 1 1.64E-08<br />

Pathway Total<br />

<strong>4.</strong>07E-07<br />

Page 54 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

WAG 1, SWMU 38% FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

2.44E-08<br />

Beryllium<br />

8.48E-12 8.40E+00 BZ b 7.13E-11<br />

Cobalt<br />

Lead<br />

5.35E-11<br />

<strong>4.</strong>88E-11<br />

B2<br />

Sodium<br />

Vanadium<br />

2.20E-10<br />

5.15E- 10<br />

NA<br />

Phenanthrene<br />

5.30E-13<br />

D<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

7.90E-02<br />

1.03E-01<br />

2.47E-02 1.24E-08 3.07E- 10<br />

Pathway Total 3.78E- 10<br />

WAG 1, SWMU 38% FSW-Future Industrial Dermal Contact with Surfacewater<br />

Arsenic 9.99E-08 3.66E+00 A 8 3.66E-07<br />

Lead 5.18E-07 B2 26<br />

Sodium<br />

Chloroform 3.24E-06 3.05E-02 B2 24 9.89E-08<br />

bis(2-Ethylhexyl)phthalate <strong>4.</strong>23E-06 7.37E-02 B2 I5 3.12E-07<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

' Pathway ~otal<br />

7.76E-07<br />

S WMU Total<br />

1.32E-04<br />

WAG 1, SWMU 38b, FSE-Future Industrial Dermal Contact with Sediment<br />

Aluminum 1.68E-03 4s<br />

Arsenic 6.81E-07 3.66E+00 A 8 2.49E-06<br />

Beryllium 8.90E-08 <strong>4.</strong>30E+02 B2 13, 1 3.83E-05<br />

Cobalt 1.27E-06 26<br />

Lead 3.45E-06 B2 26<br />

Sodium<br />

1.33E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

<strong>4.</strong>07E-05<br />

WAG 1, SWMU 38b, FSE-Future Industrial External Exposure to Sediment<br />

Aluminum<br />

h<br />

Arsenic A h<br />

Beryllium B2 b<br />

Cobalt<br />

b<br />

Lead B2 b<br />

Sodium<br />

h<br />

Gross Alpha 1.47E+O 1 b<br />

Gross Beta 3.12E+01 b<br />

Uranium-238 3.07E+00 5.25E-08 b 1.61E-07<br />

Pathway Total<br />

1.61E-07<br />

WAG 1, SWMU 38b, FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

5.04E-04<br />

Arsenic 2.04E-07 1.50E+00 A a 3.07E-07<br />

Beryllium 2.67E-08 <strong>4.</strong>30E+00 B2 a 1.15E-07<br />

Cobalt<br />

3.80E-07<br />

Lead 1.03E-06 B2<br />

Sodium<br />

<strong>4.</strong>00E-06<br />

Gross Alpha<br />

1 .O IE+03<br />

Gross Beta<br />

2.13E+03<br />

Uranium-238 2.10E+02 6.20E-11 1.30E-08<br />

Pathway Total<br />

<strong>4.</strong>34E-07<br />

WAG 1. SWMU 38h, FSE-Future Industrial Inhalation of Sediment<br />

Alummum<br />

<strong>4.</strong>71E-08<br />

Arsenic 1.91E-11 5.OOE+01 A b 9.54E-10<br />

Beryllium 2.49E-12 8.40E+00 B2 h 2.09E-11<br />

Cobalt<br />

3.55E-11<br />

Lead 9.65E-11 B2<br />

Sodium 3.73E- 10<br />

Gross Alpha<br />

9.39E-02<br />

Page 55 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Gross Beta 1.99E-01<br />

Uranium-238 1.96E-02 1.24E-08 2.43E-10<br />

~~<br />

Pathway Total<br />

1.22E-09<br />

WAG 1, SWMU 38b, FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum <strong>4.</strong>5<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-238<br />

Uranium-234<br />

Uranium-238<br />

Pathway Total<br />

S WMU Total<br />

<strong>4.</strong>13E-05<br />

WAG 1. SWMU 38c. FGW-Future Industrial Dermal Contact with Groundwater<br />

Manganese 5.79E-05 D 38<br />

Methylene Chloride 1.19E-05 7.89E-03 B2 41 9.40E-08<br />

Gross Beta<br />

Pathway Total<br />

WAG 1, SWMU 38c, FGW-Future Industrial Ingestion of Groundwater<br />

Banum 1.02E-03 NA<br />

Manganese 9.85E-03 D<br />

Methylene Chloride <strong>4.</strong>54E-04 7.50E-03 B2 a 3.41E-06<br />

Gross Beta<br />

2.41E+04<br />

Pathway Total<br />

WAG 1, SWMU 38c, FGW-Future Industrial Inhalation of Groundwater<br />

Barium<br />

NA<br />

Manganese<br />

D<br />

Methylene Chloride <strong>4.</strong>73E-05 E2<br />

Gross Beta<br />

Pathway Total<br />

WAG 1, SWMU 38c, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum <strong>4.</strong>88E-03 4s<br />

Arsenic<br />

3.14E-06 3.66Ei-00 A 8 1.15E-05<br />

Beryllium<br />

2.92E-07 <strong>4.</strong>30E+02 B2 13, 1 1.25E-04<br />

Cobalt<br />

5.04E-06<br />

26<br />

Lead<br />

7.39E-06<br />

B2 26<br />

Sodium<br />

1.06E-04<br />

llallium<br />

6.35E-08<br />

NA 52<br />

2-Hexanone<br />

2.68E-08<br />

36<br />

Aroclor- 1260<br />

<strong>4.</strong>27E-08 8.56E+00 B2 46 3.65E-07<br />

Benzo( a)anthracene 1.6 IE-07 2.35E+00 B2 2 3.79E-07<br />

Benzo(a)pyrene<br />

1.39E-07 2.35E+01 B2 2 3.28E-06<br />

Benzo(b)fluoranthene 2.04E-07 2.35E+00 B2 2 <strong>4.</strong>79E-07<br />

Phenanthrene<br />

2.71E-07<br />

D 2<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

llorium-228<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total<br />

WAG 1. SWMU 38c. FSO-Future Industrial External Exoosure to Soil<br />

9.40E-08<br />

3.41E-06<br />

1.41E-04<br />

Arsenic<br />

A b<br />

Beryllium<br />

Cobalt<br />

B2 b<br />

b<br />

Lead<br />

B2 b<br />

Sodium<br />

b<br />

Thallium NA b<br />

2-Hexanone<br />

b<br />

Aroclor- 1260 B2 b<br />

Benzo( a)anthracene B2 h<br />

Page 56 of 64


Excess Lifetime Cancer Risks (continued)<br />

WERiH'I. ANAL- IdTAL-<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Benzo(a)pyrene B2 h<br />

Benzo(bfflu0ranthene B2 h<br />

Phenanthrene D b<br />

Gross Alpha 6.34E+01 h<br />

Gross Beta 8.75E+01 h<br />

Neptunium-237 5.56E+00 <strong>4.</strong>62E-07 h 2.57E-06<br />

Thorium-228 <strong>4.</strong>67E+00 9.94E-07 h <strong>4.</strong>64E-06<br />

Uranium-235 1.02E+00 2.65E-07 h 2.69E-07<br />

Uranium-238 1.80E+01 5.25E-08 h 9.43E-07<br />

Pathway Total<br />

8.42E-06<br />

WAG 1, SWMU 38c, FSO-Future Industrial Ingestion of Soil<br />

Alummum<br />

1.46E-03<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Thallium<br />

2-Hexanone<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-23 5<br />

Uranium-238<br />

9.41E-07<br />

8.75E-08<br />

1.5 1E-06<br />

2.22E-06<br />

3.19E-05<br />

1.91E-08<br />

1.61E-09<br />

6.41E-09<br />

2.41E-08<br />

2.09E-08<br />

3.05E-08<br />

<strong>4.</strong>07E-08<br />

<strong>4.</strong>34E+03<br />

5.99E+03<br />

3.80E+02<br />

3.20E+02<br />

6.95E+01<br />

1.23E+03<br />

1.50E+00<br />

<strong>4.</strong>3 OE+OO<br />

7.70E+00<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

3.00E-10<br />

2.31E- 10<br />

<strong>4.</strong>70E-11<br />

6.20E-11<br />

A<br />

B2<br />

B2<br />

NA<br />

B2<br />

B2<br />

B2<br />

B2<br />

D<br />

Pathway Total<br />

WAG 1. SWMU 38c, FSO-Future Industrial Inhalation of Soil<br />

Aluminum<br />

1.37E-07<br />

Arsenic<br />

8.79E-11 5.00E+01<br />

Beryllium<br />

8.17E-12 8.40E+00<br />

Cobalt<br />

1.41E-10<br />

Lead<br />

2.07E- 10<br />

B2<br />

Sodium<br />

2.98E-09<br />

Thallium<br />

1.78E-12<br />

NA<br />

2-Hexanone<br />

1.50E- 13<br />

Aroclor-1260<br />

5.98E-13<br />

B2<br />

Benzo(a)anthracene 2.25E-12<br />

B2<br />

Benzo( a)pyrene<br />

1.9SE-12<br />

B2<br />

Benzo(b)fluoranthene 2.8SE-12<br />

B2<br />

Phenanthrene<br />

3.80E-12<br />

D<br />

Gross Alpha<br />

<strong>4.</strong>OSE-01<br />

Gross Beta<br />

5.59E-01<br />

Neptunium-237<br />

3.5SE-02 3.45E-08<br />

Thorium-228<br />

2.98E-02 9.68E-08<br />

Uranium-23 5<br />

6.49E-03 1.30E-08<br />

Uranium-23 8<br />

1.15E-01 1.24E-08<br />

Pathway Total<br />

a<br />

a<br />

a<br />

1.41E-06<br />

3.76E-07<br />

<strong>4.</strong>93E-08<br />

1.76E-08<br />

1.53E-07<br />

2.23E-08<br />

1.14E-07<br />

7.39E-08<br />

3.27E-09<br />

7.62E-08<br />

A h <strong>4.</strong>39E-09<br />

B2 h 6.87E-11<br />

1.23E-09<br />

2.89E-09<br />

8.44E-11<br />

1.42E-09<br />

s WMU ~otai<br />

WAG 7. SWMU 130, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 2.19E-08 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 130. FSO-Future Industrial External Exposure to Soil<br />

Lead B2 b<br />

Gross Alpha 1 .OOE-01 h<br />

Gross Beta 2.55E-0 1 h<br />

Uranium-23 8 1.55E-02 5.25E-08 h 8.12E-10<br />

Page 57 of 64<br />

2.30E-06<br />

1.01E-08<br />

1.56E-04


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

Gross Alpha<br />

6.87E+00<br />

Gross Beta<br />

1.74E+01<br />

Uranium-238 1.06E+00 6.20E-11 6.56E-11<br />

Gross Alpha<br />

6.41E-04<br />

Gross Beta<br />

1.63E-03<br />

Uranium-238 9.88E-05 1.24E-08<br />

1.23E-12<br />

Pathway Total<br />

1.23E-12<br />

SWMU Total<br />

WAG 7, SWMU 131, FSO-Future Industrial Dermal Contact with Soil<br />

Lead <strong>4.</strong>17E-09 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 131, FSO-Future Industrial External Exposure to Soil<br />

Lead B2 h<br />

Gross Alpha 2.05E-02 h<br />

Gross Beta 3.02E-02 h<br />

Uranium-238 1.91E-03 5.25E-08 h 1.00E-10<br />

Pathway Total 1 .OOE- 10<br />

WAG 7, SWMU 131, FSO-Future Industrial Ingestion of Soil<br />

Lead 1.25E-09 B2<br />

Gross Alpha<br />

1.41Ei-00<br />

Gross Beta<br />

2.07E+00<br />

Uranium-238 1.31E-01 6.20E-11 8.09E- 12<br />

Pathway Total<br />

8.09E-12<br />

WAG 7, SWMU 131, FSO-Future Industrial Inhalation of Soil<br />

Lead 1.17E- 13 B2<br />

Gross Alpha<br />

1.31E-04<br />

Gross Beta<br />

1.93E-04<br />

Uranium-238 1.22E-05 1.24E-08 1.51 E- 13<br />

Pathway Total 1.51 E- 13<br />

S WMU Total<br />

WAG 7, SWMU 132. FSO-Future Industrial Dermal Contact with Soil<br />

Lead 3.42E-07 B2 26<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 132, FSO-Future Industrial External Exposure to Soil<br />

Lead B2 h<br />

Gross Alpha<br />

2.80E-01<br />

h<br />

Gross Beta<br />

<strong>4.</strong>88E-01<br />

h<br />

Uranium-238 3.30E-02 5.25E-08<br />

h 1.73E-09<br />

Pathway Total<br />

1.73E-09<br />

WAG 7, SWMU 132, FSO-Future Industrial Ingestion of Soil<br />

Lead 1 .O2E-07 B2<br />

Gross Alpha 1.92E+O 1<br />

Gross Beta<br />

3.34E+01<br />

Uranium-238 2.26E+00 6.20E-11 1.40E- 10<br />

Pathway Total<br />

1.40E-10<br />

WAG 7, SWMU 132. FSO-Future Industrial Inhalation of Soil<br />

Lead 9.57E- 12 B2<br />

Gross Alpha<br />

1.79E-03<br />

Gross Beta<br />

3.12E-03<br />

Uranium-238 2.11E-04 1.24E-08 2.62E-12<br />

Pathway Total 2.62E- 12<br />

SWMU Total<br />

8.79E-10<br />

1.08E-10<br />

1.88E-09<br />

Page 58 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

WAG 7, SWMU 133, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 3.96E-07 B2 26<br />

Acenaphthylene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthene<br />

Dibenzo(qh)anthracene<br />

Indeno( 1,2,3-cd)pyrene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.87E-09<br />

2.15E-08<br />

1.62E-08<br />

1.74E-08<br />

9.59E-09<br />

1.45E-08<br />

1.19E-09<br />

7.95E-09<br />

1.94E-08<br />

2.35E+00<br />

2.35E+01<br />

2.35E+00<br />

2.35E-01<br />

2.35E+01<br />

2.35E+00<br />

B2<br />

B2<br />

B2<br />

D<br />

B2<br />

B2<br />

B2<br />

D<br />

2<br />

2 5.06E-OR<br />

2 3.80E-07<br />

2 <strong>4.</strong>09E-08<br />

2<br />

2 3.42E-09<br />

2 2.79E-08<br />

2 1.87E-08<br />

2<br />

WAG 7, SWMU 133, FSO-Future Industrial External Exposure to Soil<br />

Lead B2 b<br />

Acenaphthylene<br />

b<br />

Benzo(a)anthracene B2 b<br />

Benzo(a)pyrene B2 b<br />

Benzo(b)fluoranthene B2 b<br />

Benzo(g,h,i)perylene D b<br />

Benzo(k)fluoranthene B2 b<br />

Dibenzo(qh)anthracene B2 b<br />

Indeno( 1,2,3-cd)pyrene B2 b<br />

Phenanthrene D b<br />

Gross Alpha 3.72E-0 1 b<br />

Gross Beta <strong>4.</strong>36E-01 b<br />

Uranium-238 2.94E-02 5.25E-08 b 1.54E-09<br />

Pathway Total<br />

WAG 7, SWMU 133, FSO-Future Industrial Ingestion of Soil<br />

Lead 1.19E-07 B2<br />

Acenaphthylene<br />

<strong>4.</strong>30E-10<br />

Benzo(a)anthracene 3.22E-09 7.30E-01 B2 2.35E-09<br />

Benzo(a)pyrene 2.42E-09 7.30E+00 B2 a 1.77E-08<br />

Benzo(b)fluoranthene 2.61E-09 7.30E-01 B2<br />

1.90E-09<br />

Benzo(g,h,i)perylene 1.44E-09 D<br />

Benzo(k)fluoranthene 2.18E-09 7.30E-02 B2 1.59E- 10<br />

Dibenzo(a,h)anthracene 1.78E-10 7.30E+00 B2 1.30E-09<br />

Indeno( 1,2,3-cd)pyrene I. 19E-09 7.30E-0 1 B2 8.71E-10<br />

Phenanthrene 2.92E-09 D<br />

Gross Alpha 2.55E+01<br />

Gross Beta<br />

2.98E+Ol<br />

Uranium-238 2.01E+00 6.20E-11 1.25E-10<br />

Pathway Total<br />

WAG 7, SWMU 133, FSO-Future Industrial Inhalation of Soil<br />

Lead 1.11E- 11 B2<br />

Acenaphthylene <strong>4.</strong>01E-14<br />

Benzo(a)anthracene 3.01E-13 B2<br />

Benzo(a)pyrene 2.26E-13 B2<br />

Benzo(b)fluoranthene 2.43E- 13 B2<br />

Benzo(g,h,i)perylene 1.34E-13 D<br />

Benzo(k)fluoranthene 2.03E-13 B2<br />

Dibenzo(a,h)anthracene 1.66E-34 B2<br />

Indeno( 1,2,3-~d)pyrene 1.llE-13 B2<br />

Phenanthrene 2.72E-13 D<br />

Gross Alpha<br />

2.38E-03<br />

Gross Beta<br />

2.79E-03<br />

Uranium-238 1.88E-04 1.24E-08 2.33E-12<br />

Pathway Total<br />

SWMU Total<br />

WAG 7. SWMU 134, FSO-Future Industrial Dermal Contact with Soil<br />

Lead 6.36E-08 B2 26<br />

Benzo(a)anthracene 7.34E-10 2.35E+00 B2 2 1.73E-09<br />

Page 59 of 64<br />

5.22E-07<br />

1.54E-09<br />

2.44E-08<br />

2.33E-12<br />

5.48E-07


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Benzo(a)pyrene 6.85E-10 2.35E+01 B2 2 1.61E-08<br />

Benzo(b)fluoranthene 1.02E-09 2.35E+00 B2 2 2.41E-09<br />

Benzo(g,h,i)perylene 3.62E- 10 D 2<br />

Phenanthrene 1.64E-09 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.03E-08<br />

WAG 7, SWMU 134, FSO-Future Industrial External Exposure to Soil<br />

Lead B2 b<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

2.85E-01<br />

3.22E-01<br />

2.19E-02<br />

5.25E-08<br />

BZ<br />

B2<br />

BZ<br />

D<br />

D<br />

WAG 7, SWMU 134, FSO-Future Industrial Ingestion of Soil<br />

Lead 1.91E-08 B2<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo@)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

5.43E-11<br />

2.47E-10<br />

D<br />

D<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

1.15E-09<br />

l.lOE-10 7.30E-01 B2 8.04E-11<br />

1.03E-10 7.30E+00 B2 a 7.50E- 10<br />

1.53E-10 7.3OE-01 B2 1.12E- 10<br />

1.95E+01<br />

2.21E+01<br />

1.50E+00 6.20E-11 9.28E-11<br />

1.15E-09<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

1.03E- 14<br />

BZ<br />

9.59E-15<br />

B2<br />

1.43E- 14<br />

B2<br />

5.07E-15<br />

D<br />

2.30E-14<br />

D<br />

1.82E-03<br />

2.06E-03<br />

1.40E-04 1.24E-08 1.73E- 12<br />

S WMU Total<br />

WAG 7, SWMU 8% FSE-Future Industrial Dermal Contact with Sediment<br />

Alummum 7.61E-04 <strong>4.</strong>5<br />

Arsenic 1.61E-06 3.66E+00 A 8 5.89E-06<br />

Beryllium 1.70E-07 <strong>4.</strong>30E+02 B2 13, 1 7.31E-05<br />

Cobalt 2.88E-06 26<br />

Lead 2.16E-06 B2 26<br />

Sodium<br />

2.51E-05<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

WAG 7, SWMU 8% FSE-Future Industrial External Exposure to Sediment<br />

Aluminum<br />

b<br />

Arsenic A b<br />

Beryllium B2 b<br />

Cobalt<br />

b<br />

Lead BZ b<br />

Sodium<br />

b<br />

Gross Alpha<br />

1.04E+O 1<br />

b<br />

Gross Beta<br />

1.72E+O 1<br />

b<br />

Uranium-238<br />

1.25E+00 5.25E-08<br />

b 6.57E-08<br />

Pathway Total<br />

Page 60 of 64<br />

1.73E-12<br />

7.90E-05<br />

6.57E-08<br />

2.24E-08


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

WAG 7, SWMU 8% FSE-Future Industrial Ingestion of Sediment<br />

Aluminum<br />

2.28E-04<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

Pathway Total<br />

<strong>4.</strong>83E-07 1.5OE+00 A a 7.25E-07<br />

5.10E-08 <strong>4.</strong>30E+00 BZ a 2.19E-07<br />

8.64E-07<br />

6.48E-07<br />

B2<br />

7.54E-06<br />

7.15E+02<br />

l.l8E+03<br />

8.56E+01 6.20E-11 5.31E-09<br />

~~<br />

9.49E-07<br />

WAG 7, SWMU 8% FSE-Future Industrial Inhalation of Sediment<br />

Aluminum<br />

2.13E-08<br />

Arsenic<br />

<strong>4.</strong>51E-11 5.00E+01 A b 2.26E-09<br />

Beryllium<br />

<strong>4.</strong>76E-12 8.40E+00 B2 b <strong>4.</strong>00E-11<br />

Cobalt<br />

Lead<br />

8.07E-11<br />

6.OSE-11<br />

B2<br />

Sodium<br />

Gross Alpha<br />

Gross Beta<br />

Uranium-238<br />

7.04E-10<br />

6.67E-02<br />

1.lOE-01<br />

8.00E-03 1.24E-08 9.91E-11<br />

Pathway Total<br />

2.39E-09<br />

WAG 7, SWMU 8% FSW-Future Industrial Dermal Contact with Surfacewater<br />

Aluminum 495<br />

Antimony 1.53E-06 NA 7<br />

Arsenic 1.08E-07 3.66E+00 A 8 3.94E-07<br />

Cadmium 2.16E-07 B1 16, 1<br />

Lead 3.09E-07 B2 26<br />

Manganese 1.27E-03 D 38<br />

Silicon<br />

Sodium<br />

Sulfate<br />

Thallium NA 52<br />

Vanadium <strong>4.</strong>58E-05 NA 58, 5<br />

Methylene Chloride 1.22E-06 7.89E-03 B2 41 9.60E-09<br />

Gross Alpha<br />

Gross Beta<br />

Pathway Total<br />

<strong>4.</strong>03E-07<br />

S WMU Total<br />

WAG 7, SWMU 8b, FGW-Future Industrial Dermal Contact with Groundwater<br />

Aluminum<br />

4s<br />

Beryllium 1.09E-06 <strong>4.</strong>30E+02 B2 13, 1 <strong>4.</strong>67E-04<br />

Cobalt 26<br />

Iron 26<br />

Manganese 5.13E-04 D 38<br />

Nickel 1.34E-OS NA 44<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1, I-Dichloroethene 1.82E-06 6.00E-0 1 C 31 1.09E-06<br />

1,2-Dichloroethene 3.35E-06 NA<br />

Phenanthrene 5.62E-06 D 2<br />

Trichloroethene 1.72E-06 7.33E-02 NA 57 1.26E-07<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathwav Total <strong>4.</strong>68E-04<br />

WAG 7, SWMU 8b, FGW-Future Industrial Ingestion of Groundwater<br />

Alummum<br />

1.69E-01<br />

Page 61 of 64<br />

8.04E-05


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Beryllium 1.85E-04 <strong>4.</strong>30E+00 B2 a 7.94E-04<br />

Cobalt<br />

Iron<br />

Manganese<br />

Nickel<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,1 -Dichloroethene<br />

2.98E-03<br />

<strong>4.</strong>30E+00<br />

8.73E-02<br />

2.29E-03<br />

1.75E+00<br />

<strong>4.</strong>19E-02<br />

2.78E+00<br />

8.39E-03<br />

3.39E-05 6.00E-01<br />

D<br />

NA<br />

C a 2.03E-05<br />

1,2-Dichloroethene<br />

Phenanthrene<br />

Trichloroethene<br />

5.34E-04<br />

3.49E-06<br />

1.86E-05 1.1OE-02<br />

NA<br />

D<br />

NA e 2.05E-07<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

9.55E+04<br />

<strong>4.</strong>97E+05<br />

1.48E+04 3.00E-10<br />

<strong>4.</strong>44E-06<br />

Thorium-228<br />

<strong>4.</strong>88E+03 2.31E-10<br />

1.13E-06<br />

Uranium-234<br />

8.29E+04 <strong>4.</strong>44E-11<br />

3.68E-06<br />

Uranium-235<br />

6.96E+03 <strong>4.</strong>70E-11<br />

3.27E-07<br />

Uranium-238<br />

1.75E+05 6.20E-11<br />

1.08E-05<br />

Pathway Total<br />

8.35E-04<br />

WAG 7, SWMU 8b, FGW-Future Industrial Inhalation of Groundwater<br />

Aluminum<br />

Beryllium<br />

Cobalt<br />

Iron<br />

Manganese<br />

Nickel<br />

Silica<br />

Silicon<br />

Sulfate<br />

Sulfide<br />

1,1 -Dichloroethene<br />

1,2-Dichloroethene<br />

Phenanthrene<br />

Trichloroethene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Tkonum-228<br />

Uranium-234<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

8.40E+00 B2 b<br />

D<br />

NA<br />

3.53E-06 1.20E+00 C<br />

NA<br />

D<br />

1.94E-06 6.00E-03 NA<br />

3.45E-08<br />

9.68E-08<br />

1.40E-08<br />

1.30E-08<br />

1.24E-08<br />

b<br />

e<br />

<strong>4.</strong>24E-06<br />

1.16E-08<br />

WAG 7, SWMU 8b, FSO-Future Industrial Dermal Contact with Soil<br />

Aluminum 6.33E-03 495<br />

Arsenic 2.36E-06 3.66E+00 A 8 8.62E-06<br />

Beryllium <strong>4.</strong>05E-07 <strong>4.</strong>30E+02 B2 13, 1 1.74E-04<br />

Cobalt <strong>4.</strong>50E-06 26<br />

Lead 5.8OE-06 B2 26<br />

Phosphate (ortho)<br />

3.32E-05<br />

Sodium<br />

6.33E-05<br />

Thallium 9.00E-08 NA 52<br />

2-Methylnaphthalene 1.40E-07 43<br />

Aroclor-1260 3.33E-08 8.56E+00 B2 46 2.85E-07<br />

Benzo( a)anthracene 2.01E-07 2.35E+00 B2 2 <strong>4.</strong>74E-07<br />

Benzo(a)p yrene 2.93E-07 2.35E+01 B2 2 6.89E-06<br />

Benzo@)fluoranthene 3.31E-07 2.35E+00 B2 2 7.79E-07<br />

Dibenzofuran<br />

2.87E-07<br />

Indeno( 1,2,3-cd)pyrene 2.68E-07 2.35E+00 B2 2 6.31E-07<br />

Naphthalene 2.93E-07 D 43<br />

Phenanthrene 2.67E-07 D 2<br />

Gross Alpha<br />

Gross Beta<br />

Page 62 of 64<br />

<strong>4.</strong>25E-06


~~<br />

Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

Pathway Total<br />

1.92E-04<br />

WAG 7, SWMU 8b, FSO-Future Industrial External Exposure to Soil<br />

Aluminum<br />

b<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Meth ylnaphthalene<br />

Aroclor-1260<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Dibenzokan<br />

Indeno( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

A<br />

BZ<br />

BZ<br />

NA<br />

BZ<br />

BZ<br />

BZ<br />

B2<br />

BZ<br />

D<br />

D<br />

b<br />

b<br />

b<br />

b<br />

h<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

b<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

<strong>4.</strong>80E+01<br />

8.05E+O 1<br />

9.13E+00 <strong>4.</strong>62E-07<br />

b<br />

h<br />

b <strong>4.</strong>22E-06<br />

Thorium-228<br />

5.11E+00 9.94E-07<br />

b 5.08E-06<br />

Thorium-230<br />

2.37E+03 <strong>4.</strong>40E-11<br />

b 1.04E-07<br />

Uranium-23 5<br />

8.81E-01 2.65E-07<br />

b 2.33E-07<br />

Uranium-238<br />

1.73E+01 5.25E-08<br />

b 9.09E-07<br />

Pathway Total<br />

1.05E-05<br />

XAti 7, SWMU 8b, FSO-Future Industrial Ingestion of Soil<br />

Aluminum<br />

1.90E-03<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

Lead<br />

Phosphate (ortho)<br />

Sodium<br />

Thallium<br />

2-Methylnaphthalene<br />

Aroclor- 1260<br />

Benzo(a)anthracene<br />

Benzo( a)pyrene<br />

Benzo(b)fluoranthene<br />

Dibenzofuran<br />

Indene( 1,2,3-cd)pyrene<br />

Naphthalene<br />

Phenanthrene<br />

Gross Alpha<br />

Gross Beta<br />

Neptunium-237<br />

Thorium-228<br />

Thorium-230<br />

Uranium-235<br />

Uranium-238<br />

7.07E-07<br />

1.22E-07<br />

1.35E-06<br />

1.74E-06<br />

9.96E-06<br />

1.90E-05<br />

2.70E-08<br />

2.10E-08<br />

5.00E-09<br />

3.02E-08<br />

<strong>4.</strong>39E-08<br />

<strong>4.</strong>96E-08<br />

<strong>4.</strong>30E-08<br />

<strong>4.</strong>02E-08<br />

<strong>4.</strong>40E-08<br />

<strong>4.</strong>01E-08<br />

3.28E+03<br />

5.5 1E+03<br />

6.25E+02<br />

3.5OE+02<br />

1.63E+05<br />

6.03E+01<br />

1.18E+03<br />

1.50E+00<br />

<strong>4.</strong>30E+00<br />

7.70E+00<br />

7.30E-01<br />

7.30E+00<br />

7.30E-01<br />

7.30E-01<br />

3.00E- 10<br />

2.31E-10<br />

3.75E-11<br />

<strong>4.</strong>70E- 11<br />

6.20E-11<br />

A<br />

B2<br />

BZ<br />

NA<br />

BZ<br />

BZ<br />

BZ<br />

B2<br />

BZ<br />

D<br />

D<br />

a<br />

a<br />

a<br />

1.06E-06<br />

5.23E-07<br />

3.85E-08<br />

2.20E-08<br />

3.20E-07<br />

3.62E-08<br />

2.93E-08<br />

1.88E-07<br />

8.09E-OR<br />

6.09E-06<br />

2.83E-09<br />

7.35E-08<br />

8.47E-06<br />

Arsenic<br />

Beryllium<br />

Cobalt<br />

bad<br />

6.60E-11 5.OOE+01 A b 3.30E-09<br />

1.14E-11 8.40E+00 B2 b 9.54E-3 1<br />

1.26E- 10<br />

1.62E-10<br />

B2<br />

Page 63 of 64


Excess Lifetime Cancer Risks (continued)<br />

SLOPE OF SF SPECIFIC PATHWAY EXPOSUR<br />

ANALYTE CDI FACTOR EVIDENCE SOURCE RISK RISK ERISK<br />

Phosphate (ortho)<br />

9.30E-10<br />

Sodium<br />

1.77E-09<br />

Thallium 2.52E-12 NA<br />

2-Methylnap hthalene 1.96E-12<br />

Aroclor- 1260 <strong>4.</strong>66E-13 B2<br />

Benzo(a)anthracene 2.82E- 12 B2<br />

Benzo(a)pyrene <strong>4.</strong>10E-12 B2<br />

Benzo(b)fluoranthene <strong>4.</strong>63E-12 BZ<br />

Dibenzofuran<br />

<strong>4.</strong>02E-12<br />

Indene( 1,2,3-cd)pyrene 3.75E-12 BZ<br />

Naphthalene <strong>4.</strong>11E- 12 D<br />

Phenanthrene 3.74E-12 D<br />

Gross Alpha<br />

3.07E-01<br />

Gross Beta 5.14E-0 1<br />

Neptunium-237 5.84E-02 3.45E-08 2.01E-09<br />

Thorium-228 3.27E-02 9.68E-08 3.16E-09<br />

Thorium-230<br />

1.52E+01 1.72E-08 2.61E-07<br />

Uranium-235 5.63E-03 1.30E-08 7.32E-11<br />

Uranium-238 1.llE-01 1.24E-08 1.37E-09<br />

Pathway Total<br />

2.71E-07<br />

S WMU Total<br />

1.52E-03<br />

Page 64 of 64


Appendix L.8<br />

Chemicals of Concern


mnmsuMMARyFo~<br />

ANTIMONY<br />

DECEMBER 1992<br />

Prepared by<br />

Robert k Young, PbD., D.kB.T.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National hboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy<br />

under Contract No. DE-ACO5-840FU1400


ntis page intentionally le/t blank


EXECUTIVESUMMARY<br />

Antimony (Sb) is a naturally occurring metal that is used in various manufacturing<br />

processes. It exists in valence states of 3 <strong>and</strong> 5 (Budavari, 1989; ATSDR. 1990). Antimony<br />

is a common urban air pollutant (Beliles, 1979). Exposure to antimony may be via inhalation,<br />

oral <strong>and</strong> dermal routes (ATSDR, 1990).<br />

Antimony is sparingly absorbed following ingestion or inhalation (Felicetti et al., 1974a;<br />

Gerber et al., 1982, ATSDR, 1990). Both gastrointestinal <strong>and</strong> pulmonary absorption are a<br />

function of compound solubility. Antimony is transported in the blood, its distribution varying<br />

among species <strong>and</strong> dependent on its valence state (Felicetti et al., 1974b). Antimony is not<br />

metabolized but may bind to macromolecules <strong>and</strong> react covalently with sulfhydryl <strong>and</strong><br />

phosphate groups (A’ISDR, 1990). Excretion of antimony is primarily via the urine <strong>and</strong> feces,<br />

<strong>and</strong> is also dependent upon valence state (Cooper et aL, 1%8, Ludersdorf et aL, 1987;<br />

ATSDR, 1990).<br />

Acute oral exposure of humans <strong>and</strong> animals to high doses of antimony or antimonycontaining<br />

compounds (antimonials) may cause gastrointestinal disorders (vomiting, diarrhea),<br />

respiratory difficulties, <strong>and</strong> death at extremely high doses (Bradley <strong>and</strong> Frederick, 1941;<br />

Beiiles, 1979; ATSDR, 1990). Subchronic <strong>and</strong> chronic oral exposure may affect hematologic<br />

parameters (ATSDR, 1990). Long-term exposure to high doses of antimony or antimonials<br />

has been shown to adversely affect longevity in animals (Schroeder et al., 1970). Limited data<br />

suggest that prenatal <strong>and</strong> postnatal exposure of rats to antimony interferes with vasomotor<br />

responses (Marmo et aL, 1987; Rossi et aL, 1987).<br />

Acute inhalation exposure of humans may cause gastrointestinal disorders (probably due<br />

to ingestion of airborne antimony) (AISDR 1990). Exposure of animals to high<br />

concentrations of antimony <strong>and</strong> antimonials (especially stibine gas) may result in pulmonary<br />

edema <strong>and</strong> death (Price et ai., 1979). Long-term occupational exposure of humans has<br />

resulted in electrocardiac disorders, respiratory disorders, <strong>and</strong> possibly increased mortality<br />

(Renes, 1953; Breiger et ai., 1954). Antimony levels for these occupational exposure<br />

evaluations ranged from 2.2 to 11.98 mg Sb/m3. Based on limited data, occupational exposure<br />

of women to metallic antimony <strong>and</strong> several antimonials has reportedly caused alterations in<br />

the menstrual cycle <strong>and</strong> an increased incidence of spontaneous abortions (Belyaeva, 1967).<br />

Reproductive dysfunction has been demonstrated in rats exposed to antimony trioxide<br />

(Beiyaeva, 1967).<br />

No data were available indicating that dermal exposure of humans to antimony or its<br />

compounds results in adverse effects. However dermal application of high doses of antimony<br />

oxide (1,584 mg Sbkg) resulted in the death of rabbits within one day (IBTL, 1972). Eye<br />

irritation due to exposure to stibine gas <strong>and</strong> several antimony oxides has been reported for<br />

humans (Stevenson. 1965; Potkonjak <strong>and</strong> Pavlovich, 1983).<br />

The U. S. EPA (U.S. EPA, 1991, 1992) has calculated subchronic <strong>and</strong> chronic oral<br />

reference doses (RfDs) of 4E-4 mg/kg/day based on decreased longevity <strong>and</strong> alteration of<br />

blood chemistry in rats chronically exposed to potassium antimony tartrate in the drinking ,<br />

water (5 ppm equivalent to 0.35 mg Sb/kg/day). An uncertainty factor of LOO0 was applied:<br />

10 for extrapolation from a lowest-obsented-adverse-effect-level (LOAEL) to a no-observed-<br />

1


adverse-effect-level (NOAEL), 10 for extrapolation from animal data, <strong>and</strong> 10 €or protection<br />

of sensitive populations.<br />

The primary target organ €or acute oral exposure to antimony appears to be the<br />

gastrointestinal tract (irritation, diarrhea, vomiting) <strong>and</strong> targets for long-term exposure are the<br />

blood (hematological disorders) <strong>and</strong> liver (mild hepatotoxicity) (ATSDR, 1990). Inhalation<br />

exposure to antimony affects the respiratory tract (pneumoconiosis, restrictive airway<br />

disorders), with secondary targets being the cardiovascular system (altered blood pressure <strong>and</strong><br />

electrocardiograms) <strong>and</strong> kidneys (histological changes) (Renes, 1953; Breiger et al., 1954).<br />

Only limited evidence exists €or reproductive disorders due to antimony exposure (Belyaeva,<br />

1967).<br />

Although some data indicate that long-term exposure of rats to antimony trioxide <strong>and</strong><br />

trisulfide increased the incidence of lung tumors (Wong et al, 1979; Watt, 1980, Groth et aL,<br />

1986; Bio/dynamics, lw), the U.S. EPA has not evaluated antimony or antimonials for<br />

carcinogenicity <strong>and</strong> a Weight*€-Evidence classification is currently unavailable.<br />

2


1. INTRODUCTION<br />

Antimony (CAS No. 7440-36-0) is a naturally occumng metalloid element (displaying<br />

both metallic <strong>and</strong> nonmetallic properties) existing in valence states of 3 <strong>and</strong> 5 (Budavari,<br />

1989, ATSDR, 1990). Metallic antimony <strong>and</strong> a few trivalent antimony compounds are the<br />

most significant regarding exposure potential <strong>and</strong> toxicity (ATSDR, 1990). Antimony (Sb)<br />

is used in metallurgical processes, paints <strong>and</strong> enamels, various textiles, rubber, <strong>and</strong> fire<br />

retardation (antimony trioxide). Antimony is a common urban air pollutant, occurring at an<br />

average concentration of 0.001 pg/m3 (Beliles, 1979). Exposure to antimony may occur via<br />

inhalation <strong>and</strong> by ingestion of contaminated food. Some antimonials such as potassium<br />

antimony tartrate have been used medicinally as parasiticides (Beliles, 1979).<br />

21. ABWRPTION<br />

Antimony is only slowly absorbed from the gastrointestinal tract. Based on animal data,<br />

gastrointestinal absorption of antimony was estimated to be 2 to 7% (Felicetti et al., 1974a;<br />

Gerber et al., 1982). The specific chemical form will determine the absorption efficiency of<br />

ingested antimony. Antimony has been detected in the blood of occupationally exposed<br />

individuals, but it is uncertain if this was due solely to pulmonary absorption or also to<br />

ingestion following mucociliary transport from the upper respiratory tract (ATSDR, 1990).<br />

Alveolar deposition <strong>and</strong> subsequent absorption of small particle-size antimony or antimony<br />

compounds is likely, with absorption also being a function of compound solubility. Sunagawa<br />

(1981) <strong>and</strong> Aimworth (1988) provided data showing a lack of a dose-response relationship<br />

for absorption, <strong>and</strong> that antimony levels in lungs <strong>and</strong> livers of rodents reached a plateau,<br />

thereby suggesting that antimony absorption by tissues may be a saturable process. Studies<br />

with rabbits exposed to antimony trioxide or pentoxide provided evidence for dermal<br />

absorption of these forms of antimony (1B"L. 1972; Myers et aL, 1978).<br />

Antimony is transported in the blood, its partitioning between erythrocytes <strong>and</strong> plasma<br />

being a function of the valence state of the element. Exposure to trivalent antimony resulted<br />

in higher antimony levels in erythrocytes than in the plasma while exposure to pentavalent<br />

antimony resulted in a reversal of this partitioning (Felicetti et al., 1974b). However, the<br />

distri'bution of parenterally administered antimony is highly variable among species, <strong>and</strong> can<br />

not be accounted for solely by valence state (Felicetti et aL, 1974b; Beliles, 1979). Antimony<br />

has been detected in the liver <strong>and</strong> spleen (more so for pentavalent forms), <strong>and</strong> the thyroid<br />

gl<strong>and</strong> (trivalent forms) (Beliles, 1979). Felicetti et aL (1974a,b) also reported accumulation<br />

of antimony in the skeletal system <strong>and</strong> in fur.<br />

31. MErABoLIsM<br />

Like other metallic elements, antimony is not subject to catabolism. Its metabolic<br />

transformations are limited to binding with macromolecules, <strong>and</strong> covalent interactions with<br />

sulfhydryl groups <strong>and</strong> phosphates. There is no definitive data regarding the interconversion<br />

3


of valence states of antimony (ATSDR, 1990).<br />

2<strong>4.</strong> EXC”I0N<br />

Animal <strong>and</strong> human data are available indicating both urinary <strong>and</strong> fecal excretion of<br />

antimony (ABDR, 1990). Workers exposed to antimony trioxide had increased urinary levels<br />

of antimony (Cooper et al, 1968, Ludersdorf et aL, 1987). Urinary excretion of antimony was<br />

documented for workers exposed to antimony fumes (Renes, 1953; Breiger et al., 1954).<br />

Fecal excretion of antimony following ingestion of antimonials represents primarily<br />

unabsorbed antimony. However, there is evidence suggesting that the valence state of<br />

antimony may affect the excretory mute. Parenteral administration experiments with animals<br />

<strong>and</strong> humans have indicated that trivalent antimony is excreted primarily in the urine while<br />

pentavalent antimony is excreted in the feces (Felicetti et aL, 1974b; Edel et al., 1983).<br />

Whole-body clearance of trivalent antimony tartrate is biphasic with 90% of the body burden<br />

being excreted Within 24 hours, <strong>and</strong> the slower phase having a half-life of 16 days (Felicetti<br />

et al., 1974b). Urinary antimony levels in a human subject remained above normal (1 pg/g<br />

creatinine) for one week following a single oral dose (amount unknown) of antimony<br />

trisulfate (Bailly et aL, 1991). This same study also documented biliary excretion <strong>and</strong><br />

enterohepatic circulation of parenterally administered antimony in rats.<br />

3. NONCARCINOGENIC HEALTH EFFECIS<br />

3.1. ORAL EXPOSURES<br />

3.1.1. Acute Toxicity<br />

3.1.1.1. Human<br />

-<br />

Acute poisoning has occur re^ as the result o€ accidental or suicidal ingestion of<br />

antimonials (Beliles, 1979) with death ensuing Within several hours. Symptoms of severe<br />

antimony poisoning include vomiting, watery diarrhea, collapse, irregular respiration, <strong>and</strong><br />

hypothermia. A single dose of potassium antimony tartrate (equivalent to 0.53 mg Sbkg)<br />

produced vomiting (Dunn, 1928).<br />

3.1.1.2 Animal<br />

Toxic effects ranging from gastrointestinal disorders to death have been documented €or<br />

animals following acute oral expure to antimonials. Bradley <strong>and</strong> Frederick (1941) reported<br />

that a single dose (300 mg Sbkg) of the organic antimonial, potassium antimony tartrate,<br />

induced myocardial infarction <strong>and</strong> death in rats. However, several studies using inorganic<br />

antimonials (metallic antimony, antimony oxide, or antimony trioxide) reported that doses as<br />

high as 27,410 mg Sbkg were not fatal to rats (ATSDR, 1990).<br />

3.12 Subdhronw: TOX~C~Q<br />

3.1.21. Human<br />

4


No information was available regarding the toxic effects of subchronic oral exposure of<br />

humans to antimony or antimonials.<br />

3.122 Animal<br />

Several studies have described the systemic subchronic toxicity of antimony <strong>and</strong><br />

antimonials in animals <strong>and</strong> are summarized in A'ISDR (1990) <strong>and</strong> U.S. EPA (1980).<br />

Subchronic (24-week) exposure of rats to metallic antimony at doses of 500 to 1,OOO<br />

mg/kg/day decreased plasma protein levels, hemoglobin levels, <strong>and</strong> hematocrit (Sungawa, 1981;<br />

Hiraoka, 1986). Sungawa (1981) also reported mild hepatotoxicity in rats receiving 418 mg<br />

%&$day<br />

(as antimony trioxide) or 500 mg Sbkg/day (as metallic antimony). A decrease in<br />

red blood cell count was reported by Sungawa (1981) for rats given 418 mg Sbkg/day (as<br />

antimony trioxide) for 24 weeks, <strong>and</strong> an increase reported by Smyth <strong>and</strong> Thompson (1945)<br />

in rats treated with same compound at a dose of 894 mg Sb/kg/day for 30 days. Fleming<br />

(1982) reported that dogs receiving antimony trioxide (6,644 mg Sbkg/day) for 32 days<br />

exhibited severe weight loss, vomiting, <strong>and</strong> muscle weakness <strong>and</strong> dyskinesia of the hind limbs.<br />

A lower dose (&I mg Sbkg/day) produced severe diarrhea. Using data from Fleming (1982),<br />

ATSDR (1990) reported a noabserved-adverseeffect-level (NOAEL) of 501 mg Sbkg for<br />

rats receiving the compound for 20 days. Exposure of CD-1 mice to potassium antimony<br />

tartrate in the drinking water (5 ppm for 540 days) significantly reduced the lifespan of both<br />

des <strong>and</strong> females (Kanisawa <strong>and</strong> Schroeder, 1W).<br />

3.13. CbronicTaxidty<br />

3.13.1. Human<br />

No information was available regarding the chronic toxicity of antimony in humans.<br />

3.13.1. Animal<br />

Schroeder et al. (1970) showed an increase in serum cholesterol <strong>and</strong> a decrease in<br />

fasting glucose levels for rats receiving a lifetime exposure to potassium antimony tartrate<br />

(746 mg Sbkg) in drinking water. However, the biological significance of these findings is<br />

not certain (ATSDR, 1990). This same study also provided data showing that long-term<br />

exposure of rats to potassium antimony tartrate in the drinking water (0.262 mg Sbkglday<br />

equivalent to 2 ppm in drinking water)<br />

resulted in decreased lifespan.<br />

3.1.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1. Human<br />

No information was available regarding the developmental or reproductive toxicity of<br />

antimony in humans.<br />

3.1.<strong>4.</strong>1. Animal<br />

The effect of prenatal <strong>and</strong> postnatal exposure of rats (gestation day one to postnatal day<br />

5


60) to antimony trichloride indicated that drinking water levels as low as 0.1 mg% produced<br />

alterations in vasomotor responses (Marmo et al., 1987; Rossi et al., 1987). The same effect<br />

was observed for exposure throughout lactation to postnatal day 60. Although the antimony<br />

trichloride exposure affected vasomotor responses during the postnatal developmental period,<br />

the design of these studies did not allow for definitive conclusions regarding the prenatal<br />

developmental toxicity of the compound.<br />

3.15.1. Subchronic<br />

ORAL RfD,:<br />

4E-4 mg/kg/day (metallic antimony)<br />

9E-4 mg/kg/day (potassium antimony tartrate)<br />

4E-4 mg/kg/day (antimony tetroxide, antimony trioxide)<br />

5E-4 mg/kg/day (antimony pentoxide)<br />

UNCERTAINTY FACI'OR: loo0<br />

NO&<br />

None<br />

3.152 Chronic<br />

ORAL RED,:<br />

4E-4 mg/kg/day (metallic antimony)<br />

9E-4 mg/kg/day (potassium antimony tartrate)<br />

4E-4 mg/kg/day (antimony tetroxide, antimony trioxide)<br />

5E-4 mg/kg/day (antimony pentoxide)<br />

UNCERTAINTY FACTOR: loo0<br />

MODIFYING FAaOR: 1<br />

NO&<br />

None<br />

LO&<br />

035 mg/kg/day<br />

CONFIDENCE<br />

Study:<br />

Data base:<br />

RfD:<br />

Low<br />

Low<br />

Low<br />

VERIFICATION DATE: 11106185<br />

PRINCIPAL STUDY Schroeder et aL. 1970<br />

CO-:<br />

Based on decreased longevity <strong>and</strong> altered blood chemistry values in rats<br />

chronically exposed to 5 ppm potassium antimony tartrate in drinking water. An<br />

uncertainty factor of 1,ooO was applied to account for extrapolation from animal data<br />

(lo), use of a LOAEL (lo), <strong>and</strong> for protection of sensitive populstions (10). The values<br />

for all of the compounds were calculated based on elemental equivalent weight of<br />

antimony (U.S. EPA, 1991, 1992).<br />

6


32 INHALATIONEXPOSURES<br />

321. Aca~teToxicity<br />

321.1. Human<br />

Inhalation of antimony dust by factory workers pra~ced gastrointestinal irritation,<br />

probably the result of antimony dust transported via the mucociliary escalator (AISDR,<br />

1990). However, no information regarding the acute inhalation toxicity of antimony was<br />

available.<br />

3212 Animal .<br />

Exposure of rats <strong>and</strong> guinea pigs to stibine gas (SbH,) at a concentration of 1,395 mg<br />

Sbh' for 30 minutes resulted in pulmonary edema <strong>and</strong> death (Price et al., 1979). At 799<br />

mg Sb/m3, the guinea pigs <strong>and</strong> rats exhibited only renal tubular dilation.<br />

3221. Human<br />

Several occupational exposure studies have been conducted that evaluated the effects<br />

of subchronic cxposure of smelter workers to antimony fumes. Renes (1953) reported that<br />

c 5 month exposures to antimony fumes at concentrations ranging from <strong>4.</strong>69 to 11.82 mg/m3<br />

produced various conditions (rhinitis, dermatitis, laryngitis, bronchitis, pneumonitis,<br />

conjunctivitis, <strong>and</strong> septal perforations) the severity of which increased with increasing duration<br />

of scposure. These workers, however, were also exposed to low concentrations of arsenic<br />

(039 to 1.10 mum3). The effects of occupational cxposure to antimony trioxide (0.58 to 55<br />

mg/m3) for periods of 8 months to 2 years were reported by Breiger et al. (1954). Eight of<br />

the employees died during this period but only one death had ocamed in the 16 years prior<br />

to the use of antimony. Additionally, abnormal electrocardiograms were detected in 37 of 75<br />

workers <strong>and</strong> some workers also exhibited elevated blood pressure. The findings of this study<br />

are compromised by concurrent exposure to phenol formaldehyde resin. However, the<br />

investigators noted that no additional deaths occurred <strong>and</strong> the incidence of electrocardiac<br />

anomalies decreased following cessation of antimony use.<br />

3.222 Animal<br />

Gross et al. (1952) reported that inhalation exposure of rats to antimony trioxide for up<br />

to 14 months resulted in lipoid pneumonia. Myocardial damage <strong>and</strong> alteration of<br />

electrocardiograms were observcd for rats <strong>and</strong> rabbits exposed for six weeks to antimony<br />

trisulfide dust at concentrations of 220 <strong>and</strong> <strong>4.</strong>02 mg Sb/m3, respectively (Brieger et aL, 1954).<br />

This same study also noted similar effects in dogs exposed for 10 weeks to antimony trisulfide<br />

(3.98 mg Sbim3). Thirteen-week exposure of rats to antimony trioxide (0.92 mg Sb/m3)<br />

resulted in nonreversible proliferation of alveolar macrophages (Bio/dynamia, 1989). Sevtral<br />

studies reviewed in A'ISDR (1990) reported interstitial fibrosis in rats exposed for 12 to 145<br />

months to antimony trisulfide or antimony trioxide at concentrations ranging from 1.6 to 83.6<br />

mg Sbim?<br />

7


3-3.1. Human<br />

Occupational exposure to antimony trioxide <strong>and</strong>/or antimony pentoxide dust (9 to 31<br />

years) resulted in respiratory effects including pneumoconiosis, chronic bronchitis, chronic<br />

emphysema, pleural adhesions, <strong>and</strong> obstructive pulmonary effects (Cooper et aL, 1968,<br />

Potkonjak <strong>and</strong> Pavlovich, 1983). The pneumoconiosis was characterized by chronic coughing,<br />

wheezing, <strong>and</strong> upper airway irritation. Shorter-term occupational exposures (Renes, 1953;<br />

Brieger et aL, 1954) are described in <strong>Section</strong> 3.2.21.<br />

3-32 Animal<br />

No information regarding the chronic toxicity of antimony or antimony-wntaining<br />

compounds was available, although animal studies employing long-term exposures (12 to 1<strong>4.</strong>5<br />

months) examined the effects of several antimony-containing compounds (see <strong>Section</strong> 3.22.2).<br />

32<strong>4.</strong> Devclopmentai <strong>and</strong> Reproductive Toxicity<br />

In a report lacking in detail, Belyaeva (1%7) noted an increased incidence of<br />

spontaneous abortions <strong>and</strong> disturbances in the menstrual cycle of women occupationally<br />

exposed to airborne metallic antimony, antimony trioocide, <strong>and</strong> antimony pentasulfide<br />

3242 Animal<br />

Belyaeva (1967) reported a decrease in the number of ofipring for rats exposed to<br />

antimony trioxide (209 mg Sb/m3) prior to mating <strong>and</strong> throughout gestation. Exposure to this<br />

concentration prior to mating resulted in a 67% failure in conception. Metaplasia in the<br />

uterus <strong>and</strong> disturbances in ovum maturation were detected in the animals that did not<br />

conceive.<br />

Reference concentrations are currently unavailable.<br />

33. oTHERROUTESOFExpoGuRE<br />

33.1. AcuteTcdcity<br />

33.1.1. Human<br />

No dermatologic or systemic effects were noted for human subjects having induction<br />

patches containing antimony trioxide in place for 24 hours (IWZ 1972).<br />

.<br />

8


33.12 Animat<br />

Dermal application of antimony oxide (1,584 mg Sbkg) resulted in the death of rabbits<br />

within one day (ISTI.., 1972) <strong>and</strong> dermal application of antimony trioxide (6,686 Sb mag)<br />

was also fatal to rabbits within one day (Myers et al., 1978).<br />

Ocular application of antimony oxide or antimony thioantimonate (79 to 100 mg Sb) to<br />

rabbits resulted in eye irritation (Horton et aL, 1986, IBTL., 1972; WRL, 1979) but similar<br />

application of antimony trioxide (345 to 83.6 mg Sb) did not produce irritation (Gross et aL,<br />

1955; Myers et aL, 1978).<br />

Exposure of rats <strong>and</strong> guinea pigs to stibine gas (Price et ai., 1979) or antimony trioxide<br />

(Bio/dynamics, 1985; 1989) caused eye irritation. It is likely that this effect was due to direct<br />

contact to airborne compounds rather than an inhalation-mediated toxicity.<br />

332 subchroruc Tdty<br />

3321. Human<br />

'<br />

Occupational exposure to airborne antimony or antimony trioxide has resulted in<br />

dermatitis (epidermal cellular necrosis with inflammatory cellular reactions) <strong>and</strong> ocular<br />

irritation (ocular conjunctivitis), the effects being more pronounced in higher temperature<br />

environments (Stevenson, 1%5; Potkonjak <strong>and</strong> Pavlovich, 1983).<br />

3322 Animal<br />

Thirteen-week dermal exposure of rabbits to a 5% solution of a mixture of antimony<br />

trisulfide <strong>and</strong> antimony pentasulfide did not produce significant signs of toxicity (Horton et<br />

aL.1986). -<br />

No human or animal data were available regarding the chronic toxicity of antimony by<br />

other exposure mutes.<br />

33.<strong>4.</strong> hdopmentalToxkity<br />

NO human or animal data were available regarding the developmentalheproductive<br />

toxicity of antimony by other exposure routes.<br />

9


3.<strong>4.</strong> TARGET ORGANS/CRITICAL EFFECIS<br />

3.<strong>4.</strong>1. Oral Expuns<br />

3.<strong>4.</strong>1.1. primary Taqpt(s)<br />

1. Gastrointestinal tract: The gastrointestinal tract appears to be the primary target<br />

€or acute <strong>and</strong> long-term oral exposure to antimony <strong>and</strong> antimonials. Effects are<br />

characterized by imtation resulting in vomiting <strong>and</strong> diarrhea These effects have<br />

been documented €or both humans <strong>and</strong> animals.<br />

3.<strong>4.</strong>12 other Target@)<br />

1.<br />

2<br />

3.<br />

<strong>4.</strong><br />

Cardiovascular system: Data arc available suggesting that oral exposure to<br />

antimony or antimonials may affect the cardiovascular system resulting in a<br />

decreased hypotensive response.<br />

Blood: Animal data are available showing mild hematologk effects although the<br />

biological significance of these effects is uncertain.<br />

Liver: Limited data in animals have shown mild hepatotoxkity following oral<br />

exposure to antimony <strong>and</strong> antimonials.<br />

Developmental toxicity is suggested by animal data showing that prenataupostnatal<br />

exposure to antimony may affect cardiovascular functions.<br />

3.421. Primary Target($)<br />

1. Respiratory tract: The respiratory tract is the primary target for toxicity of<br />

inhaled antimony <strong>and</strong> antimonials following acute, subchronic, <strong>and</strong> chronic<br />

exposure. Both human <strong>and</strong> animal data have demonstrated various forms of<br />

restrictive airway diseases including pneumoconiosis, bronchitis, emphysema,<br />

pulmonary edema, <strong>and</strong> varying degrees of imtation <strong>and</strong> inflammation.<br />

1. Cardiovascular system: Cardiovascular effects (alterations in blood pressure <strong>and</strong><br />

electrocardiograms) have been documented in humans exposed to antimony <strong>and</strong><br />

antimonials. Similar effects have also been verifed using several animals species.<br />

2 Kidney: Renal toxicity (histological changes) has been observed €or animals<br />

exposed to stibine gas <strong>and</strong> various antimony oxides <strong>and</strong> sulfides.<br />

3. Reproductive tract Limited data are available indicating adverse effects on the<br />

reproductive system of women occupationally exposed to antimony. One study<br />

in rats has also shown reproductive/developmental toxicity of antimony.<br />

10


<strong>4.</strong>1. ORAL p[posuRE<br />

<strong>4.</strong>1.1. Human<br />

<strong>4.</strong>12. Animal<br />

No information was available regarding the carcinogenicity of antimony in humans.<br />

No definitive data were available regarding the carcinogenicity of antimony in animals.<br />

Although evidence for an increased incidence of cancer was not observed for rats <strong>and</strong> mice<br />

fed potassium antimony tartrate (0.262 <strong>and</strong> 035 mg Sbkg/day, respectively), the maximum<br />

tolerated dose was not used (Schroeder, 1968; Kanisawa <strong>and</strong> Schroeder, 1969; Schroeder,<br />

1970).<br />

421. Human<br />

Evidence of increased incidence of cancer was not detected in workers exposed to<br />

antimony oxide for 9 to 31 years (Potkonjak <strong>and</strong> PavloVich, 1983).<br />

422 Animal<br />

Lung tumor incidence was increased for rats exposed for one year to <strong>4.</strong>2 or 36 rng<br />

Sbhn' as antimony trioxide (Wong et al, 1979, Watt, 1980, Groth et al., 1986) or 17.48 mg<br />

Sb/m3as antimony trisulfide (Wong et aL, 1979; Groth et al, 1986). An increased incidence<br />

of lung tumors was also reported by Bio/dynamics (1989) for rats exposed to antimony tnioxidc<br />

(3.76 mg Sb/m3) <strong>and</strong> by Watt (1983) for pigs exposed to the same compound at a<br />

concentration of <strong>4.</strong>2 mg Sbhn3.<br />

43. OTHER ROUTES OF EXPOWRE<br />

No data were available regarding the potential carcinogenicity of antimony <strong>and</strong><br />

antimonials by other router of exposure.<br />

<strong>4.</strong><strong>4.</strong> EPA mGHT-OF-EVIDRKE CXASIFICA'IION<br />

The U.S. EPA has not evaluated antimony regarding its potential carcinogenicity <strong>and</strong>,<br />

therefore, a Weightsf-Evidence classification has not been assigned (U.S. EPA, 1991).<br />

45. CARCINOGENICITY SLxlPE FACIORS<br />

None have been calculated.<br />

11


5. REFERENCES<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1990. Antimony. ATSDFUU.S.<br />

Public Health Service, DRAFT.<br />

Ainsworth, N. 1988 Distribution <strong>and</strong> biological effects of antimony in contaminated<br />

grassl<strong>and</strong>. Dissertation. (Cited in A'ISDR, 1990)<br />

Bailly, R, R Lauwerys, J. P. Buchet, P. Mahieu <strong>and</strong> J. Konings. 1991. Experimental <strong>and</strong><br />

human studies on antimony metabolism: their relevance for the biological monitoring of<br />

workers exposed to inorganic antimony. Brit. J. Indust. Med. 4893-97.<br />

Beliles, R P. 1979. The lesscr metals. In Oehme, F. W., Ed., Toxicity of heavy metals in the<br />

environment, Marcel Dekker, New York, pp. 547615.<br />

Belyaeva, A P.<br />

1132. (Cited in ATSDR, 1990)<br />

1967. The effect of antimony on reproduction. Gig. Truda. Prof. Zabol.<br />

Bio/dynamiu. 1985. A three month inhalation toxicity study of antimony trioxide in the rat<br />

followed by a recovery perid Prepared by Bio/dynamics, Inc. E Millstone, NJ for the<br />

Antimony Oxide Industry Assoc., Washington, D.C (Cited in ATSDR, 1990)<br />

Bio/dynamics. 1989. A one-year inhalation toxicity study of antimony trioxide in the rat (with<br />

a one year recsovcry period)- month 18 interim report. Prepared by Bio/dynamics, Inc., E<br />

Millstone, NJ for the Antimony Oxide Industry Assoc, Washington, D.C. (Cited in ATSDR,<br />

1990)<br />

Bradley, W.R <strong>and</strong> W. G. Frederick 1941. The toxicity of antimony - animal studies. Ind<br />

Med. 1015-22 (Cited in ATSDR, 1990)<br />

Breiger, €I., C W. Semisch, J. Stasney <strong>and</strong> D.A Piatnek. 195<strong>4.</strong> Industrial antimony poisoning.<br />

Iadust. Med. Health 23521-523. (Cited in ATSDR, 1990)<br />

Budavari, S. ed. 1989. The Merck Index An Encyclopedia of Chemicals, Drugs, <strong>and</strong><br />

Biologicals. 1 lth Ed. Merck <strong>and</strong> CQ., Rabway, NJ. p. 110.<br />

Cooper, Dlk, E P. Pendergrass, A J. Vonvald, et aL 1968 Pneumoconiosis among workers<br />

ia an antimony industry. Am. J. RoentgenoL Rad. Ther. Nuclear Med. 103:495-508. (Cited<br />

in ATSDR, 1990)<br />

Duan, J. T. 1928. A curious case of antimony poisoning. Analyst 531532-533. (Cited ia<br />

ATSDR, 1990)<br />

Felicetti, S. W., R G. Thomas <strong>and</strong> €2.0. McCLellan. 1974a. Retention of inhaled antimony-<br />

124 in the beagie dog as a function of temperature of aerosol formation. Health Phys. 26525-<br />

531.<br />

12


Felicetti, S. W., R G. Thomas <strong>and</strong> R. 0. McClellan. 1974b. Metabolism of two valence states<br />

of inhaled antimony in hamsters. Am. Ind. Hyg. Assoc. J. 355292-300. (Cited in ATSDR,<br />

1990)<br />

Fleming, A. J. 1982. The toxicity of antimony trioxide. Sponsored by E I. DuPont de<br />

Nemours <strong>and</strong> Co., Wilmington, DE O'IS215027. (Cited in ATSDR, 1990)<br />

Gerber, G. B., J. Maes <strong>and</strong> B. Eykens. 1982 Transfer of antimony <strong>and</strong> arsenic to the<br />

developing organism. Arch. Toxicol. 49159-168<br />

Gross, P., J. H. U. Brown, <strong>and</strong> T. E Hatch. 1952 Experimental endogenous lipoid<br />

pneumonia. Am. J. PathoL 28211-221. (Cited in A'ISDR 1990)<br />

Gross, P., J. H. U. Brown, M. L Westrick, et aL 1955. Toxicological study of calcium<br />

halophosphate phosphers <strong>and</strong> antimony trioxide. I. Acute <strong>and</strong> chronic toxicity <strong>and</strong> some<br />

pharmacologic aspects. Arch. Ind. Health 11:473-478. (Cited in A'ISDR, 1990)<br />

Groth, D. R,'L E Stettler, J. R Burg, et aL 1986. Carcinogenic effects of antimony trioxide<br />

<strong>and</strong> antimony ore concentrate in rats. J. ToxiwL Environ. Health. 18607426. (Cited in<br />

ATSDR 1990)<br />

Hiraoka, N. 1986. The toxicity <strong>and</strong> org<strong>and</strong>istniution of antimony after chronic<br />

administration to rats. J. Kyoto Prefect. Univ. Med. 95997-1017. (Cited in ATSDR 1990)<br />

Horton J. R, Gawroski, C. I,., Newton, P. E, et aL 1986. Evaluation of the acute tooriCity,<br />

hitation, sensitization, <strong>and</strong> subchronic dermal toxicity of antimony thioantimonate lubricant.<br />

NTIS/AD-A166 873/0/ (Cited in ATSDR, 1990)<br />

IBTL (Industrial Biotest Laboratories).<br />

O'IS2&5223. (Cited in ATSDR 1990)<br />

1972. Acute toxicity with antimony oxide.<br />

Kankawa, M. <strong>and</strong> H. A Schroeder. 1969. Life term studies on the effects of trace elements<br />

on spontaneous tumors in mice <strong>and</strong> rats. Cancer Res. 29892-895. (Cited in ATSDR, 1990)<br />

Ludersdorf, R, A Fuchs, P. Mayer et al. 1987. Biological assessment of exposure to<br />

antimony <strong>and</strong> lead in the glass-producing industry. Int. Arch. Occup. Environ. Health 59469-<br />

47<strong>4.</strong> (Cited in A'ISDR, 1990)<br />

Marmo, E., M. G. Matera, R Acampora, et aL 1987. Prenatal <strong>and</strong> postnatal metal exposure:<br />

effect on vasomotor reactivity development of pup. Cur. Thcr, Res. 42S23-838<br />

Myers, R C, E. R Homan, C S. Well, et aL 1978. Antimony trioxide range-finding toxicity<br />

studies. Carnegie-Mellon Inst. of Res, carnegie-Mellon Univ., Pittsburgh, PA OTS206062<br />

(Cited in ATSDR, 1990)<br />

Potkonjak, V. <strong>and</strong> M. Pavlaicb 1983. AntimoniosiS: A particular form of pneumoconiosh<br />

1. Etiology, clinical <strong>and</strong> x-ray findings. Int. Arch. Occup. Environ. Health 51:199-207. (Cited<br />

in ATSDR, 1990)<br />

.<br />

13


Price, N. H., W. G. Yates <strong>and</strong> S. D. Allen. 1979. Toxicity evaluation for establishing IDLH<br />

values. National Institute for Occupational Safety <strong>and</strong> Health, Cincinnati, OH; PB87-229498.<br />

(Cited in ATSDR, 1990)<br />

Renes, L E 1953. Antimony poisoning in industry. Arch. In& Hyg. 799-108.<br />

Rossi, E, R Acampora, C. Vacca, et al. 1987. Prenatal <strong>and</strong> postnatal antimony exposure in<br />

rats: effect on vasomotor reactivity development of pups. Teratogen. Carcinogen. Mutagen.<br />

7:491-4%.<br />

Schroeder, H. A, M. Mitchener, J. J. Balassa, et al. 1968. Zirconium, niobium, antimony <strong>and</strong><br />

fluorine in mice: Ef€ects on growth, survival <strong>and</strong> tissue levels. Nutr. 9595-101.<br />

Schroeder, H. A, M. Mitchener <strong>and</strong> A P. Nason. 1970. Zirconium, niobium, antimony,<br />

vanadium <strong>and</strong> lead in rats: Life-time studies. J. Nutr. 10&59-68.<br />

Smyth, H.F., Jr. <strong>and</strong> W. L. Thompson. 1945. The single dose <strong>and</strong> subacute-toxicity of<br />

antimony oxide (Sb20,). Mellon Inst. of Indust. Res, Univ. of Pittsburgh. 013206062. (Cited<br />

in ATSDR, 1990)<br />

Stevenson, C. J. 1965. Antimony spots. Trans. St. John's Hospital Dermat. SOC. 51:40-42<br />

(Cited in ATSDR, 1990)<br />

Sunagawa, S. 1981. Experimental studies on antimony poisoning. Igaku Kenkyu 51:129-142<br />

(Cited in ATSDR, 1990)<br />

U.S. EPA 1980. Ambient water quality criteria document for antimony. EPA-440/5-8M)20,<br />

US. EPA 1991. Antimony. Integrated Risk Information System (IRIS). Environmental<br />

Criteria <strong>and</strong> Assessment Office,Ofice of Health <strong>and</strong> Environmental Assessment, Cincinnati,<br />

OH.<br />

U.S. EPA 1992. Health Effects Assessment Summary Tables, Fy-1992 AnnuaL OfTce of<br />

Research <strong>and</strong> Development, OfTce of Emergency <strong>and</strong> Remedial Response, Washington, D.C.<br />

OERR 9200.6-303(X).<br />

Watt, W.D. 1980. Chronic inhalation toxicity of antimony trioxide: validation for the TLV -<br />

,progress report-summary of results. OTS206195. (Cited in ATSDR, 1990)<br />

WRL (Wil Research Laboratories). 1979. Acute eye irritation study in rabbits with antimony<br />

oxide. PPG Indust., Inc., Pittsburgh, PA (Cited in A'ISDR, 1990)<br />

Wong, L C. K, J. M. Winston, J. Hagensen, et aL 1979. Study of carcinogenicity <strong>and</strong> toxicity<br />

of inhaled antimony trioxide, antimony ore concentrate <strong>and</strong> thallic oxide in rats. NIOSWUS.<br />

Dept. Health. 0130511065. (Cited in ATSDR, 1990)<br />

14


TOXICITYSUMMARY<br />

for<br />

INORGANIC ARSENIC<br />

April 1992<br />

Prepared by<br />

Dennis M. Opresko, PbD.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

+Managed by Martin Marietta Energy Systems, Inc., for the US. Department of Energy<br />

under Contract No. DE-AC05-840R21400


Thir page intentionaUy lefi blank


The toxicity of inorganic arsenic (As) depends on its valence state (-3, +3, or +5), <strong>and</strong><br />

also on the physical <strong>and</strong> chemical properties of the compound in which it occurs. Trivalent<br />

(Ast3) compounds are generally more toxic than pentavalent (As”) compounds, <strong>and</strong> the<br />

more water soluble compounds are usually more toxic <strong>and</strong> more likely to have systemic effects<br />

than the less soluble compounds, which are more likely to cause chronic pulmonaxy effects<br />

if inhaled. One of the most toxic inorganic arsenic compounds is arsine gas (ASH,). It should<br />

be noted that laboratory animals are generally less sensitive than humans to the toxic effects<br />

of inorganic arsenic. In addition, in rodents the critical effects appear to be immunosuppression<br />

<strong>and</strong> hepato-renal dysfunction, whereas in humans the skin, vascular system, <strong>and</strong><br />

peripheral nemus system are the primary target organs.<br />

Water soluble inorganic arsenic compounds are absorbed through the G.I. tract (>90%)<br />

<strong>and</strong> lungs; distributed primarily to the liver, kidney, lung, spleen, aorta, <strong>and</strong> skin; <strong>and</strong> excreted<br />

mainly in the urine at rates as high as 80% in 61 hr following oral dosing (U.S. EPA, 1984;<br />

ATsDR, 1989, Crecelius, 1977). Pentavalent arsenic is reduced to the trivalent form <strong>and</strong><br />

then methylated in the liver to less toxic methylarsinic acids (ATSDR, 1989).<br />

Symptoms of acute inorganic arsenic poisoning in humans are nausea, anorexia, vomiting,<br />

epigastric <strong>and</strong> abdominal pain, <strong>and</strong> diarrhea. Dermatitis (edoliative erythroderma), m d e<br />

cramps, cardiac abnormalities, hepatotoxicity, bone marrow suppression <strong>and</strong> hematologic<br />

abnormalities (anemia), vascular lesions, <strong>and</strong> peripheral neuropathy (motor dysfunction,<br />

paresthesia) have also been reported (US. Air Force, 1990. ATSDR, 1989, Franzblau <strong>and</strong><br />

Lilis, 1989; U.S. EPA 1984, Armstrong et al, 1984, Hayes, 1982; Mizuta et aL, 1956). Oral<br />

doaes as low as 20-60 pg/kg/day have been reported to cause toxic effects in some individuals<br />

(ATSDR, 1989). Severe exposures can result in acute encephalopathy, congestive heart<br />

failure, stupor, convulsions, paralysis, coma, <strong>and</strong> death. The acute lethal dose to humans has<br />

been estimated to be about 0.6 mg/kg/day (ATSDR, 1989). General symptoms of chronic<br />

arsenic poisoning in humans are weakness, general debility <strong>and</strong> lassitude. loss of appetite <strong>and</strong><br />

energy, loss of hair, hoarseness of voice, loss of weight, <strong>and</strong> mental disorders (Hindmarsh <strong>and</strong><br />

McCurdy, 1986). Primary target organs are the skin (hyperpigmentation <strong>and</strong> hyperkeramis)<br />

frerada et ai. 1%0, Tseng et ai, 1968; Zaldivar 1974; Cebrian et al., 1983; Huang et al,<br />

19851, nemus system (peripheral neuropathy) (Hindmarsh et al., 1977, 1986; Valentine et<br />

al.,<br />

1% Heyman et aL, 1956, Mizuta et al, 1956: Tay <strong>and</strong> Seah, 19751, <strong>and</strong> vascular system<br />

pSeng et al, 1%8, Borgano <strong>and</strong> Greiber, 1972; Salcedo et aL, 1984; Wu et al., 1989, Hansen,<br />

19901. Anemia, leukopenia, hepatomegaly, <strong>and</strong> portal hypertension have also been reported<br />

(Terada et aL, 1%0, Viallet et al., 1972; Morris et aL, 1974; Datta, 1976). In addition,<br />

possible reproductive effects include a high male to female birth ratio (Lyster, 1977).<br />

In animals, acute oral exposures can cause gastrointestinal <strong>and</strong> neurological effects<br />

(Heymod <strong>and</strong> Sortwell. 1979). Oral LD, values range from about 10 to 300 mgikg<br />

(-R, 1989; US. Air Force, 1990). Low subchronic doses can result in<br />

immunosuppression, (Bfakely et al, 1980) <strong>and</strong> hepato-renal effects (Mahaffey et al, 1981;<br />

Brown et ai., 1976; Woods <strong>and</strong> Fowler, 1977,1978 Fowler <strong>and</strong> Woods, 1979; Fowler et al.,<br />

1979). Chronic exposures have also resulted in mild hyperkeratosis <strong>and</strong> bile duct enlargement<br />

With hyperplasia, focal necrosis, <strong>and</strong> fibrosis (Baroni et aL, 1963; Byron et at, 1967).<br />

1


Reduction in litter size, high male/female birth ratios, <strong>and</strong> fetotoxicity without significant fetal<br />

abnormalities occur following oral exposures (Schroeder <strong>and</strong> Mitchener, 1971; Hood et aL,<br />

1977; Bdey et al., 1981); however, parenteral dosing has resulted in exencephaly,<br />

encephaloceles, skeletal defects, <strong>and</strong> urogenital system abnormalities (Ferm <strong>and</strong> Carpenter,<br />

1968; Hood <strong>and</strong> Bishop, 1972; Beaudoin, 1974; Burk <strong>and</strong> Be<strong>and</strong>oin, 1977).<br />

The Reference Dose for chronic oral exposures, 0.0003 mg/kg/day, is based on a NOAEL<br />

of O.OOO8 mg/kg/day <strong>and</strong> a LOAEL of 0.014 mg/kg/day for hyperpigmentation, keratosis, <strong>and</strong><br />

possible vascular complications in a human population consuming arseniccontaminated<br />

drinking water (U.S. EPA, 1991a). Because of uncertainties in the data U.S. EPA (1991a)<br />

states that "strong scientific arguments can be made for various values within a factor of 2 or<br />

3 of the currently recommended RfD value." The subchronic Reference Dose is the same<br />

as the chronic IUD, 0.0003 mg/&g/day (U.S. EPA, 1992).<br />

Acute inhalation exposures to inorganic arsenic can damage mucous membranes, cause<br />

rhinitis, pharyngitis <strong>and</strong> laryngitis, <strong>and</strong> result in nasal septum perforation (U.S. PA, 1m).<br />

Chronic inhalation exposures, as occurring in the workplace, can lead to rhino-pharynolaryngitis,<br />

tracheobronchitis, (Lundgren, 1954); dermatitis, hyperpigmentation, <strong>and</strong><br />

hyperkeratosis (Perry et al., 1948, Pinto <strong>and</strong> McGill, 1955); leukopenia (Kyle <strong>and</strong> Pease, 1965;<br />

Hine et aL, 1977); peripheral nerve dysfunction as indicated by abnormal nerve conduction<br />

velocities (Feldman et aL, 1979; Blom et aL, 1985; L<strong>and</strong>au et al., 1977); <strong>and</strong> peripheral<br />

vascular disorders as indicated by Raynaud's syndrome <strong>and</strong> increased vasospastic reactivity in<br />

fingers exposed to low temperatures (Lagerkvist et aL, 1986). Higher rates of cardiovascular<br />

disease have also been reported in some arsenic-exposed workers (Lee <strong>and</strong> Fraumeni, 1969,<br />

krelson et aL, 1978 Wingren <strong>and</strong> Axelson, 1985). Possible reproductive effects include a<br />

high frequency of spontaneous abortions <strong>and</strong> reduced birth weights (Nordstrbm et al,<br />

1978a,b). Arsine gas (ASH,), at concentrations as low as 3-10 ppm for several hours, can<br />

cause toxic effects. Hemolysis, hemoglobinuria, jaundice, hemolytic anemia, <strong>and</strong> necrosis of<br />

the renal tubules have been reported in exposed Workers (ACGIH, 1986, Fowler <strong>and</strong><br />

Webberg, 1974).<br />

Animal studies have shown that inorganic arsenic, by intratracheal instillation, can cause<br />

pulmonary inflammation <strong>and</strong> hyperplasia (Webb et al, 1986,1987), lung lesions (Pershagen<br />

et al., 1982), <strong>and</strong> immunosuppression (Hatch et al. (1985). Long-term inhalation exposures<br />

have resulted in altered conditioned reflexes <strong>and</strong> CNS damage (Rozenshstein, 1970).<br />

Reductions in fetal weight <strong>and</strong> in the number of live fetuses. <strong>and</strong> increases in fetal<br />

abnormalities due to retarded osteogenesis have been obserred following inhalation exposures<br />

(Nagymajtenyi et al., 1985).<br />

Subchronic <strong>and</strong> chronic RfCs for inorganic arsenic have not been derived.<br />

Epidemiological studies have revealed an association between arsenic concentrations in<br />

drinking water <strong>and</strong> increased incidences of skin cancers (including squamous cell carcinomas<br />

<strong>and</strong> multiple basal cell carcinomas), as well as cancers of the liver, bladder, respiratory <strong>and</strong><br />

gastrointestinal tracts (U.S. EPA, 1987; IARC, 1987; Sommers et aL, 1953; Reymann et aL,<br />

1978 Dobson et at, 1965; Chen et aL, 1985, 1986). Occupational exposure studies have<br />

shown a clear correlation between exposure to arsenic <strong>and</strong> lung cancer mortality (IARC,<br />

1987; U.S. EPA, 1991a). U.S. EPA (1991a) has placed inorganic arsenic in weight-of-<br />

2


evidence group A, human carcinogen. A drinking water unit risk of 5E-5(@)" has been<br />

proposed (U.S. EPA, 1991a); derived from drinking water unit risks for females <strong>and</strong> males<br />

that are equivalent to slope factors of 1.OE-3 (@g/day)" (Females) <strong>and</strong> 2.OE-3 (clgflrglday)''<br />

(males) (U.S. EPA, 1987). For inhalation exposures, a unit risk of <strong>4.</strong>3E-3 (pg/m3)-' (U.S.<br />

EPA, 1991a) <strong>and</strong> a slope factor of 5.0E+1 (mg/kg/day)-' have been derived (U.S. EPA, 1992).<br />

3


1. INTRODUCIION<br />

The toxicity of inorganic compounds containing arsenic depends on the valence or<br />

oxidation state of the arsenic (-3, +3, or +5), as well as on the physical <strong>and</strong> chemical<br />

properties of the compound in which it occurs. Trivalent (Ast3) compounds such as arsenic<br />

trioxide (As,O,), arsenic trisulfide (As&, <strong>and</strong> sodium arsenite (NaAsOJ, are generally more<br />

toxic than pentavalent (As”) compounds such as arsenic pentoxide (As,O,), sodium arsenate<br />

(NaWO,), <strong>and</strong> calcium arsenate (Ca3(ASO4)2). Trivalent arsenic interacts with sulfhydryl<br />

groups of proteins <strong>and</strong> enzymes; pentavalent arsenic substitutes for phosphate groups<br />

important in oxidative phosphorylation (Squibb <strong>and</strong> Fowler, 1983). The relative toxicity of<br />

the trivalent <strong>and</strong> pentavalent forms may also be affected by factors such as the water solubility<br />

of the compound. Although the more water soluble arsenic compounds are generally more<br />

toxic <strong>and</strong> more likely to have systemic effects, the less soluble compounds are more likely to<br />

cause chronic pulmonary effects if inhaled. One of the most toxic arsenic compounds is<br />

arsine gas (AH,) with arsenic in the -3 valence state.<br />

It should be noted that laboratory animals are generally less sensitive than humans to the<br />

toxic effects of inorganic arsenic. In addition, in rodents the critical effects appear to be immunosuppression<br />

<strong>and</strong> hepato-renal dysfunction, whereas in humans the skin. vascular system,<br />

<strong>and</strong> peripheral nervous system are the primary target organs.<br />

Z METABOLISM AND DISPOSITION<br />

21. ABSORPTION<br />

Absorption of water soluble inorganic arsenic compounds through the G.I. tract is very<br />

high. In humans, absorption rates of %.5% for trivalent sodium arsenite <strong>and</strong> 94% for<br />

soluble pentavalent arsenic have been reported (Bettley <strong>and</strong> OShea, 1975; Pomroy et aL,<br />

1980). In contrast, G.I. absorption of the less soluble arsenic trisulfide <strong>and</strong> lead arsenate was<br />

reported to be only 20-30% in hamsters (Marafante <strong>and</strong> Vahter, 1987). In tests on humans,<br />

absorption of the insoluble arsenic selenide appeared to be neglible as indicated by the<br />

absence of an increase in urinary arsenic excretion (Mappes, 1977).<br />

Absorption of arsenic in the lungs is dependant on particle size as well as water solubility;<br />

respirable particles (0.1-1 p) are carried further into the lungs <strong>and</strong> are therefore more likely<br />

to be absorbed (ATSDR 1989). Estimates of pulmonary absorption may be complicated by<br />

the fact that some of the particles may be cleared from the lungs, then swallowed <strong>and</strong><br />

absorbed through the G.I. tract. In studies on smelter workers exposed to arsenic dusts of<br />

about 5 p particle size, Lagerkvist et al. (1986) estimated that 75% of the dust would be<br />

deposited in the respiratory tract <strong>and</strong> MO of this would be absorbed directly or through the<br />

stomach after mucocillary clearance.<br />

4


22 DISX'RIBUTION<br />

Following absorption of trivalent or pentavalent arsenic compounds, arsenic is initially<br />

accumulated in the liver, kidney, lung, spleen, aorta, <strong>and</strong> skin. With the exception of the skin,<br />

clearance from these organs is rapid. Arsenic is also extensively deposited in the hair <strong>and</strong><br />

nails (U.S. EPA, 1984).<br />

Arsenic compounds are subject to metabolic transformation. In both humans <strong>and</strong> animals,<br />

pentavalent arsenic compounds are reduced to trivalent forms <strong>and</strong> then methylated in the<br />

liver to less toxic methylarsinic acids (ATSDR, 1989).<br />

2<strong>4.</strong> EXCREIION<br />

Arsenic is cleared from the body relatively rapidly <strong>and</strong> primarily in the urine. Urinary<br />

excretion rates of 80% in 61 hr following oral doses <strong>and</strong> 30430% in 4-5 days following<br />

parenteral doses have been measured in humans (Crecelius. 1977; Hunter et al., 1942).<br />

Arsenic is also lost from the body in the hair <strong>and</strong> nails, since this represents a non-biologically<br />

available arsenic pool.<br />

3. NONCARCINOGENIC HEALTH EFFECIS<br />

3.1. ORAL EXPOSURES<br />

3.1.1. Acute Toxicity<br />

-<br />

3.1.1.1. Human<br />

Common symptoms of inorganic arsenic poisoning are nausea, anorexia, vomiting,<br />

epigastric <strong>and</strong> abdominal pain, <strong>and</strong> diarrhea. Dermatitis (exfoliative erythroderma), muscle<br />

cramps, cardiac abnormalities, hepatotoxicity, bone m a w suppression <strong>and</strong> hematologic<br />

abnormalities (anemia <strong>and</strong> leukopenia), vascular lesions, <strong>and</strong> peripheral neuropathy (motor<br />

dysfunction, long axon Wallerian degeneration) have also been reported (U.S. Air Force,<br />

1990, A'TSDR, 1989, Franzblau <strong>and</strong> Lilis, 1989, U.S. EPA, 1984; Armstrong et A, 1984,<br />

Hayes, 1982; Mizuta et al., 1956).<br />

Oral doses as low as 20-60 pg/kg/day have been reported to cause toxic effects in some<br />

individuals (ATSDR, 1989). Severe exposures can result in acute encephalopathy, congestive<br />

heart failure, stupor, convulsions, paralysis, coma, <strong>and</strong> death. The acute lethal dose to<br />

humans has been estimated to be about 0.6 mg/kg/day (ATSDR, 1989). A dose estimated at<br />

3 muday for a 1-2 month period was fatal to 1% of a group of infants receiving amniccontaminated<br />

milk (Hamamoto, 1955).


3.1.1.2 Animal<br />

Monkeys exposed to acutely toxic doses of inorganic arsenic exhibit gastrointestinal<br />

distress <strong>and</strong> neurological effects. Adolescent <strong>and</strong> infant Rhesus monkeys receiving 5 daily oral<br />

doses of a complex inorganic arsenic compound containing the equivalent of 7.5 mgkg of<br />

arsenic trioxide exhibited loss of condition, vomiting, diarrhea, salivation <strong>and</strong> uncontrolled<br />

shaking of the head (Heywood <strong>and</strong> Sortwell, 1979).<br />

LD, values for inorganic arsenic compounds in laboratory animals range from about 10<br />

to 300 mgkg (ASTDR, 1989, U.S. Air Force, 1990).<br />

3.1.21. Human<br />

Depending on the dose <strong>and</strong> duration, subchronic exposures to inorganic arsenic can cause<br />

toxic effects similar to those caused by acute <strong>and</strong>/or chronic exposures. Skin <strong>and</strong> vascular<br />

disorders, neuropathy, gastroenteritis, hepatotoxicity, <strong>and</strong> hematological abnormalities (anemia<br />

<strong>and</strong> leukopenia) have been reported in individuals exposed for time periods ranging from less<br />

than 6 months to 13 years (ATSDR 1989, Huang et aL, 1985).<br />

Borgono <strong>and</strong> Greikr (1972) reported a 12% incidence of skin abnormalities in children<br />

whose drinking water contained 0.6-0.8 mg As/L. The earliest cases occurred about 4-5 years<br />

after the initial exposure. Cardiovascular effects, including Raynaud’s syndrome, acrocyanosis,<br />

angina pectoris, hypertension, myocardial infarction, mesenteric thrombosis, systemic occlusive<br />

a*rial disease, bronchiectasis, <strong>and</strong> recurrent broncho-pneumonia were also observed in this<br />

group of subjects (Zaldivar, 1980). The bronchiectasis <strong>and</strong> recurrent broncho-pneumonia<br />

were attributed to an immunosuppressive action of arsenic in the lungs. A significant<br />

decrease in the incidence of skin abnormalities was observed following a reduction in drinking<br />

water concentration to about 0.04 mg/L After 4 years at the lower exposure, effects were<br />

rarely Seen in children younger than 12 years old (Borgono et al., 1977).<br />

Central nemus system deficits (hearing loss, eye damage, abnormal EEGs, mental<br />

retardation, epilepsy), electrocardiographic changes (elevated ST wave <strong>and</strong> extended QT<br />

interval), <strong>and</strong> skin abnormalities (melanosis, desquamation, rashes, <strong>and</strong> hyperkeratosis)<br />

occurred in infants who had been fed arsenicoontaminated milk for 1-2 months (Hamamoto,<br />

1955). It was estimated that the daily arsenic intake was about 3 mg/day (U.S. EPA, 1984).<br />

Immunosuppression <strong>and</strong> hepato-renal toxicity have been identified as toxic effects in<br />

rodents. Immunosuppression, as measured by hemagglutination, radial immunodiffusion, <strong>and</strong><br />

Cunningham plaque assays, was observed in mice exposed for 3 week to sodium arsenite<br />

levels of 05 ppm in drinking water (Blakely et aL, 1980). Reported hepato-renal effects<br />

include: (1) mild swelling of renal tubular cell mitochondria <strong>and</strong> decreases in liverderived<br />

serum enzymes (aspartate aminotransferase [ASTI <strong>and</strong> alkaline phosphatase) in rats following<br />

10 weeks exposure to 50 ppm dietary arsenate (Mahaffey et aL, 1981); (2) functional <strong>and</strong><br />

ultrastructural changes in the kidneys of rats exposed for 6 weeks to arsenate concentrations<br />

6


of 85 <strong>and</strong> 125 ppm in drinking water (Brown et al., 1976); (3) disruption of liver biosynthesis<br />

of heme <strong>and</strong> 8-aminolevulinic (ALA) synthetase activity in mice <strong>and</strong> rats exposed for 6 wk<br />

to 40 <strong>and</strong> 85 ppm arsenic in drinking water (Woods <strong>and</strong> Fowler, 1977, 1978); (4) alteration<br />

of hepatocyte mitochondrial structure <strong>and</strong> liver enzyme activity (monoamine oxidase,<br />

cytochrome oxidase) in rats <strong>and</strong> mice exposed for 6 week to 20-85 ppm sodium arsenate in<br />

drinking water (Fowler <strong>and</strong> Woods, 1979; Fowler et al., 1979); <strong>and</strong> (5) increases in serum<br />

AST <strong>and</strong> alanine aminotransferase (UT) levels due to hepatocyte plasma membrane<br />

dysfunction in beagle dogs fed dietary levels of sodium arsenite equivalent to 4 mgkg for 58<br />

days followed by 8 mg/kg/day for an additional 125 days (Neiger <strong>and</strong> Osweiler, 1989).<br />

In a six-month study in which rats were fed 250 ppm pentavalent or trivalent arsenic,<br />

Douglas <strong>and</strong> Blendermann (1961) found that trivalent arsenic caused bile duct lesions <strong>and</strong> a<br />

significant depression in growth.<br />

Although arsenic-induced skin disorders are not commonly seen in rodents, eaerna,<br />

hyperplasia, <strong>and</strong> hyperkeratosis were reported in two-week-old rats dosed for 40 days by<br />

stomach intubation with 2 mg/kg/day or 10 mg/kg/day of arsenic trioxide (Ishinishi et at,<br />

1976). Avoidance conditioning responses were also impaired by these dose levels (Osato,<br />

!9n>*<br />

3.13. Chronic Toxicity<br />

3.13.1. Human<br />

General symptoms of chronic arsenic poisoning are weakness, general debility <strong>and</strong><br />

lassitude, loss of appetite <strong>and</strong> energy, loss of hair, hoarseness of the voice, loss of weight, <strong>and</strong><br />

mental abnormalities (Hindmarsh <strong>and</strong> McCurdy, 1986). Skin, neurological, <strong>and</strong> vascular<br />

disorders are the most common effects seen following long-term exposures.<br />

Skin abnormalities, particularly hyperpigmentation <strong>and</strong> hyperkeratosis have been observed<br />

in populations exposed to arsenic in drinking water (Terada et al. 1%0, Tseng et al., 1968,<br />

Zaldivar 1974; Cebrian et al., 1983; Huang et al., 1985). Tseng et al. (1968) reported an<br />

incidence rate of 18% for hyperpigmentation <strong>and</strong> 7% for hyperkeratosis in a Taiwanese<br />

population whose drinking water contained an average arsenic concentration of 0.4-0.6 ppm<br />

Skin abnormalities were also reported in 40% of patients consuming Fowler’s solution for 6-<br />

26 years (Hen, 1965).<br />

Arsenic-induced neurotoxicity is manifested as a peripheral neuropathy involving both<br />

sensory <strong>and</strong> motor nerves, <strong>and</strong> resulting in numbness <strong>and</strong> paresthesia, diminished sensations<br />

of touch, pain, heat, <strong>and</strong> cold, <strong>and</strong> muscle weakness (Hindmarsh et aL, 1977; Hindmarsh <strong>and</strong><br />

McCurdy, 1986, Valentine et al., 1982, Heyman et al., 1956, Mizuta et al., 1956; Tay <strong>and</strong><br />

Seah, 1975).<br />

Peripheral vascular disorders have been reported in several populations whose drinking<br />

water contained high arsenic levels (Tseng et aL, 1%8* Salcedo et al., 1984; Chen et al,<br />

1988). Blackfoot disease (a condition cawed by arteriosclerosis <strong>and</strong> thromboangiitis<br />

obliterans), which can result in gangrene of the lower extremities, occurred in 0.9% of one<br />

such population (Tseng et al., 1%8, 1977). Epidemiological studies <strong>and</strong> mechanistic<br />

7


considerations have implicated arsenic as a possible causative factor in arteriosclerotic plaque<br />

formation <strong>and</strong> cardiovascular disease (Wu et ai., 1989, Hansen, 1990; Penn, 1990).<br />

Chronic oral exposures to arsenic reportedly have also resulted in anemia, leukopenia,<br />

liver swelling, <strong>and</strong> noncirrhotic portal hypertension (Terada et al., 1960; Viallet et al., 1972;<br />

Morris et al., 1974; Datta, 1976 Nevens et al., 1990).<br />

3.132 Animal<br />

Studies in rats have demonstrated no-adverseeffect levels of 1.4 (males) <strong>and</strong> 1.6 mg<br />

Askglday (females) for sodium arsenite <strong>and</strong> 28 (males) <strong>and</strong> 3.25 mg As/kg/day (females) for<br />

sodium arsenate (Byron et al., 1%7). Similar studies on dogs revealed a no-adverseeffect<br />

level at 1.1 mg As/kg/day. A drinking water concentration of 5 ppm produced no toxic effects<br />

in rats when administered over an entire lifetime (Schroeder et al., 1968).<br />

Mild hyperkeratosis has been reported in mice exposed for a lifetime to arsenic oxide in<br />

drinking water at a concentration of 0.01% (Baroni et al., 1963).<br />

Bile duct enlargement with hyperplasia of the gl<strong>and</strong>ular elements, focal necrosis, <strong>and</strong><br />

fibrosis was Seen in rats receiving dietary arsenic levels of 125 <strong>and</strong> 250 ppm as sodium arsenite<br />

<strong>and</strong> 250 <strong>and</strong> 400 ppm as sodium arsenate for up to two years (Byron et aL, 1967). Lifetime<br />

(29 mo) exposure to lead arsenate at a dietary level of 1850 pprn also caused bile duct lesions<br />

in rats (Kroes et aL, 1974).<br />

3.1.<strong>4.</strong> DRlelopmental <strong>and</strong> Reproductive Tolddty<br />

3-1.<strong>4.</strong>1. Human<br />

A high male-to-female birth ratio (157 to 10) was reported for a population that may<br />

have been exposed to elevated arsenic levels in their drinking water 10 to 11 months earlier<br />

(Lyster, 1977).<br />

3.1.42 Animal<br />

Chronic exposure of pregnant mice to 5 ppm sodium arsenite in drinking water resulted<br />

in a slight reduction in litter size <strong>and</strong> a higher male/female ratio (increased from 0.93 to 1.71),<br />

but no adverse effects on fetal development (Schder <strong>and</strong> Mitchner, 1971). Oral doses as<br />

high as 120 mgAcg/day of sodium arsenate were reported to be fetotoxic but not teratogenic<br />

to rats (Hood et aL, 1977). Oral doses of 25-40 mgkg of sodium arsenite caused prenatal<br />

mortality <strong>and</strong> a low, but non-significant, incidence of fetal malformations (exencephaly) in<br />

mice (Baxley et aL, 1981).<br />

3.15.1. Subchronic<br />

ORAL RfD. 0.0003 mg/kg/day (U.S. EPA. 1992)<br />

UNCERTAINTYFACIOR: 3<br />

8


NOAEL: O.OOO8 mgAcg/day, epidemiological study.<br />

COMMENT: The same study applies to the subchronic <strong>and</strong> chronic RfD (see <strong>Section</strong><br />

3.1.5.2).<br />

3.152 chronic<br />

ORAL RfD: 0.0003 mg/kg/day (U.S. EPA, 1991a)<br />

UNCERTAINTYFACTOR: 3<br />

MODlFYINGFACTOR 1<br />

NOAEL: 0.0008 mg/kg/day, epidemiological study<br />

CONFIDENCE:<br />

StndF Medium<br />

Data Base:Medium<br />

=.Medium<br />

VERIFICATION DATE: 11/15/90<br />

PRINCIPAL STUDIES: Tseng, W.P. 1977; Tseng et al., 1968<br />

COMMENT: The NOAEL was based on an arithmetic mean of 0.009 mg/L in drinking<br />

water (range 0.001-0.17 mg/L), a daily water consumption of <strong>4.</strong>5 L, <strong>and</strong> an arsenic intake<br />

in food of 0.002 muday. A LOAEL of 0.014 mg/kg/day for hyperpigmentation, keratosis,<br />

<strong>and</strong> possible vascular complications. was based on an arithmetic mean of 0.14 mg/L in<br />

drinking water (<strong>4.</strong>5 Uday), <strong>and</strong> 0.002 mg/kg in food. The UF of 3 is to account for both<br />

the lack of data to preclude reproductive toxicity as a critical effect <strong>and</strong> to account for<br />

some uncertainty in whether the NOAEL of the Critical study accounts for all sensithe<br />

individuals.<br />

NOTE: U.S. EPA (1991a) states that "strong scientific arguments can be made for various<br />

values within a factor of 2 or 3 of the currently recommended RfD value, i.c, 0.1-0.8<br />

)rg/kg/day"; therefore, considerable flexibility is allowed in formulating regulatory decisions.<br />

3.21. Acute Toxicity<br />

321.1. Human<br />

Inorganic arsenic dusts can cause respiratory irritation <strong>and</strong> mucous membrane damage<br />

leading to rhinitis, pharyngitis or laryngitis. Several weeks exposure to high concentrations<br />

can result in nasal septum perforation (U.S. EPA, 1984). Although inhalation exposures to<br />

most inorganic arsenic compounds are not usually associated with acute lethality (ATSDR,<br />

1989); exposure to 250 ppm of arsine gas is instantly fatal <strong>and</strong> several hours exposure to<br />

concentrations as low as 10 ppm can produce toxic symptoms <strong>and</strong> may also be fatal (Fowler<br />

<strong>and</strong> Webberg, 1974; NOSH, 1979). Arsine causes severe hemolysis, hernoglobmuria,<br />

9


jaundice, hemolytic anemia, <strong>and</strong> necrosis of the renal tubules (ACGIH, 1986; Fowler <strong>and</strong><br />

Weissberg, 1974).<br />

3.21.2 Animal<br />

Intratracheal instillation studies indicate that inorganic arsenic can have direct toxic effects<br />

on respiratory tissue. Trivalent arsenic oxide <strong>and</strong> gallium arsenide were shown to cause<br />

pulmonary inflammation <strong>and</strong> hyperplasia in rats (Webb et aL, 1986, 1987), <strong>and</strong> calcium<br />

arsenate caused lung lesions in hamsters; however, arsenic trioxide <strong>and</strong> arsenic trisulfide did<br />

not have such an effect (Pershagen et aL, 1982).<br />

The pulmonary immune response can be affected by inorganic arsenic compounds. Hatch<br />

et al. (1985) reported significant increases in mortality of mice due to infectious streptococcal<br />

challenge following intratracheal injection of sodium arsenite, <strong>and</strong> Aranyi et aL (1985)<br />

reported similar increases in mortality as well as decreases in pulmonary bactericidal activity<br />

to MebsielZa pneumonia following single <strong>and</strong> multiple inhalation exposures to arsenic trioxide.<br />

Exposure of mice to arsine concentrations as low as 25 ppm caused significant decreases<br />

in red blood cells, hematocrit <strong>and</strong> hemoglobin, as well as significant increases in white blood<br />

cell counts, <strong>and</strong> mean corpuscular volume of RBC. Erythropoiesis in bone marrow cells was<br />

impaired <strong>and</strong> erythropoiesis in the spleen was increased (Hong et al., 1989).<br />

3221. Human<br />

Subchronic inhalation exposures to inorganic arsenic are expected to cause toxic effects<br />

similar to those resulting from chronic exposures (see <strong>Section</strong> 3.2.3).<br />

Rats exposed for 3 months to 46 )rum3 of arsenic trioxide aerosol exhibited altered<br />

conditioned reflexes <strong>and</strong> CNS damage as evidenced by pericellular edema <strong>and</strong> neuronal<br />

cytolysis in the brain (Rozenshstein. 1970).<br />

Rats exposed to 0.025 ppm arsine gas for 90 days developed anemia (Blair et al., 1990).<br />

Higher exposure levels (primarily 2.5 ppm) resulted in bone marrow hypcrplasia, increased<br />

splenic hemosiderosis <strong>and</strong> extramedullary hematopoiesis, decreased packed cell volume,<br />

increased delta-aminolevulinic acid dehydratase activity, <strong>and</strong> increased relative spleen weight.<br />

Similar effects were seen in mice <strong>and</strong> hamsters.<br />

3a.1. Human<br />

Information on the inhalation toxicity of inorganic arsenic is derived primarily from<br />

occupational expotsure studies, particularly those involving smelter workers. Early studies<br />

identified chronic respiratory diseases (rhinitis, pharyngitis, laryngitis, tracheobronchitis, <strong>and</strong><br />

10


pulmonary insufficiency) <strong>and</strong> blood disorders (leukopenia) in exposed workers (Lundgren,<br />

1954; Kyle <strong>and</strong> Pease, 1%5). In one study, a 23% incidence of relative neutropenia occurred<br />

in 130 smelter workers exposed to arsenic air concentrations averaging less than 0.5 mum3<br />

(Hine et aL, 1977).<br />

Neurological disorders (peripheral newe dysfunction indicated by abnormal nerve<br />

conduction velocities) have been documented in smelter workers exposed to arsenic<br />

concentrations of sO.5 mum3 (Feldman et al., 1979 Blom et al., 1985; L<strong>and</strong>au et al., 1977).<br />

Chronic encephalopathy, evidenced by cognitive impairment <strong>and</strong> psychological symptoms was<br />

reported in two workers exposed to arsenic fumes for 14-18 months (Morton <strong>and</strong> Caron,<br />

1989). Abnormal electromyograms were reported for populations living near an arsenic mine<br />

<strong>and</strong> smelter (Takahashi, 1974). Hearing losses have been reported in children living near a<br />

coal-fired power plant burning high-arsenic content coal (U.S. EPA, 1984).<br />

Chronic exposure of smelter workers to low levels of atmospheric arsenic (so5 mg/m3)<br />

caused subtle changes in the peripheral vascular system, as indicated by an increased incidence<br />

of Raynaud’s syndrome (white fingers) <strong>and</strong> increased vasospastic reactivity in fingers exposed<br />

to low temperatures (Lagerhist et al., 1986). Higher rates of cardiovascular disease have also<br />

been reported in some arsenicexposed workers (Lee <strong>and</strong> Fraumeni, 1%9 Axelson et aL,<br />

1978; Wingren <strong>and</strong> Axelson, 1985).<br />

Dermatitis, hyperpigmentation, <strong>and</strong> hyperkeratosis were observed in early studies of<br />

workers exposed to inorganic arsenic (Perry et al., 1948, Pinto <strong>and</strong> McGill, 1953); howevcr,<br />

it is not known to what degree the reported effects were due to direct skin contact <strong>and</strong><br />

accidental ingestion of the arsenic dust.<br />

Chronic exposure to very low levels of arsine gas may have a cumulative effect in causing<br />

anemia (FowIer <strong>and</strong> Weissberg, 1974).<br />

Glaser et al. (1986) exposed male Wistar rats to aerosols (~0.3 pm MMAD) of arsenic<br />

trioxide for 18 months at concentrations of 0.60, <strong>and</strong> 200 pg/m3. The animals were observed<br />

for one year after the termination of the exposures <strong>and</strong> no adverse effects on body weight,<br />

hematology, clinical chemistry, or macro- or microscopic structure of internal organs were<br />

reported.<br />

32<strong>4.</strong>1. Human<br />

A significantly higher frequency of spontaneous abortions (1 1% vs 7.6%) <strong>and</strong> significantly<br />

reduced birth weights were recorded for a population living near a copper smelter when<br />

compared with control populations (Nordstrbm et al., 1978a.b).<br />

3242 Animal<br />

11


Nagymajtenyi et al. (1985) exposed mice for 4 hr/day to an aerosol of arsenic trioxide<br />

(285 mum3) on days 9-12 of gestation, <strong>and</strong> found a significant reduction in fetal weight <strong>and</strong><br />

in the number of live fetuses. In addition, there was a significant increase in the number of<br />

fetuses with retarded osteogenesis <strong>and</strong> an increase in the frequency of chromosomal<br />

aberrations (chromosome breaks <strong>and</strong> chromatid exchanges). Concentrations of 2.9 mg/m' <strong>and</strong><br />

0.26 mg/m3 caused no significant changes, except a slight decrease in fetal weight.<br />

Subchronic <strong>and</strong> chronic FUCs for inorganic arsenic have not been derived.<br />

33. oTHERRO~OFExpomTRE<br />

33.1. Acute Taddty<br />

33.1.1. Human<br />

Information on the acute toxicity of inorganic arsenic to humans by other routes of<br />

exposure was not available.<br />

33.12 Animal<br />

Intraperitoneal LDw, values of 4-20 mgkg for various inorganic arsenic compounds have<br />

been reported (A'ISDR, 1989).<br />

332 SubcbFWw: * Toxicity<br />

3321. Human<br />

-<br />

Information on the subchronic toxicity of inorganic arsenic to humans by other routes of<br />

exposure was not available.<br />

3322 Animal I<br />

Intraperitoneal injections of sodium arsenate solution at a dose level of 0.2 m&g for two<br />

months, resulted in inner ear damage <strong>and</strong> hearing loss in guinea pigs (Aly et aL, 1975).<br />

333. Chronic Taxicity<br />

333.1. Humau<br />

Skin contact with inorganic arsenic dusts in occupationally exposed workers has been<br />

associated with direct dermatitis, allergenic hypersensitivity, <strong>and</strong> conjunctivitis (U.S. EP4<br />

1984, Pinto <strong>and</strong> McGI11, 1953; Holmqvist, 1951).<br />

12


333.2 Animal<br />

Weekly injections of up to 10 mg/kg/day, for 18 months did not produce signs of<br />

neuropathy in rats (Schaumburg, 1980).<br />

33.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

33.<strong>4.</strong>1. Human<br />

Information on the developmental <strong>and</strong> reproductive toxicity of inorganic arsenic to<br />

humans by other routes of exposure was not available.<br />

33.42 Animal<br />

Some inorganic arsenic compounds cause teratogenic effects when administered<br />

parenterally. Intravenous injections of sodium arsenate into hamsters on day 8 of gestation<br />

at dose levels of 15, 17.5, or 20 mgkglday resulted in exencephaly, encephaloceles, skeletal<br />

defects, <strong>and</strong> urogenital system abnormalities in fetuses (Ferm <strong>and</strong> Carpenter, 1968).<br />

Intraperitoneal injections of sodium arsenate, at doses levels of 30 mg/kg/day or higher,<br />

resulted in similar terata in rats <strong>and</strong> mice (Hood <strong>and</strong> Bishop, 1972; Beaudoin, 1974; Burk <strong>and</strong><br />

Beaudoin, 1!377).<br />

3.<strong>4.</strong> TARGEI' ORGAN/C€UTIICAL EFFEcIs<br />

3.<strong>4.</strong>1.1. Primary Target Organs<br />

1. Skk Hyperpigmentation ana hyperkeratosis in humans.<br />

2 Newus System: Peripheral neuropathy <strong>and</strong> CNS effects in humans.<br />

3. Cardiovascular System: Peripheral <strong>and</strong> cardiovascular disorders in humans.<br />

1. Blood. Hematological changes (anemia, leukopenia).<br />

2 Liver: Liver swelling in humans; cirrhosis <strong>and</strong> portal hypertension in animals.<br />

3. G.I. System: Gastroenteritis in humans <strong>and</strong> monkeys at high doses.<br />

<strong>4.</strong> Reproductive Effects: Increased male to female birth ratio in animals <strong>and</strong> possibly in<br />

humans.<br />

13


3.42 Inhalam * nbpxwres<br />

3.421. Primary Target Organs<br />

1. Skin: Dermatitis <strong>and</strong> possibly hyperpigmentation <strong>and</strong> hyperkeratosis in humans.<br />

2. Nervous System: Peripheral neuropathy <strong>and</strong> CNS effects in humans.<br />

3. Cardiovascular System: Peripheral vascular disorders in humans.<br />

3.<strong>4.</strong>2.2 other Target Organs<br />

1. Respiratory system: Rhinitis, laryngitis, tracheobronchitis, pulmonary insufficiency, <strong>and</strong><br />

nasal septum perforation.<br />

2 Blood: Hematological changes (anemia, leukopenia).<br />

3. Developmental Effects: Increase in spontaneous abortions, reduction in birth weight<br />

observed in animals <strong>and</strong> humans.<br />

<strong>4.</strong>1. ORAL EXPOSURES<br />

<strong>4.</strong>1.1. Human<br />

Epidemiological studies have revealed a close association between arsenic concentrations<br />

in drinking water <strong>and</strong> increased incidences of skin cancers, including squamous cell carcinomas<br />

<strong>and</strong> multiple basal cell carcinomas (U.S. EPA, 1987). Tseng et al. (1968) reported skin cancer<br />

rates of 26, 10.1 <strong>and</strong> 21.4 per lo00 in Taiwancse populations whose drinking water contained<br />

~0.30, 030-059, <strong>and</strong> 20.6 ppm As. respectively. No cases of skin cancer were seen in a<br />

control population of 7500 whose drinking water contained 0.001-0.017 ppm As. Cebrian et<br />

aL (1983) reported a 3.6-fold increase in skin lesions thought to be associated with epidermoid<br />

or basal cell carcinomas, in residents of a Mexican town whose drinking water contained 0.4<br />

PPm As-<br />

Chronic oral exposure to arsenic has aiso been linked to various types of internal cancers,<br />

including those of the liver, bladder, <strong>and</strong> respiratory <strong>and</strong> gastrointestinal tracts (U.S. EPA,<br />

198% IARC, 1987, Sommers <strong>and</strong> McManus, 1953; Reymann et d, 1978 Dobson et aL, 1%5;<br />

Chen et aL, 1985,1986).<br />

4-12 Animal<br />

OF the many studies conducted on laboratory animals, only a few have been able to show<br />

a positive association between oral exposure to arsenic <strong>and</strong> increased tumor incidence. both<br />

(1966/67) reported increased incidences of adenocarcinomas of the skin, lung, peritoneum,<br />

14


<strong>and</strong> lymph nodes in NMRI mice dosed with arsenic trioxide or Fowler’s solution once per<br />

week for 5 months (estimated total dose 7 mganimal). Katsnelson et al. (1986) reported that<br />

arsenic trioxide induced a low incidence of adenocarcinomas at the site of its implantation in<br />

the stomach of rats. In addition, Shirachi et al. (1983) reported that sodium arsenite<br />

enhanced the incidence of renal tumors induced in rats by intraperitoneal injection of the<br />

carcinogen N-nitrosodiethylamine.<br />

421. Human<br />

Occupational exposure studies of smelter <strong>and</strong> pesticide workers have shown a close<br />

association between exposure to arsenic <strong>and</strong> lung cancer mortality (IARC, 1987; U.S. EPA,<br />

1991a). A dose- <strong>and</strong> durationdependent increased frequency of respiratory tract cancers was<br />

found in copper smelter workers exposed to air-borne arsenic concentrations averaging up<br />

to 62 mum3 (arithmetic mean) (Lee <strong>and</strong> Fraumeni, 1%9; Lee-Feldstein, 1983,1986,1989).<br />

St<strong>and</strong>ardized mortality ratios (SMR) as high as 981 <strong>and</strong> a maximum relative risk of 6 were<br />

reported (Lee-Feldstein, 1986, 1989). At another smelter, lung cancer mortality rates were<br />

correlated with cumulative arsenic exposure as measured by urinary arsenic excretion values,<br />

<strong>and</strong> arsenic concentrations of 10 mum3 were linked to a SMR greater than 200 (Enterline<br />

<strong>and</strong> Marsh, 1982, Enteriine et al., 1987). Similarly, in a study of Swedish smelter workers, a<br />

clear positive dose-response relationship was found between cumulative arsenic exposure <strong>and</strong><br />

lung cancer mortality <strong>and</strong> the overall SMR was 372 (Jirup et al., 1989). Both proportionate<br />

mortality <strong>and</strong> cohort studies of pesticide workers have also shown an increased incidence of<br />

lung cancer deaths (Ott et al., 1974; Mabuchi et al., 1979).<br />

An increased risk of lung cancer may also occur in non-occupationally exposed populations<br />

living in areas with high atmospheric levels of arsenic resulting from industrial emissions.<br />

Higher lung cancer rates have been reported in residents living near smelters (Brown et aL,<br />

1984; Pershagen 1985) <strong>and</strong> near an arsenic pesticide manufacturing plant (Matanoski et aL,<br />

1981).<br />

Several animal studies have shown an association between tumor induction <strong>and</strong> exposure<br />

to arsenic by inhalation or intratracheal instillation. Ivankovic et al. (1979) reported that lung<br />

tumors developed in 9 of 15 BD IX rats given a single intratracheal instillation of Bordeaux<br />

mixture (4% calcium arsenate containing 0.07 mg As). In another study, calcium arsenate<br />

induced a borderline increase in lung adenomas following intratracheal instillation, but arsenic<br />

trisulfide had no effect on tumor incidence. Perinatal treatment of mice with arsenic trioxide<br />

resulted in the induction of lung adenomas (Rudnay <strong>and</strong> BarzSanyi 1981), <strong>and</strong> intratracheal<br />

instillation of the same compound in hamsters resulted in respiratory tract carcinomas,<br />

adenomas, papillomas <strong>and</strong> adenomatoid lesions (Ishinishi et al., 1983; Pershagen et aL,<br />

1 Ma,<br />

b).<br />

43. OTHERROUTESOF-<br />

15


Osswald <strong>and</strong> Goerttle (1971) reported a high incidence (11/19) of lymphocytic leukemia<br />

or lymphomas in female Swiss mice injected intravenously with 0.5 mg Askg (as sodium<br />

arsenate) once per week for 20 weeks. In a second study with pregnant mice injected<br />

subcutaneously with 0.5 m@g, once per day for 20 days during pregnancy, 1 1 of 24 developed<br />

the same types of tumors.<br />

DiPaolo <strong>and</strong> Cast0 (1979) reported that sodium arsenate induced cell transformations bz<br />

vim in Syrian hamster embryo cells, <strong>and</strong> Cast0 et al. (199) reported that sodium arsenite<br />

enhanced virus-induced cell transformation.<br />

<strong>4.</strong><strong>4.</strong> EPA WEXGHT-OF-EVIDENCE<br />

<strong>4.</strong><strong>4.</strong>1. Oral<br />

Classification - A; human carcinogen (U.S. EPA, 1991b)<br />

Basis - Increased skin cancer incidence in several populations consuming drinking water<br />

with high arsenic concentrations.<br />

4-42 Inhalation<br />

Classification - A; human carcinogen (U.S. EPA, 1991a)<br />

Basis - Increased lung cancer mortality in populations exposed primarily through<br />

inhalation.<br />

45. SIXlPEFACLORS<br />

45.1. Oral<br />

SLOPE FACTOR: 1.OE-3 (pg/kg/dayyl (females) <strong>and</strong> 20E-3 (Ccgflrgday)" (males) (U.S.<br />

EPA, 1987). These slop factors were based on unit risks of 3E-5 (females) <strong>and</strong> 7E-5<br />

(&)*I (males) that were used to derive a single drinking water unit risk as shown below.<br />

DRINKING WATER UNIT RISK: 5E-5 (@)-I<br />

(U.S. EPA, 1991a).<br />

PRINCIPAL STUDIES: Tseng et al.. 1968; Tseng, 1977<br />

VERIFICATION DATE: Not given.<br />

COMMENT: The final unit risk is the arithmetic mean of the unit risks derived for<br />

females <strong>and</strong> males in a population in Taiwan exposed to arsenic in drinking water.<br />

Uncertainties associated with this unit risk involve the dose-response relationship,<br />

particularly in regard to (1) differential mortality due to other arsenic-induced diseases,<br />

(2) the possibility that ingestion of arseniccontaminated foods contributed to the effects,<br />

<strong>and</strong> (3) the shape of the dose-response cum at low doses. A memor<strong>and</strong>um from the<br />

EPA administrator noted that the "uncertainties associated with ingested inorganic arsenic<br />

are such that estimates could be modified downwards as much as an order of magnitude,<br />

relative to risk estimates associated with most other carcinogens."<br />

16


452 Inhalation<br />

SLOPE FAmOR 5.OE+1 (mg/kg/day)-’ (U.S. EPA, 1992)<br />

INHALATION UNIT RISK: <strong>4.</strong>3E-3 (pg/m3)” (U.S. EPA, 1991a)<br />

PRINCIPAL STUDIES: Brown <strong>and</strong> Chu, 1983a-c. Lee-Feldstein, 1983; Higgins, 1982,<br />

Enterline <strong>and</strong> Marsh, 1982<br />

VERIFICATION DATE: 01/13/88<br />

COMMENT: The final unit risk is the geometric mean of the geometric means for<br />

distinct exposed populations of workers at two different copper smelters. It was assumed<br />

that the increase in age-specific mortality was a function only of cumulative exposure.<br />

The unit risk should not be used if the air concentration exceeds 2 @m3 (U.S. EPA,<br />

1992).<br />

17


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ACGM (American Conference of Governmental Industrial Hygienists). 1986.<br />

Documentation of TLVs. Arsine. American Conference of Governmental Industrial<br />

Hygienists, Cincinnati, OH. p. 39.<br />

Aly, S. Mousa; El-Kahky, M.; Saleh, A; El-Mofty, A 1975. Toxic deafness. Histological<br />

study of the effect of arsenic, salicylates, <strong>and</strong> quinine on the organ of Corti of guinea pigs.<br />

J. Egypt. Med. Assoc. 58144-157. (Cited in U.S. EPA, 1984).<br />

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Health 15163-172<br />

Armstrong, C.W.; Stroube, RB.; Rubio, T.; Siudyla, EA; Miller, G.B. 198<strong>4.</strong> Outbreak of<br />

fatal arsenic poisoning caused by contaminated drinking water.<br />

39276-279.<br />

Arch. Environ. Health<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1989. Toxicological Profile<br />

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Atlanta, G k ATSDR/TP-8SK)2<br />

Axelson, 0.; Dahlgren, E; Jason, C.-D.; Rehnlund, S.O. 1978. Arsenic exposure <strong>and</strong><br />

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Baxley, M.N; Hood, RD.; Vedel, G.C; Harrison, W.P.; Szczech, G.M. 1981. Prenatal<br />

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26749-756.<br />

Beaudoin, AR. 197<strong>4.</strong> Teratogenicity of sodium arsenate in rats. Teratology 10153-158.<br />

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Bettley, F.R; O’Shea, J.A 1975. The absorption of arsenic <strong>and</strong> its relation to carcinoma.<br />

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in B6C3F1 mice, Fischer 344 rats, <strong>and</strong> Syrian golden hamsters: system organ studies <strong>and</strong><br />

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Blakely, B. R; Sisodia, C.S.; Mukkur, T.K. 1980. The effect of methylmercury, tetraethyl<br />

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Blom, S.; Lagerkvist, B.; Linderholm, H. 1985. Arsenic exposure to smelter workers: clinical<br />

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Burk D.; Beaudoin, AR 1977. Arsenate-induced renal agenesis in rats.<br />

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Teratology<br />

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of Carcinogenicity: an Updating of IARC Monographs <strong>Volume</strong>s 1 to 42 IARC Monographs<br />

on the Evaluation of Carcinogenic Risks to Humans, supplement 7. Geneva.<br />

Ishinishi, N.; Osato, K; Kodama, Y.; Kunitake, E 1976. Skin effects <strong>and</strong> carcinogenicity of<br />

arsenic trioxide: a prelinrinary experimental study in rats. In: Effects <strong>and</strong> Dose-Response<br />

Relationships of Toxic Metals, G.F. Nordberg, ed. Elscvier Scientific, Amsterdam. pp.<br />

471479.<br />

Ishinishi, N.; Yamamoto, A; Hisanaga, A: Inamasu, T. 1983. Tumorigenicity of arsenic<br />

trioxide to the lung in Syrian golden hamsters by intermittent instillations. Cancer Lett.<br />

21:141-147. (Cited in IARC, 1987).<br />

Ivankwic, S.; Eisenbr<strong>and</strong>, G.; Preussmann, R 1979. Lung carcinoma induction in BD rats<br />

after single intratracheal instillation of an arseniccontaining pesticide mixture formerly used<br />

in vineyards. Int. J. Cancer. 24786-788. (Cited in IARC 1980).<br />

Ji!rup, L; Pershagen, G.; Wall, S. 1989. Cumulative arsenic exposure <strong>and</strong> lung cancer in<br />

smelter workers: a dose-response study. Am. J. Ind. Med. 1531-42<br />

Katsnelson, BA; Nebstnova, Y.M.; Blokhin, V.A 1986. Stomach carcinogenesis induction<br />

by chronic treatment with arsenic (Russ.). Vopr. OnkoL 32-73. (Cited in IARC, 1987).<br />

Knoth, W. 1966-67. Arsenic treatment. Arch. Klin. Exp. Derm. 22722823<strong>4.</strong> (Cited in<br />

mc, 1980)<br />

22


TOXICITYSUMMARY FOR<br />

BARIUM<br />

DECEMBER 1W<br />

Prepared by<br />

A.A. Francis, M.S., D.A.B.T.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory<br />

Oak Ridge, Tennessee<br />

Repared for<br />

OAK RIDGE REsERvAnoN ENVIRONMENTAL<br />

REsLoRAnON PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc. for the U.S. Department of Energy<br />

under Contract No. DE-AC05-840R21400


This page intentionally lefi blank.


The soluble salts of barium, an alkaline earth metal, are toxic in mammalian systems. They<br />

are absorbed rapidly from the gastrointestinal tract <strong>and</strong> are deposited in the muscles, lung<br />

<strong>and</strong> bone. Barium is excreted primarily in the feces.<br />

At low doses, barium acts as a muscle stimulant <strong>and</strong> at higher doses affects the newus<br />

system eventually leading to paralysis. Acute <strong>and</strong> subchronic oral doses of barium cause<br />

vomiting <strong>and</strong> diarrhea, followed by decreased heart rate <strong>and</strong> elevated blood pressure. Higher<br />

doses result in cardiac irregularities, weakness, tremors, anxiety <strong>and</strong> dyspnea. A drop in serum<br />

potassium may account for some of the symptoms. Death can occur from cardiac <strong>and</strong><br />

respiratory failure. Acute doses around 0.8 grams can be fatal to humans.<br />

Subchronic <strong>and</strong> chronic oral or inhalation exposure primarily affects the cardiovascular<br />

system resulting in elevated blood pressure. A LOAEL of 0.51 mg bariudkglday based on<br />

increased blood pressure was observed in chronic oral rat studies (Perry et al., 1983), whereas<br />

human studies identified a NOAJX of 0.21 mg barium/kg/day (Wones et al., 1990; Brenniman<br />

<strong>and</strong> Levy, 1984). The human data were used by the EPA to calculate a chronic <strong>and</strong><br />

subchronic oral reference dose (RfD) of 0.07 mg/kg/day (U.S. EPA, 1991, 1992). In the<br />

Wones et aL study, human volunteers were given barium up to 10 mg/L in drinking water for<br />

10 weeks. No clinically significant effects were observed, An epidemiological study was<br />

conducted by Brenniman <strong>and</strong> Levy in which human populations ingesting 2 to 10 mg/L of<br />

barium in drinking water were compared to a population ingesting 0 to 0.2 m@L<br />

No<br />

significant individual differences were seen; however, a significantly higher mortality rate from<br />

all combined cardiovascular diseases was observed with the higher barium level in the 65+<br />

age group. The average barium concentration was 73 mg/L, which corresponds to a dose of<br />

0.20 mgkg/day. Confidence in the oral RfD is rated medium by the<br />

-<br />

EPA<br />

Subchronic <strong>and</strong> chronic inhalation exposure of human populations to bariumcontaining dust<br />

can result in a benign pneumoconiosis called ”baritosis”. This condition is often accompanied<br />

by an elevated blood pressure but does not result in a change in pulmonary function.<br />

Exposure to an air concentration of 5.2 mum3 for 4 hours/day for 6 months has been<br />

reported to result in elevated blood pressure <strong>and</strong> decreased body weight gain in rats<br />

(Tarasenko et al., 1977).<br />

Reproduction <strong>and</strong> developmental effects were also observed.<br />

Increased fetal mortality was seen after untreated females were mated with males treated with<br />

5.2 mg/m3 of barium. Similar results were obtained with female rats treated with 13.4 mg/m3.<br />

The NOAEL for developmental effects was 1.15 mg/m3. An inhalation reference concentration<br />

(RfC) of 0.005 mglm’ for subchronic <strong>and</strong> O.ooO5 m@m3 for chronic expure was calculated<br />

by the EPA based on the NOAEL for developmental effects (U.S. EP& 1992).<br />

These effects have not been substantiated in humans or other animal systems.<br />

Barium has not been evaluated by the U.S. EPA for evidence of human carcinogenic<br />

potential (U.S. EPA, 1991).<br />

1


1. INTRODUCI'XON<br />

Barium (CAS registry number 7440-39-3) is a divalent alkaline-earth metal found only in<br />

combination with other elements in nature. The most important of these combinations are<br />

the peroxide, chloride, sulfate, carbonate, nitrate, <strong>and</strong> chlorate. The pure metal oxidizes<br />

readily <strong>and</strong> reacts with water emitting hydrogen; it is chemically similar to calcium (Weast,<br />

R.C. 1987). The most likely source of barium in the atmosphere is from industrial emissions.<br />

Since it is usually present as a particulate form, it can be removed from the atmosphere by<br />

wet precipitation <strong>and</strong> deposition. Due to the element's tendency to form salts with limited<br />

solubility in soil <strong>and</strong> water, it is expected to have a residence time of hundreds of years <strong>and</strong><br />

is not expected to be very mobile. Acidic conditions, however, will increase the solubility of<br />

some barium compounds facilitating their movement from the soil to the groundwater (U.S.<br />

EA, 1984). Trace amounts of barium were found in over 99% of the surface waters <strong>and</strong><br />

finished drinking water samples (average values of43 pg/L, <strong>and</strong> 286 pgL, respectiveb) across<br />

the United States (National Academy of Sciences, 1977).<br />

2 MEI'ABOLISMANDDIspomnoN<br />

21. Aborption<br />

The soluble forms of barium salts are rapidly absorbed into the blood from the intestinal<br />

tract. The rates of absorption of a number of barium salts have been measured in rats<br />

following oral exposure to small quantities (30 m a body weight). The relative absorption<br />

rates were found to be. barium chloride > barium sulfate > barium carbonate. Large doses<br />

of barium sulfate do not increase the uptake of this salt because of its low solubility<br />

(McCauley <strong>and</strong> Washington, 1983; U.S. EPA, 1984).<br />

Systemic toxic effects have been observed following both oral <strong>and</strong> inhalation exposure. No<br />

absorption kinetics are available following inhalation exposure, although it is obvious that<br />

absorption does occur (US. EPA, 1984).<br />

Barium absorbed into the bloodstream disappears in about 24 hours, however, it is deposited<br />

in the muscles, lungs <strong>and</strong> bone. Very little is stored in the kidneys, k r , spleen, brain, heart<br />

or hair. It remains in.the muscles about 30 hours after which the concentration decreases<br />

slowly. The deposition of barium into bone is similar to calcium but occurs at a faster rate<br />

(Stokinger, 1981). "he half life of barium in bone is estimated to be about 50 days (Machata,<br />

1988).<br />

3. Metabolism<br />

About 54% of the barium dose is protein bound. Barium is known to activate the secretion<br />

of catecholamines from the adrenal medulla without prior calcium deprivation. It may<br />

displace calcium from the cell membranes, thereby increasing permeability <strong>and</strong> p'ovidhg<br />

2


stimulation to muscles. Eventual paralysis of the central nervous system can occur (Stokinger,<br />

1981).<br />

A tracer study in rats utilizing ''%a demonstrated that 7% <strong>and</strong> 20% of the barium dose was<br />

excreted in 24 hours in the urine <strong>and</strong> feces respectively. In contrast, calcium is primarily<br />

excreted in the urine. The clearance of barium is enhanced with saline infusion. (Stokinger,<br />

1981).<br />

3. NONCARCINOGENIC HEALTH EFFECIS<br />

3.1. Oral Expuns<br />

3.1.1. Acute T-<br />

3.1.1.1. Human<br />

A number of accidental barium poisonings have OCCUK& following the ingestion of barium<br />

salts. The estimated fatal dose of barium carbonate, a rodenticide, is about 5 grams for a 70<br />

kg human (Arena, 1979). The LDS for barium chloride is estimated at about 1 gram for a<br />

70 kg human (Machata, l-), <strong>and</strong> the LD, (lowest published lethal dose) is reported to be<br />

about 0.8 grams (Lewis <strong>and</strong> Sweet, 1984). The acute symptoms include: excess salivation,<br />

vomiting, diarrhea, increased blood pressure, muscular tremors, weakness, paresis, anxiety,<br />

dyspnea, <strong>and</strong> cardiac irregularities. A severe loss of potassium can account for some of the<br />

symptoms. Convulsions <strong>and</strong> death from cardiac <strong>and</strong> respiratory failure can occur. Magnesium<br />

<strong>and</strong> sodium sulfate are antidotal if taken soon after ingestion since either salt will result in<br />

the formation of insoluble barium sulfate <strong>and</strong> prevent further absorption. Survival for more<br />

than 24 hours is usually followed by complete recovery (Arena, 1979).<br />

3.1.12. Animal<br />

Similar acute symptoms occur in animals, however higher daws are usually involved. The<br />

LDu, for rats is listed as 630 mgkg for barium carbonate; 118 mgkg for barium chloride, <strong>and</strong><br />

921 mgkg for barium acetate (Lewis <strong>and</strong> Sweet, 1984).<br />

3.12 SubchronicToxicity<br />

3.121. Human<br />

An experiment testing the subchronic toxicity of barium chloride on human volunteers was<br />

conducted by Wones et aL (1990). The diets of 11 male subjects were controlled. They wcrc<br />

given 15 Uday of distilled <strong>and</strong> charcoal-filtered drinking water that contained 0 mg/I barium<br />

for weeks 1 <strong>and</strong> 2,5 mg/L for weeks 3 to 6, <strong>and</strong> 10 mg/L for weeks 7 to 10. NO clinically<br />

significant effects were observed in blood pressures, serum chemistry, urhalysk. or<br />

electrocardiograms. The 10 mg/L (021 mgkg/day) dose was identified as a NOAEL<br />

3


3.122 Animal<br />

Groups of 30 male <strong>and</strong> 30 female Charles River rats were exposed to barium chloride at 0,<br />

10, 50 or 250 ppm in drinking water for 90 days (Tardiff et al., 1980). The highest average<br />

dose in this study was calculated to be 45.7 mg/kg/day for female rats. No significant clinical<br />

signs of toxicity were observed. Blood pressure was not measured.<br />

McCauley et aL (1%) conducted drinking water studies in which six male Sprague-Dawley<br />

rats/group were given water containing 0, 10,100 or 250 mg/L barium for 36 weeb, or 1.10,<br />

100 or lo00 mg/L barium for 16 weeks. Female rats were given 0 or 250 mg/L for 46 weeb.<br />

Animals receiving the lo00 mg/L dose developed ultrastructural changes in the kidney<br />

glomeruli. No other effects were reported.<br />

Tardiff et aL (1980) exposed groups of 30 male <strong>and</strong> 30 female Charles River rats to 0, 10,<br />

SO, or 250 ppm barium (given as barium chloride) in drinking water for 90 days. A slight<br />

reduction in adrenal weights was seen in female rats with the 250 pprn (45.7 mg/kg/day) dose<br />

at 13 weeks <strong>and</strong> in male rats with the 50 ppm (8.1 mg/kg/day) <strong>and</strong> the 250 ppm (38.1<br />

mg/kg/day) doses at 8 weeb, no other adverse effects were observed. No clear dose effect<br />

or dose duration effect was seen with the adrenal weight decrease: therefore, the clinical<br />

significance is uncertain.<br />

3.13. CbOnicTadeity<br />

3.13.1. Human<br />

An epidemiology study conducted by Brenniman <strong>and</strong> Levy (1984) compared a human<br />

population ingesting barium levcis of 2 to 10 mg/L in their drinking water to a population<br />

ingesting 0 to 0.2 mg/L Although significantly higher mortality rates from all cardiovascular<br />

diseases were observed with the higher barium level in the 65 <strong>and</strong> over age group, there were<br />

no significant individual differences in blood pressures, strokes, or heart <strong>and</strong> renal diseases<br />

within the two groups. The average barium concentration for the mortality study was 7.3<br />

mg/L, which corresponds to a dose of 0.20 mg/kg/day assuming drinking water consumption<br />

of 2 Uday for a 70 kg human.<br />

3.132 Animal<br />

A series of experiments were performed in which groups of 52 male <strong>and</strong> female Long-Evans<br />

rats <strong>and</strong> 42 male <strong>and</strong> female Swiss mice were exposed to 5 mg barium/L (given as barium<br />

acetate) in drinking water for their lifetime (Schroeder <strong>and</strong> Mitchener, 1975a,b). The barium<br />

doses were about 023 <strong>and</strong> 0.825 mg/kg/day for rats <strong>and</strong> mice, respectively. No adverse clinical<br />

effects were observed, however, blood pressure was not measured. There was a slight but<br />

significant reduction in longevity of treated male mice when measured as the mean age at<br />

death of the last surviving 10% of animals. The overall average life span of the group,<br />

however, was about the same as the control group (U.S. EPA 1984, US. EPA, 1989)<br />

Perry et at (1983) exposed 12-13 female weanling rats/pup to 0,1,10 or 100 pprn barium<br />

(given as barium chloride) for up to 16 months. Average doses were calculated to be 0,0.051,<br />

051 <strong>and</strong> 5.1 mg/kg/day (US. EPA, 1985). A clinically significant increase in average blood<br />

4


pressure was observed in the highest dose group; a slight but statistically significant increase<br />

was seen in the 10 ppm (0.51 mgAcg/day) dose group. The controlled diet, which restricted<br />

the intake of trace metals, calcium <strong>and</strong> potassium, may have contributed to the effect.<br />

3.1.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Taxicity<br />

information on developmental <strong>and</strong> reproductive toxicity in humans or animals following oral<br />

exposure was unavailable.<br />

3.15. Dcse<br />

3.15.1. Subchronic<br />

ORAL RfD,:<br />

0.07 mg/kg/day (U.S. EPA, 1992)<br />

UNCERTAINTYFACI'OR 3<br />

NOAEL:<br />

021 mgkg/&y<br />

PRINCIPAL STUDIES:<br />

The same studies <strong>and</strong> comments apply to both the subchronic <strong>and</strong> chronic RfD derivations.<br />

See <strong>Section</strong> 3.152<br />

3.152 cbonic<br />

ORAL IUD;<br />

0.07 mgAcg/day (U.S. EPA, 1991)<br />

UNCERTAINTYFACI'OR 3<br />

MODIFYINGFAOR 1<br />

NOAEL:<br />

021 mgkg/day<br />

CONFIDENCE:<br />

Study:<br />

Medium<br />

Data Base<br />

Medium<br />

RfD:<br />

Medium<br />

VERIFICATION DATE: 06/21/90<br />

PRINCIPAL STUDIES. Wones et aL (1990); Brenniman <strong>and</strong> Levy (1984).<br />

coMMEN?s: The RED values are based on a weight-ofevidence approach ushg<br />

subchronic to chronic human drinking water studies. Tbe uncertainty factor<br />

accounts for protecting sensitive individuals <strong>and</strong> is reduced from the usual factor<br />

of 10 because the selected studies examined the population judged most at risk.<br />

321. AcuteToxicity<br />

Barium carbonate dust has been reported to be a bronchial irritant. Barium oxide dust is<br />

considered a dermal <strong>and</strong> nasal irritant (Stokinger, 1981).<br />

.<br />

5


3.2.2 SubchronicToxicity<br />

3.2.21. Human<br />

Industrial workers exposed to barium dust., usually in the form of barium sulfate or<br />

carbonate, often develop a benign pneumoconiosis referred to as ”baritosis”. Because of the<br />

radiopacity of barium compounds, this condition can be specifically diagnosed radiologically.<br />

After removal from the sources of exposure, baritosis is reversible in most cases. Baritosis<br />

results in a significantly higher incidence of hypertension, but no changes are usually seen in<br />

pulmonary function (Stokinger, 1981; U.S. EPA, 1991).<br />

Male rats were exposed to 1.15 <strong>and</strong> 5.2 mghn’ of barium carbonate dust for 4 houdday for<br />

6 montbs. The high dose animals developed increased arterial pressure; decreased body<br />

weight gain; decreased blood levels of hemoglobin, sugar, protein, cholinesterase <strong>and</strong><br />

thrombocytts; increased blood levels of leukocytes, phosphorous <strong>and</strong> alkaline phosphatase;<br />

increased urine calcium; <strong>and</strong> perivascular <strong>and</strong> peribronchial sclerosis in the lungs. (U.S. EPA,<br />

1984; Tanqenko et aL, 1977).<br />

323. ChronicToxicity<br />

323.1. Human<br />

Baritah also occurs in workers chronically exposed to barium containing dust. Hypertension<br />

is the only reported adverse clinical effect (US. EPA, 1991).<br />

Information on the chronic inhalation toxicity of barium in animals was unavailable.<br />

3.2<strong>4.</strong> -tal <strong>and</strong> Reproductive Toxicity<br />

Tarasenko et al. (1977) performed a series of experiments designed to test for possible<br />

reproductive <strong>and</strong> developmental effects. Increased fetal mortality was observed following the<br />

mating of males exposed to barium carbonate (52 mg/m3 air) with untreated females.<br />

Decreased sperm motility was observed in males treated with 226 mg/m’ the mating of<br />

females exposed to 13.4 mg/m3 for 4 months also resulted in inmasad fetal mortality <strong>and</strong> a<br />

general underdewelopment of the newborn pups. Ovarian follicle atresia was seen in female<br />

rats exposed to 3.1 mg/m3. There were no significant adverse effects with the 1.15 mg/m3<br />

concentration (U.S. EPA, 1984).<br />

33.1. Subchroaic<br />

INHALATION RfC,: 0.005 mg/m3; 0.001 mg/kg/day (US. EPA, 1992)<br />

UNCERTAINTYFACTOR 100<br />

6


NOAEL:<br />

PRINCIPAL STUDY<br />

1.15 mg BaCOJm3 given 4 hdday (U.S. EPA, 1992)<br />

The same study <strong>and</strong> comments apply to the subchronic<br />

<strong>and</strong> chronic RfC. The study is described in section<br />

32<strong>4.</strong><br />

3-32<br />

cbmnic<br />

INHALATION RfC,: 0.0005 mg/m3; O.OOO1 mg/kg/day; (U.S. EPA, 1992)<br />

UNCERTAINTY FACTOR. loo0<br />

NOAEk<br />

1.15 mg BaCOJm’ @en 4 hdday (U.S. EPA, 1992)<br />

PRINCIPAL STUDY Tarasenko et aL, 1977.<br />

COMMENTS: The 1.15 mg/m3 dose was a NOAEL,, however the 5.2 mum3 dose,<br />

which resulted in developmental effects, was used as the basis €or the RfC<br />

calculations.<br />

33.<br />

33.1.<br />

33.1.1.<br />

other Routes of Expure<br />

hte Toxicity<br />

HUman<br />

Barium oxide dust is considered to be a dermal <strong>and</strong> nasal irritant (Stokinger, 1981).<br />

33.12<br />

Animal<br />

A number of experiments have utilized intravenous <strong>and</strong> subcutaneous injections to measure<br />

lethal levels of soluble barium compounds. LD, values €or barium chloride, nitrate <strong>and</strong><br />

acetate were determined in two strains of mice by intravenous injection (Syed <strong>and</strong> Hosain,<br />

1972). The affected animals either died within one hour or survived the treatment. The LD,<br />

values obtained were: 8.128.49 <strong>and</strong> 1132 mg bariumkg for the chloride, nitrate <strong>and</strong> acetate,<br />

respectively, in Swiss-Webster mice; 19.20, 20.10 <strong>and</strong> 2331 mg barium/kg for the chloride,<br />

nitrate <strong>and</strong> acetate, respectively, in ICR mice. Although the relative toxicity of the barium<br />

salts remained the same, there was an unexplained two-fold difference in the LD, values<br />

between the two mice strains.<br />

Tbe LD, has been determined by subcutaneous injection in mice to be 10 mgkg €or the<br />

barium nitrate <strong>and</strong> chloride salts. The LDb in rabbits was 55 mgkg €or the chloride <strong>and</strong> 96<br />

mg/kg for the acetate salts. The LDb values vary widely with the route <strong>and</strong> test animal. For<br />

example, with barium chloride the LDb value €or oral administration to rabbits is 170 mgkg,<br />

whereas the value for subcutaneous injection is 55 mgkg. Subcutaneous injection in mice<br />

results in a value of 10 mgkg, which is higher than the LD, value for intravenous injection<br />

in the Swiss-Webster strain (Lewis <strong>and</strong> Sweet, 1984).<br />

332 subchronicTaxicity<br />

Information on the subchronic toxicity in humans <strong>and</strong> animals is unavailable.<br />

7


333. CbrOnicToxkity<br />

Information on the chronic toxicity in humans <strong>and</strong> animals is unavailable.<br />

33.<strong>4.</strong> Dmhpmental <strong>and</strong> Reproductive Toxicity<br />

Information on the developmental <strong>and</strong> reproductive toxicity in humans <strong>and</strong> animals is<br />

unavailable.<br />

3.<strong>4.</strong><br />

3.<strong>4.</strong>1.<br />

3.<strong>4.</strong>1.1.<br />

Target-tiCalEEeCtS<br />

-m-K==<br />

mTa%w)<br />

1. Cardiovascular system: Subchronic to chronic symptoms include increased blood<br />

pressure <strong>and</strong> increased incidence of cardiovascular disease in humans. An acute<br />

overdose can result in cardiac irregularities. Convulsions <strong>and</strong> death from cardiac<br />

<strong>and</strong> respiratory failure can occur.<br />

2 Nervous system: Acute to subchronic symptoms include weakness, tremors,<br />

anxiety, <strong>and</strong> dyspnea. An acute overdose can result in convulsions <strong>and</strong> death from<br />

cardiac <strong>and</strong> respiratory failure.<br />

3.<strong>4.</strong>12<br />

-Targc&<br />

1. Gastrointestinal system: Acute to subchronic symptoms include excess salivation,<br />

vomiting <strong>and</strong> diarrhea in humans.<br />

3.42<br />

3.421.<br />

-ET==<br />

primaryT=Sw<br />

1. Cardiovascular system: Symptoms inciude increased blood pressure in humans.<br />

2 Reproduction <strong>and</strong> development: Subchronic exposure of rats resulted in<br />

decreased sperm motility <strong>and</strong> ovarian follicle atresia. Increased fetal mortality <strong>and</strong><br />

underdevelopment of newborn pups were also reported.<br />

3.4a<br />

-TargCt(r)<br />

1. Lungs: Subchronic to chronic exposure in humans results in a pneumoconiosis<br />

known as "baritosis" that usually does not adversely affect pulmonary function.<br />

8


<strong>4.</strong>1.<br />

<strong>4.</strong>1.1. Human<br />

Information on the carcinogenicity of barium in humans is unavailable.<br />

4-12 Animal<br />

No significant differences in tumor incidence were found in either rats or mice in the<br />

lifetime exposure experiments of Schroeder <strong>and</strong> Mitchener (1975a,b), described in <strong>Section</strong><br />

3.13.2.<br />

Information on the carcinogenicity of barium in humans <strong>and</strong> animals is unavailable.<br />

Information on the Carcinogenicity of barium in humans <strong>and</strong> animals is unavailable.<br />

<strong>4.</strong><strong>4.</strong> EPA W&htd-EvidcDoc<br />

Barium has not been evaluated by the US. EPA for evidence of human carcinogenic<br />

potential (U.S. EPA, 1991).<br />

Data are insufficient to calculate a slope factor for barium.<br />

9


Arena, J.M.<br />

Publisher, Springfield, Ill. pp. 173-179.<br />

5. REFERENCES<br />

1W9. Poisoning - Toximlogy - Symptoms - Treatments. Charles C. Thomas,<br />

Brenniman, G.R <strong>and</strong> P.S. Levy. 198<strong>4.</strong> High barium levels in public drinking water <strong>and</strong> its<br />

association with elevated blood pressure.<br />

Calabrese, Ed. Princeton Scientific Publications, Princeton NJ. pp. 231-249.<br />

In: Advances in Modem Toxicology IX, EJ.<br />

Lewis, RJ. <strong>and</strong> D.V. Sweet, eds. 198<strong>4.</strong> Registry of Toxic Effects of Chemical Substances,<br />

Vol. 1. US. Department of Health <strong>and</strong> Human Senrices, Public Health Service, Centers for<br />

Dkase Control, Nationai Institute for Occupational Safety <strong>and</strong> Health, Cincinnati, OH.<br />

Machata, G. 1988. Barium. In H<strong>and</strong>book on Toxicity of Inorganic Compounds, eds. H.G.<br />

Seiler <strong>and</strong> H. Sigel, Marcel Dekker, Inc. pp. 97-101.<br />

McCauley, P.T. <strong>and</strong> LS. Washington. 1983. Barium bioavailability as the chloride, sulfate or<br />

carbonate salt in the rat. Drug Chem. Toxicol. 6(2): 209-217.<br />

McCauley, P.T., B.H. Douglas, RD. Laurie <strong>and</strong> RJ. BuU 1985. Investigations into the<br />

effect of drinking water barium on rats. Environ. Health Perspect. Vol. IX, EJ. Calabrese,<br />

Ed. Princeton Scientific Publications, Princeton, NJ. pp.197-210.<br />

Perry, H.M., SJ. Kopp, M.W. Erlanger <strong>and</strong> EF. Perry. 1983. Cardiovascular effects of<br />

chronic barium ingestion. In: Trace Substances in Environmental Health, ?MI, D.D.<br />

Hempha Ed. Proc. Univ. Missouri’s 17th Ann. Conf. on Trace Substances in Environmental<br />

Health. University of Missouri Press, Columbia, MO. pp. 155-16<strong>4.</strong><br />

Scluoeder, H. <strong>and</strong> M. Mitchener. 197%. Life-term studies in rats: Effects of aluminum,<br />

barium, beryllium <strong>and</strong> tungsten. J. Nutr. 105: 421-427.<br />

Schroeder, H. <strong>and</strong> M. Mitchener. 197%. Life-term effects of mercury, methyl mercury <strong>and</strong><br />

nine other trace metals on mice. J. Nutr. 105: 452-458<br />

Stokinger, H.E 1981. The Metals. In Patty’s Industrial Hygiene <strong>and</strong> Toxicology, Vol2A, eds.<br />

G.D. Clayton <strong>and</strong> EE Clayton, John Wiley & Sons, New Yort pp. 1531-1537.<br />

Syed, I.B. <strong>and</strong> F.Hosain. 1972 Determination of ID50 of Barium Chloride <strong>and</strong> Allied<br />

Agents. Toxicol. AppL Pharm. U: 150.152<br />

Tarasenko, M, 0. Promin <strong>and</strong> A Silayev. 1977. Barium compounds as industrial poisons (an<br />

experimental study). J. Hyg. Epidem. Microbiol. Immunol. 21: 361-373.<br />

Tardiff, RG., M. Robinson <strong>and</strong> N.S. Ulmer. 1980. Subchronic oral toxicity of barium<br />

chloride in rats. J. Environ. PathoL Toxic01 4(5-6): 267-276.<br />

10


U.S.EPA 198<strong>4.</strong> Health Effects Assessment for Barium. Prepared by the Office of Health<br />

<strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> M ment Ofice, Cincinnati,<br />

OH for the Office of Emergency <strong>and</strong> Remedial Response, Washington, D.C.<br />

U.S.EPA 1985. Drinking Water Health Effects Criteria Document on Barium. Prepared<br />

by the Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria And<br />

Assessment Office,Cincinnati, OH for the Office of Drinking Water, Washington, DC. NTIS<br />

PB &118031.<br />

U.S.EPA 1989. Reportable Quantity Document for Barium <strong>and</strong> Compounds. Prepared by<br />

the Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment<br />

Office,Cincinnati, OH for the Office of Solid Waste <strong>and</strong> Emergency Response, Washington,<br />

Dc<br />

US. EPA 1991. Integrated Risk Information System (IRIS). Health Risk Assessment for<br />

Barium. On line. (Verification date 6/21/90.) Office of Health <strong>and</strong> Environmental Assessment,<br />

Environmental Criteria <strong>and</strong> Assessment Office,Cincinnati, OH.<br />

U.S.EPA 1992. Health Effects Assessment Summary Tables. Annual FY-92 Prepared by<br />

the Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment<br />

Office, Cincinnati, OH for the Office of Emergency <strong>and</strong> Remedial Response, Washington<br />

DC. OHEA ECAO-cIN-821.<br />

US. National Academy of Sciences. 1977. Drinking Water <strong>and</strong> Health. Safe Drinking<br />

Water Committee, Advisory Center on Toxicology, Assembly of Life Sciences, National<br />

Research Council. Washington, D.C. pp 211-212<br />

Weast, RC, J.A Melvin <strong>and</strong> W.H. Beyer (4). 1987. CRC H<strong>and</strong>book of Chemistry <strong>and</strong><br />

Physics. CRC Press, Inc, Boca Raton, Florida, pp B-9.<br />

Wones, RG., B.L Stadler <strong>and</strong> L.A. Frohman. 1990. Lack of effect of drinking water barium<br />

on cardiovascular risk factor. Environ. Health Perspect. 85: 1-13.<br />

11


September 1992<br />

Prepared By<br />

Andrew Francis<br />

Chemical Hazard Evaluation Group<br />

Biomedical Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Restarch Division<br />

Oak Ridge National Laboratmy*<br />

Oak Ridge, Tern-<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVm0-a<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems. Inc, for the US. m a t<br />

Contract No. DE-Aa)5840R21400<br />

of &q


Thfr page mtcntionally lefi blank<br />

2


Benz[aanthracenc, along with a number of other polycyclic aromatic hydrocarbons, arc<br />

natural products produced by the incomplete combustion of organic materiai. The arrangement<br />

of the aromatic rings in the benz[gJanthracenc molecule gives it a "bay region" often correlated<br />

with carcinogenic properties. In general, the bay-region polycyclic aromatic hydrocarbons <strong>and</strong><br />

some of their metabolites arc bmam to react with ceiiular macromolecules, including DNA, which<br />

may account for both their toxicity <strong>and</strong> carcinogenicity. The inducible mixed-function oxidase<br />

enzymes oxidiz benz(@&acme<br />

to form metabolites with increased water solubility that can be<br />

efficiently excreted in the urine. A minor product of this axidation, a bay-region diol epoxide,<br />

reacts readily With DNA <strong>and</strong> has been shown to be highly cardnogenic (us. EA, 1980, 1984;<br />

Jerina, et aL, 1977).<br />

The toxic efftcts of benz(glanthracene <strong>and</strong> simiiar potycyClic aromatic hydrocarbons arc<br />

primarily directed toward tissues that contain proliferating cells. Animal studies indicate that<br />

exposure to bay-region polycyclic aromatic hydrombons can damage the hematopoietic system<br />

leading to progressive anemia as well as agranulocytosis (Robinson, et aL, 1975; Cawein <strong>and</strong><br />

Sydnor, 1968). The lymphoid system can also be affected resulting in lymphopenia. Toxic effects<br />

have been OM in the rapidly dividing cells of the intestinal epithelium, spermatogonia <strong>and</strong><br />

resting spermatocytes in the testis <strong>and</strong> primary ooc$e of the ovary (Philips et al, 1973;<br />

Mackinzic <strong>and</strong> Angevine, 1981; Kraup, 1970; Ford <strong>and</strong> Huggins, 1963; Mattison <strong>and</strong> ThorgeirsJon,<br />

19n, US. EPA, 19&0* 1984). Most of these effects have occuffcd following both oral <strong>and</strong><br />

parcntcral exposure. Epithelial proliferation <strong>and</strong> cell hyperplasia in the respiratory tract have<br />

bew reported following subchronic inhalation exposure (RemikSchuller <strong>and</strong> Moht, 1974;<br />

Saffiotti et & 1968). However, because of the lack of quantitative data, neither a reference dose<br />

nor 8 reference concentration have been derived (VS E9k 191).<br />

The primary conccrii with beaanthraccne exposure is its potential carcinogenicity. There<br />

is no unequivocal dircct evidence of the carcinogenicity of the compound to humans, however,<br />

bem&Janthraccne <strong>and</strong> other known carcinogenic polycyclic aromatic hydmaubons arc<br />

components of cod tar, soot, coke oven emissions <strong>and</strong> tobacco smoke. There is adequate<br />

evidence of its carcinogenic properties in animais. Oral exposures of mice to benz[aanthraccne<br />

have resulted in hepatomas, pulmonary adenomas <strong>and</strong> forestomach papillomas (Klein, 1%3; Bock<br />

<strong>and</strong> King, 1959; US. EPA, 1991). The EPA ueight-ofcvidenct classification is: B2, probable<br />

human Carcinogen, for both oral <strong>and</strong> inhalation cxposure based on adequate animal evidence <strong>and</strong><br />

no human evidence (US. EPA, 1991). A slope factor has not been derived specifically for<br />

benz(&Janthracme by the EPA (US. EPA, 1991). Howlcvtr, an oral slope factor of 73<br />

(mg/kg/dayr' has becn calculated for benzDwpyrcne based on the incidence of stomach tumors in<br />

mice treated with bcnzo(&yrcne (Neal <strong>and</strong> Rigdon, 1967; US. EPA, l-, 19&$1992a). A<br />

drinking water unit risk of 21E-4 (pg/Lrl has also been calculated for bep;oo(&yene (US. EPA,<br />

1992a). An inhalation slope factor oE 6.1 (mg/kg/day)" (US. EPA, 1992b) was calculated for<br />

benu>[@yrene based on the incidence of respiratory tumors in golden hamsters treated with<br />

benzo a pyrene crriyssen et aL, 1981; US. EPA, 1980; 1984). An inhalation unit risk of 1.E-3<br />

(p@'$ has also been calculated for benm~pyrcne (US. EPA, 1992b).


1. KNTRODUCXION<br />

--<br />

Bcnz[aanthraccne (CAS registry number 56-55-3) is a poiycycfic aromatic hydrocarbon<br />

containing four aromatic rings two of which share carbons with only one other ring. It is soluble in<br />

alcohol, ether <strong>and</strong> benzene but practically insoluble in water (9.4 pgh @ 25°C) (us. =A, 1984;<br />

Weast, 1987). There is no commercial application for be@@mthraccne, however, it is a ubiquitous<br />

contaminant formed during the incomplete combustion of organic material. kaz(Jantbraccne.iS -<br />

found in various kinds of smoke <strong>and</strong> flue gases, tobacco smoke, tobacco smokc condcnsatc,<br />

automobile exhaust, roasted coffee <strong>and</strong> in charcoal broiled, barbccutd or smoked meats. It is ako<br />

found in creosote, coal tar, petroleum asphalt, <strong>and</strong> a variety of foob, bduding vcgetablc oils <strong>and</strong>.<br />

baker's ycas~ It is an atmospheric con taminnnt near pomr plants <strong>and</strong> busy highways, <strong>and</strong> tends to<br />

bind to particulate matter in the atmosphere. The p- removal mcchaojsm from the atmosphae<br />

is thought to be ozonolysis reactions, where the arpected half-life is less than 1 day to scvcral weeks<br />

dependent on the nature of the particuiatc matter to which it is adsorbed. Benz[ganthtaceac is also<br />

adsorbed to soil particulates where it undergoes degradation by microor@ms. It can persist in the<br />

soil from days to yean depending on the adsorbent <strong>and</strong> the mlcrootganisms prcscrJt 'Ihe water<br />

insolubility of benz[aanthraccnc limits its movement through the soil (Sittig, 1985; Sax, 1981; US.<br />

EPA 1984).<br />

2l. ABSORFITON<br />

Animal studies have shown that polycyclic aromatic hydrocarbons in genCrai <strong>and</strong><br />

bcx@&uithraccnt in particular are absorbed from the gastrointestinal tract (Ree~ et & 1971)<br />

Specifsc inhalation studies on b@&nthraccne were not available, but poiyammatic hydrocartKrmr<br />

as a class are cotlsidcred capable of crossing epithelial membranes. Studies with benzoMpyrcne ad<br />

pyrcne have shown rapid pulmonary absorption by rats (Kotin et aL, 19&9; Vainio et aL,.l976<br />

Mitchell <strong>and</strong> Tu, 1979). Quantitative data on bcnzjdanthraccne absorption arc not available for<br />

either the oral or inhaiation routes.<br />

Specific studies on the dutriiution of bez@danthracene in humans were not available.<br />

Howcvcr, animaI studies using related porycvclic aromatic h#mcarbons, chiefly beazo[alm--<br />

indicate that these compounds arc distriiuted in a wide variety of body tissues, cventuaIly becamiDg<br />

localized primarily in fatty tissues. Appmxhatdy 80 to 90% of the adminijtered b enzom<br />

disappeared from the blood within 6 minutes following 8 single intravenous 10 pg injection. A m@ -<br />

equiliiriumwasrcachcdbctwecnthebioud<strong>and</strong>liver. Tliehalftime€orbamj;lllpyrcnerundfromthe<br />

liver was about 10 minutcs; huwmer, the disappearance was bip&sic with a rapid initial p b -<br />

followed by a slower phase lasting 6 hours or longer. Removal from thc brain was slower than hrom<br />

the liver with bcnzo~pyrenconcentration increasing in fat tissucS for over 6 hours (schlede, et<br />

1970a). The disappearance of bcnzo[&yrcne fr~m aU tissues is acetltrattd by pretreatment with<br />

benzo[&yrcne ?his pretreatment indm microsod enzyme activities that arc h h d h the


oxidation <strong>and</strong> detoxification of polycyclic aromatic hydrocarbons (Schlede, et aL, 1970b; US. EPA,<br />

--<br />

1980).<br />

The arrangement of the aromatic rings in the molecule creates what has been termed a "bay<br />

region" imparting certain properties to the polycyciic aromatic hydrocarbons. Benz[aanthracene <strong>and</strong><br />

other bay-region polycyciic aromatic hydroahom undergo oxidation by microsomal enzymes<br />

(cytochrome f-450 miroed-function oxidase system) to excretabie metabolites. Unfortunately, some<br />

intermediary metabolites, chiefly the bay-region diol epoxides, can reaay react with DNA <strong>and</strong> ptiy<br />

increase carcinogenic activity. The bcnz[aJanthracene 3,4diolepoxide is a very minor metabolite of<br />

benz[danthracene oxidation, which may account for its weak tumorigenic properties when compared<br />

to some other bay region polycyciic aromatic hydrocarbons (m et aL, 1984, Jerina, et at, 1977).<br />

24 EXCREI'ION<br />

The oxidized products produced by the cytochrome P-450 mixed-function oxidase systcm exhibit<br />

increased reactivity <strong>and</strong> wig undergo conjugation With intracellular mOlecuies such as glutathione<br />

resulting in compounds that have inrrtased solubility in water <strong>and</strong> can be cxcretcd efficiently in the<br />

urine. Less soluble metabolites <strong>and</strong> the parent compound can be excreted through the hepatobiliary<br />

system in the feces. prior exposure to a polyqdic aromatic hydrocarbon results in the induction of<br />

the mixed-function oxidase enzymes <strong>and</strong> greatly in- the rate of excretion by increasing the<br />

formation of water soluble metabolites (US. EPA, 1980).<br />

3.1. ORAL-<br />

3.1.1.1. Human<br />

Direct evidence of acute toxicity resulting from oral expure of humans to bcwmthracene -<br />

is unavailable.<br />

Specific studies on the acute oral toxicity of benzfalanthracene in animah were not available,.<br />

howtver, several effects arc common to the.poiycyclic aromatic hydrocahn class of compounck.<br />

Genedy thcse compounds <strong>and</strong> their metabolites are moJt toxic to targets that contain rapidly<br />

proliferating cck They arc known to bind to proteins <strong>and</strong> nucleic acids <strong>and</strong> may interfere with the.<br />

processes involved in ccll growth <strong>and</strong> division (US. EPA, 1980). The hematopoietic <strong>and</strong> lymphoid -<br />

system arc common targets, as well as the intestinal cpitheiium <strong>and</strong> the testis.<br />

shgle feedings of 112 or 133 mg dimethyl be@danthraccnentg body weight of female rats.<br />

re~dted in severe depression of hematopoietic <strong>and</strong> lymphoid precursors. Since only the more rapidly


proliferating cells wcfc affccttd by benzwanthracenc, the authors suggested inhibition of DNA<br />

replication was involved in the toxicologic response (Cawin <strong>and</strong> Sydnor, 1%8, US. EPA, 1980). In<br />

another experiment, female rats given 300 mg dimethyl benzfdanthracenekg by gavage displayed<br />

injury to the intestinal epithelium <strong>and</strong> developed a progressive anemia. Mortality of rats was about<br />

65% at this dose (Philip et aL, 1973).<br />

3.12 Subcl~~nicTdaicity<br />

No relevant reports of human subchronic oral exposure to benz[aanthracene weft available.<br />

Specific data on the toaic effects of subchronic exposure of animals to benzjdanthracene were --<br />

not available. Experiments with other polycyclic aromatic hydrocarbons indicate that subchronic <strong>and</strong><br />

acute exposures result in similar effects. Oml exposure of mice to 120 mg benm[&yrcne/kg body<br />

weight/day for 6 months resulted in sevccc aplastic anemia. The inducibility of the microsomal mkifunction<br />

oxidase enzymes was shown to influence survival Poorly inducible mice (AKWN mice,<br />

Ahd/Ahd type) died within 4 weeks. whereas the inducrile mice survivcd for the 6 month period. This<br />

acpCriment demonstrate the detox,&ation of a polycyciic aromatic hydrocarbon by the mixed- .<br />

function oxidase system (Robinson et aL, 1975; US. EPA 1984).<br />

3.l3.1.<br />

Human<br />

No r eht<br />

3.132 Animal<br />

reports of human chronic oral exposure to bc@&mthraccne were available.<br />

-.<br />

Chronic experiments designed to demonstrate the carcinogenic nature of polycyclic aromatic<br />

hydrocarbons were inadequate to determine noncarcinogenic effects (U.S. EPA 1984).<br />

3.L<strong>4.</strong>L Hualall<br />

Studies dcscrr'bing developmental <strong>and</strong> reproductive effects in humans following oral exposure to<br />

-anthracene were not available.<br />

Specifid data on dcveiopmental <strong>and</strong> reproductive toxicity resuiting from exposure of animah to<br />

~anthra#newercunavailable. H~,studiesusingsimilarpo~caromatic hydrocarbonr<br />

indicate that exposure to theseannpouads muyresultin rcproductiveefkts. Rigdon <strong>and</strong> R<strong>and</strong>s<br />

(1964) fed frrnalr rats SO mg beruxr~pyrcnc/kg/day for 35, months induding the gestation period<br />

IncrtaJed feral mortality was reen in all 7 trcated females. The treated dams did not show gn#s sip


of toxicity, although failure to lactate resulted in the death of the only surviving offspring Within 3<br />

days of birth.<br />

Decreased fertility <strong>and</strong> gonadal weights in both sexes were seen in the offspring of mice treated<br />

orally with 10 mg/kg/day benzo[g]:lpyrene during gestation. A dose of 40 mg/kgday resulted in almost<br />

compiete sterility. No effect on fetal body weight or survival of the pups was reported (Mackendt<br />

<strong>and</strong> Angevinc, 1981).<br />

Kraup (1970) reported the destruction of small oocytes <strong>and</strong> the reduction of the numbers of<br />

growing <strong>and</strong> large OOCytCS following oral administration of dimethyl benz[danthracene to mice (US.<br />

EPA, 1980).<br />

A reference dose for chronic or subchronic oral exposure to k@danthracene is not available.<br />

32 INHAIATIONEXPOSURES<br />

321. AatttToxicity<br />

321.1. Human<br />

Information on the acute toxicity resulting from the inhslation exposure of humans to<br />

bcnz[3l)anthraccne was unavailable<br />

32L2 Animal<br />

Information on the acute tarticity resulting from the inhalation exposure of animak to<br />

benz(4anthracenc was unavailablc<br />

3221. Human<br />

Information on the toxicity resulting from the subchronic inhalation cxposwc of humans to<br />

benzj~antbracenc was unavailable.<br />

Information on the toxicity resulting from the subchronic inhalation exposure of animals to<br />

bcnz~anthraccne was unavaiiabie. However, subcbronic inhnlation exposures of golden hamsters<br />

to other potycyctic aromatic hydrocarboos, including dimethyl bcnz(&nthracene, benzo~pyrenc. <strong>and</strong><br />

di’benzo[~]pyrene. caused epithelial proliferation <strong>and</strong> cell hyperplasia in the respiratory tract (total<br />

weekly doae of benzo[&.pne was 0.63 mg). These effects lllt~ually seen without marked<br />

infiammation or necrwsis by the 11th wcek of exposure, <strong>and</strong> p d the dcvclopmcnt of rc~phtary<br />

tract tumors (Rd-SchuUet <strong>and</strong> Mob, 1974 SaottL et al, 1968; US. EPA 1980).<br />

.-<br />

7-


33. ChmicTaxicity<br />

323.1. Human<br />

- -<br />

Idomation on the toxicity resulting from the chronic inhalation exposure of humans to<br />

benzjdanthraocnc was unavailable.<br />

3232. Animal<br />

Infarmation on the toxicity resuiting from the chronic inhalation exposure of animals to<br />

benz[i&nthraccne was unavailable. Experiments utilizing the chronic c~rposurt of animals to 0th<br />

polycyclic aromatic hydtocarbons wen designed to study carcinogenesis <strong>and</strong> are not suitable for<br />

describing toxicity efftcts.<br />

32<strong>4.</strong>1. Human<br />

No~reports were available on developmental <strong>and</strong> reproductive effects in humans following<br />

inhalation exposurt to bcnz(danthracenc.<br />

3242 Aaimal<br />

No reports were available on developmental <strong>and</strong> reproductive effects in a&&<br />

inhalation exposure to be4gJanthraCene.<br />

following<br />

A reference concentration for chronic or sukrhronic inhalation v urt to beatfaanthracare<br />

is not avaiiable.<br />

33. OTIIER ROuflEis OF EXPOSURE<br />

33.1, AeutcT0;xiCity<br />

33.1.1. Human<br />

Dm evidence of acute toxicity resulting from exposure of humans to bcnzManm:b<br />

other routes is unavaiiable<br />

Smglc injections ofpoiycyclic aromatic hychcabus have demonstrated the toxic effects of the<br />

compounds on rapidly proliferating cells. An intraperitoncai injection of 3-mcthyicholanthrwe (03<br />

to 1.0 mg) in 12 hour to 9 day-oid mice resulted in severe degeneration of the thymus, reduction ki<br />

weight of the splecn <strong>and</strong> mesenteric lymph nodes, degcncratim of bone marrow dls, <strong>and</strong> retardation<br />

of thyroid gl<strong>and</strong> dcvc1opmcnt. Increased mortaiity was observed with newborn mice after treatmeat<br />

(YaSuhh 1961).<br />

8-


Philips et al. (1973) gave male rats a single intravenous injection of 50 mgkg of 7,12-<br />

dimethylbenz[g]anthracene. The targets that were affected included darriage to the intestinal<br />

epithelium, atrophy of the hematopoietic elements, decreased weight of lymphoid organs,<br />

agranulocytosis, lymphopenia, <strong>and</strong> progressive anemia A similar experiment demonstrated a<br />

decreased [“C]-labtlcd thymidine incorporation into the DNAin the cells of small <strong>and</strong> large intesthe,<br />

spleen, bone marraw, cenrical lymph nodes, thymus, <strong>and</strong> testis. This inhibition, which was as high as<br />

90%, was seen 6 hours after treatment <strong>and</strong> indicated a reduction in DNA synthesis b these orgm,<br />

which normally contain rapidly dividing cek<br />

3321. Human<br />

Subchronic or chronic dermal exposure of workers to materials such as coal tar. mineral 0% <strong>and</strong><br />

petroleum waxa containing benz[&nthracene <strong>and</strong> other polycpctic aromatic h-ns rcsultcd<br />

in the devciopment of dermatitis <strong>and</strong> hyperkeratoses (Huepcr, 1963; NB, 1972)-<br />

33zL Animal<br />

Topical application of benz(~anthraccne <strong>and</strong> other poefic aromatic hydrocarbons to ~~OUSC<br />

skin results in the destruction of sebaceous gl<strong>and</strong>s, hypcrplssia hypcrkeratoais, <strong>and</strong> ulceration of the<br />

skin. The sebaceous gl<strong>and</strong>s arc the most sensitive stn~cturcs to polycyclrc hydrocarbolu. A.<br />

correlation exists between the carcinogenic activity of bcnz[&xUhractne <strong>and</strong> its t ~dv toward the<br />

scbactous gl<strong>and</strong>s (Bock 1961).<br />

Weeklysubcutaneous injections of diknzwanthracenc, benz(&anthracene <strong>and</strong> anthracene in<br />

Ilnioc resulted in dilated lymph sinuses <strong>and</strong> a decrease of lymphoid cells Within 40 week The lymph<br />

gl<strong>and</strong>s contained increased numbers of reticulum (stem) cells <strong>and</strong> an accumulation of iron. Decnased<br />

spleen weight was obscmd in the mice receiving dibcnz[g&]anthfacene (Hoch-Ugeti, 1941).<br />

Lasnit& <strong>and</strong> Woodhouse (1944) studied the effects of subcutanwus injections of<br />

dibenz[wanthraccne, benzo[aJpyrcne, 3-methylcholanthrcne, <strong>and</strong> anthracene on lymph nodes in rats.<br />

Injections were given 5 times weekly for scvcral week <strong>and</strong>, with the exception of anthracene, resulted<br />

in extravascular red blood cells in the lymph spaces <strong>and</strong> the presence of large pigmented cells.<br />

333.1. Human<br />

Subchronic or chronic e ~ ~ ~ of ~ uthe rskin c to polyqdk aromatic hydrocarbon-neg<br />

materials can caw dumatitis in humans (scc&on 3321.).<br />

chronic exposure experiments using various route wcre designed to examine cancer end points<br />

<strong>and</strong> are not generally useful as toxicity studies. The qualitative resultt, however, gcncdy reflect<br />

those obscnnd for the cf€ccts from single or-subchronic exposures to polycyclic aromatic<br />

hydmcahons (US. EP& 1980).<br />

9-


33.<strong>4.</strong> Dercbpmental <strong>and</strong> Reproductive Toxicity<br />

33.<strong>4.</strong>1. Human<br />

--<br />

Information on the developmental <strong>and</strong> reproductive toxicity of beN4anthracene in humans by<br />

other routes of exposure was unavailable.<br />

33.42 Animal<br />

Single intravenous injections of 0.5 to 20 mg dimethyl be@danthracene in =day old rats or<br />

injections of 5.0 mg in 6O.day old rats resulted in degeneratk change in the testis 38 to 40 days<br />

after treatment These lesions included the destruction of spermatogonia <strong>and</strong> resting SpennatOcJrter<br />

(Ford <strong>and</strong> Huggins, 1963). In a similar acpcrimcnt, the destruction of primary in mice was<br />

also seen after injection of 3-mcthykholanthrcn~. The effezt in this experiment was correiated with<br />

the ability of the mice to induce the microsomal miroed-function oxidase enqmes following treatment<br />

(Mattison <strong>and</strong> Thorgeirson, 1977).<br />

3.<strong>4.</strong> TARGEI' ORG-CAL EFFECIS<br />

3.4-1.1. Primarjr T-r)<br />

1. Hematopoietic system: Animal studies have shown atrophy of the hematopoietic elements<br />

leading to progresshe anemia <strong>and</strong> agrarrulocytosit after exposure to polycyclic aromatk<br />

w==bo=<br />

2, Lymphoid sysw Shrinkage of lymphoid organs <strong>and</strong> rymphopeaia have been noted in -<br />

animals cxposcd to potyEgclic aromatic hydrocarbons.<br />

3. Intestinal epithelium: Damage to the rapidly growing cpithefial cells of animals has bcen<br />

okrved following cxposute to polycyclic aromatic hydrocarbons<br />

<strong>4.</strong> Testis or wary Destruction of the spermatogonia <strong>and</strong> resting spermatocytes in males <strong>and</strong><br />

the primary oocytes in female, following exposure to poiycyclic aromatic hydrocarbonJ.<br />

3.421, RiumryTm<br />

1. Fbsphtory tract: Animal experiments have shown epithctial pmlEeration <strong>and</strong>-cell<br />

hyperplasia following rubchronic exposure topolycyclic aromatic hydrocarboas. This effect<br />

be a preneoplastic lesion.<br />

.<br />

10


<strong>4.</strong> CARcINoGmm<br />

<strong>4.</strong>1. ORALExposuREs<br />

<strong>4.</strong>1.1. Human<br />

Data relating human oral exposure to benz(4anthracene <strong>and</strong> subsequent cancer deveIopment<br />

was not available. -anthracene is a component of mixtures that have been associated with<br />

human C~IICCK such as coal tar, soots, coke oven emissions, automobile exhaust, <strong>and</strong> cigarette smoke<br />

(USEPA 1980; 1984).<br />

<strong>4.</strong>12 Animal<br />

Klein (1963) treated male mice with 3% benz[&nthraoene in Method-aerosol 0.T.by gavage<br />

3 timesheck for 5 weeks. Timm~ were evaluated on days 437-444 <strong>and</strong> 547 after the initiation of<br />

treatment. An increased incidence of pulmonary adenomas <strong>and</strong> hepatomas was noted at alI<br />

observation times when compared with controls. The incidence of pulmonary adenomas reached 95%<br />

<strong>and</strong> the incidence of hepatoma reached 100% after 547 days. Back <strong>and</strong> King (1959) administered<br />

8 or 16 gavage treatments of benzjgJanthracene to mice at 3-7 day intexvals over a 16.month period.<br />

They found forestomach papiilomas in the treated groups (un) <strong>and</strong> none in the control group (ODs).<br />

Treatment of Swiss mice with benzo[&yrcne, a related po&fic aromatic h m Q also<br />

dted in stoznach tumors. Mice were fed doses ranging between 1 <strong>and</strong> 250 ppm in the diet for 110<br />

days. The appearance of squamous cell papillomas <strong>and</strong> carcinomas was roughly dose dependent. The<br />

cancer incidences observed were for the control, 1/23 for 2.6 rng/kg/day9 1/40 for 53 mglkglday,<br />

4/40 for 5.S mwday, <strong>and</strong> 19i23 for 13.0 mg/kg/day (Neal <strong>and</strong> Rigdon, 1967).<br />

42 INHALATION-<br />

421. Humnn<br />

Data on human inhalation cxposure to benz[danthraccne <strong>and</strong> subsequent cancer development<br />

was not available. Be@gJanthraccne is a component of mixtures containing other polycyclic aromatic<br />

hydrocarborrs that have been associated with human cancers such as coaj tar, soots, coke oven<br />

emissions, automobile exhaust, <strong>and</strong> cigarette smoke (US. EPA, 1980; 1984).<br />

422 Animal<br />

Data on inhalation exposure of animals to ~anthnccne <strong>and</strong> substqucnt cancer<br />

dcvtlopment were not available. There arc studies, howevcr, !hat show tumor development following<br />

inhalation of related polycyciic aromatic hydmaubons Golden hamsters wcposed by inhalation to<br />

9.5 m&n3 benzo[j&yrcne for 45 houdday for 10 wee4 followed by 3 hodday for up to 675 d ~ ,<br />

developed tumon of the naral cavity, largnx, trachea <strong>and</strong> pharyrm The high dose a b caused tunron<br />

of the upper digestive tract (Thysen et aL, 1981).<br />

11


43. OTRER ROUTES OF EXPOSURE<br />

43.1. Human<br />

.-<br />

Data relating other routes of c~rposurto benz[danthracene <strong>and</strong> subsequent cancer d-bprncat<br />

were not available. BenzjgJanthracene is a component of mixtures that have been d ated with<br />

human cancers such as coal tar, soots, cokc oven emissions, automobile exhaust, <strong>and</strong> cigarette smoke<br />

(U.S. EPA, 1980; 1984). 8<br />

432 Animal<br />

Intraperitoneal injections of mice with bex4&inthracene in dhethylsutfojoide on days 1,8, <strong>and</strong><br />

15 of age (total dose of 638 pglmouse) resulted in liver adenomas <strong>and</strong> carcinomas in male mice (31/39<br />

total tumors treated, 25/39 adenomas, 2/28 total controls) <strong>and</strong> pulmonary adenomas in female mice<br />

(6/32 treated, ODZ coxitrob) 1 year after expo~ure (wislocki et al, 1986).<br />

Subcutantous injection of mice with bcnzjaanthracene resulted in sarcomaJ at the site of<br />

injection 9 months following treatment. Injection of 5.0 mg produccd a sarcoma incidence of 34%<br />

with no tumors seen in controls (Steher <strong>and</strong> Edgecomb, 1952).<br />

A number of studies have shown ~&nthracene to have initiating activity <strong>and</strong> to act as a<br />

complcte carcinogen in skin painting assays in scvcral strains of mice (IARC 1973; US. EPA, 1991b).<br />

Levin et ai. (1984) tested the tumor-initiating activity of bc@danthraccne <strong>and</strong> a number of its<br />

metabolic products in a mouse skin painting assay. A single d- of 0.4 or 2.5 pmole of<br />

bcnzla)anthracene followed by 25 web of promotion with 12-O-tetrad~~photboc13-aatcrte<br />

resulted in skin tumor incidence of 7% for the controls, 14% for 0.4 pmole, <strong>and</strong> 36% for 23 pmole.<br />

<strong>4.</strong><strong>4.</strong> EPA WEIGR"!!EEVXDENCE<br />

CLASSIFICATION Group B2 - Probable Human Carcinogen (US. EPA, 1991b).<br />

BASIS: Based on no human data <strong>and</strong> suf€icient data from animal expcrimCntt<br />

Bcx@&mthractne has becn shown to produce tumors in mice exposed by gavage; t w<br />

application: <strong>and</strong> intraperitoneal, subcutancoru or intramuscular injection (US. EPA 1991).<br />

CLASIFICATION Group B2 - Pmbable Human Caxknogcn (US EPA, 1991b).<br />

BASIS: Based on no human data <strong>and</strong> suflicient data from animal<br />

Be@&mthraccne has been shown to produce tumon in mice exposed by gavage tow<br />

apptication: <strong>and</strong> intraperitoneal, subcutaneous or intramuscular injection (US. EPA 1991). A<br />

related bay-region polycyclic aromatic hydrocarbon, bcnm~pyrenc, has been shown to cause<br />

respiratory tract tumors in goiden hamsten when given by inhalation exposure frhJlssea et al,<br />

1S1).<br />

12-


45. CARCINOGENIClTY SIDPE FACXORS<br />

45.1. Oral<br />

An oral slope factor has not been calculated specifically for benzwanthracene (Us. EPA, 1991).<br />

Benzolalwrcne:<br />

SLOPE FACTOR<br />

73 (rng/kg/day)'' (US. EPA, 1980,1984,1992a).<br />

DRINKING WATER UNIT RISR 21E-4 (pgAJ' (US. EPA, 1992a)<br />

VERZFICATION DATE: 071011p2<br />

PRINCIPALSTUDY: Neal <strong>and</strong> Rigdon (1967).<br />

TI& slop factor was calculated by the EP& (1W) from data ob- from<br />

experiments using bcnzo~pyrene <strong>and</strong> was based on the incidence of stomach tumors in mi=<br />

This slop factor was applied to protect humans from the d o g e ~ effects c of pome<br />

aromatic hydrocarborn as a chemical class. It is not currently available on IRIS for specific uc<br />

with be~anthraccne<br />

45.2 Inhslation<br />

mfaluvrcng<br />

SLOPE FACXIR<br />

INHALATION UNIT RISK:<br />

VERIFICATION D AE<br />

PRINaPALrnX<br />

-<br />

Not verified.<br />

laysten et aL (1981).<br />

(US EPA, 1992b)<br />

(US EPA 199%).<br />

mMMEN'I3 This slope factor was calculated by the EPA (1984) from data obtained from-.<br />

experiments using benoo~pyrae <strong>and</strong> was bascd on the incidence of rcsphtory tumors in<br />

golden hamsters. This slope factor was applied to protect humans from the carcinogenic effects<br />

of polycyclic aromatic hydrocarbons as a chemical class. It is not currently available on IRIS for<br />

specific use with bcnzla)anthraccnc<br />

13


5. REFERENCES<br />

Bock, F.G. 196<strong>4.</strong> Early effects of hydmxrbons on mammalian skin.<br />

4 126.<br />

.-<br />

Prop. Expo Tumor Rea.<br />

Bock, F.G.<strong>and</strong> D.W. King. 1959. A study of the sensitivity of the mouse forestomach toward certain<br />

polycyclic hydrocarbans. J. NatL Cancer IIUL 23: 833-839.<br />

Cawein, MJ. <strong>and</strong> K.L. Sydnor. 1968 Suppression of cellular activity in the reticuloendothclial<br />

system of the rat by 7,12dimethyi~anthracenc Cancer Res. 28: 320.<br />

Ford, E <strong>and</strong> C HuggiPs. 1963. selectivt destruction in testis indd by 7J2-<br />

dimcthyl~anthcenc. J.Exp.Med ll&27.<br />

Hoch-Ligcti, C 1941. Studies on the changes in the lymphoid tissues of mice treated with<br />

carcinogenic <strong>and</strong> non-cardnogenic hydracarbons Cancer Res 1: 48<strong>4.</strong><br />

Hueper, W.C. 1963. Chemically induced skin cancers in man. NatL Cancer Inst. Monograph. 10:<br />

371.<br />

IARC (International ABency for Reruucb on Cancer). 1973. Certain Potycyciic Aromatic<br />

Hydrocarbons <strong>and</strong> Heterocyclic Compounds. Monographs on the Evaluation of the carcinogenic<br />

Risk of Chemicak to Man. Polynuclear Aromatic Compounds. VoL 3. Lyon, France.<br />

Jerina, D.M., R khr, M. Schaefer-Riddet, H.Yagi,J.M. Karle, D.R. -* AW. WOOQ AYE<br />

Lu, D. Ryan, S. West. W. M n <strong>and</strong> AH. Coany. 1977. Bay-region e- of dihydrodiok: A<br />

concept explaining the mutagenic <strong>and</strong> carcinogenic activity of benzrowm aad<br />

benzoManthraceac in: Origins of Human Cancer. cdd Spring Harbor Laboratory. pp. 639-657.<br />

Katin, p., et at I=. Dstriiution, retention, <strong>and</strong> elimination of 14C-39~~ne.ak<br />

administtation to mice <strong>and</strong> rats. J. NatL b a r Inst 23: 541.<br />

Lajnitzki, A <strong>and</strong> DL Woodhousc 194<strong>4.</strong> The effect of 1,2,5,6d1~t&raccne on the lpph<br />

nodes of the rat. J. Anat. 78: 121.<br />

Levin, W., RL Chang, AW. WOOQ RYagi, D.R’hakkcr, D.M. Jerina<strong>and</strong>k H.Conmy- lB<strong>4.</strong><br />

High StercwcieCtiVity among the optical isomers of the diastueomeric bay-rcgion diotcpoaider of<br />

anthracene in the expression of tumorigenic activity in murine tumor model. Cancer Rer<br />

44: 929-933.<br />

.


Aattisoa, D.R. <strong>and</strong> S.S. Thorgeirssoa. 1977. Ovarian metabolism of polycyclic aromatic hydrocarbons<br />

<strong>and</strong> associated ototoxicity in the mouse. GyntcoL Invest. 8 11. -.<br />

Mitchell, CE <strong>and</strong> K. W. Tu 1979. Distribution, retention <strong>and</strong> elimination of pyrene in rats after<br />

inhalati01~ J. ToxicOL Emriron. Health. 5: 1171-1179.<br />

National Academy of Sciences. 1972 Biological effects of atmospheric pollutants: Particulate<br />

polycyclic organic matter. Washington,D.C<br />

Neal, J. <strong>and</strong> RH. Rigdon. 1967. Gastric tumors in mice fed bcnzo(dpyrene: A quantitative study.<br />

Tex Rep. BioL Med. 25: 553.<br />

Rees, EO., et aL 1971. A study of the mechanism of intestid absorption of<br />

Biochem. Biophys. Acta. 225: 96<br />

ReSchuller, H. <strong>and</strong> U. Mob. 197<strong>4.</strong> Investigations on the CarcinogCnic burden by air pollution<br />

in man. Ix Ear@ pathological alterations of the bronchial epithelium in Syrian goldcn hamsters after<br />

intratracheal instillation of bu~~~pyrene. Pl.BaLt. Hyg., L Abt. Ong. R 159: 493.<br />

Rigdon, FLH. <strong>and</strong> EG. RCM& 196<strong>4.</strong> EIftct of feeding -e on reproduction in the rat.-<br />

Eqcricnth a224-226.<br />

Robinson, J.R., J S Felton, RC Lcvitt, S S Thotgitrsson <strong>and</strong> D.W. Nebert 1975. Relationship<br />

W "aromatic hydrocarbon rcqxinsivcnd <strong>and</strong> thesurvival timer in mice trurtedwithvaxious<br />

drugs <strong>and</strong> eavkunmental compoun&. Mol PbannaeoL 11: 850.865.<br />

motti, U., et aL. 1968. A method for the experimental induction of bronchogenic Catcinoma.<br />

Cancer Rcs. 28: 10<strong>4.</strong><br />

Sax, N.I. 1981. Cancer Causing Chemicals. Van Nostr<strong>and</strong> Rci~ihold, Ncw York, p. 299.<br />

schlede, F: et al. 19706. Stimulatory effect of benzo[dpyrene <strong>and</strong> phcnobarbital pretreatment on<br />

the biliary cxuetion of benoo@Jpyrcne metabolites in the rat Canccr Res. 30: 2898.<br />

SChlcde, E, et al. 197oa EEEcct of enzyme induction on the metaboh <strong>and</strong> tissue distniutbn of<br />

bcnzo@Jpe CinarRer. 30:2893.<br />

sitti& M. 1985. H<strong>and</strong>book of Toxic <strong>and</strong> Hazardous Chemicals <strong>and</strong> Carcinogens, Second Edition.<br />

Naye~ Publications, Park Rids New Jersey, pp.109-110.<br />

Stcincr, P.E <strong>and</strong> J.H. Edgecomb. 1952 cardnogenicity of 13-benzarrtbraoenc. Cancer Rca 125-<br />

657-659.<br />

Taysstn, F; J. Althoff, G. Kirnmde <strong>and</strong> U. Moht. 1981. Inhslation studies with Bcnm~pyrcuc<br />

in Syrian golderr hamster& J. Natl Caacer Inst bbc 575-577.<br />

15


US. EPA 1980. Water Quaiity Criteria Document for Polynuclear Aromatic Hydrocarbons.<br />

Prepared by the Office of Research <strong>and</strong> Development, Environmental Criteria And Assessment<br />

Office, Cincinnati,OH for the Office of Water Regulations <strong>and</strong> St<strong>and</strong>ards, Washington, DC<br />

US. EPA 198<strong>4.</strong> Hcalth Effects Assessment for Polycyclic Aromatic Hyd-ns. Prepared by<br />

the Office of Htalth <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment Office,<br />

Cincinnati, OH for the OfEcc of Emergency <strong>and</strong> Remedial Response, Washington, DC 'EP.A./540/1-<br />

86-013.<br />

US. EfA 1991. Integrated Risk Information System (nus). Health Risk Assessment for<br />

BenzfaJanthracene. OnLine. Office of Hcaith <strong>and</strong> Environmental Assessment, Environmental Criteria<br />

<strong>and</strong> Asscsslaent 0- Cincinnati, OH.<br />

US. EPA 1- Integrated Risk Infonaation System @us). Health Risk Asstssment for<br />

&nmww~. OnLiae. Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria<br />

<strong>and</strong> Assessmcat Ofh, Cincianati OH.<br />

US. EPA 1992b. Hcalth EEects Assessment Summary Tables, Prepared by the Office of Health<br />

<strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment Office,Cincinnati, OH for<br />

the Office of Emcrgcncy <strong>and</strong> Remedial Response, Washington,DC<br />

Vainio, H.,et aL 1976. The fate of intratracheaUy installed benzo[~pyrenc in the isolated petfrrred<br />

rat lung of both control <strong>and</strong> 20-methylcholanthrene pretreated rats. Res. canm. chem. PathoL<br />

PharmacoL 13: 259.<br />

Wmlocki, P.G., E.S. Bagan, AYX. tu, et aL 1986. TumorigeniCity of nitrated derivatives of p~mne,<br />

benz(~anchraCcne, chryJerrc <strong>and</strong> berrzro[dpe in the newborn mouse assay. Carcinogenuk 7:<br />

1317-1322.<br />

Yasuhira, K 196<strong>4.</strong> Damage to the thymus <strong>and</strong> other lymphoid tissues from 3-mcthylcholanthrcnc,<br />

<strong>and</strong> subsequent thymoma production, in mice. Cancer Res. 24 558.<br />

16


TOXICITY SUMMARY FOR<br />

BENZO[u]PYRENE<br />

December 1994<br />

Prepared by:<br />

Rosmarie A. Faust, Ph.D.<br />

Chemical Hazard Evaluation Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health Sciences Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy under<br />

Contract No. DE-AC05-MOR21400


THIS PAGE INTENTIONALLY LEFT BLANK


EXECUTIVE SUMMARY<br />

Benzo[a]pyrene is a polycyclic aromatic hydrocarbon (PAH) that can be derived from coal tar.<br />

Benzo[u]pyrene occurs ubiquitously in products of incomplete combustion of fossil fuels <strong>and</strong> has been<br />

identified in ambient air, surface water, drinking water, waste water, <strong>and</strong> char-broiled foods (IARC,<br />

1983). Benzo[a]pyrene is primarily released to the air <strong>and</strong> removed from the atmosphere by<br />

photochemical oxidation <strong>and</strong> dry deposition to l<strong>and</strong> or water. Biodegradation is the most important<br />

transformation process in soil or sediment (ATSDR, 1990).<br />

Benzo[a]pyrene is readily absorbed following inhalation, oral, <strong>and</strong> dermal routes of administration<br />

(ATSDR, 1990). Following inhalation exposure, benzo[u]pyrene is rapidly distributed to several tissues<br />

in rats (Sun et al., 1982; Wey<strong>and</strong> <strong>and</strong> Bevan, 1986). The metabolism of benzo[o]pyrene is complex <strong>and</strong><br />

includes the formation of a proposed ultimate carcinogen, benzo[a]pyrene 7,8 diol-9,lO-epoxide (IARC,<br />

1983). The major route of excretion is hepatobiliary followed by elimination in the feces (EPA, 1991).<br />

No data are available on the systemic (non-carcinogenic) effects of benzo[a]pyrene in humans. In<br />

mice, genetic differences appear to influence the toxicity of benzo[a]pyrene. Subchronic dietary<br />

administration of 120 mg/kg benzo[a]pyrene for up to 180 days resulted in decreased survival due to<br />

hematopoietic effects (bone MITOW depression) in a "nonresponsive" strain of mice (Le., a strain whose<br />

cytochrome P-450 mediated enzyme activity is not induced as a consequence of PAH exposure). No<br />

adverse effects were noted in "responsive" mice (i.e., a strain capable of inducing increased cytochrome<br />

P-450 mediated enzyme activity as a consequence of PAH exposure) (Robinson et al., 1975).<br />

Immunosuppression has been reported in mice administered daily intraperitoneal injections of 40 or 160<br />

mg/kg of benzo[u]pyrene for 2 weeks, with more pronounced effects apparent in "nonresponsive" mice<br />

(Blanton et al., 1986; White et al., 1985). In utero exposure to benzo[a]pyrene has produced adverse<br />

developmentaVreproductive effects in mice. Dietary administration of doses as low as 10 mg/kg during<br />

gestation caused reduced fertility <strong>and</strong> reproductive capacity in offspring (Mackenzie <strong>and</strong> Angevine, 1981),<br />

<strong>and</strong> treatment by gavage with 120 mg/kg/day during gestation caused stillbirths, resorptions, <strong>and</strong><br />

malformations (Legraverend et al., 1984). Similar effects have been reported in intraperitoneal injection<br />

studies (ATSDR, 1990). Neither a reference dose (RfD) nor a reference concentration (RfC) has been<br />

derived for benzo[a]pyrene.<br />

Numerous epidemiologic studies have shown a clear association between exposure to various<br />

mixtures of PAHs containing benzo[a]pyrene (e.g., coke oven emissions, roofing tar emissions, <strong>and</strong><br />

cigarette smoke) <strong>and</strong> increased risk of lung cancer <strong>and</strong> other tumors. However, each of the mixtures also<br />

contained other potentialIy carcinogenic PAHs; therefore, it is not possible to evaluate the contribution<br />

of benu>[u]pyrene to the carcinogenicity of these mixtures (IARC, 1983; EPA, 1991). An extensive data<br />

base is available for the carcinogenicity of benzo[u]pyrene in experimental animals. Dietary<br />

administration of benzo[a]pyrene has produced papillomas <strong>and</strong> carcinomas of the forestomach in mice<br />

(Neal <strong>and</strong> Rigdon, 1967), <strong>and</strong> treatment by gavage has produced mammary tumors in rats (McCormick<br />

et al., 1981) <strong>and</strong> pulmonary adenomas in mice (Wattenberg <strong>and</strong> Leong, 1970). Exposure by inhalation<br />

<strong>and</strong> intratracheal instillation has resulted in benign <strong>and</strong> malignant tumors of the respiratory <strong>and</strong> upper<br />

digestive tracts of hamsters (Ketkar et al., 1978; Thyssen et al., 1981). Numerous topical application<br />

studies have shown that benzo[a]pyrene induces skin tumors in several species, although mice appear to<br />

be the most sensitive species. Benzo[u]pyrene is a complete carcinogen <strong>and</strong> also an initiator of skin<br />

tumors (IARC, 1973; EPA, 1991). Benzo[u]pyrene has also been reported to induce tumors in animals<br />

when administered by other routes, such as intravenous, intraperitoneal, subcutaneous, intrapulmonary,<br />

<strong>and</strong> transplacental.<br />

iii


Based on United States Environmental Protection Agency (EPA) guidelines, benzo[a]pyrene was<br />

assigned to weight-of-evidence group B2, probable human carcinogen. For oral exposure, the slope<br />

factor <strong>and</strong> unit risk are 7.3E+O (mg/kg/day)-' <strong>and</strong> 2.1E-4 (pg/L)-', respectively (EPA, 1994).<br />

iv


1. INTRODUCTION<br />

Benzo[a]pyrene (CAS Reg. No. 50-32-8), also known as 1,4-benzo[u]pyrene (BaP), is a polycyclic<br />

aromatic hydrocarbon (PAH) with a chemical formula of C20H,2 <strong>and</strong> a molecular weight of 252.3. It<br />

exists as yellowish plates <strong>and</strong> needles, has a boiling point of 310-312°C at 10 mm Hg (Budavari et al.,<br />

1989), a melting point of 178"C, <strong>and</strong> a density of 1.35 (EPA, 1991). Benzo[u]pyrene is practically<br />

insoluble in water but is soluble in benzene, toluene, xylene <strong>and</strong> sparingly soluble in alcohol <strong>and</strong> methanol<br />

(Budavari et ai., 1989). It has a vapor pressure of 5.0 x 1-' torr <strong>and</strong> a log octanol/water coefficient of<br />

6.04 (EPA, 1991).<br />

No current commercial production or use of benzo[a]pyrene is known. It occurs ubiquitously in<br />

products of incomplete combustion <strong>and</strong> in fossil fuels. It has been identified in surface water, tap water,<br />

rain water, groundwater, waste water, <strong>and</strong> sewage sludge (EPA, 1991). Benzo[u]pyrene is primarily<br />

released to the air <strong>and</strong> removed from the atmosphere by photochemical oxidation <strong>and</strong> dry deposition to<br />

l<strong>and</strong> or water. Biodegradation is the primary transfonnation process in soil or sediment (ATSDR, 1990).<br />

The estimated half-lives for benzo[a]pyrene are less than 1-6 days in the atmosphere, less than 1-8 hours<br />

in water;5-10 years in sediment, <strong>and</strong> greater than 14-16 months in soil (for complete degradation) (EPA,<br />

1984). Benzo[u]pyrene is one of a number of PAHs on EPA's priority pollutant list (ATSDR, 1990).<br />

2. METABOLISM AND DISPOSITION<br />

2.1 ABSORPTION<br />

Benzo[u]pyrene is readily absorbed by the oral, inhalation, <strong>and</strong> dermal routes of exposure (ATSDR,<br />

1990). Rats given benzo[u]pyrene in starch solution by gavage (100 mg) or in the diet (250 mg) absorbed<br />

40% or 60%. respectivefy, of the administered compound (Chang, 1943). The absorption of<br />

benzo[a]pyrene from the gastrointestinal tract of mice <strong>and</strong> cats is enhanced when it is solubilized in<br />

vehicles possessing both lipophilic <strong>and</strong> hydrophilic properties (Ekwalf et al., 1951). Once benzo[a]pyrene<br />

has entered the small intestine, it is solubilized by bile salts <strong>and</strong> absorbed (Ermala et al., 1951).<br />

In rats exposed by inhalation to 1 pg/L radiolabeled benzo[u]pyrene for 30 minutes, monitoring of<br />

excretion over a 2-week period showed nearly complete recovery of radioactivity (predominantly in<br />

feces), indicating nearly complete absorption (Sun et al., 1982).<br />

Under in vitro conditions, 3% of an applied dose of benzo[u]pyrene permeated human skin after<br />

24 hours. When tested in several animal species, the permeation was highest in the mouse (10%) <strong>and</strong><br />

lowest in the guinea pig (0.1%) (Kao et al., 1985). Following topical application of radiolabeled<br />

benzo[u]pyrene to the skin of mice, Heidelberger <strong>and</strong> Weiss (1951) recovered most of the radioactivity<br />

in the feces within 16 days, indicating significant absorption of benzo[u]pyrene through the skin.<br />

2.2 DISTRIBUTION<br />

According to Rees et al. (1971), 10-20% of an intragastric dose of benzo[u]pyrene (10 mg) entered<br />

the thoracic lymph duct in rats (levels in other tissues were not determined). Other data concerning the<br />

tissue distribution of benzo[u]pyrene following oral exposure were not available.


2<br />

In rats exposed by inhalation, distribution of absorbed benzo[u]pyrene is rapid, with highest levels<br />

found in the liver, esophagus, small intestine, <strong>and</strong> blood 30 minutes after exposure (Sun et al., 1982).<br />

Five minutes after intratracheal instillation of benzo[u]pyrene to rats, the percentages of the administered<br />

dose in tissues were lungs (59.5%), carcass (1<strong>4.</strong>4%), liver (12.5%), blood (3.9%), <strong>and</strong> intestines (1.9%).<br />

At 60 minutes, the percentages were lungs (15.4%), carcass (27.1%). liver (15.8%), blood (1.6%), <strong>and</strong><br />

intestines (9.9%) (Wey<strong>and</strong> <strong>and</strong> Bevan, 1986).<br />

Topical administration of ''C-benzo[u]pyrene in benzene to the shaved backs of mice was followed<br />

by a biphasic disappearance of radioactivity from the application site, with half-lives of 40 <strong>and</strong> 104 hours<br />

(Heidelberger <strong>and</strong> Weiss, 1951).<br />

Benzo[u]pyrene can readily cross the placenta following oral, intravenous, or subcutaneous<br />

..<br />

-ion.<br />

This observation is consistent with the observed toxicity in the fetuses <strong>and</strong> offspring of<br />

maternally exposed rodents (IARC, 1983; ATSDR, 1990).<br />

2.3. METABOLISM<br />

The metabolism of benzo[u]pyrene has been extensively studied in the literature <strong>and</strong> only the most<br />

important pathways will be presented in this summary. As outlined in L4RC (1983), benzo[u]pyrene is<br />

metabolized initially by the microsomal cytochrome P-450 monooxygenase system to several arene<br />

oxides, which may rearrange spontaneously to phenols, undergo hydration to the corresponding transdihydrodiols,<br />

or react covalently with glutathione, either spontaneously or in a reaction catalyzed by<br />

glutathione-S-transferases. One of the phenolic metabolites, 6-hydroxybenzo[u]pyrene, is further oxidized<br />

to the 1,6-, 3,6-, or 6,12-quinones. The phenols, quinones, <strong>and</strong> dihydrodiols can be detoxified by<br />

conjugation to glucuronides <strong>and</strong> sulfate esters, <strong>and</strong> the quinones can also form glutathione conjugates.<br />

In addition to conjugation, the dihydrodiols undergo further oxidative metabolism. Benzo[u]pyrene<br />

7.8dihydrodiol is in part oxidized to 7,8diol-9,10-epoxide, a compound considered to be the ultimate<br />

carcinogenic metabolite of benzo[u]pyrene.<br />

2.4 EXCRETION<br />

Hepatobiliary excretion <strong>and</strong> elimination in the feces is the primary route for benu>[u]pyrene<br />

metabolic excretions (EPA, 1991). Two weeks following inhalation exposure to radiolabeled<br />

benzo[u]pyrene for 30 minutes, most of the radioactivity was recovered in the feces of rats (Sun et al.,<br />

1982). Similarly, essentially all of the radioactivity was recovered in the feces of mice that had been<br />

treated topically with radiolabeled benzo[u]pyrene (Heidelberger <strong>and</strong> Weiss, 1951). Kotin et al. (1959)<br />

reported that approximately 75% of a subcutaneously injected dose of benzo[u]pyrene was recovered in<br />

the feces of mice within 6 days of injection, while only 12% was eliminated in the urine. In rats, 39%<br />

of an intravenous dose was found in the bile at 3 hours <strong>and</strong> as much as 96% by 14 hours. Less than 1 %<br />

of recovered benzo[u]pyrene in the bile was metabolized. In rats with bile duct cannulation, 3-41 of<br />

the dose was recovered in the urine, while intact rats had a urinary excretion of 7-14%, suggesting<br />

enterohepatic circulation of metabolites. No evidence suggested that benzo[u]pyrene is eliminated via<br />

expired air.


3<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1 ORALEXPOSURES<br />

3.1.1 Acute Toxicity<br />

Information on the acute oral toxicity of benzo[u]pyrene in humans or animals is not available.<br />

3.1.2 Subchronic Toxicity<br />

3.1.2.1 Human<br />

Information on the subchronic oral toxicity of benzo[u]pyrene in humans is not available.<br />

3.1.2.2 Animal<br />

Genetic differences appear to influence the oral toxicity of benzo[u]pyrene in mice. Robinson et<br />

al. (1975) investigated the effects of oral administration of benzo[u]pyrene in several strains of mice,<br />

classified as "responsive" (those capable of producing increased levels of cytochrome P-450 mediated<br />

enzymes as a consequence of PAH exposure) or "nonresponsive" (those not highly responsive to<br />

producing increased levels of cytochrome P-450 mediated enzymes as a consequence of PAH exposure).<br />

Following dietary administration of 120 mg/kg of benzo[u]pyrene for up to 180 days, survival of all<br />

"nonresponsive" mice was shortened. Death appeared to be due to bone marrow depression (aplastic<br />

anemia, pancytopenia). The "responsive" mice remained healthy for at least 6 months. The authors<br />

concluded that decreased survival in "nonresponsive" mice was associated with a single gene difference<br />

in PAH responsiveness.<br />

3.1.3 Chronic Toxicity<br />

Information on the chronic oral toxicity of benzo[u]pyrene in humans or animals was not available.<br />

3.1.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1 Human<br />

Information on the developmental <strong>and</strong> reproductive toxicity of benzo[u]pyrene in humans following<br />

oral exposure is not available.<br />

3.1.<strong>4.</strong>2 Animal<br />

No reproductive or developmental toxicity was observed in male or female White Swiss mice fed<br />

diets containing 0, 250, 500, or lo00 mgkg benzo[u]pyrene over various time periods during mating,<br />

gestation, <strong>and</strong> lactation (Rigdon <strong>and</strong> Neal, 1965). However, Mackenzie <strong>and</strong> Angevine (1981) reported<br />

that administration of 10 mg/kg to CD-1 mice by gavage during gestation produced decreased gonadal<br />

weights <strong>and</strong> reduced fertility <strong>and</strong> reproductive capacity in the offspring. Higher doses (40 mg/kg) caused<br />

almost complete sterility in both sexes of offspring.<br />

Legraverend et al. (1984) investigated the effect of genetic differences in benzo[u]pyrene metabolism<br />

on the reproductive or developmental toxicity in "responsive" <strong>and</strong> "nanresponsive" mice (benzo[u]pyrene


4<br />

metabolism occurs more readily in the "responsive" genotypes). Pregnant mice were fed 120 mg/kg/day<br />

on days 2-10 of gestation. Treatment with benzo[u]pyrene resulted in stillbirths, resorptions, <strong>and</strong><br />

malformations in both genotypes of mice; however, the incidence of these effects was higher among<br />

"nonresponsive" embryos than among "responsive" embryos. The study suggests that it is benzo[a]pyrene<br />

<strong>and</strong> not a metabolite which is responsible for the noted adverse effects.<br />

3.1.5 Reference Dose<br />

An oral reference dose (RfD) for benzo[u]pyrene has not been derived.<br />

3.2 INHALATION EXPOSURES<br />

3.2.1 Acute Toxicity<br />

Information on the acute toxicity of benzo[u]pyrene in humans or animals following inhalation<br />

exposure is not available.<br />

3.2.2 Subchronic Toxicity<br />

Information on the subchronic toxicity of benzo[u]pyrene in humans or animals following inhalation<br />

exposure is not available.<br />

3.2.3 Chronic Toxicity<br />

Information on the chronic toxicity of benzo[u]pyrene in humans or animals following inhalation<br />

exposure is not available.<br />

3.2.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

Information on the developmental <strong>and</strong> reproductive toxicity of benzo[u]pyrene in humans or animals<br />

following inhalation exposure is not available.<br />

3.2.5 Reference Concentration<br />

An inhalation reference concentration (RfC) for benzo[u]pyrene has not been derived.<br />

3.3 OTHER ROUTES OF EXPOSURE<br />

3.3.1 Acute Toxicity<br />

3.3.1.1 Human<br />

Information on the acute toxicity of benzo[u]pyrene in humans by other routes of exposure was not<br />

available.<br />

3.3.1.2 Animal


5<br />

The intraperitoneal (i.p.) LDSo for the mouse is 232 mg/kg (Salamone, 1981), <strong>and</strong> the subcutaneous<br />

(s.c.) LDSo for the rat is 50 mgkg (RTECS, 1994). Reduced survival was reported in "responsive" mice<br />

administered a single i.p. injection of 500 mg/kg benzo[u]pyrene (Robinson et al., 1975). Subcutaneous<br />

injections of benzo[u]pyrene (5, 20, or 40 mg/kg) caused a dose-related suppression of both T-cell<br />

independent <strong>and</strong> T-cell dependent antigens in mice (White <strong>and</strong> Holsapple, 1984). Wojdani et al. (1984)<br />

injected two strains of mice with tumor target cells; this treatment was followed by i.p. injections of 0,<br />

0.5, 5, or 50 mgkg of benzo[u]pyrene. At the two higher doses, significant decreases were reported in<br />

lymphocytes binding to target cells or killing target cells. The investigators indicated that lymphocytemediated<br />

immunity may be inhibited by benzo[u]pyrene <strong>and</strong> that this immunosuppresive effect may<br />

contribute to its carcinogenicity.<br />

3.3.2 Subchronic Toxicity<br />

3.3.2.1 Human<br />

Information on the subchronic toxicity of benzo[u]pyrene by other routes of exposure in humans<br />

is not available.<br />

3.3.2.2 Animal<br />

Immunotoxic effects as a consequence of benzo[u]pyrene have been studied by a number of<br />

investigators. For example, a 60% suppression of antibody response was reported in B6C3Fl mice (a<br />

highly "responsive" strain) administered 14 daily S.C. injections of 160 pmol/kg benzo[u]pyrene. In<br />

DBN2 mice (a strain not highly "responsive") subjected to the same dosing protocol, immunosuppression<br />

was more pronounced (White et al., 1985). Daily S.C. injections of 40 mg/kg benzo[u]pyrene for 14 days<br />

resulted in a 98% depression of the T-celldependent antibody response in B6C3Fl mice. Polyclonal<br />

antibody responses were reduced 50 to 66% following benzo[u]pyrene (Blanton et al., 1986).<br />

3.3.3 Chronic Toxicity<br />

Information on the chronic toxicity of benzo[u]pyrene by other routes of exposure in humans or<br />

animals is not available.<br />

3.3.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.3.<strong>4.</strong>1 Human<br />

Information on the developmental or reproductive toxicity of benzo[u]pyrene by other routes of<br />

exposure in humans was not available.<br />

3.3.<strong>4.</strong>2 Animal<br />

Adverse developmental/reproductive effects were observed in several injection studies with<br />

benzo[u]pyrene. These studies are reviewed in an ATSDR report (1990). but experimental details were<br />

not provided. Intraperitoneal administration of benzo[u]pyrene to mice has resulted in stillbirths,<br />

resorptions, <strong>and</strong> malformations; decreases in follicular growth <strong>and</strong> corpora lutea; <strong>and</strong> testicular changes.<br />

Subcutaneous injections of benzo[u]pyrene produced increased resorptions in rats <strong>and</strong> direct embryonal<br />

injection led to decreased fetal survival in mice.


3.4 TARGET ORGANS/CRITICAL EFFECTS<br />

3.<strong>4.</strong>1 Oral Exposures<br />

3.<strong>4.</strong>1.1 Primary target organs<br />

6<br />

1. Hematopoietic system: Subchronic oral exposure produced bone marrow depression<br />

(aplastic anemia <strong>and</strong> pancytopenia) <strong>and</strong> ultimately death in "nonresponsive" mice.<br />

2. Reproductioddeveloprnent : Exposure during gestation of mice produced decreased<br />

gonadal weights, reduced fertility, <strong>and</strong> sterility in offspring. Stillbirths, resorptions, <strong>and</strong><br />

malformations were seen in "responsive" <strong>and</strong> "nonresponsive" mice; however, the<br />

incidence of these effects was higher in "nonresponsive" mice.<br />

3.<strong>4.</strong>1.2 Other target organs<br />

Other target organs for oral exposure have not been identified.<br />

3.<strong>4.</strong>2 Inhalation Exposures<br />

Target organs for inhalation exposure to benzo[u]pyrene have not been identified.<br />

3.<strong>4.</strong>3 Other Routes of Exposure<br />

3.<strong>4.</strong>3.1 Primary target Organs<br />

1. Immune system: Subcutaneous injections of benzo[a]pyrene administered over a 2-week period<br />

caused depressed antibody responses in mice.<br />

2. Reproductioddevelopment : Intraperitoneal injections of benzo[a]pyrene have resulted in<br />

stillbirths, resorptions, malformations, decreased follicular growth <strong>and</strong> corpora lutes, <strong>and</strong><br />

testicular changes in mice. Subcutaneous injections produced increased resorptions in rats.<br />

3.<strong>4.</strong>3.2 Other target organs<br />

Other target organs for other routes of exposure have not been identified.<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1 ORALEXPOSURES<br />

<strong>4.</strong>1.1 Human<br />

Information on the carcinogenicity of benzo[u]pyrene in humans following oral exposure is not<br />

available.


7<br />

<strong>4.</strong>1.2 Animal<br />

In a study by Brune et al. (1981), male <strong>and</strong> female Sprague-Dawley rats were fed 0.15 mg/kg every<br />

9th day or 5 timedweek for life. The incidence of tumors of the forestomach, esophagus, <strong>and</strong> larynx<br />

(combined) was 5% for controls <strong>and</strong> for rats fed benzo[u]pyrene every 9th day <strong>and</strong> 16% for rats fed<br />

benzo[u]pyrene 5 times/week. Administration of a single 50-mg dose of benzo[u]pyrene or of 8 weekly<br />

doses of 6.25 mg by gavage induced mammary tumors in LEWMai rats (McCormick et al., 1981). The<br />

incidence of mammary carcinomas after 90 weeks was 77% for the single exposure <strong>and</strong> 67% for the<br />

multiple exposures. Mammary tumors were observed in 30% of controls. Huggins <strong>and</strong> Yang (1962)<br />

reported that a single oral dose of 100 mg benzo[u]pyrene administered by gavage induced mammary<br />

tumors in 8/9 female Sprague-Dawley rats.<br />

Neal <strong>and</strong> Rigdon (1967) fed male <strong>and</strong> female CFW-Swiss mice a diet containing 1 to 250 ppm<br />

benzo[u]pyrene for up to 197 days. No tumors were found in the control group <strong>and</strong> in groups treated<br />

with 1, 10, or 30 ppm. However, forestomach papillomas <strong>and</strong> carcinomas developed at dietary<br />

concentrations of greater than or equal to 40 ppm. The authors indicated that the tumor incidence was<br />

related to both the concentration <strong>and</strong> the number of doses administered. Female mice administered 200<br />

or 300 ppm benzo[u]pyrene in the diet for a relatively short time (12 weeks) developed tumors of the<br />

forestomach (Triolo et al., 1977). Pulmonary adenomas developed in A/HeJ mice treated by gavage with<br />

two daily doses of 3 mg benzo[u]pyrene at 2-week intervals (Wattenberg <strong>and</strong> Leong, 1970). The<br />

pulmonary tumor count increased from 0.3 tumordmouse in controls to 16.6 tumors/mouse in the treated<br />

group at 30 weeks of age.<br />

<strong>4.</strong>2 INHALATION EXPOSURES<br />

<strong>4.</strong>2.1 Human<br />

Numerous epidemiologic studies have shown a clear association between inhalation exposure to<br />

various mixtures containing PAHs (e.g., coke oven emissions, roofing tar emissions, <strong>and</strong> cigarette smoke)<br />

<strong>and</strong> increased risk of lung cancer <strong>and</strong> other cancers. Each of these mixtures contained benzo[u]pyrene<br />

as well as other carcinogenic PAHs <strong>and</strong> other potentially carcinogenic chemicals; therefore, it is not<br />

possible to evaluate the contribution of benzo[u]pyrene to the carcinogenicity of these mixtures (IARC,<br />

1983; EPA, 1991).<br />

<strong>4.</strong>2.2 Animal<br />

Thyssen et al. (1981) exposed Syrian hamsters to benzo[u]pyrene at concentrations of 0, 2.2, 9.5,<br />

or 46.5 mg/m3, <strong>4.</strong>5 hours/day for 10 days <strong>and</strong> then 3 hours/day for up to 675 days. No treatment-related<br />

tumors were observed in hamsters exposed to 2.2 mg/m3 or in controls. Hamsters exposed to 9.5 mg/d<br />

developed papillomas <strong>and</strong> squamous cell carcinomas located primarily in the nasal cavity, larynx, trachea,<br />

<strong>and</strong> pharynx. In addition to respiratory tract tumors, hamsters exposed to the highest concentration also<br />

developed tumors of the upper digestive tract.<br />

Intratracheal administration of benzo[u]pyrene also induced neoplasms of the respiratory tract in<br />

male <strong>and</strong> female Syrian hamsters. Weekly intratracheal administration of benzo[u]pyrene (total doses<br />

18.2 or 36.4 mg/animal) for 52 weeks produced a doserelated increase of tracheal papillomadcarcinomas<br />

<strong>and</strong> lung adenomas. Similar effects were reported following weekly intratracheal administration of doses<br />

ranging from 0.1 to 1 mg up to 40 weeks, but the response was not clearly dose-related (Ketkar et al.,<br />

1978).


8<br />

<strong>4.</strong>3 OTHER ROUTES OF EXPOSURE<br />

<strong>4.</strong>3.1 Human<br />

Human tumorigenicity has been reported in a number of studies as a result of dermal exposure to<br />

complex mixtures of PAHs containing benzo[a]pyrene. An early report (Pott, 1775) described scrotal<br />

cancer in chimney sweeps. More recently, skin cancer has occurred in workers exposed to shale oil<br />

(Purde <strong>and</strong> Etlin, 1980) <strong>and</strong> creosote (Lenson, 1956). However, the contribution of benzo[u]pyrene to<br />

the carcinogenicity of these PAH mixtures is uncertain.<br />

In an experimental study, epidermal changes (erythema, pigmentation, <strong>and</strong> desquamation) were<br />

reported following daily applications of a 1 % solution of benzo[a]pyrene to the skin of humans over a<br />

4-month period. Although reversible <strong>and</strong> benign, these changes were thought to represent early stages<br />

of neoplastic proliferation (Cottini <strong>and</strong> Mazzone, 1939). It should be noted that benzo[a]pyrene was<br />

applied as a solution in benzene, <strong>and</strong> no benzene control was evaluated. Similar epithelial changes were<br />

reported in humans accidentally exposed to benzo[u]pyrene (EPA, 1984).<br />

<strong>4.</strong>3.2 Animal<br />

Benzo[a]pyrene is among the most potent <strong>and</strong> best documented skin carcinogens <strong>and</strong> is commonly<br />

used as a positive control in skin application assays of other chemicals. Benzo[a]pyrene has been shown<br />

to cause skin tumors in mice, rats, rabbits, <strong>and</strong> guinea pigs, although mice appear to be the most sensitive<br />

species. It is both an initiator <strong>and</strong> complete carcinogen in mouse skin (IARC, 1973; EPA, 1991).<br />

Wynder <strong>and</strong> Hoffmann (1959) applied 0.001, 0.005, or 0.01% benzo[a]pyrene in acetone to the<br />

backs of female Swiss mice three times weekly for life. For the three dose groups, the incidence of skin<br />

papillomas was 95, 100, or 85%. respectively, <strong>and</strong> the incidence of skin carcinomas was 4, 86, or 95%.<br />

respectively. Data for a solvent control group were not provided. In initiatiordpromotion experiments,<br />

Hoffmann <strong>and</strong> Wynder (1966) applied 10 doses of benzo[u]pyrene in dioxane (total dose 0.25 mg) every<br />

2 days to the skin of mice. This treatment was followed by application of 2.5% croton oil in acetone.<br />

Skin papillomas developed in 80% of treated animals <strong>and</strong>% 7% of controls (receiving croton oil alone).<br />

The modifying effects of solvents on the carcinogenicity of benzo[a]pyrene have been demonstrated<br />

in several studies. For example, Bingham <strong>and</strong> Falk (1969) treated C3H/He mice topically with different<br />

concentrations of benzo[alpyrene in either ndodecane or a ndodecaneldecalin mixture three times weekly<br />

for 50 weeks. When ndodecaneldecalin was used as a solvent, malignant skin tumors appeared in 5/24<br />

mice treated with 0.00002% benzo[u]pyrene, <strong>and</strong> the tumor incidence increased at higher concentrations.<br />

With decalin alone as a solvent, malignant skin tumors developed in 5/12 mice treated with 0.02%, but<br />

none were seen at lower concentrations. Other topical application studies with mice demonstrated<br />

synergistic effects of cigarette smoke condensates on skin tumor induction (IARC, 1973).<br />

Benzo[u]pyrene has been shown to produce tumors at various sites by other modes of<br />

administration. A 94% incidence of lung adenomas was reported in newborn mice injected i.p. with 280<br />

pg/mouse of benzo[a]pyrene (Busby et al., 1984). Newborn rats treated with a single i.p. injection of<br />

0.59 -01 benzo[u)pyrene/kg <strong>and</strong> observed for life developed hepatic tumors. The tumor incidence was<br />

37% for males <strong>and</strong> 57% for females (Peraino et al., 1984). Several studies reported injection site tumors<br />

in mice, rats, guinea pigs, hamsters, <strong>and</strong> some primates administered S.C. injections of benzo[a]pyrene<br />

@PA, 1994). In addition to injection site sarcomas, newborn mice administered benzo[u]pyrene by S.C.<br />

injection developed hepatomas or lung adenomas (EPA, 1991; IARC, 1973). Benzo[u]pyrene has also


9<br />

been reported to induce tumors when administered by the intravenous <strong>and</strong> transplacental route; by<br />

implantation in the stomach wall, renal parenchyma, <strong>and</strong> brain; by injection in the renal pelvis; <strong>and</strong> by<br />

vaginal painting ( EPA, 1994).<br />

<strong>4.</strong>4 EPA WEIGHT-OF-EVIDENCE<br />

Classification: B2, probable human carcinogen (EPA, 1994).<br />

Basis: Human data specifically linking benzo[a]pyrene to a carcinogenic effect are lacking,<br />

However, multiple animal studies in many species demonstrating benzo[a]pyrene to be<br />

carcinogenic by numerous routes exist (EPA, 1994).<br />

Note: The carcinogenicity risk assessment for benzo[a]pyrene may change in the future<br />

pending further review by EPA.<br />

<strong>4.</strong>5 CARCINOGENICITY SLOPE FACTORS<br />

<strong>4.</strong>5.1 Oral<br />

SLOPE FACTOR: 7.3E+O (mg/kg/day)-' (EPA, 1994)<br />

UNIT RISK: 2.1E4 (pg/L)-'<br />

PRINCIPAL STUDIES: Brune et al., 1981; Neal <strong>and</strong> Rigdon, 1967;<br />

Rabstein et al., 1973 (historical control data)<br />

COMMENT: The slope factor, the geometric mean of four calculated slope factors [range<br />

<strong>4.</strong>5E+O to 11.7E+O (mg/kg/day)-'I, was derived using multiple data sets from different studies<br />

employing more than one sex, strain, <strong>and</strong> species. EPA considered the data less than optimal but<br />

acceptable.<br />

<strong>4.</strong>5.2 Inhalation<br />

An inhalation slope factor has not been calculated.<br />

5. REFERENCES<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1990. Toxicological Profile for<br />

Benzo(u)pyrene. Prepared by ICF-Clement, under Contract No. 68424235. ATSDFUTP-88-05.<br />

Bmgham, E. <strong>and</strong> H.L. Falk. 1969. Environmental carcinogens. The modifying effect of cocarcinogens<br />

on the threshold response. Arch. Environ. Health 19: 779-783.<br />

Blanton, R.H., M. Lyte, M.J. Myers, <strong>and</strong> P.H. Bick. 1986. Immunomodulation by polyaromatic<br />

hydrocarbons in mice <strong>and</strong> murine cells. Cancer Res. 46: 2735-2739.


10<br />

Brune, H., R.P. Deutsch-Wenzel, M. Habs, et al. 1981. Investigation of the tumorigenic response to<br />

benzo(a)pyrene in aqueous caffeine solution applied orally to Sprague-Dawley rats. J. Cancer Res.<br />

Clin. Oncol. 102: 153-157.<br />

Budavari, S., M.J. O'Neil <strong>and</strong> A. Smith. 1989. The Merck Index. Merck & Co., Rahway, NJ, p. 172.<br />

Busby, W.F., Jr., M.E. Goldman, P.M. Newberne <strong>and</strong> G.N. Wogan. 198<strong>4.</strong> Tumorigenicity of<br />

fluoranthene in a newborn mouse lung adenoma bioassay. Carcinogenesis 5: 1311-1316.<br />

Chang, L.H. 1943. The fecal excretion of polycyclic hydrocarbons following their administration to the<br />

rat. J. Biol. chem. 151: 93-99. (Cited in EPA, 1984; EPA, 1991)<br />

Cottini, G.B. <strong>and</strong> G.B. Mazzone. 1939. The effects of 3,4:benzpyrene on human skin. Am. J. Cancer<br />

37: 186-195. (Cited in EPA, 1991)<br />

Ekwall, P., P. E da, K. Seda <strong>and</strong> L. Sjoblom. 1951. Gastric absorption of 3.4-benzpyrene. 11. The<br />

significance of the solvent for the penetration of 3.4-beqyrene into the stomach wall. Cancer Res.<br />

1 1 : 758-763.<br />

Ermala, P., K. SeWa <strong>and</strong> P. Ekwall. 1951. Gastric absorption of 3,4-benzpyrene. I. The effect of<br />

physiologic processes on absorption. Cancer Res. 11: 753-757.<br />

Heidelberger, C. <strong>and</strong> S.M. Weiss. 1951. The distribution of radioactivity in mice following<br />

administration of 3 ,4-benzpyrene-5-C1' <strong>and</strong> 1,2,5,6dibenZanthracene-9,10-@ . Cancer Res.<br />

11: 885-891.<br />

Hoffmann, D. <strong>and</strong> E.L. Wynder. 1966. [Beitrag zur wcinogenen Wirkung von Dibenzopyrenen.]<br />

Z. Krebsforsch. 68: 137-149.<br />

Huggins, C. <strong>and</strong> N.C. Yang. 1962. Induction <strong>and</strong> extinction of mammary cancer. Science 137: 257-<br />

262.<br />

IARC (International Agency for Research on Cancer). 1973. Benzo(a)pyrene. In: lARC Monographs<br />

on the Evaluation of Carcinogenic Risk of the chemical to Man. Certain Polycyclic Aromatic<br />

Hydrocarbons <strong>and</strong> Heterocyclic Compountls, Vol. 3. World Health Organization, Lyon, France,<br />

pp. 91-136.<br />

IARC (International Agency for Reseakh on Cancer). 1983. Benzo[a]pyrene. In: IARC Monographs<br />

on the Evaluation of Carcinogenic Risks to H um. Polynuclear Aromatic Compoundr. Part 1.<br />

Chemical, Environmental <strong>and</strong> Experimental Data, Vol. 32. World Health Organization, Lyon,<br />

France, pp. 33-22<strong>4.</strong><br />

Kao, J., F.K. Patterson <strong>and</strong> J. Hall. 1985. Skin penetration <strong>and</strong> metabolism of topically applied<br />

chemicals in six mammalian species, including man: An in vitro study with benzo[a]pyrene <strong>and</strong><br />

testosterone. Toxicol. Appl. Phannacol. 81: 502-516.<br />

Ketkar, M., G. Reznik, P. Schneider <strong>and</strong> U. Mohr. 1978. Investigations on the carcinogenic burden<br />

by air pollution in man. Intratracheal instillation studies with benzo[a]pyrene in bovine albumin in<br />

Syrian hamsters. Cancer Lett. 4: 235-239. .


Kroes, R; Van Logten, MJ.; Berkvins, J.M.; deVries, I.; van Esch, GJ. 197<strong>4.</strong> Study on the<br />

carcinogenicity of lead arsenate <strong>and</strong> sodium arsenate <strong>and</strong> the poSsible synergistic effect of<br />

diethylnitrosamine. Food Cosmet. Toxicol. 12:671-679.<br />

Kyle, R.A; Pease, G.L 1965. Hematologic aspects of arsenic intoxication. New Eng. J.<br />

Med. 273( 1):18-23.<br />

Lagerkvist, B.E.A; Linderholm, H.; Nordberg, G.F. 1986. Vasospastic tendency <strong>and</strong><br />

Raynaud's phenomenon in smelter workers exposed to arsenic. Environ. Res. 39465-47<strong>4.</strong><br />

Lagerkvist, B.E.A; Linderholm, I%; Nordberg, G.F. 1988. Arsenic <strong>and</strong> Raynaud's<br />

phenomenon. Vasospastic tendency <strong>and</strong> excretion of arsenic in smelter workers before <strong>and</strong><br />

after summer vacation. Int. Arch. Occup. Environ. Health 60:361-36<strong>4.</strong><br />

L<strong>and</strong>au, ED.; Thompson, DJ.; Feldman, R.G.; Goble, GJ.; Dixon, WJ. 1977. Selected<br />

Noncarcinogenic Effects of Industrial Exposure to Inorganic Arsenic. U.S. Environmental<br />

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27


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TOXICITY SUMMARY FOR<br />

BENZO[b]FLUORANTHENE<br />

May 1994<br />

Prepared by<br />

Rosmarie A. Faust, Ph.D.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy System, Inc., for the US. Department of Energy under<br />

Contract No. DE-AC05-840R21400


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EXECUTIVE SUMMARY<br />

Benzo[b]fluoranthene, a crystalline solid with a chemical formula of C&H,* <strong>and</strong> a molecular weight<br />

of 252.32 (Lide, 1991), is a polycyclic aromatic hydrocarbon (PAH) with one five-membered ring <strong>and</strong><br />

four six-membered rings. There is no commercial production or known use of this compound<br />

(IARC, 1983). Benzo[b]fluoranthene is found in fossil fuels <strong>and</strong> occurs ubiquitously in products of<br />

incomplete combustion. It has been detected in mainstream cigarette smoke; urban air; gasoline engine<br />

exhaust; emissions from burning coal <strong>and</strong> from oil-fired heating; broiled <strong>and</strong> smoked food; oils <strong>and</strong><br />

margarine (IARC, 1983); <strong>and</strong> in soils, groundwater, <strong>and</strong> surface waters at hazardous waste sites<br />

(ATSDR, 1990).<br />

No absorption data were available for benzo[b]fluoranthene; however, by analogy to structurallyrelated<br />

PAHs, primarily benzo[u]pyrene, it would be expected to be absorbed from the gastrointestinal<br />

tract, lungs, <strong>and</strong> skin (EPA, 1991). Major metabolites of benzo[b]fluoranthene formed in vitro in rat<br />

liver include dihydrodiols <strong>and</strong> monohydroxy derivatives (Amin et al., 1982) <strong>and</strong> monohydroxy derivatives<br />

in mouse epidermis (Geddie et al., 1987).<br />

No' data were found concerning the acute, subchronic, chronic, developmental, or reproductive<br />

toxicity of benzo[b]fluoranthene. No data were available for the derivation of an oral reference dose<br />

(RfJ3) or inhalation reference concentration (RfC) (EPA, 1994).<br />

No long-term oral or inhalation bioassays were available to assess the carcinogenicity of<br />

benzo[b]fluoranthene. Benzo[b]fluoranthene was tested for carcinogenicity in dermal application, lung<br />

implantation, subcutaneous (s.c.) injection, <strong>and</strong> intraperitoneal (i.p.) injection studies. Dermal<br />

applications of 0.01-0.5% solutions of benzo[b]fluoranthene for life produced a high incidence of skin<br />

papillomas <strong>and</strong> carcinomas in mice (Wynder <strong>and</strong> Hoffmann, 1959). In initiation-promotion assays, the<br />

compound was active as an initiator of skin carcinogenesis in mice (LaVoie et al., 1982; Amin<br />

et al., 1985). Sarcomas <strong>and</strong> carcinomas of the lungs <strong>and</strong> thorax were seen in rats receiving single lung<br />

implants of 0.1-1 mg benzo[b]fluoranthene (Deutsch-Wenzel et al., 1983). Newborn mice receiving<br />

0.5 pmol bem[b]fluoranthene via i.p. injection developed liver <strong>and</strong> lung tumors (LaVoie et al., 1987).<br />

<strong>and</strong> mice administered three S.C. injections of 0.6 mg benzo[b]fluoranthene developed injection site<br />

sarcomas (IARC, 1993).<br />

Based on no human data <strong>and</strong> sufficient evidence for Carcinogenicity in animals, EPA has assigned<br />

a weight-of-evidence classification of B2, probable human carcinogen, to benzo[b]fluoranthene<br />

(EPA, 1994).<br />

iii


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1. INTRODUCTION<br />

Benzo[b]fluoranthene (CAS Reg. No. 205-99-2), also known as benz(e)acephenanthrylene,<br />

3,4-benz(e)acephenanthrylene, 2,3-benzofluoranthene, 3,4-benzofluoranthene, <strong>and</strong> benzo(e)fluoranthene<br />

(IARC, 1983) is a polycyclic aromatic hydrocarbon (PAH) with one five-membered ring <strong>and</strong> four sixmembered<br />

rings. It is a crystalline solid with a chemical formula of t&H12, a molecular weight of<br />

252.32, <strong>and</strong> a melting point of 168°C (Lide, 1991). Benzo[b]fluoranthene is virtually insoluble in water<br />

<strong>and</strong> is slightly soluble in benzene <strong>and</strong> acetone (IARC, 1983). It has a vapor pressure of lo-'' to 106 torr<br />

at 20"C, an octanol/water partition coefficient of 1.1x106, <strong>and</strong> a Henry's Law constant of 1.22~10<br />

(ATSDR, 1990). There is no commercial production or known use of this compound (IARC, 1983).<br />

Benzo[b]fluoranthene is found in fossil fuels <strong>and</strong> occurs ubiquitously in products of incomplete<br />

combustion. It has been detected in mainstream cigarette smoke; urban air; gasoline engine exhaust;<br />

emissions from burning coal <strong>and</strong> from oil-fired heating; broiled <strong>and</strong> smoked food; oils <strong>and</strong> margarine<br />

(IARC, 1973); <strong>and</strong> in soils, groundwater, <strong>and</strong> surface waters at hazardous waste sites (ATSDR, 1990).<br />

Benzo[b]fluoranthene is one of a number of PAHs on the United States Environmental Protection<br />

Agency's (EPA's) priority pollutant list (ATSDR, 1990).<br />

2. METABOLISM AND DISPOSITION<br />

2.1 ABSORPTION<br />

Data regarding the gastrointestinal or pulmonary absorption of benzo[b]fluoranthene in humans or<br />

animals were not available. However, data from structurally-related PAHs, primarily benzo[a]pyrene,<br />

suggest that benzo[b]fluoranthene would be absorbed from the gastrointestinal tract, lungs, <strong>and</strong> skin<br />

(EPA, 1991).<br />

2.2 DISTRIBUTION<br />

No human or animal data were available concerning the tissue distribution of benzo[b]fluoranthene.<br />

2.3 METABOLISM<br />

Amin et al. (1982) investigated the in vitro metabolism of benzo[b]fluoranthene by rat liver<br />

microsomes <strong>and</strong> identified 5- <strong>and</strong> 6-hydroxybenzo[b]fluoranthene <strong>and</strong> 4- or<br />

7-hydroxybem[b]fluoranthene as major metabolites. The principal dihydrodiol metabolite formed was<br />

trm-1 1,12dihydro-l1,12dihydroxybenzo[b]fluoranthene. Geddie et al. (1987) investigated the<br />

metabolism of benzo[b]fluoranthene in mouse epidermis. Following dermal application of<br />

benzo[b]fluoranthene, 4-, 5-, <strong>and</strong> 6-hydroxybenzo[b]fluoranthene were identified as major metabolites.<br />

Sulfate <strong>and</strong> glucuronide conjugates of these hydroxy compounds were also detected.<br />

1


2<br />

2.4 EXCRETION<br />

No human or animal data were available concerning the excretion of benzo[b]fluoranthene.<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1 ORALEXPOSURES<br />

Information on the acute, subchronic, chronic, developmental, or reproductive oral toxicity of<br />

benzo[b]fluoranthene in humans or animals was not available. Because of a lack of toxicity data, an oral<br />

reference dose (RfD) for benzo[b]fluoranthene has not been derived (EPA, 1994).<br />

3.2 INHALATION EXPOSURES<br />

Information on the acute, subchronic, chronic, developmental, or reproductive toxicity of<br />

benzo[b]fluoranthene in humans or animals following inhalation exposure was not available. Because of<br />

a lack of toxicity data, an inhalation reference concentration (RfC) for benzo[b]fluoranthene has not been<br />

derived (EPA, 1994).<br />

3.3 OTHER ROUTES OF EXPOSURE<br />

Information on the acute, subchronic, chronic, developmental, or reproductive toxicity of<br />

benzo[b]fluoranthene in humans or animals by other routes of exposure was not available.<br />

3.4 TARGET ORGANS/CRITICAL EFFECTS<br />

No data were available to determine target organs/critical effects for oral, inhalation, or other routes<br />

of exposure to benzo[b]fluoranthene.<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1 ORALEXPOSURES<br />

Information on the carcinogenicity of benzo[b]fluoranthene in humans or animals following oral<br />

exposure was not available.


3<br />

<strong>4.</strong>2 INHALATION EXPOSURES<br />

<strong>4.</strong>2.1 Human<br />

Although there are no human data that specifically link exposure to benzo[b]fluoranthene to human<br />

cancers, benzo[b]fluoranthene is a component of mixtures that have been associated with human cancer.<br />

These mixtures include coal tar, soots, coke oven emissions, <strong>and</strong> cigarette smoke (EPA, 1994).<br />

<strong>4.</strong>2.2 Animal<br />

Information on the carcinogenicity of benzo[b]fluoranthene in animals following inhalation exposure<br />

was not available.<br />

<strong>4.</strong>3 OTHER ROUTES OF EXPOSURE<br />

<strong>4.</strong>3.1 Human<br />

Infodon on the carcinogenicity of benzo[b]fluoranthene in humans by other routes of exposure<br />

was not available.<br />

<strong>4.</strong>3.2 Animal<br />

Benzo[b]fluoranthene was tested for carcinogenicity in dermal application, lung implantation,<br />

subcutaneous (s.c.) injection, <strong>and</strong> intraperitoneal (i.p.) injection bioassays.<br />

Wynder <strong>and</strong> Hoffmann (1959) applied 0.01, 0.1, or 0.5% solutions of benzo[b]fluoranthene in<br />

acetone three times weekly to the skin of three groups of 20 Swiss mice for life; there were no untreated<br />

or vehicle controls. The highest dose produced skin papillomas in 100% <strong>and</strong> carcinomas in 90% of<br />

treated mice within 8 months; the intermediate dose produced papillomas in 65% <strong>and</strong> carcinomas in 85%<br />

of treated mice within 12 months. Of 10 surviving mice that received the lowest dose, only one animal<br />

developed a papilloma after 14 months.<br />

A single dermal application of 1 mg benzo[b]fluoranthene in acetone produced no tumors in 20<br />

Swiss mice during a 63-week observation period (Van Duuren et al., 1966). However, the same protocol<br />

followed by repeated applications of croton resin produced papillomas in 18/20 <strong>and</strong> carcinomas in 5/20<br />

treated mice.<br />

LaVoie et al. (1982) evaluated the tumor-initiating activity of benzo[b]fluoranthene by applying<br />

initiation doses of 0, 10, 30, or 100 pg benzo[b]fluoranthene in acetone (10 doses, every other day) to<br />

the skin of Cr1:CD-1 mice (20/group). This procedure was followed by treatment with 12-0-<br />

tetradecanoyl-phorbol-13-acetate (TPA), 3 times weekly for 20 weeks. There was a dose-related<br />

increased incidence of skin tumors, predominantly squamous cell papillomas. Skin tumors were seen in<br />

0, 45, 60, <strong>and</strong> 80% of mice treated with 0, 10, 30, or 100 pg bem[b]fluoranthene, respectively. A<br />

similar initiatiodprotowl by Amin et al. (1985) resulted in a comparable increased incidence of skin<br />

tumors in female Swiss albino mice.


4<br />

Sixteen male <strong>and</strong> 14 female XW nc/Z mice were given three S.C. injections of 0.6 mg<br />

benzo[b]fluoranthene in olive oil over a period of 2 months (IARC, 1973). Injection site sarcomas<br />

developed in 18/24 surviving mice, with an average latent period of <strong>4.</strong>5 months.<br />

Female Osborne-Mendel rats (35/group) received single lung implants of 0.1, 0.3, or 1 mg<br />

benzo[b]fluoranthene in a mixture of beeswax <strong>and</strong> trioctanoin (Deutsch-Wemi et al., 1983). An<br />

untreated group <strong>and</strong> a group receiving the vehicle served as controls. Granulomatous inflammatory<br />

lesions developed at the injection sites. After a lifetime of observation, there was a dose-related increased<br />

incidence of epidermoid carcinomas <strong>and</strong> pleomorphic sarcomas in the lung <strong>and</strong> thorax (combined). The<br />

observed incidences were 1/35, 3/35, <strong>and</strong> 13/35, respectively, in the low-, mid-, <strong>and</strong> highdose groups.<br />

No lung tumors were reported in untreated <strong>and</strong> vehicle controls. In contrast, multiple intratracheal<br />

instillations of benzo[b]fluoranthene, administered as 30 weekly doses of 0.05 or 0.5 mg, did not induce<br />

a significant number of respiratory tract tumors in male Syrian golden hamsters (Sellakumar <strong>and</strong> Shubik,<br />

1974). The group receiving the higher dose had one papilloma of the trachea at week 99.<br />

LaVoie et al. (1987) administered i.p. injections of benzo[b]fluoranthene in dimethyl sulfoxide to<br />

newborn CD-1 mice (15 males <strong>and</strong> 17 females) on days 1, 8, <strong>and</strong> 15 of age at a total dose of<br />

0.5 pmol/mouse. The animals were sacrificed at 52 weeks of age. Treatment with benzo[b]fluoranthene<br />

induced hepatic tumors (adenomas <strong>and</strong> hepatomas combined) in eight male mice. One hepatoma<br />

developed in 1/17 male controls; no hepatic tumors were seen in female treated mice or in female<br />

controls. Lung adenomas were found in two male <strong>and</strong> in three female mice; no lung tumors occurred<br />

in controls.<br />

<strong>4.</strong>4 EPA WEIGHT OF EVIDENCE<br />

Classification-B2; probable human carcinogen (EPA, 1994)<br />

Basis-Based on no human data <strong>and</strong> sufficient data from animal bioassays.<br />

Benzo[b]fluoranthene produced tumors in mice after lung implantation, i.p. or S.C. injection, or skin<br />

painting.<br />

<strong>4.</strong>5 CARCINOGENICITY SLOPE FACTORS<br />

No carcinogenicity slope factors were calculated.<br />

5.- REFERENCES<br />

Amin, S., E.J. LaVoie, <strong>and</strong> S.S. Hecht. 1982. "Identification of metabolites of benzo[b]fluoranthene."<br />

Carcinogenesis 3: 171-17<strong>4.</strong><br />

Amin, S., K. Huie, <strong>and</strong> S.S. Hecht. 1985. "Mutagenicity <strong>and</strong> tumor initiating activity of methylated<br />

benzo[b]fluoranthene. " Carcinogenesis 6: 1023-1025.


5<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1990. Toxicological Profile for Polycyclic<br />

Aromatic Hydrocarbons. Acenaphthene, Acenaphthylene, Anthracene, Benzo(a)anthracene,<br />

Benzo (a)pyrene, Benzo(h)jluoranthene, Benzo (g, i, h)perylene, Benzo (k)jluoranthene, Chrysene,<br />

Dibmo (a, h)anthracene, Fluoranthene, Fluorene, Zndeno (1,2,3-c, d)pyrene, Phenanthrene, Pyrene.<br />

Prepared by Clement International Corporation, under Contract No. 205-88-0608. ATSDWTP-90-<br />

20.<br />

Deutsch-Wenzel, R.P., H. Brune, G. Grimmer, et al. 1983. "Experimental studies in rat lungs on the<br />

carcinogenicity <strong>and</strong> dose-response relationships of eight frequently occurring environmental<br />

polycyclic aromatic hydrocarbons. J. Natl. Cancer Znst. 71 : 539-54<strong>4.</strong><br />

Geddie, J.E., S. Amin, K. Hui, et al. 1987. "Formation <strong>and</strong> tumorigenicity of benzo[b]fluoranthene<br />

metabolites in mouse epidermis. I' Carcinogenesis 8: 1579-158<strong>4.</strong><br />

IARC (International Agency for Research on Cancer). 1973. "Benzo[b]fluoranthene." In: LARC<br />

Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Certain Polycyclic<br />

Aromatic Hydrocarbons <strong>and</strong> Heterocyclic Compounds, Vol3. Lyon, France, pp. 69-81.<br />

IARC (International Agency for Research on Cancer). 1983. "Benzo[b]fluoranthene." In: LQRC<br />

Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans. Polycyclic Aromatic<br />

Compo&, Part 1, Chemid, Environmental <strong>and</strong> Experimental Data, Vo132. Lyon, France, pp.<br />

33-91, 147-153.<br />

LaVoie, E.J., S. Amin, S.S. Hecht, et al. 1982. "Tumor initiating activity of dihydrodiols of<br />

benzo[b]fluoranthene, benzoljlfluoranthene, <strong>and</strong> benzo[k]fluoranthene. I' Carcinogenesis 3 : 49-52.<br />

LaVoie, E.J., J. Braley, J.E. Rice, et al. 1987. "Tumorigenic activity for non-alternant polynuclear<br />

aromatic hydrocarbons in newborn mice." Cancer Lett. 34: 15-20.<br />

Lide, D.R., Ed. 1991. CRC H<strong>and</strong>book of Chemistry <strong>and</strong> Physics, 1991-1992. 72nd ed. Boca Raton,<br />

FL, p. 3-96.<br />

Sellakumar, A. <strong>and</strong> P. Shubik. 197<strong>4.</strong> "Carcinogenicity of different polycyclic hydrocarbons in the<br />

respiratory tract of hamsters." J. Natl. Cancer Znst. 53: 1713-1719.<br />

United States Environmental Protection Agency (EPA). 1991. Drinking Water Criteria Document for<br />

Polycyclic Aromatic Hydrocarbonr (PM). Prepared by the Environmental Criteria <strong>and</strong> Assessment<br />

Office, Office of Health <strong>and</strong> Environmental Assessment, U.S. Environmental Protection Agency,<br />

Cincinnati, OH, for the Office of Drinking Water. ECAO-CIN-DO10.<br />

United States Environmental Protection Agency (EPA). 199<strong>4.</strong> Integrated Risk Information System<br />

(IRIS). Environmental Criteria <strong>and</strong> Assessment Office, Office of Health <strong>and</strong> Environmental<br />

Assessment, Cincinnati, OH.


6<br />

Van Duuren, B.L., A. Sivak, A. Segal, et al. 1966. "The tumor-promoting agents of tobacco leaf <strong>and</strong><br />

tobacco smoke condensate." J. Nutl. Cancer Inst. 37: 519 -526.<br />

Wynder, E.L. <strong>and</strong> D. Hoffmann. 1959. "The carcinogenicity of benzofluoranthenes." Cancer 12:<br />

1194-1 199.


TOXICITYSUMMARY FOR<br />

BERYLLIUM<br />

April, 1992<br />

Prepared by:<br />

Mary Lou Daugherty, M.S.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division*<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of<br />

Energy under Contract No. DE-AC05-840R21400


Thir page intentionally lefi blank


EXECUTIVESUMMARY<br />

Beryllium is present in the earth's crust, in emissions from coal combustion, in surface<br />

water <strong>and</strong> soil, <strong>and</strong> in house dust, food, drinking water, <strong>and</strong> cigarette smoke (U.S. EPA,<br />

1987a). However, the highest risk for exposure occurs among workers employed in beryllium<br />

manufacturing, fabricating, or reclamation industries (ATSDR, 1988). Workers encounter<br />

dusts <strong>and</strong> fumes of many different beryllium compounds; the current occupational st<strong>and</strong>ard<br />

for worker cxposure to beryllium is 2 ram3 during an 8-hour workshift (OSHA, 1989).<br />

Inhaled beryllium is absorbed slowly <strong>and</strong> localizes mainly in the lungs, bone, liver <strong>and</strong><br />

kidneys (Stiefel et aL, 1980, Reeves et aL, 1%7; Reeves <strong>and</strong> Vorwald, 1%7; Zorn et al., 1988;<br />

Tepper et aL, 1961; Meehan <strong>and</strong> Smyth, 1967). Ingested beryllium undergoes limited<br />

absorption <strong>and</strong> localizes in liver, kidneys, lungs, stomach, spleen <strong>and</strong> the large <strong>and</strong> small<br />

intestines (Crowley et al., 1949 Furchner et aL, 1973; Watanabe et al., 1985). Significant<br />

absorption of beryllium or its compounds through intact skin is unlikely because of its<br />

chemical properties (U.S. EPA. 1987b). Beryllium per se is not biotransformed, but soluble<br />

salts may be converted to less soluble compounds in the lung (U.S. EPA, 198%). Most orally<br />

administered beryllium passes through the gastrointestinal tract unabsorbed <strong>and</strong> is excreted<br />

in the feces (Reeves, 1%5), whereas inhaled water-soluble beryllium salts are excreted mainly<br />

by the kidneys (Zorn et aL, 1988).<br />

Limited data indicate that the oral toxicity of beryllium is low. No adverse effects<br />

were noted in mice given 5 ppm beryllium in the drinking water in a lifetime bioassay<br />

(Schroeder <strong>and</strong> Mitchener, 1975a,b). The dose (converted to 0.54 mag bw/day) was the noadverseeffect<br />

level (NOAEL) used in the calculation of the chronic oral RfD for beryllium<br />

of 0.005 madday (U.S. EPA, 1991a).<br />

In contrast, the toxicity of inhaled beryllium is welldocumented. Humans inhaling<br />

"massive" doses of beryllium compounds (such as the water soluble sulfate, fluoride, chloride,<br />

<strong>and</strong> oxide) may develop acute berylliosis (Constantinidis, 1978). ATSDR (1988) estimated<br />

that, based on existing data, the disease could develop at levels ranging from approximately<br />

2-1000 pg Be/m3. This disease usually develops shortly after exposure <strong>and</strong> is characterizcd<br />

by rhinitis, pharyngitis, <strong>and</strong>/or tracheobronchitis, <strong>and</strong> may progress to severe pulmonary<br />

symptoms. The severity of acute beryllium toxicity correlates with exposure levels, <strong>and</strong> the<br />

disease is now rarely observed in the United States because of improved industrial hygiene<br />

(Zorn et aL, 1988, Kriebel et al., 1988b).<br />

Humans inhaling beryllium may also develop chronic berylliosis which, in contrast to<br />

acute berylliosis, is highly variable in onset, is more likely to be fatal, <strong>and</strong> can develop a few<br />

months to 220 years after exposure (Constantinidis, 1978 Hall et al., 1959; Kriebel et aL,<br />

1988b). Chronic beryllium disease is a systemic disease that primarily affects the lungs <strong>and</strong><br />

is characterized by the development of noneseating granulomas. Tbe disease most likely<br />

results' from a hypersensitivity response to beryllium as evidenced by positive patch tests<br />

(Nishimura, 1966) <strong>and</strong> positive lymphocyte transformation tests (Williams <strong>and</strong> Williams (1983)<br />

in exposed individuals. Granulomas may also appear in the skin, liver, spleen, lymph nodes,<br />

myocardium, skeletal muscles, kidney, bone, <strong>and</strong> salivary gl<strong>and</strong>s (Kriebel et aL, 1988b;<br />

Freiman <strong>and</strong> Hardy, 1970).<br />

-<br />

1


Epidemiologic studies have suggested that beryllium <strong>and</strong> its compounds could be<br />

human carcinogens. In a study that covered 15 regions of the U.S.,Berg <strong>and</strong> Burbank (1972)<br />

found a significant correlation between cancers of the breast, bone <strong>and</strong> uterus <strong>and</strong> the<br />

concentration <strong>and</strong> detection frequency of beryllium in drinking water. However, imperfect<br />

analytical <strong>and</strong> sampling methods used in the study prompted the US. EPA (1986b) to<br />

conclude that these results are not proof of cause <strong>and</strong> effect relationships between cancer <strong>and</strong><br />

beryllium in drinking water. Studies in workers exposed to beryllium, mostly via inhalation,<br />

have shown significant increases in observed Over expected lung cancer incidences (Bayliss<br />

et al., 1971; Bayliss <strong>and</strong> Lainhart, 1972, Bayliss <strong>and</strong> Wagoner, 19n, Wagoner et aL, 1980,<br />

Mancuso, 1970; 1979; 1980). The U.S. EPA (1986a), in evaluating the total database for the<br />

association of lung cancer with occupational exposure to beryllium, noted several limitations,<br />

but concluded that the results must be considered to be at least suggestive of a carcinogenic<br />

risk to humans. In laboratory studies, beryllium sulfate caused increased incidences of<br />

pulmonary tumors in rats <strong>and</strong> rhesus monkeys (Vonvald, 1953,1%2 1968, Vomld et aL,<br />

1955, 1966, Schepers et aL, 1957; Reeves <strong>and</strong> Deitch, 1969).<br />

Based on sufficient evidence for animals <strong>and</strong> inadequate! evidence for humans,<br />

beryllium has been plad in the EPA weight-ofevidence classification B2, probable human<br />

carcinogen (U.S. EPA, 1991a). For inhalation exposure, the unit risk value is 24E-3 ( pg/m3)'<br />

*, <strong>and</strong> the slope factor is 8.4 (mg/kg/day)'' (U.S. EPA, 1991b). For oral exposure, the unit risk<br />

value is 1.2E-4 (pg/L)" <strong>and</strong> the slope factor is <strong>4.</strong>3 (mg/kg/day)" (U.S. EPA, 1991a).<br />

2


1. INTRODUCIION<br />

Beryllium (Be), a metallic element, belongs to Group IIA of the periodic table <strong>and</strong><br />

has an atomic weight of 9.012 <strong>and</strong> an oxidation state of +2 (U.S. EPA, 1987a; Budavari et<br />

al., 1989). Beryllium occurs naturally in the earth's crust at concentrations ranging from 2-10<br />

ppm. It is also released into the atmosphere from coal combustion at concentrations of -0.01-<br />

0.1 ng/m3, most likely as beryllium oxide (U.S. EPA, 1987a). Beryllium occurs in house dust<br />

(0.05-0.1 pg/g), surface water (0.01-1.0 ng/g), <strong>and</strong> soil (03<strong>4.</strong>0 pg/g) (U.S. EPA, 1987a). Total<br />

daily intake values for beryllium in the general population are estimated at 1.6 ng/day in air,<br />

120 ng in food, <strong>and</strong> 285 ng in water (U.S. EPA, 198%). In addition, a smoker of one pack<br />

of cigarettes/day could inhale up to 700 ng of beryllium, depending on the type of tobacco<br />

used (U.S. EPA, 198%).<br />

Currently, beryllium has many industrial uses (e.g., in brake systems of airplanes, for<br />

neutron monochromatization, as window material for x-ray tubes, <strong>and</strong> in radiation detectors)<br />

(Zorn et al., 1988). The commercially important compound, beryllium oxide, is used in the<br />

electronics industry as a substrate for transistors <strong>and</strong> silicon chips, coil cores, <strong>and</strong> laser tubes<br />

(Zorn et ai., 1988).<br />

Although beryllium ore is relatively nontoxic, all other commercially important<br />

beryllium compounds exhibit significant pulmonary toxicity (ATSDR, 1988). Individuals<br />

employed in beryllium manufacturing, fabricating, or reclaiming industries are at highest risk<br />

for exposure <strong>and</strong> may encounter dusts <strong>and</strong> fumes of many different beryllium compounds.<br />

The current occupational st<strong>and</strong>ard for worker exposure to beryllium is 2 pg/m3 Over an &hour<br />

workshift (OSHA, 1989). The U.S.EPA (1987b) reports that new cases of chronic beryllium<br />

disease are surfacing in industries where the OSHA st<strong>and</strong>ard is exceeded, but that few cases<br />

have been reported where levels do not exceed<br />

-<br />

2 pg/m3.<br />

2 -METABOLISM AND DISPOSITION<br />

21. ABSORPTION<br />

The gastrointestinal absorption of beryllium <strong>and</strong> its compounds is limited; instead,<br />

these compounds form insoluble precipitates at about pH 7 (Zorn et al., 1988) <strong>and</strong> pass out<br />

of the g.i tract unabsorbed (Reeves, 1965; Furchner et aL, 1973). Two studies in which<br />

beryllium was given orally to animals as 'Be in single or repeated doses demonstrated that<br />

< 1% of the administered beryllium was absorbed (Crowley et aL, 1949; Furchner et aL, 1973).<br />

In another study, rats given beryllium sulfate (6.6 or 66.6 pg berylliudday) in drinking water<br />

for up to 24 weeks eliminated 6040% in the feces, suggesting at first that significant<br />

absorption had taken place; however, further analysis of the recovery data revealed that the<br />

metal was probably precipitated as the phosphate <strong>and</strong> was not available for absorption<br />

(Reeves, I=).<br />

The small amount of gastrointestinal absorption of beryllium that does occur depends<br />

on the specific compound administered. In hamsters, the absorption of soluble beryllium<br />

3


sulfate from the g.i. tract exceeded that of insoluble beryllium oxide <strong>and</strong> beryllium metal<br />

(Watanabe et aL, 1985); <strong>and</strong> in rats, the absorption of beryllium oxide exceeded that of the<br />

hydroxide, <strong>and</strong> the absorption of beryllium fluoride exceeded that of the chloride, sulfate,<br />

nitrate, <strong>and</strong> hydroxide (Bugryshev et al., 1984). Reeves (1%5) concluded from his studies<br />

that most of the beryllium found in the body was absorbed from the stomach at pH values<br />

(3.0-3.6 in the rat) that are favorable for maintaining beryllium salts in their ionized <strong>and</strong><br />

soluble form.<br />

Beryllium is slowly absorbed <strong>and</strong> retained by the lungs (Stiefel et al., 1980, Reeves et<br />

al., 1967; Reeves <strong>and</strong> Vonvald, 1967; Zom et aL, 1988). In one study, rats <strong>and</strong> guinea pigs<br />

were exposed for 3 hours to beryllium sulfate aerosol containing 7Be added as the chloride<br />

(Zorn et aL, 1977). Of the


demonstrated that urinary beryllium levels for rats fed beryllium sulfate doses of 5,50, or 500<br />

mgkg for 2-years were proportional to intake (Morgareidge et al.; 1977).<br />

Inhaled water-soluble beryllium salts are excreted mainly by the kidneys, with a halflife<br />

of 2-8 week (Zorn et al., 1988). Stiefel et al. (1980) found increased levels of beryllium<br />

in the urine of cigarette smokers (2 pg/L compared with 0.9 pg/L, normal level); in animals,<br />

urinary elimination of beryllium peaked at 300 ng/g 10 hours after exposure ended. Stress,<br />

such as that brought on by pregnancy or major surgery, may mobilize beryllium in the body,<br />

<strong>and</strong> excretion of the metal in the urine may continue for years. Thus, urinary concentrations<br />

of beryllium at any point in time reflect only the amount released, <strong>and</strong> not the total body<br />

burden (Parka, 1984).<br />

Beryllium particles are cleared slowly from the lungs. S<strong>and</strong>ers et al. (1975) measured<br />

the clearance of beryllium oxide in rats <strong>and</strong> hamsters. Females of both species had slower<br />

clearance than did males. Reeves <strong>and</strong> Vorwald (1967) made similar observations in rats<br />

exposed to beryllium sulfate, <strong>and</strong> reported that the clearance half-time exceeded 63 days.<br />

Rhoads <strong>and</strong> S<strong>and</strong>ers (1985) reported that the half-time for removal of 50% of the initial lung<br />

burden of beryllium, foIlowing up to 3 hours of exposure to the metal, was 400 days.<br />

3. NONCARCINOGENIC HEALTH EFFEcrs<br />

3.1. ORALEXPOSURES<br />

3.1.1. Acute Toxicity<br />

3.1.1.1. Human<br />

Information on the acute toxicity of beryllium following oral exposure to humans was<br />

unavailable.<br />

3.1.12 Animal<br />

Acute oral LDso values for beryllium range from 18 mg Bekg as beryllium fluoride<br />

in the mouse to 200 mg Bekg as beryllium chloride in the rat (Reeves, 1986).<br />

3.12 SubchronicToxicity<br />

Information on the subchronic toxicity of beryllium following oral exposure to humans<br />

<strong>and</strong> animals was unavailable.<br />

3.13. ChronicToJdcity<br />

3.13.1. Human<br />

Information on the chronic toxicity of beryllium following oral exposure to humans<br />

was unavailable.<br />

5


3.13.2. Animal<br />

In early studies, chronic feeding of large doses of beryllium carbonate (0.1-OS%, 1-5<br />

gkg of food) to young animals produced rickets (Guyatt et al., 1933; Jacobson, 1933; Kay <strong>and</strong><br />

Skill, 1934). This effect was thought to be the result of the binding of phosphate to beryllium<br />

in the gut <strong>and</strong> the subsequent depletion of phosphorus in the body. In a two-year feeding<br />

study, rats were given dietary levels of 5, 50, or 5000 ppm beryllium (as beryllium sulfate)<br />

(Morgareidge et al., 1977). Animals of the 5000 ppm group (5 gkg of food) had slightly<br />

decreased body weights. U.S. EPA (1991a) indicates that an unpublished dietary study by Cox<br />

et al. (1975) provided a NOEL of 25 mgAcg/day for beryllium.<br />

Groups of approximately 50 male <strong>and</strong> female Long-Evans rats <strong>and</strong> Swiss mice received<br />

drinking water containing 5 pprn beryllium sulfate for life (Schroeder <strong>and</strong> Mitchener,<br />

1975a,b). Body weights were measured throughout the study, <strong>and</strong> at the time of death, the<br />

animals were dissected <strong>and</strong> gross pathology recorded. Blood <strong>and</strong> urine samples were taken<br />

from the rats only. A slight depression in growth rate was observed for male rats at 2-6<br />

months of age <strong>and</strong> glucose was detected in the urine of the female rats (p


COMMENTS: The NOEL was based on no effects in rats in a lifetime bioassay.<br />

The uncertainty factor of 100 reflects a factor of 10 each for interspecies conversion<br />

<strong>and</strong> for the protection of sensitive human subpopulations. The RfD is limited to<br />

soluble beryllium salts.<br />

3.2 INHALATIONEXPOSURES<br />

321. AcuteToxicity<br />

321.1. Human<br />

Acute beryllium diseases in humans result from the inhalation of high concentrations<br />

of highly dispersed forms of beryllium or its compounds (Zorn et al., 1988). Individuals<br />

inhaling massive doses of beryllium compounds (such as the water soluble sulfate, fluoride,<br />

chloride, <strong>and</strong> oxide) may develop acute berylliosis (Constantinidis, 1978). This disease usually<br />

develops shortly after exposure <strong>and</strong> is characterized by rhinitis, pharyngitis, <strong>and</strong>/or<br />

tracheobronchitis, <strong>and</strong> may progress to severe pulmonary disease. The severity of acute<br />

beryllium toxicity correlates with exposure levels (Zorn et al., 1988). Brief exposure to<br />

kncentrations of beryllium in air above 100 pg/m3, may cause acute pneumonitis<br />

characterized by shortness of breath, malaise, anorexia, weight loss, coughing, cyanosis,<br />

tachypnea <strong>and</strong> tachycardia (U.S. EPA, 1987, Eisenbud et al., 1948). Lung volumes arc<br />

reduced <strong>and</strong> diffuse or localized infiltrates are seen on the chest x-ray (Kriebel et aL, 1988b).<br />

Although some cases of acute beryllium disease are fatal, most are resolved within a few<br />

months (Dutra, 1948). Sprince et ai. (1983) reported that 17% of a group of patients with<br />

the acute disease developed chronic disease in 10 or more years. Acute beryllium diseasc is<br />

now rarely observed in the United States because of improved industrial hygiene (Kxiebel ct<br />

aL, 1988b).<br />

3.212 Animal<br />

LC, values for beryllium were not found in the available literature. In rats, the lethal<br />

dose for acute inhalation of beryllium sulfate was 10 mg of the salt/m3 6 hours/day for 5 days<br />

(Stiefel et al., 1980).<br />

Brief exposures to beryllium can result in long-term effects. In a pulmonary toxicity<br />

study, male rats were exposed for one hour in a nose only chamber to an aerosol of <strong>4.</strong>05 )rg<br />

of Be& (as beryllium sulfate) <strong>and</strong> were examined for toxicity for a year after exposwe<br />

(Sendelbach et ai., 1989). Parameters for lung toxicity included bronchoahmlar lavage, lung<br />

cell kinetics, <strong>and</strong> histopathologic analysis. The activities of alkaline phosphatase (Ak Pase),<br />

acid phosphatase (Ac Pase), <strong>and</strong> lactate dehydrogenase (LDH) in lavage fluids were elevated<br />

3 web after exposure; Alk Pase <strong>and</strong> LDH levels peaked 3 months after. Microscopic<br />

examination revealed progressive focal interstitial pneumonitis with a prominent ahmlar<br />

compdnent of heteromorphic macrophages, neutrophils, <strong>and</strong> debris.<br />

In a similar study, higher concentrations of beryllium (800 pg Be metal/m3 for 50<br />

initial lung burden, 625 pg) caused severe, acute chemical pneumonitis that is followed by a<br />

7'


quiescent period of minimal inflammation <strong>and</strong> mild fibrosis (Haley et al., 1990). Progressive,<br />

chronic-active, fibrosing pneumonitis appeared later.<br />

3221. Human<br />

Information on the subchronic toxicity of beryllium following inhalation exposure to<br />

humans was unavailable.<br />

The respiratory tract is the target for the subchronic inhalation toxicity of beryllium.<br />

Schepers et aL (1957) exposed 115 male <strong>and</strong> female Sherman <strong>and</strong> Wistar rats to 35 pg/m3 of<br />

beryllium (as beryllium sulfate) 8 hours/day, 5 dap/week <strong>and</strong> 4 houdday 1 dayhek for 180<br />

days. During exposure, 46 exposed rats died from a bacterial infection that affected the heart<br />

<strong>and</strong> lungs. At the end of exposure, 17 rats were sacrificed <strong>and</strong> examined for pdmonary<br />

effects. Foam-cell clusters, infiltration of macrophages, lobular septalceU proliferation <strong>and</strong><br />

peribronchial <strong>and</strong> alveolar-wall epithelialization were observed in the treated animals.<br />

Untreated controls had none of these effects. Fifty-tM, of the exposed rats were maintained<br />

in beryllium-free air for up to 18 months. These animals demonstrated a progressiwz increase<br />

in the frequency of pulmonary changes that included atrophic-vesicular emphysema <strong>and</strong><br />

metaplasia of the bronchial epithelium.<br />

A dose-response for pulmonary effects was suggested in a study of rats exposed to<br />

beryllium sulfate aerosol 7 houdday for 1-560 days (Vorwald et al., 1966). The animals<br />

exhibited no speciEc inflammatory abnormalities at an aerosol concentration of 28 pg/m3,<br />

significant inflammatory changes at 21 pg/m3, chronic pneumonitis at 42 pg/m3, <strong>and</strong> acute<br />

berylliosis at 194 pg/m3. Durations of exposure associated with these effects were not clear.<br />

Tumors developed in animals in both of the above studies: these are discussed in<br />

<strong>Section</strong> <strong>4.</strong><br />

33.1. Human<br />

Humans inhaling beryllium may develop chronic berylliosis which, in contrast to acute<br />

berylliosis, is highly variable in onset <strong>and</strong> can develop a few months to a years after<br />

exposure (Constantinidis, 1978 Ktiebel et aL, 1988b). Exposure lasting for months to years<br />

is essential for the development of the disease (Kriebel et al., 1988b).<br />

The risk of disease, estimated at 1 to 10% (Eisenbud <strong>and</strong> Lisson, 1983). is probably<br />

related to both the’ magnitude of the exposure <strong>and</strong> the type of beryllium compound. The<br />

more soluble compounds apparently cause the acute disease; whereas, the less soluble<br />

compounds ax more likely to be associated with the chronic disease (Machle et al., 1948).<br />

This suggests that the risks are now much lower as a result of the increased effectiveness of<br />

current occupational <strong>and</strong> environmental controls (Kriebel et ai., 1988b). In at least one<br />

8


exception to this. five workers developed lung granulomas after working in an area where<br />

beryllium fume concentrations were consistently


3 3 2 Animal<br />

Rats exposed 7 hourslday, 5 daysheek for 72 weeks to 34 pg/m3 of beryllium (as<br />

beryllium sulfate) had increased lung weights <strong>and</strong> inflammatory <strong>and</strong> proliferative changes <strong>and</strong><br />

clusters of macrophages in the alveolar spaces (Reeves et al., 1967).<br />

See also the section on subchronic exposure, inhalation effects (3-2.2.2).<br />

3.2<strong>4.</strong> Developmental <strong>and</strong> ReprodudiveTmkity<br />

Information on the developmentaVreproductive toxicity of beryllium following<br />

inhalation exposure to humans <strong>and</strong> animals was unavailable.<br />

3-3. Referenoe Concentration<br />

A subchronic or chronic reference concentration for beryllium was not available.<br />

33. OTHER ROUTES OF ExposuRE<br />

33.1. AarteTOaidty<br />

33.1.1. Human<br />

Beryllium is a direct irritant <strong>and</strong> may cause edema <strong>and</strong> inflammation of any contacted<br />

tissue (Kriebel et al., 1988b). The eyes <strong>and</strong> skin are common targets of the acute imtant<br />

effects of beryllium (Kriebel et al., 1988b). Cutaneous injuries from beryllium metal, alloys,<br />

or oxide may require surgical excision of the foreign substance to promote h&g (Zorn et<br />

al., 1988). In addition to primary dermatitis, beryllium may sensitize the skin to subsequent<br />

contact with the metal. Dermatitis usually abates after exposure stops, but ulceration can<br />

result from particles retained in the skin (Kriebel et aL, 198%).<br />

33.12 Animal<br />

Information on the acute toxicity of beryllium following exposure to animals by other<br />

routes was unavailable.<br />

Information on the subchronic toxicity of beryllium following exposure to humans or<br />

animals by other routes was unavailable.<br />

333. (=bonicToxicity<br />

333.1. Human '<br />

Chronic dermal contact by beryllium <strong>and</strong> its compounds may result in skin sensitization<br />

<strong>and</strong> contact dermatitis in predisposed persons (Zorn et al., 1988).<br />

10


333.2 Animal<br />

Information on the chronic toxicity of beryllium following exposure to animals by<br />

other routes was unavailable.<br />

33.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

Information on the developmentaUreproductive toxicity of beryllium following<br />

exposure to humans by other routes was unavailable.<br />

33.42 Animai<br />

Intratracheal injection of rats with 50 mg/kg of beryllium chloride or beryllium oxide<br />

on (one or more) days 3,5, or 8 of gestation produced increases in fetal mortality, decreases<br />

in fetal weight, <strong>and</strong> increases in the percentages of pups with internal abnormalities<br />

(Selivanova <strong>and</strong> Savinova, 1986).<br />

Rats, treated intratracheally with beryllium oxide (0.2 mg berylliudrat) <strong>and</strong> allowed<br />

to mate repeatedly over 15 months, displayed no change in reproductive performance (Clary<br />

et aL, 1975).<br />

3.<strong>4.</strong> TARGEI' ORGANSICRITICAL EFFECIS<br />

3.<strong>4.</strong>1.1. PrimrUy Target Organs<br />

Skeletal system: Rickets in young animals appeared to be the result of the binding<br />

of phosphate to beryllium in the gut.<br />

3.<strong>4.</strong>12 Other Target Organs<br />

None<br />

3.42 lnhalrtionExposures<br />

3.<strong>4.</strong>21. Primary Target Organs<br />

Lungs: Chronic beryllium disease is characterized as an immunologkdly mcdiatcd<br />

granulomatous lung disease in humans <strong>and</strong> appears to be the result of direct chemical<br />

toxicity <strong>and</strong> foreign-body-type reactions in rats.<br />

3.4Z Other Target Organs<br />

Skin, liver, spleen, lymph nodes, myocardium, skeletal muscles, kidney, bone, <strong>and</strong><br />

salivary gl<strong>and</strong>s may &%it granulomas, similar to those of the lungs.<br />

11


<strong>4.</strong> CARCXNOGENICITY<br />

<strong>4.</strong>1. ORALEXPOSURES<br />

<strong>4.</strong>1.1. Human<br />

In the late 1970’s, epidemiological studies suggested that beryllium <strong>and</strong> its compounds<br />

could be human carcinogens. In a study that cwered 15 regions of the U.S., Berg <strong>and</strong><br />

Burbank (1972) found a significant correlation between cancers of the breast, bone, <strong>and</strong><br />

uterus <strong>and</strong> the concentration <strong>and</strong> detection frequency of beryllium in drinking water.<br />

Mortality rates in areas with beryllium in the drinking water were excessive only for nonwhite<br />

males. The probability of a positive association ranged from O.OO6-0.040. However, imperfect<br />

analytical <strong>and</strong> sampling methods used in the study prompted the US. EPA (1986b) to<br />

conclude that these results were not proof of cause <strong>and</strong> effect relationships between cancer<br />

<strong>and</strong> beryllium in drinking water.<br />

<strong>4.</strong>1.2 Animal<br />

Chronic oral administration of beryllium to animals produced equivocal carcinogenicity<br />

results in two studies. In one study, mice <strong>and</strong> rats treated with drinking water containing 5<br />

ppm beryllium (as beryllium sulfate) had slightly higher incidences of leukemias <strong>and</strong> grossly<br />

observed tumors, but the increases were not statistically significant (Schroeder <strong>and</strong> Mitchener,<br />

1975a,b). In the other study, male Wistar rats fed diets containing 0, 5, 50, or 500 ppm<br />

beryllium as beryllium sulfate for 104 weeb had statistically significant increases in the<br />

incidence of reticulum cell sarcoma at the two lowest doses, but no response at the highest<br />

dose (Morgareidge et al., 1975). The U.S. EPA (1986b) concluded that this study is<br />

suggestive of a carcinogenic response to ingested beryllium, but the lack of response at the<br />

high dose <strong>and</strong> the lack of peer review or publication of the study limits the interpretation as<br />

a positive study.<br />

<strong>4.</strong>2 INHAIA”IONEXP0SURES<br />

421. Human<br />

Infante et al. (1980) conducted a lung cancer mortality study of white males listed in<br />

the BCR using a retrospective cohort method. Of the cohort consisting of 421 individuals,<br />

139 had died <strong>and</strong> 64 had no vital statistics; 15 of the 139 that died had no cause of death<br />

listed. In terms of total cancer, 19 deaths were observed vs. 1241 expected for white males.<br />

In term of lung cancer, 6 deaths were observed 15 or more years after exposure vs. 281<br />

expected (~~0.01). However, the study used the NIOSH life table program which results in<br />

an 11% excess in the calculated expected number of lung cancer deaths (Wagoner et aL,<br />

1980). When the expected lung cancer deaths were adjusted for using the NIOSH program,<br />

the p value was reduced to ~0.09, questionable or borderline significance. Further analysis<br />

of the data from this study revealed a positive correlation for increased cancer <strong>and</strong> acute (but<br />

not chronic) beryllium disease. However, the NIOSH life tables were used for some of the<br />

calculations <strong>and</strong> the results are therefore questionable (U.S. EPA, 1987).<br />

12


Several epidemiological studies of lung cancer were conducted among beryllium<br />

workers from two plants (Bayliss et al., 1971; Bayliss <strong>and</strong> Lainhart, 1972; Bayliss <strong>and</strong><br />

Wagoner, 1977; Wagoner et al., 1980; Mancuso, 1970; 1979 1980). The studies, based on<br />

personnel records <strong>and</strong> social security quarterly earnings reports, were equivocal regarding the<br />

carcinogenicity of beryllium. For example, three studies revealed significant increases in<br />

observed over expected lung cancer cases in workers who were (a) employed from 1942-1967<br />

<strong>and</strong> followed for ten additional years (pc0.05) (Bayliss <strong>and</strong> Wagoner, 1977; Wagoner et al.,<br />

1980); (b) employed from 1937-1948 <strong>and</strong> followed for 30 additional years (~~0.01) (Mancuso,<br />

1980); <strong>and</strong> (c) combined workers of both plants who were employed from 1942-1948 <strong>and</strong><br />

followed for an additional 28 years (Pc0.01) (Mancuso, 1979). However, the studies were<br />

considered to be limited because of methodological constraints <strong>and</strong> deficiencies such as no<br />

correction for smoking (U.S. EPA, 1991a).<br />

The U.S.EPA (1986a) evaluated the total database for the association of lung cancer<br />

with occupational exposure to beryllium, <strong>and</strong> noted several limitations. However, in spite of<br />

the limitations of the studies, U.S. EPA (1986a.b) concluded that the results must be<br />

considered to be at least suggestive of a carcinogenic risk to humans.<br />

Inhalation studies have tested the carcinogenic potential of beryllium in various animal<br />

species. Table 1 shows that beryllium sulfate causes increased incidences of pulmonq<br />

tumors in rats <strong>and</strong> rhesus monkeys (Vonvald, 1953, 1962, 1%. Vorwald et al., 1955, 1966,<br />

Schepers et al., 1957; Reeves <strong>and</strong> Deitch, 1969). Rats exposed to concentrations of beryllium<br />

ranging from 1.8 to 180 mg/m3 exhibited increased incidences of pulmonary carcinomas that<br />

ranged from 20 to 100% (Vorwald 1953; 1%2). The animals were exposed 33-38 hoursheel<br />

for 3 to 24 months. The incidence of lung tumors exhibited a weakly positive correlation With<br />

exposure concentration <strong>and</strong> duration. Schepers et al. (1957) observed a 43% increase in the<br />

incidence of pulmonary carcinomas in rats exposed to 32-35 mg/m3 beryllium 44 hoursheel<br />

for 69 months followed by an l&month obsemtion period. These investigators identified<br />

eight histologically distinct types of tumors in the lungs of exposed rats. The tumors were<br />

metasticking <strong>and</strong> transplantable. Reeves <strong>and</strong> Deitch (1%9) observed an approximate 100%<br />

incidence in lung tumors in rats exposed to 36 mg/m3 beryllium 35 hoursheek for up to 18<br />

months. The studies of these investigators indicated that tumor yield in rats was dependent<br />

upon age at exposure rather than on duration of exposure.<br />

Tumor incidences were also increased in rats exposed to beryllium phosphate,<br />

beryllium fluoride, <strong>and</strong> beryl ore (Schepers, 1961; Wagner et al, 1969).<br />

43. OTHER ROUTES OF EXPOSURE<br />

Beryllium is carcinogenic when administered by intratracheal <strong>and</strong> intravenous<br />

injections <strong>and</strong> implantation into bone. Intratracheal injection o€ beryllium into rats induced<br />

cancer’incidences ranging from @loo%, with latency periods of at least 6 to 9 months<br />

(Vonvald <strong>and</strong> Reeves, 1959; Spencer et al., 1968, 1972, Ishinishi et aL, 1980, Groth et al.,<br />

1972; 1976; 1980, Groth <strong>and</strong> MacKay* 1971). Several investigators have induced<br />

osteosarcomas in rabbits (Nash, 1950; Dum <strong>and</strong> Largent, 1950; Yamaguchi <strong>and</strong> Katsura,<br />

1963; Sissons, 1950; <strong>and</strong> others) <strong>and</strong> mice (Cloudman et al., 1949) with intravenous injection<br />

13


Concentration Weekly Exposure Duration of Exposure Incidence of Pulmonary Reference<br />

(mghn’ as Be) lime (hours) (months) Carcinoma<br />

Emyllium sulfate<br />

Rat<br />

Rat<br />

33-35 33-38 12-14 4B (females) Vmld, 1953<br />

33-35 33-38 13-18 17/17 Vorwald et al., 1955<br />

32-35 44 6-9, followed by 58/136 SCheperS et al., 1957<br />

18-month observation<br />

55 33-38 3-18 55/74 Vorwald, 1962<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

180 33-38 12 11R7 Vorwald, 1962<br />

18 33-38 3-22 72/103 Vorwald, 1%2<br />

18 33-38 8-2 1 31/63 Vmld, 1962<br />

18 33-38 9-24 47190 Vmld, 1962<br />

18 33-38 11-16 9t21 Vmld. 1962<br />

1 a-2.0 33-38 E21 25/50 Vowald, 1962<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

Rat<br />

14


~<br />

TABLE 1. (Continued)<br />

cOmpOUnd/Species<br />

BcqUium sulfhtc<br />

Rat<br />

Rat<br />

Rat<br />

Rhesus monkey<br />

Rhesus monkey<br />

Guinea pig<br />

Guinea pig<br />

Guinea pig<br />

Concentration Weekly Exposure Du~~~ion of Exposure Incidence of Pulmonary Reference<br />

(mglm' as Be) lime (hours) (mom hs) Carcinoma<br />

36 35 9 15/15 (both sexes) Reem <strong>and</strong> Deitch, 1969<br />

-16 35 12 21R1 (both sexes) Reeves <strong>and</strong> Deitch, 1%9<br />

-16 35 18 13/15 (both sexes) Reeves <strong>and</strong> Deitch, 1%9<br />

35-200 42 8 014 (females) Schepers, 1964<br />

-78.8 15 36+ 811 1 Vorwald, 1964<br />

35 NR' 12 0 Schepers, 1%1<br />

36 35 12 2/20 Schepers, 1971<br />

3.7-30.4 35 18-24 0158 Reeves et al., 1972<br />

-m-<br />

Rat<br />

Rat<br />

Rhesus monkey<br />

Rhesus monkey<br />

Rhesus monkey<br />

Bayllium Buoride<br />

Rat<br />

Rhesus monkey<br />

32-35 NR' 1-12 35-60/17@' Schepcn, 1%1<br />

227 NR' 1-12 7/4@ schepen, 1%1<br />

200 42 8 014 (females)<br />

Schepers, 1%1<br />

~- ~<br />

1100 42 8 014 (females) Schepen, 1964<br />

8Mo 42 8 0/4 (females) Shepers, 1964<br />

9 NR' 6-15 10-20/200 Schepcrs, l%l<br />

180 42 8 014 (females) Schepers, 1964<br />

15


Y<br />

I<br />

I<br />

Conantration 4<br />

TABLE 1. (Continued)<br />

Reference<br />

ii<br />

'NR = Not reported<br />

bNumbcr of tumorsMumber of animals exposed<br />

16


<strong>and</strong> subperiosteal or intraosseous implantation of beryllium <strong>and</strong> several of its compounds.<br />

The incidence of osteosarcoma ranged from 0-100% by either route of administration, with<br />

a latency period of r9 months.<br />

<strong>4.</strong><strong>4.</strong> EPA WEIGHT-OF-EVIDENCE<br />

<strong>4.</strong><strong>4.</strong>1. Oral<br />

Not assigned.<br />

<strong>4.</strong>42 Inhalation<br />

Classification - B2, probabIe human carcinogen<br />

Basis - Inadequate evidence for humans; sufficient evidence for animals (U.S. EPA,<br />

1991a). "Beryllium has been shown to induce lung cancer via inhalation in rats <strong>and</strong><br />

monkeys <strong>and</strong> to induce osteosarcomas in rabbits via intravenous or intramedullary<br />

injection. Human epidemiology studies are considered to be inadequate."<br />

45. SLOPEFAClKlRS<br />

45.1. Oral<br />

SLOPE FACTOR: <strong>4.</strong>3 (mg/kg/day)-'<br />

DRINKING WATER UNIT RISK: 1x4 (pg/Lr'<br />

VERIFICATION DATE: 02/01/89 (U.S. EPA, 1991a)<br />

PRINCIPAL, STUDY Schroeder <strong>and</strong> Mitchener (1975a)<br />

452 Inhalation<br />

SLOPE FACTOR: 8.4 (mg/kg/day)"<br />

INHALATION UNIT RISK: 24E-3 ( pglm')"<br />

VERIFICATION DATE: OSAW88 (U.S. EPA, 1991a)<br />

PRINCIPAL STUDY Wagoner et al. (1980)<br />

17


5. REFERENCES<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1988. Toxicological Profile<br />

for Beryllium. Prepared by Syracuse Research Corporation under Contract 6&C8-o00<strong>4.</strong> U.S.<br />

Public Health Service. ATSDm-88/09.<br />

Bayliss, D.L. <strong>and</strong> W.S. Lainhart. 1972. Mortality patterns in beryllium production workers.<br />

Presented at the Am. Ind Hygiene Assoc. Cod OSHA Exhibit No. 66, Docket No. H005.<br />

(Cited in U.S. EPA, 1987a)<br />

Bayliss, D.L <strong>and</strong> J.K. Wagoner. 1977. Bronchogenic cancer <strong>and</strong> cardio-respiratory disease<br />

mortality among white males employed in a beryllium production facility. OSHA Beryllium<br />

hearing, 1977, Exhibit 13.F. (Cited in US. EPA, 1987a)<br />

Bayliss, D.L, W.S. Lainhart, LJ. Crally, R Ligo, H. Ayer <strong>and</strong> E Hunter. 1971. Mortality<br />

patterns in a group of former beryllium workers. In: Tran. 334rd AM. Meeting ACGIH,<br />

Toronto, Canada. p. 94-107. (Cited in U.S. EPA, 1987a)<br />

Berg, J.W. <strong>and</strong> F.Burbank 1972. Correlations between carcinogenic trace metals in water<br />

suppIy <strong>and</strong> cancer mortality. AM. N.Y. Acad. Sci 199: 249-261.<br />

Budavari, S., MJ. O'Neil, A Smith <strong>and</strong> P.E Heckelman, Eds. 1989. Beryllium. In: The<br />

Merck Index Merck & Co., Inc., Rahway, NJ. p. 181.<br />

Bugqshev, P.F. T.I. Zaikina, Y.I. Moskalev. 198<strong>4.</strong> Adsorption of beryllium from the rat<br />

gastrointestinal tract. Gig. Tr. Prof. Zabol. 6 52-53. (Cited in ATSDR 1988)<br />

Clary, JJ., LS. Bl<strong>and</strong> <strong>and</strong> H.E Stokinger. 1975. The effect of reproduction <strong>and</strong> lactation<br />

on the onset of latent chronic beryllium disease. ToxiwL Appl. PharmawL 33: 214-221.<br />

Cloudman, A.M., D. Vining, S. Barkulis <strong>and</strong> J.j. Nickson. 1949. Bone changes following<br />

intravenous injections of beryllium. Am. J. Pathol. 25: 810-811.<br />

Constantinidis, K. 1978. Acute <strong>and</strong> chronic beryllium disease. Br. J. Clin. Pract. 32: 127-136.<br />

(Cited in U.S. EPA, 1987a)<br />

Cox, G.E., DE Bailey <strong>and</strong> K. Morgareidge. 1975. Chronic feeding studies with beryllium<br />

sulfate in rats. Unpublished report submitted by the Food <strong>and</strong> Drug Research Laboratories,<br />

Inc., to the Aluminum Company of America, Pittsburgh, PA (Cited in U.S. EPA, 1991a)<br />

Crowley, J.F., J.G. Hamilton <strong>and</strong> KJ. Scott. 1949. The metabolism of camer-free<br />

radioberyllium in the rat. J. Biol. Chem. 177: 975-98<strong>4.</strong><br />

Cullen, M.R, J.R Kominsky, M.D. Rossman, et al. 1987. Chronic beryllium disease in a<br />

precious metal refinery, clinical epidemiologic <strong>and</strong> immunologic evidence for continuous risk<br />

from exposure to low level beryllium fume. Am. Rev. Respir. Dis. 135: 201-208<br />

18


Dutra, F.R. <strong>and</strong> EJ. Largent. 1950. Osteosarcoma induced by beryllium oxide. Am. J.<br />

Pathol. 26. 197-208.<br />

Dutra, F.R. 1948. The pneumonitis <strong>and</strong> granulomatosis peculiar to beryllium workers. Am.<br />

J. Pathol. 24 1137.<br />

Eisenbud, M. <strong>and</strong> J. Lisson. 1983. Epidemiological aspects of beryllium-induced<br />

nonmalignant lung disease: 30-year update. J. Occup. Med. 25: 196-202<br />

Eisenbud, M., C.F. Berghout <strong>and</strong> LT. Steadman. 1948. Environmental studies in plants <strong>and</strong><br />

laboratories using beryllium: the acute disease. J. In& Hyg. 30 281-285.<br />

Freiman, D.G. <strong>and</strong> H.L Hardy. 1970. Beryllium disease: the relation of pulmonary pathology<br />

to clinical course <strong>and</strong> prognosis based on a study of 130 cases from the U.S. Beryllium Case<br />

Registry. Hum Pathol. 1: 25-4<strong>4.</strong> (Cited in Kriebel et al., 1988b)<br />

Furchner, J.E, C.R Richmond <strong>and</strong> J.E. London. 1973. Comparative metabolism of<br />

radionuclides in mammals: VII. Retention of beryllium in the mouse, rat, monkey <strong>and</strong> dog.<br />

Health PhF. 24 292300.<br />

Groth, D.H. <strong>and</strong> C.R MacKay. 1971. Chronic pulmonary pathology in rats after<br />

intratracheal injection. ToxicoL Appl. Pharmacol. 19: 392<br />

Grot&, D.H., C Kommiheni <strong>and</strong> G.R MacKay. 1980. Carcinogenicity of beryllium hydroxide<br />

<strong>and</strong> alloys. Environ. Res. 21: 63-8<strong>4.</strong><br />

Groth, D.H.,LP. Scheel <strong>and</strong> G.R MacKay. 1972 Comparative pulmonary effects of Be <strong>and</strong><br />

As compounds in rats. Lab. Invest. 26; 447-448<br />

Groth, D.H.. L Stehler <strong>and</strong> G. MacKay. 1976. Interactions of mercury, cadmium, selenium,<br />

tellurium, arsenic <strong>and</strong> beryllium In: G.F. Nordberg, Ed. Effects <strong>and</strong> Dose-Response<br />

Relationships of Toxic Metals. Elsevier Publishing CO., Amsterdam. p. 527-543.<br />

Guyatt, B.L, H.D. Kay <strong>and</strong> H.D. Branion 1933. Beryllium rickets. J. Nutr. 6 313-32<strong>4.</strong><br />

Haley, PJ., G.L Finch, M.D. Hoover <strong>and</strong> RG. Cuddihy. 1990. The acute toxicity of inhaled<br />

beryllium metal in rats. Fundam. Appl. ToxicoL 15: 767-778.<br />

Hall, T.C, CH. Wood, J.D. Stoeclde <strong>and</strong> LB. Tepper. 1959. Case data from the Beryllium<br />

Registry. Am. Med. Assoc. Arch. Ind. Health 19 100-103.<br />

Infante, P.F., J.K. Wagoner <strong>and</strong> N.I. Sprince. 1980. Mortality patterns from lung cancer <strong>and</strong><br />

non-neoplastic respiratory disease among white males in the United States.Beryl1ium Case<br />

Registry. Environ. Res. 21: 35-43.<br />

Ishinishi, N., M. Mizunow, T. Inamasu <strong>and</strong> A HisanageL 1980. Experimental study on<br />

carcinogenicity of beryllium oxide <strong>and</strong> arsenic trioxide to the lung of the rats by intratracheal<br />

instillation. Fukuokd Igaku Zasshi 71: 19-26. (Cited in U.S. EPA, 1987a)<br />

19


Jacobson, S.A. 1933. Bone lesions in rats produced by the substitution of beryllium for<br />

calcium in the diets. Arch. Pathol. 15: 18-26.<br />

Kay, H.D. <strong>and</strong> D.L Skill. 193<strong>4.</strong> Prevention <strong>and</strong> cure of beryllium rickets. Biochem. J. 28:<br />

1222-1 229.<br />

Kriebel, D., N.L Sprince, E.A. Eisen, LA. Greaves, H A Feldman <strong>and</strong> R.E. Greene. 1988a.<br />

Beryllium exposure <strong>and</strong> pulmonary function: A cross sectional study of beryllium workers.<br />

Br. J. Ind. Med. 45: 167-173.<br />

Kriebel, D., J.D. Brain, N.L. Sprince <strong>and</strong> H. Kazemi. 1988b. The pulmonary toxicity of<br />

beryllium. Am. Rev. Respir Dis. 137: 464-473.<br />

Machle, W., E Beyer <strong>and</strong> E Gregorius. 1948. BeryllioaiS Occup. Med. 5: 671-683.<br />

Mancuso, T.F. 1970. Relation of duration of employment <strong>and</strong> prior illness to respiratory<br />

cancer among beryllium workers. Environ. Res. 3: 251-275.<br />

Mancuso, T.F. 1979. Occupational lung cancer among beryllium workers in dusts <strong>and</strong><br />

disease. In: R. Lemen <strong>and</strong> J. Dement, Eds. Proc. Conf. Occup. Exp. to Fibrous <strong>and</strong><br />

Particulate Dust <strong>and</strong> Their Extension into the Environment. Pathrotox Publishers, Inc.<br />

(Cited in U.S. EPA, 1987a)<br />

Mancuso, Rf. 1980. Mortality study of beryllium industry workers’ occupational lung cancer.<br />

Environ. Res. 21: 48-55.<br />

Meehan, W.R <strong>and</strong> LE Smyth. 1967. Occurrence of beryllium as a trace element in<br />

environmental materials. Environ. Sci TechnoL 1: 839-84<strong>4.</strong><br />

Morgareidge, K, G.E Cax <strong>and</strong> D.E. Bailey. 1975. Chronic feeding studies with beryllium<br />

sulfate in rats. Food <strong>and</strong> Drug Research Laboratories, Inc. Fmal Report to the Aluminum<br />

Company of America, Pittsburgh, Pa. (Cited in U.S. EPA, 1987a)<br />

Morgareidge, IC. G.E Cox, D.E Bailey <strong>and</strong> MA Gallo. 1977. Chronic oral toxicity of<br />

beryllium in the rat. Toxicol. Appl. Phannacol. 41: 204-205.<br />

Nash, P. 1950. Experimental production of malignant tumors by beryllium. Lancet 1: 519.<br />

Nishimura, M. 1966. Clinical <strong>and</strong> experimental studies on acute beryllium disease. Nagoya<br />

J. Med. Sci. 18 17-4<strong>4.</strong> (Cited in U.S. EPA, 1987a)<br />

OSHA (Occupational Safety <strong>and</strong> Health Administration). 1989. Toxic <strong>and</strong> hazardous<br />

substances. Table 2-1. 29 CFR XMI, section 1910.1ooO.<br />

Parkes, W.R 198<strong>4.</strong> Occupational Lung Disorders, 2nd ed. Butterworths, London. p. 333.<br />

(Cited in Zorn et al, 1988)<br />

.<br />

20


Reeves, AL 1965. The absorption of beryllium from the gastrointestinal tract. Arch.<br />

Environ. Health 11: 209-21<strong>4.</strong><br />

Reeves, AL 1979. In: L Ftr’berg, G.F. Nordberg <strong>and</strong> V.B. Vouk, Eds. H<strong>and</strong>book of the<br />

Toxicology of Metals. ElsevierbJorth Holl<strong>and</strong>, Amsterdam. p. 329.<br />

Reeves, AL 1986. Beryllium. In: Toxicology of Metals, Vol. I., 2nd ed. Elsevier Science<br />

Publishing Co., New York, pp.<br />

Reeves, AL. <strong>and</strong> D. Deitch. 1969. Influence of age on the carcinogenic response to<br />

beryllium inhalation. In: S. Harishima, Ed. Proc. 16th Internat. Cong. Occup. Health,<br />

Tokyo, Japan. Japan Industrial Safety Association, Tokyo, Japan. p. 651-652 (Cited in U.S.<br />

EPA, 1987a)<br />

Reeves, AL <strong>and</strong> AJ. Vorwald. 1%7. Beryllium carcinogenesis. IL Pulmonary deposition<br />

<strong>and</strong> clearance of inhaled beryllium sulfate in the rat. Cancer Res. 27: 446-451.<br />

Reeves, AL., D. Deitch <strong>and</strong> A.J. Vorwald. 1967. Beryllium carcinogenesis. I. Inhalation<br />

exposure of rats to beryllium sulfate aerwoL Cancer Res. 27: 439-445.<br />

Reeves, AI,.,N.D. Krivanek, EK. Busby <strong>and</strong> RH. Swanborg. 1972. Immunity to pulmonary<br />

berylliosis in guinea pigs. Int. Arch. Occup. Environ. Health 29: 209-220.<br />

Rhoads, K <strong>and</strong> CL S<strong>and</strong>ers. 1985. Lung clearance, translocation <strong>and</strong> acute toxicity of<br />

arsenic, beryllium, cadmium, cobalt. lead, selenium, vanadium, <strong>and</strong> ytterbium oxides following<br />

deposition in rat lung. Environ. Res. 36 359-378.<br />

S<strong>and</strong>ers, CL, W.C. Cannon, GJ. Powers, RR Adee <strong>and</strong> D.M. Meier. 1975. Toximlogy of<br />

high-fired k’jlium oxide inhaled by rodents. Arch. Environ. Health 30 546-551.<br />

Schepers, G.W.H.<br />

Exp. Tumor Res. 2 203-22<strong>4.</strong><br />

1961. Neoplasia experimentally induced by beryllium compounds. Pmg.<br />

Schepers, G.W.H. 196<strong>4.</strong> Biological action of beryllium: Reaction of the monkey to inhaled<br />

aerosols. Ind. Med. Surg. 33: 1-16.<br />

Schepers, G.W.H. 1971. Lung tumors of primates <strong>and</strong> rodents. II. Ind. Med. 40: 23-31.<br />

Schepers, G.W.H., T.M. Durkan, AB. Delahant <strong>and</strong> F.T. Creedon. 1957. The biological<br />

action of inhaled beryllium sulfate: A preliminary chronic toxicity study on rats. Am. Med.<br />

Assoc Arch. Ind. Health 15: 32-38.<br />

Schroeder, H.A. <strong>and</strong> M. Mitchener. 1975a Life-term studies in rats; Effects of aluminum,<br />

bariuni, beryllium <strong>and</strong> tungsten. J. Nutr. 105: 421-427.<br />

Schroeder, HA. <strong>and</strong> M. Mitchener. 197%. We-term effects of mercury, methyl rnwcuy,<br />

<strong>and</strong> nine other trace metals on mice. J. Nutr. 105: 452-458.<br />

21


Selivanova, LM. <strong>and</strong> T.B. Savinova. 1986. Effects of beryllium chloride <strong>and</strong> oxide on the<br />

sexual function of female rats <strong>and</strong> development of their progeny. Gig. Sank 8: 44-46.<br />

Sendelbach, LE, A.F. Tryka <strong>and</strong> H. Witchi. 1989. Progressive lung injury over a one-year<br />

period after a single inhalation exposure to beryllium sulfate. Am. Rev. Resp. Dis. 139 1003-<br />

1009. (MEDLARS II, TOXLINE)<br />

Sissons, H.A 1950. Bone sarcomas produced experimentally in the rabbit using compounds<br />

of beryllium. Acta Unio. Int. Contra. Cancrum. 7: 171. (Cited in U.S. EPA, 1987a)<br />

Spencer, J.C., RH. Hook, J.A Blumenshine, S.B. Md=ollister, S.E Sadek <strong>and</strong> J.C. Jones.<br />

1968. Toxiwlogical studies on beryllium oxides <strong>and</strong> berylliumcontaining exhaust products.<br />

AMRG7R48-148. Aeromedical Res. Lab., Wright-Patterson AFB, Dayton, OH. 9<strong>4.</strong> (Cited<br />

in U.S. EPA, 1987a)<br />

Spencer, H.C, S.B. McCollister, JJ. Kociba, C.G. Humiston <strong>and</strong> G.L Sparschu 1972<br />

Toxicological evaluation of beryllium motor exhaust products. AMRL-72-118. Aeromedical<br />

Research Lab., Wright-Patterson AEB., Dayton, OH. 94 p. (Cited in U.S. EPA, 1987a)<br />

Sprince, N.L <strong>and</strong> H. Kazemi. 1983. Beryllium disease. In: Rom, W., Ed. Environmental<br />

<strong>and</strong> Occupational Medicine, 1st ed. Little, Brown, Boston. pp. 481490. (Cited in fiebel<br />

et aL, 1988b)<br />

Stiefel, T., K Schulze, H. Zorn <strong>and</strong> G. Tolg. 1980. Toxiwkinetic <strong>and</strong> toxicdynamic studies<br />

of bexyllium. Arch. ToxiwL 45 81-92<br />

Tepper, LB., HL Hardy <strong>and</strong> RJ. Chamberlin. 1961. Toxicity of Beryllium Compounds.<br />

Elsevier, New York, pp. 146-168. (Cited in AIISDR, 1988)<br />

U.S.EPA (US. Environmental Protection Agency). 1986a. Health Assessment Document<br />

for Beryllium. Prepared by the Office of Health <strong>and</strong> environmental Assessment,<br />

Environmental Criteria <strong>and</strong> Assessment Office, Research Triangle Park, NC. External<br />

Review Draft. EPA 600-8-84-026B. (Cited in U.S. EPA, 1987a)<br />

U.S. EPA (US. Environmental Protection Agency). 1986b. Drinking Water Criteria<br />

Document for Beryllium. Prepared by the Office of Health <strong>and</strong> Environmental Assessment,<br />

Environmental Criteria <strong>and</strong> Assessment Office, Cincinnati, OH for the office of Drinking<br />

Water, Washington, DC<br />

US. EPA (U.S. Environmental Protection Agency). 1987a Health Effects Assessment for<br />

Beryllium <strong>and</strong> Compounds. Prepared for Office of Solid Waste <strong>and</strong> Emergency Response by<br />

Environmental Criteria <strong>and</strong> Assessment Office, Office of Health <strong>and</strong> Environmental<br />

Assessment, US. EPA, Washington, DC ECAO-CIN-H113.<br />

U.S. EPA (US. Environmental Protection Agency). 1987b. Health Assessment Document<br />

for Beryllium. Office of Health <strong>and</strong> Emrironmental Assessment, US. EPA (EPA/600/&<br />

84/026F)<br />

22


U.S. EPA (U.S. Environmental Protection Agency). 1991a. Beryllium. Integrated Risk<br />

Information System (IRIS). Environmental Criteria <strong>and</strong> Assessment Office,Office of Health<br />

<strong>and</strong> Environmental Assessment, Cincinnati, OH.<br />

U.S. EPA (U.S. Environmental Protection Agency). 1991b. Health Effects Assessment<br />

Summary Tables. FY-1991 Annual, January, 1991. OEce of Research <strong>and</strong> Development,<br />

Office of Emergency <strong>and</strong> Remedial Response, U.S. Environmental Protection Agency,<br />

Washington, DC. p. A-10.<br />

Vorwald, AJ. 1968. Biologic manifestation of toxic inhalation in monkeys. In: H. Vagtborg,<br />

Ed. Use of Nonhuman Primates in Drug Evaluation. Univ of Texas Press, Austin, TX. p.<br />

2 (Citedin U.S. EA, 1987a)<br />

Vorwaid, AJ. 1962 Progress report (unpublished). Grant No. F-253-6. Am. Cancer SOC.<br />

(Cited in U.S. EPA, 1987a)<br />

Vorwald, AJ. 1953. Adenocarcinoma in the lung of albino rats exposed to compounds of<br />

beryllium. In: Cancer of the Lung - An Evaluation of the Problem. Proc. of the Scientific<br />

Session, Annual Meeting, November. Am. Cancer Soc., New York. p. 103-109. (Cited in<br />

U.S. EPA, 1987a)<br />

Vorwald, AJ. <strong>and</strong> kL Reeves. 1959. Pathologic changes induced by beryllium compounds.<br />

Arch. In& Health 19 190-199.<br />

Vorwald AJ., P.C. Pratt <strong>and</strong> F. Urban. 1955. The production of pulmonary cancer in<br />

albino rats exposed by inhalants to an aerosol of beryllium sulfate. Acta. Unio. Int. Cancrum.<br />

11: 735. (Cited in U.S. EPA, 1Wa)<br />

Vorwald, AJ, AL Reeves <strong>and</strong> EJ. Urban. 1966. Experimental beryllium toxicology. In:<br />

€LE Stokinger, Ed. Beryllium - Its industrial Hygiene Aspects. Academic Press, New York.<br />

pp. 201-23<strong>4.</strong><br />

Wagner, W.D., D.H. Groth, J.L Holtz, G.E. Madden <strong>and</strong> RE Stokinger. 1969.<br />

Comparative chronic inhalation toxicity of beryllium ores, bertr<strong>and</strong>ite <strong>and</strong> beryl, with<br />

production of pulmonary tumors by beryl. Toxicol. Appl. Pharmacol. 15: 10-29.<br />

Wagoner, J.K, P.F. Infante <strong>and</strong> D.L Bayliss. 1980. Beryllium: An etiologic agent in the<br />

induction of lung cancer, nonneoplastic respiratory disease <strong>and</strong> heart disease among<br />

industrially exposed workers. Environ. Res. 21: 15-3<strong>4.</strong><br />

Watanabe, K., S. Shima, S. Tachiirawa, et al. 1985. Biotoxicity <strong>and</strong> beryllium distribution in<br />

organs by oral administration of beryllium compounds for long periods. 11. Experimental stud<br />

23


ToxIClTY SUMMARY FOR<br />

BiS( 2--)PHTHALATE<br />

MARCH 1993<br />

Prepared by<br />

Andrew Francis, M.S., DABT<br />

Chemical Hazard Evaluation Group<br />

Biomedical Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory'<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of<br />

Energy under Contract No. DE-A~S-840R21400


page intentionally left blank


Bk(2-ethylhexyl)phthalate is a colorless oily liquid that is extensively used as a<br />

plasticizer in a wide variety of industrial, domestic <strong>and</strong> medical products. It is an<br />

environmental contaminant <strong>and</strong> has been detected in ground water, surface water, drinking<br />

water, air, soil, plants, fsh <strong>and</strong> animals (Sittig, 1985; S<strong>and</strong>meyer <strong>and</strong> Kirwin, 1978). It is<br />

rapidly absorbed from the gastrointestinal tract primarily as mono(2ethylhexyl)phthalate<br />

(Pollack et al., 1985; Teirlynck <strong>and</strong> Belpaire, 1985). The diester can be absorbed through the<br />

skin <strong>and</strong> from the lungs (Elsisi et aL, 1989; Pegg, 1982). It is rapidly metabolized in the blood<br />

<strong>and</strong> tissues to the monoester, which can be excreted as a glucuronide conjugate or further<br />

hydrolyzed to phthalic acid <strong>and</strong> excreted (Kluwe, 1982; Albro et al., 1982).<br />

Animal studies have indicated that the primary target organs are the liver <strong>and</strong> kidneys<br />

(Carpenter et aL, 1953; U.S. EPA, 1987a,b); however, higher doses are reported to result in<br />

testicular effects <strong>and</strong> decreased hemoglobin <strong>and</strong> packed cell volume (Kluwe et al., 1982; Gray<br />

et ai., 1977). The primary intracellular effects of bk(2ethylhexyl)phthalate in the liver <strong>and</strong><br />

kidneys are an increase in the smooth endoplasmic reticulum <strong>and</strong> a proliferation in the<br />

number <strong>and</strong> size of peroxisomes (Kluwe et al., 1982, Reddy <strong>and</strong> Lalwani, 1983; Tomasawski<br />

et aL, 1986). An epidemiological study reported no toxic effects from occupational exposure<br />

to air concentrations of bk(2ethylhexyl)phthalate up to 0.16 mg/m3 (Thiess et aL, 1978).<br />

Other studies on occupational exposures to mixtures of phthalate esters containing bir(2-<br />

ethylhq1)phthalate have reported polyneuritis <strong>and</strong> sensory-motor polyneuropathy with<br />

decreased thrombocytes, leukocytes <strong>and</strong> hemoglobin in some exposed workers (Milkov et aL,<br />

1973; Gilioli et al., 1978). Developmental toxicity studies with rats <strong>and</strong> mice have shown that<br />

bir(2ethylhexyl)phthalate is fetotoldc <strong>and</strong> teratogenic when given orally during gestation<br />

(Wolkowski-Tyl et aL, 1984a <strong>and</strong> b; Shiota <strong>and</strong> Mima, 1985). Oral exposure has ais0 been<br />

shown to result in decreased sperm count in rats (Siddipui <strong>and</strong> Srivastava, 1992)<br />

A Reference Dose (RfD) of 0.02 mg/kg/day for both subchronic <strong>and</strong> chronic oral<br />

exposure was calculated from a lowest-observed-adver-effect level (LOAEL) of 19<br />

mg/lcg/day based on increased relative liver weight in guinea pigs given 0, 19, or 64 mg bk(2-<br />

ethylhexyl) phthalat&g/day for 12 months in their diet (Carpenter et aL, 1953; U.S. EPA,<br />

1992 a,b). A Reference Concentration (Euc) €or inhalation exposure is not available (U.S.<br />

EPA, 1992b).<br />

bir(2ethylhexyl)phthalate is known to induce the proliferation of peroxisomes, which<br />

has beem associated with carcinogenesis (Rao <strong>and</strong> Reddy, 1991). Dosedependent,<br />

statistically-significant increases in the incidences of hepatocellular carcinomas <strong>and</strong> combined<br />

carcinomas <strong>and</strong> adenomas were seen in mice <strong>and</strong> rats exposed to bis(2ethylhexyl)phthalatc<br />

in their diet for 103 weeb (Kluwe, et al, 1982). An increased incidence of neoplastic<br />

nodules <strong>and</strong> hepatocellular carcinomas was also reported in rats (Rao et al., 1990).<br />

Based on U.S. EPA guidelines, bk(2ethylhexyl)phthalate was assigned to weight-ofevidence<br />

Group BZ probable human carcinogen, on the basis of an increased incidence of<br />

liver tumors in rats <strong>and</strong> mice. A carcinogenicity slope factor (st') of 0.014 (mgikg/day)'* for<br />

oral exposure was based on the combined incidence of hepatocellular carcinomas <strong>and</strong><br />

1


adenomas in male mice (Kluwe, et al., 1982, U.S. EPA, 1992b). A drinking water unit risk<br />

- of <strong>4.</strong>OE-7 (pg/L)” was calculated based on the q,.. A quantitative estimation of carcinogenic<br />

risk from inhalation exposure is not available (US EPA, 1992b).<br />

2


1. INTRODUCIION<br />

Bh(2-ethylhexyl)phthalate or di(2-ethylhexyl)phthalate (C;,H,O,, CAS registry<br />

number 117-81-3) is a clear oily liquid with a molecular weight of 390.5<strong>4.</strong> It has a melting<br />

point of -50°C; a boiling point of 387°C at 760 mm Hg <strong>and</strong> 230°C at 5 mm Hg; <strong>and</strong> a vapor<br />

pressure of 1.2 mm Hg at 2WC It has a density of 0.9861 <strong>and</strong> is practically insoluble in<br />

water (0.40 mgL at 25°C). bis(2-ethylhexyl)phthalate has a flash point of 2183°C. The<br />

relatively high flash point, boiling point <strong>and</strong> low vapor pressure contribute to the high stability<br />

of this phthalic acid ester (Sittig, 1985; S<strong>and</strong>meyer <strong>and</strong> Kirwin, 1978; U.S. EPA. 1987a).<br />

Bis(2-ethylhexyl)phthalate is primarily used in the plastics industry as a plasticizer with<br />

such varied applications as wire insulation, food packaging <strong>and</strong> biomedical applications such<br />

as tubing <strong>and</strong> blood containers. Other uses include vacuum pump oil <strong>and</strong> as a dielectric fluid<br />

in capacitors (U.S. EPA, 1987b, Budavari, 1989). The combined annual production of dioctyl<br />

phthalates in the United States exceeds 300 million pounds (U.S. EPA, 198fb). The widespread<br />

uses of bi,s(2-ethylhexyl)phthalate have made the compound, along with other phthalic<br />

acid esters, ubiquitous in the environment. It has been detected in ground water, surface<br />

water, drinking water, air, soil, plants, fish <strong>and</strong> animals. Air concentrations in certain PVC<br />

manufacturing plants have been reported to range from below 0.02 to 05 mum3 (Vainiotalo<br />

<strong>and</strong> Pfaffti, 1990). Some exposure OCCUK from leaching of the compound from mntainers<br />

used in the food <strong>and</strong> medical industries (U.S. EPA, 1987b; Callahan et aL, 1979). This is of<br />

particular concern to patients exposed to large amounts of blood or blood products. 'Ihe<br />

chemical is extracted from the containers by the blood <strong>and</strong> is converted to mono(2-<br />

ethy1hexyl)phthalate by a plasma enzyme (Labow et al, 1988). Experiments have shown that<br />

33 mg bis(2ethylhexyl)phthalate/gm of bag material were extracted in five days with bovine<br />

calf serum, whereas bags tested with saline resulted in no soluble plasticizers (Chawla <strong>and</strong><br />

Hinberg, 1991).<br />

In the environment, bir(2ethylhexyl)phthalate undergoes biodegradation in water <strong>and</strong><br />

soil, <strong>and</strong> is predicted to react with hydroxyl radicals in the atmosphere. It is estimated to have<br />

a half life of about 12 hours in the air, 10 to 20 days in the soil, <strong>and</strong> days to weeks in water<br />

(U.S. EPA, 1987qb). Volatilization of bh(2ethylhexyl)phthalate from contaminated water<br />

does not contribute significantly to its removal. The half-life of the molecule due to<br />

evaporation alone from bodies of water has been estimated to be as long as 15 years (US.<br />

EPA, 1987a.b; Callahan et aL, 1979). In the marine environment bis(2-ethylhexyl)phthdatc<br />

has been shown to be rapidly degraded by experimental microcosms (Davey et A, 1990). It<br />

has been found to bind to organic acids in the soil <strong>and</strong> water resulting in an increase in its -<br />

solubility <strong>and</strong> its mobility in the environment (Matsuda <strong>and</strong> Schnitzer, 1971). It also adsorbs<br />

to both freshwater <strong>and</strong> marine sediments where it may serve as a long-term sink (U.S.EPAb,<br />

1987, Sullivan et al., 1982).<br />

Experiments have shown that fLh do not extensively bioaccumulate biS(2-<br />

ethylhexy1)phthalate. Rainbow trout studies indicate $hat the diester is converted to the<br />

monoester by the gills before absorption from the water occurs, thus limiting the absorption<br />

of the diester (Barron et at, 1989).<br />

3


2 METABOLISM AND DISPOSITION<br />

21. ABSORPTION<br />

Bk(2ethylhexyl)phthalate can be absorbed from the gastrointestinal tract., the lungs,<br />

<strong>and</strong> through the skin. Over 90% of an oral dose of bk(2ethylhexyl)phthalate was absorbed<br />

by the gastrointestinal tract of rats as evidenced by the excretion of metabolites (Williams <strong>and</strong><br />

Blanchfield, 1974). However, gastrointestinal absorption is complicated by the hydrolysis of<br />

the diester to the monoester derivative by pancreatic enzymes <strong>and</strong> enzymes in intestinal<br />

mucosal cells. The monoester is then absorbed. Gavage studies on rats by Teirlynck <strong>and</strong><br />

Belpaire (1985) showed an average plasma concentration of 8.8 pg/d of the diester compared<br />

to 63.2 &ml of the monoester 3 hours following a single oral dose of 2.8 g/kg of bk(2-<br />

ethylhexy1)phthdate. Similar studies by Pollack et aL (1985) demonstrated that 80% of a<br />

single oral dose was absorbed as the monoester, whereas only 13% of the dose was absorbed<br />

as bk(2-ethylhexyl)phthalate. These observations must be taken into account when route-toroute<br />

extrapolations are considered (U.S. EPA 1987b).<br />

Although it is known that phthalic acid esters can be absorbed by inhalation, there are<br />

little quantitative data available for this route of exposure (U.S. EPA 1987a). Pegg (1982)<br />

studied the pulmonary absorption of an aerosol of 14C-6k(2-ethylhexyl)phthalate by adult male<br />

Sprague-Daw19 rats, The animals were exposed for 6 hours to a concentration of 100 mg/m3<br />

in a heads-only chamber. The radioactivity appearing in the blood at various times following<br />

exposure <strong>and</strong> the radioactivity tccovered from urine, feccs, skin <strong>and</strong> the carcass were<br />

measured 72 hours after expasurc. The disappearance of radioactivity ftom lung tissue was<br />

also measured leading to the conclusion that absorption was rapid <strong>and</strong> complete.<br />

Bk(2ethylhezyl)phthalate can also be absorbed through the skin. This is primarily<br />

a hazard €or workers in the plastics industry, but other exposures can occur such as contact<br />

with the chemical leached horn vinyl swimming pool liners (U. S. EPA 1980). Quantitative<br />

absorption data are not available, however, guinea pig studies have indicated a LDW of 10<br />

gkg for dermal exposure (Autian, 1973; US. EPA, 1980). Excretion <strong>and</strong> distribution of<br />

radioactive labeled [“C]-bk(2ethylhexyl)phthalate applied to the shaved backs of male F-344<br />

rats at concentrations of 30 to 40 mg/kg was followed Over a period of seven days<br />

demonstrating dermal absorption by rats (see sections 2.2 <strong>and</strong> 24) (Elski et al, 1989).<br />

22 DISlRIBUTION<br />

Bk(2-ethylhexyl)phthalate <strong>and</strong> its metabolites are distributed primarily to plasma,<br />

liver, kidney, the gastrointestinal tract, <strong>and</strong> fat following oral exposure. Some metabolites<br />

have ken found in almost all tissues especially the monoester metabolite, which has been<br />

found in relatively high concentration in the testes of rats. Maximum concentrations of bk(2-<br />

ethy1hexyl)phthalate <strong>and</strong> the monoester metabolite were reached in blood <strong>and</strong> the tissues in<br />

6-24 hours after a single oral dose of 9.8 gkg in corn oil (0shi.<strong>and</strong> Hiraga, 1m U.S. =A,<br />

198%). Elsisi et aL (1989) applied 30 to 40 mg 6k(2-ethylhexyl)phthalatekg to the shaved<br />

back of F-344 rats <strong>and</strong> followed the distribution of radioactive label. Most of the label was<br />

found in fat, skin <strong>and</strong> muscle after seven days.<br />

4


23. METABOLISM<br />

The first step in metabolism of bir(2-ethylhexyl)phthalate is hydrolysis to the<br />

monoester derivative, which primarily occurs in the gastrointestinal tract following oral<br />

exposure, but also occurs in the tissues. A glucuronide conjugate can be formed with the<br />

monoester or the terminal or next to last carbon in the monoester molecule can be oxidized.<br />

After the carboxylic acid derivative is formed, the length of the side chain can be decreased<br />

by B oxidation. The monoester can also be hydrolyzed to phthalic acid (Klue, 1982; Albm<br />

et aL, 1982; Williams <strong>and</strong> Blanchfield 1974; U.S. EPA, 198%).<br />

Rat studies indicate that the diester is removed faster from most tissues than the<br />

monoester with half-lives from 15 hours for lung tissue to 284 hours for liver <strong>and</strong> 156 hours<br />

for epididymal fat. bir(2ethylhexyl)phthalate is fat soluble <strong>and</strong> remains unmetabolized in fat<br />

tissue much longer than in other tissues. The monoester has a half-life of about 32 hours in<br />

liver tissue <strong>and</strong> 68 hours in epididymal fat. It also has a half-life of about 50 hours in the<br />

testes, compared to 8.3 hours for the diester (Oishi <strong>and</strong> Hiraga, 1982, U.S. EPA 198%).<br />

The mono(Zethylheq4)phthalate metabolite has been shown to accumulate in the<br />

testes of rats following treatment with bk(2ethylhexyl)phthalate (Oishi, 1990). In vitro<br />

studies have shown that testicular tissue does not further metabolize the monoester (Albm<br />

et al., 1989).<br />

2<strong>4.</strong> EXCREIION<br />

Since bLs(2ethylhexyl)phthalate is rapidly converted to the monoester derivative,<br />

solubilization <strong>and</strong> -tion of the monoester becomes the primary metabolic task. Mm<br />

spies tested, including humans, excrete the monctester as a glucuronide conjugate in the<br />

urine, feces <strong>and</strong> bile. Rats, apparently, are an exception <strong>and</strong> primarily oxidize the terminal<br />

or next to last carbon in the monoester molecule before excretion. The monoester can also<br />

be further hydrolyzed to phthalic acid <strong>and</strong> excreted (Kluwe, 1982, Albm et aL, 1982). An<br />

average half-life of about 12 hours has been reported in humans following a single dosc of<br />

bk(2ethylhexyl)phthalate (Schmid <strong>and</strong> Schlaffer, 1985; U.S. EPA, 198%). Excretion of [“qbLr(2ethylhexyl)phthalate<br />

after dermal absorption in F-344 rats was followed over a period<br />

of seven days. Radioactive label was found in the urine <strong>and</strong> feces; urine was the major route<br />

of elimination (Elsisi et aL, 1989).<br />

3. NONCARCINOGENIC HEALTH EFFECIS<br />

3.1. ORALEXPOSURES<br />

3.1.1. Acute Tdty<br />

3.1.1.1. Human<br />

Ingestion of 5 <strong>and</strong> 10 g of bh(2ethylhexyl)phthalate by human volunteers resulted in<br />

mild gastrointestinal disturbances with the 10 g dose <strong>and</strong> no effects from the 5 g dose (Shaffer<br />

et aL, 1945).<br />

5’


3.1.12 ADimal<br />

Oral LDw values of 30 g/kg, 30.6 g/kg, <strong>and</strong> 34 gkg have been listed for mice, rats <strong>and</strong><br />

rabbits respectively (Sittig, 1985; Sax <strong>and</strong> Lewis, 1989).<br />

3.12 SubchronkToaiCity<br />

3.121. Human<br />

Information on the subchronic oral toxicity of bir(2ethylhexyl)phthalate in humans<br />

was not available.<br />

3.122 Animal<br />

Gray et aL (1977) observed a variety of symptoms after feeding groups of 15 male <strong>and</strong><br />

15 female Sprague Dawley rats 0,O.z 1.0, or 2% bis(2ethylhexyl)phthalate (0, 150, 750, or<br />

1500 mgkgday, respectively) in their diet for 17 weeks. Increased absolute <strong>and</strong> relative liver<br />

weights were observed in all treated groups. Food consumption <strong>and</strong> growth rates were<br />

reduced in the 1 <strong>and</strong> 2% treated groups. A dose-related reduction in testicular weight <strong>and</strong><br />

an increase in testicular damage were observed. Decreased hemoglobin concentration was<br />

observed in male rats, <strong>and</strong> decreased packed red cell volume was also observed in both sexes<br />

in the two highest dose groups. An interstitial nephritis, increased SGPT <strong>and</strong> decreased<br />

blood gluoose were reported by Nagasaki et al. (1974) in a 48 week rat study (U.S.EPA,<br />

1987a). Animals in this study were fed 500 or loo0 ppm bir(2-ethylhexyl)phthalate in the diet<br />

(25 or 50 rng/I@lay, rcspactively). Ota et aL (1974) reported degenerative changes in the<br />

kidneys <strong>and</strong> l kr of mice given 05 to 5 g/kg/day in the diet for 1 to 3 months. Male albino<br />

ferrets fed 1% bi3(2ethylhcxyl)phthalate in the diet for 14 months exhiiited decreased body<br />

weight, increased liver weight with morphological <strong>and</strong> biochemical changes, <strong>and</strong> testicular<br />

damage (take et al., 1976 US. EPA 1987b).<br />

3.13. CbronicTaxicity<br />

3.13.1. Human<br />

Information on the chronic oral toxicity of bis(2ethylhcxyi)phthalate in humans was<br />

not available.<br />

3.132 Animal<br />

Carpenter et al. (1953) fed groups of 32 male <strong>and</strong> 32 female Sherman rats 0,0.04,<br />

0.13, or 0.4% bis(2-ethylhsryl)phthalate (0,20,60, or 200 mgkg/day, respectively) in the diet<br />

for one year during which time they were allowed to breed. After one year, groups of eight<br />

males <strong>and</strong> eight females were continued on the same regimen <strong>and</strong> groups of 32 male <strong>and</strong> 32<br />

female of€spring were fed 0, <strong>and</strong> 0.4% (200 mg/kg/day) bis(2etbylhexyl)phthalate in the diet<br />

Sigmfkantly increased liver <strong>and</strong> kidney weights were observed with the high dose in the male<br />

parental group <strong>and</strong> in both sexes of the F, group. No other treatment related effects were<br />

reported in the rats. The same study also included guinea pigs <strong>and</strong> dogs. Groups of 22-24<br />

male <strong>and</strong> 22-24 female guinea pigs were fed the equivalent of 0, 19 or 64 mg/kg/day bir(2-<br />

6


ethylhexy1)phthalate for one year. Groups of 4 dogs r<strong>and</strong>omly selected were given the<br />

equivalent of 5<strong>4.</strong>7 mg/kg/day for about four weeks <strong>and</strong> then 0.06 mgkg/day for about 48<br />

week One dog was given a TWA dose of 79.3 mg/kg/day for a total of 246 days. Increased<br />

relative liver weight was seen in all treated groups of female guinea pigs, however, no<br />

histological changes were reported, The dog that received the TWA dose of 793 mg/&g/day<br />

developed fatty vacuolation <strong>and</strong> congestion in the liver <strong>and</strong> cloudy swelling <strong>and</strong> congestion<br />

in the kidneys. No effects were reported for the other groups of dogs (U.S. EPA, 1987a).<br />

Two year dietaly studies have been performed on groups of 50 male <strong>and</strong> 50 female<br />

F344 rats <strong>and</strong> W F , mice (NTP, 1982; Kluwe et al., 1982). Rats were given 0,6OOo, or<br />

l2,OOO ppm in the diet (0,322,674 mg/kg/day for males; 0,394, 774 mg/’kg/day for females).<br />

Mice were given 0,3000, or 6OOO ppm in the diet (0, 672, 1325 mg/kg/day for males; 0, 799,<br />

1821 mgkglday for females). Dtcreased body weight was observed in all treated male raq<br />

<strong>and</strong> female rats in the high doae group, <strong>and</strong> in all treated female mice. An increased<br />

incidence of seminiferous tubule degeneration was observed at the highest dose in both rats<br />

<strong>and</strong> mice (U.S. EPA, 1987b). Renal cysts have been reported to appear in rats fed 150 mg/kg<br />

three timeshveek for a year, but not when the chemical is given for six months (Woodward,<br />

1990).<br />

One of the most commonly observed effects of bis(2ethylhexyl)phthalate treatment<br />

is an increase in liver <strong>and</strong> kidney weights. The intracellular effects that accompany or amunt<br />

for the in- weights arc an increase in the smooth endoplasmic reticulum <strong>and</strong> a<br />

proliferation in number <strong>and</strong> size of peroxisomes. Ganning et al. (1990) fed male Spraguc-<br />

Dawley rats a diet containing 0.02, 0.2 or 2% bis(2ethylhexyl)phthalate for 102 weeks.<br />

Decreased body weight was seen only in the 2% group, however enzyme changes that reflect<br />

the proliferation of peroxisomes occurred in a dose related manner. Peroxisomal palmitoyl-<br />

CoA dehydrogenase <strong>and</strong> mitochondrial carnitine acetyltransferase activities increased to a<br />

maximum in 20 wetb. Comparable levels were also reached in the 0.2% dose group by the<br />

end of the experiment. Peroxisomal catalase increased during the first year, but decreased<br />

to control levels during the second year of treatment. All ewe activities returned to<br />

control values within 2-3 weeks following cessation of treatment. Peroxbomes contain a<br />

number of oxidative enzymes that affect the metabolism of the bir(2ethylharyl)phthalatc <strong>and</strong><br />

other intracellular molecules, especially Eats. This proliferation of peroxisomes has been<br />

linked with carcinogenic activity (Reddy <strong>and</strong> Lalwani, 1983; Tomaszewski et al., 1986).<br />

3.1.<strong>4.</strong> DeveIopmentaI <strong>and</strong> Repductivc Toxicity<br />

3.1.<strong>4.</strong>1. Human<br />

Information on deveiopmental <strong>and</strong> reproductive toxicity of bis(2-ethylhexyl)phthalak<br />

in humans following oral expasure was not available.<br />

3.1.<strong>4.</strong>2 Animal<br />

A number of studies have reported fetotoxic <strong>and</strong> teratogenic effects in rats <strong>and</strong> mice<br />

following exposure to bis(2-ethylhql)phthalate. Nikonorow et al. (1973) observed incressed<br />

resorption of fetal implants <strong>and</strong> decreased fetal weight when 1.7 g biS(2)-<br />

ethylhq1)phthalateAcg body weight was given orally on days 0-21 of gestation. Bell et aL<br />

7


(1979) reported decreased fetal body weights, increased relative fetal liver weights, <strong>and</strong><br />

reduced sterologenesis in fetal brain <strong>and</strong> liver in Sprague Dawley rats fed 05% bis(2-<br />

ethylhexy1)phthalate on days 5-18 of gestation. Wolkowski-Tyl et al. (1984a) fed groups of<br />

rats 0, 0.5, 1.0, 15, or 20% bh(2-ethylhexyl)phthalate (equivalent to 0, 356.7, 666.4, 856.5,<br />

or 1054,8 mg/kg/day, respectively) in their diet on days 0-20 of gestation. Some maternal<br />

effects were seen, including decreased body weight, increased absolute <strong>and</strong> relative liver<br />

weight, <strong>and</strong> increased gravid uterine weight. Dose-related increases in the number of fetal<br />

resorptions <strong>and</strong> in the number of dead <strong>and</strong> malformed fetuses per litter were also reported.<br />

There was a dose-related decrease in fetal weight that was significant in all treated groups.<br />

Wolkowski-Tyl et al. (1984b) also studied the effect of 0, 0.025, 0.05,0.1, or 0.15%<br />

bh(2-ethylhexyl)phthalate (equivalent to 0,44,91,191, or 292 mg/kg/day, respectively) in the<br />

diet given to mice on days 0-18 of gestation. Maternal effects observed were decreased body<br />

weight <strong>and</strong> increased relative k r weight, both effects significant at 0.1 <strong>and</strong> 0.15% in the diet.<br />

Dose-related increases in rcsorptions <strong>and</strong> in dead fetuses per litter were significant at doses<br />

of 0.1 <strong>and</strong> 0.15%. Significant increases in malformed fetuses per litter, with external, visceral<br />

<strong>and</strong> skeletal defects, were observed at doses of 20.15%. Studies utilizing higher oral doses<br />

(250, 500, lO(10 or ZOO0 mag) by Shiota <strong>and</strong> Mima (1985) <strong>and</strong> (0.05, 0.1, 0.2, 0.4 or 1.0%<br />

diet) by Shiota <strong>and</strong> Nishimura (1982) <strong>and</strong> Shiota et aL (1980) demonstrated increased<br />

numbers of fetuses with gross external malformations, including neural tube defects. The<br />

incidence of resorptions increased up to 100% in animals fed 0.4 <strong>and</strong> 1% bis(2-<br />

ethylhexy1)phthalate in their diets. Mice were shown to be most sensitive to the teratogenic<br />

effects of bis(2ethylhexyl)phthalate on days 7 <strong>and</strong> 8 of gestation. Treatment on day 7 with<br />

1 mvkg resulted in increased fetal mortality, resorptions, <strong>and</strong> gross external <strong>and</strong> skeletal<br />

anomalies Treatment on day 9 or 10 with up to 30 mUkg produced no rcsorptions, fetal<br />

mortality or malformed fetuses (Yagi et al, 1980).<br />

Mono(2ethylhcxyl)phthalate, a principle metabolite of bis(2ethylhexyl)phthalate. was<br />

fed to pregnant 0-1 mice on days 0 through 17 of gestation (0, 0.13, 0.26, 0.48 or 0.97<br />

mmoykglday). Increased maternal liver weight was observed at doses >0.48 mmovlrg <strong>and</strong><br />

decreased weight gain was observed at the 0.97 mmol dose. Dose related i n d fetal<br />

mortality, the % of litters with malformed fetuses, <strong>and</strong> the % of malformed fetuses per litter<br />

were seen in all treated groups. Other metabolites including 2ethylhexanol had no effect.<br />

Qualitatively, the effect of the monoester was similar to the diester in oral studies (Price et<br />

aL, 1991).<br />

A dose related decrease in sperm count has been reported in rats given 500 or lo00<br />

mgkg/day orally bis(2ethylhsryl)phthalate for 15 days. Decreased epididymis weight was seen<br />

in the loo0 mg/kg/day dose group (Siddiqui <strong>and</strong> Srivastava, 1992). Decreased absolute <strong>and</strong><br />

relative testicular weights were seen in rats given 2OOO mg/kg/day orally for 15 days. A<br />

decrease in testicular 17-betahydroxysteroid dehydrogenase activity was obsed at lo00 <strong>and</strong><br />

2000 mgkg/day indicative of pible decreased steroidogenesis in treated animals (Srivastava<br />

<strong>and</strong> Srivastava, 1991). The monoester metabolite accumulates in the testes <strong>and</strong> has been<br />

shown in vitro to inhiiit testicular mitochondrial respiration (pihi, 1990).<br />

8


3.15. Reference Doce<br />

3.15.1. Subchronic<br />

ORAL RfD,:<br />

UNCERTAINTY FACI'OR:<br />

Lorn<br />

0.02 mg/kg/day (U.S. EPA, 1992a)<br />

lo00<br />

19 mg/kg/day<br />

PRINCIPAL STUDIES: The same studies <strong>and</strong> comments apply to both the<br />

subchronic <strong>and</strong> chronic RfD derivations. See section 3.132.<br />

3.15.2 chronic<br />

ORAL RfD,:<br />

UNCERTAINTY FACI'OR:<br />

MODIFYING FACTOR:<br />

LOAEL:<br />

CONFIDENCE.<br />

Study:<br />

Data Base:<br />

RfD:<br />

VERIFICATION DATE:<br />

PRrNmALsmY<br />

0.02 mg/kg/day (U.S. EPA, 1992b)<br />

lo00<br />

1<br />

19 mg/kg/day<br />

Medium<br />

Medium<br />

Medium<br />

05120/8!5<br />

Carpenter et al. (1953).<br />

cOMMEN?s: The LOAEL was calculated from a 12 month experiment in which<br />

guinea pigs were given 0, 19, or 64 mg di(2ethylhayl)phthalate/kg body weight in the<br />

diet. The LOAEL of 19 mg/kg was based on increased relative liver weight. See<br />

section 3.13.2<br />

32 INHALATTON-<br />

3.21.1. Human<br />

Information on the acute inhalation toxicity of bis(2-ethylhexyl)phthalate in humans<br />

was not available.<br />

321.2 Animal<br />

Rats could survive a two hour exposure to a vapor mist created by bubbling air<br />

through heated (170°C) bh(Z-ethylhexyl)phthalate, but did after a four hour exposure<br />

(S<strong>and</strong>meyer <strong>and</strong> Kiwin, 1978).<br />

9


3221. Human<br />

A total of 101 workers in a bk(2-ethylhexy1)phthalate production plant were examined<br />

for adverse effects due to phthalate ester exposure. The air concentration of bis(2-<br />

ethylhexy1)phthalate ranged from 0.01 to 0.16 mg/m3, <strong>and</strong> the exposure was from four months<br />

to 35 years. Some of the chemical was found in the blood <strong>and</strong> urine of both the control <strong>and</strong><br />

exposed groups, however, no compound-related effects were reported (Thiess et al., 1978).<br />

3222 Animal<br />

Information on subchronic inhalation toxicity of bis(2-ethylhexyl)phthalate in animals<br />

was not available.<br />

323.1. Human<br />

No compound related effects were observed in a study of 101 workers in a bis(2-<br />

ethylhexy1)phthalate production plant exposed to 0.01 to 0.16 mg/m3 for up to 35 years<br />

(average 12 years, see section 3.2.21) (Thiess et aL, 1978).<br />

Other studies have been conducted on populations chronically exposed to mixtures<br />

of phthalic acid esters containing blr(2ethylhexyl)phthalate; therefore, the observed effects<br />

may or may not be caused by the bis(2-ethylh 1)phthalate. Ambient air concentrations of<br />

total phthalate esters ranged from 1 to 40 mg/m OT in one study (Mill;ov et aL, lm), <strong>and</strong> from<br />


32<strong>4.</strong>2 Animal<br />

Information on developmental <strong>and</strong> reproductive toxicity in animals resulting from<br />

inhalation exposure to bis(2ethylhexyl)phthalate was not available.<br />

3-3. Referenceconctntration<br />

3-3.1. Sthchronic<br />

A subchronic Reference Concentration is not available at this time.<br />

3252 chronic<br />

A chronic Reference Concentration is not available at this time.<br />

33. CYIRER ROUTES OF EXPOSURE<br />

33.1. hteTdty<br />

33.1.1. Human<br />

Bis(2ethylhexyl)phthalate is mildly irritating to the skin <strong>and</strong> irritating to the eyes <strong>and</strong><br />

mucous membranes on contact (Sittig, 1985; Sax <strong>and</strong> Lewis, 1989). Humans are also<br />

susceptible to introduction of bir(2ethylhexyl)phthalate by intravenous route since this<br />

substance is known to leach from blood containers <strong>and</strong> other PVC plastic medical equipment.<br />

However, no reports descn'bng acute adverse effects as a result of this route of exposure arc<br />

available.<br />

33.12. Animal<br />

Bk(2ethylhexyI)phthalate can be absorbed through the skin <strong>and</strong> LD, values of 25<br />

<strong>and</strong> 10 g/kg have been listed for rabbits <strong>and</strong> guinea pigs, respectively. A dose of 500 m@4<br />

hours is mildly imtating to the skin <strong>and</strong> eyes of rabbits (Sax <strong>and</strong> Lewis, 1989).<br />

3321. Human<br />

Idormation on the subchronic toxicity of bk(2-ethylhexyl)phthalate by other routes<br />

of exposure in humans was unavailable.<br />

3322 Animal<br />

Information on the subchronic toxicity of bis(2+thyIheqI)phthalate by other routes<br />

of exposure in animals was unavailable.<br />

.<br />

11


333. ChukTcxicity<br />

333.1. Human<br />

Humans needing chronic transfusions of blood are susceptible to the introduction of<br />

bis(2-ethylhexyl)phthalate by intravenous route since this substance is known to leach from<br />

blood containers <strong>and</strong> other PVC plastic medical equipment (Sittig, 1985). The diester leached<br />

from the plastic can be metabolized to the monoester by blood enzymes. The monoester has<br />

been shown to inhibit platelet phospholipase A2 possibly resulting in reduced platelet<br />

function (Labow et ai., 1988). Long term hemodialysis patients often develop renal cysts<br />

similar to that reported for rats chronically exposed to bir(2ethylhexyl)phthalate, however,<br />

a causal relationship has not been shown with leached plasticizer (Woodward, 1990). No<br />

reports specifically describing adverse effects as a result of this route of exposure were<br />

located.<br />

3332 Animal<br />

Information on the chronic toxicity of bis(2-ethylhexyl)phthalate by other routes of<br />

exposure in animals was unavailable.<br />

33.<strong>4.</strong> Dmdopmental <strong>and</strong> Reproductive Toxicity<br />

33.<strong>4.</strong>1. Human<br />

Information on the developmental aad reproductive dCity of bk(2-<br />

ethylhexy1)phthalate by other routes of exposure in humans was unavailable.<br />

33.42 Animal<br />

Male <strong>and</strong> female mice were given subcutaneous injections of 1 to 100 ml bis(2-<br />

ethyheq4)phthaIate/kg on days 1,5, <strong>and</strong> 10 <strong>and</strong> evaluated on day 21 of the experiment for<br />

reproductive performance, biochemical parameters of the gonads <strong>and</strong> histological alterations.<br />

Decreased numbers of pregnancies were reported when either sex of treated mice were mated<br />

with untreated mice. Decreased testicular weight but not ovarian weight was reported.<br />

Histological damage <strong>and</strong> increased lysosomal activity was seen in both sexes. Decreased<br />

fertility was the most sensitive indicator for gonadotoxicity (Agarwal et aL, 1989).<br />

In addition to the monoester derivative of bis(2ethylhexyl)phthalate, another principal<br />

metabolite, 2etbylhexanoic acid, exists in two enantiomeric forms, The S enantiomer was<br />

found to not be embryotoxic or teratogenic. However, intraperitoneal injection of pregnant<br />

rats with 500 m ag twice daiiy on day 7 <strong>and</strong> 8 of gestation with the R enantiomer caused<br />

decreased fetal sunrival, decreased weight of surviving fetuses, <strong>and</strong> neural tube defects in 59%<br />

of living fetuses (Hauck et al, 1990).<br />

.<br />

12


3.<strong>4.</strong> TARGET ORGANWCRITICAL EFFECIS<br />

3.<strong>4.</strong>1. Oral powr re^<br />

3.<strong>4.</strong>1.1. Primary Target Organ(s)<br />

1. Liver: Increased liver weight was observed in animals following oral treatment with<br />

bis(2ethylhexyl)phthalate.<br />

2. Kidney: Increased kidney weight was observed in animals following oral treatment<br />

with bir(2ethylhexyl)phthalate.<br />

3.<strong>4.</strong>1.2 Other Target Org8n(s)<br />

1. Fetus: l3posure to bis(2ethylhexyl)phthalate during gestation has resulted in<br />

increased fetal mortality <strong>and</strong> malformations in rats <strong>and</strong> mice,<br />

2 Testis: Treatment with bis(2ethylhexyl)phthalate has resulted in decreased<br />

testicular weight <strong>and</strong> degeneration of the seminiferous tubules in rats <strong>and</strong> mice.<br />

3. Blood. Decreased hemoglobin <strong>and</strong> packed cell volume was observed in rats<br />

exposed to bir(2ethylhexyl)phthalate.<br />

3.421. Primarp Target Organ@)<br />

1. Blood: Decreased hemoglobin <strong>and</strong> blood cell counts were observed in humans<br />

exposed to a mixture of phthalate esters containing bir(2ethylhexyI)phthalat.e.<br />

2 Nervous system: A polyneuritis <strong>and</strong> mild to moderate sensory-motor <strong>and</strong> motor<br />

polyneuropathy were observed in humans exposed to a mixture of phthalate eSteIs<br />

containing bis(2ethylhexyl)phthalate.<br />

3.4a Other Tar@ Organ(s)<br />

1. Liver: The effects on liver are likely to be independent of route of exposutc<br />

2 Kidnqr: The effects on kidney are likely to be independent of route of exposure.<br />

13


<strong>4.</strong>1. ORAL-<br />

<strong>4.</strong>1.1. Human<br />

Information on the oral carcinogenicity of bis(2ethylhexyl)phthalate in humans was<br />

unavailable.<br />

<strong>4.</strong>1.2 Animal<br />

Groups of 50 male <strong>and</strong> 50 female FEher 344 rats were g kn 0,6oOo, or 12OOO ppm<br />

bk(2-ethyhexyl)phthalat.e in their diet for 103 weeks. Groups of 50 male <strong>and</strong> 50 female<br />

B6C3F1 mice were given 0,3000, or 6OOO ppm of the chemical in their diets for 103 weeb.<br />

All animals were examined when moribund or after 105 weeb from the beginning of<br />

treatment. No clinical signs of toxicity were obsed in any of the animals. Female rats, <strong>and</strong><br />

male <strong>and</strong> female mice demonstrated a statistically significant dosedependent increased<br />

incidence of hepatocellular carcinomas <strong>and</strong> combined carcinomas <strong>and</strong> adenomas. A signjficant<br />

increase in the combined incidence of neoplastic nodules <strong>and</strong> hepatocellular carcinomas was<br />

seen in the highdose male rats (NTP, 1982, Kluwe, et at, 1982).<br />

Combined neoplastic nodules <strong>and</strong> hepatocellular carcinomas ranging from 0 to 4 per<br />

liver were reported in 11 of 14 F-344 rats on a diet containing 2% bif(2ethylhexyl)phthalat.e<br />

for 108 weeks (Rao et al, 1990).<br />

Bk(2ethyhexyl)phthalate is known to induce the production of peroxisOmes <strong>and</strong> the<br />

proliferation of pcroldsomes has been linked with carcinogenesis (Rao <strong>and</strong> Reddy, 1991) (See<br />

also section 3.13.2).<br />

42 INHALATIONEXPOSURES<br />

421. Human<br />

Information on the inhalation carcinogenicity of bir(2ethylhexyl)phthalate in humans<br />

was unavailable.<br />

422 Animal<br />

Information on the inhalation carcinogenicity of bis(2-ethylhexyl)phthalate in animals<br />

was unavailable.<br />

43. OTHER ROUTES OF ExpomTRE<br />

Information on the carcinogenicity of bir(2ethylhexyl)phthalate in animals or humans<br />

with other routes of expure was unavailable.<br />

14


<strong>4.</strong><strong>4.</strong> EPA WEIGHT-OF-EVIDENCE<br />

<strong>4.</strong><strong>4.</strong>1. oral<br />

CLASSIFICATION Group B2 - Probable Human Carcinogen (US. EPA, 1987%<br />

1987b, 1991% 1991b).<br />

BASIS: Based on an increased incidence of hepatocellular carcinomas <strong>and</strong> adenomas<br />

in both rats <strong>and</strong> mice treated with bir(2ethylhexyl)phthalate in the diet (NTP, 1982,<br />

Kluwe, et al., 1982).<br />

<strong>4.</strong>42 Inhnlatinn<br />

CLASSIFICATION Group B2 - Probable Human Carcinogen (U.S. EPA, 1987%<br />

1% 1992b).<br />

BASIS: Based on an increased incidence of hepatocellular carcinomas <strong>and</strong> adenomas<br />

in both rats <strong>and</strong> mice treated with bir(2ethylhexyl)phthalate in the diet (NTP, 1982,<br />

Kluwe, et aL, 1982).<br />

45. CARCINOGENICITY.sIxlPE FACIO=<br />

45.1. Oral<br />

SLOPE FACTOR<br />

1992b)<br />

DRINKING WATER UMT RISE<br />

I=)<br />

VERIFICATION DATE:<br />

PRINCIPAL STUDY.<br />

1.4E-2 (mg/kg/day)" (US. EPA, 1%<br />

<strong>4.</strong>OE-7 (pg/L)-' (US. EPA, 19%<br />

mom<br />

NTP (1982); muwe, et ai. (1982).<br />

COMMENTS Based on incidence of hepatocellular carcinomas <strong>and</strong> adenomas in<br />

male mice exposed orally to bir(2ethylhexyl)phthalate. Both listed references discuss<br />

the same data set.<br />

Quantitative estimation of carcinogenic risk from inhalation exposure is not<br />

available (U.S. EPA, 1992b)<br />

15


5. REFERENCES<br />

Agaxwal, D.K, W.H. Lawrence, J.E. Turner <strong>and</strong> J. Autian 1989. Effects of parenteral di(2-<br />

ethylhexy1)phthalate (DEHP) on gonadal biochemistry, pathology, <strong>and</strong> reproductive<br />

performance of mice. J. Toxicol Environ. Health. 2f5( 1): 39-59.<br />

Albro, P.W., RE Chapin, J.T. Corbett, J. Schroeder <strong>and</strong> J.LPhe1p. 1989. Mono-2-<br />

ethylhexyl phthalate, a metabolite of di(Zethylhexyl)phthalate, causally linked to testicular<br />

atrophy in rats. Toxic01 Appl. Pharmacol. loO(2): 193-200.<br />

Albro, P.W., J.T. Corbett, J.L Schroeder, S. Jordan <strong>and</strong> H. B. Matthews. 1982<br />

Pharmacokinetics, interactions with macromolecules <strong>and</strong> species differences in metabolism of<br />

DEHP. Environ. Health Penpect. 4519-25.<br />

Autian, J. 1973. Toxicity <strong>and</strong> health threats of phthalate esters: Review of the literature.<br />

Environ Health Perspect. 4 3-26.<br />

Barron, M.G., LR Schultz <strong>and</strong> W.L Hayton. 1989. Presystemic branchial metabolism limits<br />

di(2ethylhexyl)phthalate accumulation in fsh. Toxic~l. Appl. Pharmacol. !%( 1): 49-57.<br />

Bell, F.P., M. Makowske, D. Schneider <strong>and</strong> CS. Patt. 1979. Inhibition of sterologentsis in<br />

brain <strong>and</strong> liver of fetal <strong>and</strong> suckling rats from dams fed di(2ethylhexyl)phthalate plasticizer.<br />

Lipids. 14(4): 372-377.<br />

Budavari S., MJ. O'Neil, A Smith <strong>and</strong> P.E Heckelman, Eds. 1989. The Merck Index 11th<br />

ed. Merck <strong>and</strong> Co., Rahway, NJ. p. 19<strong>4.</strong><br />

Callahan, MA, M.W. Slimak, N.W. Gabel, et aL 1979. Fate of 129 Priority Pollutants. VOI.<br />

IL Office of Water Planning <strong>and</strong> St<strong>and</strong>ards, U.S. EPA, Washington, DC p. (94)l-28<br />

Carpenter, G.P., CS. Weil <strong>and</strong> RE Smyth, Jr. 1953. Chronic oral toxicity of di(2-<br />

ethylhexy1)phthalate for rats, guinea pip <strong>and</strong> dogs. J. Ind. Hyg. Occup. Med. 18: 219-226<br />

Chawla, AS. <strong>and</strong> L Hinberg. 1991. Leaching of plasticizers from <strong>and</strong> surface characterization<br />

of PVC blood platelet bags. Biomater. Artif. Cells. Immobil. Biotechnol. 19(4): 761-78<strong>4.</strong><br />

Davey, EW., KT. Perez, AE Soper, N.F. Lackie, G.E Morrison, RL Johnson <strong>and</strong> J.F.<br />

Heltshe. 1990. Significance of the surface microlayer to the environmental fate of di(2-<br />

ethylhexy1)phthalat.e predicted from marine microcosms. Mar. Chem. 31(4): 231-270.<br />

Elsisi, AE, D.E Carter <strong>and</strong> LG. Sip. 1989. Dermal abwrption of phthalate diesters in<br />

rats. Fund. appL Taxicol. 12(1): 70-77.<br />

Ganning, AE., MJ. Olsson, U. Brunk <strong>and</strong> G. Dallner. 1990. Effects of prolonged treatment<br />

with phthalate ester on rat Iiver. Pharmacol ToxicoL 67(5): 392-401.<br />

16


Gilioli, R, C Bulgheroni, T. Terrano, G. Filippini, G. Massetto <strong>and</strong> R Boeri. 1978. Studio<br />

neurologim transverwale e longitudinale di una poplazione operaia addetta alla produzione<br />

di ftalati. Med. Lav. 69(5): 620431 (cited in U.S. EPA, 1987a).<br />

Gray, TJ.B, K.R. Butterworth, I.F. Gaunt, P. Grasso <strong>and</strong> S.D. Gangolli. 1977. Short-term<br />

toxicity study of di(2-ethylhexyl)phthalate in rats. Food Cosmet. Toxiwl. 15(5): 389-400.<br />

Hauck, RS.,C. Wegner, P. Blumtritt, J.H. Fuhrhop <strong>and</strong> H. Nau 1990. Asymmetric synthesis<br />

<strong>and</strong> teratogenic activity of (R)- <strong>and</strong> (S)-2ethylhexanoic acid, a metabolite of the plasticizer<br />

di(2ethylhexyl)phthalate. Life Sci. 46(7): 513-518.<br />

Kluwe, W.M., J. K Haseman, J.F. Douglas <strong>and</strong> J.E HUE 1982 The carcinogenicity of<br />

dietary di(2ethylhcxyl)phthalate (DEHP) in Faher 344 rats <strong>and</strong> B6C3Fl mice. J. ToxiwL<br />

Environ. Health lO(4-5): 7974315.<br />

Labow, RS., E Meek, GA Adam <strong>and</strong> G. Rock. 1988. Inhibition of human platelet<br />

phospholipase A2 by mono(2-ethylhexyl)phthalate. Environ. Health. Perspect. 78 179-183.<br />

Lake, B.G., P.G. Brantom, S.D.Gangolli, K.R. Butterworth <strong>and</strong> P. Grasso. 1976. Studies<br />

on the effects of orally administered bir(2ethylhexyl)phthalate in the ferret. Toxicology.<br />

q3): 341356.<br />

Matsuda, K. <strong>and</strong> M. Schnitzer. 1971. Reactions between fulvic acid, a soil humic material,<br />

<strong>and</strong> diwl phthalates. Bull. Environ. Contam. Toxiwl. 6 200-20<strong>4.</strong><br />

Milkkov, LB., M.V. Aldjreva, T.B. Popova, et aL 1973. Health status of workers exposed<br />

to effect of phthalate plastickrs in the production of artificial leather <strong>and</strong> films (on the basis<br />

of PVC resins). Translation of Gig. Tr. Prof ZaboL 13: 14-17, 1969. NTIS PB221973-T. 5<br />

p. (cited in US. EPA, 1987a).<br />

Nagasaki, H.,S. Tomii, T. Mega, K. Hirao <strong>and</strong> L N. Yoshitaka. 197<strong>4.</strong> Chronic toxicity of<br />

dioctyl phthalate @OP) in male rats <strong>and</strong> mice. Nara Igaku Zasshi 25(6): 649-654 (cited in<br />

U.S. EPA, 1987b).<br />

Nagasaki, €L, L Tomii, T. Mega, K Hirao <strong>and</strong> LN. Yoshitaka 197<strong>4.</strong> Chronic toxicity of<br />

dioctyl phthalate (DOP) in male rats <strong>and</strong> mice. Nara Igaku Zasshi 25(6): 64965<strong>4.</strong> (cited<br />

in U.S. EPA, 1987a <strong>and</strong> b).<br />

Nikonomw, M.,H. Mazur <strong>and</strong> I€ Piekacz 1973. EDcects of orally administered plastickrs<br />

<strong>and</strong> polyvinyl chloride stabilizers in the rat. ToxicoL AppL Pharmacol. 26: 253-259.<br />

NTP (National Toxiwlogy Program). 1982 Carcinogenesis bioassay of di(2-<br />

ethylheq1)phthalate (CAS No. 11781-7) in E344 rats <strong>and</strong> B6C3F, mice (feed study). Report<br />

NIH.PUB-82-1773, NTP-80-37. NTIS PB82-184011. (Gted in U.S. EPA, 1987a <strong>and</strong> b).<br />

Oishi S. 1990. mats of phthalic acid esters on testicular mitochondrial functions in the rat.<br />

Arch ToxicoL 64(2): 143-147.<br />

17


Oishi, S <strong>and</strong> Hiraga. 1982. Distribution <strong>and</strong> elimination of di-2ethylhexyl phthalate <strong>and</strong><br />

mono-2ethylhexyl phthalate after a single oral administration of di-2ethylhexyl phthalate in<br />

rats. Arch. Toximl. 51(2):149-156.<br />

Ota, H., H. Onda, H. Kodama <strong>and</strong> N. Yamada. 197<strong>4.</strong> Histopathological studies on the effect<br />

of phthalic acid esters on the biological system of mice. Nippon Eiseigaku Zasshi. 29(5):<br />

519-52<strong>4.</strong> (cited in U.S. EPA, 1987b).<br />

Pegg, D.G. 1982 Disposition of di(2ethylhql)phthalate following inhalation <strong>and</strong> peroral<br />

exposure in rats. 073 8(d) submission. Microfiche no. 0206189. (Cited in U.S. EPA, 1987a).<br />

Pollack, G.M., RCK. Li, J.C. Ermer <strong>and</strong> D.D. Shen. 1985. Effects of route of<br />

administration <strong>and</strong> repetitive dosing on the disposition kinetics of di(2ethylhql)phthalate<br />

<strong>and</strong> its mono deesterified metabolite in rats. Toxicol. AppL Pharmaool. 79(2): 246-256.<br />

Price, CJ., RW. Tyl, M.C. Man, C.B. Myers, RE Monkey, JJ. Heindel <strong>and</strong> B.A. Schwetz<br />

1991. Developmental toxicity evaluation of DEHP metabolites in Swiss mice. Teratology.<br />

43(5): 457.<br />

Rao, MS. <strong>and</strong> J. K. Reddy. 1991. An overview of peroxisome proliferator-induced<br />

hepatocarcinogenesis. Environ. Health Perspect. 93: 205-209.<br />

Rao, M.S., AV. Yeld<strong>and</strong>i <strong>and</strong> V. Subbarao. 1990. Quantitative analysis of hepatocellular<br />

lesions induced by di(2-ethylhexyl)phthalate in F-344 rats. J. Toximi EnvirOn Health.30(2):<br />

85-89.<br />

Reddy, J. K <strong>and</strong> N.D. Lalwani. 1983. Carcinogenesis by hepatic peroxhome proliferatom:<br />

evaluation of the risk of hvpolipidemic drugs <strong>and</strong> industrial plastickts to humans. CRC Cnt.<br />

Rev. TOI~WL 12 1-58<br />

hdmeyer, EE <strong>and</strong> rf. Kirwin, Jr. 1978 Btem. In Patty’s Industrial Hygiene <strong>and</strong><br />

Taxicology, VoL 2A, eds. G.D. Clayton <strong>and</strong> F.E. Clayton, John Wiley & Sons, New York.<br />

pp. 242-2352.<br />

Sax, N.L, <strong>and</strong> RJ. Lewis. 1989. Dangerous Properties of Industrial Materials. 7th ed. VoL<br />

II. Van Nostr<strong>and</strong> Reinhold, New York.<br />

Schmid, P. <strong>and</strong> C Schlaffer. 1985. Excretion <strong>and</strong> metabolism of di(2ethylhql)phthalate<br />

in man. Xenobiotica. 15(3):251-256 (cited in U.S. EPA, 1987b)<br />

Shaffer, C.B., CP. Carpenter <strong>and</strong> RE Smyth. 1945. Acute <strong>and</strong> subacute toxicity of di(2-<br />

ethylhexy1)phthalate with note upon its metabolism. J. Ind. Hyg. TcndcoL 27: 130.<br />

Shiota, K, MJ. Chou <strong>and</strong> H. Nishimura. 1980. Embryotoxic effects of di(2-<br />

ethylhexy1)phthalate <strong>and</strong> di-n-butyl phthalate in mice. Emriron. Res. 22(1): 245-253 (cittd<br />

in U.S. PA, 1987b).<br />

18


Shiota, K. <strong>and</strong> S. Mima. 1985. Assessment of the teratogenicity of-di(2-ethylhexyl)phthalate<br />

<strong>and</strong> mono(2ethyl hexyl) phthalate in mice. Arch. ToxicoL 56(4): 263-266 (cited in U.S.<br />

EPA, 1987b).<br />

Shiota, K. <strong>and</strong> H. Nishimura. 1982 Teratogenicity of di(2ethylhexyl)phthalate<br />

<strong>and</strong> di-n-butyl phthalate in mice. Environ.Health Perspect. 45: 65-70.<br />

Siddiqui, A. <strong>and</strong> S.P. Srivastava. 195Q. Effect of di(2ethylhexyl)phthalate administration on<br />

sperm count <strong>and</strong> on sperm metabolic enzymes. Bull. Environ. Contam. Toxicol. 48(1): 115-<br />

119.<br />

Sittig, M. 1985. Di(2ethylhexyl)phthalate. in: H<strong>and</strong>book of Toxic <strong>and</strong> Hazardous Chemicals<br />

<strong>and</strong> Carcinogens, Second Ed. Noyes publications, Park Ridge, New Jersey. pp. 345-346.<br />

Srivastava, S. <strong>and</strong> S.P. Srivastava. 1991. Effect of di(2ethylhexyl)phthalate on l7bctahydrqteroid<br />

dehydrogenase activity in testis of rat. Toxicology Letters. 57(2): 235-239.<br />

Sullivan, ICE, EL Atlas <strong>and</strong> CS. Giam. 1982. Adsorption of phthalic acid eskrs from<br />

seawater. Environ. Sci. Technol. 16 428-432<br />

Teirlynck, OA <strong>and</strong> J. Belpaire. 1M. Disposition of orally administered di(2-<br />

ethylhexy1)phthalate <strong>and</strong> mono(2ethylhacyl)phthalate in the rat. Arch. ToxicoL 57(4)226-230<br />

"hies, AM, A Korte <strong>and</strong> H. Fleig. 1978. Studies on morbidity in workers exposed to di(2-<br />

ethylhexy1)phthalate. Moeglichkeiten Grenzen BioL MonitJArbietsmed. ProbL<br />

Dienstleitungsgewerbeskbeitsmed. Kolloq., Ber. Jahrestag. 18 137-154 (cited in U.S. EPA,<br />

1987a).<br />

Tomaszewski, D.E., DX A g d <strong>and</strong> RL Melnick. 1986 In vitro steady-state levels of<br />

hydrogen peroxide after exposure of male F344 rats <strong>and</strong> female B6C3F, mice to hepatic<br />

peroxhome proiiferators. Carcinogenesis 7(11): 1871-1876.<br />

U.S. EPA 1980. Ambient Water Quality Criteria for Phthalate Esters. Prepared by the<br />

Office of Research <strong>and</strong> Development, Environmental Criteria <strong>and</strong> Assessment Office,<br />

Cincinnati, OH for the Office of Water Reguiations <strong>and</strong> St<strong>and</strong>ards, Criteria <strong>and</strong> St<strong>and</strong>ards<br />

Division, Washington, DC.<br />

U.S. EPA 1987a. Health Effects Assessment for Selected Phthalic Acid Esters, h p d<br />

by the Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong><br />

Assessment Office,Cincinnati, OH for the Office of Solid Waste <strong>and</strong> Emergency Response,<br />

Washington, Dc.<br />

U.S. EPA. 1987b. Health <strong>and</strong> Environmental Effects Profile for Phthalic Acid Alkyl, Aryi<br />

<strong>and</strong> AuLyuAryl Esters, Prepared by the Office of Health <strong>and</strong> Environmental Assessment,<br />

Environmental Criteria <strong>and</strong> Assessment Office,Cincinnati, OH for the Office of Solid Waste<br />

<strong>and</strong> Emergency Response, Washington, DC<br />

19


U.S. EPA. 1% Health Effects Assessment Summary Tables, Prepared by the Office of<br />

-Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment Office,<br />

Cincinnati, OH for the Office of Emergency <strong>and</strong> Remedial Response, Washington, DC<br />

US. EPA 1992b. Integrated Risk Information System (IRIS). Health Risk Assessment for<br />

Carbon Tetrachloride. OnLine. Office of Health <strong>and</strong> Environmental Assessment,<br />

Environmental Criteria <strong>and</strong> Assessment Office,Cincinnati, OH.<br />

Vainiotalo, S. <strong>and</strong> P. PfaEfli. 1990. Air impurities in the PVC plastics industry. Ann. OCC.<br />

Hyg. 34(6)585-590.<br />

Williams, D.T. <strong>and</strong> BJ. Blanchfield. 197<strong>4.</strong> Retention, excretion <strong>and</strong> metabolism of bis(2-<br />

ethylhexy1)phthalate administered orally to the rat. Bull. Ewiron. Conuun. ToxicOL ll(4):<br />

37 1-378.<br />

Wokowski-Tyl, €2, C. Jones-Price <strong>and</strong> M.C. Marr. 1% Teratologic evaluation of<br />

diethylhexyl phthalate (CAS No. 117-81-7) in Fischer 344 rats. Gov. Rep. Announce. Index<br />

85(2): 70 (cited in U.S. EPA, 1987b).<br />

Wokowski-Tyl, R, C Jones-Price, M.C. Marr <strong>and</strong> C.A. Kimmel. 1984b. Teratologic<br />

evaluation of diethylhexyl phthalate (CAS No. 117-81-7) in CD-1 mice. Gov. Rep. Announce.<br />

Index. 8!5(2): 70 (cited in US. EPA, 1987b).<br />

Woodward, K. N. 1990. Phthalate esters, cystic kidney disease in animals <strong>and</strong> possible effects<br />

on human health: a review. Human <strong>and</strong> Exp. ToxiwL 9(6): 397401.<br />

Yagi, Y.,Y. Nhura, L Tomita, K Tsuchikawa <strong>and</strong> N. Shimoi. 1980. Teratogenic potential<br />

of di- <strong>and</strong> mono-(2ethylhexyl)phthalate in mice. J. Emriron. PathoL Toxiwl. 4(2-3): 533-544<br />

(cited in us. EPh lm).<br />

20


ToxIclTy SUMMARY FOR<br />

CADMTUM<br />

November 1991<br />

Prepared by:<br />

Robert k Young, Ph.D., D.AB.T.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory*<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc, for the U.S. Department of<br />

Energy under Contract No. DE-AC05-840R21400


7Xs page inremhmliy left blank


ExEcuTlVESuMMARY<br />

Cadmium is a naturally occurring metal that is used in various chemical forms in<br />

metallurgical <strong>and</strong> other industrial<br />

<strong>and</strong> in the production of pigments.<br />

Environmental exposure can occur via the diet <strong>and</strong> drinking water (ATSDR, 1989).<br />

Cadmium is absorbed more efficiently by the lungs (30 to 60%) than by the<br />

gastrointestinal tract, the latter being a saturable p'ocess (Nordberg et al., 1985). Cadmium<br />

is transported in the blood <strong>and</strong> widely distributed in the body but accumulates primarily in the<br />

liver <strong>and</strong> kidneys (Goyer, 1991). Cadmium burden (especially in the kidneys <strong>and</strong> liver) tends<br />

to increase in a linear fashion up to about 50 or 60 years of age after which the body burdem<br />

remains somewhat constant. Metabolic transformations of cadmium are limited to its binding<br />

to protein <strong>and</strong> nonprotein sulfhydryl groups, <strong>and</strong> various macromolecules, such as<br />

metallothionein, which is especially important in the kidneys <strong>and</strong> liver (ATSDR, 1989).<br />

Cadmium is excreted primarily in the urine.<br />

Acute oral exposure to 20-30 g have caused fatalities in humans. Exposure to lower<br />

amounts may cause gastrointestinal irritation, vomiting, abdominal pain, <strong>and</strong> diarrhea<br />

'(ATSDR, 1989). An asymptomatic period of one-half to one hour may precede the onset of<br />

clinical signs. Oral LDm values in animals range from 63 to 1125 m@g, depending on the<br />

cadmium compound (USAF, 1990). Longer term exposure to cadmium primarily affects the<br />

kidneys, resulting in tubular proteinosis although other conditions such as "itai-ita? disease<br />

may involve the skeletal system. Cadmium involvement in hypertension is not fully<br />

understood (Goyer, 1991).<br />

Inhalation exposure to cadmium <strong>and</strong> cadmium compounds may result in effects<br />

including headache, chest pains, muscular weakness, pulmonary edema, <strong>and</strong> death (USAF,<br />

1990). The l-minute <strong>and</strong> 10-minute lethal concentration of cadmium for humans has been<br />

estimated to be about 2,5500 <strong>and</strong> 250 mg/m3, respectively (Barrett et al., 1947; Beton et aL,<br />

1966). An &hour TWA (time-weighted-average) exposure level of 5 mg/m3 has been<br />

estimated for lethal effects of inhalation exposure to cadmium. <strong>and</strong> exposure to 1 mg/m3 is<br />

considered to be immediately dangerous to human health (Friberg, 1950). Renal toxicity<br />

(tubular proteinosis) may also result from inhalation exposure to cadmium (Goyer, 1991).<br />

Chronic oral RfDs of SE-4 <strong>and</strong> 1E-3 mg/kg/day have been established for cadmium<br />

e;xposure via drinking water <strong>and</strong> food, respectively (U.S. EPA, 1991). Both values reflect<br />

incorporation of an uncertainty factor of 10. The RfDs are based on an extensive data base<br />

regarding toxicokinetics <strong>and</strong> toxicity in both human <strong>and</strong> animals. the critical effect being renal<br />

tubular proteinuria Confidence in the RfD <strong>and</strong> data base is high.<br />

Inhalation RfC values are currently not available.<br />

The target organ for cadmium toxicity via oral exposure is the kidney (Goyer, 1991).<br />

For inhalation exposure, both the lungs <strong>and</strong> kidneys are target organs for cadmiwn-induced<br />

toxicity (ATSDR, 1989; Goyer, 1991).<br />

1


There is limited evidence from epidemiologic studies for cadmium-related respiratory<br />

tract cancer (ATSDR, 1989). An inhalation unit risk of 1.8E-3 ( pg/m3)" <strong>and</strong> an inhalation<br />

slope factor of 6.1E+O (mg/kg/day)-' are based on respiratory tract cancer associated with<br />

occupational exposure (U.S. EPA, 1985). Based on limited evidence from multiple<br />

occupational exposure studies <strong>and</strong> adequate animal data, cadmium is placed in weight-ofevidence<br />

group B1 - probable human carcinogen.<br />

2


1. PJTRODUCIlON<br />

Cadmium (Cd) is a naturally occurring metallic element that is used for electroplating<br />

<strong>and</strong> galvanization processes, in the production of pigments, in batteries, as a chemical reagent,<br />

<strong>and</strong> in miscellaneous industrial processes (A'ISDR, 1989). Cadmium compounds have varying<br />

degrees of solubility ranging from very soluble to nearly insoluble. The solubility affects their<br />

absorption <strong>and</strong> toxicity. Exposure to cadmium <strong>and</strong> cadmium compounds may occur in both<br />

occupational <strong>and</strong> environmental settings, the latter primarily via the diet <strong>and</strong> drinking water<br />

(ATSDR, 1989).<br />

21. ABSORPTION<br />

Cadmium is more efficiently absorbed from the lungs than from the gastrointestinal<br />

tract (ATSDR, 1989). The absorption efficiency is a function of solubility of the specific<br />

cadmium compound as well as its exposure concentration <strong>and</strong> route.<br />

Inhalation absorption usually involves cadmium in a particulate matter form with<br />

absorption being a function of deposition, which in turn is dependent upon the particle size<br />

(particles z 1Opm diameter tend to be deposited in the upper airways <strong>and</strong> particles s 0.1 Vm<br />

diameter are deposited in the alveolar region). Alveolar deposition efficiency in animal<br />

models ranges from 5 to 20% (Barrett et aL, 1947; Boisset et aL, 1978). Based on<br />

physiological modeling, cadmium deposition in the alveolar region of humans was estimated<br />

to be up to 50% for small particles (Nordberg et aL 1985). Actual cadmium absorption via<br />

inhalation exposure has been estimated to be 30 to 60% in humans (Fnirg et aL, 197%<br />

Elinder et aL, 1976). -<br />

Absorption of cadmium from the gastrointestinal tract appears to be a saturable<br />

process with the fraction absorbed decreasing at high doses (Nordberg et al., 1985). It is also<br />

important to distinguish true absorption from simple retention of cadmium in the rnkrodi<br />

of the small intestine (Foulkes et al., 1986). Shaikb <strong>and</strong> Smith (1980) reported a mean<br />

retention of 28% (1.1 to 7.0% range) for 12 human subjects given a single oral dost of<br />

radiolabeled cadmium chloride, <strong>and</strong> McLellan et aL (1978) reported 5.9% retention of<br />

cadmium chloride by 14 human subjects.<br />

Also of importance relative to cadmium absorption is that its absorption may be<br />

decreased by divalent <strong>and</strong> trivalent cations (Zn", Mg+2, CP3), <strong>and</strong> increased by iron <strong>and</strong><br />

calcium deficiencies (Flanagan et al., 1978; Foulkes et al., 1986, Goyer, 1991). Dermal<br />

absorption is relatively unimportant (ATSDR, 1989).<br />

22 DISITUBUTION<br />

Cadmium is transported in the blood by red blood cells <strong>and</strong> high-molecular-weight<br />

proteins such as albumin (Goyer, 1991). Normal blood cadmium levels in adults arc <<br />

3


lpg/dL Although cadmium is widely distributed throughout the body, most (50 to 70% of<br />

the body burden) accumulates in the kidneys <strong>and</strong> liver (Goyer, 1991). Cadmium burden,<br />

especially in the kidneys, tends to increase in a linear fashion with age up to about 50 or 60<br />

years of age after which the kidney levels remain somewhat constant or slightly decline<br />

(Goyer, 1991). There is evidence that the placenta is a partial barrier to cadmium, <strong>and</strong> that<br />

the fetus is exposed to only small amounts of maternal cadmium (ATSDR 1989).<br />

As with most metallic elements, there is little or no direct metabolic conversions of<br />

cadmium, but rather binding to various biological components, such as protein <strong>and</strong> nonprotein<br />

sulfhydryl groups <strong>and</strong> anionic groups of various macromolecules (ATSDR 1989). Of special<br />

importance, is the binding protein, metallothionein which is very effective in binding cadmium<br />

<strong>and</strong> some other metals <strong>and</strong> is instrumental in determining the disposition of cadmium in the<br />

body (e-g. concentration of cadmium in the kidneys).<br />

2<strong>4.</strong> EXCXZEI'ION<br />

The principal route of excretion is via the urine. with average daily excretion for<br />

humans being about 2 to 3 pg (ATSDR, 1989). Daily excretion represents on@ a small<br />

percentage of the total body burden, which accounts for the 17 to >30 years half-life of<br />

cadmium in the body (Tsuchiya et aL, 1972, Friirg et aL, 1974). Unabsorbed cadmium is<br />

removed from the gastrointestinal tract by fecal excretion. Typical daily cadmium excretion<br />

has been reported to be about 0.01% of the total body burden (ATSDR, 1989). There is<br />

some evidence for biliary excretion of cadmium (Klaassen et aL, 1978).<br />

3. NONCARCINOGENIC HEALTH EFFECIS<br />

3.1. ORAL EXPOSURES<br />

3.1.1. Acute Toxicity<br />

3.1.1.1. Human<br />

Doses of 1,500 to 8,900 mg (20 to 30 mg/kg) of cadmium have resulted in human<br />

fatalities, but generally, fatal poisoning from cadmium is rare (ATSDR, 1989). High doses<br />

of cadmium are known to cause gastrointestinal irritation resulting in vomiting, abdominal<br />

pain, <strong>and</strong> diarrhea (A'ISDR, 1989). Lauwerys (1979) reported that the emetic threshold for<br />

cadmium in drinking water was about 15 mg/L <strong>and</strong> CEC (1978) reported that 3 mg was an<br />

emetic threshold.<br />

Following ingestion of cadmium, an asymptomatic period of 0.5 to 1.0 hour may<br />

precede the onset of clinical signs. Depending on the severity of exposurer clinical signs of<br />

cadmium poisoning following acute exposure include: nausea, vomiting, abdominal cramps,<br />

headache, muscle cramps, exhaustion, shock, <strong>and</strong> death (USAF, 1990).<br />

4-


3.1.1.2 Animal<br />

Oral LDM values for animals range from 225 to 890 mag for elemental cadmium,<br />

63 to 88 mag for cadmium chloride, 72 mg/kg for cadmium oxide, <strong>and</strong> 590 to 1125 mgkg<br />

for cadmium stearate (USAF, 1990).<br />

3.1.2 Subchronic Toxicity<br />

3.121. Human<br />

Because the toxic effects of cadmium are a function of a critical concentration being<br />

attained in a target organ, similar effects will occur following long-term exposure to low<br />

cadmium levels <strong>and</strong><br />

short-term exposure to high concentrations (Wang <strong>and</strong> Foulkes, 1984). Consequently, renal<br />

<strong>and</strong> hepatic toxicity may occur if toxic cadmium levels are attained in these organs even<br />

during subchronic exposure, A description of cadmium-induced toxicity foilowing oral<br />

exposure is presented in <strong>Section</strong> 3.1.3. Generally, cadmium is not as toxic via oral routes as<br />

via inhalation.<br />

3.1.22 Animal<br />

Exposure of rabbits to 1.5 mol cadmium chloride in drinking water (equivalent to<br />

13 pg/kg/day) produced histological alterations in the liver but no clinical signs of toxicity<br />

(Stowe et aL, 1972). In a study by Kotsonis <strong>and</strong> Klaassen (1978), rats exhibited proteinuria<br />

after receiving cadmium chloride in the drinking water for six weeks at 30 or 100 mg/L<br />

(equivalent to 3.1 <strong>and</strong> 8.0 mg Wkg/day).<br />

Although the effects of cadmium on the immune system of humans is unclear,<br />

evidence for cadmium-induced immunotoxicity in animals is available. Koller et aL (1979<br />

noted a decrease in the number of spleen plaque-forming cells in mice receiving cadmium<br />

at 0.6 mg/kg/day for 10 weeks, <strong>and</strong> Blakley (1985) reported a dosedependent suppression of<br />

the humoral immune system in mice receiving cadmium in drinking water at concentrations<br />

of 5 to 50 mg/L for three weeks. These immune system effects occurred at kidney tissue<br />

concentrations (0.3 to 6.0 pg/g) lower than those associated with renal toxicity.<br />

3.13. ChronicToxicity<br />

3.13.1. Humans<br />

The most serious chronic effect of oral exposure to cadmium is renal toxicity. This<br />

critical effect is characterized by tubular proteinuria resulting from renal tubular dysfunction.<br />

Friirg et at (1974) estimated that this critical effect will not occur in humans until the<br />

cadmium concentration in the renal cortex exceeds 200 pg/g.<br />

Dietary intake of cadmium has also been implicated in osteomalacia, wteoporosis <strong>and</strong><br />

spontaneous fractures, conditions collectively termed "itai-itai" (ouch-ouch) disease <strong>and</strong><br />

5


originally documented in postmenopausal women in cadmiumcontaminated areas of Japan<br />

(Friberg et al., 1974).<br />

Cadmium exposure has also been implicated in hypertensive disorders, a situation that<br />

is currently not thoroughly understood or verified (ATSDR, 1989).<br />

3.13.1. Animals<br />

Rats given cadmium chloride in the drinking water at a concentration of 10 mg/L (1.2<br />

mg Cd/kg/day) exhibited no renal effects even after 24 months, although higher exposure<br />

levels induced proteinuria after six weeks exposure (Kotsonis <strong>and</strong> Klaassen, 1978).<br />

3.1.<strong>4.</strong> Developmental <strong>and</strong> Repducthe Tdty<br />

3.1.<strong>4.</strong>1. Human<br />

Developmental <strong>and</strong> reproductive toxicity in humans have not been demonstrated for<br />

oral exposure to cadmium (A'ISDR. 1989).<br />

3-1.<strong>4.</strong>1. Animal<br />

Developmental toxicity data for cadmium administered orally to rats are equivocal.<br />

Pond <strong>and</strong> Walker (1975) reported few, if any effects, for rats exposed to cadmium chloride<br />

in the drinking water (15 rngkglday) during gestation. Baranski et al. (1985) reported<br />

teratogenic effects (fused or absent legs) in rats following gavage administration of cadmium<br />

chloride (40 mg/kg/day) during gestation. Neurological effects in rat pups were detected<br />

following gestational exposure to 0.4 or 4 mg Wkg (Baranski et aL, 1986).<br />

3.15. ReEereMz h<br />

3.15.1. Subchronic<br />

ORAL, RfD,:<br />

UNCERTAINTY FACTOR:<br />

NOAEL<br />

Not available<br />

Not available<br />

Not available<br />

3.152 Chronic<br />

ORAL IUD,:<br />

UNCERTAIN'WFACTOR:<br />

MODIFYING FACTOR:<br />

NOAEL:<br />

mm<br />

CONFIDENCE:<br />

study<br />

5E-4 mg/ltg/day (water) (U.S. EPA, 1991)<br />

1E-3 mg/kg/day (food)<br />

10 (for both food <strong>and</strong> water)<br />

1 (for both food <strong>and</strong> water)<br />

0.005 mglkglday (water)<br />

0.01 mg/kg/day (food)<br />

Not available<br />

Not applicable<br />

6


Data base<br />

RfD<br />

High<br />

High<br />

VERIFICATION DATE: 05/25/88<br />

PRINCIPAL STUDYThe data supporting the IUD have been derived from<br />

many animal <strong>and</strong> human studies that have provided information on cadmium toxicity<br />

(renal toxicity using proteinuria as the critical effect) <strong>and</strong> the calculation of<br />

pharmacokinetic parameters regarding calcium absorption, distribution <strong>and</strong> excretion.<br />

COMMENTS: Due to background cadmium in the diet, no subchronic RfD<br />

was calculated.<br />

32 IIWALA'IIONEXPOSURES<br />

3.21. AcuteToxiCity<br />

321.1. Human<br />

Inhalation of cadmium fumes or dust may result in a wide range of effects, including<br />

a metallic taste, headache, dyspnea, chest pains, cough with foamy or bloody sputum, <strong>and</strong><br />

muscularwcakness. Severe exposure may result in pulmonaxy edema <strong>and</strong> death (USAF, 1990).<br />

If the pulmonary edema is resolved, late-occurring kidney <strong>and</strong>/or liver damage may develop.<br />

Peculiar to inhalation exposure to cadmium is an asymptomatic period that may precede<br />

clinical illness by four to eight hours (USAF, 1990).<br />

Based on cadmium lung burdens measured during postmortem examinations, Bamtt<br />

et aL (1947) estimated a 1-minute lethal concentration of 2,500 mum3. Beton et aL (1%<br />

conducted similar calculations <strong>and</strong> reported a 10-minute lethal concentration of 250 mghn 1 .<br />

This value was further extrapolated to an &hour lethal concentration of 5 mg/m3. F n i et<br />

aL (1974) indicated that exposure to 1 mg Wm3 for 8 hours is "immediately dangerous to<br />

humans" <strong>and</strong> the World Health Organization (WHO, 1980) identified 05 mg Wm3 as the<br />

threshold for respiratory effects resulting from an &hour exposure.<br />

3212 Animal<br />

Acute toxicity values (10-min. LG) for inhalation exposure of animals (monkeys, rats,<br />

mice, guinea pigs, dogs) to cadmium oxide range from 340 mg/m3 to 15 g/m3 (USAF, 1990).<br />

3221. Human<br />

8<br />

Both pulmonary effects (emphysema, bronchiolitis, alveolitis) <strong>and</strong> renal effects<br />

(proteinuria) may occur following subchronic inhalation exposure to cadmium <strong>and</strong> cadmiumcompounds<br />

(A'ISDR, 1989).<br />

7'


33.22 Animal<br />

Pulmonary <strong>and</strong> renal toxicity have been documented for short-term inhalation<br />

exposure of animals to cadmium <strong>and</strong> cadmium compounds (USAF, 1990). Dosedependent<br />

fibrotic lesions were observed in rats exposed to cadmium chloride aerosol at 0.3 to 1.0 mg/m3,<br />

6 hourslday for 12 weeks, but at a concentration of 20 mg/m3 most rats died within 45 days<br />

(Kutzman et aL, 1986). Friirg (1950) reported emphysema in rabbits exposed to cadmium<br />

chloride at 5 mg/m3, 3 hourslday, 20 daydmonth for 8 months.<br />

3-3.1. Human<br />

Several occupational exposure studies have indicated that inhalation to cadmium dust<br />

<strong>and</strong> cadmium compounds may result in renal <strong>and</strong> pulmonary effects.<br />

Bonnell (1955) reported that occupational exposure to cadmium oxide (1 to 270<br />

&m3) resulted in proteinuria in 16% of the workers exposed for five years or more, <strong>and</strong> an<br />

increased incidence of emphysema in those exposed for more than 10 years. The latter group,<br />

however, may have received much higher initial exposures. Kidney lesions were also reported<br />

for the majority of workers exposed to the compound at a concentration of 20 pg/m3 for 27<br />

years (Materne et aL, 1975) <strong>and</strong> tubular proteinuria detected in workers exposed to cadmium<br />

dust (0.05 mg/m3) for 6 to 12 years (Kjellstrom et aL 1977).<br />

Based on occupational exposure studies, an &hour TWA (time-weighted-average)<br />

concentration of 0.02 mg/m3 was established for a 20-year exposure to cadmium (OSHA,<br />

1989), which is equivalent to continuous exposure to 0.007 mum3 over a lifetime (AIISDR,<br />

1989).<br />

Chronic inhalation exposure studies for animals have demonstrated the carcinogenic<br />

potential of cadmium chloride <strong>and</strong> are discussed in <strong>Section</strong> <strong>4.</strong>22<br />

32<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

32<strong>4.</strong>1. Huuuun<br />

Definitive data were not available regarding the developmental or reproductive<br />

toxicity of cadmium or cadmium compounds in humans.<br />

3242 Animal<br />

Decreasedletal weight (with <strong>and</strong> without decreased maternal body weight) <strong>and</strong> minor<br />

neurobehavioral alterations in pups have been reported for rats exposed to cadmium oxide<br />

(0.16 mg/m3) or cadmium sulfate (about 3 mg/m3) during gestation (AlSDR, 1989). No other<br />

significant effects have been documented.<br />

8-


3-3. ReferenceC~ncentration<br />

The RfC for cadmium is currently under review (US. EPA, 1991).<br />

33. UI'HERROUTESOF'E)s9o5uRE<br />

33.1. AcuteToxiUty<br />

No data were available regarding the acute toxicity of cadmium by other routes of<br />

exposure.<br />

No data were available regarding the subchronic toxicity of cadmium by other routes<br />

of exposure.<br />

No data were! available regarding the chronic toxicity of cadmium by other routes of<br />

exposure.<br />

33.<strong>4.</strong> DeveIopmerdToxicity<br />

No data were available regarding the developmental toxicity of cadmium by other<br />

routes of exposure.<br />

3.<strong>4.</strong> TARGEI' ORGANWCRITICAL EFFECLS<br />

3.<strong>4.</strong>1.1. Primary Target@)<br />

1. Kidney: Renal tubular proteinuria is the primary toxic effect of long-term cadmium<br />

exposure.<br />

2 Gastrointestinal tract: Acute exposure to high levels of cadmium <strong>and</strong> cadmium<br />

compounds may cause irritation, vomiting, nausea, <strong>and</strong> diarrhea.<br />

3.<strong>4.</strong>1.2 Other Target@)<br />

The liver, bones, testes, <strong>and</strong> cardiovascular system have been shown to be affected to<br />

various de- by cadmium.<br />

9


3.421, Primary Target@)<br />

1. Kidney: Renal tubular proteinuria may result from chronic exposure to cadmium<br />

<strong>and</strong> cadmium compounds.<br />

2 Lung: Inhalation exposure to cadmium dust, fumes, aerosols, <strong>and</strong> some cadmium<br />

compounds causes irritation of the respiratory tract, emphysema, <strong>and</strong> death for acute<br />

exposure to high cadmium concentrations.<br />

3.<strong>4.</strong>22 Other Target@)<br />

No data were available indicating additional target organs/tissues for inhalation<br />

exposure to cadmium <strong>and</strong> cadmium compounds.<br />

<strong>4.</strong>1. ORAL ExPOSURE<br />

<strong>4.</strong>1.1. Human<br />

Limited epidemiologic studies have indicated that exposure to cadmium in food or<br />

drinking water is not carcinogenic (Bernard <strong>and</strong> Lauwerys, 1986).<br />

<strong>4.</strong>1.2. Animal<br />

Chronic exposure studies using animals exposed to cadmium in the diet or drinking<br />

water, have all provided negative results (ATSDR, 1989).<br />

42 INHALATION EXPOSURE<br />

421. Human<br />

Limited evidence is available from epidemiologic studies indicating that inhalation<br />

exposure to cadmium may be associated with an i n d incidence of resphtory tract<br />

cancer (ATSDR, 1989). An exposure-related increase in mortality due to lung cancer in<br />

workers with cumulative exposures of 585 to >2,920 mg Wm3 (equivalent to TWA daily<br />

exposures of 168 to 2,522 pg/ Cd/m3) was reported by Thun et aL (1985).<br />

Limited evidence is available showing that inhalation exposure to cadmium dust <strong>and</strong><br />

fumes may be &iated with prostate cancer, but the total number of cases in the various<br />

studies is small (ATSDR, 1989).<br />

A unit risk of 1.8 x lo3 ( pg/m3)" based on an increase in respiratory tract tumors in<br />

cadmium smelter workers was calculated by the U.S. EPA (1985).<br />

10


Chronic exposure of rats to cadmium chloride aerosols (125, 25, or 50 (rg/m3)<br />

produced a dose-related increase in the frequency of primary lung carcinomas (Takenaka et<br />

aL, 1983).<br />

43. OTRER ROUTES OF ExposuRE<br />

No data were available regarding the carcinogenic potential of cadmium by other<br />

routes of exposure.<br />

<strong>4.</strong><strong>4.</strong> EPA WEXGHT-0F-EVI.D~~ CLASSIFICATION<br />

<strong>4.</strong><strong>4.</strong>1. Oral<br />

Not assigned.<br />

<strong>4.</strong>42 Inhalation<br />

Classification-B1: Probable human carcinogen<br />

Basis - Limited evidence from multiple occupational exposure studies showing an<br />

association between cadmium exposure <strong>and</strong> increased incidence of lung cancer.<br />

Adequate data are available showing a carcinogenic response to cadmium by rats <strong>and</strong><br />

mice following inhalation exposure <strong>and</strong> parenteral administration.<br />

45. CARCINOGENICITY SLDPE FACIORS<br />

45.1. Oral<br />

Not assigned.<br />

452 Inhalation<br />

SLOPE FACTOR<br />

VERIFICATION DATE:<br />

(U.S. EPA, 1985; 1991)<br />

6.1 (mg/kg/day)-'<br />

ll/l2/Ss<br />

COMMENT: The inhalation unit risk is based on occupational exposure of humans<br />

to cadmium fumes (Thun et al, 1985).<br />

11


5. REFERENCES<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1989. Toxicological profile for<br />

cadmium. ATSDRKJS. Public Health Service, ATSDRKP-88/08.<br />

Baranski, B. 1985. Effect of exposure of pregnant rats to cadmium on prenatal <strong>and</strong> postnatal<br />

development of the young. J. Hyg. Epidemiol. MicrobioL Immunol. 29253-262. (Cited in<br />

A'ISDR, 1989)<br />

Baranski, B. 1986. E€€& of maternal cadmium exposure on postnatal development <strong>and</strong> tissue<br />

cadmium, copper, <strong>and</strong> zinc concentrations in rats. Arch. ToxicoL 58Z5-260. (Cited in<br />

ATSDR, 1989)<br />

Barrett, EM., DA<br />

Invin <strong>and</strong> E Semmons. 1947. Studies on the toxicity of inhaled cadmium.<br />

I. The acute toxicity of cadmium oxide by inhalation. J. Ing. Hyg. Toxicol. 29279. (Cited in<br />

ATSDR, 1989)<br />

Bernard, k <strong>and</strong> R. Lauwerys. 1986. Cadmium in human populations. Experimentia 4&143-<br />

152 (Cited in A'ISDR 1989)<br />

Beton, D.C, G.S. Andrew, H. J. Davies, L Howelss <strong>and</strong> G.F. Smith. 1966. Acute cadmium<br />

fume poisoning Frve cases with one death from renal necrosis. Br. J. Ind Med. 23292.<br />

(Cited in ATSDR, 1989)<br />

Blakley, B.R 1985. The effects of cadmium chloride on the immune response in mice. Can.<br />

J. amp. Med. 49%)4-108 (Cited in A'ISDR, 1989)<br />

Boisset, U, E Girard, J. Godin <strong>and</strong> C. Boudene. 1978. Cadmium content of lung, liver, <strong>and</strong><br />

kidney in rats exposed to cadmium oxide fumes. Int. Arch. Occup. Environ. Health 41:41-53.<br />

(Cited in ATSDR, 1989)<br />

Bonneil, J.A 1955. Emphysema <strong>and</strong> proteinuria in men casting copper-cadmium alloys. Br.<br />

J. Ind Med. 12181-197. (Cited in ATSDR 1989)<br />

CEC (Commission of the European Communities). 1978. Criteria (ddeffect relationships)<br />

for cadmium. Pergamon Press, Oxford. pp. 1-1%<br />

Elinder, CG., T. Kjellstmn, L Friirg, B. Lind <strong>and</strong> L Linman. 1976. Cadmium in kidney<br />

cortex, liver, <strong>and</strong> pancreas for Swedish autopsies. Arch. Environ. Health 31292-302.<br />

Flanagan, P.R, J. Mckllan, J. Haist, M.G. Cherian, MJ. Chamberlain <strong>and</strong> LS. Valbar.<br />

1978. Increased dietary cadmium absorption in mice <strong>and</strong> human subjects with iron deficiency.<br />

Gastroenterology 72M1-846.<br />

Foulkes, EC. 1986. Absorption of cadmium. In: Foulkes, EC, ed. H<strong>and</strong>book of<br />

Experimental Pharmacology. Vol. SO, Springer-Verlag, Berlin, pp. 75-100. (Cited in ATSDR<br />

1989)<br />

12


Friirg, L. 1950. Health hazards in the manufacture of alkaline accumulators with special<br />

reference to chronic cadmium poisoning. Acta Med. Scad. (Suppl24O) 1381-12<strong>4.</strong> (Cited in<br />

ATSDR, 1989)<br />

Friirg, I,., M. Piscator, G.F. Nordberg <strong>and</strong> T. Kjellstrom. 197<strong>4.</strong> Cadmium in environment.<br />

2nd. Ed. CRC Press, Boca Raton, FL<br />

Goyer. R 1991. Toxic effects of metals. In: Amdur, M.O., J.D. Doull <strong>and</strong> C.D. Klaassen,<br />

Eds. Casarett <strong>and</strong> Doull's Toximlogy. 4th ed Pergamon Press, New York. pp.623-680.<br />

Klaassen, C. D. 1978. Effect of metallothionein on hepatic disposition of metals. Am. J.<br />

PhysioL 234:E47-E53. (Cited in ATSDR, 1989)<br />

Kjellstrom, T., P.E Evrin <strong>and</strong> B. Rahnster. 1977. Dose-response analysis of cadmium-induced<br />

tubular proteinuria A study of urinary Brmicroglobulin excretion among workers in a battery<br />

factory. Environ. Res 13303-317. (Cited in ATSDR, 1989)<br />

Koller, LD., J. H. Exon <strong>and</strong> J.G. Roan. 1975. Antibody suppression by cadmium. Arch.<br />

Environ. Health 3098. (Cited in ATSDR 1989)<br />

Kotsonis, F. N. <strong>and</strong> C. D. Klaassen. 1978. The relationship of metallothionein to the toxicity<br />

of cadmium after prolonged administration to rats. ToxicoL Appl. Pharmacol. 4639-5<strong>4.</strong><br />

Kutzman, RS., RT. Drew, RN. Shiotsuks <strong>and</strong> B. Y. CoCkreU 1986. Pulmonary changa<br />

resulting from subchronic exposure to cadmium chloride aerosoL J. Toxicol.Environ. Health<br />

17:175-189. (Cited in ATSDR, 1989)<br />

Lauwerys, R 1979. Cadmium in man. In: Webb, N. ed. %e chemistry, biochemistry, <strong>and</strong><br />

biology of cadmium. Elscvier/North Holl<strong>and</strong> Biomedical Press, pp. 433-453. (Cited in A mR,<br />

1989)<br />

Materne, D. R Lauwerys, J. P. Buchet, H. Roels, J. Brouwers <strong>and</strong> D. Stan- 1975.<br />

Investigations sur le risques resultant de I'exposition au cadmium dam deux enterprises de<br />

production et deux entreprises d'utilisation du cadmium. Cahiers de Medecine du Travail<br />

XII:l.<br />

McLellan, J.S. P. R Flanagan, M. J. Chamberlain <strong>and</strong> L S. Valberg. 1978. Measurement of<br />

dietary cadmium absorption in humans. J. ToxicoL Environ. Health 4131-138. (Cited in<br />

ATSDR, 1989)<br />

Nordberg, G. F., T. Kjellstrom <strong>and</strong> M. Nordberg. 1985. Kinetics <strong>and</strong> metabolism. In: Fnkrg,<br />

L, CG. Elinder, T.Kjellstrom <strong>and</strong> G.F. Nordberg, eds. Cadmium <strong>and</strong> Health A toxicological<br />

<strong>and</strong> epidemiological appraisal. VoL 1. Exposure, dose, <strong>and</strong> metabolism. CRC Press, Boca<br />

Ratori, FL.,pp. 103-178. (Cited in ATsDR, 1989)<br />

OSHA (Occupational Safety <strong>and</strong> Health Administration). 1989. Air contaminants: final rule.<br />

29CFR1910, Fed. Regist. 1/19/89,542332-2983, as corrected W.2805<strong>4.</strong><br />

13


Pond, W. G. <strong>and</strong> E. F.Walker. 1975. Effects of dietary Ca <strong>and</strong> Cd level of pregnant rats on<br />

reproduction <strong>and</strong> on dam <strong>and</strong> progeny tissue mineral concentrations. Proc. Sac. Exp. BioL<br />

Med. 148:655. (Cited in ATSDR, 1989)<br />

Shaikh, 2. A <strong>and</strong> J. C Smith. 1980. Metabolism of orally ingested cadmium in humans. In:<br />

Holmstead, B., et al., eds. Mechanisms of toxicity <strong>and</strong> hazard evaluation. Elsevier/North<br />

Holl<strong>and</strong>, Amsterdam. pp. 569-57<strong>4.</strong> (Cited in A'ISDR, 1989)<br />

Stowe, H. D., M. Wilsom <strong>and</strong> R A Gayer. 1972. Clinical <strong>and</strong> morphological effects of oral<br />

cadmium toxicity in rabbits. Arch. PathoL M389-405.<br />

Takenaka, S, H. Oldiges, H. Konig, D. Hochrainer <strong>and</strong> G. OberdOrster. 1983.<br />

Carcinogenicity of cadmium chloride aerosols in Wistar rats. J. NatL Cancer Inst. 70367-373.<br />

Thun, M. J., T. M. Schnorr, A Smith, W. E Halperin <strong>and</strong> R A Lemen. 1985. Mortality<br />

among a cohort of U.S. cadmium production workers - an update. J. NatL Cancer Inst.<br />

74:325-333. (Cited in ATSDR, 1989)<br />

Tsuchiya, IC, Y. Seki <strong>and</strong> M. Sugita 1972 Organ <strong>and</strong> tissue cadmium concentration of<br />

cadavers from accidental deaths. Proc. 17th Internat. Congress Occup. Health, Buenos Aires.<br />

(Cited in A'ISDR, 1989)<br />

USAF. 1990. Cadmium. In: Installation Restoration Program Toxicology Guide, VoL 5. Hany<br />

G. Armstrong Aerospace Medical Research Laboratory, Wright Patterson AFB, OH.<br />

U.S. EPA 1985. Integrated Risk Information System (IRIS). On-tine file, 03/31/87.<br />

U.S.EPA 1991. Health Ef€ezts Summary Tables, IT-1991 Annual. Off~ce of Research <strong>and</strong><br />

Development, Office oflkergenq <strong>and</strong> Remedial Response, Washington, D.C OERR<br />

92OO.6-3O3(91-1).<br />

Wang, X P. <strong>and</strong> E C. Foulkes. 198<strong>4.</strong> Specificity of acute effects of cadmium on renal<br />

function. Toximlogy 30243-247. (Cited in ATSDR, 1989)<br />

WHO (World Health Organization). 1980. Recommended health-based limits in occupational<br />

exposure to heavy metals. Geneva. (Cited ATsDR, 1989)<br />

14


TOXICITY SUMMARY FOR<br />

1,l-DICHLOROETHYLENE<br />

September 1994<br />

Prepared by<br />

Rosmarie A. Faust, Ph.D.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Program<br />

Biomdcal <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Depariment of Energy under contract<br />

NO. DE-AC05-840R21400


THIS PAGE INTENTIONALLY LEFT BLANK


EXECUTIVE SUMMARY<br />

1,l -Dichloroethylene (CAS No. 75-35-4), also known as 1 , 1 -dichloroethene <strong>and</strong> vinylidine chloride,<br />

is a colorless liquid that is used primarily in the production of polyvinylidine chloride (PVC) copolymers <strong>and</strong><br />

as an intermebate for synthesis of organic chemicals. The major application for PVC copolymers is the<br />

production of flexible films for food packagmg such as Saran@ wrap (ATSDR, 1993).<br />

1,l-Dichloroethylene does not occuf naturally (IARC, 1986) but is found in the environment due to<br />

releases associated with its production <strong>and</strong> transport <strong>and</strong> with the production of its polymers. Because of its<br />

high volatility, releases to the atmosphere are the greatest source of ambient 1,l-dxhloroethylene. Smaller<br />

amounts are released to surface waters <strong>and</strong> soils (ATSDR, 1993). Loss of 1,l-dichloroethylene fiom water<br />

<strong>and</strong> soils is primarily due to volatilization. In the atmosphere, reaction with photochemically generated<br />

hydroxyl radicals is expected to be the predominant removal mechanism (EPA, 1987). Human exposure to<br />

1,l-dichloroethylene is potentially highest in workplace settings <strong>and</strong> in the vicinity of hazardous waste sites<br />

where the compound may contaminate environmental media (ATSDR, 1993).<br />

The primary effect of acute exposure to hgh concentrations (approximately 4000 ppm) of<br />

1,l-dichloroethylene vapor in humans is central nervous system (CNS) depression which may progress to<br />

unconsciousness (Gosselin et al., 1984). Occupational exposure has been reported to cause liver dyshction<br />

in workers (Tiemey et al., 1979). 1,l-Dichloroethylene is irritating when applied to the skin <strong>and</strong> prolonged<br />

contact can cause first degree burns (Tiemey et al., 1979). Direct contact with the eyes may cause<br />

conjunctivitis <strong>and</strong> transient corneal injury (IARC, 1986).<br />

In experimental animals, the liver <strong>and</strong> kidneys are target organs for the toxic effects of 1,ldichloroethylene.<br />

Subchronic oral exposure for 90 days to 1,l-dlchloroethylene in drinking water produced<br />

slight hepatotoxic effects at 200 ppm (Rampy et al., 1977), <strong>and</strong> chronic oral exposure to drinking water for<br />

2 years produced hepatocellular changes in males at 2100 ppm <strong>and</strong> in females at 250 ppm (Quast et al.,<br />

1983). Gavage administration of 10 mg/kg/day, 5 daydweek for 2 years produced chronic inflammation of<br />

the kidney in male <strong>and</strong> female rats <strong>and</strong> liver necrosis in male <strong>and</strong> female mice (NTP, 1982). Exposure by<br />

inhalation to 55 ppm 1,l-dichloroethylene, 6 hourdday, 5 daydweek for up to 1 year produced fatty liver<br />

changes in rats <strong>and</strong> focal degeneration <strong>and</strong> necrosis in mice (Lee et al., 1977).<br />

In a three-generation study, no treatment-related effects on reproduction or neonatal development were<br />

seen in male <strong>and</strong> female Sprague-Dawley rats administered up to 200 ppm of 1,l-dichloroethylene in the<br />

drinking water (Nitschke et al., 1983). However, inhalation exposure during gestation produced increased<br />

resorptions <strong>and</strong> minor skeletal alterations in rodents at concentrations that caused maternal toxicity. These<br />

effects were reported in rats <strong>and</strong> mice at 2 15 ppm (Short et al., 1977a) <strong>and</strong> in rats <strong>and</strong> rabbits at 280 ppm <strong>and</strong><br />

2 160 ppm, respectively (Murray et al., 1979).<br />

An oral Reference Dose (RfD) of 9E-3 mgkglday was derived for chronic exposure (EPA, 1994a) <strong>and</strong><br />

subchronic exposure to 1,l-dichloroethylene @PA, 1994b), based on liver lesions seen in rats in a 2-year<br />

drinking water study (Quast et al., 1983). The oral RfD is currently under review <strong>and</strong> may be subject to<br />

change. An inhalation Reference Concentration (RE) for 1,l-dichloroethylene is under review (EPA,<br />

1994a).<br />

An epidemiology study using a small cohort found no association between the occurrence of cancer or<br />

cancer mortality <strong>and</strong> exposure to 1,l-dichloroethylene (Ott et al., 1976). Oral carcinogenicity bioassays<br />

(drinking water or gavage exposures) with experimental animals gave generally negative results (N’I”, 1982;<br />

...<br />

lll


Quast et al., 1983; Maltoni et al., 1984, 1985). In one inhalation study (Maltoni et al., 1985), statistically<br />

significant increases in renal adenocarcinomas were noted in male Swiss mice exposed to 25 ppm for 12<br />

months. Also observed were statistically significant increases in mammary gl<strong>and</strong> carcinomas in females <strong>and</strong><br />

lung tumors in both sexes. Results of other inhalation stuhes with rats, mice, <strong>and</strong> hamsters have been<br />

negative (Hong et al., 1981; Maltoni et al., 1984; Quast et al., 1986).<br />

Based on EPA guidelines, 1,ldichloroethylene was assigned to weight-of-evidence group C, possible<br />

human carcinogen. For oral exposure, the slope factor is 6E-1 (mgkg/day)’ <strong>and</strong> the unit risk is 1.7E-5<br />

(pa)-’ (EPA, 1994a). The mhalation slope factor <strong>and</strong> unit risk are 1.2EM (mgkbday) <strong>and</strong> 5.OE-5<br />

(pg/m’)’ (EPA, 1994a), respectively.<br />

iv


1. INTRODUCTION<br />

lY1-Dichloroethylene (CAS No. 75-35-4), also known as 1,l-dichloroethene <strong>and</strong> vinylidine chloride,<br />

is a colorless liquid with a molecular weight of 96.95 <strong>and</strong> a chemical formula of C,H,Cl,. It has a boiling<br />

point of 31.7"C, a melting point of -122.5"CY a density of 1.2129 g/mL (Budavari et al., 1989), <strong>and</strong> a vapor<br />

pressure of 600 mm Hg at 25°C (EPA, 1987). 1,l-Dichloro-ethylene is produced commercially by the<br />

dehydrochlorination of 1,1,2-trichloroethane by lime or sodium hydroxide (IARC, 1986).<br />

1,l-Dichloroethylene is used primarily in the production of poiyvinylidine chloride (PVC) copolymers<br />

<strong>and</strong> as an intermdate for synthesis of organic chemicals. The major application for PVC copolymers is the<br />

production of flexible films for food packaging such as Saran@ wrap (ATSDR, 1993). 1,l-Dichloroethylene<br />

is also used as an intermediate in the production of l,l,l-trichloroethane <strong>and</strong> in the manufacture of<br />

modacrylic fibers where it is combined with acrylonitrile. Because 1 , 1 -dichloroethylene polymerizes readily<br />

<strong>and</strong> can form explosive peroxides, hydroquinone monomethyl ether (MEHQ) or phenol are generally added<br />

as a stabilizer to prevent these reactions (Haley, 1975).<br />

1,l-Dichloroethylene does not occur naturally (IARC, 1986) but is found in the environment due to<br />

releases associated with its production <strong>and</strong> transport <strong>and</strong> with the production of its polymers. Because of its<br />

high volatility, releases to the atmosphere are the greatest source of ambient 1,l-dichloroethylene. Smaller<br />

amounts of 1,l-dichloroethylene are released to surface waters <strong>and</strong> soils (ATSDR, 1993). Estimated halflives<br />

in air <strong>and</strong> water are 2 days <strong>and</strong> 1-6 days, respectively. Loss of 1,l-dichloroethylene from water <strong>and</strong> soils<br />

is primarily due to volatilization. In the atmosphere, reaction with photochemically generated hydroq4<br />

radlcals is expected to be the predominant removal mechanism @PA, 1987).<br />

Human exposure to 1,l-dlchloroethylene is potentially highest in workplace settings <strong>and</strong> in the vicinity<br />

of hazardous waste sites where the compound may contaminate environmental media (ATSDR, 1993). It is<br />

found as a contaminant in nuclear submarines <strong>and</strong> spacecratl (Gosselin et al., 1984). The general population<br />

may be exposed to low levels of 1,l-dichloroethylene in ambient air, indoor air, contaminated drinking water,<br />

<strong>and</strong> food which has come in contact with plastic wrap containing residual monomer (HSDB, 1994).<br />

2. METABOLISM AND DISPOSITION<br />

2.1 ABSORPTION<br />

No human data were available regardmg the absorption of 1,l-dichloroethylene by any route of<br />

exposure. The rapid appearance of labeled 1,l-dichloroethylene in the urine <strong>and</strong> expired air of rats given<br />

intragastric doses of ["C] 1,ldichloroethylene indicates that systemic absorption following oral dosing is<br />

rapid (EPA, 1987). 1,l-Dichloroethylene is also readily absorbed following inhalation exposure. In rats<br />

exposed to 25, 75, or 150 ppm l,ldichloroethylene, equilibrium levels were reached in the blood by 45<br />

minutes, while at 300 ppm the blood level of 1,l-dichloroethylene tended to increase gradually for 3 hours<br />

(Dallas et al., 1983).<br />

1


2<br />

2.2 DISTRIBUTION<br />

No data were available regarding the tissue distribution of 1,l-dichloroethylene in humans. In rats,<br />

1,l-dichloroethylene is rapidly hstributed to tissues following oral or dalation exposure. Following<br />

administration of a single oral dose of 350 or 500 ,q&g, the highest concentrations were found in the liver<br />

<strong>and</strong> ludneys within 30 minutes of dosing; general tissue distribution followed (Jones <strong>and</strong> Hathway, 1978b).<br />

After 72 hours, 3% or less of the administered dose was present, indicating that 1,l-dichloroethylene is not<br />

extensively stored in body tissues. Following inhalation exposure to 2000 ppm for 2 hours, rats preferentially<br />

accumulated 1 , 1 -dichloroethylene in the kidney <strong>and</strong> liver, with fasted rats having higher levels in these tissues<br />

than nonfasted rats (Jaeger et al., 1977).<br />

2.3 METABOLISM<br />

Pharmacokinetic data in animals show that metabolism is dose-dependent <strong>and</strong> saturable at inhalation<br />

concentrations of 150-200 ppm or approximately 50 mgkg orally (EPA, 1987). Metabolic conversion of<br />

1,l-hchloroethylene to an epoxide as an intermdate reactive metabolite has been proposed (IARC, 1986).<br />

The main biotransformation pathway in the rat most likely involves conjugation with glutathione (GHS),<br />

either with the epoxide or following remangement of the epoxide to chloroacetylchloride, with subsequent<br />

hydrolysis to mondoroacetic acid (ATSDR, 1993). Major urinary metabolites of 1 ,ldichloroethylene<br />

identifkd in rats are thiodihydroxyacetic acid <strong>and</strong> N-acetyl-S-cysteinylacetyl derivatives. Additional<br />

metabolites identified are chlmacetic acid, dithiohydroxyacetic acid (dithioglywlic acid), thiohydroxyacetic<br />

acid (thioglymlic acid), <strong>and</strong> methylthtoacetylamino-ethanol. Comparative studies with rodents have shown<br />

that mice metabolize 1,1 dchloroethylene to a greater extent than rats (IARC, 1986).<br />

2.4 EXCRETION<br />

No human data were available regarm the excretion of 1,ldichloroethylene. After oral<br />

administration of 5 mg radiolabeled 1,l-dichloroethylene to rats, most of the radioactivity was recovered<br />

within 72 hours (Reichert et al., 1979). Twenty one percent of the dose was recovered in the expired air,<br />

53.9% in urine, 1<strong>4.</strong>5% in feces, 2.8 % in the carcass, <strong>and</strong> 7.5% was found in the cage rinse.<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1 ORAL EXPOSURES<br />

3.1.1 Acute Toxicity<br />

3.1.1.1 Human<br />

Information on the acute oral toxicity of 1 ,I dichloroethylene in humans was not available.


3<br />

3.1.1.2 Animal<br />

Jones <strong>and</strong> Hathway (1978a) reported oral LD,, values of 1550 mgkg for rats <strong>and</strong> 194 <strong>and</strong> 217 mgkg,<br />

respectively, for male <strong>and</strong> female mice. A lethal dose of 5750 mgkg was reported for dogs (Tierney et al.,<br />

1979).<br />

Increased kidney weights, increased plasma urea nitrogen <strong>and</strong> creatinine concentrations, <strong>and</strong><br />

histopathological changes of the kidneys (vacuolization, tubular dilatation, <strong>and</strong> necrosis) were seen in rats<br />

ahstered a single oral dose of 400 mgkg of 1,l-dlchloroethylene (Jenkins <strong>and</strong> Andersen, 1978). Fastmg<br />

rats were more susceptible to the nephrotoxic effects of 1,l -dichloroethylene than nonfasting rats.<br />

Forkert et al. (1985) reported histopathological changes in Clara cells, pulmonary edema, hemorrhage,<br />

<strong>and</strong> focal lung collapse in mice administered a single oral dose of 200 mgkg of 1,l-dlchloroethylene. In<br />

contrast, Chieco et al. (1981) found no hstopathological lung changes in fasted or nonfasted rats administered<br />

a single oral dose of 200 mgkg of 1 , 1 -dichloroethylene.<br />

After oral treatment of rats with 1000 mgkg of 1,l-dichloroethylene, liver glutathione levels were<br />

decreased to 33% of the control values within 4 hours but returned to the control levels after 24 hours<br />

(Reichert et al., 1978).<br />

3.1.2 Subchronic Toxicity<br />

3.1.2.1 Human<br />

Information on the subchronic oral toxicity of 1,l-dichlorwthylene in humans was not available.<br />

3.1.2.2 Animal<br />

Ramp et al. (1977) administered 50, 100, or 200 ppm 1,l-dichloroethylene in drinking water to male<br />

<strong>and</strong> female Sprague-Dawley rats for 90 days. The only adverse effect noted was an increased incidence of<br />

cytoplasmic vacuolization of hepatocytes in the high dose group.<br />

No adverse effects were obsexved in beagle dogs administered daily doses of 6.25, 12.5, or 25 mgkg<br />

of 1,l -dichloroethylene in gelatin capsules for 97 days (Quast et al., 1983).<br />

3.13 Chronic Toxicity<br />

3.1.3.1 Human<br />

Information on the chronic oral toxicity of 1,l -dichloroethylene in humans was not available.<br />

3.1.3.2 Animal<br />

Male <strong>and</strong> female Sprague-Dawley rats were administered 50, 100, or 200 ppm 1,l-dichloroethylene in<br />

drinlung water for 2 years (Quast et al., 1983). The authors calculated a daily intake of 7, 10, or 20<br />

mg/kg/day for males <strong>and</strong> 9, 14, or 30 mgkg/day for females. There were no treatment-related effects on<br />

mortality, body weight, clinical chemistry, urinalysis, hematology, or tumor incidence. Female rats at all dose<br />

levels developed hepatic lesions, characterized as minimal hepatocellular fatty change <strong>and</strong> hepatocellular<br />

hypertrophy. In male rats, hepatocellular hypertrophy was seen at 100 <strong>and</strong> 200 ppm.


4<br />

In a 2-year gavage study conducted by NTP (1982), F344 rats <strong>and</strong> B6C3F, mice were administered<br />

1 , 1 -dichloroethylene at doses of 1 or 5 mg/kg/day (rats) <strong>and</strong> 2 or 10 mgkglday (mice), 5 daydweek for 2<br />

years. Mortality <strong>and</strong> growth rates were not af€ected in either species at either dose level. Compared with<br />

controls, an increased incidence of chronic inflammation of the kidneys occurred in high-dose male <strong>and</strong><br />

female rats, <strong>and</strong> an increased incidence of liver necrosis was observed in high-dose male <strong>and</strong> low-dose female<br />

mice.<br />

3.1.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1 Human<br />

Information on the developmental <strong>and</strong> reproductive oral toxicity of 1 , 1 -drchloroethylene in humans was<br />

not available.<br />

3.1.<strong>4.</strong>2 Animal<br />

No adverse effects were reported in Sprague-Dawley rats given 200 mg/L of 1,l-dichloroethylene in<br />

drinking water on gestation days 6-15 (Murray et al., 1979). In a three-generation study, Nitschke et al.<br />

(1983) found no treatment-related effects on reproduction or neonatal development in male <strong>and</strong> female<br />

Sprague-Dawley rats administered 50,100, or 200 mg/L of 1 , 1 -dichloroethylene in the drinking water.<br />

When rats were exposed to feed fumigated with 250 or 500 ppm 1,l-dichloroethylene, no changes in<br />

fetal mortality or fetal weight were found over several generations during a 2-year period (Alumot et al.,<br />

1976). Based on the amount eaten <strong>and</strong> the measured residue level, the investigators calculated that due to<br />

volatility only 60 to 70% of the fumigant was actually consumed.<br />

3.1.5 Reference Dose<br />

3.1.5.1 Subchronic<br />

ORAL RfD:<br />

9E-3 mg/lcg/day (EPA, 1994b)<br />

LOAEL:<br />

9 mg/kg/day<br />

UNCERTAINTY FACTOR 1000<br />

PRINCIPAL STUDY: Quast et al., 1983<br />

COMMENTS: The chronic IUD was adopted as the subchronic IUD. The chronic IUD is under<br />

review <strong>and</strong> may be subject to change (EPA, 1994a).<br />

3.1.5.2 Chronic<br />

ORAL IUD:<br />

9E-3 mg/kg/day (EPA, 1994a)<br />

LOAEL:<br />

9 mg/kg/day<br />

UNCERTAINTY FACTOR 1000<br />

PRINCIPAL STUDY:<br />

Quast et al., 1983<br />

CONFIDENCE:<br />

DATA BASE:<br />

RED:<br />

Medium<br />

Medium<br />

Medium<br />

VERIFICATION DATE: 1/22/85


5<br />

COMMENTS: The RfD is based on liver lesions seen in a 2-year drinlung water study with rats. An<br />

uncertainty factor of 10 each was applied for use of a LOAEL, interspecies variation, <strong>and</strong><br />

protection of sensitive populations. The chroNc RfD is under review <strong>and</strong> may be subject to change<br />

(EPA, 1994a).<br />

3.2 INHALATION EXPOSURES<br />

3.2.1 Acute Toxicity<br />

3.2.1.1 Human<br />

The primary effect of acute exposure to high concentrations (approximately 4000 ppm) of<br />

1,l-dddoroethylene vapor is central nervous system (CNS) depression wluch may progress to<br />

unconsciousness (Gosselin et al., 1984). Lesions of the trigeminal nerve, causing motor weakness of the jaw,<br />

eye, <strong>and</strong> tongue muscles, have been reported following acute inhalation exposure to 1,l-dichloroethylene<br />

(Henschler et al., 1970). However, subsequent evaluation suggested that the toxic agent was either monoor<br />

dichloroacetylene (Haley, 1975).<br />

3.2.1.2 Animal<br />

The lethality of 1,l-dichloroethylene appears to be dependent on dietary parameters. Inhalation LC+<br />

for 4-hour exposures were 10,000-15,000 ppm in fed rats <strong>and</strong> 500-2500 ppm in fasted rats; death was due to<br />

vascular collapse <strong>and</strong> shock (Jaeger et al., 1973).<br />

Twenty 6-hour exposures to 500 ppm caused nasal irritation, reduced weight gain, <strong>and</strong> histopathological<br />

changes in the liver of rats (Gage, 1970). Exposure of fasted rats to 200 ppm 1,l-dichloroethylene for 4 hours<br />

produced injury to liver parenchymal cells (Reynolds et al., 1980).<br />

3.2.2 Subchronic Toxicity<br />

3.2.2.1 Human<br />

Information on the subchronic inhalation toxicity of 1,l-dic-mxthylene in humans was not available.<br />

3.2.2.2 Animal<br />

Prendergast et al. (1967) exposed rats, guinea pigs, squirrel monkq, rabbits, <strong>and</strong> beagle dogs<br />

continuously to 20, 61, or 189 mg/m3 (5, 15, or 48 ppm) 1,l-dichloroethylene for 90 days. Early mortality<br />

occurred in guinea pigs <strong>and</strong> monkeys at all exposure concentrations without visible signs of toxicity<br />

compared with controls. All species had reduced body weight gains at 189 mg/m3. Also seen at the highest<br />

exposure level were increased liver alkaline phosphatase <strong>and</strong> serum glutamic-pyxuvic transaminase activities<br />

in rats <strong>and</strong> guinea pigs; kidney lesions in rats; <strong>and</strong> liver lesions in rats, dogs, <strong>and</strong> monkeys. The liver lesions<br />

were described as fatty changes, focal necrosis, hemosiderin deposition, lymphocyhc infiltration, bile duct<br />

proliferation, fibrosis, <strong>and</strong> pseudo-lobule formation.


6<br />

3.23 Chronic Toxicity<br />

3.2.3.1 Human<br />

Ott et al. (1976) studied mortality <strong>and</strong> health examination data of 138 Dow Chemical Company<br />

workers who had been exposed to 1,l-lchloroethylene at concentrations rangmg from 70 ppm<br />

(time-weighted averages) in various job categories. The length of exposure ranged from 4 year to >10 years.<br />

Except for hepatic effects noted in two indwiduals with a history of alcohol consumption, mortality,<br />

spirometry, blood chemistry (including liver <strong>and</strong> renal tests), hematological parameters, <strong>and</strong> blood pressure<br />

measurements did not differ fiom controls matched for age <strong>and</strong> smoking.<br />

In a preliminary study, Tiemey et al. (1979) reported that 27 of 46 workers exposed to 1,ldichloroethylene<br />

for 6 years or less in a 1,l-dichloroethylene polymerization plant showed a 50% or greater<br />

loss of liver function. The study provided few detids, <strong>and</strong> a follow-up study has not been reported.<br />

3.23.2 Animal<br />

Lee et al. (1977) exposed both sexes of CD rats <strong>and</strong> CD-1 mice to 55 ppm 1,ldichloroethylene vapor,<br />

6 hourdday, 5 daydweek for up to 1 year. Most treated rats developed hepatocellular fatty changes, <strong>and</strong><br />

treated mice developed various hepatocellular changes, as well as focal degeneration, <strong>and</strong> necrosis of the<br />

Iiver.<br />

Male <strong>and</strong> female Sprague-Dawley rats were exposed by inhalation to 10 or 40 ppm 1,ldichloroethylene,<br />

6 hours/day, 5 daydweek for 1 month (Quast et al., 1986). Because of lack of treatmentrelated<br />

effects, exposure was then increased to 25 or 75 ppm for 17 months, <strong>and</strong> surviving animals were held<br />

for an additional 6 months. The oniy effects attributed to 1,ldichloroethylene mhalation were hepatocellular<br />

changes in both male <strong>and</strong> female rats at both exposure levels.<br />

3.2.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.2.<strong>4.</strong>1 Human<br />

Idormation on the developmental <strong>and</strong> reproductive toxicity of 1 , 1 dichloroethylene following<br />

inhalation exposure in humans was not available.<br />

3.2.<strong>4.</strong>2 Animal<br />

Short et al. (1977a) exposed CD rats <strong>and</strong> CD-1 mice to 1,ldichloroethylene for 23 hours/day on days<br />

6-16 of gestation. Rats were exposed to 15,57,300, or 449 ppm <strong>and</strong> mice to 15,30,57, 144, or 300 ppm.<br />

Maternal toxicity was seen in both species. In rats, 25% mortality occurred in dams exposed to the two<br />

highest concentrations; food consumption <strong>and</strong> weight gain was adversely af€ected at L 15 ppm. No pregnant<br />

mice survived exposure to 144 or 300 ppm. Early resorptions were common in all exposed groups, with 49<br />

<strong>and</strong> 64% resorptions in rats exposed to 57 <strong>and</strong> 449 ppm, respectively, <strong>and</strong> 100% resorptions in mice exposed<br />

to 30 <strong>and</strong> 57 ppm, respezt~vely. Some soft tissue anomalies were observed in offspring of rats at 15 <strong>and</strong> 57<br />

ppm, <strong>and</strong> a sigruficantly (p value not given) increased incidence of incomplete ossification of sternebrae<br />

occurred in offspring of mice at 15 ppm <strong>and</strong> in offspring of rats at 15,57, <strong>and</strong> 300 ppm.<br />

Murray et al. (1979) exposed Sprague-Dawley rats <strong>and</strong> New Zeal<strong>and</strong> rabbits to 20 ppm (rats only), 80<br />

ppm, or 160 ppm 1,l-dichloroethylene vapor for 7 hourslday during organogenesis. Maternal toxicity<br />

(decreased weight gain, decreased food consumption, <strong>and</strong> increased liver weights) was observed in rats at 80


7<br />

<strong>and</strong> 160 ppm <strong>and</strong> in rabbits at 160 ppm. A statistically si&icant (pC0.05) increase of skeletal variations<br />

such as delayed ossification <strong>and</strong> wavy ribs was seen in offspring of rats exposed to both 80 <strong>and</strong> 160 ppm <strong>and</strong><br />

in offspring of rabbits exposed to 160 ppm. In rabbits, resorptions were sigdicantly (p


8<br />

3.3.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

Information on the developmental <strong>and</strong> reproductive toxicity of 1,l-dichloroethylene in humans or<br />

animals by other routes of exposure was not available.<br />

3.4 TARGET ORGANS/CRITICAL EFFECTS<br />

3.<strong>4.</strong>1 Oral Exposures<br />

3.<strong>4.</strong>1.1 Primary Target Organs<br />

1. Liver. Chronic oral exposure to 1,l dichloroethylene produced hepatocellular changes in rats<br />

<strong>and</strong> liver necrosis in mice.<br />

2. Kidneys. Chronic oral exposure to 1,l-dichloroethylene produced inflammation of the kidneys in<br />

rats.<br />

3.<strong>4.</strong>1.2 Other Target Organs<br />

Other target organs following oral exposure to 1,l -&chloroethylene were not identified.<br />

3.<strong>4.</strong>2 Inhalation Exposures<br />

3.<strong>4.</strong>2.1 Primary Target Organs<br />

1. Liver. A prelimina~~ study reported loss of liver function in workers exposed to<br />

1,l dichloroethylene. Subchronic <strong>and</strong> chroNc inhalation exposure to 1 , 1-ddloroethylene<br />

produced mild to marked histological changes in the liver of several animal species.<br />

2. Kidneys. Subchronic exposure to 1,ldichloroethylene produced kidney lesions in rats.<br />

3. Development. Exposure to 1,ldichloroethylene during gestation produced increased<br />

resorptions <strong>and</strong> minor skeletal alterations in rats, rabbits, <strong>and</strong> mice at concentrations that<br />

caused matemd toxicity.<br />

3.<strong>4.</strong>2.2 Other Target Organs<br />

Other target organs following inhalation exposure to 1 ,I-dichloroethylene were not identified.<br />

3.43 Other Routes of Exposure<br />

3.<strong>4.</strong>3.1 Primary Target Organs<br />

1. Skin. 1,1 -Dichlomethylene is initating to the skin of humans.<br />

2. Eyes. Direct contact of 1,ldichloroethylene to the eyes may cause conjunctivitis <strong>and</strong><br />

transient corned injury in humans.


9<br />

3.<strong>4.</strong>3.2 Other Target Organs<br />

Other target organs by other routes of exposure to 1,l -dichloroethylene were not idenMied.<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1 ORAL EXPOSURES<br />

<strong>4.</strong>1.1 Human<br />

Information on the carcinogenicity of 1,l-dichloroethylene in humans following oral exposure was not<br />

available.<br />

<strong>4.</strong>1.2 Animal<br />

Oral carcinogenicity studies with rats <strong>and</strong> mice gave negative results. In a 2-year gavage study<br />

conducted by NTP (1982), F344 rats <strong>and</strong> B6C3F, mice were administered 1,l-dichloroethylene at doses of<br />

1 or 5 mg/kg/day (rats) <strong>and</strong> 2 or 10 mg/kg/day (mice), 5 dayslweek for 2 years. An increased incidence (not<br />

statistically sigmficant) of adrenal pheocytochromas was seen in high-dose male rats but not in female rats.<br />

Female mice admimstered the low dose exhibited an increased incidence of lymphomas <strong>and</strong> leukemia that<br />

was not considered treatment-related. In another gavage study, male <strong>and</strong> female Sprague-Dawley rats<br />

received 0.5, 5, 10, or 20 mg/kg/day, 4 to 5 daydweek for 78 weeks, followed by a 147-week observation<br />

pod (Maltoni et al., 1984, 1985). The pattern of neoplasms <strong>and</strong> their incidences was similar to that seen<br />

in controls.<br />

No carcinogenic effects were observed in Sprague-Dawley rats administered 50 to 200 ppm (7 to<br />

30 mgkg/day) 1,l-dichloroethylene in drinking water for 2 years (Quast et al., 1983).<br />

<strong>4.</strong>2 INHALATION EXPOSURES<br />

<strong>4.</strong>2.1 Human<br />

Ott et al. (1976) found no relationship between the occurrence of cancer or cancer mortality in 138<br />

workers primarily exposed to 1,l-dichloroethylene during 1950 to 1959 <strong>and</strong> 55 workers exposed from 1960<br />

to 1969. The subjects were divided into groups exposed to


10<br />

Maltoni et al. (1985) exposed male <strong>and</strong> female Swiss mice to 10 or 25 ppm 1,1-dichloroethyleneY 4 to<br />

5 daydweek for 12 months. bterim results of this study were reported in Maltoni et al., 1977.1 A<br />

statistically signtficant (p value not given) increase in ludney adenocarcinomas was reported in male mice<br />

exposed to 25 ppm. There were also statistically si&icant increases in mammary adenocarcinomas in<br />

female mice <strong>and</strong> pulmonary adenomas in both sexes; however, a dose-response relationship was not apparent.<br />

In a second study, Sprague-Dawley rats were exposed to 10, 25, 50, 100, or 150 ppm, 4 to 5 daydweek for<br />

12 months <strong>and</strong> observed until death. A statistically si&icant (p value not given) increase in total mammary<br />

tumors (but not carcinomas) was seen only at 10 ppm <strong>and</strong> 100 ppm but not at the other concentrations tested.<br />

In a study by Hong et al. (1981), small groups of CD rats <strong>and</strong> CD-I mice of both sexes were exposed<br />

to 55 ppm 1,l-ddoroethylene, 6 hourslday, 5 daydweek for 1,3,6 (rats <strong>and</strong> mice), or 10 months (rats only).<br />

Following treatment, all groups were observed for 12 months. There was a dose-related decrease in survival<br />

in male <strong>and</strong> female mice; survival in rats was similar to controls. No treatment-related tumors were reported<br />

in rats or mice.<br />

Female Chinese hamsters were exposed to 25 ppm 1,1,-dichloroethylene for 4 hours/day, 4-5 daydweek<br />

for 52 weeks <strong>and</strong> observed for life (164 weeks) (Maltoni et al., 1984). The tumor incidence was comparable<br />

to that in controls.<br />

43 OTHER ROUTES OF EXPOSURE<br />

<strong>4.</strong>3.1 Human<br />

Information on the carcinogenicity of IJ-dichloroethylene in humans by other routes of exposure was<br />

not available.<br />

43.2 Animal<br />

Van Duuren et al. (1979) applied 40 or 121 mg ly1-dichlor0ethylene to the skin of Swiss mice three<br />

times weekly for 595 days. No skin tumors were observed. However, when 121 mg 1,1-dichloroethylene<br />

was applied once, followed 2 weeks later by dermal applications of the tumor promoter, phorbol myristate<br />

acetate (three times weekly for about 576 days), there was a statistically si@cant (p


11<br />

<strong>4.</strong>5 CARCINOGENICITY SLOPE FACTORS<br />

<strong>4.</strong>5.1 Oral<br />

SLOPE FACTOR:<br />

UNIT RISK:<br />

PRINCIPAL STUDIES:<br />

6E-1 (mg/kg/dayy' (EPA, 1994a)<br />

1.7E-5 (pa)-' (EPA, 1994a)<br />

Quast et al., 1983; NTP, 1982<br />

COMMENT: The unit risk was derived from the highest of four oral slope factors calculated from two<br />

studies that did not show a statistically sigmficant increase in tumor incidence attributable to oral<br />

exposure to 1,l-dichloroethylene. The drinking water study in rats (Quast et al., 1983) produced<br />

the lowest slope factor of 0.2 (mg/kg/day)-'. The highest slope factor [0.6 (mgAcg/day)-'] was based<br />

on renal tumors in male rats (NTP, 1982). EPA indicated that use of data showing no statistically<br />

significant increase in tumor incidence appeared justified, since the slope factor derived was within<br />

a factor of 2 of the slope factor based on data from the inhalation study by Maltoni et al. (1977,<br />

1985).<br />

<strong>4.</strong>5.2 Inhalation<br />

SLOPE FACTOR:<br />

UNIT RISK:<br />

PRINCIPAL STUDIES:<br />

1.2E4-0 (@g/day)-' (EPA, 1994b)<br />

5.OE-5 (pg/m3)-' (EPA, 1994a)<br />

Maltoni et al., 1977,1985<br />

COMMENT: The dation slope factor is based on kidney adenocarcinomas in male mice<br />

exposed for 12 months by inhalation.<br />

5. REFERENCES<br />

Alumot, E.O., E. Nachtomi, E. M<strong>and</strong>el, et al. 1976. Tolerance <strong>and</strong> acceptable daily intake of chlorinated<br />

fumigants in the rat diet. Food Cosmet. Toxicol. 14: 105-1 10.<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1993. I, I-Dichloroethylene, Update. U.S.<br />

Department of Health <strong>and</strong> Human Services, Public Health Service.<br />

Budavari, S., M.J. O'Neill, A. Smith <strong>and</strong> P.E. Heckelman, Eds. 1989. The Merck Index: An Encycloma<br />

of Chemicals, Drugs, <strong>and</strong> Biologicals, 1 lth ed. Merck & Co., Rahway, NJ, pp. 1572-1573.<br />

Chieco, P., M.T. Moslen <strong>and</strong> E.S. Reynolds. 1981. Effect of administrative vehicle on oral 1,ldichloroethylene<br />

toxicity. Toxicol. Appl. Phannacol. 57: 146-1 55.<br />

Dallas, C.E., F.W. Weir, S. Feldman, et al. 1983. The uptake <strong>and</strong> disposition of 1,ldichloroethylene in rats<br />

during inhalation exposure. Toxicol. Appl. Phannacol. 68: 140-151.<br />

EPA (US. Environmental Protection Agency). 1983. Reportable Quantity Document for 1,I-<br />

Dichloroethylene (Vinylidne Chloride). Prepared by the Environmental Criteria <strong>and</strong> Assessment<br />

OBice, Cincinnati, OH, for the Office of Solid Waste <strong>and</strong> Emergency Response. ECAO-CIN-Rl02.


12<br />

EPA (U.S. Environmental Protection Agency). 1987. Health Efects Assessment for I, 1 -Dichloroethylene.<br />

Prepared by the Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong><br />

Assessment Office, Cincinnati, OH, for the Office of Emergency <strong>and</strong> Remehal Response, Washington,<br />

DC. ECAO-CIN-HO5 la.<br />

EPA (U.S. Environmental Protection Agency). 1994a. Integrated Risk Information System (IRIS).<br />

Environmental Criteria <strong>and</strong> Assessment Office, Office of Health <strong>and</strong> Environmental Assessment, Cincinnati,<br />

OH.<br />

EPA (U.S. Environmental Protection Agency). 1994b. Health Assessment Summary Tables. Annual FY-9<strong>4.</strong><br />

Prepared by the OfEce of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong><br />

Assessment Office, Cincinnati, OH, for the Office of Emergency <strong>and</strong> Remedial Response, Washington,<br />

DC.<br />

Forkert, P.G., L. Forkert, M. Farmqui, et al. 1985. Lung injury <strong>and</strong> repair: DNA synthesis following 1,ldichloroethylene.<br />

Toxicology 36: 199-21<strong>4.</strong><br />

Gage, J.C. 1970. The subacute inhalation toxicity of 109 industrial chemicals. Br. J. Ind. Med, 27: 1-18.<br />

Gosselin, RE., RP. Smith, H.C. Hodge, et al. 198<strong>4.</strong> Clinical Toxicology of Commercial Products, 5th ed.<br />

The Williams <strong>and</strong> Willcins Co., New York, p. II-163.<br />

Haley, T.J. 1975. Vinylidine chloride: A review of the literature. Clin. Toxicol. 8: 633-643. (Cited in U.S.<br />

Air Force, 1989)<br />

Henschler, D., F. Broser <strong>and</strong> H.C. Hopf. 1970. "Polyneuritis cranialis" following poisoning with chlorinated<br />

acetylenes while h<strong>and</strong>ling vinylidine chloride copolymers. Arch. Toxikol. 26: 62-75.<br />

Hong, C.B., J.M. Winston, L.P. Thornburg, et al. 1981. Follow-up study on the carcinogenicity of vinyl<br />

chloride <strong>and</strong> vinylidme chloride in rats <strong>and</strong> mice: Tumor incidence <strong>and</strong> mortality subsequent to<br />

exposure. J. Toxicol. Emiron. Health 7: 909-92<strong>4.</strong><br />

HSDB. 199<strong>4.</strong> Hazardous Substances Data Bank. MEDLARS online information Retrieval System,<br />

National Library of Medicine. Retrieved June, 199<strong>4.</strong><br />

IARC (International Agency for Research on Cancer). 1986. Vilidine chloride. In. L4RC Monographs<br />

on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 39. IARC, Lyon, France,<br />

pp. 195-226.<br />

Jaeger, RJ., M.J. Trabulus <strong>and</strong> S.D. Murphy. 1973. The interaction of adrenalectomy, partial adrenal<br />

replacement therapy, <strong>and</strong> starvation with hepatotoxicity <strong>and</strong> lethality after 1,ldichloroethylene<br />

intoxication. Toxicol. Appl. Phannacol. 25: 491.<br />

Jaeger, RJ., L.G. Shoner <strong>and</strong> L. coffinan. 1977. 1,l-Dichloroethylene hepatotoxicity: Reposed mechanism<br />

of action <strong>and</strong> distribution <strong>and</strong> bin- of "C radioactivity following inhalation exposure in rats.<br />

Environ. Health Perspect. 21: 113-119.<br />

Jenkins, L.J., Jr., <strong>and</strong> M.E. Andersen. 1978. 1,l-Dichloroethylene nephrotoxicity in the rat. ToXcol. A&.<br />

Phannacol. 46: 131-141.


13<br />

Jones, B.K. <strong>and</strong> D.E. Hathway. 1978a. Differences in metabolism of Vinylidine chloride between mice <strong>and</strong><br />

rats. Br. J. Cancer 37: 411-417.<br />

Jones, B.K. <strong>and</strong> D.E. Hathway. 1978b. The biological fate of vinylidine chloride in rats. Chem.- Biol.<br />

Interact. 20: 27-41.<br />

Lee, C.C., J.C. Bh<strong>and</strong>ari, J.M. Winston, et al. 1977. Inhalation toxicity of vinyl chloride <strong>and</strong> vinylidine<br />

chloride. Emiron. Health Perspect. 2 1 : 25-32.<br />

Krijgsheld K.R, M.C. Lowe, E.G. Mimnaugh, et al. 1983. Lung-selective impairment of cytochrome P-450-<br />

dependent monooxygenases <strong>and</strong> cellular injury by 1 ,l-dichloroethylene in mice. Biochem. Biophys.<br />

Res. Commun. 110: 675-681.<br />

Maltoni, C., G. Gotti, L. Morisi <strong>and</strong> P. Chieco. 1977. Carcinogenicity bioassays of vinylidine chloride.<br />

Research Plan <strong>and</strong> Early Results. Med Lav. 68: 241-262. (Cited in EPA, 1992)<br />

Maltoni, C., G. Cotti <strong>and</strong> P. Chieco. 198<strong>4.</strong> Chronic toxicity <strong>and</strong> carcinogenicity bioassays of vinylidine<br />

chloride. Acta Oncol. 5: 91-145. (Cited in IARC, 1986)<br />

Maltoni, C., G. Lefemine, P. Chieco, et al. 1985. Experimental research on vinylidine carcinogenesis. In:<br />

Archives of Research on Industrial Carcinogenesis, Vol. 3, C. Maltoni <strong>and</strong> M. Mehlman, E&.<br />

Princeton Scientific Publishers, Princeton, NJ. (Cited in EPA, 1992)<br />

Murray, F.J., K.D. Nitschke, L.W. Rampy <strong>and</strong> B.A. Schwetz. 1979. Embvotoxicity <strong>and</strong> fetotoxicity of<br />

inhaled or ingested vinylidine chloride in rats <strong>and</strong> rabbits. Toxicol. Appl. Pharmacol. 49: 189-202.<br />

Nitschke, K.D., F.A. Smith, J.F. Quast, et al. 1983. A three-generation rat reproductive toxicity study of<br />

vinylidine chloride in the drinking water. Fund Appl. Toxicol. 3: 75-79.<br />

NTP (National Toxicology Program). 1982. Carcinogenesis Bioassay of Vinylidne Chloride (CAS No. 75-<br />

35-4) in F344 Rats <strong>and</strong> B6C3FI Mice (Gavage Studyl. NTP Tech. Rep. Series No. 228. NTP-80-82;<br />

NIH Publ. NO. 82-178<strong>4.</strong><br />

Ott, M.G., W.A. Fishbeck, J.C. Townsend <strong>and</strong> E.J. Schneider. 1976. A health study of employees exposed<br />

to vinylidine chloride. J. Occup. Med. 18: 735-738.<br />

Prendergast, J.A., RA. Jones, L.J. Jenkins, Jr., <strong>and</strong> J. Siegel. 1967. Ef€ects on experimental animals of longterm<br />

inhalation of trichloroethylene, carbon tetrachloride, 1,1,1 -trichloroethane,<br />

dichlorodifluoromethane, <strong>and</strong> 1 , 1 dichloroethylene. Toxicol. Appl. Pharmacol. 10: 270-289.<br />

Quast, J.F., C.G. Humiston, C.E. Wade et al. 1983. A chronic toxicity <strong>and</strong> oncogenicity study in rats <strong>and</strong><br />

subchronic toxicity study in dogs on ingested Vinylidbe chloride. Fund Appl. Toxicol. 3: 55-62.<br />

Quast, J.F., M.J. McKenna, L.W. h p y <strong>and</strong> J.M. Noms. 1986. Chronic toxicity <strong>and</strong> oncogenicity study<br />

on inhaled vinylidine chloride in rats. Fund. Appl. Toxicol. 6: 105-14<strong>4.</strong><br />

Rampy, L.W., J.F. Quast, C.G. Humiston, et al. 1977. Interim results of two-year toxicological studies in<br />

rats of vinylidine chloride incorporated in the dnnlang water or administered by repeated inhalation.<br />

Environ. Health Perspect. 21: 333-343.


14<br />

Reichert, D., H.W. Werner <strong>and</strong> D. Henschler. 1978. Role of liver glutathione in l,l-&chloroethylene<br />

metabolism <strong>and</strong> hepatotoxicity in intact rats <strong>and</strong> isolated perfused rat liver. Arch. Toxicol. 41 : 169- 179.<br />

Reynolds, E.S., M.T. Moslen, J.P. Boor <strong>and</strong> R.J. Jaeger. 1980. 1,l-Dichloroethylene hepatotoxicity. Time<br />

course of GSH changes <strong>and</strong> biochemical aberrations. Am. J. Pathol. 101: 331-342. (Cited in IARC,<br />

1986)<br />

Short, R.D., Jr., J.L. Minor, J.M. Winston, et al. 1977a. Toxicity Studies of Selected Chemicals. Task II.<br />

The Developmental Toxicity of Vinylidme Chloride Inhaled by Rats <strong>and</strong> Mice during Gestation.<br />

Prepared by Midwest Research Institute, Kansas City, MO for the Office of Toxic Substances, U.S.<br />

Environmental Protection Agency. EPA-560/6-77-022. (Cited in EPA, 1983)<br />

Short, RD., J.L. Minor, J.M. Winston, et al. 197%. A dominant lethal study in male rats after repeated<br />

exposures to vinyl chloride or vlnylidine chloride. J. Toxicol. Environ. Health 3: 965-968.<br />

Tierney D.R, T.R. Blackwood <strong>and</strong> M.R Piana. 1979. Status Assessment of Toxic Chemicals: Vinylidine<br />

chloride. Prepared by Monsanto Research Corporation for 0fk.e of Research <strong>and</strong> Development, U.S.<br />

Environmental Rotection Agency, Cincinnati, OH. EPA 600/2-79-2 100; PB80- 146442.<br />

Torkelson, T.R <strong>and</strong> V.K. Rowe. 1982. Halogenated aliphatic hydrocarbons. In: Patty’s Industrial Hygene<br />

<strong>and</strong> Toxicology, G.D. Clayton <strong>and</strong> F.E. Clayton, E&, Vol. IIC. John Wiley & Sons, New York, pp.<br />

3 5 45 -3 5 5 0.<br />

U.S. Air Force. 1989. 1,l-Dichloroethylene. In: The Installation Program Toxicology Guide, VoI. 2.<br />

Wright-Patterson Air Force Base, OH, pp. 14-1 to 14-30.<br />

Van Duuren, B.L., B.M. Goldschmidt, G. Loewengart, et al. 1979. Carcinogenicity of halogenated olefbic<br />

<strong>and</strong> aliphatic hydrocarbons in mice. J. Natl. Cancer Imt. 63: 1433-1339. (Cited in ATSDR, 1993).


TOXICITY SUMMARY FOR<br />

INDENO[~,~,~-C~JPYRENE<br />

May 1994<br />

Prepared by<br />

Rosmarie A. Faust, Ph.D.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy under<br />

Contract No. DE-AC05-MOR2 1400


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EXECUTIVE SUMMARY<br />

Indeno[l,2,3-cd]pyrene, a crystalline solid with a chemical formula of GH,2 <strong>and</strong> a molecular<br />

weight of 276.3, is a polycyclic aromatic hydrocarbon (PAH). There is no commercial production or<br />

known use of this compound (IARC, 1983). Indeno[l,2,3-~dJpyrene is found in fossil fuels <strong>and</strong> occurs<br />

ubiquitously in products of incomplete combustion (IARC, 1983) <strong>and</strong> has been identified in' soils,<br />

groundwater, <strong>and</strong> surface waters at hazardous waste sites (ATSDR, 1990).<br />

No absorption data were available for indeno[l,2,3-cd]pyrene; however, by analogy to structurallyrelated<br />

PAHs, primarily benzo[u]pyrene, it would be expected to be absorbed from the gastrointestinal<br />

tract, lungs, <strong>and</strong> skin (EPA, 1991). In vivo metabolites identified in mouse skin include the rruns-1,2-<br />

dihydrodiol <strong>and</strong> 8- <strong>and</strong> 9-hydroxy forms of indeno[l,2,3-cd]pyrene (Rice et al., 1986). Similar<br />

metabolites were formed in vitro in rat liver microsomes (Rice et al., 1985).<br />

No data were found concerning the acute, subchronic, chronic, developmental, or reproductive<br />

toxicity of indeno[l,2,3-cd]pyrene. Because of a lack of toxicity data, an oral reference dose (RfD) or<br />

inhalation reference concentration (RfC) has not been derived (EPA, 1994).<br />

No long-term oral or inhalation bioassays were available to assess the carcinogenicity of<br />

indeno[ 1,2,3-cdJpyrene. The compound was tested for carcinogenicity in dermal application, lung<br />

implant, subcutaneous (s.c.) injection, <strong>and</strong> intraperitoneal (i.p.) injection studies. Dermal application of<br />

0.1-0.5% solutions of indeno[l,2,3-cdJpyrene in acetone produced skin papillomas <strong>and</strong> carcinomas in<br />

mice (Hoffmann <strong>and</strong> Wynder, 1966). In initiation-promotion assays, indeno[l,2,3-cd]pyrene was active<br />

as an initiator of skin carcinogenesis (Hoffmann <strong>and</strong> Wynder, 1966; Rice et al., 1986). Dose-related<br />

increases of epidermoid carcinomas of the lungs were reported in rats receiving single lung implants of<br />

0.16<strong>4.</strong>15 mg indeno[l,2,3-@pyrene (Deutsch-Wenzel et al., 1983). Injection site sarcomas developed<br />

in mice given three S.C. injections of 0.6 mg indeno[l,2,3-~dJpyrene (Lacassagne et al., 1963). The<br />

compound was not tumorigenic when newborn mice received 2.1 pmol indeno[l,2,3-~dJpyrene via i.p.<br />

injection (LaVoie et al., 1987).<br />

Based on no human data <strong>and</strong> sufficient evidence for carcinogenicity in animals, the United Stated<br />

Environmental Protection Agency @PA) has assigned a weight-of-evidence classification of B2, probable<br />

human carcinogen, to indeno[ 1,2,3-cd]pyrene (EPA, 1994).<br />

iii


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iv


1. INTRODUCTION<br />

Indeno[l,2,3-cdJpyrene (CAS Reg. No. 193-39-5), also known as IP, ortho-phenylenepyrene,<br />

1 , lO-(ortho-phenylene)pyrene, 1,1@(l72-phenylene)pyrene, <strong>and</strong> 2,3-ortho-phenylenepyrene (IARC, 1983),<br />

is a polycyclic aromatic hydrocarbon (PAH) with one five-membered ring <strong>and</strong> five six-membered rings.<br />

It is a crystalline solid with a chemical formula of %Hl2, a molecular weight of 276.3, a melting point<br />

of 163.6"C (IARC, 1983), <strong>and</strong> a boiling point of 530°C (ATSDR, 1990). Indeno[l,2,3-cdJpyrene is<br />

insoluble in water but is soluble in organic solvents. It has a vapor pressure of - 1 ~10-~~ torr at 20°C,<br />

an estimated octanol/water partition coefficient of 6.584, <strong>and</strong> a Henry's Law constant of 6.95~10"<br />

(ATSDR, 1990).<br />

There is no commercial production or known use of indeno[l,2,3-cdJpyrene (IARC, 1983). The<br />

compound is found in fossil fuels <strong>and</strong> occurs ubiquitously in products of incomplete combustion. It has<br />

been detected in mainstream cigarette smoke; gasoline engine exhaust; emissions from burning coal;<br />

lubricating oils; used motor oils (IARC, 1983); <strong>and</strong> soils, surface waters, <strong>and</strong> groundwater at hazardous<br />

waste sites (ATSDR, 1990). Indeno[l,2,3-cd]pyrene is one of a number of PAHs on the United States<br />

Environmental Protection Agency's (EPA's) priority pollutant list (ATSDR, 1990).<br />

2. METABOLISM AND DISPOSITION<br />

2.1 ABSORPTION<br />

Data regarding the gastrointestinal or pulmonary absorption of indeno[l,2,3-cdJpyrene in humans<br />

or animals were not available. However, data from structurally-related PAHs, primarily benzo[u]pyrene,<br />

suggest that indeno[l,2,3-cdjpyrene would be absorbed from the gastrointestinal tract, lungs, <strong>and</strong> skin<br />

(EPA, 1991).<br />

2.2 DISTRIBUTION<br />

No human or animal data were available concerning the tissue distribution of<br />

indenor 172,3-cdJpyrene.<br />

2.3 METABOLISM<br />

In mouse skin, Rice et al. (1986) identified 8-hydroxyindo[l,2,3-cdJpyrene as the most abundant<br />

metabolite; other major metabolites included 9-hydroxyindo[ 1,2,3-cdJpyrene <strong>and</strong> fruns- 1,2dihydro-l,2-<br />

dihydroxyindenol[ 1,2,3-~dJpyrene. In vitro metabolism studies using rat liver microsomes show that<br />

some metabolites identified included the franr-l,2dihydrodiol of indeno[ 172,3-cdJpyrene, the fruns-l,2-<br />

dihydrodiols of 8- <strong>and</strong> 9-hydroxy-indeno[l,2,3-cdjpyrene, <strong>and</strong> the 1,2quinone form of indeno[l,2,3-<br />

capyrene (Rice et al., 1985).<br />

1


2<br />

2.4 EXCRETION<br />

No human or animal data were available concerning the excretion of indeno[l,2,3-cdJpyrene.<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1 ORALEXPOSURES<br />

Information on the acute, subchronic, chronic, developmental, or reproductive oral toxicity of<br />

indeno[l,2,3-cd]pyrene in humans or animals was not available. Because of the lack of toxicity data, an<br />

oral reference dose (RfD) for indeno[l,2,3-cdJpyrene has not been derived (EPA, 1994).<br />

3.2 INHALATION EXPOSURES<br />

Information on the acute, subchronic, chronic, developmental, or reproductive toxicity of<br />

indeno[l,2,3-cdJpyrene in humans or animals following inhalation exposure was not available. Because<br />

of a lack of toxicity data, an inhalation reference concentration (FUC) for indeno[ 1,2,3-cd]pyrene has not<br />

been derived (EPA, 1994).<br />

3.3 OTHER ROUTES OF EXPOSURE<br />

Information on the acute, subchronic, chronic, developmental, or reproductive toxicity of<br />

indeno[l,2,3-cdJpyrene in humans or animals by other routes of exposure was not available.<br />

3.4 TARGET ORGANWCRITICAL EFFECTS<br />

No data were available to identify target organs or critical effects for oral, inhalation, or other<br />

routes of exposure to indeno[ 1,2,3-cd]pyrene.<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1 ORALEXPOSURES<br />

Infonnarion on the carcinogenicity of indeno[l,2,3-~dJpyrene in humans or animals following oral<br />

exposure was not available.


3<br />

<strong>4.</strong>2 INHALATION EXPOSURES<br />

<strong>4.</strong>2.1 Human<br />

Although there are no human data that specifically link exposure to indeno[l,2,3-~dlpyrene to<br />

human cancers, indeno[l,2,3-cdJpyrene is a component of mixtures that have been associated with human<br />

cancer. These mixtures include coal tar, soots, coke oven emissions, <strong>and</strong> cigarette smoke (EPA, 1994).<br />

<strong>4.</strong>2.2 Animal<br />

Information on the carcinogenicity of indeno[ 1,2,3-cdJpyrene in animals following inhalation<br />

exposure was not available.<br />

<strong>4.</strong>3 OTHER ROUTES OF EXPOSURE<br />

<strong>4.</strong>3.1 Human<br />

Information on the carcinogenicity of indeno[l,2,3-cdJpyrene in humans by other routes of exposure<br />

was not available.<br />

<strong>4.</strong>3.2 Animal<br />

Indeno[ 1,2,3-Cd]pyrene was tested for carcinogenicity in skin application, initiation-promotion, lung<br />

implant, subcutaneous (s.c.) injection, <strong>and</strong> intraperitoneal (i.p.) injection bioassays.<br />

Hoffmann <strong>and</strong> Wynder (1966) applied solutions of indeno[ 1,2,3-cdJpyrene in dioxane or acetone<br />

to the skin of groups of 20 female Swiss albino mice. Solutions of 0.05 or 0.1 % indeno[l,2,3-cdJpyrene<br />

in dioxane did not induce skin tumors, whereas acetone solutions induced a dose-related increased<br />

incidence of skin tumors. No tumors were observed following treatment with 0.01 or 0.05% solutions<br />

in acetone; a concentration 0.1 % induced six papillomas <strong>and</strong> three carcinomas beginning at 9 months,<br />

<strong>and</strong> a concentration of 0.5% induced seven papillomas <strong>and</strong> five carcinomas, with the first tumor<br />

appearing after 3 months. By contrast, repeated topical application of up to 9.2 pg of indeno[l,2,3-<br />

cdJpyrene in acetone for a lifetime did not produce skin tumors in mice (Habs et al., 1980).<br />

Rice et al. (1986) evaluated the tumor-initiating activity of indeno[l,2,3-cdjpyrene by applying<br />

indeno[l,2,3-cdJpyrene in acetone every other day for 10 days (total dose 1 mg) to the skin of 20<br />

Cr1:CD-1 mice. This procedure was followed by treatment with 12-o-tetradecanoyl-phorbol-13-acetate<br />

(TPA) 3 times weekly for 20 weeks. The incidence of skin tumors was close to 100%. Hoffmann <strong>and</strong><br />

Wynder (1966) reported that 10 skin applications at 2-day intervals at a total dose of 250 pg initiated skin<br />

carcinogenesis when female Swiss albino mice were subsequently treated with croton oil. A total of 10<br />

papillomas developed in 5 animals treated with croton oil.<br />

Female Osborne-Mendel rats (35/group) received single lung implants of 0.16, 0.83, or <strong>4.</strong>15 mg<br />

indeno[172,3-cdJpyrene in a mixture of beeswax <strong>and</strong> trioctanoin (Deutsch-Wenzel et al., 1983). An<br />

untreated group <strong>and</strong> a group receiving the vehicle served as controls. Granulomatous inflammatory<br />

lesions developed at the injection sites. After a lifetime of observation, the incidence of epidermoid


4<br />

carcinomas in the lung showed a statistically significant (p=0.05) dose-related increase. The observed<br />

incidences were 3/35, 8/35, <strong>and</strong> 21/35, respectively, in the low-, mid-, <strong>and</strong> high-dose groups. In<br />

addition, one pleomorphic lung sarcoma developed in one lowdose rat. No lung tumors occurred in<br />

untreated or vehicle control animals.<br />

Male <strong>and</strong> female XW nc/Z mice (14/sex) were given S.C. injections of 0.6 mg indeno[l,2,3-<br />

capyrene in olive oil once a month for 3 months (Lacassagne et al., 1963). Injection site sarcomas<br />

developed in 10 male mice within 265 days <strong>and</strong> in 1 female mouse within 145 days. Although no<br />

concurrent controls were used, the authors reported that no spontaneous skin tumors had been observed<br />

in historical controls.<br />

LaVoie et al. (1987) administered i.p. injections of indeno[l,2,3-cdJpyrene in dimethyl sulfoxide<br />

to 30 CD-1 mice (males <strong>and</strong> females combined) on days 1, 8, <strong>and</strong> 15 of life at a total dose of<br />

2.1 pmoYmouse. The animals were sacrificed at 52 weeks of age. A lung adenoma developed in 1/11<br />

surviving male mice; no lung tumors were seen in female treated mice or in vehicle controls.<br />

Although several noncarcinogenic PAHs have been shown to reduce the ability of benzo[a]pyrene<br />

to produce injection site sarcomas, S.C. injections of indeno[ 1,2,3-cd]pyrene in tricaprylin vehicle had no<br />

such inhibiting effect ( Fa et al., 1964).<br />

<strong>4.</strong>4 EPA WEIGHT OF EVIDENCE<br />

Classification-B2; probable human carcinogen (EPA, 1994)<br />

Basis-Based on no human data <strong>and</strong> sufficient data from animal bioassays. Indeno[ 1,2,3-cdJpyrene<br />

produced tumors in mice after lung implants, S.C. injection, <strong>and</strong> dermal exposure. Indeno[l,2,3-<br />

cdJpyrene tested positive in bacterial gene mutation assays.<br />

#<br />

<strong>4.</strong>5 CARCINOGENICITY SLOPE FACTORS<br />

No carcinogenicity slope factors were calculated.<br />

5. REFERENCES<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Registry). 1990. Toxicological Profile for Polycyclic<br />

Aromatic Hydrocarbons. Acenaphthene, Acenaphtlylene, Anthracene, Benzo (a)anthracene,<br />

Benzo (a)pyrene, Benzo Ofluoranthene, Benzo (g, i, h)perylene, Benzo (klfluoranthene, Chrysene,<br />

Dibenzo(a, h)anzhene, Fluoranthene, Fluorene, Indeno(1 I 2,3-cId)pyrene, Phenanthrene, Pyrene.<br />

Prepared by Clement international Corporation, under Contract No. 205-88-0608. ATSDIUTP-90-<br />

20.<br />

Deutsch-Wenzel, R.P., H. Brune, G. Grimmer, et al. 1983. "Experimental studies in rat lungs on the<br />

carcinogenicity <strong>and</strong> dose-response relationships of eight frequently occurring environmental<br />

polycyclic aromatic hydrocarbons." J. Natl. Carrcer I.!. 71: 539-54<strong>4.</strong>


5<br />

Falk, H.L., P. Kotin, <strong>and</strong> S. Thompson. 196<strong>4.</strong> "Inhibition of carcinogenesis. The effect of polycyclic<br />

hydrocarbons <strong>and</strong> related compounds. " Arch. Environ. Health 9: 169-179.<br />

Habs, M., D. Schrnahl, <strong>and</strong> J. Misfeld. 1980. "Local carcinogenicity of some environmentally relevant<br />

polycyclic aromatic hydrocarbons after lifelong topical application to mouse skin. 'I Arch.<br />

Geschwulsgorsch. 50: 266-27<strong>4.</strong><br />

Hoffmann, D. <strong>and</strong> E.L. Wynder. 1966. "Beitrag zur carcinogen Wirkung von Dibenzopyrene." Z.<br />

Krebsforsch. 68: 137- 149.<br />

IARC (International Agency for Research on Cancer). 1973. "Indene( 1,2,3-cd)pyrene." In: IARC<br />

Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Certain Polycyclic<br />

Aromatic Hydrocarbons <strong>and</strong> Heterocyclic Compounds, Vol 3. IARC, Lyon, France, pp. 229-237.<br />

IARC (International Agency for Research on Cancer). 1983. "Indene[ 1,2,3-cd]pyrene." In: IARC<br />

Monographs on the Evalm'on of Carcinogenic Risk of Chemicals to Humans. Polycyclic Aromatic<br />

Compoundr, Part I, Chemical, Environmental <strong>and</strong> Experimental Data, Vol 32. IARC, Lyon,<br />

France, pp. 373-378.<br />

Lacassagne, A., N.P. Buu-Hoi, F. Zajdela, et al. 1963. "Activite cancerogene d'hydrocarbures<br />

aromatiques polycycliques a noyau fluoranthene. " Un. Int. Cancer Acta 19: 490-496.<br />

LaVoie, E.J., J. Braley, J.E. Rice, <strong>and</strong> A. Rivenson. 1987. "Tumorigenic activity for non-alternant<br />

polynuclear aromatic hydrocarbons in newborn mice." Cancer Lett. 34: 15-20.<br />

Rice, J.E., D.T. Coleman, T.J. Hosted, Jr., et al. 1985. "Identification of mutagenic metabolites of<br />

indeno[i,2,3-cd]pyrene formed in vitro with rat liver enzymes." Cancer Res. 45: 5421-5425.<br />

Rice, J.E., T.J. Hosted, Jr., M.C. DeFloria, et al. 1986. "Tumor-initiating activity of major in vivo<br />

metabolites of indeno[l,2,3-cd]pyrene on mouse skin. I' Carcinogenesis 7: 1761-176<strong>4.</strong><br />

U . S . EPA. 1991. Drinking Water Criteria Document for Polycyclic Aromatic Hydrocarbons (PM).<br />

Prepared by the Environmental Criteria <strong>and</strong> Assessment Office,Office of Health <strong>and</strong> Environmental<br />

Assessment, U.S. Environmental Protection Agency, Cincinnati, OH, for the Office of Drinking<br />

Water. ECAO-CIN-DOlO.<br />

U.S. EPA. 199<strong>4.</strong> Integrated Risk Information System (IRIS). Environmental Criteria <strong>and</strong> Assessment<br />

Office, Office of Health <strong>and</strong> Environmental Assessment, Cincinnati, OH.


TOXICITY SUMMARY FOR<br />

MANGANESE<br />

July 1995<br />

Prepared by:<br />

A. A. Francis <strong>and</strong> C. Forsyth<br />

Chemical Hazard Evaluation Group<br />

Biomedical <strong>and</strong> Environmental Infomation Analysis <strong>Section</strong><br />

Health Sciences Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Lockheed Martin Energy Systems, Inc., for the U.S. Department of Energy under<br />

Contract No. DE-AC05-840R2 1400


EXECUTIVE SUMMARY<br />

Manganese is an essential trace element in humans that can elicit a variety of serious toxic<br />

responses upon prolonged exposure to elevated concentrations either orally or by inhalation. The<br />

central nervous system is the primary target. Initial symptoms are headache, insomnia, dsorientation,<br />

anxiety, lethargy, <strong>and</strong> memory loss. These symptoms progress with continued exposure <strong>and</strong><br />

eventually include motor disturbances, tremors, <strong>and</strong> Mtculty in walking, symptoms similar to those<br />

seen with Parkinsonism. These motor difficulties are often irreversible. Based on human<br />

epidemiologcal studies, 0.8 mg/kg/day for dnnking water exposure <strong>and</strong> 0.34 mg/m’ in air for<br />

inhalation exposure have been estimated as lowest-observed-adverse-effect levels (LOAELs) for<br />

central nervous system effixts.<br />

Effects on reproduction (decreased fertility, impotence) have been observed in humans with<br />

inhalation exposure <strong>and</strong> in animals with oral exposure at the same or slmilar doses that initiate the<br />

central nervous system effects. An increased incidence of coughs, colds, dyspnea during exercise,<br />

bronchitis, <strong>and</strong> altered lung ventilatory parameters have also been seen in humans <strong>and</strong> animals with<br />

inhalation exposure. A possible effect on the immune system may account for some of these<br />

respiratory symptoms.<br />

Because of the greater bioavailability of manganese from water, separate reference doses (RfD)<br />

for water <strong>and</strong> diet were calculated. A chronic (EPA 1995) <strong>and</strong> subchronic RfD (EPA 1994) for<br />

drinking water of 0.005 mg/kg/day has been calculated by EPA fiom a human no-observed-adverseeffect<br />

level (NOAEL) of 0.005 mgkg/day; the NOAEL was determined fiom an epidemiological<br />

study of human populations exposed for a lifetime to manganese concentrations in drinking water<br />

rangmg fiom 3.6-2300 pg/L (Kondakis et al. 1989). A chronic (EPA 1995) <strong>and</strong> subchronic RfD<br />

(EPA 1994) of 0.14 mg/kg/day for dietary exposure has been Calculated by EPA fiom a human<br />

NOAEL of 0.14 mg/kg/day, which was determined from a series of epidemiological studies<br />

(Schroeder et al. 1966, WHO 1973, NRC 1989). Large populations with different concentrations of<br />

manganese in their diets were examined. No adverse effects that were attributable to manganese were<br />

seen in any of these groups. For both the drinlung water <strong>and</strong> dietary values, the RfD was derived<br />

from these studies without uncertamty factors since manganese is essential in human nutrition <strong>and</strong><br />

the exposure of the most sensitive groups was included in the populations examined. EPA (1995)<br />

indicates that the chronic RfD values are pendmg change.<br />

A reference concentration (RE) of 0.05 pg/m’ @PA 1995) for chronic inhalation exposure was<br />

calculated fiom a human LOAEL of 0.05 m@m3 for impairment of neurobehavioral function from<br />

an epidemiological study by Roels et al. (1992). The study population was occupationally exposed<br />

to airborne manganese dust with a median concentration of 0.948 mg/m’ for 0.2 to 17.7 years with<br />

a mean duration of 5.3 years. Neurological examinations, psychomotor tests, lung function tests,<br />

blood tests, <strong>and</strong> urine tests were used to determine the possible effects of exposure. The LOAEL was<br />

derived from an occupational-lifetime integrated respirable dust concentration of manganese dioxide<br />

expressed as mg manganese/m3 x years. Coddence in the inhalation RfC is rated mdum by the<br />

EPA.<br />

Some conflicting data exist on possible carcinogenesis following injections of manganese<br />

chloride <strong>and</strong> manganese sulfate in mice. However, the EPA weight-of-evidence classlfication<br />

...<br />

u1


is: D, not classifiable as to human carcinogenicity based on no evidence in humans <strong>and</strong> inadequate<br />

evidence in animals (EPA 1995).<br />

iv


1. INTRODUCTION<br />

Manganese (CAS registry number 7439-96-5) makes up about 0.10% of the earth's crust <strong>and</strong> is<br />

the 12th most abundant element. It can exist in oxidation states fiom -3 to +7, the most common<br />

being +4 in the chemical form of manganese dioxide (Keen <strong>and</strong> Leach 1988). The oxides <strong>and</strong><br />

peroxides are used in industry as oxidizers, <strong>and</strong> the metal is used for manufacturing metal alloys to<br />

increase hardness <strong>and</strong> corrosion resistance. In living systems, manganese is an essential element that<br />

is found most often in the +2 valence (Keen <strong>and</strong> Leach 1988, Stokinger 1981).<br />

Normal nutritional requirements of manganese are satisfied through the diet, which is the normal<br />

source of the element, with minor contributions fiom water <strong>and</strong> air (EPA 1984). The National<br />

Research Council (NRC 1989) recommends a dietary allowance of 2 to 5 mg/day for a safe <strong>and</strong><br />

adequate intake of manganese for an adult human. Toxic exposures occur largely due to particulate<br />

material in the air fiom mining <strong>and</strong> manufacturing activity.<br />

2. METABOLISM AND DISTRIBUTION<br />

2.1 ABSORPTION<br />

Intestinal absorption has been estimated to be between 3 <strong>and</strong> 10% of the amount of manganese<br />

ingested <strong>and</strong> is a multiple-step process similar to <strong>and</strong> involving some of the same binding sites as in<br />

iron absorption (EPA 1995). Experiments with isolated rat intestines indicate that manganese<br />

absorption is carrier-mdated with saturation Occurring at 0.5 mM (Testolin et al. 1993). The<br />

absorption of manganese by inhalation depends on the particle size. The larger particles are cleared<br />

from the respiratory tract by the cilia <strong>and</strong> swallowed; whereas, the fine particles (< 2.5 microns) are<br />

deposited in the lungs <strong>and</strong> must be cleared by absorption into the blood <strong>and</strong> lymph circulation (EPA<br />

1995). It is estimated that 60 to 70% of the inhaled particles are eventually swallowed (Stokhger<br />

1981).<br />

2.2 DISTRIBUTION<br />

Once absorbed, manganese is transported to organs rich in mitochondria (in particular the liver,<br />

pancreas, <strong>and</strong> pituitary) where it is rapidly concentrated. Accumulation of manganese in the central<br />

nervous system following an intraperitoneal or intramuscular injection occurs slowly reaching a<br />

maximum in about 30 days. Distribution is homogeneous in the brain with lower concentrations in<br />

the spinal cord. The average turnover time in the central nervous system is reported to be about 1 10<br />

days following intraperitoneal injection <strong>and</strong> about 55 days for intramuscular injection<br />

(Stokinger 1981).<br />

1


2<br />

23 METABOLISM<br />

Manganese does not undergo metabolism; it is absorbed <strong>and</strong> excreted unchanged. However,<br />

manganese is an essential trace element <strong>and</strong> is involved as an activator or cofactor with a number of<br />

diverse enzymes involved with energy metabolism, digestion, <strong>and</strong> lipid <strong>and</strong> protein metabolism<br />

(Orten <strong>and</strong> Neuhaus 1975).<br />

2.4 EXCRETION<br />

The normal adult body pool of about 20 mg is maintained by the liver, <strong>and</strong> excess manganese<br />

is excreted into the intestine via the bile. This control is achieved with a daily intake of 10 to 20%<br />

of the total pool; therefore, relatively large amounts are h<strong>and</strong>led by this mechanism. The normal<br />

urinary level of manganese averages about 2.75 pg/L with a range of about 1.0 to 8.0 p a. Urinary<br />

levels over 10 pg/L are indicative of manganese overexposure (Stokinger 198 1).<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1 ORALEXPOSURES<br />

3.1.1 Acute Toxicity<br />

3.1.1.1 Human<br />

Information on the acute oral toxicity of manganese in humans was unavailable.<br />

3.1.1.2 Animal<br />

Due to the control exerted by mammals over manganese absorption <strong>and</strong> excretion, acute oral<br />

toxicity is observed only after relatively large doses. However, several LDS, values have been<br />

calculated. In one oral study using Sprague-Dawley rats, manganese dichloride tetrahydrate was<br />

given by stomach tube, <strong>and</strong> the animals were observed for 14 days. The LD, was calculated to be<br />

1484 mgkg or 7.5 mmoIeAcg. The manganese concentrations in the liver, kidney, spleen, heart,<br />

testes, brain, <strong>and</strong> blood of the surviving animals retumed to control values within the 14day period<br />

(Holbrook et al. 1975).<br />

Other oral values include an LD, of 1715 mgkg for manganese dichloride in mice <strong>and</strong><br />

3730 mg/kg for manganese2' acetate in rats (Lew~s <strong>and</strong> Sweet 1984). Potassium permanganate, a<br />

strong oxidizing agent, is an irritant to mucosal tissues, is hemolyhc, <strong>and</strong> damages capillaries<br />

regardless of the route. An oral LDx, of 1090 mgkg has been determined for potassium<br />

permanganate in rats (Stokinger 1981).<br />

However, rats maintained on manganesedeficient diets for 2 1 days had higher plasma ammonia<br />

<strong>and</strong> lower plasma urea concentrations in association with lowered hepatic manganese concentrations<br />

<strong>and</strong> decreased arginase activity as compared to rats on diets containing 48 pg manganesdg diet<br />

(Brock et al. 1994).<br />

3.1.2 Subchronic Toxicity


3<br />

3.1.2.1 Human<br />

A number of epidemiological studies have been performed that document the response of human<br />

populations to subchronic or chronic exposure to elevated manganese concentrations. Signs of<br />

toxicity may appear within months <strong>and</strong> can continue for years. Initial signs of manganese toxicity<br />

usually include headache, disorientation, speech disturbances, memory loss, <strong>and</strong> acute anxiety.<br />

Prompt removal of the affected person from the source of manganese exposure usually results in<br />

reversal of most of the symptoms; however, the symptoms will increase <strong>and</strong> eventually become<br />

irreversible if the individual continues to be exposed to high manganese concentrations (Keen <strong>and</strong><br />

Leach 1988). <strong>Section</strong> 3.1.3 provides discussions of individual studies.<br />

3.1.2.2 Animal<br />

A decrease in brain amines was observed in a study of the effects of manganese chloride on<br />

brain chemistry. Male Sprague-Dawley rats were given 0.1 or 1.0 mg manganesdd in drinkrng<br />

water for 8 months after which the brains were removed, dissected, <strong>and</strong> analyzed for various brain<br />

amines. Effects were seen with both doses. Decreases in the following amines were observed:<br />

dihydroqphenylacetic, noradrenaline, homovanillic acid, 5-hydroqmdolacetic acid, noradrenaline,<br />

<strong>and</strong> serotonin.<br />

In a similar study, rats were given 0.54 mg MnC12.5H@n.L in drinking water for 90 days<br />

(Subhash <strong>and</strong> Padmashree 1991). Manganese accumulation in various brain regions was two- to<br />

three-fold that of controls. In addition, inhibition of dopamine P-hydroxylase <strong>and</strong> monoamine<br />

oxidase, decreased <strong>and</strong> increased dopamine levels, <strong>and</strong> increased serotonin were observed in various<br />

brain regions.<br />

Feedlot calves fed a diet supplemented with 50 ppm zinc methionine plus 40 ppm manganese<br />

methionine for 34 days had better response to disease challenge than control (no supplement) animals<br />

or calves supplemented with the oxide forms of zinc <strong>and</strong> manganese. Calves fed the organic form of<br />

the metals had lower temperatures, higher feed intake, <strong>and</strong> greater body weight gain foIlowing<br />

challenge with infectious bovine rhinotracheitis virus when compared to control or inorganic zinc<br />

<strong>and</strong> manganese supplemented calves (Chirase et al. 1994).<br />

3.13 Chronic Toxicity<br />

3.1.3.1 Human<br />

An epidemiological study by Schrder et al. (1966) on n o d diets in the United States,<br />

Engl<strong>and</strong>, <strong>and</strong> Holl<strong>and</strong>, demonstrated that the average daily intake of manganese ranged from about<br />

2.3 to 8.8 mg/day. Certain other diets (vegetarian) were possibly higher in manganese, but all were<br />

considered safe for chronic human consumption. In another portion of the study, patients were given<br />

9 mg manganesdday as manganese citrate for many months. Assuming the average dietary intake<br />

of 2.5 mg/day, the total manganese intake was about 11.5 mg/day. No signs of toxicity were seen in<br />

either part of the study.<br />

The World Health Organization reviewed the previous study <strong>and</strong> other dietary information <strong>and</strong><br />

concluded that 2 to 3 mg manganesdday is adequate for adults <strong>and</strong> 8 to 9 mg/day is safe (WHO<br />

1973). The Food <strong>and</strong> Nutrition Board of the National Research Council also examined the avadable<br />

evidence <strong>and</strong> determined 10 mg manganesdday to be safe. They chose an adequate <strong>and</strong> safe intake<br />

of manganese to be 2 to 5 mg/day for adults (NRC 1989).


4<br />

Sixteen cases of manganese toxicity from drinking contaminated water were reported in a study<br />

by Kawamura et al. (1941). The symptoms included lethargy, increased muscle tonus, tremor, <strong>and</strong><br />

mental disturbances. Children were affected less than the elderly. The drinking water was estimated<br />

to contain at least 28 mg manganese& which would be equivalent to an intake of 0.8 mgkglday (56<br />

mg/day) for a 70-kg adult drinking 2 L of water/day.<br />

K<strong>and</strong>alus et al. (1989) conducted an epidemiologtcal study in three areas of northwestern Greece<br />

containing maximum manganese concentrations of 1<strong>4.</strong>6, 252.6 <strong>and</strong> 2300 pgL in dnnking water.<br />

Mean concentrations of manganese in hair samples were 3.5 1,<strong>4.</strong>49 <strong>and</strong> 10.99 pg/g dry weight from<br />

the areas with low, medium, <strong>and</strong> high manganese concentrations, respectively, in drinking water. The<br />

concentration in whole blood was the same for all three areas. The individuals in the study were<br />

given a neurological examination designed to test for the presence <strong>and</strong> severity of 33 different<br />

symptoms associated with manganese central nervous system toxicity. The combined average scores<br />

for both sexes were 2.7, 3.9, <strong>and</strong> 5.2 for the low, medium, <strong>and</strong> high concentrations, respectively.<br />

Although this effect was not large, the score for the hgh concentration was sigmfkantly higher than<br />

the score recorded for the low concentration. The experiment was criticized for the small numbers<br />

of individuals tested, the lack of scatter data, <strong>and</strong> the lack of dietary data. Nevertheless, the<br />

experiment established an uncertainty about extrapolating dietary risk factors to drinking water<br />

without considering the possibility of differential absorption @PA 1995).<br />

In addition to the central nervous system effects, an iron-responsive anemia is commonly found<br />

with orally-induced manganese toxicity (Keen <strong>and</strong> Leach 1988).<br />

3.13.2 Animal<br />

A number of studies have shown that biochemical changes occur in the brains of rodents<br />

following the administration of about 1 mglmL manganese dichloride tetrahydrate in drinking water<br />

(Lai et al. 1981, Leung et al. 1981; see Sect. 3.1.2.2 for further chscussion). Various forms of<br />

manganese in the diet of mice affect biogenic amine levels in the brain. Mice were fed<br />

2 g manganesekg in the form of MnC12.4H20, Mn(CQ COOL -4% 0, MnCQ , or h4nQ for 12<br />

months (Komura <strong>and</strong> Sakamoto 1992). Manganese dioxide feeding resulted in lowered dopamine<br />

levels in the corpus striatum, hypothalamus, <strong>and</strong> midbrain. Accumulation of manganese in the brain<br />

correlated with both reduced dopamine levels in the hypothalamus <strong>and</strong> suppression of motor activity<br />

in the manganese acetate group.<br />

A study of more relevance to humans was conducted by Gupta et al. (1980). Neurological<br />

symptoms, including muscular weakness <strong>and</strong> rigidity of the lower limbs, were seen in a group of 4<br />

rhesus monkeys after 18 months treatment with 6.9 mg manganese,/kg/day @veri as manganese<br />

dichloride tetrahydrate). Degenerated neurons in the substantia nigra <strong>and</strong> scanty neuromelanin<br />

granules in pigmented cells were reported upon histological analysis.<br />

Lambs on a high manganese diet developed a reduction in hemoglobin. This observation is<br />

consistent with the anemia seen in humans <strong>and</strong> indicates that large amounts of manganese can<br />

interfere with intestd iron absorption (Stokhger 198 1).


3.1.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1 Human<br />

5<br />

Information on developmental <strong>and</strong> reproductive toxicity of manganese in humans following oral<br />

exposure was unavailable.<br />

3.1.<strong>4.</strong>2 Animal<br />

Groups of four adult male rhesus monkeys were given daily doses of 0 or 25 mg manganese<br />

chloride tetrahydratekg (6.94 mg manganesekg) by oral gavage for 18 months. The testes of the<br />

treated monkeys exhibited interstitial edema <strong>and</strong> degeneration of the seminiferous tubules<br />

(Murthy et al. 1980, EPA 1989).<br />

Other studies measured the effect of manganese chloride on various brain enzyme activities.<br />

Rats were exposed to 0, 1, or 10 mg/d in the drinking water from conception onwards. Both Na-K-<br />

ATPase <strong>and</strong> Mg-ATPase activities increased in most brain regions in treated rats as compared to<br />

controls between postnatal days 5 <strong>and</strong> 20 but were decreased by day 60. These transient enzyme<br />

changes occurred despite a dose-dependent increase in brain manganese levels (Lai et al. 1991). No<br />

differences were observed for brain monoamine oxidase activity (hung et al. 1993).<br />

Pregnant Long-Evans rats were fed diets containing 0,400,1100, or 3550 ppm manganese from<br />

day 2 of gestation. The F, offspring were fed the same diet until they were up to 225 days old.<br />

Decreased serum testosterone was observed in 100-day-old offspring exposed to 400 ppm<br />

manganese. Decreased fertility was seen upon mating the offspring receiving the 3550 ppm dose<br />

(Laskey et al. 1982).<br />

To determine the effect of excess aluminum on manganese deficiency in developing mice, dams<br />

were fed manganese deficient diets with or without hi& aluminum throughout gestation <strong>and</strong><br />

lactation. Offspring exposed to manganese deficient diets had growth retardation <strong>and</strong> reduced<br />

forelimb <strong>and</strong> hindlimb grip strength as compared to controls on postnatal day 2<strong>4.</strong> These effects were<br />

exacerbated by high aluminum (Golub et al. 1991).<br />

3.15 Reference Dose<br />

3.15.1 Subchronic: drinking water<br />

ORAL RtD,: 0.005 mgkg/day (EPA 1994)<br />

UNCERTAINTY FACTOR 1<br />

NOAEL: 0.005 mgkg/day<br />

Subchronic: diet<br />

ORAL RfD,: 0.14 mgkglday @PA 1994)<br />

UNCERTAINTY FACTOR: 1<br />

PRINCIPAL STUDIES: The same studies <strong>and</strong> comments apply for both the subchronic <strong>and</strong><br />

chronic RfD derivations. <strong>Section</strong> 3.1.5.2 provides further discussion.


6<br />

3.1.5.2 Chronic: drinking water<br />

ORAL RfD,: 0.005 mg/kg/day (EPA 1995)<br />

UNCERTAINTY FACTOR: 1<br />

MODIFYING FACTOR: 1<br />

NOAEL: 0.005 mg/kg/day<br />

CONFIDENCE:<br />

Study: Low-to-medium<br />

Data Base: Medium-to-low<br />

RfD: Medim-to-low<br />

VERIFICATION DATE: 09/22/92<br />

PRINCIPAL STUDY: Kondakis et al. 1989<br />

Chronic: diet<br />

ORAL me: 0.14 mgkg/day (EPA 1995)<br />

UNCERTAINTY FACTOR: 1<br />

MODIFYING FACTOR 1<br />

NOAEL: 0.14 mgkg/day<br />

LOAEL: none<br />

CONFIDENCE:<br />

Study: High<br />

Data Base: Medium<br />

RfD: Medium<br />

VERIFICATION DATE: 09/22/92<br />

PRINCIPAL STUDIES: Schroeder et al. 1966, WHO 1973, NRC 1989<br />

COMMENTS: Because of the greater bioavailability of manganese fiom water, a separate RfD<br />

for water was calculated. The major advantage of the Kondakk et al. (1989) study is that it<br />

examined a sensitive human subpopulation exposed for a lifetime; however, confidence is low<br />

in the study because of lack of data on concumnt dietary manganese. The dietary RfD is based<br />

on a composite of data fiom the three! principal references. The UIlCertainty factor of 1 was


7<br />

applied because the information used to determine the RfD was taken from large adult human<br />

populations, <strong>and</strong> the most sensitive subpopulation was represented within the group. Humans<br />

exert an efficient homeostatic control over manganese. It is important to recogmze that<br />

manganese is an essential human nutrient (EPA 1995). The most current IRIS records (EPA<br />

1995) indicate that the RfDs are pending change.<br />

3.2 INHALATION EXPOSURES<br />

3.2.1 Acute Toxicity<br />

3.2.1.1 Human<br />

The inhalation of manganese oxide fumes, such as could be produced from welding, can result<br />

in chills, fever, sweating, nausea, <strong>and</strong> coughmg. These influenza-like symptoms begin 4-12 hours<br />

after exposure <strong>and</strong> diminish after 24 hours. This “metal fume fever” usually causes no permanent<br />

damage unless exposure is continually repeated (Proctor et al. 1988).<br />

3.2.1.2 Animal<br />

Intratracheal injections of manganese oxides (particle size


8<br />

3.2.2 Subchronic Toxicity<br />

3.2.2.1 Human<br />

Most human studies on manganese toxicity are epidemiological studies on populations exposed<br />

to manganese compounds in dust particles. Individuals in these studies were exposed to manganese<br />

for less than one year to more than 20 years. The primary Merence between subchronic <strong>and</strong> chronic<br />

central nervous system symptoms is the reversibility of the early subchronic symptoms.<br />

An overlap exists between the inhalation <strong>and</strong> oral routes since manganese contained in larger<br />

particle sizes (greater than about 2.5 pm) is deposited in the tracheobronchial <strong>and</strong> extrathoracic<br />

regions <strong>and</strong> is cleared by the action of the cilia into the gastrointestinal tract. It is not surprising that<br />

the same central nervous system symptoms are seen with both routes (see Sect. 3.1.2.1). Respiratory<br />

system effects, nasal irritation, colds, bronchitis, <strong>and</strong> pneumonia are increased in exposed<br />

populations, <strong>and</strong> these symptoms can be seen following subchronic <strong>and</strong> chronic exposures (see Sect.<br />

3.2.3 for individual experiments).<br />

3.2.2.2 Animal<br />

Dose-dependent hyperplasia of the peribronchial tissue, pulmonary emphysema <strong>and</strong> atelectasis,<br />

exudate in the bronchioles, <strong>and</strong> thickening of the alveolar wall were observed in rhesus monkeys<br />

exposed 22 hours/day for 10 months to manganese at concentrations of 0,0.7 or 3.0 mg/m3 (given<br />

as manganese dioxide dust) (Suzuki et al. 1978).<br />

3.23 Chronic Toxicity<br />

3.23.1 Human<br />

A study was conducted by Roels et al. (1987) in which 141 males occupationally exposed to<br />

manganese dioxide, tetroxide, sulfate, carbonate, <strong>and</strong> nitrate were compared to a group of 104 males<br />

who were not occupationdly exposed to these compounds. The groups were matched in background<br />

environmental factors, work load, <strong>and</strong> shift responsibilities. The duration of employment ranged fiom<br />

1 to 19 years with a mean of 7.1 years. A higher frequency of coughs, dyspnea during exercise,<br />

episodes of acute bronchitis, <strong>and</strong> altered lung ventilatory paramem were found in the exposed<br />

group. SiMcant alterations were also found in visual reaction time, audioverbal short-term<br />

memory, eye-h<strong>and</strong> coordination, <strong>and</strong> h<strong>and</strong> steadiness in the exposed group. A LOAEL of 0.34 mg/m3<br />

was determined from these observations.<br />

A more recent study by Roels et al. (1992) examined 92 male workers exposed to manganese<br />

dioxide dust in a battery plant. Exposure time ranged fkom 0.2-17.7 years (mean, 5.3 years) <strong>and</strong><br />

exposure concentrations of respirable <strong>and</strong> total dust were 0.215 mg/m3 <strong>and</strong> 0.948 mam,<br />

respectively. No differences were found in the manganese-exposed workers for respiratoxy or<br />

neurological symptoms, spirometric measurements, hormone levels, or calcium metabolism as<br />

compared to unexposed controls. However, visual reaction time, h<strong>and</strong>-eye coordination, <strong>and</strong> h<strong>and</strong><br />

steadiness were sipficantly impaired.<br />

A group of 60 welders from three separate plants who were exposed to manganese fumes were<br />

studied by Ch<strong>and</strong>ra et al. (1981). The mean concentrations of manganese were 0.31,0.57 <strong>and</strong> 1.74<br />

mg/m3 measured in the air from plants 1,2, <strong>and</strong> 3, respectively. Frequent colds, coughmg, <strong>and</strong> fever<br />

were reported by the individuals fiom plant 1; workers from all three plants reported insomnia. Signs<br />

of neurological e ffi measured by “brisk, deep reflexes” in the legs <strong>and</strong>or arms were seen in 25,


9<br />

50, <strong>and</strong> 45% of workers in plant 1,2 <strong>and</strong> 3, respectively. Tremors were ais0 observed in one worker<br />

in plant 1 <strong>and</strong> four workers in plant 2. Increased urinary manganese <strong>and</strong> serum calcium levels were<br />

also seen in workers from all plants. A LOAEL of 0.11 mg/m3 was determined from the mean<br />

exposure at plant 1.<br />

A similar study was reported by Iregren (1990) in which 15 workers fiom each of two Swdsh<br />

foundries were studied for manganese exposure. The inhalation exposure concentration varied from<br />

0.02 to 1.4 mg/m3, <strong>and</strong> the time of exposure varied from 1 to 35 years. A reference group of two<br />

unexposed workers from the same geographic area was matched (age, type of work) to each exposed<br />

worker. Neurobehavioral function was evaluated by eight computerized tests fiom the Swdsh<br />

Performance Evaluation System <strong>and</strong> two manual dexderity tests. Signtficant differences were found<br />

between the exposed <strong>and</strong> unexposed groups in simple reaction time <strong>and</strong> manual dexterity (finger<br />

tapping speed). A concentration-response relationship, however, could not be established. A LOAEL<br />

of 0.09 mg/m3 was determined for the neurologml effects.<br />

Alloy workers with an average of 16.7 years of work in a ferromanganese <strong>and</strong> silicomanganese<br />

alloy facility were compared to matched controls for symptom reporting <strong>and</strong> on a series of nervous<br />

system function tests (Mergler et al. 1994). Respirable manganese levels in the alloy plant at<br />

stationary sampling sites averaged 0.122 mg/m’. Alloy workers had sipficantly higher manganese<br />

blood levels than the control group (1.12 pg/lOO mL vs 0.72 &lo0 mL). Symptoms reported more<br />

frequently for the alloy workers included fatigue, adverse emotional state, memory loss, amtion<br />

difficulties, nightmares, sweating without physical exertion, difficulty maintaming an erection, <strong>and</strong><br />

tinnitus. Overall the alloy workers also performed more poorly than the controls on motor function<br />

tests, optic spatial organization of movement, dynamic organization, cognitive flexibility, <strong>and</strong><br />

olfactory perception threshold.<br />

Respiratory effects, including an increased incidence of colds, bronchitis, <strong>and</strong> pneumonia, have<br />

been reported in at least four other human studies. It is believed unlikely that exposure to manganese<br />

is solely responsible for the increased respiratory symptoms. A decrease in resistance to infectious<br />

agents, possibly as a result of a weakened immune response, is probably a contributing factor (EPA<br />

1995).<br />

3.23.2 Animal<br />

Groups of 4 female rhesus monkeys were exposed to 0 or 30 mg/m3 manganese 6 hours/day, 5<br />

dayslweek for 2 years. Sigruficantly decreased dopamine concentrations were observed in the caudate<br />

<strong>and</strong> globus pallidus regions of the brains of treated monkeys. No behavioral abnormalities were noted<br />

during routine (cage side) observations. Nemobebvioral dyshction was not specifically tested<br />

(Bird et al. 1984).<br />

3.2.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.2.<strong>4.</strong>1 Human<br />

The same population of male factory workers studied by Roels (see Sect. 3.2.3.1) was also<br />

stded by Lauwerys et al. (1985) for reproductive effects. The results of a fertility questionnaire<br />

indicated that fewer children were born to workers exposed to manganese dust betwem the ages of<br />

16-25 <strong>and</strong> 26-35. The same LOAEL of 0.34 mdm3 was calculated for reproductive effects.<br />

3.2.<strong>4.</strong>2 Animal


10<br />

Decreased body weight <strong>and</strong> impaired neurobehavioral performance (balance <strong>and</strong> coordmation)<br />

were seen in the offspring of female M CR mice that were exposed to 48.9 mg manganese/m3<br />

7 hourdday for 5 daydweek. Exposure was initiated 4 months prior to breeding <strong>and</strong> continued<br />

through day 18 of gestation. Similar neurobehavioral responses were obtained from offspring of<br />

unexposed mice which were fostered to manganese-exposed females during lactation (Massaro et al.<br />

1980).<br />

3.2.5 Reference ConcentratiodDose<br />

3.2.5.1 Subchronic<br />

A subchronic RfC for manganese has not been derived (EPA 1994).<br />

3.2.5.2 Chronic<br />

INHALATION RfC: 0.00005 mg/m’ (EPA 1995)<br />

UNCERTAINTY FACTOR: 1000<br />

MODIFYING FACTOR 1<br />

NOAEL: none<br />

LOAEL: 0.05 mg/m3<br />

CONFIDENCE:<br />

Study: Medium<br />

Data Base: Medium<br />

VERIFICATION DATE: 09/23/93<br />

PRINCIPAL STUDIES: Roels et al. 1987,1992<br />

COMMENTS: The LOAEL was derived from an occupational-lifetime integrated respirable<br />

dust concentration of manganese dioxide expressed as mg manganese/m3 x years. Effects were<br />

based on impairment of neurobehavioral function as a result of occupational exposure to<br />

manganese dust. The uncertainty factor accounts for the use of a LOAEL (lo), the protection<br />

of sensitive individuals (lo), <strong>and</strong> data base limitations reflecting both the less-than-chronic<br />

exposure time <strong>and</strong> the lack of developmental data, as well as potential but unquantdkd<br />

dif€erences in the toxicity of Merent forms of manganese (1 0).


11<br />

3.3 OTHER ROUTES OF EXPOSURE<br />

3.3.1 Acute Toxicity<br />

3.3.1.1 Human<br />

Taylor <strong>and</strong> Price (1982) reported a clinical case of acute pancreatitis that resulted from<br />

hemdalysis of a patient with a solution contarninated with manganese. Symptoms, which appeared<br />

within one hour from the start of dialysis, included severe vomitmg, epigastric pain, increased heart<br />

rate, <strong>and</strong> increased blood pressure. The dialysis was discontinued after 30 minutes. The dialysate was<br />

found to contain 715 pmoVL manganese sulfate. The diagnosis of acute pancreatitis was made the<br />

next day (day 2). The patient suffered fiom a high fever7 persistent abdominal pain, weakness, <strong>and</strong><br />

a drop in serum calcium fiom day 2 through day <strong>4.</strong> A high leukocyte count persisted past day 14 after<br />

which it returned to normal. The serum manganese levels were found to be <strong>4.</strong>55, 1.71, <strong>and</strong><br />

0.65 pmol/L on days 2,3, <strong>and</strong> 6, respectively. The patient was discharged free fiom abdominal pain<br />

<strong>and</strong> on a normal diet 3 1 days after manganese exposure.<br />

3.3.1.2 Animal<br />

A number of experiments have indicated that manganese is considerably more toxic by injection.<br />

LD,, values of 121 <strong>and</strong> 255 mgkg in mice were determined for manganese dichloride given by<br />

intraperitoneal <strong>and</strong> intramuscular injections, respectively. LDso values for the tetrahydrate are 190<br />

mag for intraperitoneal injection in mice <strong>and</strong> 138 mgkg for intraperitoneal injection in rats. The<br />

latter value can be compared to the LD, of 1484 mgkg for oral exposure in rats as discussed in Sect.<br />

3.1.1.2 (Lew~s <strong>and</strong> Sweet 1984).<br />

Histological changes in the lungs of rats have been reported to occur within minutes after the<br />

injection of 40 mgkg of manganese dioxide. An injection of manganese dioxide followed by a like<br />

injection of manganese dichloride resulted in severe congestion <strong>and</strong> pulmonary edema that was often<br />

fatal (Stokinger 1981).<br />

Brain damage has been induced in rats by direct injection of manganese into the brain (Sloot et<br />

al. 1994). Intrastriatal injections of manganese chloride produced dosedependent (0.05-0.8 pmol)<br />

dopamine depletion <strong>and</strong> timedependent (0.4 mol) calcium accumulation.<br />

Sprague-Dawley or Osborne-Mendel rats injected intraperitoneally with 40 mg manganesekg<br />

(given as manganese dichloride) became hyperglycemic within 2 hours. The increase in blood sugar<br />

was accompanied by a decrease in plasma insulin. Manganese was rapidly concentrated in the liver<br />

(45 minutes) <strong>and</strong> the pancreas (15 minutes). Blood sugar values returned to control levels within 8<br />

hours after the injection (Baly et al. 1985).<br />

Intravenous injection of manganese dichloride to male New Zeal<strong>and</strong> white rabbits caused a<br />

dose-responsive decrease in mean arterial pressure (3-100 pwg), an increase in heart rate (0.3-100<br />

pM/kg), <strong>and</strong> alterations in the electrocardiogram. These effects were not attenuated by<br />

coadministration of CaC1, (Lee 1993).


12<br />

3.3.2 Subchronic Toxicity<br />

3.3.2.1 Human<br />

Information on the subchronic toxicity of manganese in humans by other routes of exposure was<br />

unavailable.<br />

33.2.2 Animal<br />

Intraperitoneal injections to mice of 5 mg manganese chloridekglday, 5 daydweek, for 9 weeks<br />

did not alter the cholinergic muscarinic receptor density or the dwociation constant of 'Hquinuclidinyl<br />

benzilate in the striatum, fiontal cortex, or hippocampus brain regons (Villalobos et<br />

al. 1994).<br />

3.3.3 Chronic Toxicity<br />

Information on the chronic toxicity of manganese in humans or animals by other routes of<br />

exposure was unavailable.<br />

3.3.4 Developmental Toxicity<br />

3.3.<strong>4.</strong>1 Human<br />

Information on the developmental toxicity of manganese in humans by other routes of exposure<br />

was unavailable.<br />

3.3.<strong>4.</strong>2 Animals<br />

Swiss mice were given doses of manganese (II) chloride tetrahydrate by subcutaneous injection<br />

at doses of 0,2,4, 8, or 16 mg/kglday on gestation days 6-15. Maternal body weight gain <strong>and</strong> feed<br />

consumption were sigdicantly reduced in the 8 <strong>and</strong> 16 mg/kg groups as compared to controls. An<br />

increase was observed in the number of late resorptions in the 4,8, <strong>and</strong> 16 mgkg groups; a reduction<br />

in fetal body weights <strong>and</strong> an increase in delayed ossification of the bones of the skull <strong>and</strong> sternebra<br />

were observed in fetuses fiom the 8 <strong>and</strong> 16 mag groups (Shchez et al. 1993).<br />

3.4 TARGET ORGANS/CRITICAL EFFECTS<br />

3.<strong>4.</strong>1 Oral Exposures<br />

3.<strong>4.</strong>1.1 Primary target(s)<br />

1. Central nervous system: Initial symptoms include headache, insomnia, disorientation,<br />

speech disturbances, memoxy loss, <strong>and</strong> acute anxiety. Prompt removal of the affected<br />

person from the manganese source usually results in reversal of most of these symptoms.<br />

Continued subchronic to chronic expo- can result in motor difficulties, tremors,<br />

difficulty walking, <strong>and</strong> exaggerated reflexes similar to Parkinsonism. These later stages<br />

of toxicity are apparently secondary effects <strong>and</strong> are not reversible although the manganese<br />

concentrations in the tissues decrease to normal levels upon removal from the manganese<br />

source.


13<br />

2. Reproductive system: Chronic feeding studles in rats have kdicated decreased fertility<br />

results fiom chronic manganese exposure. Similar subchronic studles in monkeys have<br />

shown degenerative changes in the seminiferous tubules.<br />

3.<strong>4.</strong>1.2 Other targets<br />

Blood: An iron-responsive anemia can occur with orally-induced manganese toxicity<br />

possibly due to an interference with intestinal iron absorption by excess manganese.<br />

3.<strong>4.</strong>2 Inhalation Exposures<br />

3.<strong>4.</strong>2.1 Primary target@)<br />

1. Central nervous system: The same symptoms are seen as with acute to chronic oral<br />

exposure (Sect. 3.<strong>4.</strong>1.1). Since individuals are occupationally exposed to dust containing<br />

manganese during mining <strong>and</strong> manufacturing <strong>and</strong> to metal fumes during welding,<br />

inhalation is by far the most common route of exposure for manganese toxicity.<br />

2. Respiratory system: Subchronic to chronic symptoms include an increased incidence of<br />

colds, bronchitis, <strong>and</strong> pneumonia. Dyspnea during exercise, decreased vital capacity, <strong>and</strong><br />

decreased forced expiratory vital capacity have also been reported.<br />

3. Reproductive system: Decreased f dty has been seen in subchronic to chronic human<br />

inhalation studies.<br />

3.<strong>4.</strong>2.2 Other targets<br />

1. Pancreas: Manganese is known to concentrate in the pancreas <strong>and</strong> alter insulin production<br />

in rats. Acute pancreatitis has been reported in humans following accidental intravenous<br />

exposure.<br />

2. Immune system: Evidence in animal studies suggests that acute manganese exposure by<br />

inhalation results in an immunosuppression. The observed increase in the incidence of<br />

respiratory dections with subchronic to chronic human exposure to manganese<br />

substantiates this observation.<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1 ORAL EXPOSURES<br />

Information on the carcinogenicity of manganese by the oral route in humans or animals was<br />

unavailable.<br />

<strong>4.</strong>2 INHALATION EXPOSURES<br />

Information on the carcinogenicity of manganese by the inhalation route in humans or anrmals<br />

was unavailable.


14<br />

<strong>4.</strong>3 OTHER ROUTES OF EXPOSURE<br />

<strong>4.</strong>3.1 Human<br />

Information on the carcinogenicity of manganese by other routes of exposure in humans was<br />

unavailable.<br />

<strong>4.</strong>3.2 Animal<br />

DBA/1 mice were injected subcutaneously or intraperitoneally with 0.1 mL, of a 1% aqueous<br />

solution of manganese chloride twice weekly for 6 months. An increased number of lymphosarcomas<br />

developed in the treated animals compared with the controls. The tumor incidendnumber of animals<br />

in the dose group was: 24/36, 16/39, <strong>and</strong> 16/66 for the subcutaneous, intraperitoneal, <strong>and</strong> water<br />

control groups, respectively. The tumors appeared earlier in the treated groups as well<br />

@hPaolo 1964).<br />

Groups of 10 male <strong>and</strong> 10 female each of strain A Strong mice were injected intraperitoneally<br />

with 0,6,15, or 30 mgkg manganous sulfate 3 timeslweek for 7 weeks. The ammals were sacrificed<br />

<strong>and</strong> examined for tumors after 30 weeks. An increase in the average number of pulmonary adenomadmouse<br />

was apparent at the mid <strong>and</strong> high doses but the increase was significant only at the high<br />

dose (Stoner et al. 1976).<br />

F344 rats <strong>and</strong> female Swiss mice were injected intramuscularly with manganese powder <strong>and</strong><br />

manganese dioxide (10 mg each). The F344 rats were also injected with manganese”<br />

acetyl-acetonate. No differences were seen in tumor incidence between treated <strong>and</strong> control animals<br />

with manganese powder or manganese dioxide; however, there was a si@icant increase in injection<br />

site fibrosarcomas with the manganese” acetylacetonate (Furst 1978).<br />

Witschi et al. (1981) injected female A/J mice intraperitoneally with 80 mag<br />

methylcyclopentadienyl manganese tricarbonyl. Cell proliferation was produced in the lungs but no<br />

increase in tumor incidence was seen.<br />

<strong>4.</strong>4 EPA WEIGHT-OF-EVIDENCE<br />

Classification D-Not classifiable as to human carcinogenicity @PA 1995)<br />

Basis-Existing studies are madequate to assess the carcinogenicity of manganese.<br />

<strong>4.</strong>5 CARCINOGENICITY SLOPE FACTORS<br />

No slope factors for carcinogenicity have been calculated.


15<br />

5. REFERENCES<br />

Adkins, B., Jr., G. H. Luginbuhl, F. J. Miller, <strong>and</strong> D. E. Gardner. 1980. Increased pulmonary<br />

susceptibility to streptococcal infection following dation of manganese oxide, Environ. Res.<br />

23: 110-120.<br />

Baly, D. L., B. Lonnerdal, <strong>and</strong> C. L. Keen. 1985. Effects of high doses of manganese on<br />

carbohydrate homeostasis, Toxicology Letters 25: 95-102.<br />

Bird, E. D., A. H. Anton, <strong>and</strong> B. Bullock. 198<strong>4.</strong> The effect of manganese inhalation on basal ganglia<br />

dopamine concentrations in rhesus monkeys, Neurotoxicology 5( 1): 59-66.<br />

Brock, A. A., S. A. Chapman, E. A. Ulman, <strong>and</strong> G. Wu. 199<strong>4.</strong> Dietary manganese deficiency<br />

decreases rat hepatic arpase activity, J. Nutr. 124:340-34<strong>4.</strong><br />

Ch<strong>and</strong>ra, S. V., G. S. Shukla, R. S. Strivastava, H. Singh <strong>and</strong> V. P. Gupta. 1981. An exploratory<br />

study of manganese exposure to welders, Clin. Toxicol. 18: 407-416.<br />

Chirase, N. K., D. P. Hutcheson, G. B. Thompson, <strong>and</strong> J. W. Spears. 199<strong>4.</strong> Recovery rate <strong>and</strong> plasma<br />

zinc <strong>and</strong> copper concentrations of steer calves fed organic <strong>and</strong> inorganic zinc <strong>and</strong> manganese<br />

sources with or without injectable copper <strong>and</strong> challenged with infectious bovine rhinotracheitis<br />

virus,J. him. ScI. 72:212-219.<br />

DiPaolo, J. A. 196<strong>4.</strong> The potentiation of lymphosarcomas in mice by manganous chloride, Fed.<br />

Proc. 23: 393.<br />

EPA. 198<strong>4.</strong> Health Assessment Document for Manganese, prepared by the Office of Health <strong>and</strong><br />

Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment Office, Research Triangle<br />

Park, NC.EPA 600/8-83-013F.<br />

EPA. 1989. Reportable Quantity Document for Manganese, prepared by the Office of Health <strong>and</strong><br />

Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment Office, Cincinnati, OH for<br />

the Office of Solid Waste <strong>and</strong> Emergency Response, Washington, DC.<br />

EPA. 199<strong>4.</strong> Health Eflects Assessment Summary Tables FY-I 994 Annual, prepared by the Office of<br />

Research <strong>and</strong> Development, Environmental Criteria <strong>and</strong> Assessment Office, Cincinnati, OH for<br />

the Office of Emergency <strong>and</strong> Remedial Response, Washington DC. NTIS PB94-921199.<br />

EPA. 1995. Integrated Risk Information System (IRIS). Health Risk Assessment for Manganese, on<br />

line, Office of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment<br />

Office, Cincinnati, OH.<br />

Furst, A. 1978. Tumorigenic effect of an organomanganese compound on F344 rats <strong>and</strong> Swiss albino<br />

mice: Brief communication, J. Natl. Cancer Inst. 60: 1171-1 173.<br />

Golub, M. S., B. Han, <strong>and</strong> C. L. Keen. 1991. AI <strong>and</strong> Mn: interactions in adult <strong>and</strong> developing mice,<br />

Teratology 43:490.


16<br />

Gupta, S. K., R C. Murthy <strong>and</strong> S. V. Ch<strong>and</strong>ra. 1980. Neuromelanin in manganese-exposed primates,<br />

Toxicol. Lett. 6(1): 17-20.<br />

Holbrook, C. J. Jr., M. E. Washington,H. B. hake <strong>and</strong> P. E. Brubaker. 1975. Studies on the<br />

evaluation of the toxicity of various salts of lead, manganese, platinum, <strong>and</strong> palladun, Environ.<br />

Health Persp. 10: 95-101.<br />

Iregren, A. 1990. Psychologd test performance in foundry workers exposed to low levels of<br />

manganese, Neurotox. Teratol. 12: (in press).<br />

Kawamura, R, H. Ikuta, S. Fukuzumi, et al. 1941. Intoxication by manganese in well water, Kitasato<br />

Arch. &p. Med. 18: 145-169.<br />

Kern, C. L. <strong>and</strong> R M. Leach. 1988. Manganese, In: H<strong>and</strong>book on Toxiciry of Inorganic Compounds,<br />

eds. H.G. Seiler <strong>and</strong> H. Sigel, Marcel Dekker, Inc. pp. 405415.<br />

Komura, J. <strong>and</strong> M. Sakamoto. 1992. Effects of manganese forms on biogenic amines in the brain <strong>and</strong><br />

behavioral alterations in the mouse: long-term oral administration of several manganese<br />

compounds, Environ. Res. 57:34-4<strong>4.</strong><br />

Kondakis, X. G., N. Makris, M. Leotsinidis, M. Prinou <strong>and</strong> T. Papapetropoulos. 1989. Possible<br />

health effects of high manganese concentration in drinking water, Arch. Environ. Healrh. 44(3):<br />

1 75- 1 78.<br />

Lai, J. C. K., T. K. C. Leung <strong>and</strong> L. Lim. 1981. Brain regional distribution of glutarmc acid<br />

decarboxylase, choline acetyltransferase, <strong>and</strong> acetylcholinesterase in the rat: Effects of chronic<br />

manganese chloride administration after two years, J. Neurochem. 36(4): 1443-1448.<br />

Lai, J. C., T. K. Leung, L. Lim, A. W. Chan <strong>and</strong> M. J. Minsk. 1991. Effects of chronic manganese<br />

treatment on rat brain regional sodium-potassium-activated <strong>and</strong> magnesium-activated adenosine<br />

triphosphatase activities during development, Metab. Brain Dis. 6: 165- 17<strong>4.</strong><br />

Laskey, J. W., G. L. Rehnberg, J. F. Hein <strong>and</strong> S. D. Carter. 1982. Effects of chronic manganese<br />

(Mn,O,) exposure on selected reproductive parameters in rats, J. Toxicol. Environ. Health. 9:<br />

677-687.<br />

Lauwerys, R, H. Roels, P. Genet, et al. 1985. Fertility of male workers exposed to mercury vapor<br />

or to manganese dust: A questionnaire study,Arn. J. Ind. Med. 7: 171-176.<br />

Lee, K. C. 1993. Hemodynamic <strong>and</strong> electrophysiologic effects of manganese independent of calcium<br />

in anesthetized rabbits, Meth. Find. Erp. Clin. Pharmacol. 15:743-750.<br />

Leung, T. K. C., J. C. K. Lai, <strong>and</strong> L. Lim. 1981. The regional distribution of monoamine oxidase<br />

activities towards Werent substrates: Effects in rat brain of chronic administration of<br />

manganese chloride <strong>and</strong> of aging, J. Neurochem. 36(6): 2037-2043.<br />

Leung, T. K. C., L. Lim, <strong>and</strong> J. C. K. Lia 1993. Brain regional distributions of monoamine oxidase<br />

activities in postnatal development in normal <strong>and</strong> chronically manganese-treated rats, Metab.<br />

Brain Dis. 8:137-149.


17<br />

Lewis, R J. <strong>and</strong> D. V. Sweet, eds. 198<strong>4.</strong> Regrstry of Toxic Eficts of Chemical Substances, Vol. I,<br />

U.S. Department of Health <strong>and</strong> Human Services, Public Health Service, Centers for Disease<br />

Control, National Institute for Occupational Safety <strong>and</strong> Health, Cincinnati, OH.<br />

Massaro, E. J., R B. D'Agostino, C. Stineman, J. B. Marganti, <strong>and</strong> B. A. Lown. 1980. Alterations<br />

in behavior of adult offspring of female mice exposed to MnO, dust during gestation, Fed. Proc.<br />

Fed. Am. SOC. Exp. Biol. 39: 623.<br />

Mergler, D., G. Huel, R Bowler, A. kegren, S. BBlanger, M. Baldwin, R Tardif, A. Amargiassi, <strong>and</strong><br />

L. Martin. 199<strong>4.</strong> Nervous system dysfunction among workers with long-term exposure to<br />

manganese, Environ. Res. 64: 151-180.<br />

Murthy, R C., R S. Srivastava, S. K. Gupta, <strong>and</strong> S. V. Ch<strong>and</strong>ra. 1980. Manganese induced testicular<br />

changes in monkeys, Exp. Path. 18: 240-24<strong>4.</strong><br />

NRC (National Research Council). 1989. Recommended Dietary Allowances, 9th rev. ed, Food <strong>and</strong><br />

Nutrition Board, National Research Council, National Academy Press, Washington, DC. p.<br />

230-235.<br />

Orten, J. M. <strong>and</strong> 0. W. Neuhaus. 1975. Human Biochemist?y, Ninth Edition, The C.V. Mosby<br />

Company, St. Louis. pp. 546-547.<br />

Proctor, N. H., J. P. Hughes, <strong>and</strong> M. L. Fischman. 1988. Manganese (<strong>and</strong> Compounds) in Chemical<br />

Hazard of the Workplace, Second Edition, J.B. Lippincott Company, Philadelphia. pp.307-308.<br />

Roels, H., R Lauwexys, J. P. Buchet, et al. 1987. Epidemiological survey among workers exposed<br />

to manganese: Effects on lung, central nervous system, <strong>and</strong> some biological indices, Am. J. Ind.<br />

Med. 11: 307-328.<br />

Roels, H., P. Ghyselen, J. P. Buchet, E. Ceulemans, <strong>and</strong> R R Lauwexys. 1992. Assessment of<br />

permissible exposure level to manganese in workers exposed to manganese dioxide dust, Br. J.<br />

Ind. Med. 49:25-3<strong>4.</strong><br />

Shchez., D. J., J. L. Dominge, J. M. Llobet, <strong>and</strong> C. L. Keen. 1993. Maternal <strong>and</strong> developmental<br />

toxicity of manganese in the mouse, Toxicol. Lett. 69:45-52.<br />

Schroeder, H. A., D, D. Balassa, <strong>and</strong> I. H. Tipton. 1966. Essential trace metals in man: Manganese,<br />

a study in homeostasis, J. Chron. Dis. 19: 545-571.<br />

Shiotsuka, RN. 198<strong>4.</strong> Inhalation toxicity of manganese &oxide <strong>and</strong> magnesium oxide-manganese<br />

dioxide mixture. GRAI. 85(7): 3<strong>4.</strong><br />

Sloot, W. N., A. J. van der Sluijs-Gelling <strong>and</strong> J. B. P. Gramsbergen. 199<strong>4.</strong> Selective lesions by<br />

manganese <strong>and</strong> extensive damage by iron after injection into rat striatum or hippocampus, J.<br />

Neurochem. 62:205-2 16.<br />

Stdanger, H. E. 198 1. The Metals, In: Putty's Industrial Hygiene <strong>and</strong> Toxicology, Vol2A, eds. G.D.<br />

Clayton <strong>and</strong> F.E. Clayton, John Wiley & Sons, New York pp. 1749-1769.


18<br />

Stoner, G. D., M. B. Shimlun, M. C. Troxell, T. L. Thompson, <strong>and</strong> L. S. Terry. 1976. Test for<br />

carcinogenicity of metallic compounds by the pulmonary tumor response in strain A mice,<br />

Cancer Res. 36: 1744-1747.<br />

Subhash, M. N. <strong>and</strong> T. S. Padmashree. 1991. Effect of manganese on biogenic amine metabolism in<br />

regions of the rat brain, Fd. Chem. Toxic. 29579-582.<br />

Suzuki, Y., N. Fujii, H. Yano, T. Ohkita, A. Ichikawa, <strong>and</strong> K. Nishiyama. 1978. Effects of the<br />

lnhalation of manganese dioxide dust on monkey lungs, Tokushima J. Exp. Med. 25: 1 19-125.<br />

Taylor, P. A. <strong>and</strong> J. D. E. Price. 1982. Acute manganese intoxication <strong>and</strong> pancreatitis in a patient<br />

treated with a contaminated dialysate, Can. Med. Assoc. J. 126: 503-505.<br />

Testolin, G., S. Ciappellano, A. Alberio, F. Piccinini, L. Paracchini, <strong>and</strong> A. Jotti. 1993. Intestinal<br />

absorption of manganese: an in vitro study, Ann. Nutr. Metab. 37:289-29<strong>4.</strong><br />

Villalobos, V., F. Castro, E. Bonilla, J. Estdvez, <strong>and</strong> J.O. Ddvila. 199<strong>4.</strong> Manganese toxicity:<br />

muscarinic receptor binding in the mouse braq J. Toxicol. Environ. Health 42: 185-191.<br />

WHO (World Health Organization). 1973. Trace elements in human num.tion: Manganese. Report<br />

of a WHO Expert Committee, Technical Report Service, 532, Who, Geneva, Switzerl<strong>and</strong>.<br />

p. 34-36.<br />

Witschi, H. P., P. J. Hakkinen, <strong>and</strong> J.,P. Kehrer. 1981. Mdication of lung tumor development in<br />

A.J mice, Toxicology. 2 1: 3745.


TOXICITY SUMMARY FOR<br />

METHYLENE CHLORIDE<br />

September 1993<br />

Prepared by<br />

Cheryl B. Bast<br />

Chemical Hazard Evaluation Group<br />

Biomedical Environmental Information Analysis <strong>Section</strong><br />

Health Sciences Research Division<br />

Oak Ridge National Laboratory'<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the US. Department of Energy under<br />

Contract No. DE-AC05-840R21400<br />

1


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2


EXECUTIVESUMMARY<br />

Methylene chloride (CH,Cl,, CAS No. 75-09-2), also known as dichloromethane is a colorless<br />

volatile liquid with a penetrating ether-like odor. In industry, methylene chloride is widely used as a<br />

solvent in paint removers, degreasing agents, <strong>and</strong> aerosol propellants; as a polyurethane foam-blowing<br />

agent; <strong>and</strong> as a process solvent in the pharmaceutical industry. The compound is also used as an<br />

extraction solvent for spice oleoresins, hops, <strong>and</strong> caffeine (ATSDR, 1989; IARC, 1986).<br />

Methylene chloride is readily absorbed from the lungs, the gastrointestinal tract, <strong>and</strong> to some extent<br />

through the skin. Metabolism of methylene chloride produces CO, <strong>and</strong> CO, which readily binds with<br />

blood hemoglobin to form carboxyhemoglobin (CGHb). The primary adverse health effects associated<br />

with methylene chloride exposure are central nervous system (CNS) depression <strong>and</strong> mild liver effects.<br />

Neurological symptoms described in individuals occupationally exposed to methylene chloride included<br />

headaches, dizziness, nausea, memory loss, paresthesia, tingling h<strong>and</strong>s <strong>and</strong> feet, <strong>and</strong> loss of consciousness<br />

(Welch, 1987). Major effects following acute inhalation exposure include fatigue, irritability, analgesia,<br />

narcosis, <strong>and</strong> death (ATSDR, 1989). CNS effects have also been demonstrated in animals following acute<br />

exposure to methylene chloride (Weinstein et al., 1972; Berger <strong>and</strong> Fodor, 1968).<br />

Impaired liver function has been associated with occupational exposure to methylene chloride<br />

(Welch, 1987). Liver effects have also been documented in a number of inhalation studies with laboratory<br />

animals. Subchronic exposure of rats, mice, dogs, <strong>and</strong> monkeys caused mild hepatic effects such as<br />

cytoplasmic vacuolization <strong>and</strong> fatty changes (U.S. EPA, 1983; Haun et al., 1972; Weinstein <strong>and</strong> Diamond,<br />

1972; Heppel, 1944). Hepatocellular foci, fatty changes, <strong>and</strong> necrosis were reported following chronic<br />

inhalation exposure of rats <strong>and</strong> mice (Nitschke et al., 1986~ N", 1986). Chronic oral exposure to<br />

methylene chloride via drinking water resulted in histopathological alterations of the liver in rats <strong>and</strong> mice<br />

(NCA, 1982, 1983). In addition, inhalation exposure of rats caused nonspecific degenerative <strong>and</strong><br />

regenerative changes in the kidneys (U.S. EPA, 1983; Ham et al., 1972).<br />

A subchronic <strong>and</strong> chronic oral reference dose (RfD) of 6E-2 mg/kg/day for methylene chloride has<br />

been calculated by U.S. EPA (1993a,b). This value is based on a NOAEL of 5.85 mg/kg/day derived<br />

from a chronic drinking water study with rats (NCA, 1982). This same study was adapted for the<br />

derivation of the subchronic <strong>and</strong> chronic reference concentration (RfC) of 3E+O mg/m' (NOAEL, 69<strong>4.</strong>8<br />

mg/m3) (U.S. EPA, 1993a).<br />

Studies of workers exposed to methylene chloride have not recorded a significant increase in cancer<br />

cases above the number of cases expected for nonexposed workers (Heame et al., 1987; Ott et al., 1983~<br />

Friedl<strong>and</strong>er et al., 1978). However, long-term inhalation studies with rats <strong>and</strong> mice demonstrated that<br />

methylene chloride causes cancer in laboratory animals. Mice exposed via inhalation to high<br />

concentrations of methylene chloride (2000 or 4000 ppm) exhibited a significant increase of malignant<br />

liver <strong>and</strong> lung tumors compared with nonexposed controls (NTP, 1986). Rats of both sexes exposed to<br />

concentrations of methylene chloride ranging from 500 to 4000 ppm showed increases of benign<br />

mammary tumors (Nitschke et al., 1988~ NTP, 1986; Burek et al., 1984). An inhalation study with rats<br />

<strong>and</strong> hamsters revealed sarcomas of the salivary gl<strong>and</strong> in male rats, but not in female rats or hamsters<br />

(Burek et al., 1984). Liver tumors observed in rats <strong>and</strong> mice that ingested methylene chloride in drinking<br />

water for 2 years provided suggestive evidence of carcinogenicity (NCA, 1982, 1983). Based on<br />

inadequate evidence of carcinogenicity in humans <strong>and</strong> on suficient evidence in animals, U.S. EPA<br />

(1993b) has placed methylene chloride in weight-of-evidence group B2, probable human carcinogen. A<br />

3


slope factor <strong>and</strong> unit risk of 7SE-3 (mg/kg/day)-' <strong>and</strong> 2.1E-7 (pg/L)-', respectively, (U.S. EPA, 1993b)<br />

was derived for oral exposure to methylene chloride. The inhalation unit risk is <strong>4.</strong>7E-7 (pg/m')-' (U.S.<br />

EPA, 1993b).<br />

4


1. INTRODUCTION<br />

Methylene chloride (CH,Cl,, CAS No. 75-09-2), also known as dichloromethane, is a halogenated<br />

aliphatic hydrocarbon with a molecular weight of 8<strong>4.</strong>9<strong>4.</strong> It is a colorless liquid with a penetrating etherlike<br />

odor, a boiling point of 39.7SoC, <strong>and</strong> a density of 1.3348 (2OoC/4OC). It is soluble in about 50 parts<br />

of water <strong>and</strong> is miscible with alcohol <strong>and</strong> ether (Budavari et al., 1989; IARC, 1986). The vapor is not<br />

flammable <strong>and</strong> when mixed with air is not explosive (Budavari et al., 1989); however, methylene chloride<br />

reacts vigorously with some metals. When heated to decomposition, it emits highly toxic fumes of<br />

phosgene (Sax, 1984). Methylene chloride is not known to occur naturally; it is produced by<br />

hydrochlorination of methanol or chlorination of methane or methyl chloride. Methylene chloride is<br />

widely used in a variety of industrial <strong>and</strong> commercial applications. It is used as a solvent in paint<br />

removers, degreasing agents, <strong>and</strong> aerosol propellants; as a polyurethane foam-blowing agent; as a process<br />

solvent in the pharmaceutical industry; <strong>and</strong> as an extraction solvent for spice oleoresins, hops, <strong>and</strong> caffeine<br />

(ATSDR, 1989; IARC, 1986).<br />

Human exposures to methylene chloride am highest in occupational settings <strong>and</strong> near industrialized<br />

urban areas. Consumers may be exposed to significant amounts of methylene chloride vapor in such<br />

products as paint strippers <strong>and</strong> thinners, water repellents, wood stain <strong>and</strong> varnishes, <strong>and</strong> spray paint<br />

(ATSDR, 1989). Most of the methylene chloride released to the environment enters the atmosphere, while<br />

smaller amounts enter surface water <strong>and</strong> ground water. The chlorination of drinking water also produces<br />

methylene chloride. In the atmosphere, reaction with photochemically generated hydroxyl radicals is<br />

expected to be the predominant removal mechanism. Losses of methylene chloride from water are<br />

primarily due to volatilization (U.S. EPA, 1989).<br />

2. METABOLISM AND DISPOSITION<br />

2.1. ABSORPTION<br />

Humans <strong>and</strong> animals readily absorb methylene chloride from the lungs <strong>and</strong> the gastrointestinal tract<br />

into systemic circulation. The compound is also absorbed to some extent through intact skin (ATSDR,<br />

1989; U.S. EPA, 1989). DiVincenzo <strong>and</strong> Kaplan (1981) exposed groups of 4-6 volunteers to 50, 100,<br />

150, or 200 ppm methylene chloride for 7.5 hours. Pulmonary absorption (measured as concentration in<br />

expired air) was rapid during the first hour, then began to decrease as steady-state was approached.<br />

Following cessation of exposure, methylene chloride concentrations in exhaled air dropped rapidly. U.S.<br />

EPA (1980) reported lung absorption efficiencies of 3 1-75%. The absorption of methylene chloride<br />

increased with exposure concentration, length of exposure, <strong>and</strong> activity level. The absorption of methylene<br />

chloride also appears to be related to degree of obesity in humans angstrom <strong>and</strong> Bjurstrom, 1977). When<br />

exposed to 750 ppm for 1 hour, obese subjects absorbed 30% more methylene chloride than lean subjects.<br />

Studies with rats <strong>and</strong> mice showed that methylene chloride is almost completely absorbed from the<br />

gastrointestinal tract of both species following daily gavage treatment with 50 or 200 mg/kg/day (rats) or<br />

50 or 1000 mg/kg/day (mice) for 14 days (Angel0 et al., 1986a,b). The presence of methylene chloride<br />

in various tissues of rats following immersion of the tails indicates that the compound can be absorbed<br />

through the skin (NIOSH, 1976).<br />

5


2.2. DISTRIBUTION<br />

Following absorption, methylene chloride concentrations rapidly increase in the blood to reach<br />

equilibrium levels that depend primarily on exposure concentrations. A fairly uniform distribution to<br />

heart, liver, <strong>and</strong> brain is reported (U.S. EPA, 1980). Biopsy <strong>and</strong> analysis of subcutaneous fat of obese<br />

<strong>and</strong> lean human subjects following exposure to 750 ppm methylene chloride for 1 hour showed a<br />

substantial accumulation in adipose tissue (10.2 <strong>and</strong> 8.4 mg/kg wet tissue, 1 <strong>and</strong> 4 hours postexposure,<br />

respectively). Although the concentrations in fat were slightly lower in the obese, the total amount of<br />

body fat resulted in greater total accumulation of methylene chloride (Engstrom <strong>and</strong> Bjurstrom, 1977).<br />

Methylene chloride crosses the placenta (Anders <strong>and</strong> Sunram, 1982). The compound has been<br />

detected in fetuses of pregnant women who had been chronically exposed to methylene chloride in the<br />

work place. It has also been found in milk of lactating women a few hours into a work shift (U.S. EPA,<br />

1980).<br />

2.3. METABOLISM<br />

Extensive toxicokinetic studies have shown that methylene chloride is metabolized in vivo by two<br />

pathways: (1) a mixed function oxidase (MFO) pathway mediated by the P-450 system yielding CO <strong>and</strong><br />

CO, <strong>and</strong> (2) a glutathiondependent (GST) pathway yielding only CO,. Other metabolites of methylene<br />

chloride include formaldehyde <strong>and</strong> formic acid (ATSDR, 1989). The detection of formic acid in the urine<br />

of workers exposed to methylene chloride has led investigators to suggest that methylene chloride is fmt<br />

metabolized to formaldehyde <strong>and</strong> then to formic acid (Kulova <strong>and</strong> Vlask, 1966). The MFO pathway<br />

is saturable at air concentrations of a few hundred ppm. However, the GST pathway shows no indication<br />

of saturation at inhaled concentrations up to 10,000 ppm (ATSDR, 1989). Biotransformation of methylene<br />

chloride occurs primarily in the liver, but also occurs in the lungs <strong>and</strong> kidneys (NTP, 1986).<br />

Although some CO is exhaled, a significant amount is involved in the formation of<br />

carboxymethemoglobin (CO-Hb). The formation of CGHb leads to interference with normal oxygen<br />

transport capabilities of blood, resulting in oxygen deprivation <strong>and</strong> secondary toxic effects. Bioconversion<br />

of CO <strong>and</strong> formation of CO-Hb continues after exposure (U.S. EPA, 1980).<br />

2.<strong>4.</strong> EXCRETION<br />

Excretion of methylene chloride from the body occurs primarily via expired air from the lungs as<br />

unchanged parent compound or as CO <strong>and</strong> CO,, the primary metabolites. The absorbed dose is a major<br />

determinant of the elimination produm At low exposure concentrations, a large percentage of<br />

administered methylene chloride is metabolized <strong>and</strong> eliminated as CO <strong>and</strong> CO,. At higher concentrations,<br />

more of the unchanged parent compound is exhaled in expired air (ATSDR, 1989). A small fraction of<br />

absorbed methylene chloride is also eliminated in the urine. Methylene chloride <strong>and</strong> formic acid were<br />

detected in the urine of humans exposed by inhalation to 100 or 200 ppm methylene chloride for 24 hours<br />

(DiVincenzo et al., 1972).<br />

6


3. NONCARCINOGENIC HEALTH EFFECTS-<br />

3.1. ORAL EXPOSURES<br />

3.1.1. Acute Toxicity<br />

3.1.1.1. Human<br />

Information on the acute oral toxicity of methylene chloride in humans was not available.<br />

3.1.1.2. Animal<br />

Oral LD,, values for methylene chloride of 2121 mgkg for rats <strong>and</strong> 1987 mgkg for mice indicate<br />

that the two species are similarly susceptible to the lethal effects of methylene chloride (ATSDR, 1989).<br />

3.1.2. Subchronic Toxicity<br />

3.1.2.1. Human<br />

Information on the subchronic oral toxicity of methylene chloride in humans was not available.<br />

3.1.2.1. Animal<br />

No adverse effects on behavior, body weight, survival, or clinical chemistry were observed in male<br />

<strong>and</strong> female Wistar rats exposed to drinking water containing 125 ppm methylene chloride5 for 3 months.<br />

Histopathological examination of internal organs revealed no lesions (Bommann <strong>and</strong> Loeser, 1967).<br />

Minor hematological changes <strong>and</strong> clinical chemistry parameters that reflected impaired liver function were<br />

observed in F344 rats <strong>and</strong> B6C3F, mice exposed to drinking water containing 1500,4500, or 15,000 ppm<br />

methylene chloride for 90 days (Kirschman et al., 1986). A doserelated decrease of urinary pH was seen<br />

in all treated groups of rats <strong>and</strong> increased kidney weights in female rats exposed to the highest dose.<br />

Some mid-dosed female <strong>and</strong> high-dosed male <strong>and</strong> female rats had centrilobular necrosis of the liver. Mild<br />

centrilobular fatty changes of the liver occurred in mice at 24500 ppm.<br />

3.13. Chronic Toxicity<br />

3.13.1. Human<br />

Infomation on the chronic oral toxicity of methylene chloride in humans was not available.<br />

3.13.2. Animal<br />

Drinking water studies conducted by the National Coffee Association (NCA, 1982, 1983; also<br />

reported by Serota et al., 1986qb) exposed F344 rats to 0, 5, 125, or 250 mgkglday <strong>and</strong> B6C3F, mice<br />

to 0, 60, 125, 185, or 250 mg/kg/day of methylene chloride for 104 weeks. Slight effects on<br />

hematological parameters <strong>and</strong> serum chemistry were seen in rats. Treatment-related liver effects, most<br />

prominently increased foci of cellular alterations <strong>and</strong> fatty changes, occurred in rats at all doses except<br />

7


the lowest. In mice, histomorphologic alterations of the liver were observed only in males <strong>and</strong> females<br />

receiving the highest dose.<br />

3.1.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1. Human<br />

Information on the developmental <strong>and</strong> reproductive toxicity of methylene chloride in humans<br />

following oral exposure was not available.<br />

3.1.<strong>4.</strong>2. Animal<br />

Administration of 125 ppm methylene chloride in drinking water for 91 days did not affect the estrus<br />

cycle or reproduction of male <strong>and</strong> female rats (Bornmann <strong>and</strong> Loeser, 1967).<br />

3.1.5. Reference Dose<br />

3.1.5.1. Subchronic<br />

ORAL RfD: 6E-2 mg/kg/day (U.S. EPA, 1993a)<br />

NOAEL: 5.85 mg/kg/day<br />

LOAEL: 52.58 mg/kg/day<br />

UNCERTAINTY FACTOR 100<br />

PRINCIPAL STUDY: NCA, 1982<br />

COMMENTS: The same study applies to the subchronic <strong>and</strong> chronic RfD. The study is<br />

described in <strong>Section</strong> 3.1.3.2.<br />

3.1.5.2. Chronic<br />

ORAL RfD: 6E-2 mg/kg/day (U.S. EPA, 1993b)<br />

NOAEL: 5.85 mg/kg/day<br />

LOAEL: 52.58 mg/kg/day<br />

UNCERTAINTY FACTOR: 100<br />

CONFIDENCE:<br />

Study: High<br />

DataBase: Medium<br />

m: Medium<br />

VERIFICATION DATE: 11/06/85<br />

PRINCIPAL STUDY: NCA, 1982<br />

COMMENTS: The same study applies to the subchronic <strong>and</strong> chronic RfD. The chronic RfD<br />

was based on a no-observed-adverseffect level (NOAEL) of 5.85 mg/kg/day in male rats<br />

derived from the 2-year drinking water study described in <strong>Section</strong> 3.1.3.2. Histopathological<br />

8


lesions of the liver were seen at 52.58 mg/kg/day which was considered h e lowest-observedadverse-effect<br />

level (LOAEL). The uncertainty factor includes two factors of 10 for intra- <strong>and</strong><br />

interspecies variability.<br />

3.2. INHALATION EXPOSURES<br />

3.2.1. Acute Toxicity<br />

3.2.1.1. Human<br />

Humans exposed to high concentrations of methylene chloride for short time periods may experience<br />

central nervous system effects, including narcosis, irritability, analgesia, <strong>and</strong> fatigue (ATSDR, 1989).<br />

Human volunteers exposed by inhalation to methylene chloride concentrations exceeding 300 ppm for 4<br />

hours exhibited decreased auditory <strong>and</strong> visual firnctions; exposure to approximately 800 ppm for 4 hours<br />

resulted in impaired performance of most psychomotor functions (Winneke, 1974). Exposure to 25,000<br />

ppm for 2 hours was not lethal. Exposure to 7,200 ppm caused paresthesia of the extremities after 8<br />

minutes, acceleration of the pulse after 16 minutes, <strong>and</strong> congestion of the head, a sensation of heat, <strong>and</strong><br />

slight irritation of the eyes during the first 20 minutes. At 2300 ppm, nausea occd der a 30-minute<br />

exposure (Sax, 1984). Exposure to very high (unspecified) concentrations of methylene chloride has lead<br />

to rapid unconsciousness <strong>and</strong> death, but prompt removal from exposure usually leads to complete recovery<br />

(Torkelson <strong>and</strong> Rowe, 1981). Accidental deaths have been reported as a result of acute methylene<br />

chloride exposure during paint stripping operations (Stewart <strong>and</strong> Hake, 1976; Bonventre et al., 1977). In<br />

f d poisonings, cardiac injury <strong>and</strong> heart failure have been reported as cause of death (U.S. EPA, 1980).<br />

33.13. Animal<br />

Inhalation LC,, values for methylene chloride listed by ATSDR (1989) range from 14,155 ppm (6-<br />

hour exposure) to 26,710 ppm (20-minute exposure) for mice. The LC,, for guinea pigs exposed for 6<br />

hours is 11,600 ppm. Short-term inhalation studies showed that exposure to high concentrations of<br />

methylene chloride produces central nervous system effects in several species. Slight narcosis was seen<br />

in dogs exposed to 6000 ppm after 2 hours, in guinea pigs after 2.5 hours, <strong>and</strong> in rabbits <strong>and</strong> cats after<br />

3-4 hours (Weinstein et al., 1972); deep narcosis occurred in rats exposed to 16,000-18,000 ppm for 6<br />

hours merger <strong>and</strong> Fodor, 1968).<br />

3.2.2. Subchronic Toxicity<br />

333.1. Human<br />

Unspecified neurological symptoms were reported by a group of 46 male workers who had been<br />

exposed to methylene chloride concentrations ranging from 75 to 100 ppm (duration of exposure not<br />

reported) (Cherry et al., 1980). A follow-up study on 29 of the exposed workers provided no evidence<br />

of neurological or behavioral impairment or cardiac abnormalities. Exposure of 56 workers to a 9:l<br />

methylene ch1oride:methanol atmosphere caused mental <strong>and</strong> physical tiredness <strong>and</strong> sleepiness. These<br />

parameters were significantly different only for the morning shift <strong>and</strong> correlated with blood CO-Hb levels<br />

at the end of the shift (Cherry et al., 1983). Welch (1987) reported that workers from various industries<br />

experienced a variety of CNS effects, such as headaches, dizziness, nausea, memory loss, paresthesia,<br />

tingling h<strong>and</strong>s <strong>and</strong> feet, <strong>and</strong> loss of consciousness. Workers were exposed to methylene chloride levels<br />

measured up to 100 ppm <strong>and</strong> duration of exposure was 6 months to 2 years.<br />

9


Ott et al. (1983a) found no excess mortality from circulatory system diseases among employees of<br />

a fiber production plant that used methylene chloride as a solvent. Workers were exposed for at least<br />

three months to a time-weighted-average concentration of 140 ppm methylene chloride. In a related study<br />

on cardiac function, Ott et al. (1983b) examined EKGs of 50 workers from two fiber-producing plants.<br />

Data from the plant where exposure concentrations ranged from 60-474 ppm (time-weighted-average) were<br />

compared with data from a similar plant not using methylene chloride. No significant changes in<br />

ventricular or supraventricular ectopic activity, nor ST-wave segment depression were associated with<br />

exposure to methylene chloride.<br />

A case of hepatitis was reported in a worker who had used methylene chloride in combination with<br />

other solvents. Although exposure levels were not reported, methylene chloride levels in the serum were<br />

significantly higher than those reported for other solvents. Several workers exposed to solvents in similar<br />

work environments had abnormal liver function tests (Welch, 1987).<br />

3.2.2.2. Animal<br />

In early experiments, Heppel et al. (1944) exposed rats, rabbits, <strong>and</strong> guinea pigs to 5000 ppm<br />

methylene chloride, 7 hodday, 5 daydweek for up to 6 months. Decreased growth in guinea pigs was<br />

the only observed adverse effect. Exposure to 10,000 ppm, 4 hodday, 5 daydweek for up to 8 weeks<br />

caused fatty liver changes in guinea pigs <strong>and</strong> dogs, but no adverse effects in rats <strong>and</strong> rabbits.<br />

A number of subchronic inhalation experiments were initiated due to a concern of potential exposure<br />

of astronauts to methylene chloride vapors emanating from materials used in spacecrafts. A summary of<br />

these studies was presented by U.S. EPA (1983). Mice exposed to 25 or 100 ppm methylene chloride<br />

continuously for 14 weeks had increases in spontaneous motor activity <strong>and</strong> at the lower concentration but<br />

not at the higher concentration. Rats subjected to the same exposure protocol had nonspecific renal<br />

tubular degeneration <strong>and</strong> regeneration <strong>and</strong> hepatic fatty changes <strong>and</strong> cytoplasmic vacuolization at both<br />

exposure levels. Exposure to the same concentrations produced increased carboxymethemoglobin levels<br />

in monkeys at both concentrations <strong>and</strong> in dogs only at 125 ppm. Exposure of the same four species to<br />

1000 or 5000 ppm resulted in signs of severe toxicity at 5000 ppm: narcosis was observed during the first<br />

24 hours <strong>and</strong> pronounced lethargy for the remainder of the exposure period. All rats survived, but high<br />

rates of mortality occurred in mice, dogs, <strong>and</strong> monkeys. Common findings in all species were liver <strong>and</strong><br />

kidney damage.<br />

Exposure of ICR mice to 100 ppm methylene chloride for 10 weeks produced centrilobular hepatic<br />

fat accumulation <strong>and</strong> decreased glycogen levels in mice (Weinstein <strong>and</strong> Diamond, 1972). Cytoplasmic<br />

vacuolization <strong>and</strong> fatty liver changes were also reported in rats <strong>and</strong> dogs exposed to 25-100 ppm<br />

methylene chloride for 100 days. Rats additionally exhibited nonspecific renal tubular degenerative <strong>and</strong><br />

regenerative changes (Haun et al., 1972).<br />

10


3.23. Chronic Toxicity<br />

3.23.1. Human<br />

Epidemiological studies have not shown adverse effects in humans occupationally exposed to<br />

methylene chloride. A study of male workers at Eastman Kodak exposed primarily to methylene chloride<br />

concentrations of 30-120 ppm methylene chloride for up to 30 years did not reveal any indication of<br />

increased risk of death fiom circulatory disease or other causes compared with nonexposed workers or the<br />

general population (Friedl<strong>and</strong>er et al., 1978).<br />

3.23.2. Animal<br />

Nitschke et al. (1988a) exposed male <strong>and</strong> female Sprague-Dawley rats by inhalation to 0, 50,200,<br />

or 500 ppm methylene chloride, 6 hodday, 5 daysfweek for 2 years. An increased incidence of<br />

hepatocellular vacuolization was observed in male <strong>and</strong> female rats exposed to 500 ppm; female rats also<br />

had an increased incidence of multinucleated hepatocytes. In another long-tern bioassay, increased<br />

incidences of hemosiderosis, cytomegaly, cytoplasmic vacuolization, necrosis, granulomatous<br />

inflammation, <strong>and</strong> bileduct fibrosis were observed in the livers of treated male <strong>and</strong> female F344/N rat<br />

<strong>and</strong> B6C3FI mice (NTP, 1986). The exposure concentrations were 1000,2000, or 3000 ppm for rats <strong>and</strong><br />

2000 or 4000 ppm for mice.<br />

3.2.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

3.2.<strong>4.</strong>1. Human<br />

A case-control study on possible causes of spontaneous abortions among 44 women<br />

working in the Finnish pharmaceutical industry showed an increased risk associated with exposure to<br />

several chemicals <strong>and</strong> solvents, including methylene chloride (Taskinen et al., 1986).<br />

3.2.<strong>4.</strong>2. Animal<br />

Nitschke et al. (1988b) evaluated reproductive parameters in F344 rats following exposure to<br />

concentrations of 0, 100, 500, or 1500 ppm methylene chloride over the course of two successive<br />

generations. No adverse effects on fertility, litter size <strong>and</strong> neonatal growth, or survival were noted in<br />

animals exposed to methylene chloride in either the F, or F, generation. Similarly, there were no<br />

treatment-related gross pathologic observations in either the F, or F, adults or the F, or F, weanlings.<br />

In a 2-year NTP (1 986) study, dose-related increases were observed in the incidences of testicular<br />

atrophy in male B6C3FI mice exposed to concentrations of methylene chloride ranging h m 1000 to 4000<br />

ppm, <strong>and</strong> increased incidence of ovarian <strong>and</strong> uterine atrophy was seen in female mice exposed to 2000<br />

or 4000 ppm.<br />

3.2.5. Reference Concentration<br />

33.5.1. Subchronic<br />

INHALATION W: 3E+O mg/m3 (U.S. EPA, 1993a)<br />

NOAEL: 69<strong>4.</strong>8 mg/m3<br />

11


UNCERTAINTY FACTOR: 100<br />

PRINCIPAL STUDY: Nitschke et al., 1988a<br />

COMMENTS: The same study applies to the subchronic <strong>and</strong> chronic RfC. The study is described<br />

in <strong>Section</strong> 3.2.3.2.<br />

3.2.5.2. Chronic<br />

INHALATION RfC: 3E+0 mg/m3 (U.S. EPA, 1993a)<br />

NOAEL: 69<strong>4.</strong>8 mg/m3<br />

UNCERTAINTY FACTOR: 100<br />

PRINCIPAL STUDY: Nitschke et al., 1988a<br />

COMMENTS: A 2-year inhalation study with rats served as the basis for the RfC. The RfC<br />

was based on a NOAEL of 200 ppm (69<strong>4.</strong>8 mg/m3) <strong>and</strong> liver toxicity seen at 500 ppm (1737<br />

mg/m3) as the critical effect. The uncertainty factor includes two factors of 10 for intra- <strong>and</strong><br />

interspecies variability.<br />

33. OTHER ROUTES OF EXPOSURE<br />

33.1. Acute Toxicity<br />

33.1. Humans<br />

Dennatitis has been reported in individuals exposed to methylene chloride while using paint remover<br />

formulations (Torkelson <strong>and</strong> Rowe, 1981).<br />

333. Animals<br />

For mice, the subcutaneous <strong>and</strong> intraperitoneal LD,,, values for methylene chloride are 6452 <strong>and</strong><br />

1987 mgkg, respectively (Kutob <strong>and</strong> Plaa, 1962; Klaassem <strong>and</strong> Plaa, 1966). Repeated dermal contact with<br />

methylene chloride, if allowed to evaporate, is mildly irritating to the skin of rabbits (Torkelson <strong>and</strong> Rowe,<br />

1981).<br />

333. Subchronic Toxicity<br />

Momation on the subchronic toxicity of methylene chloride by other mutes of exposure in humans<br />

or animals was not available.<br />

333. Chronic Toxicity<br />

Information on the chronic toxicity of methylene chloride by other routes of exposure in humans or<br />

animals was not available.<br />

.<br />

12


33.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

Information on the developmental or reproductive toxicity of methylene chloride by other routes of<br />

exposure in humans or animals was not available.<br />

3.<strong>4.</strong> TARGET ORGANS/CFUTICAL EFFECTS<br />

3.<strong>4.</strong>1. Oral Exposures<br />

3.<strong>4.</strong>1.1. Primary Target Organs<br />

Liver: Subchronic <strong>and</strong> chronic exposure of aninals to methylene chloride in drinking water<br />

has produced changes in clinical chemistry parameters suggesting impaired liver function,<br />

centrilobular fatty changes, <strong>and</strong> necrosis.<br />

3.<strong>4.</strong>13. Other Target O&UIS<br />

Kidneys: Increased kidney weights <strong>and</strong> decreased urinary pH suggestive of renal effects were<br />

observed in animals subchronically exposed to methylene chloride in drinking water.<br />

3.43. Inhalation Exposures<br />

3.<strong>4.</strong>2.1. Primary Target Organs<br />

1. Central nervous system: Neurological symptoms including headaches, dizziness, nausea,<br />

memory loss, paresthesia, tingling h<strong>and</strong>s <strong>and</strong> feet, <strong>and</strong> loss of consciousness were reported in<br />

workers subchronically exposed to methylene chloride. Major effects following acute exposure<br />

include fatigue, irritability, analgesia, narcosis, <strong>and</strong> death. CNS effects have also been<br />

demonstrated in animals following acute exposure.<br />

2. Liver: Chronic inhalation exposure of animals has produced hemosiderosis, cytomegaly,<br />

cytoplasmic vacuolization, necrosis, inflammation, <strong>and</strong> bile-duct fibrosis in animals. Fatty liver<br />

changes <strong>and</strong> cytoplasmic vacuolization were reported in subchronic studies. Impaired liver<br />

function has been associated with occupational exposure to methylene chloride.<br />

3. Kidneys: Subchronic inhalation exposure of animals has produced nonspecific renal tubular<br />

degenerative <strong>and</strong> regenerative changes.<br />

3.<strong>4.</strong>2.2. Other Target Organs<br />

Reproduction: An increased risk of spontaneous abortions has been associated with<br />

occupational exposure to various chemicals <strong>and</strong> solvents, including methylene chloride.<br />

Chronic exposure of animals to methylene chloride has resulted in testicular atrophy in males<br />

<strong>and</strong> in uterine <strong>and</strong> ovarian atrophy in females.<br />

3.43. Other Routes of Exposure<br />

Skin: Dermal contact has produced skin irritation.<br />

13


<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1. ORAL EXPOSURES<br />

<strong>4.</strong>1.1. Human<br />

Information on the carcinogenicity of methylene chloride in humans following oral exposure was<br />

not available.<br />

<strong>4.</strong>1.2. Animal<br />

In drinking water studies sponsored by the National Coffee Association (NCA, 1982, 1983), F344<br />

rats were administered 0, 5, 50, 125, or 250 mg/kg/day <strong>and</strong> B6C3F, mice were administered 0, 60, 125,<br />

185, or 250 mg/kg/day of methylene chloride for 104 weeks. A statistically significant (p


Another long-term inhalation study of methylene chloride exposed Sprague-Dawley rats <strong>and</strong> Syrian<br />

Golden hamsters to 0, 500, 1500, or 3500 ppm methylene chloride, 6 hoursjday, 5 daydweek for 2 years<br />

(Burek et al., 1984). Reduced survival was seen in female rats exposed to the highest concentration.<br />

Female rats showed a dose-related statistically nonsignificant increase in the number of benign mammary<br />

tumorsht. A similar response was seen in male rats, but to a lesser degree. Male rats exposed to 3500<br />

ppm also had a statistically significant (p


<strong>4.</strong>5. CARCINOGENICITY SLOPE FACTORS<br />

<strong>4.</strong>5.1. Oral<br />

SLOPE FACTOR: 7.5E-3 (mg/kg/dayy' (U.S. EPA, 1993b)<br />

UNIT RISK 2.1E-7 (&IJ' (US. EPA, 1993b)<br />

PFUNCIPAL STUDY: NTP, 1986; NCA, 1983<br />

COMMENT: The slope factor is an arithmetic mean of slope factors derived from the NTP<br />

(1986) <strong>and</strong> the NCA (1983) data. The use of liver tumor data from the NTP inhalation<br />

bioassay was considered valid since methylene chloride is rapidly absorbed following either<br />

inhalation or ingestion (U.S. EPA, 1993b).<br />

<strong>4.</strong>5.2. Inhalation<br />

UNIT RISK: <strong>4.</strong>E-7 (pg/m')-' (U.S. EPA, 1993b)<br />

PRINCIPAL STUDY: NTP, 1986<br />

VERIFICATION DATE: 04/06/89<br />

COMMENT: The unit risk incorporates information on pharmacokinetics <strong>and</strong> metabolism of<br />

methylene chloride.<br />

16


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Anders, M.W. <strong>and</strong> J. M. Sum. 1982. Transplacental passage of dichloromethane <strong>and</strong> carbon<br />

monoxide. Toxicol. Lett. 12: 23 1-23<strong>4.</strong><br />

Angelo, M.J., A.B. Pritchard, D.R, Hawkins, et al. 1986a. The pharmacokinetics of dichloromethane.<br />

I. Disposition in B6C3F, mice following intravenous <strong>and</strong> oral administration. Food Chem. Toxicol. 24:<br />

965-97<strong>4.</strong><br />

Angelo, M.J., A.B. Pritchard, D.R, Hawkins, et al. 1986b. The pharmacokinetics of dichloromethane.<br />

I. Disposition in Fischer 344 rats following intravenous <strong>and</strong> oral administration. Food Chem. Toxicol.<br />

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Berger, M. <strong>and</strong> G.G. Fodor. 1968. CNA disorders under the influence of air mixtures containing<br />

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Bonventre, J., D. Brennan, D. Juson, et al. 1977. Two deaths following accidental inhalation of<br />

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Drugs, <strong>and</strong> Biologicals, 11th ed. Merck <strong>and</strong> Co., Rahway, NJ, p. 5979.<br />

Burek, J.D., K.D. Nitschke, T.J. Bell, et al. 198<strong>4.</strong> Methylene chloride: A two-year inhalation toxicity<br />

<strong>and</strong> carcinogenicity study in rats <strong>and</strong> hamsters. Fund. Appl. Toxicol. 4: 30-47.<br />

Cherry, N., C.R. Wolf <strong>and</strong> R.M. Philpot. 1981. Some observations on workers exposed to methylene<br />

chloride. Br. J. Ind. Med. 38: 351-355.<br />

Cherry, N., H. Venable <strong>and</strong> H.A. Waldron. 1983. The acute behavioral effects of solvent exposure. J.<br />

SOC. Occup. Med. 33: 13-18. (Cited in ATSDR, 1989)<br />

DiVincenzo, G.D., F.J. Yanno <strong>and</strong> B.D. Astill. 1972. Human <strong>and</strong> canine exposure to methylene chloride<br />

vapor. Am. Ind. Hyg. Assoc. J. 33: 125-135.<br />

DiVincenzo, G.D. <strong>and</strong> C.J. Kaplan. (1981) Uptake, metabolism <strong>and</strong> elimination of methylene chloride<br />

vapor by humans. Toxicol. Appl. Pharmacol. 59: 130-140.<br />

Engstrom, J. <strong>and</strong> R. Bjurstrom. 1977. Exposure to methylene chloride. Content in subcutaneous adipose<br />

tissue. Sc<strong>and</strong>. J. Work Environ. Health 3: 215-22<strong>4.</strong><br />

'<br />

Friedl<strong>and</strong>er, B.R., F.T. Heame <strong>and</strong> S. Hall. 1978. Epidemiologic investigation of employees chronically<br />

exposed to methylene chloride. J. Occup. Med. 20: 657-666. (Cited in IARC, 1986)<br />

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Haun, C.C., E.H. Vernot, K.I. Danner, et al. 1972. Continuous animal exposure to low levels of<br />

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Force Base, Ohio. AMRL-TR-130., Paper No. 12, pp. 199-208. (Cited in U.S. EPA, 1983)<br />

Hearne, F.T., F. Grose, J.W. Pifer, et al. 1987. Methylene chloride mortality study: Dose-response<br />

characterization <strong>and</strong> animal model comparison. J. Occup. Med. 29: 217-228. (Cited in ATSDR, 1989)<br />

Heppel, L., P. Neal, T. Perrin, et al. 194<strong>4.</strong> Toxicology of dichloromethane (methylene chloride). I.<br />

Studies on effects of daily inhalation. J. Ind. Hyg. Toxicol. 26: 8-16. (Cited in NTP, 1986)<br />

IARC (International Agency for Research on Cancer). 1986. Dichloromethane. In: iARC Monographs<br />

on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. Some Halogenated Hydrocarbons<br />

<strong>and</strong> Pesticide Exposures. Vol. 41. World Health Organization, Lyon, France, pp. 43-85.<br />

Kirschman, J.C., N.M. Brown, R.H. Coots <strong>and</strong> K. Morgareigde. 1986. Review of investigations of<br />

dichloromethane metabolism <strong>and</strong> subchronic oral toxicity as the basis for the design of chronic oral studies<br />

in rats <strong>and</strong> mice. Food Chem. Toxicol. 24: 943-949.<br />

Klaassen, C. <strong>and</strong> G. Plaa. 1966. Relative effects of various chlorinated hydrocarbons on kidney <strong>and</strong> liver<br />

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Kutob, S. <strong>and</strong> G. Plaa. 1962. A procedure for estimating the hepatotoxic potential of certain industrial<br />

solvents. Toxicol. Appl. Pharmacol. 4: 34-361.<br />

Kuzelova, M. <strong>and</strong> R. Vlasak. 1966. The effect of methylene dichloride on the health of workers in<br />

production of film foils <strong>and</strong> investigation on formic acid as a methylene dichloride metabolite. Prawvni<br />

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-<br />

NCA (National Coffee Association). 1982. 24-Month Chronic Toxicity <strong>and</strong> Oncogenicity Study of<br />

Methylene Chloride in Rats. Final Report. Prepared by Hdeton Laboratories America, Inc., Vienna,<br />

VA. (Unpublished; cited in U.S. EPA, 1992a)<br />

NCA (National Coffee Association). 1983. 24-Month Chronic Toxicity <strong>and</strong> Oncogenicity Study of<br />

Methylene Chloride in Mice. Final Report. Prepared by Hazleton Laboratories America, Inc., Vienna,<br />

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NIOSH (National Institute of Occupational Safety <strong>and</strong> Health). 1976. Criteria for a Recommended<br />

st<strong>and</strong>ard ... Occupational Exposure to Methylene Chloride. US. DHEW, Cincinnati, OH.<br />

Nitschke, K.D., J.D. Bud, T.J. Bell, et ai. 1988a. Methylene chloride: A 2-year inhalation toxicity <strong>and</strong><br />

oncogenicity study in rats. Fund. Appl. Toxicol. 11: 48-59.<br />

Nitschke, K.D., D.L. Eisenbmndt, L.G. Lomax, et al. 1988b. Methylene chloride: Two-generation<br />

reproductive study in rats. Fund. Appl. Toxicol. 11: 60-67.<br />

NTP (National Toxicology Program). 1986. Toxicology <strong>and</strong> Carcinogenesis Studies of Dichloromethane<br />

(Methylene Chloride) (CAS No. 75-09-2) in F344M Rats <strong>and</strong> B6C3F,<br />

18


Mice (Inhalation Studies). U.S. Department of Health <strong>and</strong> Human Services, Public Health Service,<br />

Research Triangle Park, N.C., NTP TR 306.<br />

Ott, M.G., L.K. Skory, B.B. Holder, et al. 1983a. Health surveillance of employees occupationally<br />

exposed to methylene chloride. I. Mortality. Sc<strong>and</strong>. J. Work Environ. Health 9 (Suppl. 1): 8-16. (Cited<br />

in U.S. EPA, 1989)<br />

Ott, M.G., L.K. Skory, B.B. Holder, et al. 1983b. Health surveillance of employees occupationally<br />

exposed to methylene chloride. Twenty-four hour electrocardiographic monitoring. Sc<strong>and</strong>. J. Work<br />

Environ. Health 9 (Suppl. 1): 26-30. (Cited in U.S. EPA, 1989)<br />

Sax. 198<strong>4.</strong> Methane dichloride. In: Dangerous Properties of Industrial Materials, 6th ed. Van Nostr<strong>and</strong><br />

Reinhold Company, New York, NY, p. 1763.<br />

Smta, D.G., A.K. Thakur, B.M. Ull<strong>and</strong>, et al. 1986a A two-year drinking water study of<br />

dichloromethane in rodents. I. Rats. Food Chem. Toxicol. 24: 951-958.<br />

Serota, D.G., A.K. Thakur, B.M. Ull<strong>and</strong>, et al. 1986b. A two-year drinking water study of<br />

dichloromethane in rodents. I. Mice. Food Chem. Toxicol. 24: 959.<br />

Stewart, R.D. <strong>and</strong> C.L. Hake. 1976. Paint remover h d . J. Med. Assoc. 235: 398401. (Cited in<br />

ATSDR, 1989)<br />

Taskinen, H., M.-L. Lindbohm <strong>and</strong> K. Hemminki. 1986. Spontaneous abortions among women working<br />

in the pharmaceutical industry. Br. J. Ind. Med. 43: 199-205.<br />

Theiss, J.C., G.D. Stoner, M.B. Shimkin <strong>and</strong> E.K. Weisburger. 1977. Test for carcinogenicity of organic<br />

contaminants of United States drinking waters by pulmonary tumor response in strain A mice. Cancer<br />

Res. 37: 2717-2720.<br />

Torkelson, T.R. <strong>and</strong> V.K. Rowe. 198 1. Halogenated aliphatic hydrocarbons. In: Clayton, G.D. <strong>and</strong> F.E.<br />

Clayton, Eds., Patty’s Industrial Hygiene <strong>and</strong> Toxicology, 3rd. ed., Vol. 2B. John Wiley <strong>and</strong> Sons, New<br />

York, NY, pp. 3537-3545.<br />

U.S. EPA (U.S. Environmental Protection Agency). 1980. Ambient Water Quality Criteria for<br />

Halomethanes. Ofice of Water Regulations <strong>and</strong> St<strong>and</strong>ards, Criteria <strong>and</strong> St<strong>and</strong>ards Division, U.S.<br />

Environmental Protection Agency, Washington, DC, EPA 44015-80-05 1.<br />

U.S. EPA (U.S. Environmental Protection Agency). 1983. Reportable Quantity for Dichloromethane.<br />

Prepared by the Ofice of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment<br />

Ofice, Cincinnati, OH, for the Office of Emergency <strong>and</strong> Remedial Response, U.S. Environmental<br />

Protection Agency, Washington, DC.<br />

U.S. EPA (U.S. Environmental Protection Agency). 1985. Addendum to the Health Assessment<br />

Document for Dichloromethane. Updated Carcinogenicity Assessment. Prepared by the Health<br />

Assessment Group, U.S. Environmental Protection Agency, Washington, DC. EPA/600/8-82/004/FF.<br />

19


U.S. EPA. (US. Environmental Protection Agency). 1989. Updated Health-Assessment for Methylene<br />

Chloride. Final Draft. Prepared for the Office of Solid Waste <strong>and</strong> Emergency Response by<br />

Environmental Criteria <strong>and</strong> Assessment Ofice, Office of Health <strong>and</strong> Environmental Assessment, U.S.<br />

Environmental Protection Agency, Cincinnati, OH, ECAO-CIN-H028a.<br />

U.S. EPA (U.S. Environmental Protection Agency). 1993a. Health Assessment Summary Tables. Annual<br />

FY-93. Prepared by the Ofice of Health <strong>and</strong> Environmental Assessment, Environmental Criteria <strong>and</strong><br />

Assessment Ofice, Cincinnati, OH, for the Office of Emergency <strong>and</strong> Remedial Response, Washington,<br />

DC .<br />

U.S. EPA (U.S. Environmental Protection Agency). 1993b. Integrated Risk Information System (IRIS),<br />

Environmental Criteria <strong>and</strong> Assessment Office, Office of Health <strong>and</strong> Environmental Assessment,<br />

Cincinnati, OH.<br />

Weinstein, R.S. <strong>and</strong> S.S. Diamond. 1972. Hepatotoxicity of dichloromethane (methylene chloride) with<br />

continuous inhalation exposure at a low dose level. Proc. 3rd. Ann,. Conf. Env. Toxicol. Aerospace Med.<br />

Res. Lab., Wright-Patterson Air Force Base, Ohio. AMRL-TR-72-130., pp. 209-220. (Cited in ATSDR,<br />

1989)<br />

Weinstein, R.S., D.D. Boyd <strong>and</strong> K.C. Back. 1972. Effects of continuous inhalation of dichloromethane<br />

in the mouse-morphological <strong>and</strong> fimctional observations. Toxicol. Appl. Pharmacol. 23: 660.<br />

Welch, L. 1987. Reports of clinical disease secondary to methylene chloride exposure - a collection of<br />

141 cases. Unpublished study. Submitted to OPTSEPA 3/31. (Cited in ATSDR, 1989)<br />

Winneke, G. 197<strong>4.</strong> Behavioral effects of methylene chloride <strong>and</strong> carbon monoxide as assessed by sensory<br />

<strong>and</strong> psychomotor performance. In: Behavioral Toxicology, C. Xintaras, B.L. Johnson <strong>and</strong> I. de Gmt,<br />

Eds. U.S. Printing Ofke, Washington, DC, pp. 130-14<strong>4.</strong> (Cited in ATSDR, 1989)<br />

20


TOXICITY SUMMARY FOR<br />

NICKEL AND NICKEL COMPOUNDS<br />

July 1995<br />

Prepared by:<br />

Robert A. Young, PbD., D.A.B.T.<br />

Chemical Hazard Evaluation Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health Sciences Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

-<br />

*Managed by Lockheed Martin Energy Systems, Inc., for the US. Department of Energy under<br />

Contract No. DE-AC05-840R2 1400


EXECUTIVE SUMMARY<br />

Nickel is a naturally occurring element that may exist in various mineral forms. It is used in a<br />

wide variety of applications including metallurgical processes <strong>and</strong> electrical components, such as<br />

batteries (ATSDR 1988, USAF 1990). Some evidence suggests that nickel may be an essential trace<br />

element for mammals.<br />

The absorption of nickel is dependent on its physicochemical form, with water soluble forms<br />

being more readily absorbed. The metabolism of nickel involves conversion to various chemical<br />

forms <strong>and</strong> bindmg to various lig<strong>and</strong>s (ATSDR 1988). Nickel is excreted in the urine <strong>and</strong> feces with<br />

relative amounts for each route being dependent on the route of exposure <strong>and</strong> chemical form. Most<br />

nickel enters the body via food <strong>and</strong> water consumption, although inhalation exposure in occupational<br />

settings is a primary route for nickel-induced toxicity.<br />

In large doses (>OS g), some forms of nickel may be acutely toxic to humans when taken orally<br />

(Daldrup et al. 1983, Sunderman et al. 1988). Oral LD,, values for rats range from 67 mg nickelkg<br />

(nickel sulfate hexahydrate) to >9000 mg nickelkg (nickel powder) (ATSDR 1988). Toxic effects<br />

of oral exposure to nickel usually involve the kidneys with some evidence from animal studes<br />

showing a possible developmentalheproductive toxicity effect (ATSDR 1988, Goyer 1991).<br />

Inhalation exposure to some nickel compounds will cause toxic effects in the respiratory tract<br />

<strong>and</strong> immune system (Smialowicz et al. 1984, 1985, 1987; ATSDR 1988; Goyer 1991). Inhalation<br />

LC,, values for anrmals range from 0.97 mg nickeVm3 for rats (6-hour exposure) to 15 mg nickeVm’<br />

for m ea pigs (time not specified) (USAF 1990). Acute inhalation exposure of humans to nickel<br />

may produce headache, nausea, respiratory disorders, <strong>and</strong> death (Goyer 1 99 1, Rendall et al. 1994).<br />

Asthmatic conditions have also been documented for inhalation exposure to nickel (Goyer 1991).<br />

Soluble nickel compounds tend to be more toxic than insoluble compounds (Goyer 1991). In<br />

addition, nickel carbonyl is known to be extremely toxic to humans upon acute inhalation exposure<br />

(Goyer 1991).<br />

Data on nickel-induced reproductive/developmental effects in humans following inhalation<br />

exposure are equivocal. No clinical evidence of developmental or reproductive toxicity were reported<br />

for women workmg in a nickel refinery (Warner et al. 1979), but Chashschin et al. (1994) reported<br />

possible reproductive <strong>and</strong> developmental effects in humans of occupational exposure to nickel<br />

(0.13-0.2 mg nickeVm3). Although not validated by quantitative epidemiologic data or statistical<br />

analyses, the authors reported an apparently abnormal increase in spontaneous <strong>and</strong> threatening<br />

abortions (1617% in nickel-exposed workers vs 8-9% in nonexposed workers), <strong>and</strong> an increased<br />

incidence of non-specified structural malformations (1 7% vs 6%) was reported also. Furthermore,<br />

sensitivity reactions to nickel are well documented <strong>and</strong> usually involve contact dermatitis reactions<br />

resulting from contact with nickel-containing items such as cooking utensils, jewelry, coins, etc.<br />

(ATSDR 1988).<br />

A chronic (EPA 1995) <strong>and</strong> subchronic @PA 1994) oral reference dose (RtD) of 0.02 mg/kg/day<br />

for soluble nickel salts is based on changes in organ <strong>and</strong> body weights of rats receiving dietary nickel<br />

sulfate hexahydrate (5 madday) for 2 years. A no-observed-adverse-effect level (NOAEL) <strong>and</strong><br />

lowest-observed-adverse-effects level (LOAEL)<br />

Ill


of 5 mg/kg/day <strong>and</strong> 50 mg/kg/day, respectively, were reported in the key study<br />

(Ambrose et al. 1976). An uncertainty factor of 300 reflects interspecies extrapolation uncemty,<br />

protection of sensitive populations, <strong>and</strong> a m m g factor of 3 for a database deficient in<br />

reproductivddevelopmental studies.<br />

An inhalation reference concentration (RfC) for soluble nickel salts is under review by the<br />

RfDm Work Group (EPA 1995) <strong>and</strong> currently is not available.<br />

The primary target organs for nickel-induced systemic toxicity are the lungs <strong>and</strong> upper<br />

respiratory tract for inhalation exposure <strong>and</strong> the kidneys for oral exposure (ATSDR 1988,<br />

Goyer 199 1). Other target organs include the cardiovascular system, immune system, <strong>and</strong> the blood.<br />

Epidemiologic studies have shown that occupational inhalation exposure to nickel dust<br />

(primarily nickel subsulfate) at refmeries has resulted in increased incidences of pulmonary <strong>and</strong> nasal<br />

cancer (NAS 1975, Enterline <strong>and</strong> Marsh 1982, ATSDR 1988). Inhalation studies using rats have also<br />

shown nickel subsulfate or nickel carbonyl to be carcinogenic (Sunderman et al. 1959, Sunderman<br />

<strong>and</strong> Donnelly 1965, Ottolenght et al. 1974). Based on these data, the EPA (1995) has classified nickel<br />

subsulfate <strong>and</strong> nickel refinery dust in weight-of-evidence group A, human carcinogen.<br />

Carcinogenicity slope factors of 1.7E-M <strong>and</strong> 8.4E-01 (mg/lcg/day)” <strong>and</strong> unit risks of <strong>4.</strong>8E-04 (pg/m3)-<br />

’ <strong>and</strong> 2.4E-04 (pfl) have been calculated for nickel subsulfide <strong>and</strong> nickel refinery dust,<br />

respectively (EPA 1994, 1995). Based on an increased incidence of pulmonary carcinomas <strong>and</strong><br />

malignant tumors in animals exposed to nickel carbonyl by inhalation or by intravenous injection,<br />

this compound had been placed in weight-of-evidence group B2, probable human carcinogen (EPA<br />

1995). No unit risk values were available for nickel carbonyl. Recent analyses of epidemiologic data,<br />

however, indicate that definitive identification of a specific nickel compound as the causative agent<br />

is not yet possible (Easton et al. 1994, Langhd 1994, Roberts et al. 1994).<br />

iv


1. INTRODUCTION<br />

Nickel is a naturally occurring metal existing in various mineral forms <strong>and</strong> may be found<br />

throughout the environment includmg rivers, lakes, oceans, soil, air, drinking water, plants, <strong>and</strong><br />

animals. Soil <strong>and</strong> sedunent are the primary receptacles for nickel, but mobilization may occur<br />

depending on physico-chemical characteristics of the soil (ATSDR 1988, USAF 1990). Nickel is<br />

used in a wide variety of metallurgical processes such as electroplating <strong>and</strong> alloy production as well<br />

as in nickel-cadmium batteries. Some evidence suggests that nickel may be an essential trace element<br />

for mammals (Coyer 1991). As for most metals, the toxicity of nickel is dependent on the route of<br />

exposure <strong>and</strong> the solubility of the nickel compound (Coogan et al. 1989).<br />

2. METABOLISM AND DISPOSITION<br />

2.1 ABSORPTION<br />

Pulmonary absorption is the major route of concern for nickel-induced toxicity. Nickel may be<br />

absorbed as the soluble nickel ion (Ni”) while sparingly soluble nickel compounds may be<br />

phagocytized. The chemical form <strong>and</strong> its deposition site (determined by size, shape, density, <strong>and</strong><br />

electrical charge of the nickel particles) in the lungs will affect the extent of absorption<br />

(ATSDR 1988). Nickel may be removed fiom portions of the respiratoxy tract via mucociliary<br />

transport resulting in the material entering the gastrointestinal tract. Although nickel is poorly<br />

absorbed from the gastrointestinal tract, dietary exposure <strong>and</strong> exposure via drinking water provide<br />

most of the intake of nickel <strong>and</strong> nickel compounds (Coogan et al. 1989, Goyer 1991). As reviewed<br />

by the EPA (1986), humans <strong>and</strong> animals absorb approximately 1-10% of dietary nickel. Similar<br />

values were reported for drinking water exposure <strong>and</strong> gavage administration (ATSDR 1988). Nickel<br />

metal is poorly absorbed dermally but some nickel compounds such as nickel chloride or nickel<br />

sulfate can penetrate occluded skin resulting in up to 77% absorption within 24 hours (ATSDR<br />

1988).<br />

2.2 DISTRIBUTION<br />

Nickel is readily distributed throughout the body but may be affected by route of exposure, the<br />

chemical form, <strong>and</strong> time &r exposure (Coogan et al. 1989). Although the kidney <strong>and</strong> lungs are the<br />

primaxy sites of accumulation of nickel, other organs such as the spleen, liver, heart <strong>and</strong> testes may<br />

also accumulate the metal to a much lesser extent. Nickel is known to bind to specific proteins <strong>and</strong>or<br />

amino acids in the blood serum <strong>and</strong> the placenta. These lig<strong>and</strong>s are instrumental in the transport <strong>and</strong><br />

distribution of nickel in the body. Nickel distribution may be altered by the formation of lipophilic<br />

nickel complexes.<br />

1


2<br />

2.3 METABOLISM<br />

Nickel is not destroyed in the body, but its chemical form may be altered. The metabolism of<br />

nickel is most appropriately viewed in light of its binding to form lig<strong>and</strong>s <strong>and</strong> its transport throughout<br />

the body. Much of the toxicity of nickel may be associated with its interference with the<br />

physiological processes of manganese, zinc, calcium, <strong>and</strong> magnesium (Coogan et al. 1989). Various<br />

disease states (myocardial infarction <strong>and</strong> acute stroke) <strong>and</strong> injuries (burn injury) are associated with<br />

altered transport <strong>and</strong> serum concentrations of nickel (ATSDR 1988).<br />

2.4 EXCRETION<br />

Nickel is excreted in the urine <strong>and</strong> feces, but because it is poorly absorbed, most ingested nickel<br />

is excreted in the feces. It has been reported that fecal nickel is usually about 100 times that of<br />

urinary nickel <strong>and</strong> represents the removal of unabsorbed nickel (ATSDR 1988, Goyer 1991).<br />

Furthermore, nickel that is absorbed is excreted primarily in the urine (ATSDR 1988). Urinary nickel<br />

levels of 0.4-6.0 pg/L in nonexposed, healthy adults were reported by Sunderman et al. (1986%<br />

1989) while levels as high as 400 pg/L were reported by Sunderman et al. (1986b) for workers<br />

occupationally exposed to nickel <strong>and</strong> nickel compounds.<br />

In a study of nickel-chromium electroplaters, White <strong>and</strong> Boran (1994) noted that urinary nickel<br />

is a valid <strong>and</strong> sensitive (0.6 pg nickem urine) method of monitoring occupational exposure to<br />

soluble nickel salts. Nickel may also be excreted in the hair <strong>and</strong> sweat (ATSDR 1988).<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1 ORAL, EXPOSURES<br />

3.1.1 Acute Toxicity<br />

3.1.1.1 Human<br />

The acute lethality of nickel following oral exposure is dependent upon the chemical form of<br />

nickel. A fatal case of nickel poisoning was reported for a 2 %-year-old girl who had ingested 15 g<br />

of nickel sulfate (Daldrup et al. 1983). The cause of death was cardiac arrest. Death due to nickelinduced<br />

Adult Respiratory Distress Syndrome (ARDS) was reported for a worker spraying nickel<br />

using a thermal arc process (Rendall et al. 1994). Death occurred 13 days following 9O-minute<br />

exposure to an estimated nickel concentration of 382.1 mg/m3; total nickel intake was estimated at<br />

nearly 1 g. Nausea, vomiting, abdomtnal pain, diarrhea, headache, cough, shortness of breath, <strong>and</strong><br />

giddiness were reported for workers of an electroplating plant who drank water contaminated with<br />

nickel chloride <strong>and</strong> nickel sulfate (1.63 g/L) (Sunderman et al. 1988). Signs <strong>and</strong> symptoms of toxicity<br />

lasted for up to 2 days with uneventiid recoveries for all 32 workers. The nickel doses were estimated<br />

to be 0.5 to 2.5 g, serum nickel concentrations were 13 to 1340 pg/L, <strong>and</strong> urinary nickel<br />

concentrations were 0.15 to 12 mg/g creatinine.<br />

Some studies have provided dormation indicating the aggravation of nickel-induced dermatitis<br />

in women following exposure to dietary nickel (ATSDR 1988).


3<br />

3.1.1.2 Animal<br />

Oral LDso values for rats range from 67 mg nickelkg for nickel sulfate hexahydrate to >9000 mg<br />

nickelkg for nickel powder (ATSDR, 1988). Generally, soluble nickel compounds are more toxic<br />

than insoluble compounds. A 2-week exposure of rats to 1000 ppm nickel chloride in the drinktng<br />

water resulted in excessive mortality (RTI 1987).<br />

3.1.2 Subchronic Toxicity<br />

3.1.2.1 Human<br />

No data were available regarding the toxicity of nickel or nickel compounds in humans<br />

following subchronic oral exposure.<br />

3.1.2.2 Animal<br />

With the exception of vomiting during the initial phase of exposure to the highest dose, exposure<br />

of dogs to dietary nickel sulfate hexahydrate (100, 1000, or 2500 ppm) for 2 years failed to produce<br />

significant signs of compound-related toxicity (Ambrose et al. 1976).<br />

A 91-day study using rats given nickel chloride hexahydrate by gavage at doses of 5,35, or 100<br />

mg nickel/kg/day resulted in the death of all rats in the high-dose group by day 78, in an increase in<br />

white blood cell counts for those in the 35 mgkglday group at an interim sacrifice, <strong>and</strong> an elevated<br />

platelet count <strong>and</strong> decreased blood glucose level in the 35 mgkg group at final sacrifice (American<br />

Biogenics Corp. 1986).<br />

Renal tubular degeneration was reported for rats receiving dietary nickel acetate (0.1 to 1.0%)<br />

for several weeks.<br />

3.13 Chronic Toxicity<br />

3.13.1 Human<br />

No studies were available regarding the toxicity of nickel or nickel compounds in humans<br />

following chronic oral exposure.<br />

3.13.2 Animal<br />

No studies were available that examined the chronic oral systemic toxicity of nickel or nickel<br />

compounds in animals.<br />

3.1.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1 Human<br />

No studies were available that addressed the developmentaVreproductive toxicity of orally<br />

administered nickel or nickel compounds.


4<br />

3.1.<strong>4.</strong>2 Animal<br />

Research Triangle Institute (1987) conducted a multigeneration study using rats exposed to<br />

nickel chloride in the drinking water at nickel concentrations of 50,250, or 500 ppm (equivalent to<br />

7.3,30.8, or 51.6 mg nickel/kg/day). The highest exposure produced maternal toxicity characterized<br />

by a decrease in body weight <strong>and</strong> decreased absolute <strong>and</strong> relative liver weights of the dams. A<br />

decrease in the number of live pups per litter, an increase in pup mortality, <strong>and</strong> a decrease in the<br />

average body weight of the pups was noted for the F1, <strong>and</strong> Flb generations of the 500 ppm test group.<br />

Following statistical analyses, both the 50 <strong>and</strong> 250 ppm exposures were considered to be a noobserved-adverse-effect<br />

level (NOAEL).<br />

3.15 Reference Dose<br />

3.15.1 Subchronic<br />

ORAL RfD,: 2E-2 mg/kg/day (soluble nickel salts) (EPA 1994)<br />

UNCERTAINTY FACTOR: 300<br />

NOAEL: 100 ppm (5 mg/kg/day)<br />

3.15.2 Chronic<br />

ORAL RfDc: 2E-2 mg/kg/day (soluble nickel salts) (EPA 1995)<br />

UNCERTAINTY FACTOR 100<br />

MODIFYING FACTOR: 3<br />

NOAEL: 100 ppm (5 mg/kg/day)<br />

LOAEL: 1000 ppm (50 mgkglday)<br />

CONFIDENCE:<br />

study: Low<br />

Data base: Medium<br />

VERIFICATION DATE: 07/16/87<br />

PRINCIPAL STUDY: Arnbrose et al. 1976<br />

COMMENTS: The IUD is based on decreased organ <strong>and</strong> body weights of rats receiving<br />

dietary nickel sulfate hexahydrate (100 ppm equivalent to a dose of 5 mg/kg/day) for 2 years.<br />

An uncertainty factor of 100 reflects interspecies extrapolation <strong>and</strong> protection of sensitive<br />

populations. A moddjmg factor of three was applied to 8ccount for the absence of definitive<br />

reproductivddwelopmental studies.


5<br />

3.2 INHALATION EXPOSURES<br />

3.2.1 Acute Toxicity<br />

3.2.1.1 Human<br />

Acute inhalation exposure to nickel carbonyl results in initial headache, nausea, vomiting, <strong>and</strong><br />

chest pain, progressing to hyperpnea, cyanosis, respiratory failure, <strong>and</strong> death if the exposure is severe<br />

(Goyer 1991). A lowest toxic concentration (TC,) of 7 mg/m’ for nickel carbonyl has been reported<br />

(Sax <strong>and</strong> Lewis 1989).<br />

Asthmatic disease resulting fiom inhalation exposure to nickel <strong>and</strong> nickel compounds has been<br />

reported for nickel-plating workers <strong>and</strong> stainless steel welders (ATSDR 1988). Nicklin <strong>and</strong> Nielsen<br />

(1994) categorized these responses as (1) a rapid onset attack (antibody-mediated Type I<br />

hypersensitivity) associated with acute bronchospasm, (2) a late response reaction at 6-1 2 hours after<br />

exposure (antigen-antibody immune complex-mediated lnnammatory reaction), <strong>and</strong> 3) a mixed or<br />

combined response.<br />

3.2.1.2 Animal<br />

Acute halation toxicity studies in d s have provided LC, values ranging from 0.97 mg/m’<br />

for 6-hour exposure of rats to nickel subsulfate to 15 mg/m’ (time not specified) for guinea pigs<br />

exposed to nickel dust (USAF 1990). Acute toxic effects wil be dependent upon the chemical form,<br />

exposure concentration, <strong>and</strong> exposure duration.<br />

Several studies summarized in ATSDR (1988) indicated that 2-hour exposure of mice to nickel<br />

chloride at concentrations of 0.25 to 0.50 mg nickeYm’ caused a suppression of immune responses.<br />

3.2.2 Subchronic Toxicity<br />

3.2.2.1 Human<br />

In an evaluation of workers welding hgh-nickel alloys, it was reported that 6-week exposure<br />

to nickel fumes (0.07 to 1.1 mg nickel/m’) caused an increase in airway <strong>and</strong> eye irritations,<br />

headaches, <strong>and</strong> tiredness (Akesson <strong>and</strong> Skervfkg 1985).<br />

3.2.2.2 Animal<br />

A number of studies have examined the toxic effects of short-term exposure of animals to<br />

various chemical forms of nickel (ATSDR 1988). Exposure of rats <strong>and</strong> mice to aerosols of nickel<br />

sulfate hexahydrate (0.7 to 13.5 mg nickel/m’) for 12 days resulted in pulmonary inflammation,<br />

degenerative changes in the bronchiolar mucosa, <strong>and</strong> atrophy of the olfactory epithelium<br />

(Benson et al. 1988). Another study using the same protocol <strong>and</strong> nickel subsulfate (0.4,0.9, 1.8,2.7,<br />

3.7, or 7.3 mg nickel/m3) showed that exposure to L 5 mg Ni,S, (3.7 mg dckeVm) caused<br />

necrotizing pneumonia, emphysema, <strong>and</strong> fibrosis in both rats <strong>and</strong> mice (Benson et al. 1987).<br />

Degeneration of the olfactory epithelium was reported for the rats <strong>and</strong> mice exposed to<br />

concentrations L 1.2 mg/m3 (0.9 mg nickel/&). Inhalation exposure of rats to nickel chloride (0.109<br />

mg nickeYm’) produced hyperplastic changes in the bronchial epithelium <strong>and</strong> increased mucus<br />

secretion (Bingham et al. 1972). Similar effects have been observed for rabbits inhahng nickel dust<br />

for 3-8 months (Curstedt et al. 1983,1984; Johansson et al. 1983).


6<br />

A 13-week inhalation study conducted by the Inhalation Toxiwlogy Research Institute<br />

compared the effects of exposure of rats <strong>and</strong> mice to nickel sulfate hexahydrate, nickel subsulfate,<br />

<strong>and</strong> nickel oxide at occupationally relevant exposure concentrations. Severity of inflammation <strong>and</strong><br />

fibrosis of the lungs <strong>and</strong> alveolar macrophage hyperplasia corresponded to the water solubility of the<br />

nickel compounds with nickel sulfate being the most toxic, followed by nickel subsulfate <strong>and</strong> nickel<br />

oxide (Dunnick et al. 1989). Biochemical indexes of pulmonary toxicity (lactate dehydrogenase <strong>and</strong><br />

beta-glucuronidase activity; total protein levels) indicated the order of toxicity to be NiSO, > Ni, S,<br />

> NiO (Benson et al. 1989). Varying degrees of immunological effects in mice were also noted for<br />

these three compounds, with effects depending on dose <strong>and</strong> physicochemical form (Haley et al.<br />

1990). The investigators concluded that inhalation of these nickel compounds at occupationally<br />

relevant concentrations can result in signtficant alterations of pulmonary <strong>and</strong> systemic immune<br />

defenses.<br />

The immunotoxic effects of nickel compounds have been affumed by other investigators. Haley<br />

et al. (1990) reported immunotoxic effects in mice following 13-week exposures to various nickel<br />

compounds. Nickel subsulfide (1.8 mg nickellm’) decreased activity levels of natural killer cells<br />

while both nickel oxide (0.47, 2.0, <strong>and</strong> 7.9 mg nickellm’) <strong>and</strong> nickel subsulfate (0.45 <strong>and</strong> 1.8 mg<br />

nickeYm3) inhibited phag-c ability of alveolar macrophages. In studies with mice <strong>and</strong> rats,<br />

!bialowicz et al. (1984, 1985, 1987) found that nickel chloride affected T-cell-mediated immune<br />

responses (but not humoral immune responses) <strong>and</strong> that natural killer cells were target cells of the<br />

immunotoxic effects of nickel.<br />

3.23 Chronic Toxicity<br />

3.23.1 Human<br />

Most chronic inhalation exposures involve occupational exposure to nickel dust or nickel vapors<br />

resulting from welding nickel alloys. Generally, chronic inhalation exposure to nickel dusts <strong>and</strong><br />

aerosols contribute to respiratory disorders such as asthma, bronchitis, rhinitis, sinusitis, <strong>and</strong><br />

pneumoconiosis (USAF 1990). Chronic exposure to nickel <strong>and</strong> nickel compounds have been<br />

implicated in carcinogenic responses as discussed in Sect. <strong>4.</strong>2.<br />

3.23.2 Animal<br />

A 31-month exposure of rats to nickel oxide (0.06 or 0.20 mg nickellm’) resulted in the<br />

development of focal septal fibrosis <strong>and</strong> histological changes indicative of alveolar proteinosis<br />

(Takenaka et al. 1985). A lifetime exposure of rats to nickel oxide (42 mg nickellm3) produced<br />

emphysema <strong>and</strong> other proliferative <strong>and</strong> inflammatory changes (Wehner et al. 1975).<br />

3.2.4 Developmental <strong>and</strong> Reproductive Toxicity<br />

3.2.<strong>4.</strong>1 Human<br />

No clinical evidence of developmental or reproductive toxicity were reported for women<br />

working in a nickel refinery (Warner et al. 1979). More recently, however, Chashschin et al. (1994)<br />

reported on possible reproductive <strong>and</strong> developmental effects in humans of occupational exposure to<br />

nickel (0.13-0.2 mg nickel/m3). Although not validated by quantitative epidemiologic data or<br />

statistical analyses, the authors reported an apparedy abnormal increase in spontaneous <strong>and</strong><br />

threatening abortions (1617% in nickelexposed workers versus 8-9% in nonexposed workers) <strong>and</strong><br />

an increased incidence of nonspecified structural malformations ( 17% vs 6%) was also reported.


7<br />

3.2.<strong>4.</strong>2 Animal<br />

A reduction in fetal body weight was observed for pregnant rats exposed to nickel oxide (1.3 or<br />

2.5 mg/m’) throughout gestation (Weischer et al. 1980). The number of fetuses per litter was<br />

unaffected. Benson et al. (1988) reported degeneration of the germinal epithelium of testes in rats<br />

exposed to nickel sulfate at concentrations 2 7 mg/m’ (2 1.6 mg nickel/& ) for 12 days. Similar<br />

effects were observed for mice <strong>and</strong> rats exposed to nickel subsulfate at concentrations of 2 2.5 mg/m’<br />

(2 1.8 mg nickel/m3) (Benson et al. 1987).<br />

3.2.5 Reference Concentration<br />

Subchronic <strong>and</strong> chronic &alation RfCs for soluble nickel salts are currently under review by<br />

the R€DmWork Group @PA 1995).<br />

3.3 OTHER ROUTES OF EXPOSURE<br />

3.3.1 Acute Toxicity<br />

3.3.1.1 Human<br />

Nickel-induced contact dermatitis is well documented for humans <strong>and</strong> is the most prevalent<br />

effects of nickel in humans (ATSDR 1988). Both occupational <strong>and</strong> nonoccupational exposures are<br />

common, the latter involving commodities such as eating utensils, coins, jewelry, <strong>and</strong> tools. Data<br />

indicate women to be at greater risk for dermatitis of the h<strong>and</strong>s, possibly due to more fiequent contact<br />

with nickel-containing items. No dose-response data are available for nickel sensitivity reactions.<br />

3.3.1.2 Animal<br />

Nickel sensitivity has not been adequately demonstrated in animals (ATSDR 1988), <strong>and</strong> no<br />

mformation was available regardmg other acute effects following dermal exposure to nickel or nickel<br />

compounds.<br />

3.3.2 Subchronic Toxicity<br />

No information was available on the subchronic toxicity of nickel or nickel compounds in<br />

humans or animals by other routes of exposure.<br />

333 Chronic Toxicity<br />

No information was available on the chronic toxicity of nickel or nickel compounds in humans<br />

or animals by other routes of exposure.


8<br />

3.3.4 Developmental Toxicity<br />

No definitive information was available. Mathur et al. (1 977) reported that application of nickel<br />

sulfate hexahydrate (60 or 100 mgkglday for 30 days) to the shaved backs of rats resulted in tubular<br />

damage of the testes <strong>and</strong> sperm degeneration. However, the effects may have been due to ingestion<br />

of the compound during grooming.<br />

3.4 TARGET ORGANS/CRITICAL EFFECI'S<br />

3.<strong>4.</strong>1 Oral Exposures<br />

3.<strong>4.</strong>1.1 Primary target(s)<br />

1. Kidney: Although not documented for humans, parenteral administration studies in animals<br />

have venfied the nephrotoxicity of nickel <strong>and</strong> nickel compounds (ATSDR 1988, USAF<br />

1990).<br />

2. Blood: Alterations in whte blood cell counts of mice <strong>and</strong> decreased hematocrit in rats have<br />

been reported following gavage administration of nickel chloride (USAF 1990).<br />

3.<strong>4.</strong>1.2 Other target@)<br />

1. Skin: Some studies are available documenting the aggravation of nickel-induced dermatitis<br />

in women following exposure to dietary nickel.<br />

2. Cardiovascular system: Anecdotal information suggested that very high (15 g) acute doses<br />

of nickel sulfate may cause cardiac arrest.<br />

3.<strong>4.</strong>2 Inhalation Exposures<br />

3.<strong>4.</strong>2.1 Primary target@)<br />

1. Respiratory tract: Inhalation of nickel or nickel compounds may cause respiratory conditions<br />

such as asthma, bronchitis, rhinitis, sinusitis, <strong>and</strong> pneumocOniosis. Inhalation of nickel<br />

carbonyl may be fatal. The nature <strong>and</strong> severity of the adverse effects may vary depending<br />

on the specific nickel compound <strong>and</strong> the duration of exposure.<br />

2. Immune system: Exposure of mice to nickel subsulfide decreased activity levels of natural<br />

killer cells, <strong>and</strong> both nickel oxide (0.47-7.9 mg nickeVm3) <strong>and</strong> nickel subsulfide (0.45-1.8<br />

mg nickel/m3) inhibited phagocytic ability of alveolar macrophages. Exposure of rats <strong>and</strong><br />

mice to nickel chloride inhibited T-cell-mdated immune responses.<br />

3.<strong>4.</strong>2.2 Other target@)<br />

1. Testes: Degeneration of the germinal epithelium of the testes was observed in rats exposed<br />

to nickel sulfate at concentrations -2 7 mg/m3 (2 1.6 mg nickel/m3) for 12 days.


9<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1 ORAL EXPOSURES<br />

<strong>4.</strong>1.1 Human<br />

No information was available on the carcinogenicity of nickel or nickel compounds in humans<br />

following oral exposure.<br />

<strong>4.</strong>1.2 Animal<br />

Although several studes have been conducted assessing the carcinogenic potential of nickel<br />

compounds following oral exposure, the studies suffered from inadequate design (ATSDR 1988).<br />

t<br />

<strong>4.</strong>2 INHALATION EXPOSURE<br />

<strong>4.</strong>2.1 Human<br />

Several epidemiologic studies have investigated the potential carcinogenicity of inhaled nickel<br />

<strong>and</strong> nickel compounds (ATSDR 1988). Based on analyses of studies completed prior to 1975, the<br />

National Academy of Sciences (NAS 1975) concluded that nickel refinery workers demonstrated an<br />

increase in the incidence of pulmonary <strong>and</strong> nasal cavity cancers, specifically epidermoid, anaplastic,<br />

<strong>and</strong> pleomorphic cancers. Enterline <strong>and</strong> Marsh (1982) showed that there was an excess risk of nasal<br />

sinus cancer in nickel refi.neT workers. The st<strong>and</strong>ardized mortality ratio (SMR) was 2443.<br />

Doll et al. (1977) also reported an excess of lung <strong>and</strong> nasal cancer among nickel refinery<br />

workers. The incidence was virtually eliminated after the implementation of respirators.<br />

Magnus et al. (1980) studied workers fiom several job categories in a nickel refinery <strong>and</strong> found<br />

an increase in the risk of nasal cancer in all jobs, with the highest risk being in roastinghmelting jobs<br />

<strong>and</strong> for electrolysis workers. The authors also reported that smoking <strong>and</strong> nickel exposure appeared<br />

to be additive in their carcinogenic potential.<br />

For epidemiologic studies on stainless steel welders, Langbd (1994) noted that it was not<br />

possible to determine whether exposure to nickel or chromium VI was a greater factor in the reported<br />

increased cancer incidences for this occupational group. Additionally, Easton et al. (1994) noted that<br />

currently available data <strong>and</strong> analyses would not allow for a valid association of a specific nickel<br />

compound with the observed cancer incidences. In the absence of more definitive data, it is assumed<br />

that exposure to any nickel compound with a particle size small enough to reach nasal <strong>and</strong> bronchial<br />

tissue may constitute a respiratory cancer hazard.<br />

Although data are not available to positively identtfy which nickel compounds are responsible<br />

for inducing carcinogenic responses in humans, recent analyses have indicated nickel oxide,<br />

subsulfate, <strong>and</strong> soluble nickel to be likely c<strong>and</strong>idates (Roberts et al. 1994).


10<br />

<strong>4.</strong>2.2 Animal<br />

In an inhalation study by Ottolenghl et al. (1974), rats of both sexes were exposed to nickel<br />

subsulfate (0.97 mg nickevm’) for 78 to 84 weeks followed by a 30-week observation period.<br />

Relative to controls, there was an increase in the incidence of adenomas <strong>and</strong> adenocarcinomas in the<br />

nickel-exposed rats.<br />

Sunderman et al. (1 959) showed that repeated inhalation exposures of rats to nickel carbonyl<br />

(0.03 or 0.06 mgL) over a l-year period resulted in an increased incidence of tumors relative to<br />

controls. Lifetime inhalation exposure of rats to nickel carbonyl vapor (0.6 mgL for 30 minutes or<br />

0.03 mg/L, three timedweek) resulted in pulmonary carcinomas <strong>and</strong> metastases (Sunderman <strong>and</strong><br />

Donnelly 1965). Lau et al. (1972) induced malignant tumors at various sites in rats injected with<br />

nickel carbonyl.<br />

<strong>4.</strong>3 OTHER ROUTES OF EXPOSURE<br />

No information was available on the carcinogenicity of nickel or nickel compounds in animals<br />

by other routes of exposure.<br />

<strong>4.</strong>4 EPA WEIGHT-OF-EVIDENCE CLASSIFICATION<br />

Nickel subsulfide:<br />

Classification-A, Human carcinogen @PA 1995)<br />

Basis-Increased risks of lung <strong>and</strong> nasal cancer in humans exposed to nickel refinery dust, most<br />

of which is believed to be nickel subsulfate; increased tumor incidences in several species <strong>and</strong><br />

strains of animal for multiple routes of administration; positive results in genotoxicity assays.<br />

Nickel refinery dust:<br />

Classification-A, Human carcinogen (EPA 1995)<br />

Basis-Epidemiologic studies in several Merent countries showed nickel refinery dust to cause<br />

lung <strong>and</strong> nasal tumors in nickel sulfide matte refinery workers; animal data showed an increased<br />

incidence of carcinomas in rats following adminrstration via dation or injection.<br />

Nickel carbonyl:<br />

Classification-B2, Probable human carcinogen @PA 1995)<br />

Basis-Observation of pulmonary carcinomas <strong>and</strong> malignant tumors at various sites in rats<br />

administered nickel carbonyl by inhalation <strong>and</strong> intravenous injection, respectively; nickel<br />

administered as nickel carbonyl binds to DNA.<br />

The EPA has not evaluated soluble nickel salts for potential human carcinogenicity.


11<br />

<strong>4.</strong>5 CARCINOGENICITY SLOPE FACTOR<br />

<strong>4.</strong>5.1 Oral<br />

No slope factors for carcinogenicity of nickel <strong>and</strong> nickel compounds through ingestion have<br />

been calculated.<br />

<strong>4.</strong>5.2 Inhalation<br />

SLOPE FACTORS: 8.4E-01 (mg/kg/day)-' (nickel refinery dust) (EPA 1994)<br />

1.7Ei-O (mg/kg/day)-' (nickel subsulfide) (EPA 1994)<br />

No slope factors have been calculated for other nickel compounds.<br />

PRINCIPAL STUDY: Data sets from several occupational exposure stucjles were used <strong>and</strong> are<br />

described in EPA (1986).<br />

, VERIFICATION DATE: 04/01/87<br />

UNIT RISKS: <strong>4.</strong>8E-4 (pg/m3)-' (nickel subsulfide) (EPA 1995)<br />

2.4E-4 (pg/m3)-' (nickel refinery dust) (EPA 1995)<br />

Nickel refinery dust is a mixture of many nickel moieties, <strong>and</strong> the identity of the specific<br />

carcinogenic nickel species is not known.<br />

5. REFERENCES<br />

Akesson, B. <strong>and</strong> S. Skervfing. 1985. Exposure in welding of high nickel alloy, Int. Arch. Occup.<br />

Environ. Health 56: 11 1-1 17.<br />

Ambrose, A. M., P. S. Larson, J. R Borzelleca <strong>and</strong> G. R Hennigar, Jr. 1976. Long term toxicologic<br />

assessment ofnickel in rats <strong>and</strong> dogs,J. Food. Sci. Technol. 13: 181-187.<br />

American Biogenics Corp. 1986. Ninety day gavage study in albino rats using nickel, Final Drafi<br />

report to Research Triangle Inst. (Cited in ATSDR 1988).<br />

ATSDR (Agency for Toxic Substances <strong>and</strong> Disease Regisby). 1988. Toxicologcal Profile for Nickel,<br />

ATSDR/U.S. Public Health Service, ATSDR/TP-88/19.<br />

Benson, J. M., R L. Carpenter, F. F. Hahn, et al. 1987. Comparative inhalation toxicity of nickel<br />

subsulfate to F344M rats <strong>and</strong> B6C3FI mice exposed for twelve days, Fund. Appl. Toxicol. 9:<br />

25 1-265.<br />

Benson, J. N., D. G. Burt, R L. Carpenter, et al. 1988. Comparative inhalation toxicity of nickel<br />

sulfate to F344M rats <strong>and</strong> B6C3F, mice exposed for twelve days, Fund. Appl. Toxicol. 10:<br />

164-178.


12<br />

Benson, J. M., D. G. Burt, Y.<strong>4.</strong> Yung, et al. 1989. Biochemical responses of rat <strong>and</strong> mouse lung to<br />

inhaled nickel compounds, Toxicology 57: 255-266.<br />

Bingham, E., W. Barkley, M. Zerwas, K. Sterner, <strong>and</strong> P. Taylor. 1972. Responses of alveolar<br />

macrophages to metals. I. Inhalation of lead <strong>and</strong> nickel, Arch. Environ. Health 25: 406-41<strong>4.</strong><br />

Chashschm, V. P., P. A. Arhmna, <strong>and</strong> T. Norseth. 199<strong>4.</strong> Congenital defects, abortion <strong>and</strong> other<br />

health effects in nickel refinery workers, Science Total Environ. 148: 287-29 1.<br />

Coogan, T. P., D. M. Latta, E. T. Snow, <strong>and</strong> M. Costa. 1989. Toxicity <strong>and</strong> carcinogenicity of nickel<br />

compounds, In: Critical Reviews in Toxicology, Vol 19. McClellan, RO., ed., CRC Press, Boca<br />

Raton, FL. pp. 341-38<strong>4.</strong><br />

Curstedt, T., M. Hafinan, B. Robertson, <strong>and</strong> P. Camner. 1983. Rabbit lungs after exposure to low<br />

nickel dust combustion. I. Effects on phospholipid concentration <strong>and</strong> surfactant activity,<br />

Environ. Res. 30: 89-9<strong>4.</strong><br />

Curstedt, T., M. Casarett-Bruce, <strong>and</strong> P. Camner. 198<strong>4.</strong> Changes in glycerophosphatides <strong>and</strong> their<br />

ether analogs in lung lavage of rabbits exposed to nickel dust, Exp. Mol. Pathol. 4 1 : 226-23<strong>4.</strong><br />

Daldrup, T., K. Haarhoff <strong>and</strong> S. C. Szathmary. 1983. Toedliche nickel sulfate-intoxikation, Benchte<br />

zur Gerichtlichen Medizin 41:141-14<strong>4.</strong> (Cited in ATSDR 1988)<br />

Dunnick, J. K., M. R Elwell, J. M. Benson, et al. 1989. Lung toxicity after 13-week inhalation<br />

exposure to nickel oxide, nickel subsulfate, or nickel sulfate hexahydrate in F344M rats <strong>and</strong><br />

B6C3F, mice, Fundam. Appl. Toxicol. 12: 584-59<strong>4.</strong><br />

Easton, D. F., J. Peto, L. G. Morgan, et al. 199<strong>4.</strong> Respiratory cancer mortality in Welsh nickel<br />

refiners: which nickel compounds are responsible, In: Nickel <strong>and</strong> Human Health, Nieboer, E.<br />

<strong>and</strong> J.O. Nriagu, eds., John Wiley <strong>and</strong> Sons, Inc., New York, NY. pp. 603-619.<br />

Enterline, P. E. <strong>and</strong> G. M. Marsh. 1982. Mortality among workers in a nickel refinery <strong>and</strong> alloy plant<br />

in West VirginiqJ. Natl. CancerInst. 68: 925-933.<br />

EPA. 1986. Health Assessment Document for Nickel <strong>and</strong> Nickel Compounds, Office of Health <strong>and</strong><br />

Environmental Assessment, Environmental Criteria <strong>and</strong> Assessment Office, Research Triangle<br />

Park, NC. EPA-600/8-83-012F. NTIS PB 86-232212.<br />

EPA. 199<strong>4.</strong> Health Effects Summary Tables, FY-1994 Annual, Office of Research <strong>and</strong> Development,<br />

Office of Emergency <strong>and</strong> Remdal Response, Washington,D.C. NTIS PB94-921199.<br />

EPA. 1995. Nickel. Integrated Risk Wonnation System (IRIS), Environmental Criteria <strong>and</strong><br />

Assessment Office,Office of Health <strong>and</strong> Environmental Assessment, Cincinnati, OH.<br />

Guyer. R 1991. Toxic effects of metals, In: Casarert <strong>and</strong> Douli's Toxicoiogy, 4th<strong>4.</strong> Amdur, M.O.,<br />

J.D. hull <strong>and</strong> C.D. Klaassen, eds., Pergamon Press, New York. pp.623-680.<br />

Haley, P. J., Shopp, G. M., J. M. Benson et al. 1990. The immunotoxicity of three nickel compounds<br />

following 13-week inhalation exposure in the mouse, Fundam. Appi. Toxicol. 15: 476487.<br />

Langhd, S. 199<strong>4.</strong> Nickel-related cancer in welders, Science of the Total Environ. 148: 303-309.


13<br />

Lau, T. J., R. L. Hackett, <strong>and</strong> F. W. Sunderman. 1972. The carcinogenhty of intravenous nickel<br />

carbonyl in rats, Cancer Res. 32: 2253.<br />

Magnus, K. A. Anderen, <strong>and</strong> A. C. Hogetveit. 1980. Cancer of respiratory organs among workers at<br />

a nickel refmery in Norway, Int. J. Cancer 30: 681-685.<br />

Mathur, A. K., T. S. S. Dikshith, M. M. Llal, <strong>and</strong> S. K. T<strong>and</strong>on. 1978. Distribution of nickel <strong>and</strong><br />

cytogenetic changes in poisoned rats, Toxicology 10: 105-1 13. (Cited in ATSDR 1988)<br />

Nicklin, S. <strong>and</strong> G. D. Nielsen. 199<strong>4.</strong> Nickel <strong>and</strong> the irnmune system: current concepts, In: Nickel <strong>and</strong><br />

Human Health, Nieboer, E. <strong>and</strong> J.O. Nriagu, eds., John Wiley <strong>and</strong> Sons, Inc., New York, NY.<br />

pp. 239-259.<br />

Ottolenghl, A. D., J. K. Haseman, W. W. Payne, H. L. Falk, <strong>and</strong> H. N. MacFarhad. 197<strong>4.</strong> Inhalation<br />

studies of nickel sulfide in pulmonary carcinogenesis of rats, J. Natl. Cancer Inst. 54:<br />

1 165- 1 172.<br />

Rendall, R E. G., J. I. Phillips, <strong>and</strong> K. A. Renton. 199<strong>4.</strong> Death following exposure to fine particulate<br />

nickel fiom a metal arc process, Ann. Occup. HE. 38: 92 1-930.<br />

Roberts, R. S., J. A. Julian, N. Jadon, <strong>and</strong> D. C. F. Muir. 199<strong>4.</strong> Cancer mortality in Ontario nickel<br />

workers: 1950-198<strong>4.</strong> In: Nickel <strong>and</strong> Human Health, Nieboer, E. <strong>and</strong> J.O. Nriagu, e&., John<br />

Wiley <strong>and</strong> Sons, Inc., New York, NY. pp. 629-648.<br />

RTI (Research Triangle Institute). 1987. Two generation reproduction <strong>and</strong>fertifity study of nickef<br />

chloride administered to CD ruts in drinking water, report submitted to Office of Solid Waste,<br />

EPA, Washington, DC.<br />

Sax, N.I. <strong>and</strong> RJ. Lewis, Jr., eds. 1989. Dangerous Properties ofIndustnalMaterials, 7th Ed., Van<br />

Nostr<strong>and</strong> Reinhold, New York.<br />

Shen, H. M. <strong>and</strong> Q. F. Zhang. 199<strong>4.</strong> ksk assessment of nickel carcinogenicity <strong>and</strong> occupational lung<br />

cancer, Environ. Health Perspect. Suppl. 102: 275-282.<br />

Smialowicz, R J., R R Rogers, M. M. Riddle, <strong>and</strong> G. A. Scott. 198<strong>4.</strong> Immunologic effects of nickel:<br />

I. Suppression of cellular <strong>and</strong> humoral immunity, Environ. Res. 33: 413-427. (Cited in Shen <strong>and</strong><br />

Zhang 1994)<br />

Smialowicz, R J., R R Rogers, M. M. Riddle, et al. 1985. Immunologic effects of nickel: II.<br />

suppression of natural killer cell activity, Environ. Res. 36: 56-66. (Cited in Shen <strong>and</strong><br />

Zhang 1994)<br />

Smialowicz, R J., R R Rogers, D. G. Rowe, et al. 1987. The effects of nickel on immune function<br />

in the rat, Toxicology 44: 271-281. (Cited in Shen <strong>and</strong>zhang 1994)<br />

Sunderman, F. W., Jr., A. Aito, L. G. Morgan, <strong>and</strong> T. Norseth. 1986a. Biological monitoring of<br />

nickel. In: Nickel <strong>and</strong> Human Health, Nieboer, E. <strong>and</strong> J.O. Nriagu, eds., John Wiley <strong>and</strong> Sons,<br />

Inc., New York, NY. pp. 49-68.<br />

Sunderman, F. W., A. J. Donnelly, B. West, <strong>and</strong> J. F. Kincaid. 1959. Nickel poisoning. E.<br />

Carcinogenesis in rats exposed to nickel carbonyl, Arch. Ind. Health 20: 36.


14<br />

Sundman, F. W. <strong>and</strong> A. J. Donnelly. 1965. Studies of nickel carcinogenesis metastasizing<br />

pulmonary tumors in rats induced by the inhalation of nickel carbonyl, Am. J Pathol. 46: 1027.<br />

Sunderman, F. W., Jr., B. Dingle, S. M. Hopfer, <strong>and</strong> T. Swift. 1988. Acute nickel toxicity in<br />

electroplating workers who accidentally ingested a solution of nickel sulfate <strong>and</strong> nickel chloride,<br />

Am. J. Indust. Med. 14: 257-266.<br />

Sunderman, F. W., Jr., S. M. Hopfer, M. C. Cristomo, <strong>and</strong> M. Stoeppler. 1986b. Rapid analysis of<br />

nickel in urine by electrothermal atomic absorption spectrophotometry. Ann. Clin. Lab. Sci., In:<br />

Nickel <strong>and</strong> Human Health, Nieboer, E. <strong>and</strong> J.O. Nriagu, eds., John Wiley <strong>and</strong> Sons, Inc., New<br />

York, NY. pp. 49-68.<br />

Takenaka, S., D. Hochrainer, <strong>and</strong> H. Oldges. 1985. Alveolar proteinosis induced in rats by long-term<br />

inhalation of nickel oxide. In: Progress in Nickel Toxicology. Proc. 3rd. Int. Congress on Nickel<br />

Metabolism <strong>and</strong> Toxicology, Brown, S.S. <strong>and</strong> F.W. Sunderman, Jr., eds., Blackwell Publ. Co.,<br />

Oxford, UK. pp. 89-92.<br />

USAF. 1990. Nickel, In: Installation Restoration Program Toxicology Guide, Vol. 5. Hany G.<br />

Armstrong Aerospace Mdcal Research Laboratory, Wright Patterson AFB, OH.<br />

Warner, J. S. 1979. Nickel carbonyl. Prenatal exposure, Science 203: 1194-1 195.<br />

Wehner, A. P., R H. Busch, R J. Olson, <strong>and</strong> D. K. Craig. 1975. Chronic inhalation of nickel oxide<br />

<strong>and</strong> cigarette smoke in hamsters, Am. Ind. Hyg. Assoc. J. 36: 801-809. (Cited in ATSDR 1988)<br />

Weischer, C. H., W. Kordel, <strong>and</strong> D. Hochrainex. 1980. Effects of NiC1, <strong>and</strong> NiO in Wistar rats after<br />

oral uptake <strong>and</strong> lnhalation exposure, respectively, Zenfral Bakreriol. Mikrobiol. Hyg. (B)<br />

171:336-351. (Citedin ATSDR 1988)<br />

White, M. A. <strong>and</strong> A. M. Boran. 199<strong>4.</strong> Urinary excretion of nickel in nickel-chromium electroplaters,<br />

In: Nickel <strong>and</strong> Human Health, Nieboer, E. <strong>and</strong> J.O. Nriagu, eds., John Wiley <strong>and</strong> Sons, Inc.,<br />

New York, NY. pp. 89-96.


TOXICITY SUMMARY FOR<br />

TRICHLOROETHENE<br />

MARCH 1993<br />

Prepared by<br />

Rosmarie A. Faust, PbD<br />

Chemical Hazard Evaluation Group<br />

Biomedical Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory'<br />

Oak Ridge, Tennessee<br />

Prepared for<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy<br />

under Contract No. DE-AC05-840R21400


EXECUTIVE SUMMARY<br />

Trichloroethene (TCE) is an industrial solvent used primarily in metal degreasing <strong>and</strong><br />

cleaning operations. TCE can be absorbed through the lungs, mucous membranes, gastrointestinal<br />

tract, <strong>and</strong> the skin. TCE is extensively metabolized in humans to trichloroacetic acid <strong>and</strong><br />

trichloroethanol, as well as to several minor metabolites, with most of the absorbed dose excreted<br />

in urine (ATSDR, 1989; U.S. EPA, 1985).<br />

Human <strong>and</strong> animal data indicate that exposure to TCE can result in toxic effects on a<br />

number of organs <strong>and</strong> systems, including the liver, kidney, blood, skin, immune system, reproductive<br />

system, nervous system, <strong>and</strong> cardiovascular system. In humans, acute inhalation exposure<br />

to TCE causes central nervous system symptoms such as headache, dizziness, nausea, <strong>and</strong> unconsciousness<br />

(U.S. EPA, 1985). Among the reported effects from occupational exposure studies are<br />

fatigue, light-headedness, sleepiness, vision distortion, abnormal reflexes, tremors, ataxia,<br />

nystagmus, increased respiration, as well as neurobehavioral or psychological changes. Cardiovascular<br />

effects include tachycardia, extrasystoles, EKG abnormalities, <strong>and</strong> precordial pain (L<strong>and</strong>rigan<br />

et al., 1987; Gr<strong>and</strong>jean et al., 1955; Milby, 1968). The use of TCE as an anesthetic has been<br />

associated with cardiac arrhythmias (U.S. EPA, 1985).<br />

Cases of severe liver <strong>and</strong> kidney damage, including necrosis, have been reported in<br />

humans following acute exposure to TCE (Defalque, 1961), but these effects generally are not<br />

associated with long-term occupational exposures. In animals, TCE has produced liver enlargement<br />

with hepatic biochemical <strong>and</strong>or histological changes (Nomiyama et al., 1986; Kjellstr<strong>and</strong><br />

et al., 1981, 1983; Stott et al., 1982; Tucker et al., 1982) <strong>and</strong> kidney enlargement, renal tubular<br />

alterations <strong>and</strong>/or toxic nephropathy (NTP, 1982, 1986% 1988). Also observed in animals were<br />

hematological effects (Tucker et al., 1982; Ma~a<br />

<strong>and</strong> Brancaccio, 1967) <strong>and</strong> immunosuppression<br />

(S<strong>and</strong>ers et al., 1982). Inhalation studies with rats indicate that TCE is a developmental toxicant<br />

causing skeletal ossification anomalies <strong>and</strong> other effects consistent with delayed maturation (Healy<br />

et al., 1982; Dorfinueller et al., 1979). TCE may cause dermatitis <strong>and</strong> dermographism (U.S. EPA,<br />

1985).<br />

Reference Doses 0 s ) <strong>and</strong> Reference Concentrations (RfCs) for subchronic <strong>and</strong> chronic<br />

oral <strong>and</strong> inhalation exposure to TCE am prtsently under review by EPA (U.S. EPA, 1992a).<br />

Epidemiologic studies have been inadequate to determine if a correlation exists between<br />

exposure to TCE <strong>and</strong> increased cancer risk. Chronic oral exposure to TCE increased the<br />

incidences of hepatocellular carcinomas in mice <strong>and</strong> renal adenocarcinomas <strong>and</strong> leukemia in rats<br />

(NTP, 1988; Maltoni et al., 1986; NTP, 1986% 1982; NCI, 1976). Chronic inhalation exposure<br />

induced lung <strong>and</strong> liver tumors in mice <strong>and</strong> testicular Leydig cell tumors in rats (Maltoni et al.,<br />

1986, 1988; Fukuda et al., 1983; Bell et al., 1978). Although U.S. EPA's Science Advisory<br />

Board recommended a weight-of-evidence classification of C-B2 continuum (C = possible human<br />

carcinogen; B2 = probable human carcinogen), the agency has not adopted a current position on<br />

the weight-of-evidence classification (US. EPA, 1992b). In an earlier evaluation, TCE was<br />

assigned to weight-of-evidence Group B2, probable human carcinogen, based on tumorigenic<br />

responses in rats <strong>and</strong> mice for both oral <strong>and</strong> inhalation exposure <strong>and</strong> on inadequate data in humans<br />

(US. EPA, 1987, 1990). Carcinogen slope factors are l.lE-2 (mgAcg/day)-' <strong>and</strong> 6.OE-3<br />

1


(mgkg/day)-' for oral <strong>and</strong> inhalation exposure, respectively. The corresponding unit risks are<br />

3.2E-7 (pg/Ly' <strong>and</strong> 1.7E-6 (pg/rn'y', respectively (U.S. EPA, 1992b).<br />

2


1. INTRODUCTION<br />

Trichloroethene (trichlorothylene; TCE; CAS No. 79-0 1-6) is a colorless, highly volatile<br />

liquid that is miscible with water <strong>and</strong> a number of organic solvents (U.S. EPA, 1985). It has a<br />

molecular weight of 131.4, a boiling point of 87OC, <strong>and</strong> a density of 1.4642 at 20/4OC (Weast,<br />

1989). TCE is a man-made chemical <strong>and</strong> is not known to occur naturally. It is mainly used as<br />

a solvent in industrial degreasing <strong>and</strong> cleaning of metals, but is also used as a solvent for waxes,<br />

fats, resins, <strong>and</strong> oils, <strong>and</strong> in numerous other applications. Prior to 1977, TCE had been used as<br />

an anesthetic, grain fumigant, disinfectant, <strong>and</strong> extractant of spice oleoresins in food <strong>and</strong> of<br />

caffeine in the production of decaffeinated coffee. Workers in the vapor degreasing industry<br />

appear to be exposed to the highest atmospheric levels of TCE. TCE has been detected in both<br />

surface <strong>and</strong> ground waters; however, most (80-95%) TCE used is released to the atmosphere by<br />

evaporative losses (ATSDR, 1989).<br />

The evaluation of the toxicity of TCE is complicated by the presence or absence of<br />

stabilizers. Industrial grade TCE usually contains stabilizers such as triethylamine, triethanolamine,<br />

epichlorohydrin, or stearates, chemicals that can be toxic by themselves. In the absence<br />

of stabilizers, TCE readily decomposes to dichloroacetylene, phosgene, carbon monoxide, <strong>and</strong><br />

hydrogen chloride. These decomposition products are also toxic (O'Donoghue, 1985).<br />

2. METABOLISM AND DISPOSITION<br />

2.1. ABSORPTION<br />

Trichloroethene can be absorbed through the lungs, digestive tract, skin, <strong>and</strong> mucous<br />

membranes. The primary route of human exposure to the chemical is through pulmonary uptake,<br />

which is rapid but requires about 8 hours to teach tissue equilibrium. The total dose absorbed is<br />

directly proportional to the concentration in inspired air, <strong>and</strong> for a given concentration, body<br />

burden increases with duration <strong>and</strong> frequency of exposure, <strong>and</strong> with exercise (U.S. EPA, 1985).<br />

After ingestion, 90-95% of a dose of 40-60 mgkg was recovered in expired air <strong>and</strong> in urine of<br />

rats, suggesting almost complete absorption of the compound (Daniel, 1963). Tsuruta (1978)<br />

estimated skin absorption by in vivo <strong>and</strong> in vitro techniques <strong>and</strong> reported rates of 7.82 to 12.1<br />

pg/min/cm2 in mice.<br />

2.2. DISTRIBUTION<br />

Following uptake into the body, TCE is rapidly distributed from blood to all tissues,<br />

particularly adipose tissue, <strong>and</strong> appears in sweat <strong>and</strong> saliva (U.S. EPA, 1985). TCE readily passes<br />

through the placenta <strong>and</strong> was detected in the blood of babies at birth after the mothers had<br />

received TCE anesthesia (Laham, 1970).<br />

3


2.3. METABOLISM<br />

The principal site of TCE metabolism is the liver, although metabolism may also occur<br />

in the lungs, kidneys, spleen, <strong>and</strong> small intestine (ATSDR, 1989). The initial biotransformation<br />

may involve the formation of two intermediates, TCE epoxide <strong>and</strong> chloral. In man <strong>and</strong> animals,<br />

TCE is extensively metabolized to trichloroacetic acid, trichloroethanol, <strong>and</strong> trichloroethanol<br />

glucuronide. Several minor metabolites have also been identified, including oxalic acid,<br />

dichloroacetic acid, N-(hydroxyacetyl>aminoethanol, <strong>and</strong> carbon dioxide. Reactive intermediate<br />

metabolites, such as the epoxide, covalently bind to cellular macromolecules, principally protein<br />

<strong>and</strong> to a much smaller extent, DNA. It is estimated that humans metabolize between 40 <strong>and</strong> 75%<br />

of the retained dose (U.S. EPA, 1985). At relatively low TCE concentrations, saturation of TCE<br />

metabolism has not been demonstrated in humans. However, both oral <strong>and</strong> inhalation studies have<br />

provided evidence for saturation of TCE metabolism in rats (ATSDR, 1989). There are<br />

quantitative differences in the rates of metabolism in different species. For example, mice<br />

metabolize TCE at a greater rate than rats <strong>and</strong> as a result produce more tissue-binding metabolites<br />

in the liver <strong>and</strong> kidney when compared to rats (Stott et al., 1982).<br />

2.<strong>4.</strong> EXCRETION<br />

TCE is eliminated by two major processes, liver metabolism with subsequent elimination<br />

of metabolites <strong>and</strong> pulmonary excretion of the parent compound. In humans, most of retained<br />

TCE is excreted as urinary metabolites (58%); 5% or more may be excreted in the feces; <strong>and</strong><br />

about 1 1% is eliminated through the lungs (ATSDR, 1989). In contrast, when TCE was given<br />

by gavage to rats, 10-20% of the dose was excreted in the urine as trichloroacetic acid <strong>and</strong><br />

trichloroethanol, 0-0.5% as TCE in the feces, <strong>and</strong> 7245% as TCE in the expired air (Daniel,<br />

1963).<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

3.1. ORAL EXPOSURES<br />

3.1.1. Acute Toxicity<br />

3.1.1.1. Human<br />

Fatalities have been reported following accidental or intentional ingestion of TCE. The<br />

lethal oral dose for adults is approximately 7 g/kg (WHO, 1985). Accidental ingestion of TCE<br />

has resulted in inebriety, vomiting, diarrhea, collapse <strong>and</strong> coma, followed by either death or<br />

recovery with transient neurological sequelae (amnesia, headache, numbness, weakness of extremities,<br />

psychosis or hemiparesis). At autopsy, pulmonary edema <strong>and</strong> liver <strong>and</strong> kidney necrosis were<br />

observed Oefalque, 1961). Hepatorenal failure was reported in one fatal case of accidental<br />

ingestion of TCE (Kleinfield <strong>and</strong> Tabemhaw, 1954). There are indications that the hepatotoxic<br />

effects of TCE are enhanced by concomitant exposure to ethanol or isopropyl alcohol (IARC,<br />

1979). Case studies suggest that ingestion of 350-500 mL of TCE can produce cardiac arrhythmias<br />

(Dhuner et a]., 1957).<br />

.<br />

4


3.1.1.2. Animal<br />

Oral LD,,s for TCE are 2402 <strong>and</strong> 2443 mgkg for male <strong>and</strong> female mice, respectively,<br />

4920 mgkg for rats, <strong>and</strong> 5680 mgkg for dogs (ATSDR, 1989).<br />

3.1.2. Subchronic Toxicity<br />

3.1.2.1. Human<br />

Information on the subchronic oral toxicity of TCE in humans was Unavailable.<br />

3.1.2.2. Animal<br />

Male mice given 250-2400 mgkg TCE by gavage, 5 daydweek for 3 weeks exhibited a<br />

dose-related hepatocellular hypertrophy (Stott et al., 1982). Significantly increased liver weights<br />

were seen in male CD-1 mice given daily gavage doses of 240 mg/kg/day, but not 24 mgkg/day,<br />

for 14 days (Tucker et al., 1982). The same investigators administered TCE in drinking water<br />

to CD- 1 mice for 6 months at concentrations of 18-660 mg/kg/day (males) <strong>and</strong> 18-793 mgkg/day<br />

(females). Treatment-related effects included increased relative liver weights <strong>and</strong> increased<br />

urinary ketone <strong>and</strong> protein concentrations at 393 mg/kg/day (males) <strong>and</strong> increased liver <strong>and</strong> kidney<br />

weights at the highest doses in both sexes. Also observed at the highest doses were decreased<br />

erythrocyte <strong>and</strong> leukocyte counts <strong>and</strong> increased fibrinogen levels in males after 4 <strong>and</strong> 6 months<br />

<strong>and</strong> shortened prothrombin time in females after 6 months (Tucker et al., 1982).<br />

S<strong>and</strong>ers et al. (1982) evaluated the immune status of male <strong>and</strong> female CD-1 mice<br />

following exposure to TCE in drinking water at doses of 18-666 mgkg/day (males) <strong>and</strong> 18-793<br />

mgkg/day (females) for 4 or 6 months. The TCE-induced immunotoxic effects observed were<br />

more pronounced in females <strong>and</strong> included depressed cell-mediated response to sheep erythrocytes<br />

at 2 18 mgkg after 4 months <strong>and</strong> at 739 mg/kg/day after 6 months; depressed antibody-forming<br />

cell response at 2 437 mg/kg/day after 4 months but not after 6 months; <strong>and</strong> inhibited bone<br />

marrow stem cell colonization after 4 <strong>and</strong> 6 months.<br />

3.13. Chronic Toxicity<br />

3.13.1. Human<br />

Information on the chronic oral toxicity of TCE in humans was unavailable.<br />

3.13.2. Animal<br />

Renal effects characterized as cytomegaly were observed in F344 rats treated by gavage<br />

with 500 or 1000 mg/kg/day TCE, 5 daydweek for 103 weeks <strong>and</strong> in B6C3F, mice similarly<br />

treated with 1000 mg/kg/day OIJTP, 1982; 1986a). Also observed in rats were signs of central<br />

nervous system (CNS) toxicity, including ataxia, lethargy, convulsions, <strong>and</strong> hind limb paralysis.<br />

These effects were described as sporadic <strong>and</strong> transient. Cytomegaly of renal tubular cells <strong>and</strong><br />

toxic nephropathy was seen in ACI, August, Marshall, <strong>and</strong> OsbornaMendel rats treated by gavage<br />

with 500 or 1000 mg/kg/day for 103-104 weeks (NTP, 1988).


3.1.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1. Human<br />

Information on the developmental <strong>and</strong> reproductive toxicity of TCE in humans following<br />

oral exposure was unavailable.<br />

3.1.<strong>4.</strong>2. Animal<br />

Rats exposed to TCE by gavage in corn oil at doses of 0, 10, 100, or 1000 mg/kg/day for<br />

2 weeks prior to <strong>and</strong> throughout mating to day 21 of gestation exhibited increased maternal<br />

mortality, decreased maternal weight gain, <strong>and</strong> decreased neonatal survival in the high-dose group<br />

(Manson et al., 1984).<br />

Two-generation fertility studies (NTP, 1985, 1986b) exposed male <strong>and</strong> female F344 rats<br />

<strong>and</strong> CD-1 mice to diets containing 75, 150, or 300 mg/kg/day TCE. In tats, the two higher doses<br />

caused a reduction in the number of live pupdlitter <strong>and</strong> the highest dose caused increased testis<br />

<strong>and</strong> epididymis weights (combined) in the F, generation. Mice exposed to the highest dose<br />

exhibited increased neonatal mortality, increased testis <strong>and</strong> epididymis weights (combined) in F,<br />

mice, <strong>and</strong> reduced sperm motility in F, <strong>and</strong> F, mice.<br />

3.1.5. Reference Dose<br />

The development of a Reference Dose for TCE is under review by EPA (U.S. EPA,<br />

1992a).<br />

3.2. INHALATION EXPOSURES<br />

3.2.1. Acute Toxicity<br />

3.2.1.1. Human<br />

Acute inhalation exposure to TCE causes central nervous system symptoms, such as<br />

headache, dizziness, nausea, <strong>and</strong> in some cases unconsciousness. Lower levels may affect visual<br />

<strong>and</strong> motor performance (U.S. EPA, 1985). Case reports reviewed by Grant (1974) indicate that<br />

acute exposure to TCE may produce paralysis of the trigeminal nerve or extraocular muscle as<br />

well as vision disturbances. It was suggested that the observed visual effects were produced by<br />

decomposition products such as dichlomacetylene rather than by TCE. Although permanent<br />

central nervous system damage has been reported after exposure to TCE, respiratory <strong>and</strong> cardiac<br />

failure are the likely causes of death following acute inhalation exposure. The use of TCE as an<br />

anesthetic has been associated with cardiac arrhythmias, bradydia, atrial <strong>and</strong> ventricular<br />

premature contractions, <strong>and</strong> ventricular extrasystole (U.S. EPA, 1985). In controlled studies of<br />

human exposure, impairment of psychophysiological function was seen in volunteers exposed to<br />

1 10 ppm for two 4-hour periods. Exposure to 200 ppm for 7 hours over 5 days produced fatigue<br />

<strong>and</strong> sleepiness (IARC, 1979).<br />

6


Cases of severe liver damage, including necrosis, resulting from acute occupational<br />

exposure to lethal concentrations of TCE have been reported. A few case reports described renal<br />

dysfunction <strong>and</strong> failure resulting &om occupational or intentional exposure (U.S. EPA, 1985).<br />

33.1.2. Animal<br />

Reported LC,, values for TCE range from 7,480 to 49,000 ppm for mice <strong>and</strong> from 12,500<br />

to 26,300 ppm for rats (ATSDR, 1989). Rats exposed to 250-4,OOO pprn TCE for up to 4 hours<br />

exhibited decreased avoidance responses (Kishi et al., 1986). Sensitization of the heart to<br />

epinephrine-induced arrhythmia was observed in dogs exposed to 5,000-10,000 ppm for 10 min<br />

<strong>and</strong> in rabbits exposed to 6,000 ppm for 1 hour (U.S. EPA, 1985). Chakrabarti <strong>and</strong> Tuchweber<br />

(1988) reported that rats exposed to 1,000 or 2,000 ppm TCE for 6 hours exhibited significantly<br />

increased urinary levels of gamma-glutamyltranspeptidase activity, <strong>and</strong> glucose <strong>and</strong> protein concentrations,<br />

which are biochemical changes indicative of renal injury.<br />

3.23. Subchronic Toxicity<br />

3.2.2.1. Human<br />

L<strong>and</strong>rigan et al. (1987) reported that seven of nine TCE-exposed workers involved in a<br />

metal degreasing operation experienced fatigue, light-headedness, sleepiness, shortness of breath,<br />

dyspnea on exertion, palpitations, nausea, <strong>and</strong> headache. Similar symptoms were not reported in<br />

non-exposed controls. The mean duration of employment of exposed workers was <strong>4.</strong>4 years.<br />

Breathing zone levels of TCE for the five workers who were exposed to the highest TCE concentrations<br />

ranged h m 117 to 357 mdm’ <strong>and</strong> averaged 89 mg/m’. Short-term peak exposures<br />

ranged h m 413 to 2000 mg/m3.<br />

Gr<strong>and</strong>jean et al. (1955) evaluated the effects of TCE in 50 workers who had been occupationally<br />

exposed for an average of 3.75 years. Signs of severe neurological disturbances (vision<br />

distortion, abnormal reflexes, slow tremors, ataxia, or nystagmus) occurred in 28% of the exposed<br />

workers. Symptoms of autonomic nervous system involvement (excessive respiration, circulatory<br />

symptoms, tremors, gastrointestinal upset, palpitations, tachycardia, extrasystoles, precordial pain,<br />

<strong>and</strong> pronounced modification of dermographism) occurred in 36% of the workers. Slight to<br />

moderate psychic disturbances (short-term memory loss, slow underst<strong>and</strong>ing, emotional instability,<br />

<strong>and</strong> fewer word associations) occumd in 34% of the workers.<br />

In a case study reported by Milby (1968), vomiting <strong>and</strong> abdominal cramps, as well as an<br />

erratic heart beat, an abnormal EKG, sleepiness, weakness, <strong>and</strong> loss of appetite occd in a<br />

worker who had been exposed to TCE for 1 month. Breathing zone measurements after the<br />

incident ranged from 260 to 280 ppm TCE. James (1963) reported fatty degeneration of the liver<br />

in a worker who had become addicted to TCE over a 9-year period.<br />

3.233. Animal<br />

Nomiyama et al. (1 986) found significant hepatic dysfunction in male SpragueDawley<br />

rats continuously exposed to 50,200, or 800 ppm TCE for 12 weeks. Liver weight, total protein,<br />

albumidglobulin ratio, plasma glutamic pyruvate transaminase activity, triglyceride, cholesterol<br />

ester ratio, <strong>and</strong> cholinesterase were affected. Renal dysfunction as indicated by glycosuria <strong>and</strong><br />

7


alterations in plasma creatine, urine nitrogen, uric acid, <strong>and</strong> creatine clearance, as well as<br />

concentration-related changes in hematocrit, <strong>and</strong> erythrocyte, reticulocyte, <strong>and</strong> erythroblast counts<br />

were also seen.<br />

Rats exposed to 55 ppm TCE for 14 weeks exhibited enlarged livers but no other adverse<br />

hepatic effects (Kimmerle <strong>and</strong> Eben, 1973). Increased relative liver weight was the only hepatic<br />

effect reported in male <strong>and</strong> female rats, mice, <strong>and</strong> gerbils exposed to concentrations up to 150<br />

ppm TCE for 30 days, but the effect was more pronounced in mice than in rats or gerbils (Kjellstr<strong>and</strong><br />

et al., 1981). Histological alterations of the liver characterized by cellular atrophy were<br />

associated with liver enlargement in a study with mice exposed to 37 ppm TCE for 30 days<br />

(Kjellstr<strong>and</strong> et al., 1983).<br />

Haglid et al. (1981) reported that continuous exposure to 60 ppm TCE for 3 months<br />

resulted in biochemical <strong>and</strong> histopathological changes in the brain of Mongolian gerbils. These<br />

changes are indicative of astroglial hypertrophy <strong>and</strong>or proliferation. Behavioral changes (reduced<br />

activity) were seen in rats exposed for 12 weeks to TCE at concentrations ranging from 100 to<br />

1000 ppm (Silverman <strong>and</strong> Williams, 1975).<br />

Exposure to 2790 ppm TCE, 4 hodday, 6 daydweek for 45 days caused myelotoxic<br />

anemia in rabbits (Maim <strong>and</strong> Brancaccio, 1967). A concentration-related decrease in deltaaminolevulinate<br />

dehydratase activity (an enzyme involved in heme regulation) was seen in rats<br />

continuously exposed to 50, 400, or 800 ppm for 10 days (Fujita et ai., 1984).<br />

3.23. Chronic Toxicity<br />

3.23.1. Human<br />

Bardodej <strong>and</strong> Vyskocif (1956) evaluated 75 individuals in dry cleaning <strong>and</strong> metal dew-<br />

ing workshops who had been exposed to 5-632 ppm TCE for 1-25 years. Prenarcotic symptoms<br />

of chronic exposure included headache, sleepiness, a drunken feeling, nausea, <strong>and</strong> tinnitus. Other<br />

symptoms were intolerance to heat <strong>and</strong> sunlight, hot flashes, perspiration, exaggerated heart beat,<br />

respiratory difficulties, reddening of the skin after mechanical or heat insults, intolerance to<br />

alcohol, <strong>and</strong> dermographism. Cardiovascular effects included vasomotor changes, bradycardia,<br />

supraventricular extrasystole, <strong>and</strong> conduction velocity disturbances. In addition, numerous<br />

subjective CNS effects were reported. There was no evidence of liver or kidney damage.<br />

3.23.2. Animal<br />

Male Sprague-Dawiey rats were exposed to 100,300, or 600 ppm TCE, 7 hodday, 5<br />

daydweek for 108 weeks. Renal cytokaryomegaly occurred at 300 <strong>and</strong> 600 ppm, but not at 100<br />

ppm (Maltoni et al., 1988, 1986).<br />

8


3.2.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

3.2.<strong>4.</strong>1. Human<br />

Two studies suggest that medical personnel exposed to various solvents, including TCE,<br />

are susceptible to reproductive effects. A survey of operating mom personnel in the U.S. showed<br />

that women exposed to anesthetic waste gases (containing TCE) were subject to increased risks<br />

of spontaneous abortions <strong>and</strong> congenital abnormalities in their children. Increased risks of<br />

congenital abnormalities were also present among non-exposed wives of male operating room<br />

personnel (Cohen et al., 1974). Another survey involving 7949 physicians in the United Kingdom<br />

revealed a significantly higher fiequency of spontaneous abortions in women anesthesiologists<br />

compared with non-anesthesiologists. The frequency of minor abnormalities in children of<br />

exposed fathers was 3.09% compared with 2.35% for nonexposed fathers (Knill-Jones et al.,<br />

1975).<br />

3.2.<strong>4.</strong>2. Animal<br />

Dorfmueller et al. (1979) exposed female rats to 1800 ppm TCE for two weeks prior to<br />

mating <strong>and</strong> for 20 days during gestation <strong>and</strong> found no evidence of maternal toxicity, embryotoxicity,<br />

severe teratogenicity, or behavioral deficits in the offspring. Offspring of rats exposed<br />

during pregnancy alone showed significant increases of skeletal <strong>and</strong> soft tissue abnormalities.<br />

Reduced body weights were seen in offspring of rats with pregestational exposure alone.<br />

Wistar rats exposed to 100 ppm TCE for 4 hours daily on days 8-21 of gestation exhibited<br />

increased resorptions, reduced fetal weight gains, <strong>and</strong> increased frequency of bipartite or absent<br />

skeletal ossification centers (Healy et al., 1982). However, Sprague-Dawley rats <strong>and</strong> Swiss<br />

Webster mice exposed to 300 ppm TCE on days 5-15 of gestation exhibited no significant<br />

matemal, embryonal, or fetal toxicity <strong>and</strong> no evidence of teratogenicity (Schwetz et al., 1975).<br />

Sperm abnormalities were reported in mice exposed to 2000 ppm anesthetic-grade TCE<br />

vapor, 4 houdday for 5 days (L<strong>and</strong> et al., 1979) or to 500 ppm TCE, 7 houdday for 5 days<br />

(Beliles et al., 1980).<br />

33.5. Reference Concentration<br />

The development of a Reference Concentration is under review by EPA (U.S. EPA,<br />

1992a).<br />

3.3. OTHER ROUTES OF EXPOSURE<br />

33.1. Acute Toxicity<br />

33.1.1. Human<br />

Acute dermal exposure to TCE has been associated with reddening <strong>and</strong> dermatographic<br />

skin bums. The vapor may cause general dermatitis (U.S. EPA, 1985). Hypersensitivity to TCE,<br />

resulting in severe dermatological abnormalities, such as Steven-Johnson syndrome (erythema<br />

multiformis major), was reported in one study (Phoon et al., 1984). A skin condition termed<br />

9


“degreasers’ flush” has been reported in workers who had consumed alcohol before or after<br />

exposure to TCE (Stewart et al., 1974). Direct contact of TCE vapor or liquid with the eye<br />

causes superficial damage to the cornea, but complete recovery occurs within a few days (Grant,<br />

1974).<br />

3.3.1.2. Animals<br />

The dermal LD,, for TCE in rabbits is > 20 m ug (Smyth et ai., 1969).<br />

3.3.2. Subchronic Toxicity<br />

Information on the subchronic toxicity of TCE by other routes of exposure in humans or<br />

animals was unavailable.<br />

3.33. Chronic Toxicity<br />

Information on the chronic toxicity of TCE by other routes of exposure in humans or<br />

animals was unavailable.<br />

33.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

Information on the developmental <strong>and</strong> reproductive toxicity of TCE by other routes of<br />

exposure in humans or animals was unavailable.<br />

3.<strong>4.</strong> TARGET ORGANS/CRITICAL EFFECTS<br />

3.<strong>4.</strong>1. Oral Exposures<br />

3.<strong>4.</strong>1.1. Primary Target Organs<br />

-<br />

1. Liver: Mice developed increased liver weight <strong>and</strong> hepatocellular hypertrophy<br />

following oral exposure to TCE.<br />

2. Kidney: Rats <strong>and</strong> mice developed increased kidney weights, cytomegaly of<br />

renal tubular cells, <strong>and</strong> toxic nephropathy following oral exposure to TCE.<br />

3.<strong>4.</strong>1.2. Other Target Organs<br />

1. Central nervous system: Chronic oral exposure of rats caused transient CNS<br />

effects including ataxia, lethargy, convulsions, <strong>and</strong> hind limb paralysis.<br />

2. Reproduction: Increased neonatal mortality, increased testis <strong>and</strong> epididymis<br />

weights, <strong>and</strong> reduced sperm motility was seen in a two-generation fertility study<br />

with rats.<br />

3. Hematopoietic system: Rats exposed to TCE in drinking water exhibited<br />

decreased erythrocyte <strong>and</strong> leukocyte counts, increased fibrinogen levels, <strong>and</strong><br />

shortened prothrombin time.<br />

10


<strong>4.</strong> Immune system: Mice exposed to TCE in drinking water exhibited immunotoxic<br />

effects characterized by delayed hypersensitivity, suppressed antibody<br />

forming cell response, <strong>and</strong> decreased bone marrow stem cell colonization.<br />

3.<strong>4.</strong>2. Inhalation Exposures<br />

3.<strong>4.</strong>2.1. Primary Target Organs<br />

1. Nervous system: CNS symptoms in workers exposed to TCE by inhalation<br />

included headache, sleepiness, vision distortion, nausea, abnormal reflexes,<br />

tremors, ataxia, nystagmus, <strong>and</strong> increased respiration. TCE exposure may also<br />

cause psychic disturbances such as short-term memory loss <strong>and</strong> fewer word<br />

associations. Subchronic exposure of gerbils induced biochemical <strong>and</strong><br />

histopathological changes in the brain.<br />

2. Liver: Following inhalation exposure to TCE, rodents developed enlarged<br />

livers <strong>and</strong> biochemical changes indicative of liver damage. Liver damage in<br />

humans is primarily associated with acute exposure to TCE. The hepatotoxic<br />

effects of TCE are enhanced by concomitant exposure to alcohol.<br />

3. Kidney: Rats developed renal cytokaryomegaly following chronic inhalation<br />

exposure to TCE.<br />

<strong>4.</strong> Cardiovascular system: Occupational exposure to TCE has been associated<br />

with vasomotor changes, tachycardia, bradycardia, extrasystoles, conduction<br />

disturbances, <strong>and</strong> precordial pain. TCE sensitizes the heart to diac<br />

arrhythmias.<br />

5. Hematopoietic system: Inhalation of TCE induced myelotoxic anemia in<br />

rabbits <strong>and</strong> produced dose-related changes in several hematological indices in rats.<br />

6. Reproduction: Inhalation studies with rodents indicate that TCE may cause<br />

increased resorptions, reduced fetal body weight, <strong>and</strong> ossification anomalies.<br />

Exposure to high concentrations produced spem abnormalities in mice.<br />

3.<strong>4.</strong>2.2. Other Target Organs<br />

Skin: Reddening of the skin following mechanical or heat insults <strong>and</strong> demographism<br />

was seen in workers exposed to TCE by inhalation.<br />

11


3.<strong>4.</strong>3. Other Routes of Exposure<br />

Skin: Dermal exposure to TCE may cause general dermatitis <strong>and</strong> hypersensitivity.<br />

"Degreasers' flush" may occur in conjunction with alcohol consumption.<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1. ORAL EXPOSURES<br />

<strong>4.</strong>1.1. Human<br />

Mortality statistics for 1969- 1979 in Woburn, Massachusetts revealed a significantly<br />

elevated rate of childhood leukemia. Two of the eight municipal wells serving the community<br />

were known to be contaminated with TCE <strong>and</strong> several other chlorinated organic compounds, but<br />

the causes of leukemia were not identified in these studies (Kotelchuck <strong>and</strong> Parker, 1979; Parker<br />

<strong>and</strong> Rosen, 1981).<br />

<strong>4.</strong>1.2. Animal<br />

Maltoni et al. (1986) treated male <strong>and</strong> female Sprague-Dawley rats by gavage with TCE<br />

(99.9% pure) in olive oil at doses of 50 or 250 mg/kg/day, 4-5 daydweek for 52 weeks. There<br />

was a dose-related increase in the incidence of leukemia in males, but no increased tumor<br />

incidence in females.<br />

Significantly increased incidences of hepatocellular carcinomas occumd in B6C3F, mice<br />

that were administered time-weighted-average doses of 1170 or 1340 mg/kg/day (males) or 870<br />

or 1740 mg/kg/day (females) by gavage, 5 daydweek for 78 weeks. No compound-related<br />

carcinogenic effects were found in Osborne-Mendel rats similarly treated with 550 or 1100<br />

mg/kg/day, but this finding was inconclusive because of poor survival. The TCE used in the<br />

study was 299% pure but contained stabilizers, including epichlorohydrin, a known carcinogen<br />

(NCI, 1976).<br />

Studies by NTP (1982, 1986a) showed significantly increased incidences of hepatocellular<br />

carcinomas in male <strong>and</strong> female B6C3F, mice treated by gavage with epichlorohydrin-free TCE<br />

at a dose of 1000 mg/kg/day, 5 daydweek for 103 weeks. F344 rats treated with 1000 mg/kg/day<br />

by the same regimen exhibited renal adenomas <strong>and</strong> adenocarcinomas; this effect was not seem at<br />

500 mg/kg/day or in females at either dose level. Due to poor survival, the results in rats were<br />

considered inadequate. A third NTP study (NTP, 1988) exposed groups of male <strong>and</strong> female ACI,<br />

August, Marshall, <strong>and</strong> Osborne-Mendel rats by gavage to epichlorohydrin-free TCE in corn oil<br />

at doses of 0, 500, or 1000 mgkg, 5 daydweek for 103 weeks. There were significantly<br />

increased incidences of renal tubular cell neoplasms in low dose male Osborne-Mendel rats <strong>and</strong><br />

interstitial cell neoplasms of the testis in high-dose Marshall rats. This study also was considered<br />

inadequate for assessment of carcinogenic activity because of toxic nephrosis <strong>and</strong> low survival.<br />

Henschler et ai. (1984) compared the carcinogenicity of TCE stabiIized with epichlorohydrin<br />

(0.8%) or 1,2-epoxybutane (0.8%) to that of industrial-grade TCE in male <strong>and</strong> female<br />

12


ICRMa Swiss mice. TCE was administered daily by gavage (2.4 gkg, females; 1.8 g/kg, males)<br />

for 18 months, with <strong>and</strong> without the addition of the epoxides. Animals exposed to epichlorohydrinor<br />

1,2-epoxybutane-stabilized TCE exhibited an increased incidence of papillomas <strong>and</strong> carcinomas<br />

of the forestomach. This effect was not observed without stabilizers.<br />

<strong>4.</strong>2. INHALATION EXPOSURES<br />

<strong>4.</strong>2.1. Human<br />

Epidemiologic studies conducted by Axelson et al. (1978), Malek et al. (1979), <strong>and</strong> Tola<br />

et al. (1980) reported no significant excess cancer risks associated with occupational exposure to<br />

TCE, but the studies do not permit definite conclusions because of various study limitations such<br />

as inadequate latency periods, small sample size, lack of analysis by tumor site, <strong>and</strong> multiple<br />

chemical exposure (ATSDR, 1989; U.S. EPA, 1985). An update of one of the studies (Axelson,<br />

1986) found a slight increase of bladder cancer <strong>and</strong> lymphomas in an exp<strong>and</strong>ed cohort study;<br />

however, details of TCE exposure were not given. A retrospective cohort mortality study of drycleaning<br />

<strong>and</strong>/or laundry workers (Blair et al., 1979) found significant increases in the incidence<br />

of cancer at several sites (lung/bronchVtrachea, cervix, <strong>and</strong> skin) among a group of 330 deceased<br />

workers. This cancer increase was possibly due to dry-cleaning chemicals (carbon tetrachloride,<br />

tetrachloroethylene, <strong>and</strong> TCE) but could not be related to TCE alone. Paddle (1983) examined<br />

tumor registry records in Great Britain <strong>and</strong> found no association between liver cancer <strong>and</strong> TCE<br />

exposure in workers employed in one TCE production facility.<br />

<strong>4.</strong>22. Animal<br />

Bell et al. (1978) reported no carcinogenic effects in Charles River rats exposed to<br />

technical grade TCE at concentrations of 0, 100,300, or 600 ppm, 6 hodday, 5 daydweek for<br />

24 months. Hepatocellular carcinomas were seen in B6C3F1 mice similarly exposed to TCE, with<br />

a greater incidence of tumors occurring in males than in females. The TCE employed contained<br />

0.148% epichlorohydrin <strong>and</strong> several other additives.<br />

Wistar rats, NMR mice, <strong>and</strong> Syrian hamsters were exposed to purified TCE at 0,100, or<br />

500 ppm, 6 houdday, 5 daydweek for 18 months (Henschler et al., 1980). The only statistically<br />

significant effect was an increased incidence of malignant lymphomas in female mice. US. EPA<br />

(1987) suggested that lymphoma susceptibility may have been enhanced by virus <strong>and</strong> immunosuppression.<br />

Fukuda et al. (1983) exposed female ICR mice <strong>and</strong> Sprague-Dawley rats to reagent-grade<br />

TCE (containing 0.019% epichlorohydrin) at concentrations of 0, 50, 150, or 450 ppm, 7<br />

houdday, 5 daydweek for 104 weeks. Although then were a number of tumors at several sites<br />

in rats <strong>and</strong> mice, only lung adenocarcinomas were significantly increased in mice at the two<br />

highest concentrations compared with controls.<br />

Maltoni et ai. (1986, 1988) exposed male <strong>and</strong> female Sprague-Dawley rats, Swiss mice,<br />

<strong>and</strong> B6C3F1 mice to 100,300, or 600 ppm epoxide-fiee TCE, 7 hodday, 5 daydweek for 104<br />

weeks (rats) or 78 weeks (mice). Statistically significant increased incidences of tumors included<br />

testicular Leydig cell tumors in rats at 2100 ppm, lung adenomas in male Swiss mice at 2300<br />

13


ppm, hepatomas in male Swiss mice at 600 ppm, <strong>and</strong> lung adenomas in female B6C3F, mice at<br />

600 ppm.<br />

43. OTHER ROUTES OF EXPOSURE<br />

<strong>4.</strong>3.1. Human<br />

Information on the carcinogenicity of TCE in humans by other routes of exposure was<br />

unavailable.<br />

<strong>4.</strong>3.2. Animal<br />

Three weekly topical applications of 1 mg TCE for 581 days did not induce skin tumors<br />

in female Swiss ICRha mice. Negative results were also reported in a tumor initiation assay in<br />

which mice received a single dermal application of 1 mg TCE, followed by 3 weekly applications<br />

of a phorboi ester for 581 days (Van Duuren et al., 1979).<br />

<strong>4.</strong><strong>4.</strong> EPA WEIGHT-OF-EVIDENCE<br />

Classification: C-B2 continuum (C = possible human carcinogen; B2 = probable human<br />

carcinogen) (U.S. EPA, 1992b).<br />

Comment: This classification is a recent recommendation by EPA's Science<br />

Advisory Board. However, EPA has not adopted a current position on the<br />

weight-of-evidence classification (U.S. EPA, 1992b). An earlier evaluation (U.S.<br />

EPA, 1990) classified TCE as a weight-of-evidence B2 chemical, based on tumor<br />

responses in rats <strong>and</strong> mice exposed to TCE by the oral <strong>and</strong> inhalation routes of<br />

exposure. The available epidemiological data were inadequate to refute or<br />

demonstrate a human carcinogenic potential (U.S. EPA, 1987).<br />

<strong>4.</strong>5. CARCINOGENICITY SLOPE FACTORS<br />

<strong>4.</strong>5.1. Oral<br />

SLOPE FACTOR: l.lE-2 (mg/kg/day)*' (US. EPA, 1992b)<br />

UNIT RISK. 3.2E-7 (pg/L)-'(US. EPA, 1992b)<br />

PRINCIPAL STUDIES: NCI (1976); NTP (1983); U.S. EPA (1985, 1987, 1988)<br />

COMMENT: The slope factor <strong>and</strong> unit risk values were provided in U.S. EPA (1985).<br />

However, the carcinogenicity files for TCE have been withdrawn from IRIS pending resolution<br />

of the weight-of-evidence classification.<br />

<strong>4.</strong>5.2. Inhalation<br />

SLOPE FACTOR<br />

UNIT RISK:<br />

PRINCIPAL STUDIES:<br />

6.OE-3 (mg/kg/day)-' (U.S. EPA, I992b)<br />

1.E-6 (pg/m3y* (US. EPA, 1992b)<br />

Maltoni et al. (1986); Fukuda et al. (1983); U.S. EPA (1988)<br />

14


COMMENT: The slope factor <strong>and</strong> unit risk values were provided in U.S. EPA (1987).<br />

However, the carcinogenicity files for TCE have been withdrawn from IRIS pending resolution<br />

of the weight-of-evidence classification.<br />

15


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EPkV600f 8-82/006FA, PB 87-228045.<br />

U.S. EPA. 1988. Updated Health Effects Assessment for Trichloroethylene. Prepared by the<br />

Ofice of Health <strong>and</strong> Environmental Assessment Office, Cincinnati, OH, for the Office of<br />

Emergency <strong>and</strong> Remedial Response, Washington, DC.<br />

U.S. EPA. 1990. Trichloroethylene. Integrated Risk Information System (IRIS). Environmental<br />

Criteria <strong>and</strong> Assessment Ofice, Office of Health <strong>and</strong> Environmental Assessment, Cincinnati, OH.<br />

U.S. EPA. 1 992a. Trichloroethylene. Integrated Risk Information System (IRIS). Environmental<br />

Criteria <strong>and</strong> Assessment Office, Office of Health <strong>and</strong> Environmental Assessment, Cincinnati,<br />

OH.<br />

U.S. EPA. 1992b. Superfund Health Risk Technical Support Center, Fact Sheet for Trichloroethylene<br />

(TCE) (CASRN 79-01-6), dated Dec. 14, 1992.<br />

Van Duuren, B.L., B.M. Goldschmidt, G. Lowengat, et al. 1979. Carcinogenicity of halogenated<br />

olefinic <strong>and</strong> aliphatic hydrocarbons in mice. J. Nat. Cancer Inst. 63: 1433-1439.<br />

Weast, R.C., J.A. Spadaro, R.O. Becker, et al. 1988-1989. H<strong>and</strong>book of Chemistry <strong>and</strong> Physics,<br />

69th ed. CRC Press, Inc., Boca Raton, FL., pp. (B)127-128.<br />

WHO (World Health Organization). 1985. Environmental Health Criteria 50. Trichloroethylene.<br />

World Health Organization, Geneva, Switzerl<strong>and</strong>.<br />

20


TOXICITY SUMMARY<br />

for<br />

VANADIUM AND VANADIUM COMPOUNDS<br />

December 1991<br />

Prepared by:<br />

Dennis M. Opresko, Ph.D.<br />

Chemical Hazard Evaluation <strong>and</strong> Communication Group<br />

Biomedical <strong>and</strong> Environmental Information Analysis <strong>Section</strong><br />

Health <strong>and</strong> Safety Research Division<br />

Oak Ridge National Laboratory*<br />

Oak Ridge, Tennessee<br />

Prepared for:<br />

OAK RIDGE RESERVATION ENVIRONMENTAL<br />

RESTORATION PROGRAM<br />

*Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy<br />

under Contract No. DE-ACO5-84OR2 1400<br />

.


This page intentionally le# blank


EXECUTIVE SUMMARY<br />

Vanadium is a metallic element that occurs in six oxidation states <strong>and</strong> numerous inorganic<br />

compounds. Some of the more important compounds are vanadium pentoxide (V,O,), sodium<br />

metavanadate (NaVO,), sodium orthovanadate (N%VO,), vanadyl sulfate (VOSO,), <strong>and</strong><br />

ammonium vanadate (NH,VO,). Vanadium is used primarily as an alloying agent in steels <strong>and</strong><br />

non-ferrous metals (ATSDR, 1990). Vanadium compounds are also used as catalysts <strong>and</strong> in<br />

chemical, ceramic or specialty applications.<br />

Vanadium compounds are poorly absorbed through the gastrointestinal system (0.5-2%<br />

of dietary amount) (NRCC, 1980; ICRP, 1960; Byrne <strong>and</strong> Kosta, 19781, but slightly more readily<br />

absorbed through the lungs (20-25%) (ICRP, 1960; Davies <strong>and</strong> Bennett, 1983). Absorbed<br />

vanadium is widely distributed in the body, but short-term localization occurs primarily in bone,<br />

kidneys, <strong>and</strong> liver (Vouk, 1979; Roshchin et al., 1980; Parker et al., 1980; Sharma et al., 1980;<br />

Wiegmann et al., 1982). In the body, vanadium can undergo changes in oxidation state<br />

(interconversion of vanadyl(+4) <strong>and</strong> vanadate (+5) forms) <strong>and</strong> it can also bind with blood protein<br />

‘(transferin) (Harris et al., 1984). Vanadium is excreted primarily in the feces following oral<br />

exposures <strong>and</strong> primarily in the urine following inhalation exposures (Tipton et al., 1969; ATSDR,<br />

1990).<br />

The toxicity of vanadium depends on its physico-chemical state; particularly on its valence<br />

state <strong>and</strong> solubility. Based on acute toxicity, pentavalent NH,VO, has been reported to be more<br />

than twice as toxic as trivalent VCl, <strong>and</strong> more than 6 times as toxic as divalent VI,. Pentavalent<br />

V,O, has been reported to be more than 5 times as toxic as trivalent V,O, (Roschin, 1967). In<br />

animals, acutely toxic oral doses cause vasoconstriction, diffuse desquamative enteritis, congestion<br />

<strong>and</strong> fatty degeneration of the liver, congestion <strong>and</strong> focal hemorrhages in the lungs <strong>and</strong> adrenal<br />

cortex (Gosselin et ai., 1984). Minimal effects seen after subchronic oral exposures to animals<br />

include diarrhea, altered renal function, <strong>and</strong> decreases in erythrocyte counts, hemogloblin, <strong>and</strong><br />

hematocrit @omingo et al., 1985; Zaporowska <strong>and</strong> Wasilewski, 1990). In humans, intestinal<br />

cramps <strong>and</strong> diarrhea may occur following subchronic oral exposures. These studies indicate that<br />

for subchronic <strong>and</strong> chronic oral exposures the primary targets are the digestive system, kidneys,<br />

<strong>and</strong> blood.<br />

Reference Doses (RfD) for chronic oral exposures are: 0.007 mg/kg/day for vanadium;<br />

0.009 mg/kg/day for vanadium pentoxide; 0.02 mgikg/day for vanadyl sulfate; <strong>and</strong> 0.001<br />

mg/kg/day for sodium metavanadate (U.S. EPA, 1987, 1991qb). The subchronic RfDs for these<br />

compounds are the same as the chronic RfDs, except for sodium metavanadate, which is 0.01<br />

mg/kg/day (US. EPA, 1987, 1991qb).<br />

Inhalation exposures to vanadium <strong>and</strong> vanadium compounds result primarily in adverse<br />

effects to the respiratory system (Sax, 1984; ATSDR, 1990). In laboratory studies, minimal<br />

effects (throat irritation <strong>and</strong> coughing) occurred after an 8-hr exposure to 0.1 mg V/m3 (Zen <strong>and</strong><br />

Berg, 1967). In studies on workers occupationally exposed to vanadium, the most common<br />

reported symptoms were: imtation of the respiratory tract, conjunctivitis, dermatitis, cough,<br />

bronchospasm, pulmonary congestion, <strong>and</strong> bronchitis (Symanski, 1939; Sjoberg, 1950,195 1,1955,<br />

1956; Vintinner et al., 1955; Lewis 1959; Tebrock <strong>and</strong> Machle, 1968; Roshchin, 1968; Kiviluoto<br />

1


et al., 1981b). Quantitative data are; however, insufficient to derive a subchronic or chronic<br />

inhalation Reference Concentration (RfC) for vanadium or vanadium compounds.<br />

There is little evidence that vanadium or vanadium compounds are reproductive toxins or<br />

teratogens. There is also no evidence that any vanadium compound is carcinogenic; however,<br />

very few adequate studies are available for evaluation. Vanadium has not been classified as to<br />

carcinogenicity by the U.S. EPA (1991a).<br />

2


1. INTRODUCTION<br />

Vanadium (V) is a metal that occurs in six oxidation states <strong>and</strong> numerous chemical forms.<br />

From a toxicological st<strong>and</strong>point, the most important inorganic vanadium compounds are vanadium<br />

pentoxide (V,O,), sodium metavanadate (NaVO,), sodium orthovanadate (N%VO,), vanadyl sulfate<br />

(VOSO,), <strong>and</strong> ammonium vanadate (-NI-I,VO,) (ATSDR, 1990).<br />

About 97% of the total production of vanadium is used as an alloying agent in steels <strong>and</strong><br />

non-ferrous metals such as copper, aluminum <strong>and</strong> titanium (ATSDR, 1990). Vanadium may also<br />

have applications as an intermetallic compound (V,Ga) for superconductor applications (Baroch,<br />

1983). Vanadium compounds are also used as catalysts or in chemical, ceramic or specialty<br />

applications (Rosenbaum, 1983). Minor uses include applications as color modifiers in mercuryvapor<br />

lamps, as driers in paints <strong>and</strong> varnish, <strong>and</strong> as corrosion inhibitors in flue-gas scrubbers<br />

(Rosenbaum, 1983).<br />

2. METABOLISM AND DISPOSITION<br />

2.1. ABSORPTION<br />

Absorption of vanadium into the body depends on the chemical composition of the compound<br />

containing the vanadium, as well as on the species exposed <strong>and</strong> the route of exposure. In humans,<br />

vanadium salts are poorly absorbed from the gastrointestinal tract (Curran <strong>and</strong> Burch, 1967).<br />

Estimates of the extent of gastrointestinal absorption of dietary vanadium are 0.5 to 2% (NRCC,<br />

1980; ICRP, 1960, 1981). In rats, gastrointestinal absorption of vanadium amounted to 2.6%<br />

following oral dosing with vanadium pentoxide or vanadium oxydichloride <strong>and</strong> 17.5% following<br />

oral dosing with sodium orthovanadate (Conklin et al., 1982; Sollenberger, 1981; Wiegmann et<br />

al., 1982).<br />

Because atmospheric vanadium would most likely be present in particulate form,<br />

deposition in the lungs will be greatest for particles in the submicron size range (Waters, 1977).<br />

In humans, a pulmonary retention value of 35% <strong>and</strong> a blood absorption value of 20% have been<br />

used to determine whole body burden of vanadium pavies <strong>and</strong> Bennett, 1983). ICRP (1960)<br />

estimated that 26% of soluble vanadium is absorbed through the lungs. Studies in rats have<br />

shown that intratracheally instilled vanadium compounds such as V,O, <strong>and</strong> VOCl, disappear<br />

rapidly from the lungs; Conklin et al. (1982) reported a 40% loss of V,O, in 1 hr <strong>and</strong> 90% after<br />

3 days; Oberg et al. (1978) reported a >50% loss of VOCl, in one day; Rhoads <strong>and</strong> S<strong>and</strong>ers<br />

(1985) reported a two-phase exponential loss model for V,O, with 72% of the dose cleared from<br />

the lungs in the first phase (tn = 11 min), 28% in the second phase (tH = 1.8 days), <strong>and</strong> Edel <strong>and</strong><br />

Sabbioni (1988) reported 80-85% clearance of tetravalent <strong>and</strong> pentavalent forms of vanadium<br />

within 3 hr.<br />

Although it has been shown that vanadium (as aqueous solutions of vanadate salts) can<br />

be absorbed through the skin of experimental animals, uptake of vanadium through skin contact<br />

with airborne particulate matter is considered to be only a minor source of human exposure (NRC,<br />

1974).<br />

3


2.2. DISTRIBUTION<br />

Absorbed vanadium is widely distributed in the body, but short-term localization occurs<br />

primarily in bone, kidneys, <strong>and</strong> liver, <strong>and</strong> possibly also in the spleen <strong>and</strong> lungs (Vouk, 1979;<br />

Roshchin et al., 1980; Parker et al., 1980; Sharma et al., 1980; Wiegmann et al., 1982).<br />

2.2.1. Human<br />

Concentrations of vanadium in human tissues have been reported to range from 0 to 12<br />

pg/g (Scanlon, 1975). On a wet weight basis, .concentrations of 19-140 ng/g in<br />

lung, <strong>4.</strong>5-40 ng/g in liver, 30 ng/g in brain, 0.45-10 ng/g in muscle, 400 ng/g in<br />

lymph nodes, 200 ng/g in testes, 2.6-3.3 ng/g in kidney, <strong>and</strong> 3.0-3.2 ng/g in<br />

thyroid have been reported (Hamilton et al., 1972/73; Byrne <strong>and</strong> Kosta, 1978). In<br />

a study of workers at a metallurgic plant, the median vanadium concentration in<br />

the blood was 2.9 pg/L (Thurauf et al., 1979). In a study of workers in a<br />

ferroalloy plant, vanadium blood levels averaged 20.2 nmovL in nonexposed or low<br />

exposure workers, <strong>and</strong> 35.7 nmol/L in moderate <strong>and</strong> high exposure workers (Gylseth<br />

et al., 1979). Kiviluoto et al. (1981a) reported vanadium levels of 393 f 223<br />

nmol/L in serum of workers exposed to WAS of 0.03-0.77 mg V/m3.<br />

2.2.2. Animal<br />

Acute oral exposure to vanadium compounds results in rapid tissue distribution,<br />

particularly to bone (ATSDR, 1990). Intermediate exposures result in low levels in bone, kidneys,<br />

liver <strong>and</strong> lungs (ATSDR, 1990). Long-term dietary studies conducted on dogs revealed limited<br />

accumulation of vanadium in femoral epiphyses (1.2 to 1.5 ug/g) following 2.5 years on a diet<br />

containing 10 or 100 ppm vanadium added as vanadium pentoxide (Stokinger et al. unpublished,<br />

as reported in Stokinger, 1981). Uptake of vanadium was greater in the bones of rats than in<br />

bones of dogs exposed to the same dietary levels of vanadium. Tissue deposition of vanadium<br />

has been reported to be greater following dietary exposure to ammonium metavanadate than to<br />

vanadium pentoxide (Stokinger et al., 1981).<br />

In rats, inhalation exposure to vanadium pentoxide (0.5 mg Vim3, 6 hr daily, for 6 mo)<br />

resulted in deposition of vanadium primarily in lungs (30 pg V/g), kidneys (0.8 pg V/g), <strong>and</strong><br />

spleen (0.6 vg V/g) (Stokinger et al., 1981). Intratracheal instillation of vanadium pentoxide in<br />

the same species resulted in rapid transport to the blood, liver, <strong>and</strong> bone (Conklin et al., 1982),<br />

<strong>and</strong> deposition of 12% of the dose in the skeleton (Rhoads <strong>and</strong> S<strong>and</strong>ers, 1985). Intramcheal<br />

studies with VOCl, also revealed rapid transport to blood, heart, spleen, liver, <strong>and</strong> kidneys, <strong>and</strong><br />

relatively large deposition in the skeleton of rats (Oberg et al., 1978).<br />

23. METABOLISM<br />

In the body, vanadium can undergo changes in oxidation state <strong>and</strong> it can also fonn<br />

chemical complexes with blood proteins (ATSDR, 1990). Harris et al. (1984) followed the<br />

distribution of vanadium in blood cells <strong>and</strong> plasma of dogs injected i.v. with radiolabeled vanadyl<br />

chloride (+4 oxidation state) or ammonium vanadate (+5 oxidation state). A significant fraction<br />

of the vanadium was associated with red blood cells <strong>and</strong> 77% of the plasma vanadium was<br />

eventually bound to serum transferrin. Harris et al. (1984) noted that there is an interconversion<br />

4


of vanadyl <strong>and</strong> vanadate in the blood, probably with oxidation of the vanadyl transferrin complex<br />

taking place in the plasma, <strong>and</strong> reduction of vanadate to vanadyl ions occurring in red blood cells.<br />

Transfemn-bound vanadium may be exhanged with liver femtin (Harris et al., 1984; Chasteen<br />

et al., 1986).<br />

2.<strong>4.</strong> EXCRETION<br />

2.<strong>4.</strong>1. Human<br />

Excretion of vanadium depends on the exposure route <strong>and</strong> chemical form of the vanadium.<br />

Following oral administration of sodium metavanadate (12.5 mg/d for 12 days), 87.6% of the dose<br />

was recovered in the feces <strong>and</strong> the remainder (12.4%) in the urine (Proescher et al., 1917). The<br />

ratio of vanadium in urine to that in the diet was reported to be about 0.13 (Tipton et al., 1969).<br />

Following inhalation exposures to vanadium compounds, urinary levels can be quite high.<br />

Workers occupationally exposed to vanadium dust (0.5 mg/m3) had detectable levels of vanadium<br />

in their urine for up to 2 weeks after the exposure ended (Zenz et al., 1962). Workers exposed<br />

to 0.1-0.19 mg/m’ vanadium in a manufacturing plant had significantly higher urinary levels of<br />

vanadium (20.6 pg/L) than non-exposed workers (2.7 pa) (Orris et al. 1983). Vanadium<br />

concentrations of 37.8 pgL, median value (Thurauf et al., 1979), 46.7 pg/L, mean value (Lewis,<br />

1959), <strong>and</strong> 200-500 pa, range (Gul’ko, 1956) have been reported for urine samples from other<br />

occupationally exposed workers. In a study of workers in a ferroalloy plant, vanadium<br />

concentrations in urine when adjusted for creatinine excretion, averaged 3.6 nmoVmmol creatinine<br />

for nonexposed workers <strong>and</strong> 15.2 nmoVmmol creatinine for exposed workers (Gylseth et al.,<br />

1979). Kiviluoto et al. (1981a) reported vanadium levels of 73 S O nmoVmmol of creatinine in<br />

urine of workers exposed to WAS of 0.03-0.77 mg V/m’.<br />

2.<strong>4.</strong>2. Animal<br />

Because vanadium is poorly absorbed through the gastrointestinal tract, a large percentage<br />

of an ingested dose will be excreted unabsorbed in the feces; Patterson et al. (1986) reported that<br />

in rats, 80% of a dose of ammonium metavanadate was excreted in the feces over a period of 6<br />

days. Of the absorbed vanadium, that fraction that is deposited in the liver is excreted rapidly,<br />

but that retained in bone is mobilized more slowly (Cum <strong>and</strong> Burch, 1967). Following<br />

inhalation exposure or intratracheal or intravenous injection, much of the absorbed vanadium is<br />

excreted in the urine (ATSDR, 1990). In rats, 3240% of an intratracheal or intravenous dose was<br />

excreted in the urine in the first 3-4 days (Sabbioni <strong>and</strong> Marafante, 1978; Conklin et al., 1982).<br />

Excretion of vanadium in the urine may continue for up to 6 mo after chronic exposure is<br />

discontinued (Curran, unpublished).<br />

3. NONCARCINOGENIC HEALTH EFFECTS<br />

The toxicity of vanadium depends on its physico-chemical state; particularly on its valence<br />

state <strong>and</strong> solubility. Pentavalent vanadium is generally considered to be the most toxic form,<br />

regardless of whether it functions as an anion or cation (NRC, 1974). Based on relative median<br />

lethal doses, pentavalent ammonium vanadate (NH,VO,) has been reported to be more than twice<br />

5


as toxic as trivalent vanadium trifluoride (VCl,) <strong>and</strong> more than 6 times as toxic as divalent<br />

vanadium diiodide (VI2). Similarly, the pentavalent vanadium pentoxide (V20,) was reported to<br />

be more than 5 times as toxic as the trivalent vanadium trioxide (V,O,). In in vitro tests on rabbit<br />

alveolar macrophages, V20, was more toxic than V20, which, in turn, was more toxic than VO,<br />

(Waters et al., 1974).<br />

3.1. ORAL EXPOSURES<br />

3.1.1. Acute Toxicity<br />

3.1.1.1. Human<br />

Vanadium pentoxide <strong>and</strong> sodium metavanadate have a toxicity rating of 5, equivalent to<br />

a probable lethal oral dose in humans of 5-50 mgkg (Gosselin et al., 1984). The elemental<br />

metallic form is considered to be non-toxic.<br />

3.1.1.2. Animal<br />

Animals exposed to acutely toxic doses of vanadium compounds exhibit immediate<br />

distress, a hemorrhagic exudate from the nose, marked diarrhea, hindlimb paralysis, labored<br />

respiration, <strong>and</strong> convulsions that can lead to death (Gosselin et d., 1984). Pathologic effects<br />

include dibe desquamative enteritis <strong>and</strong> congestion of lungs, liver, kidneys, adrenal cortex,<br />

brain, spinal cord, <strong>and</strong> bone m mw (Gosselin et al., 1984). Fatty degeneration of lungs <strong>and</strong> liver<br />

<strong>and</strong> focal hemorrhages in the lungs <strong>and</strong> adrenal cortex may also occur (Gosselin et al., 1984).<br />

High concentrations of vanadium compounds may cause irreversible damage to the kidneys<br />

(Kumar <strong>and</strong> Corder, 1980). Vanadium compounds have also beem reported to be vasoconstricting<br />

agents affecting blood vessels of the lungs, spleen, kidneys, <strong>and</strong> intestine (Proescher et al., 1917;<br />

Erdmann et al., 1984). LD,, values for sodium metavanadate administered by gavage to rats <strong>and</strong><br />

mice are 4 1 mg Vkg <strong>and</strong> 3 1 mg Vkg, respectively (ATSDR, 1990).<br />

3.1.2. Snbchronic Toxicity<br />

3.1.2.1. Human<br />

Volunteers given 0.47-1.3 mg V/kg/day orally as ammonium vanadyl tartrate for three<br />

months, developed intestinal cramping <strong>and</strong> diarrhea, but no hematological abnormalities, no<br />

changes in serum chemistry indicative of adverse liver effects (glutamic oxaloacetic transferase,<br />

cholesterol, triglyceride, or phospholipid levels), <strong>and</strong> no changes in urine chemistry indicative of<br />

adverse renal effects (albumin, hemoglobin, BUN, or formed elements) (Dimond et al., 1963).<br />

3.1.2.2. Animal<br />

Sodium metavanadate at a concentration of 50 ppm in the drinking water of rats for three<br />

months resulted in slight increases in blood urea <strong>and</strong> uric acid <strong>and</strong> mild histopathological lesions<br />

in kidneys (corticomedullar microhaemorrhagic foci) <strong>and</strong> spleen (hypertrophy <strong>and</strong> hyperplasia in<br />

the white pulp) (Doming0 et ai., 1985). The exposure was equivalent to a daily dose level of 6.56<br />

mg/kg/day or 2.74 mg V/kg/day. An exposure level of 10 ppm (1.32 mg/kg/day or 0.55 mg<br />

Vkg/day) was considered a NOAEL (US. EPA, 1987). The same compound added to the food<br />

6


of rats at levels of 25 <strong>and</strong> 50 ppm for 100 days had no effect on hemoglobin levels, but did cause<br />

dose-related decreases in growth as well as diarrhea at the highest dose (9.3 mg/kg/day) (Franke<br />

<strong>and</strong> Moxon, 1937). No other parameters of toxicity were evaluated.<br />

Sodium orthovanadate in the diet of rats for six months caused no changes in heart rate<br />

or blood pressure, but did induce vasoconstriction (Susic <strong>and</strong> Kentera, 1988).<br />

Ammonium vanadate (15 mg Vkg) in the diet of rats for 2 months resulted in increased<br />

right ventricular pressure <strong>and</strong> pulmonary hypertension (Susic <strong>and</strong> Kentera, 1986). The same<br />

compound administered in drinking water of rats (200 ppm vanadium) for two months resulted<br />

in decreased growth, decreased erythrocyte count, <strong>and</strong> reduced hemoglobin <strong>and</strong> hematocrit (Gorski<br />

<strong>and</strong> Zaporowska, 1983). Additional studies confirmed that vanadium in the drinking water of rats<br />

(300 ppm V for 4 weeks) caused a decrease in erythrocyte count <strong>and</strong> hemoglogin level<br />

(Zaporowska <strong>and</strong> Wasilewski, 1991). In addition, a relative increase in reticulocytes <strong>and</strong><br />

polychromatophilic erythrocytes indicated an effect on erythrocyte maturation (Zaporowska <strong>and</strong><br />

Wasilewski, 1991).<br />

Vanadium pentoxide in the diet of male rats for 103 days (25 ppm for 35 days followed<br />

by 100 ppm for 68 days or 50 ppm for 35 days followed by 150 ppm for 68 days) resulted in a<br />

decrease in cystine content in hair <strong>and</strong> significant reductions in RBC count <strong>and</strong> hemoglobin in the<br />

high-dose group (Mountain et al., 1953).<br />

3.13. Chronic Toxicity<br />

3.13.1. Human<br />

Information on the chronic oral toxicity of vanadium to humans was not available.<br />

3.133. Animal<br />

A vanadyl sulfate concentration of 5 pg/mL in drinking water, plus a vanadium level of<br />

3.2 pg/g in the diet (<strong>4.</strong>1 mg Vkg total) of mice, was reported to cause no adverse effects over<br />

a lifetime exposure period (Schroeder <strong>and</strong> Balassa, 1967). In similar lifetime studies, rats <strong>and</strong><br />

mice exhibited no adverse effects when exposed to 5 ppm vanadium (as vanadyl sulfate) in<br />

drinking water (Schroeder et ai., 1970; Schroeder <strong>and</strong> Mitchner, 1975). The estimated dose levels<br />

were 0.7 mg V/kg/day for rats <strong>and</strong> 0.9 mg Vkglday for mice.<br />

Vanadium pentoxide in the diet of rats at levels of 10 <strong>and</strong> 100 ppm for their entire<br />

lifetime resulted in no significant toxicological effects except for a reduction in hair cystine<br />

content (Stokinger et al., 1953). The exposure level of 10 ppm was equivalent to 0.9 mg/kg/day<br />

of vanadium pentoxide (US EPA, 1987).<br />

7


3.1.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

3.1.<strong>4.</strong>1. Human<br />

Information on the oral developmental <strong>and</strong> reproductive toxicity of vanadium to humans<br />

was not available.<br />

3.1.<strong>4.</strong>2. Animal<br />

Exposure of male <strong>and</strong> female rats before mating, <strong>and</strong> of female rats during gestation <strong>and</strong><br />

lactation to sodium metavanadate by gavage (maximum of 8.4 mg Vkglday) did not induce any<br />

adverse effects on fertility, reproduction, or parturition; however, doses of <strong>4.</strong>2 mg Vkglday<br />

significantly reduced pup size <strong>and</strong> body weight at birth <strong>and</strong> 21 days later (Doming0 et al., 1986).<br />

Gavage doses of 8.4 mg V/kg/day, as sodium metavanadate, to pregnant rats on gestation days<br />

6-14 did not result in embryolethality, teratogenicity or significant visceral or skeletal<br />

abnormalities; however, there was an increase in facial <strong>and</strong> dorsal hemorrhages (Patemain et aI.,<br />

1987). In a two-generation study, altered lung collagen metabolism was seen in fetuses of adult<br />

rats receiving 2.8 mg Vkg, as sodium metavanadate in drinking water (Kowalska et al., 1988).<br />

3.1.5. Reference Dose<br />

Separate subchronic <strong>and</strong> chronic oral reference doses have been derived for vanadium,<br />

vanadium pentoxide, vanadyl sulfate, <strong>and</strong> sodium metavanadate (US. EPA, 1987, 1991a).<br />

3.1.5.1. Subchronic<br />

Vanadium<br />

-<br />

ORAL RfD:<br />

0.007 mg/kg/day (U.S. EPA, 1991a)<br />

UNCERTAMTY FACTOR: 100<br />

MODIFYlNG FACTOR NA<br />

NOAEL:<br />

0.7 mg/kg/day (rat), drinking water, lifetime<br />

PRINCIPAL STUDY: Schrocder et al., 1970<br />

COMMENTS: The NOAEL is derived from a lifetime single exposure level study in<br />

which rats were exposed to 5 ppm V, as vanadyl sulfate, in drinking water. The only<br />

reported effects were minor changes in serum chemistry. The Uncertainty Factor of 100<br />

is the product of a 10-fold uncertainty in extrapolating fiom laboratory animals to humans<br />

<strong>and</strong> a IO-fold uncertainty to protect sensitive individuals.<br />

Vanadium Dentoxide<br />

ORAL RfD:<br />

0.009 mg/kg/day (U.S. EPA, 1991b)<br />

UNCERTAMn FACTOR 100<br />

MODIFYING FACTOR: 1<br />

NOAEL:<br />

0.89 mgkglday<br />

8


PRINCIPAL STUDY: Stokinger et al., 1953<br />

COMMENTS: The NOAEL is derived from a study in which rats received 10 or 100<br />

pprn dietary vanadium pentoxide for 2.5 yr. The only change reported was a decrease in<br />

cystine levels in the hair of the exposed animals. The 10 ppm level was selected as a<br />

NOAEL. The Uncertainty Factor of 100 is the product of a 10-fold uncertainty in<br />

extrapolating from laboratory animals to humans <strong>and</strong> a 10-fold uncertainty to protect<br />

sensitive individuals.<br />

Vanadvl sulfate<br />

ORAL RfD:<br />

UNCERTAINTY FACTOR<br />

0.02 mg/kg/day (U.S. EPA, 1991a)<br />

100<br />

MODIFYING FACTOR: NA<br />

NOAEL:<br />

2.24 mg/kg/day<br />

PRINCIPAL STUDY: Schroeder et al., 1970, as reported in U.S. EPA, 1987<br />

COMMENTS: The NOAEL is derived from a single exposure level study in which rats<br />

were exposed to 5 pprn V, as vanadyl sulfate, in drinking water for 2.5 yr for a lifetime.<br />

The only reported effects were minor changes in serum chemistry. The Uncertainty<br />

Factor of 100 is the product of a 10-fold uncertainty in extrapolating from laboratory<br />

animals to humans <strong>and</strong> a 10-fold uncertainty to protect sensitive individuals.<br />

Sodium metavanadate<br />

ORAL RfD:<br />

0.01 mg/lcg/day (U.S. EPA, 1987, 1991a)<br />

UNCERTAINTY FACTOR 100<br />

MODIFYING FACTOR: NA<br />

NOAEL:<br />

1.32 mg/kg/day<br />

PRINCIPAL STUDY: Doming0 et al., 1985<br />

COMMENTS: The NOAEL is derived from a study in which rats were given 0, 5, 10<br />

<strong>and</strong> 50 ppm sodium metavanadate, in drinking water for 3 months. Impaired kidney<br />

function was seen at 50 ppm, <strong>and</strong> 10 ppm was considered a NOAEL. The Uncertainty<br />

Factor of 100 is the product of a 10-fold uncertainty in extrapolating from laboratory<br />

animals to humans <strong>and</strong> a IO-fold uncertainty to protect sensitive individuals.<br />

3.1.5.2. Chronic<br />

Vanad in m<br />

ORAL RfD:<br />

0.007 mg/kg/day (U.S. EPA, 1987, 1991a)<br />

UNCERTAINTY FACTOR. 100<br />

MODIFYING FACTOR: NA<br />

NOAEL:<br />

0.7 mg/kg/day (rat), drinking water, lifetime<br />

9


PRINCIPAL STUDY: Schroeder et al., 1970<br />

COMMENTS: The NOAEL is derived from a lifetime single exposure level study in<br />

which rats were exposed to 5 ppm V, as vanadyl sulfate, in drinking water. The only<br />

reported effects were minor changes in serum chemistry. The Uncertainty Factor of 100<br />

is the product of a 10-fold uncertainty in extrapolating from laboratory animals to humans<br />

<strong>and</strong> a 1 O-fold uncertainty to protect sensitive individuals.<br />

Vanadium Dentoxide<br />

ORAL RfD:<br />

0.009 mg/kg/day (U.S. EPA, 1987, 1991b)<br />

UNCERTAINTY FACTOR: 100<br />

MODIFYING FACTOR: 1<br />

NOAEL:<br />

0.89 mglkglday<br />

CONFIDENCE:<br />

Study:<br />

LOW<br />

Data Base: LOW<br />

RfD: Low<br />

VERIFICATION DATE: 02/26/86<br />

PRINCIPAL STUDY: Stokinger et al., 1953<br />

COMMENTS: The NOAEL is derived from a study in which rats received 10 or 100<br />

ppm dietary vanadium pentoxide for 2.5 yr. The only change reported was a decrease in<br />

cystine levels in the hair of the exposed animals. The 10 ppm level was selected as a<br />

NOAEL. The Uncertainty Factor of 100 is the product of a I0-fold uncertainty in<br />

extrapolating from laboratory animals to humans <strong>and</strong> a 10-fold uncertainty to protect<br />

sensitive individuals.<br />

Vanadvl sulfate<br />

ORAL RfD:<br />

UNCERTAINTY FACTOR:<br />

0.02 mg/kg/day (U.S. EPA, 1987, 1991a)<br />

100<br />

MODIFYING FACTOR: NA<br />

NOAEL:<br />

224 mg/kg/day<br />

PRINCIPAL STUDY: Schroeder et al., 1970<br />

COMMENTS: The NOAEL is derived from a single exposure level study in which rats<br />

were exposed to 5 ppm V, as vanadyl sulfate, in drinking water for 2.5 yr for a lifetime.<br />

The only reported effects were minor changes in serum chemistry. The Uncertainty<br />

Factor of 100 is the product of a 10-fold uncertainty in extmpolating fiom laboratory<br />

animals to humans <strong>and</strong> a 10-fold uncertainty to protect sensitive individuals.<br />

Sodium metavanadate<br />

ORAL IUD: 0.001 rngntglday (US. EPA, 1987, 1991a)<br />

10


UNCERTAINTY FACTOR: 1000<br />

MODIFYING FACTOR: NA<br />

NOAEL:<br />

1.32 mg/kg/day<br />

PRINCIPAL STUDY: Doming0 et al., 1985<br />

COMMENTS: The NOAEL is derived from a study in which rats were given 0, 5, 10<br />

<strong>and</strong> 50 ppm sodium metavanadate, in drinking water for 3 months. Impaired kidney<br />

function was seen at 50 ppm, <strong>and</strong> 10 ppm was considered a NOAEL. The Uncertainty<br />

Factor of 100 is the product of a 10-fold uncertainty in extrapolating from laboratory<br />

animals to humans, a 10-fold uncertainty to extrapolate from a subchronic to chronic<br />

exposure, <strong>and</strong> a 1 O-fold uncertainty to protect sensitive individuals.<br />

3.2. INHALATION EXPOSURES<br />

3.2.1. Acute Toxicity<br />

3.2.1.1. Human<br />

In studies on humans, the acute toxic effects of inhaled vanadium were found to be limited<br />

to eye <strong>and</strong> respiratory tract irritation; there being no evidence of disturbances to the cardiovascular<br />

system, gastrointestinal tract, kidneys, blood, or CNS (Sax, 1984; ATSDR, 1990). Typical<br />

symptoms include coughing, wheezing, rhinonhea, sore throat <strong>and</strong> chest pain (ATSDR, 1990).<br />

There is usually a latency period of 1-6 days before effects appear (Lagerkvist et al., 1986). In<br />

severe cases bronchospasms <strong>and</strong> bronchitis, accompanied by wheezing <strong>and</strong> dyspnea may occur,<br />

<strong>and</strong> bronchopneumonia may result from very high exposures (Lagerkvist et al., 1986)<br />

NOSH (1977) reported that respiratory irritation from inhalation of vanadium-containing<br />

dusts or fumes occurred at concentrations ranging from 0.1 to 85 mg/m’. At a concentration of<br />

about 1.0 mg/m3, vanadium dust caused coughing <strong>and</strong> throat irritation (Zenz <strong>and</strong> Berg, 1967).<br />

At a level of 0.1 mg/m3, an 8-hr exposure to vanadium pentoxide (0.06 mg V/m’) caused only<br />

mucus formation which was cleared by slight coughing that lasted 3-4 days (Zenz <strong>and</strong> Berg,<br />

1967). A level of 0.06 mg V/m’ was considered a NOAEL for acute exposures by ATSDR<br />

( 1990).<br />

Lees (1980) reported that workers occupationally exposed (several hours per day for eight<br />

days) to vanadium-containing dust (as a component in fuel oil ash) exhibited significant decreases<br />

in several lung function tests including forced vital capacity, forced expiratory volume, <strong>and</strong> forced<br />

mid-expiratory flow. Lung functions returned to normal several weeks after the exposures ended.<br />

There is some evidence that workers exposed to vanadium compounds become sensitized<br />

such that there is increased severity <strong>and</strong> more rapid onset of respiratory symptoms after multiple<br />

exposures (Zenz <strong>and</strong> Berg, 1967; Zenz et al., 1962; Roshchin, 1968).<br />

3.2.1.2. Animal<br />

Two of four rabbits died following 7 hr exposure to 114 rng V/m3, as V,O,; the exposures<br />

resulted in tracheitis, pulmonary edema <strong>and</strong> bronchopneumonia (Sjoberg, 1950).<br />

11


Monkeys exposed to 2.8 mg V/m3, as V,O,, for 6 hr developed increased pulmonary<br />

resistance <strong>and</strong> had increased numbers of polymorphonuclear leucocytes in bronchoalveolar lavage<br />

fluid (Knecht et al., 1985). Exposure of rats to bismuth orthovanadate 6 hdday for 2 weeks<br />

resulted in increases in lung weight <strong>and</strong> increased accumulation of alveolar macrophages, lung<br />

lipids <strong>and</strong> type I1 epithelial cells (Lee <strong>and</strong> Gillies, 1986). Rabbits exposed to vanadium pentoxide<br />

dust showed no evidence of adverse effects on cardiovasular or gastrointestinal systems, blood,<br />

spleen or brain; but they did exhibit conjunctivitis <strong>and</strong> some degree of fatty degeneration in the<br />

liver <strong>and</strong> kidneys (Sjoberg, 1950).<br />

3.2.2. Subchronic Toxicity<br />

3.2.2.1. Human<br />

Information on the subchronic inhalation toxicity of vanadium <strong>and</strong> vanadium compounds to<br />

humans was not available.<br />

3.2.2.2. Animal<br />

Repeated inhalation of vanadium pentoxide (20-40 mg/m3, 1 hr/day, for several months) by<br />

rabbits resulted in chronic rhinitis <strong>and</strong> tracheitis, emphysema, patches of lung atelectasia, <strong>and</strong><br />

bronchopneumonia (Sjoberg, 1950). Exposure of rabbits to vanadium trioxide aerosol (40-75<br />

mg/m3, 2 hdday, 9-12 months) resulted in sneezing, nasal discharge, dyspnea <strong>and</strong> tachypnea <strong>and</strong><br />

sometimes bronchial asthma (Roshchin et al., 1964; Roshchin, 1967). Similar effects were seen<br />

in rabbits exposed under the same conditions to vanadium pentoxide concentrations of 8-1 8 mg/m’<br />

or to vanadium carbide levels of 40-80 mg/m’, <strong>and</strong> also in rats exposed to vanadium pentoxide<br />

condensation aerosol (3-5 mg/m’, 2 hr/day, every second day for 3 months) <strong>and</strong> to vanadium<br />

pentoxide dust (10-40 mg/m3, 1 hr/day, for 4 months).<br />

Stokinger et al. (1953) reported that a concentration of 0.5 mg V/m3 as vanadium pentoxide<br />

dust, 6 hr/day for 6 months caused no adverse effects in rats, dogs, guinea pigs, <strong>and</strong> rabbits.<br />

Pazynich (1966) reported that albino rats exposed continuously for 70 days to 0.2 mg/m’ of<br />

vanadium pentoxide aerosol exhibited altered motor chronaxy of antagonistic muscles, decreased<br />

blood cholinesterase activity, reduced serum protein levels, including O-globulins, reduced<br />

oxyhemoglobin, <strong>and</strong> also pathological changes in the lungs (congestion, hemorrhages, bronchitis),<br />

the liver (central vein congestion, hemomhages, infihtes <strong>and</strong> degeneration), the kidneys<br />

(degeneration <strong>and</strong> necrosis of the epithelial cells of the convoluted tubules), <strong>and</strong> in the myocardial<br />

blood vessels (focal perivascular hemomhages). No adverse effects were seen in rats exposed to<br />

0.002 mg/m’.<br />

Sugiura (1978) exposed rats <strong>and</strong> mice to 1-2 mg/m3 of vanadium pentoxide 6 hdday for 3<br />

months. At concentrations up to 0.4 mg/m3, no adverse effects were seen. At higher<br />

concentrations, the rats had decreased growth rates <strong>and</strong> enlarged lungs; whereas. mice had<br />

thickened alvelolar walls <strong>and</strong> congested lungs.<br />

3.23. Chronic Toxicity<br />

3.23.1. Human<br />

.<br />

12


Data on the effects of long term inhalation exposure to vanadium have been derived mainly<br />

from studies of workers occupationally exposed to vanadium pentoxide. The most frequently<br />

reported effects were imtation to the respiratory tract, conjunctivitis <strong>and</strong> dermatitis. Cough,<br />

bronchospasm, pulmonary congestion, <strong>and</strong> bronchitis are the most common symptoms, but rhinitis,<br />

pharyngitis, pneumosclerosis, asthma, <strong>and</strong> dyspnea have also been reported (Symanski, 1939;<br />

Sjoberg, 1950; Vintinner et ai., 1955; Lewis 1959; Tebrock <strong>and</strong> Machle, 1968; Kiviluoto et al.,<br />

1981b; Sjoberg, 1956; Sjoberg, 1951, 1955; Roshchin, 1968). There is no clear evidence that<br />

chronic lung disease (emphysema, pneumoconiosis, fibrosis) results from long term exposure to<br />

vanadium compounds (NIOSH, 1977); however, it has been noted that cases of bronchial asthma<br />

<strong>and</strong> bronchitis have been reported with “sufficient fiequency to warrant concern for decreased<br />

ventilatory function, <strong>and</strong> possibly, a progressively decreasing ventilatory function” (NIOSH, 1977).<br />

Bronchiopneumonia may possibly be a secondary complication caused by the effects of vanadium<br />

on respiratory mucosa (Sjoberg, 1955).<br />

Evaluation of dose-response relationships from occupational exposure studies is difficult<br />

because of fluctuations in concentrations, lack of continuous monitoring, <strong>and</strong> potential exposure<br />

through routes other than inhalation. Generally, occupational exposures occur over wide<br />

concentration ranges, Le., 0.05-5.58 mg/m’ (Sjoberg, 1950), 0.02-3.2 mg V/m3 (Tebrock <strong>and</strong><br />

Machle, 1968), 0.004-2.116 mg V/m’ in ore dust <strong>and</strong> 0.018-58.82 mg V/m3 in vanadium<br />

pentoxide dust (Vintenner et ai., 1955), <strong>and</strong> 0.012-2.3 mg V/m3 (time-weighted average exposures)<br />

for smelter workers (Kiviluoto et al., 1981a). Therefore, minimum effect levels are difficult to<br />

quantify. The lowest exposure levels at which there was an increased incidence of respiratory<br />

distress were those in the study of Lewis (1959) in which workers were exposed to vanadium<br />

pentoxide for an average duration of 2.5 years. In this study, vanadium concentrations in seven<br />

air samples ranged from 0.018-0.925 mg Vim’, but five of the measurements were 0.1-0.38<br />

mg/rp’. In another study, vanadium processing workers exposed to 0.1-0.3 mg/m3 had lowered<br />

serum cholesterol levels but no other adverse effects (Vintinner et al., 1955).<br />

Most investigators have reported that long tenn occcupational exposure to vanadium<br />

compounds did not result in any gastrointestinal symptoms or adverse effects to the hemopoietic<br />

system, kidneys, liver, or nervous sytem (Symanski, 1939; Sjoberg, 1956: Kiviluoto et al., 1981%<br />

198 1 b). However, some workers chronically exposed to vanadium dust have reported dizziness,<br />

depression, headache, or tremors of the fingers <strong>and</strong> a ms (Levy et al., 1984; Vintinner et al., 1955).<br />

From the available pre-1974 clinical, experimental, <strong>and</strong> occupational exposure data, IIEQ<br />

(1974) concluded that clinical signs of severe chronic intoxication (hemoptysis, pneumonia,<br />

hacking cough, chest pain, lesions of the nose, <strong>and</strong> des) occurred at vanadium pentoxide air<br />

concentrations of around 1000 pg/m’; clinical signs of subtle chronic intoxication (green tongue,<br />

cough, vascularization of the cornea, conjunctivitis, colic, respiratory tract imtation, mucus, <strong>and</strong><br />

rhinorrhea) occurred at vanadium pentoxide concentrations of about 100 pg/m3 or less, <strong>and</strong><br />

subclinical chronic intoxication resulting in metabolic disorders occurred at about 1-20 pg/m’.<br />

IIEQ (1974) considered reductions in body cystine levels (as measured in fingernails) to be a<br />

major subclinical effect of vanadium exposure. Other biochemical effects that may occur without<br />

clinical signs of toxicity include reductions in serum cholesterol, decreases in coenzyme A in liver<br />

<strong>and</strong> in coenzyme Q in mitochrondria <strong>and</strong> changes in activity of Na+-, K+-ATPase, Ca-ATPase,<br />

adenylate kinase, ribonuclease, phosphofiuctokinase, <strong>and</strong> glucoss6-phosphatase) (Lagerhist et<br />

al., 1986).<br />

13


3.23.2. Animal<br />

Animal data indicate that chronic toxic effects on the respiratory system are similar to those<br />

seen in acute exposures. In addition, when the dose is sufficiently high or the exposure<br />

sufficiently long, systemic effects such as edema, hemorrhaging, <strong>and</strong> lesions can occur in the<br />

lungs, liver, <strong>and</strong> kidney.<br />

Rabbits chronically exposed to vanadium pentoxide dust showed no evidence of adverse<br />

effects on the cardiovasular or gastrointestinal systems, blood, spleen or brain; but they did<br />

develop conjunctivitis <strong>and</strong> had some fatty degeneration in the liver <strong>and</strong> kidneys (Sjoberg, 1950).<br />

Fatty changes with partial cell necrosis were seen in the liver <strong>and</strong> kidneys of rats <strong>and</strong> rabbits<br />

exposed to vanadium pentoxide, trioxide <strong>and</strong> chloride (10-70 mg/m’, 2 hr/day, 9-12 mo)<br />

(Roshchin, 1968).<br />

3.2.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

3.2.<strong>4.</strong>1. Human<br />

Infoxmation on the developmental <strong>and</strong> reproductive toxicity of vanadium <strong>and</strong> vanadium<br />

compounds following inhalation exposure was not available.<br />

3.2.<strong>4.</strong>2. Animal<br />

Information on the developmental <strong>and</strong> reproductive toxicity of vanadium <strong>and</strong> vanadium<br />

compounds following inhalation exposure was not available.<br />

3.2.5. Reference Concentration<br />

A subchronic or chronic reference concentration for vanadium is not available at this time<br />

(U.S. EPA, 1991b).<br />

14


33. OTHER ROUTES OF EXPOSURE<br />

33.1. Acute Toxicity<br />

33.1.1. Human<br />

Stokinger et al. (1953) reported that a 10% solution of sodium metavanadate is a primary<br />

irritant to human skin. Saturated solutions of ammonium metavanadate (0.5%) <strong>and</strong> vanadium<br />

pentoxide (0.8% solution) did not irritate the skin. Sjoberg (1951) reported that several workers<br />

occupationally exposed to vanadium developed what appeared to be a contact dermatitis <strong>and</strong> that<br />

in one case, skin patch tests produced eczematous lesions indicative of an allergic reaction.<br />

Proescher et al. (1917) estimated that 30 mg of sodium tetravanadate, injected intravenously,<br />

would be a fatal dose to a 70-kg man. Signs <strong>and</strong> symptoms of toxicity following a single<br />

intravenous injection of 100 mg vanadium pentoxide include nausea, vomiting, salivation,<br />

lacrimation, loss of pulse, <strong>and</strong> albumin <strong>and</strong> cylindrical casts in urine (Lagerkvist et al., 1986).<br />

33.1.2. Animal<br />

Administered to the eye of a rabbit, sodium orthovanadate caused a significant fall in<br />

intraocular pressure (Mittrag et al., 1984). The LD,, values for sodium metavanadate injected<br />

intrperitoneally is 0.1 1 mg Vkg in rats <strong>and</strong> 0.13 mg Vkg in mice (Chanh, 1965).<br />

33.2. Subchronic Toxicity<br />

333.1. Human<br />

Information on the subchronic toxicity of vanadium or vanadium compounds to humans by<br />

other routes of exposure was not available.<br />

333.2. Animal<br />

Fatty changes were seen in the liver of rats following subcutaneous injections of ammonium<br />

vanadate (1 mg Vkglday, for 30 days) (Kaku et al., 1971).<br />

333. Chronic Toxicity<br />

Information on the chronic toxicity of vanadium <strong>and</strong> vanadium compounds to humans or<br />

animals by other routes of exposure was not available.<br />

33.<strong>4.</strong> Developmental <strong>and</strong> Reproductive Toxicity<br />

33.<strong>4.</strong>1. Human<br />

Information on the developmental <strong>and</strong> reproductive toxicity of vanadium or vanadium<br />

compounds to humans by other routes of exposure was not available.<br />

33.<strong>4.</strong>2. Animal<br />

1s


There is no clear evidence that vanadium compounds are teratogenic to laboratory animals;<br />

however, in one study, exposure of pregnant Syrian golden hamsters to ammonium metavanadate<br />

(0,0.47, 1.88, or 3.75 mg/kg injected i.p. on gestation days 5 through 10) resulted in a significant<br />

increase in fetal skeletal abnormalities (micrognathia, supernumerary ribs, <strong>and</strong> alternations in<br />

sternebra1 ossification) (Carlton et al., 1982). The number of malformed offspring was small, <strong>and</strong><br />

there was no clear-cut dose/response relationship, thus, a definite assessment of teratogenicity was<br />

not possible. In this same study, there was also a decrease in the male-female fetal sex ratio, but<br />

no external <strong>and</strong> soft tissue anomalies. A delay in fetal skeletal ossification, but no implantation<br />

or teratogenic effects occurred in the offspring of mice injected with 0.15 mL of a 1 mM solution<br />

of vanadium pentoxide on day 8 of pregnancy (Wide, 1984). Exposure of female rats to 0.85<br />

mgkg of sodium metavanadate by subcutaneous injection on the 4th day of pregnancy resulted<br />

in an increase in preimplantation embryo mortality, but no teratogenic effects (Roshchin <strong>and</strong><br />

Kazimov, 1980; Roshchin et al., 1980). However, in male rats dosed intraperitoneally (0.85<br />

mg/kg/day of sodium metavanadate for 20 days), spermatogenesis was altered, sperm motility <strong>and</strong><br />

osmotic resistance was reduced, the number of dead spermatozoa increased, <strong>and</strong> morphological<br />

damage to the seminiferous epithelium was observed. There was also a decrease in fertilization<br />

of females mated to exposed males <strong>and</strong> an increase in preimplantation embryo mortality.<br />

In tests on pregnant rats, Hackett <strong>and</strong> Kelman (1983) found that vanadium accumulates in<br />

the placenta, preferentially concentrating in the membranes rather than in the fetus itself.<br />

3.<strong>4.</strong> TARGET ORGAIWCRITICAL EFFECTS<br />

Minimal effect levels <strong>and</strong> target organs may vary with the chemical form <strong>and</strong> oxidation state<br />

of the vanadium.<br />

3.<strong>4.</strong>1. Oral Exposures<br />

3.<strong>4.</strong>1.1. Primary Target Organs<br />

1. Gastrointestinal system: Diadea has been reported in humans <strong>and</strong> animals receiving<br />

ammonium vanadyl tamate <strong>and</strong> sodium metavanadate, respectively.<br />

2. Kidney: Slight changes in renal function as suggested by increases in blood urea nitrogen<br />

<strong>and</strong> uric acid have been reported in animals exposed to sodium metavanadate.<br />

3. Blood: Decreases in erythrocytes, hemogloblin, or hematocrit have been reported in<br />

animals receiving ammonium vanadate or vanadium pentoxide.<br />

3.<strong>4.</strong>1.2. Other Target Organs<br />

Other effects seen in animals chronically exposed to vanadium compounds include reduced<br />

growth rates in adults <strong>and</strong> fetuses (sodium metavanadate, ammonium vanadate), vasoconstriction<br />

(sodium orthovanadate), <strong>and</strong> facial <strong>and</strong> dorsal hemorrhages <strong>and</strong> altered lung collagen metabolism<br />

in fetuses (sodium metavanadatc).<br />

3.<strong>4.</strong>2. Inhalation Exposures<br />

16


3.<strong>4.</strong>2.1. Primary Target Organs<br />

Respiratory system: Exposure to vanadium dusts can result in respiratory tract irritation.<br />

Bronchospasms <strong>and</strong> bronchitis, accompanied by wheezing <strong>and</strong> dysnea may occur, <strong>and</strong><br />

bronchopneumonia may result from very high <strong>and</strong> prolonged exposures. The mechanism of<br />

vanadium’s effect on the respiratory system is similar to that of other metals. Vanadium<br />

damages alveolar macrophages <strong>and</strong> affects lung clearance rates.<br />

3.<strong>4.</strong>2.2. Other Target Organs<br />

1. Nervous System: Some workers chronically exposed to vanadium dust reported dizziness,<br />

depression, headache, or tremors of the fingers <strong>and</strong> arms.<br />

2. Liver <strong>and</strong> Kidney: Limited animal data suggest that chronic exposure may lead to liver<br />

<strong>and</strong> kidney abnormalities.<br />

Other effects seen in animals exposed to vanadium compounds include perivascular<br />

hemorrhages in myowdial vessels, altered muscle motor chronaxie, <strong>and</strong> changes in blood<br />

chemistry (vanadium pentoxide).<br />

<strong>4.</strong> CARCINOGENICITY<br />

<strong>4.</strong>1. ORAL EXPOSURES<br />

<strong>4.</strong>1.1. Human<br />

Citing a progress report submitted to the National Cancer Institute, Sax (1981) lists the<br />

carcinogenicity of vanadium as questionable (no other data available).<br />

<strong>4.</strong>1.2. Animal<br />

Kanisawa <strong>and</strong> Schroeder (1967) evaluated the carcinogenicity of vanadium in lifetime studies<br />

on Swiss mice. The test animals were given vanadyl sulfate in their drinking water (5 pg/mL<br />

water) <strong>and</strong> in their diet (3.2 pg/g feed) from the time they were 20-22 days old until death.<br />

NOSH (1 977) calculated that the total annual intake of vanadium in each animal would amount<br />

to 19.8 mg/100 g of body weight. There were no significant differences in the incidences of<br />

tumors (heart, lungs, kidneys, liver, spleen, <strong>and</strong> other organs were examined) between the exposed<br />

animals <strong>and</strong> the controls. Other studies using the same experimental procedures on both rats <strong>and</strong><br />

mice also indicated that vanadium was not carcinogenic at a level of 5 pg vanadyl sulfate per mL<br />

of drinking water over a lifetime exposure (Schroeder <strong>and</strong> Balassa, 1967; Schroeder et al., 1970;<br />

Schroeder <strong>and</strong> Mitchner, 1975).<br />

Stoner et al. (1976) evaluated the potential of various metallic compounds to induce lung<br />

adenomas in strain A mice. In one test group, mice were given 24 i.p. injections of vanadium<br />

(In) 2,4pentanedione (total dose, 120, 60, or 24 mg/kg) over a 30-week period. The incidence<br />

of lung tumors was not significantly different from that of the controls.<br />

17


Several studies have suggested that vanadium exhibits anti-carcinogenic activity. Thompson<br />

et al. (1984) reported that vanadyl sulfate inhibited murine mammary carcinogenesis by 1-<br />

methyl-l-nitrosourea in rats, <strong>and</strong> Djordjevic <strong>and</strong> Wampler (1985) reported that several vanadium<br />

complexes have antitumor activity against L 12 10 murine leukemia.<br />

<strong>4.</strong>2. INHALATION EXPOSURES<br />

<strong>4.</strong>2.1. Human<br />

In a statistical study relating concentrations of air pollutants to mortality indices in Great<br />

Britain, Stocks (1960) found that together with arsenic <strong>and</strong> zinc, vanadium showed a weak<br />

correlation with lung cancer, <strong>and</strong> together with beryllium <strong>and</strong> molybdenum, showed correlations<br />

with other cancers in males. In a similar study conducted by Hickey et al. (1967), there was little<br />

correlation between lung cancer mortality <strong>and</strong> vanadium levels.<br />

<strong>4.</strong>2.2. Animal<br />

Information on the carcinogenicity of vanadium to animals after inhalation exposure was not<br />

available.<br />

43. OTHER ROUTES OF EXPOSURE<br />

Information on the carcinogenicity of vanadium to humans or animals from other routes of<br />

exposure was not available.<br />

<strong>4.</strong><strong>4.</strong> EPA WEIGHT-OF-EVIDENCE<br />

The limited weight of evidence suggests that vanadium <strong>and</strong> vanadium compounds are not<br />

carcinogenic; however, few vanadium compounds have been adequately tested. Vanadium has<br />

not been classified as to carcinogenicity by the EPA. The NTP has approved vanadium pentoxide<br />

for carcinogenicity testing, but the results are yet not available (U.S. EPA, 1991b).<br />

<strong>4.</strong>5. CARCINOGENICITY SLOPE FACTORS<br />

Calculation of slope factors is not possible due to inadequate data.<br />

18


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26


Appendix L.9<br />

Historical Dataset


THIS PAGE LEFT BLANK


Appendix L.9 Historical Dataset<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

WAG 1, S WU 38, MW327<br />

1,l ,l-Trichloroethane<br />

1,l ,l-Trichloroethane<br />

1,1,2-Trichloroethane<br />

1.1.2-Trichloroethane<br />

1,l -Dichloroethane<br />

1 ,l-Dichloroethane<br />

1,l -Dichloroethene<br />

1,l -Dichloroethene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

Alkalinity<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic, Dissohred<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium. Dissolved<br />

Bromodichlaromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

Cobalt<br />

Cobalt, Dissolved<br />

Capper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dssotved Oxygen<br />

Dissolved Solids<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

Fluoride<br />

Grass Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

tron<br />

Iron. Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury, Dissolved<br />

Nickel<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium, Dissolved<br />

Radon 222<br />

Radon 222<br />

Selenium<br />

71-55-6<br />

71 -55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

47 1-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71 -43-2<br />

7440-41-7<br />

7440-41-7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

67-66-3<br />

67-66-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

DMI<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41-4<br />

100-41-4<br />

16984-40-8<br />

16984-48-8<br />

12587-46-1<br />

12587-46-1<br />

12587-47-2<br />

12587-47-2<br />

7439-89-6<br />

7439 - 89 - 6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

744062-0<br />

7440-02-0<br />

NITRATEASNIT<br />

N ITRATEASN IT<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

RN222<br />

778249-2<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5513-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MARl995<br />

07MARl995<br />

07MAR1995<br />

07MARl995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MARl995<br />

26JUNl995<br />

07MAR1995<br />

07MAR 1995<br />

07MAR1995<br />

07MARl995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MARl995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MARl995<br />

07MAR1995<br />

07MAR1995<br />

O7MAR 1995<br />

07MARl995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MARl995<br />

26JUNl995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MARI 995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

Page 1 of 176<br />

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uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

m9fl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mg1L<br />

uglL<br />

ug1L<br />

mglL<br />

rngR<br />

WlL<br />

mglL<br />

uglL<br />

uglL<br />

wnmgfl<br />

ug1L<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

wlL<br />

mg/L<br />

Feet<br />

WlL<br />

mglL<br />

mgfl<br />

ug/L<br />

ugfl<br />

mglL<br />

rnglL<br />

pCilL<br />

pCiR<br />

pCVL<br />

pciR<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

w5<br />

rng/L<br />

mglL<br />

mgk<br />

mglL<br />

wfl<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

pCilL<br />

pCi<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Selenium, Dissolved 7782-49-2 5573-95 07MAR1995 WG O.OOE+OO a 0501- mg1L<br />

Silica<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Sulfate<br />

Technetium-99<br />

Technetium99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon '<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-l,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc, Dissolved<br />

cis-I .2-dichloroethene<br />

cis-I ,2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 1 SWU 38. MW28<br />

1.1 .I-Trichloroethane<br />

1 ,I,I-Trichloroethane<br />

1 .I,2-Trichloroethane<br />

1 .I.2-Trichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroethene<br />

I .2-Dichloroethane<br />

1,2-Dchloroethane<br />

Alkalinity<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic. Dissolved<br />

Barium<br />

7631-86-9<br />

7631-86-9<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

12143-45-2<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

127-18-4<br />

127-18-4<br />

108-88-3<br />

108-88-3<br />

7440-44-0<br />

744044-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

744044-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

SO278<br />

SO278<br />

7440-61-1<br />

7440-61-1<br />

DIS U<br />

DIS U<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

156-59-2<br />

156-59-2<br />

SO296<br />

so296<br />

so296<br />

so296<br />

7 1 -55-6<br />

7 1-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

7535-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

5573-95<br />

6 6 9 6 - 9 5<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

5574-95<br />

5575-95<br />

5576-95<br />

6696-95<br />

6697-95<br />

6698-95<br />

6699-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5574-95<br />

5575-95<br />

5576-95<br />

6696-95<br />

6697-95<br />

6698-95<br />

6699-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5573-95<br />

5573-95<br />

6696-95<br />

5573-95<br />

5574-95<br />

5575-95<br />

5576-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

26JUN1995<br />

26JUN1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUNl995<br />

26JUNl995<br />

26JUN1995<br />

26JUN1995<br />

07MARl995<br />

26JUNl995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUNl995<br />

07MARI 995<br />

26JUN1995<br />

07MARI 995<br />

26JUNl995<br />

07MARl995<br />

26JUNl995<br />

07MARI 995<br />

26JUNl995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27W1995<br />

Page 2 of 176<br />

1.30E+01<br />

2.00E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.40E+01<br />

1.30E+01<br />

2.04E+02<br />

2.03E+02<br />

2.03E+02<br />

2.03E+02<br />

2.1 1E+02<br />

2.10E+02<br />

2.10E+02<br />

2.10E+02<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO O.OOE+OO<br />

O.OOE+OO O.OOE+OO<br />

5.90E+01<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

l.OOE+OO<br />

I .00E+00<br />

1 .OOE+W<br />

1.00E+00<br />

1.00E+00<br />

1.00E+00<br />

1.00E+00<br />

l.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

1.00E+00<br />

1.00E+00<br />

2.00E+00<br />

2.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OI<br />

1.00E+01<br />

1 .WE+Ol<br />

l.OOE+OI<br />

0.00E+00<br />

0.00E+00<br />

5.00E+00<br />

5.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

mglL<br />

mglL<br />

pCiL<br />

pCilL<br />

F<br />

uglL<br />

uglL<br />

0gIL<br />

uglL<br />

mg1L<br />

mg1L<br />

mg1L<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

ug1L<br />

ug/L<br />

uglL<br />

NTU<br />

NTU<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mg1L<br />

mglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

uglL<br />

UgR<br />

ugR<br />

ugfl<br />

mgk<br />

mgR<br />

mgR<br />

WlL<br />

mg/L<br />

msn<br />

mgk


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Barium, Dissolved 7440-39-3 5577-95 27MAR1995 WG O.OOE+OO<br />

N<br />

mglL<br />

Benzene<br />

Benzene<br />

71-43-2<br />

71 -43-2<br />

5577-95<br />

6700-95<br />

27MAR1995<br />

22JUN1995<br />

WG<br />

WG<br />

5.00E+00<br />

5.00E+00<br />

U<br />

U<br />

N<br />

N<br />

uglL<br />

uglL<br />

Beryllium<br />

7440-41-7<br />

5577-95 27MAR1995 WG 0.00E+00<br />

<<br />

N<br />

mgfl<br />

Beryllium, Dissolved<br />

7440-41-7<br />

5577-95 27MAR1995 WG O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

5577-95<br />

6700-95<br />

5577-95<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

WG<br />

WG<br />

WG<br />

5.00€+00<br />

5.00€+00<br />

O.OOE+OO<br />

U<br />

U<br />

c<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

mglL<br />

Cadmium, Dissolved<br />

7440-43-9<br />

5577-95 27MAR1995 WG O.OOE+OO<br />

Q<br />

mglL<br />

Calcium<br />

7440-70-2<br />

5577-95 27MAR1995 WG 1 .5OE+O1<br />

N<br />

mglL<br />

Calcium, Dissolved<br />

7440-70-2<br />

5577-95 27MAR1995 WG 1.60E+01<br />

N WlL<br />

Carbon Tetrachloride<br />

56 - 23 - 5<br />

5577-95 27MAR1995 WG 5.00E+00<br />

U<br />

N<br />

uglL<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

67-66-3<br />

67-66-3<br />

7440-47-3<br />

7440-47-3<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

5577-95<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MARl995<br />

27MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

5.00€+00<br />

1.90E+01<br />

1.90€+01<br />

5.00€+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

U<br />

U<br />

U<br />

C<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

mglL<br />

mglL<br />

ug1L<br />

ug/L<br />

mglL<br />

mglL<br />

Coban<br />

7440-48-4<br />

5577-95 27MAR1995 WG O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Cobalt. Dissolved<br />

7440-40-4<br />

5577-95 27MAR1995 w O.M)E+OO<br />

<<br />

N<br />

mglL<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

7440-50-8<br />

7440-50-8<br />

D W<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41-4<br />

100-41-4<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

27MAR 1995<br />

27MARl995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22 JUNl995<br />

27MAR1995<br />

22JUN1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

0.00E+00<br />

O.OOE+OO<br />

<strong>4.</strong>10E+01<br />

<strong>4.</strong>00€+00<br />

1.23E+02<br />

1.06€+02<br />

5.00E+00<br />

5.00E+00<br />

<<br />

<<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

Feet<br />

mg1L<br />

mg/L<br />

mglL<br />

uglL<br />

ug1L<br />

Fluoride<br />

Fluoride<br />

1690448-8<br />

16984-48-8<br />

5577-95<br />

6700-95<br />

27MARl995<br />

22JUN1995<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

N<br />

N<br />

mgfl<br />

mglL<br />

Gross Alpha<br />

12507-46-1<br />

5577-95 27MAR1995 WG l.OOE+OO 8.00E-01<br />

N<br />

pCYL<br />

Gross Alpha<br />

Gross Beta<br />

12507-46-1<br />

12507-47-2<br />

6700-95<br />

5577-95<br />

22JUN1995<br />

27MAR1995<br />

WG<br />

WG<br />

2.00E+00 5.00E-01<br />

8.00€+00 3.00€+00<br />

N<br />

N<br />

pCiL<br />

pCiL<br />

Gross Beta<br />

12587-47-2<br />

6700-95 22JUN1995 WG 1.40E+01 l.OOE+OO<br />

N<br />

pCiL<br />

Iron<br />

7439-09-6<br />

5577-95 27MAR1995 w 1.00E+00<br />

N<br />

mglL<br />

Iron, Dissolved<br />

7439 - 09 - 6<br />

5577-95 27MAR1995 WG O.OOE+OO<br />

<<br />

N<br />

mgfl<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

7439-92-1<br />

7439-92-1<br />

7439-954<br />

7439-95-4<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

27MAR1995<br />

27MARl995<br />

27MARl995<br />

27MARl995<br />

WG<br />

WG<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

6.00€+00<br />

7.00E+00<br />

<<br />

Q<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mgA<br />

mglL<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury, Dissolved<br />

Nickel<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7440-02-0<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

27MARl995<br />

27MAR1995<br />

27MAR1995<br />

27MAR 1995<br />

27MARl995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

2.00E+00<br />

2.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

Nickel, Dissolved<br />

7440-02-0<br />

5577-95 27MAR1995 WG O.OOE+OO<br />

N<br />

mgfl<br />

Nitrate as Nitrogen<br />

NITRATEASNIT 5577-95 27MARl995 w l.OOE+OO<br />

N<br />

mgfl<br />

Nitrate as Nitrogen<br />

N ITRATEAS N IT 6700-95 22JUN1995 WG l.OOE+OO<br />

N<br />

mglL<br />

Potassium<br />

Potassium, Dissolved<br />

Radon 222<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

RN222<br />

7702-49-2<br />

7782-49-2<br />

5577-95<br />

5577-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

5577-95<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

27MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

l.lOE+Ol<br />

O.OOE+OO<br />

<strong>4.</strong>63E+02 6.70E+01<br />

9.48E+03 1.24E+03<br />

O.OOE+OO<br />

0.00E+00<br />

c<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mgk<br />

mgfl<br />

pCiL<br />

pCiL<br />

mgfl<br />

mglL<br />

Silica<br />

Silica<br />

7631-86-9<br />

7631 -86-9<br />

5577-95<br />

6700-95<br />

27MAR1995<br />

22JUN1995<br />

WG<br />

WG<br />

1.90E+01<br />

1.70E+01<br />

N<br />

N<br />

rng1L<br />

mglL<br />

Silver<br />

7440-22-4<br />

5577-95 27MAR1995 WG O.WE+OO<br />

<<br />

N<br />

mglL<br />

Silver. Dissolved<br />

7440-22-4<br />

5577-95 27MAR1995 w O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Sodium<br />

7440-23-5<br />

5577-95 27MAR1995 w 1.40E+01<br />

N<br />

mglL<br />

Sodium, Dissolved<br />

7440-23-5<br />

5577-95 27MAR1995 WG 1.50E+01<br />

B<br />

N<br />

mglL<br />

Specific conductance SO145<br />

5577-95 27MARl995 w 2.22E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

5570-95 27MARl995 WG 2.20E+02<br />

N umhodcm<br />

Specific conductance SO145<br />

5579-95 27MAR1995 WG 2.17E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

5500-95 27MAR1995 w 2.16E+02<br />

N umhodcm<br />

Specific conductance SO145<br />

6700-95 22JUN1995 w 2.15E+02<br />

N umhoslcm<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Sulfate<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

12143-45-2<br />

6701-95<br />

6702-95<br />

6703-95<br />

5577-95<br />

6700-95<br />

22JUN1995<br />

22JUN1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

2.14E+02<br />

2.13E+02<br />

2.13E+02<br />

5.00E+00<br />

5.00E+00<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

mglL<br />

mgfl<br />

Technetium-99<br />

14133-76-7<br />

5577-95 27MAR1995 WG l.lOE+Ol 1.80E+01<br />

N<br />

pci5<br />

Page 3 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Technetium-99 14133-76-7 6700-95 22JUN1995 WG O.OOE+OO O.OOE+OO N pCilL<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-l,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc. Dissolved<br />

cis-1.2dichloroethene<br />

cis-1.2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 1. SWU 38, MW329<br />

1.1,l-Trichloroethane<br />

1 ,l,l-Trichloroethane<br />

1,1,2-Trichloroethane<br />

1 .I .2-Trichloroethane<br />

1 .l -Dichloroethane<br />

1,l-Dichloroethane<br />

1,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

Alkalinity<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic. Dissolved<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium. Dissolved<br />

Bromodichloromethane<br />

Bromodichloromet hane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chbride<br />

Chloride<br />

Chbroform<br />

Chloroform<br />

Chromium<br />

SO835<br />

127-18-4<br />

127-18-4<br />

108-88-3<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

744044-0<br />

156-60-5<br />

156-60-5<br />

79-01 -6<br />

79-01-6<br />

SO278<br />

SO278<br />

7440-61 -1<br />

7440-61-1<br />

DIS U<br />

DIS U<br />

75-014<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

71-55-6<br />

71-516<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

744041 -7<br />

7440-41-7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

67-66-3<br />

67-663<br />

7440-47-3<br />

5577-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

5578-95<br />

5579-95<br />

5580-95<br />

6700-95<br />

6701-95<br />

6702-95<br />

6703-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

5577-95<br />

5577-95<br />

6700-95<br />

5577-95<br />

5578-95<br />

5579-95<br />

5580-95<br />

5581 -95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581 -95<br />

6704-95<br />

5581 -95<br />

6704-95<br />

5581-95<br />

5581-95<br />

5581 -95<br />

5581 -95<br />

5581 -95<br />

5581 -95<br />

5581-95<br />

6704-95<br />

5581-95<br />

5581 -95<br />

5581-95<br />

6704-95<br />

5581 -95<br />

5581 -95<br />

55ai-95<br />

5581 -95<br />

5581-95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581 -95<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUNl995<br />

22JUN1995<br />

22JUN1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22 JUN 1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUNl995<br />

27MARl995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MARl995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

Page 4 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

6.00E+01<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

1 .OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

l.OOE+OO<br />

1 .WE+OO<br />

9.00E+00<br />

3.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+Ol<br />

l.OOE+OI<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

0.00E+00<br />

0.00E+00<br />

5.00E+00<br />

5.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

6.10E+01<br />

6.60E+01<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

0.00E+00<br />

0.00E+00<br />

5.WE+00<br />

5.00€+00<br />

0.00E+00<br />

O.OOE+W<br />

5.00E+00<br />

5.00€+00<br />

0.00E+00<br />

O.WE+W<br />

<strong>4.</strong>70E+Ol<br />

<strong>4.</strong>90E+01<br />

5.00€+00<br />

5.WE+00<br />

1.66E+02<br />

1.73E+02<br />

5.00E+00<br />

5.00E+00<br />

0.00E+00<br />

N<br />

U<br />

N<br />

U<br />

N<br />

U<br />

N<br />

U<br />

N<br />

< N<br />

c<br />

N<br />

c<br />

N<br />

< N<br />

< N<br />

< N<br />

c<br />

N<br />

c<br />

N<br />

U<br />

N<br />

U<br />

N<br />

UX<br />

N<br />

U<br />

N<br />

N<br />

N<br />

c<br />

N<br />

< N<br />

Q<br />

Q<br />

Q<br />

Q<br />

U<br />

N<br />

U<br />

N<br />

U<br />

N<br />

U<br />

N<br />

< N<br />

Q<br />

U<br />

N<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

c<br />

Q<br />

c<br />

Q<br />

U<br />

U<br />

U<br />

U<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

F<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

N N<br />

NTU<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

ug1L<br />

uglL<br />

wfl<br />

ugfl<br />

WlL<br />

mglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

wfl<br />

uglL<br />

ug1L<br />

WlL<br />

mgfl<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

W L<br />

uglL<br />

uglL<br />

mgR<br />

msn<br />

uglL<br />

ugk<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

ugfl<br />

uglL<br />

mglL<br />

mglL<br />

ugfl<br />

uglL<br />

msn


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium, Dissolved 7440-47-3 5581-95 27MAR1995 WG O.OOE+OO C N mglL<br />

Coball<br />

Coball, Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solis<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

Fluoride<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Iron<br />

Iron. Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury, Dissolved<br />

Nickel<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium, Dissolved<br />

Radon 222<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

Silica<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

SpecifG conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Sulfate<br />

Sulfate<br />

Technetium99<br />

Technetium-99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-I .2-Dichloroethene<br />

Trans-I .Z-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

7440-484<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41-4<br />

100-41-4<br />

16984-48-8<br />

16984-48-8<br />

I 2587-46-1<br />

12587-46-1<br />

12587-47-2<br />

I 2587-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7440-02-0<br />

7440-02-0<br />

N ITRATEASN IT<br />

N ITRATEAS NIT<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

RN222<br />

7782-49-2<br />

7782-49-2<br />

7631-86-9<br />

7631-86-9<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

12143-45-2<br />

14133-76-7<br />

14133-76-7<br />

so835<br />

127-18-4<br />

127-18-4<br />

108-88-3<br />

I 08-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

5581-95<br />

5581 -9s<br />

5581 -95<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581-9s<br />

6704-95<br />

5581 -95<br />

6704-95<br />

5581 -9s<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581-95<br />

5581-9s<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581 -9s<br />

5581-95<br />

5581-95<br />

5581 -95<br />

6704-95<br />

5581-95<br />

5581 -95<br />

5581-95<br />

6704-95<br />

5581-95<br />

5581-95<br />

5581-95<br />

6704-95<br />

5581 -95<br />

5581-95<br />

5581-95<br />

5581-95<br />

5581 -95<br />

5582-95<br />

5583-95<br />

5584-95<br />

6704-95<br />

6705-95<br />

6706-95<br />

6707-95<br />

5581 -95<br />

6704-95<br />

5581-95<br />

6704-95<br />

5581 -95<br />

5581-95<br />

6704-95<br />

5581 -95<br />

6704-95<br />

5581-9s<br />

5582-95<br />

5583-95<br />

5584-95<br />

6704-95<br />

6705-95<br />

6706-95<br />

6707-95<br />

5581-95<br />

6704-95<br />

5581-95<br />

6704-95<br />

27MAR 1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR 1995<br />

27MAR1995<br />

27MAR 1995<br />

27MAR1995<br />

22JUN1995<br />

27MARl995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR 1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MARl995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MARI 995<br />

22JUN1995<br />

27MAR1995<br />

27MARl995<br />

27MARl995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MARl995<br />

22JUNl995<br />

27MAR1995<br />

27MARl995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

22JUN1995<br />

22JUN1995<br />

22 JUNl995<br />

27MAR1995<br />

22JUNl995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

22JUN1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

27MAR1995<br />

22JUN1995<br />

22JUNl995<br />

22JUN1995<br />

22JUN1995<br />

27MAR1995<br />

22JUNl995<br />

27MARl995<br />

22JUN1995<br />

Page 5 of 176<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Feet<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

pCYL<br />

pCi/L<br />

pCfL<br />

pCi/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mdL<br />

mglL<br />

mglL<br />

pCVL<br />

pCilL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

mglL<br />

WlL<br />

mg/L<br />

umhoslcm<br />

umhoslcm<br />

umhoslcrn<br />

umhoslcrn<br />

umhoslcm<br />

umhoslcm<br />

umhos/crn<br />

umhoslcm<br />

WlL<br />

mglL<br />

pCVL<br />

pCVL<br />

F<br />

ugfl<br />

uglL<br />

ug1L<br />

uglL<br />

mglL<br />

rnglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mgfl<br />

uglL<br />

ug1L<br />

ugk<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Turbidity SO278 5581-95 27MAR1995 WG 6.00E+00 N<br />

NTU<br />

Turbidity<br />

SO278<br />

6704-95 22JUN1995<br />

3.00€+00<br />

N<br />

N N<br />

Uranium<br />

7440-61-1<br />

5581-95 27MAR1995 0.00€+00<br />

< N<br />

mg/L<br />

Uranium<br />

7440-61 -1<br />

670495 22JUN1995<br />

O.WE+OO<br />

< N<br />

mglL<br />

Uranium, Dissolved<br />

DIS U<br />

5581-95 27MAR1995 0.00 E+OO<br />

Q<br />

Q<br />

mglL<br />

Uranium, Dissolved<br />

DIS U<br />

6704-95 22JUN1995<br />

O.OOE+OO<br />

Q<br />

Q<br />

mglL<br />

Vinyl Chloride<br />

75-01-4<br />

5581-95 27MAR1995 1 .OOE+Ol<br />

U<br />

N<br />

uglL<br />

Vinyl Chloride<br />

75-01-4<br />

6704-95 22JUN1995<br />

l.OOE+Ol<br />

U<br />

N<br />

uglL<br />

Xylene<br />

1330-20-7<br />

5581-95 27MAR 1995<br />

l.OOE+Ol<br />

U<br />

N<br />

uglL<br />

Xylene<br />

1330-20-7<br />

6704-95 22JUN1995<br />

l.OOE+Ol<br />

U<br />

N<br />

uglL<br />

Zinc<br />

7440-66-6<br />

5581-95 27MAR1995 O.OOE+OO<br />

< N<br />

mglL<br />

Zinc, Dissolved<br />

cis-I .2-dichloroethene<br />

7440-66-6<br />

156-59-2<br />

5581-95<br />

5581-95<br />

27MAR1995<br />

27MAR1995<br />

O.OOE+OO<br />

5.00€+00<br />

Q<br />

U<br />

N<br />

mglL<br />

uglL<br />

cis-1.2-dichloroethene 156-59-2<br />

6704-95 22JUN1995<br />

5.00E+00<br />

U<br />

N<br />

ug1L<br />

PH<br />

SO296<br />

5581 -95 27MAR1995 6.00E+00<br />

N su<br />

PH<br />

SO296<br />

5582-95 27MAR1995 6.00E+00<br />

N su<br />

PH<br />

SO296<br />

5583-95 27MAR1995 6.00E+W<br />

N su<br />

PH<br />

SO296<br />

5584-95 27MARl995<br />

6.00E+00<br />

N su<br />

WAG 1, SWU 100, MWjfO<br />

1.1 ,I-Trichloroethane<br />

1.1,l-Trichloroethane<br />

1.1,2-Trichloroethane<br />

1,1,2-TrichIoroethane<br />

1,l -Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .Z-Dichloroethane<br />

1,2-DichIoroethane<br />

Alkalinity<br />

Alkalinity<br />

Antimony<br />

Antimony. Dissolved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

Cobalt<br />

Cobalt, Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

Fluoride<br />

71-55-6<br />

71-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7440-41 -7<br />

7440-41 -7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

67-66-3<br />

67-66-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

DlW<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41-4<br />

100-41-4<br />

16984-488<br />

1698448-8<br />

5585-95<br />

6708-95<br />

5585-95<br />

67oa95<br />

5585-95<br />

6708-95<br />

5585-95<br />

67oa95<br />

5585-95<br />

6708-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

6706-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

670895<br />

5585-95<br />

6708-95<br />

07MARl995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MARl995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR 1995<br />

O7MAR 1995<br />

07MAR1995<br />

07MAR1995<br />

26JUNl995<br />

07MAR1995<br />

07MARl995<br />

07MAR1995<br />

26JUNl995<br />

07MAR1995<br />

07MARI 995<br />

07MAR1995<br />

07MAR1995<br />

07MAR 1995<br />

26JUN1995<br />

07MAR1995<br />

26JUNl995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUNl995<br />

07MARl995<br />

26JUNl995<br />

07MAR1995<br />

26JUN1995<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

5.WE+00<br />

5.00E+00<br />

S.WE+OO<br />

1.22€+02<br />

1.32E+02<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

1 .WE+00<br />

l.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

0.00E+00<br />

O.WE+OO<br />

5.00E+00<br />

5.00E+00<br />

O.WE+OO<br />

O.WE+W<br />

2.90E+Ol<br />

3.20E+01<br />

5.00E+00<br />

5.00€+00<br />

2.10E+01<br />

1.90E+01<br />

5.00E+00<br />

5.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

0.WE+00<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

<strong>4.</strong>90E+OI<br />

l.OOE+OO<br />

1.74E+02<br />

1.92€+02<br />

5.00E+W<br />

5.00E+W<br />

O.WE+W<br />

O.WE+W<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

c<br />

Q<br />

c<br />

Q<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mg/L<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

ug1L<br />

uglL<br />

mglL<br />

mg/L<br />

ugfl<br />

uglL<br />

mglL<br />

rnglL<br />

mg/L<br />

WlL<br />

ugfl<br />

ugk<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mgn<br />

mglL<br />

WlL<br />

Feet<br />

mg/L<br />

W/L<br />

mg1L<br />

ugR<br />

uglL<br />

mgk<br />

wfl<br />

Gross Alpha<br />

12587-46-1<br />

5585-95 07MAR1995 2.00E+W 9.00E-01<br />

N<br />

pciL<br />

Gross Alpha<br />

12587-46-1<br />

6708-95 26JUN1995<br />

<strong>4.</strong>00E+W 9.00E-01<br />

N<br />

pciL<br />

Gross Beta<br />

Gross Beta<br />

Iron<br />

12587-47-2<br />

1258747-2<br />

7439-89-6<br />

5585-95<br />

6708-95<br />

5585-95<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

8.WE+W <strong>4.</strong>00€+00<br />

7.00E+00 1.00E+00<br />

5.00E+00<br />

N<br />

N<br />

N<br />

pCi<br />

pCi<br />

mgR<br />

Page 6 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Iron, Dissolved 7439-89-6 5585-95 07MAR1995 WG O.OOE+OO<br />

<<br />

N<br />

mg1L<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

07MAR1995<br />

07MAR1995<br />

07MAR 1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MARl995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

<<br />

c<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Mercury, Dissolved<br />

7439-97-6<br />

5585-95 07MAR1995 WG<br />

Q<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

5585-95 07MAR 1995 WG<br />

c<br />

N<br />

mglL<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium, Dissolved<br />

Radon 222<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

Silica<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Sulfate<br />

Technetium-99<br />

Technetium99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

7440-02-0<br />

N ITRATEASN IT<br />

NITRATEASNIT<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

RN222<br />

7782-49-2<br />

7782-49-2<br />

7631-86-9<br />

7631 -86-9<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

12143-45-2<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

127-18-4<br />

127-18-4<br />

10~8-3<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5585-95<br />

5586-95<br />

5587-95<br />

5588-95<br />

6708-95<br />

6709-95<br />

6710-95<br />

6711-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

5585-95<br />

6708-95<br />

558595<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR 1995<br />

07MARl995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

07MARl995<br />

O7MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

26JUNl995<br />

26JUN1995<br />

26JUN1995<br />

07MAR 1995<br />

26JUN1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

Q<br />

c<br />

c<br />

<<br />

Q<br />

c<br />

Q<br />

c<br />

<<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

pCVL<br />

pCVL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

mgfl<br />

mglL<br />

pCVL<br />

pCVL<br />

F<br />

uglL<br />

uglL<br />

uglL<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-l,2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Tfichloroethene<br />

Trichloroet hene<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01 -6<br />

6708-95<br />

5585-95<br />

5586-95<br />

5587-95<br />

5588-95<br />

6708-95<br />

6709-95<br />

6710-95<br />

6711-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

6708-95<br />

26JUN1995<br />

07MAR1995<br />

07MARl995<br />

07MAR1995<br />

07MAR1995<br />

26JUN1995<br />

26JUN1995<br />

26JUNl995<br />

26JUN1995<br />

07MAR1995<br />

26JUNl995<br />

07MAR1995<br />

26JUN1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

c<br />

c<br />

<<br />

<<br />

c<br />

c<br />

c<br />

c<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

SO278<br />

SO278<br />

7440-61 -1<br />

7440-61 -1<br />

DIS U<br />

5585-95<br />

6708-95<br />

5585-95<br />

6708-95<br />

5585-95<br />

07MAR1995<br />

26JUNl995<br />

07MAR1995<br />

26JUN1995<br />

07MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

<<br />

c<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

NTU<br />

NTU<br />

mglL<br />

mglL<br />

mglL<br />

Uranium. Dissolved<br />

DIS U<br />

6708-95 26JUN1995 WG<br />

Q<br />

Q<br />

mglL<br />

Vinyl Chloride<br />

75-014<br />

5585-95 07MAR1995 WG<br />

U<br />

N<br />

uglL<br />

Vinyl Chloride<br />

75-01-4<br />

6708-95 26JUN1995 WG<br />

U<br />

N<br />

ugfl<br />

Xylene<br />

1330-20-7<br />

5585-95 07MAR1995 WG<br />

U<br />

N wfl<br />

Xylene<br />

1330-20-7<br />

6708-95 26JUN1995 WG<br />

U<br />

N<br />

uglL<br />

Zinc<br />

7440-66-6<br />

5585-95 07MAR1995 WG<br />

c<br />

N<br />

mglL<br />

Zinc. Dissotved<br />

7440-66-6<br />

5585-95 07MAR1995 WG<br />

c<br />

N<br />

mglL<br />

cis-1.2-dichloroethene 156-59-2<br />

5585-95 07MAR1995 WG<br />

U<br />

N<br />

uglL<br />

cis-1.2dichloroethene 156-59-2<br />

6708-95 26JUN1995 WG<br />

U<br />

N<br />

uglL<br />

PH<br />

so296<br />

5585-95 07MAR1995 WG<br />

N su<br />

PH<br />

SO296<br />

5586-95 07MAR1995 WG<br />

N su<br />

PH<br />

so296<br />

5587-95 07MAR1995 WG<br />

N su<br />

PH<br />

so296<br />

5588-95 07MAR1995 WG<br />

N su<br />

Page 7 of 176


L.9 (continued)<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

WAG 1, SWU 136, MW25<br />

1 ,I,I-Trichloroethane<br />

1 ,I.I-Trichloroethane<br />

1 .I,2-Trichloroethane<br />

1 .I.2-Trichloroethane<br />

1 ,I-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethene<br />

1 .I-Dichloroethene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

Alkalinity<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

Coban<br />

Cobalt. Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

Fluoride<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Iron<br />

Iron. Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

71 -55-6<br />

71-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71 -43-2<br />

71-43-2<br />

7440-41 -7<br />

7440-41 -7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

5623-5<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

67-66-3<br />

67-66-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41-4<br />

100-41 -4<br />

16984-48-8<br />

16984-48-8<br />

12587-46-1<br />

12587-46-1<br />

12587-47-2<br />

12587-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688 - 95<br />

5565 - 95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

668695<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

06MARl995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

O6MARI 995<br />

26JUN1995<br />

O6MAR1 995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

OMARl995<br />

26JUN1995<br />

06MARI 995<br />

06MARl995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

06MARI 995<br />

06MAR1995<br />

26JUN1995<br />

O6MAR1 995<br />

06MAR1995<br />

06MARI 995<br />

26JUN1995<br />

06MAR1995<br />

-1995<br />

06MAR1995<br />

06MARl995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

26JUNl995<br />

06MARl995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MARI 995<br />

06MAR1995<br />

06MAR1995<br />

06MARl995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

26JUNI 995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

06MARl995<br />

-1995<br />

06MARl995<br />

06MAR1995<br />

-1995<br />

-1995<br />

06MARl995<br />

06MAR 1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

U<br />

U<br />

U<br />

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U<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mg/L<br />

mg/L<br />

mg/L<br />

mglL<br />

uglL<br />

uglL<br />

mg/L<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mg1L<br />

Feet<br />

mglL<br />

mgfl<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

pCiL<br />

pCilL<br />

pCiL<br />

pCi<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mg/L<br />

mglL<br />

mgfl<br />

Mercury, Dissolved<br />

7439-97-6<br />

5565-95 -1995 WG<br />

Q<br />

N<br />

mgfl<br />

Nickel<br />

7440-02-0<br />

5565-95 -1995 WG<br />

<<br />

N wfl<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium. Dissolved<br />

Radon 222<br />

Radon 222<br />

Selenium<br />

7440-02-0<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

RN222<br />

7782-49-2<br />

5565-95<br />

5565-95<br />

6688-95<br />

556595<br />

556595<br />

556595<br />

6688-95<br />

5565-95<br />

-1995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

-1995<br />

-1995<br />

26JUN1995<br />

06MARl995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

<<br />

<<br />

c<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

pCilL<br />

pciR<br />

mgfl<br />

Page 8 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Selenium, Dissolved 7782-49-2 5565-95 06MAR1995 WG O.OOE+OO Q N<br />

Silica<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conduclance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Sulfate<br />

Technetium-99<br />

Technetium-99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-I ,Z-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trichloroethene<br />

Trichbroelhene<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Uranium. Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc, Dissolved<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 1. SWU 136, MW326<br />

1 ,l,l-Trichloroethane<br />

1,l ,l-Trichloroethane<br />

1 .I ,2-Trichloroethane<br />

1.1.2-Trichloroethane<br />

1 ,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

I .I-Dichloroethene<br />

1 ,I-Dichloroethene<br />

I .2-Dichloroethane<br />

1,2-Dichloroelhane<br />

Alkalinity<br />

Alkalinity<br />

Antimony<br />

Antimony. Dissolved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

7631-86-9<br />

7631-86-9<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

12143-45-2<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

127-10-4<br />

127-184<br />

100-88-3<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

SO278<br />

SO278<br />

7440-61 -1<br />

7440-61 -1<br />

DIS U<br />

DIS U<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440 - 66 - 6<br />

7440-66-6<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

71-55-6<br />

71-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-354<br />

75-3w<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-36-2<br />

7440-30-2<br />

7440-39-3<br />

5565-95<br />

6688-95<br />

5565 - 95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

5566-95<br />

5567-95<br />

5568-95<br />

6688-95<br />

6689-95<br />

6690-95<br />

6691-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6680-95<br />

5565-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5566-95<br />

5567-95<br />

5568-95<br />

6688-95<br />

6689-95<br />

6690-95<br />

6691-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5565-95<br />

5565-95<br />

6688-95<br />

5565-95<br />

5566-95<br />

5567-95<br />

5568-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

O6MAR 1995<br />

O6MAR1 995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

26JUN1995<br />

26JUN1995<br />

26JUN1995<br />

26JUNl995<br />

O6MAR 1995<br />

26JUN1995<br />

O6MAR1 995<br />

26JUN1995<br />

06MAR1995<br />

06MAR 1995<br />

26JUNl995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

O6MAR1 995<br />

26JUN1995<br />

26JUN1995<br />

26JUN1995<br />

26JUN1995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

26JUN1995<br />

MAR1 995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

06MARl995<br />

06MAR1995<br />

06MAR1995<br />

06MARl995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

2 6JUN 1995<br />

06MAR1995<br />

06MARl995<br />

06MAR1995<br />

06MARl995<br />

06MAR1995<br />

Page 9 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

wc,<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

mglL<br />

mglL<br />

pCi/L<br />

pCilL<br />

F<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

WlL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

NTU<br />

NTU<br />

WlL<br />

WlL<br />

mglL<br />

WlL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

ugfl<br />

ugfl<br />

uglL<br />

uglL<br />

wfl<br />

WlL<br />

mgfl<br />

mg5<br />

mgfl<br />

mgfl<br />

Wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Barium, Dissolved 7440-39-3 5569-95 06MAR1995 WG O.OOE+OO<br />

N<br />

mg1L<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloride<br />

Chloroform<br />

71 -43-2<br />

71-43-2<br />

7440-41 -7<br />

7440-41 -7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

67-66-3<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

5569 - 95<br />

5569 - 95<br />

5569 - 95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MARl995<br />

06MARl995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

O6MAR 1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

U<br />

c<br />

<<br />

U<br />

U<br />

c<br />

C<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

uglL<br />

Chloroform<br />

67-66-3<br />

6692-95 26JUN1995 WG<br />

U<br />

N<br />

uglL<br />

Chromium<br />

7440-47-3<br />

5569-95 06MAR 1995 WG<br />

<<br />

N<br />

mglL<br />

Chromium, Dissolved 7440-47-3<br />

5569-95 06MARI 995 w<br />

<<br />

N<br />

mglL<br />

Coban<br />

Cobalt, Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Dissolved Solids<br />

Ethylbenzene<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41-4<br />

5569-95<br />

5569-95<br />

5569 - 95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

WMAR1995<br />

WMAR 1995<br />

06MAR1995<br />

06MAR1995<br />

26JUN1995<br />

WAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

C<br />

C<br />

<<br />

C<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

rnglL<br />

mg1L<br />

rnglL<br />

mglL<br />

Feet<br />

mglL<br />

mglL<br />

mgfl<br />

uglL<br />

Ethylbenzene<br />

Fluoride<br />

Fluoride<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Iron<br />

Iron, Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

100-41-4<br />

i 6984-48-8<br />

16984-46-8<br />

12587-46-1<br />

12587-46-1<br />

12587-47-2<br />

12587-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MARI995<br />

26JUN1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

06MARl995<br />

06MAR1995<br />

06MARI 995<br />

06MARI 995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

mglL<br />

mglL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCilL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

Manganese, Dissolved 7439-96-5<br />

5569-95 06MARI995 WG<br />

N<br />

mglL<br />

Mercury<br />

7439-97-6<br />

5569-95 06MARl995 w<br />

N<br />

mglL<br />

Mercury, Dissolved<br />

Nickel<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium, Dissolved<br />

Radon 222<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

Silica<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

7439-97-6<br />

7440-02-0<br />

7440-02-0<br />

N ITRAEASN IT<br />

N ITRATEASN IT<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

RN222<br />

7782-49-2<br />

7782-49-2<br />

7631 -86-9<br />

7631-86-9<br />

7440-22-4<br />

7440-22-4<br />

5569-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5569-95<br />

06MAR1995<br />

06MAR1995<br />

06MARl995<br />

06MAR1995<br />

26JUN 1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

06MARl995<br />

06MAR1995<br />

26JUNl995<br />

06MAR1995<br />

06MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

CS<br />

Q<br />

<<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mg1L<br />

pCiL<br />

pCiR<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Sodium<br />

Sodium, Dissolved<br />

7440-23-5<br />

7440-23-5<br />

5569-95<br />

5569-95<br />

06MAR 1995<br />

WAR1995<br />

WG<br />

WG<br />

N<br />

N<br />

mglL<br />

mg1L<br />

Specific conductance SO145<br />

5569-95 06MAR1995 WG<br />

N umhodcm<br />

Specific conductance SO145<br />

5570-95 06MARl995 WG<br />

N umhoslcm<br />

Specific conductance SO145<br />

5571-95 06MARl995 w<br />

N umhos/cm<br />

Specific conductance SO145<br />

5572-95 06MAR1995 w<br />

N umhoslcm<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

6692-95<br />

6693-95<br />

6694-95<br />

6695-95<br />

26JUN1995<br />

26JUNl995<br />

26JUNl995<br />

26JUNl995<br />

WG<br />

WG<br />

WG<br />

WG<br />

N<br />

N<br />

N<br />

N<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

Sulfate<br />

1214345-2<br />

5569-95 06MAR1995 WG<br />

<<br />

N wfl<br />

Sulfate<br />

1214345-2<br />

6692-95 26JUN1995 w<br />

<<br />

N<br />

mg1L<br />

Technetium99<br />

14133-767<br />

5569-95 06MAR1995 WG<br />

N<br />

pci5<br />

Page 10 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Technetium-99 14133-76-7 6692-95 26JUN1995 WG 2.00E+00 1.20E+01 N DCUL<br />

Temperature<br />

SO835<br />

5569-95 O6MAR 1995 WG<br />

N<br />

F<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-l,2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

127-18-4<br />

127-18-4<br />

108-88-3<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

SO278<br />

SO278<br />

7440-61 -1<br />

7440-61 -1<br />

DIS U<br />

DIS U<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

5570-95<br />

5571-95<br />

5572-95<br />

6692-95<br />

6693-95<br />

6694-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

6692-95<br />

5569-95<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

O6MAR 1995<br />

06MAR1995<br />

06MAR1995<br />

06MAR1995<br />

26JUNl995<br />

26JUN1995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

26JUN1995<br />

06MAR1995<br />

26JUN1995<br />

06MARl995<br />

26JUN1995<br />

06MAR1995<br />

26JUNl995<br />

06MARl995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

U<br />

U<br />

U<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

U<br />

U<br />

<<br />

<<br />

Q<br />

Q<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

ug1L<br />

ug1L<br />

ugk<br />

uglL<br />

NTU<br />

N N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

ugfl<br />

Xylene<br />

1330-20-7<br />

6692-95 26JUNl995 WG<br />

U<br />

N<br />

ugfl<br />

Zinc<br />

7440-66-6<br />

5569-95 06MAR1995 WG<br />

< N<br />

WlL<br />

Zinc, Dissolved<br />

7440-66-6<br />

5569-95 06MAR1995 WG<br />

< N<br />

mgk<br />

ck-1.2-dichloroethene 156-59-2<br />

5569-95 06MARl995 WG<br />

U<br />

N<br />

ugn<br />

cis-1.2-dichloroethene 156-59-2<br />

6692-95 26JUN1995 WG<br />

U<br />

N<br />

ugk<br />

PH<br />

so296<br />

5569-95 06MAR1995 WG<br />

N su<br />

PH<br />

SO296<br />

5570-95 06MAR1995 WG<br />

N su<br />

PH<br />

SO296<br />

5571-95 06MAR1995 WG<br />

N su<br />

PH<br />

SO296<br />

5572-95 06MAR1995 nG<br />

N su<br />

WAG 7, Sv\IMU 8, C746K-1<br />

1 .l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 ,l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 ,l-Dchloroethane<br />

1,l-Dichloroethane<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

<<br />

<<br />

<<br />

uglL<br />

uglL<br />

uglL<br />

1 ,l-Dchloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 .l-Dchloroethane<br />

1 ,I-Dichloroethane<br />

1,l -Dichloroethane<br />

1 .l-Dichloroethane<br />

1.1 -Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 .I -Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1.1 -Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1,l-Dichloroethene<br />

1,l-Dichloroethene<br />

. 1 .l-Dchloroethene<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-354<br />

75-354<br />

75-354<br />

75-354<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1934-92<br />

2098-92<br />

393-92<br />

516-92<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

516-92<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

04MAYl992<br />

01 JUNl992<br />

06 JULl992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

30JANl992<br />

16FEB1992<br />

05MAR1992<br />

12MARl992<br />

01 APR1992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

3OJANl992<br />

16FEB1992<br />

MAR1 992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUNl992<br />

05AUG1993<br />

05MAY1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUGl992<br />

050CTl993<br />

Page 11 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

UJ<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

UJ<br />

<<br />

<<br />

<<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugA<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugR<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

WlL<br />

WlL<br />

mglL<br />

mg1L


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Aluminum 7429-90-5 161 2-94 OlJUL1994 WS O.OOE+OO N mglL<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7~0-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

1621 -92<br />

17-94<br />

1793-92<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

21 21 -94<br />

2152-93<br />

2 1 8-95<br />

241 1-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

18-95<br />

628-92<br />

631 -95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

162 1-92<br />

1793-92<br />

1934-92<br />

393-92<br />

551 1-92<br />

619-93<br />

697-92<br />

1020-92<br />

1072-93<br />

2098-92<br />

628-92<br />

852-92<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

1836-93<br />

1934-92<br />

2121-94<br />

2152-93<br />

218-95<br />

241 1-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

18-95<br />

1918-94<br />

2098-92<br />

31 AUGl992<br />

05JANl994<br />

070CT1992<br />

05JAN1995<br />

04NOV1993<br />

05AUG1994<br />

03NOV1992<br />

01DEC1992<br />

02SEPl994<br />

10DEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

3OJANl992<br />

03MAR1995<br />

03MAR1994<br />

19AUG1992<br />

05MAY 1993<br />

05MARl992<br />

05APRl995<br />

05MAY1993<br />

12MAR1992<br />

03MAY 1995<br />

02JUN1993<br />

01 APR1992<br />

08APR1994<br />

OWY<br />

1992<br />

OlJUNl992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

3OJANl992<br />

19AUGl992<br />

M Y<br />

1993<br />

osMAR1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUN1992<br />

05AUG1993<br />

WAY<br />

1994<br />

06JUL1992<br />

02SEPl993<br />

03JUN1994<br />

03AUGl992<br />

050CT1993<br />

01 JULl994<br />

31AUG1992<br />

05JAN1994<br />

070CT1992<br />

WAN1 995<br />

04NOVl993<br />

05AUG1994<br />

03NOV1992<br />

01 DEC1992<br />

02SEPl994<br />

10DECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

3OJAN1992<br />

ow1995<br />

ow1994<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

1 .OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

1.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

3.20E+01<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.WE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

1.00E+00<br />

1.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

1.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

0 .OOE+ 00<br />

0.00E+00<br />

0.00E+00<br />

O.M)E+OO<br />

0.00E+00<br />

O.OOE+W<br />

0.00E+00<br />

O.OOE+W<br />

0.00E+00<br />

C<br />

<<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Arsenic 7440-38-2 5511-92 19AUG1992 WS O.OOE+OO < N mglL<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440 - 38 - 2<br />

7440-38-2<br />

7 4 4 0 - 3 8 - 2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440 - 39 - 3<br />

7440-39-3<br />

7 4 4 0 - 3 9 - 3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7 44 0 - 3 9 - 3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440- 39 - 3<br />

71-43-2<br />

7143-2<br />

71-43-2<br />

71-43-2<br />

71 -43-2<br />

71-43-2<br />

7143-2<br />

7 I 43-2<br />

71-43-2<br />

71-43-2<br />

7143-2<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

744041-7<br />

7440-41-1<br />

7440-41-7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

619-93<br />

628-92<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

21 21 -94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

628-92<br />

631 -95<br />

634-93<br />

697-92<br />

705-95<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621 -92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

516-92<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

5511-92<br />

O5MAY 1993<br />

05MAR1992<br />

05APR1 995<br />

EMAY 1993<br />

12MAR 1 992<br />

O3MAY 1995<br />

02JUN1993<br />

01 APRl992<br />

08APR1994<br />

04MAY 1992<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

O5MAY 1994<br />

06JUL1992<br />

O2SEP1993<br />

03JUN1994<br />

03AUG1992<br />

OSOCTI 993<br />

01 JUL1994<br />

3lAUGl992<br />

05JAN1994<br />

070CT1992<br />

05JAN1995<br />

04NOV1993<br />

05AUG1994<br />

03NOV1992<br />

OlDEC1992<br />

O2SEPl 994<br />

lODEC1993<br />

03FE61995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FE61994<br />

30JAN1992<br />

03MAR1995<br />

03MARl994<br />

19AUGI 992<br />

05MAY1993<br />

OWARI 992<br />

05APR1995<br />

05MAY 1993<br />

12MARl992<br />

03MAY 1995<br />

02JUN1993<br />

01 APR 1992<br />

08APR1994<br />

04MAY1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CTI 992<br />

03NOV1992<br />

01DECl992<br />

30JAN1992<br />

16FEB1992<br />

05MAR1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY 1 992<br />

01JUNl992<br />

06JULI 992<br />

03AUG1992<br />

3lAUG 1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3WAN1992<br />

19AUG 1992<br />

Page 13 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL'fTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Beryllium 7440-41 -7 619-93 O5MAY1993 WS O.OOE+OO<br />

c<br />

N<br />

mglL<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

O5MAR1 992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JULl992<br />

03AUG1992<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

7440-69-9<br />

7440 - 69 - 9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

1621-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

3OJANl992<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

c<br />

c<br />

c<br />

c<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

WlL<br />

WlL<br />

mg1L<br />

mg/L<br />

Bismuth<br />

7440-69-9<br />

5511-92<br />

19AUGl992<br />

0.00E+00<br />

c<br />

N<br />

mglL<br />

Bismuth<br />

7440 - 69 - 9<br />

619-93 O5MAY 1993 O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

7440 - 69 - 9<br />

7440-69-9<br />

7440 - 69 - 9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

744043-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

2121 -94<br />

2152-93<br />

216-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

O5MARl 992<br />

12MAR1992<br />

01APR1992<br />

04MAY1992<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

O5MAY 1994<br />

06JULl992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

01 JUL1994<br />

3IAUG1992<br />

osJAN1994<br />

070CT1992<br />

05JANI 995<br />

04NOV1993<br />

05AUGl994<br />

03NOV1992<br />

OlDECl992<br />

02SEPl994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEBl994<br />

30JAN1992<br />

03MAR1995<br />

03MARI994<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

c<br />

c<br />

c<br />

c<br />

c<br />

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N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

WlL<br />

mgk<br />

mglL<br />

mglL<br />

WlL<br />

wlL<br />

mglL<br />

mglL<br />

mg5<br />

mgfl<br />

mglL<br />

WIlL<br />

WlL<br />

mglL<br />

mgfl<br />

mgfl<br />

mgk<br />

Cadmium<br />

7440-43-9<br />

5511-92<br />

19AUGl992 O.OOE+W<br />

c<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

619-93 05MAY1993 O.WE+W<br />

c<br />

N wfl<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

628-92<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

954-95<br />

05MARl992<br />

05APRl995<br />

05MAY1993<br />

12MAR1992<br />

03MAYl995<br />

02JUN1993<br />

01APRI992<br />

08APRl994<br />

01 JUNl995<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

c<br />

U<br />

c<br />

c<br />

c<br />

c<br />

c<br />

<<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

wlL<br />

mgfl<br />

mgk<br />

mglL<br />

wlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1020-92 04MAY 1992<br />

1.70E+OI<br />

NT wR<br />

Calcium<br />

7440-70-2<br />

1140-92 01 JUN1992<br />

2.10E+01<br />

N w5<br />

Calcium<br />

7440-70-2<br />

1329-92 06JUL1992<br />

2.00E+01<br />

N w5<br />

Calcium<br />

7440-70-2<br />

1474-92 03AUGl992<br />

2.00E+OI<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1621-92 31AUG1992<br />

1.80E+01<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1793-92 070CT1992<br />

1.60E+01<br />

N wk<br />

Calcium<br />

7440-70-2<br />

1934-92 03NOV1992<br />

1.80E+01<br />

N wk<br />

Calcium<br />

7440-70-2<br />

2098-92 01 DECl992<br />

l.JOE+Ol<br />

N<br />

m95<br />

Calcium<br />

7440-70-2<br />

393-92 3OJAN1992 I .25E+02<br />

N wR<br />

Calcium<br />

7440-70-2<br />

5511-92 19AUGI 992<br />

2.60E+01<br />

N wfl<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

619-93<br />

628-92<br />

697-92<br />

852-92<br />

MMAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRI 992<br />

l.lOE+Ol<br />

1.50E+01<br />

I .30E+Ol<br />

1.00E+01<br />

N<br />

N<br />

N<br />

N<br />

mg5<br />

mglL<br />

Page 14 of 176<br />

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ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALWE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chloride 16887-00-6 393-92 30JAN1992 WS 1.40E+01 N mg1L<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobal<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Coban<br />

Cobal<br />

Cobalt<br />

Cobalt<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Dibromochloromethane<br />

Dissolved Oxygen<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Copper<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-484<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-484<br />

7440-48-4<br />

7440-48-4<br />

7440-484<br />

7440-484<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

124-48-1<br />

OXYGEN DIS<br />

100-41-4<br />

100-41-4<br />

10041-4<br />

100-41-4<br />

100-414<br />

100-41-4<br />

1020-92<br />

1072-93<br />

1 140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

162 1-92<br />

17-94<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

2 152-93<br />

241 1-94<br />

2689-94<br />

2859-94<br />

393-92<br />

1793-92<br />

2121-94<br />

286-94<br />

505-94<br />

5511-92<br />

619-93<br />

634-93<br />

697-92<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621<br />

-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

619-93<br />

697-92<br />

852-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621<br />

-92<br />

1793-92<br />

1934-92<br />

393-92<br />

5511-92<br />

619-93<br />

628-92<br />

852-92<br />

1020-92<br />

393-92<br />

1020-92<br />

628-92<br />

5511-92<br />

628-92<br />

2098-92<br />

697-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

MAY1992<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

05MAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUNl994<br />

03AUG1992<br />

050CT1993<br />

01 JUL1994<br />

31AUG1992<br />

05JAN1994<br />

070CT1992<br />

05JAN1995<br />

04NOV1993<br />

05AUG1994<br />

03NOV1992<br />

01DEC1992<br />

02SEPl994<br />

10DEC1993<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

30JAN1992<br />

03MARl994<br />

19AUG 1992<br />

05MAY1993<br />

05MAR1992<br />

05MAY1993<br />

12MARl992<br />

02JUNl993<br />

01 APR1992<br />

08APRl994<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

3lAUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

30JAN1992<br />

19AUGl992<br />

05MAY1993<br />

O5MARl992<br />

12MARl992<br />

01 APRl992<br />

WAY1992<br />

OlJUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

30JAN 1992<br />

19AUG1992<br />

M Y<br />

1993<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

Q4MAY1992<br />

3OJAN1992<br />

WAY1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.WE+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

0.00E+00<br />

0.00E+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

0.00€+00<br />

O.WE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+00<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

5.WE+00<br />

1.20€+01<br />

5.00E+W<br />

5.WE+00<br />

5.00E+W<br />

5.00€+00<br />

5.WE+00<br />

5.00E+00<br />

c<br />

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NT<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

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mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

w/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mgn<br />

mg1L<br />

mglL<br />

WlL<br />

mglL<br />

mgk<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

W L<br />

mglL<br />

mglL<br />

ugA<br />

mglL<br />

uglL<br />

uglL<br />

ugR<br />

uglL<br />

ugk<br />

uglL<br />

Page 15 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Ethylbenzene 100-41-4 1934-92 03NOV1992 WS 5.00E+00 < N ug1L<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCNS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCtMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

Gamma Activity<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

16984-48-8<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GAMMA<br />

1258746-1<br />

I 2587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

I 2587-46-1<br />

12587 -46- 1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

I 2587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

im7-47-2<br />

125a7-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

2098-92<br />

393-92<br />

516-92<br />

628-92<br />

697-92<br />

852-92<br />

393-92<br />

1072-93<br />

1145-95<br />

1202-93<br />

1202-94<br />

1376-94<br />

1546-93<br />

1612-94<br />

17-94<br />

i a95<br />

1836-93<br />

1918-94<br />

21 21 -94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

435-95<br />

505-94<br />

631-95<br />

785-95<br />

899-94<br />

954-95<br />

393-92<br />

1072-93<br />

1145-95<br />

1202-93<br />

1202-94<br />

1346-93<br />

1376-94<br />

1546-93<br />

1612-94<br />

17-94<br />

18-95<br />

1836-93<br />

igia94<br />

2121-94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

6165-92<br />

631-95<br />

785-95<br />

800-93<br />

899-94<br />

954-95<br />

1072-93<br />

1145-95<br />

1202-93<br />

1202-94<br />

1346-93<br />

1376-94<br />

1546-93<br />

1612-94<br />

17-94<br />

18%<br />

1836-93<br />

01DEC1992<br />

30JAN1992<br />

16FEB1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

3OJANl992<br />

16JULl993<br />

06JUL1995<br />

OSAUGl993<br />

OJMAY 1994<br />

03JUN1994<br />

050CT1993<br />

01 JULl994<br />

05JAN1994<br />

O5JANl995<br />

04NOV1993<br />

05AUG1994<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

O2DECl 994<br />

04FEB1994<br />

O3MARl995<br />

03MAR1994<br />

05APR1995<br />

03MAY 1995<br />

08APRI 994<br />

OlJUNl995<br />

3WAN1992<br />

16JUL1993<br />

06JUL1995<br />

05AUG1993<br />

[HMAY 1994<br />

02SEP1993<br />

OUUN1994<br />

050CT1993<br />

OlJUL1994<br />

05JAN1994<br />

WAN1995<br />

04NOV1993<br />

05AUG1994<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

MNOV1994<br />

02DEC1994<br />

MFEB1994<br />

3WAN1992<br />

03MARl995<br />

OW1994<br />

11 NOV1992<br />

05APR1995<br />

03MAYl995<br />

02JUNl993<br />

WAPR1994<br />

01 JUNl995<br />

16JULl993<br />

06JULl995<br />

05AUGl993<br />

05MAYl994<br />

02SEP1993<br />

OUUNl994<br />

050CT1993<br />

OlJULl994<br />

WAN1994<br />

WAN1995<br />

04NOVl993<br />

Page 16 of 176<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.WE+OO<br />

1.00E+00 0.00€+00<br />

1.00E+00 2.00E-01<br />

1.00E+00 3.00E-01<br />

<strong>4.</strong>00E+00 1.60E+00<br />

-5.00E+00 2.60E+00<br />

O.OOE+OO 8.00E-01<br />

-l.OOE+OO 5.00E-01<br />

l.OOE+OO 8.00E-01<br />

-3.OOE+00 1.90E+00<br />

1 .00E+00 6.00E-01<br />

2.00E+00 7.00E-01<br />

O.OOE+OO 7.00E-01<br />

2.00E+00 l.IOE+OO<br />

-l.OOE+OO 5.00E-01<br />

1.00E+00 6.00E-01<br />

1.00€+00 8.00E-01<br />

1.00E+00 7.00E-01<br />

1.00€+00 6.00E-01<br />

0.00€+00 5.00E-01<br />

-2.WE+00<br />

l.OOE+W 5.00E-01<br />

O.OOE+OO 6.00E-01<br />

<strong>4.</strong>00€+00<br />

1.00€+00 8.00E-01<br />

l.WE+W 8.00E-01<br />

-1.00E+00 O.OOE+OO<br />

I.WE+W 6.00E-01<br />

1.00E+00 7.00E-01<br />

5.00E+00 l.OOE+OO<br />

6.00E+00 1.00E+00<br />

6.00E+00 1.00E+00<br />

7.00€+00 <strong>4.</strong>00E+00<br />

l.lOE+Ol 2.00E+00<br />

9.00E+00 <strong>4.</strong>00E+00<br />

5.00E+00 1 .OOE+OO<br />

1.40E+OI <strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

3.WE+00 1.00E+00<br />

8.00E+00 1.00E+00<br />

< N<br />

c<br />

N<br />

UJ<br />

N<br />

c<br />

N<br />

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N<br />

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V<br />

Q<br />

V<br />

V<br />

V<br />

N<br />

V FIELD<br />

V 0712-<br />

V<br />

V<br />

N<br />

V<br />

V<br />

N<br />

V<br />

V<br />

N<br />

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N<br />

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N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCiL<br />

pCiL<br />

pCVL<br />

pCilL<br />

pCVL<br />

pCVL<br />

pciR<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pciR<br />

pCVL<br />

pCVL<br />

pcik<br />

pciiL<br />

pCiL<br />

pCVL<br />

pCVL<br />

pCiL<br />

pCVL<br />

pCiL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pcin<br />

pCVL<br />

pcik<br />

pCi<br />

pcik<br />

pCilL<br />

pcin<br />

pCi<br />

pCilL<br />

pCi<br />

pCi


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Gross Beta 12587-47-2 1918-94 05AUG1994 WS 1.00E+01 3.00E+00 PCllL<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as ChC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOBHARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOBHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7 4 3 9 - 8 9 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

2121 -94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

6165-92<br />

631-95<br />

785-95<br />

800-93<br />

899-94<br />

954-95<br />

1072-93<br />

1202-93<br />

1202-94<br />

1346-93<br />

1376-94<br />

1546-93<br />

1612-94<br />

17-94<br />

18-95<br />

1836-93<br />

1918-94<br />

2121-94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

435-95<br />

505-94<br />

631-95<br />

785-95<br />

800-93<br />

899-94<br />

954-95<br />

18-95<br />

218-95<br />

435-95<br />

631-95<br />

785-95<br />

954-95<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621 -92<br />

17-94<br />

1793-92<br />

i 8-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

2121-94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

OZSEPl994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

3OJANl992<br />

03MAR1995<br />

O3MAR 1 994<br />

1 1 NOVl992<br />

05APR1995<br />

03MAY 1995<br />

02JUN1993<br />

08APRl994<br />

01JUN1995<br />

16JUL1993<br />

05AUG1993<br />

05MAY 1994<br />

02SEP1993<br />

03JUN1994<br />

050CT1993<br />

OlJULl994<br />

OSJANI 994<br />

05JANl995<br />

04NOV1993<br />

05AUG1994<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05APR1995<br />

03MAY1995<br />

O2JUNl 993<br />

08APR1994<br />

01JUN1995<br />

05JAN 1995<br />

03FEB1995<br />

03MARl995<br />

05APRl995<br />

03MAYl995<br />

01JUNl995<br />

04MAY1992<br />

16JUL1993<br />

01 JUN1992<br />

OSAUGl993<br />

(HMAY 1994<br />

06JUL1992<br />

02SEP1993<br />

OUUNl994<br />

03AUG1992<br />

050CT1993<br />

OlJUL1994<br />

3lAUGl992<br />

05JAN1994<br />

070CT1992<br />

WAN1 995<br />

04NOV1993<br />

05AUGl994<br />

03NOV1992<br />

01DEC1992<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

Page 17 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

9.00E+00 2.00E+00<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

2.00E+00 l.OOE+OO<br />

7.00E+00 2.00E+00<br />

5.00E+00 1.00E+00<br />

<strong>4.</strong>00E+00 2.00E+00<br />

3.00E+00 l.OOE+OO<br />

-l.OOE+OO<br />

2.00E+00 l.OOE+OO<br />

5.00E+00 2.00E+00<br />

l.OOE+OO<br />

2.00E+00 O.OOE+OO<br />

3.00E+00 1 .OOE+OO<br />

2.00E+00 O.OOE+OO<br />

6.00E+00 2.00E+00<br />

2.00E+00 O.OOE+OO<br />

7.50E+01<br />

8.00E+01<br />

5.00E+01<br />

8.60E+01<br />

6.60E+01<br />

<strong>4.</strong>60E+01<br />

6.60E+01<br />

5.20E+01<br />

6.20E+01<br />

5.60E+01<br />

6.20E+01<br />

6.20E+01<br />

<strong>4.</strong>60E+01<br />

<strong>4.</strong>50E+01<br />

6.80E+01<br />

7.20E+01<br />

5.60E+01<br />

5.20E+01<br />

5.60E+01<br />

5.20E+01<br />

5.20E+01<br />

3.80E+01<br />

7.70E+01<br />

<strong>4.</strong>60E+01<br />

<strong>4.</strong>50E+01<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

0.00E+00<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

l.WE+W<br />

l.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

X<br />

X<br />

X<br />

X<br />

N<br />

X<br />

X<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

pCilL<br />

pCilL<br />

pCi/L<br />

pCilL<br />

pCilL<br />

pCVL<br />

pCilL<br />

pCilL<br />

pCVL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCilL<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaCO3<br />

mglL CaCO3<br />

mglL CaCO3<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaCO3<br />

mglL CaCO3<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaCO3<br />

mglL CaC03<br />

mg/L CaC03<br />

mglL CaCO3<br />

mg/L CaC03<br />

mglL CaC03<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WIlL<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

7439-89-6 2859-94 02DEC1994 WS 0,00E+00 mglL<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-954<br />

7439-93-2<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

551 1-92<br />

619-93<br />

628-92<br />

631 -95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1072-93<br />

11 40-92<br />

1202-93<br />

1329-92<br />

1346-93<br />

1202-94<br />

1376-94<br />

1474-92<br />

1546-93<br />

1621-92<br />

161 2-94<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

2121-94<br />

2152-93<br />

218-95<br />

241 1-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

631-95<br />

634-93<br />

697-92<br />

800-93<br />

852-92<br />

899-94<br />

954-95<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621<br />

-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

619-93<br />

628-92<br />

785-95<br />

5511-92<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1072-93<br />

1 140-92<br />

04FEB1994<br />

3OJANl992<br />

O3MAR1995<br />

03MARl994<br />

19AUG1992<br />

05MAY 1993<br />

05MAR1992<br />

05APR1995<br />

05MAY 1993<br />

12MAR1992<br />

03MAYl995<br />

02JUN1993<br />

01 APRl992<br />

08APR1994<br />

04MAY 1992<br />

16JULl993<br />

01JUN1992<br />

OSAUG1993<br />

05MAY1994<br />

06JUL1992<br />

02SEP1993<br />

03JUNl994<br />

03AUG1992<br />

050CTl993<br />

01 JULl994<br />

31AUGl992<br />

05JAN1994<br />

070CT1992<br />

05JAN1995<br />

MNOV1993<br />

OSAUG1994<br />

03NOVl992<br />

01DEC1992<br />

02SEPl994<br />

lODECl993<br />

03FEB1995<br />

070CT1994<br />

MNOV1994<br />

02DEC1994<br />

MFEB1994<br />

30JAN1992<br />

03MARl995<br />

03MAR1994<br />

19AUGl992<br />

osMAY1993<br />

osMAR1992<br />

05APR1995<br />

05MAY1993<br />

lZMARl992<br />

03MAYl995<br />

02JUN1993<br />

01APRl992<br />

08APR1994<br />

01JUN1995<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

WAN 1 992<br />

19AUGl992<br />

05MAY1993<br />

05MAR1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY1992<br />

16JULl993<br />

01JUNl992<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

l.OOE+OO<br />

2.41 E+02<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

1.00E+00<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00€+00<br />

0.00E+00<br />

0.00E+00<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+W<br />

0.00E+00<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

0.00E+00<br />

O.OOE+W<br />

O.WE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.M)E+OO<br />

O.WE+W<br />

O.M)E+OO<br />

0.00E+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+W<br />

O.WE+W<br />

0.00E+W<br />

O.WE+W<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.WE+W<br />

O.WE+OO<br />

0.00E+00<br />

3.00€+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

C<br />

C<br />

<<br />

C<br />

C<br />

<<br />

<<br />

C<br />

C<br />

<<br />

<<br />

c<br />

c<br />

C<br />

U<br />

C<br />

<<br />

<<br />

C<br />

C<br />

<<br />

C<br />

C<br />

<<br />

U<br />

C<br />

<<br />

U<br />

C<br />

C<br />

<<br />

c<br />

U<br />

<<br />

C<br />

U<br />

<<br />

c<br />

C<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

m&<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

msR<br />

mgfl<br />

Page 18 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYlE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Magnesium 7439-95-4 1202-93 OSAUG1993 WS <strong>4.</strong>00E+00 N<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7 4 3 9 - 9 5 -4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7 4 3 9 - 95 -4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7 4 3 9 - 96 - 5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

21 21 -94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

628-92<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

1 a95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

2121-94<br />

2152-93<br />

21895<br />

2421-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

62892<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

OSMAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

01 JUL1994<br />

31AUG1992<br />

O5JAN 1994<br />

070CT1992<br />

05JAN1995<br />

04NOV1993<br />

OSAUGI 994<br />

03NOV1992<br />

01DEC1992<br />

02SEPl994<br />

10DEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

30JAN1992<br />

03MARl995<br />

03MAR1994<br />

19AUGl992<br />

05MAY1993<br />

05MAR1992<br />

05APR1995<br />

O5MAY 1993<br />

12MARl992<br />

03MAY 1995<br />

02JUN1993<br />

01 APRI 992<br />

08APR1994<br />

04MAY 1992<br />

16JULl993<br />

01JUN1992<br />

05AUG 1993<br />

05MAYI 994<br />

oGJUL1992<br />

02SEP1993<br />

03JUNl994<br />

03AUG1992<br />

050CT1993<br />

01 JULl994<br />

31AUG1992<br />

05JAN1994<br />

070CT1992<br />

%JAN1995<br />

04NOV1993<br />

OSAUG1994<br />

03NOV1992<br />

01 DEC1992<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

3OJANl992<br />

03MAR1995<br />

03MARl994<br />

19AUGl992<br />

05MAY1993<br />

05MAR1992<br />

05APRI995<br />

05MAY 1993<br />

12MAR1992<br />

03MAY 1995<br />

Page 19 of 176<br />

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3.OOE+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+OO<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

6.90E+01<br />

3.00E+00<br />

3.00E+00<br />

5.00E+00<br />

3.00E+00<br />

3.OOE+00<br />

<strong>4.</strong>00E+00<br />

3.OOE+00<br />

3.00E+00<br />

3.OOE+00<br />

<strong>4.</strong>00E+W<br />

2.WE+W<br />

3.OOE+00<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.00E+00<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

3.70E+O 1<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

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mgfl<br />

mglL<br />

WlL<br />

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mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Manganese 7439-96-5 800-93 02JUN1993 WS O.OOE+OO N mglL<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Methylene Chloride<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

75-09-2<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-90-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

852-92<br />

899-94<br />

1140-92<br />

1329-92<br />

1474-92<br />

1546-93<br />

1621 -92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

551 1-92<br />

619-93<br />

697-92<br />

852-92<br />

1020-92<br />

1 140-92<br />

1329-92<br />

1474-92<br />

162 1-92<br />

1793-92<br />

2098-92<br />

393-92<br />

5511-92<br />

619-93<br />

697-92<br />

852-92<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1020-92<br />

628-92<br />

1346-93<br />

1934-92<br />

628-92<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1934-92<br />

2098-92<br />

2121-94<br />

2152-93<br />

241 1-94<br />

2689-94<br />

1918-94<br />

218-95<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

551 1-92<br />

619-93<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

628-92<br />

01 APRl992<br />

08APR1994<br />

04MAY 1992<br />

OlJUN1992<br />

06JULl992<br />

03AUG1992<br />

050CT1993<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

30JAN1992<br />

19AUG1992<br />

OWAY 1993<br />

0WAR1992<br />

12MARl992<br />

01APR1992<br />

02SEP1993<br />

04MAY1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

30JAN1992<br />

19AUG1992<br />

05MAY 1993<br />

OSMAR 1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY 1992<br />

16JULl993<br />

01JUN1992<br />

05AUGl993<br />

WAY<br />

1994<br />

06JUL1992<br />

O2SEP1993<br />

03JUN1994<br />

03AUGl992<br />

050CTl993<br />

OlJULl994<br />

3lAUGl992<br />

WAN1 994<br />

070CT1992<br />

05JANl995<br />

04NOV1993<br />

05AUG1994<br />

03NOV1992<br />

01 DEC1992<br />

02SEP1994<br />

lODEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEBl994<br />

3OJANl992<br />

03MARl995<br />

O3MARl994<br />

19AUGl992<br />

OSMAY1993<br />

OSMAR1992<br />

05APR1995<br />

OSMAY 1993<br />

12MARl992<br />

03MAY 1995<br />

02JUN1993<br />

01APR1992<br />

08APRl994<br />

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O.OOE+OO<br />

O.OOE+OO<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

3.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

0 .OOE+ 00<br />

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O.OOE+W<br />

O.WE+OO<br />

0.00E+00<br />

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O.WE+W<br />

O.OOE+W<br />

5.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

0.00E+W<br />

O.WE+W<br />

0.00E+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

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N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 20 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Niobium 7440-03-1 1020-92 04MAYl992 WS 0.00€+00 C NT mg1L<br />

Niobium<br />

7440-03-1<br />

1140-92<br />

01JUN1992 ws<br />

C<br />

N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

1329-92 06JUL1992 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

1474-92 03AUG1992 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

1621 -92 31AUG1992 ws<br />

c<br />

N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

1793-92 070CT1992 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

1934-92 03NOV1992 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

2098-92 01 DECl992 ws<br />

C<br />

N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

393-92 30JANI 992 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

5511-92 19AUG1992 ws<br />

< N<br />

mg1L<br />

Niobium<br />

7440-03-1<br />

619-93 05MAY1993 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

628-92 OSMAR1992 ws<br />

C<br />

N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

697-92 12MARl992 ws<br />

< N<br />

mglL<br />

Niobium<br />

7440-03-1<br />

852-92 OlAPR1992 ws<br />

< N<br />

mglL<br />

Nitrate as Nitrogen<br />

N ITRATEAS N IT<br />

393-92 3OJAN1992 ws<br />

C<br />

N<br />

mglL<br />

Oil <strong>and</strong> Grease<br />

SO227<br />

393-92 30JAN1992 ws<br />

< N<br />

mglL<br />

PCB<br />

1336-36-3<br />

17-94 05JANl994 ws<br />

< N<br />

uglL<br />

PCB<br />

1336-36-3<br />

1860-92 190CT1992 ws<br />

C<br />

N<br />

uglL<br />

PCB<br />

1336-36-3<br />

1934-92 03NOV1992 ws<br />

< N<br />

uglL<br />

PCB<br />

1336-36-3<br />

393-92 3OJAN 1992 ws<br />

< N<br />

uglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1020-92 04MAY 1992 ws<br />

< NT mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1140-92<br />

01 JUN1992 ws<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1329-92 06JUL1992 ws<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1474-92 03AUG1992 ws<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1621-92 31 AUG 1992 ws<br />

N<br />

mgn<br />

Phosphorus (P)<br />

7723-14-0<br />

1793-92 07OCT1992 ws<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

193492 03NOVI 992 ws<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

2098-92 OlDEC1992 ws<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

393-92 3OJAN1992 ws<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

5511-92<br />

19AUGl992 ws<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

619-93 05MAY1993 ws<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

628-92 osMAR1992 ws<br />

< N<br />

mg1L<br />

Phosphorus (P)<br />

7723-14-0<br />

697-92 12MAR1992 ws<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

852-92 01APR1992 ws<br />

C<br />

N<br />

mgk<br />

Potassium<br />

7440-09-7<br />

1020-92 04MAY1992 ws<br />

NT mglL<br />

Potassium<br />

7440-09-7<br />

1072-93 16JUL1993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

I1 40-92 01 JUN1992 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1202-93 05AUGl993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1202-94 OSMAY 1994 ws<br />

<<br />

N<br />

mgk<br />

Potassium<br />

7440-09-7<br />

1329-92 06JUL1992 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1346-93 02SEPl993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1376-94 03JUN1994 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

147492 03AUGl992 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1546-93 050CT1993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1612-94 OlJULl994 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1621-92 3lAUGl992 ws<br />

N<br />

mgn<br />

Potassium<br />

7440-09-7<br />

17-94 05JAN1994 ws<br />

C<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1793-92 070CTI 992 ws<br />

N<br />

mgk<br />

Potassium<br />

7440-09-7<br />

18-95 05JAN1995 ws<br />

N<br />

mg1L<br />

Potassium<br />

7440-09-7<br />

1836-93 04NOV1993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1918-94 OSAUG1994 ws<br />

N<br />

mg1L<br />

Potassium<br />

7440-09-7<br />

1934-92 03NOV1992 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2098-92 01 DEC1992 ws<br />

J<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2121 -94 02SEP1994 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2152-93 1 ODECl993 ws<br />

<<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7 , 218-95 03FEB1995 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2411-94<br />

070CT1994 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2689-94 04NOV1994 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2859-94 02DEC1994 ws<br />

N<br />

WlL<br />

Potassium<br />

7440-09-7<br />

286-94 04FEB1994 ws<br />

<<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

393-92 3OJAN1992 ws<br />

N<br />

WlL<br />

Potassium<br />

7440-09-7<br />

435-95 03MAR1995 ws<br />

N<br />

mg/L<br />

Potassium<br />

7440-09-7<br />

505-94 03MAR1994 ws<br />

C<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

5511-92<br />

19AUGl992 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

619-93 05MAY1993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

628-92 05MAR1992 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

631-95 05APR1995 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

634-93 OWAY 1993 ws<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

697-92 12MAR1992 ws<br />

N<br />

mgk<br />

Potassium<br />

7440-09-7<br />

785-95 03MAY 1995 ws<br />

N<br />

WlL<br />

Potassium<br />

7440-09-7<br />

800-93 02JUN1993 ws<br />

N<br />

WlL<br />

Potassium<br />

7440-09-7<br />

852-92 01 APR1992 ws<br />

<<br />

N<br />

WlL<br />

Page 21 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Potassium 7440-09-7 899-94 00APR1994 WS 2.00E+00 < N malL<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Selenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Sileon<br />

Silicon<br />

Sillcon<br />

Sikon<br />

Sillcon<br />

Sillcon<br />

Silicon<br />

Sillcon<br />

Silicon<br />

Silicon<br />

Silmn<br />

Silicon<br />

Silicon<br />

Silicon<br />

S ilicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Sillcon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

12587-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12587-46-1<br />

12507-46-1<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

7440-10-8<br />

7440-10-0<br />

7440- 10-0<br />

7440-10-8<br />

7440-10-0<br />

7440-18-8<br />

7440-10-8<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-18-0<br />

7440-18-8<br />

7440-18-8<br />

7702-49-2<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

1145-95<br />

210-95<br />

435-95<br />

631 -95<br />

705-95<br />

800-93<br />

954-95<br />

1145-95<br />

218-95<br />

435-95<br />

631-95<br />

785-95<br />

800-93<br />

954-95<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

5511-92<br />

619-93<br />

620-92<br />

697-92<br />

852-92<br />

393-92<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621 -92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

igiaw<br />

1934-92<br />

2098-92<br />

21 21 -94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

628-92<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1020-92<br />

1140-92<br />

1329-92<br />

06JUL1995<br />

03FEB1995<br />

03MARl995<br />

05APRl995<br />

03MAY 1995<br />

02 JUNl993<br />

01JUN1995<br />

06JUL1995<br />

03FEB1995<br />

03MAR1995<br />

05APR1995<br />

03MAY 1995<br />

OZJUN1993<br />

01JUN1995<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3OJANl992<br />

19AUG1992<br />

05MAYl993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

3OJAN1992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUN1992<br />

05AUG1993<br />

05MAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

O3AUG 1992<br />

050CT1993<br />

01 JUL1994<br />

3lAUGl992<br />

05JAN1994<br />

070CT1992<br />

05JANl995<br />

04NOV1993<br />

05AUGl994<br />

03NOV1992<br />

01 DEC1992<br />

02SEPl994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

04FEBl994<br />

3OJAN1992<br />

ow1995<br />

03MAR1994<br />

19AUGl992<br />

05MAY1993<br />

05MARl992<br />

OSAPR 1995<br />

05MAY 1993<br />

12MAR1992<br />

03MAY 1 995<br />

02JUNl993<br />

01APR1992<br />

00APRl994<br />

04MAY1992<br />

OlJUNl992<br />

06JUL1992<br />

Page 22 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

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ws<br />

ws<br />

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ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

c<br />

N<br />

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< N<br />

< N<br />

< NT<br />

c<br />

N<br />

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< N<br />

< N<br />

< N<br />

c<br />

N<br />

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< N<br />

< N<br />

< N<br />

.z N<br />

< N<br />

NT<br />

N<br />

N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

<<br />

X<br />

J<br />

J<br />

J<br />

B<br />

J<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Silver 7440-22-4 1474-92 03AUG1992 WS O.OOE+OO < N mg1L<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifl conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specib conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

1621 -92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

5511-92<br />

619-93<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621-92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

21 21 -94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

628-92<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1072-93<br />

1145-95<br />

1202-93<br />

1202-94<br />

1346-93<br />

1376-94<br />

1546-93<br />

1612-94<br />

17-94<br />

18-95<br />

1836-93<br />

1918-94<br />

2121-94<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

435-95<br />

505-94<br />

631-95<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3OJANl992<br />

19AUG 1992<br />

OSMAY 1993<br />

O5MAR 1992<br />

1 ZMAR1992<br />

01 APRl992<br />

MMAY 1992<br />

16JUL1993<br />

01 JUNl992<br />

05AUG1993<br />

OSMAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

OlJULl994<br />

3lAUGl992<br />

05JAN1994<br />

07OCT1992<br />

OSJAN1995<br />

04NOV1993<br />

05AUG1994<br />

03NOV1992<br />

OlDEC1992<br />

02SEP1994<br />

10DEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

04FEB1994<br />

30JAN1992<br />

O3MAR 1995<br />

03MARl994<br />

19AUG1992<br />

WAY 1993<br />

05MAR1992<br />

OSAPR1995<br />

05MAY1993<br />

I ZMAR 1992<br />

03MAY1995<br />

OZJUNl993<br />

01 APRI 992<br />

O8APR 1994<br />

16JULl993<br />

06JUL1995<br />

OSAUG1993<br />

OSMAY 1994<br />

02SEP1993<br />

03JUNl994<br />

050CT1993<br />

01 JUL1994<br />

WAN1994<br />

WAN1995<br />

04NOV1993<br />

OSAUG1994<br />

02SEP1994<br />

lODEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

OSAPRl995<br />

Page 23 of 176<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.80E+01<br />

1.50E+01<br />

2.50E+01<br />

1.80€+01<br />

l.lOE+01<br />

3.20E+01<br />

2.30E+01<br />

2.10E+01<br />

2.1 OE+01<br />

1.00E+01<br />

2.50E+01<br />

1.80E+01<br />

1.70E+01<br />

1.40E+01<br />

2.70E+01<br />

2.3OE+01<br />

2.50E+01<br />

2.20E+01<br />

1.50E+01<br />

2.40E+01<br />

1.00E+01<br />

l.ZOE+Ol<br />

3.00E+01<br />

2.70E+01<br />

1.50E+01<br />

1.20E+01<br />

5.00E+01<br />

1,40E+01<br />

l.lOE+Ol<br />

3.40E+01<br />

6.00E+00<br />

1.7OE+OI<br />

2.10E+01<br />

6.00€+00<br />

1.30E+01<br />

8.00E+W<br />

1.80E+01<br />

8.00E+00<br />

8.00E+00<br />

2.17E+02<br />

1.22E+02<br />

2.44E+02<br />

I .65E+02<br />

2.72E+02<br />

2.45E+02<br />

1.70E+02<br />

2.41E+02<br />

2.01E+02<br />

2.74E+02<br />

2.38E+02<br />

2.62E+02<br />

2.7 1 E+02<br />

1.48€+02<br />

1.63E+02<br />

3.10E+02<br />

2.81€+02<br />

1.98E+02<br />

1.69€+02<br />

1.77E+02<br />

1.66€+02<br />

2.18E+02<br />

< N<br />

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N<br />

N<br />

mg/L<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

WlL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

msn.<br />

mglL<br />

mglL<br />

mglL<br />

m9R<br />

WlL<br />

mglL<br />

mgR<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg/L<br />

mglL<br />

mglL<br />

mg/L<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcrn<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Specific conductance SO145 785-95 03MAY1995 WS 1.23E+02 N umhoslcm<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

TOX<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Technetium-99<br />

Technetium99<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

TOX.<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

14133-76-7<br />

14133-76-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

800-93<br />

899-94<br />

954-95<br />

1020-92<br />

1072-93<br />

1140-92<br />

1202-93<br />

1202-94<br />

1329-92<br />

1346-93<br />

1376-94<br />

1474-92<br />

1546-93<br />

1612-94<br />

1621 -92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1934-92<br />

2098-92<br />

21 21 -94<br />

2152-93<br />

21a-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

5511-92<br />

619-93<br />

626-92<br />

631-95<br />

634-93<br />

697-92<br />

785-95<br />

800-93<br />

852-92<br />

899-94<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

393-92<br />

393-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

1934-92<br />

393-92<br />

5511-92<br />

619-93<br />

628-92<br />

697-92<br />

852-92<br />

393-92<br />

6165-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

02JUN1993<br />

08APR1994<br />

01JUN1995<br />

04MAY 1992<br />

26JUL1993<br />

01JUN1992<br />

05AUG1993<br />

05MAY 1994<br />

06JULl992<br />

02SEP1993<br />

OUUN1994<br />

03AUG 1992<br />

050CT1993<br />

OlJUL1994<br />

31AUG1992<br />

05JANl994<br />

070CT1992<br />

05JAN1995<br />

04NOV1993<br />

05AUG1994<br />

03NOV1992<br />

01 DECI 992<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

O2DECl994<br />

04FEB1994<br />

3OJAN1992<br />

03MARI 995<br />

03MARl994<br />

19AUG1992<br />

05MAY 1993<br />

05MARl992<br />

OSAPR1995<br />

OSMAY 1993<br />

12MARl992<br />

03MAY1995<br />

O2JUN 1993<br />

OlAPR1992<br />

08APRl994<br />

01 JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

3OJAN1992<br />

3OJAN1992<br />

04MAY1992<br />

OlJUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUGI 992<br />

070CT1992<br />

03NOV1992<br />

30JAN1992<br />

19AUG1992<br />

05MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

3OJAN1992<br />

1 I NOVI 992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

Page 24 of 176<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Thallium 7440-28-0 393-92 3OJAN1992 WS O.OOE+OO N<br />

mg1L<br />

Thallium ,<br />

7440-28-0<br />

5511-92 19AUG1992 ws<br />

N<br />

mg1L<br />

Thallium<br />

7440-28-0<br />

619-93<br />

05MAY 1993 ws<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

628-92 05MARl992 ws<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

697-92 12MAR1992 ws<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

852-92 01APRl992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1020-92 04MAY1992 ws<br />

NT mg1L<br />

Thorium<br />

7440-29-1<br />

1140-92 01JUN1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1329-92 06JUL1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1474-92 03AUG1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1621 -92 31 AUG 1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1793-92 070CT1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1934-92 03NOVl 992 ws<br />

N<br />

mg1L<br />

Thorium<br />

7440-29-1<br />

2098-92 01 DEC1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

393-92 3OJANl992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

5511-92<br />

19AUG1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

619-93 05MAY1993 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

628-92 05MAR1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

697-92 12MAR1992 ws<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

852-92 01 APRl992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1020-92 04MAY1992 ws<br />

NT mg/L<br />

Tin<br />

7440-31 -5<br />

1140-92 01JUN1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1329-92 06JUL1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1474-92 03AUG1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1621-92 31AUGl992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1793-92 070CT1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1934-92 03NOV1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

2098-92 01DEC1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

393-92 30JAN1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31 -5<br />

5511-92<br />

19AUG1992 ws<br />

N<br />

Tin<br />

7440-31 -5<br />

619-93 05MAY 1993 ws<br />

N<br />

mgk<br />

Tin<br />

7440-31-5<br />

628-92 05MAR1992 ws<br />

N<br />

mg1L<br />

Tin<br />

7440-31-5<br />

697-92 12MAR1992 ws<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

852-92 01 APRI 992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

1020-92 04MAY1992 ws<br />

NT WlL<br />

Titanium<br />

7440-32-6<br />

1140-92 OlJUN1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

1329-92 06JUL1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

1474-92 03AUG 1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

1621-92<br />

31AUG1992 ws<br />

N<br />

mg1L<br />

Titanium<br />

7440-32-6<br />

1793-92 070CT1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

1934-92 03NOV1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

2098-92 01DECl992 ws<br />

N<br />

rnglL<br />

Titanium<br />

7440-32-6<br />

393-92 3OJANl992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

5511-92<br />

19AUGl992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

619-93<br />

05MAY1993 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

628-92 05MAR1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

697-92 12MAR1992 ws<br />

N<br />

mglL<br />

Titanium<br />

7440-32-6<br />

852-92 01 APRl992 ws<br />

N<br />

mglL<br />

Toluene<br />

108-88-3<br />

1020-92 WAY1992 ws<br />

NT<br />

uglL<br />

Toluene<br />

108-88-3<br />

1140-92 01JUN1992 ws<br />

N<br />

ug/L<br />

Toluene I 08-88-3<br />

1329-92 06JUL1992 ws<br />

N<br />

uglL<br />

Toluene I 08-88-3<br />

1474-92 03AUG1992 ws<br />

N<br />

uglL<br />

Toluene<br />

108-88-3<br />

1621-92 31AUG1992 ws<br />

N<br />

uglL<br />

Toluene I 08-88-3<br />

1793-92 070CT1992 ws<br />

N<br />

uglL<br />

Toluene<br />

108-88-3<br />

1934-92 03NOV1992 ws<br />

N<br />

ugR<br />

Toluene I 08-88-3<br />

2098-92 01 DECl992 ws<br />

N<br />

uglL<br />

Toluene<br />

108-88-3<br />

393-92 30JAN1992 ws<br />

N<br />

uglL<br />

Toluene<br />

108-88-3<br />

516-92 16FEB1992 ws<br />

N<br />

uglL<br />

Toluene<br />

ioaaa-3<br />

628-92 O5MARl 992 ws<br />

N<br />

uglL<br />

Toluene I 08-88-3<br />

697-92 12MAR1992 ws<br />

N<br />

uglL<br />

Toluene<br />

ioa-88-3<br />

852-92 01 APRI 992 ws<br />

N<br />

uglL<br />

Total Organic Carbon 7440-44-0<br />

393-92 3OJAN1992 ws<br />

N<br />

mglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

1140-92 OlJUN1992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 15660-5<br />

1329-92 06JULI 992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

1474-92 03AUGl992 ws<br />

N<br />

uglL<br />

Trans-I ,2-Dichloroethene 15660-5<br />

1621-92 3lAUG1992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

1793-92 07OCT1992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

1934-92 03NOV1992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

mga-92 01 DEC1992 ws<br />

N wn<br />

Trans-I ,2-Dichloroethene 156-60-5<br />

393-92 3OJAN1992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

51692 I6FEB1 992 ws<br />

N<br />

uglL<br />

Trans-I .2-Dichloroethene 156-60-5<br />

628-92 05MAR1992 ws<br />

N<br />

IIglL<br />

Page 25 of 176


L.9 (continued)<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trans-1.2-Dichloroethene 156-60-5 697-92 12MAR1992 WS 5.00E+00 < N uglL<br />

Trichloroethene<br />

79-01-6<br />

1020-92 04MAY 1992 ws 1 .OOE+OO<br />

C<br />

NT<br />

uglL<br />

Trichloroethene<br />

79-01-6<br />

1140-92<br />

01JUN1992 ws l.OOE+OO<br />

<<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01-6<br />

1329-92 06JUL1992 ws l.OOE+OO<br />

C<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01-6<br />

1474-92 O3AUG 1992 ws l.OOE+OO<br />

C<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01-6<br />

1621-92 3lAUGl992 ws l.OOE+OO<br />

<<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01 -6<br />

1793-92 070CT1992 ws l.OOE+OO<br />

C<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01 -6<br />

1934-92 03NOV1992 ws l.OOE+OO<br />

c<br />

N<br />

ug/L<br />

Trichloroethene<br />

79-01 -6<br />

2098-92 01 DEC1992 ws l.OOE+OO<br />

<<br />

N<br />

ug1L<br />

Trichloroethene<br />

79-01-6<br />

393-92 3OJANl992 ws l.OOE+OO<br />

<<br />

N<br />

uglL<br />

Trichloroet hene<br />

79-01-6<br />

516-92 16FEBl992 ws 1.00E+03<br />

UJ<br />

N<br />

ug1L<br />

Trichloroethene<br />

79-01-6<br />

628-92 05MAR1992 ws l.OOE+OO<br />

<<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01-6<br />

697-92 12MAR1992 ws l.OOE+OO<br />

C<br />

N<br />

uglL<br />

Trichloroethene<br />

79-01-6<br />

852-92 01APR1992 ws 1.00E+00<br />

C<br />

N<br />

ug1L<br />

Tungsten<br />

7440-33-7<br />

1020-92 MMAY 1992 ws O.OOE+OO<br />

C<br />

NT mglL<br />

Tungsten<br />

7440-33-7<br />

1140-92<br />

01JUN1992 ws 0.00E+00<br />

<<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

1329-92 06JUL1992 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

1474-92 03AUG1992 ws 0.00E+00<br />

<<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

1621-92 31AUG1992 ws O.OOE+W<br />

C<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

1793-92 070CT1992 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

1934-92 03NOV1992 ws O.WE+Ml<br />

C<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

2098-92 01DEC1992 ws O.OOE+W<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

5511-92 19AUG1992 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

619-93 O5MAY 1993 ws O.WE+OO<br />

c<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

628-92 05MAR 1992 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

697-92 12MARl992 ws O.OOE+W<br />

<<br />

N<br />

mglL<br />

Tungsten<br />

7440-33-7<br />

852-92 01 APRI 992 ws O.OOE+W<br />

<<br />

N<br />

mg1L<br />

Uranium<br />

7440-61 -1<br />

1020-92 04MAY 1992 ws O.WE+OO<br />

C<br />

NT mgR<br />

Uranium<br />

7440-61 -1<br />

1072-93 16JUL1993 ws O.WE+W<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

1140-92<br />

01JUN1992 ws O.OOE+W<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

1202-93 05AUG1993 ws O.WE+OO<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

1202-94 OSMAY 1994 ws O.WE+OO<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

1329-92 06JUL1992 ws O.WE+W<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

134693 02SEP1993 ws O.WE+OO<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

1376-94 03JUN1994 ws O.OOE+OO<br />

C<br />

N<br />

mgk<br />

Uranium<br />

7440-61-1<br />

1474-92 03AUGl992 ws O.WE+OO<br />

<<br />

NT mglL<br />

Uranium<br />

7440-61 -1<br />

1546-93 050CTl993 ws O.WE+W<br />

<<br />

N<br />

mg1L<br />

Uranium<br />

7440-61-1<br />

1612-94 01 JUL1994 ws O.OOE+OO<br />

C<br />

N mga<br />

Uranium<br />

7440-61-1<br />

1621-92<br />

3lAUG 1992 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

17-94 05JAN1994 ws O.WE+W<br />

c<br />

N<br />

mgk<br />

Uranium<br />

7440-61-1<br />

1793-92 070CT1992 ws O.WE+W<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

18-95 WAN1995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

183693 MNOV1993 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

1918-94 OSAUG1994 ws O.WE+W<br />

<<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

1934-92 03NOV1992 ws O.OOE+W<br />

<<br />

N<br />

mg/L<br />

Uranium<br />

7440-61-1<br />

2098-92 01DEC1992 ws O.OOE+W<br />

C<br />

N<br />

mgfl<br />

Uranium<br />

7440-61-1<br />

2121-94 OZSEPl994 ws O.WE+W<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

2152-93 lODEC1993 ws O.WE+W<br />

c<br />

N<br />

mgfl<br />

Uranium<br />

7440-61 -1<br />

21895 03FEBl995 ws O.WE+W<br />

C<br />

N<br />

mg/L<br />

Uranium<br />

7440-61 -1<br />

2411-94 070CT1994 ws O.WE+W<br />

c<br />

N<br />

mg/L<br />

Uranium<br />

7440-61-1<br />

2689-94 MNOV1994 ws O.WE+W<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

2859-94 02DEC1994 ws O.WE+W<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

286-94 MFEB1994 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

393-92 30JAN1992 ws O.WE+W<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

435-95 03MARl 995 ws O.OOE+W<br />

<<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

505-94 03MAR1994 ws O.OOE+OO<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

516-92 16FEB1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

5511-92<br />

19AUG1992 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

6165-92 llNOV1992 ws O.WE+OO<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

619-93 OSMAY 1993 ws O.WE+OO<br />

c<br />

N<br />

mg/L<br />

Uranium<br />

7440-61-1<br />

628-92 05MAR1992 ws O.WE+W<br />

C<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

631-95 05APR1995 ws O.WE+W<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

697-92 12MAR1992 ws O.WE+W<br />

c<br />

N mgn<br />

Uranium<br />

7440-61-1<br />

785-95 03MAYl995 ws O.WE+W<br />

c<br />

N mgR<br />

Uranium<br />

7440-61-1<br />

800-93 02JUN1993 ws O.WE+W<br />

c<br />

N<br />

mgfl<br />

Uranium<br />

7440-61 -1<br />

852-92 OIAPR1992 ws O.WE+OO<br />

c<br />

N<br />

mg/L<br />

Uranium<br />

7440-61-1<br />

899-94 08APR1994 ws O.WE+W<br />

c<br />

N<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

95495 OlJUNl995 ws O.WE+OO<br />

c<br />

N<br />

mgfl<br />

Vanadium<br />

7440-62-2<br />

1020-92 04MAY 1992 ws O.WE+W<br />

c<br />

NT mgfl<br />

Vanadium<br />

7440-62-2<br />

1140-92<br />

01JUNl992 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Vanadium<br />

7440-62-2<br />

1329-92 06JUL1992 ws O.WE+W<br />

c<br />

N<br />

mglL<br />

Vanadium<br />

7440-62-2<br />

1474-92 03AUGl992 ws O.WE+W<br />

c<br />

N<br />

mgfl<br />

Page 26 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Vanadium 7440-62-2 1621 -92 31AUGl992 WS O.OOE+OO < N mglL<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

1330-20-7<br />

7440-66-6<br />

7440-67-7<br />

1934-92<br />

2098-92<br />

393-92<br />

551 1-92<br />

619-93<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

11 40-92<br />

1329-92<br />

1474-92<br />

1621-92<br />

1793-92<br />

2098-92<br />

393-92<br />

516-92<br />

628-92<br />

697-92<br />

1020-92<br />

1140-92<br />

1329-92<br />

147492<br />

162 1-92<br />

1793-92<br />

1934-92<br />

2098-92<br />

393-92<br />

61 9-93<br />

628-92<br />

852-92<br />

1020-92<br />

1 140-92<br />

1329-92<br />

1621-92<br />

1934-92<br />

2098-92<br />

393-92<br />

551 1-92<br />

61 9-93<br />

628-92<br />

697-92<br />

852-92<br />

1020-92<br />

1064-92<br />

1072-93<br />

1093-92<br />

1140-92<br />

1 145-95<br />

1192-92<br />

1202-93<br />

1202-94<br />

1219-92<br />

126492<br />

1306-92<br />

1934-92<br />

852-92<br />

5511-92<br />

697-92<br />

1474-92<br />

1793-92<br />

1 108-92<br />

1329-92<br />

1346-93<br />

1366-92<br />

1376-94<br />

1415-92<br />

1474-92<br />

1546-93<br />

1441<br />

-92<br />

1500-92<br />

03NOV1992<br />

01 DEC1992<br />

30JAN1992<br />

19AUG1992<br />

O5MAY 1993<br />

O5MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

30JANI 992<br />

16FEB1992<br />

OSMAR1992<br />

12MARl992<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

30JAN1992<br />

19AUG1992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

3OJANl992<br />

19AUG1992<br />

O5MAY 1993<br />

osMAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

13MAY 1992<br />

16JULl993<br />

2WAY 1992<br />

26MAY1992<br />

01 JUN1992<br />

06JULl995<br />

O8JUNl992<br />

05AUG1993<br />

QWY<br />

1994<br />

15JUN1992<br />

22JUN1992<br />

29JUN1992<br />

06JULl992<br />

02SEP1993<br />

13JUL1992<br />

OUUN1994<br />

21JUL1992<br />

27JULl992<br />

O3AUG1992<br />

I OAUG1992<br />

050CT1993<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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c<br />

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UJ<br />

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N<br />

N<br />

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N<br />

N<br />

N<br />

NT<br />

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N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

SU<br />

su<br />

su<br />

su<br />

SU<br />

SU<br />

su<br />

SU<br />

su<br />

SU<br />

su<br />

su<br />

SU<br />

SU<br />

su<br />

SU<br />

su<br />

SU<br />

su<br />

SU<br />

su<br />

SU<br />

mglL<br />

Page 27 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

SO296 1548-92 17AUG1992 WS 7.00E+00 N su<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SWU 8, C746K-2<br />

1,l-Dchloroethane<br />

1,l-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 .l -Dchloroethane<br />

1 ,l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichbroethane<br />

1 .I-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,l-Dichloroethene<br />

1.1 -Dichloroethene<br />

1 ,l -Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1,l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-354<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-354<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1596-92<br />

1612-94<br />

1621 -92<br />

1659-92<br />

1681-92<br />

17-94<br />

1793-92<br />

18-95<br />

1836-93<br />

1918-94<br />

1964-92<br />

2098-92<br />

2121-94<br />

2134-92<br />

2152-93<br />

218-95<br />

2411-94<br />

2689-94<br />

2859-94<br />

286-94<br />

393-92<br />

435-95<br />

505-94<br />

609-92<br />

619-93<br />

628-92<br />

631-95<br />

634-93<br />

653-92<br />

697-92<br />

709-92<br />

785-95<br />

800-93<br />

824-92<br />

852-92<br />

886-92<br />

899-94<br />

919-92<br />

954-95<br />

973-92<br />

991-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099 - 92<br />

629-92<br />

69892<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

193592<br />

2099-92<br />

24AUG1992<br />

01 JUL1994<br />

31 AUG1992<br />

OlSEPl992<br />

14SEP1992<br />

05JAN1994<br />

070CT1992<br />

OSJAN1995<br />

04NOV1993<br />

05AUG1994<br />

09NOV1992<br />

01DEC1992<br />

02SEP1994<br />

07DEC1992<br />

lODEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOV1994<br />

O2DECl994<br />

04FEB1994<br />

3OJAN1992<br />

03MAR1995<br />

03MAR1994<br />

02MAR1992<br />

OSMAY 1993<br />

05MAR1992<br />

OJAPR 1995<br />

OSMAY 1993<br />

OW1992<br />

12MAR1992<br />

16MAR1992<br />

03MAY 19%<br />

02JUN1993<br />

23MAR1992<br />

01 APRl992<br />

06APR1992<br />

08APR1994<br />

13APR1992<br />

01JUN1995<br />

22APR1992<br />

27APRl992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

OJNOV1992<br />

01 DECl992<br />

05MAR 1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY1992<br />

01JUN1992<br />

06JULl992<br />

O3AUG 1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

WAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CTl992<br />

03NOV1992<br />

01 DECl992<br />

Page 28 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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INS<br />

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su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

ug/L<br />

mg/L<br />

mglL<br />

mgk<br />

mglL<br />

WlL<br />

mglL<br />

mgfl<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL'fTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Aluminum 7429-90-5 620-93 05MAY1993 WS 1.00E+00 N mglL<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7143-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

05MAR1992<br />

12MAR1992<br />

01APRl992<br />

04MAY 1992<br />

OlJUN1992<br />

06JUL1992<br />

O3AUG 1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1 992<br />

01JUN1992<br />

O6JUL1 992<br />

03AUG1992<br />

3lAUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

05MARl992<br />

12MAR1992<br />

01 APRI 992<br />

04MAY 1992<br />

01 JUNl992<br />

06JUL1992<br />

03AUG1992<br />

3lAUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY1993<br />

05MARl992<br />

1 2MARl 992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

MAR1992<br />

12MARl992<br />

01 APR1992<br />

04MAY 1992<br />

OlJUNl992<br />

06JULl992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

MAY1993<br />

05MAR1 992<br />

12MAR1992<br />

01APR1992<br />

04MAYI992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

Page 29 of 176<br />

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mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

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mglL<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

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mglL<br />

wfl<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Bismuth 7440-69-9 629-92 05MAR1992 WS O.OOE+OO C N<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Coban<br />

Coban<br />

Coban<br />

Coban<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Coban<br />

Coban<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-439<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-484<br />

7440-484<br />

7440-48-4<br />

7440-484<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-70-2<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-0<br />

7440-50-0<br />

7440-50-8<br />

7440-50-8<br />

100-414<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1794-92<br />

1622-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021<br />

-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

69892<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

629-92<br />

1622-92<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

OlJUN1992<br />

06JULI 992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOVl992<br />

OlDEC1992<br />

05MAY1993<br />

05MAR1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

(HMAY 1993<br />

osMAR1992<br />

1 ZMARI 992<br />

01 APRI 992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY1993<br />

%MAR1992<br />

12MARl992<br />

01APR1992<br />

04MAY 1992<br />

0 1 JUN 1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG1992<br />

070CTl992<br />

03NOV1992<br />

01DEC1992<br />

05MAR1992<br />

ws<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

1.90€+01<br />

1.90E+01<br />

2.00E+Ol<br />

1.70€+01<br />

1.80€+01<br />

1.50E+01<br />

1.70€+01<br />

1.50€+01<br />

1.20E+01<br />

1.40E+01<br />

l.lOE+Ol<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

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O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

5.00E+W<br />

5.WE+00<br />

1.60E+01<br />

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5.00E+00<br />

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5.00E+W<br />

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Page 30 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE MPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Ethylbenzene 100-41-4 698-92 12MAR1992 WS 5.00E+00 c N ug1L<br />

Ethylbenzene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lilhium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

100-41 -4<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439 - 89 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439 - 95 -4<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

179492<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

179492<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

01APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

OIAPRI 992<br />

04MAY1992<br />

OlJUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MARl992<br />

01 APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRI 992<br />

04MAYl992<br />

01 JUNl992<br />

06JULl992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAYl993<br />

(HMAR 1992<br />

12MARl992<br />

01 APRI 992<br />

MMAY 1992<br />

01JUN1992<br />

06JUL1992<br />

O3AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOVl 992<br />

01 DECl992<br />

OSMAY 1993<br />

05MARI 992<br />

12MARl992<br />

01 APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31 AUGI 992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

05MAR1992<br />

Page 31 of 176<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

m!35<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Wfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

WR<br />

mglL


L.9 (continued)<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Mercury 7439-97-6 698-92 12MARl992 WS O.OOE+OO c N mglL<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98.7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-18-8<br />

7440-188<br />

7440-18-8<br />

7440-188<br />

7440-18-8<br />

7440-18-8<br />

7440-188<br />

7440-188<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1861-92<br />

1935-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

OMAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APRl992<br />

04MAY1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

WAY1993<br />

WAR1992<br />

12MAR1992<br />

01 APRl992<br />

190CT1992<br />

03NOV1992<br />

WAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

WAY1993<br />

WAR1992<br />

12MARl992<br />

OlAPR1992<br />

MAY1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3IAUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

OSMAY 1993<br />

05MAR1992<br />

12MARI 992<br />

01 APRl992<br />

04MAYl992<br />

OlJUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

<<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

vvs<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Ruthenium 7440-18-8 620-93 05MAY1993 WS O.OOE+OO < N mg1L<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

12 143-45-2<br />

12 143-45-2<br />

12 143-45-2<br />

12143-45-2<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

1440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

1440-28-0<br />

7440-28-0<br />

1440-28-0<br />

7440-28-0<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY1992<br />

01JUN1992<br />

06JUL1992<br />

O3AUG 1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

05MAR1992<br />

1 2MARl 992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUG 1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OCMAYI 993<br />

O5MARl 992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31AUG1992<br />

04MAY 1992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OMAY 1993<br />

05MARl992<br />

12MAR1992<br />

01 APRI 992<br />

04MAY 1992<br />

OlJUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

Page 33 of 176<br />

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N<br />

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N<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

WlL<br />

mg/L<br />

mgfl<br />

Wk<br />

mglL<br />

WlL<br />

Wk<br />

WlL<br />

mglL<br />

Wfl<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Thallium 7440-28-0 1794-92 070CT1992 WS O.OOE+OO < N mglL<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I .'L-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trihloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

7440-31 -5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

I 08-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021 -92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141 -92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

O5MARl 992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

(HMAY 1993<br />

OSMAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY1992<br />

01 JUN1992<br />

06JULl992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

05MAR1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOVl992<br />

01DECl992<br />

05MAR1992<br />

12MAR1992<br />

OIAPRI 992<br />

04MAY1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

07OCT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAR 1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY1992<br />

OlJUN1992<br />

06JULl992<br />

03AUGl992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

Page 34 of 176<br />

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N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mgll<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

wfl<br />

mglL<br />

mgfl<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

ugfl<br />

ugfl<br />

ug1L<br />

wfl<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

ugk<br />

ugfl<br />

ugfl<br />

ugfl<br />

uglL<br />

wfl<br />

ugfl<br />

ugfl<br />

ugfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trichloroethene 79-01-6 2099-92 OlDEC1992 WS 1.00E+00<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61<br />

-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-666<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1935-92<br />

2099-92<br />

620-93<br />

698-92<br />

853-92<br />

1141-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

2099-92<br />

629-92<br />

698-92<br />

853-92<br />

1021<br />

-92<br />

11 41 -92<br />

1330-92<br />

1475-92<br />

1141-92<br />

629-92<br />

1021-92<br />

1330-92<br />

1935-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

698-92<br />

853-92<br />

1021-92<br />

1141-92<br />

1330-92<br />

1475-92<br />

1622-92<br />

1794-92<br />

1935-92<br />

2099-92<br />

620-93<br />

629-92<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

MMAYl992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

OSMARl992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31 AUGl992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

OlJUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

O3AUG 1992<br />

31 ALJG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

0 1 APR 1 992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

(HMAY 1 993<br />

05MAR1992<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

1.00E+01<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

0.00E+00<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

0 .OOE+ 00<br />

O.OOE+W<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

c<br />

c<br />

c<br />

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uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mgk<br />

mgfl<br />

mgk<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

m9fl<br />

mglL<br />

mglL<br />

mglL<br />

Page 35 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Zirconium 7440-67-7 698-92 12MAR1992 WS O.OOE+OO < N mglL<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7. smu a. ~ 7 4 6 ~<br />

1 ,I-Dichloroethane<br />

1 ,l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .l-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

so296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

853-92<br />

1021-92<br />

1065-92<br />

1094-92<br />

1109-92<br />

1141-92<br />

1193-92<br />

1220-92<br />

1265-92<br />

1307-92<br />

1330-92<br />

1367-92<br />

1416-92<br />

1442-92<br />

1475-92<br />

1501-92<br />

1549-92<br />

1597-92<br />

1622-92<br />

1660-92<br />

1682-92<br />

1794-92<br />

1965-92<br />

2099-92<br />

2135-92<br />

610-92<br />

620-93<br />

629-92<br />

654-92<br />

698-92<br />

710-92<br />

825-92<br />

853-92<br />

887-92<br />

920-92<br />

974-92<br />

992-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

01 APRl992<br />

04MAY 1992<br />

13MAY 1992<br />

20MAYl992<br />

26MAY 1992<br />

01JUN1992<br />

08JUN1992<br />

15JUNl992<br />

22JUN1992<br />

29JUN1992<br />

06JUL1992<br />

13JUL1992<br />

21 JUL1992<br />

27JUL1992<br />

03AUG1992<br />

10AUG1992<br />

17AUG1992<br />

24AUG1992<br />

31AUG1992<br />

08SEPl992<br />

14SEP1992<br />

070CT1992<br />

09NOV1992<br />

01DEC1992<br />

07DEC1992<br />

02MAR1992<br />

OWY 1993<br />

05MAR1992<br />

OM1992<br />

12MAR 1992<br />

16MAR1992<br />

23MAR1992<br />

01APR1992<br />

06APR1992<br />

13APR1992<br />

2ZAPR1992<br />

27APR1992<br />

04MAY 1992<br />

01JUNl992<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY1992<br />

01 JUN1992<br />

-1992<br />

12MAR1992<br />

OlAPR1992<br />

MY1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY1992<br />

01 JUN1992<br />

osMAR1992<br />

12MAR1992<br />

01 APR 1992<br />

MY1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

OlAPR1992<br />

my1992<br />

OlJUNl992<br />

osMAR1992<br />

Page 36 of 176<br />

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uglL<br />

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ug1L<br />

uglL<br />

ma/L<br />

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mglL<br />

WIL<br />

mgk<br />

mgk<br />

Wfl<br />

mglL<br />

mgfl<br />

mgnuglL<br />

ugk<br />

UdL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Benzene 71-43-2 699-92 12MAR1992 WS 5.00E+00 c N UglL<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Coban<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Gross Alpha<br />

Gross Beta<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithiurn<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-414<br />

12587-46-1<br />

12587-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

4952-92<br />

4952-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR 1992<br />

01APR1992<br />

04MAY1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUNl992<br />

05MAR1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY 1 992<br />

01 JUN1992<br />

05MARl992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MARl992<br />

01 APR 1992<br />

04MAY1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

12MAY 1992<br />

1 2MAY 1992<br />

04MAY1992<br />

01 JUNl992<br />

MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY 1992<br />

01JUN1992<br />

(HMAR1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY 1992<br />

01JUNl992<br />

05MAR1992<br />

Page 37 of 176<br />

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N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

ug1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mgfl<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

ug/L<br />

uglL<br />

ug1L<br />

ug1L<br />

ugfl<br />

pciR<br />

pCiL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mgn<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Mercury 7439-97-6 699-92 12MAR1992 WS O.OOE+OO < N mglL<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Sulfate<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Technetium99<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tm<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439 - 9 a - 7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-21-3<br />

7440-21 -3<br />

1440-21 -3<br />

7440-21 -3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

12143-45-2<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

14133-76-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-2&0<br />

7440-29-1<br />

7440-29- I<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1142-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

4952-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

I 142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

01 APRl992<br />

MMAY1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAY 1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MARl992<br />

01 APRI 992<br />

04MAY1992<br />

01 JUN1992<br />

05MARl992<br />

12MAR 1992<br />

01 APRI 992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MARl992<br />

01APR1992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MARl992<br />

OlAPRl992<br />

04MAY1992<br />

01JUNl992<br />

oEiMARl992<br />

12MAR1992<br />

01 APRl992<br />

04MAY1992<br />

01JUN1992<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY1992<br />

01JUNl992<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

01JUN1992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

12MAY 1992<br />

04MAY 1 992<br />

OIJUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRI 992<br />

04MAY 1992<br />

01 JUNI 992<br />

05MAR1992<br />

12MAR1992<br />

01 APRI 992<br />

MMAY 1992<br />

01JUN1992<br />

oEiMAR1992<br />

Page 38 of 176<br />

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N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

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N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Tin 7440-31-5 699-92 12MAR1992 WS O.OOE+OO < N mg1L<br />

Tin<br />

Tikanium<br />

Titanium<br />

Tiianium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-l,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans- 1,2-Dichloroeihene<br />

Trans-1.2-Dichloroethene<br />

Trans-l,2-Dichloroeihene<br />

Trichloroet hene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7. S MU 8. C746K-3A<br />

7440-31-5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 - 1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

4952-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1142-92<br />

630-92<br />

699-92<br />

854-92<br />

1022-92<br />

1066-92<br />

1095-92<br />

1110-92<br />

1142-92<br />

1194-92<br />

1221-92<br />

611-92<br />

630-92<br />

655-92<br />

699-92<br />

711-92<br />

826-92<br />

854-92<br />

886-92<br />

921-92<br />

975-92<br />

993-92<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

05MARl992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

O5MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

12MAR 1992<br />

01 APRI 992<br />

O4MAY 1992<br />

01JUN1992<br />

05MAR1992<br />

1 2MARl 992<br />

01 APRl992<br />

04MAYI 992<br />

01 JUN1992<br />

12MAY1992<br />

05MAR1992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY 1992<br />

01JUN1992<br />

OSMAR1992<br />

12MARl992<br />

01APR1992<br />

04MAY 1992<br />

01 JUNl992<br />

05MAR1992<br />

12MARl992<br />

01 APRI 992<br />

04MAY1992<br />

01 JUNl992<br />

05MAR1992<br />

12hMRI 992<br />

01 APRl992<br />

04MAY1992<br />

01 JUN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY 1992<br />

13MAY 1992<br />

2WAY 1992<br />

26MAY 1992<br />

01 JUN1992<br />

08JUN1992<br />

15JUN1992<br />

02MAR1992<br />

OSMAR1992<br />

09MAR1992<br />

12MAR1992<br />

16MAR1992<br />

23MAR1992<br />

OlAPR1992<br />

06APR1992<br />

13APRl992<br />

22APR1992<br />

27APR1992<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

<<br />

c<br />

<<br />

c<br />

c<br />

c<br />

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c<br />

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c<br />

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c<br />

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c<br />

c<br />

c<br />

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c<br />

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c<br />

<<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

<<br />

<<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

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N<br />

N<br />

NT<br />

N<br />

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N<br />

N<br />

N<br />

NT<br />

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N<br />

N<br />

N<br />

N<br />

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N<br />

N<br />

rnglL<br />

rnglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

ug1L<br />

ug1L<br />

ug1L<br />

uglL<br />

UglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mgfl<br />

mglL<br />

WlL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

Wfl<br />

mglL<br />

mglL<br />

WlL<br />

mgfl<br />

mglL<br />

mglL<br />

mg/L<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

uglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

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su<br />

Page 39 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

1 ,l-Dichloroethane 75-34-3 1331-92 06JUL1992 ws 5.00E+00 < N uglL<br />

1 ,I-Dichloroethane<br />

1,l-Dichloroethane<br />

1 ,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1,l-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-354<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1837-93<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

16JULl993<br />

O5AUGl993<br />

05MAY1994<br />

06JULl992<br />

02SEPl993<br />

03JUN1994<br />

03AUGl992<br />

050CT1993<br />

01 JULl994<br />

31 AUG 1992<br />

070CT1992<br />

O5JAN1994<br />

04NOV1993<br />

5.00€+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

1.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00€+00<br />

i.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00€+00<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

c<br />

c<br />

C<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Aluminum<br />

7429-90-5<br />

19-95 05JAN1995<br />

O.OOE+OO<br />

N<br />

Aluminum ' 7429-90-5<br />

1919-94 05AUG1994<br />

0.00E+00<br />

N<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-360<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

207-94<br />

436-95<br />

506-94<br />

5510-92<br />

621-93<br />

632-95<br />

635-93<br />

786-95<br />

801 -93<br />

900-94<br />

1331 -92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

193692<br />

2100-92<br />

333-95<br />

5510-92<br />

621-93<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331 -92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

1919-94<br />

1936-92<br />

03NOV1992<br />

01DEC1992<br />

02SEPl994<br />

1 ODEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

O3MAR1995<br />

03MAR1994<br />

19AUG 1992<br />

OSMAY 1993<br />

05APRl995<br />

05MAY 1993<br />

03MAYl995<br />

02JUN1993<br />

O8APR1994<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

1 ONOV1993<br />

03NOV1992<br />

OlDECl992<br />

22FEB1995<br />

19AUG1992<br />

OSMAY 1993<br />

16JULl993<br />

05AUG1993<br />

05MAYl994<br />

06JUL1992<br />

02SEPl993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

01 JULl994<br />

31AUG1992<br />

070CT1992<br />

05JAN1994<br />

10NOV1993<br />

04NOV1993<br />

WAN1995<br />

05AUG1994<br />

03NOV1992<br />

0.00E+00<br />

O.OOE+W<br />

1.00E+00<br />

l.WE+OO<br />

1.00E+00<br />

O.OOE+W<br />

l.OOE+OO<br />

0.00E+W<br />

1.00E+00<br />

l.OOE+OO<br />

1.00E+00<br />

0.00E+00<br />

1.00E+00<br />

0.00E+00<br />

1 .OOE+OO<br />

1.00E+00<br />

0.00E+W<br />

1.00E+00<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.M)E+M)<br />

O.WE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

0.00E+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

0.00E+W<br />

0.00E+00<br />

0.00E+00<br />

O.WE+W<br />

O.WE+W<br />

N<br />

<<br />

c<br />

X<br />

c<br />

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Page 40 of 176<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

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ws<br />

ws


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Arsenic 7440-30-2 2100-92 01DEC1992 WS O.OOE+OO < N mglL<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

7440-30-2<br />

7440-382<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440 - 30 - 2<br />

7440-30-2<br />

7440-38-2<br />

7440-38-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7 44 0 - 3 9 - 3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7 1 -43-2<br />

7 1-43-2<br />

71-43-2<br />

7 1 -43-2<br />

7440-41-7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

207-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

621-93<br />

632-95<br />

635-93<br />

786-95<br />

801-93<br />

900-94<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

10-94<br />

1033-93<br />

1037-93<br />

19-95<br />

1919-94<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

207-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

621-93<br />

632-95<br />

635-93<br />

786-95<br />

801-93<br />

900-94<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

1936-92<br />

2100-92<br />

333-95<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

1623-92<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

22FEB1995<br />

O3MAR1995<br />

03MARl994<br />

19AUG1992<br />

05MAY 1993<br />

05APR1995<br />

O5MAY 1993<br />

O3MAY 1995<br />

02JUN1993<br />

OBAPRl994<br />

16JUL1993<br />

05AUGl993<br />

O5MAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

01 JULl994<br />

3lAUG1992<br />

070CT1992<br />

05JAN1994<br />

lONOV1993<br />

04NOVl993<br />

05JAN1995<br />

05AUG1994<br />

03NOV1992<br />

01 DEC1992<br />

02SEPl994<br />

lODECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

22FEB1995<br />

03MAR1995<br />

03MAR1994<br />

19AUG1992<br />

WAY 1993<br />

05APR1995<br />

05MAY 1993<br />

OJMAY 1995<br />

02JUN1993<br />

00APR1994<br />

06JULl992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

06JULl992<br />

03AUG1992<br />

3lAUG1992<br />

070CT1992<br />

10NOV1993<br />

03NOV1992<br />

01 DECl992<br />

22FEB1995<br />

19AUGl992<br />

WAY 1993<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

Page 41 of 176<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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N<br />

C<br />

N<br />

cs<br />

N<br />

C<br />

N<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Bismuth 7440-69-9 1795-92 070CT1992 WS O.OOE+OO<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

744047-3<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

1936-92<br />

2100-92<br />

5510-92<br />

621-93<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

I<br />

833-93<br />

1837-93<br />

19-95<br />

I91 9-94<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

621-93<br />

632-95<br />

635-93<br />

287-94<br />

786-95<br />

801-93<br />

900-94<br />

955-95<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

1936-92<br />

21 00-92<br />

333-95<br />

5510-92<br />

621-93<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

1833-93<br />

1837-93<br />

19-95<br />

191 9-94<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

2412-94<br />

la94<br />

03NOV1992<br />

01 DEC1992<br />

19AUG1992<br />

05MAY1993<br />

16JULl993<br />

05AUG1993<br />

O5MAY 1994<br />

06JUL1992<br />

02SEPl993<br />

03JUN1994<br />

03AUGl992<br />

050CT1993<br />

OlJUL1994<br />

31 AUG 1992<br />

070CT1992<br />

05JAN1994<br />

1 ONOVl993<br />

04NOV1993<br />

05JAN1995<br />

05AUG1994<br />

03NOV1992<br />

01DECl992<br />

OZSEPI 994<br />

10DEC1993<br />

03FEBl995<br />

070CT1994<br />

WNOV1994<br />

02DECl994<br />

04FEB1994<br />

22FEB1995<br />

03MAR1995<br />

03MAR1994<br />

19AUG 1992<br />

05MAY1993<br />

05APR1995<br />

05MAY 1993<br />

O3MAY 1995<br />

02JUN1993<br />

OBAPRl994<br />

01 JUN1995<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

I ONOVl993<br />

03NOV1992<br />

01DECl992<br />

22FEBl995<br />

19AUGl992<br />

05MAY1993<br />

16JUL1993<br />

05AUG1993<br />

05MAY1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

01 JULl994<br />

3lAUGl992<br />

07OCT1992<br />

05JAN1994<br />

lONOVl993<br />

WNOVI 993<br />

05JAN1995<br />

O5AUG I994<br />

03NOVI 992<br />

01 DECl992<br />

O2SEPl 994<br />

10DEC1993<br />

070CT1994<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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c<br />

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4<br />

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U<br />

<<br />

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<<br />

<<br />

<<br />

<<br />

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U<br />

U<br />

<<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium 7440-47-3 2690-94 04NOV1994 WS O.OOE+OO < N mg1L<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Coban<br />

Coban<br />

Coban<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Coban<br />

Coban<br />

Coban<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GClMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

GClMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GClMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

12587-46-1<br />

1258746-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

1258746-1<br />

12587-46-1<br />

1258746-1<br />

12587-46-1<br />

12581-46-1<br />

12587-46-1<br />

12587-46-1<br />

1258746-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

2860-94<br />

287-94<br />

333-95<br />

506-94<br />

5510-92<br />

621 -93<br />

635-93<br />

801-93<br />

900-94<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

1936-92<br />

2100-92<br />

333-95<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

1936-92<br />

2100-92<br />

333-95<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1073-93<br />

1146-95<br />

1203-94<br />

1377-94<br />

1547-93<br />

18-94<br />

1837-93<br />

19-95<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

436-95<br />

506-94<br />

632-95<br />

786-95<br />

900-94<br />

955-95<br />

1073-93<br />

1146-95<br />

1203-93<br />

1203-94<br />

1347-93<br />

1377-94<br />

1547-93<br />

1613-94<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

1919-94<br />

2122-94<br />

2153-93<br />

219-95<br />

02DECI 994<br />

04FEB1994<br />

22FEB1995<br />

03MAR1994<br />

19AUG 1992<br />

O5MAY 1993<br />

O5MAY 1993<br />

02JUN1993<br />

08APR1994<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

1 ONOV1993<br />

03NOV1992<br />

01DEC1992<br />

22FEB1995<br />

19AUG1992<br />

OSMAY 1993<br />

06JUL1992<br />

O3AUG 1992<br />

31AUG1992<br />

070CT1992<br />

1 ONOVl993<br />

03NOV1992<br />

01DEC1992<br />

22FEBl995<br />

19AUG1992<br />

OSMAYl993<br />

06JUL1992<br />

03AUGl992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

16JUL1993<br />

06JUL1995<br />

05MAY I 994<br />

03JUN1994<br />

050CT1993<br />

05JANl994<br />

04NOVI 993<br />

05JANl995<br />

1 ODECl993<br />

03FEB1995<br />

07OCT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05APR1995<br />

03MAY 19%<br />

08APR1994<br />

01 JUN1995<br />

16JUL1993<br />

06JULl995<br />

OSAUG1993<br />

05MAY 1994<br />

02SEP1993<br />

03JUNl994<br />

050CTl993<br />

OlJULl994<br />

OSJANl994<br />

10NOV1993<br />

MNOV1993<br />

05JAN1995<br />

05AUG1994<br />

O2SEPl994<br />

lODEC1993<br />

03FEB1995<br />

Page 43 of 176<br />

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O.OOE+OO<br />

O.WE+OO<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+00<br />

5.00E+W<br />

5.00E+00<br />

5.00E+W<br />

5.00E+00<br />

5.WE+W<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

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O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

l.OOE+W O.OOE+OO<br />

O.OOE+OO 1.00E-01<br />

5.WE+00 1.60E+00<br />

3.OOE+00 1.30E+00<br />

9.00E+00 2.70E+00<br />

1.00E+00 6.00E-01<br />

I.WE+OO 7.WE-01<br />

l.OOE+OO I .00E+00<br />

I.OOE+W 5.00E-01<br />

-3.00E+00 1.90E+00<br />

O.OOE+OO 1.00E-01<br />

O.WE+W 7.00E-01<br />

2.00E+00 2.20E+W<br />

3.OOE+00 2.40E+00<br />

2.00E+W 1.00E+00<br />

I .00E+00 6.00E-01<br />

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uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug/L<br />

uglL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCiL<br />

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pCiL<br />

pCilL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Gross Alpha 12587-46-1 2412-94 070CT1994 WS 2.00E+00 l.OOE+OO PCVL<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Bela<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

1258747-2<br />

12587-47-2<br />

1258747-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CAC03HARDNES<br />

CACOIHARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CACO3HARDNES<br />

CACO3HARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

436-95<br />

506-94<br />

6164-92<br />

632-95<br />

786-95<br />

801-93<br />

900-94<br />

955-95<br />

1073-93<br />

1146-95<br />

1203-93<br />

1203-94<br />

1347-93<br />

1377-94<br />

1547-93<br />

1613-94<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

1919-94<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

436-95<br />

506-94<br />

6 164-92<br />

632-95<br />

786-95<br />

801 -93<br />

900-94<br />

955-95<br />

1073-93<br />

1203-93<br />

1203-94<br />

1347-93<br />

1377-94<br />

1547-93<br />

1613-94<br />

18-94<br />

1837-93<br />

19-95<br />

1919-94<br />

2122-94<br />

2153-93<br />

2 19-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

436-95<br />

506-94<br />

632-95<br />

786-95<br />

801-93<br />

900-94<br />

955-95<br />

19-95<br />

2 19-95<br />

436-95<br />

632-95<br />

786-95<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

22FEB1995<br />

03MAR1995<br />

03MAR1994<br />

llNOV1992<br />

(HAPR 1995<br />

03MAY 1995<br />

02JUN1993<br />

08APRl994<br />

01JUN1995<br />

16JULl993<br />

06JULl995<br />

OSAUG1993<br />

05MAY1994<br />

02SEP1993<br />

03JUN1994<br />

050CT1993<br />

OlJUL1994<br />

05JAN1994<br />

10NOV1993<br />

04NOV1993<br />

OSJAN1995<br />

OSAUG1994<br />

OZSEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

22FEB1995<br />

03MARl995<br />

03MARl994<br />

1 1 NOVl992<br />

05APR1995<br />

03MAY1995<br />

02JUN1993<br />

08APR1994<br />

OlJUN1995<br />

16JUL1993<br />

05AUG 1993<br />

OSMAY 1994<br />

02SEP1993<br />

03JUN1994<br />

050CT1993<br />

OlJULl994<br />

WAN1994<br />

04NOV1993<br />

WAN1995<br />

OSAUGl994<br />

02SEPl994<br />

lODEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

OSAPR1995<br />

03MAYl995<br />

02JUN1993<br />

08APR1994<br />

01JUNl995<br />

05JAN1995<br />

03FEB1995<br />

03MAR1995<br />

OSAPRl995<br />

OWY 1995<br />

Page 44 of 176<br />

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3.00E+00 1.70E+00<br />

l.OOE+OO 6.00E-01<br />

O.OOE+OO <strong>4.</strong>00E-01<br />

1.00E+00 6.00E-01<br />

l.OOE+OO 6.00E-01<br />

O.OOE+OO 6.00E-01<br />

<strong>4.</strong>00E+00<br />

1.00E+00 8.00E-01<br />

l.OOE+OO 9.00E-01<br />

-1.00E+00 O.OOE+OO<br />

1.00€+00 6.00E-01<br />

l.OOE+OO 8.00E-01<br />

6,00E+00 l.OOE+OO<br />

7.00E+00 1.00E+00<br />

1.20E+01 2.00€+00<br />

7.00E+00 3.00E+00<br />

2.70€+01 3.00E+00<br />

7.00E+00 2.00E+00<br />

3.00€+00 l.OOE+OO<br />

2.OOE+Ol 6.00E+00<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

<strong>4.</strong>00E+00 1.00€+00<br />

7.00E+00 l.OOE+W<br />

l.OOE+Ol 2.00E+00<br />

1.22E+02 5.80E+01<br />

1.70E+01 7.00E+00<br />

3.00E+00 l.OOE+OO<br />

<strong>4.</strong>00E+00 2.00E+00<br />

l.lOE+Ol 3.00E+00<br />

8.00E+00 3.00E+00<br />

<strong>4.</strong>00E+00 2.00E+00<br />

3.OOE+00 2.00E+00<br />

2.0OE+00 l.OOE+OO<br />

3.OOE+00 2.00E+00<br />

<strong>4.</strong>00E+00 2.00E+00<br />

9.00E+00<br />

<strong>4.</strong>00E+00 1 .OCE+00<br />

3.00E+00 1.00E+00<br />

6.00E+00 l.OOE+OO<br />

<strong>4.</strong>00€+00 2.00E+00<br />

2.00E+00 0.00€+00<br />

1.44E+02<br />

2.62€+02<br />

7.20E+01<br />

3.68E+02<br />

1.36E+02<br />

9.70E+01<br />

1.98E+02<br />

7.40E+01<br />

7.20E+01<br />

9.40E+01<br />

5.62€+02<br />

1.09E+O3<br />

6.20E+01<br />

5.60E+01<br />

1.64E+02<br />

8.00E+01<br />

7.60E+01<br />

7.00E+01<br />

6.00€+01<br />

6.40E+01<br />

6.40€+01<br />

<strong>4.</strong>20€+01<br />

9.20€+01<br />

5.40€+01<br />

5.80E+01<br />

0.00€+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

0.00€+00<br />

N<br />

N<br />

X<br />

N<br />

N<br />

N<br />

N<br />

N<br />

X<br />

N<br />

pCilL<br />

pCVL<br />

pciR<br />

pCVL<br />

pCilL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pciR<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCUL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCiL<br />

pCi<br />

pciR<br />

pCiL<br />

pCilL<br />

pCVL<br />

pCiL<br />

pCilL<br />

pCVL<br />

pcin<br />

pCiL<br />

pCilL<br />

pCilL<br />

pcin<br />

pcin<br />

pciR<br />

pCiL<br />

pCiL<br />

pCiL<br />

pciR<br />

pciR<br />

pCi<br />

pCiL<br />

mgR CaCO3<br />

mgR CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaCO3<br />

mgR CaC03<br />

mgfl CaC03<br />

mgR CaC03<br />

mg/L CaC03<br />

mglL CaC03<br />

mgR CaCO3<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mg/L CaCO3<br />

mglL CaCO3<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaCO3<br />

mg/L CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mgfl<br />

mgk<br />

mglL<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Hexavalent Chromium 18540-29-9 955-95 01JUN1995 WS O.OOE+OO < N mglL<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439 - 89 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439 - 89 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

1919-94<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

621-93<br />

632-95<br />

635-93<br />

786-95<br />

801 -93<br />

900-94<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

I91 9-94<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

43695<br />

506-94<br />

5510-92<br />

621-93<br />

632-95<br />

635-93<br />

786-95<br />

801 -93<br />

900-94<br />

955-95<br />

16JUL1993<br />

05AUG1993<br />

OBMAY1994<br />

06JULl 992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

OlJUL1994<br />

31AUG1992<br />

070CT1992<br />

05JAN1994<br />

10NOV1993<br />

04NOV1993<br />

O5JANl995<br />

O5AUG 1994<br />

03NOV1992<br />

01 DEC1992<br />

02SEP1994<br />

10DECl993<br />

03FEBl995<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

04FEBl994<br />

22FEBl995<br />

03MAR1995<br />

03MAR1994<br />

19AUG1992<br />

05MAY 1993<br />

05APR1995<br />

05MAY1993<br />

03MAYl995<br />

02JUNl993<br />

08APR1994<br />

16JUL1993<br />

05AUG1993<br />

(HMAY 1994<br />

06JUL1992<br />

02SEPl993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

OlJULl994<br />

31 AUGl992<br />

070CT1992<br />

05JAN1994<br />

10NOV1993<br />

04NOVl993<br />

05JAN1995<br />

05AUGl994<br />

03NOV1992<br />

01 DEC1992<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

04FEB1994<br />

22FEB1995<br />

03MAR1995<br />

03MARl994<br />

19AUG1992<br />

(HMAY 1993<br />

05APRl995<br />

05MAYI993<br />

03MAY 1995<br />

02JUN1993<br />

08APR1994<br />

01JUN1995<br />

Page 45 of 176<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

m&<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg/L<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mg5<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

w/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TfPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Lithium 7439-93-2 1331 -92 06JUL1992 WS O.OOE+OO < N<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

743946-5<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

5510-92<br />

621-93<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

161 3-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

191 9-94<br />

1936-92<br />

21 00-92<br />

2122-94<br />

21 53-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

62 1-93<br />

632-95<br />

635-93<br />

786-95<br />

801-93<br />

900-94<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331 -92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1833-93<br />

1837-93<br />

19-95<br />

191 9-94<br />

1936-92<br />

21 00-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

O3AUGl 992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

19AUGl992<br />

05MAY 1993<br />

16JUL1993<br />

05AUG1993<br />

O5MAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUNl994<br />

03AUGl992<br />

050CT1993<br />

01 JULl994<br />

31AUG1992<br />

070CT1992<br />

05JAN1994<br />

I ONOVl993<br />

04NOV1993<br />

05JAN1995<br />

05AUGl994<br />

03NOV1992<br />

01 DECI 992<br />

02SEP1994<br />

1 ODECI993<br />

O3FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

22FEBl995<br />

03MAR1995<br />

03MAR1994<br />

19AUG1992<br />

(HMAY 1993<br />

05APRI995<br />

05MAY 1993<br />

03MAY1995<br />

02JUNI 993<br />

08APR1994<br />

16JUL1993<br />

OSAUG 1993<br />

05MAY 1 994<br />

06JULl992<br />

O2SEPl993<br />

03JUN1994<br />

03AUGl992<br />

050CT1993<br />

OIJUL1994<br />

31AUG1992<br />

070CT1992<br />

WAN1994<br />

1 ONOV1993<br />

04NOV1993<br />

05JAN 1995<br />

05AUG1994<br />

03NOV1992<br />

OlDEC1992<br />

O2SEPl994<br />

10DEC1993<br />

03FEB1995<br />

07OCT1994<br />

04NOVI994<br />

02DECl994<br />

04FEB1994<br />

22-81995<br />

03MAR1995<br />

03MAR1994<br />

19AUG1992<br />

Page 46 of 176<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

8.00E+00<br />

1.40E+01<br />

<strong>4.</strong>00€+00<br />

6.00E+00<br />

2.00E+01<br />

l.OOE+OI<br />

8.00E+00<br />

<strong>4.</strong>00E+00<br />

1.10E+01<br />

6.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>WE+W<br />

5.00E+W<br />

7.WE+W<br />

2.80E+01<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

5.WE+01<br />

3.00E+00<br />

<strong>4.</strong>00E+W<br />

9.00E+00<br />

5.00E+00<br />

5.00E+W<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>WE+W<br />

<strong>4.</strong>WE+W<br />

2.20E+01<br />

3.00E+W<br />

<strong>4.</strong>00E+W<br />

3.OOE+W<br />

3.WE+W<br />

5.WE+W<br />

3.WE+00<br />

I.WE+W<br />

8.WE+00<br />

O.WE+W<br />

1 .WE+00<br />

9.00E+00<br />

2.WE+W<br />

2.WE+00<br />

1 .OOE+W<br />

3.WE+W<br />

2.WE+W<br />

l.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

l.WE+W<br />

1.40E+OI<br />

O.WE+W<br />

O.WE+W<br />

2.90E+01<br />

O.WE+OO<br />

O.WE+W<br />

3.WE+W<br />

I.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

6.WE+00<br />

< N<br />

< N<br />

< N<br />

c<br />

N<br />

< N<br />

< N<br />

< N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Manganese<br />

7439-96-5 621-93 05MAY1993 WS O.OOE+OO N mg1L<br />

Manganese<br />

7439-96-5<br />

632-95 05APR1995 ws<br />

N<br />

Manganese<br />

7439-96-5<br />

635-93 O5MAY 1993 ws<br />

N<br />

Manganese<br />

7439-96-5<br />

786-95 O3MAY 1995 ws<br />

N<br />

Manganese<br />

7439-96-5<br />

801-93 02JUNl993 ws<br />

N<br />

Manganese<br />

7439 - 96 - 5<br />

900-94 OBAPR1994 ws<br />

N<br />

Mercury<br />

7439-97-6<br />

1331-92 06JUL1992 ws<br />

c<br />

N<br />

Mercury<br />

7439-97-6<br />

1476-92 O3AUG 1992 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

1547-93 050CT1993 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

1623-92 31 AUG 1992 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

1795-92 070CT1992 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

1833-93 10NOV1993 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

1936-92 03NOV1992 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

2100-92 01 DEC1992 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

333-95 22FEB1995 ws<br />

<<br />

N<br />

Mercury<br />

7439-97-6<br />

5510-92 19AUG 1992 ws<br />

UJ<br />

N<br />

Mercury<br />

7439-97-6<br />

621-93 O5MAY 1993 ws<br />

c<br />

NT<br />

Methylene Chloride<br />

75-09-2<br />

1347-93 02SEP1993 ws<br />

J<br />

N<br />

Molybdenum<br />

7439-98-7<br />

1331-92 06JUL1992 ws<br />

<<br />

N<br />

Molybdenum<br />

7439-98-7<br />

1476-92 03AUG1992 ws<br />

<<br />

N<br />

Molybdenum<br />

7439-98-7<br />

1623-92 31AUG1992 ws<br />

c<br />

N<br />

Molybdenum<br />

7439-98-7<br />

1795-92 070CT1992 ws<br />

c<br />

N<br />

Molybdenum<br />

7439-98-7<br />

1936-92 03NOV1992 ws<br />

<<br />

N<br />

Molybdenum<br />

7439-98-7<br />

2100-92 01DECl992 ws<br />

<<br />

N<br />

Molybdenum<br />

7439-98-7<br />

5510-92 19AUG 1992 ws<br />

<<br />

N<br />

Molybdenum<br />

7439-98-7<br />

621-93 05MAY 1993 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1073-93 16JUL1993 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1203-93 OSAUGl993 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1203-94 05MAY 1994 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1331-92 06JUL1992 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1347-93 02SEP1993 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1377-94 OjJUNl994 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1476-92 03AUGl992 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1547-93 050CTl993 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1613-94 OlJUL1994 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1623-92 3lAUGl992 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1795-92 070CT1992 ws<br />

c<br />

N<br />

Nickel<br />

7440-02-0 i 8-94 OSJAN1994 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1833-93 1 ONOV1993 ws<br />

c<br />

N<br />

Nickel<br />

7440-02-0<br />

1837-93 04NOV1993 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

19-95 05JAN1995 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1919-94 05AUG1994 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

1936-92 03NOV1992 ws<br />

<<br />

N<br />

Nickel<br />

7440-02-0<br />

2100-92 01DEC1992 ws<br />

UJ<br />

N<br />

Nickel<br />

7440-02-0<br />

2122-94 02SEP1994 ws<br />

Nickel<br />

7440-02-0<br />

2153-93 1 ODEC1993 ws<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL- CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Phosphorus (P) 7723-14-0 1331 -92 06JUL1992 WS O.OOE+OO C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1476-92 03AUGl992 ws O.OOE+OO<br />

c<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1623-92 3lAUGl992 ws O.OOE+OO<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1795-92 070CT1992 ws O.OOE+OO<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1936-92 03NOV1992 ws O.OOE+OO<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

2100-92<br />

01 DEC1992 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

5510-92<br />

19AUG 1992 ws O.OOE+OO<br />

< N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

621-93 05MAY 1993 ws O.OOE+OO<br />

< N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1073-93 16JUL1993 ws 6.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1203-93 05AUG1993 ws 7.00€+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1203-94 O5MAY 1994 ws 2.00E+00<br />

C<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1331-92 06JUL1992 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1347-93 02SEP1993 ws 8.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1377-94 03JUN1994 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1476-92 03AUGl992 ws <strong>4.</strong>00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1547-93 050CTl993 ws <strong>4.</strong>00E+00<br />

N<br />

mg1L<br />

Potassium<br />

7440-09-7<br />

1613-94 01 JULl994 ws 6.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1623-92 31AUG1992 ws 5.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1795-92 070CT1992 ws <strong>4.</strong>00E+W<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

18-94 OSJANl994 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

i 833-93 10NOV1993 ws 2.00€+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1837-93 04NOV1993 ws <strong>4.</strong>00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

19-95 OUANl995 ws 3.OOE+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

1919-94<br />

OSAUG1994 ws l.OOE+Ol<br />

N<br />

mg1L<br />

Potassium<br />

7440-09-7<br />

1936-92 03NOV1992 ws <strong>4.</strong>00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2100-92 OlDEC1992 ws 2.00E+00<br />

J<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2122-94 02SEPl994 ws 1.30E+01<br />

N mgk<br />

Potassium<br />

7440-09-7<br />

2153-93 lODECl993 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

219-95 03FEBl995 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2412-94 070CT1994 ws 5.00E+00<br />

N<br />

mgfl<br />

Potassium<br />

7440-09-7<br />

2690-94 MNOV1994 ws 3.00E+W<br />

N mgk<br />

Potassium<br />

7440-09-7<br />

2a60-94 02DECl994 ws <strong>4.</strong>WE+W<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

287-94 MFEB1994 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

333-95 22FEB1995 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

436-95 OWR1995 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

506-94 03MAR1994 ws 2.00E+00<br />

<<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

5510-92 19AUG1992 ws 6.00E+W<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

621-93 OWY 1993 ws 2.WE+00<br />

C<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

632-95 OSAPR1995 ws 5.00E+00<br />

<<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

635-93 05MAY1993 ws 2.00E+00<br />

<<br />

N<br />

mg/L<br />

Potassium<br />

7440-09-7<br />

786-95 03MAY 1995 ws l.OOE+OO<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

801 -93 02JUNl993 ws 3.00E+00<br />

N mgk<br />

Potassium<br />

7440-09-7<br />

900-94 08APR1994 ws 2.00E+00<br />

<<br />

N<br />

mglL<br />

Rad Alpha<br />

12587-46-1<br />

1146-95<br />

WUL1995 ws l.OOE+OO<br />

<<br />

N pCiml<br />

Rad Alpha<br />

12587-46-1<br />

219-95 03FEB1995 ws 1 .00E+00<br />

c<br />

N pCiml<br />

Rad Alpha<br />

12587-46-4<br />

333-95 22FEB1995 ws l.OOE+W<br />

C<br />

N pCiml<br />

Rad Alpha<br />

12587-46-1<br />

436-95 03hMR1995 ws l.OOE+OO<br />

C<br />

N pCiml<br />

Rad Alpha<br />

ixa7-46-1<br />

632-95 OSAPRl995 ws l.OOE+W<br />

C<br />

N pCilml<br />

Rad Alpha i 2587-46-1<br />

7a6-95 03MAY 1995 ws 1 .WE+OO<br />

<<br />

N pCiml<br />

Rad Alpha<br />

i2sa7-46-i<br />

801-93 02JUN1993 ws l.WE+W<br />

<<br />

N pCimL<br />

Rad Alpha<br />

12587-46-1<br />

869-95 24MAY1995 ws 1 .00E+00<br />

c<br />

N pCiml<br />

Rad Alpha<br />

12587-46-1<br />

955-95 01 JUN1995 ws 1.00E+W<br />

C<br />

N pCilml<br />

Rad Beta<br />

12587-47-2<br />

1146-95 06JULl995 ws 1.00E+W<br />

C<br />

N pCilml<br />

Rad Beta<br />

12587-47-2<br />

219-95 03FEBl995 ws l.OOE+W<br />

<<br />

N pCilml<br />

Rad Beta<br />

12587-47-2<br />

333-95 22FEB1995 ws 1.00E+00<br />

<<br />

N pCiml<br />

Rad Beta<br />

12587-47-2<br />

436-95 OMARl995 ws l.WE+W<br />

<<br />

N pCiml<br />

Rad Beta<br />

12587-47-2<br />

632-95 OSAPR1995 ws 1 .00E+00<br />

C<br />

N pCilml<br />

Rad Beta<br />

12587-47-2<br />

786-95 03MAY 1995<br />

ws l.OOE+W<br />

C<br />

N pCilml<br />

Rad Beta<br />

~2587-47-2<br />

801-93 02JUNl993 ws 1.00E+00<br />

<<br />

N pCimL<br />

Rad Beta<br />

12587-47-2<br />

869-95 24MAY 1995 ws 1 .00E+00<br />

<<br />

N pCilml<br />

Rad Beta<br />

12587-47-2<br />

955-95 OlJUN1995 ws 1 .00E+00<br />

<<br />

N pCilml<br />

Ruthenium<br />

7440-188<br />

1331 -92 06JUL1992 ws 0.00E+00<br />

<<br />

N<br />

mgfl<br />

Ruthenium<br />

7440-188<br />

1476-92 03AUG1992 ws 0.00E+00<br />

<<br />

N mgk<br />

Ruthenium<br />

7440-10-0<br />

1623-92 3lAUGl992 ws 0.00E+00<br />

<<br />

N mgk<br />

Ruthenium<br />

7440-188<br />

1795-92 070CT1992 ws 0.00E+W<br />

<<br />

N Wfl<br />

Ruthenium<br />

7440-188<br />

193692 03NOV1992 ws 0.00E+00<br />

C<br />

N mgk<br />

Ruthenium<br />

7440-10-0<br />

2100-92 01 DEC1992 ws 0.00E+00<br />

<<br />

N mgk<br />

Ruthenium<br />

7440-ia-a<br />

5510-92 19AUG1992 ws O.WE+OO<br />

C<br />

N mgk<br />

Ruthenium<br />

7440-188<br />

621-93 OSMAY 1993<br />

ws 0.00E+00<br />

<<br />

N<br />

mglL<br />

Selenium<br />

7782-49-2<br />

1833-93 10NOV1993 ws 0.00E+00<br />

C<br />

N<br />

mglL<br />

Selenium<br />

7782-49-2<br />

333-95 22FEB1995 ws 0.00E+00<br />

CSX<br />

N mgfl<br />

Silicon<br />

7440-21-3<br />

1073-93 16JUL1993 ws 5.00E+W<br />

N mgk<br />

Page 48 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

ANALYTE CAS NUMBER SAMPLE ID<br />

Silicon 7440-2 1-3 1203-93 05AUG1993 WS 9.00E+00<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

7440-2 1-3<br />

7440-21-3<br />

7440-2 1-3<br />

7440-21-3<br />

7440-2 1 -3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21<br />

-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-2 1-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

1203-94<br />

1331 -92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

18-94<br />

1837-93<br />

19-95<br />

191 9-94<br />

1936-92<br />

2100-92<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

436-95<br />

506-94<br />

551 0-92<br />

62 1 -93<br />

632-95<br />

635-93<br />

786-95<br />

801 -93<br />

900-94<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

1936-92<br />

21 00-92<br />

333-95<br />

5510-92<br />

621-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1547-93<br />

1623-92<br />

2122-94<br />

1073-93<br />

1613-94<br />

1795-92<br />

1837-93<br />

19-95<br />

191 9-94<br />

1936-92<br />

21 00-92<br />

18-94<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

436-95<br />

506-94<br />

5510-92<br />

621-93<br />

635-93<br />

632-95<br />

05MAY1994<br />

06JULl992<br />

02SEP1993<br />

03JUNl994<br />

03AUGl992<br />

050CT1993<br />

OlJUL1994<br />

31AUG1992<br />

070CT1992<br />

05JAN1994<br />

04NOV1993<br />

05JAN1995<br />

OSAUG1994<br />

03NOV1992<br />

01 DECl992<br />

02SEP1994<br />

lODEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

03MARl995<br />

03MAR1994<br />

19AUG1992<br />

05MAY1993<br />

05APR1995<br />

05MAY1993<br />

03MAY1995<br />

02JUN1993<br />

08APRl994<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

1 ONOVl993<br />

03NOV1992<br />

01DEC1992<br />

22FEBl995<br />

19AUG 1992<br />

05MAYl993<br />

16JULl993<br />

OSAUG1993<br />

OSMAY 1994<br />

06JULl992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

01 JULl994<br />

3lAUGl992<br />

070CT1992<br />

05JAN1994<br />

04NOV1993<br />

05JANl995<br />

OSAUG1994<br />

03NOV1992<br />

OlDEC1992<br />

02SEP1994<br />

lODEC1993<br />

O3FEBl995<br />

07OCT1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

03MAR1995<br />

OWR1994<br />

19AUG1992<br />

05MAY 1993<br />

OSAPR1995<br />

MAY<br />

1993<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

<<br />

X<br />

J<br />

B<br />

J<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Sodium<br />

7440-23-5 786-95 O3MAY1995 WS 7.00E+00 J N<br />

mglL<br />

Sodium<br />

7440-23-5<br />

801-93 02JUNl993 ws 1.70E+01<br />

N<br />

mglL<br />

Sodium<br />

7440-23-5<br />

900-94 08APRl994 ws 8.00E+00<br />

N<br />

mglL<br />

Specific conductance SO145<br />

1073-93 16JULl993 ws 3.82E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1146-95<br />

06JUL1995 ws 1.40E+02<br />

N umhodcm<br />

Specific conductance SO145<br />

1203-93 05AUG1993 ws 6.06E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1203-94 05MAY 1994<br />

ws 2.11E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1347-93 02SEP1993 ws 7.05E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1377-94 03JUN1994 ws <strong>4.</strong>00E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1547-93 050CT1993 ws 2.22E+02<br />

N urnhoslcm<br />

Specific conductance SO145<br />

1613-94 OlJUL1994 ws 5.56E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

18-94 05JAN1994 ws 2.25E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1837-93 04NOV1993 ws 2.54E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

19-95 05JAN1995 ws 3.33E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

1919-94 05AUG1994 ws 1.22E+03<br />

N<br />

urn hoslcm<br />

Specific conductance SO145<br />

2122-94 O2SEPl994 ws 2.04E+03<br />

N umhoslcm<br />

Specific conductance SO145<br />

2153-93 lODEC1993 ws 1.71 E+02<br />

N umhodcm<br />

Specific conductance SO145<br />

219-95 03FEBl995 ws 1.96E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

2412-94 070CTl994 ws 5.16E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

2690-94 04NOV1994 ws 2.95E+02<br />

N umhoslcm<br />

Specific conductance<br />

SO145<br />

2860-94 02DEC1994 ws 2.46E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

287-94 04FEB1994 ws 1.98E+02<br />

N umhoslcm<br />

Specific conductance<br />

SO145<br />

436-95 03MAR1995 ws 2.08€+02<br />

N umhoslcm<br />

Specific conductance<br />

SO145<br />

506-94 03MAR1994 ws 1.90E+02<br />

N umhoslcm<br />

Specifc conductance<br />

SO145<br />

632-95 05APRl995 ws 2.49€+02<br />

N umhoslcm<br />

Specific conductance<br />

SO145<br />

78695 03MAY 1995 ws 1.38E+02<br />

N umhoslcm<br />

Specific conductance SO145<br />

801-93 02JUN1993 ws 2.81E+02<br />

N umhodcm<br />

Specific conductance<br />

SO145<br />

900-94 08APRl994 ws 1.42E+02<br />

N umhoslcm<br />

Specific conductance<br />

SO145<br />

955-95 OlJUNl995 ws 1.94E+02<br />

N umhodcm<br />

Strontium<br />

7440-24-6<br />

1073-93 16JULl993 ws O.OOE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1203-93 05AUG1993 ws O.OOE+OO<br />

N<br />

mg1L<br />

Strontium<br />

7440-24-6<br />

1203-94 05MAY 1994 ws O.OOE+OO<br />

N<br />

mg/L<br />

Strontium<br />

7440-24-6<br />

1331 -92 06JUL1992 ws O.WE+W<br />

N<br />

mg/L<br />

Strontium<br />

7440-24-6<br />

1347-93 02SEPl993 ws O.OOE+OO<br />

N<br />

mg5<br />

Strontium<br />

7440-24-6<br />

1377-94 O3JUNl994 ws O.WE+W<br />

N<br />

mgfl<br />

Strontium<br />

7440-24-6<br />

147692 03AUG1992 ws O.OOE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1547-93 050CTl993 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1613-94 01 JULl994 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1623-92 3lAUGl992 ws O.WE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1795-92 070CT1992 ws O.WE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

16-94 WAN1994 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1837-93 04NOV1993 ws O.WE+OO<br />

N<br />

mg/L<br />

Strontium<br />

7440-24-6<br />

19-95 WAN1995 ws I.WE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

1919-94 05AUGl994 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

193692 03NOV1992 ws O.WE+OO<br />

N<br />

mgfl<br />

Strontium<br />

7440-24-6<br />

2100-92 01DECl992 ws O.WE+OO<br />

N<br />

mgk<br />

Strontium<br />

7440-24-6<br />

2122-94 02SEPl994 ws 1 .WE+00<br />

N mgR<br />

Strontium<br />

7440-24-6<br />

2153-93 10DEC1993 ws O.OOE+W<br />

N<br />

mg/L<br />

Strontium<br />

7440-24-6<br />

219-95 03FEB1995 ws l.WE+W<br />

c<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

2412-94 070CT1994 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

2690-94 MNOV1994 ws O.WE+OO<br />

N<br />

mgfl<br />

Strontium<br />

7440-24-6<br />

2860-94 02DECl994 ws 3.WE+W<br />

<<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

287-94 MFEBl994 ws O.WE+W<br />

N mgk<br />

Strontium<br />

7440-24-6<br />

43695 03MAR1995 ws l.WE+W<br />

c<br />

N<br />

mgk<br />

Strontium<br />

7440-24-6<br />

506-94 03MARl994 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

5510-92 19AUG1992 ws O.OOE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

621-93 05MAY 1993 ws O.WE+W<br />

N<br />

mgfl<br />

Strontium<br />

7440-24-6<br />

632-95 05APRI995 ws O.WE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

635-93 05MAY1993 ws O.WE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

78695 03MAY 19% ws O.WE+W<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

801 -93 02JUNl993 ws O.OOE+OO<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

900-94 08APR1994 ws O.WE+OO<br />

N mgk<br />

Sulfate<br />

12143-45-2<br />

1331-92 06JULl992 ws 5.3OE+01<br />

N<br />

mglL<br />

Sulfate<br />

12143-45-2<br />

147692 03AUG 1992 ws 1.24E+02<br />

N<br />

mgfl<br />

Sulfate<br />

12143-45-2<br />

1623-92 3lAUGl992 ws 6.80€+01<br />

N mgn<br />

Tantalum<br />

7440-25-7<br />

1331 -92 06JUL1992 ws O.WE+W<br />

N<br />

mgfl<br />

Tantalum<br />

7440-25-7<br />

1476-92 03AUG1992 ws O.WE+OO<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1623-92 3lAUG1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1795-92 07OCT1992 ws O.WE+OO<br />

N<br />

mgfl<br />

Tantalum<br />

7440-25-7<br />

1936-92 03NOV1992 ws O.WE+W<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

5510-92 19AUGl992 ws O.WE+W<br />

N<br />

mgfl<br />

Tantalum<br />

7440-25-7<br />

621-93 OSMAY 1993 ws O.WE+W<br />

<<br />

N<br />

mglL<br />

Page 50 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Technetium-99 14133-76-7 1833-93 10NOV1993 WS 3.00E+01 2.20E+01 N DCVL<br />

Technetium-99<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Ttanium<br />

Ttanium<br />

Titanium<br />

Ttanium<br />

Ttanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-1.2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichbroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

14133-76-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

ioa-a8-3<br />

I 08-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

15660-5<br />

156-60-5<br />

156-60-5<br />

79-01 -6<br />

79-01-6<br />

79-01-6<br />

79-01 -6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

744061-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

744061-1<br />

6164-92<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

162392<br />

1795-92<br />

1936-92<br />

2100-92<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

193692<br />

2100-92<br />

5510-92<br />

621-93<br />

1331 -92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1331-92<br />

147692<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

193692<br />

2100-92<br />

5510-92<br />

621-93<br />

1073-93<br />

1203-93<br />

1203-94<br />

1331-92<br />

1347-93<br />

1377-94<br />

1476-92<br />

1-7-93<br />

1613-94<br />

1623-92<br />

1795-92<br />

i a94<br />

llNOV1992<br />

O6JUL1 992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

19AUG1992<br />

05MAY 1993<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

19AUG1992<br />

O5MAY 1993<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

19AUG 1992<br />

WAY1993<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

O7OCTI 992<br />

03NOV1992<br />

OlDECl992<br />

19AUGl992<br />

OWAY 1993<br />

OGJULI 992<br />

O3AUGl 992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CTI 992<br />

OJNOVl992<br />

01DEC1992<br />

06JUL1992<br />

03AUG1992<br />

31AUGl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

19AUG1992<br />

WAY 1993<br />

16JUL1993<br />

05AUG1993<br />

(HMAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUNl994<br />

03AUG1992<br />

050CT1993<br />

OlJULl994<br />

3lAUG 1992<br />

070CT1992<br />

05JANI 994<br />

Page 51 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

pC$L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mgR<br />

mg1L<br />

mgfl<br />

mg/L<br />

mglL<br />

mgfl<br />

mgnmglL<br />

mg/L<br />

mgfl<br />

mglL<br />

uglL<br />

uglL<br />

ugR<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugR<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgR<br />

mglL<br />

mglL<br />

m9fl<br />

mgR<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mgn-


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Uranium 7440-61-1 1833-93 10NOV1993 WS 0.00€+00<br />

c<br />

N<br />

mglL<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -I<br />

7440-61-1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

1837-93<br />

19-95<br />

1919-94<br />

1936-92<br />

2100-92<br />

2122-94<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

333-95<br />

436-95<br />

506-94<br />

5510-92<br />

6164-92<br />

621-93<br />

632-95<br />

786-95<br />

801-93<br />

900-94<br />

955-95<br />

1331-92<br />

1476-92<br />

1623-92<br />

1936-92<br />

2100-92<br />

5510-92<br />

621-93<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

2100-92<br />

1331-92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1833-93<br />

1936-92<br />

2100-92<br />

333-95<br />

5510-92<br />

621-93<br />

1331 -92<br />

1476-92<br />

1623-92<br />

1795-92<br />

1936-92<br />

04NOV1993<br />

OSJANI 995<br />

05AUGl994<br />

03NOV1992<br />

01 DEC1992<br />

02SEP1994<br />

1 ODECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

04FEBl994<br />

22FEB1995<br />

03MARl995<br />

03MAR 1994<br />

19AUGl992<br />

llNOV1992<br />

05MAY1993<br />

05APR1995<br />

03MAY 1995<br />

02 JUN 1993<br />

OBAPR1994<br />

01JUNl995<br />

06JUL1992<br />

03AUG1992<br />

3lAUG1992<br />

03NOV1992<br />

01 DEC1992<br />

19AUG1992<br />

WAY1993<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

07OCT1992<br />

03NOV1992<br />

01 DECI 992<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CTI 992<br />

lONOV1993<br />

03NOV1992<br />

01DECl992<br />

22FEB1995<br />

19AUGI 992<br />

OSMAY 1993<br />

06JUL1992<br />

03AUG1992<br />

3IAUG1992<br />

070CT1992<br />

03NOV1992<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00€+00<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00€+00<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

0.00E+W<br />

O.OOE+OO<br />

l.WE+OI<br />

I.WE+Ol<br />

1 .OOE+OI<br />

1 .WE+Ol<br />

l.WE+Ol<br />

I .WE+OI<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.M)E+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

c<br />

<<br />

c<br />

c<br />

c<br />

c<br />

c<br />

<<br />

c<br />

c<br />

c<br />

e<br />

<<br />

c<br />

c<br />

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c<br />

e<br />

c<br />

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e<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

e<br />

c<br />

e<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

e<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

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N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

cis-I ,2-dichloroethene<br />

cis-I .2-dichloroethene<br />

cis-I .2dichloroethene<br />

cis-I ,2dichloroethene<br />

cis-I ,2dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

so296<br />

so296<br />

so296<br />

2100-92<br />

5510-92<br />

621-93<br />

1203-93<br />

1347-93<br />

1613-94<br />

I91 9-94<br />

2122-94<br />

1073-93<br />

1146-95<br />

1203-93<br />

1203-94<br />

1266-92<br />

1308-92<br />

1331-92<br />

1347-93<br />

1368-92<br />

1377-94<br />

1417-92<br />

1443-92<br />

01DECl992<br />

19AUG1992<br />

OSMAY1993<br />

05AUGl993<br />

02SEPl993<br />

01 JULl994<br />

05AUGl994<br />

O2SEP1994<br />

16JUL1993<br />

06JUL1995<br />

05AUG1993<br />

05MAYl994<br />

22JUN1992<br />

29JUN1992<br />

06JUL1992<br />

02SEPl993<br />

13JUL1992<br />

OUUN1994<br />

21JULl992<br />

27JULl992<br />

0.00€+00<br />

O.WE+W<br />

O.WE+W<br />

3.WE+00<br />

3.WE+W<br />

3.00E+W<br />

9.WE+W<br />

7.WE+W<br />

7.00E+W<br />

7.00E+W<br />

7.00E+00<br />

7.WE+W<br />

7.WE+W<br />

7.WE+W<br />

7.WE+W<br />

7.WE+W<br />

7.WE+00<br />

7.WE+00<br />

7.WE+W<br />

7.00E+W<br />

e<br />

e<br />

Q<br />

J<br />

J<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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Page 52 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

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ws<br />

ws<br />

ws<br />

ws


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

PH SO296 1476-92 03AUG1992 WS 7.00E+00 N su<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SWU 8, C746K-4<br />

1,l-Dichloroethane<br />

1,l -Dichloroethane<br />

1 ,I-Dichloroethane<br />

1,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroelhene<br />

1 ,I-Dichloroethene<br />

1 .I-Dichloroelhene<br />

1 .I-Dichloroethene<br />

1,l-Dichloroethene<br />

Acetone<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

67-64-1<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1502-92<br />

1547-93<br />

1550-92<br />

1598-92<br />

1613-94<br />

1623-92<br />

1661 -92<br />

1683-92<br />

1795-92<br />

18-94<br />

1837-93<br />

19-95<br />

1919-94<br />

1966-92<br />

2100-92<br />

2122-94<br />

2136-92<br />

2153-93<br />

219-95<br />

2412-94<br />

2690-94<br />

2860-94<br />

287-94<br />

436-95<br />

506-94<br />

621 -93<br />

632-95<br />

635-93<br />

786-95<br />

801 -93<br />

900-94<br />

955-95<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

631 -92<br />

700-92<br />

855-92<br />

1839-93<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

10AUG1992<br />

050CT1993<br />

17AUG1992<br />

24AUG1992<br />

01 JULl994<br />

31AUG1992<br />

08SEPl992<br />

14SEP1992<br />

070CT1992<br />

05JAN1994<br />

04NOV1993<br />

OSJAN 1 995<br />

05AUG1994<br />

O9NOVI 992<br />

01 DECl992<br />

02SEPl994<br />

07DEC1992<br />

10DEC1993<br />

03FEB1995<br />

070CTI 994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

O5MAY 1993<br />

05APRl995<br />

05MAY1993<br />

03MAY 1995<br />

OZJUNI 993<br />

OBAPRI994<br />

OlJUN1995<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG 1992<br />

31 AUG 1992<br />

070CT1992<br />

O3NOVl 992<br />

O5MARl 992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOVl992<br />

WAR1 992<br />

1 PMARl992<br />

01APR1992<br />

04NOV1993<br />

04MAY 1992<br />

16JULl993<br />

01JUN1992<br />

05AUG1993<br />

WAY1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

OlJULl994<br />

31 AUGI 992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

05AUG1994<br />

Page 53 of 176<br />

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ug1L<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Aluminum 7429-90-5 1937-92 03NOV1992 WS l.OOE+OO N<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminurn<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

1440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-30-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-30-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

20-95<br />

2 123-94<br />

2 154-93<br />

220-95<br />

241 3-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

700-92<br />

85592<br />

1023-92<br />

1074-93<br />

I<br />

143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

631-92<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

I<br />

839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

1074-93<br />

787-95<br />

05JAN1995<br />

O2SEPl 994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DECl994<br />

04FEBI 994<br />

03MAR1995<br />

03MAR1994<br />

OSMAY 1993<br />

05MAR1992<br />

O5APR 1995<br />

05MAY 1 993<br />

12MAR1992<br />

03MAY 1995<br />

02JUNl993<br />

01 APRl992<br />

08APR1994<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

05MAYI993<br />

WAR1992<br />

12MAR1992<br />

01 APR1992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUN1992<br />

05AUG1993<br />

05MAYl994<br />

06JUL1992<br />

02SEP1993<br />

03JUNI994<br />

03AUG1992<br />

050CT1993<br />

OlJULl994<br />

3lAUG1992<br />

070CT1992<br />

MNOVI993<br />

04NOV1993<br />

WAN1994<br />

05AUGI994<br />

03NOVl992<br />

05JAN1995<br />

02SEP1994<br />

IODECI993<br />

03FEB1995<br />

070CT1994<br />

MNOV1994<br />

MNOV1994<br />

02DEC1994<br />

MFEBl994<br />

03MAR1995<br />

OW1994<br />

05MAY1993<br />

MMAR1992<br />

OSAPRI995<br />

05MAY1993<br />

12MAR1992<br />

03MAY1995<br />

02JUN1993<br />

01 APRl992<br />

08APR1994<br />

04MAY 1 992<br />

16JUL1993<br />

ws<br />

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<<br />

<<br />

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X<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Barium 7440-39-3 1143-92 01JUN1992 WS O.OOE+OO N mglL<br />

Barium<br />

7440-39-3<br />

1204-93 05AUGl993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1204-94 O5MAY 1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1332-92 06JUL1992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1348-93 02SEP1993 ws<br />

N. mglL<br />

Barium<br />

7440-39-3<br />

1378-94 03JUN1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1477-92 03AUG1992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1548-93 050CT1993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1614-94<br />

01 JUL1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1624-92 31AUG1992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1796-92 070CT1992 ws<br />

N<br />

mg1L<br />

Barium<br />

7440-39-3<br />

1839-93 MNOV1993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1840-93 04NOV1993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

19-94 05JANl994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1920-94 05AUG1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

1937-92 03NOV1992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

20-95 05JAN1995 ws<br />

<<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

2123-94 02SEP1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440 - 39 - 3<br />

2154-93 1 ODECl993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

220-95 03FEB1995 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

2413-94 070CT1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

2691-94 04NOV1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

2692-94 04NOV1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

2861-94 02DECl994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

268-94 MFEB1994 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

437-95 03MARl995 ws<br />

N<br />

mglL<br />

Barium<br />

7440 - 39 - 3<br />

507-94 03MARl994 ws<br />

N<br />

mg1L<br />

Barium<br />

7440-39-3<br />

622-93 05MAYl993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

631-92 OSMAR1992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

633-95 05APR1995 ws<br />

c<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

636-93 05MAYl993 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

700-92 12MAR1992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

787-95 03MAY 1995 ws<br />

<<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

802-93 02JUNl993 ws<br />

N<br />

WlL<br />

Barium<br />

7440-39-3<br />

855-92 01APRl992 ws<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

901-94 08APR1994 ws<br />

N<br />

mg1L<br />

Benzene<br />

71-43-2<br />

1023-92 MMAY 1992 ws<br />

<<br />

NT<br />

ug1L<br />

Benzene<br />

71-43-2<br />

1143-92<br />

01 JUN1992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71 -43-2<br />

1332-92 oGJUL1992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71-43-2<br />

1477-92 03AUG1992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71-43-2<br />

1624-92 31AUG1992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71 -43-2<br />

1796-92 070CT1992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71 -43-2<br />

1937-92 03NOVl992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71-43-2<br />

631-92 05MAR1992 ws<br />

c<br />

N<br />

uglL<br />

Benzene<br />

71-43-2<br />

700-92 12MARl992 ws<br />

<<br />

N<br />

uglL<br />

Benzene<br />

71-43-2<br />

855-92 01 APR1992 ws<br />

<<br />

N<br />

uglL<br />

Beryllium<br />

7440-41-7<br />

1023-92 WAY1992 ws<br />

<<br />

NT mg1L<br />

Beryllium<br />

7440-41-7<br />

1143-92<br />

01 JUNl992 ws<br />

<<br />

N<br />

mglL<br />

Beryllium<br />

7440-41-7<br />

1332-92 oGJUL1992 ws<br />

<<br />

N<br />

mglL<br />

Beryllium<br />

7440-41 -7<br />

1477-92 03AUGl992 ws<br />

<<br />

N<br />

mglL<br />

Beryllium<br />

7440-41 -7<br />

1624-92 31AUGl992 ws<br />

<<br />

N<br />

mglL<br />

Beryllium<br />

7440-41-7<br />

1796-92 070CT1992 ws<br />

c<br />

N<br />

WlL<br />

Beryllium<br />

7440-41-7<br />

1937-92 03NOV1992 ws<br />

<<br />

N<br />

WlL<br />

Beryllium<br />

7440-41-7<br />

622-93 OCMAY 1993 ws<br />

<<br />

N<br />

WlL<br />

Beryllium<br />

7440-41-7<br />

631-92 05MAR1992 ws<br />

<<br />

N<br />

mglL<br />

Beryllium<br />

7440-41-7<br />

700-92 1 ZMAR 1992 ws<br />

<<br />

N<br />

WlL<br />

Beryllium<br />

7440-41 -7<br />

855-92 01 APR1992 ws<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

1023-92 WAY 1992 ws<br />

<<br />

NT WlL<br />

Bismuth<br />

7440-69-9<br />

1143-92 01 JUN1992 ws<br />

c<br />

N WlL<br />

Bismuth<br />

7440-69-9<br />

1332-92 oGJUL1992 ws<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

1477-92 OJAUGl992 ws<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

1624-92 31 AUG 1992 ws<br />

<<br />

N<br />

W/L<br />

Bismuth<br />

7440-69-9<br />

1796-92 070CT1992 ws<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

1937-92 03NOV1992 ws<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

622-93 05MAY1993 ws<br />

<<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

631-92 [HMAR 1992<br />

ws<br />

c<br />

N<br />

mglL<br />

Bismuth<br />

7440-69-9<br />

700-92 12MAR1992 ws<br />

<<br />

N<br />

mgR<br />

Bismuth<br />

7440-69-9<br />

855-92 OlAPRl992 ws<br />

c<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1023-92 MMAY 1992 ws<br />

<<br />

NT mglL<br />

Cadmium<br />

7440-43-9<br />

1074-93 16JUL1993 ws<br />

c<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1143-92<br />

01JUN1992 ws<br />

<<br />

N mgk<br />

Cadmium<br />

7440-43-9<br />

1204-93 [HAUG 1993 ws<br />

<<br />

N<br />

mg/L<br />

Page 55 of 176


L.9 (continued)<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Cadmium 7440-43-9 1204-94 OSMAYl994 WS O.OOE+OO C N mglL<br />

Cadmium<br />

7440-43-9<br />

1332-92 06JULl992 ws<br />

C<br />

N<br />

mg1L<br />

Cadmium<br />

7440-43-9<br />

1348-93 02SEP1993 ws<br />

c<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1378-94 03JUN1994 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1477-92 O3AUG 1992 ws<br />

C<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1548-93 050CT1993 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1614-94 01 JUL1994 ws<br />

C<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1624-92 31 AUGl992 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1796-92 070CT1992 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1839-93 04NOV1993 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1840-93 04NOV1993 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

19-94 05JAN1994 ws<br />

c<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1920-94 05AUG1994 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

1937-92 03NOV1992 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

20-95 O5JANl 995 ws<br />

U<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

2123-94 02SEP1994 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

2154-93 10DEC1993 ws<br />

C<br />

N<br />

mgfl<br />

Cadmium<br />

7440-43-9<br />

220-95 O3FEBl 995 ws<br />

C<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

2413-94 070CT1994 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

2691-94 04NOV1994 ws<br />

C<br />

N<br />

WlL<br />

Cadmium<br />

7440-43-9<br />

2692-94 04NOV1994 ws<br />

C<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

2861 -94 02DEC1994 ws<br />

U<br />

N<br />

mg/L<br />

Cadmium<br />

7440-43-9<br />

288-94 04FEB1994 ws<br />

C<br />

N<br />

mg1L<br />

Cadmium<br />

7440-43-9<br />

437-95 03MAR1995 ws<br />

U<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

507-94 03MAR1994 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

622-93 05MAY 1993 ws<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

631-92 OSMARI 992 ws<br />

C<br />

N<br />

mg5<br />

Cadmium<br />

7440-43-9<br />

633-95 OSAPR1995 ws<br />

U<br />

N<br />

wlL<br />

Cadmium<br />

7440-43-9<br />

636-93 05MAY1993 ws<br />

< N<br />

mg/L<br />

Cadmium<br />

7440-43-9<br />

700-92 12MARl992 ws<br />

C<br />

N<br />

wlL<br />

Cadmium<br />

7440-43-9<br />

787-95 03MAY 1995 ws<br />

C<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

802-93 O2JUNl 993 ws<br />

< N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

855-92 01 APRl992 ws<br />

C<br />

N<br />

mglL<br />

Cadmium<br />

744043-9<br />

901 -94 08APRl994 ws<br />

c<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

956-95 01 JUN1995 ws<br />

C<br />

N<br />

mg/L<br />

Calcium<br />

7440-70-2<br />

1023-92 04MAY 1992 ws<br />

NT mglL<br />

Calcium<br />

7440-70-2<br />

1143-92 01JUNl992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1332-92 06JUL1992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1477-92 03AUGl992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1624-92 31 AUG1992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1796-92 070CT1992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

1937-92 03NOV1992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

622-93 05MAY 1993 ws<br />

N w5<br />

Calcium<br />

7440-70-2<br />

631-92 05MAR1992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

700-92 12MAR1992 ws<br />

N<br />

mglL<br />

Calcium<br />

7440-70-2<br />

855-92 01 APRl992 ws<br />

N<br />

wlL<br />

Chromium<br />

7440-47-3<br />

1023-92 04MAY 1992 ws<br />

C<br />

NT mg1L<br />

Chromium<br />

7440-47-3<br />

1074-93 16JUL1993 ws<br />

C<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

1143-92 01 JUN1992 ws<br />

C<br />

N<br />

WlL<br />

Chromium<br />

7440-47-3<br />

1204-93 OSAUG 1993 ws<br />

<<br />

N<br />

wlL<br />

Chromium<br />

7440-47-3<br />

1204-94 MAY 1994 ws<br />

<<br />

N<br />

wlL<br />

Chromium<br />

7440-47-3<br />

1332-92 06JUL1992 ws<br />

<<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1348-93 02SEP1993 ws<br />

C<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1378-94 OUUN1994 ws<br />

C<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1477-92 03AUG1992 ws<br />

N<br />

WlL<br />

Chromium<br />

7440-47-3<br />

1548-93 050CT1993 ws<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1614-94 OlJUL1994 ws<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1624-92 31AUGI 992 ws<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

1796-92 070CT1992 ws<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1839-93 04NOVI993 ws<br />

<<br />

N<br />

mgfL<br />

Chromium<br />

7440-47-3<br />

1840-93 04NOVI993 ws<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

19-94 WAN 1994<br />

ws<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

1920-94 (HAUGI994 ws<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

1937-92 03NOVl 992 ws<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

20-95 (HJ AN 1995 ws<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

2123-94 02SEP1994 ws<br />

N<br />

w/L<br />

Chromium<br />

7440-47-3<br />

2154-93 lODEC1993 ws<br />

<<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

2413-94 070CT1994 ws<br />

<<br />

N<br />

mglL<br />

Chromium<br />

7440-47-3<br />

2691-94 04NOV1994 ws<br />

C<br />

N<br />

mglL<br />

Chromium<br />

744047-3<br />

2692-94 04NOV1994 ws<br />

C<br />

N<br />

mg1L<br />

Chromium<br />

7440-47-3<br />

2861-94 02DEC1994 ws<br />

U<br />

N<br />

mg5<br />

Chromium<br />

7440-47-3<br />

288-94 04FEB1994 ws<br />

<<br />

N mgR<br />

Page 56 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium 7440-47-3 507-94 03MAR1994 WS O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

GCNS Scan<br />

GCNS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCNS Scan<br />

GCMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

10041-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

10041-4<br />

100-41-4<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

12587-46-1<br />

12587-46-1<br />

I 2587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

622-93<br />

631 -92<br />

636-93<br />

700-92<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631 -92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

631-92<br />

700-92<br />

855-92<br />

1074-93<br />

1147-95<br />

1204-93<br />

1204-94<br />

1378-94<br />

1548-93<br />

1614-94<br />

1840-93<br />

19-94<br />

1920-94<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

633-95<br />

787-95<br />

901-94<br />

956-95<br />

1074-93<br />

1147-95<br />

1204-93<br />

1204-94<br />

138-93<br />

1378-94<br />

1548-93<br />

O5MAY 1993<br />

O5MARl 992<br />

05MAY1993<br />

12MAR1992<br />

02JUN1993<br />

01 APRl992<br />

08APR1994<br />

04MAYl992<br />

01 JUN1992<br />

06JULl 992<br />

O3AUG 1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

O5MAY1 993<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

WMAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

05MAY1993<br />

O5MARl992<br />

12MAR1992<br />

01 APRI 992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3IAUG 1992<br />

070CT1992<br />

03NOV1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRI 992<br />

16JUL1993<br />

06JUL1995<br />

05AUG1993<br />

05MAY 1994<br />

03JUN1994<br />

050CT1993<br />

OlJUL1994<br />

04NOVI993<br />

OSJAN 1994<br />

05AUG1994<br />

05JAN1995<br />

02SEP1994<br />

10DEC1993<br />

O3FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05APR1995<br />

03MAY 1995<br />

08APR1994<br />

01JUN1995<br />

16JULl993<br />

06JUL1995<br />

05AUGI 993<br />

05MAY 1994<br />

02SEP1993<br />

03JUN1994<br />

050CT1993<br />

c<br />

c<br />

C<br />

c<br />

C<br />

c<br />

c<br />

C<br />

C<br />

<<br />

<<br />

c<br />

<<br />

<<br />

<<br />

c<br />

c<br />

C<br />

c<br />

C<br />

C<br />

c<br />

C<br />

c<br />

<<br />

c<br />

c<br />

c<br />

c<br />

<<br />

C<br />

c<br />

C<br />

<<br />

C<br />

C<br />

c<br />

c<br />

<<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

X<br />

V<br />

V<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

N<br />

N<br />

FIELD<br />

0712-<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

rnglL<br />

rnglL<br />

mg1L<br />

mglL<br />

rnglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

rnglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

rnglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

pCVL<br />

pCiR<br />

pCiL<br />

pciR<br />

pciR<br />

pCi<br />

DCiL<br />

Page 57 of 176<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

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ws<br />

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ws<br />

ws<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Gross Alpha I 2587-46-1 1614-94 OlJUL1994 WS -I.OOE+OO 6.00E-01 pCYL<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

i 2587-46-1<br />

12507-46-1<br />

12587-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12587-46-1<br />

12507-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12507-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12507-46-1<br />

12507-46-1<br />

12587-46-1<br />

12507-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12587-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12587-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12587-47-2<br />

12587-47-2<br />

CACOJHARDNES<br />

CACOBHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOBHARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

1839-93<br />

1040-93<br />

19-94<br />

1920-94<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2061-94<br />

288-94<br />

437-95<br />

507-94<br />

633-95<br />

707-95<br />

002-93<br />

901-94<br />

956-95<br />

1074-93<br />

1147-95<br />

1204-93<br />

1204-94<br />

I 348-93<br />

1378-94<br />

1548-93<br />

1614-94<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2061-94<br />

288-94<br />

437-95<br />

507-94<br />

633-95<br />

787-95<br />

802-93<br />

901-94<br />

956-95<br />

1074-93<br />

1204-93<br />

1204-94<br />

1348-93<br />

1378-94<br />

1548-93<br />

1614-94<br />

1039-93<br />

1840-93<br />

19-94<br />

1920-94<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2061-94<br />

280-94<br />

437-95<br />

507-94<br />

633-95<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

O5AUGl 994<br />

O5JANl 995<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

O3MAR 1995<br />

03MAR1994<br />

05APRl995<br />

O3MAY 1995<br />

02JUNl993<br />

08APRl994<br />

OlJUN1995<br />

16JUL1993<br />

06JULl995<br />

05AUGl993<br />

05MAY1994<br />

02SEPl993<br />

03JUNl994<br />

05OCTI 993<br />

01 JUL1994<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

05AUG1994<br />

WAN1995<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOVl994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05APR1995<br />

03MAY 1995<br />

02JUNl993<br />

08APRl994<br />

01JUNl995<br />

I6JUL1993<br />

05AUGl993<br />

OSMAY 1994<br />

02SEP1993<br />

OUUNI 994<br />

05OCTl993<br />

01 JUL1994<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

05AUGl994<br />

WAN1995<br />

02SEPl994<br />

I ODEC 1993<br />

03FEB1995<br />

070CT1994<br />

04NOVl994<br />

04NOV1994<br />

OZDECl994<br />

MFEBl994<br />

03MARI 995<br />

03MARl994<br />

05APRl995<br />

Page 58 of 176<br />

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-1.00E+00 7.00E-01<br />

1.00E+00 <strong>4.</strong>00E-01<br />

-l.OOE+OO 5.00E-01<br />

1.00E+00 7.00E-01<br />

O.OOE+OO 7.00E-01<br />

1.00E+00 7.00E-01<br />

2.00E+00 9.00E-01<br />

2.00E+00 1.40E+00<br />

l.OOE+OO 6.00E-01<br />

1.00E+00 7.00E-01<br />

1.00E+00 7.00E-01<br />

1.00E+00 7.00E-01<br />

O.OOE+OO 5.00E-01<br />

1.00E+00 6.00E-01<br />

1.00E+00 7.00E-01<br />

2.00E+00 1.20E+00<br />

1.00E+00 6.00E-01<br />

-l.OOE+OO O.OOE+OO<br />

1.00€+00 7.00E-01<br />

-2.00E+00 -1.90E+00<br />

<strong>4.</strong>00€+00 l.OOE+OO<br />

7.00E+00 l.OOE+OO<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

1.00E+01 3.00E+00<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

7.00E+00 2.00E+00<br />

3,OOE+00 1 .OOE+OO<br />

1.00E+01 3.OOE+00<br />

1.20E+01 2.00E+00<br />

7.00E+00 l.OOE+OO<br />

7.00E+00 l.OOE+OO<br />

1.20E+01 3.00E+00<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

6.00E+00 2.00E+00<br />

5.00E+00 l.OOE+OO<br />

6.00E+00 2.00E+00<br />

6.00E+00 2.00E+00<br />

0.00E+00 3.00E+00<br />

6.00E+00 2.00E+00<br />

6.00E+00 3.00E+00<br />

9.00E+00 2.00E+00<br />

<strong>4.</strong>00E+00 2.00E+00<br />

5.00E+00 2.00E+00<br />

<strong>4.</strong>00E+00 l.OOE+OO<br />

5.00E+00 1.00E+00<br />

5.00E+00 1.00E+00<br />

9.00E+00 2.00E+00<br />

7.00E+00 1.00E+00<br />

6.00E+OI<br />

7.20E+01<br />

6.00E+01<br />

5.60E+01<br />

6.20E+01<br />

7.40E+01<br />

5.60E+01<br />

6.70E+01<br />

6.70E+01<br />

7.00E+01<br />

<strong>4.</strong>60E+01<br />

6.00E+01<br />

7.00E+01<br />

5.00E+01<br />

6.20E+OI<br />

7.30E+OI<br />

6.00E+01<br />

7.20E+01<br />

6.00E+Ol<br />

7.00E+Ol<br />

6.00E+01<br />

7.80E+01<br />

6.00E+01<br />

N<br />

N<br />

N<br />

N<br />

N<br />

X<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCVL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCilL<br />

pciR<br />

pCYL<br />

pciR<br />

pCYL<br />

pCiL<br />

pCiL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCYL<br />

pCiR<br />

pCYL<br />

pCi<br />

pcin<br />

pCi<br />

pcin<br />

pCi<br />

pCi<br />

mglL CaC03<br />

mglL CaCO3<br />

mgR CaC03<br />

mgR CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mgR CaCO3<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mgR CaCO3<br />

mglL CaCO3<br />

mgR CaCO3<br />

mgR CaCO3<br />

mgR CaC03<br />

mgR CaCO3<br />

mgR CaC03<br />

mglL CaCO3<br />

mgR CaCO3<br />

mgR CaC03<br />

mglL CaCO3<br />

mgR CaC03<br />

mglL CaC03


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Hardness as CaC03 CAC03HARDNES 787-95 03MAY1995 WS <strong>4.</strong>60E+01 X mglL CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7 4 3 9 - 8 9 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

802-93<br />

901-94<br />

956-95<br />

20-95<br />

220-95<br />

437-95<br />

633-95<br />

787-95<br />

956-95<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

02 JUNl993<br />

08APR1994<br />

01JUN1995<br />

05JAN1995<br />

03FEB1995<br />

03MAR1995<br />

05APR 1995<br />

03MAY1995<br />

01 JUN1995<br />

04MAY 1992<br />

16JUL1993<br />

01JUN1992<br />

OSAUGl993<br />

05MAY 1994<br />

O6JUL1 992<br />

02SEP1993<br />

03JUN1994<br />

03AUG 1992<br />

050CT1993<br />

01 JUL1994<br />

3lAUG1992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

05JANl994<br />

05AUG1994<br />

03NOV1992<br />

OSJANl995<br />

02SEP1994<br />

lODECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

03MAR1995<br />

O3MARI 994<br />

05MAY1993<br />

05MAR1992<br />

05APR1995<br />

O5MAY 1993<br />

12MAR1992<br />

03MAY1995<br />

02 JUN1993<br />

01APR1992<br />

OBAPRl994<br />

MMAY 1992<br />

16JUL1993<br />

01JUNl992<br />

05AUGl993<br />

O5MAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUNl994<br />

03AUGl992<br />

050CT1993<br />

01 JULl994<br />

31 AUGl992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

05JAN1 994<br />

05AUG1994<br />

03NOV1992<br />

05JAN1995<br />

02SEP1994<br />

lODECl993<br />

03FEB1995<br />

07OCT1994<br />

04NOV1994<br />

Page 59 of 176<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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7.00E+01<br />

7.40E+01<br />

6.00E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

I .00E+00<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

l.OOE+OO<br />

l.WE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

1.00E+00<br />

O.OOE+OO<br />

1 .OOE+OO<br />

l.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0,00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+W<br />

O.M)E+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

<<br />

c<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL CaC03<br />

mg1L CaC03<br />

mg1L CaCO3<br />

mglL<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

wfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

m&<br />

mgfl<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL'fTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

7439-92-1 2692-94 04NOV1994 WS O.OOE+OO C N mg1L<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-92-1<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

956-95<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631 -92<br />

700-92<br />

855-92<br />

1023-92<br />

1074-93<br />

1 143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1548-93<br />

1614-94<br />

1624-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

1477-92<br />

1796-92<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

I<br />

378-94<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05MAYI 993<br />

OSMAR1992<br />

OSAPR1995<br />

OSMAY 1993<br />

12MAR1992<br />

OJMAY 1995<br />

02JUN1993<br />

01 APRl992<br />

OBAPR1994<br />

01JUN1995<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUGI 992<br />

070CT1992<br />

03NOV1992<br />

OSMAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY1992<br />

16JUL1993<br />

01 JUN1992<br />

OSAUG1993<br />

05MAY I994<br />

06JULl992<br />

02SEPl993<br />

03JUN1994<br />

03AUG1992<br />

OSOCTI 993<br />

01 JUL1994<br />

3lAUGl992<br />

070CTI 992<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

OSAUG1994<br />

03NOVl 992<br />

05JAN1995<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOVl994<br />

02DECl994<br />

04FEB1994<br />

om1995<br />

om1994<br />

05MAY 1993<br />

05MARl992<br />

OSAPR1995<br />

05MAY 1993<br />

12MAR1992<br />

03MAY 1995<br />

O2JUNl 993<br />

01 APRI 992<br />

08APR1994<br />

04MAY I<br />

992<br />

16JUL1993<br />

01JUN1992<br />

OSAUGl993<br />

05MAY1994<br />

06JUL1992<br />

02SEPl993<br />

03JUN1994<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

U<br />

N<br />

N<br />

U<br />

N<br />

N<br />

N<br />

N<br />

U<br />

N<br />

N<br />

N<br />

U<br />

N<br />

N<br />

N<br />

N<br />

U<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

C<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

C<br />

C<br />

c<br />

C<br />

<<br />

C<br />

C<br />

C<br />

<<br />

<<br />

C<br />

C<br />

C<br />

C<br />

C<br />

<<br />

<<br />

C<br />

C<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mg1L<br />

WlL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mgk<br />

mg/L<br />

WlL<br />

WlL<br />

WlL<br />

Wfl<br />

mglL<br />

Page 60 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Manganese 7439-96-5 1477-92 03AUG1992 WS O.OOE+OO N mglL<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Methylene Chloride<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

7439-96-5<br />

7439 - 96 - 5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439 - 96 - 5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

75-09-2<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440 - 02 - 0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631 -92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

114392<br />

1332-92<br />

1477-92<br />

154893<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1348-93<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

050CT1993<br />

OlJUL1994<br />

31AUG1992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

05AUG 1994<br />

03NOV1992<br />

05JAN1995<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

MNOV1994<br />

02DEC1994<br />

04FEB1994<br />

O3MAR1995<br />

03MAR1994<br />

O5MAY 1 993<br />

05MAR1992<br />

05APR1995<br />

O5MAY 1993<br />

12MAR1992<br />

03MAY 1995<br />

02JUNl993<br />

01 APRl992<br />

OBAPR1994<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUGl992<br />

050CT1993<br />

31AUGl992<br />

070CT1992<br />

03NOV1992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

02SEP1993<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

05MAY 1993<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUN 1992<br />

05AUG1993<br />

05MAY1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CTl993<br />

01 JULl994<br />

3lAUG1992<br />

070CT1992<br />

04NOV1993<br />

MNOV1993<br />

05JAN1994<br />

05AUGl994<br />

03NOV1992<br />

Page 61 of 176<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

WlL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

WlL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

W/L<br />

WlL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

WlL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

WlL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Nickel 7440-02-0 20-95 05JAN1995 WS O.OOE+OO < N mglL<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

Phosphate as P<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

PHOSPHATEASP<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

744049-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7640-09-7<br />

7440-09-7<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692 - 94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1863-92<br />

1937-92<br />

1796-92<br />

1023-92<br />

I 143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1937-92<br />

622-93<br />

631 -92<br />

700-92<br />

855-92<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861 -94<br />

288-94<br />

437-95<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MARl995<br />

03hlAR1994<br />

05MAY 1993<br />

(HMAR 1992<br />

05APR1995<br />

OSMAY 1993<br />

12MAR1992<br />

03MAY 1995<br />

02JUN1993<br />

01 APRl992<br />

O8APR 1 994<br />

04MAY 1992<br />

OlJUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

05MAY1993<br />

05MAR1992<br />

12MAR 1992<br />

01 APRI 992<br />

190CT1992<br />

03NOV1992<br />

O7OCTI 992<br />

04MAY1992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

03NOV1992<br />

OSMAY1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAYl992<br />

16JUL1993<br />

01 JUNl992<br />

05AUGl993<br />

05MAY 1994<br />

OGJULI 992<br />

02SEPl993<br />

O3JUNl994<br />

03AUG1992<br />

050CTI 993<br />

01 JULl994<br />

3lAUGl992<br />

070CT1992<br />

04NOV1993<br />

04NOVl993<br />

05JAN1994<br />

OSAUG1994<br />

03NOV1992<br />

OSJAN1995<br />

02SEP1994<br />

10DECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DECl994<br />

04FEBl994<br />

03MARl995<br />

Page 62 of 176<br />

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< N<br />

< N<br />

< N<br />

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< N<br />

c<br />

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< N<br />

< N<br />

c<br />

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< N<br />

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< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

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N<br />

N<br />

NT<br />

N<br />

N<br />

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N<br />

N<br />

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<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

wfl<br />

mglL<br />

mglL<br />

mgfl<br />

mgk<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgL<br />

mgL<br />

mgfl<br />

mglL<br />

mg5<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgk<br />

mgk<br />

mglL<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Potassium 7440-09-7 507-94 03MAR1994 WS 2.00E+00 N<br />

mglL<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

7440-10-0<br />

7440-10-8<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-10-0<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

1440-21-3<br />

7440-21 -3<br />

1440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

707-95<br />

002-93<br />

055-92<br />

901 -94<br />

1147-95<br />

220-95<br />

437-95<br />

633-95<br />

707-95<br />

002-93<br />

956-95<br />

1147-95<br />

220-95<br />

437-95<br />

633-95<br />

707-95<br />

002-93<br />

956-95<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

055-92<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1340-93<br />

1370-94<br />

1477-92<br />

1540-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1039-93<br />

1040-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2061-94<br />

200-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

63693<br />

700-92<br />

707-95<br />

802-93<br />

055-92<br />

05MAY 1993<br />

05MAR1992<br />

05APR1995<br />

05MAY1993<br />

12MAR1992<br />

03MAY 1995<br />

02 JUNl993<br />

01 APRl992<br />

00APR1994<br />

06JULl995<br />

O3FEBl 995<br />

03MAR1995<br />

05APR 1995<br />

OJMAY1995<br />

02JUN1993<br />

01JUN1995<br />

06JUL1995<br />

O3FEB1995<br />

O3MAR1995<br />

05APR 1995<br />

O3MAY 1995<br />

02JUN1993<br />

01JUN1995<br />

04MAY 1992<br />

01 JUN1992<br />

06JULl992<br />

03AUG1992<br />

31AUGl992<br />

070CT1992<br />

03NOV1992<br />

OSMAY 1993<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUN1992<br />

05AUG1993<br />

05MAYl994<br />

06JUL1992<br />

O2SEPl 993<br />

O3JUNI 994<br />

03AUG 1992<br />

050CT1993<br />

01 JUL1994<br />

3lAUGl992<br />

070CT1992<br />

MNOV1993<br />

MNOV1993<br />

05JANl994<br />

05AUG1994<br />

03NOV1992<br />

05JAN1995<br />

02SEP1994<br />

10DECl993<br />

03FEBl995<br />

070CT1994<br />

04NOV1994<br />

MNOV1994<br />

02DEC1994<br />

MFEB 1994<br />

03MAR1995<br />

03MARl994<br />

05MAYl993<br />

OSMAR1992<br />

05APR1995<br />

OSMAY 1993<br />

12MAR 1992<br />

03MAY 1995<br />

02JUN1993<br />

01APR1992<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

<<br />

C<br />

<<br />

<<br />

C<br />

C<br />

<<br />

<<br />

<<br />

<<br />

C<br />

C<br />

C<br />

C<br />

J<br />

J<br />

J<br />

B<br />

J<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mgtL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

pCilml<br />

pCUml<br />

pCUml<br />

pCilml<br />

pCilml<br />

pCVmL<br />

pCilml<br />

pCiml<br />

pCilml<br />

pCiml<br />

pCUmi<br />

pCiml<br />

pCimL<br />

pCilml<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgR<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

WlL<br />

mglL<br />

Page 63 of 176<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Silicon 7440-21-3 901 -94 08APR1994 WS 6.00E+00 N mg1L<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Specific conductance<br />

Specifc conductance<br />

Specifc conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specfic conductance<br />

Specifc conductance<br />

Specific conductance<br />

spec if^ conductance<br />

Specib conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specifc conductance<br />

Specifc conductance<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7 44 0 - 2 3- 5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1074-93<br />

1147-95<br />

1204-93<br />

1204-94<br />

1348-93<br />

1376-94<br />

1548-93<br />

1614-94<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

268-94<br />

437-95<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

05MAY1993<br />

05MAR1992<br />

12MAR1992<br />

OiAPR1992<br />

04MAY1992<br />

16JUL1993<br />

01JUNl992<br />

05AUGl993<br />

05MAY1994<br />

06JUL1992<br />

02SEP1993<br />

OUUNl994<br />

03AUG1992<br />

050CT1993<br />

01 JUL1994<br />

31AUG1992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

05AUG1994<br />

03NOV1992<br />

05JAN1995<br />

02SEP1994<br />

10DECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DEC1994<br />

04FEE1994<br />

03MAR1995<br />

03MAR1994<br />

05MAYl993<br />

05MAR1992<br />

05APR1995<br />

osMAY1993<br />

12MAR1992<br />

03MAY1995<br />

02JUNl993<br />

01APR1992<br />

08APR1994<br />

16JUL1993<br />

06JUL1995<br />

05AUGl993<br />

osMAY 1994<br />

02SEP1993<br />

03JUN1994<br />

050CT1993<br />

01 JUL1994<br />

MNOV1993<br />

MNOVl993<br />

WAN1994<br />

05AUGl994<br />

05JANl995<br />

02SEPl994<br />

1 ODECi993<br />

03FEB1995<br />

070CT1994<br />

MNOVl994<br />

MNOVl994<br />

02DECl994<br />

MFEB1994<br />

03MAR1995<br />

Page 64 of 176<br />

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ws<br />

< NT<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

< N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

B<br />

J<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

m&L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgfl<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

wfl<br />

mgfl<br />

wfl<br />

mglL<br />

mg1L<br />

mg/L<br />

mglL<br />

mgk<br />

mgfl<br />

WlL<br />

mg/L<br />

wfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

WlL<br />

mg/L<br />

WlL<br />

mg/L<br />

mglL<br />

wfl<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

umhos/cm<br />

urnhodcm<br />

umhodcm<br />

umhodcm<br />

urnhoslcm<br />

umhodcm<br />

umhodcm<br />

urnhoslcm<br />

umhodcm<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

umhodcm


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Specific conductance SO145 507-94 03MAR1994 WS 2.10E+02 N umhoslcrn<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440 - 24 - 6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

I 2143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

7440-25-7<br />

1440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-26-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

633-95<br />

787-95<br />

802-93<br />

901-94<br />

956-95<br />

1023-92<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

622-93<br />

631-92<br />

633-95<br />

636-93<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

05APR1995<br />

O3MAY 1995<br />

02JUN1993<br />

08APR1994<br />

01JUNl995<br />

04MAY 1992<br />

16JUL1993<br />

01JUN1992<br />

OSAUGI 993<br />

OSMAY 1994<br />

06JUL1 992<br />

02SEP1993<br />

03JUN1994<br />

O3AUGl 992<br />

050CT1993<br />

01JUL1994<br />

31AUGI 992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

05JAN1994<br />

OSAUG1994<br />

O3NOVl 992<br />

05JAN1995<br />

02SEPl994<br />

10DECl993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05MAY 1993<br />

05MAR1992<br />

05APR1995<br />

05MAY 1993<br />

12MAR1992<br />

03MAY1995<br />

O2JUNl 993<br />

01 APRl992<br />

08APR1994<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

04MAY 1992<br />

01 JUNl992<br />

06JULl992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

O3NOVl 992<br />

05MAY 1993<br />

osMAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAYI992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

07OCT1992<br />

03NOV1992<br />

OSMAY 1993<br />

WR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

01 JUN1992<br />

Page 65 of 176<br />

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umhoslcrn<br />

umhoslcrn<br />

umhoslcm<br />

umhoslcrn<br />

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mg/L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgn<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

WlL<br />

W/L<br />

mg/L<br />

mg/L<br />

WlL<br />

rnglL<br />

mgfl<br />

mglL<br />

mg1L<br />

mglL<br />

WlL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

WIL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mgiL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

W/L<br />

mg/L<br />

mgn<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Thorium 7440-29-1 1332-92 06JUL1992 WS O.OOE+OO < mglL<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trihloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31 -5<br />

7440-31 -5<br />

7440-31 -5<br />

7440-31 -5<br />

7440-31 -5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

7440-32-6<br />

7440-32-6<br />

1 oa-88-3<br />

108-88-3<br />

108-88-3<br />

1 oa-aa-3<br />

108-88-3<br />

1 08-aa-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

156-60-5<br />

79-01-6<br />

7440-33-7<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

11 43-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1796-92<br />

700-92<br />

1624-92<br />

1937-92<br />

631 -92<br />

700-92<br />

855.92<br />

1023-92<br />

1143-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

631-92<br />

700-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1332-92<br />

855-92<br />

631-92<br />

1477-92<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

OSMAY 1993<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

05MAY 1993<br />

OSMAR1992<br />

12MAR1992<br />

01 APR1992<br />

04h4AY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

05MAY1993<br />

05MARl992<br />

12MARl992<br />

OlAPRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

05MAR1992<br />

12MAR1992<br />

OlAPRl992<br />

04MAY 1992<br />

01 JUNl992<br />

06JUL1992<br />

03AUGI992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY1992<br />

01 JUN1992<br />

06JULl992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

05MAR1992<br />

I<br />

ZMARI 992<br />

01 APRI 992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CTl992<br />

03NOV1992<br />

OSMAY 1 993<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

ws<br />

ws<br />

ws<br />

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mgfl<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mgll<br />

mglL<br />

mglL<br />

W/L<br />

mglL<br />

mg1L<br />

WlL<br />

mglL<br />

mgfl<br />

m a<br />

ug1L<br />

ugk<br />

ugk<br />

ug1L<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

ug1L<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

ug/L<br />

ugfl<br />

ugfl<br />

uglL<br />

Wfl<br />

Wfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mgk<br />

mg/L<br />

mglL<br />

mglL<br />

WlL<br />

WlL<br />

mglL<br />

Page 66 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Uranium 7440-61-1 1023-92 04MAY1992 WS O.OOE+OO NT mglL<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

zirconium<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

1074-93<br />

1143-92<br />

1204-93<br />

1204-94<br />

1332-92<br />

1348-93<br />

1378-94<br />

1477-92<br />

1548-93<br />

1614-94<br />

1624-92<br />

1796-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1937-92<br />

20-95<br />

2123-94<br />

2154-93<br />

220-95<br />

2413-94<br />

2691-94<br />

2692-94<br />

2861 -94<br />

286-94<br />

437-95<br />

507-94<br />

622-93<br />

631 -92<br />

633-95<br />

700-92<br />

787-95<br />

802-93<br />

855-92<br />

901-94<br />

956-95<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1937-92<br />

622-93<br />

631 -92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

1477-92<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1143-92<br />

1332-92<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

O5MAY 1994<br />

06JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

OlJUL1994<br />

31 AUG 1992<br />

070CT1992<br />

04NOV1993<br />

04NOV1993<br />

OSJANl994<br />

05AUG1994<br />

03NOV1992<br />

OSJANl995<br />

02SEP1994<br />

10DEC1993<br />

03FEB1995<br />

070CT1994<br />

04NOV1994<br />

04NOV1994<br />

02DECl994<br />

04FEB1994<br />

03MAR 1995<br />

03MARl994<br />

OSMAY1993<br />

OSMAR1992<br />

OSAPR1995<br />

12MAR1992<br />

03MAY 1995<br />

02JUNl993<br />

01 APRl992<br />

OBAPRl994<br />

01 JUNl995<br />

04MAY 1992<br />

OlJUN1992<br />

06JULl992<br />

03AUG1992<br />

3lAUGl992<br />

03NOV1992<br />

OSMAY 1993<br />

OSMARl992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY 1992<br />

01 JUNl992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

MAY 1992<br />

01JUN1992<br />

06JUL 1992<br />

O3AUG1992<br />

31AUG1992<br />

07OCT1992<br />

03NOV1992<br />

WAY 1993<br />

05MAR1992<br />

12MARl992<br />

01APR1992<br />

WMAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

Page 67 of 176<br />

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mglL<br />

mglL<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

WlL<br />

Wfl<br />

mglL<br />

mglL<br />

mg1L<br />

WlL<br />

mglL<br />

mgfl<br />

mglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Zirconium 7440-67-7 1477-92 03AUG1992 WS 0.00E+00 C N mglL<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

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PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

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PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

'<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

so296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

so296<br />

7440-67-7<br />

1624-92<br />

1796-92<br />

1937-92<br />

622-93<br />

631-92<br />

700-92<br />

855-92<br />

1023-92<br />

1067-92<br />

1074-93<br />

11 11-92<br />

1143-92<br />

11 47-95<br />

11 95-92<br />

1204-93<br />

1222-92<br />

1309-92<br />

1332-92<br />

1348-93<br />

1369-92<br />

1378-94<br />

1444-92<br />

1477-92<br />

1503-92<br />

1551-92<br />

1599-92<br />

1614-94<br />

1624-92<br />

1684-92<br />

179692<br />

1096-92<br />

1204-94<br />

1267-92<br />

1418-92<br />

i 548-93<br />

1662-92<br />

1839-93<br />

1840-93<br />

19-94<br />

1920-94<br />

1967-92<br />

20-95<br />

2123-94<br />

2137-92<br />

2154-93<br />

2413-94<br />

2691-94<br />

220-95<br />

2692-94<br />

2861-94<br />

288-94<br />

437-95<br />

507-94<br />

612-92<br />

622-93<br />

631-92<br />

633-95<br />

65692<br />

636-93<br />

700-92<br />

712-92<br />

787-95<br />

802-93<br />

827-92<br />

855-92<br />

88982<br />

901-94<br />

922-92<br />

956-95<br />

976-92<br />

994-92<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

O5MAY 1993<br />

OSMARl992<br />

12MAR1992<br />

01APR1992<br />

MMAY 1992<br />

13MAY 1992<br />

16JUL1993<br />

2OMAY 1992<br />

26MAY1992<br />

OlJUN1992<br />

06JUL1995<br />

08JUN1992<br />

05AUG1993<br />

05MAY1994<br />

15JUN1992<br />

22JUN1992<br />

29JUN1992<br />

06JUL1992<br />

02SEPl993<br />

13JUL1992<br />

03JUN1994<br />

21JUL1992<br />

27JULl992<br />

03AUG1992<br />

1 OAUGl992<br />

050CTl993<br />

17AUG1992<br />

24AUG1992<br />

OlJUL1994<br />

31 AUGl992<br />

08SEP1992<br />

14SEP1992<br />

070CT1992<br />

04NOVl993<br />

04NOV1993<br />

05JAN1994<br />

05AUGl994<br />

09NOV1992<br />

05JAN1995<br />

02SEP1994<br />

07DEC1992<br />

10DEC1993<br />

03FEBl995<br />

070CT1994<br />

04NOV1994<br />

04NOVl994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

02MAR1992<br />

05MAY 1993<br />

OsMAR1992<br />

05APR1995<br />

OSMAY 1993<br />

09MAR1992<br />

12MAR1992<br />

1-1992<br />

03MAY 1995<br />

02JUN1993<br />

23MAR1992<br />

0 1 APR1992<br />

06APR1992<br />

08APR1994<br />

13APR1992<br />

01JUN1995<br />

22APR1992<br />

27APR1992<br />

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su<br />

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Page 68 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

WAG 7, SMU 8. C746K-5<br />

1 ,l-Dichloroethane<br />

1 ,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1,l-Dichloroethane<br />

1,l-Dichloroethane<br />

1.1 -Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,I-Dichloroelhene<br />

1 ,I-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1,l -Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1,l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

Acetone<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

67-64-1<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1838-93<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

147a92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1838-93<br />

1921-94<br />

1922-94<br />

ma92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

43895<br />

439-95<br />

508-94<br />

623-93<br />

04MAYl992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3OJAN1992<br />

05MAR1992<br />

12MARl992<br />

01 APR1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3OJANl992<br />

OSMAR 1992<br />

12MARl992<br />

01 APRI 992<br />

04NOV1993<br />

04MAY 1992<br />

16JULl993<br />

01JUN1992<br />

05AUG1993<br />

05MAY 1 994<br />

05AUG1993<br />

05MAY1994<br />

06JUL1992<br />

02SEP1993<br />

02SEPl993<br />

03JUN1994<br />

03JUN1994<br />

03AUG1992<br />

050CTI993<br />

050CTI993<br />

01 JULl994<br />

OlJULl994<br />

31AUGI 992<br />

070CT1992<br />

MNOV1993<br />

05AUGl994<br />

05AUG1994<br />

03NOV1992<br />

OSJAN1994<br />

05JAN1995<br />

01 DECl992<br />

O2SEPl994<br />

02SEP1994<br />

10DECl993<br />

10DEC1993<br />

WAN1 995<br />

03FEB1995<br />

03FEB1995<br />

%JAN1994<br />

070CT1994<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

O2DEC1994<br />

04FEB1994<br />

04FEB1994<br />

30JAN1992<br />

03MARl995<br />

03MPR1995<br />

03MAR1994<br />

OSMAY 1993<br />

Page 69 of 176<br />

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ug1L<br />

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mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

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mg1L<br />

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mglL<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Aluminum 7429-90-5 632-92 05MAR1992 WS O.OOE+OO N mglL<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1429-90-5<br />

1429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

1440-38-2<br />

740-38-2<br />

7440-38-2<br />

7440-38-2<br />

1440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

1440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

1440-38-2<br />

7440-38-2<br />

1440-38-2<br />

7440-38-2<br />

740-38-2<br />

7440-38-2<br />

7440-38-2<br />

740-38-2<br />

7440-38-2<br />

1440-38-2<br />

1440-38-2<br />

1440-38-2<br />

7w-3a-2<br />

7440-38-2<br />

7440-38-2<br />

7440-30-2<br />

7440-38-2<br />

7440-30-2<br />

7440-382<br />

7440-38-2<br />

7440-38-2<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

788-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

1 144-92<br />

1333-92<br />

1024-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

21 02-92<br />

395-92<br />

623-93<br />

632-92<br />

856-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

161 5-94<br />

1616-94<br />

1625-92<br />

701-92<br />

1797-92<br />

1838-93<br />

1938-92<br />

1921-94<br />

1922-94<br />

20-94<br />

21-95<br />

2 102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

21 61 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

290-94<br />

395-92<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

289-94<br />

438-95<br />

O5APRl995<br />

05APR1995<br />

05MAY 1993<br />

12MAR1992<br />

03MAY1995<br />

03MAY1995<br />

02JUNl993<br />

01 APRl992<br />

08APR1994<br />

OMPRl994<br />

MAY<br />

1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31 AUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

30JAN1992<br />

05MAY 1993<br />

O5MAR1992<br />

12MAR1992<br />

01 APRl992<br />

MAY1992<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

05MAYl994<br />

05AUG1993<br />

O5MAY 1994<br />

06JULl992<br />

02SEP1993<br />

02SEP1993<br />

03JUN1994<br />

03JUNl994<br />

03AUG1992<br />

050CT1993<br />

SOCTl993<br />

01 JULl994<br />

01 JULl994<br />

3lAUGl992<br />

070CT1992<br />

04NOV1993<br />

05AUGl994<br />

05AUG1994<br />

03NOV1992<br />

05JAN1994<br />

@JAN1995<br />

OlDECl992<br />

02SEP1994<br />

02SEP1994<br />

lODEC1993<br />

lODECl993<br />

05JAN1995<br />

O3FEBl995<br />

O3FEBl995<br />

05JANl994<br />

070CT1994<br />

070CT1994<br />

04NOVl994<br />

O2DEC1 994<br />

02DEC1994<br />

04FEB1994<br />

04FEB1994<br />

JOJAN1992<br />

ow1995<br />

ow1995<br />

03MAR1994<br />

OSMAY 1993<br />

05MAR1992<br />

05APR1995<br />

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ws<br />

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ws<br />

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ws<br />

ws<br />

ws<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OoE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

<<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALlDATlON<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Arsenic 7440-38-2 635-95 05APR1995 WS O.OOE+OO < N mg1L<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-38-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-30-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440 - 39 - 3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7143-2<br />

7143-2<br />

7143-2<br />

7143-2<br />

637-93<br />

701-92<br />

788-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1470-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1830-93<br />

1921 -94<br />

1922-94<br />

1930-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

430-95<br />

439-95<br />

50894<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

700-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

05MAY 1993<br />

12MAR1992<br />

03MAY 1995<br />

03MAY1995<br />

O2JUNl 993<br />

01 APRl992<br />

00APR1994<br />

O0APR1 994<br />

04MAY 1992<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

05MAY1994<br />

05AUG1993<br />

O5MAYl 994<br />

06JULI 992<br />

02SEP1993<br />

02SEP1993<br />

03JUN1994<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

05OCTl 993<br />

OlJULl994<br />

OlJUL1994<br />

31AUG 1992<br />

070CT1992<br />

04NOV1993<br />

05AUG1994<br />

05AUGl994<br />

03NOV1992<br />

05JANl994<br />

WAN1995<br />

01DECl992<br />

O2SEPl994<br />

O2SEPl 994<br />

10DECl993<br />

1 ODEC1993<br />

05JAN1995<br />

03FEB1995<br />

03FEB1995<br />

(HJANI 994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

02DECl994<br />

02DEC1994<br />

04FEB1994<br />

04FEB1994<br />

3OJANl992<br />

03MAR1995<br />

03MAR1995<br />

03MAR1994<br />

05MAY 1993<br />

05MAR1992<br />

05APR1995<br />

05APRl995<br />

05MAY1993<br />

12MAR1992<br />

03MAY 1995<br />

03MAYl995<br />

O2JUN1 993<br />

OIAPRI 992<br />

08APR1994<br />

OWR1994<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUGl992<br />

31AUG1992<br />

070CT1992<br />

Page 71 of 176<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

vvs<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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< N<br />

< N<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

71-43-2 1938-92 03NOV1992 WS 5.00E+00<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmiurn<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmum<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

71-43-2<br />

7 1-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7440-41 -7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

744043-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

744043-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1 144-92<br />

1333-92<br />

1478-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

623-93<br />

1625-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

120693<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1625-92<br />

1838-93<br />

161 6-94<br />

1797-92<br />

1921-94<br />

1922-94<br />

1938-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

01 DECl992<br />

3OJAN1992<br />

OSMARI 992<br />

12MAR1992<br />

01 APRl992<br />

O4MAY 1992<br />

01 JUN1992<br />

06JULI 992<br />

03AUG1992<br />

3lAUGI 992<br />

O7OCTI 992<br />

03NOV1992<br />

01 DECI 992<br />

30JAN1992<br />

05MAY1993<br />

05MAR1992<br />

12MARl992<br />

01 APR 1992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

30JAN1992<br />

05MAY1993<br />

05MAR1992<br />

1 2MARI 992<br />

01 APRl992<br />

04MAY1992<br />

16JUL1993<br />

01 JUNl992<br />

05AUG1993<br />

WAY<br />

I994<br />

O5AUG 1993<br />

(HMAY 1994<br />

06JUL1992<br />

02SEP1993<br />

02SEP1993<br />

03JUN1994<br />

03JUNl994<br />

03AUG1992<br />

050CT1993<br />

OSOCTl993<br />

OlJUL1994<br />

OlJULl994<br />

31AUG 1992<br />

070CT1992<br />

MNOV1993<br />

05AUGl994<br />

05AUG1994<br />

03NOV1992<br />

OSJANl994<br />

05JANl995<br />

01 DECl992<br />

OZSEP1994<br />

02SEP1994<br />

1 ODECI 993<br />

lODECI993<br />

WAN1995<br />

03FEB1995<br />

03FEB1995<br />

05JAN1994<br />

070CT1994<br />

070CT1994<br />

04NOVl994<br />

02DEC1994<br />

02DEC1994<br />

MFEB1994<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

0.00E+00<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

0.00~+00<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

0.00E+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

0.00E+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

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Page 72 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Cadmium 7440-43-9 290-94 04FEB1994 WS O.OOE+OO c N mglL<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chloride<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

16887-00-6<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

395-92<br />

438-95<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

788-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

957-95<br />

958-95<br />

102492<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

ma-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701 -92<br />

856-92<br />

395-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1838-93<br />

1921-94<br />

1922-94<br />

1938-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

30JANI 992<br />

03MAR1995<br />

03MAR1995<br />

03MAR1994<br />

O5MAY 1993<br />

05MAR1992<br />

OSAPR1995<br />

05APR1995<br />

OSMAYI 993<br />

12MAR1992<br />

03MAY 1995<br />

O3MAY 1995<br />

02JUN1993<br />

01 APR 1992<br />

08APR1994<br />

08APR1994<br />

01JUNl995<br />

01JUN1995<br />

04MAY 1992<br />

01JUN1992<br />

06JULI 992<br />

03AUG1992<br />

31 AUGI 992<br />

070CTl992<br />

03NOV1992<br />

01 DEC1992<br />

30JAN1992<br />

05MAYl993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

3OJAN1992<br />

04MAY 1992<br />

16JULl993<br />

01JUN1992<br />

05AUG1993<br />

05MAY 1994<br />

05AUG1993<br />

05MAY 1994<br />

06JUL1992<br />

02SEPl993<br />

O2SEPl993<br />

03JUN1994<br />

03JUN1994<br />

03AUGl992<br />

050CT1993<br />

050CTI993<br />

OlJULl994<br />

OlJUL1994<br />

3lAUGl992<br />

070CT1992<br />

04NOV1993<br />

05AUGl994<br />

05AUG 1994<br />

03NOV1992<br />

05JAN1994<br />

05JANl995<br />

OlDEC1992<br />

02SEPl994<br />

02SEP1994<br />

lODECl993<br />

I ODECI 993<br />

05JAN1995<br />

05JAN1994<br />

070CT1994<br />

070CTl994<br />

04NOVI994<br />

02DEC1994<br />

02DEC1994<br />

04FEB1994<br />

04FEB1994<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

c<br />

N<br />

U<br />

N<br />

U<br />

N<br />

< N<br />

< N<br />

c<br />

N<br />

U<br />

N<br />

U<br />

N<br />

c<br />

N<br />

c<br />

N<br />

c<br />

N<br />

< N<br />

< N<br />

< N<br />

c<br />

N<br />

c<br />

N<br />

< N<br />

< N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

<<br />

NT<br />

c<br />

N<br />

c<br />

N<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

c<br />

N<br />

c<br />

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N<br />

<<br />

N<br />

c<br />

N<br />

c<br />

N<br />

c<br />

N<br />

c<br />

N<br />

<<br />

N<br />

<<br />

N<br />

c<br />

N<br />

U<br />

N<br />

c<br />

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N<br />

<<br />

N<br />

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N<br />

<<br />

N<br />

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N<br />

c<br />

N<br />

U<br />

N<br />

U<br />

N<br />

<<br />

N<br />

c<br />

N<br />

mi&<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mdL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mg/L<br />

mglL<br />

mg/L<br />

mgfl<br />

mglL<br />

Page 73 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium 744047-3 395-92 30JAN1992 WS O.OOE+OO < N mglL<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Dissolved Oxygen<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-0<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

OXYGEN DIS<br />

100414<br />

10041-4<br />

100414<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

10041-4<br />

10041-4<br />

100-41-4<br />

100-414<br />

10041-4<br />

100-41-4<br />

I 6984-48-8<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

508-94<br />

623-93<br />

632-92<br />

637-93<br />

701-92<br />

803-93<br />

as6-92<br />

902-94<br />

903-94<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

I 938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

395-92<br />

102492<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

I 93a-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

395-92<br />

1075-93<br />

I 148-95<br />

1149-95<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1349-93<br />

1379-94<br />

I 380-94<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1921-94<br />

1922-94<br />

20-94<br />

21-95<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

03MAR1994<br />

05MAY 1993<br />

05MAR1992<br />

OSMAY 1993<br />

12MAR1992<br />

02JUNl993<br />

01 APRl992<br />

08APRl994<br />

08APR1994<br />

04MAY 1992<br />

OlJUN1992<br />

06JUL1 992<br />

03AUG1992<br />

3lAUGl992<br />

O7OCTI 992<br />

03NOV1992<br />

01 DECl992<br />

30JANl992<br />

OSMAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

01 JUNl992<br />

06JULl992<br />

03AUG1992<br />

3lAUG1992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

3WANl992<br />

05MAY1993<br />

05MAR1992<br />

12MAR1992<br />

01 APR 1992<br />

30JANl992<br />

04MAY 1992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

3 WAN1 992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

3WANl992<br />

16JUL1993<br />

06JUL1995<br />

06JULl995<br />

05AUG1993<br />

(HMAY 1994<br />

OSAUGl993<br />

05MAY1994<br />

02SEP1993<br />

03JUNI994<br />

03JUNl994<br />

050CT1993<br />

05OCTl993<br />

01 JULl994<br />

01 JUL1994<br />

05AUGl994<br />

OSAUG1994<br />

WAN1994<br />

05JAN1995<br />

02SEP1994<br />

02SEPl994<br />

1 ODEC1993<br />

10DECl993<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

4<br />

<<br />

<<br />

<<br />

<<br />

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<<br />

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<<br />

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<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

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<<br />

<<br />

<<br />

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c<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

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c<br />

c<br />

c<br />

c<br />

<<br />

4<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

V<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

FIELD<br />

FIELD<br />

0712-<br />

0712-<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

Wfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug5<br />

ugfl<br />

ugk<br />

uglL<br />

uglL<br />

w/L<br />

uglL<br />

ugfl<br />

ugfl<br />

ug1L<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

Wfl<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugR<br />

ugfl<br />

uglL<br />

ugn<br />

UglL<br />

uglL<br />

ugk<br />

ugfl<br />

Page 74 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE NPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

GCNS Scan GCNS SCAN 22-95 OSJAN1995 WS O.OOE+OO V N uglL<br />

GCNS Scan<br />

GCNS Scan<br />

GClMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GClMS Scan<br />

GClMS Scan<br />

GClMS Scan<br />

GClMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCMS Scan<br />

GClMS Scan<br />

GClMS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

Gamma Activity<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GClMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GClMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GAMMA<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

1258746-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

1258746-1<br />

12587-46-1<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

438-95<br />

439-95<br />

508-94<br />

509-94<br />

634-95<br />

63195<br />

788-95<br />

789-95<br />

902-94<br />

903-94<br />

957-95<br />

958-95<br />

395-92<br />

1075-93<br />

1 i4a-95<br />

1149-95<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1349-93<br />

137493<br />

1379-94<br />

1380-94<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

ima-93<br />

1921 -94<br />

1922-94<br />

20-94<br />

21-95<br />

212494<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

241494<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

50894<br />

634-95<br />

635-95<br />

788-95<br />

789-95<br />

803-93<br />

902-94<br />

903-94<br />

957-95<br />

95895<br />

O3FEBl995<br />

O3FEB1995<br />

OSJANl994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

02DEC1994<br />

04FEB1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1995<br />

03MAR1994<br />

03MAR1994<br />

05APR1995<br />

05APR1995<br />

O3MAY 1995<br />

O3MAYl995<br />

08APR1994<br />

08APRl994<br />

01 JUN1995<br />

01 JUN1995<br />

3OJANl992<br />

16JUL1993<br />

06JULl995<br />

06JUL1995<br />

OSAUGl993<br />

osMAY1994<br />

05AUG1993<br />

M Y 1994<br />

02SEP1993<br />

02SEPl993<br />

03JUN1994<br />

O3JUN1994<br />

05OCTl993<br />

050CT1993<br />

01 JULl994<br />

01 JUL1994<br />

04NOV1993<br />

05AUG1994<br />

05AUG1994<br />

05JAN 1994<br />

05JAN1995<br />

OZSEPl994<br />

02SEPl994<br />

10DEC1993<br />

lODEC1993<br />

05JAN1995<br />

03FEB1995<br />

03FEB1995<br />

05JAN1994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

OZDEC 1994<br />

OZDECl994<br />

04FEB1994<br />

04FEB1994<br />

30JAN1992<br />

03MAR1995<br />

03MAR1995<br />

03MAR1994<br />

05APR 1995<br />

05APRl995<br />

03MAY 1995<br />

03MAY1995<br />

02JUN1993<br />

08APR1994<br />

08APR1994<br />

01JUN1995<br />

OlJUNl995<br />

Page 75 of 176<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO O.OOE+OO<br />

l.OOE+OO <strong>4.</strong>00E-01<br />

2.00E+00 6.00E-01<br />

-2.00E+00 l.lOE+OO<br />

1.00E+00 9.00E-01<br />

-l.OOE+OO 3.00E-01<br />

l.OOE+OO l.OOE+OO<br />

6.00E+00 3.10E+00<br />

5.00E+00 2.80E+00<br />

0.00E+00 6.00E-01<br />

1.00E+00 7.00E-01<br />

5.00E+00 2.50E+00<br />

-3.00E+00 1.40E+00<br />

1.00E+00 8.00E-01<br />

l.OOE+OO 8.00E-01<br />

-2.00E+00 9.00E-01<br />

l.OOE+OO 7.00E-01<br />

1.00E+00 7.00E-01<br />

-2.00E+00 9.00E-01<br />

O.OOE+OO 8.00E-01<br />

2.00E+00 9.00E-01<br />

2.00E+00 9.00E-01<br />

O.OOE+OO 1.00E-01<br />

O.OOE+OO 2.00E-01<br />

2.00E+00 7.00E-01<br />

l.OOE+OO 5.00E-01<br />

2.00E+00 l.lOE+OO<br />

-2.00E+00 8.00E-01<br />

1.00E+00 8.00E-01<br />

l.OOE+OO l.OOE+OO<br />

l.OOE+OO 5.00E-01<br />

1.00E+00 7.00E-01<br />

1.00€+00 7.00E-01<br />

1.00E+00 5.00E-01<br />

0.00E+00 <strong>4.</strong>00E-01<br />

-3.00E+00<br />

l.OOE+OO 1.40E+00<br />

l.OOE+OO 8.00E-01<br />

-l.WE+OO 6.00E-01<br />

0.00E+00 -2.00E-01<br />

0.00E+00 -2.00E-01<br />

O.OOE+OO -1.00E-01<br />

0.00E+00 2.00E-01<br />

3.OOE+00 l.OOE+OO<br />

O.OOE+OO 6.00E-01<br />

0.00E+00 6.00E-01<br />

-2.00E+00 -1.70E+00<br />

5.00E+00 2.00E+00<br />

V<br />

X<br />

V<br />

V<br />

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uglL<br />

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uglL<br />

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uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

pCilL<br />

pCilL<br />

pcin<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCi<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCi<br />

pCiL<br />

pciR<br />

pcin<br />

pCi<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCilL<br />

pCiL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCilL<br />

pCilL<br />

pci5<br />

pCi<br />

pCilL<br />

pCiL<br />

pCiL<br />

pcin<br />

pCiL<br />

pCiR<br />

pCi<br />

pCi<br />

pCiL<br />

pCilL<br />

pciR<br />

pCiL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Gross Beta 12587-47-2 1075-93 16JUL1993 WS 6.00E+00 1.00E+00 N pCtL<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

Hardness as CaCO3<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

im7-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

I 2587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

I 2587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

I 2587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

1258747-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

CAC03HARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACOJHARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

CACO3HARDNES<br />

CACO3HARDNES<br />

CACO3HARDNES<br />

CACO3HARDNES<br />

CACO3HARDNES<br />

CAC03HARDNES<br />

1148-95<br />

1149-95<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1838-93<br />

1921-94<br />

1922-94<br />

20-94<br />

21-95<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

241594<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

43895<br />

439-95<br />

508-94<br />

634-95<br />

635-95<br />

788-95<br />

789-95<br />

803-93<br />

902-94<br />

903-94<br />

957-95<br />

95895<br />

1075-93<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1838-93<br />

1921-94<br />

1922-94<br />

20-94<br />

21-95<br />

2124-94<br />

2125-94<br />

215593<br />

2161 -93<br />

22-95<br />

221-95<br />

06JUL1995<br />

06JUL1995<br />

OSAUGI 993<br />

05MAY1994<br />

05AUGl993<br />

O5MAY 1994<br />

O2SEPl 993<br />

02SEP1993<br />

03JUN1994<br />

O3JUNl 994<br />

050CT1993<br />

050CT1993<br />

01 JULl994<br />

OlJUL1994<br />

04NOV1993<br />

05AUG1994<br />

05AUG1994<br />

05JAN1994<br />

05JAN1995<br />

02SEPl994<br />

02SEP1994<br />

10DEC1993<br />

10DEC1993<br />

05JANl995<br />

03FEB1995<br />

03FEB1995<br />

WAN1994<br />

070CT1994<br />

070CT1994<br />

MNOVl994<br />

02DECl994<br />

02DECl994<br />

04FEBl994<br />

04FEBl994<br />

3OJAN1992<br />

03MAR1995<br />

03MARl995<br />

03MAR1994<br />

05APRl995<br />

05APRl995<br />

OJMAY I 995<br />

03MAY 1995<br />

02JUNl993<br />

08APR1994<br />

08APR1994<br />

01JUN1995<br />

01 JUN1995<br />

16JUL1993<br />

05AUGl993<br />

05MAY1994<br />

MAUGl993<br />

05MAY1994<br />

02SEP1993<br />

02SEPl993<br />

03JUN1994<br />

03JUNl994<br />

050CT1993<br />

05OCTl993<br />

01 JULl994<br />

OlJULl994<br />

04NOVI993<br />

05AUG1994<br />

MAUGl994<br />

WAN1 994<br />

WAN1995<br />

02SEPl994<br />

02SEP1994<br />

lODEC1993<br />

lODECl993<br />

WAN1995<br />

03FEB1995<br />

Page 76 of 176<br />

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X<br />

X<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCVL<br />

pCVL<br />

pCVL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pci5<br />

pCVL<br />

pCVL<br />

pciR<br />

pciR<br />

pCtL<br />

pCiR<br />

pCilL<br />

pci5<br />

pCVL<br />

pCi<br />

pCVL<br />

pCiL<br />

pCVL<br />

pCVL<br />

pci5<br />

pCiL<br />

pCiL<br />

pCiL<br />

pcin<br />

pCilL<br />

pCiL<br />

pCi<br />

pCi<br />

pCiL<br />

pCiL<br />

pCVL<br />

pCVL<br />

pCiL<br />

pCi<br />

pCilL<br />

pCiL<br />

pcin<br />

pCiL<br />

pCiL<br />

pci5<br />

pCiL<br />

pci5<br />

mglL CaC03<br />

mgR CaC03<br />

mgR CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

mgR CaC03<br />

mglL CaCO3<br />

mglL CaC03<br />

mgR CaC03<br />

mglL CaCO3<br />

mglL CaC03<br />

mgR CaC03<br />

mglL CaC03<br />

mgR CaC03<br />

mgR CaC03<br />

mglL CaC03<br />

mgR CaC03<br />

mgR CaC03<br />

mglL CaCO3


L.9 (continued)<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Hardness as CaCO3 CACOJHARDNES 222-95 03FEB1995 WS 6.40E+01 mglL CaCO3<br />

Hardness as CaC03<br />

CACOJHARDNES 23-94 05JAN1994 ws 8.00E+01<br />

mi/L C ~ C O ~<br />

Hardness as CaCO3<br />

CAC03HARDNES 2414-94 07OCT1994 ws 7.20E+01<br />

mglL CaC03<br />

Hardness as CaCO3<br />

CACOJHARDNES 2415-94 070CT1994 ws 7.00E+01<br />

mg/L CaC03<br />

Hardness as CaC03<br />

CACOJHARDNES 2693-94 04NOV1994 ws 7.20E+01<br />

mglL CaC03<br />

Hardness as CaC03<br />

CACOSHARDNES 2862-94 O2DECl 994 ws 7.20E+01<br />

mglL CaC03<br />

Hardness as CaCO3<br />

CACOJHARDNES 2863-94 02DEC1994 ws 7.40E+01<br />

mglL CaCO3<br />

Hardness as CaC03<br />

CACOJHARDNES 289-94 04FEB1994 ws 6.60E+01<br />

mglL CaCO3<br />

Hardness as CaC03<br />

CAC03HARDNES 290-94 04FEBl994 ws 7.40E+01<br />

mglL CaC03<br />

Hardness as CaCO3<br />

CAC03HARDNES 438-95 03MAR1995 ws 6.20E+01<br />

mg/L CaC03<br />

Hardness as CaC03<br />

CAC03HARDNES 439-95 03MAR1995 ws 6.40E+01<br />

mg/L CaC03<br />

Hardness as CaC03<br />

CACOJHARDNES 508-94 O3MARl 994 ws 7.00E+01<br />

mglL CaC03<br />

Hardness as CaCO3 CACOJHARDNES 509-94 03MARl994 ws 7.00Et01<br />

mglL CaC03<br />

Hardness as CaCO3 CACO3HARDNES 634-95 05APRl995 ws 6.40E+01<br />

mglL CaC03<br />

Hardness as CaC03<br />

CACOJHARDNES 635-95 OMPR 1995 ws 6.40E+01<br />

mglL CaC03<br />

Hardness as CaC03<br />

CAC03HARDNES 788-95 03MAY1995 ws <strong>4.</strong>00E+01<br />

X mglL CaCO3<br />

Hardness as CaCO3 CAC03HARDNES 789-95 03MAY 1995 ws 5.20E+01<br />

mg/L CaC03<br />

Hardness as CaC03<br />

CACOJHARDNES 803-93 O2JUNl 993 ws 8.60E+01<br />

N mglL CaC03<br />

Hardness as CaCO3<br />

CAC03HARDNES 902-94 08APRl994 ws 6.00E+01<br />

mg1L CaC03<br />

Hardness as CaC03<br />

CACOJHARDNES 903-94 OBAPR1994 ws 6.60E+01<br />

mglL CaC03<br />

Hardness as CaC03<br />

CACOMARDNES 957-95 01JUN1995 ws 6.00E+01<br />

mglL CaC03<br />

Hardness as CaC03<br />

CACOJHARDNES 958-95 01JUN1995 ws 6.20E+01<br />

mglL CaC03<br />

Hexavalent Chromium 18540-29-9<br />

21-95 05JAN1995 ws O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

22-95 05JANI 995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

221-95 03FEB1995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

222-95 O3FEBl995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

438-95 OM1995 ws O.OOE+OO<br />

C<br />

N mgk<br />

Hexavalent Chromium 18540-29-9<br />

439-95 03MAR1995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

634-95 05APR1995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

635-95 05APRl995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

788-95 03MAY 1995 ws O.OOE+W<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

789-95 03MAY1995 ws O.WE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

957-95 01 JUN1995 ws O.OOE+OO<br />

<<br />

N<br />

mglL<br />

Hexavalent Chromium 18540-29-9<br />

958-95 01 JUNI 995 ws O.OOE+OO<br />

4<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1024-92 WAY1992 ws l.OOE+OO<br />

NT mglL<br />

Iron<br />

7439-89-6<br />

1075-93 16JULl993 ws l.WE+OO<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1144-92 01JUNl992 ws O.OOE+OO<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1205-93 05AUG1993 ws O.OOE+OO<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1205-94 WAY1994 ws 1.00E+00<br />

mglL<br />

Iron<br />

7439-89-6<br />

1206-93 05AUGl993 ws 1 .WE+W<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1206-94 05MAY I 994 ws l.OOE+OO<br />

mglL<br />

Iron<br />

7439-89-6<br />

1333-92 06JULl992 ws I .00E+00<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1349-93 02SEPl993 ws l.OOE+OO<br />

N<br />

mgk<br />

Iron<br />

7439-89-6<br />

1374-93 02SEP1993 ws 2.WE+W<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1379-94 03JUN1994 ws O.WE+OO<br />

mglL<br />

Iron<br />

7439-89-6<br />

1380-94 03JUN1994 ws O.WE+W<br />

mglL<br />

Iron<br />

7439-89-6<br />

1478-92 03AUGl992 ws l.OOE+OO<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1549-93 050CTI993 ws l.OOE+OO<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1550-93 050CT1993 ws I .00E+W<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1615-94<br />

OlJUL1994 ws 1.00E+W<br />

mglL<br />

Iron<br />

7439-89-6<br />

1616-94 01 JUL1994 ws O.OOE+W<br />

mglL<br />

Iron<br />

7439 -89- 6<br />

1625-92 31 AUG 1992 ws 1 .WE+OO<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

1797-92 070CT1992 ws l.OOE+OO<br />

N<br />

mgk<br />

Iron<br />

7439-89-6<br />

1838-93 MNOVl993 ws l.WE+OO<br />

mglL<br />

Iron<br />

7439-89-6<br />

1921-94 05AUGl994 ws l.OOE+OO<br />

mglL<br />

Iron<br />

7439-89-6<br />

1922-94 05AUG1994 ws 2.00E+W<br />

mglL<br />

Iron<br />

7439-89-6<br />

1938-92 O3NOVl 992 ws 1 .OOE+W<br />

N<br />

mglL<br />

Iron<br />

7439-89-6<br />

20-94 05JAN1994 ws l.OOE+OO<br />

rnglL<br />

Iron<br />

7439-89-6<br />

21-95 05JAN1995 ws 1.00E+W<br />

mglL<br />

Iron<br />

7439-89-6<br />

2102-92 01 DECl992 ws 1.00E+00<br />

N<br />

mgk<br />

Iron<br />

7439-89-6<br />

2124-94 02SEPl994 ws O.OOE+OO<br />

mglL<br />

Iron<br />

7439-89-6<br />

2125-94 02SEP1994 ws O.WE+OO<br />

mglL<br />

Iron<br />

7439-89-6<br />

2155-93 IODEC1993 ws I .WE+00<br />

mglL<br />

Iron<br />

7439-89-6<br />

2161-93 I ODEC1993 ws I.WE+W<br />

mglL<br />

Iron<br />

7439-89-6<br />

22-95 05JAN1995 ws I .WE+W<br />

mgk<br />

Iron<br />

7439-89-6<br />

221-95 03FEB1995 ws 1 .WE+00<br />

mglL<br />

Iron<br />

7439-89-6<br />

222-95 03FEB1995 ws 1 .WE+00<br />

rngk<br />

Iron<br />

7439-89-6<br />

23-94 05JAN1994 ws I.WE+W<br />

mgk<br />

Iron<br />

7439-89-6<br />

2414-94<br />

070CT1994 ws O.WE+OO<br />

mgk<br />

Iron<br />

7439-89-6<br />

2415-94 070CT1994 ws O.WE+W<br />

mglL<br />

Iron<br />

7439-89-6<br />

2693-94 04NOVl994 ws l.WE+W<br />

mgfl<br />

Iron<br />

7439-89-6<br />

2862-94 02DEC1994 ws I.WE+OO<br />

mglL<br />

Page 77 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE NPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Iron 7439-89-6 2863-94 02DEC1994 WS 1.00E+00 mplL<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-89-6<br />

7 4 3 9 - 8 9 - 6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

289-94<br />

290-94<br />

395-92<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701 -92<br />

788-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

1024-92<br />

1075-93<br />

1 144-92<br />

120593<br />

1205-94<br />

1206-93<br />

1333-92<br />

1374-93<br />

1379-94<br />

43895<br />

1206-94<br />

1349-93<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1838-93<br />

1921-94<br />

1938-92<br />

20-94<br />

21-95<br />

2 102-92<br />

2124-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395.92<br />

438-95<br />

439-95<br />

50894<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

1922-94<br />

2125-94<br />

78895<br />

789-95<br />

04FEB1994<br />

04FEB1994<br />

30JANI 992<br />

O3MAR 1995<br />

03MAR1995<br />

03MAR1994<br />

O5MAY 1993<br />

05MAR1992<br />

05APR1995<br />

05APR1995<br />

05MAY 1993<br />

12MARl992<br />

03MAY 1995<br />

03MAY1995<br />

02JUN1993<br />

01 APRI 992<br />

08APR1994<br />

08APR1994<br />

04MAY 1992<br />

16JUL1993<br />

01 JUNl992<br />

05AUG1993<br />

OSMAY 1994<br />

05AUGl993<br />

05MAYl994<br />

06JULl992<br />

O2SEPl 993<br />

02SEP1993<br />

03JUN1994<br />

03JUN 1994<br />

03AUG1992<br />

050CT1993<br />

050CT1993<br />

OlJUL1994<br />

OlJULl994<br />

3lAUGl992<br />

070CT1992<br />

04NOV1993<br />

05AUG1994<br />

OSAUGl994<br />

03NOVl992<br />

WAN1994<br />

WAN1995<br />

01 DECl992<br />

02SEP1994<br />

O2SEPl 994<br />

IODECl993<br />

1 ODECl993<br />

WAN1995<br />

03FEBl995<br />

03FEBl995<br />

WAN1994<br />

070CT1994<br />

070CT1994<br />

04NOVI994<br />

02DEC1994<br />

O2DEC1994<br />

04FEB1994<br />

ME81994<br />

3OJANl992<br />

ow1995<br />

ow1995<br />

03MARl994<br />

OSMAY I<br />

993<br />

05MAR1992<br />

05APRl995<br />

05APR1995<br />

(HMAY 1 993<br />

12MAR1992<br />

OWY<br />

1995<br />

03MAY 1995<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

4<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

e<br />

<<br />

U<br />

<<br />

<<br />

<<br />

<<br />

c<br />

U<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

U<br />

U<br />

c<br />

<<br />

<<br />

U<br />

U<br />

<<br />

<<br />

<<br />

U<br />

U<br />

<<br />

<<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mg/L<br />

mglL<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

mg5<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mg1L<br />

mgn<br />

mglL<br />

mglL<br />

mgfl<br />

mg5<br />

wn<br />

w5<br />

mgfl<br />

w5<br />

mgfl<br />

mgfl<br />

mgk<br />

Page 78 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

7439-92-1 803-93 02JUN1993 WS O.OOE+OO mglL<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithiurn<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-954<br />

7439.954<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-92-1<br />

856-92<br />

902-94<br />

903-94<br />

957-95<br />

958-95<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1797-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1549-93<br />

1550-93<br />

161 5-94<br />

1616-94<br />

1206-93<br />

1478-92<br />

1625-92<br />

1797-92<br />

1838-93<br />

1938-92<br />

1921-94<br />

1922-94<br />

20-94<br />

21-95<br />

2 102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

50894<br />

623-93<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

788-95<br />

789-95<br />

2693-94<br />

632-92<br />

01 APRl992<br />

08APR1994<br />

08APR1994<br />

01JUN1995<br />

01JUN1995<br />

04MAYl992<br />

01 JUN1992<br />

06JULl992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3OJAN1992<br />

O5MAY 1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

16JUL1993<br />

OlJUNl992<br />

05AUG1993<br />

05MAY 1994<br />

05AUG1993<br />

OSMAYl994<br />

06JULl992<br />

02SEP1993<br />

OZSEPl993<br />

03JUNl994<br />

03JUN1994<br />

03AUGl992<br />

050CT1993<br />

050CTl993<br />

01 JULl994<br />

OlJUL1994<br />

3lAUGl992<br />

070CT1992<br />

04NOV1993<br />

05AUG1994<br />

05AUGl994<br />

03NOV1992<br />

05JAN1994<br />

05JAN1995<br />

01DECl992<br />

02SEP1994<br />

O2SEPl994<br />

lODECl993<br />

lODECl993<br />

05JAN1995<br />

03FEBl995<br />

03FEB1995<br />

05JAN1994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

02DEC1994<br />

04FEB1994<br />

04FEBl994<br />

30JAN1992<br />

03MARl995<br />

OW1995<br />

03MAR1994<br />

05MAY1993<br />

05MAR1992<br />

05APRl995<br />

05APRl995<br />

MAY<br />

1993<br />

12MARl992<br />

03MAYl995<br />

03MAY1995<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

c<br />

N<br />

< N<br />

< N<br />

< N<br />

U<br />

N<br />

U<br />

N<br />

c<br />

NT<br />

c<br />

N<br />

< N<br />

c<br />

N<br />

c<br />

N<br />

< N<br />

c<br />

N<br />

c<br />

N<br />

< N<br />

c<br />

N<br />

< N<br />

< N<br />

c<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

wfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mg5<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

Page 79 of 176


L.9 (continued)<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Magnesium 7439-95-4 803-93 02JUN1993 WS 5.00€+00 N mg1L<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

856-92<br />

902-94<br />

903-94<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1797-92<br />

1838-93<br />

1922-94<br />

1938-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

21 61 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

788-95<br />

789-95<br />

803-93<br />

1625-92<br />

1921<br />

-94<br />

2862-94<br />

856-92<br />

902-94<br />

903-94<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1549-93<br />

1550-93<br />

1625-92<br />

1797-92<br />

1938-92<br />

395-92<br />

2102-92<br />

01 APRI 992<br />

08APRl994<br />

08APRl994<br />

04MAY1992<br />

16JULl993<br />

01JUN1992<br />

OSAUG1993<br />

OSMAY 1994<br />

05AUG1993<br />

05MAY 1994<br />

06JUL1992<br />

02SEPI 993<br />

02SEPl993<br />

03JUN1994<br />

O3JUNl 994<br />

03AUG1992<br />

050CT1993<br />

050CT1993<br />

01 JUL1994<br />

OlJULl994<br />

3 1 AUG 1992<br />

070CT1992<br />

04NOV1993<br />

O5AUGl 994<br />

OSAUG1994<br />

03NOV1992<br />

WAN1994<br />

WAN1995<br />

01 DECl992<br />

02SEPl994<br />

02SEP1994<br />

1 ODECI 993<br />

IODECI 993<br />

WAN1995<br />

03FEB1995<br />

03FE61995<br />

05JAN1994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

02DEC1994<br />

04FEBI994<br />

MFEB1994<br />

30JANl992<br />

03MAR1995<br />

03MAR1995<br />

03MAR1994<br />

05MAY1993<br />

05MAR1992<br />

05APRl995<br />

05APRI995<br />

05MAY 1993<br />

12MAR1992<br />

03MAY1995<br />

OMAY 1995<br />

02JUNl993<br />

01APRl992<br />

08APR1994<br />

08APR1994<br />

MAY1992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

050CT1993<br />

OSOCTI 993<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

30JAN1992<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

J.OOE+OO<br />

3.00E+00<br />

3.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+W<br />

0.00E+00<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

0.WEtW<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+W<br />

0.WEt00<br />

0.00E+00<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 80 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Mercury 7439-97-6 623-93 05MAY1993 WS O.OOE+OO<br />

NT mgIL<br />

Mercury<br />

7439-97-6<br />

632-92 O5MAR1992 ws<br />

N<br />

mg1L<br />

Mercury<br />

7439-97-6<br />

701-92 12MAR1992 ws<br />

N<br />

mglL<br />

Mercury<br />

7439-97-6<br />

856-92 01 APRl992 ws<br />

N<br />

mglL<br />

Methylene Chloride<br />

75-09-2<br />

1374-93 02SEP1993 ws<br />

N<br />

uglL<br />

Molybdenum<br />

7439-90-7<br />

1024-92 04MAY 1992 ws<br />

NT mglL<br />

Molybdenum<br />

7439-90-7<br />

1144-92<br />

01JUN1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

1333-92 MJULl992 ws<br />

N<br />

mg1L<br />

Molybdenum<br />

7439-90-7<br />

1470-92 O3AUGl 992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

1625-92 31AUG1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

1797-92 070CT1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

1930-92 03NOV1992 ws<br />

N<br />

mg1L<br />

Molybdenum<br />

7439-90-7<br />

2102-92 01DEC1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

395-92 3OJAN1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

623-93 OSMAY1993 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

632-92 05MAR1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

701-92 12MAR1992 ws<br />

N<br />

mglL<br />

Molybdenum<br />

7439-90-7<br />

856-92 01 APRl992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1024-92 04MAY 1992 ws<br />

NT mglL<br />

Nickel<br />

7440-02-0<br />

1075-93 16JUL1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1144-92 01 JUN 1992 ws<br />

N mgk<br />

Nickel<br />

7440-02-0<br />

1205-93 05AUG1993 ws<br />

N<br />

mgR<br />

Nickel<br />

7440-02-0<br />

1205-94 (HMAY 1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1206-93 OSAUG 1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1206-94 05MAY 1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1333-92 06JUL1992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1349-93 O2SEP1 993 ws<br />

N<br />

WlL<br />

Nickel<br />

7440-02-0<br />

1374-93 OZSEPI 993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1379-94 03JUN 1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1300-94 03JUN1994 ws<br />

N<br />

WlL<br />

Nickel<br />

7440-02-0<br />

1470-92 03AUGl992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1549-93 050CT1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1550-93 050CT1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1615-94 OlJUL1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1616-94<br />

01 JULl994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1625-92 31 AUGl992 ws<br />

N<br />

mg1L<br />

Nickel<br />

7440-02-0<br />

1797-92 070CT1992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1830-93 04NOV1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1921-94 05AUGl994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

1922-94 OSAUG 1994 ws<br />

N<br />

mg/L<br />

Nickel<br />

7440-02-0<br />

1938-92 03NOV1992 ws<br />

N<br />

mgk<br />

Nickel<br />

7440-02-0<br />

20-94 05JAN1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

21-95 OSJAN1995 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2102-92 01 DECl992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2124-94 02SEP1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2125-94 02SEPl994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2155-93 10DEC1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2161-93 10DEC1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

22-95 05JAN1995 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

221-95 03FEB1995 ws<br />

N<br />

mgk<br />

Nickel<br />

7440-02-0<br />

222-95 03FEB1995 ws<br />

N<br />

WlL<br />

Nickel<br />

7440-02-0<br />

23-94 05JAN1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2414-94 070CT1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2415-94 070CT1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2693-94 04NOV1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2862-94 02DEC1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

2863-94 OZDEC1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

209-94 04FEB1994 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

290-94 04FEB1994 ws<br />

N<br />

mgk<br />

Nickel<br />

7440-02-0<br />

39592 3OJANl 992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

438-95 O3MARl995 ws<br />

N<br />

WlL<br />

Nickel<br />

7440-02-0<br />

439-95 03MARI 995 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

508-94 03MAR 1994 ws<br />

N<br />

mg/L<br />

Nickel<br />

7440-02-0<br />

623-93 (HMAY 1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

632-92 OSMARI 992 ws<br />

N<br />

mgfl<br />

Nickel<br />

7440-02-0<br />

634-95 OSAPRl995 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

635-95 OSAPR1995 ws<br />

N<br />

WlL<br />

Nickel<br />

7440-02-0<br />

637-93 05MAY 1993 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

701-92 1 ZMAR I992 ws<br />

N<br />

mglL<br />

Nickel<br />

7440-02-0<br />

788-95 03MAY 1995 ws<br />

N<br />

WlL<br />

Nickel<br />

7440-02-0<br />

789-95 03MAY1995 ws<br />

N<br />

mg1L<br />

Nickel<br />

7440-02-0<br />

803-93 02JUN1993 ws<br />

N<br />

mglL<br />

Page 81 of 176


~~<br />

L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Nickel 7440-02-0 856-92 01APR1992 WS O.OOE+OO C N mglL<br />

Nickel<br />

Nickel<br />

7440-02-0<br />

7440-02-0<br />

902-94<br />

903-94<br />

08APR1994<br />

08APR1994<br />

C<br />

C<br />

N<br />

N<br />

Niobium<br />

7440-03-1<br />

1024-92 04MAY 1992<br />

C<br />

NT<br />

Niobium<br />

7440-03-1<br />

1144-92<br />

OlJUN1992<br />

C<br />

N<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Nitrate as Nitrogen<br />

Oil <strong>and</strong> Grease<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

NITRATEASNIT<br />

SO227<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

395-92<br />

395-92<br />

06JUL1992<br />

03AUGl992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

30JAN1992<br />

%MAY 1993<br />

O5MAR1992<br />

12MARl992<br />

01 APRI 992<br />

3OJANl992<br />

30JAN1992<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

pca<br />

1336-36-3<br />

1864-92 190CT1992<br />

C<br />

N<br />

pca<br />

1336-36-3<br />

1938-92 03NOV1992<br />

C<br />

N<br />

PCB<br />

1336-36-3<br />

20-94 05JAN1994<br />

C<br />

N<br />

PCB<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

1336-36-3<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723- 14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

23-94<br />

395-92<br />

1024-92<br />

I 144-92<br />

1333-92<br />

147892<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

161694<br />

1625-92<br />

1797-92<br />

183893<br />

1921-94<br />

1922-94<br />

193892<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

O5JAN 1994<br />

30JANl992<br />

04MAY 1992<br />

01 JUNl992<br />

06JULl992<br />

03AUGl992<br />

3lAUGI 992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

30JANl992<br />

WY1993<br />

osMARl992<br />

12MAR1992<br />

OlAPR1992<br />

04MAY1992<br />

16JUL1993<br />

01JUN1992<br />

05AUGl993<br />

05MAY 1994<br />

05AUG1993<br />

05MAY 1994<br />

06JUL1992<br />

02SEPl993<br />

02SEPl993<br />

03JUNl994<br />

03JUNl994<br />

03AUG 1992<br />

OSET1993<br />

050CTI993<br />

01JULl994<br />

01 JULl994<br />

31AUGl992<br />

070CT1992<br />

04NOV1993<br />

05AUGl994<br />

05AUG 1994<br />

03NOV1992<br />

05JAN1994<br />

05JAN1995<br />

OlDECl992<br />

02SEP1994<br />

02SEPl994<br />

1 ODECl993<br />

10DECl993<br />

osJANl995<br />

03FEB1995<br />

03FEBl995<br />

05JAN1994<br />

070CT1994<br />

070CT1994<br />

C<br />

C<br />

<<br />

C<br />

C<br />

C<br />

4<br />

C<br />

C<br />

e<br />

<<br />

J<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 82 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Potassium 7440-09-7 2693-94 04NOV1994 WS <strong>4.</strong>00E+00 N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2062-94 02DEC1994 ws <strong>4.</strong>00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

2063-94 02DEC1994 ws <strong>4.</strong>00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

209-94 04FEB1994 ws J.OOE+OO<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

290-94 04FEB1994 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

395-92 30JAN1992 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

430-95 03MAR1995 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

439-95 03MAR1995 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

500-94 O3MARl 994 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

623-93 05MAY 1993 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

632-92 O5MAR 1992 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

634-95 05APR 1995 ws 5.00E+00<br />

<<br />

N<br />

mgfl<br />

Potassium<br />

7440-09-7<br />

635-95 O5APR 1995 ws 5.00E+00<br />

<<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

637-93 05MAY1993 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

701-92 12MAR1992 ws 2.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

700-95 03MAY 1995 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

709-95 03MAY 1995 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

803-93 02 JUNl993 ws 3.00E+00<br />

N<br />

mg1L<br />

Potassium<br />

7440-09-7<br />

856-92 01 APRl992 ws 3.00E+00<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

902-94 00APR1994 ws 2.00E+00<br />

<<br />

N<br />

mglL<br />

Potassium<br />

7440-09-7<br />

903-94 OBAPR1994 ws 2.00E+00<br />

N<br />

mglL<br />

Rad Alpha<br />

12507-46-1<br />

1140-95 06JUL1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Alpha<br />

12507-46-1<br />

1149-95<br />

06JUL1995 ws 1.00E+00<br />

N pCilml<br />

Rad Alpha<br />

12587-46-1<br />

221-95<br />

03FEBl995 ws l.OOE+OO<br />

N pCilml<br />

Rad Alpha<br />

12507-46-1<br />

222-95 O3FEB1 995 ws l.OOE+OO<br />

N pCi/ml<br />

Rad Alpha<br />

12507-46-1<br />

438-95 03MARl995 ws l.OOE+OO<br />

N pCilml<br />

Rad Alpha<br />

12507-46-1<br />

439-95 03MAR1995 ws l.OOE+OO<br />

N pCiml<br />

Rad Alpha<br />

12507-46-1<br />

634-95 05APRl995 ws l.OOE+OO<br />

N pCilml<br />

Rad Alpha<br />

12587-46-1<br />

635-95 05APRl995 ws l.OOE+OO<br />

N pCilml<br />

Rad Alpha<br />

12587-46-1<br />

700-95 03MAY 1995 ws 1 .OOE+OO<br />

N pCiml<br />

Rad Alpha<br />

12507-46-1<br />

709-95 O3MAY 1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Alpha<br />

12507-46-1<br />

003-93 02JUN1993 ws l.OOE+OO<br />

N pCilmL<br />

Rad Alpha<br />

12507-46-1<br />

957-95 01JUN1995 ws 1.00E+00<br />

N pCilml<br />

Rad Alpha<br />

12507-46-1<br />

950-95 01JUN1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

1148-95<br />

06JULl995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

1149-95 06JUL1995 ws l.OOE+OO<br />

N pCiml<br />

Rad Beta<br />

12507-47-2<br />

221-95 03FEB1995 ws I .00E+00<br />

N pCVml<br />

Rad Beta<br />

12507-47-2<br />

222-95 03FEB1995 ws l.OOE+W<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

430-95 03MAR1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

439-95 03MAR1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

634-95 05APRl995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

635-95 05APR1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

700-95 03MAY 1995 ws 1.00E+00<br />

N pCiml<br />

Rad Beta<br />

12507-47-2<br />

709-95 03MAY1995 ws l.OOE+OO<br />

N pCilml<br />

Rad Beta<br />

12587-47-2<br />

003-93 02JUN1993 ws l.OOE+OO<br />

N pCilmL<br />

Rad Beta<br />

12507-47-2<br />

957-95 OlJUNl995 ws l.WE+W<br />

N pCilml<br />

Rad Beta<br />

12507-47-2<br />

950-95 01JUN1995 ws l.OOE+W<br />

N pCilml<br />

Ruthenium<br />

7440-10-0<br />

1024-92 WMAY 1992 ws O.OOE+OO<br />

NT mglL<br />

Ruthenium<br />

7440-10-0<br />

1144-92<br />

01JUN1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

1333-92 06JUL1992 ws 0.00E+00<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

1470-92 03AUG1992 ws O.WE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

1625-92 3lAUG1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-8<br />

1797-92 070CT1992 ws O.OOE+W<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

1938-92 03NOV1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

2102-92 01 DEC1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

395-92 30JAN1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

623-93 05MAY 1993 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

632-92 05MAR1992 ws O.OOE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

701-92 12MAR1992 ws O.WE+OO<br />

N<br />

mglL<br />

Ruthenium<br />

7440-10-0<br />

856-92 01 APRI 992 ws O.WE+OO<br />

N<br />

mglL<br />

Selenium<br />

7702-49-2<br />

395-92 30JANl992 ws O.WE+W<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1024-92 WMAY 1992 ws 2.00E+00<br />

NT mglL<br />

Silicon<br />

7440-21 -3<br />

1075-93 16JUL1993 ws 3.00E+00<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1144-92 01 JUN1992 ws l.OOE+OO<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1205-93 OSAUGl993 ws 2.WE+W<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1205-94 OSMAY 1994 ws 6.00E+00<br />

N<br />

mglL<br />

Silicon<br />

7440-21 -3<br />

1206-93 OBAUGl993 ws 2.00E+00<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1206-94 (HMAY 1994 ws 5.00E+W<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1333-92 06JUL1992 ws 2.00E+00<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1349-93 02SEPl993 ws l.OOE+OO<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1374-93 O2SEP1 993 ws l.OOE+OO<br />

N<br />

mglL<br />

Silicon<br />

7440-21-3<br />

1379-94 03JUNl994 ws 2.WE+00<br />

N<br />

mglL<br />

Page 83 of 176


L.9 (continued)<br />

MEDIA FAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Silicon 7440-21-3 1380-94 03JUN1994 WS l.OOE+OO N mglL<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1838-93<br />

1921-94<br />

1922-94<br />

1938-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

788-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

03AUG1992<br />

050CT1993<br />

050CT1993<br />

OlJUL1994<br />

OlJUL1994<br />

3lAUGl992<br />

070CT1992<br />

04NOV1993<br />

05AUG1994<br />

05AUG1994<br />

03NOV1992<br />

05JAN1994<br />

05JAN1995<br />

01 DEC1992<br />

02SEP1994<br />

OZSEPI 994<br />

10DECl993<br />

lODECl993<br />

05JAN1995<br />

03FEB1995<br />

03FEB1995<br />

05JANl994<br />

070CT1994<br />

O7OCTI 994<br />

04NOV1994<br />

O2DECl 994<br />

02DEC1994<br />

04FEB1994<br />

04FEB1994<br />

30JANl992<br />

03MAR1995<br />

03MAR1995<br />

03MAR1994<br />

05MAYl993<br />

05MAR1992<br />

05APRl995<br />

05APR1995<br />

OSMAY 1993<br />

12MARI 992<br />

03MAYl995<br />

03MAY 1995<br />

02JUNl993<br />

OlAPR1992<br />

08APRl994<br />

08APRl994<br />

04MAY 1992<br />

OlJUNl992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

30JAN1992<br />

(HMAY 1993<br />

(HMARl992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

16JUL1993<br />

01 JUNl992<br />

MAUGl993<br />

M Y 1994<br />

MAUGl993<br />

05MAY 1994<br />

06JUL1992<br />

02SEPl993<br />

02SEP1993<br />

O3JUN1994<br />

OJJlJN1994<br />

03AUGl992<br />

Page 84 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

2.00E+00<br />

3.00E+00<br />

3.00E+00<br />

2.00E+00<br />

2.00E+00<br />

2.00E+00<br />

5.00E+00<br />

2.00E+00<br />

J.OOE+OO<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

5.00E+00<br />

2.00E+00<br />

2.00E+00<br />

6.00E+00<br />

5.00E+00<br />

3.WE+OO<br />

6.00E+00<br />

5.00E+00<br />

<strong>4.</strong>WE+OO<br />

2.00E+00<br />

2.00E+00<br />

2.00E+00<br />

3.OOE+00<br />

3.00E+00<br />

6.00E+00<br />

6.00E+00<br />

2.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

6.00E+00<br />

6.00E+00<br />

2 .OOE+ 00<br />

2.00E+00<br />

2 .OOE+OO<br />

6.00E+00<br />

<strong>4.</strong>00E+00<br />

7.WE+W<br />

7.00E+00<br />

2.00E+W<br />

5.00E+00<br />

6.00E+00<br />

6.WE+00<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

I .80E+01<br />

2.10E+01<br />

2.20E+OI<br />

2.3OE+Ol<br />

l.WE+OI<br />

2.30E+01<br />

l.OOE+OI<br />

I .80E+01<br />

2.10E+01<br />

2.2OE+O1<br />

2.20E+01<br />

2.2OE+Ol<br />

1.70E+01<br />

C<br />

J<br />

J<br />

J<br />

B<br />

B<br />

J<br />

J<br />

<<br />

C<br />

<<br />

<<br />

c<br />

<<br />

C<br />

<<br />

c<br />

c<br />

c<br />

<<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

' N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg5<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgk<br />

mg/L<br />

mglL<br />

mgfl<br />

wfl<br />

mgfl<br />

wfl<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Sodium<br />

7440-23-5 1549-93 050CT1993 WS 1,80E+01 N mglL<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Speck conductance<br />

Specfic conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO1 45<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1838-93<br />

I921 -94<br />

1922-94<br />

1938-92<br />

20-94<br />

21 -95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

78895<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

1075-93<br />

I 148-95<br />

1149-95<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1838-93<br />

1921-94<br />

1922-94<br />

20-94<br />

21-95<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

050CT1993<br />

01 JUL1994<br />

01 JULl994<br />

31AUG1992<br />

070CT1992<br />

04NOV1993<br />

05AUG1994<br />

O5AUGl 994<br />

03NOV1992<br />

05JAN1994<br />

05JAN 1995<br />

OlDECl992<br />

02SEP1994<br />

02SEP1994<br />

10DECl993<br />

10DEC1993<br />

OSJANI 995<br />

03FEB1995<br />

03FEBI 995<br />

05JANl994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

O2DECl 994<br />

04FEB1994<br />

04FEB1994<br />

3OJANl992<br />

03MARI 995<br />

03MAR1995<br />

03MAR1994<br />

OSMAYI 993<br />

05MAR1992<br />

05APRl995<br />

OBAPRI 995<br />

WAY1993<br />

12MARl 992<br />

03MAY1995<br />

03MAY 1995<br />

02JUN1993<br />

01 APR 1992<br />

08APR1994<br />

OBAPRl994<br />

16JULl993<br />

06JUL1995<br />

WUL1995<br />

05AUG1993<br />

WAY1994<br />

OSAUG 1993<br />

OSMAY 1994<br />

02SEP1993<br />

O2SEPl 993<br />

03JUN1994<br />

03JUN1994<br />

OSOCTI 993<br />

050CT1993<br />

01 JUL1994<br />

01 JUL1994<br />

04NOV1993<br />

SAUG 1994<br />

05AUGl994<br />

OMAN1994<br />

05JAN1995<br />

O2SEPl 994<br />

02SEP1994<br />

10DEC1993<br />

10DEC1993<br />

osJAN1995<br />

03FEB1995<br />

03FEB1995<br />

OMAN1994<br />

1.70E+01<br />

1.90E+01<br />

2.1OE+O1<br />

1.40E+01<br />

1.40E+01<br />

2.10E+01<br />

9.00E+00<br />

l.OOE+Ol<br />

1.70E+01<br />

3.3OE+01<br />

2.20€+01<br />

1.40E+01<br />

1.90E+01<br />

1.90E+01<br />

1 .I OE+01<br />

l.lOE+Ol<br />

2.20E+01<br />

1.30E+01<br />

1.3OE+OI<br />

3.30E+01<br />

2.3OE+01<br />

2.2OE+Ol<br />

2.60€+01<br />

1.50€+01<br />

1.40E+01<br />

1.40E+01<br />

1.40E+01<br />

I .70E+01<br />

1.50E+01<br />

I .50E+01<br />

1.30E+01<br />

6.00€+00<br />

I .50E+OI<br />

2.20E+01<br />

2.20E+01<br />

6.WE+00<br />

l.lOE+OI<br />

7.00E+00<br />

7.00E+00<br />

O.OOE+OO<br />

8.00E+00<br />

9.00E+00<br />

8.00E+00<br />

2.79E+02<br />

1.74E+02<br />

1.74E+02<br />

2.76€+02<br />

2.03E+02<br />

2.76E+02<br />

2.03€+02<br />

2.54E+02<br />

2.21€+02<br />

2.82E+02<br />

2.82E+02<br />

2.68E+02<br />

2.68E+02<br />

2.51€+02<br />

2.50E+02<br />

2.78E+02<br />

1.55E+02<br />

1.54E+02<br />

3.39E+02<br />

2.88€+02<br />

2.38€+02<br />

2.38E+02<br />

1.94E+02<br />

1.94€+02<br />

2.89€+02<br />

2.18€+02<br />

2.18€+02<br />

3.39€+02<br />

J<br />

B<br />

B<br />

J<br />

J<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

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N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

Page 85 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

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ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

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ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Specific conductance SO145 2414-94 070CT1994 WS 2.82E+02 N umhoslcm<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

S t r o n t i u m<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

2415-94<br />

2693 - 94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

438-95<br />

439-95<br />

508-94<br />

509-94<br />

634-95<br />

635-95<br />

788-95<br />

789-95<br />

803-93<br />

902-94<br />

903-94<br />

957-95<br />

958-95<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

1478-92<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

1838-93<br />

1921-94<br />

1922-94<br />

I 938-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161 -93<br />

22-95<br />

221-95<br />

222-95<br />

23-94<br />

2414-94<br />

241194<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

508-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

637-93<br />

701-92<br />

788-95<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

O2DECl 994<br />

04FEB1994<br />

04FEB1994<br />

O3MAR1995<br />

03MARl995<br />

03MAR1994<br />

OJMAR1994<br />

05APR1995<br />

O5APRl995<br />

03MAY 1995<br />

03MAY 1995<br />

02JUN1993<br />

O8APRI994<br />

08APR1994<br />

01JUN1995<br />

01JUN1995<br />

04MAY 1992<br />

16JUL1993<br />

01JUN1992<br />

05AUG1993<br />

05MAY 1994<br />

05AUG1993<br />

05MAY1994<br />

06JUL1992<br />

02SEPl993<br />

02SEP1993<br />

03JUN1994<br />

03JUN1994<br />

03AUG1992<br />

050CT1993<br />

050CTl993<br />

01 JUL1994<br />

OlJUL1994<br />

31AUG1992<br />

070CT1992<br />

04NOV1993<br />

05AUG1994<br />

OSAUGl994<br />

03NOV1992<br />

WAN1 994<br />

WAN1995<br />

OlDECl992<br />

02SEP1994<br />

02SEPl994<br />

lODECl993<br />

10DEC1993<br />

05JAN1995<br />

03FEB1995<br />

03FEB1995<br />

WAN1994<br />

070CT1994<br />

07OCT1994<br />

04NOV1994<br />

02DEC1994<br />

02DECl994<br />

04FEB1994<br />

04FEB1994<br />

3OJAN1992<br />

03MAR1995<br />

03MAR1995<br />

03MARl994<br />

MAY 1993<br />

05MAR1992<br />

05APRl995<br />

05APR1995<br />

OSMAY 1993<br />

12MARl992<br />

03MAY1995<br />

Page 86 of 176<br />

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ws<br />

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ws<br />

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ws<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

2.82E+02<br />

2.92E+02<br />

2.37E+02<br />

2.36E+02<br />

2.22E+02<br />

2.22E+02<br />

2.22E+02<br />

2.22E+02<br />

2.09E+02<br />

2.10E+02<br />

2.63E+02<br />

2.63E+02<br />

I .58E+02<br />

1.57E+02<br />

2.69E+02<br />

1.60E+02<br />

1.60E+02<br />

2.11E+02<br />

2.1 OE+02<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

2.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

l.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

1 .WE+00<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

3.WE+W<br />

3.WE+00<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

1 .WE+00<br />

l.OOE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

4<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

N<br />

N<br />

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N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Strontium 7440-24-6 789-95 03MAY1995 WS O.OOE+OO N<br />

mg1L<br />

Strontium<br />

7440-24-6<br />

803-93 02JUN1993 ws<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

856-92 01APR1992 ws<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

902-94 08APR1994 ws<br />

N<br />

mglL<br />

Strontium<br />

7440-24-6<br />

903-94 08APR1994 ws<br />

N<br />

mglL<br />

Sulfate<br />

12143-45-2<br />

1144-92 01JUN1992 ws<br />

N<br />

mglL<br />

Sulfate<br />

12143-45-2<br />

1333-92 06JUL1992 ws<br />

N<br />

mglL<br />

Sulfate<br />

12 143-45-2<br />

1478-92 03AUG 1992 ws<br />

N<br />

mglL<br />

Sulfate<br />

12143-45-2<br />

1625-92 31AUG1992 ws<br />

N<br />

mglL<br />

Sulfate<br />

12143-45-2<br />

395-92 3OJAN1992 ws<br />

N<br />

mglL<br />

TOX<br />

TOX<br />

395-92 3OJAN1992 ws<br />

N<br />

uglL<br />

Tantalum<br />

7440-25-7<br />

1024-92 04MAY1992 ws<br />

NT mglL<br />

Tantalum<br />

7440-25-7<br />

1144-92 OlJUN1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1333-92 06JUL1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1478-92 03AUG1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1625-92 31AUG1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1797-92 070CT1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

1938-92 03NOV1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

395-92 3OJANl992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

623-93 O5MAY 1993<br />

ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

632-92 DSMARl992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

701-92 12MAR1992 ws<br />

N<br />

mglL<br />

Tantalum<br />

7440-25-7<br />

856-92 01APR1992 ws<br />

N<br />

mglL<br />

Technetium-99<br />

14133-767<br />

395-92 30JAN 1992 ws<br />

N<br />

pCVL<br />

Thallium<br />

7440-28-0<br />

1024-92 04MAY 1992 ws<br />

C<br />

NT mg1L<br />

Thallium<br />

7440-28-0<br />

1144-92 01JUNl992 ws<br />

<<br />

N<br />

w/L<br />

Thallium<br />

7440-28-0<br />

1333-92 06JULl992 ws<br />

<<br />

N<br />

mgfl<br />

Thallium<br />

7440 - 28 - 0<br />

1478-92 03AUG1992 ws<br />

<<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

1625-92 3lAUGl992 ws<br />

c<br />

N<br />

mgk<br />

Thallium<br />

7440-28-0<br />

1797-92 070CT1992 ws<br />

c<br />

N<br />

WlL<br />

Thallium<br />

7440-28-0<br />

1938-92 03NOV1992 ws<br />

<<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

2102-92 01 DEC1992 ws<br />

<<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

395-92 3OJAN 1992 ws<br />

<<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

623-93 OSMAY 1993 ws<br />

<<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

632-92 05MAR1992 ws<br />

<<br />

N<br />

mgfl<br />

Thallium<br />

7440-28-0<br />

701-92 12MAR1992 ws<br />

<<br />

N<br />

mglL<br />

Thallium<br />

7440-28-0<br />

856-92 01 APR 1992 ws<br />

<<br />

N<br />

mgfl<br />

Thorium<br />

7440-29-1<br />

1024-92 04MAY 1992 ws<br />

c<br />

NT mg1L<br />

Thorium<br />

7440-29-1<br />

1144-92 01JUN1992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1333-92 06JUL1992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1478-92 03AUG1992 ws<br />

<<br />

N<br />

mgfl<br />

Thorium<br />

7440-29-1<br />

1625-92 31AUG1992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1797-92 070CT1992 ws<br />

c<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

1938-92 O3NOVl 992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

2102-92 01DEC1992 ws<br />

<<br />

N<br />

mg1L<br />

Thorium<br />

7440-29-1<br />

395-92 3OJANl992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

623-93 MAY 1993 ws<br />

C<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

632-92 05MAR1992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

701-92 12MAR1992 ws<br />

<<br />

N<br />

mglL<br />

Thorium<br />

7440-29-1<br />

856-92 01 APRI 992 ws<br />

C<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1024-92 04MAY 1992 ws<br />

<<br />

NT mglL<br />

Tin<br />

7440-31-5<br />

1144-92 01JUN1992 ws<br />

<<br />

N WlL<br />

Tin<br />

7440-31-5<br />

1333-92 06JUL1992 ws<br />

<<br />

N<br />

mglL<br />

Tin<br />

7440-31 -5<br />

1478-92 03AUG1992 ws<br />

C<br />

N<br />

mglL<br />

Tin<br />

7440-31 -5<br />

1625-92 3lAUG 1992 ws<br />

C<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

1797-92 070CT1992 ws<br />

<<br />

N<br />

mglL<br />

Tin<br />

7440-31 -5<br />

1938-92 03NOV1992 ws<br />

c<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

2102-92 01 DEC1992 ws<br />

<<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

395-92 3OJANl992 ws<br />

<<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

623-93 05MAY 1993 ws<br />

<<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

632-92 OSMAR1992 ws<br />

<<br />

N<br />

mg1L<br />

Tin<br />

7440-31 -5<br />

701-92 12MAR1992 ws<br />

<<br />

N<br />

mglL<br />

Tin<br />

7440-31-5<br />

856-92 OlAPR1992 ws<br />

<<br />

N<br />

mglL<br />

Tiianium<br />

7440-32-6<br />

1024-92 04MAY1992 ws<br />

c<br />

NT mglL<br />

Tiianium<br />

7440-32-6<br />

1144-92<br />

01 JUN1992 ws<br />

<<br />

N<br />

mglL<br />

Tiianium<br />

7440-32-6<br />

1333-92 06JUL1992 ws<br />

<<br />

N<br />

mgn<br />

Tiianium<br />

7440-32-6<br />

1478-92 O3AUG 1992 ws<br />

<<br />

N<br />

mgfl<br />

Titanium<br />

7440-32-6<br />

1625-92 31AUG1992 ws<br />

<<br />

N<br />

mglL<br />

Tianium<br />

7440-32-6<br />

1797-92 070CT1992 ws<br />

<<br />

N<br />

mglL<br />

Tiianium<br />

7440-32-6<br />

193892 03NOV1992 ws<br />

<<br />

N<br />

mglL<br />

litanium<br />

7440-32-6<br />

2102-92 01 DEC1992 ws<br />

e<br />

N<br />

mg/L<br />

Wanium<br />

7440-32-6<br />

395-92 30JAN1992 ws<br />

<<br />

N WlL<br />

Page 87 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Titanium 7440-32-6 623-93 05MAY1993 WS O.OOE+OO<br />

c<br />

N<br />

Tianium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

I 08-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

I 08-88-3<br />

I 08-88-3<br />

108-88-3<br />

108-88-3<br />

I 08-88-3<br />

108-88-3<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

395-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

ma-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

I 478-92<br />

1625-92<br />

1797-92<br />

I 938-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

I 478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1075-93<br />

1144-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1333-92<br />

1349-93<br />

1374-93<br />

1379-94<br />

1380-94<br />

147692<br />

1549-93<br />

1550-93<br />

1615-94<br />

1616-94<br />

1625-92<br />

1797-92<br />

05MAR1992<br />

12MAR1992<br />

01 APR 1992<br />

04MAYI 992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01 DECI 992<br />

30JANl992<br />

05MAR1992<br />

12MAR1992<br />

01 APR1992<br />

30JANI 992<br />

04MAY 1992<br />

01JUN1992<br />

06JULl992<br />

03AUG1992<br />

31AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

30JAN1992<br />

05MAR1992<br />

12MARl992<br />

01 APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

3lAUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

3OJAN1992<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUNl992<br />

06JUL1992<br />

03AUG1992<br />

31 AUG 1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY1993<br />

-1992<br />

12MARl992<br />

01APR1992<br />

04MAY 1992<br />

16JUL1993<br />

OlJUNl992<br />

05AUGl993<br />

my1994<br />

05AUG1993<br />

05MAY 1994<br />

06JUL1992<br />

02SEPl993<br />

02SEPl993<br />

O3JUNI994<br />

03JUNl994<br />

03AUG1992<br />

050CT1993<br />

050CT1993<br />

01 JUL1994<br />

01 JUL1994<br />

3lAUGl992<br />

070CT1992<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

l.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

2.00E+00<br />

5.00E+00<br />

5.00€+00<br />

5.00€+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

5.WE+00<br />

5.WE+00<br />

5.00E+00<br />

5.OOE+W<br />

l.OOE+OO<br />

l.OOE+W<br />

l.OOE+OO<br />

1 .WE+00<br />

l.OOE+OO<br />

1 .WE+OO<br />

I.WE+OO<br />

1 .WE+W<br />

l.WE+W<br />

1 .WE+00<br />

I.OOE+W<br />

I .WE+00<br />

0.00€+00<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+W<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

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<<br />

c<br />

<<br />

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<<br />

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<<br />

<<br />

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c<br />

<<br />

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c<br />

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c<br />

<<br />

4<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 88 of 176<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Uranium 7440-61-1 1838-93 04NOV1993 WS O.OOE+OO N mglL<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

U r a n i u m<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

1921-94<br />

1922-94<br />

1938-92<br />

20-94<br />

21-95<br />

2102-92<br />

2124-94<br />

2125-94<br />

2155-93<br />

2161-93<br />

22-95<br />

221 -95<br />

222-95<br />

23-94<br />

2414-94<br />

2415-94<br />

2693-94<br />

2862-94<br />

2863-94<br />

289-94<br />

290-94<br />

395-92<br />

438-95<br />

439-95<br />

508-94<br />

509-94<br />

623-93<br />

632-92<br />

634-95<br />

635-95<br />

701-92<br />

788-95<br />

789-95<br />

803-93<br />

856-92<br />

902-94<br />

903-94<br />

957-95<br />

9-95<br />

1024-92<br />

I 144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1938-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1938-92<br />

2102-92<br />

395-92<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1144-92<br />

1333-92<br />

1478-92<br />

1625-92<br />

1797-92<br />

1936-92<br />

2102-92<br />

05AUG1994<br />

05AUGl994<br />

03NOV1992<br />

05JAN1994<br />

O5JANl 995<br />

01 DEC1992<br />

02SEP1994<br />

O2SEPl 994<br />

lODECl993<br />

lODEC1993<br />

O5JANl 995<br />

03FEB1995<br />

03FEB1995<br />

O5JANl 994<br />

070CT1994<br />

070CT1994<br />

04NOV1994<br />

02DEC1994<br />

02DEC1994<br />

04FEB1994<br />

04FEBI 994<br />

3OJANl992<br />

03MAR1995<br />

OWAR1995<br />

03MAR1994<br />

03MARl994<br />

WAY 1993<br />

WAR1992<br />

(HAPR 1995<br />

05APR1995<br />

12MAR1992<br />

03MAY 1995<br />

03MAY 1995<br />

02JUN1993<br />

01 APRl992<br />

08APRl994<br />

08APR1994<br />

01JUNl995<br />

01JUN1995<br />

04MAY1992<br />

01JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

03NOV1992<br />

01 DEC1992<br />

3OJAN1992<br />

05MAY1993<br />

05MAR1992<br />

12MAR1992<br />

01 APRl992<br />

04MAY 1992<br />

01JUN1992<br />

06JUL1992<br />

O3AUGl992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

30JANl992<br />

WAR1992<br />

12MAR1992<br />

01APR1992<br />

04MAY1992<br />

01 JUN1992<br />

06JULl992<br />

03AUG1992<br />

31AUGl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

Page 89 of 176<br />

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mg1L<br />

mglL<br />

mglL<br />

mglL<br />

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mg1L<br />

mglL<br />

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mglL<br />

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mgfl<br />

mgfl<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Zinc 7440-66-6 395-92 30JAN1992 WS O.OOE+OO c N mglL<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

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PH<br />

PH<br />

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PH<br />

PH<br />

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PH<br />

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PH<br />

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PH<br />

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PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

7440-67-7<br />

7440-67-7<br />

623-93<br />

632-92<br />

701-92<br />

856-92<br />

1024-92<br />

1 144-92<br />

1333-92<br />

1478-92<br />

1938-92<br />

1625-92<br />

1797-92<br />

2102-92<br />

395-92<br />

623-93<br />

632-92<br />

701-92<br />

1024-92<br />

1075-93<br />

1097-92<br />

11 12-92<br />

1144-92<br />

1196-92<br />

1205-93<br />

1205-94<br />

1206-93<br />

1206-94<br />

1223-92<br />

1310-92<br />

1333-92<br />

1349-93<br />

1370-92<br />

1374-93<br />

1379-94<br />

141 9-92<br />

856-92<br />

1068-92<br />

11 48-95<br />

1268-92<br />

1380-94<br />

1478-92<br />

1445-92<br />

1504-92<br />

1549-93<br />

1550-93<br />

1552-92<br />

1600-92<br />

1615-94<br />

1616-94<br />

1625-92<br />

1663-92<br />

1797-92<br />

1921-94<br />

1922-94<br />

1685-92<br />

1838-93<br />

1968-92<br />

20-94<br />

21-95<br />

2124-94<br />

2102-92<br />

2 125-94<br />

2138-92<br />

2155-93<br />

2161-93<br />

221-95<br />

23-94<br />

2414-94<br />

2693-94<br />

289-94<br />

2415-94<br />

2862-94<br />

O5MAY 1993<br />

O5MAR1992<br />

12MAR1992<br />

01APRl992<br />

04MAY 1992<br />

01 JUN1992<br />

06JUL1992<br />

03AUG1992<br />

31AUG1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

3OJANl992<br />

O5MAY 1993<br />

OJMARl992<br />

12MAR1992<br />

01APR1992<br />

04MAY 1992<br />

13MAY1992<br />

16JUL1993<br />

20MAY1992<br />

26MAY1992<br />

01JUN1992<br />

06JUL1995<br />

08JUN1992<br />

05AUG1993<br />

05MAY1994<br />

OSAUG1993<br />

05MAYl994<br />

15JUNl992<br />

22JUNl992<br />

29JUN1992<br />

06JUL1992<br />

02SEP1993<br />

13JUL1992<br />

02SEP1993<br />

03JUN1994<br />

03JUNl994<br />

2lJUL1992<br />

27JULl992<br />

03AUG1992<br />

10AUG1992<br />

05OCTl993<br />

050CT1993<br />

17AUG1992<br />

24AUGl992<br />

01 JULl994<br />

OlJULl994<br />

31AUG1992<br />

OBSEPI 992<br />

14SEP1992<br />

070CT1992<br />

04NOV1993<br />

05AUGl994<br />

MAUG1994<br />

09NOVl992<br />

05JANl994<br />

05JAN 1995<br />

OlDEC1992<br />

02SEP1994<br />

02SEP1994<br />

07DECl992<br />

10DECl993<br />

10DEC1993<br />

03FEB1995<br />

05JANl994<br />

070CT1994<br />

070CT1994<br />

04NOVl994<br />

02DECl994<br />

04FEB1994<br />

ws<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

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su<br />

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Page 90 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

SO296 290-94 04FEB1994 WS 7.00€+00 su<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, S MU 8, C746K-A<br />

1 .l-Dichloroethane<br />

1,l -Dichloroethene<br />

Aluminum<br />

Antimony<br />

Arsenic<br />

Barium<br />

Benzene<br />

Beryllium<br />

Bismuth<br />

Cadmium<br />

Calcium<br />

Chromium<br />

Coban<br />

Copper<br />

Ethylbenzene<br />

Iron<br />

Lead<br />

Lithium<br />

Magnesium<br />

Manganese<br />

Mercury<br />

Molybdenum<br />

Nickel<br />

Niobium<br />

Phosphorus (P)<br />

Potassium<br />

Ruthenium<br />

Silicon<br />

Silver<br />

Sodium<br />

Strontium<br />

Tantalum<br />

Thallium<br />

Thorium<br />

Tin<br />

Tiianium<br />

Toluene<br />

Trans-1.2-Dichloroethene<br />

Trichloroelhene<br />

Tungsten<br />

Uranium<br />

Vanadium<br />

Xylene<br />

Zinc<br />

Zirconium<br />

PH<br />

WAG 7, SMU 8. C746K-B<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

75-34-3<br />

75-35-4<br />

7429-90-5<br />

7440-36-0<br />

7440-38-2<br />

7440-39-3<br />

71-43-2<br />

7440-41-7<br />

7 4 4 0 - 6 9 - 9<br />

7440-43-9<br />

7440-70-2<br />

7440-47-3<br />

7440-48-4<br />

7440-50-8<br />

100-41-4<br />

7439-89-6<br />

7439-92-1<br />

7439-93-2<br />

7439-95-4<br />

7439-96-5<br />

7439-97-6<br />

7439-98-7<br />

7440-02-0<br />

7440-03-1<br />

7723-14-0<br />

7440-09-7<br />

7440-1 8-8<br />

7440-2 1-3<br />

7440-22-4<br />

7440-23-5<br />

7440-24-6<br />

7440-25-7<br />

7440-28-0<br />

7440-29-1<br />

7440-31 -5<br />

7440-32-6<br />

10888-3<br />

156-60-5<br />

79-01-6<br />

7440-33-7<br />

7440-61 -1<br />

7440-62-2<br />

1330-20-7<br />

7440-66-6<br />

7440-67-7<br />

SO296<br />

395-92<br />

438-95<br />

508-94<br />

509-94<br />

613-92<br />

623-93<br />

632-92<br />

634-95<br />

637-93<br />

657-92<br />

701-92<br />

713-92<br />

788-95<br />

803-93<br />

828-92<br />

856-92<br />

890-92<br />

902-94<br />

903-94<br />

923-92<br />

957-95<br />

977-92<br />

995-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

517-92<br />

3OJANl992<br />

03MAR1995<br />

03MAR1994<br />

03MAR1994<br />

02MAR1992<br />

OSMAY 1993<br />

OSMARI 992<br />

05APR 1995<br />

OSMAY 1993<br />

09MAR1992<br />

1 2MAR 1 992<br />

16MARl992<br />

OMAY 1995<br />

02JUNl993<br />

23MAR1992<br />

01 APRl992<br />

06APRl992<br />

08APR1994<br />

OBAPR1994<br />

13APRl992<br />

OlJUN1995<br />

22APR1992<br />

27APR1992<br />

16FEBl992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEBlW2<br />

16FEB1992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

16FEB1992<br />

16FEB1992<br />

16FEBl992<br />

16FEB1992<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

7.00E+00<br />

7.00E+00<br />

7.00E+00<br />

7.00E+00<br />

9.00E+00<br />

7.00E+00<br />

8.00E+00<br />

8.00E+00<br />

7.00E+00<br />

8.00E+00<br />

7.00E+00<br />

8.00E+00<br />

7.00E+00<br />

6.00E+00<br />

8.00E+00<br />

8.00E+00<br />

7.00E+00<br />

7.00E+00<br />

7.00E+00<br />

8.00E+00<br />

7.00E+00<br />

8.00E+00<br />

7.00E+00<br />

7.WE+00<br />

5.00E+00<br />

1.62E+02<br />

O.OOE+W<br />

O.WE+OO<br />

0.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

1.09E+02<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

S.WE+OO<br />

2.79E+02<br />

O.WE+OO<br />

O.WE+OO<br />

6.50E+01<br />

6.10E+01<br />

O.M)E+OO<br />

O.OOE+W<br />

1 .M)E+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

<strong>4.</strong>00E+00<br />

O.OOE+OO<br />

3.30E+Ol<br />

O.OOE+OO<br />

1.20E+01<br />

l.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

O.M)E+OO<br />

O.OOE+W<br />

5.0OE+W<br />

5.WE+00<br />

<strong>4.</strong>WE+00<br />

O.M)E+W<br />

O.OOE+OO<br />

l.OOE+OO<br />

1 .M)E+Ol<br />

l.OOE+OO<br />

O.OOE+W<br />

2.WE+00<br />

J<br />

UJ<br />

<<br />

<<br />

UJ<br />

<<br />

<<br />

UJ<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

UJ<br />

UJ<br />

J<br />

<<br />

<<br />

UJ<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

ug1L<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

uglL<br />

mglL<br />

WlL<br />

WlL<br />

mglL<br />

mgfl<br />

mg1L<br />

WlL<br />

uglL<br />

WlL<br />

mglL<br />

WlL<br />

Wfl<br />

Wfl<br />

WlL<br />

WlL<br />

mglL<br />

mgfl<br />

mglL<br />

WlL<br />

mg1L<br />

mgfl<br />

WlL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

ug1L<br />

Wfl<br />

mglL<br />

mglL<br />

uglL<br />

mglL<br />

mglL<br />

su<br />

Page 91 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

1 ,I-Dichloroethane 75-34-3 1450-92 27JUL1992 WL 5.00E+00 < N<br />

uglL<br />

1 ,I-Dichloroethane<br />

75 - 34 - 3<br />

1801 -92 07OCT1992 WL<br />

C<br />

N<br />

uglL<br />

1 ,I-Dichloroethane<br />

75-34-3<br />

2104-92<br />

01DEC1992 WL.<br />

C<br />

N<br />

uglL<br />

1 ,l-Dichloroethene<br />

75-35-4<br />

1450-92 27JULl992 WL<br />

c<br />

N<br />

uglL<br />

1 ,I-Dichloroethene<br />

75-35-4<br />

1801-92 070CTI 992 WL<br />

C<br />

N<br />

uglL<br />

1 ,I-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chloride<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Coball<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Gross Alpha<br />

Gross Beta<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71 -43-2<br />

71 -43-2<br />

71-43-2<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

16887-00-6<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-484<br />

7440-484<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

12587-46-1<br />

12587-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

2104-92<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1450-92<br />

1801-92<br />

2104-92<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

I801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

62693<br />

1939-92<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1450-92<br />

1801 -92<br />

210492<br />

1939-92<br />

1939-92<br />

I801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

01 DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOVl992<br />

01DECl992<br />

OSMAY 1993<br />

27JULl992<br />

070CT1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

OSMAYI 993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY1993<br />

O7OCTI 992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

MAY1993<br />

03NOV1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

WAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOVl 992<br />

OlMC1992<br />

05MAYI993<br />

27JUL1992<br />

070CT1992<br />

OlDECl992<br />

03NOV1992<br />

03NOV1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

ug1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

ug1L<br />

uglL<br />

uglL<br />

mg1L<br />

mglL<br />

mglL<br />

mg/L<br />

mg1L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mgfl<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

pCiL<br />

pCVL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgk<br />

mglL<br />

WlL<br />

mgk<br />

mgk<br />

Lithium<br />

7439-93-2<br />

2104-92 OlDEC1992 WL<br />

N<br />

mglL<br />

Lilhium<br />

7439-93-2<br />

626-93 05MAY I 993 VK<br />

N<br />

mgk<br />

Magnesium<br />

7439-95-4<br />

1801-92 070CT1992 VK<br />

N mgk<br />

Page 92 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Magnesium 7439-95-4 1939-92 03NOV1992 VK 2.90E+01 N<br />

mglL<br />

Magnesium<br />

7439-95-4<br />

2104-92<br />

OlDEC1992<br />

<strong>4.</strong>00E+00<br />

N<br />

mglL<br />

Magnesium<br />

7439-95-4<br />

626-93 05MAYl993<br />

3.00E+00<br />

N<br />

mglL<br />

Manganese<br />

7439 - 96 - 5<br />

1801 -92 070CT1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

Manganese<br />

7439 96 - 5<br />

1939-92 03NOV1992 1.60E+01<br />

N<br />

mg1L<br />

Manganese<br />

7439 - 96 - 5<br />

2104-92 01DEC1992 O.OOE+OO<br />

N<br />

mglL<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

Nitrate as Nitrogen<br />

Oil <strong>and</strong> Grease<br />

PCB<br />

PCB<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

7439 - 96 - 5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

N ITRATEAS N IT<br />

SO227<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1939-92<br />

1939-92<br />

1868-92<br />

1939-92<br />

2104-92<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

(HMAY 1993<br />

03NOV1992<br />

03NOV1992<br />

190CT1992<br />

03NOV1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

(HMAY 1993<br />

07OCT1992<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

5.00E+00<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

2.WE+00<br />

O.OOE+OO<br />

O.WE+OO<br />

<strong>4.</strong>00E+00<br />

<<br />

<<br />

c<br />

C<br />

<<br />

<<br />

C<br />

C<br />

<<br />

<<br />

UJ<br />

<<br />

C<br />

c<br />

C<br />

<<br />

<<br />

C<br />

c<br />

<<br />

C<br />

<<br />

<<br />

C<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

w/L<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

Potassium<br />

7440-09-7<br />

1939-92 03NOV1992 1 .ZOE+OI<br />

N<br />

mgfl<br />

Potassium<br />

7440-09-7<br />

2104-92 01 DECl992<br />

2.00E+00<br />

N wfl<br />

Potassium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Sulfate<br />

TOX<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Technetium-99<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

7440-09-7<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

12143-45-2<br />

TOX<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

14133-76-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31 -5<br />

626-93<br />

i a01 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801 -92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801 -92<br />

1939-92<br />

2104-92<br />

62693<br />

1939-92<br />

1939-92<br />

1801-92<br />

1939-92<br />

626-93<br />

1939-92<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

2104-92<br />

626-93<br />

1801-92<br />

1939-92<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

(HMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

%MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY1993<br />

03NOV1992<br />

03NOV1992<br />

070CT1992<br />

03NOV1992<br />

05MAY1993<br />

03NOV1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

2.00E+00<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

0.00E+00<br />

5.00E+00<br />

9.00E+00<br />

<strong>4.</strong>00E+00<br />

6.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

l.lOE+Ol<br />

1.90E+01<br />

1.40E+01<br />

6.00€+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

5.06E+02<br />

2.80E+01<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+OO<br />

1.30E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

5.00E+00<br />

J<br />

J<br />

<<br />

C<br />

C<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N'<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mg1L<br />

mglL<br />

wlL<br />

mgfl<br />

wlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

uglL<br />

mglL<br />

mgfl<br />

mgfl<br />

pCVL<br />

mg/L<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

w/L<br />

msfl<br />

mg/L<br />

Page 93 of 176


~~<br />

Tin<br />

Tiianium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Trans-l,2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

cis-1.2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, S\IuIIU 8. C746K-C<br />

1 .l-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 .l-Dichloroethane<br />

1.1 -Dichloroethane<br />

1.1 -Dichloroethane<br />

1 ,I-Dichloroethene<br />

1,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1,l-Dichloroethene<br />

1 .l-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

7134-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Tin 7440-31-5 2104-92 01DEC1992 VK 5.00E+00 c N mglL<br />

7440-31-5<br />

626-93 OSMAY1993 5.00E+00<br />

N<br />

mglL<br />

7440-32-6<br />

1801-92 070CT1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-32-6<br />

1939-92 03NOV1992<br />

O.OOE+OO<br />

N<br />

mg1L<br />

7440-32-6<br />

2104-92<br />

01DEC1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-32-6<br />

626-93 OBMAY 1993 O.OOE+OO<br />

N<br />

mglL<br />

108-88-3<br />

1450-92 27JUL1992 5 .OOE +00<br />

N<br />

uglL<br />

108-88-3<br />

1801-92 070CT1992<br />

5.00E+00<br />

N<br />

uglL<br />

108-88-3<br />

2104-92 01 DEC1992<br />

5.00E+00<br />

N<br />

uglL<br />

7440-44-0<br />

1939-92 03NOV1992<br />

5.00E+00<br />

N<br />

mglL<br />

156-60-5<br />

1450-92 27 JULl992<br />

5.00E+00<br />

N<br />

uglL<br />

156-60-5<br />

1801-92 070CT1992<br />

5.00E+00<br />

N<br />

uglL<br />

156-60-5<br />

2104-92<br />

01 DEC1992<br />

5.00E+00<br />

N<br />

uglL<br />

79-01-6<br />

1450-92 27JUL1992<br />

l.OOE+OO<br />

N<br />

uglL<br />

79-01-6<br />

1801-92 070CT1992<br />

l.OOE+OO<br />

N<br />

uglL<br />

79-01 -6<br />

2104-92 01 DEC1992<br />

l.OOE+OO<br />

N<br />

uglL<br />

7440-33-7<br />

1801-92 070CT1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-33-7<br />

1939-92 03NOV1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-33-7<br />

2104-92 01DEC1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-33-7<br />

626-93 05MAY 1993<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-61-1<br />

1 aoi -92 070CT1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-61-1<br />

1939-92 03NOV1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-61-1<br />

2104-92 01DEC1992<br />

O.OOE+OO<br />

N<br />

mglL<br />

7440-61 -1<br />

626-93 O5MAY 1993 O.OOE+OO<br />

N<br />

mg1L<br />

7440-62-2<br />

1939-92 03NOV1992<br />

O.OOE+OO<br />

N<br />

mg1L<br />

7440-62-2<br />

2104-92<br />

01 DECl992<br />

O.OOE+W<br />

N<br />

mgk<br />

7440-62-2<br />

626-93 05MAY1993<br />

O.OOE+W<br />

N wfl<br />

1330-20-7<br />

1450-92 27JULl992<br />

l.OOE+Ol<br />

N<br />

uglL<br />

1330-20-7<br />

1801-92 070CT1992<br />

l.OOE+Ol<br />

N<br />

ug5<br />

1330-20-7<br />

2104-92 01DEC1992<br />

l.OOE+Ol<br />

N<br />

uglL<br />

7440-66-6<br />

1801 -92 070CT1992 O.OOE+OO<br />

N<br />

mgfl<br />

7440-66-6<br />

1939-92 03NOV1992 O.OOE+OO<br />

N<br />

mglL<br />

7440-66-6<br />

2104-92 01DECl992<br />

O.OOE+OO<br />

N<br />

wlL<br />

7440-66-6<br />

626-93 OSMAYl993 0.00E+W<br />

N<br />

mglL<br />

7440-67-7<br />

1801 -92 070CT1992 O.OOE+OO<br />

N<br />

mglL<br />

7440-67-7<br />

1939-92 03NOV1992 O.OOE+OO<br />

N<br />

mglL<br />

744067-7<br />

2104-92 01 DECl992<br />

O.OOE+OO<br />

N<br />

wlL<br />

7440-67-7<br />

626-93 OSMAY1993 O.OOE+OO<br />

N<br />

mglL<br />

156-59-2<br />

1939-92 03NOV1992 9.00E+W<br />

N<br />

ugfl<br />

SO296<br />

1801-92 070CT1992 7.00E+W<br />

N su<br />

SO296<br />

1969-92 09NOV1992 6.WE+W<br />

N su<br />

so296<br />

2104-92 01 DECl992<br />

7.00E+W<br />

N su<br />

SO296<br />

2140-92 07DEC1992 7.00E+W<br />

N su<br />

SO296<br />

626-93 05MAY1993 6.00€+00<br />

N su<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

4928-92<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

4928-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

26JUN1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

08MAY1992<br />

26JUN1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

08MAYl992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

Page 94 of 176<br />

l.OOE+Ol<br />

5.00E+00<br />

5.00E+00<br />

5.00E+W<br />

5.00E+00<br />

9.00E+W<br />

5.00E+W<br />

5.00E+00<br />

5.WE+00<br />

5.00E+W<br />

5.00€+00<br />

9.00E+00<br />

O.OOE+OO<br />

6.00E+W<br />

1 .WE+00<br />

1 .WE+00<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

0.00E+W<br />

O.M)E+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

<<br />

<<br />

<<br />

<<br />

J<br />

c<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

ugfl<br />

uglL<br />

ug5<br />

ugfl<br />

uglL<br />

ug5<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mgk<br />

wlL<br />

wR<br />

mgfl<br />

mglL<br />

mglL<br />

wR<br />

wlL<br />

w5<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE lYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Barium 7440-39-3 627-93 05MAY1993 WL O.OOE+OO<br />

N<br />

mglL<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Copper<br />

Copper<br />

Copper<br />

71-43-2<br />

71 -43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

21-92<br />

<<br />

c<br />

<<br />

<<br />

<<br />

<<br />

c<br />

c<br />

<<br />

<<br />

c<br />

c<br />

<<br />

<<br />

c<br />

<<br />

c<br />

CoPPr<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-484<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-414<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

627-93<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

26JUN1992<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECI 992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY1993<br />

26JUN1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOVl992<br />

01 DECl992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOVl992<br />

01DECl992<br />

(HMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECI 992<br />

OSMAY 1993<br />

070CT1992<br />

OJNOVI 992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

WAY 1993<br />

070CT1992<br />

Page 95 of 176<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

5.00E+00<br />

5.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.WE+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.90E+01<br />

5.30E+01<br />

9.90E+01<br />

1.20E+01<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

5.WE+00<br />

5.WE+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>16E+02<br />

1.34E+02<br />

I.WE+OO<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

<strong>4.</strong>WE+00<br />

1.30E+01<br />

3.20E+01<br />

3.WE+W<br />

I .WE+W<br />

6.00E+00<br />

1.50E+01<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

0.00E+00<br />

c<br />

c<br />

UJ<br />

c<br />

c<br />

<<br />

<<br />

<<br />

c<br />

<<br />

c<br />

UJ<br />

c<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Niobium<br />

7440-03-1 1940-92 03NOV1992 WL O.OOE+OO c N mglL<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

2105-92<br />

627-93<br />

ia69-92<br />

1940-92<br />

2105-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

01DEC1992<br />

O5MAY 1993<br />

190CT1992<br />

03NOV1992<br />

01 DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

627-93<br />

1802-92<br />

1940-92<br />

05MAY 1993<br />

070CT1992<br />

O3NOVl 992<br />

< N<br />

N<br />

N<br />

Potassium<br />

7440-09-7<br />

2105-92 01 DEC1992<br />

J<br />

N<br />

Potassium<br />

7440-09-7<br />

627-93 O5MAY 1993<br />

c<br />

N<br />

Ruthenium<br />

7440-ia-a<br />

1802-92 070CT1992<br />

c<br />

N<br />

Ruthenium<br />

7440-18-8<br />

1940-92 03NOV1992<br />

c<br />

N<br />

Ruthenium<br />

7440-1 a-a<br />

2105-92<br />

01 DEC1992<br />

c<br />

N<br />

Ruthenium<br />

7440-1 a-a<br />

627-93 O5MAYl 993<br />

<<br />

N<br />

Silicon<br />

Silicon<br />

7440-21-3<br />

7440-21-3<br />

1802-92<br />

1940-92<br />

070CT1992<br />

03NOV1992<br />

<<br />

N<br />

N<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

01 DECI 992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

J<br />

c<br />

c<br />

N<br />

N<br />

N<br />

N<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Titanium<br />

Titanium<br />

Tiianium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-I .2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trichloroethene<br />

Trichbroethene<br />

Trichbroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31 -5<br />

7440-31 -5<br />

7440-31-5<br />

7440-31 -5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-883<br />

ioa-aa-3<br />

ioa-aa-3<br />

108-88-3<br />

ioa-aa-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

4928-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

01 DECl992<br />

(HMAY I 993<br />

070CT1992<br />

03NOVl992<br />

01 DECI 992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

(HMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

(HMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

WAY 1993<br />

070CT1992<br />

03NOVl 992<br />

01DEC1992<br />

(HMAY 1993<br />

26JUN1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

26JUN1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

26JUN1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

08MAY 1992<br />

O7OCTI 992<br />

03NOV1992<br />

OlDECl992<br />

J<br />

<<br />

c<br />

<<br />

c<br />

<<br />

<<br />

<<br />

c<br />

<<br />

<<br />

<<br />

c<br />

<<br />

c<br />

<<br />

<<br />

c<br />

c<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 96 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Tungsten 7440-33-7 627-93 05MAY1993 WL O.OOE+OO < N mg1L<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SWU 8, C746K-D<br />

1 ,l-Dichloroethane<br />

1,l -Dichloroethane<br />

1 .I-Dichloroethane<br />

1,l -Dichloroethane<br />

1 .I-Dchloroethene<br />

1 ,I-Dichloroethene<br />

1 .I-Dichloroethene<br />

I ,l-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-354<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440- 39 - 3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1940-92<br />

2105-92<br />

627-93<br />

1298-92<br />

1449-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1940-92<br />

2105-92<br />

627-93<br />

1802-92<br />

1970-92<br />

2105-92<br />

2141-92<br />

627-93<br />

1448-92<br />

1803-92<br />

1941 -92<br />

2106-92<br />

I 448-92<br />

1803-92<br />

1941-92<br />

2106-92<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941 -92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941 -92<br />

2106-92<br />

628-93<br />

144892<br />

1803-92<br />

1941 -92<br />

2106-92<br />

1803-92<br />

1941 -92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941 -92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

03NOV1992<br />

01DEC1992<br />

O5MAYl 993<br />

26JUN1992<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

[HMAYI 993<br />

070CT1992<br />

O9NOVI 992<br />

OlDEC1992<br />

07DECl992<br />

05MAY1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY 1993<br />

070CTI 992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY I 993<br />

070CT1992<br />

03NOV1992<br />

01 DECI 992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECI 992<br />

05MAY 1993<br />

070CT1992<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

1.00E+01<br />

l.OOE+OI<br />

l.OOE+OI<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

7.00E+00<br />

6.00E+00<br />

7.00E+00<br />

7.00E+00<br />

6.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.WE+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

1 .WE+00<br />

I .00E+00<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.WE+00<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

2.00E+01<br />

2.60E+01<br />

I .80E+01<br />

1.30E+01<br />

O.WE+OO<br />

<<br />

N<br />

I<br />

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N<br />

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Page 97 of 176


Chromium<br />

Chromium<br />

Coban<br />

Coban<br />

Coban<br />

Coban<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium 7440-47-3 1941 -92 03NOV1992 WL O.OOE+OO < N mglL<br />

7440-47-3<br />

2106-92<br />

744047-3<br />

628-93<br />

7440-484<br />

1803-92<br />

7440-48-4<br />

1941 -92<br />

744048-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41 -4<br />

100-414<br />

100-41 -4<br />

100414<br />

7439 - 89 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-224<br />

7440-224<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1448-92<br />

1803-92<br />

1941 -92<br />

2106-92<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941 -92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941 -92<br />

2106-92<br />

628-93<br />

1870-92<br />

1941-92<br />

2106-92<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

180192<br />

1941-92<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

osMAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

OSMAYl993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

WAY1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

WAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

WAY1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY1993<br />

190CT1992<br />

03NOV1992<br />

OlDEC1992<br />

07OCT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

osMAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

Page 98 of 176<br />

WL<br />

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WL<br />

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WL<br />

WL<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

ugn<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

WlL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

wfl<br />

Wfl<br />

mglL<br />

WlL<br />

uglL<br />

Wfl<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

Wfl<br />

mgfl<br />

WlL<br />

Wfl<br />

mgfl<br />

W/L<br />

mgfl<br />

WlL<br />

mgfl<br />

mg/L<br />

WlL<br />

Wfl<br />

mgn


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

ANALYTE CAS NUMBER SAMPLE ID<br />

Silver 7440-22-4 2106-92 01DEC1992 VK O.OOE+OO<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Tianium<br />

Tianium<br />

Tianium<br />

Tilanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SVWU 8, C746K-E<br />

1,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31 -5<br />

7440-31-5<br />

7440-32-6<br />

7440-29-1<br />

7440-31-5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01 -6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

I<br />

0888-3<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

so296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

628-93<br />

1803-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

628-93<br />

1803-92<br />

1941-92<br />

628-93<br />

1803-92<br />

1941<br />

-92<br />

2106-92<br />

628-93<br />

1941<br />

-92<br />

628-93<br />

1803-92<br />

1941<br />

-92<br />

2 106-92<br />

1803-92<br />

2106-92<br />

1941-92<br />

2106-92<br />

1448-92<br />

1803-92<br />

1941-92<br />

2106-92<br />

1803-92<br />

1941-92<br />

1448-92<br />

1803-92<br />

2106-92<br />

1803-92<br />

628-93<br />

I<br />

448-92<br />

2106-92<br />

1941<br />

-92<br />

1941-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941-92<br />

2106-92<br />

1941<br />

-92<br />

2106-92<br />

628-93<br />

1803-92<br />

1941<br />

-92<br />

2106-92<br />

1803-92<br />

1941-92<br />

2106-92<br />

1803-92<br />

1941-92<br />

628-93<br />

I<br />

448-92<br />

628-93<br />

2106-92<br />

628-93<br />

1803-92<br />

1971-92<br />

2106-92<br />

2142-92<br />

628-93<br />

1804-92<br />

1942-92<br />

05MAY1993<br />

070CTI 992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

(HMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAYI 993<br />

070CT1992<br />

03NOVl 992<br />

01 DECl992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

OSMAY 1993<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOVl992<br />

01 DECl992<br />

05MAY 1993<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1993<br />

070CT1992<br />

09NOVl992<br />

01 DEC1992<br />

07DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

0.00E+00<br />

l.IOE+OI<br />

1.80E+01<br />

1.40E+01<br />

6.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OM+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+00<br />

5.WE+00<br />

5.00E+00<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

5.WE+00<br />

5.00€+00<br />

5.00E+W<br />

5.00E+00<br />

1.80E+01<br />

5.00€+00<br />

5.00€+00<br />

5.00E+00<br />

l.OOE+OO<br />

1.00E+00<br />

I<br />

.00E+00<br />

I<br />

.00E+00<br />

0.00E+00<br />

O.WE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OI<br />

l.OOE+OI<br />

l.OOE+OI<br />

l.WE+OI<br />

0.00E+W<br />

O.WE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

7.WE+00<br />

6.00E+00<br />

7.00E+00<br />

7.00€+00<br />

6.00€+00<br />

5.00E+00<br />

5.WE+W<br />

c<br />

c<br />

J<br />

c<br />

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Page 99 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

1 .l-Dichloroethane 75-34-3 2107-92 01DEC1992 WL 5.00E+00 C N<br />

1.1 -Dichloroethene<br />

1,l -Dichloroethene<br />

1 ,l-Dichloroethene<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Coban<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithiurn<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7 44 0 - 3 9 - 3<br />

7429-90-5<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

7 1-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

744047-3<br />

7440-47-3<br />

7440-48-4<br />

7440484<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

1804-92<br />

1942-92<br />

2 107-92<br />

1804-92<br />

1942-92<br />

2 107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2 107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

1804-92<br />

1942-92<br />

2107-92<br />

1804-92<br />

2107-92<br />

629-93<br />

1804-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

629-93<br />

1804-92<br />

1942-92<br />

629-93<br />

1804-92<br />

1942-92<br />

629-93<br />

1804-92<br />

2 107-92<br />

629-93<br />

1804-92<br />

2107-92<br />

1804-92<br />

1942-92<br />

629-93<br />

1804-92<br />

2107-92<br />

2107-92<br />

629-93<br />

1942-92<br />

1942-92<br />

2107-92<br />

2107-92<br />

2107-92<br />

1942-92<br />

1942-92<br />

2107-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

MAY<br />

1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOVl992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

MAY<br />

1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

WL<br />

WL<br />

VM<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VM<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VM<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

WL<br />

\IK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.00E+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+W<br />

1.70E+01<br />

2.00E+01<br />

1.80E+Ol<br />

1.60E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+W<br />

5.WE+00<br />

5.00E+00<br />

S.WE+OO<br />

O.WE+OO<br />

2.WE+00<br />

2.WE+W<br />

<strong>4.</strong>00E+W<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

<strong>4.</strong>WE+W<br />

5.WE+W<br />

5.WE+W<br />

<strong>4.</strong>WE+W<br />

O.WE+W<br />

O.WE+OO<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

<<br />

<<br />

C<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

C<br />

C<br />

C<br />

<<br />

C<br />

C<br />

N<br />

C<br />

N<br />

C<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgfl<br />

mglL<br />

mg1L<br />

mg/L<br />

mgfl<br />

mgn<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

uglL<br />

ugfl<br />

uglL<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

mg1L<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

Page 100 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Manganese 7439 - 96 - 5 2107-92 01DEC1992 VK O.OOE+OO N<br />

mglL<br />

Manganese<br />

Mercury<br />

7439-96-5<br />

7439-97-6<br />

629-93<br />

1804-92<br />

O5MAY 1993<br />

070CT1992<br />

<<br />

N<br />

N<br />

mglL<br />

mglL<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

PCB<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1871 -92<br />

1942-92<br />

2107-92<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

190CT1992<br />

03NOV1992<br />

01 DECl992<br />

<<br />

<<br />

C<br />

<<br />

C<br />

<<br />

<<br />

<<br />

<<br />

UJ<br />

C<br />

<<br />

c<br />

C<br />

C<br />

<<br />

C<br />

C<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

uglL<br />

uglL<br />

uglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1804-92 070CT1992<br />

C<br />

N<br />

mglL<br />

Phosphorus (P)<br />

7723-14-0<br />

1942-92 03NOV1992<br />

<<br />

N wfl<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

01 DEC1992<br />

OWAYI 993<br />

070CTI 992<br />

03NOVl992<br />

01 DECl992<br />

C<br />

J<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

w/L<br />

WlL<br />

mglL<br />

Potassium<br />

7440-09-7<br />

629-93 05MAY 1993<br />

N<br />

mglL<br />

Ruthenium<br />

7440-188<br />

1804-92 070CT1992<br />

C<br />

N wfl<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

1942-92<br />

2107-92<br />

629-93<br />

I80492<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

03NOV1992<br />

01 DEC1992<br />

05MAYI993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

<<br />

<<br />

<<br />

<<br />

J<br />

c<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

Silver<br />

7440-22-4<br />

1942-92 03NOV1992<br />

<<br />

N<br />

mgfl<br />

Silver<br />

7440-22-4<br />

2107-92 01DEC1992<br />

<<br />

N<br />

mglL<br />

Silver<br />

7440-22-4<br />

629-93 O5MAY 1993<br />

C<br />

N wfl<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

18M-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOVI 992<br />

01DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

J<br />

c<br />

C<br />

C<br />

<<br />

c<br />

C<br />

<<br />

<<br />

C<br />

<<br />

C<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mgfl<br />

WlL<br />

mglL<br />

mg1L<br />

WllL<br />

wlL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

wlL<br />

mg/L<br />

wlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

Tin<br />

7440-31-5<br />

2107-92 01 DECl992<br />

C<br />

N<br />

mgfl<br />

Tin<br />

7440-31-5<br />

629-93 05MAY 1993<br />

<<br />

N wfl<br />

Titanium<br />

Titanium<br />

Tiianium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

<<br />

c<br />

C<br />

<<br />

C<br />

C<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mgfl<br />

wlL<br />

wlL<br />

mgfl<br />

uglL<br />

uglL<br />

u9fl<br />

Trans-I .2-Dichloroethene 156-60-5<br />

1804-92 070CT1992<br />

<<br />

N<br />

uglL<br />

Page 101 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trans-I .2-Dichloroethene 156-60-5 1942-92 03NOV1992 WL 5.00E+00 C N uglL<br />

Trans-I .2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7. SWU 8, C746K-F<br />

1 ,I-Dichloroethane<br />

1 .l-Dffihloroethane<br />

1 .I-Dichloroeihane<br />

1 ,l-Dichloroethane<br />

1 .I-Dichloroeihene<br />

1 ,l-Dichloroethene<br />

1 ,l-Dihloroethene<br />

1 ,I -Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

2107-92<br />

1804-92<br />

1942-92<br />

2107-92<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1942-92<br />

2107-92<br />

1804-92<br />

1942-92<br />

2107-92<br />

629-93<br />

180492<br />

1942-92<br />

2107-92<br />

629-93<br />

1804-92<br />

1972-92<br />

2107-92<br />

2143-92<br />

629-93<br />

1451-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1451-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1451-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

62593<br />

1800-92<br />

1943-92<br />

210592<br />

625-93<br />

1800-92<br />

1943-92<br />

210592<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY 1993<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

09NOV1992<br />

01DECl992<br />

07DECl992<br />

05MAY 1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

WAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOVl992<br />

OlDEC1992<br />

WAY 1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

070CT1992<br />

03NOVI 992<br />

01 DECI 992<br />

OWY 1993<br />

070CT1992<br />

OJNOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

Page 102 of 176<br />

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N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

WlL<br />

mglL<br />

mglL<br />

wfl<br />

su<br />

su<br />

su<br />

su<br />

su<br />

ugfl<br />

ugfl<br />

ug5<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

uglL<br />

ugfl<br />

ugk<br />

ugfl<br />

WlL<br />

wk<br />

mglL<br />

mgk<br />

mglL<br />

wfl<br />

mgk<br />

wR<br />

wk<br />

mgfl


Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Coban<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Cadmium 7440-43-9 625-93 05MAY1993 WL O.OOE+OO < N<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-18-0<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1451 -92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1867-92<br />

1943-92<br />

2108-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

62593<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAYl 993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAYI 993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAYI 993<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

O5MAYl 993<br />

070CTI 992<br />

03NOVl992<br />

01DECl992<br />

OSMAYI993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

M Y 1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOVI 992<br />

OlDEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

M Y 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAYI993<br />

190CT1992<br />

03NOV1992<br />

01 DECl992<br />

070CT1992<br />

03NOV1992<br />

01 DECI 992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

M Y 1993<br />

Page 103 of 176<br />

WL<br />

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WL<br />

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mglL<br />

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mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

uglL<br />

uglL<br />

uglL<br />

ug5<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

w5<br />

mg5<br />

mglL<br />

mg5<br />

WlL<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mg5<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mg/L<br />

mgfl<br />

mg5<br />

mgk<br />

mg5<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

ugfl<br />

uglL<br />

mglL<br />

mglL<br />

mg5<br />

mg1L<br />

mgfl<br />

mg1L<br />

WlL<br />

mglL<br />

mgtL<br />

mgfl<br />

mg5<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Silicon 7440-21-3 1800-92 070CT1992 WL 5.00E+00 < N mg1L<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-l,2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

PH<br />

PH<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

so296<br />

so296<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1451 -92<br />

1800-92<br />

1943.92<br />

2108-92<br />

1451-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1451-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1943-92<br />

2108-92<br />

625-93<br />

1451 -92<br />

1800-92<br />

1943-92<br />

2108-92<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1943-92<br />

2108-92<br />

625-93<br />

1800-92<br />

1973-92<br />

03NOV1992<br />

OlDECl992<br />

05MAY 1 993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

(HMAY 1 993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY1993<br />

03NOV1992<br />

01 DECl992<br />

(HMAY1993<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

osMAYl993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

05MAY 1993<br />

070CT1992<br />

09NOV1992<br />

Page 104 of 176<br />

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mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mglL<br />

WlL<br />

mglL<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

wfl<br />

mgfl<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

ugfl<br />

ugfl<br />

ug5<br />

uglL<br />

uglL<br />

Wfl<br />

uglL<br />

uglL<br />

WlL<br />

WlL<br />

mgfl<br />

mglL<br />

mglL<br />

mg/L<br />

WlL<br />

mglL<br />

mgfl<br />

mg1L<br />

msn<br />

ugfl<br />

ug1L<br />

ugfl<br />

ugk<br />

wk<br />

mgk<br />

mg/L<br />

msn<br />

mgfl<br />

mgk<br />

wfl<br />

mglL<br />

su<br />

su


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

PH SO296 2108-92 01DEC1992 WL 8.00E+00 N su<br />

PH<br />

PH<br />

WAG 7. SWU 8, C746K-G<br />

1 ,l-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 ,l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 ,I-Dichloroethene<br />

1 .l-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1,l-Dichloroethene<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Blsmuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Cobalt<br />

Coball<br />

Coball<br />

Coball<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lilhium<br />

SO296<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

744047-3<br />

7440-47-3<br />

744048-4<br />

7440-48-4<br />

7440-48-4<br />

7440-484<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

100-41-4<br />

100-41-4<br />

10041-4<br />

100-41-4<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-896<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

2144-92<br />

625-93<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

07DEC1992<br />

O5MAY 1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

O5MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

O5MAY 1993<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOVl 992<br />

OlDECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

W Y 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

MAY1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

W Y 1993<br />

070CT1992<br />

Page 105 of 176<br />

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su<br />

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uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mg/L<br />

mglL<br />

mg/L<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Wfl<br />

ug1L<br />

uglL<br />

ugfl<br />

uglL<br />

mglL<br />

mg/L<br />

mgfl<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

WlL<br />

WlL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

WlL<br />

WlL<br />

Wfl<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

msk<br />

mgk<br />

mgfl<br />

Wfl<br />

WlL<br />

Wfl<br />

WlL<br />

Wk<br />

WlL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL'fTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Lithium 7439-93-2 1944-92 03NOV1992 VK O.OOE+OO C N mglL<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

Niobium<br />

Niobium<br />

PCB<br />

PCB<br />

PCB<br />

Phosphate as P<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Sillcon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-90-7<br />

7439-90-7<br />

7439-90-7<br />

7439-90-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

PHOSPHATEASP<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7449-10-0<br />

7440-10-8<br />

7723-14-0<br />

7440-09-7<br />

7440-10-0<br />

7440-18-8<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-25-7<br />

7440-257<br />

7440-20-0<br />

7440-24-6<br />

7440-25-7<br />

7440-2ao<br />

7440-2ao<br />

7440-2a-o<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31 -5<br />

7440-31-5<br />

7440-31-5<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1944-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1866-92<br />

1944-92<br />

21 09-92<br />

1-92<br />

624-93<br />

1944-92<br />

624-93<br />

1799-92<br />

1944-92<br />

21 09-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

624-93<br />

1944-92<br />

624-93<br />

1799-92<br />

1944-92<br />

21 09-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

1799-92<br />

2109-92<br />

1799-92<br />

2109-92<br />

1799-92<br />

2109-92<br />

1799-92<br />

21 09-92<br />

2109-92<br />

01DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY 1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

OSMAYl993<br />

19OCTl992<br />

03NOV1992<br />

01 DECl992<br />

070CT1992<br />

03NOV1992<br />

OlDEC1992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

(HMAY 1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

MY1993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

MY1993<br />

070CT1992<br />

03NOV1992<br />

OlDECl992<br />

05MAY1993<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

MY1993<br />

07OCT1992<br />

03NOV1992<br />

OlDECl992<br />

OSMAY1993<br />

070CT1992<br />

03NOV1992<br />

MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DECl992<br />

MAY1993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

OSMAYl993<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

WL<br />

VK<br />

O.OOE+OO<br />

O.OOE+OO<br />

3.00E+00<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

O.OOE+OO<br />

2.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

<strong>4.</strong>WE+W<br />

<strong>4.</strong>00E+00<br />

2.WE+00<br />

2.00E+00<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

5.WE+W<br />

5.WE+W<br />

5.WE+W<br />

6.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

1.20E+01<br />

1.80E+01<br />

I<br />

.SOE+Ol<br />

6.WE+00<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+OO<br />

5.00E+00<br />

5.WE+W<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

<<br />

C<br />

C<br />

<<br />

<<br />

C<br />

<<br />

<<br />

C<br />

C<br />

C<br />

<<br />

C<br />

<<br />

C<br />

N<br />

< N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

ugfl<br />

ug/L<br />

ugfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgR<br />

mglL<br />

mgfl<br />

WlL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

WlL<br />

mglL<br />

WlL<br />

mglL<br />

mg1L<br />

mgfl<br />

mgfl<br />

Page 106 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Tin 7440-31 -5 624-93 05MAY1993 VK 5.00E+00 c N mglL<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Trans-1.2-Dichloroethene<br />

Trans-l.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

zirconium<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SWdU 8, C746K-GA1<br />

1.1 .l-Trichloroethane<br />

1,l.l-Trichloroethane<br />

1 .l-Dchloroethane<br />

1 .l-Dchloroethane<br />

1 ,l-Dichloroethane<br />

1,l-Dichloroethene<br />

1,l -Dichloroethene<br />

1 .l-Dichloroethene<br />

Acetone<br />

Acetone<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminurn<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

71-55-6<br />

71 -55-6<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

67-64-1<br />

67-64-1<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1944-92<br />

2109-92<br />

624-93<br />

1452-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1944-92<br />

2109-92<br />

624-93<br />

1799-92<br />

1974-92<br />

2109-92<br />

2145-92<br />

624-93<br />

140-95<br />

433-95<br />

1959-92<br />

2208-92<br />

433-95<br />

1959-92<br />

2208-92<br />

433-95<br />

1443-93<br />

1703-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

OSMAYl993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

27JULl992<br />

070CT1992<br />

03NOVl992<br />

01 DEC1992<br />

27JULl992<br />

070CT1992<br />

03NOV1992<br />

01DECl992<br />

070CT1992<br />

OSNOV1992<br />

01DEC1992<br />

05MAY1993<br />

07OCT1992<br />

03NOV1992<br />

01DEC1992<br />

05MAY 1993<br />

03NOV1992<br />

01DECl992<br />

05MAY1993<br />

27JUL1992<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

070CT1992<br />

03NOV1992<br />

01 DEC1992<br />

05MAYl993<br />

070CT1992<br />

03NOV1992<br />

01DEC1992<br />

OSMAY 1993<br />

070CT1992<br />

09NOV1992<br />

OlDEC1992<br />

07DEC1992<br />

05MAYl993<br />

2OJANl995<br />

03MAR1995<br />

05NOV1992<br />

16DEC1992<br />

O3MARl995<br />

05NOV1992<br />

16DEC1992<br />

03MAR1995<br />

15SEPl993<br />

220CT1993<br />

05MAY 1994<br />

15SEPl993<br />

050CT1993<br />

05JAN1995<br />

04NOV1993<br />

05NOVl992<br />

WAN1994<br />

10DEC1993<br />

02DEC1994<br />

04FEB1994<br />

OM1995<br />

OM1994<br />

OSMAY 1993<br />

03MAY1995<br />

WUN1993<br />

08APRl994<br />

Page 107 of 176<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.00€+00<br />

5.00€+00<br />

5.00E+00<br />

5.00E+OO<br />

5.00E+00<br />

5.00E+00<br />

l.OOE+OO<br />

1.00E+00<br />

l.OOE+OO<br />

1 .00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+Ol<br />

1.00E+01<br />

1.00E+Ol<br />

1 .00E+01<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00€+00<br />

0.00E+00<br />

0.00E+00<br />

7.00E+W<br />

7.00E+00<br />

8.00E+00<br />

7.00E+00<br />

6.00E+00<br />

5.00E+OO<br />

5.00E+00<br />

5.00€+00<br />

5.00E+W<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+W<br />

1.70E+01<br />

7.00E+OO<br />

2.14E+02<br />

1.27E+02<br />

1.18E+02<br />

3.50E+02<br />

1.06E+02<br />

2.79E+02<br />

2.98E+02<br />

2.92E+02<br />

1.62E+02<br />

3.35E+02<br />

3.02€+02<br />

3.11 E+O2<br />

3.30E+Ol<br />

1.80E+01<br />

2.6M+02<br />

9.10E+01<br />

<<br />

C<br />

C<br />

C<br />

<<br />

C<br />

<<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

<<br />

c<br />

<<br />

C<br />

<<br />

C<br />

<<br />

C<br />

Q<br />

ux<br />

ux<br />

<<br />

c<br />

ux<br />

<<br />

<<br />

ux<br />

X<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugIL<br />

uglL<br />

uglL<br />

mglL<br />

mgk<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mg1L<br />

mg/L<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mgk<br />

mglL<br />

mgfl<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

su<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

Ug/L<br />

ugfl<br />

ug/L<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgk<br />

mgk<br />

mgfl<br />

mglL<br />

WlL<br />

mgfl<br />

mgk<br />

mg/L<br />

msnmsn


L.9 (continued)<br />

...--.-<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Antimony 7440-36-0 1959-92 05NOV1992 VK O.OOE+OO < N mglL<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cad m i u m<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

744043-9<br />

744043-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-41 -3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

630-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841 -93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841 -93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

1959-92<br />

2208-92<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

952-95<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

05MAY1993<br />

O5MAY 1994<br />

15SEPl993<br />

050CT1993<br />

O5JANl995<br />

04NOV1993<br />

05NOV1992<br />

05JAN1994<br />

10DEC1993<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR 1994<br />

05MAY 1993<br />

03MAYl995<br />

04JUN1993<br />

08APR1994<br />

O5MAY 1994<br />

15SEP1993<br />

050CT1993<br />

05JAN1995<br />

04NOV1993<br />

05NOV1992<br />

05JAN1994<br />

1 ODECl993<br />

02DEC1994<br />

04FEB1994<br />

03MARl995<br />

03MAR1994<br />

05MAY1993<br />

03MAY 1995<br />

04JUN1993<br />

OBAPR1994<br />

05NOV1992<br />

16DEC1992<br />

05NOV1992<br />

OFMAY1993<br />

05NOV1992<br />

MAY1993<br />

05MAY 1994<br />

15SEPl993<br />

050CT1993<br />

WAN1995<br />

04NOV1993<br />

05NOVl992<br />

WAN1994<br />

10DECl993<br />

02DEC1994<br />

04FEB1994<br />

O3MARl995<br />

03MARl994<br />

OSMAY 1993<br />

03MAY 1995<br />

04JUN1993<br />

08APRl994<br />

01 JUNl995<br />

05NOV1992<br />

OSMAYl993<br />

MAY 1994<br />

15SEP1993<br />

05OCT1993<br />

WAN1995<br />

04NOV1993<br />

05NOV1992<br />

05JAN1994<br />

10DEC1993<br />

02DEC1994<br />

04FEB1994<br />

03MARl995<br />

03MARl994<br />

MAY1993<br />

Page 108 of 176<br />

C<br />

N<br />

N<br />

< N<br />

N<br />

CS<br />

N<br />

c<br />

N<br />

N<br />

C<br />

N<br />

X<br />

N<br />

4s<br />

N<br />

< N<br />

< N<br />

N<br />

< N<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium<br />

7440-47-3 783-95 03MAY1995 WL O.OOE+OO U N<br />

mg1L<br />

Chromium<br />

7440-47-3<br />

811-93 04JUN1993 WL<br />

N<br />

mglL<br />

Chromium<br />

Chromium<br />

Coban<br />

Cobalt<br />

Copper<br />

Copper<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

897-94<br />

952-95<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1004-93<br />

1004-95<br />

1025-93<br />

103-95<br />

1045-95<br />

1065-94<br />

1073-95<br />

1119-95<br />

1136-95<br />

1143-95<br />

1200-94<br />

1219-95<br />

1251 -94<br />

140-95<br />

1443-93<br />

1517-93<br />

1551-93<br />

1561 -94<br />

16-95<br />

1610-94<br />

1636-93<br />

1653-94<br />

1703-93<br />

1713-94<br />

176-95<br />

1777-93<br />

1786-94<br />

1833-94<br />

1841-93<br />

1895-93<br />

1916-94<br />

1967-94<br />

2003-93<br />

2022-94<br />

2094-93<br />

21-94<br />

2107-94<br />

2119-94<br />

2156-93<br />

216-95<br />

2190-93<br />

2200-94<br />

2220-93<br />

224894<br />

2267-93<br />

2332-94<br />

2409-94<br />

2476-94<br />

2479-94<br />

255-95<br />

2615-94<br />

2687-94<br />

2731-94<br />

276894<br />

2838-94<br />

2857-94<br />

291-94<br />

2918-94<br />

2987-94<br />

3005-94<br />

301-95<br />

3087-94<br />

3101-94<br />

369-95<br />

08APR1994<br />

01JUN1995<br />

05NOV1992<br />

05MAY 1993<br />

05NOV1992<br />

O5MAY 1993<br />

01 JUL1993<br />

08JUN1995<br />

09JUL1993<br />

13JAN1995<br />

13JUN1995<br />

22APR1994<br />

20JUN1995<br />

22JUN1995<br />

26JUN1995<br />

06JUL1995<br />

05MAY1994<br />

11 JUL1995<br />

13MAY 1994<br />

20JAN1995<br />

15SEP1993<br />

28SEP1993<br />

050CT1993<br />

24JUN1994<br />

05JAN1995<br />

OlJUL1994<br />

150CTl993<br />

08JUL1994<br />

220CT1993<br />

15JULl994<br />

26JANl995<br />

28OCT1993<br />

22JULl994<br />

29JUL1994<br />

04NOV1993<br />

12NOV1993<br />

05AUG1994<br />

12AUG1994<br />

24NOV1993<br />

19AUGl994<br />

OSDEC1993<br />

05JAN1994<br />

26AUG1994<br />

02SEP1994<br />

lODECl993<br />

03FEB1995<br />

15DEC1993<br />

09SEP1994<br />

22DEC1993<br />

16SEP1994<br />

30DEC1993<br />

3OSEPl994<br />

070CT1994<br />

140CT1994<br />

19OCTl994<br />

08FEB1995<br />

280CT1994<br />

04NOV1994<br />

11 NOVl994<br />

17NOV1994<br />

23NOV1994<br />

02DEC1994<br />

04FEB1994<br />

08DEC1994<br />

14DEC1994<br />

23SEPl994<br />

17FEB1995<br />

27DECl994<br />

22DECl994<br />

24FEB1995<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

WL<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

c<br />

c<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

J<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

FIELD<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Page 109 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Estimated Flow EST FLOW 417-94 18FEB1994 VM 1.30E+01 N GaVDav<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Ethylbenzene<br />

Ethylbenzene<br />

Flow<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

GCMS Scan<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

100-41-4<br />

100-41-4<br />

SO840<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

GCMS SCAN<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

433-95<br />

453-94<br />

470-95<br />

497-95<br />

510-94<br />

543-95<br />

564-95<br />

612-94<br />

629-95<br />

666-95<br />

711-95<br />

743-95<br />

746-94<br />

783-95<br />

813-95<br />

88495<br />

919-95<br />

952-95<br />

1959-92<br />

2208-92<br />

510-94<br />

1004-95<br />

1049-95<br />

1065-94<br />

1143-95<br />

1200-94<br />

1219-95<br />

140-95<br />

1517-93<br />

1551 -93<br />

16-95<br />

2479-94<br />

2768-94<br />

2857-94<br />

2987-94<br />

3005-94<br />

301-95<br />

433-95<br />

497-95<br />

629-95<br />

711-95<br />

783-95<br />

884-95<br />

897-94<br />

952-95<br />

1200-94<br />

1443-93<br />

1551 -93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

109-94<br />

1200-94<br />

1443-93<br />

1551 -93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

215693<br />

2857-94<br />

03MAR1995<br />

25FEB1994<br />

1 OMARl995<br />

17MAR1995<br />

03MAR1994<br />

23MAR1995<br />

28MAR1995<br />

17MAR1994<br />

O5APRl995<br />

13APRl995<br />

21APR1995<br />

26APR1995<br />

31MAR1994<br />

03MAYl995<br />

llMAYl995<br />

17MAY1995<br />

25MAYl995<br />

01JUNl995<br />

05NOV1992<br />

16DECl992<br />

03MAR1994<br />

OBJUNl995<br />

14JUNl995<br />

22APR 1994<br />

06JULl995<br />

05MAY 1994<br />

11 JULl995<br />

20JAN1995<br />

28SEPl993<br />

050CT1993<br />

WAN1995<br />

190CT1994<br />

17NOV1994<br />

02DEC1994<br />

14DECl994<br />

23SEPl994<br />

17FEB1995<br />

03MAR1995<br />

17MAR1995<br />

05APRl995<br />

2lAPR1995<br />

03MAY1995<br />

17MAY1995<br />

08APRl994<br />

01JUN1995<br />

OSMAYl994<br />

15SEP1993<br />

050CT1993<br />

05JANl995<br />

04NOV1993<br />

05NOV1992<br />

WAN1994<br />

1 ODECl993<br />

02DEC1994<br />

04FEBl994<br />

03MARl995<br />

03MARl994<br />

05MAYl993<br />

03MAY1995<br />

WUN1993<br />

08APR1994<br />

12JAN1994<br />

OSMAY 1994<br />

15SEP1993<br />

050CT1993<br />

WAN1995<br />

04NOVl993<br />

05NOVl992<br />

05JANl994<br />

1 ODECl993<br />

02DECl994<br />

Page 110 of 176<br />

VM<br />

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WL<br />

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VK<br />

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Q<br />

N<br />

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Q<br />

HX<br />

N<br />

N<br />

N<br />

N<br />

N<br />

PGDP<br />

N<br />

Q<br />

N<br />

Q<br />

Q<br />

Q<br />

Q<br />

N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaUDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

uglL<br />

uglL<br />

MGD<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug5<br />

uglL<br />

ugk<br />

ug/L<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

ug5<br />

ugk<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

ugfl<br />

ug1L<br />

ug1L<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mg5<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mgk<br />

mgk<br />

mglL<br />

mglL<br />

mgk<br />

mgk<br />

mgk<br />

maR<br />

mglL<br />

mgk<br />

mglL<br />

mg5<br />

mgk


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Lead 7439-92-1 291-94 04FEB1994 WL 1.00E+00<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

LIhium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

952-95<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

Manganese '<br />

7439-96-5<br />

1200-94<br />

7439-96-5<br />

1443-93<br />

7439-96-5<br />

1551-93<br />

7439-96-5<br />

16-95<br />

7439-96-5<br />

1841 -93<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439 - 96 - 5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

1551-93<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551 -93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

1959-92<br />

630-93<br />

2132-92<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551 -93<br />

16-95<br />

03MAR1995<br />

03MAR1994<br />

O5MAY 1993<br />

O3MAYl 995<br />

04JUN1993<br />

08APR1994<br />

OlJUN1995<br />

05NOV1992<br />

05MAY 1993<br />

O5MAY 1994<br />

15SEP1993<br />

050CT1993<br />

05JAN1995<br />

04NOV1993<br />

05NOV1992<br />

05JANl994<br />

1 ODECI 993<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

05MAY 1993<br />

O3MAY 1995<br />

04JUN1993<br />

08APRl994<br />

05MAY 1994<br />

15SEP1993<br />

050CT1993<br />

05JAN1995<br />

04NOV1993<br />

OSNOVI 992<br />

05JANl994<br />

10DECl993<br />

02DEC1994<br />

04FEB1994<br />

O3MARl 995<br />

03MAR 1994<br />

05MAY 1993<br />

03MAY 1995<br />

04JUN1993<br />

08APR1994<br />

050CT1993<br />

05NOV1992<br />

05MAY 1993<br />

05NOV1992<br />

05MAY 1993<br />

WAY 1994<br />

15SEPl993<br />

050CTI993<br />

O5JANl 995<br />

04NOV1993<br />

05NOV1992<br />

05JANl994<br />

10DEC1993<br />

02DEC1994<br />

MFEB 1994<br />

03MAR1995<br />

03MAR1994<br />

05MAY 1993<br />

O3MAY 1995<br />

04JUN1993<br />

08APR1994<br />

05NOVI992<br />

OSMAY 1993<br />

07DECI 992<br />

05NOV1992<br />

OsMAY1993<br />

WAY1994<br />

15SEP1993<br />

050CTI993<br />

(HJANI 995<br />

Page 111 of 176<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

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WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

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VK<br />

VK<br />

WL<br />

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WL<br />

WL<br />

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VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

1.20E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.00E+02<br />

7.10E+01<br />

7.3OE+01<br />

1 .08E+02<br />

<strong>4.</strong>50E+01<br />

8.40E+01<br />

1.06E+02<br />

9.80E+01<br />

7.3OE+01<br />

l.lOE+02<br />

1.14E+02<br />

1.08E+02<br />

1.80E+01<br />

1.80E+01<br />

1.38E+02<br />

<strong>4.</strong>10E+01<br />

1.21 E+02<br />

8.10E+01<br />

8.40E+01<br />

1.48E+02<br />

5.30E+01<br />

1.13E+02<br />

1.25E+02<br />

1.17E+02<br />

8.20E+01<br />

1.21 E+02<br />

1.00E+02<br />

1.25E+02<br />

2.00E+01<br />

1.40E+01<br />

1.60E+02<br />

<strong>4.</strong>30E+01<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

1 .00E+OO<br />

O.OOE+OO<br />

1.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

1 .00E+00<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

1.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

5.00E+00<br />

7 .OOE+ 00<br />

5.00E+00<br />

6.00E+00<br />

N<br />

N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mg1L<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

W/L<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WR<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Potassium 7440-09-7 1841-93 04NOV1993 VK 1.50E+01 N mg1L<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

7440-18-8<br />

7440-10-8<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

783-95<br />

811-93<br />

897-94<br />

1143-95<br />

433-95<br />

783-95<br />

798-93<br />

952-95<br />

1143-95<br />

433-95<br />

783-95<br />

798-93<br />

952-95<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

703-95<br />

811-93<br />

097-94<br />

1959-92<br />

630-93<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1041-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2057-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

703-95<br />

811-93<br />

097-94<br />

1200-94<br />

1443-93<br />

1551-93<br />

16-95<br />

1041-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

630-93<br />

703-95<br />

05NOVI992<br />

OSJANI 994<br />

lODECl993<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

OSMAY 1993<br />

03MAY I995<br />

O4JUN1 993<br />

08APRI994<br />

06JULl 995<br />

03MAR1995<br />

O3MAY 1995<br />

02JUN1993<br />

01JUN1995<br />

06JULl995<br />

03MAR1995<br />

03MAY1995<br />

02JUNl993<br />

01 JUN1995<br />

05NOV1992<br />

05MAY 1993<br />

05MAY 1994<br />

15SEPl993<br />

050CTI993<br />

05JAN1995<br />

04NOVl993<br />

05NOVI992<br />

OSJANl994<br />

lODECl993<br />

02DECl994<br />

04FEBl994<br />

03MAR1995<br />

03MARl994<br />

05MAYl993<br />

03MAYl995<br />

MJUNl993<br />

OBAPR 1994<br />

05NOV1992<br />

WAY 1993<br />

WAY 1994<br />

15SEPl993<br />

050CT1993<br />

WAN1 995<br />

04NOV1993<br />

05NOV1992<br />

05JAN1994<br />

lODECl993<br />

02DEC1994<br />

04FEBl994<br />

03MARI995<br />

03MAR1994<br />

OSMAY 1993<br />

03MAY 1995<br />

04JUNl993<br />

O0APRl994<br />

05MAY 1994<br />

15SEP1993<br />

OSOCT1993<br />

OSJAN1995<br />

04NOV1993<br />

OSNOV1992<br />

WAN1994<br />

10DEC1993<br />

02DECl994<br />

04FEBl994<br />

O3MAR1995<br />

03MAR1994<br />

05MAY 1993<br />

03MAY 1995<br />

Page 112 of 176<br />

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9.00E+00<br />

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<strong>4.</strong>60E+01<br />

8.00€+01<br />

2.50E+01<br />

6.50E+Ol<br />

<strong>4.</strong>60E+01<br />

5.60E+01<br />

<strong>4.</strong>90E+Ol<br />

6.80E+01<br />

8.30E+Ol<br />

5.50E+01<br />

2.10E+01<br />

I .40E+01<br />

<strong>4.</strong>80E+01<br />

5.WE+01<br />

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O.OOE+OO<br />

3.10E+01<br />

1.90E+01<br />

2.50E+01<br />

3.70E+01<br />

1 .SOE+Ol<br />

3.00E+01<br />

3.20E+01<br />

3.1OE+O1<br />

2.40€+01<br />

3.20E+01<br />

2.30E+01<br />

2.90E+01<br />

5.00E+00<br />

<strong>4.</strong>00E+00<br />

5.3OE+01<br />

l.OOE+OI<br />

l.OOE+OO<br />

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l.WE+OO<br />

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l.WE+W<br />

I .00E+00<br />

I .00E+00<br />

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l.OOE+OO<br />

I .00E+00<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Strontium 7440-24-6 811-93 04JUN1993 VK 1.00E+00 N mglL<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Titanium<br />

Tianium<br />

Toluene<br />

Toluene<br />

Trans-1.2-Dichloroethene<br />

Trans-1.2-Dichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

cis-1.2-dichloroethene<br />

cis-1.2-diihloroethene<br />

cis-l,2dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2dichloroethene<br />

7440-24-6<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-31 -5<br />

7440-31 -5<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

108-88-3<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

897-94<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1959-92<br />

2208-92<br />

1959-92<br />

2208-92<br />

1004-95<br />

1049-95<br />

1143-95<br />

1841-93<br />

1959-92<br />

21-94<br />

2156-93<br />

2208-92<br />

2267-93<br />

241-94<br />

291-94<br />

417-94<br />

433-95<br />

612-94<br />

884-95<br />

952-95<br />

1959-92<br />

630-93<br />

1200-94<br />

1551-93<br />

16-95<br />

1703-93<br />

1841-93<br />

1959-92<br />

21-94<br />

2132-92<br />

2156-93<br />

2857-94<br />

291-94<br />

433-95<br />

510-94<br />

629-95<br />

630-93<br />

783-95<br />

897-94<br />

952-95<br />

1959-92<br />

630-93<br />

1959-92<br />

2208-92<br />

1959-92<br />

630-93<br />

1959-92<br />

630-93<br />

1004-95<br />

1049-95<br />

1143-95<br />

1219-95<br />

1841-93<br />

21-94<br />

2156-93<br />

2267-93<br />

241-94<br />

291-94<br />

417-94<br />

433-95<br />

OBAPRl994<br />

05NOV1992<br />

O5MAY 1993<br />

05NOV1992<br />

05MAYl993<br />

05NOV1992<br />

OSMAY 1993<br />

05NOV1992<br />

O5MAY 1993<br />

05NOV1992<br />

O5MAY 1993<br />

05NOV1992<br />

16DEC1992<br />

05NOV1992<br />

16DEC1992<br />

OBJUN1995<br />

14JUN1995<br />

06JUL1995<br />

04NOV1993<br />

05NOV1992<br />

05JAN1994<br />

10DEC1993<br />

16DEC1992<br />

3ODEC1993<br />

21 JANl 994<br />

04FEB1994<br />

18FEB1994<br />

03MARl995<br />

17MAR1994<br />

17MAY 1995<br />

01JUNl995<br />

05NOV1992<br />

05MAYl993<br />

05MAY 1994<br />

050CT1993<br />

05JAN1995<br />

220CT1993<br />

04NOV1993<br />

OSNOV1992<br />

05JAN1994<br />

07DEC1992<br />

10DEC1993<br />

02DECl994<br />

04FEB1994<br />

03MAR1995<br />

03MARl994<br />

05APR1995<br />

WAY 1993<br />

03MAY 1995<br />

08APR1994<br />

OlJUNl995<br />

05NOVl992<br />

05MAY1993<br />

05NOV1992<br />

16DECl992<br />

05NOV1992<br />

CHMAY 1993<br />

OLNOV1992<br />

WAY 1993<br />

08JUN1995<br />

14JUN1995<br />

06JUL1995<br />

1 lJULl995<br />

04NOVl993<br />

WAN1 994<br />

10DEC1993<br />

30DEC1993<br />

21 JANl 994<br />

04FEBl994<br />

18FEBl994<br />

03MAR1995<br />

Page 113 of 176<br />

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I<br />

L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

cis-1.2-dichloroethene 156-59-2 510-94 03MAR1994 VK 1.50E+01 N ualL<br />

cis-I ,2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

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156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

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so296<br />

SO296<br />

SO296<br />

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SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

so296<br />

so296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

so296<br />

SO296<br />

629-95<br />

711-95<br />

884-95<br />

952-95<br />

1004-93<br />

1004-95<br />

1025-93<br />

103-95<br />

1045-95<br />

1065-94<br />

1073-95<br />

1119-95<br />

1136-95<br />

1143-95<br />

1200-94<br />

1219-95<br />

1251-94<br />

140-95<br />

1443-93<br />

1517-93<br />

1551-93<br />

1561-94<br />

16-95<br />

1610-94<br />

1636-93<br />

1653-94<br />

1703-93<br />

1713-94<br />

176-95<br />

1777-93<br />

1786-94<br />

1833-94<br />

1841-93<br />

1895-93<br />

1916-94<br />

1967-94<br />

1976-92<br />

2003-93<br />

2022-94<br />

2094-93<br />

21-94<br />

2107-94<br />

2132-92<br />

2156-93<br />

216-95<br />

2187-92<br />

2190-93<br />

2200-94<br />

2220-93<br />

2221-92<br />

2238-92<br />

2248-94<br />

2267-93<br />

2332-94<br />

2409-94<br />

241-94<br />

2476-94<br />

2479-94<br />

255-95<br />

261-94<br />

2615-94<br />

2687-94<br />

2731-94<br />

2768-94<br />

2838-94<br />

2857-94<br />

291-94<br />

2918-94<br />

2987-94<br />

3005-94<br />

301-95<br />

05APR1995<br />

21 APRl995<br />

17MAY 1995<br />

01JUN1995<br />

01 JUL1993<br />

08JUN1995<br />

09JUL1993<br />

13JANl995<br />

13JUN1995<br />

22APR1994<br />

20JUN1995<br />

22JUN1995<br />

26JUN1995<br />

06JUL1995<br />

05MAY1994<br />

llJULl995<br />

13MAY 1994<br />

20JANl995<br />

15SEP1993<br />

28SEPl993<br />

050CT1993<br />

24JUNl994<br />

O5JANl995<br />

01 JULl994<br />

150CT1993<br />

08JULl994<br />

220CT1993<br />

15JUL1994<br />

26JAN1995<br />

280CT1993<br />

22JUL1994<br />

29JUL1994<br />

04NOVI 993<br />

12NOV1993<br />

05AUG1994<br />

lPAUGl994<br />

09NOVl992<br />

24NOV1993<br />

19AUG 1994<br />

OSDECl993<br />

O5JANl 994<br />

26AUG1994<br />

07DEC1992<br />

lODECl993<br />

03FEB1995<br />

14DEC1992<br />

15DECl993<br />

O9SEP1 994<br />

22DEC.1993<br />

21 DECl992<br />

28MC1992<br />

16SEPl994<br />

30DECl993<br />

3OSEPl994<br />

070CT1994<br />

21 JAN1994<br />

140CTI 994<br />

190CT1994<br />

08FEBl995<br />

28JAN1994<br />

28OCT1994<br />

04NOV1994<br />

1 1 NOVl994<br />

17NOV1994<br />

23NOV1994<br />

02DECl994<br />

04FEB1994<br />

08DEC1994<br />

14DECl994<br />

23SEP1994<br />

17FEBl995<br />

Page 114 of 176<br />

Q<br />

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Q<br />

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J<br />

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FIELD<br />

FIELD<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

~~<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

SO296 3087-94 27DEC1994 WL 3.00€+00 su<br />

, SWU 8, C746K-GA2<br />

1 ,I-Dichloroethane<br />

1 .I-Dichloroethene<br />

Aluminum<br />

Antimony<br />

Arsenic<br />

Barium<br />

Benzene<br />

Beryllium<br />

Bismuth<br />

Cadmium<br />

Calcium<br />

Chromium<br />

Coban<br />

Copper<br />

Ethylbenzene<br />

Iron<br />

Lead<br />

Lithium<br />

Magnesium<br />

Manganese<br />

Mercury<br />

Molybdenum<br />

Nickel<br />

Niobium<br />

Phosphorus (P)<br />

Potassium<br />

Ruthenium<br />

Silicon<br />

Silver<br />

Sodium<br />

Strontium<br />

Tantalum<br />

Thallium<br />

Thorium<br />

Tin<br />

litanium<br />

Toluene<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

so296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

SO296<br />

75-34-3<br />

75-35-4<br />

7429-90-5<br />

7440-36-0<br />

7440-38-2<br />

7440-39-3<br />

71 -43-2<br />

7440-41-7<br />

7440-69-9<br />

7440-43-9<br />

7440-70-2<br />

7440-47-3<br />

7440-48-4<br />

7440-50-8<br />

100-41-4<br />

7439-89-6<br />

7439-92-1<br />

7439-93-2<br />

7439-954<br />

7439-96-5<br />

7439-97-6<br />

7439 - 98 - 7<br />

7440-02-0<br />

7440-03-1<br />

7723-14-0<br />

7440-09-7<br />

7440-18-8<br />

7440-21-3<br />

7440-22-4<br />

7440-23-5<br />

7440-24-6<br />

7440-25-7<br />

7440-28-0<br />

7440-29-1<br />

7440-31 -5<br />

7440-32-6<br />

108-88-3<br />

3101-94<br />

369-95<br />

417-94<br />

433-95<br />

453-94<br />

470-95<br />

497-95<br />

510-94<br />

543-95<br />

564-95<br />

612-94<br />

629-95<br />

630-93<br />

632-93<br />

651-93<br />

661-93<br />

666-95<br />

694-94<br />

711-95<br />

728-93<br />

743-95<br />

746-94<br />

783-95<br />

798-93<br />

813-95<br />

845-93<br />

855-93<br />

884-95<br />

897-94<br />

919-95<br />

935-93<br />

936-94<br />

952-95<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

22DEC1994<br />

24FEB1995<br />

18FEBl994<br />

03MAR 1995<br />

25FEB1994<br />

10MAR1995<br />

17MAR1995<br />

03MAR1994<br />

23MAR1995<br />

28MAR1995<br />

17MAR1994<br />

05APR1995<br />

05MAY1993<br />

OBMAYI 993<br />

06MAY 1 993<br />

1 1 MAY 1993<br />

13APR1995<br />

25MAR1994<br />

21APR1995<br />

2lMAY1993<br />

26APR1995<br />

31MAR1994<br />

03MAY 1995<br />

O2JUNl 993<br />

11MAYl995<br />

lOJUN1993<br />

14JUN1993<br />

17MAYI 995<br />

08APRl994<br />

25MAY 1995<br />

23JUN1993<br />

13APRl994<br />

01JUNl995<br />

05NOV1992<br />

05NOVl992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

O5NOVl 992<br />

05NOV1992<br />

05NOV1992<br />

O5NOVl 992<br />

05NOVI992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOVI992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOVI992<br />

05NOV1992<br />

O5NOVl 992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOVl992<br />

Page 115 of 176<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

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WL<br />

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VM<br />

WL<br />

WL<br />

WL<br />

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WL<br />

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WL<br />

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WL<br />

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WL<br />

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VK<br />

VK<br />

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ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

3.00€+00<br />

3.00€+00<br />

3.00€+00<br />

3.OOE+00<br />

3.00E+00<br />

3.00€+00<br />

3.00€+00<br />

3.00€+00<br />

0.00E+00<br />

2.00E+00<br />

3.00€+00<br />

2.00E+00<br />

J.OOE+OO<br />

3.OOE+00<br />

3.00E+00<br />

3.00€+00<br />

2.00E+00<br />

3.00€+00<br />

2.00E+00<br />

3.00€+00<br />

J.OOE+OO<br />

3.00€+00<br />

3.00€+00<br />

3.00€+00<br />

3.00E+00<br />

3.00€+00<br />

2.00E+00<br />

J.OOE+OO<br />

3.00€+00<br />

3.WE+OO<br />

2.00E+00<br />

J.OOE+OO<br />

2.00E+00<br />

5.00€+00<br />

5.WE+OO<br />

2.09€+02<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

5.00€+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

9.90E+01<br />

O.OOE+OO<br />

1.00E+00<br />

0.00E+W<br />

5.00€+00<br />

1.99E+02<br />

0.00E+00<br />

0.00E+00<br />

6.70€+01<br />

9.00E+01<br />

0.00E+00<br />

O.OOE+OO<br />

1.00E+00<br />

0.00E+00<br />

I.WE+OO<br />

5.00E+00<br />

O.WE+OO<br />

8.60€+01<br />

0.00E+W<br />

2.60€+01<br />

1.00E+00<br />

0.00E+W<br />

0.00E+W<br />

0.00E+00<br />

5.00€+00<br />

O.WE+W<br />

5.00€+00<br />

Q<br />

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su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

ug1L<br />

ug1L<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

wfl<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trans-I .2-Dichloroethene 156-60-5 1960-92 05NOV1992 WS 6.00E+00 N uglL<br />

Trichloroethene<br />

Tungsten<br />

Uranium<br />

Vanadium<br />

Xylene<br />

Zinc<br />

Zirconium<br />

PH<br />

WAG 7. SWU 8. C746K-GA3<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 ,I-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1 ,I-Dichloroethene<br />

Acetone<br />

Acetone<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

79-01-6<br />

7440-33-7<br />

7440-61 -1<br />

7440-62-2<br />

1330-20-7<br />

7440-66-6<br />

7440-67-7<br />

SO296<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

67-64-1<br />

67-64-1<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1960-92<br />

1977-92<br />

1961-92<br />

2092-92<br />

2209-92<br />

784-95<br />

1961 -92<br />

2092-92<br />

2209-92<br />

784-95<br />

1442-93<br />

1704-93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2058 - 94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

89594<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631 -93<br />

784-95<br />

799-93<br />

898-94<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

285594<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

05NOV1992<br />

09NOV1992<br />

05NOV1992<br />

30NOV1992<br />

16DEC1992<br />

03MAY 1995<br />

05NOV1992<br />

30NOVf992<br />

16DEC1992<br />

O3MAY 1995<br />

15SEP1993<br />

220CT1993<br />

OSMAYl994<br />

28SEP1993<br />

050CT1993<br />

O5JANl995<br />

04NOV1993<br />

05NOV1992<br />

3ONOV1992<br />

10DEC1993<br />

05JAN1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

19APR1993<br />

05APR1995<br />

(HMAY 1993<br />

03MAY 1995<br />

02 JUN 1993<br />

08APR1994<br />

05NOV1992<br />

30NOV1992<br />

19APR1993<br />

05MAY 1993<br />

05MAY 1994<br />

28SEPl993<br />

050CT1993<br />

05JAN1995<br />

04NOVl993<br />

05NOV1992<br />

3ONOV1992<br />

10DEC1993<br />

05JANl994<br />

02DEC1994<br />

04FEB1994<br />

03MARl995<br />

03MARl994<br />

19APR1993<br />

05APR1995<br />

OsMAY1993<br />

03MAYl995<br />

02JUN1993<br />

08APR1994<br />

OMY 1994<br />

28SEP1993<br />

050CT1993<br />

05JAN1995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

10DEC1993<br />

mAN1994<br />

O2DEC1 994<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

ws<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

\IK<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

WL<br />

VK<br />

VK<br />

VK<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

VK<br />

VK<br />

VK<br />

VK<br />

WL<br />

VK<br />

< N<br />

< N<br />

c<br />

N<br />

N<br />

c<br />

N<br />

N<br />

N<br />

N<br />

c<br />

c<br />

c<br />

c<br />

c<br />

c<br />

X<br />

<<br />

CS<br />

<<br />

<<br />

<<br />

cSJ+<br />

<<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Barium 7440-39-3 292-94 04FEB1994 WL O.OOE+OO N<br />

mglL<br />

Barium<br />

Barium<br />

Barium<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

434-95<br />

511-94<br />

532-93<br />

03MAR1995<br />

03MAR1994<br />

19APR1993<br />

WL<br />

WL<br />

WL<br />

< N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

Barium<br />

7440-39-3<br />

630-95 05APR1995 WL<br />

< N<br />

mglL<br />

Barium<br />

7440-39-3<br />

631-93 O5MAY 1993 WL<br />

<<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

784-95 O3MAY 1995 WL<br />

< N<br />

mglL<br />

Barium<br />

Barium<br />

7440-39-3<br />

7440-39-3<br />

799-93<br />

898-94<br />

02JUN1993<br />

O8APR 1994<br />

WL<br />

WL<br />

< N<br />

N<br />

mglL<br />

mglL<br />

Benzene<br />

71 -43-2<br />

1961 -92 05NOV1992 WL<br />

< N<br />

uglL<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

71 -43-2<br />

71-43-2<br />

74404 -7<br />

7440-47 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440 - 69 - 9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

2092-92<br />

2209-92<br />

1961-92<br />

2092-92<br />

532-93<br />

631 -93<br />

1961 -92<br />

2092-92<br />

532-93<br />

631-93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

953-95<br />

1961-92<br />

2092-92<br />

532-93<br />

631 -93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961 -92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631 -93<br />

784-95<br />

799-93<br />

89894<br />

953-95<br />

3ONOV1992<br />

16DECl992<br />

05NOV1992<br />

30NOV1992<br />

19APR1993<br />

05MAY 1993<br />

05NOV1992<br />

30NOV1992<br />

19APR1993<br />

05MAYl993<br />

05MAY1994<br />

28SEP1993<br />

05OCT1993<br />

%JAN1995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

lODEC1993<br />

05JAN1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

19APR1993<br />

OSAPR1995<br />

(HMAY 1993<br />

03MAY 1995<br />

O2JUNl 993<br />

08APR1994<br />

01 JUN1995<br />

05NOV1992<br />

30NOV1992<br />

19APR1993<br />

05MAY1993<br />

05MAY 1994<br />

28SEP1993<br />

OSOCTl993<br />

05JANl995<br />

04NOVl993<br />

05NOV1992<br />

30NOV1992<br />

10DECl993<br />

05JAN1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

19APR1993<br />

O5APR1995<br />

(HMAY 1993<br />

03MAY1995<br />

OZJUN1993<br />

08APR1994<br />

01 JUN1995<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

VK<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

\M.<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

c<br />

<<br />

<<br />

UD<br />

<<br />

UD<br />

<<br />

<<br />

<<br />

<<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mg1L<br />

Wfl<br />

mgfl<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

W/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Wfl<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

Coban<br />

7440-48-4<br />

1961-92 05NOVl992 WL<br />

N<br />

mgn<br />

Coban<br />

7440-48-4<br />

2092-92 3ONOV1992 WL<br />

N man<br />

Cobalt<br />

Cobalt<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

532-93<br />

631 -93<br />

1961 -92<br />

2092-92<br />

532-93<br />

631-93<br />

19APR1993<br />

OSMAY 1993<br />

05NOVl992<br />

3ONOV1992<br />

19APRI 993<br />

(HMAY 1993<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

WL<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mg/L<br />

mgfl<br />

mgfl<br />

Wfl<br />

mgfl<br />

Page 117 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Estimated Flow EST FLOW 1005-93 OlJUL1993 WL 3.3OE+Ol N GaVDay<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Fbw<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

1005-95<br />

1026-93<br />

104-95<br />

1046-95<br />

1066-94<br />

1074-95<br />

1137-95<br />

1144-95<br />

1201-94<br />

1220-95<br />

1252-94<br />

1290-94<br />

1347-94<br />

141-95<br />

1442-93<br />

1518-93<br />

1552-93<br />

1562-94<br />

1611-94<br />

1637-93<br />

1654-94<br />

17-95<br />

1704-93<br />

1714-94<br />

177-95<br />

177893<br />

1787-94<br />

1834-94<br />

1842-93<br />

1896-93<br />

1917-94<br />

I 96894<br />

2004-93<br />

2023-94<br />

2095-93<br />

2108-94<br />

2120-94<br />

2157-93<br />

217-95<br />

2191-93<br />

22-94<br />

2201-94<br />

2221-93<br />

2249-94<br />

226893<br />

2333-94<br />

2410-94<br />

2477-94<br />

2480-94<br />

256-95<br />

2616-94<br />

2688-94<br />

2732-94<br />

2769-94<br />

2839-94<br />

2858-94<br />

2919-94<br />

292-94<br />

2988-94<br />

3006-94<br />

302-95<br />

3088-94<br />

3102-94<br />

370-95<br />

41894<br />

434-95<br />

454-94<br />

471-95<br />

49895<br />

511-94<br />

544-95<br />

08JUN1995<br />

09JUL1993<br />

13JAN1995<br />

13JUN1995<br />

22APR1994<br />

20JUN1995<br />

26JUN1995<br />

06JUL1995<br />

O5MAY1994<br />

I1 JUL1995<br />

13MAY 1994<br />

19MAY 1994<br />

27MAY 1994<br />

20JAN1995<br />

15SEP1993<br />

28SEP1993<br />

05OCT1993<br />

24JUN1994<br />

OlJULl994<br />

I 5OCT1993<br />

OBJUL1994<br />

05JAN 1995<br />

220CT1993<br />

15JUL1994<br />

26JAN1995<br />

280CT1993<br />

22JUL1994<br />

29JUL1994<br />

04NOVl993<br />

12NOV1993<br />

O5AUG1994<br />

12AUG1994<br />

24NOV1993<br />

19AUGl994<br />

05DEC1993<br />

26AUG1994<br />

02SEPl994<br />

10DEC1993<br />

03FEB1995<br />

15DEC1993<br />

WAN1994<br />

O9SEPl 994<br />

22DEC1993<br />

16SEP1994<br />

30DECl993<br />

30SEPl994<br />

070CT1994<br />

140CT1994<br />

190CT1994<br />

08FEBl995<br />

280CT1994<br />

04NOVl994<br />

IlNOVI994<br />

17NOVI 994<br />

23NOV1994<br />

02DECl994<br />

08DECI994<br />

04FEB1994<br />

14DEC 1994<br />

23SEP1994<br />

17FEB1995<br />

27DEC1994<br />

22DECl994<br />

24FEBl995<br />

18FEB1994<br />

OW1995<br />

25FEB1994<br />

loMAR1995<br />

17MAR1995<br />

OW1994<br />

23MAR1995<br />

Page 118 of 176<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

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Q<br />

Q<br />

Q<br />

Q<br />

Q<br />

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Q<br />

Q<br />

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N<br />

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N<br />

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N<br />

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N<br />

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N<br />

N<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaUDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

Gamy<br />

Gamy


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Estimated Flow EST FLOW 565-95 28MAR1995 WL 2.90E+01 N GaVDay<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Estimated Flow<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

GCNS Scan<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

EST FLOW<br />

100-41-4<br />

10041-4<br />

100-41-4<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCMS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

GCNS SCAN<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439 - 89 - 6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

613-94<br />

630-95<br />

667-95<br />

712-95<br />

744-95<br />

747-94<br />

784-95<br />

814-95<br />

885-95<br />

920-95<br />

953-95<br />

1961 -92<br />

2092-92<br />

2209-92<br />

1005-95<br />

1050-95<br />

1144-95<br />

1220-95<br />

1518-93<br />

1552-93<br />

17-95<br />

2480-94<br />

2769-94<br />

2858-94<br />

2988-94<br />

434-95<br />

498-95<br />

630-95<br />

712-95<br />

784-95<br />

885-95<br />

953-95<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

110-94<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

17MAR1994<br />

05APR1995<br />

13APR1995<br />

2lAPRl995<br />

26APR1995<br />

31MAR1994<br />

O3MAY 1995<br />

1 1 MAY 1995<br />

17MAY 1 995<br />

25MAYl995<br />

01JUN1995<br />

05NOV1992<br />

30NOV1992<br />

16DECl992<br />

08JUN1995<br />

14JUN1995<br />

06JULl995<br />

llJUL1995<br />

28SEP1993<br />

050CT1993<br />

OSJANI 995<br />

190CT1994<br />

17NOV1994<br />

02DECl994<br />

14DECl994<br />

O3MAR 1995<br />

17MARl995<br />

05APRl995<br />

21 APRI 995<br />

03MAY 1995<br />

17MAY1995<br />

01 JUN1995<br />

05MAY1994<br />

28SEPl993<br />

050CT1993<br />

05JAN1995<br />

04NOVI993<br />

OSNOV1992<br />

3ONOV1992<br />

IODEC1993<br />

05JAN1994<br />

02DEC1994<br />

04FEB1994<br />

03MAR1995<br />

03MAR1994<br />

1 9APRI 993<br />

05APRl995<br />

05MAYl993<br />

03MAY 1995<br />

02JUN1993<br />

08APRl994<br />

12JAN1994<br />

05MAYI994<br />

28SEPl993<br />

050CT1993<br />

O5JANl995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

1ODECI 993<br />

05JAN1994<br />

02DECl994<br />

MFEBI 994<br />

03MARl995<br />

03MAR1994<br />

19APR1993<br />

05APRl995<br />

05MAY 1993<br />

03MAYl995<br />

02JUNl993<br />

08APRl994<br />

Page 119 of 176<br />

1.32E+02<br />

2.10E+01<br />

2.40E+01<br />

2.30E+02<br />

9.50E+01<br />

8.20E+01<br />

1.23E+02<br />

6.30E+01<br />

1.02E+02<br />

2.90E+01<br />

<strong>4.</strong>00E+01<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

3.05E+02<br />

3.90E+OI<br />

I.WE+Ol<br />

<strong>4.</strong>30E+01<br />

5.WE+Ol<br />

8.10E+01<br />

9.20E+01<br />

I .49E+02<br />

I.OlE+OZ<br />

2.00E+W<br />

1.04E+02<br />

I .48E+02<br />

I .31E+O2<br />

<strong>4.</strong>75E+02<br />

1.39E+02<br />

2.76E+02<br />

1.59E+02<br />

3.98E+02<br />

1.42E+02<br />

O.WE+OO<br />

5.00E+W<br />

<strong>4.</strong>00E+00<br />

3.00E+00<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

5.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.OOE+OO<br />

9.00E+W<br />

O.WE+W<br />

c<br />

c<br />

<<br />

V<br />

X<br />

X<br />

X<br />

V<br />

V<br />

X<br />

V<br />

V<br />

V<br />

X<br />

X<br />

X<br />

X<br />

X<br />

X<br />

X<br />

X<br />

B<br />

<<br />

<<br />

<<br />

U<br />

<<br />

<<br />

c<br />

<<br />

U<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

Q<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

GaVDay<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

wlL<br />

mgk<br />

WlL<br />

WlL<br />

mgk<br />

wfl<br />

wlL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

wk<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

wfl<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

wfl<br />

mglL<br />

mgfl<br />

wfl<br />

mg/L<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Lead<br />

7439-92-1 953-95 01JUN1995 WL O.OOE+OO N mglL<br />

Lithium<br />

Lithium<br />

Lithium<br />

Lithium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-965<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961 -92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631 -93<br />

784-95<br />

799-93<br />

898-94<br />

1552-93<br />

1961-92<br />

2092-92<br />

532-93<br />

631 -93<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

05NOV1992<br />

30NOV1992<br />

19APRl993<br />

O5MAY 1993<br />

05MAYl994<br />

28SEP1993<br />

050CT1993<br />

O5JANl995<br />

04NOV1993<br />

05NOV1992<br />

3ONOV1992<br />

10DEC1993<br />

05JAN1994<br />

02DEC1994<br />

04FE81994<br />

03MAR1995<br />

03MAR1994<br />

19APR1993<br />

05APRl995<br />

05MAY1993<br />

03MAY 1995<br />

02JUNl993<br />

08APR1994<br />

05MAY1994<br />

28SEP1993<br />

050CT1993<br />

WAN1995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

I ODECl993<br />

WAN1994<br />

02DEC1994<br />

MFEB1994<br />

03MAR1995<br />

03MARl994<br />

19APR 1993<br />

05APR1995<br />

05MAY I 993<br />

03MAY 1995<br />

O2JUNI 993<br />

08APRl 994<br />

050CTl993<br />

05NOVl992<br />

3ONOV1992<br />

19APR1993<br />

05MAY 1993<br />

05NOV1992<br />

30NOV1992<br />

19APR1993<br />

osMAY1993<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

8.10E+01<br />

<strong>4.</strong>70E+01<br />

<strong>4.</strong>60E+01<br />

6.70E+01<br />

3.20E+01<br />

5.00E+01<br />

7.60E+01<br />

7.00E+01<br />

7.40E+01<br />

<strong>4.</strong>10E+01<br />

7.40E+01<br />

9.00E+01<br />

7.70E+01<br />

9.10E+01<br />

7.80E+01<br />

6.60E+01<br />

7.50E+01<br />

1.40E+02<br />

<strong>4.</strong>10E+01<br />

1.69E+02<br />

5.90E+01<br />

5.70E+01<br />

8.70E+01<br />

<strong>4.</strong>10E+01<br />

6.80E+Ol<br />

1.1 IE+OZ<br />

9.20E+01<br />

9.80E+01<br />

<strong>4.</strong>90E+01<br />

9.60E+01<br />

9.3OE+01<br />

1.03E+02<br />

1.31 E+02<br />

9.60E+01<br />

8.70E+01<br />

8.1OE+Ol<br />

1.87E+02<br />

<strong>4.</strong>30E+01<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

Nickel<br />

7440-02-0<br />

1201-94 W Y 1994 1 .WE+00<br />

N<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Niobium<br />

Niobium<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

1961-92<br />

2092-92<br />

28SEP1993<br />

050CT1993<br />

WAN1995<br />

MNOV1993<br />

05NOV1992<br />

3ONOV1992<br />

lODECl993<br />

WAN1994<br />

02DEC1994<br />

MFEB1994<br />

03MARl995<br />

03MARl994<br />

19APR1993<br />

05MAY 1993<br />

03MAY 1995<br />

02JUNl993<br />

08APR1994<br />

05NOV1992<br />

30NOV1992<br />

O.WE+W<br />

O.WE+OO<br />

O.WE+W<br />

O.OOE+W<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

1 .WE+00<br />

O.WE+W<br />

O.WE+W<br />

1 .WE+00<br />

O.OOE+W<br />

O.OOE+W<br />

O.WE+W<br />

J<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 120 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Niobium 7440-03-1 532-93 19APR1993 WL O.OOE+OO < N mg1L<br />

Niobium<br />

PCB<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Alpha<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Rad Beta<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silicon<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

7440-03-1<br />

1336-36-3<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

12587-46-1<br />

12587-46-1<br />

12587-461<br />

12587-46-1<br />

12587-46-1<br />

12587-46-1<br />

1258747-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

12587-47-2<br />

1258747-2<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21 -3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

631-93<br />

2133-92<br />

1961 -92<br />

2092-92<br />

532-93<br />

631-93<br />

1201-94<br />

I 518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961 -92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

1144-95<br />

434-95<br />

630-95<br />

784-95<br />

799-93<br />

953-95<br />

1144-95<br />

434-95<br />

630-95<br />

784-95<br />

799-93<br />

953-95<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1201-94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

05MAY 1993<br />

07DEC1992<br />

05NOVI 992<br />

30NOV1992<br />

19APR 1993<br />

05MAY1993<br />

O5MAY 1994<br />

28SEP1993<br />

05OCTl 993<br />

05JAN1995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

10DEC1993<br />

05JAN1994<br />

02DEC1994<br />

04FEBl994<br />

03MARl995<br />

03MARl994<br />

19APR1993<br />

05APR1995<br />

O5MAY 1993<br />

03MAY 1995<br />

02JUN1993<br />

08APR1994<br />

06JUL1995<br />

03MAR1995<br />

05APRI995<br />

03MAY1995<br />

O2JUNl 993<br />

01 JUNl995<br />

06JULl995<br />

O3MARl 995<br />

05APR1995<br />

03MAY 1995<br />

02JUN1993<br />

01JUN1995<br />

05NOV1992<br />

3ONOV1992<br />

19APR1993<br />

05MAY1993<br />

(HMAY 1994<br />

28SEPl993<br />

050CTl993<br />

05JANl995<br />

04NOV1993<br />

05NOV1992<br />

JONOVI992<br />

IODECI 993<br />

05JAN1994<br />

02DECl994<br />

04FEB1994<br />

03MAR1995<br />

03MAR 1994<br />

19APR1993<br />

05APRl995<br />

OSMAY 1993<br />

03MAY I995<br />

02JUN1993<br />

08APR1994<br />

05NOV1992<br />

3ONOV1992<br />

19APRl993<br />

(HMAY 1993<br />

(HMAY 1994<br />

28SEP1993<br />

050CT1993<br />

05JANl995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

Page 121 of 176<br />

WL<br />

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WL<br />

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WL<br />

WL<br />

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VK<br />

WL<br />

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WL<br />

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VK<br />

WL<br />

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N<br />

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N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Sodium 7440-23-5 2157-93 10DEC1993 WL 3.40E+01 N mglL<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium<br />

Tantalum<br />

Tantalum<br />

Tantalum<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Thorium<br />

Tin<br />

Tin<br />

Tin<br />

Tin<br />

Titanium<br />

Titanium<br />

Titanium<br />

Titanium<br />

Toluene<br />

To I u e n e<br />

Toluene<br />

Trans-I ,2-Dichloroethene<br />

Trans-I .2-Dichloroethene<br />

Trans-I ,2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichkroethene<br />

Trichloroethene<br />

Trichbroethene<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-25-7<br />

7440-25-7<br />

7440-25-7<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-31-5<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

7440-32-6<br />

108-88-3<br />

loa-88-3<br />

I 08-88-3<br />

156-60-5<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

799-93<br />

898-94<br />

1201 -94<br />

1518-93<br />

1552-93<br />

17-95<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2858-94<br />

292-94<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631 -93<br />

784-95<br />

799-93<br />

898-94<br />

1961-92<br />

532-93<br />

631-93<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1961 -92<br />

2092-92<br />

532-93<br />

631 -93<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1961-92<br />

2092-92<br />

2209-92<br />

1961-92<br />

2092-92<br />

2209-92<br />

1050-95<br />

1066-94<br />

1144-95<br />

1201-94<br />

1704-93<br />

1842-93<br />

1961-92<br />

2092-92<br />

2157-93<br />

22-94<br />

2209-92<br />

2268-93<br />

242-94<br />

292-94<br />

418-94<br />

434-95<br />

OSJANI 994<br />

02DECl994<br />

04FEBI 994<br />

O3MARl 995<br />

03MAR1994<br />

19APR1993<br />

DSAPR 1995<br />

05MAY1993<br />

03MAY 1995<br />

02JUN1993<br />

08APR1994<br />

OSMAY 1994<br />

28SEP1993<br />

050CT1993<br />

OSJANl995<br />

04NOV1993<br />

05NOV1992<br />

30NOV1992<br />

10DECl993<br />

OSJANI994<br />

02DEC1994<br />

04FEB1994<br />

03MARl995<br />

03MAR1994<br />

19APRl993<br />

05APR 1995<br />

OSMAY 1993<br />

03MAY 19%<br />

02JUN1993<br />

08APR1994<br />

05NOV1992<br />

19APR1993<br />

WAY1993<br />

05NOV1992<br />

3ONOVI 992<br />

19APR 1993<br />

WAY 1993<br />

05NOVI992<br />

30NOV1992<br />

19APRl993<br />

OSMAY1993<br />

05NOV1992<br />

30NOV1992<br />

19APRl993<br />

WAY1993<br />

OSNOV1992<br />

30NOV1992<br />

19APR1993<br />

05MAY1993<br />

05NOV1992<br />

3ONOVl992<br />

16DECl992<br />

OSNOV1992<br />

3ONOV1992<br />

16DECl992<br />

14JUN1995<br />

22APR1994<br />

06JULl995<br />

05MAY 1994<br />

220CT1993<br />

04NOV1993<br />

05NOV1992<br />

3ONOV1992<br />

lODECl993<br />

05JAN1994<br />

16DEC1992<br />

3ODECl993<br />

21 JAN1 994<br />

04FEB1994<br />

18FEB1994<br />

03MARl995<br />

Page 122 of 176<br />

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mglL<br />

mglL<br />

mglL<br />

mg/L<br />

wlL<br />

wlL<br />

mglL<br />

mglL<br />

w5<br />

mglL<br />

WlL<br />

wlL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

wlL<br />

WlL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mg1L<br />

wlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgIL<br />

mg/L<br />

mglL<br />

mglL<br />

WlL<br />

uglL<br />

w3R<br />

ugfl<br />

uglL<br />

uglL<br />

ug1L<br />

ug5<br />

uglL<br />

wfl<br />

uglL<br />

uglL<br />

Wfl<br />

uglL<br />

ugfl<br />

ug5<br />

uglL<br />

ug1L<br />

uglL<br />

w5<br />

uglL<br />

UgR<br />

w35


~~<br />

L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trichloroethene 79-01-6 511-94 03MAR1994 VK l.OOE+OO N uglL<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Tungsten<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-33-7<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

613-94<br />

630-95<br />

712-95<br />

784-95<br />

885-95<br />

898-94<br />

953-95<br />

1961-92<br />

2092-92<br />

532-93<br />

631 -93<br />

1201-94<br />

1552-93<br />

17-95<br />

1704-93<br />

1842-93<br />

1961-92<br />

2092-92<br />

17MAR1994<br />

O5APRl 995<br />

21APR1995<br />

03MAYl995<br />

17MAYl995<br />

08APR1994<br />

01JUN1995<br />

05NOVl992<br />

30NOV1992<br />

19APR1993<br />

05MAY 1993<br />

05MAY 1994<br />

050CT1993<br />

05JAN1995<br />

220CT1993<br />

04NOV1993<br />

05NOV1992<br />

3ONOV1992<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

UglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Uranium<br />

Uranium<br />

7440-61-1<br />

7440-61 -1<br />

2133-92<br />

2157-93<br />

07DEC1992<br />

lODEC1993<br />

N<br />

N<br />

w/L<br />

mglL<br />

Uranium<br />

7440-61 -1<br />

22-94 OSJAN1994<br />

N<br />

mglL<br />

Uranium<br />

7440-61-1<br />

2858-94 02DECl994<br />

N<br />

mglL<br />

Uranium<br />

7440-61 - 1<br />

292-94 04FEB1994<br />

N<br />

mglL<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

Zirconium<br />

cis-1.2-dichloroethene<br />

cis-I ,2dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-l,2dichloroethene<br />

cis-1.2dichloroethene<br />

cis-l,2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-I .2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-1.2-dichloroeihene<br />

cis-1.2-dichloroethene<br />

cis-I ,2-dichloroethene<br />

cis-1.2dichloroethene<br />

cis-1.2dichloroethene<br />

cis-l,2-dichloroethene<br />

cis-I .2dichloroethene<br />

cis-1.2-dichloroethene<br />

cis-I ,2dichloroethene<br />

cis-I .2-dichloroethene<br />

cis-I .2dichloroethene<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

15659-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

156-59-2<br />

434-95<br />

511-94<br />

532-93<br />

630-95<br />

631-93<br />

784-95<br />

898-94<br />

953-95<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1961-92<br />

2092-92<br />

2209-92<br />

1961-92<br />

2092-92<br />

532-93<br />

631-93<br />

1961-92<br />

2092-92<br />

532-93<br />

631 -93<br />

1050-95<br />

1066-94<br />

1144-95<br />

1201-94<br />

1220-95<br />

1290-94<br />

1704-93<br />

1842-93<br />

2157-93<br />

22-94<br />

2268-93<br />

242-94<br />

292-94<br />

418-94<br />

434-95<br />

511-94<br />

613-94<br />

630-95<br />

712-95<br />

784-95<br />

885-95<br />

898-94<br />

03MARl995<br />

03MAR1994<br />

19APR1993<br />

05APR1995<br />

05MAYl993<br />

03MAY1995<br />

08APR1994<br />

01 JUN1995<br />

05NOVI992<br />

30NOV1992<br />

19APR1993<br />

05MAY 1993<br />

05NOV1992<br />

30NOV1992<br />

16DEC1992<br />

05NOV1992<br />

3ONOV1992<br />

19APRl993<br />

05MAY1993<br />

05NOV1992<br />

30NOV1992<br />

19APR1993<br />

05MAY1993<br />

1 AIUN1995<br />

22APR1994<br />

06JUL1995<br />

05MAY 1994<br />

11 JULl995<br />

19MAY 1994<br />

220CT1993<br />

04NOVl993<br />

lODECl993<br />

05JAN1994<br />

3ODEC1993<br />

21 JAN1 994<br />

04FEB1994<br />

18FEB1994<br />

03MARl995<br />

03MAR1994<br />

17MAR1994<br />

OSAPR1995<br />

21 APRl995<br />

03MAY 1995<br />

17MAY 1995<br />

08APRl994<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

Q<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg5<br />

ug1L<br />

uglL<br />

uglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

ug1L<br />

ugfl<br />

ugfl<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

cis-1.2dichloroethene 156-59-2<br />

953-95 OlJUNl995<br />

N<br />

uglL<br />

PH<br />

so296<br />

1005-93 OlJULl993<br />

N su<br />

PH<br />

SO296<br />

1005-95 08JUN1995<br />

su<br />

Page 123 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DAE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

DH SO296 1026-93 09JUL1993 WL 3.00E+00 N su<br />

SO296<br />

104-95 13JANl995<br />

su<br />

so296<br />

1046-95 13JUN1995<br />

su<br />

SO296<br />

1066-94 22APR1994<br />

su<br />

SO296<br />

1074-95 20JUN1995<br />

su<br />

SO296<br />

1137-95<br />

26JUN1995<br />

su<br />

SO296<br />

1144-95 06JUL1995<br />

su<br />

SO296<br />

1201 -94 05MAY 1994<br />

su<br />

SO296<br />

1220-95 llJUL1995<br />

su<br />

SO296<br />

1252-94 13MAY 1994<br />

su<br />

SO296<br />

1290-94 19MAY 1994<br />

su<br />

so296<br />

1347-94 27MAY 1994<br />

su<br />

SO296<br />

141-95 2OJANl995<br />

Q<br />

N su<br />

SO296<br />

1442-93 15SEP1993<br />

N su<br />

SO296<br />

1518-93<br />

28SEP1993<br />

su<br />

SO296<br />

1552-93 050CT1993<br />

su<br />

SO296<br />

1562-94 24JUNI 994<br />

Q FIELD su<br />

SO296<br />

1611-94 01 JULl994<br />

Q FIELD su<br />

SO296<br />

1637-93 150CTl993<br />

su<br />

SO296<br />

1654-94 08JUL1994<br />

Q<br />

su<br />

so296<br />

17-95 OBJANl995<br />

su<br />

SO296<br />

1704-93 220CT1993<br />

su<br />

so296<br />

1714-94 15JUL1994<br />

Q<br />

su<br />

SO296<br />

177-95 26JAN1995<br />

su<br />

so296<br />

1778-93 280CT1993<br />

su<br />

SO296<br />

1787-94 22JULl994<br />

Q<br />

su<br />

SO296<br />

1834-94 29JULl994<br />

Q<br />

su<br />

SO296<br />

f842-93 04NOW993<br />

su<br />

so296<br />

1896-93 12NOV1993<br />

su<br />

SO296<br />

1917-94 05AUG1994<br />

Q<br />

su<br />

so296<br />

1968-94 12AUGl994<br />

Q<br />

su<br />

SO296<br />

1978-92 09NOV1992<br />

N su<br />

SO296<br />

200493 24NOV1993<br />

su<br />

SO296<br />

2023-94 19AUG1994<br />

Q<br />

su<br />

SO296<br />

2092-92 30NOV1992<br />

N su<br />

so296<br />

2095-93 OSDEC1993<br />

su<br />

so296<br />

2108-94<br />

26AUG1994<br />

Q<br />

su<br />

so296<br />

2133-92 07DEC1992<br />

N su<br />

so296<br />

2157-93 10DEC1993<br />

su<br />

so296<br />

217-95 03FEB1995<br />

Q<br />

N su<br />

so296<br />

2188-92 14DECl992<br />

N su<br />

so296<br />

2191 -93 15DEC1993<br />

su<br />

so296<br />

22-94 05JAN1994<br />

su<br />

so296<br />

2201-94 09SEPl994<br />

Q<br />

su<br />

so296<br />

2221-93 22DEC1993<br />

J<br />

su<br />

so296<br />

2222-92 21DECl992<br />

N su<br />

so296<br />

2239-92 28DEC1992<br />

N su<br />

so296<br />

2249-94 16SEPl994<br />

Q FIELD su<br />

so296<br />

2268-93 30DECl993<br />

su<br />

SO296<br />

2333-94 3OSEPl994<br />

Q FIELD su<br />

so296<br />

2410-94 070CT1994<br />

Q<br />

N su<br />

so296<br />

242-94 21JAN1994<br />

su<br />

SO296<br />

2477-94 140CT1994<br />

Q<br />

N su<br />

SO296<br />

2480-94 190CTl994<br />

su<br />

so296<br />

256-95 08FEBl995<br />

su<br />

so296<br />

2616-94 280CT1994<br />

Q<br />

N su<br />

SO296<br />

262-94 28JAN1994<br />

su<br />

so296<br />

2688-94 04NOV1994<br />

Q<br />

N su<br />

so296<br />

2732-94 11 NOVI 994<br />

su<br />

so296<br />

2769-94 17NOV1994<br />

su<br />

so296<br />

2839-94 23NOV1994<br />

su<br />

so296<br />

2858-94 02DEC1994<br />

su<br />

so296<br />

2919-94 08DECl994<br />

su<br />

SO296<br />

292-94 04FEB1994<br />

su<br />

so296<br />

2988-94 14DEC1994<br />

su<br />

SO296<br />

3006-94 23SEPl994<br />

Q FIELD su<br />

so296<br />

302-95 17FEBl995<br />

Q<br />

N su<br />

so296<br />

3088-94 27DECl994<br />

su<br />

SO296<br />

3102-94 22DECl994<br />

su<br />

so296<br />

370-95 24FEBl995<br />

su<br />

so296<br />

418-94 18FEBl994<br />

su<br />

so296<br />

434-95 OJMAR1995<br />

su<br />

Page 124 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

DH SO296 454-94 25FEB1994 WL 3.00E+00 su<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SVMU 8, H216<br />

1 ,I,I-Trichloroelhane<br />

1 .I.I-Trichloroethane<br />

1 ,I.I-Trichloroethane<br />

1 .l.l-Trichloroethane<br />

1 ,I,I-Trichloroelhane<br />

1 .I,l-Trichloroethane<br />

1.1 .I-Trichloroethane<br />

I,l,l-Trichloroethane<br />

1 .I.I-Trichloroethane<br />

1 .I.2,2-TetrachloroeIhane<br />

1 ,I.2.2-TeIrachloroelhane<br />

1 ,I,2,2-Tetrachloroelhane<br />

l11,2,2-Tetrachloroethane<br />

1 .I.2.2-Tetrachloroethane<br />

1 .I,2.2-TetrachloroeIhane<br />

1 ,I.2,2-Tetrachloroethane<br />

1 ,I.2.2-Telrachloroethane<br />

1 .I,2.2-Telrachloroethane<br />

1 ,I.2-Trichloroelhane<br />

1 .I.2-Trichloroethane<br />

I .I,2-Trichloroethane<br />

I .1.2-Trichloroethane<br />

1 .I,2-Trichloroelhane<br />

1.1.2-Trichloroelhane<br />

I .I.2-Trichloroethane<br />

1 ,I.2-Trichloroethane<br />

1 ,I.2-Trichloroethane<br />

1 .I-Dichloroethane<br />

I .I-Dichloroethane<br />

1 ,I-Dichloroelhane<br />

1 .I-Dichloroelhane<br />

I ,l-Dichloroelhane<br />

1 .I-Dichloroelhane<br />

1 .I-Dichloroethane<br />

1 .I-Dichloroethane<br />

I ,I-Dichloroethane<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroelhene<br />

1 ,l-Dichloroelhene<br />

1 ,I-Dichloroethene<br />

1,l-Dichloroelhene<br />

1 ,l-Dichloroethene<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

71 -55-6<br />

71-55-6<br />

71-55-6<br />

71 -55-6<br />

71-55-6<br />

71-55-6<br />

71-55-6<br />

71-55-6<br />

71-55-6<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-00-5<br />

79-00-5<br />

79-00-5<br />

79-00-5<br />

79-00-5<br />

79-00-5<br />

7 9 - 0 0 - 5<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

471-95<br />

498-95<br />

51 1-94<br />

544-95<br />

565-95<br />

613-94<br />

630-95<br />

631-93<br />

633-93<br />

652-93<br />

662-93<br />

667-95<br />

695-94<br />

71 2-95<br />

729-93<br />

744-95<br />

747-94<br />

784-95<br />

799-93<br />

814-95<br />

846-93<br />

856-93<br />

885-95<br />

898-94<br />

920-95<br />

936-93<br />

937-94<br />

953-95<br />

CH2 13145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH2I 3161 -00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213I 56-00000<br />

CH213157-00000<br />

CH213158-OOWO<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH2 13162-OoM)O<br />

(31-1213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00OOO<br />

CH213158-00000<br />

CH2I 3159-00000<br />

CH213160-DUP<br />

CH2I 3161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH21316DDUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CHZ13155-00000<br />

CH21 3156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159M1000<br />

10MAR1995<br />

17MAR1995<br />

03MAR1994<br />

23MARl995<br />

28MAR1995<br />

17MAR 1994<br />

05APR 1 995<br />

05MAY 1993<br />

OSMAY 1993<br />

06MAY 1993<br />

1 1 MAY 1993<br />

13APR1995<br />

25MAR 1994<br />

2lAPRl995<br />

21MAYl993<br />

26APRl995<br />

31 MAR1 994<br />

O3MAY 1 995<br />

O2JUNl 993<br />

llMAYl995<br />

I OJUNI 993<br />

14JUN1993<br />

17MAY1995<br />

08APR1994<br />

25MAY1995<br />

23JUN 1993<br />

13APRl994<br />

01JUNl995<br />

18FEBl991<br />

18FEBl991<br />

1 8FEBI 991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBI 991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

Page 125 of 176<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

1 ,l-Dichloroethene 75-35-4 CH213160-DUP 18FEB1991 SO 6.00E+00 U N<br />

1 ,l-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1,2,4-Trichlorobenzene<br />

1,2,4-Trichlorobenzene<br />

1.2 ,4-Trichlorobenzene<br />

1,2,4-Trichlorobenzene<br />

1,2 ,+Trichlorobenzene<br />

1.2.4-Trichlorobenzene<br />

1,2,4-Trichlorobenzene<br />

1,2.4-Trichlorobenzene<br />

1 .2,4-Trichlorobenzene<br />

1,2-Dichlorobenzene<br />

1,2-Dichlorobenzene<br />

1,2-DichIorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichlorobenzene<br />

1,2-Dichlorobenzene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

1,2-Dichloroethane<br />

1,2-Dichloroethane<br />

1 .Z-Dchloroethane<br />

1,2-Dichloroethane<br />

1,2-Dichloroethane<br />

1,2-Dchloroethene<br />

1,2-Dchloroethene<br />

1.2-Dichloroethene<br />

1.2-Dichloroethene<br />

1.2-Dichloroethene<br />

1,2-DichIoroethene<br />

1,2-Dichloroethene<br />

1.2-Dichloroethene<br />

1.2-Dchloroethene<br />

1.2-Dichloropropane<br />

1.2-Dichloropropane<br />

1.2-Dichloropropane<br />

1.2-Dchloropropane<br />

1.2-Dichloropropane<br />

1.2-Dichloropropane<br />

1.2-Dichloropropane<br />

1 ,Z-Dichloropropane<br />

1.2-Dichloropropane<br />

1 ,fDichlorobenzene<br />

1,3-Dichlorobenzene<br />

1,3-Dichlorobenzene<br />

1 ,3-Dchlorobenzene<br />

1,3-Dichlorobenzene<br />

1,3-Dchlorobenzene<br />

1,3-Dichlorobenzene<br />

1.3-Dichlorobenzene<br />

1 ,J-Dichlorobenzene<br />

1 ,+Dichlorobenzene<br />

1 .4-Dchbrobenzene<br />

1 ,CDichlorobenzene<br />

1 .CDichlorobenzene<br />

1 .4-Dchlorobenzene<br />

1 ,+Dichlorobenzene<br />

1 A-Dchbrobenzene<br />

1.4-Dichlorobenzene<br />

1,4-Dchbrobenzene<br />

2.4,5-TrichlorophenoI<br />

2,4,5-TrichlorophenoI<br />

2,4,!LTrichlorophenoI<br />

2.<strong>4.</strong>5-Trichlorophenol<br />

2.<strong>4.</strong>5-Trichlorophenol<br />

2,<strong>4.</strong>5-Trichlorophenol<br />

75-35-4<br />

75-35-4<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

541-73-1<br />

541-73-1<br />

541 -73-1<br />

541 -73-1<br />

541-73-1<br />

541-73-1<br />

541-73-1<br />

541-73-1<br />

541-73-1<br />

106-46-7<br />

106-46-7<br />

106-46-7<br />

106-46-7<br />

106-46-7<br />

10646-7<br />

106-46-7<br />

106-46-7<br />

106-46-7<br />

95-95-4<br />

959%<br />

95-95-4<br />

95-95-4<br />

95-95-4<br />

95-95-4<br />

CH213161-00000<br />

CH213162-00000<br />

CH21 3145-00000<br />

CH213155-00000<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-M)000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH21 3161-00000<br />

CH2I 3162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OW00<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-OOOOO<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OOOW<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CHZl3162-ooMx)<br />

CH213145-00000<br />

CH213155-00000<br />

CHZl3156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2I 3159-00000<br />

CH2131 60-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156MH)oo<br />

CH213157-00000<br />

CH21315a00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

1 8FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

l8FEBl991<br />

18FEB1991<br />

I8FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

1 LIFE61 991<br />

18FEB1991<br />

CH213162-00000 18FEBl991<br />

CH2 13145-OO~ 18FEBl991<br />

CH213155-00000 18FEBl991<br />

CHZl3156-OooOO 18FEB1991<br />

CHZl3157-00000 18FEBl991<br />

CHZl31 sa00000 18FEBl991<br />

CH213159M)ooo 18FEBl991<br />

CH2131 60-DUP 18FEB1991<br />

CH213161 MH)oo 18FEB1991<br />

CH213162-OOOOO 18FEB1991<br />

CH21314!5-0OOOO 18FEB1991<br />

CH213155-00000 18FEB1991<br />

CH213156-00000 18FEB1991<br />

CH213157-00000 18FEB1991<br />

CH213158-00000 18FEB1991<br />

CH213159-00000 18FEB1991<br />

Page 126 of 176<br />

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N<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

2,4,5-Trichlorophenol 95-95-4 CH213160-DUP 18FEB1991 SO 2.00E+03 U N ugh<br />

2,4,5-Trichlorophenol<br />

2,4,5-Trichlorophenol<br />

2,4,6-Trichlorophenol<br />

2,4,6-Trichlorophenol<br />

2,4,6-TrichlorophenoI<br />

2,4,6-Trichlorophenol<br />

2,4,6-Trichlorophenol<br />

2,4,6-Trichlorophenol<br />

2.4,6-TrichlorophenoI<br />

2,<strong>4.</strong>6-TrichlorophenoI<br />

2,<strong>4.</strong>6-Trichlorophenol<br />

2.4-Dichlorophenol<br />

2,4-Dichlorophenol<br />

2 ,CDichlorophenol<br />

2.4-Dichlorophenol<br />

2,4-Dichlorophenol<br />

2,CDichlorophenol<br />

2.4-Dichlorophenol<br />

2.4-Dichlorophenol<br />

2,4-Dichlorophenol<br />

2.4-Dimethylphenol<br />

2,4-Dimethylphenol<br />

2.4-Dimethylphenol<br />

2.4-Dimethylphenol<br />

2 ,4-Dimethylphenol<br />

2,4-Dimethylphenol<br />

2 ,4-Dimethylphenol<br />

2,4Dimethylphenol<br />

2.4-Dimethylphenol<br />

2 ,4-Dinitrophenol<br />

2,CDinilrophenol<br />

2 ,+Dinitrophenol<br />

2.4-Dinitrophenol<br />

2 +Dinitrophenol<br />

2,4-Dinitrophenol<br />

2,4-Dinitrophenol<br />

2 ,&Dinitrophenol<br />

2,4-Dinitrophenol<br />

2,CDinitrotoluene<br />

2 +Dinitrotoluene<br />

2 ,&Dinitrotoluene<br />

2 .4-Dinitrotoluene<br />

2 ,4-Dinitrotoluene<br />

2,CDinitrotoluene<br />

2.4-Dinitrotoluene<br />

2 ,4-Dinitrotoluene<br />

2 .4-Dinitrotoluene<br />

2 ,B-DinitrotoIuene<br />

2.6-Dinitrotoluene<br />

2,6-Dinitrotoluene<br />

2.6-Dinitrotoluene<br />

2,6-Dinitrotoluene<br />

2,6-Dinitrotoluene<br />

2,6-Dinitrotoluene<br />

2.6-Dinitrotoluene<br />

2.6-Dinitrotoluene<br />

2-Butanone<br />

2-Butanone<br />

2-Butanone<br />

2-Butanone<br />

95-95-4<br />

95-95-4<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

120-83-2<br />

105-67-9<br />

105-67-9<br />

105-67-9<br />

10547-9<br />

105-67-9<br />

105-67-9<br />

105-67-9<br />

105-67-9<br />

105-67-9<br />

51-28-5<br />

51-28-5<br />

51-28-5<br />

51-28-5<br />

51-28-5<br />

51-28-5<br />

51-285<br />

51-28-5<br />

51-28-5<br />

121-14-2<br />

121 -14-2<br />

121 -14-2<br />

121-14-2<br />

121-14-2<br />

121 -14-2<br />

121-14-2<br />

121 -14-2<br />

121 -14-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

78-93-3<br />

78-93-3<br />

78-93-3<br />

7893-3<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH2 13161 -00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-OOOOO<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-OOOoO<br />

CH2I 3155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-0oooO<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213I 45-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-OOMM<br />

CH213162-00000<br />

CH213145-M)000<br />

CH2 13155-OOOOO<br />

CH213156-OOOOO<br />

CH213157-00000<br />

CH213158-WWO<br />

CH213159-00000<br />

CH213160-DUP<br />

CH2I 3161 -0oooO<br />

CH213162-00000<br />

CH213145-00000<br />

CH21 3155-00000<br />

CH213156-00000<br />

CH213157-OOOOO<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

U<br />

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2-Butanone<br />

78-93-3<br />

CH213158-~0 18FEB1991<br />

U<br />

N<br />

2 -But anon e<br />

2-Butanone<br />

2-Butanone<br />

2-Butanone<br />

2-Chloronaphthalene<br />

2-Chloronaphthalene<br />

2-Chloronaphlhalene<br />

2-Chloronaphthalene<br />

2-Chloronaphthalene<br />

2-Chloronaphthalene<br />

78-93-3<br />

78-93-3<br />

78-93-3<br />

78-93-3<br />

91-58-7<br />

91-587<br />

91-587<br />

91 -58-7<br />

91-58-7<br />

91-587<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-WOW<br />

CH213157-00000<br />

CH21315B00000<br />

CH213159-00000<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

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N<br />

Page 127 of 176<br />

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so<br />

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so<br />

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so<br />

so


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

2-Chloronaphthalene 91-58-7 CH213160-DUP 18FEB1991 SO 3.90E+02 U N<br />

2-Chloronaphthalene<br />

2-Chloronaphthalene<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Meth ylnaphthalene<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Meth ylphenol<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

3.3-Dichlorobenzidine<br />

3,3-Dihlorobenzidine<br />

3.3-Dichlorobenzidine<br />

3,3-Dihlorobenzidine<br />

3.3-Dihlorobenzidine<br />

3.3-Dichlorobenzidine<br />

3.3-Dihlorobenzidine<br />

3,3’-Dichlorobenzidine<br />

3,3’-Dichlorobenzidine<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

91 -58-7<br />

91 -58-7<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

591 -78-6<br />

591-78-6<br />

591 -78-6<br />

591-78-6<br />

591 -78-6<br />

591-78-6<br />

591 -78-6<br />

591-78-6<br />

591-78-6<br />

91 -57-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

88-744<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

88-75-5<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

91-94-1<br />

99-09-2<br />

99-09-2<br />

99-09-2<br />

99-09-2<br />

99-09-2<br />

99-09-2<br />

CH213161-00000<br />

CH213162-OOOOO<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-OOOOO<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-OoooO<br />

CHZ13160-DUP<br />

CH213161-00000<br />

CH213162-OOOOO<br />

CH2 13145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2I 3159-00000<br />

CH2I 3160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-OOOOO<br />

CH213156-OoooO<br />

CH213157-OoooO<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-OoooO<br />

CH213155-ooOOO<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2 13159-ooOOO<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-OOOOO<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-OoooO<br />

CH2 13145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-WOO0<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

1 BFEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBI 991<br />

1 OFEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

I8FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

Page 128 of 176<br />

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3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>1 OE+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

6.50E+01<br />

1.20E+01<br />

1.20E+01<br />

l.lOE+Ol<br />

1.2OE+O1<br />

l.lOE+Ol<br />

1.20E+01<br />

1.20E+01<br />

1.20E+01<br />

l.lOE+Ol<br />

3.90E+02<br />

<strong>4.</strong>1 OE+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

2.00E+03<br />

2.10E+03<br />

2.00E+O3<br />

1.80E+O3<br />

1.90E+03<br />

2.00E+03<br />

2.00E+03<br />

1.90E+03<br />

I .90E+O3<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70€+02<br />

<strong>4.</strong>00E+02<br />

3.9OE+02<br />

3.90E+02<br />

3.90E+02<br />

7.80E+02<br />

8.20E+02<br />

8.20E+02<br />

7.30E+02<br />

7.40E+02<br />

8.1 OE+02<br />

7.80E+02<br />

7.80E+02<br />

7.80E+02<br />

2.00E+O3<br />

2.1OE+O3<br />

2.00E+03<br />

1.80E+O3<br />

I .90E+03<br />

2.00E+03<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

3-Nitroaniline 99-09-2 CH213160-DUP 18FEB1991 SO 2.00E+03<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

4,4-DDD<br />

4,4-DDD<br />

<strong>4.</strong>4-DDD<br />

<strong>4.</strong>4-DDD<br />

4,4-DDD<br />

4,4-DDD<br />

4,4-DDD<br />

<strong>4.</strong>4-DDD<br />

4,4-DDD<br />

4,4-DDE<br />

4,4-DDE<br />

<strong>4.</strong>4-DDE<br />

4,4-DDE<br />

<strong>4.</strong>4-DDE<br />

4,4-DDE<br />

<strong>4.</strong>4-DDE<br />

<strong>4.</strong>4-DDE<br />

<strong>4.</strong>4-DDT<br />

4,4'-DDT<br />

4,4-DDT<br />

4,4-DDT<br />

4,4-DDT<br />

<strong>4.</strong>4-DDT<br />

4,4-DDE<br />

4,4'-DDT<br />

<strong>4.</strong>4'-DDT<br />

4,4'-DDT<br />

<strong>4.</strong>6-Dinlro-2-methylphenol<br />

4,6-Dinitro-2-methylphenol<br />

4,6-Dinitro-2-methylphenol<br />

4,6-Dinitro-2-methylphenol<br />

<strong>4.</strong>6-Dinlro-2-met hylphenol<br />

4,6-Dinlro-2-rnethylphenol<br />

<strong>4.</strong>6-Dinlro-2-methylphenol<br />

<strong>4.</strong>6-Dinlro-2-methylphenol<br />

<strong>4.</strong>6-Din Wro-2-methylphenol<br />

4-Bromophenyl-phenylether<br />

4-Bromophenyl-phenylether<br />

4-Bromophenyl-phenylether<br />

4-Bromophenyl-phenylether<br />

4-Bromophenyl-phen ylether<br />

CBromophenyl-phenylether<br />

4-Bromophenyl-phenylether<br />

4-Bromophenyl-phenylether<br />

4-Bromophenyl-phenylether<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloroaniline<br />

4-Chloroaniline<br />

4-Chloroaniline<br />

4-Chloroaniline<br />

4Chloroaniline<br />

4-Chloroaniline<br />

QChloroaniline<br />

CChloroaniline<br />

4-Chloroaniline<br />

4-Chlorophenyl-phenylther<br />

4-Chlorophenyl-phenylther<br />

4-Chlorophenyl-phenylther<br />

4ChlorophenyCphenylether<br />

4-Chlorophenyl-phenylether<br />

4-Chlorophen yl-phen ylether<br />

99-09-2<br />

99-09-2<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-54-8<br />

72-55-9<br />

72-55-9<br />

72-55-9<br />

72-55-9<br />

72-55-9<br />

72-55-9<br />

72-55-9<br />

72-55-9<br />

7 2 - 5 5 - 9<br />

50-29-3<br />

50-29-3<br />

50-29-3<br />

50-29-3<br />

50-29-3<br />

50-29-3<br />

50-29-3<br />

50-29-3<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

534-52-1<br />

101-55-3<br />

101-55-3<br />

101-55-3<br />

101-55-3<br />

101 -55-3<br />

101-55-3<br />

101-55-3<br />

101-55-3<br />

101 -55-3<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

106-47-8<br />

106-47-8<br />

106-47-8<br />

106-47-8<br />

106-478<br />

106-47-8<br />

106-47-8<br />

106-47-8<br />

7005-72-3<br />

7005-72-3<br />

7005-72-3<br />

7005-72-3<br />

7005-72-3<br />

50-29-3<br />

59-50-7<br />

106-47-8<br />

7005-72-3<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH2 131 55-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161<br />

-oooOO<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-OoooO<br />

CH213162-00000<br />

CH2 13145-ooOOO<br />

CH213155-OoooO<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH21315&00000<br />

CH2 13159-oooO0<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-OoooO<br />

CH213159-oM)OO<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OWW<br />

CH2 13157-00000<br />

CH213156-00000<br />

CH213159-00000<br />

CH213156-00000<br />

CH213162-00000<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

l8FEB1991<br />

1 8FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

1 8FEBl991<br />

1 8FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

so<br />

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SO<br />

SO<br />

SO<br />

SO<br />

U<br />

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U<br />

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U<br />

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U<br />

U<br />

U<br />

U<br />

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U<br />

U<br />

U<br />

U<br />

U<br />

J<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

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N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

NT<br />

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NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

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N<br />

Page 129 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

4-Chlorophenyl-phenylether 7005-72-3 CH213160-DUP 18FEB1991 SO 3.90E+02 U N<br />

4-Chlorophenyl-phenylether<br />

4-Chlorophenyl-phenylether<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthylene<br />

Acenaphthylene<br />

Acenaphthylene<br />

Acenaphth ylene<br />

Acenaphthylene<br />

Acenaphthylene<br />

Acenaphthylene<br />

Acenaphthylene<br />

Acenaphthylene<br />

Acetone<br />

Acetone<br />

Acetone<br />

Acetone<br />

Acetone<br />

Acetone<br />

Acetone<br />

Acetone<br />

Acetone<br />

Aldrin<br />

Aldrin<br />

Aldrin<br />

Aldrin<br />

Aldrin<br />

Aldrin<br />

7005-72-3<br />

7005-72-3<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

106-44-5<br />

100-01-6<br />

100-01 -6<br />

100-01 -6<br />

100-01-6<br />

100-01-6<br />

100-01-6<br />

100-01 -6<br />

100-01-6<br />

100-01-6<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

83-32-9<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

208-96-8<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

67-64-1<br />

309-00-2<br />

309-00-2<br />

309-00-2<br />

309-00-2<br />

309-00-2<br />

309-00-2<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2I 3159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH2I 3155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-000W<br />

CH213156-00000<br />

CH2I 3157-0oooO<br />

CH213158-000W<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2I 3160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00OOO<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-oooOO<br />

CH21 3157-0oooO<br />

CH213158-00000<br />

CH213159-00000<br />

CH21 3160-DUP<br />

CH21 3161 -00000<br />

CH2I 3162-ooOOO<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OWOO<br />

CH213157-00000<br />

CH213158-oooOO<br />

CH213159-M)ooo<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH21 3157-00000<br />

CH213158-00000<br />

CH2I 3159M)ooo<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBI 991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBI 991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1 991<br />

Page 130 of 176<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

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so<br />

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so<br />

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SO<br />

so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

3.90E+02<br />

3.90E+02<br />

1.20E+01<br />

1.20E+01<br />

l.lOE+Ol<br />

1.20E+01<br />

l.lOE+Ol<br />

1.20E+01<br />

1.20E+01<br />

1.20E+01<br />

I.lOE+OI<br />

3.90E+02<br />

<strong>4.</strong>1 OE+02<br />

<strong>4.</strong>1 OE+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.9OE+02<br />

2.00E+O3<br />

2.10E+03<br />

2.00E+O3<br />

1.80E+O3<br />

1.90E+03<br />

2.00E+O3<br />

2.00E+O3<br />

1.90E+03<br />

I .90E+03<br />

2. WE+03<br />

2.10E+O3<br />

2.00E+O3<br />

I .80E+O3<br />

I .90E+03<br />

2.00E+O3<br />

2.00E+O3<br />

I .90E+03<br />

I .90E+03<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

8.80E+Ol<br />

6.30EtOl<br />

I .00E+02<br />

8.10E+01<br />

7.40Et01<br />

<strong>4.</strong>3OE+01<br />

3.80E+01<br />

9.80E+01<br />

7.70E+01<br />

1.00E+Ol<br />

9.00E+00<br />

1.00E+01<br />

9.00E+00<br />

9.00E+00<br />

9.00E+00<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

UB<br />

B<br />

B<br />

B<br />

B<br />

B<br />

B<br />

B<br />

B<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

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N<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TfPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Aldrin 309 - 00 - 2 CH213160-DUP 18FEB1991 SO 9.00E+00 U<br />

NT<br />

Aldrin<br />

Aldrin<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

309-00-2<br />

309-00-2<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

120-12-7<br />

120-12-7<br />

120-12-7<br />

120-12-7<br />

120-12-7<br />

120-12-7<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2 13159-00000<br />

CH2131 60-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-OOOW<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-OOOOO<br />

Antimony '<br />

Antimony<br />

Antimony<br />

Antimony<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

120-12-7<br />

120-12-7<br />

120-12-7<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

50-32-8<br />

50-32-8<br />

50-32-8<br />

50-32-8<br />

50-32-8<br />

50-32-8<br />

CH2 13159-OOOOO<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-OoooO<br />

CH213158-00000<br />

CH2 13159-00000<br />

CH213160-DUP<br />

CH213161-OoooO<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00OOO<br />

CH2 13156-OOOOO<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161 -OOO00<br />

CH213162-00000<br />

CH2 13145-OOOOO<br />

CH213155-00000<br />

CH213156WOW<br />

CH213157-OOOOO<br />

CH213158-00000<br />

CH213159-OOOOO<br />

CH2131 60-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OOOOO<br />

CH213157-OOOOO<br />

CH213158-00000<br />

CH213159-WOO0<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CHZ13158-00000<br />

CH213159-00000<br />

18FEB1991<br />

18FEB1991<br />

1 8FEB1991<br />

18FEB1991<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Benzo(a)pyrene<br />

. ...<br />

50-32-8 CH213160-DUP 18FEB1991 SO 3.90E+02<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h.i)perylene<br />

Benzo(g.h.i)perylene<br />

Benzo(g.h.i)perylene<br />

Benzo(g.h,i)perylene<br />

Benzo(g.h.i)perylene<br />

Benzo(g.h,i)perylene<br />

Benzo(g,h.i)perylene<br />

Benzo(g.h,i)perylene<br />

Benzo(g,h.i)perylene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzoic Acid<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Bromodichloromethane<br />

Bromodichlorornethane<br />

Bromodichlorornethane<br />

Bromodichbrornethane<br />

Bromodichlorornethane<br />

Bromodichlorornethane<br />

50-32-8<br />

50-32-8<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

205-99-2<br />

191 -24-2<br />

191 -24-2<br />

191 -24-2<br />

191 -24-2<br />

191-24-2<br />

191 -24-2<br />

191 -24-2<br />

191-24-2<br />

191-24-2<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

207-08-9<br />

65-85-0<br />

6585-0<br />

65-85-0<br />

65-85-0<br />

65-85-0<br />

65-85-0<br />

65-85-0<br />

65-85-0<br />

65-85-0<br />

100-51-6<br />

100-51-6<br />

100-51-6<br />

100-51-6<br />

100-516<br />

100-51 -6<br />

100-51-6<br />

100-51-6<br />

100-51-6<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

75-274<br />

75-27-4<br />

75-27-4<br />

75-274<br />

75-274<br />

75-274<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-OOOOO<br />

CH213145-00000<br />

CH213155-OoooO<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-OOOOO<br />

CH213156-OOOOO<br />

CH213157-M)(xM<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161 -oooOO<br />

CH213162-oooO0<br />

CH213145-oooOO<br />

CH2 13155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-WOW<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH21315sMK)o<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-WWO<br />

CH2 13159-00000<br />

CH213160-DUP<br />

CH213161-WOOO<br />

CH213162-00000<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-oooO0<br />

CH213155-00000<br />

CH213156MKXW1<br />

CH213157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-M)oO<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-M)o<br />

CH213159-00000<br />

18FEB1991<br />

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18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

Page 132 of 176<br />

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SO<br />

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SO<br />

so<br />

SO<br />

SO<br />

SO<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3,70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.9OE+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>1 OE+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

2.00E+O3<br />

2.10E+O3<br />

2.00E+03<br />

1.80E+03<br />

I .90E+03<br />

2.00E+03<br />

2.00E+03<br />

I .90E+03<br />

I .90E+03<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>30E+01<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>30E+01<br />

3.70E+02<br />

<strong>4.</strong>10E+01<br />

5.00E+01<br />

3.90E+02<br />

I .00E+02<br />

1 .00E+00<br />

I.WE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.WE+OO<br />

0.00E+00<br />

1.00E+00<br />

0.00E+00<br />

0.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.WE+00<br />

6.00E+00<br />

U<br />

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B<br />

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N<br />

N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Bromodichloromet hane 75-27-4 CH213160-DUP 18FEB1991 SO 6.00€+00 U N udkg<br />

Bromodichloromet hane 75-27-4<br />

CH213161-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Bromodichloromet hane 75-27-4<br />

CH213162-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213145-OOOOO 18FEB1991 6.00€+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213155-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213156-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213157-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213158-00000 18FEB1991<br />

6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213159-00000 18FEB1991<br />

6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213160-DUP 18FEB1991<br />

6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213161-00000 18FEB1991<br />

6.00E+00<br />

U<br />

N<br />

Bromoform<br />

75-25-2<br />

CH213162-00000 18FEB1991<br />

6.00€+00<br />

U<br />

N<br />

Bromomethane<br />

74-83-9<br />

CH213145-00000 18FEB1991 1.20E+01<br />

U<br />

N<br />

Bromomethane<br />

74-83-9<br />

CH213155-00000 18FEB1991 1.20E+01<br />

U<br />

N<br />

Bromornethane<br />

74-83-9<br />

CH213156-00000 18FEB1991 l.lOE+Ol<br />

U<br />

N<br />

Bromomethane<br />

74-83-9<br />

CH213157-00000 18FEB1991 1.20€+01<br />

U<br />

N<br />

Bromomethane<br />

74-83-9<br />

CH213158-OOOOO 18FEB1991 l.lOE+Ol<br />

U<br />

N<br />

Bromomeihane<br />

74-83-9<br />

CH213159-00000 18FEB1991 1.20E+01<br />

U<br />

N<br />

Bromomethane<br />

74-83-9<br />

CH2131 60-DUP 18FEBl991<br />

1.20E+01<br />

U<br />

N<br />

Bromomethane<br />

74-83-9<br />

CH213161-00000 18FEB1991 1.20E+01<br />

U<br />

N<br />

Bromomefhane<br />

74-83-9<br />

CH2 13162-OOOOO<br />

18FEB1991 l.lOE+Ol<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213145-00000 18FEBl991<br />

1.00E+00<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213155-00000 18FEB1991 l.OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213156-00000 18FEB1991 l.OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213157-00000 18FEB1991 1 .OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213158-00000 18FEB1991 l.OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213159-OoooO 18FEB1991 l.OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH2 13160-DUP<br />

18FEB1991 1 .OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213161 -00OOO 18FEB1991 l.OOE+OO<br />

U<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH213162-00000 18FEB1991 I .00E+00<br />

U<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213145-00000 18FEB1991 l.llE+04<br />

'E<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213155-00000 18FEB1991 1.35E+03<br />

E'<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213156OoooO 18FEB1991 1.22E+O3<br />

'E<br />

N<br />

Calcium<br />

7440-70-2<br />

CH2I 3157-00000<br />

18FEB1991 6.90€+02<br />

B'E<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213158-00000 18FEB1991 1.07€+03<br />

E'<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213159-00000 18FEB1991 9.14E+02<br />

B'E<br />

N<br />

Calcium<br />

7440-70-2<br />

CH21316O-DUP 18FEB1991 8.66E+02<br />

E'<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213161-00000 18FEB1991 8.86E+02<br />

BE.<br />

N<br />

Calcium<br />

7440-70-2<br />

CH213162-OoooO 18FEB1991 5.72E+02<br />

BE'<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213145-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213155-00000 18FEB1991 2.00E+00<br />

JB<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213156-00OOO 18FEB1991 2.00E+00<br />

JB<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213157-00000 18FEB1991 2.00E+00<br />

JB<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213158-00000 18FEB1991 2.00E+00<br />

JB<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213159-00000 18FEBI991 2.00E+00<br />

JB<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213160-DUP 18FEB1991 2.00€+00<br />

JB<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CHZI 3161 -00000 18FEBI 991<br />

2.00E+00<br />

BJ<br />

N<br />

Carbon Disulfide<br />

75-15-0<br />

CH213162-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213145-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213155-WOO0 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213156-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213157-00000 18FEB1991 6.00E+W<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213158-WOW 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213159-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213160-DUP 18FEB1991 6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH2 1316 1 -oooOO 18FEBl991<br />

6.00E+00<br />

U<br />

N<br />

Carbon Tetrachloride 56-23-5<br />

CH213162-00000 18FEB I99 I<br />

6.00€+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213145-oooOO 18FEB1991 6.00E+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213155-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213156-00000 18FEB1991 6.WE+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213157-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213158-00000 18FEB1991<br />

6.00€+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CHZl3159-00000 18FEB1991 6.00E+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213160-DUP 18FEB1991 6.00E+00<br />

U N<br />

Chlorobenzene<br />

108-90-7<br />

CH213161-00000 18FEBl991<br />

6.00E+00<br />

U<br />

N<br />

Chlorobenzene<br />

108-90-7<br />

CH213162-oooO0 18FEB1991 6.00E+00<br />

U<br />

N<br />

Chloroethane<br />

75-00-3<br />

CH213145-00000 18FEB1991<br />

1.20E+01<br />

U<br />

N<br />

Chloroethane<br />

75-00-3<br />

CH213155-00000 18FEB1991<br />

1 .ZOE+Ol<br />

U<br />

N<br />

Chloroeihane<br />

75-00-3<br />

CH2 13156-00000<br />

18FEBl991<br />

l.lOE+Ol<br />

U<br />

N<br />

Chloroeihane<br />

75-00-3<br />

CH2 13157-00000<br />

18FEB1991 1.20E+01<br />

U<br />

N<br />

Chloroethane<br />

75-00-3<br />

CH2 13158-oooW<br />

I 8FEB 1991<br />

1.10E+01<br />

U<br />

N<br />

Chloroethane<br />

75-00-3<br />

CH213159-00000 18FEB1991<br />

1.20E+01<br />

U<br />

N<br />

Page 133 of 176<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chloroethane 75-00-3 CH213160-DUP 18FEB1991 SO 1.2OE+Ol U N<br />

Chloroethane<br />

Chloroethane<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Coban<br />

Coban<br />

Cobalt<br />

Coban<br />

Coban<br />

Coban<br />

Coban<br />

Cobalt<br />

Coban<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Dbn-butylphthalate<br />

75-00-3<br />

75-00-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

7440-47-3<br />

7440-47-3<br />

744047-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

218-01-9<br />

218-01 -9<br />

218-01-9<br />

218-01 -9<br />

218-01 -9<br />

218-01-9<br />

218-01 -9<br />

218-01 -9<br />

218-01 -9<br />

744048-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

744048-4<br />

7440-484<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

57- 12-5<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

84-74-2<br />

84-74-2<br />

84-74-2<br />

84-74-2<br />

84-74-2<br />

84-74-2<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CHZl316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-OW00<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-'00000<br />

CHZl3160-DUP<br />

CHZl3161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-OOoOO<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-OWOO<br />

CH213145-00000<br />

CHZI 3155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH21315g00000<br />

CH213159-00000<br />

CHZl3160-DUP<br />

CH213161-00000<br />

CH2 13162-WWO<br />

CH213145-00000<br />

CH213155Mxxw)<br />

CH2 13156-ooOOO<br />

CHZI 3157-00000<br />

CH213158-WOW<br />

CH2I 3159-00000<br />

CH2131 60-DUP<br />

CH213161 -00000<br />

CH213162-00000<br />

CH213145-00000<br />

CHZl3155-00000<br />

CH213156-00000<br />

CH213157-ooOOO<br />

CHZl3158-00000<br />

CHZI 3159-00000<br />

CHZI316O-DUP<br />

CHZl3161MK)00<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159MHHH)<br />

CH2 131 GQDUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155M)oO<br />

CH2 131 sM)o<br />

CHZI3157-00000<br />

CH21315800000<br />

CHZ 13159-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

1 OFEB1991<br />

18FEBl991<br />

18FEB 199 1<br />

18FEB1991<br />

18FEBl991<br />

18FEB199 1<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl 991<br />

18FEB1991<br />

18FEBl991<br />

18FEB199 1<br />

18FEBI991<br />

Page 134 of 176<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Di-n-butylphthalate 84-74-2 CH213160-DUP 18FEB1991 SO 9.20E+01 JB<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Dibenzo(a,h)anthracene<br />

Dibenzo(a ,h)anthracene<br />

Dibenzo(a,h)anthracene<br />

Dibenzo(a ,h)anthracene<br />

Dibenzo(a ,h)anthracene<br />

Dibenzo(a,h)anthracene<br />

Dibenzo(a ,h)anthracene<br />

Dibenzo(a.h)anthracene<br />

Dibenzo(a.h)anthracene<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibenzofuran<br />

Dibromochloromethane<br />

Dibromochloromethane<br />

Dibromochloromethane<br />

Dibromochlorornet hane<br />

Dibromochloromethane<br />

Dibromochloromethane<br />

Dibromochloromethane<br />

Dibromochloromethane<br />

Dibromochlorornethane<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Dieldrin<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Endosulfan I<br />

Endosulfan I<br />

Endosulfan I<br />

Endosulfan I<br />

Endosulfan I<br />

Endosulfan I<br />

84-74-2<br />

84-74-2<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

117-84-0<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

132-64-9<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

124-48-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

60-57-1<br />

84-662<br />

84-66-2<br />

84-66-2<br />

84-66-2<br />

84-66-2<br />

84-66-2<br />

84-66-2<br />

84-66-2<br />

84-66-2<br />

131 -11-3<br />

131-11-3<br />

131 -11-3<br />

131 -11-3<br />

131 -11-3<br />

131-11-3<br />

131 -11-3<br />

131-11-3<br />

131-11-3<br />

959-98-8<br />

959-98-8<br />

959-98-8<br />

959-98-8<br />

959-988<br />

959-988<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2 13160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH2 13161 -00000<br />

CH2 13162-0oooO<br />

CH213145-~00<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH2I 3160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-oooO0<br />

CH213158-00000<br />

CH2 13159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH2I 3162-OOOOO<br />

CH213145-OoooO<br />

CH213155-WOO0<br />

CH213156-00000<br />

CH213157-00000<br />

CH21315RWOO0<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-WOO0<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213156-00000<br />

CH213159-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBI 991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

1 8FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBI 991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBI 991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

Page 135 of 176<br />

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2.20E+02<br />

3.90E+02<br />

<strong>4.</strong> I OE+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70€+02<br />

<strong>4.</strong>00E+02<br />

3.90€+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>1 OE+02<br />

<strong>4.</strong>1 OE+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>1 OE+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

2.00E+01<br />

I .90E+01<br />

1.90E+01<br />

1.70E+01<br />

1.70E+01<br />

1.80E+01<br />

I .90E+01<br />

1.80E+01<br />

I .90E+01<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10€+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

6.80E+01<br />

3.90E+02<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>10E+02<br />

3.60E+02<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.9OE+O2<br />

3.9OE+02<br />

1 .OOE+OI<br />

9.00E+00<br />

1.00E+Ol<br />

9.00E+00<br />

9.00€+00<br />

9.00E+00<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Endosulfan I 959-98-8 CH213160-DUP 18FEB1991 SO 9.00E+00 U<br />

NT<br />

Endosulfan I<br />

Endosulfan I<br />

Endosulfan II<br />

959-98-8<br />

959-98-8<br />

33213-65-9<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

9.00E+00<br />

9.00E+00<br />

2.00E+01<br />

U<br />

U<br />

U<br />

NT<br />

NT<br />

NT<br />

Endosulfan II<br />

33213-65-9<br />

CH21 3155-00000<br />

18FEB1991 I .90E+01<br />

U<br />

NT<br />

Endosulfan II<br />

Endosulfan II<br />

Endosulfan II<br />

Endosulfan II<br />

Endosulfan II<br />

Endosulfan II<br />

Endosulfan II<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endosulfan Sulfate<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Endrin Ketone<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluoranlhene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Heptachlor<br />

Heptachlor<br />

Heptachlor<br />

Heptachlor<br />

Heptachlor<br />

Heptachlor<br />

33213-65-9<br />

33213-65-9<br />

33213-65-9<br />

33213-65-9<br />

33213-65-9<br />

33213-65-9<br />

33213-65-9<br />

1031-07-8<br />

1031-07-8<br />

1031-07-8<br />

1031 -07-8<br />

1031 -07-8<br />

1031-07-8<br />

1031-07-8<br />

1031-07-8<br />

1031 -07-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

72-20-8<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

53494-70-5<br />

100-414<br />

100-414<br />

100-414<br />

100-41-4<br />

100-41-4<br />

100-41-4<br />

100-414<br />

100-414<br />

100414<br />

20644-0<br />

20644-0<br />

20644-0<br />

20644-0<br />

206-44-0<br />

20644-0<br />

20644-0<br />

20644-0<br />

206-44-0<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

86-73-7<br />

7644-8<br />

76448<br />

76448<br />

7644-8<br />

7644-8<br />

7644-8<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH2 13162-00000<br />

CH2I 3145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH213156-OO000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213I 45-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-oooO0<br />

CH213159-00000<br />

CH21316dDUP<br />

CH2I 3161 -00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-oooOO<br />

CH2I 3159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH21315MH)o<br />

CH213157-00000<br />

CH213158-00000<br />

CH2 13159-00000<br />

CH213160-DUP<br />

CH2 13161 -oooOO<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161M)o<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-OOOOO<br />

CH21315800000<br />

CH213159-00000<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEBI 991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

I8FEBl99I<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

1.90E+01<br />

1.70E+01<br />

1.70€+01<br />

1.80E+01<br />

1.90E+01<br />

1.80€+01<br />

I .90E+01<br />

2.00E+01<br />

1.90E+01<br />

1.90E+01<br />

1.70E+01<br />

1.70E+01<br />

1.80E+01<br />

1.90E+01<br />

1.80E+01<br />

1.90E+01<br />

2.00E+01<br />

1.90E+01<br />

1.90E+01<br />

1.70E+01<br />

1.70E+01<br />

1.80E+01<br />

1.90E+01<br />

1.80E+01<br />

1.90E+01<br />

2.00E+01<br />

1.90E+01<br />

1.90E+OI<br />

1.70E+01<br />

1.70E+01<br />

I .80E+01<br />

I .90E+OI<br />

I .80E+Ol<br />

I .90E+01<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.WE+00<br />

6.00E+W<br />

6.00E+00<br />

6.WE+W<br />

6.00E+00<br />

3.90E+02<br />

6.10E+01<br />

<strong>4.</strong>50E+01<br />

6.3OE+01<br />

3.70E+02<br />

6.50E+01<br />

7.00E+01<br />

5.00E+OI<br />

1.40E+02<br />

3.90E+02<br />

<strong>4.</strong>10€+02<br />

<strong>4.</strong>10E+02<br />

3.60E+O2<br />

3.70E+02<br />

<strong>4.</strong>00E+02<br />

3.90E+02<br />

3.90E+02<br />

3.90E+02<br />

I.WE+Ol<br />

9.00E+00<br />

1 .00E+01<br />

9.00E+00<br />

9.00E+00<br />

9.00E+00<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

J<br />

J<br />

J<br />

U<br />

J<br />

J<br />

J<br />

J<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

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NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

Page 136 of 176<br />

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so<br />

so<br />

so<br />

so<br />

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so<br />

so<br />

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so<br />

so<br />

so<br />

so


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

HeDtachlor 76-44-8 CH213160-DUP 18FEB1991 SO 9.00E+00 U<br />

NT<br />

Heptachlor<br />

Heptachlor<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Heptachlor Epoxide<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorocyclopentadiene<br />

76-44-8<br />

76-44-8<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

1024-57-3<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

118-74-1<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

87-68-3<br />

77-47-4<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2I 3158-OOOOO<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH2 13162-OOOOO<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Hexachlorocyclopentadiene 77-47-4<br />

CH213155-~0 18FEB1991<br />

U<br />

N<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

77-47-4<br />

77-47-4<br />

77-47-4<br />

77-47-4<br />

77-47-4<br />

77-47-4<br />

77-47-4<br />

67-72-1<br />

67-72-1<br />

67-72-1<br />

67-72-1<br />

67-72-1<br />

67-72-1<br />

67-72-1<br />

67-72-1<br />

CH213156-oooO0<br />

CH213157-OOOOO<br />

CH213158-00000<br />

CH213159-OOOOO<br />

CH21316O-DUP<br />

CH2I 3161 -0oOOO<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OOOW<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Hexachloroethane<br />

67-72-1<br />

CH213162-~0 18FEB1991<br />

U<br />

N<br />

Indeno(l.2.3-cd)pyrene<br />

Indeno(l,2.3-cd)pyrene<br />

Indeno(l,2,3-cd)pyrene<br />

Indeno(1,2,bcd)pyrene<br />

Indeno(l.2,3-cd)pyrene<br />

Indeno(l.2,3-cd)pyrene<br />

Indeno(l.2 ,J-cd)pyrene<br />

Indeno(l.2 ,bcd)pyrene<br />

Indeno(l.2.3-cd)pyrene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

CH213145-00000<br />

CH2I 3155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-WOO0<br />

CH213159-00000<br />

CH2I 3160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-OOO00<br />

CH213155-00000<br />

CH213156-OOO00<br />

CH213157-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

E<br />

E<br />

E<br />

E<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Iron<br />

7439-89-6<br />

CH2I 3158-00000<br />

18FEB1991<br />

E<br />

N<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

lsophorone<br />

lsophorone<br />

lsophorone<br />

lsophorone<br />

lsophorone<br />

lsophorone<br />

7439-896<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

78-59-1<br />

78-59-1<br />

78-59-1<br />

78-59-1<br />

78-59-1<br />

78-59-1<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2I 3145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

E<br />

E<br />

E<br />

E<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 137 of 176<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

so


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

lsophorone 78-59-1 CH213160-DUP 18FEB1991 SO 3.90E+02<br />

U<br />

N<br />

lsophorone<br />

78-59-1<br />

CH213161-00000 18FEB1991 SO<br />

U<br />

N<br />

lsophorone<br />

78-59-1<br />

CH2 13162-00000 18FEB1991 SO<br />

U<br />

N<br />

Lead<br />

7439-92-1<br />

CH213145-00000 18FEB1991 so<br />

v\n\r<br />

N<br />

Lead<br />

7439-92-1<br />

CH213155-00000 18FEBI 991 SO<br />

N<br />

N<br />

Lead<br />

7439-92-1<br />

CH2 13156-00000<br />

18FEB1991 SO<br />

N<br />

N<br />

Lead<br />

7439-92-1<br />

CH213157-00000 18FEB1991 so<br />

NS<br />

N<br />

Lead<br />

Lead<br />

Lead<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

CH213158-00000<br />

CH2I 3159-OW00<br />

CH2 13160-DUP<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

N<br />

NW<br />

NW<br />

N<br />

N<br />

N<br />

Lead<br />

7439-92-1<br />

CH213161-00000 18FEB1991 SO<br />

NW<br />

N<br />

Lead<br />

7439-92-1<br />

CH213162-00000 18FEB1991 so<br />

NW<br />

N<br />

Magnesium<br />

7439-95-4<br />

CH213145-00000 18FEB1991 so<br />

N<br />

Magnesium<br />

7439 - 95 -4<br />

CH213155-00000 18FEB1991 SO<br />

N<br />

Magnesium<br />

Magnesium<br />

7439-95-4<br />

7439-95-4<br />

CH213156-00000<br />

CH213157-OOOOO<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

B<br />

N<br />

N<br />

Magnesium<br />

7439-95-4<br />

CH2 13158-WOOO<br />

18FEB1991 SO<br />

B<br />

N<br />

Magnesium<br />

7439-95-4<br />

CH213159-00000 18FEBI 991 so<br />

B<br />

N<br />

Magnesium<br />

7439-95-4<br />

CH213160-DUP 18FEB1991 so<br />

B<br />

N<br />

Magnesium<br />

7439-95-4<br />

CH213161-00000 18FEB1991 so<br />

B<br />

N<br />

Magnesium<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-OoooO<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

B<br />

N'E<br />

NE'<br />

'NE<br />

NE'<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Manganese<br />

Manganese<br />

Manganese<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

NE'<br />

NE'<br />

NE'<br />

N<br />

N<br />

N<br />

Manganese<br />

7439-96-5<br />

CH213161-00000 18FEB1991 SO<br />

NE'<br />

N<br />

Manganese<br />

7439-96-5<br />

CH213162-WOO0 18FEB1991 so<br />

NE'<br />

N<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Mercury<br />

7439-97-6<br />

CH21316O-DUP 18FEB1991 SO<br />

U<br />

N<br />

Mercury<br />

7439-97-6<br />

CH213161-00000 18FEB1991 so<br />

U<br />

N<br />

Mercury<br />

7439-97-6<br />

CH213162-00000 18FEB1991 so<br />

U<br />

N<br />

Methoxychlor<br />

Methoxychlor<br />

Methoxychlor<br />

72-43-5<br />

72-43-5<br />

72-43-5<br />

CH213145-00000<br />

CH213155-00000<br />

CH2131<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

U<br />

U<br />

U<br />

NT<br />

NT<br />

NT<br />

Methoxychlor<br />

72-43-5<br />

CH213157-00000 18FEB 1991 SO<br />

U<br />

NT<br />

Methoxychlor<br />

72-43-5<br />

CH213158-00000 18FEB1991 so<br />

U<br />

NT<br />

Methoxychlor<br />

72-43-5<br />

CH213159-00000 18FEBI 991 so<br />

U<br />

NT<br />

Methoxychlor<br />

72-43-5<br />

CH213160-DUP 18FEB1991 SO<br />

U<br />

NT<br />

Methoxychlor<br />

72-43-5<br />

CH213161 -oooOO 18FEB1991 SO<br />

U<br />

NT<br />

Methoxychlor<br />

72-43-5<br />

CH213162-00OOO 18FEB1991 so<br />

U<br />

NT<br />

Methylene Chloride<br />

75-09-2<br />

CH213145-00000 18FEB1991 SO<br />

UB<br />

N<br />

Methylene Chloride<br />

75-09-2<br />

CH213155-00000 18FEB1991 so<br />

B<br />

N<br />

Methylene Chloride<br />

75-09-2<br />

CH213156-00000 18FEB1991 so<br />

B<br />

N<br />

Methylene Chloride<br />

Methylene Chloride<br />

Methylene Chloride<br />

Methylene Chloride<br />

75-09-2<br />

75-09-2<br />

75-09-2<br />

75-09-2<br />

CH2 13157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

SO<br />

B<br />

B<br />

B<br />

B<br />

N<br />

N<br />

N<br />

N<br />

Methylene Chloride<br />

75-09-2<br />

CH213161-00000 18FEB1991 SO<br />

B<br />

N<br />

Methylene Chloride<br />

75-09-2<br />

CH213162-00000 18FEBl991 SO<br />

B<br />

N<br />

N-Nilrosodi-n-propylamine 621 -64-7<br />

CHZI 3145-00000<br />

18FEB1991 so<br />

U<br />

N<br />

N-Nilroso-di-n-propyhmine<br />

N-Nitroso-di-n-propyhrnine<br />

621 -64-7<br />

621-64-7<br />

CH213155-00000<br />

CHPI 31<br />

18FEBI 991<br />

18FEB1991<br />

SO<br />

SO<br />

U<br />

U<br />

N<br />

N<br />

N-Nitroso-di-n-propylarnine 621 -64-7<br />

CHZI 3157-00000<br />

18FEB1991 SO<br />

U<br />

N<br />

N-Nitroso-di-n-propylamine 62164-7<br />

CH213158-00000 18FEB1991 so<br />

U<br />

N<br />

N-Nilroso-di-n-propylamine<br />

N-Nilroso-di-n-propylamine<br />

N-Nilroro-di-n-propyhmine<br />

N-Nitroso-di-n-propybmine<br />

N-Nitrosodiphenyhmine<br />

N-Nitrosdiphenylamine<br />

N-Nitrosodiphenylamine<br />

N-Nitrosodiphen yhmine<br />

N-Nitrosdiphenylamine<br />

N-Nitrosodiphenyhmine<br />

621-64-7<br />

621-64-7<br />

621-64-7<br />

62164-7<br />

86-30-6<br />

86-30-6<br />

86-30-6<br />

86-30-6<br />

86-30-6<br />

86-30-6<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-MX)o<br />

CH213162-00000<br />

CH213145-00000<br />

CH21 3155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-OoooO<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

SO<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Page 138 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

N-Nitrosodiphenylamine . .<br />

86-30-6 CH213160-DUP 18FEB1991 SO 3.90E+02 U<br />

CH2 13161 -00000<br />

N-Nitrosodiphenylamine<br />

N-Nlrosodiphenylamine<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Neptunium-237<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

PCB-1016<br />

PCB-1016<br />

PCB-1016<br />

PCB-1016<br />

PCB-I 016<br />

PCB-1016<br />

PCB-1016<br />

PCB-1016<br />

PCB-1016<br />

PCB-1221<br />

PCB-1221<br />

PCB-122 1<br />

PCB-1221<br />

PCB-1221<br />

PCB-1221<br />

PCB-1221<br />

PCB-I221<br />

PCB-1221<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1232<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1242<br />

PCB-1248<br />

PCB-1248<br />

PCB-1248<br />

PCB-1248<br />

PCB-I 248<br />

86-30-6<br />

86-30-6<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

13994-20-2<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

98-95-3<br />

12674-1 .2<br />

12674-1 -2<br />

12674-1 .2<br />

12674-1 .2<br />

12674-1 .2<br />

12674-11-2<br />

12674-11-2<br />

12674-11-2<br />

12674-11-2<br />

11104-28-2<br />

11104-28-2<br />

11104-28-2<br />

1 I 104-28-2<br />

11104-28-2<br />

11104-28-2<br />

11104-28-2<br />

11104-28-2<br />

11104-28-2<br />

11141 -16-5<br />

11141-16-5<br />

11141-16-5<br />

11141-16-5<br />

11141-16-5<br />

11141-16-5<br />

11141-16-5<br />

11141-16-5<br />

11141-16-5<br />

53469-21-9<br />

53469-21-9<br />

53469-21-9<br />

53469-21-9<br />

53469-21 -9<br />

52469-21-9<br />

53469-21-9<br />

53469-21-9<br />

53469-21-9<br />

12672-29-6<br />

12672-29-6<br />

12672-29-6<br />

12672-29-6<br />

12672-29-6<br />

CH21 3162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-MXX)O<br />

CH213162-00000<br />

CH21 3145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH223159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-OOOOO<br />

CH213157-00000<br />

~~2131 58-00000<br />

CH21 3159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH2I 3162-00000<br />

CH213145-OOOOO<br />

CH213155-OoooO<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH2 13158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-OOOOO<br />

CH213145-00000<br />

CH21315500000<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FE61991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FE61991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FE61991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB 1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

I8FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

Page 139 of 176<br />

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U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

PCB-1248 12672-29-6 CH2 13159-00000 18FEB1991 SO 9.1 OE+01 U NT ug/kg<br />

PCB-1248<br />

PCB-1248<br />

PCB-1248<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1254<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

PCB-1260<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phenol<br />

Plutonium-239<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

12672-29-6<br />

12672-29-6<br />

12672-29-6<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11097-69-1<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

11096-82-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

85-01-8<br />

85-01-8<br />

85-01-8<br />

85-01 -8<br />

85-01-8<br />

85-01-8<br />

85-01-8<br />

85-01-8<br />

85-01-8<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

15117-48-3<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

7782-49-2<br />

7782-49-2<br />

na2-49-2<br />

778249-2<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-OOOOO<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2 13159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-OOOM)<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-oooO0<br />

CH213158-OOO00<br />

CH213159-00000<br />

CH213160-DUP<br />

CHZl3161-OOOOO<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-OOOOO<br />

CH213156-00000<br />

CH213157-OOOOO<br />

cn21315a00000<br />

CH213159-00000<br />

CH2 13160-DUP<br />

CHZ13161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-oooOO<br />

CH213156-00000<br />

CH213157-00000<br />

CH21315a00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161 -OOO00<br />

CH213162-00000<br />

CH213145-00OOO<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

cH21315a00000<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH2 13158M)ooo<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-0oooO<br />

CH213155-00000<br />

CH2131 %-WOO0<br />

CH213157-00000<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

lSFEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

Page 140 of 176<br />

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N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Selenium 7782-49-2 CH213158-00000 18FEB1991 SO O.OOE+OO<br />

U<br />

N mglKG<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Styrene<br />

Styrene<br />

Styrene<br />

Styrene<br />

Styrene<br />

Styrene<br />

Styrene<br />

Styrene<br />

Styrene<br />

Technetium99<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

7782-49-2<br />

7782 2<br />

7782-49-2<br />

7782-49-2<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440 - 23- 5<br />

7440-23-5<br />

7440-23-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

14133-767<br />

I 27-18-4<br />

127-18-4<br />

i 27-18-4<br />

127-18-4<br />

127-18-4<br />

127-18-4<br />

i 27-18-4<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH2 13162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-OOOOO<br />

CH2I 3158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161-OOO00<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-MWXM<br />

CH213145-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH2 13156-MWXM<br />

CH213157-00000<br />

CH213158-00000<br />

CH2 13159-00000<br />

CH2 13160-DUP<br />

18FEB1991<br />

18FEB1991<br />

1 BFEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

1 OFEBI 991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

I 8FEBl991<br />

18FEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OoE+OO<br />

O.OOE+OO<br />

2.00E+00<br />

l.OOE+OO<br />

1.00E+00<br />

l.OOE+OO<br />

1.00E+00<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

2.20E+02<br />

2.28~+02<br />

2.45E+02<br />

1.81E+02<br />

2.52E+02<br />

2.11E+02<br />

i.a5~+02<br />

1.79€+02<br />

1.18E+02<br />

6.00E+00<br />

6.00E+00<br />

6.00€+00<br />

6.00€+00<br />

6.00E+00<br />

6.00E+00<br />

6.00€+00<br />

6.00€+00<br />

6.00E+00<br />

1.60E+02 7.24E+02<br />

6.00E+00<br />

6.00E+00<br />

6.00€+00<br />

6.00€+00<br />

6.00E+00<br />

6.00E+00<br />

6.00€+00<br />

U<br />

U<br />

U<br />

U<br />

B<br />

U<br />

U<br />

U<br />

U<br />

U<br />

B<br />

U<br />

U<br />

UB<br />

0<br />

B<br />

B<br />

B<br />

B<br />

B<br />

B<br />

B<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

127-18-4<br />

127-18-4<br />

CH213161-00000<br />

CH213162-00000<br />

18FEB1991<br />

18FEB1991<br />

6.00€+00<br />

6.00€+00<br />

U<br />

U<br />

N<br />

N<br />

Thallium<br />

7440-28-0<br />

CH213145-00000 18FEB1991 I .00E+00<br />

UN<br />

N<br />

Thallium<br />

7440-28-0<br />

CH2 13155-OOOW 18FEBl991<br />

1 .WE+OO w N<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thorium-230<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toluene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Toxaphene<br />

Trichbroethene<br />

Trichbroeihene<br />

7440-250<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

14269-63-7<br />

108-88-3<br />

108-88-3<br />

I 08-88-3<br />

108-88-3<br />

I 08-88-3<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

ioa-aa-3<br />

8001-35-2<br />

8001-35-2<br />

8001-35-2<br />

8001-35-2<br />

8001 -35-2<br />

8001 -35-2<br />

8001-35-2<br />

8001-35-2<br />

8001 -35-2<br />

79-01-6<br />

79-01-6<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH2 131 sMKK)oo<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2131 6QDUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

l8FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

1 BFEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl 991<br />

18FEBl991<br />

I 8FEB1991<br />

1.00E+00<br />

1 .00E+00<br />

1.00E+00<br />

I.WE+OO<br />

I.WE+W<br />

1.00E+00<br />

1 .00E+00<br />

5.20€+02 <strong>4.</strong>00E+01<br />

6.00E+00<br />

6.00E+00<br />

6.00€+00<br />

6.00€+00<br />

6.00€+00<br />

6.00€+00<br />

6.00€+00<br />

6.00€+00<br />

6.00E+00<br />

2.00E+02<br />

I .90E+02<br />

1.90E+02<br />

I .70E+02<br />

1.70E+02<br />

i .a0~+02<br />

I .90E+02<br />

I .80~+02<br />

I .90E+02<br />

l.WE+OO<br />

I.WE+W<br />

UN<br />

UN<br />

UNW<br />

UN<br />

UN<br />

UMN<br />

UWN<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

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NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

Page 141 of 176<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

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so<br />

so<br />

so<br />

so<br />

so<br />

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so<br />

so


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trichloroethene 79-01-6 CH213156-00000 18FEB1991 SO 1.00€+00 U N<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Uranium234<br />

Uranium235<br />

Uranium238<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alpha-BHC<br />

alphachlordane<br />

alphachlordane<br />

alpha-Chlordane<br />

alpha-Chlordane<br />

alpha-Chlordane<br />

alpha-Chlordane<br />

alpha-Chlordane<br />

alpha-Chlordane<br />

79-01 -6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

13966-29-5<br />

15117-96-1<br />

24678-82-8<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

108-05-4<br />

I 0805-4<br />

108-05-4<br />

108-05-4<br />

ioao5-4<br />

108-05-4<br />

108-05-4<br />

108-05-4<br />

108-05-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

319-84-6<br />

5103-71-9<br />

5103-7 1-9<br />

5103-71-9<br />

5103-7 1-9<br />

5103-71 -9<br />

5103-71 -9<br />

5103-71 -9<br />

5103-71 -9<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213145-00000<br />

CH213145-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH2I 3156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2 13160-DUP<br />

CH2 13161 -00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH213156-00000<br />

CH21 3157-00000<br />

CH213158-00000<br />

CH2 13159-~00<br />

CH2 13160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155MHMO<br />

CH213156-00000<br />

CH21 3157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161 -00000<br />

CH213162-OW00<br />

CH213145-00000<br />

CH213155-00000<br />

CH2 13156-oooO<br />

CH213157-00000<br />

CH2 131580oWO<br />

CH2 13159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-000OO<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00OOO<br />

CH213162-OWOO<br />

CH213145-00000<br />

CH213155-oMxK)<br />

CH213156-oMxK)<br />

CH213157-000(W<br />

CH21315800000<br />

CH213159-ooOOO<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145M)o<br />

CH2 13155-00000<br />

CH213156-000OO<br />

CHZl3157-OOOOO<br />

CH21315800000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213I 61 -00000<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

I SFEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

1 OFEBI 991<br />

1 SFEBI 991<br />

18FEB1991<br />

18FEBI 991<br />

18FEBl991<br />

18FEBl991<br />

lSFEBl991<br />

18FEB1991<br />

lSFEB1991<br />

lSFEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

I8FEB1991<br />

18FEB1991<br />

-16FEB1991<br />

18FEBl991<br />

18FEBl991<br />

ISFEBI991<br />

I 8FEB 1991<br />

18FEBl991<br />

1 SFEBI 991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

1 SFEBI 991<br />

18FEB1991<br />

18FEB1991<br />

18FEBI991<br />

Page 142 of 176<br />

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l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

1.90E+02 6.00E+01<br />

1.50E+01 1.50€+01<br />

2.50E+02 6.00E+01<br />

1.80E+01<br />

1.60E+01<br />

1.70€+01<br />

1.50E+01<br />

1.50E+01<br />

2.70E+01<br />

3.30E+01<br />

1.60E+01<br />

1.90E+01<br />

1.20E+01<br />

1.20E+01<br />

l.lOE+Ol<br />

1.20E+01<br />

l.lOE+Ol<br />

I .20E+Ol<br />

I .20E+01<br />

1.20E+01<br />

l.lOE+Ol<br />

I .00E+00<br />

1.00€+00<br />

l.WE+OO<br />

1 .WE+00<br />

l.OOE+OO<br />

I .WE+00<br />

I .00E+00<br />

l.OOE+OO<br />

I .WE+OO<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

<strong>4.</strong>00E+01<br />

3.20E+01<br />

1.3OE+OI<br />

<strong>4.</strong>00E+00<br />

<strong>4.</strong>00E+00<br />

5.00E+00<br />

5.00E+00<br />

9.00E+00<br />

9.00E+00<br />

l.WE+Ol<br />

9.00E+00<br />

1.00E+Ol<br />

9.OoE+80<br />

9.00E+00<br />

9.00E+00<br />

9.00E+00<br />

9.00E+00<br />

9.00E+W<br />

9.80E+01<br />

9.30E+01<br />

9.60E+01<br />

8.70E+01<br />

8.60E+01<br />

9.10E+01<br />

9.30E+01<br />

8.90E+01<br />

U<br />

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NT<br />

NT<br />

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NT<br />

NT<br />

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NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT<br />

NT


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

alpha-Chlordane 5103-71-9 CH213162-00000 18FEB1991 SO 9.30E+01<br />

U NT uglkg<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

beta-BHC<br />

bis(2-Chloroethoxy)methane<br />

bis(2-Chloroethoxy)methane<br />

bis(2-Chloroethoxy)methane<br />

bis(2-Chloroe1hoxy)methane<br />

bis(2-Ch1oroethoxy)methane<br />

bis(2-Chloroe1hoxy)methane<br />

bis(2-Chloroe1hoxy)methane<br />

bs(2-Chloroethoxy)methane<br />

bis(2-Chloroe1hoxy)methane<br />

bis(2-Ch1oroethyl)ether<br />

bis(26hloroethyl)ether<br />

bis(2-Ch1oroethyl)ether<br />

bis(2-Ch1oroethyl)ether<br />

bis(2-Ch1oroethyl)elher<br />

bis(2-Ch1oroethyl)ether<br />

bis(2-Ch1oroethyl)ether<br />

bis(2-Ch1oroethyl)ether<br />

bis(2-Ch1oroethyl)ether<br />

bs(2-ChloroisopropyI)ether<br />

bis(2-ChloroisopropyI)ether<br />

bis(2-Chloroisopropyl)elher<br />

bis(2-Chloroisopropyl)ether<br />

bis(2-ChloroisopropyI)ether<br />

bis(2-Chloroisopropyl)ether<br />

bis(2-Chloroisopropyl)t?ther<br />

bis(2-Chloroisopropyl)ether<br />

bis(2-Chloroisopropyl)ether<br />

bis(2-Ethy1hexyl)phthalate<br />

bs(2-Ethylhexyl)phthalale<br />

bis(2-Ethy1hexyl)phthalate<br />

bis(2-Ethy1hexyl)phthalate<br />

bs(2-Ethy1hexyl)phthalate<br />

bis(2-Ethy1hexyl)phthalate<br />

bis(2-Ethy1hexyl)phthalate<br />

bis(2-Ethy1hexyI)phthalate<br />

bis(2-Ethy1hexyl)phthalate<br />

cis-I ,3-Dichloropropene<br />

cis-I ,3-Dichloropropene<br />

cis-I .3-Dichloropropene<br />

cis-I .3-Dichloropropene<br />

cis-I ,3-Dichloropropene<br />

cis-1.3-Dichloropropene<br />

cis-I ,3-Dichloropropene<br />

cis-I .3-Dichloropropene<br />

cis-I ,3-Dichloropropene<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

delta-BHC<br />

gamma-BHC(Lindane)<br />

gamma-BHC(Lindane)<br />

gamma-BHC(Lindane)<br />

gamma-BHC(Lindane)<br />

gamma-BHC(Lindane)<br />

gamma-BHC(Lindane)<br />

garnma-BHC(Lindane)<br />

gamma-BHC(Lindane)<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

319-85-7<br />

111-91-1<br />

1 I 1-91 -1<br />

111-91-1<br />

111-91-1<br />

111-91-1<br />

111-91-1<br />

111-91-1<br />

111-91-1<br />

111-91-1<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

108-60- 1<br />

108-60-1<br />

108-60-1<br />

108-60-1<br />

10860-1<br />

108-60-1<br />

108-60-1<br />

108-60-1<br />

108-60-1<br />

117-81-7<br />

117-81 -7<br />

117-81-7<br />

117-81-7<br />

117-81 -7<br />

117-81 -7<br />

117-81 -7<br />

117-81-7<br />

117-81-7<br />

10061 -01-5<br />

10061 -01-5<br />

10061-01-5<br />

10061-01 -5<br />

10061-01-5<br />

10061-01-5<br />

10061 -01-5<br />

10061-01-5<br />

10061 -01-5<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

319-86-8<br />

58-89-9<br />

58-89-9<br />

58-89-9<br />

58-89-9<br />

58-89-9<br />

58-89-9<br />

58-89-9<br />

5889-9<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH2 13157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213 159-00000<br />

CH213160-DUP<br />

CH2 13161 -00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH2 13155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH2I 3159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-OW00<br />

CH213155-00000<br />

CH213156-0OO00<br />

CH2I 3157-ooOO0<br />

CH213158-00000<br />

CH213159-00000<br />

CH2131 60-DUP<br />

CH213161-OOOOO<br />

CH213162-00000<br />

CH213145-WOO0<br />

CH213155-00000<br />

CH213156-WOO0<br />

CH213157-WOO0<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH2 13145-WOO0<br />

CH213155-WOO0<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-ooOO0<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH2 13156-00000<br />

CH213157-00000<br />

CH2I 3158-OOOOO<br />

CH213159-00000<br />

CH213160-DUP<br />

CH213161-00000<br />

CH213162-00000<br />

CH213145-00000<br />

CH213155-WOO0<br />

CH2I 3156-WWO<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH21316O-DUP<br />

CH213161-00000<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

16FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

U<br />

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Page 143 of 176<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

gamrna-BHC(Lindane) 58-89-9 CH213162-00000 18FEB1991 SO 9.00E+00 U NT<br />

gamma-Chlordane<br />

gamma-Chlordane<br />

gamma-Chlordane<br />

gamrna-Chlordane<br />

gamma-Chlordane<br />

gamma-Chlordane<br />

gamma-Chlordane<br />

gamma-Chlordane<br />

gamrna-Chlordane<br />

trans-1.3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

trans-I .3-Dichloropropene<br />

trans-I .3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

trans-I .3-Dichloropropene<br />

WAG 7, SWU 8. MWI 84<br />

1 .I,l-Trichloroethane<br />

1 .I.I-Trichloroethane<br />

1 .I.1-Trichloroethane<br />

1 ,I,2.2-Tetrachloroethane<br />

1 ,I.2.2-Tetrachloroethane<br />

1 ,I.2.2-Tetrachloroethane<br />

1.1.2-Trichloroethane<br />

1 .I,2-Trichloroethane<br />

1,1.2-Trichloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroethene<br />

1 .I-Dichloroethene<br />

1.2 .4-Trichlorobenzene<br />

1.2 .4-Trichlorobenzene<br />

1.2 .CTrichlorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichlorobenzene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

1 .Z-Dichloroethane<br />

1.2-Dchloroethene<br />

1.2-Dehloroethene<br />

1 .2-Dichloroethene<br />

1.2-Dchloropropane<br />

1.2-Dichloropropane<br />

1.2-Dchloropropane<br />

1.3-Dichlorobenzene<br />

1.3-Dichlorobenzene<br />

1.3-Dichlorobenzene<br />

1.4-Dichlorobenzene<br />

1.4-Dichlorobenzene<br />

1.4-Dichlorobenzene<br />

2.<strong>4.</strong>5-Trichlorophenol<br />

2.4,5-Trichlorophenol<br />

2.4,5-Trichlorophenol<br />

2.<strong>4.</strong>6-Trichlorophenol<br />

2.<strong>4.</strong>6-Trichlorophenol<br />

2.4 .6-Tric hlorop henol<br />

2 ,4-Dichlorophenol<br />

2.4-Dichlorophenol<br />

2.4-Dchlorophenol<br />

2 .CDimethylphenol<br />

2.4-Dimethylphenol<br />

2.4-Dimethylphenol<br />

2.4-Dinitrophenol<br />

2 .CDinitrophenol<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

5103-74-2<br />

10061-02-6<br />

10061-02-6<br />

10061 -02-6<br />

10061-02-6<br />

10061 -02-6<br />

10061-02-6<br />

10061-02-6<br />

10061 -02-6<br />

10061 -02-6<br />

71 -55-6<br />

71-55-6<br />

71-55-6<br />

79-34-5<br />

79-34-5<br />

79-34-5<br />

79-00-5<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

75-35-4<br />

120-82-1<br />

120-82-1<br />

120-82-1<br />

95-50-1<br />

95-50-1<br />

95-50-1<br />

107-06-2<br />

107-06-2<br />

107-06-2<br />

540-59-0<br />

540-59-0<br />

540-59-0<br />

78-87-5<br />

78-87-5<br />

78-87-5<br />

541 -73-1<br />

541 -73-1<br />

541-73-1<br />

106-46-7<br />

106-46-7<br />

106-46-7<br />

95-95-4<br />

95-95-4<br />

95-95-4<br />

88-06-2<br />

88-06-2<br />

88-06-2<br />

12083-2<br />

120-83-2<br />

120-83-2<br />

105-67-9<br />

10567-9<br />

105-67-9<br />

51-28-5<br />

51-28-5<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH2 13160-DUP<br />

CH213161-00000<br />

CH2 13162-00000<br />

CH213145-00000<br />

CH213155-00000<br />

CH213156-00000<br />

CH213157-00000<br />

CH213158-00000<br />

CH213159-00000<br />

CH213160-DUP<br />

CH2 13161 -00000<br />

CH213162-00000<br />

CH2 10144-00000<br />

CH2 10223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-ooOo0<br />

CH210224-DUP<br />

6028-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

6028-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CHZ10144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2 10144-00000<br />

CH210223-OW00<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH21014e00000<br />

CH210223-00000<br />

CH21022CDUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144MKxx)<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2 I01 4400000<br />

CH21022300000<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

l8FEBl 991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEB1991<br />

18FEBl991<br />

18FEB1991<br />

1 8FEB1 991<br />

03APRI 991<br />

03MAY1991<br />

03MAY 1991<br />

03APR1991<br />

O3MAY 1991<br />

03MAY I991<br />

03APR1991<br />

03MAY I991<br />

03MAYI991<br />

1 9OCTl 992<br />

03APRl991<br />

03MAYl991<br />

03MAY 1991<br />

19OCTl992<br />

03APRl991<br />

03MAY 199 1<br />

03MAYl991<br />

03APR1991<br />

03MAYl991<br />

03MAYl991<br />

O3APRl 991<br />

03MAYl991<br />

03MAY1991<br />

03APR1991<br />

03MAY1991<br />

03MAYl991<br />

O3APR1991<br />

03MAY1991<br />

OMAYl991<br />

03APR1991<br />

03MAY1991<br />

03MAY 1991<br />

03APRl991<br />

03MAYl991<br />

03MAY 1991<br />

03APRl991<br />

03MAYI 991<br />

03MAYI99I<br />

03APR1991<br />

03MAYl991<br />

03MAYl991<br />

03APR1991<br />

03MAY 1991<br />

03MAYI991<br />

03APR1991<br />

03MAY1991<br />

03MAY 1991<br />

03APRI 991<br />

O3MAYlDDl<br />

03MAY1991<br />

03APR1991<br />

03MAYl991<br />

Page 144 of 176<br />

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WG<br />

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WG<br />

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WG<br />

WG<br />

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WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

9.80E+01<br />

9.30E+01<br />

9.60E+01<br />

8.70E+01<br />

8.60E+01<br />

9.10E+01<br />

9.30E+01<br />

8.90E+01<br />

9.30E+01<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.WE+OO<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.OOE+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

l.lOE+Ol<br />

I .00E+01<br />

1.00E+01<br />

1.10E+01<br />

1.00E+01<br />

1 .00E+01<br />

5.00E+00<br />

5.00E+00<br />

B.WE+W<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

l.lOE+01<br />

1 .00E+01<br />

1 .00E+01<br />

l.lOE+Ol<br />

1.00E+Ol<br />

I.WE+Ol<br />

5.50E+01<br />

5.00E+01<br />

5.00E+O1<br />

l.lOE+Ol<br />

1.00E+01<br />

l.OOE+Ol<br />

l.lOE+Ol<br />

1 .00E+01<br />

1.00E+01<br />

l.lOE+Ol<br />

1.00E+01<br />

1 .00E+01<br />

5.50E+OI<br />

5.00E+OI<br />

U<br />

U<br />

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U<br />

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L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

2,CDinitrophenol 51-28-5 CH210224-DUP 03MAY1991 WG 5.00E+01 U UdL<br />

2 ,4-Dinitroioluene<br />

2,4-Dinitrotoluene<br />

2,CDinitrotoluene<br />

2,6-Dinitrotoluene<br />

2.6-Dinitrotoluene<br />

2,6-Dinitrotoluene<br />

2-Butanone<br />

121-14-2<br />

121 -14-2<br />

121-14-2<br />

606-20-2<br />

606-20-2<br />

606-20-2<br />

78-93-3<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210I 44-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

OJAPR1991<br />

03MAY1991<br />

03MAYl991<br />

03APRI 991<br />

03MAYl991<br />

03MAYl991<br />

O3APRl 991<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

1.10E+01<br />

1.00E+01<br />

1.00E+01<br />

l.lOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

R<br />

UilL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

2-Butanone<br />

2-Butanone<br />

2-Chloronaphthalene<br />

2-Chloronaphthalene<br />

2-Chloronaphthalene<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Chlorophenol<br />

2-Hexanone<br />

2-Hexanone<br />

2-Hexanone<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Methylnaphthalene<br />

2-Melhylphenol<br />

2-Methylphenol<br />

2-Methylphenol<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitroaniline<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

2-Nitrophenol<br />

3,3’-Dichlorobenzidine<br />

3,3’-Dichlorobenzidine<br />

78-93-3<br />

78-93-3<br />

91-58-7<br />

91-58-7<br />

91-58-7<br />

95-57-8<br />

95-57-8<br />

95-57-8<br />

591 -78-6<br />

591-78-6<br />

591-78-6<br />

91-57-6<br />

91-57-6<br />

91-57-6<br />

95-48-7<br />

95-48-7<br />

95-48-7<br />

88-74-4<br />

88-74-4<br />

88-74-4<br />

8875-5<br />

88-75-5<br />

88-75-5<br />

91 -94-1<br />

91-94-1<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH2 10223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH2 10224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2101 44-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

O3MAY 1991<br />

OJMAY 1991<br />

03APRl991<br />

O3MAY 1991<br />

O3MAY 1991<br />

03APRl991<br />

03MAYl991<br />

03MAY1991<br />

03APRl991<br />

03MAY I991<br />

03MAY1991<br />

03APRI991<br />

OMAY 1991<br />

03MAY1991<br />

O3APRl 991<br />

03MAY I991<br />

03MAY 1991<br />

03APR 1991<br />

03MAY1991<br />

03MAY1991<br />

03APR1991<br />

03MAY1991<br />

03MAYI 991<br />

03APRl991<br />

03MAY I991<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

l.OOE+OI<br />

l.OOE+Ol<br />

l.lOE+Ol<br />

l.OOE+Ol<br />

l.OOE+OI<br />

I.lOE+OI<br />

l.OOE+OI<br />

l.OOE+Ol<br />

1.00E+01<br />

1.00E+01<br />

l.OOE+OI<br />

l.lOE+Ol<br />

1 .00E+01<br />

l.OOE+Ol<br />

l.lOE+Ol<br />

l.OOE+OI<br />

l.OOE+OI<br />

5.5OE+O1<br />

5 .OOE+O 1<br />

5.00E+01<br />

l.lOE+Ol<br />

1 .OOE+OI<br />

l.OOE+Ol<br />

2.20€+01<br />

2.00E+01<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

ug/L<br />

uglL<br />

uglL<br />

uglL<br />

ugn<br />

u9R<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

ugR<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

3,3’-Dichlorobenzidine 91-94-1<br />

CH210224-DUP 03MAYI991 WG 2.00E+01<br />

U<br />

Ug/L<br />

3-Nitroaniline<br />

99-09-2<br />

CH210144-00000 03APR1991 WG S.SOE+OI<br />

U<br />

uglL<br />

3-Nitroaniline<br />

3-Nitroaniline<br />

99-09-2<br />

99-09-2<br />

CH210223-00000<br />

CH210224-DUP<br />

03MAYl991<br />

03MAYl991<br />

WG<br />

WG<br />

5.00E+01<br />

5.00E+01<br />

U<br />

U<br />

uglL<br />

ugfl<br />

4,6-Dinitro-2-methylphenol 534-52-1<br />

CH2lOi 44-00000 03APRI 991 WG 5.50E+01<br />

U<br />

uglL<br />

4,6-Dinitro-2-methylphenol<br />

4,6-Dinlro-2-methylphenol<br />

4-Bromophenyl-phenylether<br />

534-52-1<br />

53452-1<br />

101-55-3<br />

CH210223-00000<br />

CH210224DUP<br />

CH210144-00000<br />

03MAY1991<br />

03MAYl991<br />

03APRl991<br />

WG<br />

WG<br />

WG<br />

5.00E+01<br />

5.00€+01<br />

l.lOE+OI<br />

U<br />

U<br />

U<br />

ugR<br />

ugk<br />

ug/L<br />

4-Bromophenyl-phenylether 101-55-3<br />

CH2 10223-~003MAYI991<br />

WG 1.00E+01<br />

U<br />

ugfl<br />

4-Bromophenyl-phenylether<br />

4-Chloro-3-met hylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloro-3-methylphenol<br />

4-Chloroaniline<br />

4-Chloroaniline<br />

CChloroaniline<br />

4-Chlorophen yl-phenylether<br />

4-Chlorophenyl-phen ylelher<br />

4-Chlorophenyl-phenylether<br />

Methyl-2-pentanone<br />

4-Melhyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methylphenol<br />

4-Methylphenol<br />

4-Methylphenol<br />

QNitroaniline<br />

4-Nitroaniline<br />

4-Nitroaniline<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

4-Nitrophenol<br />

101 -55-3<br />

59-50-7<br />

59-50-7<br />

59-50-7<br />

106-47-8<br />

106-47-8<br />

106-47-8<br />

7005-72-3<br />

7005-72-3<br />

7005-72-3<br />

108-10-1<br />

108-10-1<br />

108-10-1<br />

106-44-5<br />

106-44-5<br />

10644-5<br />

100-01 -6<br />

100-01-6<br />

100-01-6<br />

100-02-7<br />

100-02-7<br />

100-02-7<br />

CH210224DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH21014400000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH2 10223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2 1014440000<br />

CH210223-00000<br />

CH210224-DUP<br />

03MAY1991<br />

03APR 1991<br />

03MAYl991<br />

03MAY1991<br />

O3APRl99l<br />

03MAY1991<br />

03MAY 1991<br />

03APR1991<br />

03MAY1991<br />

OWY1991<br />

03APRl991<br />

03MAYI 991<br />

03MAY1991<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

03APRl991<br />

03MAY1991<br />

03MAYl991<br />

03APR1991<br />

03MAYl991<br />

03MAY I99 1<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

I .00E+01<br />

l.lOE+Ol<br />

I .OOE+OI<br />

I .00E+01<br />

l.lOE+Ol<br />

1 .00E+01<br />

1.00E+01<br />

l.lOE+OI<br />

1.00E+01<br />

1.00E+01<br />

1.00E+01<br />

l.WE+OI<br />

1.00E+01<br />

I .10E+01<br />

1.00E+01<br />

l.OOE+OI<br />

5.50E+01<br />

5.00E+01<br />

5.00E+Ol<br />

5.50E+01<br />

5.00E+OI<br />

5.00E+01<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

Acenaphthene<br />

83-32-9<br />

CH21 0144-00000<br />

03APR1991 WG l.IOE+OI<br />

U<br />

ugfl<br />

Acenaphthene<br />

Acenaphthene<br />

Acenaphthylene<br />

Acenaphth ylene<br />

83-32-9<br />

83-32-9<br />

208-96-8<br />

208-96-8<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

03MAY 1991<br />

03MAY I99 1<br />

03APR1991<br />

03MAY1991<br />

WG<br />

WG<br />

WG<br />

WG<br />

1 .OOE+OI<br />

I .00E+01<br />

l.lOE+Ol<br />

1.00E+01<br />

U<br />

U<br />

U<br />

U<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

Acenaphthykne<br />

208-96-8<br />

CH210224-DUP 03MAY1991 WG 1 .00E+01<br />

U<br />

ugfl<br />

Acetone<br />

67-64-1<br />

CH21014400000 03APRl991 WG 1.70€+01<br />

UB<br />

J<br />

ugfl<br />

Acetone<br />

67-64-1<br />

CH21022500000 03MAYI 991 WG 1.50E+01<br />

UB<br />

JB<br />

ugfl<br />

Page 145 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Acetone 67-64-1 CH210224-DUP 03MAY1991 WG 1.20E+01 UB JB uglL<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum, Dissolved<br />

Aluminum, Dissolved<br />

Anthracene<br />

Anthracene<br />

Anthracene<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony, Dissolved<br />

Antimony. Dissolved<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic<br />

Arsenic, Dissolved<br />

Arsenic, Dissolved<br />

Arsenic, Dissolved<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium<br />

Barium, Dissolved<br />

Barium, Dissolved<br />

Barium, dissolved<br />

Benzene<br />

Benzene<br />

Benzene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(b)fluoranthene<br />

Benzo(b)Ruoranthene<br />

Benzo(g.h.i)perylene<br />

Benzo(g,h.i)perylene<br />

Benzo(g,h.i)perylene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzo(k)fluoranthene<br />

Benzoic Acii<br />

471-34-1<br />

471-34-1<br />

471-34-1<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

120-12-7<br />

120-12-7<br />

120-12-7<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

71-43-2<br />

56-55-3<br />

56-55-3<br />

56-55-3<br />

50-32-8<br />

50-32-8<br />

50-32-8<br />

205-99-2<br />

20599-2<br />

20599-2<br />

191-24-2<br />

191 -24-2<br />

191-24-2<br />

207-08-9<br />

207-08-9<br />

207-06-9<br />

65-85-0<br />

4097-92<br />

4821-94<br />

5569 - 93<br />

4097-92<br />

4686-92<br />

4821 -94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4821-94<br />

5569-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH2 10144-OOOOO<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

4686-92<br />

4821 -94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4821-94<br />

5569-93<br />

4097-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH21014e00000<br />

CH210223-00000<br />

CH2 10224-DUP<br />

CH21014400000<br />

CH2 10223-00000<br />

CH210224-DUP<br />

CH210144-OOOOO<br />

CH210223-00000<br />

CH2 10224DUP<br />

CH2 10144-OOOOO<br />

CH210223-00000<br />

CH210224-DUP<br />

CH21014400000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

31JAN1992<br />

3OMAR1992<br />

14MAR1994<br />

23JUNl993<br />

190CT1992<br />

03APR1991<br />

03APR1991<br />

03MAY1991<br />

03MAY1991<br />

14MAR1994<br />

23JUNl993<br />

03APRl991<br />

03MAYl991<br />

03MAYl991<br />

30MAR1992<br />

14MAR1994<br />

23JUNl993<br />

19OCTl992<br />

03APRl991<br />

03APRl991<br />

03MAY1991<br />

03MAY 1991<br />

31 JAN1992<br />

14MAR 1994<br />

23JUN1993<br />

31JAN1992<br />

3OMAR1992<br />

14MAR1994<br />

23JUNl993<br />

190CT1992<br />

03APR1991<br />

03APRl991<br />

03MAY1991<br />

03MAYl991<br />

31JANl992<br />

14MAR1994<br />

23JUN1993<br />

3lJANl992<br />

3oMAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APR1991<br />

03APR1991<br />

03MAY1991<br />

03MAY 1991<br />

14MARl994<br />

23JUN1993<br />

31JAN1992<br />

03APRl991<br />

03MAY 1991<br />

03MAYl991<br />

03APRl991<br />

03MAYl991<br />

03MAYl991<br />

03APR1991<br />

03MAY 1991<br />

03MAY 1991<br />

03APRI991<br />

03MAY 1991<br />

03MAYl991<br />

O3APR 1991<br />

03MAY1991<br />

03MAY 1991<br />

03APRl991<br />

03MAY 199 1<br />

03MAYl991<br />

03APR1991<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

\M3<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

5.40E+02<br />

2.70E+02<br />

5.52E+02<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

2.30E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.lOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+W<br />

O.WE+W<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+W<br />

O.WE+OO<br />

0.00E+00<br />

0.00E+00<br />

5.00E+00<br />

S.OOE+OO<br />

5.00E+OO<br />

l.lOE+Ol<br />

l.WE+Ol<br />

l.OOE+Ol<br />

1.10E+01<br />

l.OOE+Ol<br />

1 .00E+01<br />

l.lOE+Ol<br />

1 .OOE+01<br />

1.00E+Ol<br />

l.lOE+Ol<br />

1.00E+01<br />

l.OOE+Ol<br />

l.lOE+Ol<br />

1 .WE+Ol<br />

l.WE+Ol<br />

5.50E+01<br />

E<br />

UE<br />

U'<br />

U'<br />

U<br />

U<br />

U<br />

<<br />

<<br />

<<br />

<<br />

U<br />

U<br />

UN<br />

UN<br />

<<br />

<<br />

<<br />

BNS<br />

BNS<br />

BWN<br />

BWN<br />

E<br />

BE<br />

B<br />

B<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

H<br />

N<br />

N<br />

N<br />

H<br />

H<br />

N<br />

JE<br />

E<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

N<br />

N<br />

JBNS<br />

JBNS<br />

JBWN<br />

JBW<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

H<br />

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JE<br />

JBE<br />

B<br />

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N<br />

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N<br />

Page 146 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL'fTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Benzoic Acid 65-85-0 CH210223-00000 03MAY1991 WG 5.00E+01 U uglL<br />

Benzoic Acid<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Alcohol<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Benzyl Butyl Phthalate<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium<br />

Beryllium, Dissolved<br />

Beryllium, Dissolved<br />

Beryllium, Dissolved<br />

Bismuth<br />

Bismuth<br />

Bismuth<br />

Bismuth, Dissolved<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Bromoform<br />

Bromoform<br />

Bromoform<br />

Bromomethane<br />

Bromomethane<br />

Bromomethane<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium, Dissolved<br />

Cadmium, Dissolved<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium, Dissolved<br />

Calcium, Dissolved<br />

Calcium, Dissolved<br />

Calcium.Dissolved<br />

Carbon Disulfide<br />

Carbon Disulfide<br />

Carbon Disulfide<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chlorobenzene<br />

Chlorobenzene<br />

65-85-0<br />

100-51-6<br />

100-51 -6<br />

100-51 -6<br />

85-68-7<br />

85-68-7<br />

85-68-7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41 -7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-41 -7<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

7440-69-9<br />

75-27-4<br />

75-27-4<br />

75-27-4<br />

75-25-2<br />

75-25-2<br />

75-25-2<br />

74-83-9<br />

74-83-9<br />

74-83-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

744043-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

75-15-0<br />

75-15-0<br />

75-15-0<br />

56-23-5<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

108-90-7<br />

108-90-7<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH2 10144-DIS<br />

CH2 10223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

4686-92<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH2 10223-00000<br />

CH2 10224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-OOOOO<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH2I 0224-DUPDI<br />

4097-92<br />

4821 -94<br />

5569-93<br />

4821 -94<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224DUP<br />

4097-92<br />

4821-94<br />

5569-93<br />

CH21014400000<br />

CH210223-00000<br />

CH210224DUP<br />

CH210144-00000<br />

CH210223-00000<br />

O3MAY 1991<br />

03APR1991<br />

03MAY 1 991<br />

O3MAY 1991<br />

03APR1991<br />

O3MAY 1991<br />

03MAY 1991<br />

31 JANl 992<br />

3OMAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APRl991<br />

03APR1991<br />

03MAY1991<br />

03MAY1991<br />

31 JAN1992<br />

14MAR1994<br />

23JUN1993<br />

31 JANl 992<br />

30MAR1992<br />

190CT1992<br />

31 JANl 992<br />

03APRl991<br />

03MAY 1991<br />

03MAY1991<br />

03APRl991<br />

03MAYl991<br />

03MAYl991<br />

03APRI 991<br />

03MAY 1991<br />

03MAYI 991<br />

31 JANl 992<br />

3OMAR1992<br />

14MARl994<br />

23JUN1993<br />

190CTl992<br />

O3APRl 991<br />

O3APRl 991<br />

03MAY 1991<br />

03MAY I991<br />

31 JAN1992<br />

14MAR1994<br />

23JUN1993<br />

31JAN1992<br />

30MAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APR1991<br />

03APR1991<br />

03MAY1991<br />

03MAY 1991<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

14MAR1994<br />

O3APRl 99 1<br />

03MAY 1991<br />

O3MAY1991<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

31 JANl 992<br />

14MAR1994<br />

23JUN1993<br />

03APR199 1<br />

03MAY 1991<br />

03MAY1991<br />

03APR1991<br />

03MAYi991<br />

Page 147 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

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WG<br />

WG<br />

WG<br />

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\NG<br />

WG<br />

5.00E+01<br />

1.10E+01<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.IOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00€+00<br />

0.00€+00<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00€+00<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

I .00€+01<br />

0.00E+00<br />

0.00€+00<br />

0.00€+00<br />

0.00E+00<br />

0.00€+00<br />

0.00€+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

0.00E+00<br />

1.15E+02<br />

1.09E+02<br />

1.26E+02<br />

1.18E+02<br />

9.80E+01<br />

2.12E+02<br />

2.09E+02<br />

I .85E+02<br />

1.82E+02<br />

1.14E+02<br />

1.39€+02<br />

1.17€+02<br />

1.39E+02<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+OO<br />

5.00€+00<br />

1.40E+OI<br />

7.00€+00<br />

8.00E+00<br />

I .60€+01<br />

1.60€+01<br />

1.60€+01<br />

5.00E+00<br />

5.00€+00<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

C<br />

<<br />

C<br />

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C<br />

B<br />

U<br />

U<br />

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C<br />

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U<br />

U<br />

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U<br />

U<br />

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C<br />

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U<br />

U<br />

U<br />

U<br />

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E<br />

E<br />

U<br />

U<br />

N<br />

N<br />

N<br />

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N<br />

N<br />

H<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

H<br />

N<br />

JE<br />

JE<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

uglL<br />

ugfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chlorobenzene 10890-7 CH210224-DUP 03MAY1991 WG 5.00E+00 U uglL<br />

Chloroethane<br />

Chloroethane<br />

Chloroethane<br />

Chloroform<br />

Chloroform<br />

Chloroform<br />

Chloromethane<br />

Chloromethane<br />

Chloromethane<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium, Dissolved<br />

Chromium, Dissolved<br />

Chromium, Dissolved<br />

Chrysene<br />

Chrysene<br />

Chrysene<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt<br />

Cobalt<br />

Cobalt, Dissolved<br />

Cobalt. Dissolved<br />

Cobalt. Dissolved<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

copper<br />

Copper, Dissolved<br />

Copper, Dissolved<br />

Copper, Dissolved<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Cyanide<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Di-n-butylphthalate<br />

Di-noctylphthalale<br />

Di-n-octylphthalate<br />

Di-n-octylphthalate<br />

Dibenzo(a,h)anlhracene<br />

Dibenzo(a.h)anthracene<br />

Dibenzo(a,h)anthracene<br />

Dibenzofuran<br />

Dibenzofuran<br />

75-00-3<br />

75-00-3<br />

75-00-3<br />

67-66-3<br />

67-66-3<br />

67-66-3<br />

74-87-3<br />

74-87-3<br />

74-87-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

216-01 -9<br />

218-01-9<br />

218-01-9<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

7440-4a-4<br />

744048-4<br />

7440-48-4<br />

740-48-4<br />

7440-48-4<br />

7440-484<br />

7440-4a-4<br />

7440-484<br />

7440-50-8<br />

7440-50-8<br />

740-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

57-12-5<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

84-74-2<br />

84-74-2<br />

04-74-2<br />

117840<br />

117-84-0<br />

117840<br />

53-70-3<br />

53-70-3<br />

53-70-3<br />

132-64-9<br />

132-64-9<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4686-92<br />

4821 -94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH2 10223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH2I 0144-OoooO<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH2 10224-DUPD I<br />

4097-92<br />

4821 -94<br />

5569-93<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

CH210144-00000<br />

CH210144-00000<br />

CH210223-00000<br />

CH210223-DIS<br />

CH210226DUP<br />

CH210224-DUPDI<br />

4686-92<br />

4821-94<br />

5569-93<br />

5877-94<br />

6028-92<br />

6703-94<br />

6796-93<br />

7756-93<br />

CH21014440000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH21014400000<br />

CH21022J-00000<br />

CH210224DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

03APR1991<br />

OMAY 1991<br />

03MAY1991<br />

03APR1991<br />

O3MAYl 991<br />

03MAY1991<br />

03APR1991<br />

03MAY1991<br />

03MAY1991<br />

30MAR1992<br />

14MAR1994<br />

23JUNl993<br />

190CT1992<br />

03APRI 991<br />

03APR1991<br />

O3MAY I991<br />

03MAY1991<br />

3lJAN1992<br />

14MAR1994<br />

23JUN1993<br />

03APR1991<br />

03MAY 1991<br />

OWY1991<br />

31 JAN1 992<br />

30MAR1992<br />

14MARI 994<br />

23JUN1993<br />

190CT1992<br />

O3APR 1991<br />

O3APRl 991<br />

OMAY 1991<br />

03MAYI 991<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

30MAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APRl991<br />

O3APRl 991<br />

03MAY 1991<br />

OjMAYl991<br />

31 JAN1992<br />

14MAR1994<br />

23JUN1993<br />

03APR 1991<br />

03APR1991<br />

03MAY 1991<br />

03MAYl991<br />

03MAYI 991<br />

03MAY1991<br />

3OMARI 992<br />

14MAR1994<br />

23JUNl993<br />

29JUN1994<br />

190CT1992<br />

O6SEP1 994<br />

21SEP1993<br />

08DECl993<br />

O3APRI991<br />

OJMAYI99I<br />

OWY I991<br />

03APRI 991<br />

03MAY I991<br />

OWYl991<br />

03APR1991<br />

OWAYI 991<br />

03MAYl991<br />

03APR1991<br />

03MAY 1991<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

<<br />

c<br />

<<br />

<<br />

U<br />

U<br />

U<br />

<<br />

<<br />

<<br />

U<br />

U<br />

U<br />

<<br />

<<br />

<<br />

<<br />

<<br />

B<br />

B<br />

B<br />

B<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

UN<br />

UN<br />

U<br />

U<br />

<<br />

<<br />

<<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

UJB<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

N<br />

N<br />

N<br />

N<br />

Page 148 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Dibenzofuran 132-64-9 CH210224-DUP 03MAY1991 WG 1.00E+01 U ug1L<br />

Dibromochloromethane<br />

Dibromochloromet hane<br />

Dibromochloromethane<br />

Diethylphthalate<br />

Diethylphthalate<br />

Diethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dimethylphthalate<br />

Dissolved Oxygen<br />

Dissolved Oxygen<br />

Dissolved Oxygen<br />

Dissolved Oxygen<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Dissolved Solids<br />

Ethylbenzene<br />

Elhylbenzene<br />

Ethylbenzene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluoranthene<br />

Fluorene<br />

Fluorene<br />

Fluorene<br />

Fluoride '<br />

Fluoride<br />

GC/MS Scan<br />

Gamma Activity<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Alpha<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Gross Beta<br />

Hardness as CaC03<br />

Hardness as CaCO3<br />

Hardness as CaC03<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobenzene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorobutadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachlorocyclopentadiene<br />

Hexachloroethane<br />

Hexachloroethane<br />

Hexachloroethane<br />

Indeno(l,2.3-cd)pyrene<br />

Indeno(l,2.3-cd)pyrene<br />

Indeno(l,2.3-cd)pyrene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron. Dissolved<br />

124-40-1<br />

124-48-1<br />

124-40-1<br />

04-66-2<br />

04-66-2<br />

84-664<br />

131-11-3<br />

131 -11-3<br />

131-11-3<br />

OXYGEN DIS<br />

OXYGEN DIS<br />

OXYGEN DIS<br />

OXYGEN DIS<br />

OXYGEN DIS<br />

SO266<br />

SO266<br />

100-41 -4<br />

100-41 -4<br />

100-41 -4<br />

206-44-0<br />

206-44-0<br />

206-44-0<br />

06-73-7<br />

06-73-7<br />

06-73-7<br />

16904-40-0<br />

16904-40-0<br />

GCNS SCAN<br />

GAMMA<br />

12587-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-46-1<br />

12507-47-2<br />

12587-47-2<br />

12507-47-2<br />

12587-47-2<br />

12507-47-2<br />

12507-47-2<br />

12507-47-2<br />

CACO3HARDNES<br />

CAC03HARDNES<br />

CACOJHARDNES<br />

118-74-1<br />

110-74-1<br />

110-74-1<br />

07-60-3<br />

07-60-3<br />

87-60-3<br />

77-47-4<br />

77-47-4<br />

77-47-4<br />

67-72-1<br />

67 -72- 1<br />

67-72-1<br />

193-39-5<br />

193-39-5<br />

193-39-5<br />

7439-09-6<br />

7439-89-6<br />

7439-89-6<br />

7439-09-6<br />

7439-89-6<br />

7439-89-6<br />

7439-09-6<br />

7439-09-6<br />

7439-89-6<br />

7439-09-6<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH2 10223-OOOOO<br />

CH210224-DUP<br />

CH210144-00000<br />

CH2 10223-00000<br />

CH2 10224-DUP<br />

4821-94<br />

5569-93<br />

6703-94<br />

6796-93<br />

7756-93<br />

4021-94<br />

5569-93<br />

CH210144-00000<br />

CH2 10223-00000<br />

CH2 10224-DUP<br />

CH2I 0144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2 10144-00000<br />

CH2 10223-00000<br />

CH210224-DUP<br />

4821-94<br />

5569-93<br />

4686-92<br />

4686-92<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6703-94<br />

6796-93<br />

7756-93<br />

4097-92<br />

4606-92<br />

4821-94<br />

5569-93<br />

6703-94<br />

6796-93<br />

7756-93<br />

CH210144-00000<br />

CH2 10223-OOOOO<br />

CH210224-DUP<br />

CH2101 44-00000<br />

CH210223-00000<br />

CH2 10224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4686-92<br />

4021-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

03APR1991<br />

O3MAY1 991<br />

O3MAYl99l<br />

03APR1991<br />

03MAY1991<br />

03MAY 1 99 1<br />

03APR1991<br />

03MAY 1991<br />

03MAY1991<br />

14MARI 994<br />

23JUN1993<br />

O6SEPl 994<br />

21 SEP1993<br />

O8DEC1993<br />

14MAR1994<br />

23JUN1993<br />

03APR1991<br />

03MAY 1991<br />

03MAY 1991<br />

03APR1991<br />

03MAY 1991<br />

03MAY I99 1<br />

03APR1991<br />

03MAY1991<br />

03MAY 1991<br />

14MARI 994<br />

23JUN1993<br />

30MAR1992<br />

30MARI 992<br />

31 JAN1992<br />

3OMAR1992<br />

14MAR 1994<br />

23JUN1993<br />

06SEP1994<br />

21 SEPl993<br />

08DECI993<br />

31JAN1992<br />

30MARl992<br />

14MAR1994<br />

23JUN1993<br />

06SEPI 994<br />

2lSEP1993<br />

08DEC1993<br />

03APRl991<br />

03MAYl991<br />

03MAY1991<br />

03APRl991<br />

03MAY 1991<br />

03MAY1991<br />

OWR1991<br />

03MAYl991<br />

03MAY1991<br />

03APR1991<br />

03MAY1991<br />

03MAY 199 1<br />

03APR1991<br />

03MAY 1991<br />

03MAY1991<br />

03APR1991<br />

03MAYI 991<br />

03MAY 1991<br />

31 JAN1992<br />

30MAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APRl991<br />

03APR1991<br />

03MAYI 991<br />

03MAY 1991<br />

31JAN1992<br />

Page 149 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

ViG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

nG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

Q<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

E<br />

E<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

J<br />

J<br />

J<br />

N<br />

N<br />

N<br />

H<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

N<br />

JE<br />

JE<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug/L<br />

uglL<br />

uglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

w/L<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

ug/L<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

uglL<br />

pCi<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pciR<br />

pCiL<br />

mglL CaC03<br />

mglL CaC03<br />

mglL CaC03<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

0gIL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mSn<br />

mg1L<br />

mglL<br />

WlL<br />

mgk<br />

mglL<br />

WlL<br />

WlL<br />

WlL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALWE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Iron. Dissolved 7439-89-6 4821 -94 14MAR1994 WG 8.10E+01 N mglL<br />

Iron. Dissolved<br />

lsophorone<br />

lsophorone<br />

lsophorone<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead, Dissolved<br />

Lithium<br />

Lithium<br />

Lithium, Dissolved<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium, Dissolved<br />

Magnesium, Dissolved<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese, Dissolved<br />

Manganese, Dissolved<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury. Dissolved<br />

Methylene Chloride<br />

Methylene Chloride<br />

Methylene Chloride<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum<br />

Molybdenum, Dissolved<br />

Molybdenum, Dissolved<br />

Molybdenum, Dissolved<br />

N-Nitroso-di-n-propyhmine<br />

N-Nitroso-di-n-propybmine<br />

N-Nitroso-di-n-propylamine<br />

N-Nitrosodiphenybrnine<br />

N-Nlrosodiphenylamine<br />

N-Nitrosodiphenylarnine<br />

Naphthalene<br />

Naphthalene<br />

Naphthalene<br />

Neptunium-237<br />

Neptunium-237<br />

Neptunium237<br />

Nickel<br />

Nickel<br />

Nickel<br />

7439-89-6<br />

78-59-1<br />

78-59-1<br />

78-59-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-965<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

7439-97-6<br />

75-09-2<br />

75-09-2<br />

75-09-2<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

7439-98-7<br />

621 -64-7<br />

621-64-7<br />

621-64-7<br />

86-30-6<br />

86-30-6<br />

86-30-6<br />

91-20-3<br />

91-20-3<br />

91-20-3<br />

13994-20-2<br />

13994-20-2<br />

13994-20-2<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

5569-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4686 - 92<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH2 10224-DUPDI<br />

4097-92<br />

4097-92<br />

6028-92<br />

4097-92<br />

4097-92<br />

4821-94<br />

5569 - 93<br />

602892<br />

CH210144-OOOW<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4686-92<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

4097-92<br />

4821-94<br />

5569-93<br />

CH21014400000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2I 0144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

468692<br />

4821-94<br />

23JUN1993<br />

O3APRl 991<br />

03MAYI 991<br />

O3MAY 1991<br />

31JANl992<br />

30MAR1992<br />

190CT1992<br />

03APR1991<br />

03APR1991<br />

O3MAY 1991<br />

O3MAY 1991<br />

31JAN1992<br />

31 JANl 992<br />

190CT1992<br />

31JAN1992<br />

3lJANl992<br />

14MAR1994<br />

23JUNl993<br />

190CT1992<br />

03APR1991<br />

O3APRl99l<br />

O3MAY 1991<br />

O3MAY 1991<br />

31 JANl 992<br />

14MAR1994<br />

23JUN1993<br />

31JANl992<br />

3OMARl992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APR1991<br />

03APR 199 1<br />

03MAYl991<br />

03MAYl991<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

3OMAR1992<br />

190CT1992<br />

03APR1991<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

31JAN1992<br />

03APR1991<br />

03MAY 1991<br />

03MAY 1991<br />

31 JAN1992<br />

3OMAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

03APR1991<br />

03MAY1991<br />

03MAYl991<br />

03APRl991<br />

03MAY1991<br />

03MAY 1991<br />

03APR1991<br />

03MAYl991<br />

03MAY1991<br />

03APR1991<br />

03MAY 1991<br />

03MAY 1991<br />

31 JAN1992<br />

3OMAR1992<br />

1-1994<br />

Page 150 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WI;<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

6.60E+01<br />

l.lOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

3.70E+01<br />

3.10E+01<br />

3.60E+01<br />

3.30€+01<br />

<strong>4.</strong>50E+OI<br />

<strong>4.</strong>20E+01<br />

<strong>4.</strong>60E+01<br />

<strong>4.</strong>50E+01<br />

3.60E+01<br />

3.20E+01<br />

3.60E+01<br />

6.00E+00<br />

6.WE+00<br />

6.WE+W<br />

7.00E+00<br />

5.00E+00<br />

9.00E+00<br />

8.00E+00<br />

7.00E+00<br />

7.00E+00<br />

6.WE+W<br />

6.00E+W<br />

7.00E+00<br />

0.00E+00<br />

O.OOE+W<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

5.00E+00<br />

2.20E+01<br />

1.60E+01<br />

0.00E+00<br />

0.00E+00<br />

O.WE+W<br />

0.00E+00<br />

0.00E+00<br />

0.00E+W<br />

O.WE+W<br />

0.00E+00<br />

l.lOE+Ol<br />

1 .WE+Ol<br />

l.OOE+Ol<br />

1 .IOE+OI<br />

1 .00E+01<br />

1.00E+Ol<br />

1 .lOE+Ol<br />

l.OOE+Ol<br />

1.00E+Ol<br />

O.OOE+W 1.01E+00<br />

0.00E+00 9.00E-02<br />

O.OOE+OO 9.00E-02<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+W<br />

U<br />

U<br />

U<br />

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c<br />

<<br />

NS<br />

NW<br />

UWN<br />

UWN<br />

c<br />

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NE<br />

NE<br />

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U<br />

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UJB<br />

UB<br />

UB<br />

<<br />

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U<br />

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N<br />

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JNW<br />

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N<br />

N<br />

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H<br />

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JE<br />

N<br />

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JNE<br />

N<br />

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N<br />

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N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Nickel 7440-02-0 5569-93 23JUN1993 WG O.OOE+OO c mglL<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel. Dissolved<br />

Nickel, Dissolved<br />

Nickel, Dissolved<br />

Niobium<br />

Niobium<br />

Niobium, Dissolved<br />

Nitrate<br />

Nitrate<br />

Nitrate<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrobenzene<br />

Nitrobenzene<br />

Nitrobenzene<br />

PCB-1016<br />

PCB-1016<br />

PCB-1221<br />

PCB-1221<br />

PCB-1232<br />

PCB-1232<br />

PCB-I 242<br />

PCB-1242<br />

PCB-1248<br />

PCB-1248<br />

PCB-1254<br />

PCB-1254<br />

PCB-1260<br />

PCB-1260<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Pentachlorophenol<br />

Phenanthrene<br />

Phenanthrene<br />

Phenanthrene<br />

Phenol<br />

Phenol<br />

Phenol<br />

Phosphate<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus (P)<br />

Phosphorus, Dissolved<br />

Plutonium-239<br />

Plutonium-239<br />

Plutonium-239<br />

Plutonium239<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium. Dissolved<br />

Potassium, Dissolved<br />

Potassium, Dissolved<br />

Pyrene<br />

Pyrene<br />

Pyrene<br />

RAD Alpha<br />

RAD Beta<br />

Ruthenium<br />

Ruthenium<br />

Ruthenium<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

7440-03-1<br />

14797-55-8<br />

14797-55-8<br />

14797-55-8<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

N ITRATEASN IT<br />

98 - 95 - 3<br />

98-95-3<br />

98-95-3<br />

12674-11-2<br />

12674-11-2<br />

I1 104-28-2<br />

11104-28-2<br />

11141 -16-5<br />

11141-16-5<br />

53469-21-9<br />

53469-21-9<br />

12672-29-6<br />

12672-29-6<br />

11097-69-1<br />

11097-69-1<br />

11096-82-5<br />

11096-82-5<br />

87-86-5<br />

87-86-5<br />

87-86-5<br />

85-01-8<br />

85-01-8<br />

85-01 -8<br />

108-95-2<br />

108-95-2<br />

108-95-2<br />

14265-44-2<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

7723-14-0<br />

15117-48-3<br />

15117-48-3<br />

15117-48-3<br />

15117-48-3<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

129-00-0<br />

129-00-0<br />

129-00-0<br />

12587-46-1<br />

12587-47-2<br />

7440-18-8<br />

7440-18-8<br />

7440-18-8<br />

6028-92<br />

CH210144-00000<br />

CH210144-DlS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH2 10224-DUP<br />

4097-92<br />

4821-94<br />

5569-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2 10223-OW00<br />

CH210224-DUP<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2 10223-00000<br />

CH210224-DUP<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-ooOOO<br />

CH210223-00000<br />

CH210224DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4097-92<br />

4686-92<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH21022CDUPDI<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821 -94<br />

5569-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

5569-93<br />

5569-93<br />

4097-92<br />

4686-92<br />

6028-92<br />

190CT1992<br />

03APR1991<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

31 JAN1 992<br />

14MARl994<br />

23JUNl993<br />

31 JANl 992<br />

190CT1992<br />

31JAN1992<br />

03APR1991<br />

OMAY 1991<br />

03MAY1991<br />

31JANl992<br />

14MAR1994<br />

23JUN1993<br />

03APR1991<br />

OMAYI 991<br />

03MAY1991<br />

03MAY 1991<br />

03MAY1991<br />

03MAY1991<br />

O3MAY 1991<br />

03MAY1991<br />

03MAY1991<br />

03MAY 1991<br />

03MAY 1991<br />

03MAY 1991<br />

03MAY 1991<br />

03MAYI 991<br />

03MAYI 991<br />

03MAY I991<br />

03MAY1991<br />

O3APRl 991<br />

03MAY1991<br />

03MAY1991<br />

03APR1991<br />

03MAY1991<br />

03MAY I991<br />

03APRI991<br />

03MAYl991<br />

03MAY1991<br />

31 JANl 992<br />

31JAN1992<br />

3OMAR1992<br />

190CTl992<br />

31JAN1992<br />

O3APRl 991<br />

03APRl991<br />

03MAY1991<br />

03MAYl991<br />

3OMARl 992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

O3APRl 991<br />

03APR1991<br />

03MAYl991<br />

03MAYI 991<br />

31 JAN1992<br />

14MAR1994<br />

23JUN1993<br />

03APR1991<br />

03MAY 1991<br />

OJMAY1991<br />

2UUN1993<br />

2UUN1993<br />

31JAN1992<br />

3OMAR1992<br />

190CT1992<br />

Page 151 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

v\EG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

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WG<br />

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WG<br />

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WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

I .00E+00<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.lOE+Ol<br />

1.00E+01<br />

l.OOE+OI<br />

3.00E+00<br />

3.00E+00<br />

3.OOE+00<br />

3.OOE+00<br />

3.00E+00<br />

3.WE+00<br />

3.00E+00<br />

3.00E+00<br />

3.00E+00<br />

3.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.WE+00<br />

5.00E+W<br />

S.SOE+Ol<br />

5.00E+01<br />

5.00E+01<br />

l.lOE+OI<br />

1.00E+00<br />

1.00E+00<br />

l.lOE+Ol<br />

l.OOE+OI<br />

l.OOE+OI<br />

2.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO 9.11E-02<br />

O.OOE+OO 7.40E-02<br />

O.OOE+OO 2.00E-01<br />

O.WE+OO 1.30E-01<br />

1.20E+01<br />

1.20E+01<br />

1.20E+01<br />

1.20E+Ol<br />

1.50E+01<br />

1.30E+01<br />

1.30E+01<br />

1.30E+01<br />

1.40E+01<br />

1.20E+01<br />

I .2OE+O1<br />

I .00E+00<br />

1.00E+01<br />

l.WE+Ol<br />

l.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

e<br />

B<br />

U<br />

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N<br />

H<br />

H<br />

N<br />

N<br />

N<br />

N<br />

J<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

UgR<br />

uglL<br />

UdL<br />

ugk<br />

ug1L<br />

uglL<br />

ug1L<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

WIL<br />

mg1L<br />

pCiL<br />

pCiL<br />

pCUL<br />

pCUL<br />

mglL<br />

mgk<br />

mgk<br />

W L<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mg/L<br />

mg/L<br />

mg/L<br />

Usn<br />

ugfl<br />

ugk<br />

pCilml<br />

pCi/ml<br />

mgk<br />

mgk<br />

mgk


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Ruthenium, Dissolved 7440-18-8 4097-92 31JAN1992 WG O.OOE+OO < N mglL<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium, Dissolved<br />

Semi-Volatile Organic Qual<br />

Silica<br />

Silica<br />

Silicon<br />

Silicon<br />

Silicon, Dissolved<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver<br />

Silver, dissolved<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium, Dissolved<br />

Sodium, Dissolved<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Strontium<br />

Strontium<br />

Strontium<br />

Strontium, Dissolved<br />

Styrene<br />

Styrene<br />

Styrene<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfide<br />

Sulfide<br />

Sulfide<br />

Tantalum<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

SVOL<br />

7631 -86-9<br />

7631 -86-9<br />

7440-21-3<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440-22-<strong>4.</strong><br />

7440-224<br />

7440-22-4<br />

7440-22-4<br />

7440-22-4<br />

7440 - 23 - 5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

7440-24-6<br />

100-42-5<br />

100-42-5<br />

100-42-5<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

1214345-2<br />

1214345-2<br />

12143-45-2<br />

18496-25-8<br />

18496-25-8<br />

18496-25-8<br />

7440-25-7<br />

4097-92<br />

4686-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4097-92<br />

4821-94<br />

5569-93<br />

4097-92<br />

6028-92<br />

4097-92<br />

4097-92<br />

4686-92<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH2 10223-DIS<br />

CH2 10224-DUPDI<br />

4097-92<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821 -94<br />

5569-93<br />

4686-92<br />

4821-94<br />

4822-94<br />

4823-94<br />

4824-94<br />

5569-93<br />

5570-93<br />

5571-93<br />

5572-93<br />

6703-94<br />

6704-94<br />

6705-94<br />

6706-94<br />

6796-93<br />

6797-93<br />

6798-93<br />

6799-93<br />

7756-93<br />

7757-93<br />

7758-93<br />

7759-93<br />

4097-92<br />

4686-92<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

482 1-94<br />

5569-93<br />

CH210144MX)o<br />

CH21022J-00000<br />

CH210224DUP<br />

CH2 101 44-00000<br />

CH210223-00000<br />

CH210224DUP<br />

4097-92<br />

31 JANl 992<br />

30MAR1992<br />

03APRl991<br />

03APRl991<br />

O3MAY 1991<br />

03MAY1991<br />

31 JANl 992<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

31 JANl 992<br />

190CT1992<br />

31 JANl 992<br />

31 JANl 992<br />

3OMAR1992<br />

190CT1992<br />

03APRl991<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

31 JAN1992<br />

31JANl992<br />

30MAR1992<br />

1 MAR1994<br />

23JUN1993<br />

19OCTl992<br />

03APR1991<br />

03APR199 1<br />

03MAYl991<br />

03MAY1991<br />

31 JAN1992<br />

14MAR1994<br />

23JUN1993<br />

3OMAR1992<br />

14MAR1994<br />

14MAR1994<br />

14MARl994<br />

14MAR1994<br />

23JUN1993<br />

23JUN1993<br />

23JUN1993<br />

23JUN1993<br />

06SEPl994<br />

06SEPl994<br />

06SEP1994<br />

06SEP1994<br />

21 SEP1993<br />

21 SEPl993<br />

21SEPl993<br />

2lSEP1993<br />

08DEC1993<br />

08DECl993<br />

08DECl993<br />

08DECl993<br />

31 JAN1992<br />

3OMAR1992<br />

190CTl992<br />

31 JAN1992<br />

03APRl991<br />

03MAY 1991<br />

03MAYl991<br />

31JAN1992<br />

14MAR1994<br />

23JUN1993<br />

03APR1991<br />

03MAYl991<br />

03MAY1991<br />

03APR1991<br />

03MAY 1991<br />

03MAY 1991<br />

31 JAN1992<br />

Page 152 of 176<br />

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O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

5.02E+02<br />

2.40E+01<br />

1.20E+01<br />

1.20E+01<br />

l.lOE+Ol<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.WE+OO<br />

O.OOE+OO<br />

2.70E+01<br />

2.60E+01<br />

l.OOE+Ol<br />

2.50E+01<br />

2.50E+01<br />

2.60E+Ol<br />

2.60E+Ol<br />

3.00E+01<br />

2.90E+Ol<br />

2.80E+01<br />

1 .WE+Ol<br />

2.40E+01<br />

1.23E+03<br />

1.26E+03<br />

1.25E+O3<br />

1.25E+03<br />

1.23E+03<br />

1.27E+O3<br />

1.24E+03<br />

1.24E+03<br />

1.24E+O3<br />

1.02€+03<br />

1 .O2E+O3<br />

1.03E+03<br />

1.03E+03<br />

1.09E+03<br />

1.09E+03<br />

1.11E+O3<br />

1.10E+03<br />

1.13E+03<br />

1 .11E+O3<br />

l.llE+O3<br />

1 .lE+O3<br />

l.OOE+OO<br />

l.WE+W<br />

l.OOE+W<br />

1 .WE+W<br />

5.WE+00<br />

5.WE+W<br />

S.WE+W<br />

1.32E+02<br />

2.53E+02<br />

1.77E+02<br />

2.61E+02<br />

2.18E+02<br />

2.11E+02<br />

O.WE+W<br />

O.WE+W<br />

O.WE+W<br />

O.WE+OO<br />

C<br />

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mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

mgfl<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhos/cm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhos/cm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

urnhoslcm<br />

mglL<br />

mglL<br />

wfl<br />

mglL<br />

ug/L<br />

ugfl<br />

ug/L<br />

mgfl<br />

mgfl<br />

mgfl<br />

wfl<br />

mgfl<br />

mgfl<br />

mglL<br />

mglL<br />

mgfl<br />

wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SPMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Tantalum 7440-25-7 4686-92 30MAR1992 WG O.OOE+OO N malL<br />

Tantalum<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Temperature<br />

Temperature<br />

Temperature<br />

Temperature<br />

Temperature<br />

Temperature<br />

Temperature<br />

Telrachloroethene<br />

Tetrachloroethene<br />

Tetrachloroelhene<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium, Dissolved<br />

Thallium, Dissolved<br />

Thallium, Dissolved<br />

Thorium<br />

Thorium, Dissolved<br />

Thorium-230<br />

Thorium-230<br />

Thorium-230<br />

Thorium-230<br />

Tin<br />

Tin<br />

Tin<br />

Tin, Dissolved<br />

Tiianium<br />

Titanium<br />

Tiianium. Dissolved<br />

Toluene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-1.2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroelhene<br />

Tungsten<br />

Tungsten, Dissolved<br />

7440-25-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

SO835<br />

SO835<br />

SO835<br />

SO835<br />

SO835<br />

SO835<br />

127-18-4<br />

127-18-4<br />

127-18-4<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-2a-o<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-2a-o<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

14269-63-7<br />

14269-63-7<br />

14269-63-7<br />

14269-63-7<br />

7440-31-5<br />

7440-31 -5<br />

7440-31 -5<br />

7440-31 -5<br />

7440-32-6<br />

7440-32-6<br />

7440-34-6<br />

108-88-3<br />

108-88-3<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

744044-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

6028-92<br />

1110-91<br />

4686 - 92<br />

4821-94<br />

5569-93<br />

6028-92<br />

6703-94<br />

6796-93<br />

7756-93<br />

CH210144-OW00<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH2 10224-DUPDI<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

6703-94<br />

6796-93<br />

7756-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH210144-M)oO<br />

CHZlO144-DIS<br />

CH2 10223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

482 1-94<br />

5569-93<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4686-92<br />

6028-92<br />

4097-92<br />

4097-92<br />

6028-92<br />

4097-92<br />

CH2 lO144oooOO<br />

CH210223-OOOOO<br />

CH21022CDUP<br />

4821-94<br />

4822-94<br />

4823-94<br />

4824-94<br />

5569-93<br />

5570-93<br />

5571-93<br />

5572-93<br />

6028-92<br />

1110-91<br />

4821-94<br />

5569-93<br />

6028-92<br />

6703-94<br />

6796-93<br />

7756-93<br />

CH2 10144-00000<br />

CH210223-WOO0<br />

CH210224-DUP<br />

6028-92<br />

4097-92<br />

190CT1992<br />

03APR1991<br />

3OMAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

06SEP1994<br />

21 SEP1993<br />

08DEC1993<br />

03APR1991<br />

03APR1991<br />

03MAY1991<br />

03MAY1991<br />

30MAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

06SEP1994<br />

21SEPl993<br />

08DEC1993<br />

03APR1991<br />

03MAY1991<br />

03MAYl991<br />

3OMAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

03APRl991<br />

03APR1991<br />

03MAY 1991<br />

03MAY 1991<br />

31JAN1992<br />

14MARl994<br />

23JUN1993<br />

190CT1992<br />

3lJAN1992<br />

03APR1991<br />

03APRl991<br />

03MAYl991<br />

03MAY1991<br />

31JAN1992<br />

3OMAR1992<br />

190CT1992<br />

31JAN1992<br />

31 JANl 992<br />

190CT1992<br />

3lJAN1992<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

1 MAR1994<br />

1 MAR1 994<br />

14MAR1994<br />

14MAR1994<br />

23JUN1993<br />

23JUN1993<br />

23JUN1993<br />

23JUN1993<br />

190CT1992<br />

03APR1991<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

06SEP1994<br />

21SEP1993<br />

OBDEC1993<br />

03APRl991<br />

03MAY1991<br />

03MAY1991<br />

190CTl992<br />

31 JANl 992<br />

Page 153 of 176<br />

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N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

H<br />

H<br />

H<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCVL<br />

pCilL<br />

pCVL<br />

pCilL<br />

pCVL<br />

pCilL<br />

pCilL<br />

pCVL<br />

F<br />

F<br />

F<br />

F<br />

F<br />

F<br />

F<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

pCilL<br />

pCA<br />

pCiL<br />

pCilL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

mg/L<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

WlL<br />

WlL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE NPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Turbidity SO278 4097-92 31JAN1992 WG 1.52E+02 N NTU<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Uranium-234<br />

Uranium-234<br />

Uranium-234<br />

Uranium-234<br />

Uranium-235<br />

Uranium235<br />

Uranium-235<br />

Uranium-235<br />

Uranium238<br />

Uranium-238<br />

Uranium-238<br />

Uranium-238<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium, Dissolved<br />

Vanadium, Dissolved<br />

Vanadium, Dissolved<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc. Dissolved<br />

Zinc, Dissolved<br />

Zinc, Dissolved<br />

Zirconium<br />

Zirconium<br />

Zirconium, Dissolved<br />

bis(2-Ch1oroethoxy)methane<br />

bis(2-Chloroethoxy)methane<br />

bis(2-Ch1oroethoxy)methane<br />

bis(2-Chloroethy Qether<br />

bis(2-Ch1oroethyl)ether<br />

bis(2-ChloroethyQether<br />

bis(2-ChloroisopropyQether<br />

bis(2-ChloroisopropyI)ether<br />

bis(2-ChloroisopropyQether<br />

bk(2-EthylhexyQphthabte<br />

bis(2-EthylhexyQphthalate<br />

bis(2-EthylhexyQphthabte<br />

cis-I .Z-dichloroethene<br />

cis-I .3-Dichloropropene<br />

cis-I .3-Dichloropropene<br />

SO278<br />

SO278<br />

SO278<br />

SO278<br />

SO278<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61-1<br />

DIS U<br />

13966-29-5<br />

13966-29-5<br />

13966-29-5<br />

13966-29-5<br />

15117-96-1<br />

15117-96-1<br />

15117-96-1<br />

15117-96-1<br />

24678-82-8<br />

24678-82-8<br />

24678-82-8<br />

24678-82-8<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

I 08-05-4<br />

108-05-4<br />

108-05-4<br />

75-01-4<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

7440-67-7<br />

111-91-1<br />

111-91-1<br />

111-91-1<br />

111-44-4<br />

111-44-4<br />

111-44-4<br />

108-60-1<br />

108-60-1<br />

108-60-1<br />

117-81-7<br />

117-81-7<br />

117-81-7<br />

156-59-2<br />

10061 -01-5<br />

10061 -01-5<br />

4821-94<br />

5569-93<br />

6703-94<br />

6796-93<br />

7756-93<br />

4097-92<br />

4686-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

CH210144-00000<br />

CH21014CDIS<br />

CH210223DIS<br />

CH210224-DUPDI<br />

CH210144-00000<br />

CH2 I01 44-DIS<br />

CH210223-DIS<br />

CH2 10226DUPDI<br />

4686-92<br />

4821-94<br />

5569-93<br />

CH210144-00000<br />

CH210144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821-94<br />

5569-93<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH2I 0144-00000<br />

CH210223-00000<br />

CH210224-DUP<br />

4097-92<br />

4821-94<br />

5569-93<br />

6028-92<br />

CH2 10144-OOOOO<br />

CH2I 0144-DIS<br />

CH210223-DIS<br />

CH210224-DUPDI<br />

4097-92<br />

4821 -94<br />

5569-93<br />

4686-92<br />

6028-92<br />

4097-92<br />

CH210144-00000<br />

CH2 10223-00000<br />

CH210224DUP<br />

CH2 1014440000<br />

CH210223-00000<br />

CH210224-DUP<br />

CH210144-00000<br />

CH210223-00000<br />

CH21022CDUP<br />

CH21014400000<br />

CH210223-00000<br />

CH210224-DUP<br />

6026-92<br />

CH21014400000<br />

CH210223-00000<br />

14MAR1994<br />

23JUN1993<br />

O6SEPI 994<br />

21SEP1993<br />

08DEC1993<br />

31JAN1992<br />

3OMAR1992<br />

14MAR1994<br />

23JUN1993<br />

190CT1992<br />

31 JAN 1992<br />

03APRl991<br />

03APR1991<br />

03MAY1991<br />

03MAYl991<br />

03APR1991<br />

O3APRl 991<br />

03MAY I991<br />

03MAYl991<br />

03APR199.1<br />

O3APR1 991<br />

03MAY1991<br />

03MAY 1991<br />

30MAR1992<br />

14MARl994<br />

23JUN1993<br />

O3APRl 991<br />

03APRI 991<br />

03MAY 1991<br />

03MAY 1991<br />

31 JAN1992<br />

14MAR1994<br />

23JUNl993<br />

03APRl991<br />

03MAY I991<br />

03MAY 1991<br />

03APRl991<br />

03MAY 1991<br />

03MAYl991<br />

03APR I991<br />

03MAYl991<br />

03MAY 1991<br />

31 JAN1992<br />

14MAR1994<br />

23JUNI993<br />

190CT1992<br />

03APR1991<br />

OBAPRI 991<br />

WAY I991<br />

03MAY 1991<br />

31 JAN1992<br />

14MARl994<br />

23JUN1993<br />

30MARI 992<br />

190CT1992<br />

31JAN1992<br />

03APRl991<br />

03MAY1991<br />

03MAYI991<br />

O3APR 1991<br />

03MAY I99 I<br />

03MAYl991<br />

O3APRI99I<br />

03MAYl991<br />

03MAY I99 1<br />

03APR1991<br />

03MAYl991<br />

03MAYl991<br />

190CTI 992<br />

03APRI991<br />

03MAY1991<br />

Page 154 of 176<br />

WG<br />

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2.70E+02<br />

3.80E+02<br />

2.50E+02<br />

1.70E+02<br />

3.30€+02<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00€+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.00E+00 7.40E-01<br />

O.OOE+OO 2.60E-01<br />

O.OOE+OO 5.00E-02<br />

O.OOE+OO 7.00E-02<br />

O.OOE+OO <strong>4.</strong>61E-01<br />

O.OOE+OO 1.20E-01<br />

O.OOE+OO 2.00E-02<br />

O.OOE+OO 2.00E-02<br />

1.00E+00 7.00E-01<br />

1.00E+00 3.60E-01<br />

0.00E+00 8.00E-02<br />

O.OOE+OO 8.00E-02<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

l.OOE+Ol<br />

1.00E+01<br />

I .00E+01<br />

l.OOE+OO<br />

1.00E+00<br />

1 .00E+00<br />

5.00E+00<br />

5.WE+00<br />

5.00E+W<br />

O.WE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.OOE+OO<br />

0.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+W<br />

0.00E+00<br />

O.OOE+OO<br />

l.lOE+Ol<br />

1.00€+01<br />

I.OOE+Ol<br />

l.lOE+Ol<br />

1 .OOE+OI<br />

1 .00E+01<br />

I.IOE+OI<br />

l.WE+OI<br />

l.OOE+OI<br />

l.lOE+Ol<br />

I.WE+Ol<br />

l.OOE+Ol<br />

I .00E+01<br />

5.00E+00<br />

5.00E+00<br />

c<br />

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C<br />

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U<br />

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NTU<br />

NTU<br />

NTU<br />

NTU<br />

NTU<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCilL<br />

pCifL<br />

pCiL<br />

pCilL<br />

pCilL<br />

mglL<br />

mglL<br />

rnglL<br />

rnglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug/L<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

mgk<br />

WlL<br />

mglL<br />

mglL<br />

mg1L<br />

mg5<br />

mg1L<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mgk<br />

mglL<br />

mg/L<br />

uglL<br />

ugJL<br />

UdL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

ugk<br />

ugfl<br />

ugk<br />

uglL<br />

ugfl<br />

uglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

cis-l,3-Dichloropropene 10061-01-5 CH210224-DUP 03MAY1991 WG 5.00E+00 U ug/L<br />

PH<br />

SO296<br />

4097-92 31JAN1992 WG<br />

su<br />

PH<br />

SO296<br />

4686-92 3OMAR1992<br />

WG<br />

su<br />

PH<br />

SO296<br />

4821-94 14MARl994 WG<br />

su<br />

PH<br />

SO296<br />

4822-94 14MARl994 WG<br />

su<br />

PH<br />

SO296<br />

4823-94 14MAR1994 WG<br />

su<br />

PH<br />

SO296<br />

4824-94 14MAR1994 WG<br />

su<br />

PH<br />

SO296<br />

5569-93 23JUN1993 WG<br />

su<br />

PH<br />

SO296<br />

5570-93 23JUN1993 WG<br />

su<br />

PH<br />

SO296<br />

5571-93 23JUNl993 WG<br />

su<br />

PH<br />

SO296<br />

5572-93 23JUN1993 WG<br />

su<br />

PH<br />

SO296<br />

6028-92 190CT1992 WG<br />

Q<br />

su<br />

PH<br />

SO296<br />

6703-94 O6SEP1 994 WG<br />

su<br />

PH<br />

SO296<br />

6704-94 O6SEP1 994 WG<br />

su<br />

PH<br />

SO296<br />

6705-94 06SEP1994 WG<br />

su<br />

PH<br />

SO296<br />

6706-94 O6SEP1 994 WG<br />

su<br />

PH<br />

SO296<br />

6796-93 2lSEPl993 WG<br />

su<br />

PH<br />

SO296<br />

6797-93 21SEP1993 WG<br />

su<br />

PH<br />

SO296<br />

6798-93 21 SEPl993 w<br />

su<br />

PH<br />

SO296<br />

6799-93 2lSEP1993 w<br />

su<br />

PH<br />

SO296<br />

7756-93 08DEC1993 WG<br />

su<br />

PH<br />

SO296<br />

7757-93 08DECl993 WG<br />

su<br />

PH<br />

SO296<br />

7758-93 08DEC1993 WG<br />

su<br />

PH<br />

SO296<br />

7759-93 08DEC1993 WG<br />

su<br />

trans-l,3-Dichloropropene 10061-02-6 CH210144-WOOO 03APRl991 w<br />

U<br />

uglL<br />

trans-l,3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

10061-02-6<br />

10061 -02-6<br />

CH2I 0223-00000<br />

CH210224-DUP<br />

03MAYl991<br />

03MAY1991<br />

WG<br />

WG<br />

U<br />

U<br />

uglL<br />

uglL<br />

WAG 7, SVWU 8, MW24<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

471-34-1<br />

471-34-1<br />

471-34-1<br />

1950-88<br />

3016-91<br />

4099-92<br />

14SEP1988<br />

29AUG1991<br />

01FEB1992<br />

WG<br />

WG<br />

WG<br />

T<br />

N<br />

N<br />

mglL<br />

mgfl<br />

mglL<br />

Alkalinity<br />

471-34-1<br />

5406-92 1 lAUGl992 WG<br />

N<br />

mglL<br />

Aluminum<br />

7429-90-5<br />

4099-92 OlFEB1992 w<br />

<<br />

N<br />

mg/L<br />

Aluminum, dissolved<br />

Americium 241<br />

Americium 241<br />

Americium 241<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

Barium, dissolved<br />

Beryllium<br />

Beryllium, Dissolved<br />

7429-90-5<br />

AM241<br />

AM241<br />

AM241<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-41-7<br />

7440-41-7<br />

4099-92<br />

1950-88<br />

3016-91<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

01 FEB1992<br />

14SEP1988<br />

29AUGl991<br />

11AUGI 992<br />

01 FEBI 992<br />

01 FEB1992<br />

OlFEB1992<br />

OlFEB1992<br />

01 FEB1992<br />

01 FEB1992<br />

01 FEBl992<br />

01FEBl992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

e<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

pCiL<br />

pCVL<br />

pCi<br />

mg/L<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

Bismuth<br />

Bismuth, Dissolved<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

4099-92<br />

4099-92<br />

195088<br />

2295-89<br />

2979-90<br />

OlFEBl992<br />

01 FEB1992<br />

14SEPl988<br />

25AUGl989<br />

05SEP1990<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

c<br />

<<br />

N<br />

N<br />

T<br />

T<br />

T<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

301691 29AUG 1991 WG<br />

<<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

4099-92 01 FEBl992 w<br />

N<br />

mglL<br />

Cadmium<br />

7440-43-9<br />

5406-92 llAUG1992 WG<br />

N<br />

mglL<br />

Cadmium, Dissolved<br />

7440-43-9<br />

4099-92 OlFEBl992 w<br />

N<br />

mgn-<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium, Dissolved<br />

Cesium137<br />

Cesium1 37<br />

Cesium-137<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

10045-97-3<br />

10045-97-3<br />

10045-97-3<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

7440-47-3<br />

7440-47-3<br />

7440-473<br />

7440-47-3<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

1950-88<br />

301691<br />

5406-92<br />

195088<br />

301691<br />

4099-92<br />

5406-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

14SEP1988<br />

25AUG1989<br />

OSSEP1990<br />

29AUGl991<br />

OlFEBl992<br />

llAUG1992<br />

OlFEB1992<br />

14SEP1988<br />

29AUGI 991<br />

1 lAUGl992<br />

14SEPl988<br />

29AUG1991<br />

01 FEB1992<br />

llAUG1992<br />

14SEPl988<br />

25AUG1989<br />

O5SEP1990<br />

29AUG1991<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

v\IG<br />

WG<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

T<br />

T<br />

T<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

pciR<br />

pciR<br />

pciR<br />

mglL<br />

mg5<br />

mglL<br />

mglL<br />

mgk<br />

mg1L<br />

mglL<br />

mgfl<br />

Page 155 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium 7440-47-3 4099-92 01FEB1992 WG O.OOE+OO C N mglL<br />

Chromium<br />

Chromium, Dissolved<br />

Cobalt<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt, Dissolved<br />

Color<br />

Color<br />

Color<br />

Color<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Depth to Water<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Fluoride<br />

Fluoride<br />

Fluoride<br />

Fluoride<br />

GCMS Scan<br />

Gamma Activity<br />

Gross Alpha<br />

Gross Beta<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron, Dissolved<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead, Dissolved<br />

Lithium<br />

Lithium. Dissolved<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium, Dissolved<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

10198-40-0<br />

10198-40-0<br />

10198-40-0<br />

7440-48-4<br />

COLOR<br />

COLOR<br />

COLOR<br />

COLOR<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

SO266<br />

SO266<br />

SO266<br />

SO266<br />

16984-48-8<br />

16984-48-8<br />

16984-48-8<br />

16984-48-8<br />

GCMS SCAN<br />

GAMMA<br />

1258746-1<br />

12587-47-2<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

5406-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

3016-91<br />

5406-92<br />

4099-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

195088<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

5406-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

5406-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

5406-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

3016-91<br />

5406-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

llAUG1992<br />

01FEB1992<br />

01FEB1992<br />

14SEP1988<br />

29AUG1991<br />

11 AUGl992<br />

01 FEB1992<br />

14SEP1988<br />

29AUG1991<br />

01FEB1992<br />

11AUGl992<br />

14SEP1988<br />

25AUGl989<br />

05SEPl990<br />

29AUGl991<br />

OlFEB1992<br />

llAUGl992<br />

01FEB1992<br />

14SEP1988<br />

25AUG1989<br />

05SEP1990<br />

29AUG1991<br />

11 AUGl992<br />

14SEP1988<br />

25AUG1989<br />

05SEP1990<br />

29AUGl991<br />

11 AUGl992<br />

14SEP1988<br />

25AUG1989<br />

05SEP1990<br />

29AUG1991<br />

1 lAUGl992<br />

14SEP1988<br />

29AUG1991<br />

01FEB1992<br />

11 AUGl992<br />

14SEPl988<br />

29AUG1991<br />

01FEBl992<br />

1 lAUGl992<br />

OlFEB1992<br />

01 FEBl992<br />

OlFEBl992<br />

01FEB1992<br />

14SEP1988<br />

29AUGl991<br />

11AUG1992<br />

14SEP1988<br />

25AUG1989<br />

05SEPl990<br />

29AUG 1991<br />

01FEBl992<br />

llAUG1992<br />

OlFEB1992<br />

14SEP1988<br />

25AUGl989<br />

05SEP1990<br />

29AUG 1991<br />

01 FEE1 992<br />

1 lAUGl992<br />

OlFEBl992<br />

OlFEB1992<br />

OlFEBl992<br />

14SEP1988<br />

25AUGl989<br />

05SEP1990<br />

29AUGl991<br />

OlFEB1992<br />

llAUG1992<br />

01 FEBl992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

c<br />

N<br />

< N<br />

< N<br />

NT<br />

N<br />

N<br />

C<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

T<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

Q<br />

c<br />

e<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

T<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

Page 156 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANAL'fTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Manganese<br />

7439-96-5 1950-88 14SEP1988 WG O.OOE+OO HT mglL<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese, Dissolved<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

25AUG1989<br />

05SEP1990<br />

29AUG1991<br />

01FEB1992<br />

llAUGl992<br />

01 FEE1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Mercury<br />

7439-97-6<br />

4099-92 01 FEB1992 WG<br />

N<br />

mglL<br />

Mercury, Dissolved<br />

7439-97-6<br />

4099 - 92<br />

01 FEE1992 WG<br />

N<br />

mg1L<br />

Molybdenum<br />

Molybdenum, Dissolved<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel, Dissolved<br />

Niobium<br />

Niobium, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

PCB<br />

PCB<br />

PCB<br />

PCB<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphorus (P)<br />

Phosphorus, Dissolved<br />

Potassium<br />

Potassium, Dissolved<br />

Qual IR<br />

Radium-226<br />

Radium-226<br />

Radium226<br />

Ruthenium<br />

Ruthenium, Dissolved<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium, Dissolved<br />

Silicon<br />

Silicon, Dissolved<br />

Silver<br />

Silver, dissolved<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Strontium<br />

Strontium. Dissolved<br />

7439-98-7<br />

7439-98-7<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

NITRATEASNIT<br />

N ITRATEASN IT<br />

N ITRATEASN IT<br />

N ITRATEAS N IT<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

QUAL IR<br />

13982-63-3<br />

13982-63-3<br />

13982-63-3<br />

7440-18-8<br />

7440-18-8<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

4099-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

3098-91<br />

1950-88<br />

3016-91<br />

5406-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-92<br />

1950-88<br />

301691<br />

3038-91<br />

3039-91<br />

3040-91<br />

4099-92<br />

5406-92<br />

5407-92<br />

5408-92<br />

5409-92<br />

4099-92<br />

4099-92<br />

01 FEE1992<br />

OlFEB1992<br />

14SEP1988<br />

25AUG1989<br />

05SEP1990<br />

29AUG1991<br />

01FEB1992<br />

11 AUGl992<br />

01FEB1992<br />

01 FEE1992<br />

01 FEE1992<br />

14SEP1988<br />

29AUG1991<br />

01 FEB1992<br />

1 lAUGl992<br />

14SEP1988<br />

29AUG1991<br />

01 FEE1 992<br />

1 lAUGl992<br />

14SEP1988<br />

29AUGl991<br />

01FEB1992<br />

1 lAUGl992<br />

OlFEB1992<br />

01 FEBl992<br />

01FEB1992<br />

01FEB1992<br />

OSSEPl991<br />

14SEP1988<br />

29AUGl991<br />

11AUG1992<br />

01 FEE1 992<br />

01 FEE1992<br />

14SEP1988<br />

25AUGl989<br />

(HSEPl990<br />

29AUGl991<br />

01 FEBl992<br />

1 lAUGl992<br />

01FEB1992<br />

01 FEBl992<br />

01FEB1992<br />

OlFEBl992<br />

OlFEB1992<br />

14SEP1988<br />

25AUG1989<br />

05SEPl990<br />

29AUGl991<br />

01 FEB1992<br />

11AUG1992<br />

01FEB1992<br />

14SEP1988<br />

29AUG1991<br />

29AUG1991<br />

29AUG1991<br />

29AUG1991<br />

OlFEB1992<br />

llAUG1992<br />

llAUG1992<br />

llAUG1992<br />

11AUG1992<br />

OlFEBl992<br />

01 FEE1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

v\IG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

N<br />

N<br />

T<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

T<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

comment<br />

pCVL<br />

pCVL<br />

pCVL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

W/L<br />

mglL<br />

WlL<br />

mglL<br />

WlL<br />

mg1L<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

urnhodcm<br />

umhodcm<br />

umhodcm<br />

umhodcm<br />

umhodcm<br />

mglL<br />

mglL<br />

Page 157 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Sulfate 12143-45-2 1950-88 14SEP1988 WG 5.00E+00 < HT mglL<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

Tantalum<br />

Tantalum.Dissolved<br />

Technetium-99<br />

Technetium99<br />

Technetium-99<br />

Technetiurn-99<br />

Technetium-99<br />

Technetium-99<br />

Temperature<br />

Temperature<br />

Thallium<br />

Thallium, Dissolved<br />

Thorium<br />

Thorium. Dissolved<br />

Tin<br />

Tin, Dissolved<br />

Titanium<br />

Titanium, Dissolved<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trihloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten, Dissolved<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Vanadium<br />

Vanadium, Dissolved<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

12143-45-2<br />

12143-45-2<br />

12 143-452<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

7440-25-7<br />

7440-25-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

SO835<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

7440-32-6<br />

7440-34-6<br />

7440-44-0<br />

744044-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

744044-0<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

SO278<br />

SO278<br />

SO278<br />

SO278<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

DIS U<br />

7440-62-2<br />

7440-62-2<br />

7440-66-6<br />

7440-66-6<br />

7440-666<br />

7440-66-6<br />

3016-91<br />

4099-92<br />

5406-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

5406-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

5406-92<br />

1950-88<br />

3016-91<br />

3038-91<br />

3039-91<br />

3040-91<br />

5406-92<br />

5407-92<br />

5408-92<br />

5409-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

4099-92<br />

5406-92<br />

3016-91<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

4099 - 92<br />

1950-88<br />

3016-91<br />

302-91<br />

3039-91<br />

3040-91<br />

5406-92<br />

5407-92<br />

5408-92<br />

5409-92<br />

1950-88<br />

2295-89<br />

301691<br />

3098-91<br />

5406-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

3016-91<br />

4099-92<br />

5406-92<br />

195088<br />

3016-91<br />

4099-92<br />

5406-92<br />

4099-9?<br />

4099-92<br />

4099-92<br />

1950-88<br />

2295-89<br />

2979-90<br />

3016-91<br />

29AUG1991<br />

01 FEB1992<br />

11 AUGI 992<br />

14SEP1988<br />

25AUG1989<br />

OSSEP1990<br />

29AUG 1991<br />

llAUG1992<br />

14SEP1988<br />

25AUG1989<br />

O5SEPl 990<br />

29AUG1991<br />

11 AUGl992<br />

14SEP1988<br />

29AUG1991<br />

29AUG1991<br />

29AUGl991<br />

29AUG1991<br />

11 AUGl992<br />

11AUG1992<br />

11 AUG 1992<br />

11 AUG 1992<br />

01 FEBI 992<br />

01FEBl992<br />

14SEPl988<br />

25AUG1989<br />

OSSEPl990<br />

29AUGl991<br />

OlFEB1992<br />

llAUG1992<br />

29AUG1991<br />

I AUG1992<br />

01 FEBI 992<br />

01FEBl992<br />

01FEBl992<br />

01FEBl992<br />

01FEB1992<br />

01 FEB 1992<br />

01 FEB1992<br />

01 FEBl992<br />

14SEPl988<br />

29AUGl991<br />

29AUGl991<br />

29AUG1991<br />

29AUG1991<br />

1 AUG 1992<br />

llAUGl992<br />

1 AUGl992<br />

11 AUGl992<br />

14SEP1988<br />

25AUGl989<br />

29AUGl991<br />

OSSEPI 991<br />

1 I AUGI 992<br />

01 FEE1992<br />

01 FEBI 992<br />

14SEPI 988<br />

29AUG1991<br />

OlFEB1992<br />

llAUG1992<br />

14SEP1988<br />

29AUG1991<br />

01FEB1992<br />

llAUG1992<br />

01 FEBI 992<br />

01 FEBI 992<br />

OlEB1992<br />

I ~SEP~ 9aa<br />

25AUG1989<br />

OSSEPI 990<br />

29AUG1991<br />

Page 158 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

m<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

5.00E+00<br />

l.OOE+OI<br />

8.00E+00<br />

O.OOE+OO<br />

1.00€+00<br />

<strong>4.</strong>00E+00<br />

-2.00E+00 0.00€+00<br />

-<strong>4.</strong>00€+00 3.00E+00<br />

3.00E+00<br />

l.OOE+Ol<br />

-1.30E+01<br />

-1.20E+01 O.OOE+OO<br />

-6.00E+00 2.00E+00<br />

9.00E+00<br />

l.lOE+Ol<br />

5.00E+00<br />

1.80E+01<br />

1.30E+01<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

2.50E+01<br />

2.50€+01<br />

O.OOE+OO<br />

7.00E+00 0.00€+00<br />

<strong>4.</strong>00E+00 O.OOE+OO<br />

1.60E+01 l.lOE+Ol<br />

7.10E+01<br />

6.90E+01<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

O.WE+OO<br />

1 .WE+W<br />

l.OOE+Ol<br />

5.00E+00<br />

6.00E+00<br />

<strong>4.</strong>00E+W<br />

I .WE+00<br />

1.00E+00<br />

1.00E+00<br />

l.OOE+OO<br />

I .00E+W<br />

1.00€+00<br />

I.WE+OO<br />

l.OOE+OO<br />

1 .WE+00<br />

l.OOE+OO<br />

O.OOE+OO<br />

9.00E+00<br />

8.00E+00<br />

I .40E+01<br />

2.30E+01<br />

O.OOE+OO<br />

O.OOE+W<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

2.30E+01<br />

5.30E+Ol<br />

2.WE+01<br />

l.lOE+Ol<br />

< N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

J<br />

UJ<br />

J<br />

J<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

HT<br />

T<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

PCYL<br />

pCiL<br />

pCiL<br />

pCVL<br />

PCYL<br />

pCYL<br />

pCYL<br />

pCVL<br />

pCiL<br />

pCYL<br />

ug1L<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

pCVL<br />

pCiL<br />

pCi<br />

PCiL<br />

pCiL<br />

pCYL<br />

F<br />

F<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mgn<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

mg/L<br />

mg/L<br />

mglL<br />

mglL<br />

uglL<br />

ugk<br />

uglL<br />

ugk<br />

UglL<br />

mglL<br />

mg1L<br />

NTU<br />

NTU<br />

NTU<br />

N N<br />

mgk<br />

mgk<br />

mgk<br />

mgfl<br />

mgk<br />

mgn<br />

mgfl<br />

mgk<br />

mg/L<br />

W L<br />

mgk


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE lYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Zinc 7440-66-6 4099-92 01FEB1992 WG 3.50E+01 N mq1L<br />

Zinc<br />

Zinc, Dissolved<br />

N<br />

N<br />

Zirconium<br />

Zirconium, Dissolved<br />

<<br />

<<br />

N<br />

N<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, S WU 8, MW25<br />

Depth to Water<br />

Technetium-99<br />

Trichloroethene<br />

WAG 7. SWvlU 8, MW26<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

Aluminum<br />

Aluminum, dissolved<br />

Americium 241<br />

Americium 241<br />

Americium 241’<br />

Americium 241<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

Barium, dissolved<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bismuth<br />

Bismuth. Dissolved<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium, Dissolved<br />

Cesium1 37<br />

Cesium137<br />

Cesium-137<br />

Cesium-I 37<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium, Dissolved<br />

Coball<br />

Coball 60<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt 60<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

DTW<br />

141 33-76-7<br />

79-01-6<br />

471-34-1<br />

471-34-1<br />

471-34-1<br />

7429-90-5<br />

7429-90-5<br />

AM241<br />

AM241<br />

AM241<br />

AM241<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

7440-41 -7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

10045-97-3<br />

10045-97-3<br />

10045-97-3<br />

10045-97-3<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-484<br />

10198-40-0<br />

10198-40-0<br />

10198-40-0<br />

10198-40-0<br />

5406-92<br />

4099-92<br />

4099-92<br />

4099-92<br />

1950-88<br />

3016-91<br />

3038-91<br />

3039-91<br />

3040-91<br />

5406-92<br />

5407-92<br />

5408-92<br />

5409-92<br />

1952-88<br />

1952-88<br />

1952-88<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101 -92<br />

4101-92<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

4101 -92<br />

4101-92<br />

4101-92<br />

4101 -92<br />

4101-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

1843-88<br />

3017-91<br />

4101-92<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101 -92<br />

4101 -92<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

11AUG1992<br />

01FEB1992<br />

01 FEB1992<br />

01 FEB1992<br />

14SEP1988<br />

29AUG1991<br />

29AUGl991<br />

29AUG1991<br />

29AUG1991<br />

11AUG1992<br />

11AUG1992<br />

llAUG1992<br />

1 1 AUGl992<br />

14SEP1988<br />

14SEP1988<br />

14SEP1988<br />

28AUGl991<br />

01 FEB1992<br />

llAUG1992<br />

01 FEB1992<br />

01FEB1992<br />

23AUG1989<br />

04SEP1990<br />

28AUGl991<br />

1 lAUG1992<br />

01 FEB1992<br />

01FEB1992<br />

01FEB1992<br />

01 FEBl992<br />

01 FEB1992<br />

01FEB1992<br />

01FEB1992<br />

OlFEBl992<br />

01FEB1992<br />

01FEB1992<br />

01SEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUG1991<br />

01 FEB1992<br />

llAUGl992<br />

01 FEBI 992<br />

01SEP1988<br />

23AUGl989<br />

04SEPI 990<br />

28AUG1991<br />

01FEBl992<br />

I 1 AUGl992<br />

01FEBl992<br />

23AUG1989<br />

04SEP1990<br />

28AUG1991<br />

11 AUGl992<br />

OlSEP1988<br />

28AUG1991<br />

01 FEB1992<br />

11 AUGl992<br />

OlSEPl988<br />

23AUG1989<br />

04SEPl990<br />

28AUGl991<br />

OlFEB1992<br />

I AUGI 992<br />

01FEBl992<br />

01FEB1992<br />

23AUG1989<br />

04SEP1990<br />

28AUGl991<br />

11AUG1992<br />

Page 159 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

w<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

w<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

T<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

Feet<br />

pCiL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

pCiL<br />

pCVL<br />

pCiL<br />

pCilL<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mgfl<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

pCilL<br />

pCiL<br />

pCVL<br />

pCVL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

Wfl<br />

mg/L<br />

mglL<br />

mgfl<br />

pCilL<br />

pcin<br />

pcin<br />

PCiR


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Cobalt, Dissolved 7440-48-4 4101-92 01FEB1992 WG O.OOE+OO < N mglL<br />

Color<br />

Color<br />

Color<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Depth lo Water<br />

Depth to Water<br />

Depth lo Water<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Fluoride<br />

Fluoride<br />

Fluoride<br />

GCMS Scan<br />

Gross Alpha<br />

Gross Beta<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron. Dissolved<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead, Dissolved<br />

Lithium<br />

Lithium, Dissolved<br />

M Alkalinity<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury. Dissolved<br />

Molybdenum<br />

COLOR<br />

COLOR<br />

COLOR<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

SO266<br />

SO266<br />

SO266<br />

SO266<br />

16984-48-8<br />

I 6984-48-8<br />

16984-48-8<br />

GCMS SCAN<br />

12587-46-1<br />

12587-47-2<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

M ALKALINITY<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7439-98-7<br />

3017-91<br />

4101 -92<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

1843-88<br />

3017-91<br />

4101-92<br />

5410-92<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

1843-88<br />

3017-91<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

1843-88<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101 -92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101 -92<br />

5410-92<br />

4101-92<br />

4101 -92<br />

4101 -92<br />

4101-92<br />

28AUG 199 1<br />

OlFEB1992<br />

11AUG1992<br />

01SEPl988<br />

23AUGl989<br />

04SEP1990<br />

28AUG1991<br />

01 FEBl 992<br />

11AUG1992<br />

01 FEE1992<br />

23AUG1989<br />

04SEP1990<br />

28AUG1991<br />

11AUGl992<br />

01SEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUG1991<br />

1 1 AUGl992<br />

01SEP1988<br />

23AUGl989<br />

04SEP1990<br />

28AUG1991<br />

1 1 AUG 1992<br />

01SEP1988<br />

28AUG1991<br />

01 FEBI 992<br />

1 1AUG1992<br />

28AUG1991<br />

OlFEBl992<br />

1 1 AUGI 992<br />

01 FEBl992<br />

01FEBl992<br />

01 FEE1992<br />

01SEP1988<br />

28AUG1991<br />

1 1 AUG 1992<br />

OlSEPl988<br />

23AUGl989<br />

04SEPl990<br />

28AUG1991<br />

01FEB1992<br />

1 1 AUG 1992<br />

01 FEB1992<br />

01 SEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUG 1991<br />

01FEB1992<br />

1 1 AUG 1992<br />

01FEB1992<br />

01FEB1992<br />

01FEB1992<br />

OISEPI988<br />

OlSEPl988<br />

23AUGl989<br />

04SEP1990<br />

28AUGl99 1<br />

01 FEB1992<br />

1 1 AUG 1992<br />

01 FEB1992<br />

01SEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUGl991<br />

01FEB1992<br />

llAUGl992<br />

OlFEBl992<br />

OlFEB1992<br />

OlFEB1992<br />

OlFEBl992<br />

Page 160 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

2.80E+01<br />

6.50E+01<br />

I .80E+02<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

3.40E+01<br />

3.20E+01<br />

2.50E+01<br />

3.30E+01<br />

1.50E+01<br />

l.OOE+Ol<br />

1 .WE+00<br />

3.OOE+00 O.OOE+OO<br />

3.OOE+00 l.OOE+OO<br />

3.60E+01<br />

-<strong>4.</strong>00E+00<br />

l.OOE+OO<br />

2.20E+01 O.OOE+OO<br />

2.10E+01 5.00E+00<br />

2.44E+02<br />

I .73E+02<br />

2.30E+02<br />

2.24E+02<br />

O.WE+W<br />

3.95E+02<br />

O.WE+OO<br />

O.WE+OO<br />

2.00E+00 O.OOE+OO<br />

<strong>4.</strong>90E+01 6.00E+00<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

1.80E+OI<br />

O.OOE+OO<br />

I .00E+00<br />

3.50E+01<br />

<strong>4.</strong>00E+W<br />

<strong>4.</strong>WE+00<br />

O.WE+OO<br />

1 .WE+00<br />

O.OOE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+W<br />

O.WE+W<br />

2.32E+02<br />

<strong>4.</strong>20E+01<br />

3.WE+OI<br />

3.70E+01<br />

2.90E+01<br />

2.30E+01<br />

1.60E+01<br />

2.20E+01<br />

O.OOE+W<br />

O.WE+OO<br />

O.WE+OO<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

<<br />

a<br />

<<br />

<<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Molybdenum, Dissolved 7439-98-7 4101-92 01FEB1992 WG O.OOE+OO<br />

C<br />

N<br />

mglL<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel, Dissolved<br />

Niobium<br />

Niobium, Dissolved<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

PCB<br />

PCB<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

1336-36-3<br />

1336-36-3<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101 -92<br />

4101-92<br />

4101-92<br />

1843-88<br />

3017-91<br />

4101 -92<br />

5410-92<br />

3017-91<br />

5410-92<br />

1843-88<br />

3017-91<br />

4101-92<br />

5410-92<br />

01SEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUG1991<br />

01 FEB1992<br />

1 lAUG 1992<br />

01 FEB1992<br />

01FEB1992<br />

01FEB1992<br />

01SEP1988<br />

28AUGl991<br />

01 FEBl992<br />

1 lAUGl992<br />

28AUG1991<br />

llAUG1992<br />

01SEP1988<br />

28AUG 1991<br />

01 FEE1992<br />

11AUG1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wr;<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

2.00E+00<br />

2.00E+00<br />

2.00E+00<br />

2.00E+00<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

<<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

<<br />

HT<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Phosphorus (P)<br />

Phosphorus, Dissolved<br />

Potassium<br />

Potassium, Dissolved<br />

Radium226<br />

Radium-226<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

13982-63-3<br />

13982-63-3<br />

4101 -92<br />

4101 -92<br />

4101-92<br />

4101-92<br />

2292-89<br />

2980-90<br />

01 FEBl992<br />

01 FEE1992<br />

01 FEE1992<br />

01 FEE1992<br />

23AUG1989<br />

04SEP1990<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

l.OOE+OO<br />

O.OOE+OO<br />

9.00E+00<br />

l.OOE+Ol<br />

O.OOE+OO<br />

O.OOE+OO<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

pCVL<br />

pciR<br />

Radium226<br />

13982-63-3<br />

3017-91 28AUGl991 WG l.OOE+OO O.OOE+OO<br />

N<br />

pCiL<br />

Radium-226<br />

13982-63-3<br />

5410-92 llAUG1992 WG O.OOE+OO O.OOE+OO<br />

N<br />

pCiL<br />

Ruthenium<br />

Ruthenium, Dissolved<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium, Dissolved<br />

Silicon<br />

Silicon, Dissolved<br />

Silver<br />

Silver, dissolved<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Strontium<br />

Strontium, Dissolved<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

7440-18-8<br />

7440-18-8<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

7440-235<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

4101-92<br />

4101-92<br />

1843-88<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101 -92<br />

4101 -92<br />

4101 -92<br />

4101 -92<br />

4101-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101-92<br />

3017-91<br />

3032-91<br />

3033-91<br />

3034-91<br />

4101-92<br />

5410-92<br />

5411-92<br />

5412-92<br />

5413-92<br />

4101 -92<br />

4101-92<br />

1843-88<br />

3017-91<br />

4101 -92<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

OlFEB1992<br />

OlFEBl992<br />

01SEP1988<br />

MSEPl990<br />

28AUG1991<br />

01 FEE1 992<br />

11AUGl992<br />

01FEB1992<br />

01FEBl992<br />

01 FEE1992<br />

01FEB1992<br />

01 FEE1992<br />

01 SEP1988<br />

23AUG1989<br />

04s EP 1990<br />

28AUGl991<br />

01 FEE1992<br />

11 AUGl992<br />

01FEB1992<br />

28AUG1991<br />

28AUGl991<br />

28AUG1991<br />

28AUG1991<br />

01FEB1992<br />

1 AUGl992<br />

11AUG1992<br />

11AUGl992<br />

1 lAUGl992<br />

OlFEBl992<br />

01FEBl992<br />

01SEPl988<br />

28AUGl991<br />

01 FEE1992<br />

llAUG1992<br />

01SEPl988<br />

23AUGl989<br />

04SEP1990<br />

28AUG1991<br />

1 lAUG 1992<br />

01 SEPl988<br />

23AUG1989<br />

MSEPl990<br />

28AUGl991<br />

1 lAUG 1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

W E<br />

WG<br />

O.OOE+OO<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00E+00<br />

8.00E+00<br />

6.00E+00<br />

0.00E+00<br />

O.OOE+OO<br />

l.OOE+OO<br />

1.60E+01<br />

l.OOE+OO<br />

l.OOE+OO<br />

l.OOE+OO<br />

2 .OOE+ 00<br />

2.00E+00<br />

2.73E+02<br />

<strong>4.</strong>50E+02<br />

<strong>4.</strong>51E+02<br />

<strong>4.</strong>48E+02<br />

0.00E+00<br />

2.75E+02<br />

7.00E+00<br />

0.00E+00<br />

0.00E+00<br />

l.OOE+OO<br />

0.00E+00<br />

l.lOE+Ol<br />

2.20E+01<br />

2.40E+01<br />

1.20E+Ol<br />

3.00E+00<br />

2.00E+00<br />

3.00E+00<br />

-2.00€+00 O.OOE+OO<br />

-2.00E+00 1.00E+00<br />

-3.00E+00<br />

-1.00E+00<br />

-9.00E+00<br />

-3.00E+00 O.OOE+OO<br />

1 .00E+00 O.OOE+OO<br />

C<br />

C<br />

<<br />

C<br />

C<br />

C<br />

C<br />

C<br />

C<br />

<<br />

N<br />

N<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

HT<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

WlL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

WIL<br />

mgfl<br />

WlL<br />

mglL<br />

WIL<br />

mglL<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhodcm<br />

UMHOSICM<br />

UMHOSICM<br />

UMHOSICM<br />

mglL<br />

WlL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

pCVL<br />

pCiL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCiL<br />

pCVL<br />

pciR<br />

pCilL<br />

Page 161 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

TOX TOX 2292-89 23AUG1989 WG 6.90E+01 HT ug1L<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

Tantalum<br />

Tantalum,Dissolved<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Technetium-99<br />

Temperature<br />

Temperature<br />

Thallium<br />

Thallium, Dissolved<br />

Thorium<br />

Thorium, Dissolved<br />

Tin<br />

Tin, Dissolved<br />

Titanium<br />

lidanium, Dissolved<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten, Dissolved<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Vanadium<br />

Vanadium, Dksolved<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc, Dissolved<br />

Zirconium<br />

Zirconium, Dissolved<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, S WU 8. W 7<br />

1 ,l .l-Trichloroethane<br />

1,1,1-Trichloroethane<br />

1.1.2.2-Tetrachloroethane<br />

1 ,1.2,2-Tetrachloroethane<br />

1 ,1,2-Trichloroethane<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

7440-25-7<br />

7440-25-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

SO835<br />

7440-28-0<br />

7440-280<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

7440-32-6<br />

7440-34-6<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-444<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

SO278<br />

SO278<br />

SO278<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

7440-61-1<br />

DIS U<br />

7440-62-2<br />

7440-62-2<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-67-7<br />

7440-67-7<br />

so296<br />

so296<br />

so296<br />

SO296<br />

so296<br />

SO296<br />

so296<br />

so296<br />

7 1-556<br />

71-55-6<br />

79-345<br />

79-34-5<br />

79-00-5<br />

2980-90<br />

3017-91<br />

3032-91<br />

3033-91<br />

3034-91<br />

4101-92<br />

4101-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

3017-91<br />

5410-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

4101-92<br />

4101 -92<br />

4101 -92<br />

4101-92<br />

4101 -92<br />

2292-89<br />

2980-90<br />

3017-91<br />

3032-91<br />

3033-91<br />

3034-91<br />

5410-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

5410-92<br />

4101 -92<br />

4101-92<br />

3017-91<br />

4101 -92<br />

5410-92<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101 -92<br />

5410-92<br />

4101 -92<br />

4101-92<br />

4101-92<br />

1843-88<br />

2292-89<br />

2980-90<br />

3017-91<br />

4101-92<br />

5410-92<br />

4101 -92<br />

4101-92<br />

4101-92<br />

3017-91<br />

3032-91<br />

3033-91<br />

3034-91<br />

5410-92<br />

5411-92<br />

5412-92<br />

5413-92<br />

04SEP1990<br />

28AUGl991<br />

28AUG1991<br />

28AUG1991<br />

28AUGl991<br />

01FEBl992<br />

01 FEBl992<br />

01SEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUG1991<br />

01FEBl992<br />

1 1AUGl992<br />

28AUG1991<br />

1 lAUGl992<br />

01 FEB1992<br />

OlFEB1992<br />

01FEBl992<br />

01FEBl992<br />

01FEB1992<br />

01 FEB1992<br />

01 FEBl992<br />

01 FEBl992<br />

23AUG1989<br />

04SEPl990<br />

28AUG1991<br />

28AUG1991<br />

28AUG1991<br />

28AUG1991<br />

llAUGl992<br />

01SEPl988<br />

23AUG1989<br />

04SEPl990<br />

28AUG1991<br />

11AUGl992<br />

01 FEBl992<br />

01FEB1992<br />

28AUG1991<br />

01FEB1992<br />

11AUG1992<br />

23AUG1989<br />

04SEPl990<br />

28AUG 1991<br />

OlFEBl992<br />

llAUG1992<br />

OlFEB1992<br />

01FEBl992<br />

OlFEB1992<br />

OlSEP1988<br />

23AUG1989<br />

04SEP1990<br />

28AUGl991<br />

OlFEB1992<br />

llAUG1992<br />

01FEB1992<br />

01FEBl992<br />

01FEBl992<br />

28AUG1991<br />

28AUG1991<br />

28AUG1991<br />

28AUG199 1<br />

llAUG1992<br />

llAUG1992<br />

11AUGl992<br />

llAUGl992<br />

CH200029-00000 190CT1989<br />

CH200631-00000 22AUG1990<br />

CH200029-00000 190CT1989<br />

CH200631-00000 22AUG1990<br />

CH200029-00000 190CTl989<br />

Page 162 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

w<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

w<br />

HT<br />

J<br />

N<br />

J<br />

N<br />

J<br />

N<br />

Q<br />

N<br />

< N<br />

< N<br />

C<br />

HT<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

1.1.2-Trichloroethane 79-00-5 CH200631-00000 22AUG1990 WG 5.00E+00 U ug/L<br />

1 .l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 ,l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1.2.4-Trichlorobenzene<br />

1,2-Dichlorobenzene<br />

1,2-Dichloroethane<br />

1.2-Dichloroethane<br />

1.2-Dichloroethene<br />

1.2-Dichloroethene<br />

1.2-Dichloropropane<br />

1.2-Dichloropropane<br />

1.3-Dichlorobenzene<br />

1 ,4-Dichlorobenzene<br />

2,4,5-Trichlorophenol<br />

2,4,6-TrichlorophenoI<br />

2 ,4-Dichlorophenol<br />

2,4-Dimethylphenol<br />

2,4-Dinitrophenol<br />

2.4-Dinitrotoluene<br />

2.6-Dinitrotoluene<br />

2-Butanone<br />

2-Butanone<br />

2-Chloronaphthalene<br />

2-Chlorophenol<br />

2-Hexanone<br />

2-Hexanone<br />

2-Methylnaphthalene<br />

2-Methylphenol<br />

2-Nitroaniline<br />

2-Nitrophenol<br />

3,3'-Dichlorobenzidine<br />

3-Nitroaniline<br />

<strong>4.</strong>4-DDD<br />

4,4'-DDE<br />

4,4-DDT<br />

<strong>4.</strong>6-Dinitro-2-methylphenol<br />

4-Bromophenyl-phenylether<br />

4-Chloro-3-methylphenol<br />

4-Chloroaniline<br />

4-Chlorophenyl-phenylether<br />

4-Methyl-2-pentanone<br />

4-Methyl-2-pentanone<br />

4-Methylphenol<br />

4-Nitroaniline<br />

4-Nitrophenol<br />

Acenaphthene<br />

Acenaphthylene<br />

Acetone<br />

Acetone<br />

Aldrin<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

Alkalinity<br />

Aluminum<br />

Aluminum<br />

Aluminum<br />

Aluminum, dissolved<br />

Americium 241<br />

Americium 241<br />

Americium 241<br />

Americium 241<br />

Americium 241<br />

Anthracene<br />

Antimony<br />

Antimony<br />

Antimony<br />

Antimony. Dissolved<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

120-82-1<br />

95-50-1<br />

107-06-2<br />

107-06-2<br />

540-59-0<br />

540 - 59 - 0<br />

78-87-5<br />

78-87-5<br />

541 -73-1<br />

106-46-7<br />

95-95-4<br />

88-06-2<br />

120-83-2<br />

105-67-9<br />

51-28-5<br />

121 -14-2<br />

606-20-2<br />

78-93-3<br />

78-93-3<br />

91-58-7<br />

95-57-8<br />

591-78-6<br />

591-78-6<br />

91-57-6<br />

95-48-7<br />

88-74-4<br />

88-75-5<br />

91-94-1<br />

99 - 09 - 2<br />

72-54-8<br />

72-55-9<br />

50-29-3<br />

534-52-1<br />

101-55-3<br />

59-50-7<br />

106-47-8<br />

7005-72-3<br />

108-10-1<br />

108-10-1<br />

106-44-5<br />

100-01-6<br />

100-02-7<br />

83-32-9<br />

208-96-8<br />

67-64-1<br />

67-64-1<br />

309-00-2<br />

471 -34-1<br />

471-34-1<br />

471-34-1<br />

471-34-1<br />

471-34-1<br />

471-34-1<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

7429-90-5<br />

AM241<br />

AM241<br />

AM241<br />

AM241<br />

AM241<br />

120-12-7<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

7440-36-0<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

143888<br />

2293-89<br />

2981-90<br />

301891<br />

4102-92<br />

5414-92<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

143888<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

CH200029-00000<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

22AUGl990<br />

190CT1989<br />

22AUG 1990<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

190CT1989<br />

19OCTl989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

lOOCTl989<br />

190CTl989<br />

22AUG1990<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CTl989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

19OCTl989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

22AUG1990<br />

190CTl989<br />

19OCTl989<br />

190CT1989<br />

190CTl989<br />

190CT1989<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

1 OAUGl988<br />

23AUG1989<br />

05SEP1990<br />

O5SEP1991<br />

01 FEB1992<br />

1 1 AUGl992<br />

01 FEBl992<br />

190CT1989<br />

lSOCTl989<br />

01FEB1992<br />

1 OAUGl988<br />

23AUG1989<br />

05SEP1990<br />

05SEP1991<br />

llAUG1992<br />

190CT1989<br />

01FEB1992<br />

190CT1989<br />

190CTl989<br />

01FEB1992<br />

Page 163 of 176<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

w<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

wc,<br />

WG<br />

\I\EG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

wc,<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

w<br />

WG<br />

WG<br />

WG<br />

w<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

l.OOE+Ol<br />

1.00Et01<br />

5.00E+00<br />

5.00Et00<br />

5.00E+00<br />

5.00E+00<br />

5.00Et00<br />

5.00E+00<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

5.00Et01<br />

1.00Et01<br />

1.00Et01<br />

1.00Et01<br />

5.00E+01<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

6.00€+00<br />

1.00Et01<br />

l.OOE+Ol<br />

1.00E+01<br />

l.OOE+W<br />

l.OOE+Ol<br />

1.00E+01<br />

5.00E+01<br />

l.OOE+Ol<br />

2.00E+01<br />

5.00E+01<br />

0.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+01<br />

1.00Et01<br />

1.00E+01<br />

1.00Et01<br />

l.OOE+Ol<br />

1.00Et01<br />

l.OOE+Ol<br />

1.00Et01<br />

5.00Et01<br />

5.00E+01<br />

1.00Et01<br />

1.00Et01<br />

l.OOE+Ol<br />

<strong>4.</strong>40E+02<br />

0.00E+00<br />

7.00E+01<br />

1.01 Et02<br />

1.01Et02<br />

6.6OE+Ol<br />

9.10Et01<br />

8.80E+01<br />

0.00E+00<br />

1.00E+00<br />

0.00E+00<br />

0.00€+00<br />

1 .00E+00<br />

1.00Et00<br />

-5.00€+00<br />

0.00E+00 O.OOE+OO<br />

-1.00E+00 0.00Et00<br />

1.00E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

0.00Et00<br />

O.OOE+OO<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

J<br />

U<br />

U<br />

U<br />

J<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

BE<br />

U<br />

U'<br />

<<br />

R<br />

J<br />

J<br />

R<br />

R<br />

R<br />

J<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

pCVL<br />

pci5<br />

pci5<br />

pci5<br />

pCiL<br />

Wfl<br />

mgfl<br />

WlL<br />

WR<br />

Wfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Arsenic<br />

7440-38-2 4102-92 01FEB1992 WG O.OOE+OO c<br />

N mg1L<br />

Arsenic<br />

Arsenic<br />

7440-38-2<br />

7440-38-2<br />

CH200029-00000<br />

CH200029-DIS<br />

190CTl989<br />

190CTl989<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

U<br />

U<br />

Arsenic, Dissolved<br />

7440-38-2<br />

4102-92 01 FEE1992 WG O.OOE+OO<br />

C<br />

Barium<br />

7440-39-3<br />

4102-92 OlFEB1992 w O.OOE+OO<br />

Barium<br />

Barium<br />

Barium, dissolved<br />

Benzene<br />

Benzene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrene<br />

Benzo(b)fluoranthene<br />

Benzo(g,h,i)perylene<br />

7440-39-3<br />

7440-39-3<br />

7440-39-3<br />

71 -43-2<br />

71-43-2<br />

56-55-3<br />

50-32-8<br />

205-99-2<br />

191-24-2<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH2 00029-00000<br />

CH200029-00000<br />

190CT1989<br />

190CT1989<br />

OlFEB1992<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00€+00<br />

5.00E+00<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

l.OOE+Ol<br />

B'<br />

B'<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

Benzo(k)fluoranthene 207-08-9<br />

CH200029-00000 190CT1989 WG l.OOE+Ol<br />

U<br />

Benzoic Acid<br />

65-85-0<br />

CH200029-00000 190CT1989 WG 5.00E+01<br />

U<br />

Benzyl Alcohol<br />

100-51-6<br />

CH200029-00000 190CT1989 w I .00E+01<br />

U<br />

Benzyl Butyl Phthalate<br />

Beryllium<br />

85-68-7<br />

7440-41-7<br />

CH200029-00000<br />

4102-92<br />

190CT1989<br />

01 FEE1992<br />

WG<br />

WG<br />

1.00E+01<br />

O.OOE+OO<br />

U<br />

C<br />

Beryllium<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bismuth<br />

Bismuth, Dissolved<br />

7440-41-7<br />

7440-41-7<br />

7440-41-7<br />

7440-69-9<br />

7440-69-9<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

4102-92<br />

190CT1989<br />

190CT1989<br />

01 FEBl 992<br />

01FEB1992<br />

01FEB1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

UN<br />

UN<br />

c<br />

C<br />

C<br />

Bromodichloromethane 75-27-4<br />

CH200029-00000 190CT1989 WG 5.00E+00<br />

U<br />

Bromodichloromethane 75-27-4<br />

CH200631-00000 22AUG1990 w 5.00E+00<br />

U<br />

Bromoform<br />

75-25-2<br />

CH200029-00000 190CTl989 w 5.00E+00<br />

U<br />

Bromoform<br />

75-25-2<br />

CH200631-00000 22AUG1990 w 5.00E+00<br />

U<br />

Bromomethane<br />

74-83-9<br />

CH200029-00000 19OCTI 989 w 1.00E+01<br />

U<br />

Bromomethane<br />

Cadmium<br />

Cadmium<br />

Cadmium<br />

74-83-9<br />

7440-43-9<br />

7440-43-9<br />

7440-43-9<br />

CH200631-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

22AUG1990<br />

10AUG1988<br />

23AUG1989<br />

05SEP1990<br />

WG<br />

WG<br />

WG<br />

WG<br />

1.00E+01<br />

0.00€+00<br />

0.00€+00<br />

0.00E+00<br />

U<br />

C<br />

<<br />

c<br />

T<br />

T<br />

T<br />

Cadmium<br />

7440-43-9<br />

3oia91 05SEP1991 WG 0.00E+00<br />

C<br />

N<br />

Cadmium<br />

7440-43-9<br />

4102-92 01FEB1992 w 0.00E+00<br />

c<br />

N<br />

Cadmium<br />

7440-43-9<br />

5414-92 I AUG1992 w 0.00E+00<br />

<<br />

N<br />

Cadmium<br />

7440-43-9<br />

CH200029-00000 19OCTI 989 WG 0.00E+00<br />

N<br />

J<br />

Cadmium<br />

7440-43-9<br />

CH200029-DIS 190CT1989 w 0.00E+00<br />

N J<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium<br />

Calcium<br />

Calcium<br />

Cakium<br />

Calcium<br />

Cakium<br />

Calcium<br />

Calcium, Dissolved<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

7440-70-2<br />

4102-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

OlFEB1992<br />

10AUGl988<br />

23AUGl989<br />

05SEPl990<br />

05SEPl991<br />

01 FEB1992<br />

1 lAUG1992<br />

190CT1989<br />

190CT1989<br />

01FEB1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

O.WE+OO<br />

1.00E+01<br />

1.40€+01<br />

I .50E+Ol<br />

1.60€+01<br />

1.60€+01<br />

1.40€+01<br />

1.40E+01<br />

1.40€+01<br />

1.60E+01<br />

C<br />

N<br />

HT<br />

HT<br />

T<br />

N<br />

N<br />

N<br />

J<br />

N<br />

Carbon Disulfide<br />

Carbon Disulfide<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Cesium1 37<br />

Cesium137<br />

Cesium-I37<br />

75-15-0<br />

75-15-0<br />

56-23-5<br />

56-23-5<br />

10045-97-3<br />

10045-97-3<br />

10045-97-3<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

22AUG1990<br />

IOAUGI 988<br />

23AUG1989<br />

05SEPl990<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

\IK;<br />

WG<br />

5.00E+00<br />

5.00€+00<br />

5.00E+00<br />

5.00E+00<br />

0.00E+00<br />

0.00E+00<br />

l.OOE+OO<br />

U<br />

U<br />

U<br />

U<br />

NT<br />

NT<br />

NT<br />

Cesium-137<br />

10045-97-3<br />

3oiagi O5SEPl 991 WG O.00E+OO 0.00E+00<br />

N<br />

Cesium-137<br />

10045-97-3<br />

541492 1 lAUGl992 WG 0.00€+00 O.OOE+OO<br />

N<br />

Chloride<br />

16887-00-6<br />

1438-88 10AUGl988 w 7.90€+01<br />

T<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

Chloride<br />

16887-00-6<br />

16887-00-6<br />

16887-00-6<br />

16887-<br />

16887-00-6<br />

16887-00-6<br />

2293-89<br />

2981-90<br />

3oiagi<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

23AUGl989<br />

05SEP1990<br />

05SEP1991<br />

01FEB1992<br />

llAUG1992<br />

190CTl989<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

8.00E+Ol<br />

7.90€+01<br />

7.70€+01<br />

7.80€+01<br />

8.6OE+Ol<br />

0.00€+00<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

Chlorobenzene<br />

Chlorobenzene<br />

Chloroethane<br />

Chloroethane<br />

Chloroform<br />

Chloroform<br />

Chloromethane<br />

Chloromethane<br />

1 oa90-7<br />

108-90-7<br />

75-00-3<br />

75-00-3<br />

67-66-3<br />

67-66-3<br />

74-87-3<br />

74-87-3<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CHZW631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

22AUG1990<br />

19OCTl989<br />

22AUG1990<br />

190CT1989<br />

22AUG1990<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

5.WE+OO<br />

5.00E+00<br />

I .00E+01<br />

1.00€+01<br />

3.80E+01<br />

5.00E+00<br />

1.00E+01<br />

l.OOE+OI<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

Page 164 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Chromium 7440-47-3 1438-88 10AUG1988 WG O.OOE+OO < T mglL<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium<br />

Chromium, Dissolved<br />

Chrysene<br />

Cobalt<br />

Cobalt<br />

Coban<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt 60<br />

Cobalt, Dissolved<br />

Color<br />

Color<br />

Color<br />

Color<br />

Color<br />

Color<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper<br />

Copper, Dissolved<br />

Cyanide<br />

Depth to Water<br />

Depth to Water<br />

Depth lo Water<br />

Depth to Water<br />

Depth to Water<br />

Di-n-butylphthalale<br />

Dkn-octylphthalate<br />

Dibenzo(a.h)anthracene<br />

Dibenzofuran<br />

Dibromochloromethane<br />

Dibromochloromethane<br />

Dieldrin<br />

Diethylphthalate<br />

Dimethylphthalate<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Alpha<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Beta<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Dissolved Solids<br />

Endosulfan I<br />

Endosulfan I1<br />

Endosulfan Sulfate<br />

Endrin<br />

Endrin Ketone<br />

Ethylbenzene<br />

Et h y I be N e n e<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

7440-47-3<br />

218-01-9<br />

7440-48-4<br />

7440-48-4<br />

7440-48-4<br />

10198-40-0<br />

10198-40-0<br />

10198-40-0<br />

10198-40-0<br />

10198-40-0<br />

7440-48-4<br />

COLOR<br />

COLOR<br />

COLOR<br />

COLOR<br />

COLOR<br />

COLOR<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

7440-50-8<br />

57-12-5<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

DTW<br />

84-74-2<br />

11744-0<br />

53-70-3<br />

132-64-9<br />

124-48-1<br />

124-481<br />

60-57-1<br />

84-66-2<br />

131-11-3<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

ALPHA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

BETA DIS<br />

SO266<br />

SO266<br />

SO266<br />

SO266<br />

SO266<br />

SO266<br />

959-98-8<br />

33213-65-9<br />

1031-07-8<br />

72-20-8<br />

53494-70-5<br />

10041-4<br />

100-41-4<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH200029-00000<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

4102-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

143888<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

541 4-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

30 18-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-OooOO<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CHZ00029-00000<br />

CH200631-00000<br />

23AUG1989<br />

05SEP1990<br />

05SEPl991<br />

01 FEB1992<br />

llAUG1992<br />

190CT1989<br />

190CT1989<br />

01 FEB1992<br />

190CT1989<br />

01 FEB1992<br />

190CT1989<br />

190CT1989<br />

10AUG1988<br />

23AUG1989<br />

05SEP1990<br />

05SEP1991<br />

11 AUGI 992<br />

01FEB1992<br />

10AUG1988<br />

23AUG1989<br />

O5SEPl 990<br />

05SEP1991<br />

01 FEB1992<br />

11 AUGl992<br />

10AUG1988<br />

23AUGl989<br />

OSSEPI 990<br />

05SEPl991<br />

01FEBl992<br />

1 I AUGl992<br />

190CT1989<br />

190CTI 989<br />

01 FEBl992<br />

190CT1989<br />

10AUG1988<br />

23AUG1989<br />

05SEP1990<br />

05SEPl991<br />

11 AUGl992<br />

19OCTI 989<br />

I 9OCTl 989<br />

I 9OCTI 989<br />

190CT1989<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

1 OAUG1988<br />

23AUGl989<br />

05SEP1990<br />

O5SEPl 991<br />

1 I AUGl992<br />

IOAUGI 988<br />

23AUGl989<br />

05SEPl990<br />

05SEP1991<br />

1 AUG 1992<br />

I OAUG 1988<br />

23AUGl989<br />

05SEPl990<br />

O5SEPl 991<br />

OlFEB1992<br />

llAUG1992<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

22AUG1990<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

m<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WI;<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

< T<br />

< T<br />

4 N<br />

< N<br />

< N<br />

B<br />

B<br />

< N<br />

U<br />

< N<br />

U<br />

U<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

c<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

T<br />

N<br />

N<br />

N<br />

<<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

R<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

R<br />

R<br />

R<br />

R<br />

R<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

mglL<br />

Units<br />

Units<br />

Units<br />

units<br />

Units<br />

units<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mgfl<br />

mg1L<br />

mglL<br />

Feet<br />

Feel<br />

Feet<br />

Feet<br />

Feet<br />

ug1L<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

pcia<br />

pci5<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCiL<br />

pCilL<br />

pCiL<br />

mg1L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugR<br />

ugR<br />

ug1L<br />

Page 165 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Fluoranthene 206-44-0 CH200029-00000 190CT1989 WG l.OOE+OI U uglL<br />

Fluorene<br />

Fluoride<br />

Fluoride<br />

Fluoride<br />

Fluoride<br />

Fluoride<br />

GCIMS Scan<br />

Gamma Activity<br />

Gross Alpha<br />

Gross Beta<br />

Hardness as CaC03<br />

Heptachlor<br />

Heptachlor Epoxide<br />

Hexachlorobenzene<br />

Hexachlorobutadiene<br />

Hexachlorocyclopentadiene<br />

Hexachloroethane<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Hexavalent Chromium<br />

Indeno(l.2.3-cd)pyrene<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron<br />

Iron. Dissolved<br />

lsophorone<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead<br />

Lead, Dissolved<br />

Llhium<br />

Lithium. Dissolved<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury<br />

Mercury<br />

Mercury, Dissolved<br />

Methoxychlor<br />

Methylene Chloride<br />

Methylene Chloride<br />

Molybdenum<br />

Molybdenum, Dissolved<br />

86-73-7<br />

16984-48-8<br />

16984-48-8<br />

16984-48-8<br />

16984-48-8<br />

16984-48-8<br />

GCIMS SCAN<br />

GAMMA<br />

12587-46-1<br />

12587-47-2<br />

CACOJHARDNES<br />

76-44-8<br />

1024-57-3<br />

118-74-1<br />

87-68-3<br />

77-47-4<br />

67-72-1<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

18540-29-9<br />

193-39-5<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

7439-89-6<br />

78-59-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-92-1<br />

7439-93-2<br />

7439-93-2<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-954<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-976<br />

7439-97-6<br />

7439-97-6<br />

72-43-5<br />

75-09-2<br />

75-09-2<br />

7439-98-7<br />

7439-98-7<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

3018-91<br />

4102-92<br />

5414-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

CH200029-00000<br />

CH200029-00000<br />

CH2 00029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981 -90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

4102-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029DIS<br />

4102-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH200029-00000<br />

CH200029-00000<br />

CH20063100000<br />

4102-92<br />

4 102-92<br />

190CT1989<br />

lOAUG1988<br />

23AUG1989<br />

05SEP1991<br />

OlFEBl992<br />

llAUG1992<br />

01 FEB1992<br />

01FEBl992<br />

OlFEB1992<br />

01 FEBl992<br />

190CTl989<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

190CTl989<br />

190CT1989<br />

19OCTI 989<br />

lOAUGl988<br />

23AUGl989<br />

05SEP1990<br />

05SEP1991<br />

11 AUGl992<br />

190CT1989<br />

1 OAUGl988<br />

23AUG1989<br />

05SEP1990<br />

05SEP1991<br />

01 FEBl992<br />

I AUGI 992<br />

I 9OCTI 989<br />

190CTI989<br />

01FEB1992<br />

190CT1989<br />

I OAUG 1988<br />

23AUG1989<br />

05SEPI990<br />

05SEP1991<br />

01 FEBI 992<br />

11AUGl992<br />

190CT1989<br />

I 9OCTl 989 '<br />

OlFEB1992<br />

OlFEBl992<br />

OIFEB1992<br />

I OAUGl988<br />

23AUG1989<br />

05SEP1990<br />

05SEPl991<br />

01 FEB1992<br />

1 lAUGl992<br />

190CT1989<br />

190CTl 989<br />

01FEB1992<br />

lOAUGl988<br />

23AUG1989<br />

05SEPl990<br />

05SEPl991<br />

01 FEBl992<br />

I lAUGl992<br />

I 9OCTI 989<br />

19OCT1989<br />

OIFEB1992<br />

01FEBl992<br />

19OCTI 989<br />

190CT1989<br />

01FEB1992<br />

190CT1989<br />

190CTl989<br />

22AUG1990<br />

OlFEBl992<br />

01EB1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

wc,<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc,<br />

WG<br />

\M;<br />

wc,<br />

WG<br />

wc,<br />

WG<br />

WG<br />

wc,<br />

WG<br />

WG<br />

U<br />

Q<br />

U<br />

<<br />

<<br />

<<br />

<<br />

c<br />

N<br />

BNW<br />

<<br />

N'<br />

N.<br />

c<br />

U<br />

U<br />

c<br />

U<br />

U<br />

UB<br />

c<br />

<<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

R<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

J<br />

J<br />

N<br />

HT<br />

T<br />

T<br />

N<br />

N<br />

N<br />

J<br />

J<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

J<br />

N<br />

T<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

J<br />

N'<br />

N<br />

N<br />

N<br />

R<br />

UJ<br />

N<br />

N<br />

Page 166 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

N-Nitroso-di-n-propylamine 621-64-7 CH200029-00000 190CT1989 WG 1.00E+01 U ug1L<br />

N-Nitrosodiphen ylamine<br />

Naphthalene<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel<br />

Nickel, Dissolved<br />

Niobium<br />

Niobium, Dissolved<br />

Nitrate<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrate as Nitrogen<br />

Nitrobenzene<br />

PCB<br />

PCB<br />

PCB<br />

PCB<br />

PCB<br />

PCB<br />

PCB-1016<br />

PCB-1221<br />

PCB-1232<br />

PCB-1242<br />

PCB-1248<br />

PCB-1254<br />

PCB-1260<br />

Pentachlorophenol<br />

Phenanthrene<br />

Phenol<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphate as P<br />

Phosphorus (P)<br />

Phosphorus, Dissolved<br />

Potassium<br />

Potassium<br />

Potassium<br />

Potassium. Dissolved<br />

Pyrene<br />

RAD SCREEN<br />

Radium226<br />

Radium226<br />

Radium226<br />

Radium-226<br />

Radium-226<br />

Ruthenium<br />

Ruthenium, Dissolved<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium<br />

Selenium, Dissolved<br />

Silicon<br />

Silicon, Dissolved<br />

Silver<br />

Silver<br />

86-30-6<br />

91-20-3<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-02-0<br />

7440-03-1<br />

7440-03-1<br />

14797-55-a<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

N ITRATEASN IT<br />

N ITRATEAS N IT<br />

NITRATEASNIT<br />

NITRATEASNIT<br />

98-95-3<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

1336-36-3<br />

12674-11-2<br />

11104-28-2<br />

11141 -16-5<br />

53469-21-9<br />

12672-29-6<br />

11097-69-1<br />

11096-82-5<br />

87-86-5<br />

85-01-8<br />

108-95-2<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

PHOS PHATEAS P<br />

PHOSPHATEASP<br />

PHOSPHATEASP<br />

7723-14-0<br />

7723-14-0<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

7440-09-7<br />

129-00-0<br />

R SCREEN<br />

13982-63-3<br />

13982-63-3<br />

13982-63-3<br />

13982-63-3<br />

13982-63-3<br />

7440-18-8<br />

7440-18-8<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7782-49-2<br />

7440-21-3<br />

7440-21-3<br />

7440-22-4<br />

7440-22-4<br />

CH200029-00000<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

4102-92<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH200029-00000<br />

2917-89<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

4102-92<br />

4102-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3016-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

CH200029-ooOOO<br />

190CT1989<br />

190CT1989<br />

10AUG1988<br />

23AUG1989<br />

O5SEPl 990<br />

O5SEPl 991<br />

01 FEB1992<br />

11 AUGl992<br />

190CT1989<br />

190CT1989<br />

01 FEE1992<br />

01 FEBl 992<br />

01 FEE1992<br />

190CT1989<br />

10AUG1988<br />

23AUG1989<br />

O5SEPl 990<br />

05SEP1991<br />

OlFEB1992<br />

I 1 AUGI 992<br />

190CT1989<br />

10AUGl988<br />

23AUG1989<br />

05SEPl990<br />

05SEPl991<br />

01FEBl992<br />

11AUG1992<br />

190CT1989<br />

190CTl989<br />

19OCTI 989<br />

19OCTl 989<br />

190CTl989<br />

190CT1989<br />

190CTl989<br />

190CT1989<br />

1 SOCTI 989<br />

190CTl989<br />

1 OAUG 1988<br />

23AUG1989<br />

05SEPl990<br />

OLSEPI 991<br />

OlFEB1992<br />

llAUG1992<br />

01 FEB1992<br />

01 FEB1992<br />

01 FEE1992<br />

190CT1989<br />

190CT1989<br />

01 FEB1992<br />

190CT1989<br />

190CT1989<br />

10AUGl988<br />

23AUG1989<br />

05SEP1990<br />

05SEP1991<br />

11 AUGl992<br />

01FEB1992<br />

01FEBl992<br />

1 OAUG1988<br />

23AUG1989<br />

05SEP1990<br />

05SEPl991<br />

OlFEB1992<br />

I AUG1992<br />

190CT1989<br />

190CT1989<br />

01FEB1992<br />

01FEB1992<br />

OlFEB1992<br />

01FEB1992<br />

190CT1989<br />

Page 167 of 176<br />

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T<br />

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HT<br />

N<br />

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T<br />

T<br />

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N<br />

N<br />

NW<br />

N<br />

N<br />

N<br />

N<br />

R<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg/L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

uglL<br />

uglL<br />

ug1L<br />

ug/L<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

uglL<br />

ug/L<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

mg/L<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

pCilml<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCiL<br />

pCVL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mgfl<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALME CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Silver<br />

7440-22-4 CH200029-DIS 190CT1989 WG O.OOE+OO UN R mg1L<br />

Silver, dissolved<br />

7440-22-4<br />

4102-92 01 FEBl 992<br />

c<br />

N<br />

mglL<br />

Sodium<br />

7440-23-5<br />

143858 lOAUG1988<br />

HT mglL<br />

Sodium<br />

7440-23-5<br />

2293 - 89<br />

23AUGl989<br />

HT mglL<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Strontium<br />

Strontium, Dissolved<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

7440-24-6<br />

7440-24-6<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

1438-88<br />

1439-88<br />

1440-88<br />

1441-88<br />

2293-89<br />

2981 -90<br />

3018-91<br />

3041-91<br />

3042-91<br />

3043-91<br />

4102-92<br />

5414-92<br />

5415-92<br />

5416-92<br />

5417-92<br />

4102-92<br />

4102-92<br />

05SEP1990<br />

05SEPl991<br />

OlFEB1992<br />

llAUGl992<br />

190CT1989<br />

190CT1989<br />

01FEB1992<br />

10AUG1988<br />

10AUG1988<br />

10AUG1988<br />

10AUG1988<br />

23AUG1989<br />

OSSEPl990<br />

05SEP1991<br />

05SEP1991<br />

O5SEPl991<br />

O5SEPl991<br />

01 FEE1992<br />

11 AUG 1992<br />

11 AUG 1992<br />

11AUG1992<br />

11 AUG 1992<br />

01 FEBl 992<br />

01 FEBl 992<br />

T<br />

N<br />

N<br />

N<br />

J<br />

N<br />

T<br />

T<br />

T<br />

T<br />

HT<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhodcm<br />

umhoslcm<br />

umhoslcm<br />

mglL<br />

mglL<br />

Styrene<br />

Styrene<br />

S u lfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfate<br />

Sulfide<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Alpha<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

Suspended Beta<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

Tantalum<br />

Tantaium.Dissolved<br />

Technetium99<br />

Technetium99<br />

Technetium-99<br />

Technetium99<br />

Technetium99<br />

Technetium99<br />

Temperature<br />

Temperature<br />

100-42-5<br />

100-42-5<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

12143-45-2<br />

18496-25-8<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GA SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

GB SUSP<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

TOX<br />

7440-25-7<br />

7440-25-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

14133-76-7<br />

SO835<br />

SO835<br />

CH200029-00000<br />

CH200631-00000<br />

1438-88<br />

229359<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-00000<br />

143858<br />

229359<br />

2981-90<br />

3oiagi<br />

5414-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

1438-88<br />

143988<br />

1440-88<br />

144188<br />

2293-89<br />

2981-90<br />

3018-91<br />

3041-91<br />

3042-91<br />

3043-91<br />

5414-92<br />

5415-92<br />

5416-92<br />

5417-92<br />

4102-92<br />

4102-92<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200631-00000<br />

2293-89<br />

2981-90<br />

190CT1989<br />

22AUG1990<br />

10AUG1988<br />

23AUG1989<br />

OSSEPl990<br />

05SEP1991<br />

01 FEBl992<br />

11AUG 1992<br />

190CT1989<br />

190CT1989<br />

10AUG1988<br />

23AUG1989<br />

OSSEP1990<br />

OSSEPl991<br />

1 lAUG1992<br />

10AUG1988<br />

23AUG1989<br />

05SEPl990<br />

OSSEP1991<br />

11AUGI 992<br />

1 OAUGl988<br />

10AUGl988<br />

1 OAUG 1988<br />

10AUG1988<br />

23AUG1989<br />

05SEP1990<br />

05SEPl991<br />

05SEPl991<br />

O5SEPl991<br />

05SEP1991<br />

I lAUGl992<br />

1 lAUGl992<br />

llAUGl992<br />

11 AUGl992<br />

01 FEE1 992<br />

01 FEBl 992<br />

23AUG1989<br />

05SEPl990<br />

05SEP1991<br />

01FEB1992<br />

1 lAUGl992<br />

22AUG1990<br />

23AUG 1989<br />

05SEP1990<br />

U<br />

U<br />

<<br />

UJ<br />

J<br />

J<br />

J<br />

c<br />

<<br />

UA<br />

HT<br />

HT<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

T<br />

HT<br />

T<br />

T<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

T<br />

HT<br />

N<br />

N<br />

N<br />

H<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mgIL<br />

mg5<br />

mglL<br />

mglL<br />

pCilL<br />

pCilL<br />

pci5<br />

pCilL<br />

pCiL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pCilL<br />

pci5<br />

uglL<br />

uglL<br />

ug5<br />

uglL<br />

ug5<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug5<br />

uglL<br />

ugn<br />

mg/L<br />

mg/L<br />

pCi<br />

pCiL<br />

pci5<br />

pCiL<br />

pCi<br />

pci5<br />

F<br />

F<br />

Page 168 of 176<br />

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w<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

w<br />

w<br />

WG<br />

WG<br />

WG<br />

w


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Temperature SO835 3018-91 O5SEP1991 WG 6.70E+01 N F<br />

Temperature<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Thallium<br />

Thallium<br />

Thallium<br />

Thallium, Dissolved<br />

Thorium<br />

Thorium, Dissolved<br />

Tin<br />

Tin, Dissolved<br />

Titanium<br />

Titanium. Dissolved<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Toxaphene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Trichloroet hene<br />

Trichloroethene<br />

Tungsten<br />

Tungsten, Dissolved<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Turbidity<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium<br />

Uranium, Dissolved<br />

Vanadium<br />

Vanadium<br />

Vanadium<br />

Vanadium, Dissolved<br />

Vinyl Acetate<br />

Vinyl Acetate<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc<br />

Zinc, Dissolved<br />

Zirconium<br />

SO835<br />

SO835<br />

127-18-4<br />

127-18-4<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-28-0<br />

7440-29-1<br />

7440-29-1<br />

7440-31-5<br />

7440-31-5<br />

7440-32-6<br />

7440-34-6<br />

108-88-3<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

8001-35-2<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

79-01-6<br />

7440-33-7<br />

7440-33-7<br />

SO278<br />

SO278<br />

SO278<br />

SO278<br />

SO278<br />

SO278<br />

7440-61-1<br />

7440-61-1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

7440-61 -1<br />

DIS U<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

7440-62-2<br />

108-05-4<br />

108-05-4<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-66-6<br />

7440-666<br />

7440-67-7<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200631-00000<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

4102-92<br />

CH200029-00000<br />

CH200631-00000<br />

143848<br />

1440-88<br />

229349<br />

2981 -90<br />

3018-91<br />

3041-91<br />

3042-91<br />

3043-91<br />

5414-92<br />

5415-92<br />

5416-92<br />

5417-92<br />

CH200029-00000<br />

143888<br />

2293-89<br />

2981-90<br />

3018-91<br />

5414-92<br />

CH200029-00000<br />

CH200631-00000<br />

4102-92<br />

4102-92<br />

1438-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

143888<br />

229399<br />

2981-90<br />

3oiagi<br />

4102-92<br />

5414-92<br />

4102-92<br />

4102-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

CH2W029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200631-00000<br />

143848<br />

229349<br />

2981-90<br />

3018-91<br />

4102-92<br />

5414-92<br />

CH200029-00000<br />

CH200029-DIS<br />

4102-92<br />

4102-92<br />

01 FEB1992<br />

11 AUGl992<br />

190CT1989<br />

22AUG1990<br />

01 FEB1992<br />

190CT1989<br />

190CT1989<br />

01FEB1992<br />

01FEB1992<br />

01 FEB1992<br />

01 FEB1992<br />

01 FEB1992<br />

01 FEBl992<br />

01 FEB1992<br />

190CT1989<br />

22AUG1990<br />

10AUG1988<br />

1 OAUG 1988<br />

23AUG1989<br />

05SEPl990<br />

05SEP1991<br />

05SEP1991<br />

05SEPl991<br />

05SEPl991<br />

11 AUGl992<br />

11 AUGl992<br />

llAUG1992<br />

llAUGl992<br />

19OCTl989<br />

1 OAUGl988<br />

23AUGl989<br />

05SEPl990<br />

OSSEP1991<br />

I lAUG1992<br />

190CT1989<br />

22AUGl990<br />

01FEB1992<br />

01FEB1992<br />

IOAUGI 988<br />

23AUG1989<br />

05SEP1990<br />

05SEP1991<br />

01 FEBl992<br />

llAUG1992<br />

lOAUG1988<br />

23AUG1989<br />

OSSEPl990<br />

05SEP1991<br />

01FEB1992<br />

1 lAUGl992<br />

01FEB1992<br />

01 FEB1992<br />

190CT1989<br />

1 SOCTI 989<br />

01 FEBl992<br />

19OCT1989<br />

22AUG1990<br />

190CT1989<br />

22AUG1990<br />

190CT1989<br />

22AUG1990<br />

lOAUGl988<br />

23AUGl989<br />

05SEPI 990<br />

05SEP1991<br />

OlFEB1992<br />

1 I AUGl992<br />

190CT1989<br />

19OCTl989<br />

01FEB1992<br />

OlFEB1992<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc.<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

wc.<br />

WG<br />

WG<br />

WG<br />

ws<br />

wc.<br />

WG<br />

WG<br />

wc.<br />

WG<br />

5.60E+01<br />

7.40E+01<br />

5.00E+00<br />

5.00E+00<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

5.00E+00<br />

5.00E+00<br />

6.00E+00<br />

7.00E+00<br />

l.OOE+OO<br />

1 .WE+00<br />

2.00E+00<br />

2.00E+00<br />

2.00E+00<br />

2.00E+00<br />

2.WE+00<br />

1.00E+00<br />

l.OOE+OO<br />

l.OOE+OO<br />

1 .00E+00<br />

l.OOE+OO<br />

1.00E+00<br />

1 .00E+00<br />

2.00E+01<br />

l.OOE+W<br />

5.00E+00<br />

5.00E+00<br />

1.00E+W<br />

1.00E+00<br />

2.70E+01<br />

l.lOE+Ol<br />

6.00E+01<br />

1 .5OE+O1<br />

1.50E+01<br />

<strong>4.</strong>20E+01<br />

O.WE+W<br />

0.00E+W<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.WE+OO<br />

O.WE+OO<br />

O.WE+W<br />

O.WE+W<br />

0.00E+00<br />

O.WE+OO<br />

O.WE+OO<br />

I.WE+OI<br />

I.WE+Ol<br />

1.00E+01<br />

1 .00E+OI<br />

5.00E+00<br />

5.00E+00<br />

9.50E+01<br />

5.60E+01<br />

5.40E+Ol<br />

3.1OE+O1<br />

5.3OE+01<br />

5.30E+01<br />

1.20E+01<br />

3.70E+01<br />

3.90€+01<br />

O.OOE+W<br />

U<br />

U<br />

<<br />

UNW<br />

UN<br />

C<br />

<<br />

<<br />

<<br />

<<br />

<<br />

<<br />

U<br />

U<br />

U<br />

N<br />

NW<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

NT<br />

NT<br />

NT<br />

N<br />

N<br />

N<br />

N<br />

T<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

HT<br />

T<br />

T<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

HT<br />

HT<br />

HT<br />

N<br />

N<br />

N<br />

J<br />

J<br />

N<br />

N<br />

F<br />

F<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

WlL<br />

mglL<br />

Wk<br />

mgfl<br />

uglL<br />

uglL<br />

uglL<br />

ugfl<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

mg/L<br />

mglL<br />

NTU<br />

NTU<br />

NTU<br />

NTU<br />

NTU<br />

NTU<br />

WlL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mgk<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

ugk<br />

mglL<br />

mgk<br />

mgk<br />

mglL<br />

mgk<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

Page 169 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Zirconium. Dissolved 7440-67-7 4102-92 OlFEB1992 WG O.OOE+OO < N mglL<br />

alpha-BHC<br />

alpha-Chlordane<br />

beta-BHC<br />

bis(2-Chloroethoxy)methane<br />

bis(2-Chloroethybether<br />

bis(2-Chloroisopropybether<br />

bis(2-Ethy1hexyf)phthalate<br />

cis-1 ,3-Dichloropropene<br />

cis-1 .3-Dichloropropene<br />

delta-BHC<br />

garnma-BHC(Lindane)<br />

gamma-Chlordane<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

PH<br />

trans-l,3-Dichloropropene<br />

trans-1.3-Dichloropropene<br />

WAG 7, SVWU 8, W O O<br />

1 ,I,l-Trichloroethane<br />

1.1,l-Trichloroethane<br />

1 .I.2-Trichloroethane<br />

1.1.2-Trichloroethane<br />

1 .l-Dichloroethane<br />

1 .l-Dichloroethane<br />

1 .I-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

Cobalt<br />

Cobalt, Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Ethylbenzene<br />

319-84-6<br />

5103-71-9<br />

319-85-7<br />

11 1-91-1<br />

111-44-4<br />

108-60-1<br />

117-81-7<br />

10061-01-5<br />

10061-01 -5<br />

319-86-8<br />

58-89-9<br />

5103-74-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

so296<br />

SO296<br />

10061-02-6<br />

10061-02-6<br />

71-55-6<br />

71-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

47 1-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7440-41 -7<br />

744041-7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

6766-3<br />

67-66-3<br />

744047-3<br />

744047-3<br />

7440-48-4<br />

744048-4<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

10041-4<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200631-00000<br />

CH200029-00000<br />

CH200029-00000<br />

CH200029-00000<br />

1438-88<br />

1439-88<br />

1440-88<br />

1441-88<br />

2293-89<br />

2981-90<br />

3018-91<br />

3041-91<br />

3042-91<br />

3043-91<br />

4102-92<br />

5414-92<br />

5415-92<br />

5416-92<br />

5417-92<br />

CH200029-00000<br />

CH200631-00000<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

190CT1989<br />

190CTl989<br />

19OCTl989<br />

19OCTl989<br />

19OCTl989<br />

lSOCTl989<br />

190CT1989<br />

19OCTl989<br />

22AUG1990<br />

190CT1989<br />

190CT1989<br />

190CT1989<br />

lOAUG1988<br />

1 OAUG 1988<br />

10AUG1988<br />

1 OAUG 1988<br />

23AUG1989<br />

OSSEP1990<br />

OSSEP1991<br />

05SEPl991<br />

OBSEPl991<br />

OSSEP1991<br />

OlFEB1992<br />

1 1 AUGl992<br />

1 1 AUGl992<br />

1 1 AUGl992<br />

1 1 AUGl992<br />

190CT1989<br />

22AUG1990<br />

21MAR1995<br />

12JUL1995<br />

21 MARl 995<br />

12JULl995<br />

21 MARl 995<br />

12JULl995<br />

21 MARl 995<br />

12JULl995<br />

21MAR1995<br />

12JUL1995<br />

21MAR1995<br />

21 MARl 995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

12JUL1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

12JULl995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

12JULl995<br />

21 MARl 995<br />

21MAR1995<br />

12JULl995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

2 1MAR1995<br />

21MAR1995<br />

2lMAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

Page 170 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

U<br />

ux<br />

ux<br />

U<br />

U<br />

<<br />

<<br />

Q<br />

c<br />

Q<br />

<<br />

U<br />

U<br />

U<br />

U<br />

c<br />

<<br />

U<br />

U<br />

U<br />

U<br />

<<br />

Q<br />

J<br />

<<br />

<<br />

U<br />

R<br />

UJ<br />

UJ<br />

R<br />

R<br />

H<br />

H<br />

H<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

ug5<br />

uglL<br />

uglL<br />

uglL<br />

45<br />

uglL<br />

ugfl<br />

uglL<br />

ugfl<br />

uglL<br />

45<br />

wlL<br />

mg5<br />

mglL<br />

w5<br />

mglL<br />

mglL<br />

W/L<br />

ugIL<br />

uglL<br />

w/L<br />

wfl<br />

uglL<br />

uglL<br />

WlL<br />

w5<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

uglL<br />

ug1L<br />

mg5<br />

mglL<br />

WlL<br />

mgR<br />

mgk<br />

wfl<br />

Feet<br />

mglL<br />

w5<br />

ugfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Ethylbenzene 100-41-4 7070-95 12JUL1995 WG 5.00E+01 U N uglL<br />

Fluoride<br />

Gross Alpha<br />

Gross Beta<br />

Iron<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury, Dissolved<br />

Nickel<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Potassium<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Technetium99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-1.2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Uranium<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc, Dissolved<br />

cis-1.2-dichloroethene<br />

cis-1.2dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SWU 0, MWOl<br />

1 ,l,l-Trichloroethane<br />

1 ,l,l-Trichloroethane<br />

1.1.2-Trichloroethane<br />

1,1,2-Trichloroethane<br />

1,l-Dichloroethane<br />

1.1 -Dichloroethane<br />

1 .l-Dichloroethene<br />

1 ,l-Dichloroethene<br />

1,2-DichloroeIhane<br />

1.2-Dichloroethane<br />

Alkalinity<br />

Antimony<br />

16904-40-0<br />

12507-46-1<br />

12507-47-2<br />

7439-09-6<br />

7439-92-1<br />

7439-92-1<br />

7439 - 95 -4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7440-02-0<br />

7440-02-0<br />

N ITRATEAS N IT<br />

7440-09-7<br />

RN222<br />

7702-49-2<br />

7702-49-2<br />

7631-06-9<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

14133-76-7<br />

SO035<br />

127-18-4<br />

127-10-4<br />

100-08-3<br />

100-00-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

SO270<br />

7440-61-1<br />

DIS U<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

71 -55-6<br />

71-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

7440-36-0<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5 5 4 9 - 9 5<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5550-95<br />

5551-95<br />

5552-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5550-95<br />

5551 -95<br />

5552-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5549-95<br />

5549-95<br />

7070-95<br />

5549-95<br />

5550-95<br />

5551-95<br />

5552-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

5553-95<br />

21MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

21 MAR 1995<br />

21 MAR 1995<br />

21 MAR 1995<br />

21 MARl 995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

2lMARl995<br />

21 MAR 1995<br />

21 MARl 995<br />

2 lMARl995<br />

21MARl995<br />

21MAR1995<br />

21 MARl 995<br />

2lMARl995<br />

2 lMARl995<br />

21MAR1995<br />

21 MAR1 995<br />

21 MARl 995<br />

21MAR1995<br />

2lMARl995<br />

21MAR1995<br />

21 MAR1 995<br />

21 MAR1995<br />

21 MAR1995<br />

2lMAR1995<br />

2lMAR1995<br />

21MAR1995<br />

21 MARl 995<br />

12JUL1995<br />

21 MARl 995<br />

12JULl995<br />

2lMARl995<br />

2 1 MARl 995<br />

21 MARl 995<br />

21MAR1995<br />

21 MAR1995<br />

12JUL1995<br />

2lMARl995<br />

12JUL1995<br />

2lMARl995<br />

2 lMARl995<br />

2lMARl995<br />

21MAR1995<br />

12JUL1995<br />

21 MARl 995<br />

12JUL1995<br />

21 MARl 995<br />

21 MARl 995<br />

21 MARl 995<br />

12JUL1995<br />

21MAR1995<br />

2 1MAR1995<br />

2 lMARl995<br />

2lMARl995<br />

21MAR1995<br />

12JUL1995<br />

21MAR1995<br />

12JULl995<br />

21MAR1995<br />

12JULl995<br />

21MAR1995<br />

12JUL1995<br />

2lMARl995<br />

12 JULl995<br />

21MAR1995<br />

21MAR1995<br />

Page 171 of 176<br />

< N<br />

N<br />

N<br />

<<br />

<<br />

c<br />

Q<br />

c<br />


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

mglL<br />

Antimony, Dissolved 7440-36-0 5553-95 21MAR1995 WG O.OOE+OO<br />

-<br />

U<br />

Arsenic<br />

7440-38-2<br />

5553-95 2 lMARl995 WG<br />

C<br />

N<br />

mg/L<br />

Arsenic, Dissolved<br />

7440-38-2<br />

5553-95 21 MARl 995 WG<br />

Q<br />

N<br />

mglL<br />

Barium<br />

7440-39-3<br />

5553 - 95<br />

21 MARl 995 WG<br />

c<br />

N<br />

mg1L<br />

Barium, Dissolved<br />

7440-39-3<br />

5553-95 21MAR1995 WG<br />

C<br />

N<br />

mglL<br />

Benzene<br />

71-43-2<br />

5553-95 21 MAR 1995<br />

WG<br />

UJX<br />

N<br />

uglL<br />

Benzene<br />

71 -43-2<br />

7074-95 12JUL1995 WG<br />

U<br />

N<br />

uglL<br />

Beryllium<br />

7440-41-7<br />

5553 - 95<br />

21 MARl 995 WG<br />

c<br />

N<br />

mglL<br />

Beryllium, Dissolved<br />

7440-41 -7<br />

5553-95 21 MARl 995 WG<br />

c<br />

N<br />

mglL<br />

Bromodichloromethane 75-27-4<br />

5553-95 2lMARl995 WG<br />

UJX<br />

N<br />

uglL<br />

Bromodichloromethane 75-27-4<br />

7074-95 12JUL1995 WG<br />

U<br />

N<br />

uglL<br />

Cadmium<br />

7440-43-9<br />

5553-95 2lMAR 1995 WG<br />

C<br />

N<br />

mglL<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

5553-95<br />

5553-95<br />

5553-95<br />

21 MAR1 995<br />

21 MARl 995<br />

21 MARl 995<br />

WG<br />

WG<br />

WG<br />

c<br />

N<br />

N<br />

N<br />

mglL<br />

mg1L<br />

mglL<br />

Carbon Tetrachloride 56-23-5<br />

5553-95 21MAR1995<br />

WG<br />

UJX N<br />

ug/L<br />

Carbon Tetrachloride<br />

Chloride<br />

56-23-5<br />

16887-00-6<br />

7074-95<br />

5553-95<br />

12JULl995<br />

21MAR1995<br />

WG<br />

WG<br />

U<br />

N<br />

N<br />

uglL<br />

mglL<br />

Chloroform<br />

67-66-3<br />

5553-95 21 MARl 995 WG<br />

UJX<br />

N<br />

uglL<br />

C hloroform<br />

67-66-3<br />

7074-95 12JUL1995 WG<br />

U<br />

N<br />

uglL<br />

Chromium<br />

7440-47-3<br />

5553-95 21 MAR1 995 WG<br />

c<br />

N<br />

mglL<br />

Chromium, Dissolved 7440-47-3<br />

5553-95 21MAR1995 WG<br />

c<br />

N<br />

mglL<br />

Coban<br />

7440-48-4<br />

5553-95 21MAR1995 WG<br />

C<br />

N<br />

mglL<br />

Cobatl, Dissolved<br />

7440-48-4<br />

5553-95 21MAR1995 WG<br />

C<br />

N<br />

mglL<br />

Copper<br />

7440-50-8<br />

5553-95 2lMARl995 WG<br />

c<br />

N<br />

mglL<br />

Copper, Dissolved<br />

7440-50-8<br />

5553-95 2lMARl995 WG<br />

c<br />

N<br />

mglL<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Ethylbenzene<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

10041-4<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

21 MAR1 995<br />

21 MARl 995<br />

21 MAR1 995<br />

21 MAR1 995<br />

WG<br />

WG<br />

WG<br />

WG<br />

UJX<br />

N<br />

N<br />

N<br />

N<br />

Feet<br />

mglL<br />

mglL<br />

uglL<br />

Ethylbenzene<br />

100-41-4<br />

7074-95 12JULl995 WG<br />

U<br />

N<br />

uglL<br />

Fluoride<br />

16984-4a-a<br />

5553-95 21 MARl 995 w<br />

N<br />

mglL<br />

Gross Alpha<br />

Gross Beta<br />

Iron<br />

12587-46-1<br />

12587-47-2<br />

7439-89-6<br />

5553-95<br />

5553-95<br />

5553-95<br />

2IMARl995<br />

21MAR1995<br />

21MAR1995<br />

WG<br />

WG<br />

WG<br />

N<br />

N<br />

N<br />

pCilL<br />

pciA<br />

mglL<br />

Iron. Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-954<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

21 MARl 995<br />

21 MAR1 995<br />

21 MARl 995<br />

21MAR1995<br />

21MAR1995<br />

21MARI 995<br />

21 MAR1 995<br />

21 MAR1 995<br />

WG<br />

WG<br />

WG<br />

WG<br />

\IKj<br />

WG<br />

WG<br />

WG<br />

c<br />

c<br />

C<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mg/L<br />

mg1L<br />

mglL<br />

mglL<br />

Mercury, Dissolved<br />

7439-97-6<br />

5553-95 21MAR1995 WG<br />

Q<br />

N<br />

mg/L<br />

Nickel<br />

7440-02-0<br />

5553-95 21MAR1995 WG<br />

C<br />

N<br />

mglL<br />

Nickel. Dissolved<br />

Nitrate as Nitrogen<br />

7440-02-0<br />

NITRATEASNIT<br />

5553-95<br />

5553-95<br />

21MAR1995<br />

21MAR1995<br />

WG<br />

WG<br />

c<br />

c<br />

N<br />

N<br />

mglL<br />

mglL<br />

Potassium<br />

7440-09-7<br />

5553-95 21 MARl 995 WG<br />

N<br />

mgk<br />

Potassium, Dissolved 7440-09-7<br />

5553-95 21MAR1995 WG<br />

N<br />

mglL<br />

Radon 222<br />

RN222<br />

5553-95 21MAR1995 WG<br />

N<br />

pCilL<br />

Selenium<br />

7782-49-2<br />

5553-95 21MAR1995 w<br />

eN<br />

N<br />

mglL<br />

Selenium. Dissolved<br />

7782-49-2<br />

5553-95 21MAR1995 WG<br />

Q<br />

mglL<br />

Silica<br />

Silver<br />

Silver. Dissolved<br />

7631-86-9<br />

7440-22-4<br />

7440-22-4<br />

5553-95<br />

5553-95<br />

5553-95<br />

21MAR1995<br />

21MAR1995<br />

21MARI 995<br />

WG<br />

WG<br />

WG<br />

c<br />

c<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mg/L<br />

Sodium<br />

7440-23-5<br />

5553-95 21MAR1995 WG<br />

0<br />

N<br />

mglL<br />

Sodium, Dissolved<br />

7440-23-5<br />

5553-95 21MAR1995 w<br />

0<br />

N<br />

mglL<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

5553-95<br />

5554-95<br />

555595<br />

5556-95<br />

5553-95<br />

21MAR1995<br />

21MAR1995<br />

21 MAR1995<br />

21MAR1995<br />

21MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

N<br />

N<br />

N<br />

N<br />

N<br />

umhodcm<br />

umhodcm<br />

umhoslcm<br />

umhodcm<br />

mglL<br />

Technetium99<br />

14133-76-7<br />

5553-95 21MAR1995 WG<br />

N<br />

pCiL<br />

Temperature<br />

SO835<br />

5553-95 21MAR1995 WG<br />

N<br />

F<br />

Tetrachloroethene<br />

127-18-4<br />

5553-95 21MAR1995 WG<br />

UJX N<br />

uglL<br />

Tetrachloroethene<br />

127-18-4<br />

7074-95 I 2JULl 995 WG<br />

U<br />

N<br />

uglL<br />

Toluene<br />

108-86-3<br />

5553-95 21MAR1995 w<br />

U JX<br />

N<br />

uglL<br />

Toluene<br />

108-88-3<br />

7074-95 12JULl995 WG<br />

U<br />

N<br />

uglL<br />

Total Organic Carbon 7440-44-0<br />

5553-95 21MAR1995 w<br />

N mgR<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

5554-95<br />

555595<br />

5556-95<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

WG<br />

WG<br />

WG<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mgfl<br />

Page 172 of 176


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE TYPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Trans-I .2-Dichloroethene 156-60-5 5553-95 21MAR1995 WG 5.00€+00 UJX N ug1L<br />

Trans-I ,2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Uranium<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc, Dissolved<br />

cis-I .2-dichloroethene<br />

cis-I ,2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

WAG 7, SVUvlU 8. MW302<br />

1 .I,I-Trichloroethane<br />

I ,I,I-Trichloroethane<br />

1 .I,2-Trichbroethane<br />

1 ,I.2-Trichloroethane<br />

1,l-Dichloroethane<br />

1 .I-Dichloroethane<br />

1,l-Dichloroethene<br />

1 ,I-Dichloroethene<br />

1.2-Dichloroethane<br />

I .2-Dichloroethane<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissotved<br />

Arsenic<br />

Arsenic, Dissolved<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

Beryllium, Dissolved<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

Coban<br />

Cobalt, Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

Gross Alpha<br />

Gross Beta<br />

Iron<br />

Iron. Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

156-60-5<br />

79-01 -6<br />

79-01 -6<br />

SO278<br />

7440-61-1<br />

DIS U<br />

75-01-4<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

71-55-6<br />

71 -55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-38-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7440-41-7<br />

7440-41-7<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

67-66-3<br />

67-66-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7440-50-8<br />

7440-50-8<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

100-41-4<br />

100-41-4<br />

16984-48-8<br />

12587-46-1<br />

12587-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7074-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

7074-95<br />

5 5 5 3 - 9 5<br />

7074-95<br />

5553-95<br />

5553-95<br />

5553-95<br />

7074-95<br />

5553-95<br />

5554-95<br />

5555-95<br />

5556-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

12JUL1995<br />

2 lMARl995<br />

12JUL1995<br />

21 MAR1 995<br />

21 MAR 1995<br />

21 MAR1 995<br />

21MAR1995<br />

12JULl995<br />

21MAR1995<br />

12JUL1995<br />

21 MARl 995<br />

21 MAR1 995<br />

2lMARl995<br />

12JUL1995<br />

21 MARl 995<br />

2lMAR 1995<br />

21 MARl 995<br />

21MAR1995<br />

2 IMARI 995<br />

12JULl995<br />

21MAR1995<br />

12JUL1995<br />

21 MAR1995<br />

12JULl995<br />

21 MAR1995<br />

12JUL1995<br />

21 MAR1 995<br />

12JULl995<br />

21 MAR1 995<br />

21 MARl 995<br />

2IMAR1995<br />

21MARl995<br />

21MAR1995<br />

21MARI 995<br />

2lMARl995<br />

21 MAR1 995<br />

12JUL1995<br />

21MAR1995<br />

21 MAR1995<br />

21 MAR1 995<br />

12JULl995<br />

21 MAR1 995<br />

2IMAR1995<br />

2lMARl995<br />

21 MARl 995<br />

2lMARl995<br />

12JUL1995<br />

21MAR1995<br />

2lMARl995<br />

12JULl995<br />

21MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

2lMARl995<br />

2lMARl995<br />

21 MARl 995<br />

21 MAR1 995<br />

21MAR1995<br />

2lMARl995<br />

21 MARl 995<br />

12JULl995<br />

21 MAR1 995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

21MAR1995<br />

21MAR1995<br />

Page 173 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

w<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

5.00E+00<br />

1.00€+00<br />

1.00E+00<br />

2.80€+01<br />

0.00E+00<br />

0.00E+00<br />

1.00E+01<br />

l.OOE+Ol<br />

1.00E+01<br />

1 .OOE+Ol<br />

O.OOE+OO<br />

0.00E+00<br />

2.50E+01<br />

2.50€+01<br />

6.00€+00<br />

6.00E+00<br />

6.00E+00<br />

6.00E+00<br />

U<br />

U JX<br />

ux<br />

UJX<br />

ux<br />

UJX<br />

U<br />

<<br />

<<br />

JX<br />

UJX<br />

U<br />

U JX<br />

U<br />

UJX<br />

U<br />

U JX<br />

U<br />

UJX<br />

U<br />

<<br />

Q<br />

<<br />

Q<br />

UJX<br />

U<br />

<<br />

<<br />

UJX<br />

U<br />

<<br />

c<br />

U JX<br />

U<br />

UJX<br />

U<br />

c<br />

<<br />

<<br />

<<br />

<<br />

<<br />

UJX<br />

U<br />

<<br />

<<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

ug1L<br />

N N<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

uglL<br />

uglL<br />

ug/L<br />

uglL<br />

uglL<br />

ug/L<br />

uglL<br />

uglL<br />

ug1L<br />

uglL<br />

mglL<br />

mg/L<br />

rnglL<br />

mglL<br />

mglL<br />

mglL<br />

rn@<br />

uglL<br />

uglL<br />

mglL<br />

rnglL<br />

uglL<br />

ug/L<br />

mglL<br />

mglL<br />

mglL<br />

rngk<br />

uglL<br />

UglL<br />

mgfl<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Feet<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

mglL<br />

pci/L<br />

pCiL<br />

mgk<br />

mgk<br />

W L<br />

mglL<br />

mgfl<br />

mgfl


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE WPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury, Dissolved<br />

Nickel<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium, Dissolved<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7440-02-0<br />

7440-02-0<br />

NITRATEASNIT<br />

7440-09-7<br />

7440-09-7<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

21MAR1995<br />

2lMARl995<br />

21 MARl 995<br />

21 MARl 995<br />

21MARl995<br />

21MAR1995<br />

2 lMARl995<br />

21 MARl 995<br />

21 MARl 995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

O.OOE+OO<br />

l.OOE+OO<br />

l.lOE+Ol<br />

O.OOE+OO<br />

c<br />

Q<br />

<<br />

c<br />

c<br />

c<br />

Q<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

mglL<br />

mg1L<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

mglL<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

Silica<br />

RN222<br />

7782-49-2<br />

7782-49-2<br />

7631-86-9<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

21MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

21 MARl 995<br />

WG<br />

WG<br />

WG<br />

WG<br />

1.05E+02 1.20E+01<br />

O.OOE+OO<br />

O.OOE+OO<br />

<strong>4.</strong>70E+01<br />

CN<br />

Q<br />

N<br />

N<br />

N<br />

pCVL<br />

mg1L<br />

mglL<br />

mglL<br />

Silver<br />

7440-22-4<br />

5557-95 21MAR1995 WG O.OOE+OO<br />

c<br />

N<br />

WlL<br />

Silver. Dissolved<br />

7440-22-4<br />

5557-95 21MAR1995<br />

WG O.OOE+OO<br />

< N<br />

mglL<br />

Sodium<br />

Sodium, Dissolved<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Technetium-99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-I .2-Dichloroethene<br />

Trans-l,2-Dichloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Uranium<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc, Dissolved<br />

cis-1.2-dichloroethene<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

14133-76-7<br />

SO835<br />

127-10-4<br />

127-18-4<br />

108-80-3<br />

108-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

SO278<br />

7440-61-1<br />

DIS U<br />

75-014<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

156-59-2<br />

5557-95<br />

5557-95<br />

5557-95<br />

5558-95<br />

5559-95<br />

5560 - 95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5558-95<br />

5559-95<br />

5560-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

7078-95<br />

5557-95<br />

5557-95<br />

5557-95<br />

21 MARl 995<br />

21 MAR1 995<br />

21 MARl 995<br />

21 MARl 995<br />

21 MAR1 995<br />

21MAR1995<br />

21 MAR1995<br />

21 MAR1995<br />

21 MARl 995<br />

21MAR1995<br />

12 JULl995<br />

2lMARl995<br />

12JUL1995<br />

21 MAR1 995<br />

21MAR1995<br />

21 MARl 995<br />

21MAR1995<br />

21MAR1995<br />

12JUL1995<br />

21MAR1995<br />

12JULl995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

12JULl995<br />

21 MAR1 995<br />

12JUL1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

ViG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

7.50E+01<br />

8.10E+01<br />

7.54E+02<br />

7.61E+02<br />

7.60€+02<br />

7.58E+02<br />

1.31E+02<br />

8.00E+W 2.40E+01<br />

5.50E+Ol<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

5.00E+00<br />

2.00E+00<br />

2.00E+W<br />

2.00E+00<br />

2.WE+00<br />

S.WE+W<br />

S.WE+OO<br />

1 .WE+00<br />

l.WE+W<br />

2.20E+OI<br />

O.WE+W<br />

O.WE+OO<br />

l.OOE+OI<br />

l.OOE+OI<br />

l.OOE+OI<br />

1.00E+01<br />

O.OOE+W<br />

O.OOE+OO<br />

S.WE+W<br />

B<br />

B<br />

UJX<br />

U<br />

UJX<br />

U<br />

UJX<br />

U<br />

UJX<br />

U<br />

UJX<br />

U<br />

UJX<br />

U<br />

<<br />

<<br />

UJX<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

mglL<br />

mglL<br />

umhoslcm<br />

umhoslcm<br />

umhoslcm<br />

umhosfcm<br />

mglL<br />

pCVL<br />

F<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

mgk<br />

mil5<br />

mgk<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

NTU<br />

W/L<br />

mglL<br />

uglL<br />

uglL<br />

uglL<br />

ug1L<br />

mgk<br />

WlL<br />

uglL<br />

cis-I ,2-dichloroethene 156-59-2<br />

7078-95 12JUL1995 WG S.WE+W<br />

U<br />

N<br />

uglL<br />

PH<br />

SO296<br />

5557-95 2lMARl995 WG 6.00E+W<br />

N su<br />

PH<br />

SO296<br />

5558-95 21MAR1995 WG 6.WE+00<br />

N su<br />

PH<br />

SO296<br />

5559-95 2lMAR1995 WG 6.00E+00<br />

N su<br />

PH<br />

SO296<br />

5560-95 21MAR1995 WG 6.00E+00<br />

N su<br />

WAG 7. SWU 8. MW303<br />

1 .I,I-Trichloroethane<br />

1 .I,l-Trichloroethane<br />

1, I .2-Trichloroethane<br />

1,1,2-TrichIoroethane<br />

1 .I-Dichloroethane<br />

1 .I-Dichloroethane<br />

1 .I-Diihloroethene<br />

1 .l-Dichloroethene<br />

1.2-Dichloroethane<br />

1.2-Dichloroethane<br />

Alkalinity<br />

Antimony<br />

Antimony, Dissolved<br />

Arsenic<br />

Anenic, Dissolved<br />

Barium<br />

Barium, Dissolved<br />

Benzene<br />

Benzene<br />

Beryllium<br />

71 -55-6<br />

7 1-55-6<br />

79-00-5<br />

79-00-5<br />

75-34-3<br />

75-34-3<br />

75-35-4<br />

75-35-4<br />

107-06-2<br />

107-06-2<br />

471-34-1<br />

7440-36-0<br />

7440-36-0<br />

7440-30-2<br />

7440-38-2<br />

7440-39-3<br />

7440-39-3<br />

71-43-2<br />

71-43-2<br />

7440-41 -7<br />

5561 -95<br />

7082-95<br />

5561-95<br />

7082-95<br />

5561 -95<br />

7082-95<br />

5561-95<br />

7082-95<br />

5561-95<br />

7082-95<br />

5561-95<br />

5561 -95<br />

5561-95<br />

5561 -95<br />

5561 -95<br />

5561 -95<br />

5561-95<br />

5561-95<br />

7082-95<br />

5561 -95<br />

21 MAR1 995<br />

12JULl995<br />

2lMAR 1995<br />

1 PJULl995<br />

2lMARl995<br />

12JULl995<br />

21MAR1995<br />

lZJULl995<br />

2 lMARl995<br />

lZJULl995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

21MAR1995<br />

2 1 MAR 1995<br />

2lMARl995<br />

21MAR1995<br />

21 MARl 995<br />

12JULl995<br />

21MAR1995<br />

Page 174 of 176<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

\IK;<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

WG<br />

S.WE+OO<br />

5.00E+00<br />

5.00E+W<br />

5.00E+W<br />

S.WE+OO<br />

5.00E+00<br />

S.WE+W<br />

5.WE+W<br />

5.00E+W<br />

S.WE+OO<br />

5.07E+02<br />

O.WEt00<br />

O.WE+W<br />

O.OOE+W<br />

O.WE+W<br />

O.OOE+OO<br />

O.WE+OO<br />

5.00E+W<br />

5.WE+00<br />

O.WE+OO<br />

UJX<br />

U<br />

UJX<br />

U<br />

UJX<br />

U<br />

U JX<br />

U<br />

UJX<br />

U<br />

<<br />

Q<br />

<<br />

Q<br />

<<br />

c<br />

UJX<br />

U<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

uglL<br />

ugk<br />

uglL<br />

ugk<br />

mgk<br />

Wk<br />

mgk<br />

mgk<br />

mgk<br />

mglL<br />

mglL<br />

ugfL<br />

uglL<br />

mglL


L.9 (continued)<br />

MEDIA RAD RESULT VALIDATION<br />

ANALYTE CAS NUMBER SAMPLE ID DATE MPE RESULT ERROR QUALIFIER QUALIFIER UNITS<br />

Beryllium. Dissolved 7440-41 -7 5561-95 21MAR1995 WG O.OOE+OO < N mg1L<br />

Bromodichloromethane<br />

Bromodichloromethane<br />

Cadmium<br />

Cadmium, Dissolved<br />

Calcium<br />

Calcium, Dissolved<br />

Carbon Tetrachloride<br />

Carbon Tetrachloride<br />

Chloride<br />

Chloroform<br />

Chloroform<br />

Chromium<br />

Chromium, Dissolved<br />

Cobalt<br />

Cobalt, Dissolved<br />

Copper<br />

Copper, Dissolved<br />

Depth to Water<br />

Dissolved Oxygen<br />

Dissolved Solids<br />

Ethylbenzene<br />

Ethylbenzene<br />

Fluoride<br />

Gross Alpha<br />

Gross Beta<br />

Iron<br />

Iron, Dissolved<br />

Lead<br />

Lead, Dissolved<br />

Magnesium<br />

Magnesium, Dissolved<br />

Manganese<br />

Manganese, Dissolved<br />

Mercury<br />

Mercury, Dissolved<br />

Nickel<br />

Nickel, Dissolved<br />

Nitrate as Nitrogen<br />

Potassium<br />

Potassium. Dissolved<br />

Radon 222<br />

Selenium<br />

Selenium, Dissolved<br />

Silica<br />

Silver<br />

Silver, Dissolved<br />

Sodium<br />

Sodium, Dissolved<br />

Specifc conductance<br />

Specific conductance<br />

Specific conductance<br />

Specific conductance<br />

Sulfate<br />

Technetium99<br />

Temperature<br />

Tetrachloroethene<br />

Tetrachloroethene<br />

Toluene<br />

Toluene<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Total Organic Carbon<br />

Trans-I ,2-Dichloroethene<br />

Trans-I .2-Dchloroethene<br />

Trichloroethene<br />

Trichloroethene<br />

Turbidity<br />

Uranium<br />

Uranium, Dissolved<br />

Vinyl Chloride<br />

75-27-4<br />

75-27-4<br />

7440-43-9<br />

7440-43-9<br />

7440-70-2<br />

7440-70-2<br />

56-23-5<br />

56-23-5<br />

16887-00-6<br />

67-66-3<br />

67-66-3<br />

7440-47-3<br />

7440-47-3<br />

7440-48-4<br />

7440-48-4<br />

7 4 4 o - 5 o - a<br />

7440-50-8<br />

DTW<br />

OXYGEN DIS<br />

SO266<br />

100-41-4<br />

100-41 -4<br />

i69a4-48-a<br />

12587-46-1<br />

ma7-47-2<br />

7439-89-6<br />

7439-89-6<br />

7439-92-1<br />

7439-92-1<br />

7439-95-4<br />

7439-95-4<br />

7439-96-5<br />

7439-96-5<br />

7439-97-6<br />

7439-97-6<br />

7440-02-0<br />

7440-02-0<br />

N ITRATEASN IT<br />

7440-09-7<br />

7440-09-7<br />

RN222<br />

7782-49-2<br />

7782-49-2<br />

7631-86-9<br />

7440-22-4<br />

7440-22-4<br />

7440-23-5<br />

7440-23-5<br />

SO145<br />

SO145<br />

SO145<br />

SO145<br />

12143-45-2<br />

14133-76-7<br />

so835<br />

127-18-4<br />

in-18-4<br />

108-88-3<br />

ioa-88-3<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

7440-44-0<br />

156-60-5<br />

156-60-5<br />

79-01-6<br />

79-01-6<br />

so278<br />

7440-61-1<br />

DIS U<br />

75-01-4<br />

5561 -95<br />

7082-95<br />

5561 -95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561 -95<br />

7082-95<br />

5561 -95<br />

5561-95<br />

7082-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561 -95<br />

5561 -95<br />

5561 -95<br />

5561-95<br />

7082-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561 -95<br />

5561 -95<br />

5561 -95<br />

5561 -95<br />

5561-95<br />

5561-95<br />

5561 -95<br />

5561 -95<br />

5561-95<br />

5561 -95<br />

5562-95<br />

5563-95<br />

5564-95<br />

5561 -95<br />

5561 -95<br />

5561 -95<br />

5561-95<br />

7082-95<br />

5561 -95<br />

7082-95<br />

5561-95<br />

5562-95<br />

5563-95<br />

5564-95<br />

5561-95<br />

7082-95<br />

5561-95<br />

7082-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

5561-95<br />

21 MARl 995<br />

I 2JUL 1995<br />

21MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

21MAR1995<br />

21 MAR1 995<br />

12JUL1995<br />

2 lMARl995<br />

21MAR1995<br />

12JUL1995<br />

21MAR1995<br />

21 MAR1995<br />

21 MARl 995<br />

21 MAR 1995<br />

21 MARl 995<br />

21 MARl 995<br />

2lMAR 1995<br />

21MAR1995<br />

21MAR1995<br />

2 IMARI 995<br />

12JULl995<br />

2 lMARl995<br />

2 IMARI 995<br />

2 IMARI 995<br />

2 IMARI 995<br />

2 lMAR1995<br />

2 lMARl995<br />

21MARl995<br />

2IMAR1995<br />

2lMARl995<br />

2lMARl995<br />

21MARI 995<br />

2 I MAR 1995<br />

21 MARl 995<br />

21MAR1995<br />

2lMAR1995<br />

21 MAR1 995<br />

21MAR1995<br />

21 MAR1995<br />

21 MAR1 995<br />

21 MARl 995<br />

21MAR1995<br />

21 MAR1 995<br />

21MARl995<br />

2 IMARI 995<br />

21MARI 995<br />

2 IMARI 995<br />

21 MAR1995<br />

21MAR1995<br />

21 MARl 995<br />

21 MAR1 995<br />

2 IMARI 995<br />

21 MAR 1995<br />

21 MAR1 995<br />

2lMARl995<br />

12JUL1995<br />

21 MARl 995<br />

12JUL1995<br />

21 MARl 995<br />

21MARl995<br />

21 MAR1 995<br />

21 MARl 995<br />

21MAR1995<br />

12 JULl995<br />

21 MAR1 995<br />

12JULl995<br />

2 IMARI 995<br />

2lMAR 1995<br />

21 MAR1 995<br />

21 MARl 995<br />

Page 175 of 176<br />

UJX<br />

N<br />

U<br />

N<br />

c<br />

N<br />

< N<br />

N<br />

N<br />

U JX<br />

N<br />

U<br />

N<br />

N<br />

UJX<br />

N<br />

U<br />

N<br />

C<br />

N<br />

< N<br />

< N<br />

Q<br />

C<br />

N<br />

< N<br />

N<br />

N<br />

N<br />

U JX<br />

N<br />

U<br />

N<br />

N<br />

N<br />

N<br />

N<br />

N<br />

<<br />

N<br />

<<br />

N<br />

N<br />

N<br />

N<br />

N<br />

<<br />

N<br />

Q<br />

N<br />

c<br />

N<br />

<<br />

N<br />

<<br />

N<br />

N<br />

N<br />

N<br />


L.9 (continued)<br />

ANALYTE<br />

Vinyl Chloride<br />

Xylene<br />

Xylene<br />

Zinc<br />

Zinc, Dissolved<br />

cis-I .Z-dichloroethene<br />

cis-I ,2-dichloroethene<br />

PH<br />

PH<br />

PH<br />

PH<br />

CAS NUMBER<br />

75-01-4<br />

1330-20-7<br />

1330-20-7<br />

7440-66-6<br />

7440-66-6<br />

156-59-2<br />

156-59-2<br />

SO296<br />

SO296<br />

SO296<br />

SO296<br />

SAMPLE ID<br />

7082-95<br />

5561-95<br />

7082-95<br />

5561-95<br />

5561 -95<br />

5561 -95<br />

7082-95<br />

5561 -95<br />

5562-95<br />

5563-95<br />

5564-95<br />

DATE<br />

12JUL1995<br />

21MAR1995<br />

1 2JULl995<br />

21MAR1 995<br />

21 MAR1 995<br />

21 MARl 995<br />

12JUL1995<br />

21 MARl 995<br />

2 1 MARl 995<br />

ZlMAR1995<br />

2lMARl995<br />

MEDIA RAD RESULT VALIDATION<br />

TYPE RESULT ERROR QUALIFIER QUALIFIER<br />

WG I.OOE+OI<br />

U<br />

N<br />

WG I.OOE+OI<br />

UJX N<br />

WG 1.00E+01<br />

U<br />

N<br />

WG 0.00E+00<br />

< N<br />

WG 0.00E+00<br />

< N<br />

WG 5.00E+00<br />

U JX<br />

N<br />

WG 5.00E+00<br />

U<br />

N<br />

WG 6.00E+00<br />

N<br />

WG 6.00E+00<br />

N<br />

WG 6.00E+00<br />

N<br />

WG 6.00€+00<br />

N<br />

UNITS<br />

uglL<br />

uglL<br />

uglL<br />

mglL<br />

mglL<br />

uglL<br />

uglL<br />

su<br />

su<br />

su<br />

su<br />

Page 176 of 176


Appendix L. 10<br />

Results of Integrated Exposure Uptake Biokinetic Model for Lead


Internal Correspondence<br />

MARTIN MARIEITA ENERGY SYSTEMS, INC.<br />

Date: September 6, 1995<br />

To:<br />

From:<br />

Subject:<br />

Fred Dolislager<br />

Kowetha Davidson (1060 COM, Rm. 103, MS6480)<br />

Integrated Exposure Uptake Biokinetic (IEUBK) Model for Lead<br />

I have included the printouts for the lead model. The model was run for ages of 0 to 5 years; 1<br />

used 5 years because that is the age group used for the other runs 1 did for you. The lead<br />

concentrations in soil <strong>and</strong> vegetables were all run. When the concentration in vegetables was<br />

below 0.001 kg lead/g, the vegetable concentrations were not input into the model, because the<br />

program rounds off to three decimals. The program was run assuming that consumption of<br />

homegrown vegetables was 25% of all vegetable consumption (the average value according to<br />

EPA). I also ran a duplicate set of values setting the soil concentration to 200 ,ug lead/g just in case<br />

your model did not account for background levels of lead in soil. This value is the default<br />

established by the U.S. Environmental Protection Agency. The concentration for house dust was<br />

calculated using the multiple source analysis in which the values for dust were based on a 70%<br />

conversion of soil to dust <strong>and</strong> a air-todust conversion of 100 pg Pb in dustlpg Pb/m3 of air. Default<br />

values were used for air (0.1 pg Pb/m3) <strong>and</strong> drinking water (4 pg/L).<br />

The current directive from EPAs Office of Solid Waste <strong>and</strong> Emergency Response (OSWER)<br />

(directive # 934<strong>4.</strong>4-12) for soil lead recommends a screening level of 400 ppm (mg/kg or 1919) for<br />

residential l<strong>and</strong> use. A screening level is not a cleanup level, but is defined as the level of<br />

contamination above which there may be sufficient concern to warrant site-specific study of risk.<br />

The directive also states that OSWER would attempt to limit exposure of children to soil lead such<br />

that the estimated risk of blood lead exceeding 10 pg/dL would be 5% or less <strong>and</strong> that OSWER<br />

would apply EPA's IEUBK model on a site-specific basis. I have not included printouts of the lead<br />

model output for soil lead concentrations at the screening level of 400 ppm. I will give these to you<br />

if you want them.<br />

When the values for both soil <strong>and</strong> vegetables from Wag 1 , 7, <strong>and</strong> KOW were input into the model,<br />

the results showed that, in each case, the probability that blood lead levels in children 0-5 years


old would exceed 10 pg/dL is estimated to be 0.97% or less when consumption of homegrown<br />

vegetables approximated 25% of the vegetable intake. If the soil lead concentrations is set to the<br />

default level (200 pg/g) <strong>and</strong> homegrown vegetables are consumed, the probability of blood lead<br />

levels in children 0-5 years old exceeding 10 pg/dL is estimated to be 2.70% or less. These results<br />

indicate that the concentration of lead in the soil <strong>and</strong> vegetables would not present a health concern<br />

for children.


Table J.l. Concentrations <strong>and</strong> Chronic Daily Intakes of Lead<br />

-.<br />

ANALYTE UNITS COW (VEGETABLES]<br />

Residential ,WAG1 , S W 38,soil<br />

Lead<br />

mg/kg 1.38EM1 1.lOE-02 9. Dl I 9<br />

Kesidentlal , w ~ti i , SwhlvtOO, soil - 13.8 - - - ..-<br />

Lead mg/kg 1.30EM1 <strong>4.</strong>58E-03 0. bo5 d<br />

W J I?iLD<br />

Keslm , , SWMUfX,-soiT-<br />

V'<br />

Residential , WAG 7 , SWMU 8, soil<br />

-<br />

,/<br />

Lead m& 9.96EM0 7.97E-03 3. ocf<br />

Residential , WAG T , SWMU 130, soil<br />

."& J<br />

kKl __ m& 1.13EM1 6.01E-05 .. jrn<br />

1 /,<br />

Residential , WAG 7 , SWMU 131, soil<br />

3<br />

- Lead mgkg 8.49EM0 1.2OE-04-2k- -<br />

Lead mg/kg 1.99EM1 1.15E-05 * rr? &-J<br />

Resident&-- , WAG 7 , SWMU 132, soil if.+<br />

Lead mgkg 1.17EM2 9.39E-04 '.M 'A& V'<br />

ResiGtid , WAG 7 , SWMU 133, soil / 19<br />

Lead mg/kg 1.62E+02 1.09E-03 0 ' '<br />

a<br />

-7GesidentiaI , WAG 7 , SWMU 134, soil I @ > 2<br />

Lead m& 2.60EMl 1.75E-04 1- 'I@'<br />

-.-<br />

Residential<br />

a-(r ~<br />

, WAG KOW, SWMU 95, soil<br />

Lead m& 3.59E+01 2.88E-02 '7<br />

- KisidGtial , WAG KOW, SWMU 157, soil 33-1 a<br />

Lead<br />

Residential , WAG KOW, SWMU 944 soil<br />

mg/kg 1.47EM1<br />

I Ylq<br />

1.18E-02 reo'<br />

Lead<br />

mg/kg 1.44EM1 1.192-02 3 r O l v<br />

lq#Y<br />

Y<br />

._3<br />

J<br />

-2<br />

Page 1 of 1


AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

DIET:<br />

DEFAULT<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

House Dust (ug Pb/g)<br />

150.0<br />

150.0<br />

150.0<br />

150.0<br />

150.0<br />

150.0<br />

150.0<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-----------<br />

3.8<br />

<strong>4.</strong>2<br />

3.9<br />

3.7<br />

3.1<br />

2.7<br />

2.5<br />

Total Uptake<br />

( ug/day 1<br />

____--------<br />

7.00<br />

10.00<br />

10.49<br />

10.51<br />

0.91<br />

8.71<br />

a.83<br />

Soil+Dust Uptake<br />

( ug/day 1<br />

_______-----<br />

<strong>4.</strong>06<br />

6.40<br />

6.46<br />

6.54<br />

<strong>4.</strong>93<br />

<strong>4.</strong>47<br />

<strong>4.</strong>23


1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

'-6:<br />

a-7:<br />

2.65<br />

3.00<br />

2.92<br />

2.86<br />

3.04<br />

3.37<br />

0.92<br />

0.96<br />

0.99<br />

1.05<br />

1.11<br />

1.13<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


I<br />

t<br />

Cutoff: 10.0 ug/dL<br />

Z above: 1.66<br />

Z Below: 98.34<br />

C. Mean: 3.7<br />

LEaD 0.99d<br />

e 2 4 6 8 10 12 14 16 18 20<br />

BLOOD LEAD CONCENTRATION <br />

0 to 60 Months


LEAD MODEL Version 0.99d bl Q6 L, SW NU 'i5 @,so \\<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

idoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Lher AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.011 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

13.8<br />

13.8<br />

13: 8<br />

13.8<br />

13.8<br />

13.8<br />

13.8<br />

House Dust (ug Pb/g)<br />

19.7<br />

19.7<br />

19.7<br />

19.7<br />

19.7<br />

19.7<br />

19.7<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

-3:<br />

-4 :<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-----------<br />

2.0<br />

2.0<br />

1.9<br />

1.8<br />

1.6<br />

1.6<br />

1.5<br />

Total Uptake<br />

(ug/day)<br />

____--------<br />

3.69<br />

<strong>4.</strong>58<br />

5.11<br />

5.06<br />

<strong>4.</strong>85<br />

5.10<br />

5.49<br />

Soil+Dust Uptake<br />

(ug/day)<br />

------------<br />

0.42<br />

0.66<br />

0.66<br />

0.67<br />

0.50<br />

0.45<br />

0.42


YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

( ug/day)<br />

_----------<br />

Water Uptake<br />

( ug /day)<br />

---_-------_<br />

2.87 0.38<br />

2.92 0.96<br />

3.39 1-00<br />

3.30 1.03<br />

3.22 1.07<br />

3.43 1.13<br />

3.82 1.15<br />

Paint Uptake<br />

( ug/day)<br />

-----------_<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

Air Uptake<br />

(ug /day)<br />

--------<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


?<br />

rp<br />

rp<br />

L<br />

Probabi 1 i ty Densi<br />

Function fcblood<br />

?<br />

f


LEAD MODEL Version 0.99d wbk(Ci,SwMY 3 8, 50; \<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.011 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

Lung Ats. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: constant conc.<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

Additional Dust Sources: None<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

House Dust (ug Pb/g)<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

200.0<br />

DEFAULT<br />

DEFAULT<br />

MATERNAL, CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

( ug/ dL 1<br />

-----------<br />

<strong>4.</strong>2<br />

<strong>4.</strong>6<br />

<strong>4.</strong>3<br />

<strong>4.</strong>1<br />

3.5<br />

3.1<br />

2.8<br />

Total Uptake<br />

( ug/day 1<br />

--__--------<br />

7.79<br />

11.05<br />

11.66<br />

11.73<br />

9.92<br />

9.71<br />

9.85<br />

Soil+Dust Uptake<br />

( ug /day 1<br />

-----_-_____<br />

<strong>4.</strong>67<br />

7.35<br />

7.43<br />

7.52<br />

5.68<br />

5.15<br />

<strong>4.</strong>88<br />

Diet Uptake Water Uptake Paint Uptake Air Uptake


YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

-3:<br />

2-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

(ug/day) ( ug/day 1<br />

----------- ------_-____<br />

2.73 0.37<br />

2.76 0.91<br />

3.22 0.95<br />

3.16 0.98<br />

3.13 1.04<br />

3.35 1.11<br />

3.74 1.13<br />

(ug/day)<br />

---___-_____<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

(ug/day)<br />

- - - - - - - -<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


Cutoff: 10.0 ug/dL Z Above: 2.70 -<br />

Z Below: 97.30<br />

C. Mean: <strong>4.</strong>1<br />

-<br />

-<br />

-<br />

-<br />

-<br />

-<br />

-<br />

LEAD 0.99d<br />

BLOOD LEAD CONCENTRATION


-<br />

LEAD MODEL Version 0.99d 'W &61, /,-O,bd<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

'ndoor AIR Pb Conc: 30.0 percent of outdoor.<br />

ther AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.005 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g) House Dust (ug Pb/g)<br />

13.0 19.1<br />

13.0 19.1<br />

13.. 0 19.1<br />

13.0 19.1<br />

13.0 19.1<br />

13.0 19.1<br />

13.0 19.1<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

'-3:<br />

-4 :<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

( ug/ dL )<br />

-----------<br />

2.0<br />

1.9<br />

1.8<br />

1.7<br />

1.6<br />

1.5<br />

1.5<br />

Total Uptake<br />

( ug/day 1<br />

___---------<br />

3.63<br />

<strong>4.</strong>48<br />

<strong>4.</strong>98<br />

<strong>4.</strong>93<br />

<strong>4.</strong>72<br />

<strong>4.</strong>96<br />

5.33<br />

Soil+Dust Uptake<br />

(ug/day)<br />

____--------<br />

0.40<br />

0.64<br />

0.64<br />

0.64<br />

0.48<br />

0.43<br />

0.41


YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

(&day 1<br />

____-------<br />

2.83<br />

2.85<br />

3.28<br />

3.19<br />

3.10<br />

3.30<br />

3.67<br />

Water Uptake<br />

(ug /day)<br />

--------_-__<br />

0.38<br />

0.96<br />

1.00<br />

1.03<br />

1.07<br />

1.13<br />

1.15<br />

Paint Uptake<br />

(ug/day)<br />

------------<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

Air Uptake<br />

( ug / day)<br />

--_-----<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


1 ~ 1 ) , ) , 1 1 1 1 1 1 1 , I , ,<br />

Cutoff: 10.0 ug/dL<br />

Z Above: 0.01<br />

Z Below: 99.99<br />

C. Mean: 1.9<br />

-<br />

-<br />

-<br />

-<br />

-<br />

1 # 1 , 1 ,<br />

0 1 2 3 4 5 6 7 8 9 18


LEAD MODEL Version 0.99d<br />

V A 6 1, SWFCL 100, So ;\<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day) Lung Abs. (%)<br />

0-1 1.0<br />

2.0 32.0<br />

1-2 2.0<br />

3.0 32.0<br />

2-3 3.0<br />

5.0 32.0<br />

3-4 <strong>4.</strong>0<br />

5.0 32.0<br />

4-5 <strong>4.</strong>0<br />

5.0 32.0<br />

5-6 <strong>4.</strong>0<br />

7.0 32.0<br />

6-7 <strong>4.</strong>0<br />

7.0 32.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.005 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

DEFAULT<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

House Dust (ug Pb/g)<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

3.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-----------<br />

3.9<br />

<strong>4.</strong>2<br />

3.9<br />

3.7<br />

3.2<br />

2.8<br />

2.6<br />

Total Uptake<br />

( ug/ day 1<br />

---___---___<br />

7.16<br />

10.06<br />

10.62<br />

10.66<br />

9.07<br />

8.91<br />

9.07<br />

Soil+Dust Uptake<br />

( ug/day)<br />

------------<br />

<strong>4.</strong>05<br />

6.40<br />

6.46<br />

6.53<br />

<strong>4.</strong>93<br />

<strong>4.</strong>46<br />

<strong>4.</strong>23


YEAR<br />

------<br />

'1:<br />

-2 :<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

(ug/day)<br />

---_-______<br />

2.71<br />

2.71<br />

3.14<br />

3.07<br />

3.03<br />

3.24<br />

3.61<br />

Water Uptake<br />

( ug / day )<br />

------------<br />

0.37<br />

0.92<br />

0.96<br />

0.99<br />

1.05<br />

1.11<br />

1.13<br />

Paint Uptake<br />

(ug/day)<br />

----__--____<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

Air Uptake<br />

( ug/day)<br />

- - - - - - - -<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


Cutoff: 10.0 ug/dL<br />

Z Rbouc: 1.76<br />

Z Below: 98.24<br />

C. Mean: 3.8<br />

LERD 8.99d<br />

- ' , I , 1<br />

0 2 4 6 8 10 12 14 16 18 20<br />

BLOOD LERD CONCENTRlIION <br />

0 to 60 Months


LEAD MODEL Version 0.99d W f4 6 1, S k wu 13 b, Sa; I<br />

ATR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

?door AIR Pb Conc: 30.0 percent of outdoor.<br />

>ther AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

DIET:<br />

DEFAULT<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g) House Dust (ug Pb/g)<br />

8.5 15.9<br />

8.5 15.9<br />

8.5 15.9<br />

8.5 15.9<br />

8.5 15.9<br />

8.5 15.9<br />

8.5 15.9<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

-----_<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

---------_-<br />

1.9<br />

1.8<br />

1.7<br />

1.6<br />

1.5<br />

1.4<br />

1.4<br />

Total Uptake<br />

( ug /day)<br />

-----_------<br />

3.38<br />

<strong>4.</strong>27<br />

<strong>4.</strong>70<br />

<strong>4.</strong>62<br />

<strong>4.</strong>44<br />

<strong>4.</strong>66<br />

<strong>4.</strong>99<br />

Soil+Dust Uptake<br />

( ug/day 1<br />

-----------_<br />

0.31<br />

0.49<br />

0.49<br />

0.50<br />

0.37<br />

0.33<br />

0.31


1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

2.79<br />

3.14<br />

3.03<br />

2.93<br />

3.10<br />

3.42<br />

0.96<br />

1.00<br />

1.03<br />

1.07<br />

1.13<br />

1.15<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


I I ' 1 1 '<br />

A<br />

I , I I I I I<br />

Cutoff: 10.0 ug/dL<br />

z Above: 0.00<br />

z Below: 100.00<br />

G. Mean: 1.7<br />

LEnD 0.99d<br />

J<br />

J<br />

e 1 2 3 4 5 6 7 8<br />

BLOOD LEAD CONCENTRATION


LEAD MODEL Version 0.99d vAAG 3, SwWk 3 ; Ss:/<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Lung Abs. (%I<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.008 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

10.0<br />

10.0<br />

10,. 0<br />

10.0<br />

10.0<br />

10.0<br />

10.0<br />

DEFAULT<br />

House Dust (ug Pb/g)<br />

17.0<br />

17.0<br />

17.0<br />

17.0<br />

17.0<br />

17.0<br />

17.0<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-----------<br />

2.0<br />

1.9<br />

1.8<br />

1.7<br />

1.6<br />

1.5<br />

1.5<br />

Total Uptake<br />

( ug /day 1<br />

_-----------<br />

3.59<br />

<strong>4.</strong>42<br />

<strong>4.</strong>94<br />

<strong>4.</strong>89<br />

<strong>4.</strong>71<br />

<strong>4.</strong>96<br />

5.34<br />

Soil+Dust Uptake<br />

( ug/day )<br />

------------<br />

0.34<br />

0.54<br />

0.54<br />

0.54<br />

0.41<br />

0.37<br />

0.35


YEAR<br />

_____-<br />

-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

(ug/day)<br />

-----------<br />

2.85<br />

2.89<br />

3.33<br />

3.25<br />

3.16<br />

3.37<br />

3.75<br />

Water Uptake<br />

(ug/day)<br />

__-----_--__<br />

0.38<br />

0.96<br />

1.00<br />

1.03<br />

1.07<br />

1.13<br />

1.15<br />

Paint Uptake<br />

( ug /day )<br />

---_--------<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

Air Uptake<br />

(ug/day)<br />

------- -<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


Cutoff: 10.0 us/dL<br />

X Above: 0.01<br />

z Below: 99.99<br />

C. Mean: 1.8<br />

LEAD 0.99d<br />

e 2 3 4 5 6 7 8 9<br />

BLOOD LEAD CONCENTRATION


LEAD MODEL Version 0.99d \MAG?, SWmk 8,Sa;l<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

?door AIR Pb Conc: 30.0 percent of outdoor.<br />

cher AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.008 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

, 2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

House Dust (ug Pb/g)<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

-3 :<br />

-4 :<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL 1<br />

-----------<br />

3.9<br />

<strong>4.</strong>2<br />

<strong>4.</strong>0<br />

3.8<br />

3.2<br />

2.8<br />

2.6<br />

Total Uptake<br />

( ug/day 1<br />

------------<br />

7.18<br />

10.09<br />

10.67<br />

10.71<br />

9.12<br />

8.97<br />

9.14<br />

Soil+Dust Uptake<br />

( ug/ day 1<br />

------------<br />

<strong>4.</strong>05<br />

6.39<br />

6.45<br />

6.53<br />

<strong>4.</strong>92<br />

<strong>4.</strong>46<br />

<strong>4.</strong>23


YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

( ug/day 1<br />

--------__-<br />

2.73<br />

2.75<br />

3.19<br />

3.13<br />

3.09<br />

3.30<br />

3.68<br />

Water Uptake<br />

(ug/day)<br />

___-_-______<br />

0.37<br />

0.92<br />

0.96<br />

0.99<br />

1.05<br />

1.11<br />

1.13<br />

Paint Uptake<br />

( ug/ day)<br />

----__----__<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

Air Uptake<br />

(ug/day)<br />

--------<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


1 ' 1 ' 1 ' 1 1 ~ , , , 1 , 1 , I<br />

Cutoff: 10.0 ug/dL<br />

Z Iboue: 1.76<br />

Z Below: 98.24<br />

C. Mean: 3.8<br />

LEIID 0.99d<br />

2 4 6 8 10 12 14 16 18 20<br />

BLOOD LElD CONCENIRATION


LEAD MODEL Version 0.99d<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

DIET:<br />

DEFAULT<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

11.3<br />

11.3<br />

11.3<br />

11.3<br />

11.3<br />

11.3<br />

11.3<br />

DEFAULT<br />

House Dust (ug Pb/g)<br />

17.9<br />

17.9<br />

17.9<br />

17.9<br />

17.9<br />

17.9<br />

17.9<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

Blood Level Total Uptake<br />

( ug/dL 1 ( ug /day 1<br />

----------- ______------<br />

1.9 3.43<br />

1.9 <strong>4.</strong>36<br />

1.8 <strong>4.</strong>78<br />

1.7 <strong>4.</strong>71<br />

1.5 <strong>4.</strong>51<br />

1.4 <strong>4.</strong>72<br />

1.4 5.04<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Soil+Dust Uptake<br />

( ug/day)<br />

------------<br />

0.37<br />

0.58<br />

0.58<br />

0.59<br />

0.44<br />

0.39<br />

0.37


1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

.6 :<br />

a-7:<br />

2.78<br />

3.13<br />

3.03<br />

2.93<br />

3.10<br />

3.42<br />

0.96<br />

1-00<br />

1.03<br />

1.07<br />

1.13<br />

1.15<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


I I 1 I 1 I I I I I I I I I I I<br />

Cutoff: 10.0 ug/dL<br />

Z Aboue: 0.01<br />

Z Below: 99.99<br />

C. Mean: 1.8<br />

-<br />

-<br />

-<br />

-<br />

-<br />

LEAD 0.99d<br />

I I I I I<br />

1 2 3 4 5 6 7 8 9


LEAD MODEL Version 0.99d Wh6 ?,5mb* 131, 56; \<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

:door AIR Pb Conc: 30.0 percent - of outdoor.<br />

-her AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day) Lung Abs. (%)<br />

0-1<br />

1.0<br />

2.0 32.0<br />

1-2<br />

2.0<br />

3.0 32.0<br />

2-3<br />

3.0<br />

5.0 32.0<br />

3-4<br />

<strong>4.</strong>0<br />

5.0 32.0<br />

4-5<br />

<strong>4.</strong>0<br />

5.0 32.0<br />

5-6<br />

6-7<br />

<strong>4.</strong>0<br />

<strong>4.</strong>0<br />

7.0<br />

7.0<br />

32.0<br />

32.0<br />

DIET:<br />

DEFAULT<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

19.9<br />

19.9<br />

19.9<br />

19.9<br />

19.9<br />

19.9<br />

19.9<br />

DEFAULT<br />

House Dust (ug Pb/g)<br />

23.9<br />

23.9<br />

23.9<br />

23.9<br />

23.9<br />

23.9<br />

23.9<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-----------<br />

2.0<br />

2.0<br />

1.9<br />

1.8<br />

1.6<br />

1.5<br />

1.5<br />

Total Uptake<br />

(ug/day)<br />

------------<br />

3.60<br />

<strong>4.</strong>63<br />

5.05<br />

<strong>4.</strong>99<br />

<strong>4.</strong>72<br />

<strong>4.</strong>91<br />

5.22<br />

Soil+Dust Uptake<br />

(ug/day)<br />

------------<br />

0.54<br />

0.86<br />

0.86<br />

0.87<br />

0.65<br />

0.58<br />

0.55<br />

Diet Uptake Water Uptake Paint Uptake Air Uptake<br />

YEAR<br />

----e-<br />

(ug/day 1<br />

-----------<br />

(ug/day)<br />

------------<br />

( ug /day 1<br />

------------<br />

(ug/day)<br />

--------<br />

0.5-1: 2.66 0.38 0.00 o. 02


1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

2.78<br />

3.13<br />

3.02<br />

2.93<br />

3.10<br />

3.42<br />

0.96<br />

1.00<br />

1.03<br />

1.07<br />

1.13<br />

1.15<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


Cutoff: 10.0 ug/dL<br />

z lboue: 0.01<br />

Z Below: 99.99<br />

C. Mean: 1.9<br />

LElD 0.99d<br />

1 2 3 4 5 6 7 8 9 10<br />

BLOOD LElD CONCENIRlI I ON < ug/dL><br />

0 to 60 Months


AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day) Lung Abs. (%)<br />

0-1 1.0 2.0 32.0<br />

1-2 2.0<br />

3.0<br />

32.0<br />

2-3 3.0<br />

5.0<br />

32.0<br />

3-4 <strong>4.</strong>0<br />

5.0<br />

32.0<br />

4-5 <strong>4.</strong>0<br />

5.0<br />

32.0<br />

5-6 <strong>4.</strong>0<br />

7.0<br />

32.0<br />

6-7 <strong>4.</strong>0<br />

7.0<br />

32.0<br />

DIET:<br />

DEFAULT<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

117.0<br />

117.0<br />

117.0<br />

117.0<br />

117.0<br />

117.0<br />

117.0<br />

DEFAULT<br />

House Dust (ug Pb/g)<br />

91.9<br />

91.9<br />

91.9<br />

91.9<br />

91.9<br />

91.9<br />

91.9<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL, CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

( ug /dL )<br />

-----------<br />

3.0<br />

3.2<br />

3.0<br />

2.8<br />

2.4<br />

2.2<br />

2.0<br />

Total Uptake<br />

( ug /day<br />

------------<br />

5.47<br />

7.59<br />

8.04<br />

8.01<br />

7.00<br />

6.98<br />

7.18<br />

Soil+Dust Uptake<br />

( ug/day<br />

------------<br />

2.47<br />

3.91<br />

3.94<br />

3.97<br />

2.98<br />

2.69<br />

2.55


1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

-6 :<br />

*-7:<br />

2.70<br />

3.06<br />

2.97<br />

2.89<br />

3.07<br />

3.39<br />

0.94<br />

0.98<br />

1.01<br />

1.06<br />

1.12<br />

1.14<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


I I I I I I I I I<br />

1<br />

Cutoff: 10.0 ug/dL<br />

z above: 0.39<br />

z Below: 99.61<br />

C. Mean: 2.9<br />

LEdD 0.99d<br />

2 4 6 8 10 12 14 16<br />

BLOOD LEaD CONCENTRLTION


LEAD MODEL Version 0.99d M 4~ 6 7 I sv mk 133, 6<br />

\<br />

ATR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

ndoor AIR Pb Conc: 30.0 percent of outdoor.<br />

,ther AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day) Lung Abs. (%)<br />

0-1 1.0 2.0 32.0<br />

1-2 2.0 3.0 32.0<br />

2-3 3.0 5.0 32.0<br />

3-4 <strong>4.</strong>0 5.0 32.0<br />

4-5 <strong>4.</strong>0 5.0 32.0<br />

5-6 <strong>4.</strong>0 7.0 32.0<br />

6-7 <strong>4.</strong>0 7.0 32.0<br />

Diet: alternate diet selected by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.001 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

DEFAULT<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g)<br />

162.0<br />

162.0<br />

162.0<br />

162.0<br />

162.0<br />

162.0<br />

162.0<br />

House Dust (ug Pb/g)<br />

123.4<br />

123.4<br />

123.4<br />

123.4<br />

123.4<br />

123.4<br />

123.4<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

-3 :<br />

-4 :<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-------____<br />

3.5<br />

3.7<br />

3.5<br />

3.3<br />

2.8<br />

2.5<br />

2.3<br />

Total Uptake<br />

(ug/day)<br />

------------<br />

6.44<br />

8.92<br />

9.44<br />

9.46<br />

8.13<br />

8.04<br />

8.22<br />

Soil+Dust Uptake<br />

( ug/day 1<br />

------------<br />

3.34<br />

5.27<br />

5.32<br />

5.37<br />

<strong>4.</strong>04<br />

3.66<br />

3.46


YEAR<br />

------<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

(ug/day)<br />

___------__<br />

2.71<br />

2.69<br />

3.10<br />

3.02<br />

2.97<br />

3.17<br />

3.53<br />

Water Uptake<br />

(ug/day 1<br />

_______-____<br />

0.37<br />

0.92<br />

0.97<br />

1.00<br />

1.05<br />

1.12<br />

1.14<br />

Paint Uptake<br />

Air Uptake<br />

( ug/day )<br />

------------<br />

(ug/day)<br />

--------<br />

0.00 0.02<br />

0.00 0.03<br />

0.00 0.06<br />

0.00 0.07<br />

0.00 0.07<br />

0.00 0.09<br />

0.00 0.09


I I I I I I I I I I<br />

Cutoff: 10.0 us/dL<br />

z Above: 0.97<br />

z Below: 99.03<br />

C. Mean: 3.4<br />

L<br />

LEAD 0.99d<br />

0 2<br />

-<br />

I I I<br />

4 6 8 10 12 14 16 18<br />

BLOOD LEAD CONCENTRATION <br />

0 to 60 Months


AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

Indoor AIR Pb Conc: 30.0 percent of outdoor.<br />

Other AIR Parameters:<br />

Age Time Outdoors (hr)<br />

0-1<br />

1.0<br />

1-2<br />

2.0<br />

2-3<br />

3.0<br />

3-4<br />

<strong>4.</strong>0<br />

4-5<br />

<strong>4.</strong>0<br />

5-6<br />

<strong>4.</strong>0<br />

6-7<br />

<strong>4.</strong>0<br />

Vent. Rate (m3/day)<br />

2.0<br />

3.0<br />

5.0<br />

5.0<br />

5.0<br />

7.0<br />

7.0<br />

Lung a s . (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

3iet: al-ernate diet selec-ed by user as follows:<br />

Home-grown Fruit: 0.000 ug Pb/g 0.0 %<br />

Home-grown Vegetables: 0.001 ug Pb/g 25.0 %<br />

Recreational Fish: 0.000 ug Pb/g 0.0 %<br />

Wild Game: 0.000 ug Pb/g 0.0 %<br />

3RINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

Soil (ug Pb/g) House Dust (ug Pb/g)<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

200.0 150.0<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

.YATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

ZALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

------<br />

3.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL 1<br />

-----------<br />

3.9<br />

<strong>4.</strong>2<br />

3.9<br />

3.7<br />

3.2<br />

2.8<br />

2.6<br />

Total Uptake<br />

(ug/day)<br />

------------<br />

7.13<br />

10.01<br />

10.55<br />

10.59<br />

9.00<br />

8.83<br />

8.97<br />

Soil+Dust Uptake<br />

( ug/ day 1<br />

------------<br />

<strong>4.</strong>06<br />

6.40<br />

6.46<br />

6.53<br />

<strong>4.</strong>93<br />

<strong>4.</strong>46<br />

<strong>4.</strong>23


YEAR<br />

- ___-<br />

-1:<br />

--2 :<br />

2-3:<br />

3-4;<br />

4-5:<br />

5-6:<br />

6-7:<br />

Diet Uptake<br />

(ug/day)<br />

__----_-___<br />

2.69<br />

2.66<br />

3.07<br />

3.00<br />

2.96<br />

3.16<br />

3.52<br />

Water Uptake<br />

( ug /day 1<br />

_-_-_-------<br />

0.37<br />

0.92<br />

0.96<br />

0.99<br />

1.05<br />

1.11<br />

1.13<br />

Paint Uptake<br />

(ug/day 1<br />

------------<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

Air Uptake<br />

(ug/day 1<br />

------- -<br />

0.02<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


Cutoff: 10.0 us/dL<br />

x Above: 1.76<br />

Z Below: 98.24<br />

C. Mean: 3.7<br />

LEAD 0.99d<br />

BLOOD LEAD CONCENTRATION <br />

0 to 60 Honthr


'LEAD MODEL Version 0.99d<br />

vk(93, 5wwU 13'4,s0'1\<br />

AIR CONCENTRATION: 0.100 ug Pb/m3 DEFAULT<br />

idoor AIR Pb Conc: 30.0 percent of outdoor.<br />

,cher AIR Parameters:<br />

Age Time Outdoors (hr) Vent. Rate (m3/day)<br />

0-1 1.0 2.0<br />

1-2 2.0 3.0<br />

2-3 3.0 5.0<br />

3-4 <strong>4.</strong>0 5.0<br />

4-5 <strong>4.</strong>0 5.0<br />

5-6 <strong>4.</strong>0 7.0<br />

6-7 <strong>4.</strong>0 7.0<br />

DIET:<br />

DEFAULT<br />

Lung Abs. (%)<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

32.0<br />

DRINKING WATER Conc: <strong>4.</strong>00 ug Pb/L<br />

WATER Consumption: DEFAULT<br />

SOIL & DUST:<br />

Soil: constant conc.<br />

Dust: Multiple Source Analysis<br />

DEFAULT<br />

Age<br />

0-1<br />

1-2<br />

2-3<br />

3-4<br />

4-5<br />

5-6<br />

6-7<br />

soil (ug Pb/g)<br />

26.0<br />

26.0<br />

26.0<br />

26.0<br />

26.0<br />

26.0<br />

26.0<br />

House Dust (ug Pb/g)<br />

28.2<br />

28.2<br />

28.2<br />

28.2<br />

28.2<br />

28.2<br />

28.2<br />

Additional Dust Sources: None DEFAULT<br />

Soil contribution conversion factor: 0.70<br />

Air contribution conversion factor: 100.0<br />

PAINT Intake: 0.00 ug Pb/day<br />

DEFAULT<br />

MATERNAL CONTRIBUTION: Infant Model<br />

Maternal Blood Conc: 2.50 ug Pb/dL<br />

CALCULATED BLOOD Pb <strong>and</strong> Pb UPTAKES:<br />

YEAR<br />

__--__<br />

0.5-1:<br />

1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

Blood Level<br />

(ug/dL)<br />

-----------<br />

2.0<br />

2.0<br />

1.9<br />

1.8<br />

1.7<br />

1.6<br />

1.5<br />

Total Uptake<br />

(ug/day)<br />

-----_______<br />

3.72<br />

<strong>4.</strong>82<br />

5.25<br />

5.18<br />

<strong>4.</strong>86<br />

5.04<br />

5.34<br />

Soil+Dust Uptake<br />

( ug/day 1<br />

___---------<br />

0.67<br />

1.06<br />

1.06<br />

1.07<br />

0.80<br />

0.72<br />

0.68


1-2:<br />

2-3:<br />

3-4:<br />

4-5:<br />

5-6:<br />

6-7:<br />

2.77<br />

3.12<br />

3.02<br />

2.93<br />

3.10<br />

3.42<br />

0.96<br />

1.00<br />

1.03<br />

1.07<br />

1.13<br />

1.15<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.00<br />

0.03<br />

0.06<br />

0.07<br />

0.07<br />

0.09<br />

0.09


I I , , , , ,<br />

I I ( I I I I I I I I ,<br />

Cutoff: 18.8 ug/dL -<br />

x Above: 0.82<br />

x Below: 99.98 -<br />

C. Hean: 1.9<br />

-<br />

-<br />

-<br />

-<br />

-<br />

-<br />

-<br />

-<br />

LEAD 8.99d<br />

3 ' W I ' -<br />

0 1 2 3 4 5 6 7 8 9 18


Appendix L. 11<br />

Superfund’s St<strong>and</strong>ard Default Exposure Factors for the Central<br />

Tendency <strong>and</strong> Reasonable maximum exposure


THIS PAGE LEFT BLANK


DEC- 13-93 MON 645 h B W / E M P - 02<br />

DEC 1 6 1993<br />

FOR TBE CENTRAL TENDENCY AND<br />

REASONABLE MAXIMUM EXPDSVRE


DEC-13-93 W O N<br />

8:58 645 A B W A E M<br />

P,<br />

TABLE OF COtJTENTS<br />

1.0 iNTRODUCTfON<br />

L.l Cebtral Tendency<br />

1.2 Reasonable Maximum Exposure (EWE)<br />

1.3 Residential Exposure<br />

1.4 Occupational. Exposure<br />

(8<br />

2.0 CONCENTRATION<br />

-<br />

Page<br />

3<br />

5<br />

5<br />

6<br />

6<br />

c<br />

3.0 EXPOSURE FREQUENCY<br />

3.1 Central Tendency<br />

3.1.1 Residential<br />

3.. 1.2 Occupational<br />

3.2 Reasonable Maximum Exposure<br />

3.2.1 Residential<br />

3.2.2 Occupational<br />

<strong>4.</strong>0 EXPOSURE DURATION<br />

<strong>4.</strong>1 Central Tendency<br />

<strong>4.</strong>1.1 Residential<br />

<strong>4.</strong>1.2 Occupational c<br />

<strong>4.</strong>2 Reasonable Maximum Exposure<br />

<strong>4.</strong>2'.1 Residential<br />

<strong>4.</strong>2.2 Occupational<br />

5.0 BODY WEIGHT<br />

5.1 Child<br />

5.2 Adult<br />

6.0 INGESTION OF POTABLE WATER<br />

6.1 Central Tendency<br />

6.1. I Residential Ingestion Rate<br />

6.1.2 Occupational Ingestion Rate<br />

5.2 ReaSonable Maximum Exposure<br />

6.2.1 Residential Ingestion Rate<br />

6.2.2 Occupational Ingestion Rate<br />

7.0 INGESTTON OF SOIL AND DUSTS<br />

7.1 Central Tendency Exposure<br />

7.1,1 Chfld's Ingestion Rate<br />

7.1.2 Adult Ingestion Rate: Non-Contact Intensive<br />

7.1.3 Adult Ingestion Rate: contact Intensive<br />

7.1.4 Residential Exposure Scenario: Child + Adult<br />

7.1.5 Exposure Frequency <strong>and</strong> Duration: Central<br />

Tendency<br />

7.2 Reasonable Maximum Exposure<br />

7.2.1 Child's Ingestion Rate<br />

7.2-2 Adult Ingestion Rate: Non-Contact Intensive<br />

7.2.3 Adult Ingestion Rate: Contact Intensive<br />

7.2.4 Residential Exposure Scenario: Child + Adult<br />

8<br />

6<br />

9<br />

9<br />

9<br />

9<br />

9<br />

9<br />

10<br />

10<br />

10<br />

10<br />

11<br />

11<br />

11<br />

1


l3EC-13-93 W O N s:59 6 5 4 5 A B W J E M<br />

P- 84<br />

7.Zr5 Exposure Frequency <strong>and</strong> Duration: FHE<br />

7.3 General Exposure Frequency <strong>and</strong> Duration<br />

Considerations<br />

7.4 Frabticn Ingested from the Contaminated Source<br />

7.5 Matkix Effect<br />

8.0 INHA1,ATION OF CONTAMINANTS<br />

9.0 IN,GGSTION OF LOCALLY CAUGHT FISH<br />

10 .o INGESTS& OF PRODUCE<br />

10.1 Total Produce Consumption Rates<br />

10.2 Crdp Specific Ingestion Rates<br />

.-<br />

11<br />

12<br />

12<br />

12<br />

13<br />

13<br />

14<br />

15<br />

16<br />

TABLE OF DEF@LT<br />

- KEFERENCES<br />

EXF’OSURE FACTORS<br />

17<br />

18<br />

2


1.0 INTRODUCTZON<br />

Last spring, EPA's Risk Assessment Council released a memor<strong>and</strong>um<br />

entitled "Guidance on Ri6k Characterization for Risk Managers <strong>and</strong><br />

Risk AssessorsU (U.S. EPA 1992) in which the council advocated<br />

greater interface between risk assessment <strong>and</strong> risk management,<br />

greater discussion of confidence <strong>and</strong> uncertainty in the risk<br />

assessment, <strong>and</strong> presentation of the range of possible exposures<br />

including the use of multiple risk descriptors. Focusin-g<br />

specifically on this last point regarding the exposure<br />

assessment, the Risk Assessment Councfl (RAC) clearly indicated<br />

that it expects all risk assessments "to address or provide<br />

descriptions of (I) individual risk to include the central<br />

tendency <strong>and</strong> high end portions of the risk distribution, (2)<br />

important subgroups of the population such as highly exposed or<br />

highly susceptible groups or individuals, if known, <strong>and</strong> (3)<br />

population risk".<br />

. For several years now, the Superfund program ha6 considered<br />

exposure to sensitive subgroups or populations a8 applicable <strong>and</strong><br />

has been estimating individual risk corresponding to the<br />

reasonable maximum exposure (RME). The Rtsk Assessment Guidance<br />

for SyDerfund: Human Health Evaluation Ma (Part A) (U.S. EPA<br />

1989) also known as RAGS, defines the -%the highest exposure<br />

that is reasonably expected to occur at a site <strong>and</strong> in practice is<br />

estimated by,combining 90 - 95th percentile values for some but<br />

not all exposure parameters. Shortly after RAGS was released,<br />

the Superfund Program developed the "St<strong>and</strong>ard Default Exposure<br />

Factors" Supplemental Guidance (U.S. €PA 1991) t0 Promate<br />

consistency in the evaluation of the RME exposure in baseline<br />

risk assessments when site-specific data was lacking. It is the<br />

position of the Superfund Program that RACS <strong>and</strong> the st<strong>and</strong>ard<br />

default values for the RME are consistent with the Risk<br />

Assessment Council's expectation to provide a description of the<br />

high-end portion of the risk distribution.<br />

..<br />

Until the guidance contained herein was developed, existing<br />

Superfund guidance did not provide a framework in which to<br />

estimate risk corresponding to the central tendency portion of<br />

the risk disttibution as called for by the Risk Assessment<br />

Council. Perceiving a need to fill this void, a workgroup was<br />

organized by the Superfund Program in October of 19928 comprised<br />

mainly of EPA Regional Superfund risk assessors, with the PurpQse<br />

of defining the central tendency for use in Superfund baseline<br />

risk assessments. Over the course of the following SfX months8<br />

the workgroup,convened periodically to discuss an approach <strong>and</strong><br />

identify st<strong>and</strong>ard default exposure factors for the central<br />

tendency. In'doing so, the workgroup also felt it beneficial to<br />

review the current default exposure factors for the RME <strong>and</strong><br />

identify whether any changes were warranted at this time.<br />

Consequently, this guidance builds on the concepts identified in<br />

RAGS Part A <strong>and</strong> the Risk Assessment Council's recommendations<br />

regarding risk descriptors for the central tendency. It<br />

supersedes the st<strong>and</strong>ard default exposure factors for the RME<br />

3


contained in the guidance of the same name (U.S. EPA 1991).<br />

Reliance on the point estimate approach vs. the use of monte<br />

carlo techniques to characterize the range of possible exposure<br />

estimates was initially discussed by the workgroup as both<br />

approaches have merit in addressing the Risk Assessment Council's<br />

call to present the range of possible exposures <strong>and</strong> risk<br />

outcomes. In the end, the workg_roup concluded that to0 many<br />

issues regarding the practical application of monte Carlo<br />

technique8 remained unresolved <strong>and</strong> would require a significant<br />

investment of time <strong>and</strong> resources to address such that the<br />

traditional point estimate approach to exposure assessments was<br />

favored at this time. Additionally, the point estimate approach<br />

to exposure vas deemed fully consistent with the intent of tho<br />

Risk Assessment Council in their memo. .<br />

As there pr6Bently is an agency-wide effort underway to address<br />

all Of the Risk Assessment Council8 s recommendations (including<br />

the use of mbnte carlo techniques <strong>and</strong> revisions to EPA's Exposure<br />

Factors H<strong>and</strong>book iacorporating distributions for the Various<br />

exposure parheters), the guidance contained herein for the<br />

Superfund Prdgram is subject to change <strong>and</strong> consequently should be<br />

viewed as interim in status. When such agency-wide guidance is<br />

available, if is expected that it may supersede this guidance.<br />

The guidance'contsined herein has been developed to encourage a<br />

ConsiSt@nt approach to assessing exposures when there is a lack<br />

of site-specific data or consensus on which parameter value to<br />

choose, given a range of possibilities. Accordingly, the<br />

exposure factors presented in this document are generally<br />

considered mast appropriate <strong>and</strong> should be used in baseline risk<br />

assessments unless alternate or site-specific values can be<br />

clearly justified by supporting data.<br />

Supporting data for many of the exposure factors presented in<br />

this guidance can be found in the Exposure Factors H<strong>and</strong>book (EFH;<br />

U.S. €PA, 1990). Additionally, in some instances, peer reviewed<br />

studies were utilized to identify suitable default values as well<br />

as group consensus techniques when a faced with a great deal of<br />

uncertainty. In these instances, either the study or a clearly<br />

documented logical approach used to identify default factors is<br />

referenced.<br />

The general exposure equation into which these st<strong>and</strong>ard factors<br />

are to be utilized is as follows:<br />

- Intake C x IR x EF x ED<br />

BW x AT<br />

C =<br />

uhere<br />

Concentration of the contaminant in a given medium<br />

IR = Intake/Contact Rate; the amount.of contaminated<br />

medium contacted per unit time or event<br />

EF = Exposure Frequency<br />

4


DEC-13-93 MON 0 1 8 1 645 F5BW/EM<br />

P. fa7<br />

ED * Exposure Duration<br />

BW t Body Weight<br />

AT PL Averaging Time (equal to exposure duration for<br />

non-carcinogens <strong>and</strong> 70 years for carcinogens)<br />

1.1 Cehtral Tendency (a)<br />

The Risk Assessment Council defined the central<br />

tendency risk descriptor as either the arithmetic mean<br />

risk or the median risk <strong>and</strong> continues to say that the<br />

arithmetic mean risk can be derived by using average<br />

va$ues for all the exposure factors though cautions<br />

that when dealing with skewed data, the median or 50th<br />

pekcentfle may better approximate the midpoint of a<br />

distribution (U.S. EPA 1992). As a result, any<br />

approach to the identification-of default factors for<br />

the central tendency should seek to identify average or<br />

50th percentile values whenever possible. In keeping<br />

with this approach, default exposure factors<br />

approximating the average or 50th percentile value have<br />

beCn identified whenever possible for use in central<br />

tehdency exposure evaluations.<br />

1.2 Rebaonablr Harthunt Exposure (RME)<br />

The Risk Use-ssment Council defined a high end risk<br />

descriptor as one which characterizes risk to an<br />

individual at the upper end of the risk distrabutlm.<br />

Conceptually, it can be equated to about the 90th<br />

pekcentile of the population distribution (U.S. EPA<br />

1992). As previously indicated, the reasonable maximum<br />

e+osure (RME) terminology used by the Superfund<br />

Prdgram is believed consistent with this description.<br />

Thd Risk Assessment Guidance for Suuqrfund : Human<br />

mlth E valuation Manual (Part A) (RAGS) defines the<br />

RME as the highest exposure that is reasonably expected<br />

to occur at a site <strong>and</strong> in practice is estimated by<br />

combining upper bound (90 - 95th percentile) values for<br />

sode but not all exposure parameters. Consequenrly,<br />

the Superfund Program will continue to use the current<br />

terminology of reasonable maximum exposure (-1 in<br />

fulfilling the Risk Assessment Council's m<strong>and</strong>ate to<br />

evaluate a high end risk descriptor.<br />

In keeping with the previous default factor guidance<br />

(U-S. EPA 1991), 90 to 95th percentile values were<br />

targeted in this guidance document when identifying<br />

default factors for intake/contacc- rate, exposure<br />

frequency, <strong>and</strong> exposure duration. An average value or<br />

conservative estimate of the media average contacted<br />

over the exposuze period was targeted for<br />

identification of default values for body weight <strong>and</strong><br />

exposure concentration respectively,<br />

5


DEC-13-93 W O N 9 l C a l 645 A B W / E M<br />

Within the context of this guidance, st<strong>and</strong>ard default<br />

exeosure factors have been identified for various<br />

exposure pathways <strong>and</strong> receptor populations owing to the<br />

differsnt nature <strong>and</strong> magnitude of the assumed<br />

exbosure. Generally speaking, default values for<br />

reeidentlal <strong>and</strong> occupational receptors have been<br />

identified <strong>and</strong> serve as the general basis for<br />

organization of this guidance.<br />

--<br />

1.3 Reaideatirl Erpoauro<br />

Redidential default exposure factors are generally<br />

relevant whenever there are OE reasonably may be<br />

eaected to be residences on or adjacent to the site.<br />

The contadnation may be on the site itself or may have<br />

midrated from it. With the exception of exposure to<br />

contaminated soils, distinctions are not Usually made<br />

id the default parameters for exposures to different<br />

aged receptors. Because of the higher intake to body<br />

weight ratio presumed to occur during the early years<br />

(ages 1-6) for this exposure pathway, special attention<br />

should be given to evaluating exposure for this pathway<br />

<strong>and</strong> is discussed in sections 7.<strong>4.</strong> <strong>and</strong> 7.5.<br />

1.4 occbpationsi Exporruca<br />

Occupational default exposure factors are generally<br />

relevant whenever the site serves or may reasonably be<br />

cected to serve aa a place of temporary or permanent<br />

employment. Examples of employment in which one may be<br />

prebumed to come in contact with contaminated media<br />

dght include employment at the facility itself or<br />

nearby facilities (commercial/ industrial), servicing<br />

of fhe facility (grounds keeper/utility maintenance),<br />

or construction of new facilities oz the demolition of<br />

old facilities on or adjacent to the site.<br />

2.0 CONCENTRATION<br />

Central T<strong>and</strong>edcy <strong>and</strong> RME<br />

The concentration term in the intake equation is the arithmetic<br />

average of the concentration that is contacted over the exposure<br />

period. _mmzua_the uncertainty associated with any estimate.<br />

0-Fexposure cdncentration, the 95% percent upper confidence limit<br />

an-the arithmetic average concentration will be used for this<br />

variable in both the central tendency <strong>and</strong> reasonable maximum<br />

e_aposure estidates. - Consideration should be given to the data<br />

set upon which the 954 upper confidence limit of the mean value<br />

is generated so as to represent as closely as possible the nature<br />

(acute vs. chronic) of potential exposures.<br />

In some instances, there may be great variability in measured or<br />

modeled concentration values such as when Qjp::few samples are<br />

taken or when model inputs are uncertain. I these cases the<br />

*-mu---!-*<br />

u p p e i ~ t * a ~ t haverage e concen +FE? a ion-zay- even<br />

exceed the x dm d u e observed or predicted. Should this<br />

6


DEC-13-93 W O N 9 : ~ 2645 A B W A E M<br />

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scenario arise, then the simple arithmetic mean <strong>and</strong> maximum<br />

concentratioas's%%%ld-be'~used 'for the central tendency <strong>and</strong><br />

reasonable maximum exposure concentrations respectively.<br />

3.0 EXPOSURE FREQWENCY<br />

The following default exposure frequencies may be utilized unless<br />

otherwise indicated or site-specific data is available.<br />

3.1 Cenhal Tendency<br />

3,k.l Residential<br />

The central tendency residential default exposure<br />

frequency of 234 days/year corresponds to the fraction<br />

of time estimated that is actually spent at home (64<br />

percent) for both men <strong>and</strong> women based on a study of<br />

time use patterns summarized in,the EFH W.S. EPA<br />

1990). Because the study included both personal <strong>and</strong><br />

work related travel, a 365 day year was used from which<br />

to compute the 64 percent.<br />

3.1.2 Occupational ?<br />

3.2 Reasonable Maximum Exposure<br />

3.2,.1 Residential<br />

The RME residential default exposure frequency of 350<br />

mystyear is based on the previously identified default<br />

value which assumes a two week vacation each year.<br />

This i s viewed as a reasonably conservative estimate of<br />

exposure frequency absent site-specific data.<br />

3.2.2 Occupational<br />

The RME occupational default exposure frequency of 250,<br />

dZy$/year Is consistent with the previously identified<br />

default value <strong>and</strong> is based on a 5 day work week with<br />

two weeks of vacation each year. This is viewed as a<br />

reasonably-conservative estimate of exposure frequency<br />

absent site-specific data.<br />

<strong>4.</strong>0 EXPOSURE DURATION<br />

The following default exposure durations may be utilized unless<br />

otherwise indicated or site-specific data is available.<br />

<strong>4.</strong>1 Central Tendency<br />

<strong>4.</strong>1.1 Residential<br />

The residentfal central tendency default exposure<br />

duration of S'ycars is based on data summarized in the<br />

EFH (U.S. EPA 1990) in which the average length Of<br />

residence in the same house of people who own their own<br />

home was estimated to be 9 years.<br />

<strong>4.</strong>1.2zC-mpational ?<br />

7


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<strong>4.</strong>2 Rearonable Maximum Exposure<br />

<strong>4.</strong>2.1 Residential<br />

The RME residential default exposure duration of 3.0<br />

%-ears is based on data summarized in the EFR (U.S. EPA<br />

1940) In which the 90th percentile for the length of<br />

residence in the same house of people who own their own<br />

home was estimated to be 30 years.<br />

<strong>4.</strong>2.2 Occupational<br />

The,.RME occupational default exposure duration of 25<br />

p,ears*is based upon the 95th percentile for the number<br />

of years worked at the same location as reported by the<br />

U.S. Bureau of Labor Statistics, 1990.<br />

5.0 BODY wEIGET<br />

The average body weight is to be utilized'for both the central<br />

tendency <strong>and</strong> pMe exposure evaluations in keeping with the<br />

- respective definitions.<br />

5.1 Child<br />

The approximate average body weight of young children (boys<br />

'ad girls combined) under the age of 6 years is<br />

approximately 15 kg (U.S. EPA 1990). Distributions of body<br />

weights hnd average body weights <strong>and</strong> for other age groups<br />

can be found in the EFH (U.S. EPA 19901.<br />

5.2 Adult<br />

The average body weight of XI--g corresponds to.the average<br />

weight of men <strong>and</strong> women age 18-75 as reported in EFH (U.S.<br />

EPA 1990). Distributions of body weights <strong>and</strong> average body<br />

weights for other age groups can be found in the EFH (U.S.<br />

EPA 19901.<br />

6.0 ZNGCSTXON OF POTABU WATER<br />

6.1 Central Tendency<br />

6-1.1. Residential Ingestion Rate<br />

The central tendency potable water ingestion rate for<br />

an adult-of 114 llday is based on the average intake<br />

observed from five studies as summarized in the EFH<br />

(U.S. €PA 1990). The observed range reported across<br />

the five studies was from 0.26 - 2.8 llday.<br />

6.1.2 Occupational Ingestion Rate<br />

Nosdata upon which to base a default value.<br />

6.2 Reasonable Maxhwa Exposure<br />

6.2.1 Residential Ingestion Rate<br />

The RME potable water ingestion rate of-FUday is<br />

close to the 90th percentile of values measured <strong>and</strong><br />

estimated by researchers as summarized in EFH (U.S. €PA<br />

1990). It is also the value currently used by EPA's<br />

Office of Water in establishing drinking water<br />

st<strong>and</strong>ards.<br />

8


DEC-13-93 MON<br />

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..<br />

* .<br />

c<br />

6.2.2. Occupational Ingestion Rate<br />

Nn data upon which to base a default value.<br />

7.0 INGESrXbN OF SOIL AND DUST<br />

Due to the importance of the receptor's age <strong>and</strong> behavioral<br />

characteristics, default ingestion rates for this exposure<br />

pathway have been established based on the characteristics of the<br />

receptor rather than on the location of the exposure (residential<br />

vs. occupatidnal). Default ingestion rates for this pathway are<br />

as described Qelow in <strong>Section</strong>s 7.1 <strong>and</strong> 7.2-<br />

7.1 Central Tendency<br />

7 .l.l.<br />

child's Ingestion Rate<br />

Nunierous studies have documented that the propensity to<br />

ingest non-food items is greatest in the early years of<br />

development, As a result, children between the ages of<br />

l'<strong>and</strong> 6 years are of greatest concern as they are<br />

expected to have the greatest exposure to contaminated<br />

soils <strong>and</strong> dusts via ingestion. Numerous studies<br />

(tracer studies <strong>and</strong> estimates of deposationfexposed<br />

,surface area) have resulted in wide ranging estimates<br />

of the amount of sail <strong>and</strong> dusts ingested by young<br />

children'making it difficult to identify a single value<br />

for' use as the central tendency. Additionally, owing<br />

to the nature of the experimental studies, it is<br />

extremely difficult to separate the contribution to<br />

exposure resulting from exterior soils vs. interior<br />

dusts. As d result-the ingestion rate is reported as<br />

the combined rate for soils <strong>and</strong> dusts.<br />

It vas believed by-a consensus of workgroup members<br />

that the iestian rate of 100 mg/day as a Central<br />

tendency ingestion rate for a child between the ages of<br />

r6yyears was within reason based on results using<br />

traeer elements (Davis et al. 1990 <strong>and</strong> Calabrese 19891.<br />

Furthermore, 100 mg/day is nearly identical to the<br />

ingestion rate for this age group based on age specific<br />

values utilized in support of the NAAQS for lead (U.S.<br />

EPA 1989b) <strong>and</strong> the lead biokinetic uptake model.<br />

7.1r2 Adtflt'!.s Ingestion Rate: Non-Contact Intensive<br />

For the adult who does Rot engage in soil or dust<br />

contact intensive activities on a regular basis<br />

(apartment dweller, typical homeowner, office worksf,<br />

teacher, professional, etc.) the soil <strong>and</strong> dust default<br />

inge]stion rate for the central tendency of SB,aq/daybased<br />

on a study of Calabrese 1990 (with supporting<br />

estimates from Hawley 1985).<br />

7.1.3 Adult's Ingestion Rate: Contact Intensive<br />

For adults who routinely engage in heavy contact with<br />

soils <strong>and</strong> dusts on a regular basis (including seasonal<br />

work), the workgroup was unable to identify a default<br />

9


DEC-13-93 MON<br />

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soil ingestion rate corresponding to the central<br />

tendency given the data available. Tt is suggested<br />

that an evaluation of the RME scenario for this<br />

receptor be conducted.<br />

l.i.<strong>4.</strong> W3;iiential: Child + Adult Combined<br />

In evaluating a residential exposure scenario for this<br />

pathway, a weighted average of the child's <strong>and</strong> adult's<br />

exposure is to be utilized. The duration of exposure<br />

fog.the central tendency ha6 been defined as consisting<br />

of'riihe-years (average number for years at the same<br />

dwelling). It is the default position to assume that<br />

fat 2-of the nine years, intake will be at the child's<br />

rate <strong>and</strong>'xor-the rernaining-Tyears, intake will be at<br />

thq-adult rate, This is consistent with the proportion<br />

of time one is assumed to be a young child that is<br />

utilized for Fua residential calculations. Thus<br />

residential exposure for the central tendency should<br />

generally be evaluated as follows:<br />

4- ,$*35 9 7<br />

2 Years x 100 ma/dav t 7 Years x 50 ma/dav<br />

q3<br />

15 kg 70 kg<br />

--<br />

--,<br />

7,1,.5 Exposure Frequency <strong>and</strong> Duration: Central Tendency<br />

The default value for the duration of exposure for the<br />

central tendency scenario is 9 years for a residential<br />

ex&sure based on the average length of stay in a home<br />

as keported in the EFK (U.S-EPA 1990). It should be<br />

noted that generally the intake over the 9 year<br />

exposure period is to be computed as described in<br />

section 7.1.<strong>4.</strong> The default<br />

+<br />

expasura..freaue ncy- €or the 7<br />

central tendency is 350 da s/ ea-rrdue to the nature in<br />

which the soil ingest on rates have been computed<br />

(avkrage daily exposure).<br />

A default exposure frequency <strong>and</strong> duration has not been<br />

specified for the central tendency occupational<br />

scenario at this time as St ha8 not been discussed by<br />

the workgroup.<br />

7.2 Reasonable Maximum Exposure<br />

7.2.133@3-ci!.$;rirgestion Rate<br />

The'default RME ingestion rate for a young child age 1-<br />

6 years of age of .-28b~~g~day_represents the consensus<br />

opinion of the workgroup based on review of available<br />

data <strong>and</strong> is believed to correspond to a conservative<br />

estimate of an average ingestion rate for this age<br />

group over a chronic period of exposure.<br />

Unfortunately, the available data did not support<br />

identification of the 90 or 95 percentile value,<br />

was the consensus among workgroup participants that<br />

over the 6 year period of concern for this receptor<br />

category, the value of 200 mg/day waa reasonable to<br />

It<br />

10


DEC-13-93 MON -:e4 64s A B W / E M P- 13<br />

t ~<br />

assume. It should be noted that this value was nPt<br />

F,cessarily deemed relevant for acute exposures when a<br />

child may-engage in intensive contact with Soils <strong>and</strong><br />

dusts for a brief period of time. In these situations,<br />

ingestion rates greater than this value may be<br />

warranted.<br />

7.2.2 Adult's rngestion Rate: Non-Contact Intensive<br />

The M default soil <strong>and</strong> dust ingestion rate of 100<br />

mi#day is based a study of Sedman (1989). This value<br />

is presumed suitable for non-contact intensive<br />

scenarios (apartment dweller, typical homeowner, off ice<br />

worker, teacher, professional, etc. 1<br />

7.2.3'Adult's IngestiQn,Rate: Contact Intensive<br />

The RME default soil <strong>and</strong> dust hgestion rate of 480<br />

%>/day is deemed appropriate for acute exposures (those<br />

le6s than a year in duration). This value is based on<br />

estimates made by Hanley (19651 in which he estimated<br />

deposition rates, exposed surface areas of the h<strong>and</strong>s,<br />

<strong>and</strong> the fraction inadvertently consumed.<br />

7.2.4 RG'T*&ntial: Child + Adult<br />

In evaluating a residential RME exposure scenario, the<br />

exposure duration for the RME has been defined as<br />

consisting of 30 years (90 percentile for years at the<br />

same dwelling U.S. EPA 1990). It shall generally<br />

assumed when evaluating the RME residential exposure<br />

for the ingestion of soil <strong>and</strong> dusts that fxts6'of the<br />

Wy-ears, intake will be at the child's rate <strong>and</strong> for<br />

.the remaining 24 years, intake will be at the adult<br />

w e . Thus residential RME exposure for this pathway<br />

should generally be evaluated as follows:<br />

a<br />

4 vears x 200 mq/dav + 24 v ears x 100 mu/dav<br />

15 kg 70 kg<br />

-T<br />

7.2.5 Exposure Frequency <strong>and</strong> Duration: RME<br />

The default value for the duration of exposure for the<br />

RME scenario is 30 years for a residential exposure<br />

based on the 90th percentile for the length of stay in<br />

a home as reported in the EFH (U.S.EPA 1990). It<br />

should be noted that generally the intake over the 30<br />

year exposure period is to be computed as described in<br />

section 7.2.<strong>4.</strong> The default exposure frequency for the<br />

RME is 350 daysjyear due to the nature in which the<br />

sail ingestion rates have been computed (average daily<br />

exposure) <strong>and</strong> assuming a two week period away from home<br />

each year.<br />

The default value for the<br />

RME occupational scenario<br />

percentile for the number<br />

11<br />

-.<br />

c<br />

y&<br />

H<strong>4.</strong>3 1(,<br />

duration of exposure for the<br />

is 25 years based on the 95th<br />

of years worked at the same


DEC-13-93 W O N<br />

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location (Bureau of Labor Statistics 1990). The<br />

exposure frequency of 250 days/year corresponds to a<br />

. five day work week,<br />

7.3<br />

7.4<br />

General Exposure Fzequency <strong>and</strong> Duration Considerations<br />

Owing to the strong age <strong>and</strong> behavioral dependent nature<br />

of'this exposure, exposure durations <strong>and</strong> frequencies<br />

other than the default values may be warranted for this<br />

exposure pathway. For example, a situation may arise<br />

in'which a child-care facility is of concern <strong>and</strong> the<br />

residential default values for exposure frequency <strong>and</strong><br />

durtation may not be appropriate. Similarly, certain<br />

occupations may lead to intensive exposure but for<br />

brief periods of time (i.e. construction workers, field<br />

laborers, seasonal workers, etc.) rendering use of the<br />

occupational default values for' exposure frequency <strong>and</strong><br />

dJration Inappropriate.<br />

Additionally, there may be situations in which a Region<br />

believes it necessary to adjust the exposure frequency<br />

to account for meteorological conditions which may be<br />

presumed to drastically reduce or eliminate exposure to<br />

potential contaminants via soil ingestion. In these<br />

situations, any adjustments to tho exposure freWenCy<br />

to reflect local weather patterns should first be<br />

approved by the Regional Office-<br />

For these reasons, the default exposure durations <strong>and</strong><br />

exposure frequencies may not always be relevant for the<br />

expesurt at h<strong>and</strong>. Elctra care should be taken when<br />

idehtifying suitable exposure frequencies <strong>and</strong> durations<br />

far this exposure pathway.<br />

Frahtioa Ingested From the Contaminated Source<br />

The fraction ingested from the contaminated source is<br />

an important variable that often gets overlooked when<br />

evaluating scenarios that are largely dependent on the<br />

receptor coming to the source of contamination rather<br />

than the contamination migrating to the receptor. Dub<br />

Eo variations in the proximity of the receptor to the<br />

contaminated source, size of the contaminated source,<br />

recaptors of concern, mobility of receptors, <strong>and</strong> the<br />

nat\ire of exposure, default values for the fraction<br />

ingested from the contaminated source are not possible.<br />

Howdver, *it-advocated that this factor be given,<br />

e a - catef ul cansid~r~t~on-w~e~-'e~iuating this<br />

eiiposuKpTEiiay.<br />

7.5 Matrix Effect<br />

A parameter unique to all combinations of compounds <strong>and</strong><br />

soil types- the matrix effect - accounts for the<br />

tendency of a compound to bind to soils. The more<br />

"soil loving" a compound is, the less likely it is to<br />

12


DEC-13-93 W O N<br />

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de$orb <strong>and</strong> become bioavailable in the gastrointestinal<br />

tr+ct once ingested. Chemical <strong>and</strong> physical properties<br />

of contaminants <strong>and</strong> tho soil. can thus have a profound<br />

effect on the bioavailability of a compound.<br />

Unfortunately che data do not exist to support default<br />

desorption values for all compounds at this time though<br />

work i s currently underway to develop some guidance in<br />

this area. At present, any adjustments for this<br />

phenomenon are left open to the discretion of the<br />

Regional Office.<br />

8.0 INBALATl!ON OF COHTAXINANk8<br />

It is antiddated that at some time in the future, inhalation<br />

exposures w i l l be evaluated using inhalation reference<br />

concentrations. However, at this xime, tbe methodology is not<br />

yet avcilabJe <strong>and</strong> consequently, inhalatian rates <strong>and</strong> resulting<br />

dose (mg/kg/day) are the approach that is advocated for this<br />

- exposure pathway. Inhalation rates are dependent on age, sex,<br />

<strong>and</strong> activity level to name just a few factors <strong>and</strong> can be fbwd in<br />

the-Exposure Factors H<strong>and</strong>book (U.S. EPA 1990).<br />

The same defajalt inhalation raEa,h@$,Been Adentified for both the<br />

central tendehcy <strong>and</strong>-the-!posure sceparios. Thfs is in<br />

keeping with the assumption regarding inhalation rate used in the<br />

derivation of, cancer potency estimates <strong>and</strong> inhalation reference<br />

concentrations. . The default value of m-m'!jday COrreSpOndS to a<br />

reference man's inhalation rate who is at rest 8 hourstday <strong>and</strong> at<br />

a light activity level (i.e. domestic work, personal care,<br />

hobbies, minor indoor home improvements) for the remaining 16<br />

hours/day.<br />

9.0 INGESTIO~ OF LOCALLY -GET FISK<br />

The evaluation of this exposure pathway will not always be<br />

relevant to ebery site. The receptor of concern for this pathway<br />

is apt to include both the recreational fisherman <strong>and</strong> a<br />

subsistence fisherman <strong>and</strong> thear family. The preferred approach<br />

to the evaluation of this errpasure pathway is to obtain site?<br />

specific-dqregarding consumption rates <strong>and</strong> fishing habits.<br />

This is due tb the strong influence of local habits, populations,<br />

<strong>and</strong> condition9 on the resulting exposure.<br />

when site-specific data are not feasible to obtain, tEKdefatalt<br />

app-r3-deF-SUgg88ted for thls exposure pathway is based on an<br />

cst&g~tk or-the avara&e- sizeof a fish meal <strong>and</strong> merely varies the<br />

e%posure freqiency,-duxation, <strong>and</strong> fraction ingested from the -<br />

Sontaainated Source between the central tendency <strong>and</strong> the RME<br />

estimates. With this approach, recreational <strong>and</strong> subsistence<br />

fishermen can be assumed to consume the same amount of fish per<br />

eating occasidn yet differ in the frequency or number of fish<br />

meals actual13 consumed <strong>and</strong> the fraction of fish meals consumed<br />

that originated from the contaminated source. This change in<br />

approach was adopted because it was believed to better<br />

characterize exposure resulting from an intermittent <strong>and</strong> often<br />

13


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infrequent dxposure pathway than the default approach previously<br />

advocated which relied on an intake rate averaged over a year of<br />

exposure.<br />

he average :amount of fish consumed per eating,Bccaaion was<br />

observed to be ldS.g/6eal- or about 5 ounces as reported in the<br />

study of Pad et al. (1982). The range reported far the size of<br />

the fish mea?. was from 43 g/meal (5th percentile!_tO 565 g/meal<br />

(99th percentile). The study vas based on the results Of a selfadministere+USDA<br />

nationwide consumption survey from 1977-78 of<br />

individuals in 48 states. The amount of fish corresponds to<br />

consumption habits for fin-fish as reported on-.a:uet weight<br />

basis. It' daes not include shellfish. Although fish consumption<br />

habits have ,likely increased over the past 15 years, the Pa0<br />

study was believed to be the best study available upon which to<br />

base a default value.<br />

Owing to the very site-specific nature of the frequency of this<br />

exposure, no:defaults are given at this time for exposure<br />

frequency (fish meals/year) . However, estimates of the average<br />

<strong>and</strong> 90th - 95th percentile for the frequency of exposure should<br />

be used for the central tendency <strong>and</strong> RME respectively, Default<br />

values for *sure duration are those which are consistent with<br />

residential default values previously identified of-9'yearsmar<br />

qqntral tendency <strong>and</strong> 30.years €or the RHE. Additionally, it<br />

was believed that a site-specific value far tho fraction of fish<br />

consumed iroh tho contaminated source was appropriate rather than<br />

establishing'a default value for this factor. The average <strong>and</strong><br />

the 90th - 45th percentile values are suggested far the central<br />

tendency <strong>and</strong> RME for this parameter respectively.<br />

10.0 INGESTiQN OF PRODUCE<br />

The fOllowin approach has been suggested for this exposure<br />

pathway prov I! ded it is relevant to the risk evaluation:<br />

a. Strongly consider evaluating consumption of homegrown<br />

produce if it constitutes a current exposure pathway <strong>and</strong> if<br />

produce,ia available for analysis. If produce is not<br />

available for analysis, evaluation of this exposure pathway<br />

is open to the discretion of the Regional Office<br />

(recognizing that this decision is apt to depend on,the<br />

level of confidence in available plant uptake models).<br />

b. If the decision is made to employ an uptake model, the<br />

Region is strongly encouraged to seek the assistance <strong>and</strong>/or<br />

review of the proposed approach by ECAO-Cincinnati.<br />

c. e?n*evaluating this exposure-pathuayr preference should-,<br />

be given for site specific-consumption rates (obtainable vfa<br />

door tO :door surveys) if feasible., When site specific<br />

consmptfon rates are not feasible, either generic defaults<br />

regarding total consumption rates for all fruits combined or<br />

all vegetables combined (uSDA 1960) or defaults based on the<br />

14


mEC- 13--9= MON -3rla-r 645 A B W / E M<br />

average amount of a fruit or vegetable consumed on a given<br />

eating occasion (Pao et al- 19821 together with site<br />

specific exposure frequencies is suggested.<br />

d. The fraction ingested assumed to originate from a<br />

contaminated source will always be a site specific<br />

determihation.<br />

The choice of which of the approaches described belzw should be<br />

utilized for'the identification of default ingestion rate values<br />

1s left up to the risk assessor based on their underst<strong>and</strong>ing of<br />

the site. T)ze USDA (1980) results are based on the average<br />

consumption rate as self-reported over a three day period <strong>and</strong><br />

included non-consumers as well as consumers in the calculation.<br />

In contrast,nthe data of interest from Pa0 et a1.(1982) focused<br />

on the amount consumed of various food crops far a given eating<br />

occasion. m2irk"d3men def sult values .are used,,Lhe same<br />

ingestion rake utilize%"far-the-'central tendency is advocated far<br />

use in evaluking the RME scenario.yXf'- lib euggested that in<br />

these<br />

-<br />

instances, merely-the exposure frequency, duration, <strong>and</strong> the<br />

fraction ingbsted from the contaminated source vary between.the<br />

central tendency <strong>and</strong> the RME evaluations-<br />

10.2 Total produce Consumption Rate8 (USDA 1980, U.S. EPA<br />

1990)<br />

A8:summarized fn the EFH (U.S. EPA 19901, the USDA<br />

estimated the average intake on any one day of.dClfsits<br />

combined-AsaUkgt rson <strong>and</strong><br />

oximatcly -11s of t h i s ~ ~ ~ ! ~ be 6 dssumed & ~ d<br />

8- much"~3f10 of this<br />

C92'glday) could be assumed to be homegrown as a<br />

reaqonable m maximum exposure case.<br />

Thb average intake on any one day for ai&&--vegstables<br />

w n e d was- estimated as 201 g/dawg-ZJrt_hermore,<br />

approximately 1/4 (50 g/day) of this amount could be<br />

assumed ta-be homegrown-on average <strong>and</strong> astlnuch as 215.<br />

(864 gtaay c a u F ~ ~ ~ ~<br />

reasonable maximum exposure case.<br />

Due to the nature of the study, (a daily average intake<br />

over a three day exposure period), it can be assumed<br />

that the contact rates represent a chronic value. If<br />

this approach is selected, then the exposure frequency<br />

.e.<br />

for the- central" tendency <strong>and</strong>-WE-should be 356-<br />

diy'styear. The defaq t-ex -duration-raf lects the<br />

reddential- central -$,,tr,'p ten ency value of -mrs-or 30:<br />

ysars-fdr-the-RME scenario- Assumptions regarding the<br />

fraction ingested from the contaminated source are not<br />

specified though national averages for the fraction<br />

that can be assumed to be homegrown have been suggested<br />

as a described above.<br />

15


P- 18<br />

10.2<br />

-<br />

Crop Specific coasumption Habits (Peo et al. 1992)<br />

As, sumrnerized in the attached table, average values for<br />

the amount of a particular fruit or vegetable consumed<br />

on a given eating occasion can be identified based on<br />

the results of a nationwide survey conducted by the<br />

USDA as summarized in Pa0 et al. (1982). Additionally,<br />

the authors' reported the distribution of consumption<br />

vahes observed for each fruit or vegetable included in<br />

the survey. The Pao at al. data was based on the USDA<br />

nationwide food consumption survey conducted In 1977-<br />

78 Y<br />

Default values for the frequency of exposure have not<br />

been identified <strong>and</strong> are subject to site-specific<br />

determinations reflecting local consumption habits.<br />

The default exposure duration reflects the residential<br />

cgdtral tendency value of 9 years or 30 years for the<br />

W E scenario. The fraction ingested originating from<br />

the contaminated source has not been specified but is<br />

open to consideration of site-specific factors.<br />

16


P. 19<br />

C. .<br />

.I<br />

14Sghnd -fK 30 years<br />

wslh %<br />

70 kg


.<br />

m<br />

2<br />

Attachment 2 .<br />

Quantity Consumed Per ellno OCCaSlOn of Various Frultr <strong>and</strong> Ve@abltm (gram)<br />

Paa et. al. 1982<br />

Percontlte<br />

std.<br />

I<br />

food category WQ. dw. 5th 25th 60th 75th BOW 95th 99th Max.<br />

fresh grapefruit 159 58 106 134 134 165 268 268 330 660<br />

fresh oranges 146 57 73 14s 145 145. iao 228 360 1160<br />

appk3 141 49 69 138 138 138 212 212 276 636-<br />

bananas 106 37 SO 95 119 119 136 238 476<br />

canteloup<br />

171 91 61 136 136 272 212 272 529 896<br />

,raw pears 163 68 82 164 164 164 164 320 , 328 2132,<br />

raw peaches 160 75 76 152 I52 152 304 364 ' 456 760<br />

raisins 39 28 3 14 28 43 73 ' 73 145 290<br />

white potatoes 125 90 29 03 105 170 236 280 426 1260<br />

cabbage /cole slaw . 68 45 15 40 60 90 120 120 240 1020<br />

Q -<br />

faw carrots 43 40 4 13 31 55 100 122 183 500.<br />

raw celery<br />

33 24 8 17 28 40 60 80 120 204<br />

g raw cucumbers 80 78 8 24 10 110 158 220 316 840<br />

lefluce/tossed salads 65 59 10 20 5s 93 140 186 270 1080,<br />

B raw onions<br />

31 33 3 17 18 36 57 72 180 350<br />

Et 1 raw tomoatoes 81 55 30 45 62 119 123 182 246 72E!<br />

cooked bromli 112 68 30 78 90 165 185 190 360 680<br />

cooked cabbage 128 83 28 75 145 150 225 300 450 610<br />

- cooked cartots 79 50 19 46 75 92 150 155 276 736<br />

m<br />

,r mrn onloff cab<br />

95 56 21 65 83 123 170 170 330 050<br />

$ lima beans 110 75 21 67 88 I70 1?5 219 350 075<br />

01 cow peas, fleld peas <strong>and</strong><br />

p blackeve peas 131 aa 22 88 88 175 196 350 350 ?OO.<br />

u aaokedgreenpeas 90 57 20 43 85 05 170 170 330 080<br />

3 cooked spinach 121 70 24 ?0 103 185 205 205 380 454<br />

o strlng beans 86 54 18 67 16 135 140 140 280 840<br />

cooked summer squash 145 98 27 105 108 215 215 352 430 860<br />

cooked sweet potatoes 136 87 38 a6 114 is5 225 230 450 1020<br />

cucumber pickles 45 45 7 30 65 30 130 222 455<br />

i<br />

Cooked vegetables Includes canned.


DEC-13-9Z MON<br />

9te9 645 ABW0-EM<br />

P.21<br />

c- .<br />

WFERENCES<br />

Calabrese, E.J., Barnes, R., Stanek, E.J., Pastides, H., Gilbert,<br />

C.E., Veneman, P., wang, X., Lasztity, A., <strong>and</strong> P.T. Kosteck.<br />

1989. 3ow Much soil Do Young Children Ingest: an EpldemioLogic<br />

Study. Reg. (rax. <strong>and</strong> Phamac. 10:123-137.<br />

Davis, S., Wallerr P1, Buschbom, R., Ballou, J. <strong>and</strong> P. White.<br />

1990. Quantitative Estimates of Soil Ingestion in Normal<br />

Children between the Ages of 2 <strong>and</strong> 7 Years: Population-based<br />

Estimates Using Aluminum, Silicon, <strong>and</strong> Titanium as Soil Tracer<br />

Elements. Are. Environ. Health. 45(21 :112-122.<br />

Hawley, J.K. 1985. Assessment of health risk from exposure to<br />

contaminated soil. Risk Analysis 5 (4) : 289-302-<br />

..<br />

- Pao, E.M, Flehing, K.H., Guenther, P..M. et al. 1982. Foods<br />

commonly eateh by individuals: amount per day <strong>and</strong> per eating<br />

occasion- W.$. Department of Agriculture. Home Economics Report<br />

No. 4<strong>4.</strong><br />

Sedman, R. 1989. Development of Applied Action Levels for Soil<br />

Contact: A Scenario for the Exposure of Humans to Soils in a<br />

Residential Setting. Environmental Health Perspectives. VOl 79,<br />

pg 291-313.<br />

W.S. Bureau of Labor Statistics. 1990. Statistical summary:<br />

tenure with current employer as of January 1987. (transmitted<br />

via facsimile, Sept. 7, 1990).<br />

USDA., 1380. W.S. Department of Agriculture. Food <strong>and</strong> nutrient<br />

intakes of individuals in one day in the United States, Spring<br />

1977. Nationwide Food Consumption Survey 1977-19778. Preliminary<br />

Report No. 2 .<br />

U.S. EPA 1989.n Risk Assessment Guidance for SuPerfund: Human<br />

Health Evaluation Manual (Part A) , EPA/540/1-89-002. December<br />

1989.<br />

U.S. EPA 1989b. Review of the National Ambient Air Quality<br />

St<strong>and</strong>ards for 'Lead: Exposure Analysis Methodology <strong>and</strong> Validation.<br />

USEPA Office of Air Quality Planning <strong>and</strong> St<strong>and</strong>ards. EPA 450/2-<br />

es/oii.<br />

U.S. EPA 1990. Exposure Factors H<strong>and</strong>book. EPA/600/8-89-043.<br />

March 1990.<br />

U.S. €PA 1991. "Human Health Evaluation Manual, Supplemental<br />

Guidance: St<strong>and</strong>ard Default Exposure Factors". OSWER Directive<br />

9285.6-03. March 25, 1991.<br />

U.S. €PA 1992. "Guidance on Risk Characterization for Risk<br />

Managers <strong>and</strong> Risk Assessors. Memor<strong>and</strong>um from Henry Habicht to<br />

Assistant Administrators. Feb. 26, 1992


APPENDIX M<br />

SCREENING ECOLOGICAL RISK ASSESSMENT<br />

TABLES


Table 6.1. Toxicological benchmarla for screening contaminants of potential concern for efkctr on aquatic biota<br />

Estimated Estimated Estimated LCV I* Scnsitive<br />

LO"* uNSL EC,- Aquatic Lev'* Lev'* LCV'* EC,'* Species Test Population Secondary Secondary NAWQC'* NAWQC"<br />

Chemical CAS Number Daphnidt Fish Fish Masts Dapbnidi Fitb Invertebrata Daphnids EC,- EC,- Acute Values' Chronic Values Acute Chronic<br />

Aluminum 7429905 460 lpoo 1288 540 75 750 87<br />

Antimony 7440160 610 5400 IM)o 1900 79 985 104<br />

Arsenic 74403112<br />

Barium 7440391 5800 69 I 18<br />

Cadmium 7440439 2 0 I3 17 0 75 0013 41 1.9 I I<br />

Calcium 7440702 I IM)o<br />

Chloride 161187006<br />

Chmmium I8540299 2 6 132 73.18 05 0 266 I16 16 II<br />

Cobalt 7440484 5. I 290 44 3 98 195 106<br />

coppa 7440508 I 0.21 38 6.066 0 205 0 26 8.6 18 12<br />

Imn 743911% I58 1300 16 loo0<br />

Lud 7439921 500 12 26 I8 118 25 46 0 35 71 82 32<br />

Magnesium 7439954 82000<br />

Mang~!W 743996s I loo I 770 I 100 I12 1470 80 1<br />

Nickel 7440020 5 5 35 128 4 45 II 213 1400 I60<br />

Potassium 7440097 53000<br />

Selenium 7782492 100 91.65 118.32 23 260 260 15<br />

Siliean 7440213<br />

Silva 7440224 10 2.6 0 12 0 56 0 14 0 12 0 36 4 10<br />

Sodium 7440235 moo00<br />

Stmntium 7440246 42000 6100 620<br />

Thallium 7440280 100 130 57 64 67 164 180<br />

V<strong>and</strong>ium 7440622 940 80 410 12 284 19 I<br />

Zinc 7440666 10 46.71 36.41 5243 21 80 I20 I IO<br />

Chlomfonn 67661 4481 I240 ' $62 3360 I88<br />

Methylene Chloride 75092<br />

Toluene 108883 25229 1269 245000 200 1150 I76<br />

bii(2-Ethylhoyl)phLalate I17817 3 8.4 3 50 286 12 2<br />

cis4 . 2-Dichle<br />

I36592<br />

Ethylbenzene 100414 12922 438000 440 198 6970 189<br />

I - LCV - Lowest Chronic Value<br />

2 - EC" . Effective Conccnlrltion that a reduction of 20% of the gowrh prOhKtion m n<br />

3 - NAWQC -National Ambient Water Quality Criteria<br />

a - All toxicity value were cxtnaed fmm 'PC-Dam Buc: Screening Bmchmuiu fm Emlogical Risk Assessment (revised Dccanba 1994)'<br />

Environmental Sciences Division. Hulth Scienca Raurch Division, ORNL<br />

- - m toxicolagiul benchmark wu unavailable


Table 6.2. Toxicological benchmarks for screening contaminants of potential concern for effects on sediment-associated biota<br />

Effects Effects EPA I,'<br />

Chemical CAS Number Range Low ange Mcdiu OMOE '*' EPA *' Region V H&S '.' WIDNR "'<br />

Aluminum 7429905<br />

Arsenic<br />

7440382<br />

Barium<br />

7440393<br />

Beryllium<br />

7440417<br />

Calcium<br />

7440702<br />

Chromium<br />

I8540299<br />

Cobalt<br />

7440484<br />

Copper<br />

7440508<br />

Iron<br />

7439896<br />

Lead<br />

743992 I<br />

Magnesium<br />

7439954<br />

Manganese<br />

7439965<br />

Mercury<br />

7439976<br />

Nickel<br />

7440020<br />

Potassium<br />

7440097<br />

Selenium<br />

7782492<br />

Sodium<br />

7440235<br />

Vanadium<br />

7440622<br />

Zinc<br />

7440666<br />

Acetone<br />

6764 I<br />

Benzene<br />

71432<br />

bis(2-Ethylhexy1)phthalate<br />

1 I7817<br />

Di-n-butylphthalate<br />

84742<br />

Fluoranthene<br />

206440<br />

Phenanthrene<br />

85018<br />

Pyrcne 129000<br />

1 = OMOE - Ontario Ministry of the Environment<br />

2 = EPA - United States Environmental Protection Agency<br />

3 = H&S - Hull <strong>and</strong> Suter<br />

4 = WINDR - Wisconsin Division of Natural <strong>Resource</strong>s<br />

8.20E+00<br />

8. I OE+O 1<br />

3.40E+OI<br />

<strong>4.</strong>678+01<br />

1.50E-01<br />

2.1 OE+01<br />

1.50E+02<br />

7.00E+OI<br />

3.708+02<br />

2.708+02<br />

2.18E+02<br />

7.10E-01<br />

5. I6E+OI<br />

<strong>4.</strong>10E+02<br />

<strong>4.</strong>608+02<br />

I. 70E+04<br />

6.408-02<br />

5.208-02<br />

8.908+05<br />

<strong>4.</strong>2 I E+OI<br />

a =All toxicity values wen extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

- = no toxicological benchmark was unavailable<br />

5.00E+02


Table 63 Toxicological benchmarlo for screening contpmhwb of potential concern for<br />

effects on soil <strong>and</strong> Utter invertebmtes <strong>and</strong> hetertrophie proceaaca'<br />

Contaminant CAS ID Plants SoWerobes Enrthwom<br />

(mg/kg) (dG3) (mg/kg)<br />

91576<br />

99092<br />

50293<br />

83329<br />

208968<br />

67641<br />

120127<br />

11096825<br />

71432<br />

56553<br />

50328<br />

205992<br />

191242<br />

207089<br />

117817<br />

86748<br />

218019<br />

84742<br />

53703<br />

132649<br />

206440<br />

86737<br />

193395<br />

91203<br />

85018<br />

129000<br />

108883<br />

79016<br />

1330207<br />

7429905<br />

76644 17<br />

7440360<br />

7440382<br />

7440393<br />

7440417<br />

7440439<br />

7440702<br />

18540299<br />

7440484<br />

7440508<br />

57125<br />

7439896<br />

743992 1<br />

7439954<br />

7439965<br />

7439976<br />

7440020<br />

7440097<br />

7782492<br />

7440224<br />

7440235<br />

7440280<br />

#N/A<br />

#N/A<br />

MIA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

MIA<br />

MIA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

200<br />

#N/A<br />

#NIA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NIA<br />

#N/A<br />

200<br />

#N/A<br />

0<br />

50<br />

#N/A<br />

5<br />

10<br />

500<br />

10<br />

3<br />

#NIA<br />

1<br />

20<br />

100<br />

#N/A<br />

0<br />

50<br />

#N/A<br />

500<br />

0.3<br />

30<br />

#NIA<br />

1<br />

2<br />

#N/A<br />

1<br />

#N/A<br />

#N/A<br />

#NIA<br />

#NIA<br />

#N/A<br />

#NIA<br />

#N/A<br />

#NlA<br />

MIA<br />

#N/A<br />

#N/A<br />

#NlA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NIA<br />

#N/A<br />

#NlA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

MIA<br />

#N/A<br />

#N/A<br />

#NIA<br />

MIA<br />

6.00E+02<br />

MIA<br />

#N/A<br />

1 .OOE+02<br />

3.00E+03<br />

#N/A<br />

2.00E+01<br />

MIA<br />

1.00E+01<br />

1.00E+03<br />

1.00E+02<br />

#N/A<br />

2.OOEM2<br />

9.00E+02<br />

#NIA<br />

1.00E+02<br />

3. WE4 1<br />

9.00EMl<br />

#N/A<br />

1.00E+02<br />

5.0OEM1<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

MIA<br />

#NlA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NlA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NIA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

3.00E+0 1<br />

#N/A<br />

#N/A<br />

#N/A<br />

MIA<br />

#NlA<br />

#N/A<br />

#NIA<br />

#N/A<br />

#N/A<br />

#NIA<br />

6.00EM 1<br />

#N/A<br />

#NIA<br />

2.00EN 1<br />

#N/A<br />

<strong>4.</strong>00E-o 1<br />

#NIA<br />

5.00E+01<br />

#N/A<br />

#N/A<br />

5.00Ei-02<br />

#NIA<br />

#N/A<br />

1 .OOM1<br />

2.00E+02<br />

#N/A<br />

7.00E+01<br />

#NIA<br />

#N/A<br />

MIA


Table 6.3 (continued) Toxicologial benchmarks for screming contaminants of potential concern for<br />

efferts on roil <strong>and</strong> litter invertebmtea <strong>and</strong> hetertmphic prac-'<br />

Contaminant CAS ID Phts SoilMicroba Jhrthworms<br />

(mg/kP) (mg/kg) (mg/kg)<br />

V d U m 7440622 2 2.00E+01 #N/A<br />

Zinc 7440666 50 1 .OOE+O2 2.00E+02<br />

a - All benchmarks extract4 hm PC-Data Base: Screening benchmarks for ecolo@d risk ass*ismcnt<br />

Revised December 199<strong>4.</strong> Environmental Sciences Division & Health Scicnces Research Division,<br />

Oak Ridge National Labomtory.<br />

#NA = Benchmark not available.


Table 6.4 Todcologial bmchmnrlo for r c contaminants ~ of potential concern<br />

for effects on nildliTe'<br />

91576<br />

99092<br />

#NIA<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NfA<br />

#N/A<br />

50293<br />

83329<br />

208968<br />

1.586<br />

#N/A<br />

#NfA<br />

1.994<br />

#N/A<br />

#NfA<br />

2.262<br />

#N/A<br />

#N/A<br />

67641<br />

19.825<br />

2<strong>4.</strong>92<br />

#N/A<br />

120127<br />

MIA.<br />

#N/A<br />

#NfA<br />

11096825<br />

#N/A<br />

#NIA<br />

#N/A<br />

71432<br />

23.23<br />

29.201<br />

33.135<br />

56553<br />

50328<br />

#N/A<br />

0.88 I<br />

MIA<br />

1.108<br />

#NIA<br />

1.257<br />

205992<br />

191242<br />

207089<br />

117817<br />

#N/A<br />

#N/A<br />

#N/A<br />

16.154<br />

#N/A<br />

#N/A<br />

#N/A<br />

20.305<br />

#NIA<br />

#N/A<br />

#N/A<br />

23.041<br />

86748<br />

218019<br />

84742<br />

53703<br />

132649<br />

206440<br />

#N/A<br />

#N/A<br />

48<strong>4.</strong>699<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

609.274<br />

#N/A<br />

W A<br />

#NlA<br />

#N/A<br />

#NlA<br />

691.356<br />

#N/A<br />

#NIA<br />

#N/A<br />

86737<br />

193395<br />

91203<br />

85018<br />

#N/A<br />

#N/A<br />

UNIA<br />

#NIA<br />

MIA<br />

#NIA<br />

#N/A<br />

#N/A<br />

#NlA<br />

#N/A<br />

#N/A<br />

#N/A<br />

129000<br />

108883<br />

79016<br />

#N/A<br />

22.895<br />

0.617<br />

#N/A<br />

28.78<br />

0.175<br />

#N/A<br />

32.6J7<br />

0.88<br />

1330207<br />

7429905<br />

7664417<br />

7440360<br />

1.815<br />

1.701<br />

#NIA<br />

0.11<br />

2.282<br />

2.138<br />

W A<br />

0.138<br />

2.589<br />

2.426<br />

#N/A<br />

0.157<br />

7440382<br />

7440393<br />

7440417<br />

0.111<br />

10.777<br />

1.308<br />

0.14<br />

13.547<br />

1.645<br />

0.158<br />

15372<br />

1.866<br />

7440439<br />

7440702<br />

18540299<br />

7440484<br />

0.169<br />

MIA<br />

6.502<br />

#N/A<br />

0.212<br />

#NIA<br />

8.174<br />

MIA<br />

0.24<br />

#N/A<br />

9.275<br />

#N/A<br />

7440508<br />

32.826<br />

41.263<br />

46.822<br />

57125<br />

74398%<br />

12.547<br />

MIA<br />

15.772<br />

MIA<br />

17.897<br />

#N/A<br />

743992 1<br />

15.86<br />

19.936<br />

22.622<br />

7439954<br />

#N/A<br />

MIA<br />

#N/A


Table 6.4 (continued) Toxicological benchmnrh for screening conemirunts of potential concern<br />

for effects on nildlife'<br />

Madm White-footed Short-tailed<br />

Contaminant CAS ID vole^ Mouae' shrrn'<br />

Q<br />

(mgkz-d)<br />

Mang8tlCSC 7439965 17<strong>4.</strong>456 219.293 248.837<br />

Macury 7439976 0.013 0.016 0.018<br />

Nickel 7440020 79.298 99.679 113.108<br />

Potassium 7440097 MIA MIA MIA<br />

Selenium 7782492 0.066 0.083 0.094<br />

Silver 7440224 MIA #NlA #NIA<br />

SOdiUm 7440235 MIA MIA #NIA<br />

Thallium 7440280 0.015 . 0.019 0.021<br />

VaMdium 7440622 0.377 0.474 0.538<br />

Zinc 7440666 317.192 398.715 452.43<br />

1 = All benchrmuks e- from PC-Data Bsse: Smening benchnuuks for ecological risk .ssessnnd<br />

Revised Decemba 199<strong>4.</strong> Environmental Scimces Division & Health Sciences Rarearch Division,<br />

Oak Ridge National Laborrtory.<br />

2 = Value rrprcsad No Observed Advaac Effects Levels (NOAELP).<br />

#NA = Benchmark not available.


Table 6.5. Bioaccumulation factors<br />

Soil to Plant<br />

Plant-to-Meat<br />

Earthworm to<br />

BTF (wet wt.) BTF (wet wt.) Predator BTF (wet wt.) for Aquatic<br />

COPC CASNumbcr Kor [m] (daydig) Soum (days&) Source (day%)' Orgnnisnis'<br />

Aluminum 7429905 6.00E-04 [fl I.5OE-03 [i] 5.44842 I 4 na<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

CdTlium<br />

Calcium<br />

chromium VI<br />

Cobalt<br />

I4<br />

I 4<br />

I 4<br />

Id<br />

na<br />

COP<br />

If on<br />

Lead<br />

Magnesium<br />

Mangange<br />

Maw<br />

Nickel<br />

Potsssium<br />

Selenium<br />

Silver<br />

Sodium<br />

Thallium<br />

Tin<br />

Vanadium<br />

Zinc<br />

AcenaphthmC<br />

Acenaphthylene<br />

Acetone<br />

Anlhrscene<br />

Aroclor 1260<br />

Bm(a)anthracene<br />

Benzene<br />

Bcluo(a)pyrmc. 3,4-<br />

Bcmo(b)flmthene<br />

Bmo(g,h,i)pcrylcnc<br />

Benzo(k)flomanthme<br />

Bis(2-cthylh~l)atc<br />

chloroform<br />

7440360<br />

7440382<br />

7440393<br />

7440417<br />

7440439<br />

7440702<br />

18540299<br />

7440484<br />

7440508<br />

74398%<br />

7439921<br />

7786303<br />

7439965<br />

7439976<br />

7440020<br />

7447407<br />

7782492<br />

7440224<br />

7440235<br />

7440280<br />

74403 1 5<br />

7440622<br />

7440666<br />

208968<br />

208968<br />

67641<br />

120127<br />

11096825<br />

56553<br />

71432<br />

50328<br />

205992<br />

191242<br />

207089<br />

117817<br />

67663<br />

*<br />

*<br />

1.00E+04<br />

5 .O 1 E+03<br />

5.80E-0 I<br />

2.82E+04<br />

1.41E+07<br />

3.98E+05<br />

1.328+02<br />

l.l5E+06<br />

l.l5E+06<br />

<strong>4.</strong>00E+06<br />

1.15E+06<br />

<strong>4.</strong>10E+00<br />

9.33E+01<br />

fi]<br />

5.04E-05<br />

6.00E-03<br />

1 .OOE-02<br />

1.5OE-03<br />

8.25E-02<br />

5.25E-02<br />

3.75E-05<br />

5.408-03<br />

1.80E-02<br />

<strong>4.</strong>50E-05<br />

2.09E-04<br />

8.25842<br />

6.80E-02<br />

3.00E-01<br />

1.80E-02<br />

3.00E-01<br />

I .00E-01<br />

2.25E-02<br />

7.50E-03<br />

6.00E-05<br />

3.00E-01<br />

8.25E-04<br />

9.90E-02<br />

2.83E-02<br />

<strong>4.</strong>22E-02<br />

7.%E+OO<br />

1.56E-02<br />

<strong>4.</strong>28E-04<br />

3.37E-03<br />

3.45E-01<br />

1.82E-03<br />

1.82E-03<br />

8.87E-04<br />

1.82E-03<br />

2.57E4-00<br />

<strong>4.</strong>22E-01<br />

<strong>4.</strong>00E-05<br />

2.00E-03<br />

1.30E-05<br />

1.00E-03<br />

<strong>4.</strong>00E-04<br />

2.00E-03<br />

9.00E-03<br />

1.00E-04<br />

9.00E-03<br />

2.00E-02<br />

<strong>4.</strong>00E-04<br />

2.OOE-02<br />

5.00E-04<br />

1.00E-02<br />

5.208-03<br />

1.80E-02<br />

1.00E-01<br />

3.00E-03<br />

8.00E-02<br />

<strong>4.</strong>00E-02<br />

1 .OOE-02<br />

2.50E-03<br />

l.OOE-01<br />

2.51E-04<br />

I .26E-04<br />

1.46E-08<br />

7.08E-04<br />

3.5 4E-0 1<br />

I .OOE-02<br />

3.32E-06<br />

2.89E-02<br />

2.89E-02<br />

1.00E-01<br />

2.89842<br />

1.03E-07<br />

2.34E-06<br />

na<br />

1.46E-0 1<br />

3.768-02<br />

na<br />

7.36E-0 1<br />

na<br />

7.84E-02<br />

na<br />

8.32E-02<br />

6.OSE-02<br />

7.208-02<br />

8.48E-02<br />

6.40E-02<br />

1.54E-01<br />

6.568-02<br />

NI<br />

na<br />

na<br />

na<br />

na<br />

na<br />

na<br />

na<br />

<strong>4.</strong>80E-02<br />

<strong>4.</strong>85E-02<br />

<strong>4.</strong>85E-02<br />

5.12E-02<br />

<strong>4.</strong>85E-02<br />

<strong>4.</strong>32E-02<br />

<strong>4.</strong>85E-02<br />

5.44842<br />

3.36E-02<br />

2.40E-02<br />

3.36E-02<br />

<strong>4.</strong>85E-02<br />

<strong>4.</strong>85E-02<br />

BAF<br />

1.00E+00<br />

2.80E+02<br />

<strong>4.</strong>00E+00<br />

2.00E+00<br />

5.00E+01<br />

2.00E+02<br />

3.00E+02<br />

I 4 2.10E+02<br />

I 4 1 .OOE+O2<br />

14 3.00E+02<br />

I 4<br />

na<br />

I 4 <strong>4.</strong>00E+02<br />

I4 6.30E+04<br />

I 4 I .00E+02<br />

na<br />

8.00E+00<br />

2.00E+00<br />

1.00E+02<br />

1.00E+04<br />

na<br />

1.00E-02<br />

1.00E+03<br />

14 3.90E+02<br />

IYI na<br />

IYl 2.00E-01<br />

Izl na<br />

IYl<br />

na<br />

I 4<br />

na<br />

IYI<br />

na<br />

I 4 3.00E+01<br />

I 4<br />

na<br />

14 na<br />

I4<br />

na<br />

IYI 3. I OE+O2<br />

IY 1 6.00E+00


Table 6.5. Bioaccumulation factors (continued)<br />

Soil to Plant Plant-to-Meat Earthworm to BAF<br />

BTF (wet wt.) BTF (wet wt.) Predator BTF (wet wt.) for Aquatic<br />

COPC CASNumber Kow [ml (days&) Source (daydig) Source (day%)* Organisnisi<br />

chrysenc 218019 <strong>4.</strong>07E+05 3.32E-03 [a] 1.02E-02 [a] 7.04E-02 I4 na<br />

Dibcnzo(a, h)anhccne 53703 <strong>4.</strong>07E+05 3.328-03 [a] 1.02E-02 [a] 7.848-02 I4 na<br />

Dibenzofinnn I32649 1.30E+04 ti] 2.438-02 [a] 3.278-04 [a] <strong>4.</strong>85E-02 [Y I na<br />

Dibutylphthalate 84742 <strong>4.</strong>00E+05 3.36843 [a] l.OOE-02 [a] <strong>4.</strong>85E-02 [YI na<br />

Dichlmthanc, 1,l- 75343 6.17E+OI 5.36E-01 [a] 1.55E-06 [a] <strong>4.</strong>85E-02 [YI na<br />

Dichloroethylene. 1.1- 75354 6.92EMl 5.02E-01 [a] 1.748-06 [a] <strong>4.</strong>85E-02 [YI 7.00E+00<br />

Dichloroethylmc. I.2.C- 540590 7.90E+01 <strong>4.</strong>65E-01 [a] 1.988-06 [a1 <strong>4.</strong>85E-02 [YI 7.00E+00<br />

Dichlmthylmc. 1.2,T- 156605 3.02E+OO 3.07EMO [a] 7.598-08 lal <strong>4.</strong>85E-02 IYI 7.00E+00<br />

Fluoranthcne 206440 7.94E+04 8.55E-03 [a] 1.99E-03 Ial 5.928-02 [zl na<br />

Fluorene 86737 1.58E+04 2.17E-02 [a]<br />

3.97E-04 [a] 3.20E-02 [Zl na<br />

Indcno(l,2,3-CD)pyrene 193395 3.16E+06 1.02E-03 [a] 7.94E-02 lal 6.56842 I4 na<br />

Methylnaphthalene 91576 7.24E+03 3.418-02 [a] 1.82844 [a) 3.20E-02 14 na<br />

Naphthalene 91203 1.70E+03 7.89E-02 [a] <strong>4.</strong>27E-05 1.1 3.36E-02 I4 <strong>4.</strong>30E+02<br />

Phenanthrene 85018 2.888+04 1.54E-02 [a] 7.238-04 Ial <strong>4.</strong>48842 14 na<br />

129000 2.098+05 <strong>4.</strong>89E-03 [a] 5.25E-03 la1 6.24E-02 14 na<br />

Toluene 108883 5.37EM2 1.54E-01 [a] 1.35E-05 1.1 <strong>4.</strong>858-02 IYl 8.30E+01<br />

Trichlmthylcnc 79016 2.40Ei-02 2.45E-01 [a] 6.03E-06 [a] <strong>4.</strong>858-02 lYl 1.70E+01<br />

Xylcna (mixcd) 108383 1.82E+03 7.58E-02 [a] <strong>4.</strong>57E-05 Ial 2.88E-01 I4 3.208+02<br />

[a) Trnvia <strong>and</strong> Arms (1988). Plant BTF dcrivcd 6m regrauion quation: log(BTF) = 1.588-0.578 log(Kow) <strong>and</strong><br />

Converted to a wet weight bash .Mrming planta arc 85% water (USEPA 1993). Plant-to-meat BTF dcrivcd h<br />

regression equation: log(BTF) = log(Kow) - 7.6.<br />

[b] IAEA (1993). Original dish BTF converted to a wet weight basis assuming radish WM 91% water (IAEA 1993).<br />

[c] IAEA (1993). Plant type WM unspecified in IAEA (1993). Convcded BTF to wet weight basir assming plantr arc<br />

85% water (USEPA 1993).<br />

[dl IAEA (1993). Original grass BTF converted to a wet weight basis assuming gram is 90% walcr (IAEA 1993).<br />

[el NCRP (1989).<br />

[fl Baa et a!. (1984). Plant type wat unspecified in Baa et al.. Converted BTF to wet weight batis assuming plants.<br />

arc 85% wata (USEPA 1993).<br />

[g] IAEA (1993) value reported for plant-to-goat.<br />

[h] IAEA (1993) value reported for Pl~t-to-bC~f.<br />

[i] Baa et al. (1984) value rcportcd for plant-to-bccf.<br />

ti] Kow obtained 6om SupCmnd Chcmicd Data Uatrix (1993).<br />

[k] Kow obtained h Montgomery <strong>and</strong> Welkom (1990).


Table 6.5. Bioaccumulation factors (continued)<br />

[I] IAEA (1993). Original fodder BTF convetted to a wet weight basis assuming fodder WM 81% water (IAEA 1993).<br />

[m] Kow - Chemical specific octanol-water patition cocfiicimt obtained from chcmlib.dat, MEPAS 1/26/95.<br />

na = not available<br />

= not applicable<br />

[z] - Extracted from Beyer & Stafford (1993). Converted to wet weight basis assuming 84% water wnlcnt for earthworm (Sample & Sutcr, 1994).<br />

1 = Bamrhousc etd. 1988


Table 6.6. Species-specific exposure parameters for wildlife'<br />

Receptor Body Dietary Water Fraction Fraction Fraction<br />

Species Weight Ingestion Rate Ingestion Rate Soil Invertebrate Plant<br />

(kn) Wd) Wd)<br />

Meadow Vole 0.044 0.005 0.006 0.024 0 0.976<br />

Short-tailed Shrew 0.015 0.009 0.0033 0.13 0.87 0<br />

White-footed Mouse 0.022 0.0034 0.0066 0.01 0.49 0.5<br />

Belted Kingfisher 0.148 0.075 0.016 0 0 0<br />

a = Values extracted from Opresko et. al. 1995 (Revision). Toxicological Benchmarks for Wildlife.<br />

Risk Assessment Program. Lockheed-Martm Energy Systems, Inc. ES/ER/IhI-86/R2.


Table 6.7. Ecological hazard quotients for surface water-associated in the northhouth ditch psrallel to 4th street at PGDP, WAG 1, Fire Training Area (SWMU 100)<br />

Representative Eatinatd Eatimatd Eatinated LCV Ir Scndtive<br />

Commtntion LCV" LCVtC EC,& Aquatic LCV''. LCV'" EC," Specin Tnt Population Secondary Secondary NAWQC'" NAWQC"'<br />

Cbedcal (mJL) Daphnida Fiah nab Planla Daphnids Flsb Imvertebrata Daphnida EC," EC," Acute V~lua' Chronic Valun Acute Chronic<br />

Aluminum I22E+OI - 265E-02 6428-03 371E-03<br />

2 268-02 I 638-01<br />

Brium 116E-01 ZOOE-05 - I 68E-03 3 OSE-02<br />

1638-02 14OE-01<br />

Cdmium 1338-02 - 665E-03 887E-02 7828-03 1778-02 l.OZE+OO 309E-03 3 4lE-03 I21E-02<br />

Cddum 4 IOE+OI - 3S3E-04 -<br />

Chromium 6 09E-02 - 305E-02 993E-03 832E-04 122E-01 2298-01 I93E-04 3 81E-03 5 54E-03<br />

cobslt 3 208-03 - 627E-04 I IOE-05 7 27E-04 804804 1648-05 I OSE-03<br />

Copper 6 87EM - 687E-02 2998-01 I8lEM I13E-02 33SE-01 ZME-OI 7998-03 3 82E-03 5 738-03<br />

lrOn I34E+Ol - 848EM 103E-02 8 388-01 I 348-02<br />

tad I 568-02 - 3 128-05 1278-03 826E-04 613E-04 4 468-02 2 20E-04 I90E-04 4888-03<br />

Magnesium 5 17E+00 - 6308-05<br />

2 73E41 - 248E-04 I54E-04 2 48E-04 2448-03 1868-04 3 40E-03<br />

Nickel 1668-02 - 3328-03 3328-03 474E-04 I29E-04 3698-04 1518-03 7728-05<br />

Potauium 2 37E+00 - 4478-05<br />

Sodium 102E+OI I50E-05 -<br />

Vanadium I98E-02 - 2 IiE-05 248804 4 60E-05 6 19E-04 6 978-05 I 04E-03<br />

Zinc I44E-01 - 480E-03 308E-03 395E-03 275E-05 686E-03 I 80E-03 I 20E-03 I 3 I E-03<br />

Hazard Index IME-05 - I40E-01 4 98E-01 464EM I21E-02 1.34E+W l.'lSE+W I 728-02 I95E-03 3 60E-02 I 248-02 4 30E-02<br />

I - LCV -Lowest Chronic Vdw<br />

2 - Et? - Effective Concmtnh 'on that a reduction of 20% of the pwih pmduction occurs<br />

3 - NAWQC -National Ambient WUer Quality Critma<br />

a All toxicity values were extracted &om'PC-Data Base Screening Benchmarks for Ecological Risk Assessment (revised December 1994)'<br />

Environmental Sciences Division. Hdth Sciences Rerearch Division, ORNL<br />

Huard Quotients M unitlnr<br />

- - no( able to quantify because tnnsfn factor or toxicological benchmark was unavailable<br />

Bold Vdue indicates hazard quotient OT huvd index is veater than I<br />

I 19E-05<br />

I04E-04


~ ~~ -<br />

Table 6.8. Ecological baurd quotients for surface water-associated in the castlwcst ditch parallel to railroad tracks which intersect 4th street at PGDP, WAG I, Fire Training Area (SWMU 100)<br />

RcprntaUve Estimated Estimated Estimated LCV la Sensitive<br />

'<br />

CMcatmtion LO''* ECn- Aq.atlc LCV'" LCV"' LCV'* ECnL Spccia Tat Population Secondary Secondary NAWQC '" NAWQC'"<br />

Cbcmlc.l (mJL) Dapbnids Fib Flsb PIanb Dapbnids FM Iaverlebrata Dapbnlds ECnb ECna' Acute Vaiua. Cbronic Valua Acute Chronic<br />

Aluminum<br />

3 8IEiOO<br />

- 8.28E-03 20iE-03 I16E-03<br />

7068-03 508E-02<br />

5 OBE-03 4 388-02<br />

Anmic<br />

Barium<br />

I40E-03<br />

1378-01 2 36E-05<br />

1988-03 3 61 E-02<br />

Calcium<br />

Chromium<br />

5 98E+Oi<br />

8 8OE-03<br />

4 40E-03<br />

5 16E-04<br />

I44E-03 I2OEM<br />

I 768-02 3 3 I E-02 2 788-05<br />

5 SOE-04 8 WE-04<br />

COPW<br />

6 20E-03<br />

6 20E-03 2 70E-02 I 631-03 I OZE-03 3 02E-02 2 388-02 721864<br />

3 448-04 5 17E-04<br />

Iron<br />

4 MEiOO<br />

2 56E-02 3 I IE-03<br />

2 S3E-01<br />

4 04E-03<br />

Lud<br />

2 7lE-02<br />

5 42E-05 2 21E-03 I 44E-03 I06E-03<br />

7 748-02 3 828-04<br />

3 30E-04 8 478-03<br />

Magnesium<br />

I34E+OI<br />

163E-04<br />

M ~ g m 2 58E-01<br />

235EM I46EM<br />

23SE-00<br />

2 30E-03 I 76E-M 3 21E-03<br />

Potassium<br />

2 92EiOO<br />

5 5IE-05<br />

Sodium<br />

2 5OE+01 3 68E-05<br />

Vanadium<br />

4 20E-03<br />

4 478-06 5 25E-05<br />

9 778-06<br />

I31E-04 I48E-05 2 20E-M<br />

Zinc<br />

2 68EM<br />

8 93EM 574EM 7368-04 5 ilE-06 I 28E-03 3 35E-04 2238-04 2448-04<br />

Huurd Index 6 ME45 I 158-02 5 77E-02 7 238-03 2 09E-03 3 OIE-01 I 36E-01 3 90E-03 2 17E-03 3 958-02 I 4SE-03 I 41E-02<br />

I LCV la~nr<br />

Chronic Value<br />

2 - EC? - EfTcctive Concmtrmiim tha a reduction of 20% of the vow& production occurs<br />

3 - NAWQC - National Ambient Wder Quality Criteria<br />

a All toxicity dun were d htn 'PC-Dam Bue Screening Benchmarks for Ecological Risk Aueummt (revid Decemba 1994)'<br />

Environmental Sciences Division. Health Scienm Ruuch Divirim, ORNL<br />

* H d pwCienb re unitlm<br />

- - no( hie to quantify kuur transfer factor or toxicological bmchmark wu unavailable<br />

Bold Value indiatn haud quotient or h d index is pats thur I


Table 6.9. Ecological hazard quotients for sediment-associated in the northhouth ditch parallel to 4th street<br />

at PGDP, WAG 1, Fire Training Area (SWMU 100)<br />

Representative<br />

Concentration EKects EKects EPA<br />

Cht mica1 (mg/kg) Range Low Range Medium OMOE ” EPA ’*’ Region V H&S ’’ WIDNR ‘,’<br />

Aluminum<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Nickel<br />

Potassium<br />

Selenium<br />

Sodium<br />

Vanadium<br />

Zinc<br />

Acetone<br />

bis~2-Ethvlhexvl~ohthala~<br />

I .23E+04<br />

5.70E+00<br />

2.74E+02<br />

8.30E-01<br />

1.31E+04<br />

1.94E+O I<br />

I .64E+OI<br />

1.66E+01<br />

2.478+04<br />

I. I5E+OI<br />

2.348+03<br />

1.758+03<br />

I .47E+OI<br />

9.908+02<br />

1.60E-01<br />

I .35E+02<br />

3.94E+01<br />

I .63E+02<br />

1.90E-01<br />

I .30E-01<br />

6.958-01<br />

2.40E-01<br />

<strong>4.</strong>88E-01<br />

2.468-01<br />

7.00E-01<br />

1.09E+00<br />

8.14E-02<br />

5.248-02<br />

6.158-02<br />

5.288-02<br />

2.858-01<br />

3.988-01<br />

9.50E-0 1<br />

7.468-01<br />

3.80E+00<br />

1.45E+00<br />

2.97E+00<br />

I .46E-07<br />

5.488-01<br />

Hazard Index 3.46E+00 9.3 1E-01 S.SOE+OO 1.45E+00 2.97E+00 5.48E-01<br />

1 = OMOE - Ontario Ministry of the Environment<br />

2 = EPA - United States Environmental Protection Agency<br />

3 = H&S - Hull <strong>and</strong> Suter<br />

4 = WINDR - Wisconsin Division of Natural <strong>Resource</strong>s<br />

a = All toxicity values were extracted from ”PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)”<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

= Hazard Quotients arc unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.10. Ecological hazard quotients for sediment-associated organisms in the east ditch parallel to railroad tracks<br />

which intersect 4th street at PGDP, WAG 1, Fire Training Area (SWMU 100)<br />

Representativc<br />

Concentration EKects EKects EPA &'<br />

Chemical (mgkg) Range Low Range Medium OMOE '' EPA **' Region V H&S WIDNR '*'<br />

Aluminum 9.588+03<br />

Arsenic 5.20E+00 6.348-01 7.438-02 8.67E-01<br />

Barium<br />

Beryllium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

1.01 E+02<br />

6.40E-01<br />

2.06E+03<br />

3.00E+OI<br />

8.308+00<br />

3.70E-01 8.1 IE-02 l.lSE+OO<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Nickel<br />

1.04E+01 3.06E-01 3.858-02<br />

I .69E+04 9.948-01<br />

I .01 E+OI 2.16E-01 <strong>4.</strong>638-02<br />

1.448+03<br />

7.14E+02<br />

1.55E+00<br />

I.OIE+OI <strong>4.</strong>81E-01 I .96E-01<br />

Potassium 5.638+02<br />

Selenium<br />

2.00E-01<br />

Sodium<br />

I .26E+02<br />

Vanadium<br />

2.46E+Ol<br />

Zinc 3.898+01 2.598-01 9.498-02<br />

Acetone 3.808-02 5.94E-01<br />

2.02E-0 1<br />

Hazard Index 2.27E+00 5.3 IE-01 3.57E+00 9.94E-01 5.948-01 2.02E-01<br />

1 = OMOE - Ontario Ministry of the Environment<br />

2 = EPA - United States Environmental Protection Agency<br />

3 = H&S - Hull <strong>and</strong> Suter<br />

4 = WINDR - Wisconsin Division of Natural <strong>Resource</strong>s<br />

a = All toxicity values wen extracted from "E-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

= Hazard Quotients are unitless<br />

- - not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is gnatcr than I.


Table 6.1 1 Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 1, Fire Training Area (SWMU 100)<br />

Rcprcscnta tivc<br />

Concen tration<br />

Soil<br />

Chcmical (mg/lrL!) Plants Microbes Earthworms<br />

Aluminum<br />

Ammonia as Nitrogen<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

Copper<br />

Cyanide<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Mercury<br />

Nickel<br />

Potassium<br />

Selenium<br />

Sodium<br />

Vanadium<br />

Zinc<br />

8.39E+03<br />

7.90E+00<br />

I .39E+00<br />

5.638+00<br />

1.03E+02<br />

<strong>4.</strong>348-01<br />

I .5 I E-01<br />

7.22E+04<br />

I. 10E+OI<br />

6.548+00<br />

8.7 I E+OO<br />

3.20E-01<br />

I .27E+04<br />

1.74E+01<br />

1.64E+03<br />

7.408+02<br />

1.33E-01<br />

8. I7E+00<br />

<strong>4.</strong>868+02<br />

<strong>4.</strong>678-01<br />

1.54E+02<br />

2.36E+OI<br />

2.89E+O I<br />

236E+02<br />

3.40E-01<br />

9.50E-01<br />

3.12E-01<br />

S.00E-02<br />

1.13E-01<br />

1.54E+01<br />

5.60E-0 I<br />

9.60E-02<br />

7.58E-01<br />

2.24E+00<br />

8.678-0 I<br />

3.80E-01<br />

6.60E-0 I<br />

1.59E+01<br />

7.948-01<br />

1.97E+01<br />

9.50E-02<br />

5.208-02<br />

I .70E-02<br />

1.54E+00<br />

I.12E-02<br />

9.608-02<br />

7.80E+01<br />

<strong>4.</strong>2 I E62<br />

1.12E+01<br />

8.67843<br />

I .27E-01<br />

6.608-03<br />

1.59E+00<br />

3.97E-01<br />

1.58E-01<br />

I .70E-02<br />

3.85E+01<br />

I .92E-01<br />

7.588-02<br />

2.60E+00<br />

5.70E-02<br />

9.43E-03<br />

1.99E-01<br />

3-Nitroaniline<br />

Acetone<br />

Di-n-butylphthalate<br />

Toluene<br />

8.10E-02<br />

3.20E-02<br />

2.1 BE-01<br />

1.00E-03<br />

2.55E-03<br />

5.00E-06<br />

Xylene<br />

3.00E-03<br />

Hazard Index 2.75E+O2 1.13E+02 <strong>4.</strong>18E+01<br />

a = All toxicity values were extracted fiom "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

= Hazard Quotients arc unitless<br />

- = not able to quanti@ because transfer factor or toxicological benchmark wm unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.12 Ecological bazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 1, Fire Training Area (SWMU 100)<br />

Rcprcsentattvc Meadow Vole ' White-footed Mouse ' Short-tailed Shrew '<br />

Conccntratlon DaUyIntnke MMEL' Hwrd DnUyIntPkc NOAEL' H w d DdyIntnkr NOAELb H~znrd<br />

Ammonia as Nitrogen<br />

Antimony<br />

7.90E+00<br />

1.39E+00<br />

#N/A<br />

3.80E-03<br />

#N/A<br />

l.lOE-O1 3.45E-02<br />

#N/A<br />

2.15E-03<br />

Arsenic<br />

5.63E+00 1.91E-02 l.llE-01 1.72E-01 7.34E-02<br />

Barium<br />

1.03E+02 3.95E-01 1.08E+01 3.6733-02 6.88E-01<br />

&rytlium<br />

<strong>4.</strong>34E-01 1.26E-03 1.31E+00 9.60E-04 7.2 1E-04<br />

Cadmium<br />

1.51E-Ol 1.798-03 1.69E-01 1.06E-02 9.61E-03<br />

Calcium<br />

Chium<br />

7.228+04<br />

l.IOE+Ol<br />

#N/A<br />

3.00E-02<br />

#N/A<br />

6.50E+00 <strong>4.</strong>62843<br />

#N/A<br />

8.23E-02<br />

Cobalt<br />

copper<br />

6.54E+00<br />

8.71 E+OO<br />

2.18E-02<br />

<strong>4.</strong>11E-02<br />

#N/A<br />

3.28E+01 1.25E-03<br />

1.28E-02<br />

8.05E-02<br />

cyanids<br />

3.20E-01 2.89E-0 I 1.25E+01 2.30E-02 2.02E-01<br />

Iron<br />

Lead<br />

I .27E+04<br />

1.74E+01<br />

#N/A<br />

<strong>4.</strong>79E-02<br />

#N/A<br />

1.59E+01 3.02E-03<br />

#NIA<br />

1.22E-01<br />

Magnesium<br />

Manganese<br />

I .64E+03<br />

7.40E+02<br />

#NIA<br />

7.60E+00<br />

#N/A<br />

1.74E+02 <strong>4.</strong>36E-02<br />

#NlA<br />

8.62E+00<br />

Mercury<br />

1.33E-01<br />

<strong>4.</strong>79E-03 1.30E-02 3.68E-01 <strong>4.</strong>84E-03<br />

Nickel<br />

8.17EMO 3.86842 7.93E+01 <strong>4.</strong>87E-04 6.468-02<br />

Potassium<br />

Selenium<br />

<strong>4.</strong>868+02<br />

<strong>4.</strong>67E-O 1<br />

#N/A<br />

6.45E-03<br />

#N/A<br />

6.60E-02 9.78E-02<br />

#N/A<br />

<strong>4.</strong>33E-03<br />

Sodium<br />

Vanadium<br />

1.54E+02<br />

2.368+01<br />

5.48E-01<br />

6.658-02<br />

#NIA<br />

3.77E-01 1.76E-01<br />

3.27E-01<br />

3.80E-02<br />

Zinc<br />

2.89E+OI 3.96841 3.17E+02 1.25E-03 2.66E-01<br />

3-Nitromilinc<br />

Acetone<br />

8.10E-02<br />

3.20E-02<br />

#N/A<br />

2.83E-02<br />

#N/A<br />

1.98E+O1 1.43E-03<br />

#N/A<br />

1.98E-02<br />

Di-n-but ylphthalate<br />

2.18E-01 6.763-04 <strong>4.</strong>85E+02 1.39E-06 1.19E-03<br />

Toluene<br />

I .00E-03 1.98E-05 2.29E+OI 8.63E-07 1.71E-05<br />

Xylene 3.00E-03 #N/A 1.82E+00 #N/A<br />

#N/A<br />

1.38E-01 3.568-02<br />

1.40E-01 5.24E-01<br />

1.35E+01 5.08E-02<br />

1.65E+00 <strong>4.</strong>38E-04<br />

2.12E-01 <strong>4.</strong>53842<br />

#N/A<br />

8.17E+00 1.01E-02<br />

#N/A<br />

<strong>4.</strong>13E+O 1 1.95E-03<br />

1.58E+Ol 1.28E-02<br />

#N/A<br />

1.99E+01 6.12E-03<br />

#N/A<br />

2.19E+02 3.93E-02<br />

1.60E-02 3.02E-01<br />

9.97E+01 6.48844<br />

#N/A<br />

8.30E-02 5.22E-02<br />

#N/A<br />

<strong>4.</strong>74E-0 1 8.01 E-02<br />

3.99E+02 6.67E-04<br />

#N/A<br />

2.49E+01 7.96E-04<br />

6.09E+02 1.968-06<br />

2.88E+OI 5.93E-07<br />

2.28E+00<br />

#N/A<br />

1.08E-01<br />

8.678-01<br />

1. I lE+O 1<br />

3.39E-02<br />

6.988-02<br />

#N/A<br />

I .31 E+OO<br />

5.1 OE-01<br />

1.06E+00<br />

3.31E-02<br />

#N/A<br />

2.0 I E+OO<br />

#N/A<br />

8.24E+01<br />

2.10E-02<br />

9.17E-0 1<br />

#N/A<br />

3.64842<br />

1.20E+01<br />

1.84E+00<br />

2.25E+00<br />

#N/A<br />

3.31E-03<br />

2.25E-02<br />

1.03E-04<br />

#N/A<br />

#N/A<br />

1.57E-01<br />

1 S8E-0 1<br />

1.54E+01<br />

1.87E+00<br />

2.40E-01<br />

#NIA<br />

9.28E+00<br />

#N/A<br />

<strong>4.</strong>68E+01<br />

1.79E+O I<br />

#N/A<br />

2.26E+01<br />

#N/A<br />

2.498+02<br />

1.80E-02<br />

1.13E+02<br />

#N/A<br />

9.40E-02<br />

#NIA<br />

5.38E-01<br />

<strong>4.</strong>52E+02<br />

#N/A<br />

#N/A<br />

6.91 E+O2<br />

3.27E+01<br />

2.59E+00<br />

6.91E-01<br />

5.49E+OO<br />

7.24E-0 I<br />

1.8 1E-02<br />

2.9 1 E-0 1<br />

1.4 1E-0 1<br />

2.26E-02<br />

3.85E-03<br />

8.89E-02<br />

3.3 1 E-0 1<br />

l.l7E+OO<br />

8.11E-03<br />

3.88E-01<br />

3.42E+OO<br />

<strong>4.</strong>98E-03<br />

3.26E-05<br />

3.16E-06<br />

Hazard Index 1.44E+O1 2.30E+01 3.72E+02<br />

a = All toxicity vduu were eldraded from "PC-Data Base: Scmning Bench& for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

b = NOAEL - NO Advn~e Ef' Level<br />

= Hazard Quotients are unitless<br />

- = not able to quantify because transfa factor or to~wlogical benchmark was unavailable<br />

Bold Value indicatu hazard quotient or hazard index is greater than 1.


Table 6.13. Ecological hazard quotients for plants, soil, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 7, Underground Storage Tanks (SWMU132)<br />

Representative<br />

Concentration<br />

Soil<br />

Chemical (me/kel Plants a Microbes Earthworms<br />

Lead 1.38E+02 2.76M00 1.53E-01 2.768-0 1<br />

Di-n-butylphthalate 3.30E-01 1.65E-03<br />

bis(2-Ethy lhexy l)phthalate<br />

m,p-Xylenes<br />

0-Xylene<br />

2.30E-01<br />

3.00E-03<br />

2.00E-03<br />

Hazard Index 2.76&+00 1.53E-01 2.76E-0 1<br />

a = All toxicity values wen extracted fiom “PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)”<br />

Environmental Sciences Division. Health Sciences Research Division, ORNL<br />

* = Hazard Quotients arc unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.1<strong>4.</strong> Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 7, Underground Storage Tanks (SWMU132)<br />

Repmenhtkc Meadow Vole a White-footed Mouse Short-hUed S hm<br />

Concentration DdyInWrc NOAEL‘ Hsvrd DnilyIn@ke NOAEL’ Hazard Dallylntake NOAEL’ Hazard<br />

chemled (msny) (mrW (mgW Quotients (mg/Lb) (wflts) Quotients (mgkg) (nigh) Quotients<br />

Lead 1.38Ea2 3.80E-01 1.59E+01 2.39E-02 9.68E-01 1.99E+OI <strong>4.</strong>86E-02 1.60E+01 2.26E+Ol 7.OSE-01<br />

Di-n-butylphthalate 3.30E-01 1.02E-03 <strong>4.</strong>8SE+02 2.11E-06 1.81E-03 6.09E+02 2.97E-06 3.418-02 6.91E+02 <strong>4.</strong>93E-05<br />

bis(2-Ethylhexyl)ate 2.30E-01 6.628-02 1.62E+01 <strong>4.</strong>10E-03 <strong>4.</strong>69E-02 2.03E+OI 2.3 1 E-03 2.38E-02 2.30E+01 1.03E-03<br />

nsPxYlmes 3.00E-03 3.34E-05 #NIA 8.76E-05 #N/A 6.8SE-04 #N/A<br />

0-Xylene 2.00E-03 #NIA #N/A #N/A #N/A #N/A #N/A<br />

Hazard lndex 2.80E-02 S.09E-02 7.06E-01<br />

a = All toxicity values wen extracted !?om“PC-Data Base: Screening hchmarks for Ecological Risk Assessment (revised December 1994)”<br />

Emironmental Sciences Division, Health Scimces Research Division, ORNL<br />

b = NOAEL -NO Advmc E5& Level<br />

= Hazard Quotimds are unitlas<br />

#N/A 01 - = not able to quanti@ because truufa factor or toxicological benchmark was unavailable


Table 6.15. Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 7, Undergound Storage Tanks (SWMU 133)<br />

Representative<br />

Concentration<br />

Chemical (mg/kg) Plrnb Microbes ’ Earthworms ’<br />

Ammonia as Nitrogen<br />

<strong>4.</strong>10E+00<br />

Lead<br />

Acenaphthene<br />

Accnaphthylenc<br />

Anthracene<br />

Benzo(a)anthraccnc<br />

Benzo(a)p yrenc<br />

Bcnzo(b)fluoranthenc<br />

Benzo(g,h,i)perylene<br />

Benzo(k)fluoranthenc<br />

Carbazole<br />

Chrysenc<br />

Di-n-butylphthalate<br />

Dibenzo(qh)anthracenc<br />

Fluoranthene<br />

Fluorene<br />

Indene( 1.2f-cd)pyrene<br />

Phenanthrene<br />

Pyrene<br />

bis(2-Ethyl hexy1)phthalate<br />

1.628+02<br />

3.00E-01<br />

6.60E-01<br />

9.00E-0 I<br />

5.20E+00<br />

3.90E+00<br />

<strong>4.</strong>20E+00<br />

2.30E+00<br />

3.50E+00<br />

3 .OOE-01<br />

6.20E+00<br />

I .60E-0I<br />

2.50E-01<br />

8.50E+00<br />

2.30E-01<br />

1.90E+00<br />

<strong>4.</strong>70E+00<br />

9.40E+00<br />

2.10E-01<br />

334E+00<br />

8.00E-04<br />

Soil<br />

I .80E-01 3.24841<br />

7.67E-03<br />

Hazard Index 3.24E+00 I .80E-01 3.32E-01<br />

a = All toxicity values were extracted from “PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)”<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL.<br />

* =Hazard Quotients arc unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.16. Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 7, Undergound Storage Tanks (SWMU 133)<br />

Rcpmcntativc Meadow Vole ’ Whltc-footed Mouse Short-tailed Shrew ‘<br />

Conccntrntlon DaUy Intake NOAEL ’ H.zPrd DaUy Intake NOAEL ’ Hazard Daily lntnke NOAEL’ Hazard<br />

ChrmlCd (mgnc6) (mrk) (mgnc6) Quotients (m&) (mEkg) Quotients (Wnc6) (mgkg) Quotients<br />

<strong>4.</strong>1 OE+OO<br />

1.62E+02<br />

3.00E-01<br />

6.60E-01<br />

9.00E-01<br />

5.20E+00<br />

3.90E+00<br />

<strong>4.</strong>20E+00<br />

2.30E+00<br />

3.50E+00<br />

3.00E-0 I<br />

6.20E+00<br />

1.60E-O 1<br />

2.50E-01<br />

8.50EdO<br />

2.30E-01<br />

1.90E+00<br />

<strong>4.</strong>70E+00<br />

9.40E+00<br />

#N/A<br />

<strong>4.</strong>46E-01<br />

#N/A<br />

3.87E-03<br />

<strong>4.</strong>01 E-03<br />

1.61E-02<br />

1.14E-02<br />

1.23E-02<br />

6.50E-03<br />

1.03E-02<br />

#N/A<br />

1.92E-02<br />

<strong>4.</strong>96E-04<br />

7.74E-04<br />

3.12342<br />

1. I8E-03<br />

5.40E-03<br />

2.08E-02<br />

3.07E-02<br />

#N/A<br />

1.59E+Ol<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

8.81 E-0 1<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

<strong>4.</strong>85E+02<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

2.81E-02<br />

1.30E-02<br />

1.02E-06<br />

#N/A<br />

1.14E+00<br />

#N/A<br />

<strong>4.</strong>86E-03<br />

5.96E-03<br />

2.64E-02<br />

2.26E-02<br />

1.788-02<br />

7.89E-03<br />

1.48E-02<br />

#N/A<br />

<strong>4.</strong>42E-02<br />

8.76E-04<br />

1.93E-03<br />

5.69E-02<br />

1.30E-03<br />

1.2SE-02<br />

2.88842<br />

6.25E-02<br />

#N/A<br />

1.99E+Ol<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

l.llE+OO<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NIA<br />

6.09E+02<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

5.70E-02<br />

2.04E-02<br />

1.44E-06<br />

.-<br />

#N/A<br />

1.87E+01<br />

#N/A<br />

6.80E-02<br />

9.43E-02<br />

5.23E-01<br />

<strong>4.</strong>15E-01<br />

<strong>4.</strong>01 E-01<br />

2.08E-01<br />

3.34E-01<br />

#N/A<br />

7.11E-01<br />

1.6SE-02<br />

2.97E-02<br />

9.26E-01<br />

2.18E-02<br />

2.13E-01<br />

<strong>4.</strong>778-0 I<br />

1.04E+00<br />

#N/A<br />

2.26E+01<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

1.26E+00<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

6.91E+02<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

8.28E-01<br />

3.30E-01<br />

2.39E-OS<br />

bis(2-Ethylhexyl)phihdats 2.10E-01 6.04E-02 1.62E+01 3.74E-03 <strong>4.</strong>28E-02 2.03E+01 2.11E-03 2.17E-02 2.30E+01 9.42E-04<br />

Hazard Index <strong>4.</strong>48E-02 7.9SE-02 1.16E+00<br />

a = All toxicity values were extracted fiom “PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)”<br />

Environmental Sciemxs Division, Health Sciences R*learch Division, ORNL<br />

b = NOAEL - NO Adverse E ffd Level<br />

= Hazard Quotients arc ~ Ntles~<br />

#N/A or - = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is pter than 1.


Table 6.17; Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 7, Underground Storage Tanks (SWMU 134)<br />

Representative<br />

Concentration<br />

Chemical (mgkg) Plants a Microbes Earthworms<br />

Lead 1.50EMI 3.00E-01 1.67E-02 3.00E-02<br />

Benzo(a)anthracenc<br />

1.40E-01<br />

Benzo(a)pynne<br />

1.40E-01<br />

Bcnzo(b)fluoranthenc<br />

2.1 OE-0 I<br />

Bcnzo(g,h,i)pcrylene 7.208-02<br />

Bcnzo(k)fluoranthene<br />

Carbazole<br />

7.90E-02<br />

1. I OE-0 I<br />

Chrysene<br />

1.70E-01<br />

Di-n-buty lphthalate 5.50E-01 2.758-03<br />

Fluoranthenc<br />

<strong>4.</strong>50E-01<br />

Indeno( I ,2,3-cd)pynnc 7.908-02<br />

Phenanthnne<br />

2.60E-0 I<br />

Pynnc 3.30E-01<br />

Soil<br />

Hazard Index 3.03E-01 1.678-02 3.00E-02<br />

a = All toxicity values wen extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research- Division, ORNL<br />

= Hazard Quotients arc unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable


Table 6.18. Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 7, Underground Storage Tanks (SWMU 134)<br />

Repnsentative Meadow Vole ' White-footed Mouse ' Short-Med S hm '<br />

Concentration DnUy Intake NOAEL' Hazard DPUy Intake NOAEL ' Hazard DailyIntake NOAEL' Hazard<br />

Chemled (wk) mny) (m&) Quotients (ww (mgkg) Quotients (W/kg) (mg/kg) Quotients<br />

Lead 1.50EMI <strong>4.</strong>13E-02 1.59EM1 2.60E-03 1 .OSE-Ol 1.99E+01 5.28E-03 1.73E+00 2.26E+01<br />

Bmzo(a)anthracene<br />

ho(a)Wrme<br />

Bmzo(b)fluoranthene<br />

&nzo(g,h.i)perylene<br />

Bcnzo(k)fluoranthms<br />

Carbazole<br />

chryrme<br />

Di-n-butylphthalate<br />

Fluoranthene<br />

Indmo(l,2J-cd)pyrene<br />

Phmuahrens<br />

1.40E-01<br />

1.40E-01<br />

2.1 OE-0 I<br />

7.20E-02<br />

7.90E-02<br />

l.lOE-O1<br />

1.70E-0 I<br />

5.5OE-01<br />

<strong>4.</strong>50E-01<br />

7.90E-02<br />

2.60E-0 I<br />

<strong>4.</strong>34E-04<br />

<strong>4.</strong>10E-04<br />

6.15E-04<br />

2.03E-04<br />

2.31E-04<br />

#NIA<br />

5.26E-04<br />

1.70E-03<br />

1.65E-03<br />

2.24E-04<br />

1.15E-03<br />

#N/A<br />

8.8 I E4 1<br />

#N/A<br />

#NIA<br />

#N/A<br />

#N/A<br />

#N/A<br />

<strong>4.</strong>85EM2<br />

#NIA<br />

#N/A<br />

#N/A<br />

<strong>4.</strong>66E-04<br />

3.52E-06<br />

7.11 E-04<br />

8.13344<br />

8.88E-04<br />

2.47E-04<br />

3.348-04<br />

#N/A<br />

I .2lE-03<br />

3.01 E-03<br />

3.01E-03<br />

5.21E-04<br />

1.59E-03<br />

#N/A<br />

I.llE+OO<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NIA<br />

6.098+02<br />

#NIA<br />

#NIA<br />

#N/A<br />

7.34E-04<br />

<strong>4.</strong>94E-06<br />

1.41E-02<br />

1.49E-02<br />

2.01E-02<br />

6.52E-03<br />

7.55 E-03<br />

#N/A<br />

1.95E-02<br />

5.68E-02<br />

<strong>4.</strong>90E-02<br />

8.878-03<br />

2.64E-02<br />

#NIA<br />

1.26E+00<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

6.91E+02<br />

#N/A<br />

#N/A<br />

#NIA<br />

4?ene<br />

3.30E-01 1.08E-03 #N/A 2.19E-03 #N/A 3.65E-02 #N/A<br />

Hazard Index 3.07E-03 6.02E-03 8.868-02<br />

a = All toxicity values werc extracted fiom "PC-Data Base: Screening Benchmarlo for Ecological Risk Assessmmt (revised December 1994)"<br />

Environmental Sciencw Division, Health Scimces Research Division, ORNL<br />

b = NOAEL - No Advem Effeds Level<br />

= Hazard Quotients are unitless<br />

#N/A or - = not able to quantify because transfer factor or tolriwlogical benchmark was unavailable<br />

7.66E-02<br />

1.19E-02<br />

8.22E-05


Table 6.19. Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 1, TCE Spill Site (SWMU 136)<br />

Reprcsen t i tive<br />

Concentration<br />

Soil<br />

Chemical (mgkg) Plants Microbes Earthworms<br />

Aluminum 7.248+03 1.45E+02 1.21 E+01<br />

Ammonia as Nitrogen<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

9.90E-01<br />

1.70E+00<br />

6. I OE+OO<br />

7.248+01<br />

<strong>4.</strong>30E-01<br />

2.60E-01<br />

2.58E+04<br />

2.90E+O I<br />

2.70E+01<br />

3.40E-01<br />

6.10E-01<br />

1.45E-01<br />

<strong>4.</strong>308-02<br />

8.67842<br />

2.90E+01<br />

6.10E-02<br />

2.41E-02<br />

1.30E-02<br />

2.90E+00<br />

1.02E-01<br />

1.30E-02<br />

7.25E+01<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Nickel<br />

Potassium<br />

Sodium<br />

Sulfate<br />

Thallium<br />

Vanadium<br />

Zinc<br />

Benzene<br />

Benzo(a)anthraccnc<br />

Benzo(a)pyrcne<br />

Benzo(b)fluoranthcnc<br />

Benzo(g,h,i)perylene<br />

6.00E+00<br />

2.13E+04<br />

6.508+00<br />

6.038+02<br />

8.56E+02<br />

7.70E+00<br />

2.788+02<br />

8.678+01<br />

9.728+02<br />

1.40E-01<br />

2.43E+OI<br />

2.14E+O I<br />

2.00E-03<br />

3.80E-01<br />

5.2OE-Ol<br />

6.40E-01<br />

2.70E-01<br />

1.35E+00 2.708-02<br />

6.00E-02 6.00E-02<br />

1.07E+02<br />

I .30E-01 7.228-03<br />

1.71E+00<br />

2.57E-01<br />

I .40E-01<br />

l.22E+01<br />

<strong>4.</strong>28E-01<br />

8.56E+00<br />

8.56E-02<br />

1.22E+00<br />

2.14E-01<br />

I .20E-01<br />

1.30E-02<br />

3.858-02<br />

1.07E-01


Table 6.19. Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 1, TCE Spill Site (SWMU 136) (continued)<br />

Represen tathe<br />

Concentration<br />

Chemical (mg/kg) Plants Mieroba ' Earthworms '<br />

Benzo(k)fluoranthene<br />

2.30E-01<br />

Chrysene<br />

<strong>4.</strong>50E-01<br />

Di-n-butyl phthalate 2.2OE-01 l.lOE-03<br />

Dibenzo(a,h)anthracene<br />

Fluoranthene<br />

Indeno(l,2,3cd)pyrene<br />

Phenanthrene<br />

Pyrene<br />

Trichloroethene<br />

8.10E-02<br />

3.40E-01<br />

3.1 OE-01<br />

7.908-02<br />

2.80E-0 1<br />

<strong>4.</strong>00E-03<br />

Soil<br />

Hazard Index 1.91E+02 1.32E+O2 7.29E+01<br />

a = All toxicity values were extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division. ORNL<br />

* = Hazard Quotients arc unitless<br />

- =not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than I.


Table 6.20. Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 1, TCE Spill Site (SWMU 136)<br />

Representative Meadow Vole ' White-footed Mouse '<br />

Short-tailed Shrew<br />

Concentration DaUy InW NOAEL ' Hazard DdyIntakc NOAEL' Hazard DaUy Intake NOAEL' Hazard<br />

chemical (W/kb) (mak) (mmW Quotients (mmkg) (mgkg) Quotients (wkg) (mgkg) Quotients<br />

Aluminum<br />

Ammonia (u Nitrogen<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Nickel<br />

Potassium<br />

Sodium<br />

Sulfate<br />

Thallium<br />

Vanadium<br />

zinc<br />

Bcnzene<br />

Benzo(a)anthracene<br />

Benzo(a)pyrcne<br />

Bcnzo@)fluoranthene<br />

Bcnzo(&i)perylene<br />

7.24E+03<br />

9.90E-01<br />

1.70E+00<br />

6.10E+00<br />

7.24E+01<br />

<strong>4.</strong>30E-01<br />

2.60E-01<br />

2.58E+04<br />

2.90E+01<br />

2.70E+01<br />

6.00E+00<br />

2.13EM4<br />

6.5OE+00<br />

6.03E+02<br />

8.56E+02<br />

7.70E+00<br />

2.78EM2<br />

8.67E+01<br />

9.72E+02<br />

1.40E-01<br />

2.43E+01<br />

2.14E+01<br />

2.00E-03<br />

3.80E-01<br />

5.20E-01<br />

6.40E-01<br />

2.70E-01<br />

2.OZE+01<br />

#N/A<br />

<strong>4.</strong>65843<br />

2.07E-02<br />

2.78E-01<br />

1.24E-03<br />

3.09E-03<br />

#N/A<br />

7.92E-02<br />

8.98E-02<br />

2.83E-02<br />

#N/A<br />

1.798-02<br />

#N/A<br />

8.79E+00<br />

3.648-02<br />

#N/A<br />

3.09E-01<br />

#N/A<br />

3.83E-04<br />

6.85842<br />

2.93E-01<br />

8.21 E-05<br />

1.18E-03<br />

1.52E-03<br />

1.87E-03<br />

7.63E-04<br />

1.70Ei-00<br />

#NIA<br />

1.10E-0 I<br />

1.1 I E-01<br />

1.08E+01<br />

I .31 E+OO<br />

1.69E-01<br />

#N/A<br />

6.50E+00<br />

#N/A<br />

3.28E+01<br />

#N/A<br />

1.59E+Ol<br />

#N/A<br />

1.74E+02<br />

7.93E+Ol<br />

#N/A<br />

#N/A<br />

#N/A<br />

1.5OE-02<br />

3.77E-01<br />

3.17E+02<br />

2.32E+01<br />

#N/A<br />

8.8 IE-0 1<br />

#N/A<br />

#N/A<br />

1.19EMI<br />

<strong>4.</strong>22E-02<br />

1.86E-01<br />

2.58E-02<br />

9.51 E-04<br />

1.83E-02<br />

1.22E-02<br />

8.63E-04<br />

1.13E-03<br />

5.04E-02<br />

<strong>4.</strong>59E-04<br />

2.55E-02<br />

1.82E-01<br />

9.25E-04<br />

3.53E-06<br />

1.73E-03<br />

<strong>4.</strong>14E+01<br />

#N/A<br />

2.63E-03<br />

7.95E-02<br />

<strong>4.</strong>84E-01<br />

7.14E-04<br />

I .66E-02<br />

#N/A<br />

2.17E-0 I<br />

5.30E-02<br />

5.54E-02<br />

#N/A<br />

<strong>4.</strong>56E-02<br />

#N/A<br />

9.978+00<br />

6.09E-02<br />

#N/A<br />

1.84E-0 I<br />

#N/A<br />

2.17E-04<br />

3.9 1 E-02<br />

1.97E-01<br />

6.38E-05<br />

1.93E-03<br />

3.02E-03<br />

2.71E-03<br />

9.26E-04<br />

2.14E+00<br />

#NIA<br />

1.38E-01<br />

1.40E-01<br />

1.35E+01<br />

1.65E+00<br />

2.12E-01<br />

#N/A<br />

8.17E+00<br />

#N/A<br />

<strong>4.</strong>13E+01<br />

#N/A<br />

I .99E+01<br />

#N/A<br />

2.19E+02<br />

9.978+01<br />

#N/A<br />

#NIA<br />

#N/A<br />

1.90E-02<br />

<strong>4.</strong>74E-01<br />

3.99E+02<br />

2.92E+01<br />

#N/A<br />

1.1 1E+00<br />

#N/A<br />

#N/A<br />

1.93E+01<br />

I .9 I E-02<br />

5.683-01<br />

3.57E-02<br />

<strong>4.</strong>348-04<br />

7.81E-02<br />

2.66E-02<br />

1.34E-03<br />

2.29E-03<br />

<strong>4.</strong>55E-02<br />

6.11E-04<br />

I. I4E-02<br />

8.25E-02<br />

<strong>4.</strong>94E-04<br />

2.19E-06<br />

2.72E-03<br />

7.708+02<br />

#NIA<br />

1.33E-01<br />

9.39E-03<br />

7.82E+00<br />

3.35E-02<br />

1.20E-01<br />

#N/A<br />

3.45E+00<br />

2. I 1 E+OO<br />

7.29E-01<br />

#N/A<br />

7.51E-01<br />

#N/A<br />

9.548+01<br />

8.64E-01<br />

#NIA<br />

6.76E+00<br />

#N/A<br />

I .09E-02<br />

1.90E+00<br />

1.67E+00<br />

2.07E-04<br />

3.82E-02<br />

5.53E-02<br />

6.11 E-02<br />

2.44E-02<br />

2.43E+00<br />

#N/A<br />

1.57E-01<br />

I S8E-01<br />

1.54E+01<br />

1.87E+00<br />

2.40E-01<br />

#N/A<br />

9.288+00<br />

#N/A<br />

<strong>4.</strong>68E+01<br />

#N/A<br />

2.26E+01<br />

#N/A<br />

2.49E+02<br />

1.13E+02<br />

#N/A<br />

#N/A<br />

#N/A<br />

2. IOE-02<br />

5.38E-01<br />

<strong>4.</strong>52E+02<br />

3.31 E+01<br />

#NIA<br />

1.26E+00<br />

#N/A<br />

#N/A<br />

3.18E+02<br />

8.45E-01<br />

5.953+00<br />

5.09E-01<br />

1.80E-02<br />

5.0 I E-01<br />

3.72E-01<br />

1.56E-02<br />

3.32E-02<br />

3.83E-01<br />

7.64E-03<br />

5.20E-0 I<br />

3.52E+00<br />

3.69E-03<br />

6.24E-06<br />

<strong>4.</strong>40E-02


Q Hazard<br />

Table 6.20. Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 1, TCE Spill Site (SWMU 136) (continued)<br />

Representative Meadow Vole a White-footed Mouse Short-tailed Shrew ’<br />

Concentration DdIyInWrc NOAEL’ Hazard DnilyIntPke NOAEL’ Hazard DaUy Intake NOAEL ’ Hazard<br />

Chemlcd (W4) (WCr) (mgkg) Qootienta CmtL) (mgkg) Quotients (nvYk)<br />

&nz*)fluoranthene 2.30E-01 6.748-04 #N/A 9.738-04 #N/A 2.20E-02 #N/A<br />

Chrysme <strong>4.</strong>50E-01 1.39E-03 #N/A 3.2 1 E43 #N/A S.16E-02<br />

Din-butylphthalate 2.20E-0 I 6.828-04 <strong>4.</strong>85E+02 l.41E-06 1.20E-03 6.09E+02 2.27E-02 6.91E+02 3.29E-OS<br />

1.98E-06<br />

8.10E-02 2.51E-04 #N/A 6.278-04 #N/A 9.63E-03 #N/A<br />

3.40E-01 1.25E-03 #N/A 2.27E-03 #N/A 3.70E-02 #N/A<br />

3.10E-0 I 8.80E-04 #N/A 2.04E-03 #N/A 3.488-02 #N/A<br />

7.908-02 3.50E-04 #N/A <strong>4.</strong>84E-04 #NIA 8.0 1E-03 #N/A<br />

2.80E-01 9.15E-04 #N/A 1.86E-03 #N/A 3.10E-02 #N/A<br />

Trichloroahcne <strong>4.</strong>00E-03 1.19E-04 6.17E-01 1.94E-04 9.64E-05 7.7SE-01 I .24E-04 <strong>4.</strong>13E-04 8.80E-01 <strong>4.</strong>70E-04<br />

(nigkg)<br />

#N/A<br />

Quotients<br />

Hazard Index 1.24E+01 2.02E+01 3.303+02<br />

a = All toxicity values were extracted from “PC-Data Base: Screening Benchmarks for Ecological Risk Asscssmmt (revised December 1994)”<br />

Environmental Scienca Division, Health Sciences Research Division, ORNL<br />

b = NOAEL - NO A~VCISC Effcds Level<br />

Quotients arc unitless<br />

#N/A or - = not able to quanti@ because transfer fador or toXicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.21. Ecological hazard quotients for surface water-associated in the northlsouth ditch along fence parallel to Portal Road No. 1 at PCDP, WAG 1, Sewage Treatment Plant (SWMU 38)<br />

Representative Eatinatd EaUaald EaBnatd LCV IC Sensitive<br />

Concratntlon LCV1* LCV'* ECn'. Aqnatic LO''* LCV"* LCV'" EC," Species Test Population Sceondary Secondary NAWQC '" NAWQC'"<br />

Cbemical (mtW Daphnidr Fish Fish Phats Daphnidr Fish Iuvertebrata Daphnidr ECn" ECn" Acute Values' Chronic Valma' Acute Chronic<br />

Anenk<br />

BllrlUm<br />

Caldum<br />

Chmmlum<br />

CWPW<br />

Im<br />

Lead<br />

Mag n e 8 l u m<br />

Mll~~~ZIE<br />

Nldrd<br />

Potassium<br />

S e l en I u m<br />

Silver<br />

Sodlum<br />

Chlomform<br />

TOhMlle<br />

i lOE-03<br />

I WE02<br />

I57EMI<br />

3 IOE-03<br />

6 20E-03<br />

3 79E-01<br />

5 70E-03<br />

5 75EMO<br />

3 15E-02<br />

7 30E-03<br />

2 IOEMO<br />

I WE43<br />

5 30E-03<br />

2 06EIOI<br />

4 00E-03<br />

5 008-03<br />

3.288-06<br />

3 038-05<br />

1.92E-07<br />

I98E-07<br />

3.94E-06<br />

I55E-03<br />

- 6208-03<br />

I14E-05<br />

1.468-03<br />

I 908-05<br />

I .77E4<br />

- 2.04E-08<br />

I35E-04<br />

5 06E-04<br />

2 70E-02<br />

2 40E-03<br />

4 658-04<br />

7 OlE-05<br />

2 86E-05<br />

1468-03<br />

3 %E45<br />

2 078-05<br />

2 ME43<br />

blr(2-Elhylhexyl)phlhalata 2.00E-03 - - 6.67EM 2.3118-04 - 6.678-04 - <strong>4.</strong>00E-05 6.998-06 6.218-05 -<br />

4 24E-05<br />

1638-03<br />

2 928-04<br />

3 02E-04<br />

1788-05<br />

2 WE44<br />

2 ISE-05<br />

4 42E-02<br />

3 238-06<br />

I .02E-03<br />

2 248-04<br />

5.69E-05<br />

6.2OE-03<br />

3.028-02<br />

2.37842<br />

2.86E-05<br />

1.62E-04<br />

7.60E-05<br />

9.468-03<br />

I 17E-02<br />

2 388-02<br />

I63E-02<br />

6 648-04<br />

7 31E-04<br />

3 798-02<br />

9818-06<br />

7 21E-04<br />

8 OIE-05<br />

2818-04<br />

3 408-05<br />

1668-02<br />

7 12E-06<br />

2 50E-05<br />

2 758-04<br />

2 14E-05<br />

I 19E-06<br />

I 598-06<br />

5 00E-03<br />

3 92E-04<br />

147E-02<br />

2 I3E-OS<br />

2 84E-05<br />

1948-04<br />

3 448-04<br />

6 95E-05<br />

521E-06<br />

7 31E-06<br />

I 29E-03<br />

2 828-04<br />

5 17E-04<br />

3 798-04<br />

1788-03<br />

4 56E-05<br />

5 43E-05<br />

Hwrd Index 347EM 3948-06 - 9421-03 34118-02 4698-02 I30E-03 705E-02 9 IOE-02 I78E-02 306E-04 2 OZE-02 1 91E-03 3 ME-03<br />

I LCV -Lowest Chronic Value<br />

2 - E P - Effective Conantdon La a reduction of 20% of Le growlh produdion occurs<br />

3 - NAWQC - National Ambient Walu Quality C hrh<br />

a - All toxicity values were emed<br />

fmm 'PC-D.u Bue Sersening Benchmarks for Ecological RI* Auammt (mid December 1994).<br />

Envimnmmul Scimcu Division. HdL Scimcer R d Division. OWL<br />

* * Hacard Quotients are un~tlua<br />

- - not able to quantify becars msfer faor or toxicologicd benchmark wm unavulabk


Table 6.22. Ecological hazard quotients for surface water-associated organisms in the eastlwest ditch parallel to Water Works Road at PGDP, WAG 1, Sewage Treatment Plant (SWMU 38)<br />

Representative Estimated Erliantd Ltimnted LCV Scnrilive<br />

Comrmtrntloa LCV IC LCV '*' EC," Aquatic LCV "* LCV LCV ECZ," Species Tat Population Sccoodnry Secondary NAWQC'" NAWQC'"<br />

Cbcalcnl (-m) Dapbaidr Fisb Fish nanb Dnpbmldi Fisb Iavertebrntn Dapbnidr EC," EC,"' Acute Vnlua' Chronic Values' Acute Chronic<br />

Aluminum 5 84E-01 1278-03 307EM I78E-04 I WE43 7 798-03 7 798-04 6 71 E-03<br />

Barium 9 5ZE-02 I64E-05 138E-03 2 5 I E-02<br />

Cdcium<br />

Coppr<br />

Ira,<br />

M.gnerium<br />

Mmgmre<br />

Potassium<br />

Sodium<br />

Zinc<br />

Ethylbenzene<br />

7 l4E+01 6 16E-04<br />

3 IOE-03 - 3 108-03 l35E-02 8 i6EM 5 llE-04 I 5IE-02 I l9E-02 36OE-04 i 728-04 ZSBE-04<br />

I I4E+00 7228-03 877E-04 7 13E-02 I14E-03<br />

6 8UE+OO - 8398-05<br />

6 56E-01 - S%EM 371EM 5 % E4 5 868-03 4 468-04 8 17E-03<br />

5 6oE+00 I06EM<br />

I59EMI 2348-05 -<br />

8 668-02 - 289803 I85E-03 2388-03 165E-05 4 I2E-03 I O8E-03 7228-04 787E-04<br />

I WE43 1478-07 - - 434E-09 - 432846 4 778-06 2 738-07 4 88E-06<br />

Toluene I soe-03 5.95E-08 l.llE-06 - 612E-Ob - 7 50E-06 4 768-07 8 52E-06<br />

Hazard Index 400E-05 l.lEE-06 - 7268-03 2.43842 462E-03 5.28E-04 8.80E-02 2388-02 7318.03 I8ZE-03 3 328-02 I67E-03 8.908-03<br />

I - LCV - Lo-<br />

Chronic Vdue<br />

production O~CUN<br />

Ambient Wlter Quality Critaia<br />

- All toxicity vdua were exbrtrd h 'PC-Data Bue: Saeming Benchmvks fa Ecologid Risk Assesmenl (mid Deu?mba 1994)'<br />

Environmental Sciences Division. Hdth Scimm Research DivirioR OWL<br />

2 - EC? - ERCAVC conanbairn IIW I ruiuaion ofzw. of the uo~rh<br />

3 - NAWQC - N d d<br />

- H urd Quotimu pe unitleu<br />

- - no( able to quanti* bemuse transfa factor M toxidogid benchmark w u unavailable


Table 6.23. Ecological hazard quotients for sediment-associated organisms in the north/south ditch along fence parallel<br />

to Portal Road No. 1 at PGDP, WAG I, Sewage Treatment Plant (SWMU 38)<br />

Representative<br />

Concentmtion Efkb Eflects EPA<br />

Chemlenl (mgkg) Range Low Range Medium OMOE '*' EPA*" Region V H&S '*' WIDNR 4'<br />

Aluminum<br />

<strong>4.</strong>60E+03<br />

Arsenic 1.5OE+00 1.83E-01 2. I4E-02 2.5OE-01<br />

Barium 3.47E+01 6.94E-02<br />

Beryllium<br />

1.60E+00<br />

Calcium<br />

I. l3E+03<br />

Chromium 8.53E+01 l.OSE+OO 2.31E-01 3.2SE+OO<br />

Cob&<br />

I .01E+01<br />

copper 1.53E+O 1 <strong>4.</strong>5OE-01 5.67E-02<br />

Iron <strong>4.</strong>85E+04 2.8SE+OO<br />

Lcad 9.20E+00 1.97E-01 <strong>4.</strong>22E-02<br />

Magnesium<br />

3.34E+02<br />

Manganese<br />

<strong>4.</strong>62E+02<br />

l.OOE+OO<br />

M- 1.30E-01 8.67E-01 1.83E-01<br />

Nickel 1.62E+01 7.71E-01 3.14E-0 1<br />

Potassium<br />

1.70E+02<br />

Selenium<br />

2.30E-01<br />

Sodium<br />

<strong>4.</strong>1 SE+Ol<br />

Vanadium<br />

9.72E+01<br />

Zinc 5.91E+01 3.94E-01 1.44E-01<br />

Benzene 5.00E-03 9.62E-02<br />

Di-n-butylphlhalatc 2.60E-01 6.18E-03<br />

Fluoranthme 1.60E-01<br />

2.58E-02<br />

Phenanthrene 1.00E-01 5.56E-02<br />

Pyr*le<br />

1.90E-01<br />

bis(2-Ethylhexyl)late 2.90E-01 3.26E-07<br />

Hazard Index 3.923+00 9.92E-01 <strong>4.</strong>543+00 8.14E-02 2.85E+OO 1.OZE-01 6.94E-02<br />

1 = OMOE - Ontario Ministry of the E&rOnm&<br />

2 = EPA - United States Environmental Protection Agency<br />

3 = H&S - Hull <strong>and</strong> SU~N<br />

4 = WINDR - Wisconsin Division ofNalural <strong>Resource</strong>s<br />

a = All toxicity values were extracted 6um "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

= Hazard Quotients arc unitless<br />

- = not able to because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.2<strong>4.</strong> Ecological hazard quotients for sediment-associated organisms in the east/west ditch parallel to<br />

Water Works Road, Sewage Treatment Plant (SWMU 38)<br />

Representative<br />

Concentnation Effeets EffCCt.9 EPA<br />

Chedcd (mg/kg) Range Low Range Medium OMOE ’*’ EPA”’ Region V H&S WIDNR 4’<br />

Aluminum<br />

8.88E+03<br />

Arsenic 3.60E+00 <strong>4.</strong>39E-01 5.14E-02 6.00E-01<br />

Barium 7.54E+01 1.5 1 E-0 1<br />

Beryllium <strong>4.</strong>70E-0 1<br />

Calcium<br />

3.40E+03<br />

Chromium 1.59E+OI 1.96E-01 <strong>4.</strong>30E-02 6.12E-01<br />

Cobalt<br />

6.70E+00<br />

cow 1.92E+Ol 5.65E-01 7.1 lE-02<br />

Iron 1.27E+04 7.47E-01<br />

Lead 1.82E+O 1 3.90E-01 8.35E-02<br />

Magnesium<br />

1.27E+03<br />

<strong>4.</strong>58E+02 9.96E-01<br />

Nickel 1.28E+OI 6.10E-01 2.48E-01<br />

Potassium<br />

5.58E+02<br />

Selenium<br />

3.40E-01<br />

Sodium<br />

7.04E+01<br />

Vanadium<br />

I .98E+01<br />

Zinc 2.65E+02 1.77K+OO 6.46E-0 I<br />

Acetone 6.50E-02 1.02EM0<br />

Fludene 2.10E-01 3.39E-02<br />

M a e<br />

2.00E-01<br />

Hazard Index 3.97E+00 1.14E+00 2.21EMO 3.39E-02 7.478-03 l.OZE+OO 1.5 1E-01<br />

1 = OMOE - Ontario Ministry of the Environment<br />

2 = EPA - United Stat- Environmmtal Rotection Agency<br />

3 = H8S - Hull Md Suer<br />

4 = WINDR - Wiscoruin Division of Natural <strong>Resource</strong>s<br />

a = All toxicity values were extmcted h “PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)”<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

= Hazard Quotients are unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than I.


Table 6.25. Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 1, Sewage Treatment Plant (SWMU 38)<br />

Rcprescn ta tivc<br />

Concentration<br />

Chemicd (mglkg) Planb ' Microbes ' Earthworms '<br />

Aluminum I. I7E+04 2.78EM2 232E+Ol<br />

Ammonia as Nitrogen<br />

1.35E+OI<br />

Antimony 1.50E+00 3.008-01<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Mercury<br />

Nickel<br />

Potassium<br />

Selenium<br />

Silver<br />

Sodium<br />

Vanadium<br />

6.88E+00<br />

8.06E+OI<br />

5.73E-0 1<br />

9.228+04<br />

2.13E+01<br />

1.06E+O I<br />

I .86E+01<br />

2.028+04<br />

2.09E+01<br />

2.508+03<br />

7. I I E+02<br />

1.08E+00<br />

I .27E+01<br />

6.598+02<br />

2.868-01<br />

I .03E+00<br />

9.40E+01<br />

3.08E+OI<br />

134EM0<br />

1.90E-01<br />

7.60E-02<br />

2.78E+Ol<br />

8.658-01<br />

2.668-01<br />

6.52E-01<br />

2.16E+00<br />

1.20Et01<br />

5.438-01<br />

3.908-01<br />

7.50E-01<br />

1.96E+01<br />

Soil<br />

I .34E-01<br />

3.168-02<br />

2.78E+00<br />

1.738-02<br />

2.668-01<br />

1.34E+02<br />

3.628-02<br />

1.08E+01<br />

1 .2OE-Ol<br />

1.818-01<br />

3.908-03<br />

3.00E-02<br />

1.96E+00<br />

2.238-01<br />

6.95E+01<br />

5.328-01<br />

6.528-02<br />

3.60E+01<br />

8.158-02<br />

5.5 7E-03<br />

Zinc 6.65E+01 3.00E+00 1.50E+00 7.50E-OI<br />

Acenaphthenc<br />

6.00E-02<br />

Acetone 3.708-02<br />

Anthracene 7.208-02<br />

Aroclor- I260<br />

<strong>4.</strong>71E-02<br />

Benzo(a)anthracene 1.508-01


Table 6.25. Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 1, Sewage Treatment Plant (SWMU 38) (continued)<br />

Representative<br />

Concentration<br />

Chemica~ (mglkg) Plants ' Microbes ' Earthworms '<br />

Benzo(a)pyrene 1.308-01<br />

Benzo(b)fluoranthene I ,908-01<br />

Benzo(k)fluoranthene 6.408-02<br />

Carbazole <strong>4.</strong>808-02<br />

Chrysene<br />

I SOE-01<br />

Di-n-butyl phthalate 5.998-01 9.008-03<br />

Phenanthrene 2.668-01<br />

Pyrene 2.698-01<br />

Soil<br />

Hazard index 3.48E+02 1.75E+02 1.07E+02<br />

a = All toxicity values were extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

* = Hazard Quotients arc unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than I.


Table 6.26. Ecological hazard quotients for wildlife receptors asociated with surface soil at<br />

PGDP, WAG 1, Sewage Treatment Plant (SWMU 38)<br />

Representative Meadow Volt ' White-footed Mouse ' Short-tailed Shrcw '<br />

Concentration DaUyIntnkc NOAEL' Hazard DPilyIntalrc NOAEL' Hazard DailyIntake NOAEL' Hazard<br />

chemlcd (mrh) (mgny) (w4) Quotients (mrW (mgk) Quotients (mg/ks) (mg/kg) Quotlents<br />

Aluminum<br />

Ammonia as Nitrogen<br />

Antimony<br />

Arsenic<br />

Barium<br />

Bayllium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Mangan-<br />

MaCUl-y<br />

Nickel<br />

Potassium<br />

Selenium<br />

Silva<br />

Sodium<br />

Vanadium<br />

Zinc<br />

Acenaphthene<br />

Acetone<br />

Anthracene<br />

Aroclor-1260<br />

Bmzo(a)anthrame<br />

1.17E+04<br />

I .35E+O 1<br />

I.5OE+00<br />

6.88E+00<br />

8.06E+01<br />

5.73E-01<br />

9.22E+04<br />

2.13E+O I<br />

1.06E+OI<br />

1.86E+O 1<br />

2.OZE+04<br />

2.09E+01<br />

2.50E+03<br />

7.1 1 E+OZ<br />

1.08E+00<br />

1.27E+01<br />

6.59E+02<br />

2.86E-01<br />

1.03E+00<br />

9.40E+O 1<br />

3.08E+01<br />

6.65E+01<br />

6.00E-02<br />

3.70E-02<br />

7.20E-02<br />

<strong>4.</strong>7lE-02<br />

l.SOE-0 1<br />

3.27E+01<br />

#N/A<br />

<strong>4.</strong>1 OE-03<br />

2.33E-02<br />

3.09E-01<br />

1.6633-03<br />

#N/A<br />

5.823-02<br />

3.53E-02<br />

8.79E-02<br />

#N/A<br />

5.75E-02<br />

#N/A<br />

7.30E+00<br />

3.89E-02<br />

6.00E-02<br />

#N/A<br />

3.958-03<br />

5.38E-03<br />

3.35E-01<br />

8.688-02<br />

9.IZE-01<br />

#N/A<br />

3.28E-02<br />

3.2 1 E-04<br />

1.31E-04<br />

<strong>4.</strong>65844<br />

1.70E+00<br />

#N/A<br />

1. IOE-01<br />

I.IIE-0I<br />

1.08E+OI<br />

1.31E+00<br />

#NIA<br />

6.50E+00<br />

#N/A<br />

3.28E+OI<br />

#N/A<br />

1.59E+01<br />

#N/A<br />

1.74E+02<br />

1.30E-02<br />

7.93E+01<br />

#N/A<br />

6.60E-02<br />

#N/A<br />

#N/A<br />

3.77E-01<br />

3.17E+02<br />

#N/A<br />

1.98E+01<br />

#N/A<br />

#N/A<br />

#N/A<br />

1.92EMl<br />

3.73E-02<br />

2.10E-01<br />

2.87E-02<br />

1.27E-03<br />

8.95E-03<br />

2.68E-03<br />

3.62E-03<br />

<strong>4.</strong>19E-02<br />

2.99EMO<br />

7.57E-04<br />

5.99E-02<br />

2.30E-01<br />

2.87E-03<br />

1.65E-03<br />

6.683+01<br />

#N/A<br />

2.32E-03<br />

8.978-02<br />

5.38E-01<br />

9.52E-04<br />

#N/A<br />

1.59E-01<br />

2.08E-02<br />

1.72E-01<br />

#N/A<br />

1.47E-01<br />

#N/A<br />

8.28E+00<br />

3.93E-02<br />

I .OOE-0 I<br />

#N/A<br />

2.65E-03<br />

3.38E-03<br />

2.00E-01<br />

<strong>4.</strong>96E-02<br />

6.1 1E-01<br />

#N/A<br />

2.29E-02<br />

<strong>4.</strong>77E-04<br />

2.47E-04<br />

7.628-04<br />

2.14E+00<br />

#N/A<br />

1.38E-01<br />

1.40E-01<br />

1.35E+01<br />

1.65E+00<br />

#N/A<br />

8.17E+00<br />

#N/A<br />

<strong>4.</strong>13E+01<br />

#NIA<br />

1.99E+O 1<br />

#NIA<br />

2.19E+02<br />

1.60E-02<br />

9.97E+0 I<br />

#N/A<br />

8.308-02<br />

#N/A<br />

#N/A<br />

<strong>4.</strong>74E-01<br />

3.998+02<br />

#N/A<br />

2.49E+01<br />

#NIA<br />

#N/A<br />

#NfA<br />

3.13E+01<br />

1.68E-02<br />

6.41E-01<br />

3.97E-02<br />

5.79E-04<br />

1.953-02<br />

<strong>4.</strong>16E-03<br />

7.35 E-03<br />

3.78E-02<br />

2.45&+00<br />

1 .O I E-03<br />

3.20E-02<br />

I .OSE-01<br />

3.538-03<br />

9.21 E-04<br />

1.24E+03<br />

#N/A<br />

1.17E-01<br />

1.06E+00<br />

8.71E+00<br />

<strong>4.</strong>47E-02<br />

#N/A<br />

2.53E+00<br />

8.27E-01<br />

2.26E+00<br />

#N/A<br />

2.42E+00<br />

#N/A<br />

7.92E+01<br />

1.71 E4 1<br />

1.43E+00<br />

#NIA<br />

2.23E-02<br />

8.03E-02<br />

7.33E+00<br />

2.40E+00<br />

5.19E+00<br />

#N/A<br />

3.828-03<br />

7.54E-03<br />

<strong>4.</strong>87E-03<br />

I .5 1 E-02<br />

2.43E+00<br />

#N/A<br />

1 S7E-01<br />

1 BE-01<br />

1.54E+01<br />

1.87E+00<br />

#N/A<br />

9.28E+00<br />

#N/A<br />

<strong>4.</strong>68E+01<br />

#N/A<br />

2.26E+Ol<br />

#NIA<br />

2.49E+02<br />

1.80E-02<br />

I. 13E+02<br />

#N/A<br />

9.40E-02<br />

#N/A<br />

#N/A<br />

5.388-0 I<br />

<strong>4.</strong>52E+02<br />

#N/A<br />

#N/A<br />

#N/A<br />

#N/A<br />

#NJA<br />

5.13E+02<br />

7.458-01<br />

6.71E+00<br />

5.67E-01<br />

2.40E-02<br />

2.73E-01<br />

<strong>4.</strong>82E-02<br />

1.07E-0 I<br />

3.18E-01<br />

9.49E+00<br />

1.26E-02<br />

2.37E-01<br />

<strong>4.</strong>473+00<br />

1.15E-02


Table 6.26. Ecological hazard quotients for wildlife receptors asociated with surface soil at<br />

PGDP, WAG 1, Sewage Treatment Plant (SWMU 38) (continued)<br />

Repmcntative Mudow Vole ' White-footed Mouse ' Short-tailed Shrew '<br />

Concentrntlon DpuyInt.lrr NOAEL' Hazard DaUyIntake NOAEL' Hazard DdyIntake NOAEL' Hazard<br />

Chemlcd (mglkb) (web) (mmW Quotlenb (mmW (nigkg) Quotients (nigkg) (mgkg) Quotients<br />

-o(ah)me 1.30E-01 3.8 I E44 8.81E-01 <strong>4.</strong>328-04 7.55E-04 l.llE+OO 6.81E-04 1.38E-02 1.26E+00 I.lOE-02<br />

Bmzo(b)fluoranthene 1.90E-01 5.57E-04 #NIA 8.04E-04 #N/A 1.828-02 #N/A<br />

&nzO(k)flUoranthens 6.40E-02 1.878-04 #N/A 2.71E-04 #N/A 6.11E-03 #N/A<br />

Carbazole <strong>4.</strong>80E-02 #N/A #N/A #N/A #N/A #N/A #N/A<br />

Chrysme I. 5OE-01 <strong>4.</strong>64E-04 #N/A I .07E-03 #N/A 1.72E-02 #N/A<br />

Di-n-butylphthalate 5.99E-01 1.86E-03 <strong>4.</strong>85EM2 3.83E-06 3.28E-03 6.09E+02 5.38E-06 6.39E-02 6.91E+02 8.95E-05<br />

PhenanthrenS 2.66E-01 I.lsE-03 #N/A 1.63E-03 #N/A 2.70E-02 #N/A<br />

41me 2.69E-01 8.79E-04 #N/A 1.798-03 #N/A 2.978-02 #N/A<br />

Hazard Index 2.28E+Q1 3.46E+01 5.36E+Q2<br />

a * All toxicity values were extracted fiom "E-Data Base: Scnming Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Scimces Division, Health Sciences Research Division, ORNL<br />

b = NOAEL - NO Adverse Effcds Level<br />

* = Hazard Quotimts are unitless<br />

#N/A or - = not able to quantify because transfer fador or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greats than I.


Table 6.27. Ecological hwrd quotients lor surface water-associated organisms in the unnamed tributary of Big Bayou Creek at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8)<br />

Rcpracntatlv Estimated Estimated EStimated LCV Scnsitlve<br />

Concentration LCV IC LCV ECm- Aquatic LCV IC LCV IC LCV IC ECnb Spzcles Test Population Secondary Secondary NAWQC ’.’ NAWQC‘.’<br />

Chemical (mgk) Daphnidr Fish Fish PIanb Daphnlda Fisb Invertebrata Daphnids ECmb ECmL’ Acute Values’ Chronic Values’ Acute Chronic<br />

Almnimna<br />

2.15E+OO<br />

<strong>4.</strong>678-03 1.13E-03 6.54E-04<br />

3.98843 2.87E-02<br />

2.87843<br />

Antimony<br />

Awic<br />

1.68E-02<br />

l.18E-03<br />

2.75E-05 3. I lE-06 I.05E-05<br />

8.84E-06<br />

2.13E-04 1.71E-05 1.628-04<br />

BUiuin<br />

Cadmium<br />

Calcium<br />

chloride<br />

Cbmmium<br />

Copper<br />

lrofi<br />

Lead<br />

Magnesium<br />

Mm8-<br />

Nickel<br />

Potassium<br />

Selenium<br />

Silicon<br />

SOdilrm<br />

Smntium<br />

Sulfate<br />

Thallium<br />

Vmadiuin<br />

Zinc<br />

Methylene Chloride<br />

cis-l.2-DicNdene<br />

5.28E-02<br />

2.38E-03<br />

2.49EM1<br />

1.40EMI<br />

<strong>4.</strong>40E-03<br />

5.78E-03<br />

8. I5E+OO<br />

3.40843<br />

5.80E+OO<br />

1.39EMI<br />

7.40E-03<br />

3.2IEMO<br />

1.06E-03<br />

5.04EW<br />

1.80EMI<br />

I.I4E+OO<br />

<strong>4.</strong>48EMI<br />

1.25E-03<br />

5.04E-01<br />

<strong>4.</strong>41E-01<br />

3.00E-03<br />

6.83E-03<br />

9.10E-06<br />

2.65E-05<br />

1.19E-03<br />

5.78E-03<br />

6.80E-06<br />

l.48E-03<br />

1.06E-05<br />

1.2SE-05<br />

1.478-02<br />

1.59E-02<br />

2.15E-04<br />

2.51E-02<br />

5.16E-02<br />

2.77E-04<br />

7.07E-05<br />

1.268-02<br />

1.48E-03<br />

6.06E-05<br />

I. 16E-05<br />

2.7 I E-05<br />

9.62E-06<br />

5.36E-04<br />

9.448-03<br />

1.40E-03<br />

1.52E-03<br />

6.27E-03<br />

l.8OE-04<br />

7.85E-03<br />

2.11E-04<br />

I.2OE-05<br />

2.19E-05<br />

6.30843<br />

1.21E-02<br />

Huud Index 3.56E-05 - 2.79842 1.18E-01 3.65E-02 1.23E-03 5.59E-01 2.66E-01 1.47E-01 1.22E-02 2.15E-01 7.528-03 <strong>4.</strong>07E-02<br />

I = LCV - Lowest Chronic Value<br />

2 - E? - Effective Concenmtion that a reduction of 20% of the moWh production OCCM<br />

3 - NAWQC - National Ambient Water Quality Criteria<br />

- Huud Qdenb me unitlesr<br />

- =not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

9.538-04<br />

1.348-04<br />

5.768-05<br />

8.41E-05<br />

a - All toxicity values were exmctcd &om “PC-Dab Base: SEmning Benchmarks for Ecological Risk Assessment (revised Dcccmbcr 1994)”<br />

Envimnmentd Sciences Division, Health Scicncn Research Divisim OWL<br />

3.17E-03<br />

2.82842<br />

5.09E-01<br />

1.268-02<br />

1.64E-04<br />

<strong>4.</strong>24845<br />

1.95E-05<br />

1.l7E-03<br />

1.83E-01<br />

2.22E-02<br />

9.71843<br />

6.73E-04<br />

<strong>4.</strong>088-04<br />

2. IOE-02<br />

5.53E-04<br />

6.728-04<br />

<strong>4.</strong>798-05<br />

1.24E-01<br />

3.44845<br />

I87E-05<br />

1.588-02<br />

5.518-03<br />

7.64E-04<br />

9.46843<br />

1.87E-04<br />

7.62E-06<br />

1.77843<br />

1.39E-02<br />

I .73E-01<br />

1.848-03<br />

6.94E-05<br />

2.64E-02<br />

6. IOE-04<br />

3.218-04<br />

<strong>4.</strong>ISE-OS<br />

5.298-06<br />

<strong>4.</strong>088-06<br />

3.68843<br />

2.16E-03<br />

<strong>4.</strong>82864<br />

8.1SE-03<br />

1.06E-03<br />

<strong>4.</strong>63E-OS<br />

3.03E-OS<br />

4 .O 1 E-03


~~<br />

~ ~ ~ ~ -<br />

Table 6.28. Ecological hazard quotients for sediment-associated organisms in the unnamed tributary of Big Bayou Creek<br />

at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8)<br />

Represcnta tive<br />

Concentration Effects Effects EPA '*'<br />

Chemical (mglkg) Range Lon Range Medium OMOE '' EPA *.' Region V H&S 3*' WIDNR "'<br />

A I u m i n u m<br />

Antimony<br />

Arsenic<br />

Barium<br />

Beryllium<br />

Calcium<br />

Chromium<br />

Cobalt<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Nickel<br />

Potassium<br />

Selenium<br />

Sodium<br />

Vanadium<br />

Zinc<br />

Di-n-butvlahthalate<br />

<strong>4.</strong>02E+03<br />

I .90E+00<br />

8.5 I E+OO<br />

9.7 I E+OI<br />

8.98E-03<br />

5.76 E+02<br />

<strong>4.</strong>64E+01<br />

1.52E+OI<br />

5.30E+00<br />

3.60E+04<br />

1.14E+O 1<br />

2.918+02<br />

9.83E+02<br />

7.09E+00<br />

1.858+02<br />

2.648-01<br />

I .33E+02<br />

5.348+01<br />

1.84E+01<br />

2.72E-0 I<br />

9.50E-01<br />

1.04E+00<br />

5.738-01<br />

1.56E-01<br />

2.44E-03<br />

3.38841<br />

1.23E-01<br />

7.60E-02<br />

I .22E-01<br />

1.25E-01<br />

1.968-02<br />

5.23E-02<br />

1.37E-01<br />

<strong>4.</strong>49842<br />

2.14E+00<br />

2.12Et00<br />

6.468-03<br />

I .94E-0 I<br />

Hazard Index<br />

3.42E+00 5.77E-01 5.34E+00 2.12E+00 6.468-03 I .94E-01<br />

I = OMOE - Ontario Ministry of the Environment<br />

2 = EPA - United States Environmental Protection Agency<br />

3 = HBS - Hull <strong>and</strong> Suter<br />

4 = WMDR - Wisconsin Division ofNatural <strong>Resource</strong>s<br />

a = All toxicity values wen extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division. Health Sciences Research Division, ORNL<br />

* = Hazard Quotients arc unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than I.


.<br />

e<br />

= a<br />

a;<br />

f<br />

4-<br />

N<br />

?<br />

. g ,<br />

09<br />

9<br />

0 0<br />

0 0<br />

+ +<br />

' g g<br />

33


Table 6.29. Ecological hazard quotients for plants, soil microbes, <strong>and</strong> earthworms associated<br />

with surface soil at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8) (continued)<br />

Representative<br />

Concentration<br />

Chemical (mg/kg) Phb ' Microbes ' rrthworms<br />

Acetone<br />

1.58E-01<br />

Anthracene<br />

2.878-0 I<br />

Aroclor-1260 7.608-02<br />

Benzene 6.748-03<br />

Bcnzo(a)anthracenc<br />

3.1 OE-01<br />

Bcnzo(a)pyrenc<br />

2.95E-01<br />

Bcnzo(b)fluoranthcne 3.76841<br />

Benzo(k)fluomthene I .80E-0 I<br />

Carbazole<br />

2.00E-01<br />

Chryscnc<br />

3.40E-01<br />

Di-n-butylphthalate 2.67E-01 1.35843<br />

Dibcnzohran 2.76841<br />

Fluoranthcne<br />

8.01 E41<br />

Fluorene 2.91 E-01 I .278-02<br />

Indeno( 1.2.3-cd)pyrcne 2.30E-01<br />

Naphthalene 2.97841<br />

Phenanthrene<br />

Pyrene<br />

9.79841<br />

5.19E-0 I<br />

Hazard Index 1.99E+02 l.38E+02 <strong>4.</strong>13E+OI<br />

Soil<br />

a = All toxicity values were extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994)"<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

= Hazard Quotients are unitless<br />

- = not able to quantify because transfer factor or toxicological benchmark was unavailable<br />

Bold Value indicates hazard quotient or hazard index is greater than 1.


Table 6.30. Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (WMU 8)<br />

Rcpmentathre Meadow Vole ' Whlte-footed Mouse a Short-tailed Shrew '<br />

Concentration Dilly Intake NOAEL ' Hazard Dilly Intake NOAEL' Hazard Daily Inlake NOAEL ' Hazard<br />

Chcmlml (~&) (msntp) (msntp) Quotlcnb (mgntp) (mgkg) Quotlents (melke) (me/kp) Quotlenb<br />

Ahrminum<br />

7.00Et03<br />

1.96Etol 1.7OEt00 1. ISE+Ol <strong>4.</strong>00E+01 2.14E+00 1.87E+01 7.45Et02 2.43E+OO<br />

~<br />

3.07E+02<br />

Antimony<br />

ArscniC<br />

Buium<br />

Snyllium<br />

CJdmiUm<br />

C l k i<br />

Chromium<br />

Cobalt<br />

copper<br />

Iron<br />

Lead<br />

MagnelIim<br />

Mmg.nesc<br />

Nickel<br />

Phosphate (do)<br />

Potauaium<br />

Sclcnium<br />

1.92E+OO<br />

3.78Et00<br />

8.46EtOl<br />

7.06E-01<br />

2.82E-01<br />

8.25Et04<br />

I. l6E+01<br />

9.61E+00<br />

1.03E+01<br />

1.27Et04<br />

I. I8Et01<br />

1.53Et03<br />

1.14Et03<br />

1. 50E-01<br />

1.17EtOl<br />

5.70EtOl<br />

<strong>4.</strong>13Et02<br />

7.68E-01<br />

5.25E-03<br />

1.28E-02<br />

3.25841<br />

2.048-03<br />

3.35E-03<br />

#N/A<br />

3.1 IE-02<br />

3.20E-02<br />

<strong>4.</strong>87E-02<br />

#N/A<br />

3.25E-02<br />

#NIA<br />

1.17Eto1<br />

5.40E-03<br />

5.53E-02<br />

#N/A<br />

#N/A<br />

1.06E-02<br />

l.lOE-O1<br />

I.llE-01<br />

1.08EtOI<br />

1.31E+00<br />

1.69E-01<br />

#N/A<br />

6.50EtOO<br />

#N/A<br />

3.28Et01<br />

#N/A<br />

1.59E+01<br />

#N/A<br />

1.74E+02<br />

I .30E-02<br />

7.93Et01<br />

#NlA<br />

#N/A<br />

6.608-02<br />

<strong>4.</strong>77E-02<br />

1.16E-01<br />

3.01E-02<br />

1.56E-03<br />

1.98E-02<br />

<strong>4.</strong>87E-03<br />

1.48E-03<br />

2.05E-03<br />

6.713-02<br />

<strong>4.</strong>15E-01<br />

6.97E-04<br />

1.61E-01<br />

2.97E-03<br />

<strong>4.</strong>93E-02<br />

5.65E-01<br />

1.17E-03<br />

I.80E-02<br />

#N/A<br />

8.68E-02<br />

1.89E-02<br />

9.5 I E42<br />

#N/A<br />

8.28E-02<br />

#N/A<br />

1.33EtoI<br />

5.45E-03<br />

9.25E-02<br />

#NlA<br />

#N/A<br />

7.12E-03<br />

1.38E-01<br />

1.4OE-01<br />

1.35Et01<br />

1.65E+OO<br />

2.12E-01<br />

#N/A<br />

8.17EtUO<br />

#N/A<br />

<strong>4.</strong>13Et01<br />

#N/A<br />

1.99Et01<br />

#N/A<br />

2.19E+02<br />

1.60E-02<br />

9.97E+O1<br />

#N/A<br />

#NIA<br />

8.30E-02<br />

2.16E-02<br />

3.52E-01<br />

<strong>4.</strong>17E-02<br />

7.13E-04<br />

8.47E-02<br />

1.06E-02<br />

2.31E-03<br />

<strong>4.</strong>15E-03<br />

6.05E-02<br />

3.41E-01<br />

9.283-04<br />

8.58E-02<br />

1 SOE-01<br />

5.82E-01<br />

9.14EtOO<br />

5.5 1E-02<br />

1.3OE-01<br />

#N/A<br />

1.38EtW<br />

7.50E-01<br />

1.25Et00<br />

#N/A<br />

1.36E+OO<br />

#N/A<br />

1.27Et02<br />

2.37E-02<br />

1.31E+00<br />

#N/A<br />

#N/A<br />

5.99E-02<br />

1.57E-01<br />

1.58E-01<br />

1.54Et01<br />

1.87E+OO<br />

2.40E-01<br />

#N/A<br />

9.28Et00<br />

#N/A<br />

<strong>4.</strong>68Et01<br />

#N/A<br />

2.268+01<br />

#N/A<br />

2.49E+02<br />

1.8OE-02<br />

1.13E+02<br />

#N/A<br />

#N/A<br />

9.4OE-02<br />

9.54E-01<br />

3.68E+OO<br />

5.95E-01<br />

2.9SE-02<br />

5.438-01<br />

1.49E-01<br />

2.67E-02<br />

6.03E-02<br />

5.1OE-01<br />

1.32E+OO<br />

1.16E-02<br />

6.37E-01<br />

S M<br />

7.39E-01<br />

3.86E-03 #N/A<br />

2.43E-03 #N/A<br />

5.76E-02<br />

#N/A<br />

SOdiUm<br />

Thallium<br />

VmdiUIll<br />

zinc<br />

2-Methytnaphthalme<br />

4,4'-DDT<br />

Acmaphthmc<br />

6.32Et01<br />

1.38E-0 I<br />

1.78E+01<br />

3.77EtOt<br />

1.20E-01<br />

2.50E-03<br />

2.50E-01<br />

2.25841<br />

3.77E-04<br />

5.02E-02<br />

5.17E-01<br />

7.82E-04<br />

7.24E-06<br />

#N/A<br />

#N/A<br />

1.50E-02<br />

3.77E-01<br />

3.17Et02<br />

#N/A<br />

I. 59Et00<br />

#N/A<br />

2.52E-02<br />

1.33E-01<br />

1.6313-03<br />

<strong>4.</strong>57E-06<br />

1.34E-01<br />

2.14E-04<br />

2.86E-02<br />

3.47E-01<br />

7.93E-04<br />

l.33E-05<br />

#N/A<br />

#N/A<br />

1.90E-02<br />

<strong>4.</strong>74E-01<br />

3.99E+02<br />

#N/A<br />

1.99E+00<br />

#N/A<br />

I. 13E-02<br />

6.04E-02<br />

8.69E-04<br />

6.69E-06<br />

<strong>4.</strong>93EtOO<br />

1.08E-02<br />

1.39EtOO<br />

2.94E+00<br />

1.14E-02<br />

2.58E-04<br />

#N/A<br />

#NfA<br />

2.1OE-02<br />

5.388-01<br />

<strong>4.</strong>52E+02<br />

#N/A<br />

2.26E+00<br />

#N/A<br />

5.13E-01<br />

2.58EtOO<br />

6.5OE-03<br />

1.14E-04


Table 6.30. Ecological hazard quotients for wildlife receptors associated with surface soil at<br />

PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8) (continued)<br />

Represenlatlve Meadow Vole ’ White-footed Mouse Short-tailed Shrew<br />

Concentration Dailylnlake NOAEL’ Huvd Ddy Intake NOAEL ’ Hazard Daily Intake NOAEL ’ Hazard<br />

Chemlal (ms/lrs) (ms/lrs) (me) Quotients (wm) (msnCg) Quotients (wntg) (mgnCe) Quotlents<br />

I. 58E-0 I<br />

1.4OE-01<br />

I .98E+01<br />

2.87E-01<br />

7.60E-02<br />

6.74E-03<br />

3.1OE-01<br />

2.95841<br />

3.76E-01<br />

l.8OE-01<br />

2.00E-01<br />

3.40E-01<br />

2.67E-01<br />

2.76E-01<br />

8.0 IE-0 I<br />

2.91E-01<br />

2.30E-01<br />

2.97E-01<br />

9.79E-01<br />

1.288-03<br />

2.11E-04<br />

2.77E-04<br />

9.61E-04<br />

8.64E-04<br />

l.10E-03<br />

5.27E-04<br />

#NlA<br />

l.OSE-03<br />

8.28E-04<br />

#NIA<br />

2.948-03<br />

1.5OE-03<br />

6.53E-04<br />

3.41E-03<br />

<strong>4.</strong>34E-03<br />

UN/A<br />

#NlA<br />

2.32EMI<br />

#NlA<br />

8.81E-01<br />

#N/A<br />

INIA<br />

#NlA<br />

YNIA<br />

<strong>4.</strong>85Et02<br />

INIA<br />

UNIA<br />

#NlA<br />

INIA<br />

INIA<br />

MIA<br />

5.19E-01 1.70E-03 #NlA<br />

7.0633-03 9.80E-02 2.49E+OI<br />

1 ME-03 #N/A<br />

3.99E-04 UNIA<br />

1.19E-05 2.1 SE-04 2.92E+Ol<br />

1.57E-03 UNIA<br />

9.81E-04 1.71E-03 l.llE+OO<br />

1.59E-03 #N/A<br />

7.62E-04 #N/A<br />

UN/A<br />

#N/A<br />

2.4313-03 INIA<br />

1.71E-06 1.468-03 6.09E+02<br />

#N/A<br />

#NlA<br />

5.36E-03 #NlA<br />

I HE-03 UNIA<br />

1.52E-03 #NlA<br />

3.02E-03 UN/A<br />

6.00E-03 #NlA<br />

3.4SE-03 #N/A<br />

3.93E-03 1.631-02 #N/A<br />

3.01E-02<br />

UNIA<br />

7.85E-03<br />

UN/A<br />

7.378-06 6.96844 3.3 IE+OI<br />

3.12E-02 UNIA<br />

1 S5E-03 3.14E-02 1.26E+00<br />

3.59842 UN/A<br />

l.72E-02 UNIA<br />

UN/A<br />

UNIA<br />

3.90842 UNIA<br />

2.4OE-06 2.76E-02 6.91 E+02<br />

UNIA<br />

UNIA<br />

8.728-02 UN/A<br />

2.76E-02 UNIA<br />

2.58E-02 #N/A<br />

2.84E-02 UN/A<br />

- . 9.93E-02 UN/A<br />

5.741-02 UNIA<br />

2.10E-05<br />

2.5OE-02<br />

3.99E-05<br />

Hazud Index<br />

l.ZSE+Ol<br />

1.98E+01<br />

3.19E+02<br />

I = An toxicity dues wcrc extracted from “PCData Bue: Screening Benchmarks for Ecological Risk Assessment (ntised December 1994)”<br />

Environmental Scienccs Won, Health Sciences Research Division, ORNL.<br />

b = NOAEL -NO Advcrse Eff~~ts h l<br />

= Hazard Quotients arc ~Ntless<br />

#N/A or - = not able to quantify because transfer factor or toxicological bcnchmuk wan unavailable<br />

Bold Value indicated huud quotient or hupd mdcx h &!mater than I.


Table 6.31. Ecological hazard quotients for the piscivore (Kingfisher) associated with surface water in<br />

the unnamed tributary of Big Bayou Creek at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8)<br />

Chemical<br />

Fish Kingfisher Benchmark<br />

Rcpresentrt ve ncentrrtion BCF for Fish' Hazard Quotient<br />

im$r Concentration (waterIb<br />

Aluminum I .43E+02 O.OOE+OO O.OOE+OO<br />

Antimony<br />

Barium<br />

Beryllium<br />

Cadmium<br />

Calcium<br />

Chloride<br />

Chromium<br />

Cobalt<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Mercury<br />

Nickel<br />

Phosphorus (P)<br />

Potassium<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Strontium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

Tungsten<br />

Vanadium<br />

Zinc<br />

Zirconium<br />

I, I-Dichloroethane<br />

5.468-02<br />

8.44E-01<br />

6.268-02<br />

2.9OE-03<br />

7.338+01<br />

I .20E+O I<br />

7.00E-02<br />

I .00E+00<br />

5.57E-02<br />

9.748+02<br />

6.91E+00<br />

5.698+01<br />

8.59E+Ol<br />

<strong>4.</strong>20E-04<br />

9.99E-01<br />

<strong>4.</strong>17E+00<br />

6.13E+00<br />

l.OOE+OO<br />

3.89E+Ol<br />

3.57E+OI<br />

l.OOE+OO<br />

5.06E+02<br />

I .00E+00<br />

8.39E-0 I<br />

l.OOE+OO<br />

1.22E+00<br />

1.93E+00<br />

I .00E+00<br />

<strong>4.</strong>928-03<br />

l.OOE+OO<br />

<strong>4.</strong>00E+00<br />

2.00E+00<br />

5.00E+OI<br />

3.00E+02<br />

2.1 OE+O2<br />

3.00E+02<br />

<strong>4.</strong>00E+02<br />

6.30E+04<br />

I .00E+02<br />

I .OOE+O2<br />

1.00E+04<br />

I .OOE-02<br />

I .00E+03<br />

O.OOE+OO<br />

5.46E-02<br />

3.38E+00<br />

1.25E-OI<br />

1.45E-01<br />

3.00E+02<br />

1. I7E+OI<br />

2.07E+03<br />

3,44E+04<br />

2.65E+Ol<br />

9.998+01<br />

3.578+03<br />

8.39E+03<br />

I .22E-02<br />

I .93E+03<br />

O.OOE+OO<br />

2.408-02 l.lOE+OJ


Table 6.31. Ecological hazard quotients for the piscivore (Kingfisher) associated with surface water in the<br />

unnamed tributary of Big Bayou Creek at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8) (continued)<br />

Chemical<br />

Fish Kingfisher Benchmark<br />

RepresentatpgJijmcentration BCF for Fish' Conecntration<br />

m<br />

(water)b<br />

Hazard Quotient<br />

I, I-Dichloroethene 5.278-03 7.00E+00 3.698-02<br />

1,2-Dichloroethenc 5.50E-02 7.00E+00 3.858-01<br />

Acetone 5 SOE-02 2.00E-01 I. IOE-02<br />

Trichloroethene 2.10E-03 1.70E+OI 3.57E-02<br />

Xylene 3.408-03<br />

bis(2-Ethylhcxyl)phthalate 2.00E-03 3. I OE+02 6.20E-0 I 2.228+00 2.79E-01<br />

cis- I ,2-Dichloroethene <strong>4.</strong>21 E-02<br />

trans-I .2-Dichloroethene <strong>4.</strong>98843 7.00E+00 3.49E-02<br />

Hazard Index<br />

1.10E+O3<br />

Bold value indicates hazard quotient or hazard index is greater than 1<br />

- = not able to quantify because transfer factor or benchmarks were unavailable<br />

= Hazard Quotients arc unitless<br />

a = bioconcentration factors were extracted from "Relative Toxicity Estimates <strong>and</strong> Bioaccumulation Factors for the Defense Priority Model",<br />

Environmental Sciences Division, Health Sciences Research Division, ORNL<br />

b = Benchmark values were extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment (revised December 1994).


Table 6.32. Ecological hazard quotients* for wildlife receptors associated with surface water in the<br />

unnamed tributary of Big Bayou Creek at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8)<br />

Vole Vole Hazard Mouse<br />

Chemical Re reseptat've hh~se HQ Shrew Benchmark' Shrew HQ Deer Benchmark' Deer HQ<br />

Conccktratlon [ md) Benchmark' Quotient (HQ) Benchmark'<br />

Aluminum I .43E+02 1.25E+OI l.lSE+OI 7.13E+00 2.01E+01 I. I OE+OI 1.30E+01 2.45E+00 5.843+01<br />

Antimony<br />

8.08E-01 6.768-02 <strong>4.</strong>628-01<br />

I. 188-01 7.14E-01 7.65E-02<br />

I .59E-01<br />

3.438-01<br />

Barium<br />

7.90E+OI I ,078-02 <strong>4.</strong>528+01 1.878-02 6.998+01 I .21 E-02<br />

I .55E+OI<br />

5.44E-02<br />

Beryllium<br />

9.60E+00 6.528-03 5.488+00 I. 148-02 8.488+00 7.38E-03<br />

I .88E+00<br />

3.32E-02<br />

Cadmium<br />

1.24E+00 2.35843 7.068-0 I <strong>4.</strong>11E-03 1.09E+00 2.658-03 2.43E-01<br />

1.19E-02<br />

Calcium<br />

Chloride<br />

Chromium<br />

Cobalt<br />

Copper<br />

Iron<br />

Lead<br />

Magnesium<br />

Manganese<br />

Mercury<br />

Nickel<br />

Phosphorus (PI<br />

Potassium<br />

Ruthenium<br />

Silicon<br />

Sodium<br />

Strontium<br />

Sulfate<br />

Tantalum<br />

Thallium<br />

Tungsten<br />

Vanadium<br />

Zinc<br />

Zirconium<br />

I ,I-Dichloroethane<br />

I, I -Dichlorocthene<br />

5.468-02<br />

8.44E-01<br />

6.268-02<br />

2.908-03<br />

7.338+01<br />

I .20E+OI<br />

7.008-02<br />

I .00E+00<br />

5.578-02<br />

9.748+02<br />

6.91E+00<br />

5.698+0 I<br />

8.598+0 I<br />

<strong>4.</strong>208-04<br />

9.99E-0 I<br />

<strong>4.</strong> I7E+00<br />

6.13E+00<br />

I .00E+00<br />

3.898+01<br />

3.578+01<br />

I .00E+00<br />

5.068+02<br />

I .00E+00<br />

8.398-0 1<br />

l.OOE+OO<br />

I .22E+OO<br />

1.93E+00<br />

I .00E+00<br />

<strong>4.</strong>928-03<br />

5.278-03<br />

2.4 IE+02<br />

I. 16E+02<br />

1.28E+03<br />

9.30E-02<br />

5.82E+02<br />

3.82E+03<br />

I .09E-01<br />

2.77E+OO<br />

2.338+03<br />

I. 12E+OI<br />

<strong>4.</strong>36E+02<br />

2.3 I E-04<br />

5.948-02<br />

6.71E-02<br />

<strong>4.</strong>528-03<br />

I .72E-03<br />

2.628-04<br />

7.70E+00<br />

<strong>4.</strong>4 I 8-01<br />

8.308-04<br />

8.90E-02<br />

1.2 I E-05<br />

I .38E+02<br />

6.65E+01<br />

7.318+02<br />

5.30E-02<br />

3.32E+02<br />

2. I8E+03<br />

6.208-02<br />

1.58E+00<br />

1.33E+03<br />

6.42E+00<br />

2.498+02<br />

<strong>4.</strong>058-04<br />

1.04E-01<br />

1.188-01<br />

7.928-03<br />

3 .O I E-03<br />

<strong>4.</strong>588-04<br />

I .35E+01<br />

7.728-01<br />

1.458-03<br />

1 S6E-0 1<br />

2.1 IE-05<br />

2.338+02<br />

1.03E+02<br />

1. I38+03<br />

8.208-02<br />

5.14E+02<br />

3.38E+03<br />

9.60E-02<br />

2.458+00<br />

2.06E+03<br />

9.93E+00<br />

3.86E+02<br />

2.628-04<br />

6.72E-02<br />

7.598-02<br />

5.12E-03<br />

I .94E-03<br />

2.96E-04<br />

8.74E+00<br />

<strong>4.</strong>998-01<br />

9.38E-04<br />

1.01E-01<br />

1.378-05<br />

<strong>4.</strong>72E+01<br />

2.288+01<br />

2.5 I E+02<br />

1.80E-02<br />

I. I4E+02<br />

7.5 OE+02<br />

2. I OE-02<br />

5.43E-01<br />

<strong>4.</strong>568+02<br />

2.2OE+OO<br />

8.56E+0 1<br />

I. I8E-03<br />

3.03E-01<br />

3.428-01<br />

2.33 E-02<br />

8.768-03<br />

1.338-03<br />

<strong>4.</strong>00E+01<br />

2.25E+00<br />

<strong>4.</strong>23E-03<br />

<strong>4.</strong>54E-01<br />

6. I6E-05


Table 6.32. Ecological hazard quotients* for wildlife receptors associated with surface water in the<br />

unnamed tributary of Big Bayou Creek at PGDP, WAG 7, C-746-K Sanitary L<strong>and</strong>fill (SWMU 8) (continued)<br />

Chemical<br />

Vole Vole Hazard Mouse<br />

Re rescotat ve Mouse HQ Shrew Benchmark' Shrew HQ Deer Benchmark' Deer HQ<br />

COnC&tlOn bfl) Benchmark' Quotient (HQ) Benchmark'<br />

I ,2-Dichloroethene 5.508-02 2.928+02 1.888-04 I .678+02 3.308-04 2.588+02 2. 138-04 5.738+01 9.608-04<br />

Acetone 5.50E-02 1.458+02 3.788-04 8.31E+01 6.628-04 2.858+01 1.938-03<br />

Trichloroethene 2. I OE-03 <strong>4.</strong>528+00 <strong>4.</strong>648-04 2.598+00 8. I2E-04 <strong>4.</strong>008+00 5.25E-04 8.88E-01 2.368-03<br />

Xylene 3.408-03 I .33E+OI 2.558-04 7.61E+00 <strong>4.</strong>478-04 I. 18E+OI 2.898-04 2.61E+00 I ,308-03<br />

bis(2-Ethylhexyl)phthalate 2.00E-03 I. 18E+02 1.698-05 6.778+01 2.958-05 I .O5E+O2 1.91E-05 2.32E+OI 8.608-05<br />

cis- I ,2-Dichloroethene <strong>4.</strong>218-02<br />

trans-I .2-Dichloroethcne <strong>4.</strong>98843<br />

Hazard Index 1.99E+01 3.49E+O1 2.26E+01 l.O2E+O2<br />

Bold value indicates hazard quotient or hazard index is greater than I<br />

- = not able to quantify because transfer factor or benchmarks were unavailable<br />

* = Hazard Quotients arc unitless<br />

a = All toxicity values were extracted from "PC-Data Base: Screening Benchmarks for Ecological Risk Assessment<br />

(revised December 1994), Environmental Sciences Division, Health Sciences Research Division, ORNL


I<br />

Table 6.31. Estimated radiation doses' (uCy/h) to aquatic organisms exposed to radionuclides in surface water <strong>and</strong> sediment<br />

at WAG 1 SWMU 38.<br />

WAG 1, SWMU 38, Ditcb 1 - SUrfaCC water <strong>and</strong> sediment<br />

Sediment RME (pCUg) SurLce water RME (pCi/L)<br />

Total dose<br />

Radionuclide invert. fish invert. fish Small insects L8rge insects Small fish .<br />

Gross Alpha 8.338+00 8.33E+OO I. I5E+OO 1.15E+OO na na na<br />

Gross Beta 1.09E+01 1.09E+O I 6.18E+00 6.18E+00 na na na<br />

Technetium-99 2.31E+00 2.31 E+OO 3.88E+00 3.88E+00 I .68E-04 1.688-04 1.688-04<br />

Uranium-234 2. I4E+00 2.14E+00 9.30E-01 9.30841 1.928-02 I .928-02 I .928-02<br />

Uranium-235 5.00E-02 5.00E-02 8.00E-02 8.00E-02 I S9E-03 I .59E-03 1.568-03<br />

Uranium-238 2.61E+00 2.61E+00 I .04E+OO 1.04E+OO 1.898-02 1.89E-02 1.898-02<br />

Total 398-02 3.998-02 3.988-02<br />

WAG 1, SWMU 38, Ditch 2 -Surface water <strong>and</strong> sediment<br />

Sediment RME (pCVg) Surface water RME (pCVL) Total dose<br />

Radionuclide invert. fish invert. fish Small insects Lame insects Small fish<br />

Gross Alpha 9.90E+00 9.90E+00 <strong>4.</strong>9 I E+01 <strong>4.</strong>91E+OI na na na<br />

Gross Beta 2.10E+01 2.1 OEM 1 3 .O 1 E+O 1 3.01E+OI na na na<br />

Neptunium-237 O.OOE+OO O.OOE+OO 3.40E-01 3.40E-01 2.11E-02 2.11E-02 2. I 1 E-02<br />

Plutonium-238 0.00E+00 O.OOE+OO 2.00E-01 2.OOE-0 I I .43E-02 1.438-02 1.438-02<br />

Plutonium-240 O.OOE+OO O.OOE+OO <strong>4.</strong>00E-02 <strong>4.</strong>00E-02 2.688-03 2.688-03 2.688-03<br />

Plutonium-242 O.OOE+OO O.OOE+OO 2.00E-02 2.OOE-02 I .27E-03 1.278-03 . 1.278-03<br />

Technetium-99 3.12E+OO 3.12E+00 2.25E+00 2.25E+OO 9.72845 9.728-05 9.72E-05<br />

Thorium-228 0.00E+00 0.00E+00 I .60E-01 1.60E-01 3.748-02 3.74E-02 3.748-02<br />

Thorium-230 O.OOE+OO 0.00E+00 I .80E-01 1.80E-01 3.648-02 3.648-02 3.64E-02<br />

Thorium-232 O.OOE+OO 0.00E+00 7.00E-02 7.00E-02 I .21 E-02 I .2 I 8-02 1.2 I E42<br />

Uranium-234 I .44E+00 I .44E+OO 1.22E+00 1.22E+00 2.528-02 2.528-02 2.528-02<br />

Uranium-235 1.00E-01 1.00E-01 8.00E-02 8.00E-02 1.658-03 I .658-03 1.598-03<br />

Uranium-238 2.07E+OO 2.07E+00 I .50E+00 1.5OE+OO 2.738-02 2.728-02 2.72E-02<br />

Total<br />

1.79E-01 1.79E-01 1.798-01<br />

'Total doses presented are sum of internal <strong>and</strong> external exposures estimated following Blaylock et al. (1993). Internal exposures were<br />

insignificant relative to external exposures; therefore, total doses (uGyh) were similar for all groups.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies are not applicable.


Table 6.32. Estimated internal, external, <strong>and</strong> total radiation doses (radslyr) from surface soil for<br />

wildlife receptors at WAG 1 SWMU 38.<br />

Surface soil<br />

Meadow vole Short-tailed shrew White-footed mouse<br />

Radionuclide RME' Internal External Total Internal External Total Internal External Total<br />

Neptunium237 1.38E+00 1.96E-08 8.84E-04 8.84E-04 1.49E-07 8.84E-04 8.84E-04 1.01E-08 8.84E-04 8.84E-04<br />

Plutonium-238 1.37E-01 1.72E-11 <strong>4.</strong>63E-06 <strong>4.</strong>63E-06 1.67E-10 <strong>4.</strong>63E-06 <strong>4.</strong>63E-06 8.45E-12 <strong>4.</strong>63E-06 <strong>4.</strong>63E-06<br />

Plutonium-239 8.00E-02 9.40E-12 1.19E-06 1.19E-06 9.15E-11 1.19E-06 1.19E-06 <strong>4.</strong>62E-12 1.19E-06 1.19E-06<br />

Plutonium-240 l.lOE-01 1.30E-11 3.55E-06 3.55E-06 1.26E-10 3.55E-06 3.55E-08 6.37E-12 3.55E-06 3.55E-06<br />

Plutonium242 1.33E-02 1.49E-12 3.58E-07 3.58E-07 1.45E-11 3.58E-07 3.58E-07 7.31E-13 3.58E-07 3.58E-07<br />

Technetium99 3.48E+00 2.45E-10 0.00E+00 2.45E-10 7.70E-12 0.00E+00 7.70E-12 1.48E-10 O.OOE+OO 1.48E-10<br />

Thorium-228 1.21E+00 1 .!%E49 7.45E-05 7.46E-05 1.46E-08 7.45E-05 7.46E-05 7.75E-10 7.45E-05 7.46E-05<br />

Thorium230 1.59E+00 1.77E-09 <strong>4.</strong>60E-05 <strong>4.</strong>60E-05 1.65E-08 <strong>4.</strong>60E-05 <strong>4.</strong>60E-05 8.79E-10 <strong>4.</strong>60E-05 <strong>4.</strong>60E-05<br />

Thorium-232 1.34E+00 1.28E-09 3.33E-05 3.33E-05 1.2OE-08 3.33E-05 3.33E-05 6.36E-10 3.33E-05 3.33E-05<br />

Uranium234 l.l7E+Ol <strong>4.</strong>17E-08 3.78E-04 3.78E-04 5.14E-07 3.78E-04 3.78E-04 7.34E-08 3.78E-04 3.78E-04<br />

Uranium235 1.12E+00 3.85E-09 3.22E-03 3.22E-03 <strong>4.</strong>74E-08 3.22E-03 3.22E-03 6.76E-09 3.22E-03 3.22E-03<br />

Uranium-238 1.37E+01 <strong>4.</strong>30E-08 3.48E-04 3.48E-04 5.30E-07 3.48E-04 3.48E-04 7.56E-08 3.48E-04 3.48E-04<br />

Total 1.13E-07 <strong>4.</strong>99E-03 <strong>4.</strong>99E-03 1.28E-06 <strong>4.</strong>99E-03 <strong>4.</strong>99E-03 1.68E-07 <strong>4.</strong>99E-03 <strong>4.</strong>99E-03<br />

'RME = Reasonable maximum exposure in pCi/g.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.


na<br />

Table 6.33. Estimated radiation doses' (uGy/h) to aquatic organisms exposed to radionuclides in surface water <strong>and</strong> sediment<br />

at WAG 1 SWMU 100.<br />

WAG 1, SWMU 100, Ditch 1 - Surface water <strong>and</strong> sediment<br />

Sediment RME (pCi/g) Surface water RME (pCin) Total dose<br />

Radionuclide invert. fish invert. fish Small insects Large insects Small fish<br />

Gross Alpha 9.13E+00 9.13E+00 3.96E+00 3.96E+00 0.00E+00 O.OOE+OO O.OOE+OO<br />

Gross Beta 1.87E+O 1 1.87E+OI 6.99E+00 6.99E+00 0.00E+00 O.OOE+OO O.OOE+OO<br />

Technetium-99 1.45E+00 1.45E+00 2.06E+OO 2.06Ei-00 8.89E-05 8.89E-05 8.89E-05<br />

Uranium-234 1.12E+00 1.12E+00 1.16E+00 1.16E+00 2.39E-02 2.39E-02 2.39E-02<br />

Uranium-235 5.00E-02 5.00E-02 6.00E-02 6.00E-02 1.21 E-03 1.20E-03 1.17E-03<br />

Uranium-238 1.27E+OO 1.27E+00 1.53E+00 1.53Ei-00 2.78E-02 2.788-02 2.78E-02<br />

Total 5.30E-02 5.30E-02 5.30E-02<br />

WAG 1, SWMU 100, Ditch 2 -Surface water <strong>and</strong> sediment<br />

Sediment RME (pcilg) Surface water RME (pCin) Total dose<br />

Radionuclide invert. fish invert. fish Small insects Large insects Small fish<br />

Gross Alpha 1.43E+01 1.43E+01 7.628+00 7.62E+00 na na na<br />

Gross Beta 2.30E+O 1 2.30E+01 1. I5E+OI l.ISE+Ol na na ~<br />

Technetium-99 2.29E+00 2.29E+00 <strong>4.</strong>898+00 <strong>4.</strong>89E+00 2.1 1 E-04 2.1 1 E-04 2.1 IE-04<br />

Uranium-234 3.74E+00 3.74E+00 5.13E+00 5.13E+00 1.06E-01 1.06E-01 1.06E-01<br />

Uranium-235 1.35E+00 1.35E+00 2.348+00 2.34E+00 <strong>4.</strong>63E-02 <strong>4.</strong>63E-02 <strong>4.</strong>54E-02<br />

Uranium-23 8 <strong>4.</strong>08E+00 <strong>4.</strong>08E+00 9.498+00 9.49E+00 1.72E-01 1.72E-01 I .72E-01<br />

Total 3.25E-0 1 3.25E-01 3.248-0 1<br />

'Total doses presented are sum of internal <strong>and</strong> external exposures estimated following Blaylock et al. (1 993). Internal exposures were<br />

insignificant relative to external exposures; therefore, total doses (uGyh) were similar for all groups.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies are not applicable.


Table 6.3<strong>4.</strong> Estimated internal, external, <strong>and</strong> total radiation doses (radslyr) from surface soil for<br />

wildlife receptors at WAG 1 SWMU 100.<br />

Surface soil<br />

Meadow vole Short-tailed shrew White-footed mouse<br />

Radionuclide RME' Internal External Total Internal External Total Internal External Total<br />

Gross Alpha 1.31 E+Ol na na na na na na na na na<br />

Gross Beta<br />

Neptunium237<br />

Plutonium-238<br />

Plutonium-240<br />

Technetium-99<br />

Thorium228<br />

Thorium-230<br />

Thorium-232<br />

Uranium-233/234<br />

Uranium234<br />

Uranium-235<br />

Uranium-238<br />

Total<br />

2.06E+Ol<br />

2.00E-02<br />

1.60E-03<br />

2.70E-02<br />

8.7OE-01<br />

1.18E+00<br />

1.31E+00<br />

1.10E+00<br />

1.45E+00<br />

1.82E+00<br />

<strong>4.</strong>25E-01<br />

1.78E+00<br />

na<br />

2.84E-10<br />

2.01 E-1 3<br />

3.18E-12<br />

6.12E-11<br />

1.52E-09<br />

1 A6E-09<br />

1.05E-09<br />

5.22E-09<br />

6.49E-09<br />

1.46E-09<br />

5.59E-09<br />

2.31E-08<br />

na<br />

1.28E-05<br />

5.41 E-08<br />

8.72E-07<br />

O.WE+W<br />

7.27E-05<br />

3.79E-05<br />

2.73E-05<br />

3.55E-05<br />

5.88E-05<br />

1.22E-03<br />

<strong>4.</strong>52E-05<br />

1.51E-03<br />

na<br />

1.28E-05<br />

5.41 E-08<br />

8.72E-07<br />

6.12E-11<br />

7.27E-05<br />

3.79E-05<br />

2.73E-05<br />

3.55E-05<br />

5.88E-05<br />

1.22E-03<br />

<strong>4.</strong>52E-05<br />

1.51E-03<br />

na<br />

2.16E-09<br />

1.95E-12<br />

3.lOE-11<br />

1.93E-12<br />

1.42E-08<br />

1.36E-08<br />

9.81 E-09<br />

6.43E-08<br />

8.00E-08<br />

1 J30E-08<br />

6.88E-08<br />

2.71E-07<br />

na<br />

1.28E-05<br />

5.41E-08<br />

8.72E-07<br />

0.00E+00<br />

7.27E-05<br />

3.79E-05<br />

2.73E-05<br />

3.55E-05<br />

5.88E-05<br />

1.22E-03<br />

<strong>4.</strong>52E-05<br />

1.51E-03<br />

na<br />

1.28E-05<br />

5.41 E-08<br />

8.72E-07<br />

1.93E-12<br />

7.27E-05<br />

3.79E-05<br />

2.73E-05<br />

3.55E-05<br />

5.89E-05<br />

1.22E-03<br />

<strong>4.</strong>53E-05<br />

1.51E-03<br />

na<br />

1.46E-10<br />

9.07E-14<br />

1.56E-12<br />

3.70E-11<br />

7.56E-10<br />

7.24E-10<br />

5.22E-10<br />

9.17E-09<br />

'1.14E-08<br />

2.56E-09<br />

9.82E-09<br />

3.52E-08<br />

na<br />

1.28E-05<br />

5.4lE-08<br />

8.72E-07<br />

O.OOE+OO<br />

7.27E-05<br />

3.79E-05<br />

2.73E-05<br />

3.55E-05<br />

5.88E-05<br />

1.22E-03<br />

<strong>4.</strong>52E-05<br />

1.51E-03<br />

na<br />

1.28E-05<br />

5.41 E-08<br />

8.72E-07<br />

3.70E-11<br />

7.27E-05<br />

3.79E-05<br />

2.73E-05<br />

3.55E-05<br />

5.88E-05<br />

1.22E-03<br />

<strong>4.</strong>52E-05<br />

1.51E-03<br />

I<br />

RME = Reasonable maximum exposure in pCi/g.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.


Table 6.35. Estimated internal, external, <strong>and</strong> total radiation doses (raddyr) from surface soil for<br />

wildlife receptors at WAG I SWMU 136.<br />

Surface soil<br />

Meadow vole Short-tailed shrew White-footed mouse<br />

Radionuclide RME' Internal External Total Internal External Total Internal External Total<br />

Gross Alpha ' 5.63E+00 na na na na na na na na na<br />

Gross Beta 6.42E+W na na na na na na na na na<br />

Technetium-99 9.70E-01 6.83E-11 O.OOE+W 6.83E-11 2.15E-12 O.OOE+OO 2.15E-12 <strong>4.</strong>12E-11 O.OOE+OO <strong>4.</strong>12E-11<br />

Uranium234 8.30E-01 2.96E-09 2.68E-05 2.68E-05 3.65E-08 2.68E-05 2.68E-05 5.20E-09 2.68E-05 2.68E-05<br />

Uranium-235 <strong>4.</strong>00E-02 1.37E-10 1.15E-04 1.15E-04 1.69E-09 1.15E-04 1.15E-04 2.4lE-10 1.15E-04 1.15E-04<br />

Uranium-238 8.70E-01 2.73E-09 2.21E-05 2.21E-05 3.36E-08 2.21E-05 2.21E-05 <strong>4.</strong>80E-09 2.21E-05 2.21E-05<br />

Total 5.90E-09 1.64E-04 1.64E-04 7.18E-08 1.64E-04 1.64E-04 1.03E-08 1.64E-04 1.64E-04<br />

I<br />

RME = Reasonable maximum exposure in pCVg.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.


Table 6.36. Estimated internal, external, <strong>and</strong> total radiation doses (raddyr) from surface soil for<br />

wildlife receptors at WAG 7 SWMU 132.<br />

Surface soil<br />

Meadow vole Short-tailed shrew White-footed mouse<br />

Radionuclide RME' Internal External Total Internal External Total Internal External Total<br />

Gross Alpha 9.83E+00 na na na na na na na na na<br />

Gross Beta 1.88E+Ol na na na na na na na na na<br />

Technetium-99 5.lOE-01 3.59E-11 O.WE+W 3.59E-11 1.13E-12 O.OOE+W 1.13E-12 2.17E-11 O.WE+OO 2.17E-11<br />

Uranium-234 1 .lOE+OO 3.93E-09 3.55E-05 3.55E-05 <strong>4.</strong>83E-08 3.55E-05 3.56E-05 6.90E-09 3.55E-05 3.55E-05<br />

Uranium235 1.40E-01 <strong>4.</strong>8lE-10 <strong>4.</strong>03E-04 <strong>4.</strong>03E-04 5.92E-09 <strong>4.</strong>03E-04 <strong>4.</strong>03E-04 8.45E-10 <strong>4.</strong>03E-04 <strong>4.</strong>03E-04<br />

Uranium-238 1.50E+00 <strong>4.</strong>71E-09 3.8lE-05 3.81E-05 5.80E-08 3.8lE-05 3.8lE-05 8.27E-09 3.8lE-05 3.81E-05<br />

Total 9.15E-09 <strong>4.</strong>76E-04 <strong>4.</strong>76E-04 1.12E-07 <strong>4.</strong>76E-04 <strong>4.</strong>76E-04 1.60E-08 <strong>4.</strong>76E-04 <strong>4.</strong>76E-04<br />

'RME = Reasonable maximum exposure in pCi/g.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.


Table 6.37. Estimated internal, external, <strong>and</strong> total radiation doses (rads/yr) from surface soil for<br />

wildlife receptors at WAG 7 SWMU 133.<br />

Meadow vole Short-tailed shrew White-footed mouse<br />

Surface soil<br />

Radionuclide RME' Internal External Total Internal External Total Internal External Total<br />

Gross Alpha 1.26E+Ol na na na na na na na na na<br />

Gross Beta 1.64E+Ol na na na na na na na na na<br />

Technetium-99 1.20E+00 8.44E-11 0.00E+00 8.44E-11 2.66E-12 O.OOE+OO 2.66E-12 5.lOE-11 O.OOE+OO 5.10E-11<br />

Uranium-233Q34 1.22E+00 <strong>4.</strong>39E-09 2.98E-05 2.98E-05 5.41E-08 2.98E-05 2.99E-05 7.72E-09 2.98E-05 2.98E-05<br />

Uranium234 1.07E+00 3.82E-09 3.46E-05 3.46E-05 <strong>4.</strong>70E-08 3.46E-05 3.46E-05 6.71 E-09 3.46E-05 3.46E-05<br />

Uranium-235 5.00E-02 1.72E-10 1.44E-04 1.44E-04 2.1 lE-09 1.44E-04 1.44E-04 3.02E-10 1.44E-04 1.44E-04<br />

Uranium-238 1.59E+00 <strong>4.</strong>99E-09 <strong>4.</strong>04E-05 <strong>4.</strong>04E-05 6.15E-08 <strong>4.</strong>04E-05 <strong>4.</strong>04E-05 8.77E-09 <strong>4.</strong>04E-05 <strong>4.</strong>04E-05<br />

Total 1.35E-08 2.49E-04 2.49E-04 1.65E-07 2.49E-04 2.49E-04 2.35E-08 2.49E-04 2.49E-04<br />

I<br />

RME = Reasonable maximum exposure in pCi/g.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.


Table 6.38. Estimated internal, external, <strong>and</strong> total radiation doses (raddyr) from surface soil for<br />

wildlife receptors at WAG 7 SWMU 13<strong>4.</strong><br />

Surface soil<br />

Meadow vole Short-tailed shrew White-footed mouse<br />

Radionuclide RME' Internal External Total Internal External Total Internal External Total<br />

Gross Alpha 7.78E+00 na na na na na na na na na<br />

Gross Beta 1.62E+Ol na na na na na na na na na<br />

Technetium-99 9.60E-01 6.76E-11 0.00E+00 6.76E-11 2.12E-12 O.OOE+OO 2.12E-12 <strong>4.</strong>08E-11 O.OOE+OO <strong>4.</strong>08E-11<br />

Uranium-234 8.40E-01 3.00E-09 2.71E-05 2.71 E-05 3.69E-08 2.71 E-05 2.72E-05 5.27E-09 2.71E-05 2.71 E-05<br />

Uranium-235 7.M)E-02 2.40E-10 2.01E-04 2.01E-04 2.96E-09 2.01E-04 2.01E-04 <strong>4.</strong>22E-10 S2.01E-04 2.01E-04<br />

Uranium-238 l.l4E+OO 3.58E-09 2.89E-05 2.89E-05 <strong>4.</strong>41E-08 2.89E-05 2.90E-05 6.29E-09 2.89E-05 2 90E-05<br />

Total 6.88E-09 2.57E-04 2.57E-04 8.40E-08 2.57E-04 2.57E-04 1.20E-08 2 57E-04 2.57E-04<br />

'RME = Reasonable maximum exposure in pCi/g.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.<br />

$r I


3.20E-02.<br />

Table 6.39. Estimated radiation doses' (uGylh) to aquatic organisms exposed to radionuclides in surface water <strong>and</strong> sediment<br />

at WAG 7 SWMU 8.<br />

WAG 7, SWMU 8, Bayou Creek - Surface water<br />

Sediment RME (pCVg) Surface water RME (pCuL) Total dose<br />

Radionuclide invert. fish invert. fish Small insects Large insects Small fish<br />

Gross Alpha 7.928+00 7.04E+00 9.00E+00 1.21 E+OO na na na<br />

Gross Beta I .67E+01 1.16E+OI 1.22E+02 7.33E+00 na na na<br />

Technetium-99 7.968-01 7.968-01 3.OOE+OI I .66E+01 1.30E-03 1.30E-03 7.17E-04<br />

Uranium-233034 9.1 OE-0 I 9.10E-01 <strong>4.</strong>50E-0 I <strong>4.</strong>50E-01 9.398-03 9.388-03 9.388-03<br />

Uranium-234 I. IOE+00 8.61 E-01 3.20E-01 2.978-01 6.618-03 6.61 E-03 6.138-03<br />

Uranium-235 6.00E-02 6.00E-02 9.608-02 9.608-02 1.90E-03 I .90E-03 1.87E-03<br />

Uranium-238 8.90E-01 8.43E-01 2.16E-01 2.16E-01 3.93E-03 3.938-03 3.92E-03<br />

Total 2.318-02 2.31842 2.208-02<br />

WAG 7, SWMU 8, Ieacbate<br />

Sediment RME (pCVg) Surface water RME (pCVt) Total dose<br />

Radionuclide invert. fish invert. fish Small insects Large insects Small fish<br />

Gross Alpha nd nd 6.51E+02 3.47EMl na na na<br />

Gross Beta nd nd 3.00E+02 1.78E+01 na na na<br />

Neptunium-237 nd nd 5.30E-01 5.30E-01 3.28EE-Q2r.<br />

Plutonium-238 nd nd I .30E-01 I .30E-01 9.28E-b3 2 '<br />

I 3.28E-02<br />

'9.28E-03 _-:-_9.28E-O3<br />

Plutonium-240 nd nd 7.00E-02 7.00E-02 <strong>4.</strong>69843 "E<strong>4.</strong>69E-03 '<strong>4.</strong>69843 I<br />

Plutonium-242 nd nd 2.00E-02 2.00E-02 1.27E-03 1.278-03 . 1.278-03<br />

Technetium-99 nd nd I .30E+OI 1.13E+OI 5.61844 5.61E-04 <strong>4.</strong>888-04<br />

Thorium-228 nd nd <strong>4.</strong>30E-01 <strong>4.</strong>30E-01 1 .OIE-OI 1.01E-01 1.01 E-01<br />

Thorium-230 nd nd 5.80E-01 5.80E-01 1.17E-01 1. I7E-01 1.17E-01<br />

Thorium-232 nd nd <strong>4.</strong>90E-01 <strong>4.</strong>90E-01 8.50842 8.508-02 8.508-02<br />

Uranium-234 nd nd 6.82E+00 6.82E+00 1.41 E-01 1.41 E-01 1.41 E-01<br />

Uranium-235 nd nd <strong>4.</strong>30E-01 <strong>4.</strong>30E-01 8.20E-03 8.20E-03 8.20E-03<br />

Uranium-238 nd nd 7.47E+OO 7.478+00 1.36E-01 1.36E-01 1.36E-01<br />

Total 6.368-0 1 6.368-01 6.368-01<br />

'Total doses presented arc sum of internal <strong>and</strong> external exposures estimated following Blaylock et al. (1993). Internal<br />

exposures were insignificant relative to external exposures; therefore, total doses (uGylh) were similar for all groups.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies arc not applicable.<br />

nd =No data available.


Table 6.40. Estimated internal, external, <strong>and</strong> total radiation doses (rads/yr) from surface soil for<br />

wildlife receptors at WAG 7 SWMU 8.<br />

Meadow vole Short-tailed shrew White-footed m owe<br />

Surface soil<br />

Radionuclide RME Interoal External Total Internal External Total Internal External Total<br />

Gross Alpha 9.90E+00 na na na na na na ma na na<br />

Gross Beta<br />

Neptunium-237<br />

Plutonium-239<br />

Technetium-99<br />

Thorium-230<br />

Uranium-234<br />

Uranium235<br />

Uranium-238<br />

1.83E+Ol<br />

2.00E+00<br />

-2.00E+00<br />

8.79E+00<br />

5.20E+02<br />

3.74E+01<br />

8.33E-01<br />

5.25E+01<br />

na<br />

2.84E-08<br />

-2.35E-10<br />

6.19E-10<br />

5.79E-07<br />

1.33E-07<br />

2.86E-09<br />

1.65E-07<br />

na<br />

1.28E-03<br />

-2.97E-05<br />

0.00E+00<br />

1.50E-02<br />

$.21E-03<br />

2.40E-03<br />

2.33E-03<br />

na<br />

1.28E-03<br />

-2.97E-05<br />

6.19E-10<br />

1.50E-02<br />

1.21E-03<br />

2.40E-03<br />

1.33E-03<br />

na<br />

2.16E-07<br />

-2.29E-09<br />

1.95E-11<br />

5.40E-06<br />

1 ME-06<br />

3.52E-08<br />

2.03E-06<br />

na<br />

1.28E-03<br />

-2.97E-05<br />

0.00E+00<br />

1 SE-02<br />

1.21E-03<br />

2.4OE-03<br />

1.33E-03<br />

na<br />

1.28E-03<br />

-2.97E-05<br />

1.95E-11<br />

1.5iE-02<br />

I.stE*’<br />

2.4OE-03<br />

1.34E-03<br />

na<br />

1.46E-08<br />

-1.t6E-10<br />

3.74E-10.<br />

2.87E-07<br />

2.34E-07<br />

5.03E-09<br />

2.90E-07<br />

na<br />

1.28E-03<br />

-2.97E-05<br />

O.oQE+OO<br />

1.5oE-02<br />

l.WE-03<br />

2.40E-03<br />

1.33E-03<br />

na<br />

1.28E-03<br />

-2.97E-05<br />

3.74E-10<br />

1.5OE-02<br />

1.21 E-03<br />

2.40E-03<br />

1.33E-03<br />

Total 9.09E-07 2.12E-02 2.12E-02 9.33EQQ 2.12E-02 2.12E-02 8.31E-07 2.12&0% 2.12E-02<br />

1<br />

‘WE = Reasonable maximum exposure in pCVg.’<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.<br />

na = Gross alpha <strong>and</strong> beta doses were not estimated because specific decay energies were not applicable.

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