DEPARTMENT OF PHYSICS IN-HOUSE SYMPOSIUM 2008
DEPARTMENT OF PHYSICS IN-HOUSE SYMPOSIUM 2008
DEPARTMENT OF PHYSICS IN-HOUSE SYMPOSIUM 2008
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<strong>DEPARTMENT</strong> <strong>OF</strong> <strong>PHYSICS</strong><br />
<strong>IN</strong>-<strong>HOUSE</strong> <strong>SYMPOSIUM</strong> <strong>2008</strong><br />
<strong>IN</strong>DIAN <strong>IN</strong>STITUTE <strong>OF</strong> SCIENCE<br />
BANGALORE 560012<br />
(NOVEMBER 24-25, <strong>2008</strong>)
FORWARD<br />
As a periodic review of its activities, The Department of Physics has been<br />
organizing In-House Symposium on annual basis during recent years. This one-day<br />
symposium usually consists of oral presentations by selected faculty members and<br />
students, and poster presentations by all those who would like to present their recent<br />
results. This year we have 10 talks by faculty, 2 by post-doctoral fellows, 17 by the senior<br />
students and as many as 28 posters by the rest. I hope this package would be as<br />
reasonable representation of the ongoing research activities in the department. This event<br />
is also particularly useful to freshers to familiarize themselves with the current research<br />
activity in our Department in various branches of Physics.<br />
I would like to thank Drs. Prabal Maiti, Arindam Ghosh and Banibrata<br />
Mukhopadhyay of our Department who have shouldered the responsibility to organize<br />
this In-House Symposium. I urge all of you to actively participate in this important<br />
scientific activity. I hope you will all have an enjoyable and fruitful day.<br />
Prof. Chandan Dasgupta<br />
Chairman<br />
November 24-25, <strong>2008</strong>
08.55-09:00 Welcome<br />
Chandan Dasgupta<br />
<strong>IN</strong>-<strong>HOUSE</strong> <strong>SYMPOSIUM</strong><br />
<strong>DEPARTMENT</strong> <strong>OF</strong> <strong>PHYSICS</strong><br />
Indian Institute of Science<br />
November 24-25, <strong>2008</strong><br />
TECHNICAL PROGRAMME<br />
(Venue: Physics Lecture Hall- I)<br />
Day 1<br />
(24/11/<strong>2008</strong>)<br />
09:00-10:25 SESSION I<br />
Chair: Vasant Natarajan<br />
09:00-09:20 F1 Chanda J. Jog<br />
The surprisingly flattened dark matter halo of the Andromeda<br />
Galaxy<br />
09:20-09:40 F2 H. R. Krishnamurthy<br />
Novel Physics in Hetero-structures of Strongly Correlated<br />
Materials<br />
09:40-09:55 S1 S. Srivastava<br />
Polymer nanocomposites near glass transition: Role of interface<br />
09:55-10:10 S2 Naresh Babu Pendya<br />
Observation of low temperature Persistent Photoconductivity in<br />
flower shaped dendritic PbS structures<br />
10:10-10:25 S3 T. Phanindra Sai<br />
Fabrication and Electrical Characterization of Charge Transfer<br />
Molecular Wires<br />
10:25-11:00 TEA<br />
11:00-12:55 SESSION II<br />
Chair: Prabal K Maiti<br />
11:00-11:20 F3 Chandan Dasgupta<br />
Growing length and time scales in glass forming liquids<br />
11:20-11:40 F4 Jaydeep Basu<br />
Nanophotonics with Quantum Dot Arrays and Optical Near Fields
11:40-11:55 S4 S. K. Biswas<br />
Diffuse optical tomographic non-invasive breast and brain imager<br />
using a single laser light source<br />
11:55-12:10 S5 Murthy O. V. S. N<br />
High pulsed field magnetotransport and hole mobility in HgCdTe<br />
12:10-12:25 S6 K. G Padmalekha<br />
EMR Studies of LSMO nanoparticles dispersed in PVA<br />
12:25-12:40 S7 Mogurampelly Santosh<br />
Force Induced DNA Melting<br />
12:40-12:55 S8 N. Kamaraju<br />
Ultrafast electron dynamics and cubic optical nonlinearity of<br />
single and double walled carbon nanotubes<br />
12:55-14:00 LUNCH<br />
14:00-15:30 POSTER + TEA<br />
15:30-17:15 SESSION III<br />
Chair: Rahul Pandit<br />
15:30-15:50 F5 A. K. Sood<br />
Nonequilibrium Fluctuations in Sheared Jammed States<br />
15:50-16:10 F6 K. P. Sinha<br />
Extended Einstein-Hilbert (E-H) action and the emergence of<br />
Riccions as cosmic dark matter and consequent cosmic<br />
acceleration<br />
16:10-16:25 S9 Sunil Kumar<br />
Low frequency vibrational modes in carbon nanotubes: terahertz<br />
time domain spectroscopy<br />
16:25-16:45 P1 Rema Krishnaswamy<br />
Jamming and shear banding in two dimensional suspensions<br />
16:45-17:00 S10 Surajit Saha<br />
Phonon anomaly in pyrochlore spin-ice Dy2Ti2O7 and nonmagnetic<br />
Lu2Ti2O7: A temperature dependent Raman and x-ray<br />
study<br />
17:00-17:15 S11 K Vijay Kumar<br />
Brownian Inchworm Model of a Self-propelled particle<br />
Day 2<br />
(25/11/<strong>2008</strong>)<br />
09:00-10:25 SESSION IV<br />
Chair: V. Venkataraman
09:00-09:20 F7 Ramesh Chandra Mallik<br />
Thermoelectric Properties of Co4Sb12 Skutterudite Materials with<br />
In Addition<br />
09:20-09:40 F8 Diptiman Sen<br />
Scattering of electrons from an interacting region<br />
09:40-09:55 S12 Prasad Perlekar<br />
Statistically Steady Turbulence in Soap Films: Direct Numerical<br />
Simulations with Ekman Friction<br />
09:55-10:10 S13 Samriddhi Sankar Ray<br />
Hyperviscosity, Bottlenecks and New Surprises in the Galerkintruncated<br />
Burgers Equation<br />
10:10-10:25 S14 Avatar Tulsi<br />
General framework for quantum search algorithms<br />
10:25-11:00 TEA<br />
11:00-12:40 SESSION V<br />
Chair: S. V. Bhat<br />
11:00-11:20 F9 S. Ramakumar<br />
Crystal Structures of native and substrate complex of an alkali<br />
thermostable xylanase from an alkalophilic Bacillus sp. NG-27.<br />
Structural insights into alkalophilicity.<br />
11:20-11:40 F10 Arindam Ghosh<br />
Intrinsic magnetism in high-mobility semiconductor – a bottom-up<br />
route to spin-electronics?<br />
11:40-11:55 S15 D. Samal<br />
The incongruous observation of phase separation in La0.85<br />
Sr0.15CoO3 spin –glass system<br />
11:55-12:10 S16 Amrita Singh<br />
New electrochemistry based route to Materials Engineering in<br />
Nanoscale Systems<br />
12:10-12:25 S17 M Suheshkumar Singh<br />
Ultrasound-modulated Diffuse Optical Tomographic Imaging<br />
System for Screening Breast Cancer<br />
12:25-12:45 P2 Norio Kikuchi<br />
A filament in an active medium: buckling, stiffening and negative<br />
dissipation<br />
VOTE <strong>OF</strong> THANKS BY CHAIRMAN
POSTERS<br />
No<br />
P1<br />
P2<br />
P3<br />
P4<br />
P5<br />
P6<br />
P7<br />
P8<br />
P9<br />
P10<br />
P11<br />
P12<br />
P13<br />
P14<br />
P15<br />
P16<br />
Name Title<br />
Arjun Joshua and V. Venkataraman<br />
Enhancement of sensitivity of detection of Kerr rotation by time averaging<br />
Vikram Rathee, Sajal Kumar Ghosh, Rema Krishnaswamy, V. A. Raghunathan<br />
and A. K. Sood<br />
Reentrant phase behavior of a mixed surfactant system with strongly binding<br />
counter-ions<br />
Geetanjali, D. Banerjee and S V Bhat<br />
Structural, magnetic and EMR studies of CaMnO3 nanoparticles<br />
Sayak Ghoshal and P.S.Anil Kumar<br />
Magnetic and Magnetotransport studies of ZnO films with and without intrinsic<br />
magnetic moment<br />
Sumilan Banerjee, Chandan Dasgupta, and T. V. Ramakrishnan<br />
Ginzburg Landau Theory for Cuprate Superconductivity<br />
Suropriya Saha and Sriram Ramaswamy<br />
Non Equilibrium noise in electrophoresis: the micro-ion wind<br />
Sakshath. S. and P. S. Anil Kumar<br />
Magnetic Anisotropy in Epitaxial Fe/MgO films grown by Pulsed Laser<br />
Deposition<br />
Debangsu Roy, and P.S. Anil Kumar<br />
Observation of the exchange spring behavior in hard-soft- ferrite nanocomposite<br />
Biswanath Chakraborty, Anindya Das and A.K. Sood<br />
Probing the local stress in Graphene by Raman Spectroscopy<br />
Chinkhanlun Guite and V. Venkataraman<br />
Electrical detection of spin polarized electrons in semiconductors using a radiofrequency<br />
pick-up coil<br />
Anupam Gupta, Prasad Perlekar, and Rahul Pandit<br />
Polymer Addtives in Decaying Two-Dimensional Turbulence<br />
Smarajit Karmakar, Chandan Dasgupta and Srikanth Sastry<br />
Numerical study of a glass forming liquid in two dimensions to test the dimension<br />
dependence of the Adam-Gibbs relation<br />
Ramakanta Naik,R.Ganesan,K.S.Sangunni.<br />
Compositional dependence of the optical changes in (As2S3)1-xSbx chalcogenide<br />
film.<br />
Nitin P. Lobo and K.V. Ramanathan<br />
Measurement of Heteronuclear dipolar couplings- A systematic study of cross<br />
polarization dynamics for Separated Local Field (SLF) experiments<br />
S.M. Mohanasundaram and Arindam Ghosh<br />
Detection of microcantilever deflection using electron transport measurements<br />
Chandni U and Arindam Ghosh<br />
A fluctuation-based probe to criticality in structural transitions
P17<br />
P18<br />
P19<br />
P20<br />
P21<br />
P22<br />
P23<br />
P24<br />
P25<br />
P26<br />
P27<br />
P28<br />
Jayakrishna Khatei and K.S.R. Koteswara Rao<br />
Temperature dependent photoluminescence study in Hg1-xCdxTe (x~0.8) nano<br />
and microcrystals<br />
Alok Ranjan Nayak, T.K. Shajahan, and Rahul Pandit<br />
The Dependance of Spiral-Wave Dynamics on Inhomogeneities in the TNNP<br />
Model of Cardiac Tissue<br />
Nitin Kumar, Sayantan Majumdar, Aditya Sood, Rama Govindarajan, Sriram<br />
Ramaswamy and A.K. Sood<br />
Motion of falling spheres and rising bubbles in a viscoelastic gel: spontaneous<br />
oscillations and bursting<br />
Sayantan Majumdar and A.K. Sood<br />
Negative viscosity fluctuations and their universality in a driven repulsive<br />
colloidal glass<br />
Aditya A. Wagh, H.L.Bhat, P. S. Anil Kumar and Suja Elizabeth<br />
MAGNETOTRANSPORT STUDIES <strong>OF</strong> FLOAT ZONE-GROWN Gd1-<br />
xSrxMnO3 S<strong>IN</strong>GLE CRYSTAL<br />
Paramita Kar Choudhury, Debjani Bagchi, and Reghu Menon<br />
Conformational modification by conjugation length and solvent in rigid-rod<br />
organic semiconductor<br />
K Jugeshwar Singh, G Clark, K P Ramesh and Reghu Menon<br />
H-NMR and charge transport in metallic polypyrrole at ultra-low temperatures<br />
and high magnetic fields<br />
Atindra Nath Pal and Arindam Ghosh<br />
Resistance noise in electrically biased bilayer graphene<br />
Meghana Dharmik and Prabal Maiti<br />
Structure and stability of carbon and boronnitride nanorings<br />
R.Koushik and Arindam Ghosh<br />
Conductivity noise in strongly correlated systems<br />
Manas Khan and A. K. Sood<br />
Out-of-Equilibrium Microrheology to Probe Directional Viscoelastic Properties<br />
under Shear<br />
Biswaroop Mukherjee, Prabal K. Maiti, Chandan Dasgupta and A. K. Sood<br />
Jump reorientation of water molecules confined in narrow carbon nanotubes
TALK<br />
ABSTRACTS
The surprisingly flattened dark matter halo of the Andromeda Galaxy<br />
Chanda J. Jog<br />
The rotation curve of a spiral galaxy is normally used to deduce its dark matter<br />
halo content. Another complementary constraint is provided by the vertical scaleheights<br />
of the interstellar gas, but this has not been exploited much in the literature.<br />
We use both these for the nearby Andromeda galaxy to determine its halo density<br />
distribution (Banerjee & Jog <strong>2008</strong>, Astrophysical Journal, 685, 254). We<br />
model the galaxy as a gravitationally coupled star-gas system responding to the<br />
external force-field of the dark matter halo. We show that a highly flattened oblate<br />
halo with an axis ratio of 0.4, and an isothermal density profile, provides the best<br />
fit to the observed data. The flattened shape of the dark matter halo is a robust<br />
result, and is strikingly different from the spherical shape generally assumed. This<br />
has important implications for galaxy formation which will be discussed.<br />
A similar approach has been applied to the low surface brightness galaxy UGC<br />
7321 for which the scaleheight information is available. Here the best-fit result from<br />
our model implies high gas dispersion, this could explain the low star formation seen<br />
in this galaxy (Banerjee, Matthews & Jog <strong>2008</strong>, Mon. Not. Roy. Astron.<br />
Soc., submitted).<br />
1
Novel Physics in Hetero-structures of Strongly Correlated<br />
Materials<br />
H. R. Krishnamurthy<br />
Department of Physics, Indian Institute of Science<br />
The study of hetero-structures constructed out of strongly correlated materials,<br />
such as oxides, has been attracting a lot of attention recently. One of the reasons for<br />
interest in these systems is that new physical phenomena emerge in these heterostructures<br />
that are absent in the bulk materials they are composed from. I will review a<br />
few recent examples, like the appearance of two-dimensional electron gases at the<br />
interfaces between band and Mott insulators, and their low-temperature<br />
superconductivity, and discuss the physics involved. I will end with a brief discussion of<br />
our recent research [1], showing the possibility of another such striking, quantum<br />
emergent phenomenon, namely that at sufficiently low temperatures, a finite width Mott<br />
insulator sandwiched between two metallic leads could display perfect dc conductance.<br />
[1] H. Zenia , J.K. Freericks, H. R. Krishnamurthy,Th. Pruschke : arXiv:0809.4993v1
Polymer nanocomposites near glass transition : Role of interface<br />
S.Srivastava and J.K.Basu<br />
Department of Physics<br />
The unique optical, thermo mechanical, electronic properties of polymer nanocomposite<br />
provide opportunities for better understanding of certain fundamental aspects of polymer<br />
nanocomposite. Recent experiments show that such drastic change in properties results<br />
due to possibility of the existence of a region with modified property at the nanoparticlepolymer<br />
interface as well as due to confinement .Thermal property, importantly, Glass<br />
transition is effected significantly which is an important property in determining the<br />
suitability of a polymer nanocomposite for many application. Thus to understand the<br />
dynamics of the polymer segments at interface needs to be probed with high resolution<br />
technique to relate this to macroscopic properties like visco-elasticity, glass transition<br />
(T g ), etc. To address this issue we have performed highly sensitive modulated differential<br />
scanning calorimetry (MDSC) measurements of glass transition of<br />
polymethylmethacrylate (PMMA) capped gold nanoparticles dispersed in same matrix.<br />
Experiments have shown that T g decreases for non-interactive metal-polymer interface<br />
and increases for the attractive interaction, however we have shown for the first time the<br />
cross over in the sign of the shift of T g for a neutral polymer-metal interface[1]. The<br />
dynamics of polymer segments at the metal - polymer interface can be controlled by the<br />
variation of the interfacial width, σ, which is an important parameter to study<br />
confinement effect on the polymer glass transition.. We have used a new parameter,<br />
nanoparticle-polymer interfacial width, σ, in elucidating role of surface effects on glass<br />
transition of polymers. Our results [2] show that interfacial width less than characteristic<br />
length, ξ, results in reduction and more than it gives rise to enhancement in the glass<br />
transition temperature of the polymer.<br />
To study the effect of interface on the dynamics of such systems we have performed X-<br />
ray photon correlation spectroscopy measurements . Measurements performed at various<br />
temperatures around the glass transition temperature of the polymer nanocomposite<br />
powders revealed intriguing differences in the respective wave vector dependent<br />
intermediate scattering function elucidating the role of interface morphology [3] in<br />
determining the relaxation dynamics, especially a gel - to –attractive glass transition,<br />
References:<br />
1). S.Srivastava and J.K. Basu, J. Nanoscience and Nano Technology 7, 2101, 2007.<br />
2). S.Srivastava and J.K. Basu, Physical Review Letter 98, 165701, 2007.<br />
3). S. Srivastava , A. K. Kandar, and J. K. Basu, M.K. Mukhopadhyay, and S. Narayanan<br />
(Manuscript under review).
Observation of low temperature Persistent Photoconductivity in flower<br />
shaped dendritic PbS structures<br />
Naresh Babu Pendya, K.S.R.K.Rao<br />
Semiconductor Lab, Department of Physics, I.I.Sc. Bangalore-560012<br />
Abstract<br />
Persistent Photoconductivity (PPC) has been observed in flower shaped PbS dendrite<br />
structures upto 220 o K for first time. Potential variation due to the presence of various<br />
sized particles might be the cause for the PPC. PPC relaxation behavior can be well<br />
β<br />
described by a stretched-exponential function I ( t) = I (0)exp[ −( t τ) ]( β ≺ 1) where<br />
τ is the relaxation time constant and β the decay exponent. The photocurrent build-up<br />
curves can be described by an equivalent stretched-exponential function<br />
I ( t) = I [1 −exp( − ( αt) β ] . Along with the PPC, we also observed Negative Persistent<br />
ppc<br />
max<br />
Photoconductivity (NPPC) below 40 o K, and above which it is Positive Persistent<br />
Photoconductivity (PPPC). A metastable state at 40 K might be the reason for the above<br />
observations. The exact nature of the metastable state is not known at present. These<br />
primary results certainly encourage us to do more measurements on this system as well<br />
on other dendrite structures.<br />
ppc<br />
ppc
Fabrication and Electrical Characterization of Charge Transfer Molecular Wires<br />
T.Phanindra Sai *, 1 and A.K.Raychaudhuri 1, 2<br />
1 Department of Physics, Indian Institute of Science, Bangalore-560012<br />
2 Unit for Nanoscience, S.N.Bose National Center for Basic Sciences,<br />
Salt Lake Kolkata-700 098<br />
----------------------------------------------------------------------------------------------------<br />
The aim of the present work was to grow isolated molecular wires of charge transfer complex and<br />
study their electrical and transport properties. The molecular wires were grown using thermal coevaporation<br />
technique, where the donor and acceptor charge transfer molecules are simultaneously<br />
evaporated form two different crucibles in a vacuum chamber on to a lithographically patterned<br />
substrates. An electric field is also applied between anode and cathode to enhance the growth of the<br />
molecular wires. The donor materials used were TMTTF and TTF and the acceptor was TCNQ. The<br />
substrate is also maintained at a constant temperature during evaporation. SEM images of the molecular<br />
wires grown across wider and larger electrode gaps showed that each molecular wire consists of bunches<br />
of smaller wires of diameter 200 nm in the case of TMTTF-TCNQ samples and even 50 nm in the case<br />
of TTF-TCNQ wires. We are interested in studying the properties of the single molecular wire of these<br />
charge transfer molecules of different widths ranging from 500 nm down to 50 nm. To fabricate single<br />
molecular wires e beam lithography was used to write contact pads with reduced electrode gaps and<br />
electrode widths onto silicon oxide substrates. A resistance vs temperature measurement of the grown<br />
molecular wires shows a semiconductor like behavior whereas previous studies on single crystals of<br />
TTF-TCNQ molecules have shown metallic behavior. This happens because the wires grown by thermal<br />
evaporation does not have the 1:1 stiochiometry due to different vapor pressures of TTF and TCNQ<br />
molecules.<br />
* Tetrathiafulvalene (TTF), Tetracayanoquinodimethane (TCNQ), Trimethyltetrathiafulvalene (TMTTF).
Growing length and time scales in glass forming liquids<br />
Smarajit Karmakar 1 , Chandan Dasgupta 1,2 , Srikanth Sastry 2<br />
1 CCMT, Department of Physics, Indian Institute of Science, Bangalore<br />
2 Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore<br />
Explaining the enormous increase in the viscosity and relaxation time of a liquid<br />
upon supercooling is essential for an understanding of the structural glass transition.<br />
Although the notion of a growing length scale of “cooperatively rearranging regions”<br />
is often invoked to explain dynamical slow down, the role of length scales relevant<br />
to glassy dynamics is not well established. Recent studies of spatial heterogeneity<br />
in the local dynamics provide fresh impetus in this direction. Using finite-size<br />
scaling for the first time for a realistic glass former, we establish that the growth<br />
of dynamical heterogeneity with decreasing temperature is governed by a growing<br />
dynamical length scale. However, the dependence of the simultaneously growing<br />
relaxation time on system size does not exhibit the same scaling behaviour as the<br />
dynamical heterogeneity. We show that the relaxation time is instead determined,<br />
for all studied system sizes and temperatures, by the configurational entropy, in<br />
accordance with the Adam-Gibbs relation, but in disagreement with the prevailing<br />
belief that the configurational entropy is not relevant above the critical temperature<br />
of mode coupling theory. These results provide new insights into the dynamics of<br />
glass-forming liquids and pose serious challenges to existing theoretical descriptions.
Nanophotonics with Quantum Dot Arrays and Optical Near Fields.<br />
Haridas M and Jaydeep Basu<br />
Nanophotonics, which involves local electromagnetic interactions between nanometerscale<br />
materials and an optical near field (ONF), promises to open the doors towards next<br />
generation technology for quantum information processing using light and quantum<br />
devices. ONF's are characterised by the presence of optical fields with high lateral spatial<br />
frequencies able to excite surface states not accessible by means of conventional far-field<br />
optical excitations including possibilities of exciting dipole-forbidden states. Scanning<br />
Near field Optical Microscopy (SNOM) is recently developed experimental technique<br />
used to produce such ONF and combines the advantages of the relatively new scanning<br />
probe based microscopy, with the rich and well developed field optical spectroscopy.<br />
SNOM has been widely used to study single and coupled quantum dots as well as<br />
metallic nanostructures. Most of the experimental and theoretical studies limited to<br />
studying very small number of ideal quantum dots which are homogeneous and are<br />
arranged an in an ordered manner without disorder. However, for any potential device<br />
applications, the real system would involve a large array of QDs in which both<br />
inhomogenity and disorder would be present. Studying the coupling of ONF with such a<br />
QD array would lead to a understanding of not only the differences with the far- field<br />
spectra but also the role of disorder and inhomogenity in the near field spectra of large<br />
scale QD arrays.<br />
Here we will discuss the use of SNOM to study coupling between ONF and excitons in<br />
large scale arrays of CdSe QD. The PL spectra collected in SNOM mode and in confocal<br />
mode (far field) from the CdSe based QD arrays shows striking differences. We also<br />
compare the spatially resolved PL spectra collected in SNOM mode from different region<br />
of the QD array and find coupling fine structure in such spectra. We discus the possible<br />
sources of such fine structures and point to the need for a unified theory to treat the ONF<br />
and excitons in QD arrays as a single coupled quantum system.<br />
Reference:<br />
1. Haridas M and J. K. Basu (submitted)<br />
2. Haridas M and J. K. Basu (manuscript in preparation)<br />
3. Haridas M and J. K. Basu (manuscript in preparation)
Diffuse optical tomographic non-invasive breast and brain imager using a single laser<br />
light source<br />
S. K. Biswas 1 , K. Rajan 1 , and R. M. Vasu 2<br />
Department of Physics 1<br />
Department of Instrumentation 2<br />
Indian Institute of Science, Bangalore, 560012 India.<br />
Near-Infrared (NIR) diffuse optical tomography technique has the capability of providing good<br />
quantitative reconstruction of distribution of tissue absorption and scattering parameters with additional<br />
inputs such as input and output modulation depth and photon leakage correction through<br />
the measurement process. The light transport through a tissue is diffusive in nature and can be<br />
modeled using diffusion equation (DE). The optical parameters of the inhomogeneity can be recovered<br />
if they are close to the optical properties of the background. Diffusion equation for photon<br />
transport is solved using Finite Element Method (FEM) and Jacobian is modeled for reconstructing<br />
the optical parameters of the object. We study the development and performance of DOT system<br />
using 100MHz modulated single laser source and multiple detectors. The theory has been evolving<br />
continuously over the past 15 years but very few has come forward to implement and handover a<br />
product to human society. Diffuse Optical Tomography (DOT) is a promising tool for non-invasive<br />
imaging of deep tissue. To reduce the gap between the theory and the experiment we have calculated<br />
the 2-D input modulation depth from 3-D diffusion to model the 2-D diffusion of photons. The<br />
photon leakage when light traverses from fiber tip to the phantom is estimated using a solid angle<br />
model. We study the development and performance of DOT system using 100MHz modulated single<br />
laser source and multiple detectors. The experiment is carried out with 5mm, 6mm 8mm (diameter)<br />
inhomogeneities with absorption coefficient almost three times as that of the background. The<br />
experimental result shows that our single source system with additional inputs such as separated<br />
2-D input/output modulation depth from 3-D diffusion and weighted air fiber interface correction is<br />
capable of detecting 5mm 6mm and 8mm separately and can identify the size difference of multiple<br />
inhomogeneities with zero localization error.<br />
FIG. 1: Reconstructed results from Experimental data for single as well as multiple inhomogeneities with different sizes. The<br />
size of inhomogeneities are 5mm shown in Fig.1:a and 6mm , 8mm shown in Fig.1b . The reconstructed image shows the exact<br />
positions of inhomogeneities as it were in the phantoms that we used in our experiment.
High pulsed field magnetotransport and hole mobility in HgCdTe<br />
Murthy O.V.S.N., V. Venkataraman, R.K. Sharma<br />
Mercury Cadmium Telluride, despite competition, is still a material of choice for<br />
manufacturers of infrared detectors especially in the 10 μm region due to its high<br />
efficiency. Being a narrow gap semiconductor, its physics is much different from the<br />
Si/GaAs genus. A study on magnetotransport in bulk as well as epilayers of HgCdTe at<br />
both low and high temperatures is presented.<br />
We have designed, constructed and calibrated high performance pulsed magnets<br />
operating upto 17T from 77K-300K and 12T down to 4K for magnetotransport<br />
measurements [1]. Data is obtained using a fast A/D card and analyzed using digital lockin<br />
method.<br />
The composition of the samples under study is determined using optical absorption<br />
measurements. High magnetic fields are required to probe low mobility holes owing to<br />
the electronic domination of conductivity at low B even in p-type samples. Multicarrier<br />
analysis is used to extract mobilities and densities from the measured mixed conductivity<br />
tensor upto 15T. Hole mobility at higher temperatures from 200K-300K in magnetic<br />
fields is investigated using a hybrid method by various scattering mechanisms. We have<br />
solved Boltzmann transport equation numerically without relaxation time approximation<br />
[2] to include polar optical phonon scattering. Other scattering mechanisms taken into<br />
account with or without using relaxation time approximation [3] are: ionized impurity,<br />
nonpolar optical, acoustic, dislocation, alloy disorder and piezoelectric. Results are<br />
presented comparing our data with the calculated mobility.<br />
[1] Murthy O.V.S.N., Venkataraman V., Rev. Sci. Instrum. 78, 113905 (2007)<br />
[2] Rode, D.L., Phys. Rev. B 2, 1012 (1970)<br />
[3] Yadava, R.D.S. et al, J. Electron Mater. 23, 1359 (1994)
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Force Induced DNA Melting<br />
Mogurampelly Santosh † and Prabal K Maiti *<br />
Center for Condensed Matter Theory, Department of Physics,<br />
Indian Institute of Science, Bangalore12<br />
Abstract<br />
When pulled along the axis, doublestrand DNA undergoes a large conformational<br />
change and elongates roughly twice its initial contour length at a pulling force about<br />
70 pN. The transition to this highly overstretched form of DNA is very cooperative.<br />
Applying force perpendicular to the DNA axis (unzipping), doublestrand DNA can<br />
also be separated into two singlestranded DNA which is a fundamental process in<br />
DNA replication. We study the DNA overstretching and unzipping transition using<br />
fully atomistic molecular dynamics (MD) simulations and argue that the<br />
conformational changes of double strand DNA associated with either of the above<br />
mentioned processes can be viewed as force induced DNA melting. As the force at<br />
one end of the DNA is increased the DNA start melting abruptly/smoothly after a<br />
critical force depending on the pulling direction. The critical force f m , at which DNA<br />
melts completely decreases as the temperature of the system is increased. The melting<br />
force in case of unzipping is smaller compared to the melting force when the DNA is<br />
pulled along the helical axis. In the cases of melting through unzipping, the doublestrand<br />
separation has jumps which correspond to the different energy minima arising<br />
due to different base pair sequence. The fraction of WatsonCrick base pair hydrogen<br />
bond breaking as a function of force does not show smooth and continuous behavior<br />
and consists of plateaus followed by sharp jumps.<br />
†<br />
santosh@physics.iisc.ernet.in<br />
*<br />
maiti@physics.iisc.ernet.in
Ultrafast electron dynamics and cubic optical nonlinearity of single<br />
and double walled carbon nanotubes.<br />
N. Kamaraju, Sunil Kumar, B. Karthikeyan and A. K. Sood<br />
Department of Physics, Centre for Ultrafast Laser Applications, Indian Institute of<br />
Science, Bangalore-560012.<br />
We have studied cubic optical nonlinearities of single walled carbon nanotube (SWNT)<br />
suspensions and a free standing thin film of double walled carbon nanotubes (DWNT) using 790<br />
nm, 80 femtosecond light pulses in open and closed aperture z-scan experiments. The nanotube<br />
suspensions were prepared in water using sodium dodecyl sulphate [1] and by microwave<br />
treatment with amide functionalization [2]. We have developed a modified theoretical expression<br />
to analyze the z-dependent transmission (both open and closed aperture) in the saturable limit.<br />
This gives a value of Im (χ (3) ) ~ 4.9 x 10 -10 (0.45 x10 -10 ) esu and Re (χ (3) ) ~ 5.4 x 10 -10 (2.2 x10 -9 )<br />
esu for SWNT (DWNT). Degenerate femtosecond pump-probe experiments (790nm, 80 fs) to<br />
investigate [3] the optical switching time and the underlying ultrafast electron dynamics in<br />
DWNT show ultrafast (97 fs) photo bleaching followed by a photo-induced absorption with a<br />
slow relaxation of 1.8 ps, whereas microwave treated SWNT suspension shows a bi-exponential<br />
ultrafast photo-bleaching with time constants of 160 fs (130 fs) and 920 fs (300 fs) for water<br />
soluble (amide functionalized) nanotubes.<br />
We thank Department of Science and Technology for financial support. This work was<br />
done in collaboration with Bhalchandra Kakade, Vijayamohanan K. Pillai, Alexander Moravsky,<br />
R. O. Loutfy, Srini Krishnamoorthy, Shekhar Guha and C. N. R. Rao.<br />
Reference:<br />
1. “Large nonlinear absorption and refraction coefficients of carbon nanotubes estimated<br />
from femtosecond z-scan measurements”, N. Kamaraju, Sunil Kumar, Srinivasan<br />
Krishnamurthy, Shekhar Guha, A. K. Sood, C. N. R. Rao. Appl. Phys. Lett. 91, 251103<br />
(2007).<br />
2. “Ultrafast electron dynamics and cubic optical nonlinearity of free standing thin film of<br />
double walled carbon nanotubes”, N. Kamaraju, Sunil Kumar, B. Karthikeyan,<br />
Alexander Moravsky, R. O. Loutfy and A. K. Sood. Appl. Phys. Lett. 93, 091903 (<strong>2008</strong>).<br />
3. “Ultrafast switching time and third order nonlinear coefficients of microwave treated<br />
single walled carbon nanotube suspensions”, N Kamaraju, Sunil Kumar, B. Karthikeyan,<br />
Bhalchandra Kakade, Vijayamohanan K. Pillai and A. K. Sood, J. Nanoscience and<br />
Nanotech. (<strong>2008</strong>).
Nonequilibrium Fluctuations in Sheared<br />
Jammed States<br />
A.K. Sood<br />
Department of Physics, Indian Institute of Science<br />
Bangalore 560 012, India.<br />
Recently we have shown that the shear rate at a fixed shear stress in a<br />
micellar hexagonal phase exhibits large fluctuations, including several negative<br />
values [1]. The probability distribution functions (PDF’s) of the global power<br />
flux to the system derived from the shear rate fluctuations are Gaussian or non-<br />
Gaussian, depending on the external drive (applied stress) on the system. In<br />
both cases, the PDF is consistent with the Gallavotti-Cohen steady state<br />
fluctuation theorem. We show that an effective temperature of the jammed state<br />
can be measured using fluctuation theorem. Interestingly, the non-Gaussian PDF<br />
of the global power flux to the system matches exactly with one of the universal<br />
extreme value distribution.<br />
1. S. Mazumdar and A.K. Sood, Phys. Rev. Lett. 101, 78301 (<strong>2008</strong>).
Extended Einstein-Hilbert (E-H) action and the emergence of Riccions as<br />
cosmic dark matter and consequent cosmic acceleration<br />
K.P.Sinha<br />
<strong>IN</strong>SA Honorary Scientist<br />
Department of Physics<br />
Indian Institute of Science<br />
Bangalore 560 012.<br />
Abstract:<br />
When higher-order curvature terms are added to E-H action Ricci<br />
scalars behave as a massive physical field and obey Klein-Gordon type<br />
equation. These particles are called Riccions. The role of riccions<br />
as cosmic dark matter is explored. It is found that the universe will<br />
accelerate when appropriate conditions are satisfied particularly in<br />
the later period of the evolution of the universe.<br />
The dual nature of the Ricci scalar in the present model solve<br />
many problems such as the removal of the gravitation singularity1,<br />
creation of spinless particles2 , the creation of spin particles and<br />
antiparticles3 and the dominance of baryonic matter besides being the<br />
source of dark matter4<br />
References:<br />
1. S.K.Srivastava and K.P.Sinha, Phys. Lett. B 307, 40 (1993)<br />
2. K.P.Sinha and S.K.Srivastava, Pramana 44, 333 (1995)<br />
3. S.K.Srivastava and K.P.Sinha, Mod. Phys. Lett A 12, 2933 (1997)<br />
4. S.K.Srivastava and K.P.Sinha, Mod. Phys. Lett A. (in press)
Low frequency vibrational modes in carbon nanotubes:<br />
terahertz time domain spectroscopy<br />
Sunil Kumar 1 , N. Kamaraju 1 , Marc Tondusson 2 , E. Freysz 2 and A. K. Sood 1,*<br />
1 Department of Physics and Center for Ultrafast Laser Applications,<br />
Indian Institute of Science, Bangalore 560 012, India<br />
2 CPMOH, Universite de Bordeaux I, 351, Cours de la liberation, 33405 Talence cedex, Fance<br />
* Electronic address: asood@physics.iisc.ernet.in<br />
Ultrafast terahertz time domain spectroscopy (THz-TDS) has been used to study the far<br />
infrared (FIR) optical properties of double walled carbon nanotubes (DWNTs) in the 0.1-<br />
3.0 THz frequency range. The 200 nm freely standing DWNT film, used in our<br />
experiments works as a THz filter in the time domain as the input THz power is cut by<br />
almost half while the spectral transmission remains almost constant in the 0.1-2.0 THz<br />
range. This feature, usually expected for metallic substrates with patterned whole arrays<br />
[1] or metamaterials with artificial structures [2], suggests a possible application of such<br />
films of carbon nanotubes (CNTs) for real time control and modulation of THz radiation.<br />
The spectral dielectric response of the film shows small but distinct resonant dispersive<br />
features at frequencies, 0.46 and 0.76 THz related to the very low frequency flexural<br />
modes of vibration around the tube axis. Such low frequency phonon modes in CNTs had<br />
been predicted theoretically [3, 4] but so far could not be detected experimentally. In<br />
addition we have observed a broad absorption band at around 1.45 THz similar to that<br />
seen in single walled CNTs (SWNTs) attributed to the electronic excitation across the<br />
FIR band gap induced by intertube coupling and curvature in bundles of metallic<br />
nanotubes [5]. The optical conductivity was measured to be very high, of the order of<br />
2x10 14 sec -1 which confirms the metallic nature of the film (optical conductivity of metals<br />
~ 10 16 sec -1 ).<br />
References<br />
1. C. L. Pan, C. F. Hsieh, R. P. Pan, M. Tanaka, F. Miyamaru, M. Tani, M. Hangyo, Opt.<br />
Exp. 13, 3921 (2005).<br />
2. H. T. Chen, W. J. Padilla, J. M. O. Zide, A. C. Gossard, A. J. Taylor, Nature 444, 597<br />
(2006).<br />
3. H. Suzuura, T. Ando, Phys. Rev. B 65, 235412 (2002).<br />
4. G. D. Mahan and Gun Sang Jeon, Phys. Rev. B 70, 075405 (2004).<br />
5. M. Ouyang, J. L. Huang, C. L. Cheung, C. M. Lieber, Science 292, 702 (2001).
Jamming and shear banding in two dimensional suspensions<br />
Sayantan Majumdar, Rema Krishnaswamy and A. K. Sood<br />
The flow behaviour of jammed systems which exhibit a solid-like elastic behaviour at<br />
low shear stress and flow above a critical yield stress is often described by<br />
phenomenological models, where a homogenous flow is predicted at a fixed shear<br />
stress. Recent studies however, indicate that most jammed systems unjam through the<br />
formation of shear bands where only part of the system flows. Two dimensional (2D)<br />
colloidal suspensions where the flow behaviour can be visualized relatively easily are<br />
eminently suited for understanding the role of the microstructure in determining the<br />
jamming or yielding behaviour. I will discuss some of our recent studies where we<br />
investigate the viscoelastic and flow behaviour of dense monodisperse and bidisperse<br />
2D colloidal suspensions formed at fluid interfaces by combining surface rheology<br />
with optical microscopy.<br />
In densely packed colloidal monolayers at packing fractions > 0.8, the shear rate at a<br />
fixed shear stress exhibits large fluctuations with positive and negative values. The<br />
validity of Steady State Fluctuation Relation in these sheared two dimensional<br />
suspensions will also be examined.
Phonon anomaly in pyrochlore spin-ice Dy 2 Ti 2 O 7 and non-magnetic Lu 2 Ti 2 O 7 :<br />
A temperature dependent Raman and x-ray study<br />
Surajit Saha, 1 Surjeet Singh, 2 B. Dkhil, 3 S. Dhar, 4 R. Suryanarayanan, 2 G. Dhalenne, 2<br />
A. Revcolevschi, 2 and A. K. Sood 1<br />
1 Department of Physics, Indian Institute of Science, Bangalore, India.<br />
2 Laboratoire de Physico-Chimie de l’Etat Solide,Universite Paris-Sud, Orsay, France.<br />
3 Laboratoire Structures, Ecole Centrale Paris, Chatenay-Malabry Cedex, France and<br />
4 Tata Institute of Fundamental Research, Mumbai, India<br />
Abstract<br />
We present here temperature-dependent Raman, x-ray diffraction and specific heat<br />
studies between room temperature and 12 K on single crystals of spin-ice pyrochlore<br />
compound Dy 2 Ti 2 O 7 and its non-magnetic analogue Lu 2 Ti 2 O 7 . Raman data show a “new”<br />
band not predicted by factor group analysis of Raman-active modes for the pyrochlore<br />
structure in Dy 2 Ti 2 O 7 , appearing below a temperature of T c =110 K with a concomitant<br />
contraction of the cubic unit cell volume as determined from the powder x-ray diffraction<br />
analysis. Low temperature Raman experiments on O 18 -isotope substituted Dy 2 Ti 2 O 7<br />
confirm the phonon origin of the “new” mode. These findings, absent in Lu 2 Ti 2 O 7 ,<br />
suggest that the room temperature cubic lattice of the pyrochlore Dy 2 Ti 2 O 7 undergoes a<br />
“subtle” structural transformation near T c . We find anomalous red-shift of some of the<br />
phonon modes in both the Dy 2 Ti 2 O 7 and the Lu 2 Ti 2 O 7 as the temperature decreases, which<br />
is attributed to strong phonon-phonon anharmonic interactions.
Brownian Inchworm Model of a Self-propelled particle<br />
K Vijay Kumar, 1, ∗ Adrian Baule, 2, † Sriram Ramaswamy, 1, ‡ and Madan Rao 3, §<br />
1 CCMT, Department of Physics, Indian Institute of Science, Bangalore 560012, India.<br />
2 The Rockefeller University, 1230 York Avenue, New York, NY 10065, USA.<br />
3 Raman Research Institute, Bangalore 560080, India.<br />
Directed motion without an imposed external gradient is seen not only in living systems but<br />
also in agitated granular matter. The essential ingredients are an external energy input and<br />
an inherent asymmetry. Unlike traditional “Brownian ratchet models”of directed motion,<br />
the asymmetry of interest in the above systems is internal to the motile objects, and does<br />
not lie in an external periodic potential.<br />
In this work, we present a Brownian inchworm model of a self-propelled elastic dimer<br />
in the absence of an external potential. Nonequilibrium noise together with a stretchdependent<br />
damping form the propulsion mechanism. The crucial asymmetry is in the<br />
stretch-dependence of the damping coefficients. Our model connects three key nonequilibrium<br />
features – position-velocity correlations, a nonzero mean internal force, and a drift<br />
velocity. Our analytical results, both perturbative calculations and an exact solution, display<br />
striking current reversals and compare very well with numerical simulations [1, 2]. The<br />
model unifies the propulsion mechanisms of DNA helicases, polar rods on a vibrated surface,<br />
crawling keratocytes and Myosin VI.<br />
∗<br />
Electronic address: vijayk@physics.iisc.ernet.in<br />
† Electronic address: abaule@rockefeller.edu<br />
‡ Electronic address: sriram@physics.iisc.ernet.in;<br />
Also at CMTU, JNCASR, Bangalore 560064, India.<br />
§ Electronic address: madan@rri.res.in; Also at NCBS (TIFR), Bangalore 560065, India.<br />
[1] K Vijay Kumar, S. Ramaswamy and M. Rao, Phys. Rev. E, 77, 020102(R), (<strong>2008</strong>).<br />
[2] Adrian Baule, K Vijay Kumar and Sriram Ramaswamy, J. Stat. Mech., P11008 (<strong>2008</strong>).
Thermoelectric Properties of Co 4 Sb 12 Skutterudite Materials with In Addition<br />
Ramesh Chandra Mallik * , Christian Stiewe, Gabriele Karpinski, Ralf Hassdorf, Eckhard Müller<br />
German Aerospace Center (DLR), Institute of Materials Research,<br />
D-51170 Cologne, Germany<br />
* Department of Physics, Indian Institute of Science, Bangalore, 560 012, India<br />
Abstract<br />
The properties of Co 4 Sb 12 with various In additions were studied. X-ray diffraction<br />
technique used for structural and phase analysis. The homogeneity and morphology of<br />
the samples were observed by the Seebeck microprobe and scanning electron<br />
microscopy, respectively. The temperature dependence of the Seebeck coefficient,<br />
electrical and thermal conductivity was measured from room temperature up to 673 K.<br />
The Seebeck coefficient of all In-added Co 4 Sb 12 materials was negative. When the In<br />
concentration increases, then the Seebeck coefficient decreases. The samples with In<br />
additions above the limit (x= 0.22) show an even lower Seebeck coefficient due to the<br />
formation of secondary phases: InSb and CoSb 2 . The temperature variation of the<br />
electrical conductivity is semiconductor-like. The thermal conductivity of all the samples<br />
decreases with temperature. The central region of the In 0.4 Co 4 Sb 12 ingot shows the lowest<br />
thermal conductivity probably due to the combined effect of (a) rattling due to maximum<br />
filling and (b) the presence of a small amount of fine -dispersed secondary phases at the<br />
grain boundaries. Thus, regardless of the non-single-phase morphology, a promising ZT<br />
value of 0.96 at 673 K has been obtained with an In addition above the filling limit.<br />
Email: rcmallik@physics.iisc.ernet.in
Scattering of electrons from an interacting region<br />
Diptiman Sen (CHEP)<br />
We study the problem of transmission of electrons through a region where they<br />
interact with each other. The two-particle problem turns out to completely solvable. We<br />
show that if there is no other source of scattering, the interactions always reduce the<br />
conductance from the value of 2e^2/h. But if the region itself causes scattering,<br />
interactions can either increase or decrease the conductance. We discuss the possibility of<br />
two-particle resonance, in which two particles with a particular value of the total energy<br />
can transmit through the region even though they cannot individually do so.<br />
Collaborators:<br />
Abhishek Dhar and Dibyendu Roy (RRI) and Abhiram Soori
Statistically Steady Turbulence in Soap Films: Direct Numerical Simulations with<br />
Ekman Friction<br />
Prasad Perlekar 1, ∗ and Rahul Pandit 1, †<br />
1 Centre for Condensed Matter Theory, Department of Physics,<br />
Indian Institute of Science, Bangalore 560012, India.<br />
We present a detailed direct numerical simulation (DNS) designed to investigate the combined<br />
effects of walls and Ekman friction on turbulence in forced soap films. We concentrate on the<br />
forward-cascade regime and show how to extract the isotropic parts of velocity and vorticity structure<br />
functions and thence the ratios of multiscaling exponents. We find that velocity structure functions<br />
display simple scaling whereas their vorticity counterparts show multiscaling; and the probability<br />
distribution function of the Weiss parameter Λ, which distinguishes between regions with centers<br />
and saddles, is in quantitative agreement with experiments.<br />
∗ Electronic address: perlekar@physics.iisc.ernet.in<br />
† Electronic address: rahul@physics.iisc.ernet.in;<br />
also at Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, Bangalore, India
Hyperviscosity, Bottlenecks and New Surprises in the Galerkin-truncated Burgers<br />
Equation 1<br />
Samriddhi Sankar Ray<br />
It is shown that the replacement in hydrodynamical equations of the usual dissipation by a high<br />
power α of the Laplacian leads asymptotically to truncating the dynamics to a a finite number<br />
of Fourier modes. When this number is large, a range of thermalized modes appear through the<br />
mechanism discovered by Cichowlas et al. The dynamics at small and intermediate wavenumbers<br />
is governed by the ordinary Navier–Stokes equations but a huge bottleneck in thermal equilibrium<br />
with Gaussian statistics is present at large wavenumbers. The usual (α = 1) bottleneck can be<br />
viewed as an aborted thermalization. Practical implications for turbulence modelling are discussed.<br />
We then discuss surprises in the Galerkin-truncated Burgers Equation.<br />
1. Hyperviscosity, Galerkin truncation and bottlenecks in turbulence,<br />
U. Frisch, S. Kurien, R. Pandit, W. Pauls, Samriddhi Sankar Ray, A. Wirth, and J-Z Zhu.<br />
Phys. Rev. Lett. 101, 144501.
General framework for quantum search algorithms<br />
Avatar Tulsi<br />
Department of Physics, Indian Institute of Science, Bangalore-560012, India.<br />
Grover’s quantum search algorithm drives a quantum computer from a<br />
prepared initial state to a desired final state by using selective transformations<br />
of these states. We present a framework when one of the selective<br />
transformations is replaced by a more general unitary transformation. Our<br />
framework encapsulates several previous generalizations of Grover’s algorithm<br />
like Kato’s algorithm, Ambainis’ algorithm for element distinctness<br />
problem, spatial search algorithms, and quantum random walk search algorithms.<br />
Our framework also explains the phase-matching condition.<br />
We discuss two applications of our framework. The first one is related<br />
to the problem of two-dimensional spatial search. The previous algorithms<br />
take √ N ln N steps to solve this problem, and it was an open question<br />
whether the performance can be improved. Our framework allows us to<br />
design a faster algorithm that solves the problem in √ N ln N steps. The<br />
second application is a better quantitative understanding of adiabatic search<br />
algorithms.<br />
References<br />
[1] General framework for quantum search algortihms<br />
Avatar Tulsi, quant-ph/0806.1257, Accepted for publication in Phys. Rev. A.<br />
[2] Faster quantum walk algorithm for the two-dimensional spatial search<br />
Avatar Tulsi, Phys. Rev. A 78, 012310 (<strong>2008</strong>).<br />
[3] Adiabatic quantum computation with a one-dimensional projector Hamiltonian.<br />
Avatar Tulsi, quant-ph/0806.0385, Accepted for publication in Phys. Rev. A.<br />
1
Crystal Structures of native and substrate complex of an<br />
alkali thermostable xylanase from an alkalophilic Bacillus<br />
sp. NG-27. Structural insights into alkalophilicity.<br />
Ramakumar, S.<br />
Department of Physics<br />
Indian Institute of Science, Bangalore – 560012, <strong>IN</strong>DIA<br />
Crystal structures are known for several glycosyl hydrolase family 10 (GH10) xylanases.<br />
However, none of them is from an alkalophilic organism that can grow in alkaline conditions.<br />
We have determined the crystal structures at 2.2 Å of a GH10 extracellular endoxylanase<br />
(BSX) from an alkalophilic Bacillus sp. NG-27, for the native and the complex enzyme with<br />
xylosaccharides. The industrially important enzyme is optimally active and stable at 343 K<br />
and at a pH of 8.4. Comparison of the structure of BSX with those of other thermostable<br />
GH10 xylanases optimally active at acidic or close to neutral pH showed that the solvent<br />
exposed acidic amino acids. Asp and Glu, are markedly enhanced in BSX, while solventexposed<br />
Asn was noticeably depleted. The BSX crystal structure when compared with<br />
putative three-dimensional homology models of other extracellular alkalophilic GH10<br />
xylanases from alkalophilic organisms suggests that a protein surface rich in acidic residues<br />
may be an important feature common to these alkali thermostable enzymes. A comparison of<br />
the surface features of BSX and of halophilic proteins allowed us to predict the activity of<br />
BSX at high salt concentrations, which we verified through experiments. This offered us<br />
important lessons in the polyextremophilicity of proteins, where understanding the structural<br />
features of a protein stable in one set of extreme conditions provided clues about the activity<br />
of the protein in other extreme conditions. The work brings to the fore the role of the nature<br />
and composition of solvent-exposed residues in the adaptation of enzymes to polyextreme<br />
conditions, as in BSX.
Intrinsic magnetism in high-mobility semiconductor – a bottom-up route to spinelectronics?<br />
Arindam Ghosh<br />
Ultra high-mobility GaAs/AlGaAs heterostructures are excellent systems for simulating<br />
elementary magnetic interactions with great control. The usual methods of generating magnetism in these<br />
semiconducting systems are two-fold: (1) defining quantum dot assemblies where each dot contains an odd<br />
number of electrons so that they play the role of d-electrons embedded in a metallic matrix, or (2) doping<br />
GaAs with magnetic atoms such as Mn. Here we propose a new route towards achieving a long-range<br />
magnetism in GaAs/AlGaAs heterostructures that does not require either formation of quantum dots or<br />
external doping of magnetic atoms. The idea is based on a two-component nature of background potential<br />
fluctuations in modulation-doped GaAs/AlGaAs systems which naturally trap localized spins at specific<br />
values of conduction electron density. A surface gate can modulate the mutual interaction between the<br />
spins, making the magnetic state tunable electrically. Although the present devices required the<br />
experiments to be carried out at sub-Kelvin temperature range, our experiments suggest that such a model<br />
can be utilized in realizing spin field-effect transistors in low-dimensional semiconductors over a wide<br />
parameter range.<br />
Ref:<br />
[1] A. Ghosh et al., Phys. Rev. Lett. 92, 116601 (2004);<br />
[2] A. Ghosh et al., Phys. Rev. Lett. 95, 066603 (2005).<br />
[3] C. Siegert, A. Ghosh, M. Pepper, I. Farrer and D. A. Ritchie, Nature Physics 3, 315 (2007).<br />
[4] C. Siegert, A. Ghosh, M. Pepper, I. Farrer, D. A. Ritchie, D. Anderson and G. A. C. Jones, Phys. Rev. B<br />
(<strong>2008</strong>).
The incongruous observation of phase separation in La 0.85 Sr 0.15 CoO 3<br />
spin –glass system<br />
D. Samal a , C. Shivakumara b and P.S. Anil Kumar a<br />
a Department of Physics, Indian Institute of Science, Bangalore, 560012, India<br />
b Solid State and Structural Chemistry Unit, Indian Institute of Science<br />
Phase separation in hole-doped Cobaltites (La 1-x Sr x Co x O 3 ) is drawing renewed interest recently.<br />
In particular, the magnetic behavior of La 0.85 Sr 0.15 CoO 3 has been subjected to a controversial<br />
debate for the last several years; while some groups show evidence for phase separation, others<br />
show spin glass behavior. An attempt is made to resolve the controversy related to “phase<br />
separation versus spin glass” behavior in this compound. Here, we present the results of<br />
comprehensive investigation of dc magnetization, ac susceptibility, and magnetotransport<br />
properties of La 0.85 Sr 0.15 CoO 3 samples. We contemplate that the phase separation in<br />
La 0.85 Sr 0.15 CoO 3 is neither intrinsic nor inherent but it is a consequence of the preparation<br />
conditions. It is realized that low temperature annealed sample (LTA) shows phase separation<br />
where as the high temperature annealed (HTA) sample shows pure spin glass behavior. The<br />
Brillouin like behavior of field cooled dc magnetization with temperature and apparently no<br />
frequency dependent peak shift in ac susceptibility for LTA sample characterizes it to be of<br />
ferromagnetic like where as a kink in field cooled dc magnetization and considerable amount<br />
(~3K) of frequency dependent peak shift in ac susceptibility for HTA sample characterizes it to<br />
be a pure spin glass state. The magneto transport properties show that the HTA sample is more<br />
semiconducting as compared to LTA sample. This is interpreted in terms of presence of isolated<br />
as well as coalescing metallic ferromagnetic clusters in case of LTA sample. Both LTA as well as<br />
HTA samples exhibit glassy transport phenomena i.e. glassy response to application or removal<br />
of application of magnetic field with respect to time. The magnetoresistance at 10K for HTA<br />
sample exhibits a huge value (~65%) as compared to the LTA sample and it monotonically<br />
decreases with rise in temperature. Such a high value of MR in case of HTA sample is strongly<br />
believed due to spin dependent part of random potential distribution. Further, the slow decay of<br />
remnant magnetization with progress of time and existence of hysteresis at higher temperatures<br />
(up to 200K) in case of LTA sample as compared to HTA sample clearly unveils different<br />
magnetic states associated with them.<br />
e-mail: debphy@physics.iisc.ernet.in
New electrochemistry based route to Materials Engineering in Nanoscale Systems.<br />
Amrita Singh and Arindam Ghosh<br />
Department of Physics, Indian Institute of Science, Bangalore, 560012<br />
By appropriate engineering of electro-deposition technique, we have realized silver nanowires (AgNWs) in both hcp<br />
and fcc phase at room temperature. The nanowires stabilized in high energy 4H phase [1], exhibit some exotic<br />
properties. The measured noise level is heavily suppressed in 4H AgNWs as compared to fcc silver nanowires which<br />
is attributed to restricted dislocation dynamics in hexagonal crystal structure [2]. The time resolved transmission<br />
electron microscopy (TEM) shows a kinemetically new growth mechanism during electro-deposition. We observe a<br />
temperature independent noise behavior in hcp AgNWs, which is uncommon for metals. Moreover, these nanowires<br />
also exhibit a temperature induced phase transformation and acquire an unconventional fcc phase at low<br />
temperatures, which is supported by temperature dependent TEM measurement, higher order resistance fluctuation<br />
spectroscopy and Differential Scanning Calorimetry. Thus, the electron transport results pave a new understanding<br />
of the crystal structure dependent microscopic origin of noise in single crystal nanowires and our growth<br />
technique promises to produce high quality nano-materials with unprecedented control on its electrical and structural<br />
properties.<br />
[1] Amrita Singh and Arindam Ghosh, J. Phys. Chem. C, 112, 3460-3463, <strong>2008</strong>.<br />
[2]Amrita Singh, T. Phanindra Sai and Arindam Ghosh, Applied Physics Letters 93, 102107 (<strong>2008</strong>).
Ultrasound-modulated Diffuse Optical Tomographic Imaging System for Screening<br />
Breast Cancer<br />
M Suheshkumar Singh and K Rajan<br />
Department of Physics, Indian Institute of Science<br />
Bangalore-560012, India.<br />
R M Vasu<br />
Department of Instrumentation, Indian Institute of Science<br />
Bangalore-560012, India.<br />
Near-Infrared (NIR) diffuse optical tomography (DOT) has been a promising tool for non-invasive<br />
imaging of optical parameters of tissues inside body over the past 15 years. Unfortunately, due<br />
to diffusive nature of light, sophisticated reconstruction algorithms are required to achieve good<br />
imaging depth and a reasonable resolution. Ultrasound (US), on the otherhand, is less scattered by<br />
soft tissues and it has been in use for imaging in biomedical ultrasound systems. Combination of<br />
the contrast sensitive property of light and good localization of ultrasound provides a challenging<br />
technique to reconstuct images of thicker biological tissues deep inside the body non-invasively.<br />
The US modulated optical signals which traverse the tissue are detected by using a CCD camera<br />
as detector array and the pixel map formed on the CCD is used to characterise the embedded<br />
inhomogeneity. The use of CCD camera improves the signal-noise-ratio (SNR) by averaging the<br />
signals from all of the CCD pixels. The conventional filtered backprojection algorithm is used for<br />
reconstruction. The pixel map is a measure of the projection data. A sequence of two to four images<br />
are captured on CCD camera with phase of US modulation signal shifted by 0 ◦ , 90 ◦ , 180 ◦ and 270 ◦<br />
w.r.t. the signal of the laser source. From these images, the modulation depth (ac/dc) and the<br />
correlation co-efficient of the signals which are the signatures of the pathological changes can be<br />
extracted. It is possible to reconstruct 2-D or 3-D images of a tissue object parameters using this<br />
method. For pre-clinical study of validity of the system, an inanimate object (phantom) is used as<br />
sample tissues. The phantom used is made of poly vinyl alcohol (PVA) and its mechanical, optical,<br />
and acoustic properties are tailored by subjecting an acquous solution of PVA stock and water to a<br />
suitable number of freeze-thaw cycles and by varying the degree of hydrolysis in the PVA stock.<br />
Keywords: Insonified, Tagged, Inhomogeneity, Backprojection
A filament in an active medium:<br />
buckling, stiffening and negative dissipation<br />
Norio Kikuchi 1 , Allen Ehrlicher 2 , Daniel Koch 2 , Josef A. K¨as 2 , Sriram Ramaswamy 1 ,<br />
and Madan Rao 3,4<br />
1 Centre for Condensed Matter Theory, Department of Physics,<br />
Indian Institute of Science, Bangalore 560 012, India<br />
2 Institute of Soft Matter Physics, Linn´estraße 5, 04103 Leipzig, Germany<br />
3 Raman Research Institute, C.V. Raman Avenue, Bangalore 560 080, India<br />
4 National Centre for Biological Sciences (TIFR), Bellary Road, Bangalore 560 065,<br />
India<br />
We present a generic theory for the dynamics of a stiff filament in an active<br />
medium with orientational correlations, such as a microtubule in contractile<br />
actin. In sharp contrast to the case of a passive medium, we find the filament<br />
can stiffen, and possibly oscillate, or buckle, depending on the contractile or<br />
tensile nature of the activity and the filament-medium anchoring interaction.<br />
We present experiments on the behaviour of microtubules in the growth cone<br />
of a neuron, which provide evidence for these apparently opposing<br />
behaviours. We also demonstrate a strong violation of the<br />
fluctuation-dissipation (FD) relation in the effective dynamics of the filament,<br />
including a negative FD ratio. Our theory also applies to the dynamics of<br />
axons and auditory hair cells. Detailed tests of our predictions can be made<br />
using a single filament in actomyosin extracts or bacterial suspensions.
POSTER<br />
ABSTRACTS
Enhancement of sensitivity of detection of Kerr rotation by time<br />
averaging<br />
Arjun Joshua and V. Venkataraman<br />
Abstract<br />
Experiments in spintronics necessarily involve the detection of spin polarization. The sensitivity<br />
of this detection becomes an important factor to consider when extending the low temperature<br />
studies on semiconductor spintronic devices to room temperature, where the spin signal is weaker.<br />
In pump-probe experiments which optically inject and detect spins, the sensitivity is often improved<br />
by using a photoelastic modulator (PEM) for lock-in detection. However, spurious signals can arise<br />
if diode lasers are used as optical sources in such experiments, along with a PEM. In this work,<br />
we eliminated the spurious electromagnetic coupling of the PEM onto the probe diode laser, by<br />
the double modulation technique. We also developed a test for spurious modulated interference<br />
in the pump-probe signal, due to the PEM. Besides, an order of magnitude enhancement in the<br />
sensitivity of detection of spin polarization by Kerr rotation, to 3 × 10 −8 rad, was obtained by<br />
using the concept of Allan variance to optimally average the time series data over a period of 416<br />
s. With these improvements, we are able to experimentally demonstrate at room temperature,<br />
photoinduced steady-state spin polarization in bulk GaAs.<br />
Thus, the advances reported here<br />
facilitate the use of diode lasers with a PEM for sensitive pump-probe experiments. They also<br />
constitute a step towards detection of spin-injection in Si at room temperature.
Reentrant phase behavior of a mixed surfactant system with<br />
strongly binding counter-ions<br />
Vikram Rathee 1 , Sajal Kumar Ghosh 2 , Rema Krishnaswamy 1 ,<br />
V. A. Raghunathan 2 and A. K. Sood 1<br />
1 Department of Physics, Indian Institute of Science, Bangalore<br />
2 Raman Research Institute, Bangalore<br />
The role of strongly binding counter ion in a mixed surfactant system consisting of<br />
oppositely charged amphiphiles, is to decrease the spontaneous curvature of the<br />
micellar aggregates giving rise to a change in their morphology from<br />
Spheres Rods Disks Vesicles , on varying the surfactant composition.<br />
Hence a rich phase behavior is observed in the concentrated micellar solutions of such<br />
systems with a variety of liquid crystalline phases. We will present our recent studies on<br />
the microstructure and dynamics of micellar solutions consisting of an anionic surfactant<br />
sodium dodecyl sulphate (SDS) and a strongly binding counter ion paratoluene<br />
hydrochloride (PTHC).<br />
Small angle x-ray scattering studies reveal a novel route from hexagonal to lamellar<br />
phase through a reentrant phase transition rod like Nematic Isotropic disk<br />
like nematic, on varying α= [PTHC]/[SDS], molar ratio at a fixed surfactant<br />
concentration (1). We will present our studies on SDS+PTHC system with higher<br />
surfactant concentration. A distinct viscoelastic and flow behavior is observed for the two<br />
nematic phases. The results are analyzed in conjunction with the observation from<br />
polarizing microscope and x-ray scattering measurements.<br />
(1) S.K.Ghosh, Ph.D. Thesis; Raman Research Institute, Bangalore (unpublished).
Structural, magnetic and EMR studies of CaMnO 3 nanoparticles<br />
Geetanjali, D. Banerjee and S V Bhat<br />
Calcium manganite, CaMnO 3 is the end member of the much studied doped rare earth pervoskite<br />
RE 1-x Ca x MnO 3 (x=1) and is a G-type antiferromagnetic insulator, with a Neel temperature of<br />
120 K. Recently we have shown that [1] many rare earth manganites loose their antiferromagnetic<br />
ground state and become ferromagnetic when prepared in nano scale (nanoparticles and nanowires).<br />
In this work, we investigate the behavior of CaMnO 3 nanoparticles.<br />
Sol-gel method was used to prepare the calcium manganite nanoparticles (D~50 nm). XRD, TEM<br />
and SEM were used to characterize the sample. X-band EMR studies were carried out between<br />
room temperature and 4 K. At room temperature, a relatively narrow (ΔH pp ≈ 900 Oe) and strong<br />
signal was observed in contrast with the broad (ΔH pp ≈ 1300 Oe), weak signal observed in the bulk<br />
CaMnO 3 [2]. The line-width shows a further reduction around 270 K indicating a possible<br />
ferromagnetic transition and a sharp increase around 120 K characteristic of an antiferromagnetic<br />
transition. The details of ac-susceptibility measurements and the analysis of EMR parameters will<br />
be presented in an attempt to understand the magnetism in nanoparticles of CaMnO 3 .<br />
References:<br />
[1] S.S.Rao, K.N. Anuradha, S.Sarangi, and S.V. Bhat; APL., 87, 182503 (2005)<br />
S.S.Rao, S. Tripathi, D.Pandey and S.V. Bhat, Phys. Rev. B 74, 144416 (2006)<br />
[2] S.B. Oseroff, M. Torikachvili, J. Singley, S. Ali, S.W. Cheong, S.Schultz, Phys. Rev. B 53,<br />
6521 (1996)<br />
Acknowledgments:<br />
The authors would like to thank M.M. Borgohain, K.G. Padmalekha and K.S. Bhagyashree for help<br />
in experiments.<br />
Dr. P.S. Anil Kumar’s help in ac-susceptibility measurements is gratefully acknowledged.
Magnetic and Magnetotransport studies of ZnO films with and without<br />
intrinsic magnetic moment<br />
Sayak Ghoshal and P.S.Anil Kumar<br />
Department of Physics, Indian Institute of Science, Bangalore-560012, <strong>IN</strong>DIA<br />
Transition metal doped ZnO was perceived to be an important material in view of the<br />
applications in Spintronic devices. Recently, we have shown that under suitable conditions of<br />
preparation, pure ZnO also can exhibit intrinsic magnetic moment and we were able to tune this<br />
moment by tuning the oxygen content in the pure ZnO films. We have also shown that this<br />
intrinsic moment is suppressed by an order of magnitude by doping with transition metal, in our<br />
case Cobalt. In addition, the magnetic properties of the bulk Co doped ZnO is also process<br />
dependent. Transport studies on the pure ZnO films reveal the correlation between the carrier<br />
concentration and the magnetic property of these films, which in turn helps us to exclude the<br />
extrinsic origin of the moment. We observed negative magnetoresistance (MR) for the ZnO films<br />
with higher conductivity and with intrinsic moment and positive MR for the less conducting<br />
diamagnetic ZnO films at 4.6K. For the doped sample we observe competition between the<br />
positive and negative MR and their behavior at different temperatures and fields. In this<br />
presentation, magnetic and magneto-transport properties of pure as well as Co doped ZnO films<br />
will be presented.
Ginzburg Landau Theory for Cuprate Superconductivity<br />
Sumilan Banerjee, Chandan Dasgupta, and T. V. Ramakrishnan ∗<br />
Dept. of Physics, Indian Institute of Science,<br />
Bangalore 560012. ∗ Also Banaras Hindu University, Varanasi 221005, India.<br />
Abstract<br />
We propose and develop the consequences of a theory in which the free energy F of a cuprate is<br />
expressed as a functional of the complex nearest neighbour spin singlet bond pair order parameter<br />
∆ ij exp (iφ ij ). F is a sum of two terms ∑ m (a∆2 m +b∆4 m ), and F 1 = c ∑ mn ∆ mn cos (φ m − φ n ); here<br />
m is the site corresponding to ij on the dual lattice (also square) and m,n are nearest neighbours.<br />
The doping x and temperature T dependences of a,b and c are rationalized ( eg, c ∝ x for small x).<br />
The pseudogap ( due to incoherent bond pairs) and the parabolic x dependence of T c ( AF ordering<br />
of the 2d-XY spin ∆ m exp (iφ m ) leading to d wave superconductivity) are described. The observed<br />
C v (T) behaviour is shown to be due to order parameter fluctuations. Detailed calculations of the<br />
vortex structure show a crossover from a Josephson like to a BCS like form with increasing doping,<br />
mirroring a similar change in superconductivity.<br />
1
Non Equilibrium noise in electrophoresis: the micro-ion wind<br />
Suropriya Saha and Sriram Ramaswamy<br />
We have obtained the extended nonequilibrium Langevin eqs for a single colloidal particle<br />
in externally applied electric field. The eq. for the system has been obtained by Squires<br />
who has assumed that only source of noise is thermal and satisfies Fluctuation-dissipation.<br />
We have looked into the manner in which the fluctuations of the counter-ion concentration<br />
lead, in the presence of an electric field to additional sources of noise in the colloid motion.<br />
We have shown that the particle shows enhanced brownian motion (the ‘extra-noise’ being<br />
proportional to field strength), i.e. systems are in steady non-equillibrium states. We have<br />
studied two systems- SysI: A neutrally buoyant particle drifting uniformly under the field<br />
in an unbounded fluid; SysII: A particle with density higher than the fluid, stably levitated<br />
by the balance between gravity sedimenting it towards a wall and the electric field driving<br />
it away from the wall. A qualitative measure of the extra-noise has been obtained for the<br />
two cases. In the first case the noise is found to be comparable or two to three orders of<br />
magnitude more than the thermal noise. In the second case the noise is found to be at least<br />
comparable to the thermal noise. In both cases the extra noise is anisotropic- strength in<br />
the electric field direction is nearly an order of magnitude more than that in the transverse<br />
plane. An effective temperature (T eff ) is defined as the ratio ωS(ω) , which would be the<br />
2Imχ(ω)<br />
temperature in a thermal equilibrium system. T eff is obtained as a function of frequency<br />
‘ω’ and is shown that T eff has strong ‘ω’ dependence; T eff(ω=0)<br />
changes by a factor of 2 as ω<br />
T<br />
changes from 0 to 5.5Dκ 2 (D = diffusivity of the micro-ion s, κ −1 = debye screening length).<br />
Nonequilibrium effects are clearly very significant in these systems.<br />
Abstarct for Poster<br />
1
Magnetic Anisotropy in Epitaxial Fe/MgO films grown by Pulsed<br />
Laser Deposition<br />
Sakshath. S. and P. S. Anil Kumar<br />
Department of Physics, Indian Institute of Science, Bangalore 560012<br />
Email: sakshath@physics.iisc.ernet.in<br />
Abstract<br />
We report the observation of uniaxial in-plane magnetic anisotropy using MOKE<br />
studies on the top ferromagnetic layer of the Fe/MgO/Fe single crystalline Magnetic<br />
tunnel junctions grown epitaxially on GaAs(100) substrates. Squid measurements show<br />
that independent magnetic switching of the ferromagnetic layers is present at<br />
sufficiently thick MgO layers.
Observation of the exchange spring behavior in hard-soft- ferrite nanocomposite<br />
Debangsu Roy a , and P.S. Anil Kumar a*<br />
a Department of Physics, Indian Institute of Science, Bangalore, 560012, India<br />
Bangalore, 560012, India<br />
Nanocomposite of hard and soft ferrite are prepared by the mixing of the individual<br />
ferrite components at appropriate ratio and subsequent heat treatment. Initially the<br />
microstructure of the individual phases is controlled by suitable processing. We have<br />
observed the exchange spring behavior in the soft-hard ferrite composite for the first time<br />
by tailoring the particle size of the individual phases and by suitable thermal treatment of<br />
the composite. It is found that the exchange interaction dominates over the dipolar<br />
interaction for smaller particle sizes of the soft ferrite. The magnetization of the<br />
composite showed hysteresis loop that is characteristic of the exchange spring system.<br />
With the following method of preparation we were successful enough to get an<br />
enhancement in the Fe3O4 and BaCa2Fe16O27 nanocomposite. An enhancement of<br />
(BH) max of ~13% for a particular mixture compared to the parent hard Ferrite. The<br />
presence of the exchange interaction between the hard and the soft grains was confirmed<br />
by the Henkel plot.
Probing the local stress in Graphene by Raman Spectroscopy<br />
Biswanath Chakraborty, Anindya Das and A.K. Sood<br />
Department of Physics, Indian Institute of Science , Bangalore - 560012,<br />
India<br />
We observe the strain induced softening of G and 2D Raman mode of monolayer<br />
graphene, on Si/SiO 2 . The strain in the graphene flake is largely due to the fabrication<br />
process. During mechanical exfoliation, the graphene layer is stretched as a result of<br />
friction between the HOPG adhered to scotch tape and the oxide surface. We show a<br />
softening up to ~ 32 cm -1 for G peak along with a 2D softening of ~ 80 cm -1 . Both these<br />
modes exhibit splitting into two peaks, which evolve as we vary the incident polarization<br />
direction. This evolution serves as an easy method to determine the local stress axis along<br />
the flake. We also report a non uniform distribution of strain on the graphene sample. A<br />
tensile strain of ~0.4% is reported here.
Electrical detection of spin polarized electrons in semiconductors<br />
using a radio-frequency pick-up coil<br />
Chinkhanlun Guite and V. Venkataraman<br />
Department of Physics, IISc Bangalore<br />
We present here preliminary results from an experiment which involves the measurement of<br />
electronic spin polarization in bulk semiconductors using electromagnetic induction. The<br />
main idea is to excite the electrons from the valence band to the conduction band using a<br />
circularly polarized laser. Due to the strong spin-orbit coupling in the valence band, a part of<br />
the angular momentum of the circularly polarized light is transferred to the electron which<br />
allows the excited electron to be spin polarized to certain degree of efficiency, for e.g. 50%<br />
for GaAs. The spin of the excited electron decays with a lifetime of about 50 ps at 300 K. In<br />
steady state, for a pump intensity of about 200mW at 808nm, a spin polarized density of ~10 9<br />
cm -3 can be achieved in GaAs. The weak magnetization generated by this population can be<br />
detected by sensitive modulation techniques.<br />
The laser light was phase modulated using an electro-optic modulator from left to right<br />
circular polarization at a high frequency of 2.5 MHz. This creates an alternating spin<br />
polarization in the sample, which generates varying magnetic field at the frequency of the<br />
modulator. Using a sensitive inductive pick-up coil with a Q~40 at 2.5MHz and an RF Lockin<br />
Amplifier, the induced voltage can be detected and studied. We have measured a signal of<br />
~10nV in our experimental setup against an expected signal of ~2nV. We are currently<br />
involved in eliminating the spurious intensity modulation background, which is ~5-10 times<br />
larger than the signal, by suitably choosing the phase-modulation scheme. We believe this<br />
measurement technique will give an insight into the behavior of electronic spins inside GaAs<br />
and can be extended to other materials, particularly indirect semiconductors such as Ge.
Polymer Addtives in Decaying Two-Dimensional Turbulence<br />
Anupam Gupta, Prasad Perlekar, and Rahul Pandit<br />
Centre for Condensed Matter Theory,<br />
Department of Physics, Indian Institute of Science,<br />
Bangalore 560012, <strong>IN</strong>DIA<br />
We present direct numerical simulations of decaying, two-dimensional isotropic turbulence with<br />
polymer additives. We find that, on the addition of polymers to the turbulent fluid, the enstrophydissipation<br />
rate reduces. This is the two-dimensional analogue of energy-dissipation-rate reduction<br />
in three-dimensional turbulence. We relate the reduction of the enstrophy-dissipation rate to changes<br />
in the fluid energy spectrum, in the presence of polymers, especially at small length scales.
Numerical study of a glass forming liquid in two dimensions to test the dimension<br />
dependence of the Adam-Gibbs relation<br />
Smarajit Karmakar 1 , ∗ Chandan Dasgupta 1,2, , † and Srikanth Sastry 2,‡<br />
1 Centre for Condensed Matter Theory, Department of Physics, Indian Institute of Science, Bangalore, India<br />
2 Condensed Matter Theory Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore, India.<br />
In a recent study [1], we confirmed the existence of a dynamic correlation length that grows as the liquid is<br />
supercooled, by performing a detailed finite-size scaling analysis of dynamic heterogeneity in a model glass-forming<br />
liquid. The observed behaviour of this correlation length as a function of temperature is qualitatively consistent with<br />
recent predictions of inhomogeneous mode coupling theory. However, our study also showed that it is necessary to<br />
take into account properties of the underlying potential energy landscape (in particular, the configurational entropy)<br />
to understand the dynamics of supercooled liquids even above the dynamic transition temperature of mode coupling<br />
theory. Contrary to expectations, we found that the empirical Adam-Gibbs relation [2] between the relaxation<br />
time and the configurational entropy describes our simulation results very well. Motivated by this observation, we<br />
have examined whether the same Adam-Gibbs relation also holds good in any arbitrary dimension. We have tried<br />
to determine whether the Adam-Gibbs relation has any dimension dependence by performing molecular dynamics<br />
simulations of the Kob-Anderson binary mixture [5] in two dimensions. This question arises partly because of the<br />
recent success of the Random First Order Transition Theory (RFOT) [3, 4] where configurational entropy plays<br />
a major role, leading to a dimension dependent Adam-Gibbs-type relation[2]. We have also performed a detailed<br />
finite-size scaling analysis of a four-point density-density correlation function [6] to extract the underlying correlation<br />
length and calculated the configurational entropy to test whether one can explain the results using RFOT. We found<br />
that indeed the Adam-Gibbs relation has dimension dependence, but our results are not fully consistent with the<br />
predictions of either mode coupling theory or RFOT.<br />
[1] Growing length and time scales in glass forming liquids - Smarajit Karmakar, Chandan Dasgupta, and Srikanth Sastry,<br />
http://arxiv.org/abs/0805.3104<br />
[2] Adam, G and Gibbs, J H (1965),J. Chem. Phys. 43:139–146.<br />
[3] T. R. Kirkpatrick and P. G. Wolynes, Physical Review A. 35, 3072 (1987)<br />
[4] T. R. Kirkpatrick and D. Thirumalai, Physical Review A. 40, 1045 (1989)<br />
[5] Kob, W and Andersen, H C (1995), Phys. Rev. E 51:4626–4641.<br />
[6] C Dasgupta, A V Indrani, S Ramaswamy and M K Phani, Europhys. Lett. 15, 307(1991)<br />
∗ Electronic address: smarajit@physics.iisc.ernet.in<br />
† Electronic address: cdgupta@physics.iisc.ernet.in<br />
‡ Electronic address: sastry@jncasr.ac.in
Compositional dependence of the optical changes in (As 2 S 3 ) 1-x Sb x<br />
chalcogenide film.<br />
Ramakanta Naik,R.Ganesan,K.S.Sangunni.<br />
Department of Physics, Indian Institute of Science, Bangalore, 560012,India.<br />
Arsenic trisulfide (As 2 S 3 ) is the most studied chalcogenide glass and deserves applications<br />
in infrared optics and optical coatings because of its excellent IR transmission, large glass<br />
forming tendency, and resistance to moisture and chemicals. Studies on thin films of Sb 2 S 3<br />
are attracting wide attention, for its special applications as a target material for television<br />
cameras, microwave devices, switching devices and various opto electronic devices. Even<br />
though As and Sb belongs to the same group of the periodic table, As 2 S 3 and Sb 2 S 3 do not<br />
display the same glass forming tendency. Glassy Sb 2 S 3 is very difficult to form and its<br />
preparation requires high cooling rates. However, addition of As 2 S 3 to Sb 2 S 3 enhances<br />
greatly the glass forming ability of the later and glasses in the mixed As-Sb-S system can<br />
be formed. Recently we prepared the ternary As-S-Sb chalcogenide glass composition<br />
(As 2 S 3 ) 1-x Sb x by keeping As/S ratio same with 2%,7%,10% and 15% of the Sb content.<br />
The purpose of the work is two fold; first to study the local glass structure as a function of<br />
composition and second to explore the possibility of mixed As-S-Sb bridges. A number of<br />
works exist which trace the influence of composition and preparation conditions of the<br />
films on the physiochemical properties. These glasses are sensitive to the absorption of<br />
electromagnetic radiation and show a variety of photo induced effects as a result of<br />
illumination. These changes are accompanied by changes in the optical constants, i.e.,<br />
changes in the optical band gap, refractive index and optical absorption coefficient. These<br />
light-induced changes are favoured in chalcogenide glasses due to their structural<br />
flexibility (low coordination of chalcogens) and also due to their high-lying lone-pair p<br />
states in their valence bands. Annealing of chalcogenide glasses can affect the<br />
photoinduced changes, in particular irreversible effects occur in as-deposited films, while<br />
reversible effects occur in well-annealed films as well as bulk glasses. Changes in local<br />
atomic structure are observed on illumination with light having photon energy near the<br />
optical band gap of the chalcogenide. The film composition was checked by EDAX. The<br />
compositional dependence of the (As 2 S 3 ) 1-x Sb x films were studied through FTIR, XPS and<br />
Raman experiments. Addition of Sb results in the increase of density of the bulk (As 2 S 3 ) 1-x<br />
Sb x alloy. The optical band gap of the (As 2 S 3 ) 1-x Sb x films decreases while the width of<br />
localized states increases with the increase in Sb content. The peak shift and intensity<br />
variation of the core level spectra were resulted due to the addition of Sb. It can be<br />
suggested that the photo and thermally induced changes are caused by chemical bond<br />
redistribution,according to the equation<br />
2M-S=M-M+S-S (1)<br />
Where M stands for As or Sb, S is for sulfer and dash denotes a chemical bond. The<br />
equilibrium of Eq. (1) can be moved in both directions, depending on the initial state of<br />
the film and the conditions of light exposure or annealing. Photo and thermally induced<br />
changes can be assigned to chemical bond redistribution.Bleaching of the asprepared film<br />
due to annealing is assigned to an increase of heteropolar bond density. Photodarkening<br />
of the illuminated film and annealed illuminated film is due to the increase in homo polar<br />
bond density.
Measurement of Heteronuclear dipolar couplings-<br />
A systematic study of cross polarization dynamics for<br />
Separated Local Field (SLF) experiments<br />
Nitin P. Lobo a and K.V. Ramanathan b<br />
a Department of Physics and b NMR Research Centre<br />
Indian Institute of Science, Bangalore-560012<br />
Separated Local Field (SLF) spectroscopy based on the transient<br />
oscillations observed during cross polarization represents a class of two<br />
dimensional solid state NMR experiments in which the coherent transfer of<br />
energy between dipolar coupled spin systems provides a means of resolving<br />
heteronuclear dipolar couplings on the basis of chemical shifts and<br />
characterizing them. It has become one of the important methods of<br />
structural elucidation of oriented molecules. Nematic liquid crystals, which<br />
orient in magnetic field have been extensively studied by this technique. In<br />
this method spin evolution during polarization transfer gives rise to the<br />
dipolar cross peaks, which for a two spin system can be understood to arise<br />
from evolution under mutually commuting zero and double- quantum<br />
subspaces. Under the conditions of exact Hartman-Hahn match, the<br />
evolution in the zero-quantum sub space alone contributes to the dipolar<br />
cross peak while the evolution in the double-quantum sub-space contributes<br />
only to the axial-peak. Increasing the cross peak intensity enhances the<br />
sensitivity of the experiment, while suppression of the axial-peak enables<br />
resolution of cross-peaks arising from small dipolar couplings. This requires<br />
that the initial density matrix is essentially of zero-quantum in nature which<br />
can, for example, be achieved by Polarization Inversion (PI). Subsequently,<br />
the dipolar oscillations are monitored with the removal of the homonuclear<br />
dipolar couplings by a suitable decoupling scheme. Experiments on simple<br />
oriented systems has been carried out to estimate the relative cross-peak to<br />
axial-peak intensities in 2D-SLF experiments based on the dipolar oscillations<br />
during cross polarization. Along with CP pulse sequence other pulse<br />
sequences namely CP with Polarization Inversion (PI-CP), another novel<br />
variation of the standard CP experiment i.e. Equilibrium X-nuclearpolarization<br />
enhanced cross-polarization (EXE-CP) and PISEMA experiment<br />
have been considered. In combination with Frequency Switched Lee-<br />
Goldburg (FSLG) homonuclear decoupling sequences, experiments on the<br />
oriented liquid crystalline samples carried out and the performance of the<br />
pulse schemes compared. Since Dipolar couplings provide useful structural<br />
and dynamics information the present study is aimed at optimizing and<br />
improving methods used for the measurement of heteronuclear dipolar<br />
couplings for static oriented samples using solid state NMR methods.
Detection of microcantilever deflection using electron transport measurements<br />
S.M. Mohanasundaram and Arindam Ghosh<br />
Department of Physics, IISc<br />
Abstract:<br />
Using Silicon bulk micromachining technique, we have fabricated Silicon dioxide microcantilevers.<br />
On top of it, we have deposited and patterned Gold thin films using lift-off<br />
process. When we apply a force on the micro-cantilever, it bends and applies an elastic<br />
strain on the metal film. For our initial experiments, force is applied by using the surface<br />
tension of an evaporating liquid (propan-2-ol). Electrical resistance is measured during<br />
the process. We have found that the mechanical strain clearly translates into a change in<br />
the electrical resistance. We are also planning to measure the resistance fluctuations as<br />
function of mechanical strain. This kind of micro-cantilevers can be used for applications<br />
such as Atomic Force Microscopy (AFM), bio-molecular sensing, etc.
A fluctuation-based probe to criticality in structural transitions<br />
Chandni U and Arindam Ghosh<br />
Department of Physics, Indian Institute of Science, Bangalore- 12.<br />
Many natural phenomena, extending from geophysics, biology to material science, involve<br />
slowly driven dissipative systems that are far from thermal equilibrium. The universal critical<br />
dynamics in these systems defines a class of athermal phase transitions that are triggered only<br />
by an external field that act as the tuning parameter and to which the systems respond through<br />
scale‐free avalanches in physical observables. In spite of decades of research, the relevance of<br />
the tuning parameter in this scale‐invariant dynamics at criticality is still an open question.<br />
Experiments are inconclusive whether these systems self organize to the critical state over a<br />
broad range of external field, or if there exists a unique critical point that is smudged by a wide<br />
critical zone as postulated by the concept of ‘plain‐old criticality’. Here, through experimental<br />
determination of time dependent avalanches, or noise, in electrical resistivity during<br />
temperature‐driven martensite transformation in thin nickel‐titanium films, we demonstrate<br />
that higher order statistics of avalanches can serve as an excellent kinetic detector of criticality<br />
in continuously driven non‐equilibrium systems. We show, for the first time, the existence of a<br />
singular `global instability' or divergence of the correlation length as a function of temperature<br />
in martensite transition indicating, (i) mapping of non‐equilibrium first order phase transition<br />
and equilibrium critical phenomena, and (ii) conventional nature of critical behavior, even<br />
though many previous experimental results as well as theoretical models predict a selforganized<br />
criticality in such systems. These results not only establish an independent<br />
experimental probe to critical phenomena in a wide variety of complex natural systems, but<br />
perhaps also call for a re‐evaluation of existing experimental data in various cases.<br />
References:<br />
1. "Signature of martensitic transformation on conductivity noise in thin films of NiTi shape<br />
memory alloys", Chandni U., Arindam Ghosh, H. S. Vijaya and S. Mohan, Applied Physics<br />
Letters 92, 112110 (<strong>2008</strong>). (Also in arXiv:0811.0101 (<strong>2008</strong>))<br />
2. “Criticality of tuning in athermal phase transitions”, U. Chandni, Arindam Ghosh, H. S.<br />
Vijaya and S. Mohan, arXiv:0811.0102 (<strong>2008</strong>).
Temperature dependent photoluminescence study in Hg 1-x Cd x Te<br />
(x~0.8) nano and microcrystals<br />
Jayakrishna Khatei and K.S.R. Koteswara Rao<br />
Abstract<br />
Hg 1-x Cd x Te (MCT) nanoparticles have been prepared by solvothermal method<br />
which is a facile, low-cost, solution phase approach to the large scale preparation of MCT<br />
at 180 o C. Different compositions of MCT (x~0.1, 0.3, 0.4, 0.5 & 0.8) have been prepared<br />
by varying the proportion of Hg and Cd. EDAX result revealed that the compositions are<br />
very much close to the intended one. The photoluminescence (PL) measurements of<br />
nanocrystalline Hg 1-x Cd x Te (x~0.1, 0.3, 0.4, 0.5 & 0.8) have been performed at room<br />
temperature as well as low temperature. The temperature dependent PL characterization<br />
has been done over the temperature range 10-300 K on higher composition Hg 1-x Cd x Te<br />
(x~0.8) nanocrystals. The detailed characteristics of the PL emission which shows a<br />
broad emission from 0.6eV to 1eV consisting of 5 prominent peaks (0.92, 0.76, 0.68, 0.61<br />
and 0.57eV) and the peak intensity at different temperature were studied. With increasing<br />
temperature, these peaks show different temperature dependences. The intensity of most<br />
of the peaks increases with temperature from 10 K to 50 K and then the intensity<br />
decreases with increase in the temperature. The position of the emission peaks remains<br />
constant with change in temperature. These anomalous intensity behaviors of the PL<br />
spectra are explained on the basis of defect levels.<br />
* The results will be presented as poster.
The Dependance of Spiral-Wave Dynamics on Inhomogeneities in the TNNP Model of<br />
Cardiac Tissue<br />
Alok Ranjan Nayak 1 , T.K. Shajahan 2 , and Rahul Pandit 1<br />
1 Centre for Condensed Matter Theory,<br />
Department of Physics, Indian Institute of Science,<br />
Bangalore 560012, <strong>IN</strong>DIA<br />
and<br />
2 Indian Institute of Science Education and Research (IISER),<br />
Thiruvananthapuram 695016, <strong>IN</strong>DIA<br />
Regular electrical activation waves in cardiac tissue lead to the rhythmic contraction and expansion<br />
of the heart that ensures blood supply to the whole body. Irregularities in the propagation<br />
of these activation waves can result in cardiac arrhythmias, like ventricular tachycardia (VT) and<br />
ventricular fibrillation (VF), which are major causes of death in the industrialised world. Indeed<br />
there is growing consensus that spiral or scroll waves of electrical activation in cardiac tissue are<br />
associated with VT, whereas, when these waves break to yield spiral- or scroll-wave turbulence,<br />
VT develops into life-threatening VF: in the absence of medical intervention, this makes the heart<br />
incapable of pumping blood and a patient dies in roughly two-and-a-half minutes after the initiation<br />
of VF. Thus studies of spiral- and scroll-wave dynamics in cardiac tissue pose important challenges<br />
for in vivo and in vitro experimental studies and for in silico numerical studies of mathematical<br />
models for cardiac tissue.<br />
We present a detailed and systematic study of spiral-wave turbulence in a mathematical model<br />
for ventricular myocytes proposed recently by ten Tusscher et al [1] In particular, we use extensive<br />
numerical simulations [2] to elucidate the interaction of spiral-wave in it with conduction and ionic<br />
inhomogeneities that occur commonly in cardiac tissue. We also examine a control scheme that has<br />
been suggested for the control of spiral turbulence, via low-amplitude current pulses, in this model.<br />
[1] ten Tusscher, K.H.W.J., Noble, D., Noble, P.J., Panfilov, A.V. A model for human ventricular tissue.Am. J. Physiol. Heart<br />
Circ. Physiol. 286, H1573−H1589, 2004.<br />
[2] T.K. Shajahan, Alok Ranjan Nayak, and Rahul Pandit. Spiral-Wave Turbulence and its Control in the Presence of Inhomogeneities<br />
in Four Mathematical Models of Cardiac Tissue. Submitted for publication, <strong>2008</strong>.
Motion of falling spheres and rising bubbles in a viscoelastic gel:<br />
spontaneous oscillations and bursting<br />
Nitin Kumar 1 , Sayantan Majumdar 1 , Aditya Sood 2 , Rama Govindarajan 3 , Sriram Ramaswamy 1 and A.K. Sood 1<br />
1<br />
Department of Physics, Indian Institute of Science, Bangalore-560 012, India<br />
2 Department of Materials and Metallurgical Engineering, Indian Institute of Technology, Kanpur-208 016, India<br />
3 Engineering Mechanics Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore-560 064, India<br />
Abstract<br />
The motion of a spherical ball falling under gravity through a simple Newtonian fluid is governed by the<br />
well-known Stokes’ law where the ball attains a steady terminal velocity after a certain time when the net<br />
force on the ball becomes zero. However, in non-Newtonian fluids, the velocity of the ball does not<br />
achieve a steady state and shows large fluctuations [1] .<br />
We will report our recent experiments done in surfactant CTAT in water, which forms a viscoelastic<br />
wormlike micellar gel. We show experimentally that a ball falling in the viscoelastic gel undergoes a<br />
transition from a steady state velocity to oscillatory behaviour as the weight of the ball is increased. The<br />
oscillations in velocity of the ball are non-sinusoidal, consisting of high-frequency bursts occurring<br />
periodically at intervals long compared to the period within the bursts. We offer a simple theoretical<br />
model based on the interplay of the mobility tensor of the particle and the orientational order parameter of<br />
the micelle solution. For the case of bubbles, the situation is interesting as both shape and size can vary [2] .<br />
We show that an air bubble rising in the viscoelastic gel shows a discontinuous jump in the velocity at a<br />
critical volume (V c ) jump , of the bubble, followed by a drastic change in its shape from a "teardrop" to<br />
almost spherical. We also observe shape oscillations for bigger bubbles with the tail swapping in and out<br />
periodically.<br />
References:<br />
[1] A. Jayaraman and A. Belmonte, Phys. Rev. E (67), 065301(R) (2003)<br />
[2] Nestor Z. Handzy and Andrew Belmonte, Phys. Rev. Lett. 92, 124501 (2004)
Negative viscosity fluctuations and their universality in a driven repulsive colloidal<br />
glass<br />
Sayantan Majumdar and A.K. Sood<br />
Department of Physics, Indian Institute of Science, Bangalore 560012, India<br />
Abstract<br />
There are a lot of recent interests in the statistical properties of non-equilibrium fluctuations in<br />
driven jammed systems. Recently proposed Fluctuation Relations (FR) [1] predict the symmetry<br />
properties of the Probability Distribution Functions (PDF) of these fluctuations arbitrary far from<br />
equilibrium. Also it has been observed that the PDF of a global measure in a large class of highly<br />
correlated equilibrium and non-equilibrium systems have the same functional form [2].<br />
In this context we have studied the statistical properties of non-equilibrium fluctuations in a<br />
driven repulsive colloidal glass of Laponite. Laponite particles are disk shaped with a diameter of<br />
~30 nm and thickness of ~1 nm. When these particles are suspended in water they acquire more<br />
and more surface charge with time because of gradual ion dissociation. Due to strong long range<br />
electrostatic interaction they can form a colloidal glass even at very low volume fraction (~ 3<br />
wt %). We study the viscosity of 3 wt % Laponite solution in water as a function of time by<br />
applying a constant shear stress on the sample. With time the particles form a highly jammed<br />
state (a colloidal glass). The viscosity (and shear rate) shows large fluctuations including many<br />
negative values. The PDF of these fluctuations can be Gaussian or non-Gaussian depending on<br />
the applied stress but they satisfy the Gallavotti-Cohen Steady State Fluctuation Relation (SSFR)<br />
for both Gaussian and non-trivial case of non-Gaussian PDF. The PDF of global power<br />
fluctuations for very high applied stresses become strongly non-Gaussian and follow exactly the<br />
same Universal functional form predicted in [2]. We attribute this remarkable observation to the<br />
presence of high degree of spatial and temporal correlation in a jammed state.<br />
References<br />
[1] G. Gallavotti and E. D. G. Cohen, Phys. Rev. Lett. 74, 2694 (1995); G. Gallavotti and E. D.<br />
G. Cohen, J.Stat.Phys. 80, 931 (1995).<br />
[2] S. T. Bramwell et al. Nature, vol 396, 10 December 1998; S. T. Bramwell et al. Phys. Rev.<br />
Lett. 84, 3744 (2000).
MAGNETOTRANSPORT STUDIES <strong>OF</strong> FLOAT ZONE-GROWN Gd 1-x Sr x MnO 3<br />
S<strong>IN</strong>GLE CRYSTAL<br />
Aditya A. Wagh, H.L.Bhat, P. S. Anil Kumar and Suja Elizabeth<br />
Department of Physics, Indian Institute of Science, Bangalore-560012, India<br />
The multiferroic behavior, observed in manganites containing small rare-earth cations,<br />
has attracted considerable attention in recent times because of the interesting physics involved<br />
as well as their high application potential (1). Colossal Magnetoresistance exhibited by mixed<br />
valence perovskites has motivated us to study the effect of strontium substitution in<br />
multiferroic gadolinium manganite crystals. Single crystal of Gd 1-x Sr x MnO 3 (x=0.5) was grown<br />
by Float Zone (FZ) technique. Initially, Gd 1-x Sr x MnO 3 was synthesized by solid state reaction.<br />
Crystals were grown using four mirror optical image furnace with a typical growth rate of 1<br />
mm/hr. Crystallinity was ascertained by X-ray diffraction. Chemical composition was<br />
estimated by ICPAES analysis. Transport properties of grown crystals were studied in the<br />
temperature range 40 to 300 K. Temperature evolution of electrical resistivity of all the crystals<br />
showed semiconducting behaviour as expected (2). Magnetoresistance measurements were<br />
performed by applying a magnetic field perpendicular to the direction of current. Drastic<br />
reduction in the resistivity was observed in the presence of magnetic field. At relatively high<br />
magnetic field a metal-insulator transition was observed and this transition temperature was<br />
field dependent. The temperature and field dependence of the magnetoresistance was also<br />
studied in detail. The magnetization of the samples was measured by vibrating sample<br />
magnetometer in the temperature range 5 to 300 K. Gd 0.5 Sr 0.5 MnO 3 crystal exhibited a<br />
bifurcation in the zero-field cooled (ZFC) and field cooled (FC) plots. The electrical and the<br />
magnetic properties of these crystals will be discussed in detail.<br />
References:<br />
(1) Kadomtseva A. M. et. al. JETP Letters, Vol. 82, No. 9, pp. 590–593 (2005)<br />
(2) Garcia-Landa B. et. al. Journal of Applied Physics, Vol. 83, No.12,7664 (1998)
Conformational modification by conjugation<br />
length and solvent in rigid-rod organic<br />
semiconductor<br />
Paramita Kar Choudhury * , Debjani Bagchi, and Reghu Menon<br />
Department of Physics, Indian Institute of Science, Bangalore 560012, India<br />
The conducting polymer MEH-PPV poly [2-methoxy-5-2 ’ –ethyl-hexyloxy)-1,4-<br />
phenylene vinylene] is an important optoelectronic material for thin film devices, as it<br />
exhibits fluorescence in the visible region of the spectrum. By studying the polymer chain<br />
conformations with small angle X-ray scattering (SAXS), we have explored the factors<br />
such as conjugation length and effect of solvents, which can remarkably alter the<br />
fluorescence and conductivity of MEH-PPV films. The studies reveal that increase in<br />
effective conjugation in organic polymers changes their conformation by making them<br />
more rigid-rod like in the nano-scale regime. At a slightly larger length scale we find<br />
oriented stacking and long range ordering of the worm-like chains even in a very dilute<br />
solution. Aromatic non-polar solvent xylene solvates the backbone leaving the chains<br />
more rigid and stacked, while non-aromatic polar solvent tetrahydrofuran (THF) solvates<br />
the lateral groups and leads to lesser, and more randomly oriented coil structures.
1H-NMR and charge transport in metallic polypyrrole at ultra-low<br />
temperatures and high magnetic fields<br />
K Jugeshwar Singh, G Clark, K P Ramesh and Reghu Menon<br />
The temperature dependence of conductivity, proton spin relaxation time (T1) and<br />
magnetoconductance (MC) in metallic polypyrrole (PPy) doped with PF6. have been<br />
carried out at mK temperatures and high magnetic fields. At T < K both electron.electron<br />
interaction (EEI) and hopping contributes to conductivity. The temperature dependence<br />
of a proton T1 is classified in three regimes: (a) for T 50 K,<br />
relaxation is due to the dipolar interaction modulated by the reorientation of the<br />
symmetric PF6 groups following the Bloembergen, Purcell and Pound (BPP) model. The<br />
data analysis shows that the Korringa ratio is enhanced by an order of magnitude. The<br />
positive and negative MC at T < 250 mK is due to the contributions from weak<br />
localization and Coulomb-correlated hopping transport, respectively. The role of EEI is<br />
observed to be consistent in conductivity, T1 and MC data, especially at T
Resistance noise in electrically biased bilayer graphene<br />
Atindra Nath Pal and Arindam Ghosh<br />
Department of Physics, Indian Institute of Science, Bangalore 560 012, India<br />
Abstract:<br />
The growing interest in bilayer graphene (BLG) is fueled by the ability to control the energy gap<br />
between its valence and conduction bands through external means. We demonstrate that the<br />
low‐frequency resistance fluctuations, or noise, in bilayer graphene is strongly connected to its<br />
band structure, and displays a minimum when the gap between the conduction and valence<br />
band is zero. Using double‐gated bilayer graphene devices we have tuned the zero gap and<br />
charge neutrality points independently, which offers a unique mechanism to investigate the<br />
low‐energy band structure, charge localization and screening properties of bilayer graphene.<br />
We show: (1) the noise to be minimum when band gap (Δ g ) = 0 even if it corresponds to a<br />
nonzero carrier density (n), (2) the evidence of localized states near the band tails even at Δ g =<br />
0, with a mobility edge that strongly depends on the external electric field E, and finally, (3) a<br />
method to directly determine the dielectric properties of BLG in both electron and hole‐doped<br />
regimes.<br />
References:<br />
1. Oostinga, J. B.; Heersche, H. B.; Liu, X; Morpurgo, A. F.; Vandersypen, L. M. K. Nat.<br />
Mater., 7, 151, 2007.<br />
2. T. Ohta, A. Bostwick, T. Seyller, K. Horn, E. Rotenberg, Science 313 (2006) 951.<br />
3. Yu‐Ming Lin and Phaedon Avouris, NANO LETTERS 8 : 2119 DOI 10.1021/nl0802411<br />
<strong>2008</strong>.<br />
4. E. McCann, Phys. Rev. B 74 (2006) 161403.
Structure and stability of carbon and boronnitride nanorings<br />
Meghana Dharmik and Prabal Maiti<br />
Center for Condensed Matter Theory,Department of Physics,Indian Institute of Science.<br />
We have studied the structure and stability of Carbon and BoronNitride<br />
nanorings using Molecular mechanics calculations.We have used conjugate gradient<br />
method to minimize the nanorings using Dreiding force field to get an estimate of the<br />
critical diameter of the nanoring.Below the critical diameter the ring structure is unstable<br />
with formation of kinks.Above the critical diameter kinks disappear and the ring structure<br />
is stable.The critical diameter of the nanoring strongly depends on the chirality of the<br />
tube and increases with increase in tube diameter .We identify the kink location with the<br />
high strain energy region .Our calculation suggests that for a given chirality Boron –<br />
Nitride nanoring has larger critical diameter than the corresponding Carbon nanoring.<br />
This might be due to the strong coulombic interaction arising due to the polar interaction<br />
between the B and N atoms.
Conductivity noise in strongly correlated systems<br />
R.Koushik and Arindam Ghosh<br />
Department of Physics,<br />
Indian Institute of science, Bangalore- 560012, India<br />
Abstract:<br />
Modulation doped GaAs/AlGaAs heterostructures are ideal candidates to study the<br />
effects of disorder on electron-electron interaction in a systematic manner. In these<br />
systems the strength of the disorder is determined by an undoped AlGaAs spacer, which<br />
separates the charged silicon dopants from the two dimensional electron gas, and can be<br />
tuned to atomic precision in molecular beam epitaxy. Several disorder-stabilized strongly<br />
interacting many-body phases have been predicted in numerous theoretical studies in<br />
these systems, in particular when the effect of interaction is non-perturbative.<br />
Conventional techniques, based on time averaged current-voltage characteristics, are<br />
however often inconclusive in this regard. In this work, we report the measurement of<br />
low-frequency resistivity fluctuations in mesoscopic 2D electron systems in delta-doped<br />
GaAs/AlGaAs heterostructures in the strongly interacting regime. Our measurements at<br />
low temperatures (267 mK) reveals a spectacular increase over six orders of magnitude in<br />
resistivity noise with a decrease in applied bias, which cannot be explained using hopping<br />
(variable-range or nearest-neighbor) conduction mechanisms. Our measurement<br />
technique is quite unique in the sense we have kept the AC bias across the sample<br />
constant at 30uV and varied the DC bias across the sample from -800uV to +800uV. We<br />
attribute the results to the manifestation of a new many-body quantum state of the<br />
electrons that has been recently claimed in the context of metallic transport in 2D.<br />
References:<br />
1. Modulation origin of 1/f noise in two-dimensional hopping, V.Ya.Pokrovskii, A.V.<br />
Savchenko, W.R. Tribe and E.N. Linfield, Phys Rev B 64, 201318 (2001)<br />
2. Onset of glassy dynamics in a Two-Dimensional Electron system in Silicon, Snezana<br />
Bogdanovich and Dragana Popovic, PRL 88, 236401 (2002)<br />
3. Low temperature collapse of electron localization in two dimensions, Matthias<br />
Baenninger, Arindam Ghosh, Michael Pepper, Harvey E.Beere, Ian Farrer, and David<br />
A. Ritchie, PRL 100, 016805 (<strong>2008</strong>)<br />
4. Conductivity noise in strongly correlated systems, R. Koushik, Baenninger et al.<br />
under preparation
Out-of-Equilibrium Microrheology to Probe Directional<br />
Viscoelastic Properties under Shear<br />
Manas Khan and A. K. Sood<br />
Department of Physics, Indian Institute of Science, Bangalore - 560012, India<br />
Many wormlike micellar systems exhibit appreciable shear thinning due to shear induced<br />
alignment. As the micelles get aligned, introducing directionality in the system, the<br />
viscoelastic properties no longer remain isotropic. An optical tweezers based technique<br />
enables us to probe the out-of-equilibrium rheological properties of CTAT system<br />
simultaneously along two orthogonal directions - parallel to the applied shear, as well as<br />
perpendicular to it. While the displacements of a trapped bead - in response to active drag<br />
force - carry signature of conventional shear thinning, its spontaneous position<br />
fluctuations along the perpendicular direction manifest an orthogonal shear thickening.
Jump reorientation of water molecules confined in narrow carbon<br />
nanotubes<br />
Biswaroop Mukherjee 1,3, , ∗ Prabal K. Maiti 1,∗ , † Chandan Dasgupta 1,3, , ‡ and A. K. Sood 2,§<br />
1 Centre for Condensed Matter Theory, Department of Physics,<br />
Indian Institute of Science, Bangalore 560 012, India<br />
2 Department of Physics, Indian Institute of Science, Bangalore 560 012, India<br />
3 Condensed Matter Theory Unit, Jawaharlal Nehru Centre<br />
for Advanced Scientific Research, Bangalore 560 064, India.<br />
Abstract<br />
We use molecular dynamics (MD) simulations to study the reorientational dynamics of water<br />
molecules confined inside narrow carbon nanotubes immersed in a bath of water. Our simulations<br />
show that the confined water molecules exhibit bistability in their reorientational relaxation,<br />
which proceeds by angular jumps between the two stable states. The energy barrier between these<br />
two states is about 2k B T. These jumps cause the ratio of the timescales of the first and second<br />
order reorientational correlation functions to exceed the value in the diffusive limit. The analytic<br />
solution of a simplified model, which qualitatively explains this “unusual” relaxation, is also<br />
presented. These results will have important implications in understanding proton conduction in<br />
water-filled ion channels.<br />
PACS numbers:<br />
1
∗<br />
Electronic address: biswa@physics.iisc.ernet.in<br />
† Electronic address: maiti@physics.iisc.ernet.in<br />
‡ Electronic address: cdgupta@physics.iisc.ernet.in<br />
§ Electronic address: asood@physics.iisc.ernet.in<br />
2