Electron Beam Flue Gas Treatment - PlasTEP
Electron Beam Flue Gas Treatment - PlasTEP
Electron Beam Flue Gas Treatment - PlasTEP
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Aromatic VOC decomposition<br />
mechanism<br />
Positive ions’ charge transfer reactions<br />
Radical – neutral particles reactions<br />
•OH radical reactions<br />
M + + RH = M + RH +<br />
˙OH + C 6<br />
H 5<br />
CH 3<br />
= R1˙ (OH radical addition)<br />
C 6<br />
H 5<br />
CH 3<br />
+ ˙OH = R2˙ + H 2<br />
O ( H atom abstraction)<br />
•Organic radicals’ reactions<br />
R. Atkinson: Chem. Rev. 85 (1985) 69<br />
C 6<br />
H 6<br />
+ ˙OH = C 6<br />
H 5<br />
OH + H (H atom elimination)<br />
R˙ + O 2<br />
= RO 2˙<br />
2 RO 2˙ = 2RO˙ + O 2<br />
RO 2˙ + NO = RO˙ + NO 2<br />
RO˙ + O 2<br />
= HO 2˙ + products ( aromatic-CHO, -OH)<br />
RO˙ aliphatic products
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