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Biofuels: Optimism and Concerns - Desert Research Institute

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<strong>Biofuels</strong>:<br />

<strong>Optimism</strong> <strong>and</strong> <strong>Concerns</strong><br />

2008 MIT/NESCAUM<br />

Symposium on Urban Transportation<br />

Endicott House<br />

Dedham, Massachusetts<br />

August 13, 2008<br />

S. Kent Hoekman, Ph.D.<br />

<strong>Desert</strong> <strong>Research</strong> <strong>Institute</strong><br />

Division of Atmospheric Sciences<br />

Kent.Hoekman@dri.edu


Outline<br />

1. Background on U.S. Energy Usage<br />

2. Policy <strong>and</strong> Regulatory Drivers for <strong>Biofuels</strong><br />

3. Feedstocks for <strong>Biofuels</strong><br />

4. Biomass Conversion Technologies<br />

5. Environmental Considerations<br />

6. Promoting Responsible Growth of <strong>Biofuels</strong><br />

7. Summary <strong>and</strong> Conclusions<br />

2


Historical Energy Use in the U.S.<br />

(Years 1775 – 2005)<br />

Current use of every primary energy source is greater now<br />

than at any previous time in U.S. history<br />

Source: http://www.eia.doe.gov/emeu/aer/pdf/aer.pdf<br />

3


Recent <strong>and</strong> Future U.S. Energy Production<br />

(Years 1980 – 2030)<br />

Source: EIA Annual Energy Outlook 2008<br />

4


Quads<br />

U.S. Renewable Energy<br />

(2006; with projections to 2030)<br />

In 2006, about 6.3% of total U.S. energy consumption came from<br />

renewables (including hydroelectric).<br />

14<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

2006<br />

2030<br />

Source: DOE-EIA; Annual Energy Outlook 2008<br />

Biomass Energy<br />

Municipal Waste<br />

Residential Wood<br />

Wind<br />

Solar<br />

Geothermal<br />

Hydroelectric<br />

Other Trans Fuels<br />

Biodiesel<br />

Ethanol<br />

Current annual gasoline consumption is about 140 billion gallons –<br />

equivalent to 17.6 Quads<br />

5


Drivers for <strong>Biofuels</strong> in the U.S.<br />

• “America is addicted to oil.”<br />

– President G. W. Bush; January 2006<br />

• Federal Executive Actions:<br />

– Advanced Energy Initiative (AEI) (2006)<br />

– 20-in-10 Plan (2007)<br />

• Federal Legislative Actions:<br />

– Energy Policy Act of 2005<br />

– Energy Independence <strong>and</strong> Security Act<br />

of 2007<br />

• State Actions:<br />

– California Low Carbon Fuel St<strong>and</strong>ard<br />

– California AB-32 (GHG reduction)<br />

State of the Union<br />

Address (1/31/07)<br />

6


Benefits <strong>and</strong> Challenges of <strong>Biofuels</strong><br />

Improved Energy<br />

Security<br />

• Increased domestic<br />

supply<br />

• Widely distributed<br />

resources<br />

• Greater supply<br />

reliability<br />

• Petroleum reduction<br />

Economic<br />

Productivity<br />

• Price stability<br />

• Increased rural<br />

development<br />

• Reduced trade<br />

deficit<br />

• Improved global<br />

competitiveness<br />

Environmental<br />

And Other<br />

Impacts<br />

• GHG impacts<br />

• Carbon<br />

sequestration<br />

• L<strong>and</strong> <strong>and</strong> water use<br />

• Wildlife habitat<br />

• Biodiversity<br />

• Food resources<br />

7


Terminology for Liquid Transportation Fuels<br />

(Common terms, but not universally accepted)<br />

1. Conventional Fuels: produced from petroleum<br />

2. Alternative Fuels: produced from non-petroleum sources,<br />

including other fossil sources (coal, natural gas)<br />

3. Renewable Fuels: produced from modern biological precursors<br />

(plants <strong>and</strong> animals)<br />

4. <strong>Biofuels</strong>: synonymous with “Renewable Fuels”<br />

5. 2 nd Generation <strong>Biofuels</strong>: <strong>Biofuels</strong> produced from non-food<br />

feedstocks – especially lignocellulose<br />

6. Biodiesel: methyl esters produced from fats <strong>and</strong> oils<br />

7. Renewable Diesel: non-fossil hydrocarbon fuel produced via<br />

hydroprocessing of fats <strong>and</strong> oils<br />

8. Cellulosic Fuels: produced via biochemical or thermochemical<br />

conversion of lignocellulosic materials<br />

9. Clean Fuels: ??<br />

8


Rapid Growth of <strong>Biofuels</strong> in the U.S.<br />

• Currently dominated by corn-based<br />

ethanol<br />

– 6.4 billion gallons in 2007<br />

– Supplies about 4% of U.S. gasoline<br />

dem<strong>and</strong><br />

– Requires about 15% of U.S. corn crop<br />

• Biodiesel is growing, but still small<br />

– 0.45 billion gallons in 2007<br />

– Supplies ~1% of U.S. diesel dem<strong>and</strong><br />

– Main feedstocks:<br />

• U.S. – soy oil <strong>and</strong> waste oils<br />

• Europe – rapeseed oil<br />

9


Billion Gallons/Year<br />

2005<br />

Energy Act<br />

2007 Energy Act<br />

U.S. Renewable Fuels Production<br />

<strong>and</strong> Volume Requirements, bg/y<br />

36<br />

32<br />

Production Volumes<br />

Energy Act Requirements<br />

28<br />

24<br />

Cellulosic<br />

Ethanol<br />

20<br />

16<br />

Other Renewables<br />

Biodiesel<br />

12<br />

8<br />

4<br />

Ethanol<br />

Biodiesel<br />

Corn Ethanol<br />

Corn Ethanol<br />

0<br />

Year<br />

36 bg/y represents about 25% of current gasoline volume<br />

10


Biomass Resource Base in U.S.<br />

Primary<br />

Secondary<br />

Tertiary<br />

Forest Resources<br />

• Logging residues<br />

• Forest fuel treatment<br />

• Fuel wood<br />

• Mill residues<br />

• Pulping liquors<br />

• Wood processing residues<br />

• Construction debris<br />

• Demolition debris<br />

• Urban tree trimmings<br />

• Packaging waste<br />

Agricultural Resources<br />

• Crop residues<br />

• Grain<br />

• Perennial grasses<br />

• Woody crops<br />

• Animal manures<br />

• Food/feed processing<br />

residues<br />

• Municipal solid waste<br />

(MSW)<br />

• L<strong>and</strong>fill gases<br />

11


U.S. Forest Biomass Resources,<br />

million dry tons/year (mdt/y)<br />

Source: DOE/USDA, The Technical Feasibility of a Billion-Ton Annual Supply<br />

(April 2005)<br />

12


Potential U.S. Agricultural Biomass<br />

Resources (mdt/y)<br />

Source: DOE/USDA, The Technical Feasibility of a Billion-Ton Annual Supply (April 2005)<br />

13


Major <strong>Biofuels</strong> Production Pathways<br />

Feedstock Process Main Fuel Products<br />

Starch, Sugar<br />

Corn, sugar cane,<br />

sorghum, etc.<br />

Lignocellulose<br />

Wood waste<br />

Grasses<br />

Trees<br />

Ag. waste<br />

Triglycerides<br />

Vegetable oils<br />

Animal fats<br />

Algal lipids<br />

Hydrolysis/<br />

Fermentation<br />

Biochemical<br />

Pretreatment<br />

Enzymatic Hydrolysis<br />

Fermentation<br />

Thermochemical<br />

gasification<br />

pyrolysis<br />

Transesterification<br />

Hydroprocessing<br />

Ethanol<br />

Ethanol<br />

Alcohols,<br />

Hydrocarbons<br />

Fatty Acid Methyl<br />

Esters (Biodiesel)<br />

Hydrocarbons<br />

(Renewable Diesel)<br />

14


DOE’s Integrated Biorefinery Concept<br />

Source: NREL (2006)<br />

15


Environmental <strong>Concerns</strong> with <strong>Biofuels</strong><br />

• Water quantity <strong>and</strong> quality<br />

• Runoff of nutrients <strong>and</strong><br />

agricultural chemicals<br />

• Long-term impacts of crop<br />

residue removal<br />

• Disruption of habitat<br />

• Effects on biodiversity<br />

• Sustainability of agricultural<br />

<strong>and</strong> forestry practices<br />

For ecologic dimensions of biofuels, see links at:<br />

www.esa.org/science_resources/biofuelsResources.php<br />

16


Life-Cycle Impacts of <strong>Biofuels</strong><br />

Many different life-cycle assessments<br />

(LCA) have been conducted by many<br />

different researchers.<br />

Very controversial area. Results<br />

depend upon assumptions about:<br />

‣ Allocations of energy <strong>and</strong> GHGs to coproducts<br />

‣ Agricultural practices <strong>and</strong> resulting GHG<br />

emission rates (especially N 2 O)<br />

‣ Type <strong>and</strong> extent of fossil energy used in<br />

life-cycle<br />

‣ L<strong>and</strong> use changes: CO 2 debt created<br />

by l<strong>and</strong> clearing <strong>and</strong> new cultivation<br />

17


Many LCA Studies Conducted for Ethanol<br />

• Recent model developed by<br />

Ferrell et al. to harmonize<br />

assumptions used in many LCA<br />

studies.<br />

• In general, results show:<br />

- Small energy <strong>and</strong> GHG benefits<br />

from corn-derived ethanol<br />

- Large benefits from cellulosic<br />

ethanol<br />

• Limitation: study considers only<br />

direct effects, not indirect effects<br />

due to l<strong>and</strong> use changes<br />

Source: Farrell et al, Science, 311, 506-508 (2006)<br />

18


General Observations Regarding LCA of <strong>Biofuels</strong><br />

• Importance of indirect effects is now recognized<br />

– No consensus on how to quantify these effects<br />

– No consensus on how (or if) to incorporate into policy<br />

• LCA results are highly scenario specific – very difficult to<br />

generalize for a particular biofuel<br />

• 2 nd generation biofuels are clearly preferred over 1 st<br />

generation biofuels<br />

• Recent publications of interest:<br />

- R.Hammerschlag, Environ. Sci. Technol. 40, 1744-1750 (2006)<br />

- E.A.Farrell et al., Science, 311, 506-508 (2006)<br />

- J.P.W.Scharlemann <strong>and</strong> W.F.Laurance, Science 319, 43-44 (2008)<br />

- J.Fergione et al., Science 319, 1235-1238 (2008)<br />

- T.Searchinger et al. Science 319, 1238-1240 (2008)<br />

19


Promoting Responsible Growth of <strong>Biofuels</strong> (1 of 4)<br />

1. Avoid “One-Size-Fits-All” Approach<br />

– Maximize usage of local/regional biomass resources<br />

– Minimize transportation of feedstocks<br />

– Exp<strong>and</strong> diversity of feedstocks, processes, <strong>and</strong> products<br />

– There is no single best technology<br />

• Match technology with available feedstock<br />

• Integrate technologies – biorefinery concept<br />

20


Promoting Responsible Growth of <strong>Biofuels</strong> (2 of 4)<br />

2. Emphasize Sustainability of <strong>Biofuels</strong><br />

– Life-cycle assessments (LCA) are very important<br />

• Must be improved/exp<strong>and</strong>ed<br />

• Consider both direct <strong>and</strong> indirect effects<br />

• Consider energy, GHG, environ., <strong>and</strong> ecological impacts<br />

• Develop common metrics that accurately reflect true impacts<br />

– Minimize tradeoff between food <strong>and</strong> fuel. Consider 1 st<br />

generation biofuels as temporary transition to 2 nd generation<br />

– Economic sustainability is also important<br />

Source: CEC Report 600-2007-004-Rev., August 2007<br />

21


Promoting Responsible Growth of <strong>Biofuels</strong> (3 of 4)<br />

3. Promote Consumer Acceptance<br />

– Dem<strong>and</strong> high fuel quality<br />

• At refinery gate, <strong>and</strong> in marketplace<br />

• Develop <strong>and</strong> enforce product specifications<br />

– Maximize use of existing infrastructure<br />

• Refining, blending, storage, distribution, marketing<br />

• Minimize changes for consumer<br />

– Ensure acceptable cost, availability, convenience, <strong>and</strong><br />

performance of products<br />

22


Promoting Responsible Growth of <strong>Biofuels</strong> (4 of 4)<br />

4. Integrate Biomass-to-<strong>Biofuels</strong> Supply Chain<br />

– All steps in supply chain are important<br />

– Entire chain must be economically sustainable<br />

Source: DOE Biomass Multi-Year Program Plan (2007)<br />

23


Summary <strong>and</strong> Conclusions (1 of 2)<br />

1. 2 nd Generation biofuels can<br />

play an important role in<br />

stabilizing GHGs <strong>and</strong><br />

reducing petroleum<br />

dependency.<br />

2. <strong>Biofuels</strong> industry is<br />

currently undergoing rapid<br />

transformation <strong>and</strong> growth.<br />

• Many biochemical <strong>and</strong><br />

thermochemical<br />

technologies are being<br />

explored<br />

• No single “best approach”<br />

is likely to emerge<br />

Source: http://celebrating200years.noaa.gov<br />

24


Summary <strong>and</strong> Conclusions (2 of 2)<br />

3. U.S. has abundant natural resources to support<br />

production of 2nd generation biofuels sufficient to<br />

displace 30-40% of conventional fuels.<br />

4. Sustainable implementation of biofuels requires:<br />

• Careful attention to adverse impacts on natural resources,<br />

environment, <strong>and</strong> ecology<br />

• Development of common metrics <strong>and</strong> methods for assessing<br />

life-cycle impacts<br />

5. For widespread consumer acceptance, biofuels must<br />

be conveniently available, affordable, <strong>and</strong> compatible<br />

with conventional fuel/vehicle systems.<br />

25


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