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Jump into the PVC car - Solvay Plastics

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Des Markets produits, and Products des marchés<br />

<strong>Jump</strong> <strong>into</strong> <strong>the</strong><br />

<strong>PVC</strong> <strong>car</strong><br />

Citroën<br />

After losing speed during <strong>the</strong> 1990s, <strong>PVC</strong> is racing back <strong>into</strong> <strong>the</strong> <strong>car</strong> market. Its ideal performances in certain<br />

applications and its very competitive cost make it an ideal material for motor vehicle manufacturers.<br />

The <strong>car</strong> industry is a major market<br />

for <strong>PVC</strong>, purchasing 50 Kt/year<br />

of compounds in Europe 1 . An<br />

average <strong>car</strong> contains 10-15 kg of <strong>PVC</strong>,<br />

in a wide range of applications. <strong>Jump</strong> in<br />

for a demonstration.<br />

Open <strong>the</strong> door, sit inside and you can<br />

easily spot <strong>the</strong> <strong>PVC</strong>, used mainly to<br />

increase comfort and for decoration. Its<br />

main use is for dashboards, but we also<br />

fi nd it on doors, arm-rests, seats, sun<br />

visors, gearstick covers and sometimes<br />

in <strong>the</strong> protective <strong>car</strong>pets, in <strong>the</strong> form<br />

of one or more layers of compact<br />

<strong>PVC</strong>, foamed <strong>PVC</strong> or in combination<br />

with polyurethane fi lms and/or coated<br />

textiles.<br />

<strong>PVC</strong> formulations can easily be adapted<br />

to suit <strong>the</strong> requirements for each<br />

application: a fi lm intended for a seat, for<br />

example cannot be <strong>the</strong>rmoformed <strong>into</strong> a<br />

<strong>car</strong> dashboard. Climatic conditions in <strong>the</strong><br />

country where <strong>the</strong> vehicle is to be sold<br />

are also taken <strong>into</strong> account, to enable<br />

<strong>the</strong> <strong>PVC</strong> to withstand extremes of heat<br />

or cold. “For those parts exposed to <strong>the</strong><br />

sun, especially dashboards and doors, <strong>car</strong>e<br />

is needed to avoid ‘fogging’. A few years<br />

ago it was noticed that new <strong>PVC</strong> coverings<br />

(Editor’s note: o<strong>the</strong>r plastics suffer <strong>the</strong> same<br />

problem) tended to deposit an oily fi lm<br />

on <strong>car</strong> windows as additives evaporated.<br />

Today manufacturers have become very<br />

strict on this point. So we have put in a<br />

lot of work in R&D to remedy this”, points<br />

out Françoise Brisse, R&D and Quality<br />

Manager at Atlas innovations, a company<br />

that produces <strong>the</strong>se fi lms 2 .<br />

“The colours are invariably neutral, in<br />

particular grey. Right now we are seeing<br />

a trend towards very matt fi nishes”, she<br />

explains to Wave. “We take advantage<br />

of <strong>the</strong> opportunities <strong>PVC</strong> offers to move<br />

on from imitation lea<strong>the</strong>r to more technical<br />

grain effects with o<strong>the</strong>r textures. For<br />

example, <strong>the</strong> metallic look of <strong>the</strong> passenger<br />

compartment of <strong>the</strong> Citroen C3 Pluriel.”<br />

O<strong>the</strong>r competing materials for <strong>the</strong>se<br />

applications are TPU (<strong>the</strong>rmoplastic<br />

polyurethane), TP (<strong>the</strong>rmoplastic<br />

polyolefi n) and lea<strong>the</strong>r for certain topof-<strong>the</strong>-range<br />

vehicles.<br />

Dashboards<br />

<strong>PVC</strong> is popular for dashboards because<br />

of its ease of processing in <strong>the</strong> “slush<br />

moulding” process, which offers an<br />

easy way of producing complex shapes.<br />

The negative mould of <strong>the</strong> dashboard,<br />

containing <strong>the</strong> fi nishing grain, is fi rst<br />

heated to around 220° C. <strong>PVC</strong> powder<br />

is <strong>the</strong>n poured in. The powder melts and<br />

<strong>the</strong> mould is turned in every direction<br />

to ensure that <strong>the</strong> <strong>PVC</strong> reaches every<br />

corner of <strong>the</strong> mould, before <strong>the</strong> surplus<br />

is drained from <strong>the</strong> mould. This results<br />

in a uniform layer of ca 1mm left on<br />

<strong>the</strong> entire surface of <strong>the</strong> mould, which<br />

The heavyweights<br />

of weight<br />

reduction<br />

<strong>PVC</strong> can be used to imitate lea<strong>the</strong>r, but also to obtain o<strong>the</strong>r effects. The Lancia Thesis<br />

dashboard is slush moulded in <strong>PVC</strong> by equipment manufacturer Visteon.<br />

Visteon<br />

<strong>Plastics</strong> are certainly a “heavy” argument<br />

for making vehicles lighter and<br />

reducing fuel consumption. Appearing<br />

for <strong>the</strong> fi rst time in <strong>the</strong> 1960s,<br />

today <strong>the</strong>y make up about 20%<br />

of a vehicle’s weight, i.e. generally<br />

between 170 and 260 kg. The most<br />

widely used polymers (elastomers,<br />

<strong>the</strong>rmoplastics, <strong>the</strong>rmosetting resins<br />

and composites) today are <strong>the</strong> polyolefi<br />

ns PP and PE, polyurethanes<br />

(PUR), <strong>PVC</strong> – up to 10 to 15 kg per<br />

<strong>car</strong> – and acrylonitrile-butadienestyrene<br />

(ABS) 4 .<br />

8<br />

1<br />

SolVin estimate (not including <strong>car</strong> seats)<br />

2<br />

The main European companies that manufacture <strong>PVC</strong> foils for <strong>car</strong>s are Benecke-Kaliko (Germany), Vulcafl ex<br />

(Italy), Sioen (Belgique), Mecaseat, Atlas innovations, Yeramex (France).<br />

3<br />

The 3 main European producers of compounds used in <strong>car</strong>s are ATO, <strong>Solvay</strong> and LVM.<br />

4<br />

Source: Étude prospective Plasturgie automobile pour le Nord-Pas de Calais, ADIT, 2003


Dashboards are one of <strong>the</strong> main applications<br />

for <strong>PVC</strong> in <strong>car</strong>s today.<br />

is heated for a few seconds to complete<br />

<strong>the</strong> gelation. The mould is <strong>the</strong>n cooled<br />

and <strong>the</strong> new “skin” is removed, placed<br />

on <strong>the</strong> dashboard (for example in PP).<br />

A polyurethane foam is <strong>the</strong>n injected<br />

between <strong>the</strong> materials to bond <strong>the</strong>m<br />

toge<strong>the</strong>r and make <strong>the</strong> dashboard<br />

comfortable to <strong>the</strong> touch.<br />

This technique has been in use since <strong>the</strong><br />

1980s, and is now so successful that it<br />

is used to produce almost 80% of all<br />

dashboards, with demand continuing<br />

to increase 3 . “Carmakers like BMW and<br />

Renault, s<strong>car</strong>ed away in recent years by<br />

<strong>the</strong> bad environmental image propagated<br />

by <strong>the</strong> anti-<strong>PVC</strong> lobbies, are coming back”,<br />

according to Christian Popin, a specialist<br />

in <strong>the</strong> automobile market at <strong>PVC</strong><br />

compound producer Benvic.<br />

“We have a project for <strong>the</strong> end of 2005<br />

for <strong>the</strong> new BMW X3 and X5 for <strong>the</strong><br />

US market and ano<strong>the</strong>r in 2006 for <strong>the</strong><br />

European market.” A fur<strong>the</strong>r example of<br />

this return to favour is <strong>the</strong> fact that since<br />

July 2004 Benoac (Benecke group) has<br />

Did you know?<br />

How much <strong>PVC</strong> is <strong>the</strong>re in a <strong>car</strong>?<br />

An Audi A8 has been calculated to<br />

contain 15.3 kg, comprising 5.4 kg<br />

of cable sheathing, 4 kg of fi lms and<br />

moulded iparts, 0.9 kg of dashboard<br />

covering and 5 kg of mastic sealant.<br />

been supplying more than 2000 skins a<br />

day for <strong>the</strong> dashboard of <strong>the</strong> new Ford<br />

Focus. A record order worth 25 million<br />

euros over 6 years. Luxury vehicles like<br />

Jaguars and <strong>the</strong> Porsche Cayenne are<br />

also fi tted with <strong>PVC</strong> skins.<br />

In place of <strong>the</strong> slush technique,<br />

less complex dashboards can<br />

also be fi nished with simple<br />

<strong>the</strong>rmoformed <strong>PVC</strong> foil (for<br />

cheaper <strong>car</strong>s) or lined with a<br />

layer of <strong>PVC</strong> foam to obtain<br />

a softer touch.<br />

Comfortably<br />

seated<br />

Being a good seat<br />

covering and having<br />

<strong>the</strong> honour of welcoming<br />

passengers’<br />

Faurecia<br />

posteriors is a tall<br />

order. The <strong>PVC</strong> must<br />

be easy to sew, supple to resist threading<br />

on <strong>the</strong> seat, not create folds nor crack<br />

under <strong>the</strong> passengers’ weight, be resistant<br />

to abrasion, stains and also cleaning.<br />

This is also where <strong>PVC</strong> comes <strong>into</strong> its<br />

own, allowing many fi nishing effects.<br />

Cable sheathing<br />

O<strong>the</strong>r <strong>PVC</strong> applications in <strong>car</strong>s are<br />

much less visible, indeed many of <strong>the</strong>m<br />

you would never suspect existed.<br />

One of <strong>the</strong> main applications is for<br />

sheathing low voltage electrical cables.<br />

Here <strong>PVC</strong> offers major advantages: good<br />

fi re and low temperature<br />

resistance, easy processing,<br />

low cost, and <strong>the</strong> possibility<br />

of recycling by <strong>the</strong><br />

Vinyloop ® process. Here<br />

too, after diffi cult times<br />

between 1995-2000,<br />

when manufacturers<br />

turned towards PE or<br />

PP, <strong>PVC</strong> is back in <strong>the</strong><br />

race. All <strong>the</strong> more so<br />

since, whilst <strong>PVC</strong> has<br />

traditionally been used<br />

for classes 1 (passenger<br />

compartments) and<br />

2 applications, <strong>PVC</strong><br />

compounds now meet<br />

category 3 requirements.<br />

“To be accepted in this category,<br />

<strong>the</strong> cable has to pass testing in<br />

what are extreme conditions for <strong>PVC</strong>:<br />

being kept at 150°C for 10 days and <strong>the</strong>n<br />

being spooled at -40°C without cracking”,<br />

Christian Popin explains.<br />

Under <strong>the</strong> bonnet, <strong>PVC</strong>, which also<br />

offers good abrasion resistance, is used<br />

as protection or a retractable sleeve to<br />

streng<strong>the</strong>n <strong>the</strong> durits (tubes used to<br />

Citroën<br />

PSA<br />

Audi<br />

Apart from its use for door coverings, <strong>PVC</strong> can<br />

be expanded with blowing agents, which act<br />

like baking soda in a cake, <strong>into</strong> foam fi lling for<br />

doors and sun visors.<br />

Here <strong>PVC</strong> foam under <strong>the</strong><br />

microscope.<br />

9


Markets and Products<br />

PSA<br />

<strong>PVC</strong> is applied during bodywork<br />

assembly onto parts at risk from<br />

stone chipping, to stop <strong>the</strong> paint<br />

from fl aking and <strong>the</strong> bodywork<br />

from rusting.<br />

<strong>car</strong>ry liquids between <strong>the</strong> different parts<br />

of <strong>the</strong> engine).<br />

Body armour<br />

<strong>PVC</strong> is also used in ano<strong>the</strong>r application<br />

which, being invisible, is unknown to your<br />

average driver. As “mastic” it is applied<br />

to <strong>the</strong> sensitive parts of <strong>the</strong> bodywork,<br />

for example to <strong>the</strong> welds of <strong>the</strong> engine<br />

compartment, where it protects against<br />

oxidation; under <strong>the</strong> body to make <strong>the</strong><br />

passenger compartment damp, dust<br />

and fume-proof, and to parts at risk<br />

from stone chipping. Plastisol, a mixture<br />

of <strong>PVC</strong> and plasticisers, is pulverised<br />

onto <strong>the</strong> bodywork before <strong>the</strong> fi rst<br />

coat of paint. The two layers are <strong>the</strong>n<br />

stoved simultaneously. “At least 90% of<br />

manufacturing sites use <strong>PVC</strong> mastic, which<br />

is cheaper than polyurethane mastic and<br />

more effective than bitumen”, Hermann<br />

Eichholz from SolVin Customer Technical<br />

Services <strong>PVC</strong> Emulsion told Wave.<br />

Sealing<br />

We fi nish this guided tour with a few<br />

more applications. The joints of <strong>the</strong> fi xed<br />

windows and <strong>the</strong> back window also use<br />

<strong>PVC</strong>, in particular in North America (18<br />

to 20 kt/year) and Japan. Using <strong>the</strong> socalled<br />

encapsulation technique, perfect<br />

waterproofi ng is obtained by injecting<br />

<strong>PVC</strong> <strong>into</strong> a mould which represents<br />

exactly <strong>the</strong> space between <strong>the</strong> glass and<br />

<strong>the</strong> <strong>car</strong> wall.<br />

Whilst <strong>the</strong> <strong>PVC</strong> protective strips along<br />

<strong>the</strong> sides of <strong>car</strong> bodies have in most<br />

cases been replaced by PP, <strong>the</strong> roof<br />

profi les (<strong>the</strong> fi ne black or coloured strip<br />

running above <strong>the</strong> doors) in many cases<br />

remain in <strong>PVC</strong>.<br />

Finally, <strong>PVC</strong> can also be used for <strong>the</strong><br />

roofs and side and rear windows of<br />

convertibles and cross-country vehicles.<br />

After some rough driving in <strong>the</strong><br />

1990s, it looks like a straight road<br />

ahead for <strong>PVC</strong>.<br />

■<br />

Intermodal<br />

transport<br />

award for<br />

SolVin Italia<br />

SolVin has just won <strong>the</strong> 5 th<br />

Intermodal Award of <strong>the</strong> European<br />

Intermodal Association for its<br />

SIRIO (SolVin Italia Railway<br />

Intermodal Operations) rail-road<br />

transportation system. SolVin <strong>PVC</strong><br />

for Italy is brought in by train to<br />

two depots near Milan, and <strong>the</strong>n<br />

forwarded on to customers by<br />

road. As well as putting SolVin Italia<br />

ahead of <strong>the</strong> competition in terms<br />

of logistics excellence (punctuality<br />

and lack of contamination), this<br />

system also brings environment<br />

benefi ts, cutting out 10,000 trans-<br />

Alpine truck journeys and saving<br />

2.4 million litres of diesel every<br />

year.<br />

10<br />

Daimler Chrysler<br />

The Chrysler Sebring Convertible 2005, which is proving a great success in <strong>the</strong> United<br />

States, has an electrically controlled <strong>PVC</strong> hood incorporating <strong>the</strong> roof, side and rear<br />

windows.<br />

On 2 November 2004, <strong>the</strong><br />

European Intermodal Association<br />

(E.I.A.) handed <strong>the</strong> Intermodal<br />

Award to SolVin Italia’s Managing<br />

Director Paolo Groppi. The EIA,<br />

which is supported by <strong>the</strong> European<br />

Commission and Parliament, seeks to<br />

promote intermodal transport and to<br />

develop best practice in this fi eld.

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