Day 12: 10 Constructed Response Questions - Revsworld
Day 12: 10 Constructed Response Questions - Revsworld
Day 12: 10 Constructed Response Questions - Revsworld
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<strong>Questions</strong> for Exam Practice<br />
One <strong>Day</strong> at a Time<br />
A not-so-overwhelming book to practice<br />
Chemistry Regents exam questions<br />
30 days of questions sets<br />
Answers given to all questions<br />
Clean Clear Easy-to-understand explanations of<br />
correct answers<br />
2 full Regents exams<br />
Track Your Progress<br />
Effiong Eyo<br />
Scholastic Publishing<br />
Surviving Chemistry Book Series<br />
Family of five books that are certain to:<br />
Excite students to study<br />
Engage students in learning<br />
Enhance students understanding<br />
For more information and to order<br />
www.e3chemistry.com (877) 224 – 0484<br />
info@e3chemistry.com
Format of this book:<br />
This book contains sets of Chemistry Regents exam questions organized<br />
into days. There are a total of 30 days of questions review.<br />
On all ODD days, students will practice only Multiple Choice exam<br />
questions. The number of multiple choice questions increases from <strong>10</strong> to<br />
15 to 20 on days 1 – 25. The Two regents exams offer students the<br />
opportunity to practice (on days 27 and 29) two sets of 50 multiple<br />
choice questions.<br />
On all EVEN days, students will practice only <strong>Constructed</strong> <strong>Response</strong><br />
exam questions. The number of <strong>Constructed</strong> <strong>Response</strong> questions stays<br />
constant at <strong>10</strong> from days 2 – 26. The two Regents exams offer students<br />
the opportunity to practice (on days 28 and 30) two sets of 30 to 34<br />
<strong>Constructed</strong> <strong>Response</strong> questions .<br />
Answers:<br />
Answers are given to all exam questions in this book.<br />
Explanations:<br />
Clean, Clear, and Easy-to-understand explanations are given to all<br />
questions on <strong>Day</strong>s 1 – 26.<br />
The Goal of this book:<br />
The format of this book is intended to allow students to:<br />
. Practice more chemistry Regents exam questions than with any<br />
other book<br />
. Build up confidence in exam taking<br />
. Build up knowledge of testable chemistry concepts<br />
. Track their progress as the Regents exam day approaches<br />
. Be better prepared for the chemistry Regents exam<br />
. Do ALL of the above without being too overwhelm
Table of Contents<br />
Multiple Choice <strong>Questions</strong> Sets<br />
<strong>Day</strong><br />
<strong>Questions</strong> Answers and<br />
Explanations<br />
1 pg 1 - 2 pg 4<br />
3 pg 9-<strong>10</strong> pg <strong>12</strong><br />
5 pg 17-18 pg 20<br />
7 pg 25-26 pg 28<br />
9 pg 35-37 pg 38-39<br />
11 pg 47-49 pg 50-51<br />
13 pg 57-59 pg 60-61<br />
15 pg 69-72 pg 74-75<br />
<strong>Day</strong> <strong>Questions</strong><br />
Answers and<br />
Explanations<br />
17 pg 81-83 pg 84-86<br />
19 pg 93-95 pg 96-97<br />
21 pg <strong>10</strong>5-<strong>10</strong>8 pg 1<strong>10</strong>-1<strong>12</strong><br />
23 pg 119-<strong>12</strong>2 pg <strong>12</strong>4-<strong>12</strong>6<br />
25 pg 133-137 pg 138-140<br />
27 pg 147-157 pg 158<br />
29 pg 179-188 pg 190<br />
<strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong> Sets<br />
<strong>Day</strong> <strong>Questions</strong> Answers <strong>Day</strong> <strong>Questions</strong> Answers<br />
2 pg 5-6 pg 8<br />
18 pg 87-89 pg 90-91<br />
4 pg 13-15 pg 16 20 pg 99-<strong>10</strong>1 pg <strong>10</strong>2-<strong>10</strong>3<br />
6 pg 21-22 pg 24 22 pg 113-115 pg 116-117<br />
8 pg 29-30 pg 32-33 24 pg <strong>12</strong>7-<strong>12</strong>9 pg 130-140<br />
<strong>10</strong> pg 41-42 pg 44-45 26 pg 141-143 pg 144-145<br />
<strong>12</strong> pg 53-55 pg 56 28 pg 159-167 pg 174-177<br />
14 pg 63-65 pg 66-67 30 pg 191-199 pg 207-211<br />
16 pg 77-79 pg 80<br />
Track Your Progress Pg 213 - 214
<strong>Day</strong> 1: <strong>10</strong> Multiple choice questions<br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. Which subatomic particle is negatively charged?<br />
(1) electron (3) positron<br />
(2) neutron (4) proton<br />
2. An element that is malleable and is a good conductor of heat and<br />
electricity could have an atomic number of<br />
(1) 16 (3) 29<br />
(2) 18 (4) 35<br />
3. The chemical bonding in sodium phosphate, Na 3PO 4, is classified as<br />
(1) ionic, only<br />
(2) metallic, only<br />
(3) both covalent and ionic<br />
(4) both covalent and metallic<br />
4. At 65 o C, which compound has a vapor pressure of 58 kilopascals?<br />
(1) ethanoic acid (3) propane<br />
(2) ethanol (4) water<br />
5. Which compound is a saturated hydrocarbon?<br />
(1) propanal (3) propene<br />
(2) propane (4) propyne<br />
6. A beta particle may be spontaneously emitted from<br />
(1) a ground-state atom<br />
(2) a stable nucleus<br />
(3) an excited electron<br />
(4) an unstable nucleus<br />
7. The compound C 2H 4 and C 4H 8 have the same<br />
(1) freezing point at standard temperature<br />
(2) boiling point at standard temperature<br />
(3) molecular formula<br />
(4) empirical formula<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 1
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<strong>Day</strong> 2:<br />
<strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> questions<br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 through 3 on the information below.<br />
Two isotopes of potassium are K-37 and K-42.<br />
1. What is the total number of neutrons in the nucleus of a K-37<br />
atom? [1]<br />
2. How many valance electrons are in an atom of K-42 in the ground<br />
state? [1]<br />
3. Explain, in terms of subatomic particles, why K-37 and K-42 are<br />
isotopes of potassium? [1]<br />
Base your answers to questions 4 through 6 on the potential energy<br />
diagram below.<br />
4. What is the heat of reaction for the forward reaction? [1] ____ KJ<br />
5. What is the activation energy for the forward reaction with<br />
the catalyst? [1]<br />
_____KJ<br />
6. Explain, in terms of the function of a catalyst, why the curves on the<br />
potential energy diagram for the catalyzed and the uncatalyzed<br />
reactions are different? [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 5
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<strong>Day</strong> 3: <strong>10</strong> Multiple Choice questions<br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. Which element has the greatest density at STP?<br />
(1) barium (3) magnesium<br />
(2) beryllium (4) radium<br />
2. A 1.0-mole sample of krypton gas has a mass of<br />
(1) 19 g (3) 39 g<br />
(2) 36 g (4) 84 g<br />
3. Standard pressure is equal to<br />
(1) 1 atm (3) 273 atm<br />
(2) 1 kPa (4) 273 kPa<br />
4. According to the kinetic molecular theory, the molecules of an ideal<br />
gas<br />
(1) have a strong attraction for each other<br />
(2) have a significant volume<br />
(3) move in random, constant, straight-line motion<br />
(4) are closely packed in a regular repeating pattern<br />
5. The isomers butane and methyl propane differ in their<br />
(1) molecular formulas<br />
(2) structural formula<br />
(3) total number of atoms per molecule<br />
(4) total number of bonds per molecule<br />
6. In the formula X 2O , the symbol X could represent an element in<br />
Group<br />
(1) 1 (3) 15<br />
(2) 2 (4) 18<br />
7. Molarity is defined as<br />
(1) moles of solutes per kilogram of solvent<br />
(2) moles of solute per liter of solution<br />
(3) mass of a solution<br />
(4) volume of solvent<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 9
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 11
<strong>Day</strong> 4: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 and 2 on the information below.<br />
Archimedes (287 – 2<strong>12</strong> BC), a Greek inventor and<br />
mathematician, made several discoveries important to science today.<br />
According to a legend, Hiero, the king of Syracuse, commanded<br />
Archimedes to find out if the royal crown was made of gold, only. The<br />
king suspected that the grown consisted of a mixture of gold, tin, and<br />
copper.<br />
Archimedes measured the mass of the crown and the total<br />
amount of water displaced by the crown when it was submerged. He<br />
repeated the procedure using individual samples, one gold, one tin, and<br />
one copper. Archimedes was unable to determine that the crown was<br />
not made entirely of gold without damaging it.<br />
1. Identify one physical property that Archimedes used in his<br />
comparison of the metal samples. [1]<br />
2. Determine the volume of a 75-gram sample of gold at STP. [1]<br />
Base your answers to questions 3 and 4 on the information below.<br />
Many esters have distinctive odors, which lead to their widespread use<br />
as artificial flavorings and fragrances. For example, methyl butanoate<br />
has an odor like pineapple and ethyl methanoate has an odor like<br />
raspberry.<br />
3. In the space below, draw a structural formula for the ester that has<br />
an odor like pineapple. [1]<br />
4. What is the chemical name for an alcohol that reacts with methanoic<br />
acid to produce the ester that has an odor like raspberry? [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 13
<strong>Day</strong> 4: continue.<br />
Base your answers to question 8 through <strong>10</strong> on the information below.<br />
A beaker contains <strong>10</strong>0.0 millimeters of a dilute aqueous solution of<br />
ethanoic acid at equilibrium. The equation below represents this system.<br />
HC 2H 3O 2(aq) < === > H+(aq) + C 2H 3O 2 -(aq)<br />
8. Compare the rate of the forward reaction to the rate of the reverse<br />
reaction for this system. [1]<br />
9. Describe what happens to the concentration of H+(aq) when <strong>10</strong><br />
drops of concentrated HC 2H 3O 2(aq) are added to this system. [1]<br />
<strong>10</strong>. In the space below, draw a structural formula for<br />
ethanoic acid. [1]<br />
<strong>Day</strong> 4<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 15
<strong>Day</strong> 5: <strong>10</strong> Multiple Choice questions<br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. What is the mass number of a carbon atom that contains six protons,<br />
eight neutrons, and six electrons?<br />
(1) 6 (3) 14<br />
(2) 8 (4) 20<br />
2. An atom in the ground state has a stable valance electron<br />
configuration. This atom could be an atom of<br />
(1) Al (3) Na<br />
(2) Cl (4) Ne<br />
3. Which equation represents an exothermic reaction at 298 K?<br />
(1) N 2(g) + O 2(g) --------- > 2NO)g)<br />
(2) C(s) + O 2(g) ---------- > CO 2(g)<br />
H<br />
(3) KNO 3(s) --------- 2O<br />
> K+(aq)<br />
H<br />
(4) NH 4Cl(s) -------- 2O<br />
> NH 4<br />
+(aq) + Cl-(aq)<br />
4. Compared to the freezing and boiling point of water at 1 atmosphere,<br />
a solution of salt and water at 1 atmosphere has a<br />
(1) lower freezing point and a higher boiling point<br />
(2) lower freezing point and a lower boiling point<br />
(3) higher freezing point and a lower boiling point<br />
(4) higher freezing point and a higher boiling point<br />
5. Which word equation represents a neutralization reaction?<br />
(1) base + acid ---- > salt + water<br />
(2) base + salt ---- > water + acid<br />
(3) salt + acid ---- > base + water<br />
(4) salt + water ---- > acid + base<br />
6. Which particle has the greatest mass?<br />
(1) an alpha particle (3) a neutron<br />
(2) a beta particle (4) a positron<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 17
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<strong>Day</strong> 6: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. Identify one ion from Table F that can combine with Pb 2+( aq) to<br />
produce an insoluble compound. [1]<br />
2. Describe one appropriate laboratory test that can be used to<br />
determine the malleability of a solid sample of an element at room<br />
temperature. [1]<br />
3. State two methods to increase the rate of a chemical reaction and<br />
explain, in terms of particle behavior, how each method increases the<br />
reaction rate. [2]<br />
Base your answers to questions 4 through 5 on the graph below, which<br />
represents the cooling of a substance starting at a temperature above its<br />
boiling point.<br />
4. What is the boiling point of this substance? [1]<br />
5. Which segment of the graph represents the gas phase, only? [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 21
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 23
<strong>Day</strong> 7: <strong>10</strong> Multiple Choice questions<br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. Which conclusion was a direct result of the gold foil experiment?<br />
(1) An atom is mostly empty space with a dense positively charged<br />
nucleus<br />
(2) An atom is composed of at least three types of subatomic<br />
particles<br />
(3) An electron has a positive charge and is located inside the nucleus<br />
(4) An electron has properties of both waves and particles<br />
2. Which atom has an atom with the greatest attraction in a chemical<br />
bond?<br />
(1) As (3) N<br />
(2) Bi (4) P<br />
3. Which formula represents a polar molecule?<br />
(1) Br 2 (3) CH 4<br />
(2) CO 2 (4) NH 3<br />
4. In which sample is the average kinetic energy of particles greatest?<br />
(1) <strong>10</strong>. mL of HCl(aq) at 25 o C (3) <strong>10</strong>. mL of H 2O(l) at 35 o C<br />
(2) 15. mL of HCl(aq) at 20 o C (4) 15. mL of H 2O(l) at 30 o C<br />
5. System in nature tend to undergo changes toward<br />
(1) lower energy and less disorder<br />
(2) lower energy and more disorder<br />
(3) higher energy and less disorder<br />
(4) higher energy and more disorder<br />
6. Which half-reaction equation represents the reduction of a potassium<br />
ion?<br />
(1) K + + e- ---- > K (3) K + --- > K + e-<br />
(2) K + e- ----- > K + (4) K ---- > K+ + e-<br />
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<strong>Day</strong> 8: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 and 2 on the information below.<br />
A light bulb contains argon gas at a temperature of 295 K and a pressure<br />
of 75 kilopascals. The light bulb is switch on, and after 30 minutes its<br />
temperature is 418 K. Assume the volume of the light bulb remains<br />
constant.<br />
1. In the space below show a correct numerical setup for calculating the<br />
pressure of the gas inside the light bulb at 418 K. Assume the volume<br />
of the light bulb remains constant. [1]<br />
2. What Celsius temperature is equal to 418 K ? [1] ___ o C<br />
Base your answers to questions 3 through 5 on the diagram of a voltaic cell<br />
and the balance ionic equation below.<br />
3. What is the total number of moles of electrons needed to completely<br />
reduce 6.0 moles of Ni 2+ (aq) ions? [1]<br />
____ mol<br />
4. Identify one metal from Reference Table J that is more easily reduced<br />
than Mg(s) . [1]<br />
5. Explain the function of salt bridge in the voltaic cell. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 29
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<strong>Day</strong> 8: Answers and Explanations: continue<br />
7) +5 Recall: sum of charges in a compound must equal zero (0)<br />
Note: In KClO 3 K = +1 1(+1) = +1 (total + so far)<br />
Determine charge of Cl : Must be<br />
O = -2 3 (-2) = -6 total – in formula<br />
+ 5 for charges to<br />
equal 0<br />
8) Alpha decay or natural transmutation<br />
Note: Decay mode (alpha) for C-14 is listed on Table N<br />
Recall: alpha decay is a type of natural transmutation<br />
9) 28650 y Note: This is a half-life problem that should be set up<br />
and solve using the fraction remaining equation<br />
Recall: Fraction Remaining equation is on Table T<br />
Use fraction 1 / 32 to determine # of half-life periods (n)<br />
Fraction Remaining = 1/ 32 = 1/ 2 n n = 5<br />
Use equation below to determine length of time<br />
Length of Time = half-life x n<br />
= 5730 x 5 = 28650 y<br />
Note: Half-life of C-14 (5730 yrs) is given on Table N<br />
<strong>10</strong>) C-13 is different from C-<strong>12</strong> in that C-13 has a different<br />
number (more) neutrons.<br />
Note: C-<strong>12</strong> and C-13 are isotopes<br />
Recall: isotopes are different because of the different<br />
numbers of neutron<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 33
<strong>Day</strong> 9: <strong>10</strong> Multiple Choice questions<br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. In the wave-mechanical model of the atom, orbitals are regions of<br />
the most probable locations of<br />
(1) protons (3) neutrons<br />
(2) positrons (4) electrons<br />
2. As the elements of Group 17 are considered in order of increasing<br />
atomic number, there is an increase in<br />
(1) atomic radius<br />
(2) electronegativity<br />
(3) first ionization energy<br />
(4) number of electrons in the first shell<br />
3. What is the chemical formula for iron (III) oxide?<br />
(1) FeO (3) Fe 3O<br />
(2) Fe 2O 3 (4) Fe 3O 2<br />
4. Given a formula for oxygen:<br />
. . . .<br />
O . . = O . .<br />
What is the total number of electrons shared between the atoms<br />
represented in this formula?<br />
(1) 1 (3) 8<br />
(2) 2 (4) 4<br />
5. What is the IUPAC name of the organic compound that has the<br />
formula shown below?<br />
H<br />
I<br />
H – C – H<br />
H H H H<br />
I I I I<br />
H – C – C – C – C – C – H<br />
I I I I I<br />
H H H H H<br />
(1) 1,1-dimethylbutane (3) hexane<br />
(2) 2-methylpentane (4) 4-methylpentane<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 35
<strong>Day</strong> 9: continue.<br />
9. A sample of a gas occupies a volume of 50. millimeters in a<br />
cylinder with a movable piston. The pressure of the sample is 0.90<br />
atmosphere and the temperature is 298 K. What is the volume of<br />
the sample at STP?<br />
(1) 41 mL (3) 51 mL<br />
(2) 49 mL (4) 55 mL<br />
<strong>10</strong>. Which general formula represents the compound CH 3CH 2CCH?<br />
(1) C nH n (3) C nH 2n-2<br />
(2) C nH 2n (4) C nH 2n+2<br />
<strong>Day</strong> 9<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 37
<strong>Day</strong> 9: Answers and Explanations: continue<br />
7) 3 Note: Part of the answer to this questions requires using Table G.<br />
According to Table G<br />
In <strong>10</strong>0g H 2O at 25 o C: 35g of KCl forms a saturated solution<br />
In 50g H 2O at 25 o C : 17.5 g of KCl will be a saturated solution<br />
(Half amount of H2O)<br />
(Half the grams of KCl)<br />
Note:<br />
only 5 g of KCl is in solution in the question<br />
Recall: a solution (which is always a homogeneous mixture)<br />
containing less (5g KCl) than the saturated amount<br />
(17.5 g) is unsaturated<br />
8) 1 Note from the graph: melting occurs between the 2 nd and 5 th<br />
minutes ( a total of 3 minutes) at 50 o C<br />
9) 1 Note: This is a Gas law problem:<br />
Use Combined Gas Law equation on Table T to setup and solve<br />
for the new volume<br />
P 1V 1 P 2V 2<br />
T 1<br />
= T 2<br />
(.9)(50) = 1(X)<br />
298 273<br />
Setup<br />
298 X = (.9) (50) (273 cross-multiply to get<br />
X = 41.2 mL calculated result for V 2<br />
<strong>10</strong>) 3 Note the following about the formula: CH 3CH 2CCH (C 4H 6 )<br />
there are 4 C 6 H (the number of H is twice the<br />
number of C minus 2)<br />
Relate: This formula fits general formula C nH 2n-2<br />
(Listed on Table Q for alkynes)<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 39
<strong>Day</strong> <strong>10</strong>: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. What is the oxidation number of nitrogen in NO(g) ? [1]<br />
2. Write an electron configuration for an atom of aluminum-27 in an<br />
excited state. [1]<br />
3. What color is bromcresol green after it is added to a sample of<br />
NaOH(aq)? [1]<br />
4. Because tap water is highly acidic, water pipes made of iron erode<br />
over time, as shown by the balanced ionic equation below:<br />
2Fe + 6H+ ------ > 2Fe 3+ + 3H 2<br />
Explain, in terms of chemical reactivity, why copper pipes are less<br />
likely to corrode than iron pipes. [1]<br />
Base your answers to questions 5through 6 on the information below.<br />
Given the balance equation for an organic reaction between butane<br />
and chlorine that takes place at 300 o C and <strong>10</strong>1.3 kilopascals:<br />
C 4H <strong>10</strong> + Cl 2 ----- > C 4H 9Cl + HCl<br />
5. Identify the type of organic reaction shown. [1]<br />
6. In the space below, draw the structural formula for the organic<br />
product. [1]<br />
7. Explain, in terms of collision theory, why the rate of the reaction<br />
would decrease if the temperature of the reaction mixture was<br />
lowered to 200. o C with pressure remaining unchanged. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 41
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<strong>Day</strong> <strong>10</strong>: Answers and Explanations: continue<br />
7. Rate of the reaction will decrease when temperature is decreased<br />
because particles will collide less frequently due to a<br />
decrease in their average kinetic energy.<br />
8.<br />
9.<br />
<strong>10</strong>. As atomic number increases, boiling point increases.<br />
Note: Your answer may vary based on your graph<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 45
<strong>Day</strong> 11: 15 Multiple Choice questions<br />
Start: Answer all 15 questions on this day before stopping.<br />
1. Which particle has a mass approximately the same as the mass of a<br />
proton?<br />
(1) an alpha particle (3) a neutron<br />
(2) a beta particle (4) a positron<br />
2. The most common isotope of chromium has a mass of 52. Which<br />
notation represents a different isotope of chromium?<br />
(1) 52 Cr (3) 24 Cr<br />
24 52<br />
(2) 54 Cr (4) 24 Cr<br />
24 54<br />
3. Which substance can be broken down by chemical means?<br />
(1) CO (3) Ca<br />
(2) Ce (4) Cu<br />
4. The bonds in BaO are best described as<br />
(1) covalent, because valance electrons are shared<br />
(2) covalent, because valance electrons are transferred<br />
(3) ionic, because valance electrons are shared<br />
(4) ionic, because valance electrons are transferred<br />
5. The net energy released or absorbed during a reversible chemical<br />
reaction is equal to<br />
(1) the activation energy of the endothermic reaction<br />
(2) the activation energy of the exothermic reaction<br />
(3) the difference in the potential energy of products and the<br />
potential energy of the reactants<br />
(4) The sum of the potential energy of the products and the<br />
potential energy of the reactants<br />
6. Which class of organic compounds has a molecule that contain<br />
nitrogen atom?<br />
(1) alcohol (3) ether<br />
(2) amine (4) ketone<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 47
<strong>Day</strong> 11: continue.<br />
<strong>12</strong>. The diagram below represents the nucleus of an atom.<br />
9 p<br />
11 n<br />
What are the atomic number and the mass number of this atom?<br />
(1) The atomic number is 9 and the mass number is 19<br />
(2) The atomic number is 9 and the mass number is 20<br />
(3) The atomic number is 11 and the mass number is 19<br />
(4) The atomic number is 11 and the mass number is 20<br />
13. Which list of elements consist of metalloids?<br />
(1) B, Al, Ga (3) O, S, Se<br />
(2) C, N, P (4) Si, Ge, As<br />
14. Which volume of 0.<strong>10</strong> M NaOH(aq) exactly neutralizes<br />
15.0 millimeters of 0.20 M HNO 3 (aq) ?<br />
(1) 1.5 mL (3) 3.0 mL<br />
(2) 7.5 mL (4) 30. mL<br />
15. Which fraction of an original 20.00-gram sample of nitrogen-16<br />
remains unchanged after 36.0 seconds?<br />
(1) 1 / 5 (3) 1 / 16<br />
(2) 1 / 8 (4) 1 / 32<br />
<strong>Day</strong> 11<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 49
<strong>Day</strong> 11: Answers and Explanations. continue<br />
11) 2 Note: according to the equation, NH 3 accepts a H+ to<br />
become NH 4<br />
+<br />
NH 3 + H 2O ------- > NH 4<br />
+ + OH-<br />
H + (proton) H + (proton)<br />
acceptor<br />
donor<br />
<strong>12</strong>) 2 Recall: Atomic number (9) = number of protons (9p)<br />
Recall: Mass number (20) = Protons (9) + neutrons (11)<br />
13) 4 Use Periodic Table to note elements that are metalloids<br />
14) 4 Note: This is a titration problem<br />
Use titration equation on Table T to setup and solve for volume<br />
M A V A = M B V B<br />
Setup<br />
(0.20)(15.0) = (0.<strong>10</strong>) (X)<br />
Solve 30 mL = X<br />
15) 4 Note: This is a half-life problem that can be solved in two steps.<br />
First: Calculate number of half-life periods (n) from times.<br />
length of time (T) 36<br />
n= = = 5<br />
half- life (t) 7.2<br />
Note: half-life of N-16 is on Table N<br />
Second: Calculate Fraction remaining using Table T equation<br />
1 1 1<br />
Fraction remaining = = =<br />
2 n 2 x 2 x 2 x 2 x 2 32<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 51
<strong>Day</strong> <strong>12</strong>: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 through 3 on the information below.<br />
The particle diagrams below represents the reaction between two<br />
nonmetals, A 2 and Q 2.<br />
Key<br />
= Atom of element A<br />
= Atom of element Q<br />
reactants<br />
products<br />
1. Using the symbols A and Q, write the chemical formula of the<br />
product. [1]<br />
2. Identify the type of chemical bond between an atom of element A<br />
and an atom of element Q. [1]<br />
3. Compare the total mass of the reactants to the total mass of the<br />
product. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 53
6. On the grid below, plot the data from the data table for<br />
frequency and energy. Circle and connect the points, including<br />
the point (0,0) that has already been plotted and circled for you. [1]<br />
7. A spectral line in the infrared region of the spectrum of hydrogen has<br />
a frequency of 2.3 x <strong>10</strong> 14 hertz. Using your graph, estimate the<br />
energy associated with this spectral line. [1]<br />
_________ x <strong>10</strong> -19<br />
8. Explain, in terms of subatomic particles and energy states, why light<br />
is emitted by the hydrogen gas. [1]<br />
9. Identify one condition not mentioned in the passage, under which<br />
hydrogen gas behaves most like an ideal gas. [1]<br />
<strong>Day</strong> <strong>12</strong><br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 55
<strong>Day</strong> 13: 15 Multiple Choice questions<br />
Start: Answer all 15 questions on this day before stopping.<br />
1. Which quantity identifies an element?<br />
(1) atomic number<br />
(2) mass number<br />
(3) total number of neutrons in an atom of the element<br />
(4) total number of valance electrons in an atom of the element<br />
2. Which element has the greatest density?<br />
(1) calcium (3) chlorine<br />
(2) carbon (4) copper<br />
3. Which equation shows conservation of atoms?<br />
(1) H 2 + O 2 ----- > H 2O<br />
(2) H 2 + O 2 ------ > 2H 2O<br />
(3) 2H 2 + O 2 ---- > 2H 2O<br />
(4) 2H 2 + 2O 2 ---- > 2H 2O<br />
4. A solid substance is an excellent conductor of electricity. The<br />
chemical bonds in this substance are mostly<br />
(1) ionic, because valance electrons are shared between atoms<br />
(2) ionic, because the valance electrons are mobile<br />
(3) metallic, because the valance electrons are stationary<br />
(4) metallic, because the valance electrons are mobile<br />
5. Which barium salt is insoluble in water?<br />
(1) BaCO 3 (3) Ba(ClO 4) 2<br />
(2) BaCl 2 (4) Ba(NO 3) 2<br />
6. Which substance is an Arrhenius acid?<br />
(1) Ba(OH) 2 (3) H 3PO 4<br />
(2) CH 3COOCH 3 (4) NaCl<br />
7. Which energy conversion occurs in a voltaic cell?<br />
(1) chemical energy to electrical energy<br />
(2) chemical energy to nuclear energy<br />
(3) electrical energy to chemical energy<br />
(4) nuclear energy to electrical energy<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 57
<strong>Day</strong> 13: continue.<br />
14. The potential energy diagram for a chemical reaction is shown<br />
below.<br />
Each interval on the axis labeled “Potential Energy (KJ)” represents<br />
40 kilojoules. What is the heat of reaction?<br />
(1) -<strong>12</strong>0 KJ (3) +40 KJ<br />
(2) -40 KJ (4) +160 KJ<br />
15. Given the balanced equation representing a nuclear reaction:<br />
235 1 142 91<br />
U + n ----- > Ba + Kr + 3X + energy<br />
92 0 56 36<br />
Which particle is represented by X?<br />
(1) 0 e (3) 4 He<br />
-1 2<br />
(2) 1 H (4) 1 n<br />
1 0<br />
<strong>Day</strong> 13<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 59
<strong>Day</strong> 13: Answers and Explanations continue.<br />
<strong>10</strong>) 1 Recall: Brittleness and low conductivity describe nonmetallic<br />
solids.<br />
Relate: Sulfur is a nonmetal.<br />
11) 4 Recall: A decrease in pH (becomes more acidic) is a result of<br />
an increase in hydronium (H 3O + ) or hydrogen ion<br />
(H+) concentration .<br />
Recall: <strong>10</strong> fold increase in H 3O + = 1 value decrease in pH<br />
<strong>10</strong>0 fold increase in H 3O + = 2 values decrease in pH<br />
Correct choice (pH 3 to pH 1 ) is a 2 value decrease<br />
<strong>12</strong>) 3 Determine greatest common factor and reduce the subscripts by<br />
that factor.<br />
Note: C 6H <strong>12</strong>Cl 2O 2 has GCF of 2, and can be reduced to<br />
C 3H 2ClO<br />
13) 1 Note: C 3H 8 fits general formula for alkanes,C nH 2n+6 (Table Q)<br />
Note: CH 4 is also an alkane, therefore, same homologous series<br />
14) 3 Recall: Heat of reaction (∆H) = Hproduct – Hreactant<br />
Note from diagram: Hproduct (<strong>12</strong>0 KJ) and Hreactant (80 KJ).<br />
Calculate: Heat of reaction (∆H) = <strong>12</strong>0 KJ – 80 KJ = +40 KJ<br />
15) 4 Note: The equation represent fission reaction<br />
Recall: neutrons ( 1 n ) are also released during fission process.<br />
0<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 61
<strong>Day</strong> 14: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 though 3 on the data table below.<br />
Formulas and Boiling Points of Selected Alkanes.<br />
Name Formulas Boiling Point at<br />
1 ATM ( o C)<br />
methane CH 4 -162<br />
ethane C 2H 6 -89<br />
propane C 3H 8 -42<br />
butane C 4H <strong>10</strong> -0.5<br />
pentane C 5H <strong>12</strong> 36<br />
1. In the space below, draw a structural formula for butane. [1]<br />
2. At standard pressure and 298 K, which alkane is a liquid? [1]<br />
3. What is the boiling point of propane at 1 atmosphere, in<br />
Kelvins? [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 63
<strong>Day</strong> 14: continue.<br />
Base your answers to questions 9 and <strong>10</strong> on the information below.<br />
A 4.86 gram sample of calcium reacted completely with<br />
oxygen to form 6.80 grams of calcium oxide. This<br />
reaction is represented by the balanced equation below.<br />
2 Ca(s) + O 2(g) ----- > 2CaO(s)<br />
9. Determine the total mass of oxygen that reacted. [1]<br />
<strong>10</strong>. Explain, in terms of electrons, why the radius of a calcium ion is<br />
smaller than the radius of a calcium atom. [1]<br />
<strong>Day</strong> 14<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 65
<strong>Day</strong> 14: Answers and Explanations:<br />
continue<br />
7) No change in solubility<br />
Recall: Pressure change has no effect<br />
on solubility of a solid such as KNO 3(s)<br />
8) 60 grams<br />
Use Table G: saturation amount of KNO 3 at 15 o C = 30g<br />
Calculate amount that settle to bottom<br />
= Grams KNO 3 in solution – saturated grams at 15 o C<br />
= 90 g – 30 g = 60g<br />
9) 1.94 g Recall: Total Mass of Reactants = Total Mass of Products<br />
Ca + O 2 ------ > 2 CaO<br />
4.86 g + 1.94 g = 6.80 g<br />
<strong>10</strong>) Radius of a calcium ion ( Ca 2+ ) is smaller than the radius of a<br />
calcium atom (Ca ) because a calcium ion has 2 less electrons<br />
(or 1 less electron shell) than Ca atom<br />
Recall: Ca forms a Ca 2+ ion (See Periodic Table).<br />
Recall: an atom becomes a positive ion by losing electrons<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 67
<strong>Day</strong> 15: 15 Multiple Choice questions<br />
Start: Answer all 15 questions on this day before stopping.<br />
1. Which statement describes the relative energy of the electrons in the<br />
shell of a calcium atom?<br />
(1) An electron in the first shell has more energy than an electron in<br />
the second shell<br />
(2 An electron in the first shell has the same amount of energy as an<br />
electron in the second shell<br />
(3) An electron in the third shell has more energy than an electron in<br />
the second shell<br />
(4) An electron in the third shell has less energy than an electron in the<br />
second shell<br />
2. Which Group 14 element is a metalloid?<br />
(1) tin (3) lead<br />
(2) silicon (4) carbon<br />
3. Which formula represents a molecular compound?<br />
(1) Kr (3) N 2O 4<br />
(2) LiOH (4) NaI<br />
4. A reaction is most likely to occur when reactant particle collide with<br />
(1) proper energy, only<br />
(2) proper orientation, only<br />
(3 both proper energy and proper orientation<br />
(4) neither proper energy nor proper orientation<br />
5. Which element is present in every organic compound?<br />
(1) carbon (3) nitrogen<br />
(2) fluorine (4) oxygen<br />
6. What is the total number of valance electrons in an atom of<br />
germanium in the ground state?<br />
(1) 8 (3) 14<br />
(2) 2 (4) 4<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 69
<strong>Day</strong> 15: continue.<br />
<strong>12</strong>. What is the percent composition by mass of hydrogen in<br />
NH 4HCO 3 (gram-formula mass = 79 grams per mole)<br />
(1) 5.1 % (3) <strong>10</strong>. %<br />
(2) 6.3 % (4) 50. %<br />
13. Which particle model diagram represents only one compound<br />
composed of elements X and Z?<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 71
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 73
<strong>Day</strong> 15: Answers and Explanations: continue<br />
9) 1 Recall: single replacement, decomposition and synthesis<br />
reactions are all considered redox reactions.<br />
Note: Choice 1 equation is a synthesis reactions.<br />
or<br />
Recall: a reaction equation is a redox if there is a change of<br />
oxidation numbers (lost and gained of electrons)<br />
Note: Both P and Cl go through changes in oxidation numbers<br />
<strong>10</strong>) 2 Recall : number of electron = number of protons (Atomic #)<br />
Note: numbers in configuration are number of electrons<br />
Sum of numbers in the configuration<br />
2 – 8 – 18 – 32 – 18 – 1 = 79 = number of protons<br />
11) 2 Recall: compounds containing both ionic and covalent<br />
bonds likely contain a polyatomic ion or have three<br />
or more elements<br />
Note: Sodium nitrate (NaNO 3) contains a polyatomic ion<br />
(NO 3). It also contains three different elements<br />
<strong>12</strong>) 2 Note: Percent composition equation is on Table T<br />
total mass of 5 H<br />
% H = x <strong>10</strong>0<br />
formula mass<br />
5<br />
% H = x <strong>10</strong>0 = 6.1 %<br />
79<br />
13) 1 Recall: a diagram of a compound must show the two<br />
different atoms touching (bonding)<br />
All units in the diagram must be identical.<br />
14) 1 Temperature: Least entropy must be lowest temp. (266 K)<br />
Phase: Lowest entropy must be a solid. Br 2(s)<br />
15) 1 Note: this is a half-life problem that can be solved in two steps.<br />
First determine number of half-life period from masses.<br />
25 g---> <strong>12</strong>.5 ----> 6.25 ---- > 3.<strong>12</strong>5 g (3 arrows = 3 periods)<br />
Second: use equation below to determine half-life<br />
Length of time 3.9 x <strong>10</strong><br />
Half-life = = 9<br />
= 1.3 x <strong>10</strong><br />
half-life periods 3<br />
9 y<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 75
<strong>Day</strong> 16: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 through 3 on the information below.<br />
A <strong>10</strong>0.0-gram sample of NaCl(s) has an initial temperature of 0 o C. A<br />
chemist measures the temperature of the sample as it is heated. Heat is not<br />
added at a constant rate. The heating curve for the sample is shown below.<br />
1. Determine the temperature range over which the entire NaCl sample<br />
is a liquid. [1]<br />
2. Identify one line segment on the curve where the average kinetic<br />
energy of the particles of the NaCl sample is changing. [1]<br />
3. Identify one line segment on the curve where the NaCl sample is in a<br />
single phase and capable of conducting electricity. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 77
<strong>Day</strong> 16: continue.<br />
Base your answers to questions 7 through <strong>10</strong> on the information below.<br />
When a person perspires (sweats), the body loses many sodium ions<br />
and potassium ions. The evaporation of sweat cools the skin.<br />
After a strenuous workout, people often quench their thirst with<br />
sport drinks that contain NaCl and KCl. A single 250.0 grams serving<br />
of one sport drink contains 0.055 gram of sodium ions.<br />
7. In the space below, show a numerical setup for calculating the<br />
concentration of sodium ions in this sport drinks, expressed as<br />
percent by mass. [1]<br />
8. Describe the transfer of energy between skin and the surroundings as<br />
a person perspires and the sweat evaporates. [1]<br />
9. State why the salt in sport drinks are classified as electrolytes. [1]<br />
<strong>10</strong>. In the space in your answer booklet, draw a Lewis electron-dot<br />
diagram for one of the positive ions lost by the body as a person<br />
perspires. [1]<br />
<strong>Day</strong> 16<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 79
<strong>Day</strong> 17: 15 Multiple Choice questions<br />
Start: Answer all 15 questions on this day before stopping.<br />
1. An atom of an element forms a 2+ ion. In which Group on the<br />
Periodic Table could this element be located?<br />
(1) 1 (3) 13<br />
(2) 2 (4) 17<br />
2. During all chemical reactions, mass, energy, and charge are<br />
(1) absorbed (3) formed<br />
(2) conserved (4) released<br />
3. Samples of four Group 15 elements, antimony, arsenic, bismuth, and<br />
phosphorus, are in the gaseous phase. An atom in the ground state of<br />
which element requires the least amount of energy to remove its most<br />
loosely held electron?<br />
(1) As (3) P<br />
(2) Bi (4) Sb<br />
4. An atom of an element has a total of <strong>12</strong> electrons. An ion of the same<br />
element has a a total of <strong>10</strong> electrons. Which statement describes the<br />
charge and radius of the ion?<br />
(1) The ion is positively charged and its radius is smaller than the<br />
radius of the atom<br />
(2) The ion is positively charged and its radius is larger than the<br />
radius of the atom<br />
(3) The ion is negatively charged and its radius is smaller than the<br />
radius of the atom<br />
(4) The ion is negatively charged and its radius is larger than the<br />
radius of the atom<br />
5. At STP, which 2.0 gram sample of matter uniformly fills a<br />
340-millimeters closed container?<br />
(1) Br 2(l) (3) KCl(aq<br />
(2) Fe(NO 3) 2(s) (4) Xe(g)<br />
6. At standard pressure, which element has a freezing point below<br />
standard temperature?<br />
(1) In (3) Hf<br />
(2) Ir (4) Hg<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 81
<strong>Day</strong> 17: continue.<br />
13. The table below indicates the stability of six nuclides.<br />
Stability of Six Nuclide<br />
Nuclide Stability<br />
C-<strong>12</strong> stable<br />
C-14 unstable<br />
N-14 stable<br />
N-16 unstable<br />
O-16 stable<br />
O-19 unstable<br />
All atoms of the unstable nuclide listed in this table have<br />
(1) an odd number of neutrons<br />
(2) an odd number of protons<br />
(3) more neutrons than protons<br />
(4) more protons than neutrons<br />
14. What is the oxidation number of sulfur in Na 2S 2O 3?<br />
(1) -1 (3) +6<br />
(2) +2 (4) +4<br />
15. Which two compounds have the same molecular formula but<br />
different chemical and physical properties?<br />
(1) CH 3CH 2Cl and CH 3CH 2Br<br />
(2) CH 3CHCH 2 and CH 3CH 2CH 3<br />
(3) CH 3CHO and CH 3COOCH 3<br />
(4) CH 3CH 2OH and CH 3OCH 3<br />
<strong>Day</strong> 17<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 83
<strong>Day</strong> 17: Answers and Explanations: continue<br />
<strong>10</strong>. 1 Note: This is parts per million concentration problem<br />
Use parts per million equation (Table T) to setup and solve<br />
ppm =<br />
Grams of solute<br />
x 1 000 000<br />
Grams of solution<br />
Grams of solute =<br />
Grams of solute =<br />
ppm x grams of solution<br />
1 000 000<br />
5 x <strong>10</strong>00<br />
1 000 000<br />
= 0.005 g<br />
11) 2 Note: An indicator (Table M) is good for distinguishing<br />
between two solutions of different pH if the indicator<br />
will change different colors in the two solution.<br />
Note: According to pH range for bromcresol green (Table M)<br />
In a solution with pH 3.5, bromcrsol green will be yellow.<br />
In a solution with pH 5.5, bromcresol green will be blue.<br />
<strong>12</strong>) 3 Recall: a correct reduction equation must show :<br />
electrons (e-) lost to the left of arrow and<br />
sum of charges must be equal on both sides<br />
Note: Mn 4+ + e- ---- > Mn 3+ is a correct reduction<br />
equation because e- is left of arrow and sum of<br />
charges are equal (+3) on both sides.<br />
13) 3 Note: This choice is the only true information for all the<br />
unstable nuclei: They each have more neutrons<br />
(mass # - atomic #) than protons (atomic #)<br />
Note: unstable nuclei mass # = protons (atomic #) + neutrons<br />
C-14 14 6 8<br />
N-16 16 7 9<br />
O-19 19 8 11<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 85
<strong>Day</strong> 18: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
1. Describe one chemical property of Group 1 metals that results from<br />
the atoms of each metal having only one valance electrons. [1]<br />
2. Given the balance equation representing a reaction:<br />
N 2(g) + O 2(g)<br />
+ 182.6 KJ --- > 2NO (g)<br />
On the labeled axes below, draw a potential energy diagram for this<br />
reaction . [1]<br />
Potential Energy<br />
Reaction Coordinate<br />
3. Write one electron configuration for an atom of silicon in an excited<br />
state. [1]<br />
4. Write the empirical formula for the compound C 8H 18. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 87
<strong>Day</strong> 18: continue.<br />
Base your answers to questions 8 through <strong>10</strong> on the information below.<br />
Isotopes<br />
Naturally Occurring Isotopes of Sulfur.<br />
Atomic Mass<br />
(atomic mass unit, u)<br />
Natural Abundance<br />
(%)<br />
32S 31.97 94.93<br />
33S 32.97 0.76<br />
34S 33.97 4.29<br />
36S 35.97 0.02<br />
8. State, in terms of the number of subatomic particles, one similarity<br />
and one difference between the atoms of these isotopes of sulfur. [1]<br />
9. In the space below, draw a Lewis electron-dot diagram<br />
for an atom of sulfur-33. [1]<br />
<strong>10</strong>. In the space below, show a correct numerical setup<br />
for calculating the atomic mass of sulfur. [1]<br />
<strong>Day</strong> 18<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 89
<strong>Day</strong> 18: Answers and Explanations: continue<br />
7) 915 J Note: This is a heat calculation problem<br />
Recall: Heat equations are on Table T<br />
Use heat of fusion equation: q = m Hf<br />
Setup and solve: Heat (q) = (7.5)(<strong>12</strong>2) = 915 J<br />
8) Similarity They all have same number of protons<br />
Difference: They have different number of neutrons.<br />
Recall: Isotope is defined as atoms of the same element<br />
with same number of protons but different<br />
number of neutrons<br />
9) Recall: A Lewis electron-dot structure must show<br />
the symbol of the atom ( S) and dots equal<br />
to the number of its valance electrons (6).<br />
Recall: Number of valance electrons (6) is the last<br />
number in a configuration ( 2 – 8 – 6)<br />
See Periodic Table.<br />
<strong>10</strong>) (.9493 x 32) + (.0076 x 33) + (.0429 x 34) + (.0002 x 36)<br />
Note: Setup may vary slightly<br />
Note: Setup must show the addition of all the products of<br />
( decimal of each percent x the mass #)<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 91
<strong>Day</strong> 19: 15 Multiple Choice questions<br />
Start: Answer all 15 questions on this day before stopping.<br />
1. An atom in the ground state has seven valance electrons. The atom<br />
could be an atom of which element?<br />
(1) calcium (3) oxygen<br />
(2) fluorine (4) sodium<br />
2. Which statement identifies the element arsenic?<br />
(1) Arsenic has atomic number of 33.<br />
(2) Arsenic has a melting point of 84 K.<br />
(3) An atom of arsenic in the ground state has eight valance electrons.<br />
(4) An atom of arsenic in the ground state has a radius of 146 pm..<br />
3. What is the number of electrons in an atom of potassium?<br />
(1) 18 (3) 20<br />
(2) 19 (4) 39<br />
4. Which statement describes a chemical property of hydrogen gas?<br />
(1) Hydrogen gas burns in air<br />
(2) Hydrogen gas is colorless<br />
(3) Hydrogen gas has a density of 0.000 9 g/cm 3 at STP<br />
(4) Hydrogen gas has a boiling point of 20. K at standard pressure.<br />
5. Which unit can be used to express solution concentration?<br />
(1) J/mol (3) mol/L<br />
(2) L/mol (4) mol/s<br />
6. Given the equation representing a system at equilibrium:<br />
H 2O(s) < ===== > H 2O(l)<br />
At which temperature does this equilibrium exist at <strong>10</strong>1.3 kilopascals?<br />
(1) 0 K (3) 32 K<br />
(2) 0 o C (4) 273 o C<br />
7. Which metal is more active than Ni and less active then Zn?<br />
(1) Cu (3) Mg<br />
(2) Cr (4) Pb<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 93
<strong>Day</strong> 19: continue.<br />
14. The graph below represents the relationship between temperature<br />
and time as heat is added to a sample of H 2O.<br />
Which statement correctly describes the energy of the particles of the<br />
sample during interval BC ?<br />
(1) Potential energy decreases and average kinetic energy increases<br />
(2) Potential energy increases and average kinetic energy decreases<br />
(3) Potential energy increases and average kinetic energy remains the<br />
same.<br />
(4) Potential energy remains the same and average kinetic energy<br />
increases.<br />
15. Given the balanced equation representing a reaction:<br />
C 3H 8(g ) + 5O 2(g) ---- > 3CO 2(g) + 4H 2O(l)<br />
What is the total number of moles of O 2(g) required for the<br />
complete combustion of 1.5 moles of C 3H 8(g) ?<br />
(1) 0.30 mol (3) 4.5 mol<br />
(2) 1.5 mol (4) 7.5 mol<br />
<strong>Day</strong> 19<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 95
<strong>Day</strong> 19: Answers and Explanations<br />
9) 4 Recall: Hydroxide (OH-) are produced by bases.<br />
Note: Bases(such as KOH) are listed on Table L<br />
<strong>10</strong>) 2 Note: Of all the changes to the reaction given as choices ,<br />
a decrease in temp is the change that will produce<br />
slower rate (proceed slower)<br />
All other changes will produce faster rates of reaction<br />
11) 1 Note: Table G shows solubility of substances<br />
Note: At any given temperature, the substance closest to<br />
bottom is the least soluble at that temperature.<br />
Note: At 6.0 o C, KClO 3 curve is closest to the bottom<br />
<strong>12</strong>) 2 Recall: an excited state configuration is not the same as what’s<br />
on the Periodic Table for a given element.<br />
Note: The correct choice has <strong>10</strong> e- = # of e- in a neon atom.<br />
But the configuration is differently arranged from one<br />
given on Periodic Table for a ground state Ne.<br />
13) 1 Recall: decay mode are given on Table N<br />
Note: according to Table N, both Ca-37 and Fe-53 decay by<br />
emitting a positron (β+)<br />
14) 3 Note: During BC, temperature is constant (therefore, no<br />
change in average kinetic energy)<br />
Recall: When kinetic energy is constant, potential energy changes.<br />
15) 4 Note: This is a mole proportion problem<br />
Setup mole proportion to solve:<br />
1 C 3H 8(g ) + 5O 2(g) ---- > 3CO 2(g) + 4H 2O(l)<br />
1.5 x<br />
1<br />
=<br />
5<br />
1.5 x x = (1.5) (5) = 7.5 mol<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 97
<strong>Day</strong> 20: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 and 2 on the information below.<br />
In 1987, J.J. Thompson demonstrated in an experiment that<br />
cathode rays were deflected by an electric field. This suggested that<br />
cathode rays were composed of negatively charged particles found in all<br />
atoms. Thomson concluded that the atom was a positively charged sphere<br />
of almost uniform density in which negatively charged particles were<br />
embedded. The total negative charge in an atom was balanced by the<br />
positive charge, making the atom electrically neutral.<br />
In the early 1900’s, Ernest Rutherford bombarded a very thin<br />
sheet of gold foil with alpha particles. After interpreting the results of the<br />
gold foil experiment, Rutherford proposed a more sophisticated model of<br />
the atom.<br />
1. State one conclusion from Rutherford’s experiment that contradicts<br />
one conclusion made by Thomson. [1]<br />
2. State one aspect of the modern model of the atom that agrees with a<br />
conclusion made by Thomson. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 99
<strong>Day</strong> 20: continue.<br />
Base your answer to questions 6 through 8 on the information below.<br />
During a bread-making process, glucose is converted to<br />
ethanol and carbon dioxide, causing the bread dough to<br />
rise. Zymase, an enzyme produced by yeast, is a catalyst<br />
needed for this reaction.<br />
6. Balance the equation below for the reaction that causes bread dough<br />
to rise, using the smallest whole-number coefficients. [1]<br />
zymase<br />
___ C 6H <strong>12</strong>O 6 ------- > ___C 2H 5OH + ___CO 2<br />
7. In the space in your answer booklet, draw a structural formulas for<br />
the alcohol formed in this reaction. [1]<br />
8. State the effect of zymase on the activation energy for this<br />
reaction. [1]<br />
-------------------------------------------------------------------------<br />
9. Explain, in terms of collision theory, why the rate of a chemical<br />
reaction increases with an increase in temperature. [1]<br />
<strong>10</strong>. Base on the Periodic Table, explain why chlorine and bromine have<br />
similar chemical properties [1]<br />
<strong>Day</strong> 20<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>10</strong>1
<strong>Day</strong> 20: Answers and Explanations: continue<br />
6) C 6H <strong>12</strong>O 6 ------- > 2C 2H 5OH + 2CO 2<br />
Recall: a balanced equation must show conservation of atoms;<br />
Number of each atom on both sides must be the same<br />
Note: The coefficients above allows there to be 6 C, <strong>12</strong> H, and<br />
6 O atoms on each side of the equation .<br />
7) H H<br />
I I<br />
H – C – C – OH<br />
I I<br />
H H<br />
Note: The position of the OH may vary<br />
8) Zymase (a catalyst) lowers activation energy for the reaction.<br />
or<br />
Zymase provides alternate pathways for the reaction.<br />
9) When temperature increases, reaction rate increases because there<br />
will be an increase in the kinetic energy of the particles and<br />
the frequency of collisions.<br />
<strong>10</strong>) Cl and Br have similar chemical properties because: (answers may vary)<br />
Cl and Br are in the same Group (17).<br />
Cl and Br are halogens<br />
Cl and Br have the same number of valance electrons<br />
Cl and Br have similar oxidation state.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>10</strong>3
<strong>Day</strong> 21: 20 Multiple Choice questions<br />
Start: Answer all 20 questions on this day before stopping.<br />
1. Which subatomic particles are located in the nucleus of a neon atom?<br />
(1) electrons and positrons<br />
(2) electrons and neutrons<br />
(3) protons and neutrons<br />
(4) protons and electrons<br />
2. An atom of argon rarely bonds to an atom of another element<br />
because an argon atom has<br />
(1) 8 valance electrons<br />
(2) 2 electrons in the first shell<br />
(3) 3 electron shells<br />
(4) 22 neutrons<br />
3. Bronze contains 90 to 95 percent copper and 5 to <strong>10</strong> percent tin.<br />
Because these percentages can vary, bronze is classified as<br />
(1) a compound (3) a mixture<br />
(2) an element (4) a substance<br />
4. Which compound has hydrogen bonding between its molecules?<br />
(1) CH 4 (3) KH<br />
(2) CaH 2 (4) NH 3<br />
5. At STP, which list of elements contains a solid, a liquid, and a gas?<br />
(1) Hf, Hg, He (3) Ba, Br 2, B<br />
(2) Cr, Cl 2, C (4) Se, Sn, Sr<br />
6. The three isomers of pentane have different<br />
(1) formula mass (3) molecular mass<br />
(2) empirical formula (4) structural formula<br />
7. Which molecule contains a nonpolar covalent bond?<br />
(1) O = C = O (3) Br – Br<br />
Cl<br />
I<br />
(2) C = O (4) Cl – C – Cl<br />
I<br />
Cl<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>10</strong>5
<strong>Day</strong> 21: continue.<br />
15. Which structural formula is correct for 2-methyl-3-pentanol?<br />
16. The atomic mass of element A is 63.6 atomic mass units. The only<br />
naturally occurring isotopes of element A are A-63 and A-65. The<br />
percent abundances in a naturally occurring sample of element A are<br />
closest to<br />
(1) 31% A-63 and 69% A-65<br />
(2) 50% A-63 and 50% A-65<br />
(3) 69% A-63 and 31% A-65<br />
(4) <strong>10</strong>0% A-63 and 0% A-65<br />
17. Given the balance equation:<br />
4Fe(s) + 3O 2(g)<br />
---- > 2Fe 2O 3(s) + 1640KJ<br />
Which phrase best describes this reaction?<br />
(1) endothermic with ∆H = +1640 KJ<br />
(2) endothermic with ∆H = -1640 KJ<br />
(3) exothermic with ∆H = +1640 KJ<br />
(4) exothermic with ∆H = -1640 KJ<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>10</strong>7
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>10</strong>9
<strong>Day</strong> 21: Answers and Explanations<br />
9) 3 Recall: Fusion is a nuclear process of joining two smaller<br />
nuclei of H to form a larger nucleus of He.<br />
<strong>10</strong>) 2 Note: If the sample contains 74.5 % by mass of chlorine, the<br />
remaining percent of 25.5 % will be of the mass of Mg<br />
Relate: the mass of Mg in sample is, therefore, 25.5 % of 190.2 g.<br />
Calculate 25.5 % of 190.2 g to get mass of Magnesium (Mg).<br />
0.255 x 190.2 = 48.5 g<br />
11) 2 Recall: sublimation is a phase change of solid ----- > gas<br />
<strong>12</strong>) 1 Note: correct choice is a fact related to all Arrhenius acids<br />
13) 4 Recall the four common types of nuclear reactions are :<br />
Nuclear energy reactions: fission and fusion<br />
Natural Transmutation: alpha and beta decay, position emission.<br />
Artificial Transmutation<br />
14) 1 Recall: A positive ion is formed when an atom loses its valance<br />
electrons.<br />
Note: The + ion is always smaller because the atom also loses the<br />
entire valance shell.<br />
15) 2 Note: This structure is correct because it shows:<br />
a methyl (CH 3) group on the 2 nd C atom (2-methyl)<br />
an OH group on the 3 rd C (3-pentanol)<br />
The long chain has 5 C atoms (pent-)<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 111
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to question 1 through 3 on the information below.<br />
The compound NH 4Br(s) and NH 3(g) are soluble in water. Solubility<br />
data for NH 4Br(s) in water are listed in the table below.<br />
Solubility of NH 4Br in H 2O<br />
Temperature<br />
( o C)<br />
<strong>Day</strong> 22: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Mass of NH 4Br per<br />
<strong>10</strong>0. g of H 2O<br />
(g)<br />
0 60.<br />
20. 75.<br />
40. 90.<br />
60. <strong>10</strong>5<br />
80. <strong>12</strong>0<br />
<strong>10</strong>0. 135<br />
1. On the grid to the right, plot the data from the data table.<br />
Circle and connect the points. [1]<br />
2. Determine the total mass of NH 4Br(s) that must be dissolved in<br />
200. grams of H 2O at 60. o C to produce a saturated solution. [1]<br />
3. Compare the solubility of NH 4Br(s) and NH 3(g), each in <strong>10</strong>0. grams<br />
of H 2O, as temperature increases at standard pressure. Your<br />
response must include both NH 4Br(s) and NH 3(g). [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 113
<strong>Day</strong> 22: continue.<br />
8. What is the chemical formula for tin (II) fluoride? [1]<br />
9. How many parts per million of fluoride ions are present in the<br />
analyzed sample? [1]<br />
<strong>10</strong>. Is the town’s drinking water safe to drink? support your decision<br />
using information in the passage and your calculated fluoride level in<br />
question 9. [1]<br />
<strong>Day</strong> 22<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 115
<strong>Day</strong> 22: Answers and Explanations<br />
7) F<br />
.. -<br />
: :<br />
..<br />
Note: Fluoride ion is F- (See Periodic Table for<br />
charge on a fluorine)<br />
Recall: A Lewis electron-dot diagram for all negative (-)<br />
ions (except H-) must show 8 dots around the<br />
ion symbol.<br />
8) SnF 2 Use criss-cross method to determine correct formula.<br />
tin (II) fluoride<br />
Sn 2+ F 1- Recall: (II) means +2 charge for Sn<br />
SnF 2<br />
9) 14.3 ppm Use part per million equation on Table T to calculate.<br />
Grams of solute<br />
ppm = x <strong>10</strong>0000<br />
Grams of solution<br />
0.00250<br />
ppm =<br />
x <strong>10</strong>00000 = 14.3 ppm<br />
(175 g + .00250)<br />
<strong>10</strong>) No Note: because the ppm concentration of F- ion (14.3 ppm)<br />
exceeds the safe limit of F- ion (4 ppm) set by<br />
Environmental Protection Agency.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 117
<strong>Day</strong> 23: 20 Multiple Choice questions<br />
Start: Answer all 20 questions on this day before stopping.<br />
1. Compared to a proton, an electron has<br />
(1) greater quantity of charge and the same sign<br />
(2) greater quantity of charge and the opposite sign<br />
(3) the same quantity of charge and the same sign<br />
(4) the same quantity of charge and the opposite sign<br />
2. Which two notation represents atoms that are isotopes of the same<br />
element?<br />
<strong>12</strong>1 119 19 19<br />
(1) Sn and Sn (3) O and F<br />
50 50 8 9<br />
<strong>12</strong>1 <strong>12</strong>1 39 39<br />
(2) Sn and Sn (4) Cl and K<br />
50 50 17 19<br />
3. Which substance can be decomposed by a chemical change?<br />
(1) calcium (3) copper<br />
(2) potassium (4) ammonia<br />
4. Based on Reference Table S, the atoms of which of these elements<br />
have the strongest attraction for electrons in a chemical bond?<br />
(1) N (3) P<br />
(2) Na (4) Pt<br />
5. Which Period 4 element has the most metallic properties?<br />
(1) As (3) Ge<br />
(2) Br (4) Se<br />
6. What is the total number of pairs of electrons shared in a molecule<br />
of N 2?<br />
(1) one pair (3) three pairs<br />
(2) two pairs (4) four pair<br />
7. Which statement best describes the shape and volume of an<br />
aluminum cylinder at STP?<br />
(1) It has definite shape and a definite volume<br />
(2) It has definite shape and no definite volume<br />
(3) It has no definite shape and a definite volume<br />
(4) It has no definite shape and no definite volume<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 119
<strong>Day</strong> 23: continue.<br />
13. Which chemical equation is correctly balanced?<br />
(1) H 2(g) + O 2(g) ----- > H 2O(g)<br />
(2) N 2(g) + H 2(g) ------ > NH 3(g)<br />
(3) 2NaCl(s) --------- > Na(s) + Cl 2(g)<br />
(4) 2KCl(s) ----- > 2K(s) + Cl 2(g)<br />
14. Which type of bond is found in sodium bromide?<br />
(1) covalent (3) ionic<br />
(2) hydrogen (4) metallic<br />
15. Which Lewis electron dot is correct for CO 2?<br />
16. Two sample of gold that have different temperatures are placed in<br />
contact with one another. Heat will flow spontaneously from a<br />
sample of gold at 60 o C to a sample of gold that has a temperature of<br />
(1) 50 o C (3) 70 o C<br />
(2) 60 o C (4) 80 o C<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>12</strong>1
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>12</strong>3
<strong>Day</strong> 23: Answers and Explanations: continue<br />
9) 3 Note: The correct choice is a definition of an electrolyte.<br />
<strong>10</strong>) 2 Note: The correct choice is a fact related to systems in nature<br />
11) 2 Note: You are comparing a higher NaCl solution concentration<br />
(0.8 M) to a lower concentration (0.1 M).<br />
Recall: The higher the concentration, the higher the boiling<br />
point and the lower the freezing point of a solution.<br />
<strong>12</strong>) 2 Note: The electron transition in the question is from a higher<br />
shell (3 rd ) to a lower shell (2 nd )<br />
Recall: Energy is released (emitted) by an electron as the<br />
electron moves from a higher to lower shell.<br />
13) 4 Recall: Equation is balanced when the number of each atom is<br />
equal on both sides (demonstrates conservation)<br />
Note: The correct equation has 2 K and 2 Cl on both sides<br />
14) 3 Note: sodium bromide is composed of a metal (Na) and a<br />
nonmetal (Br)<br />
Recall: Ionic bond is formed between a metal and a nonmetal.<br />
15) 3 Recall: Structure of CO 2 is O = C = O<br />
This Lewis structure for choice 3 is correct because:<br />
. It shows the correct number of shared electrons<br />
. It shows all atoms with octet (8) of electrons<br />
16) 1 Recall: Heat only flows from high temp object to lower temp.<br />
Note: This choice is correct b/c heat will from a gold at<br />
60 o C to a gold with a lower temp (50 o C)<br />
17) 4 Recall these equilibrium facts:<br />
Concentration (measureable quantity) of substances<br />
must be constant.<br />
Rate of forward and reveres reactions must be equal<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>12</strong>5
<strong>Day</strong> 24: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to questions 1 through 2 on the balanced equation below.<br />
Fe(s)<br />
+ HNO 3(aq) ---- > Fe(NO 3) 2(aq) + H 2(g)<br />
1. What is the total number of oxygen atoms represented in the formula<br />
of the iron compound produced? [1]<br />
2. Explain, using information from Reference Table J, why this reaction<br />
is spontaneous.<br />
Base your answers to questions 3 and 4 on the information below.<br />
In a titration, 15.65 millimeters of a KOH(aq) solution exactly<br />
neutralized <strong>10</strong>.00 millimeters of a 1.22 M HCl(aq) solution.<br />
3. Complete the equation below for the titration reaction by writing<br />
the formula for each product. [1]<br />
KOH + HCl<br />
---- > _____ + ______<br />
4. In the space below, show a correct numerical setup for calculating<br />
the molarity of KOH(aq) solution. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>12</strong>7
<strong>Day</strong> 24: continue.<br />
Base your answers to questions 7 and 8 on the information below.<br />
An atom has an atomic number of 9, a mass number of 19,<br />
and an electron configuration of 2 – 6 – 1.<br />
7. What is the total number of neutrons in this atom? [1]<br />
8. Explain why the number of electrons in the second and third shells<br />
shows that this atom is in an excited state? [1]<br />
Base your answers to question 9 and <strong>10</strong> on the information below.<br />
The balanced equation below represents the reaction<br />
between magnesium metal and hydrochloric acid to<br />
produce aqueous magnesium chloride and hydrogen gas.<br />
Mg(s) + 2HCl(aq) ---- > MgCl 2(aq)<br />
+ H 2(g)<br />
A piece of Mg(s) has a volume of 0.0640 cubic centimeters. This<br />
piece of Mg(s) reacts completely with HCl(aq) to<br />
produce H 2(g). The H 2(g) produced has a volume of 1<strong>12</strong><br />
millimeters and a pressure of 1.00 atmosphere at 298 K.<br />
9. The volume of the piece of Mg(s) is expressed to what number of<br />
significant figures? [1]<br />
<strong>10</strong>. In the space below, show a correct numerical setup for calculating<br />
the volume of the H 2(g) produced if the conditions<br />
are changed to STP. [1]<br />
<strong>Day</strong> 24<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved <strong>12</strong>9
<strong>Day</strong> 24: Answers and Explanations: continue<br />
7) <strong>10</strong> Recall: Neutrons = Mass # - Atomic # (protons)<br />
19 - 9 = <strong>10</strong><br />
8) The configuration is in the excited state because the 3 rd shell only<br />
has 6 (not full with 8) while the 2 nd contains an electron.<br />
9) 3 Note: In the number 0.0640 : the last 3 digits are significant<br />
Recall the following rules for counting significant numbers:<br />
.All zero to start a number (0.0 640) are NOT significant<br />
.All Real numbers (0.064 0) are significant<br />
.If a number has a decimal point, all zeros at the end of<br />
the number are significant 0.0640)<br />
<strong>10</strong>) Note: This is a gas law problem<br />
Determine factors from<br />
passage and question<br />
P 1 = 1 atm P 1 = 1 atm<br />
T 1 = 298 K T 2 = 273<br />
V 1 = 1<strong>12</strong> ml V 2 = unknown<br />
STP<br />
Use the Combined Gas law equation on Table T to setup<br />
P 1V 1 P 2V 2<br />
=<br />
T 1 T 2<br />
V 2 =<br />
(1) (1<strong>12</strong>) (1) (V 2)<br />
=<br />
298 273<br />
or<br />
1(273)(1<strong>12</strong>)<br />
298<br />
your setup may vary from<br />
these two setups<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 131
<strong>Day</strong> 25: 20 Multiple Choice questions<br />
Start: Answer all 20 questions on this day before stopping.<br />
1. Which subatomic particles has a negative charge?<br />
(1) proton (3) neutron<br />
(2) electron (4) positron<br />
2. Which statement best describes the nucleus of an aluminum atom?<br />
(1) It has a charge of +13 and is surrounded by <strong>10</strong> electrons.<br />
(2) It has a charge of +13 and is surrounded by 13 electrons.<br />
(3) It has a charge of -13 and is surrounded by <strong>10</strong> electrons.<br />
(4) It has a charge of -13 and is surrounded by 13 electrons.<br />
3. Two different samples decomposed when heated. Only one of the<br />
samples is soluble in water. Based on this information, these two<br />
samples are<br />
(1) both the same element<br />
(2) two different elements<br />
(3) both the same compound<br />
(4) two different compounds<br />
4. Which of these elements has the lowest melting point?<br />
(1) Li (3) K<br />
(2) Na (4) Rb<br />
5. Which list consists of types of chemical formulas?<br />
(1) atoms, ions, molecules<br />
(2) metals, nonmetals, metalloids<br />
(3) empirical, molecular, structural<br />
(4) synthesis, decomposition, neutralization<br />
6. Which formula represents a nonpolar molecule?<br />
(1) H 2S (3) CH 4<br />
(2) HCl (4) NH 4<br />
7. An aqueous solution of sodium chloride is best described as a<br />
(1) homogeneous compound<br />
(2) homogeneous mixture<br />
(3) heterogeneous compound<br />
(4) heterogeneous mixture<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 133
<strong>Day</strong> 25: continue.<br />
<strong>12</strong>. What is the oxidation number assigned to manganese in KMnO 4?<br />
(1) +7 (3) +3<br />
(2) +2 (4) +4<br />
13. A student tested a 0.1 M aqueous solution and made the following<br />
observations:<br />
. conducts electricity<br />
. turns blue litmus to red<br />
. reacts with Zn(s) to produce gas bubbles.<br />
Which compound could be the solute in this solution?<br />
(1) CH 3OH (3) HBr<br />
(2) LiBr (4) LiOH<br />
14. Which equation represents a neutralization reaction?<br />
(1) 4Fe(s) + 3O 2(g) ------ > 2Fe 2O 3(s)<br />
(2) 2H 2(g) + O 2(g) ------ > 2H 2O(l)<br />
(3) HNO 3(aq) + KOH(aq) --- > KNO 3(aq) + H 2O(l)<br />
(4) AgNO 3(aq) + KCl(aq) ------- > KNO 3(aq) + AgCl(s)<br />
15. Given the balance equation representing a redox reaction:<br />
2Al + 3Cu 2+ ---- > 2Al 3+ + 3Cu<br />
Which statement is true about this reaction?<br />
(1) Each Al loses 2e- and each Cu 2+ gains 3e-<br />
(2) Each Al loses 3e- and each Cu 2+ gains 2e-<br />
(3) Each Al 3+ gains 2e- and each Cu loses 3e-<br />
(4) Each Al 3+ gains 3e- and each Cu loses 2e-<br />
16. The percent composition by mass of magnesium in<br />
MgBr 2 (gram-formula mass = 184 grams/mole) is equal to<br />
(1) 24 x <strong>10</strong>0 (3) 184 x <strong>10</strong>0<br />
184 24<br />
(2) 160. x <strong>10</strong>0 (4) 184 x <strong>10</strong>0<br />
184 160.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 135
<strong>Day</strong> 25: continue.<br />
19. Which diagram represents the nucleus of an atom of 27 Al?<br />
13<br />
14 n<br />
27 p<br />
27 n<br />
13 p<br />
(1) (3)<br />
14 n<br />
40 n<br />
13 p<br />
13 p<br />
(2) (4)<br />
(2) (4)<br />
20. The chart below shows the spontaneous nuclear decay of<br />
U-238 to Th-234 to Pa-234 to U-234.<br />
What is the correct order of nuclear decay modes for the change<br />
from U-238 to U-234?<br />
(1) β-decay, γ decay, β-decay<br />
(2) β-decay, β-decay, α decay<br />
(3) α decay, α decay, β-decay<br />
(4) α decay, β-decay, β-decay<br />
<strong>Day</strong> 25<br />
Stop. Correct your answers and note how many correct Points<br />
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<strong>Day</strong> 25: Answers and Explanations: continue<br />
11) 2 Note: this configuration is correct b/c the numbers in the<br />
configuration add up to 17 (# of electrons in Cl atom)<br />
BUT, arranged differently from the ground State<br />
configuration on the Periodic Table.<br />
<strong>12</strong>) 1 Recall: sum of charges in a compound must equal zero.<br />
Note: This charge of Mn (+7) adds to charge of K (+1) and<br />
the total charge of O (-8) to equal zero.<br />
13) 3 Note: the observations describe properties of acids.<br />
Note: HBr is an acid (Use Table K)<br />
14) 3 Recall: Neutralization is a reaction of an acid (HNO 3) with a<br />
base (KOH) to produce salt (KNO 3) and water (H 2O)<br />
as products.<br />
15) 2 Note the following oxidation number changes of Al and Cu 2+ .<br />
Al --------- > Al 3+ + 3e- (each Al loses 3 e-)<br />
Cu 2+ + 2e- ----- > Cu (each Cu 2+ gains 2 e-)<br />
16) 1 Use Table T percent composition equation to setup:<br />
Total Mass of Mg<br />
% Mg = x <strong>10</strong>0<br />
Gram-formula mass<br />
% Mg =<br />
24<br />
x <strong>10</strong>0<br />
184<br />
17) 4 Recall: The difference between the Potential Energy (PE) of<br />
the products and the Potential Energy of the reactants is<br />
∆H (heat of reaction)<br />
∆H = PE of products – PE of reactants<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 139
<strong>Day</strong> 26: <strong>10</strong> <strong>Constructed</strong> <strong>Response</strong> <strong>Questions</strong><br />
Start: Answer all <strong>10</strong> questions on this day before stopping.<br />
Base your answers to 1 through 3 on the information below.<br />
In a laboratory, 0.<strong>10</strong>0 mole of colorless hydrogen iodide gas at room<br />
temperature is placed in a 1.00-liter flask. The flask is sealed and warmed,<br />
causing the HI(g) to start decomposing to H 2(g) and I 2(g). Then the<br />
temperature of the contents of the flask is kept constant. During this<br />
reaction, the contents of the flask change to a pale purple-colored mixture<br />
of HI(g), H 2(g), and I 2(g). When the color of the mixture in the flask stops<br />
changing, the concentration of I 2(g) is determine to be 0.013 mole per liter.<br />
The relationship between concentration and time for the reactant and<br />
products is shown in the graph below.<br />
1. Write a balanced equation to represent the decomposition reaction<br />
occurring in the flask. [1]<br />
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<strong>Day</strong> 26: continue.<br />
Base your answers to questions 22 to 24 on the information below.<br />
The hydrocarbon 2-methylpropane reacts with iodine as<br />
represented by the balanced equation below. At Standard pressure,<br />
the boiling point of 2-methylpropane is lower than the boiling<br />
point of 2-iodo-2-methylpropane.<br />
6. To which class of organic compound does this organic product<br />
belong? [1]<br />
7. Explain, in terms of bonding, why the hydrocarbon 2-methylpropane<br />
is saturated. [1]<br />
8. Explain the difference in the boiling points of 2-methylpropane and<br />
2-iodo-2-methylpropane in terms of both molecular polarity and<br />
intermolecular forces. [2]<br />
Molecular polarity: [1]<br />
Intermolecular forces: [1]<br />
<strong>Day</strong> 26<br />
Stop. Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 143
<strong>Day</strong> 26: Answers and Explanations: continue<br />
5) Hit the solid with a hammer to see if it flattens into a thin sheet.<br />
Recall: Malleability describes how easily a solid can be flattened<br />
when struck.<br />
6) Halide or organic halide<br />
Note: The product contains iodine (a halogen, Group 17)<br />
7) The hydrocarbon 2-methylpropane is saturated because it<br />
contains all single bonds between the carbon atoms.<br />
8) Molecular polarity: 2-methylpropane has a lower boiling<br />
point than 2-iodo-2-methylpropane<br />
because it is less polar.<br />
Intermolecular forces: 2-methylpropane has a lower<br />
boiling point than 2-iodo-2-methylpropane<br />
because it has weaker intermolecular<br />
forces.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 145
<strong>Day</strong> 27: Chemistry Regents Exam: August 2009<br />
Start: Answer all questions in Part A and B-1 before stopping<br />
Part A: Answer all questions in this part<br />
Directions (1 – 30): For each statement or question, write on the separate<br />
answer sheet the number of the word or expression that, of those given,<br />
best completes the statement or answer the question. Some questions may<br />
require the use of the Reference tables for Physical setting/Chemistry.<br />
1. Which particle has the least mass?<br />
(1) 4 He (3) 1 n<br />
(2) 1 H (4) o e<br />
2. What information is necessary to determine the atomic mass of the<br />
element chlorine?<br />
(1) The atomic mass of each artificially produced isotope of chlorine,<br />
only<br />
(2) The relative abundances of each naturally occurring isotope of<br />
chlorine, only<br />
(3) The atomic mass and the relative abundances of each naturally<br />
occurring isotope of chlorine<br />
(4) The atomic mass and the relative abundances of each naturally<br />
occurring and artificially produced isotope of chlorine<br />
3. In an atom of argon-40, the number of protons<br />
(1) equals the number of electrons<br />
(2) equals the number of neutrons<br />
(3) is less than the number of electrons<br />
(4) is greater than the number of electrons<br />
4. An electron is a sodium atom moves from the third shell to the fourth<br />
shell. This change is a result of the atom<br />
(1) absorbing energy (3) gaining an electron<br />
(2) releasing energy (4) losing an electron<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 147
<strong>Day</strong> 27: Chemistry Regents Exam: August 2009<br />
Part A.<br />
Continue<br />
<strong>10</strong>. Why is a molecule of CO 2 nonpolar even though the bonds between<br />
the carbon atom and the oxygen atoms are polar?<br />
(1) The shape of the CO 2 molecule is symmetrical.<br />
(2) The shape of the CO 2 molecule is asymmetrical.<br />
(3) The CO 2 molecule has a deficiency of electrons.<br />
(4) The CO 2 molecule has an excess of electrons.<br />
11. Which formula represents a molecular compound?<br />
(1) HI (3) KCl<br />
(2) KI (4) LiCl<br />
<strong>12</strong>. Which element has the greatest density at STP?<br />
(1) Scandium (3) Silicon<br />
(2) Selenium (4) Sodium<br />
13. Particles are arranged in a crystal structure in a sample of<br />
(1) H 2(g) (3) Ar(g)<br />
(2) Br 2(l) (4) Ag(s)<br />
14. The relatively high boiling point of water is due to water having<br />
(1) hydrogen bonding<br />
(2) metallic bonding<br />
(3) nonpolar covalent bonding<br />
(4) strong ionic bonding<br />
15. Matter is classified as<br />
(1) substances, only<br />
(2) substances or as a mixture of substances<br />
(3) homogeneous mixture, only<br />
(4) homogeneous mixture or as a heterogeneous mixture<br />
16. Which substance can not be decomposed by chemical changes?<br />
(1) ammonia (3) propanol<br />
(2) copper (4) water<br />
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<strong>Day</strong> 27: Chemistry Regents Exam: August 2009<br />
Part A.<br />
Continue<br />
21. According to the kinetic molecular theory, which statement describes<br />
the particles in a sample of an ideal gas?<br />
(1) the force of attraction between the gas particles is strong<br />
(2) The motion of the gas particles is random and straight-line<br />
(3) The collisions between the gas particles cannot result in a transfer<br />
of energy between the particles<br />
(4) The separation between the gas particles is smaller than the size of<br />
the gas particles themselves.<br />
22. The activation energy of a chemical reaction can be decreased by the<br />
addition of<br />
(1) a catalyst (3) electrical energy<br />
(2) an indicator (4) thermal energy<br />
23. A straight-chain hydrocarbon that has only one double bond in each<br />
molecule has the general formula<br />
(1) C nH 2n-6 (3) C nH 2n<br />
(2) C nH 2n-2 (4) C nH 2n+2<br />
24. Why can an increase in temperature lead to more effective collision<br />
between reactant particles and an increase in the rate of a chemical<br />
reaction?<br />
(1) The activation energy of the reaction increases.<br />
(2) The activation energy of the reaction decreases.<br />
(3) The number of molecules with sufficient energy to react increases.<br />
(4) The number of molecules with sufficient energy to react decreases.<br />
25. Which reaction results in the production of soap?<br />
(1) esterification (3) polymerization<br />
(2) fermentation (4) saponification<br />
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<strong>Day</strong> 27: Chemistry Regents Exam: August 2009<br />
Part B-1: Answer all questions in this part.<br />
Directions (31 – 50): For each statement or question, write on the<br />
separate answer sheet the number of the word or expression that, of<br />
those given, best completes the statement or answer the question.<br />
Some questions may require the use of the Reference tables for<br />
Physical setting/Chemistry.<br />
31. Which electron configuration represents an excited state for a<br />
potassium atom?<br />
(1) 2-8-7-1 (3) 2-8-8-1<br />
(2) 2-8-7-2 (4) 2-8-8-2<br />
32. A sample of an element is malleable and can conduct electricity. This<br />
element could be<br />
(1) H (3) S<br />
(2) He (4) Sn<br />
33. Which general trend is demonstrated by Group 17 elements as they are<br />
considered in order from top to bottom on the Periodic Table?<br />
(1) a decrease in atomic radius<br />
(2) a decrease in electronegativity<br />
(3) an increase in first ionization energy<br />
(4) an increase in nonmetallic behavior<br />
34. Which element is a liquid at 758 K and standard pressure?<br />
(1) gold (3) platinum<br />
(2) silver (4) thallium<br />
35. Which equation represents a decomposition reaction?<br />
(1) CaCO 3(s) ------- > CaO(s) + CO 2(g)<br />
(2) Cu(s) + 2AgNO 3(aq) ---- > 2Ag (s) + Cu(NO 3) 2(aq)<br />
(3) 2H 2(g) + O 2(g) --- > 2H 2O(l)<br />
(4) KOH(aq) + HCl(aq) --- > KCl(aq) + H 2O(l)<br />
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<strong>Day</strong> 27: Chemistry Regents Exam: August 2009<br />
Part B-1. Continue.<br />
41. Given the bright-line spectra of the three elements and the<br />
spectrum of a mixture formed from at least two off these<br />
elements.<br />
Which elements are present in this mixture?<br />
(1) E and D, only (3) D and G, only<br />
(2) E and G, only (4) D, E, and G<br />
42. Given the balanced particle-diagram equation:<br />
Which statement describes the type of change and the<br />
chemical properties of the product and reactant?<br />
(1) The equation represents a physical change, with the product and<br />
the reactants having different chemical properties.<br />
(2) The equation represents a physical change, with the product and<br />
the reactants having identical chemical properties<br />
(3) The equation represents a chemical change, with the product and<br />
the reactants having different chemical properties.<br />
(4) The equation represents a chemical change, with the product and<br />
the reactants having identical chemical properties.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 155
<strong>Day</strong> 27: Chemistry Regents Exam: August 2009<br />
Part B-1. Continue.<br />
47. Which formula represents an unsaturated hydrocarbon?<br />
48. What is the oxidation state of nitrogen in the compound<br />
NH 4Br?<br />
(1) -1 (3) -3<br />
(2) +2 (4) +4<br />
49. A student completes a titration by adding <strong>12</strong>.0 millimeters of<br />
NaOH(aq) of unknown concentration to 16.0 millimeters of<br />
0.15 M HCl(aq). What is the molar concentration of the<br />
NaOH(aq)?<br />
(1) 0.11 M (3) 1.1 M<br />
(2) 0.20 M (4) 5.0 M<br />
50. What is the half-life of a radioisotope if 25.0 grams of an<br />
original 200. gram sample of the isotope remains unchanged<br />
after 11.46 days?<br />
(1) 2.87 d (3) 11.46 d<br />
(2) 3.82 d (4) 34.38<br />
<strong>Day</strong> 27<br />
Stop: Correct your answers and note how many correct Points<br />
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<strong>Day</strong> 28: Physical Setting: Chemistry Regents Exam<br />
August 2009<br />
Start: Answer all questions in Part B-2 and Part C before stopping<br />
Part B-2: Answer all questions in this part<br />
Directions (51-63): Record your answers in the spaces provided in your<br />
answer booklet. Some questions may require the use of the Reference<br />
Tables for Physical Setting/Chemistry.<br />
51. Identify the element in Period 3 of the Periodic Table that reacts<br />
with oxygen to form an ionic compound represented by the formula<br />
X 2O. [1]<br />
52. Given the unbalanced equation representing a reaction:<br />
2C 6H <strong>12</strong> + 7O 2 ---- > 4CO 2 + 6H 2O<br />
Determine the total number of moles of oxygen that react<br />
completely with 8.0 moles of C 2H 6. [1]<br />
_____ mol<br />
53. On the potential energy diagram in your answer booklet, draw an<br />
arrow to represent the activation energy of the forward reaction. [1]<br />
54. Describe the electrons in an atom of carbon in the ground state.<br />
Your response must include:<br />
. the charge of an electron [1]<br />
. the location of electrons based on the wave-mechanical model [1]<br />
. the total number of electrons in a carbon atom [1]<br />
55. Determine the mass of 5.20 moles of C6H<strong>12</strong> (gram-formula<br />
mass = 84.2 grams/mole). [1]<br />
_____ g<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 159
<strong>Day</strong> 28: Chemistry Regents Exam: August 2009<br />
Base your answers to questions 59 though 63 on the information below:<br />
Bond energy is the amount of energy required to break a chemical<br />
bond. The table below gives a formula and the carbon-nitrogen<br />
bond energy for selected nitrogen compounds.<br />
Compound Formula Carbon-Nitrogen<br />
Bond Energy<br />
(KJ/mol)<br />
hydrogen cyanide H – C = N 890.<br />
isocyanic acid H – N = C = O 615<br />
methaneamine<br />
Part B-1. Continue.<br />
H<br />
I<br />
H – C – N – H<br />
I I<br />
H H<br />
293<br />
59. Describe, in terms of electrons, the type of bonding between the<br />
carbon atom and the nitrogen atom in a molecule of<br />
methanamide. [1]<br />
60. Identify the noble gas that has atoms in the ground state with the<br />
same electron configuration as the nitrogen in a molecule of<br />
isocyanic acid. [1]<br />
61. State the relationship between the number of electrons in a carbonnitrogen<br />
bond and carbon-nitrogen bond energy. [1]<br />
62. Explain, in terms of charge distribution, why a molecule of<br />
hydrogen cyanide is polar. [1]<br />
63. A 3.2-gram sample of air contains 0.000 74 gram of hydrogen<br />
cyanide. Determine the concentration, in parts per million, of the<br />
hydrogen cyanide in this sample. [1]<br />
____ ppm<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 161
<strong>Day</strong> 28: Chemistry Regents Exam: August 2009<br />
Base your answer to questions 65 through 67 on the information below.<br />
A student used blue litmus paper and phenolphthalein paper as an<br />
indicator to test the pH of distilled water and five aqueous household<br />
solutions. Then the student used a pH meter to measure the pH of the<br />
distilled water and each solution. The results of the student’s work are<br />
recorded in the table below.<br />
Liquid Tested<br />
Color of<br />
Blue<br />
Litmus<br />
Paper<br />
Color of<br />
Phenolphthalein<br />
Paper<br />
2% milk blue colorless 6.4<br />
distilled water blue colorless 7.0<br />
household<br />
ammonia<br />
Part C. Continue.<br />
blue pink 11.5<br />
lemon juice red colorless 2.3<br />
tomato juice red colorless 4.4<br />
vinegar red colorless 3.3<br />
Measured<br />
pH value<br />
Using a pH<br />
meter<br />
65. Identify the liquid tested that has the lowest hydronium ion<br />
concentration. [1]<br />
66. Explain, in terms of the pH range for the color change on<br />
Reference Table M, why the litmus is not appropriate to differentiate<br />
the acidity levels of tomato juice and vinegar. [1]<br />
67. Based on the measured pH values, identify the liquid tested that is<br />
<strong>10</strong> times more acidic than vinegar. [1]<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 163
<strong>Day</strong> 28: Chemistry Regents Exam: August 2009<br />
Part C. Continue.<br />
Base your answers to questions 73 through 76 on the information below.<br />
In a laboratory investigation, a student constructs a voltaic cell<br />
with iron and copper electrodes. Another student constructs a<br />
voltaic cell with zinc and iron electrodes. Testing the cells during<br />
operation enables the students to write the balanced ionic equations<br />
below:<br />
Cell with iron and copper electrodes:<br />
Cu 2+ (aq) + Fe(s) ---- > Cu(s) + Fe 2+ (aq)<br />
Cell with zinc and iron electrodes:<br />
Fe 2+( aq) + Zn(s) ----- > Fe(s) + Zn 2+ (aq<br />
73. State evidence from the balance equation for the cell with iron and<br />
copper electrodes that indicates the reaction in the cell is an<br />
oxidation-reduction reaction. [1]<br />
74. Identify the particles transferred between Fe 2+ and Zn during the<br />
reaction in the cell with zinc and iron electrodes. [1]<br />
75. Write a balance half-reaction equation for the reduction that takes<br />
place in the cell with zinc and iron electrodes. [1]<br />
76. State the relative activity for the three metals used in these two<br />
voltaic cells. [1]<br />
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<strong>Day</strong> 28: Chemistry Regents Exam: August 2009<br />
Part C. Continue.<br />
Base your answers to questions 80 through 81 on the information below.<br />
Scientists are investigating the production of energy using<br />
hydrogen-2 nuclei (deuterons) and hydrogen-3 nuclei (tritons).<br />
The balanced equation below represents one nuclear reaction<br />
between two deuterons.<br />
2 H + 2 H --- > 3 He + 1 n + 5.23 x<strong>10</strong> -13 J<br />
1 1 2 0<br />
80. State, in terms of subatomic particles, how a deuteron differs from<br />
a triton. [1]<br />
81. Identify the type of nuclear reaction represented by the equation. [1]<br />
<strong>Day</strong> 28<br />
Stop: Correct your answers and note how many correct Points<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 167
Answer Booklet: August 2009<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 169
Answer Booklet: August 2009<br />
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Answer Booklet: August 2009<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 173
<strong>Day</strong> 28: Chemistry Regents Exam August 2009<br />
Answers Part B-2<br />
59) .Covalent bond<br />
.Electrons are shared in the bond<br />
continue<br />
60) Ne, Neon, element number <strong>10</strong><br />
61) As the number of shared electrons in a C – N bond<br />
increases, the bond energy increases<br />
OR<br />
Less energy is required to break a single C – N than to break<br />
a triple C – N bond.<br />
62) The molecule has an asymmetrical structure<br />
The molecule has unequal distribution of charges<br />
63) 230 ppm or 2.31 x <strong>10</strong> 2 ppm<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 175
<strong>Day</strong> 28: Chemistry Regents Exam: August 2009<br />
75) Fe 2+ + 2e- ---- > Fe<br />
Answers Part C continue.<br />
76) Zinc is more reactive than iron, and iron is more reactive than<br />
copper.<br />
The order of decreasing activity is Zn, Fe, Cu<br />
Copper is least active and zinc is most active<br />
m <strong>12</strong>9.5 g <strong>12</strong>9.5<br />
77) d = = or<br />
V 14.8 cm3 14.8<br />
8.75 g/cm 3<br />
78) <strong>10</strong>84 o C<br />
79) 13.8 g<br />
80) A deuteron has one neutron a triton has two neutrons<br />
81) Fusion or thermonuclear fusion or nuclear fusion<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 177
<strong>Day</strong> 29: Chemistry Regents Exam: January 20<strong>10</strong><br />
Start: Answer all questions in Part A and B-1 before stopping<br />
Part A: Answer all questions in this part<br />
Directions (1 – 30): For each statement or question, write on the separate<br />
answer sheet the number of the word or expression that, of those given,<br />
best completes the statement or answer the question. Some questions may<br />
require the use of the Reference tables for Physical setting/Chemistry.<br />
1. Which two particles have opposite charges?<br />
(1) an electron and a neutron<br />
(2) an electron and a proton<br />
(3) a proton and a neutron<br />
(4) a proton and a positron<br />
2. Which statement describes how an atom in the ground state becomes<br />
excited?<br />
(1) The atom absorbs energy, and one or more electrons move to a<br />
higher electron shell<br />
(2) The atom absorbs energy, and one or more electrons move to a<br />
lower electron shell<br />
(3) The atom releases energy, and one or more electrons move to a<br />
higher electron shell<br />
(4) The atom releases energy, and one or more electron move to a<br />
lower electron shell<br />
3. An element that has a low first ionization energy and good<br />
conductivity of heat and electricity is classified as a<br />
(1) metal (3) nonmetal<br />
(2) metalloid (4) noble gas<br />
4. The chemical properties of calcium are most similar to the chemical<br />
properties of<br />
(1) Ar (3) Mg<br />
(2) K (4) Sc<br />
5. Which element is a liquid at STP?<br />
(1) argon (3) chlorine<br />
(2) bromine (4) sulfur<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 179
<strong>Day</strong> 29: Chemistry Regents Exam: January 20<strong>10</strong><br />
Part A. Continue.<br />
13. Which element has an atom with the greatest tendency to attract<br />
electrons in a chemical bond?<br />
(1) carbon (3) silicon<br />
(2) chlorine (4) sulfur<br />
14. The nitrogen atom in a molecule of N 2 share a total of<br />
(1) one pair of electrons<br />
(2) one pair of protons<br />
(3) three pairs of electrons<br />
(4) three pairs of protons<br />
15. An ionic compound is formed when there is a reaction between the<br />
elements of<br />
(1) strontium and chlorine<br />
(2) hydrogen and chlorine<br />
(3) nitrogen and oxygen<br />
(4) sulfur and oxygen<br />
16. Which compound has both ionic and covalent bonding?<br />
(1) CaCO 3 (3) CH 3OH<br />
(2) CH 2Cl 2 (4) C 6H <strong>12</strong>O 6<br />
17. The liquids hexane and water are placed in a test tube. The test<br />
tube is stoppered, shaken, and placed in a test tube rack. The liquid<br />
separated into two distinct layers because hexane and water have<br />
different<br />
(1) formula mass<br />
(2) molecular polarities<br />
(3) pH value<br />
(4) specific heat<br />
18. Which statement describes the particles of an ideal gas based on the<br />
kinetic molecular theory?<br />
(1) The gas particles are relatively far apart and have negligible volume.<br />
(2) The gas particles are in constant, nonlinear motion<br />
(3) The gas particles have attractive forces between them.<br />
(4) The gas particles have collisions without transferring energy.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 181
<strong>Day</strong> 29: Chemistry Regents Exam: January 20<strong>10</strong><br />
Part A. Continue.<br />
25. When one compound dissolves in water , the only positive ion<br />
produced in the solution is H 3O + (aq). This compound is classified as<br />
(1) a salt<br />
(2) a hydrocarbon<br />
(3) an Arrhenius acid<br />
(4) an Arrhenius base<br />
26. Which nuclear emission has the greatest mass and the least<br />
penetrating power?<br />
(1) an alpha particle (3) a neutron<br />
(2) a beta particle (4) a positron<br />
27. Which radioisotope has an atom that emits a particle with a mass<br />
number of 0 amu and a charge of +1?<br />
(1) 3 H (3) 19 Ne<br />
(2) 16 Ne (4) 239 Pu<br />
28. In which type of reaction do two lighter nuclei combine to form one<br />
heavier nucleus?<br />
(1) combustion (3) nuclear fission<br />
(2) reduction (4) nuclear fusion<br />
29. For which compound is the process of dissolving in water<br />
exothermic?<br />
(1) NaCl (3) NH 4Cl<br />
(2) NaOH (4) NH 4NO<br />
30. Which quantity must be equal for a chemical reaction at<br />
equilibrium?<br />
(1) the activation energies of the forward and reverse reaction<br />
(2) the rates of the forward and reverse reactions<br />
(3) the concentrations of the reactants and products<br />
(4) the potential energies of the reactants and products<br />
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<strong>Day</strong> 29: Chemistry Regents Exam: January 20<strong>10</strong><br />
36. Given the balanced equation representing a reaction:<br />
CaO(s) +<br />
Part B-1. Continue.<br />
CO 2 --- > CaCO 3(s) + heat<br />
What is the total mass of CaO(s) that reacts completely with<br />
88 grams of CO 2(g) to produce 200. grams of CaCO 3(s)?<br />
(1) 56 g (3) 1<strong>12</strong> (g)<br />
(2) 88 g (4) 288 g<br />
37. What is the empirical formula of a compound that has a carbon-tohydrogen<br />
ratio of 2 to 6?<br />
(1) CH 3 (3) C 3H<br />
(2) C 2H 6 (4) C 6H 2<br />
38. Given the balanced equation representing a reaction:<br />
H 2(g) + Cl 2(g) --- > 2HCl(g) + energy<br />
Which statement describes the energy changes in this reaction?<br />
(1) Energy is absorbed as bonds are formed, only.<br />
(2) Energy is released as bond are broken, only<br />
(3) Energy is absorbed as bonds are broken, and energy is released as<br />
bonds are formed.<br />
(4) Energy is absorbed as bonds are formed, and energy is released as<br />
bonds are broken.<br />
39. Which solution has the highest boiling point at standard pressure?<br />
(1) 0.<strong>10</strong> M KCl(aq)<br />
(2) 0.<strong>10</strong> M K 2SO 4(aq)<br />
(3) 0.<strong>10</strong> M K 3PO 4(aq)<br />
(4) 0.<strong>10</strong> M KNO 3(aq)<br />
40. What is the molarity of 1.5 liters of an aqueous solution that<br />
contains 52 grams of lithium fluoride, LiF (gram-formula<br />
mass = 26 grams/mole)?<br />
(1) 1.3 M (3) 3.0 M<br />
(2) 2.0 M (4) 0.75 M<br />
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<strong>Day</strong> 29: Chemistry Regents Exam: January 20<strong>10</strong><br />
46. Given the formula for an organic compound:<br />
H H H H O<br />
I I I I II<br />
H – C – C – C – C – C – OH<br />
I I I I<br />
H H H H<br />
Part B-1. Continue.<br />
This compound is classified as an<br />
(1) aldehyde (3) ester<br />
(2) amine (4) organic acid<br />
47. Butanal and butanone have different chemical and physical<br />
properties primarily because of differences in their<br />
(1) functional groups<br />
(2) molecular masses<br />
(3) molecular formula<br />
(4) number of carbon atoms per molecule<br />
48. Which salt is produced when sulfuric acid and calcium react<br />
completely?<br />
(1) CaH 2 (3) CaS<br />
(2) CaO (4) CaSO 4<br />
49. Which radioisotope is used to treat thyroid disorders?<br />
(1) Co-60 (3) C-14<br />
(2) I-131 (4) U-238<br />
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<strong>Day</strong> 30: Chemistry Regents Exam: January 20<strong>10</strong><br />
Start: Answer all questions in Part B-2 and Part C before stopping<br />
Part B-2: Answer all questions in this part<br />
Directions (51-65): Record your answers in the spaces provided in your<br />
answer booklet. Some questions may require the use of the Reference<br />
Tables for Physical Setting/Chemistry.<br />
51. Based on Table G, determine the total mass of NH 3 that must be<br />
dissolved in 200. grams of water to produce a saturated solution at<br />
20. o C? [1]<br />
______ g<br />
52. Determine the total time that must elapse until ¼ of an original<br />
sample of the radioisotope Rn-222 remains unchanged. [1]<br />
______ d<br />
Base your answers to questions 53 through 55 on the information below.<br />
A phase change for carbon dioxide that occurs spontaneously at 20. o C<br />
and 1.0 atmosphere is represented by the balanced equation below.<br />
CO 2(s) + energy ---- > CO 2(g)<br />
53. Write the name of this phase change. [1]<br />
54. Describe what happens to the potential energy of the CO 2<br />
molecules as this phase change occurs. [1]<br />
55. Use the key to draw at least five molecules in the box to represent<br />
CO 2 after this phase change is completed. [1]<br />
Key<br />
= CO 2 molecule<br />
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<strong>Day</strong> 30: Chemistry Regents Exam: January 20<strong>10</strong><br />
Base your answers to questions 61 through 63 on the information below.<br />
The atomic and ionic radii for sodium and chlorine are shown in<br />
the table below.<br />
Atomic and Ionic Radii<br />
Particle<br />
Na atom 190.<br />
Na+ ion <strong>10</strong>2<br />
Cl atom 97<br />
Part B-2. Continue<br />
Cl- ion 181<br />
Radius(pm)<br />
61. Write the ground state electron configuration for the ion that has a<br />
radius of 181 picometers. [1]<br />
62. Convert the radius of an Na+ ion to meters. [1]<br />
____ m<br />
63. Explain, in terms of atomic structure, why the radius of an Na atom<br />
is larger than the radius of an Na+ ion. [1]<br />
Base your answers to questions 64 through 65 on the information below.<br />
The nucleus of one boron atom has five protons and four neutrons.<br />
64. Determine the total number of electrons in the boron atom. [1]<br />
65. Determine the total charge of the boron nucleus. [1]<br />
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<strong>Day</strong> 30: Chemistry Regents Exam: January 20<strong>10</strong><br />
Part C Continue.<br />
Base your answer to questions 69 through 71 on the information below.<br />
In a laboratory investigation, magnesium reacts with hydrochloric<br />
acid to produce hydrogen gas and magnesium chloride. The<br />
reaction is represented by the unbalanced equation below.<br />
Mg(s) +<br />
HCl(aq) ---- > H 2(g) + MgCl 2(aq)<br />
69. State, in terms of the relative activity of elements, why this reactions<br />
is spontaneous. [1]<br />
70. Balance the equation in your answer booklet, using the smallest<br />
whole-number coefficients. [1]<br />
___Mg(s) +<br />
__HCl(aq) ---- > __ H 2(g) + __MgCl 2(aq)<br />
71. Write a balance half-reaction equation for the oxidation that<br />
occurs. [1]<br />
Base your answers to questions 72 through 75 on the information below.<br />
An experiment is performed to determine how concentration<br />
affects the rate of reaction. In each of the four trials, equal volume<br />
of solution A and Solution B are mixed while temperature and<br />
pressure are held constant. The concentration of solution B is held<br />
constant, but the concentration of solution A is varied. The<br />
concentration of solution A and the time for the reaction to go to<br />
completion for each trial are recorded in the data table on the next<br />
page.<br />
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<strong>Day</strong> 30: Chemistry Regents Exam: January 20<strong>10</strong><br />
Part C. Continue.<br />
Base your answers to questions 76 through 78 on the information below.<br />
Carbon has three naturally occurring isotopes. C-<strong>12</strong>, C-13, and<br />
C-14. Diamonds and graphite are familiar forms of solid carbon.<br />
Diamond is one of the hardest substances known, while graphite<br />
is a very soft substance. Diamond has a rigid network of bonded<br />
atoms. Graphite has atoms bonded in thin layers that are held<br />
together by weak forces.<br />
Recent experiments have produced new forms of solid carbon<br />
called fullerenes. One fullerene, C 60, is a spherical, cage-like<br />
molecule of carbon.<br />
76. Determine both the total number of protons and the total number<br />
of neutrons in an atom of the naturally occurring carbon isotope<br />
with the largest mass. [1]<br />
Protons: _______<br />
Neutrons: ______<br />
77. Identify the type of bonding in a fullerene molecules. [1]<br />
78. State, in terms of the arrangement of atoms, the difference between<br />
diamond and graphite. [1]<br />
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<strong>Day</strong> 30: Regents Exam: Chemistry January 20<strong>10</strong><br />
Part C. Continue.<br />
Base your answer to questions 82 through 84 on the information below.<br />
The diagram below shows a system in which water is being<br />
decomposed into oxygen gas and hydrogen gas. Litmus is used as<br />
an indicator in the water. The litmus turns red in test tube 1 and<br />
blue in test tube 2.<br />
The oxidation and reduction occurring in the test tubes are<br />
represented by the balanced equations below.<br />
Test tube 1: 2H 2O(l) --- > O 2(g) + 4H + 4e-<br />
Test tube 2: 4H 2O(l) + 4e- --- > 2H 2(g) + 4OH-(aq)<br />
82. Identify the information in the diagram that indicates this system is<br />
an electrolytic cell. [1]<br />
83. Determine the change in oxidation number of oxygen during the<br />
reaction in test tube 1. [1]<br />
From _____ to<br />
_______<br />
84. Explain, in terms of the products formed in Test tube 2, why litmus<br />
turns blue in test tube 2. [1]<br />
<strong>Day</strong> 30<br />
Stop: Correct your answers and note how many correct Points<br />
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Answer Booklet: January 20<strong>10</strong><br />
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Answer Booklet: January 20<strong>10</strong><br />
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<strong>Day</strong> 30: Chemistry Regents Exam January 20<strong>10</strong><br />
51) 1<strong>12</strong> g + 3 g<br />
Answers Part B-2<br />
52) 7.64 d<br />
53) Sublimation<br />
54) The potential energy of the CO 2 molecules increases<br />
The CO 2(g) molecules have more potential energy than the<br />
CO 2(s) molecules.<br />
55)<br />
56)<br />
Your diagram may vary<br />
(molecules should be spread out)<br />
57) Ag+ or Hg 2+ or Pb 2+ or silver ion or Lead(II) ion<br />
58) Alkane C nH 2n+2<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 207
Answers Part C.<br />
66) At STP, the intermolecular forces of I 2 are stronger than F 2.<br />
The intermolecular forces are weaker in F 2.<br />
67)<br />
<strong>Day</strong> 30: Chemistry Regents Exam January 20<strong>10</strong><br />
68) 0.5 g<br />
69) Magnesium is more active than hydrogen.<br />
H 2 is less active than Mg..<br />
70) __Mg(s) + 2 HCl(aq) ----- > __H 2(g) + ___MgCl 2(aq)<br />
71) Mg --- > Mg 2+ + 2e-<br />
72) As the concentration of A decreases, the rate of reaction<br />
decreases.<br />
As the concentration of solution A was decreased, the time for<br />
the reaction to finish increased.<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 209
<strong>Day</strong> 30: Chemistry Regents Exam January 20<strong>10</strong><br />
Answers Part C<br />
continues.<br />
78) Diamond has atoms bonded strongly in three dimensional network.<br />
Diamond has a rigid network of bonded atoms.<br />
Graphite has atoms that are held weakly between layers.<br />
Graphite has atoms bonded in thin layers that are held together.<br />
by weak forces.<br />
79) Combustion<br />
80)<br />
81) 144 Ba or<br />
144 Ba or Barium-144 or Ba-144<br />
82) A battery is part of the cell and is providing energy that causes the<br />
reaction.<br />
Electricity is used to operate the cell.<br />
83) -2 to 0<br />
56<br />
84) Litmus turns blue when enough OH- ions is produced.<br />
The reaction in Test Tube 2 produces OH- ions that makes this<br />
solution basic. Litmus is blue in a basic solution<br />
Copyright © 2011 E3 Scholastic Publishing. All Rights Reserved 211
Track Your Progress: Multiple Choice <strong>Questions</strong><br />
How well have you been improving on the<br />
multiple choice questions? It’s easy to find out.<br />
Get the correct points that you noted<br />
at the end of each multiple choice questions<br />
set (Odd <strong>Day</strong>s).<br />
Plot the points on the graph below.<br />
You hope to see an upward trend on<br />
each graph.<br />
Correct Points<br />
<strong>10</strong><br />
9<br />
8<br />
7<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
0 1 3 5 7 9<br />
<strong>Day</strong><br />
Correct Points<br />
15<br />
14<br />
13<br />
<strong>12</strong><br />
11<br />
<strong>10</strong><br />
9<br />
8<br />
7<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
0<br />
11 13 15 17 19<br />
<strong>Day</strong><br />
Correct Points<br />
20<br />
19<br />
18<br />
17<br />
16<br />
15<br />
14<br />
13<br />
<strong>12</strong><br />
11<br />
<strong>10</strong><br />
9<br />
8<br />
7<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
0 21 23 25<br />
<strong>Day</strong><br />
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Reference Tables / Chemistry<br />
Table A: Standard Temperature and Pressure<br />
Table B: Physical Constants for water<br />
Table C: Selected Prefixes<br />
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Reference Tables / Chemistry<br />
Table F: Solubility Guidelines<br />
Table G: Solubility Curves<br />
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Reference Tables / Chemistry<br />
Table I: Heat of Reactions at Table J<br />
<strong>10</strong>1.3 kPa and 298 K Activity Series<br />
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Reference Tables / Chemistry<br />
Table O: Symbols Used in Nuclear Chemistry<br />
Table P: Organic Prefixes<br />
Table Q: Homologous Series of Hydrocarbons<br />
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