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Crystal Engineering on Organic Pigments

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Polymorph screening<br />

without knowledge of the crystal structure<br />

CH 3<br />

Cl<br />

N N<br />

O<br />

O<br />

S<br />

H O<br />

O<br />

2<br />

Ca 2+<br />

Until 1997: Only 1 polymorphic form<br />

No crystal structure<br />

Compound known since 1902<br />

[Deutsches Reichspatent Nr. 145908<br />

by Griesheim-Elektr<strong>on</strong> (Frankfurt)]<br />

(Ba 2+ salt: used for<br />

newspaper printings ...)<br />

Then we started syntheses and crystallizati<strong>on</strong>s ...

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