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<strong>Excellence</strong> <strong>in</strong> recycl<strong>in</strong>g…<br />

October 2006


Explor<strong>in</strong>g Umicore


Umicore: a history of transformation<br />

1887 1900 1960 1970 1980 1990 2001 2003<br />

Asturienne<br />

Vieille-Montagne<br />

Acec<br />

Société m<strong>in</strong>ère du Bécéka (Sibeka)<br />

Union M<strong>in</strong>ière<br />

Metallurgie Hoboken<br />

Us<strong>in</strong>e de désarg (Degussa)<br />

Compagnie des Metaux d’Overpelt<br />

Société Générales des M<strong>in</strong>erais<br />

Méchim<br />

MDK Komb<strong>in</strong>at Pirdop<br />

Sogem<br />

Degussa (precious metals, automotive catalysts, fuel cells) dmc² PMG<br />

3


Umicore:<br />

a world leader <strong>in</strong> specialty materials<br />

Umicore’s activities are centred <strong>in</strong> 4<br />

bus<strong>in</strong>ess areas: Advanced<br />

Materials, Precious Metals Products<br />

& Catalysts, Precious Metals<br />

Services and Z<strong>in</strong>c Specialties.<br />

Umicore’s expertise <strong>in</strong> materials<br />

science, chemistry and<br />

metallurgy can make a real<br />

difference, be it <strong>in</strong> products that are<br />

essential to everyday life or those at<br />

the cutt<strong>in</strong>g edge of new<br />

technological developments.<br />

4


Umicore: activities <strong>in</strong> four bus<strong>in</strong>ess groups<br />

Precious<br />

Metals<br />

Management<br />

Precious<br />

Metals<br />

Services<br />

Precious<br />

Metals<br />

Ref<strong>in</strong><strong>in</strong>g<br />

Automotive<br />

Catalysts<br />

Electro-<br />

Optic<br />

Materials<br />

Precious Metals Products & Catalysts<br />

Precious<br />

Metals<br />

Chemistry<br />

Specialty<br />

Oxides &<br />

Chemicals<br />

Technical<br />

Materials<br />

Eng<strong>in</strong>eered<br />

Metal<br />

Powders<br />

Advanced Materials<br />

Th<strong>in</strong> Film<br />

Products<br />

Element 6<br />

Abrasives<br />

(40%)<br />

Z<strong>in</strong>c<br />

Specialties<br />

Jewellery<br />

& Electroplat<strong>in</strong>g<br />

Z<strong>in</strong>c<br />

Alloys<br />

Z<strong>in</strong>c<br />

Chemicals<br />

Build<strong>in</strong>g<br />

Products<br />

Padaeng<br />

Industry<br />

(46%)<br />

Additional<br />

<strong>in</strong>fo<br />

5


Precious<br />

Metals<br />

Services<br />

§ Umicore is the world leader <strong>in</strong> the<br />

recycl<strong>in</strong>g of precious metals. It<br />

provides recycl<strong>in</strong>g and ref<strong>in</strong><strong>in</strong>g<br />

services at its plant <strong>in</strong> Hoboken,<br />

Hanau and <strong>in</strong> Brazil.<br />

§ Recovers approximately 20 metals<br />

<strong>in</strong>clud<strong>in</strong>g: gold, silver, plat<strong>in</strong>um,<br />

rhodium and palladium.<br />

§ Metals Management function for,<br />

among others, the hedg<strong>in</strong>g,<br />

leas<strong>in</strong>g, purchas<strong>in</strong>g and sale of<br />

precious metals.<br />

The ma<strong>in</strong> feed materials are byproducts<br />

of the non-ferrous metal<br />

and photographic <strong>in</strong>dustries, spent<br />

automotive and <strong>in</strong>dustrial catalysts<br />

and electronic scrap<br />

<strong>in</strong> mio € H1 2005 H1 2006<br />

Revenue 117.5 166.6<br />

EBIT (recurr<strong>in</strong>g) 28.9 62.6<br />

EBITDA 52.2 77.3<br />

ROCE % 23.6 44.8<br />

6


Precious<br />

Metals<br />

Products &<br />

Catalysts<br />

§ Umicore is one of the world’s<br />

lead<strong>in</strong>g producers of automotive<br />

catalysts and the lead<strong>in</strong>g producer<br />

of catalysts for diesel eng<strong>in</strong>es.<br />

§ Other products and services are<br />

based on precious metals (most often<br />

PGMs) and used <strong>in</strong> a wide variety of<br />

<strong>in</strong>dustries <strong>in</strong>cl. jewellery,<br />

electroplat<strong>in</strong>g, glassmak<strong>in</strong>g,<br />

electronics and <strong>in</strong> various chemical<br />

processes.<br />

§ Th<strong>in</strong> Film Products provides target<br />

materials for a wide range of<br />

applications.<br />

The bus<strong>in</strong>ess has a global reach with<br />

production sites on four cont<strong>in</strong>ents.<br />

This bus<strong>in</strong>ess group is mostly made up<br />

of units acquired as part of the PMG<br />

acquisition which was f<strong>in</strong>alised July ‘03.<br />

<strong>in</strong> mio € H1 2005 H1 2006<br />

Revenue 375.4 426.7<br />

EBIT (recurr<strong>in</strong>g) 71.6 71.7<br />

EBITDA 91.3 94.6<br />

ROCE % 24.2 20.8<br />

7


Advanced<br />

Materials<br />

§ Lead<strong>in</strong>g global position <strong>in</strong> cathode<br />

materials for lithium –ion batteries,<br />

cobalt powders for hard metal,<br />

applications, germanium<br />

substrates for space solar cells.<br />

§ Produces high-purity metals,<br />

alloys, compounds and eng<strong>in</strong>eered<br />

products for a wide range of other<br />

specialist applications.<br />

§ Advanced Materials has <strong>in</strong>dustrial<br />

operations around the world.<br />

Synthetic diamond and superabrasives<br />

activities are conducted<br />

<strong>in</strong> a jo<strong>in</strong>t venture with Element Six.<br />

<strong>in</strong> mio € H1 2005 H1 2006<br />

Revenue 138.6 143.7<br />

EBIT (recurr<strong>in</strong>g) 27.7 24.3<br />

EBITDA 37.5 36.4<br />

ROCE % 13.7 13.0<br />

8


Z<strong>in</strong>c<br />

Specialties<br />

§ Umicore’s strategy is to pursue<br />

leadership positions <strong>in</strong> specialty<br />

products with added value: z<strong>in</strong>c<br />

chemicals, alloys and build<strong>in</strong>g<br />

products.<br />

§ Umicore is also the world’s<br />

foremost z<strong>in</strong>c recycler.<br />

§ Primary production <strong>in</strong> Belgium,<br />

France and <strong>in</strong> 46% owned<br />

Padaeng Industries <strong>in</strong> Thailand.<br />

Umicore’s focus on recycl<strong>in</strong>g is<br />

central to its closed loop bus<strong>in</strong>ess<br />

model.<br />

<strong>in</strong> mio € H1 2005 H1 2006<br />

Revenue 229.1 207.0<br />

EBIT (recurr<strong>in</strong>g) 16.9 27.2<br />

EBITDA 37.3 47.2<br />

ROCE % 8.3 10.8<br />

9


Umicore has <strong>in</strong>dustrial applications on all cont<strong>in</strong>ents<br />

& serves an <strong>in</strong>ternational customer base<br />

10


Umicore: Committed to susta<strong>in</strong>able<br />

development<br />

Turnover<br />

Revenues<br />

EBIT<br />

EBITDA<br />

Net Consolidated Profit<br />

Capital Employed<br />

Workforce<br />

H1<br />

2005<br />

€<br />

million<br />

3,263.5<br />

861.1<br />

121.7<br />

203.8<br />

1,707.0<br />

13,193<br />

77.2<br />

H1<br />

2006<br />

€<br />

million<br />

4,521.0<br />

944.4<br />

160.5<br />

251.3<br />

109.6<br />

1,937.0<br />

15,956<br />

In June 2005 Umicore was ranked<br />

<strong>in</strong> world’s top-50 companies for<br />

comb<strong>in</strong>ed f<strong>in</strong>ancial and corporate<br />

social responsibility performance.<br />

Umicore ranked 8th <strong>in</strong> terms of<br />

corporate social responsibilities.<br />

Umicore recognizes that its<br />

commitment to f<strong>in</strong>ancial success<br />

must also take <strong>in</strong>to account the<br />

broader economic, environmental<br />

and social impact of its operations.<br />

11


Explor<strong>in</strong>g<br />

Umicore<br />

Precious Metals Ref<strong>in</strong><strong>in</strong>g


UPMR Worldwide<br />

UAR,<br />

Cov<strong>in</strong>gton,<br />

USA<br />

UPMR,<br />

Guarulhos,<br />

Brazil<br />

Cycleon, Paris, France<br />

UAR, Hoboken, Belgium<br />

UPMR, Hoboken, Belgium<br />

UPMR, Hanau, Germany<br />

UAR, Alzenau, Germany<br />

UMS,<br />

Shanghai,<br />

Ch<strong>in</strong>a<br />

13


UPMR Worldwide<br />

Hoboken Hanau Guarulhos<br />

§ UPMR’s largest <strong>in</strong>dustrial<br />

activities are located at<br />

Hoboken, near Antwerp<br />

(Belgium).<br />

§ Around 1,150 people active <strong>in</strong><br />

sampl<strong>in</strong>g & assay<strong>in</strong>g activities,<br />

<strong>in</strong> smelt<strong>in</strong>g & ref<strong>in</strong><strong>in</strong>g<br />

operations and <strong>in</strong> commercial<br />

& support<strong>in</strong>g services.<br />

§ First operations started <strong>in</strong> 1887<br />

as a desilver<strong>in</strong>g plant and is<br />

now the world’s largest<br />

precious metals recycl<strong>in</strong>g<br />

facility.<br />

§ UPMR Hanau (Germany)<br />

<strong>in</strong>cludes a sampl<strong>in</strong>g & sales<br />

department<br />

§ Particularly the autocatalyst<br />

recycl<strong>in</strong>g facilities are run out<br />

of Hanau.<br />

§ 20 people are active <strong>in</strong> Hanau.<br />

§ UPMR operates <strong>in</strong> Guarulhos,<br />

near Sao Paulo (Brazil) and has<br />

silver & gold ref<strong>in</strong><strong>in</strong>g activities.<br />

§ The sales department is serv<strong>in</strong>g<br />

the South-American market <strong>in</strong><br />

order to supply our Brazilian<br />

ref<strong>in</strong>ery as well Hoboken’s<br />

plant.<br />

§ Employment: 50 people<br />

14


UPMR: the lead<strong>in</strong>g precious metals recycler<br />

• Unique and <strong>in</strong>novative<br />

technology<br />

• Outstand<strong>in</strong>g services to<br />

an <strong>in</strong>ternational customer<br />

basis<br />

• A wide range of complex<br />

precious metals bear<strong>in</strong>g<br />

materials<br />

• Efficient recovery of 17<br />

different metals<br />

• Apply<strong>in</strong>g world class<br />

environmental standards<br />

15


Umicore Precious Metals Services*<br />

Key Figures<br />

EBITDA<br />

EBIT<br />

Average Capital Employed<br />

ROCE<br />

Capital Expenditure<br />

Workforce<br />

Surface<br />

* Bus<strong>in</strong>ess units Precious Metals Ref<strong>in</strong><strong>in</strong>g & Precious Metals Management<br />

H1 2005<br />

€ million<br />

52.2<br />

28.9<br />

245.1<br />

23.6%<br />

4.8<br />

1,279<br />

H1 2006<br />

€ million<br />

77.3<br />

62.2<br />

277.7<br />

44.8%<br />

9.8<br />

1,294<br />

116 hectares<br />

16


Umicore Precious Metals Ref<strong>in</strong><strong>in</strong>g<br />

SMELTERS &<br />

REFINERS INDUSTRY MARKET<br />

e.g.<br />

tankhouse<br />

slimes<br />

ref<strong>in</strong>ed metal e.g. computers<br />

production<br />

scrap<br />

precious<br />

metals<br />

e.g. copper scrap<br />

e.g.<br />

electronic<br />

scrap<br />

precious<br />

metals<br />

17


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

18


Raw Materials Supply<br />

Each year UPMR processes around<br />

300,000 tonnes of more than 200<br />

different types of raw materials<br />

conta<strong>in</strong><strong>in</strong>g lead/copper/nickel and<br />

precious metals.<br />

19


Types of raw materials<br />

By-products Recyclable products<br />

By-products<br />

from nonferrous<br />

<strong>in</strong>dustry<br />

e.g. drosses from<br />

lead smelters,<br />

slimes from copper<br />

<strong>in</strong>dustry,…<br />

Spent<br />

Industrial<br />

Catalysts<br />

Industrial<br />

catalysts from oil<br />

ref<strong>in</strong><strong>in</strong>g &<br />

petrochemical<br />

<strong>in</strong>dustry<br />

Electronic<br />

Scrap<br />

e.g. pr<strong>in</strong>ted circuit<br />

boards<br />

Spent<br />

Automotive<br />

Catalysts<br />

end-of-life<br />

car catalysts<br />

Precious metal<br />

bear<strong>in</strong>g raw<br />

materials<br />

e.g. fuel cells,<br />

photographic<br />

residues<br />

20


Supply distribution<br />

Spent<br />

Catalysts<br />

12%<br />

Electronic<br />

Scrap<br />

10%<br />

Others<br />

5%<br />

By-products<br />

73%<br />

21


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

22


Sales<br />

We recover and sell precious,<br />

special & base metals, chemicals &<br />

derivated products.<br />

23


Umicore Precious Metals Ref<strong>in</strong><strong>in</strong>g has<br />

flexible capacity for PM’s …<br />

Capacity t/y<br />

Output t/y<br />

From<br />

recyclables<br />

Ag Au Pt Pd Rh<br />

2,400<br />

1,200<br />

25%<br />

100<br />

25<br />

25%<br />

16<br />

12<br />

65%<br />

24<br />

15<br />

65%<br />

4<br />

3<br />

30%<br />

24


Precious Metals added value products<br />

§ Besides the production of ref<strong>in</strong>ed precious metals Umicore<br />

produces a range of complex precious metal bear<strong>in</strong>g<br />

materials serv<strong>in</strong>g a wide range of <strong>in</strong>dustries <strong>in</strong>clud<strong>in</strong>g<br />

automotive, jewellery, electronics, pharmaceutical and<br />

optics.<br />

§ Umicore Precious Metals Products & Catalysts with its<br />

headquarters <strong>in</strong> Hanau (Germany) generates added value<br />

to Hoboken ref<strong>in</strong>ed metals<br />

Additional<br />

<strong>in</strong>fo<br />

25


Precious Metals<br />

Silver<br />

(Ag)<br />

Gold<br />

(Au)<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

tankhouse and various slimes, lead sulphate, ashes, …<br />

silver 99.9+ % & 99.99 % granules<br />

jewellery, co<strong>in</strong>s, electronic & imag<strong>in</strong>g <strong>in</strong>dustries,<br />

catalysts, batteries<br />

tankhouse and various slimes, electronic scrap,<br />

sweeps & bullions<br />

gold 99.99 % gra<strong>in</strong>s & <strong>in</strong>gots (12.5 kg bars or smaller)<br />

jewellery, <strong>in</strong>vestment, co<strong>in</strong>s, electronic <strong>in</strong>dustries, …<br />

26


Precious Metals<br />

Plat<strong>in</strong>um<br />

(Pt)<br />

Palladium<br />

(Pd)<br />

Rhodium<br />

(Rh)<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Residues from the PGM m<strong>in</strong><strong>in</strong>g, slimes, catalysts,<br />

electronic scrap<br />

99.95 % powder (sponge)<br />

Jewellery (Pt), <strong>in</strong>dustrial & automotive catalysts,<br />

electronic <strong>in</strong>dustry, …<br />

27


Precious Metals<br />

Iridium<br />

(Ir)<br />

Ruthenium<br />

(Ru)<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Various slimes and precious metal bear<strong>in</strong>g products<br />

High grade salt (Ru > 75%)<br />

Hard metal and heat resistant alloys, electronic<br />

<strong>in</strong>dustry, …<br />

28


Base & special metals<br />

Pb<br />

125,000t<br />

Cu<br />

40,000t<br />

Sb<br />

3,000t<br />

Capacities for other non - PM elements<br />

Sn<br />

1,000t<br />

Bi<br />

400t<br />

Ni<br />

2,000t<br />

In<br />

30t<br />

Se<br />

600t<br />

Te<br />

150t<br />

Slags<br />

140,000t<br />

Additional<br />

<strong>in</strong>fo<br />

29


Base Metals<br />

Lead<br />

(Pb)<br />

Copper<br />

(Cu)<br />

Nickel<br />

(Ni)<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

drosses, lead sulphates, slags, …<br />

HER 99,97%, Crystal Pb 99,99%, PbCu<br />

Batteries, build<strong>in</strong>g products, …<br />

drosses, tankhouse slimes, copper cement, electronic<br />

scrap, …<br />

see www.cumerio.com<br />

cables, wires …<br />

drosses, slimes, electronic scrap, …<br />

nickel sulphate<br />

batteries, sta<strong>in</strong>less steel, …<br />

30


Chemicals & derivated products<br />

Sodium<br />

Antimonate<br />

Aggregate<br />

for<br />

concrete<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Orig<strong>in</strong><br />

Applications<br />

drosses, slags, tankhouse slimes, …<br />

Sodium antimonate<br />

flame retardant, decolor<strong>in</strong>g agent, oxygen removal<br />

additive (TV-glass)<br />

the slag is the rema<strong>in</strong>der of our metallurgical process<br />

additive for concrete & dyke fortification<br />

31


Special Metals<br />

Indium<br />

(In)<br />

Selenium<br />

(Se)<br />

Tellurium<br />

(Te)<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

Orig<strong>in</strong><br />

Grade<br />

Applications<br />

z<strong>in</strong>c & lead ores<br />

In foil & InH<br />

Indium T<strong>in</strong> Oxide (ITO) for use <strong>in</strong> flat screens,<br />

electronics & semiconductors, solders & low melt<strong>in</strong>g<br />

po<strong>in</strong>t alloys, batteries, …<br />

tankhouse slimes<br />

SeHP 5N, SeHP 5N+, NaSe, SeTG 2N5, SeTG, 3N,<br />

SeSG 4N5 & Se Crude Wet<br />

<strong>in</strong> glass <strong>in</strong>dustry as color<strong>in</strong>g agent, pigments, animal<br />

feed, photo electric cells, …<br />

by-products from copper & lead <strong>in</strong>dustry, tankhouse<br />

slimes<br />

TeTG & TeHP<br />

steel, brass & copper alloys, solar cells<br />

32


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

33


Customer support<br />

UPMR provides a complete range of<br />

commercial and f<strong>in</strong>anc<strong>in</strong>g services for<br />

an optimal match with our costumers<br />

needs.<br />

Logistical assistance is provided as<br />

well as cross border transports and all<br />

legislative related matters.<br />

34


Comprehensive customer service<br />

§ UPMR is present worldwide to provide all<br />

necessary support.<br />

§ UPMR provides its clients complete<br />

<strong>in</strong>com<strong>in</strong>g and outgo<strong>in</strong>g logistical assistance<br />

for raw materials and for ref<strong>in</strong>ed metals &<br />

products.<br />

§ UPMR assists the customer <strong>in</strong> tak<strong>in</strong>g care of<br />

all environmental and adm<strong>in</strong>istrative<br />

obligations result<strong>in</strong>g from <strong>in</strong>ternational waste<br />

regulations and shipments, such as the Basel<br />

Convention, the Decision of the OECD<br />

Council and the Council Regulation (EEC).<br />

§ UPMR’s VAT warehouse allows our clients to<br />

trade with their metal credit loco Hoboken<br />

without VAT registration <strong>in</strong> Belgium and<br />

without declaration to the related EU Tax<br />

authorities.<br />

35


Metals Management service<br />

Basel Convention<br />

LBMA<br />

§ Optimal metal valorisation is ensured by<br />

UPMR’s expertise team, watch<strong>in</strong>g<br />

closely London fix<strong>in</strong>gs and market<br />

<strong>in</strong>formation.<br />

§ Supplier ‘s Risk management can be<br />

facilitated through forward pric<strong>in</strong>g,<br />

transmission of limit orders or more specific<br />

solutions.<br />

36


Metals Management service<br />

§ Our metals management ensures an optimal valorisation of raw<br />

materials. Ref<strong>in</strong>ed metals can be returned or can be repurchased at<br />

the best available market conditions.<br />

§ Clear <strong>in</strong>dividual metal accounts reflect all of the results of the metal<br />

transactions.<br />

§ UPMR offers special services like f<strong>in</strong>anc<strong>in</strong>g, leas<strong>in</strong>g, swaps, metal<br />

account transfers, pledges, early metal returns, market <strong>in</strong>formation,<br />

regular metal statement, ...<br />

37


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

38


A unique metallurgy…<br />

In<br />

Bi<br />

Ag<br />

Pb<br />

Sn<br />

Au<br />

Te<br />

As<br />

Pd<br />

Cu<br />

Sb<br />

Se<br />

Pt<br />

Ni<br />

Ir<br />

Rh<br />

Ru<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Pb, Cu & Ni are the base metals<br />

that drive our unique recycl<strong>in</strong>g<br />

process.<br />

By us<strong>in</strong>g the specific properties of<br />

these collector metals, precious<br />

and other secondary metals are<br />

recovered with the greatest<br />

efficiency.<br />

Our <strong>in</strong>-house developed precious<br />

metals ref<strong>in</strong>ery is one of the<br />

world’s largest and most efficient<br />

ref<strong>in</strong><strong>in</strong>g facility.<br />

39


H 2 SO 4<br />

Sulphuric Acid<br />

Nickel Ref<strong>in</strong>ery<br />

Ni<br />

SO 2<br />

PMresidue<br />

Sampl<strong>in</strong>g<br />

Smelter<br />

Raw Materials<br />

Precious Metals Operations<br />

Cu-bullion<br />

Leach<strong>in</strong>g & Electro W<strong>in</strong>n<strong>in</strong>g<br />

PM-residue<br />

Precious Metals Ref<strong>in</strong>ery<br />

Pb-slags<br />

Cu-matte<br />

Ni-speiss<br />

Agresidue<br />

Seresidue<br />

Base Metals Operations<br />

Blast Furnace<br />

Lead Ref<strong>in</strong>ery<br />

Pb-bullion<br />

Special Metals Ref<strong>in</strong>ery<br />

In-Te-residue<br />

Cu Ag, Au, Pt, Pd, Rh, Ir, Ru In, Se, Te Pb, Bi, Sb,<br />

Sn, As<br />

Additional<br />

<strong>in</strong>fo<br />

Slags 40


Precious Metals Operations<br />

Smelter<br />

§ Unique Isa smelt, submerged lance combustion technology, <strong>in</strong>ject<strong>in</strong>g oxygen<br />

enriched air and fuel <strong>in</strong> a molten bath.<br />

§ Separat<strong>in</strong>g precious metals, <strong>in</strong> a copper bullion, from mostly all other metals,<br />

concentrated <strong>in</strong> a lead slag.<br />

§ Operat<strong>in</strong>g at 1,000 mt/day at an availability > 92%. Brick rel<strong>in</strong><strong>in</strong>g period over<br />

14 months.<br />

§ Highly flexible technology for PM recycl<strong>in</strong>g<br />

q variability of physical aspect (lumps, f<strong>in</strong>es, wet,<br />

dry, shredded material, ...)<br />

q variability of feed mix (e.g. volume e-scrap vs.<br />

total volume)<br />

q ratio PM/ PGM’s and impurities <strong>in</strong> the feed mix<br />

41


Precious Metals Operations:<br />

Leach<strong>in</strong>g and Electro W<strong>in</strong>n<strong>in</strong>g<br />

§ Leach copper to collect precious metals <strong>in</strong> a residue for further ref<strong>in</strong><strong>in</strong>g <strong>in</strong> the<br />

precious metals ref<strong>in</strong>ery.<br />

§ Increase PM-content <strong>in</strong> residue from <strong>in</strong>take (Cu-granules) with factor 10.<br />

§ Wax- less Cu Electro W<strong>in</strong>n<strong>in</strong>g process, operat<strong>in</strong>g at 270A/m², actual current<br />

efficiency > 92%, produc<strong>in</strong>g 99.99% pure Cu-cathodes.<br />

§ Highly flexible technology<br />

q Ratio copper / other metals<br />

q PM and PGM content<br />

42


Precious Metals Operations<br />

Precious Metals Ref<strong>in</strong>ery<br />

§ Comb<strong>in</strong>ation of classical methods (e.g. cupellation) and unique <strong>in</strong>-house<br />

developed processes (e.g. silver ref<strong>in</strong>ery).<br />

§ Unique flexibility on ratio of gold, plat<strong>in</strong>um, palladium and secondary<br />

PGM’s versus silver, vary<strong>in</strong>g substantially accord<strong>in</strong>gly raw material feed.<br />

§ High purity metal production:<br />

q Ag: 5N<br />

q Au: 4N+<br />

q Pt, Pd, Rh: 3N5, catalytic grade<br />

q Ir, Ru: concentrates<br />

43


Base Metals Operations<br />

Blast Furnace<br />

The gases are further treated <strong>in</strong>to<br />

gas clean<strong>in</strong>g <strong>in</strong>stallation.<br />

The gases leave the furnace at<br />

around 200 °C.<br />

At the middle of the furnace the gas<br />

temperature is about 400 °C<br />

The warm gases heats-up the<br />

“cold” feed.<br />

The burned cokes produce gases<br />

with a temperature up to 1700 °C<br />

Reaction between hot air and<br />

cokes.<br />

Blow<strong>in</strong>g hot air at 600 °C <strong>in</strong>to the<br />

furnace.<br />

GASES<br />

Feed<br />

Gases<br />

- The feed is a mixture of more than 20 different products<br />

-Smelt<strong>in</strong>g capacity up to 1000 ton/day<br />

- Productions:<br />

200 - 250 ton lead / day<br />

FEED<br />

Feed<strong>in</strong>g the furnace with a<br />

mixture of cokes and lead<br />

conta<strong>in</strong><strong>in</strong>g products.<br />

Dry<strong>in</strong>g of the feed by the hot<br />

gasses.<br />

Heat<strong>in</strong>g up of the feed to 400 °C.<br />

Heat<strong>in</strong>g up of the feed to 800 °C.<br />

Smelt<strong>in</strong>g of the feed. Due to a<br />

complex set of metallurgical<br />

reactions different liquid and<br />

gaseous phases are formed.<br />

Liquid phases are tapped at<br />

1200 °C.<br />

44


Base Metals Operations<br />

Lead Ref<strong>in</strong>ery<br />

§ The Lead ref<strong>in</strong>ery treats the lead-bullion from the blast furnace<br />

q 95% Pb with As, Sn, Sb, In, Te, Ag, Bi<br />

§ In a batch type process these impurities are <strong>in</strong>dividually separated<br />

q As- salt retrograded to the Blast Furnace<br />

q Sn- salt for third party treatment<br />

q Sb- salt for sales<br />

q In & Te- residue for treatment <strong>in</strong> the Special Metals Ref<strong>in</strong>ery<br />

q Ag-skimm<strong>in</strong>gs for treatment <strong>in</strong> the Precious Metals Ref<strong>in</strong>ery<br />

q Bi-skimm<strong>in</strong>gs for third party treatment<br />

§ The ma<strong>in</strong> f<strong>in</strong>al product is ref<strong>in</strong>ed lead<br />

q 99.99 % Pb, at a capacity of 90,000 ton/year<br />

45


Base Metals Operations<br />

Special Metals Ref<strong>in</strong>ery<br />

Selenium, tellurium and <strong>in</strong>dium form the product<br />

portfolio of UPMR Special Metals. These metals are<br />

extracted from side-streams of the PMO and the Leadref<strong>in</strong>ery.<br />

In Se Te<br />

Selenium is often present <strong>in</strong> copper ore and is recovered from tankhouse slimes. It is<br />

used <strong>in</strong> the glass and pigment <strong>in</strong>dustry, <strong>in</strong> reprography applications, <strong>in</strong> <strong>in</strong>frared optics and<br />

solar cell technologies. UPMR has a production capacity of 600 tonnes per year.<br />

Tellurium is also ma<strong>in</strong>ly generated <strong>in</strong> a by-product of the copper <strong>in</strong>dustry. Tellurium<br />

improves the mach<strong>in</strong>ability of steel, is used <strong>in</strong> rubber vulcanisation and catalysts, as well<br />

as <strong>in</strong> thermoelectric applications. UPMR has an annual production capacity of 150 tonnes.<br />

Indium is not found <strong>in</strong> the native state, but is associated with lead and z<strong>in</strong>c <strong>in</strong> many ores.<br />

80% of the <strong>in</strong>dium consumption is dedicated to the production of Indium-T<strong>in</strong>-Oxide (ITO),<br />

which is a transparant conductive oxide used <strong>in</strong> flat screen displays. Applications of <strong>in</strong>dium<br />

also <strong>in</strong>clude low melt<strong>in</strong>g po<strong>in</strong>t alloys, control rods for nuclear reactors and hermetic seals<br />

for cryogenic applications. UPMR has a production capacity of 30 tonnes per year.<br />

46


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

47


Sampl<strong>in</strong>g & Assay<strong>in</strong>g<br />

The wide variety and complexity of<br />

<strong>in</strong>com<strong>in</strong>g materials mean that<br />

sampl<strong>in</strong>g & assay<strong>in</strong>g are<br />

Key Succes Factors <strong>in</strong> determ<strong>in</strong><strong>in</strong>g<br />

our customer’s f<strong>in</strong>ancial yield.<br />

UPMR allocates more than 15% of<br />

its operat<strong>in</strong>g budget to these<br />

services.<br />

48


Raw materials flow<br />

Arrival of raw<br />

materials<br />

Physical reception<br />

Primary sample<br />

Weigh<strong>in</strong>g <strong>in</strong>formation<br />

Moisture determ<strong>in</strong>ation<br />

F<strong>in</strong>al sample<br />

preparation of<br />

primary sample<br />

W&S report<br />

Samples for customers<br />

Loss of identity<br />

Bulk Smelter<br />

Laboratory Assay Exchange<br />

Determ<strong>in</strong>ation of<br />

metals content<br />

Settlement of results<br />

between customer &<br />

UPMR<br />

49


Sampl<strong>in</strong>g<br />

§ Unique state-of-the-art facilities<br />

§ Dedicated to process all raw materials<br />

§ Key drivers:<br />

q maximiz<strong>in</strong>g automations<br />

q adequate capacities <strong>in</strong> grow<strong>in</strong>g segments (e-scrap, auto catalysts, …<br />

q shorten<strong>in</strong>g the lead times<br />

q respect<strong>in</strong>g environmental, health & safety standards<br />

§ Investment of 15 Million € <strong>in</strong> last 10 years<br />

§ Employment: 90 people<br />

§ Secured area, ± 5000 lots & 300,000 t/y<br />

50


Ma<strong>in</strong> sampl<strong>in</strong>g processes<br />

Autocatalysts<br />

Decann<strong>in</strong>g & sampl<strong>in</strong>g<br />

of ceramic convertors<br />

<strong>in</strong> Hoboken (Belgium),<br />

Hanau-Alzenau<br />

(Germany).<br />

Shredd<strong>in</strong>g & sampl<strong>in</strong>g<br />

of metallic convertors<br />

<strong>in</strong> Alzenau (Germany)<br />

Electronic scrap<br />

Two seperate l<strong>in</strong>es<br />

for shredded and<br />

unshredded<br />

electronic scrap<br />

F<strong>in</strong>e free-flow<strong>in</strong>g<br />

material<br />

Sampl<strong>in</strong>g via<br />

blend<strong>in</strong>g<br />

e.g. sweeps,<br />

<strong>in</strong>dustrial<br />

catalysts<br />

Metallic material<br />

Sampl<strong>in</strong>g after<br />

remelt<strong>in</strong>g<br />

F<strong>in</strong>al sample preparation<br />

Wet material Lumpy material<br />

Homogenisation<br />

by mix<strong>in</strong>g<br />

Automatic spear<br />

sampl<strong>in</strong>g<br />

e.g. leach<br />

products, slimes<br />

Sampl<strong>in</strong>g via<br />

mill<strong>in</strong>g<br />

51


Laboratory<br />

§ Recognized leadership <strong>in</strong> the precious metals <strong>in</strong>dustry<br />

§ An up-to-date analytical equipment, supported by<br />

§ Key drivers:<br />

q a robust quality assurance system<br />

q a laboratory <strong>in</strong>formation and management system (LIMS)<br />

q Customer orientation<br />

q Respect for short lead times<br />

q Cont<strong>in</strong>uously <strong>in</strong>vestment <strong>in</strong> analytical research and method improvement<br />

§ Employment: 75 chemists<br />

§ Workload: 70,000 samples/y<br />

52


Assay<strong>in</strong>g process<br />

§ Internationally recognised by our customers <strong>in</strong><br />

precious metals assay<strong>in</strong>g us<strong>in</strong>g conventional<br />

fire assay & chemical procedures. Highly<br />

experienced <strong>in</strong> Pb, Cu and NiS collection.<br />

§ In-house developed technologies/processes.<br />

§ Extensive wet chemistry experience.<br />

§ Environmental analysis, <strong>in</strong>clud<strong>in</strong>g diox<strong>in</strong>s (by Gas<br />

Chromatography – Mass Spectrometry).<br />

§ Trace metals determ<strong>in</strong>ation.<br />

§ Broad range of <strong>in</strong>strumental techniques:<br />

q X-Ray Fluorescence (XRF)<br />

q Inductive Coupled Plasma (ICP)<br />

q Optical Emission Spectrometry (OES)<br />

q Graphite Furncace Atomic Absorption Spectrometry<br />

(GFMAS)<br />

53


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

54


Susta<strong>in</strong>able Development:<br />

For Umicore Precious Metals Ref<strong>in</strong><strong>in</strong>g, susta<strong>in</strong>able<br />

development implies:<br />

§ Cont<strong>in</strong>uous improvement of environmental<br />

performance.<br />

§ Social responsibility especially towards the local<br />

community.<br />

§ A challeng<strong>in</strong>g and support<strong>in</strong>g policy towards our<br />

personnel.<br />

§ Economic sound management <strong>in</strong> a Total Quality<br />

approach.


Environment:<br />

cont<strong>in</strong>uous reduction of air emissions<br />

45<br />

40<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

20<br />

18<br />

16<br />

14<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

Stack emission of lead (t/y)<br />

80 85 90 93 94 95 96 97 98 99 00 01 02 03 04 05<br />

Diffuse emission of lead (t/y)<br />

81 83 85 87 89 91 93 95 97 99 01 03 05<br />

Substantial<br />

reduction<br />

from 2008<br />

Test with<br />

w<strong>in</strong>d screens<br />

for further<br />

reduction<br />

56


Environment:<br />

well perform<strong>in</strong>g waste water treatment<br />

§ All site waters (process water, cool<strong>in</strong>g water, ra<strong>in</strong><br />

water, spr<strong>in</strong>kl<strong>in</strong>g waters,…) are treated; there is no direct dra<strong>in</strong> away to<br />

the River Scheldt.<br />

§ 2/3 of all treated water is reused <strong>in</strong> the plant<br />

§ Emission standards are largely observed<br />

50<br />

45<br />

40<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

Concentrations <strong>in</strong> % of emission standard<br />

93 94 95 96 97 98 99 00 01 02 03 04 05<br />

Pb Cd Cu NO2+NO3<br />

57


Environment:<br />

contribution to “Kyoto Protocol”<br />

3500<br />

3000<br />

2500<br />

2000<br />

1500<br />

1000<br />

500<br />

0<br />

2002 2003 2004 2005<br />

(budget)<br />

Energy Consumption (<strong>in</strong> TJ) Energy Recovery (<strong>in</strong> TJ)<br />

Energy Recovery (<strong>in</strong> %)<br />

12%<br />

10%<br />

8%<br />

6%<br />

4%<br />

2%<br />

0%<br />

§ UPMR strives to respect the climate<br />

change/CO 2 objectives:<br />

q Heat recover<strong>in</strong>g facilities at smelter, blast<br />

furncace and lead ref<strong>in</strong>ery.<br />

q Efficiency <strong>in</strong>crease at LEW.<br />

q Several improvement projects<br />

§ Covenant with the authorities with<br />

pledge to stay with<strong>in</strong> the world top for<br />

energy efficiency.<br />

58


Social responsability<br />

Soil remediation project <strong>in</strong> adjacent<br />

residential area “Moretusburg”:<br />

q Replacement of 30 cm of historical<br />

contam<strong>in</strong>ated soil by clean earth<br />

q 700 houses and public area<br />

q Activities will start <strong>in</strong> September 2006<br />

59


Social responsibility:<br />

communication and <strong>in</strong>formation<br />

§ Yearly environmental report, distributed on 7,000 copies<br />

§ Yearly <strong>in</strong>formation session to <strong>in</strong>habitants<br />

§ Consultation Committee with representatives of residentials and<br />

authorities<br />

§ Free telephone number 7/7 and 24/24<br />

§ Visits, open house, …<br />

§ Special <strong>in</strong>formation efforts for soil remediation project of Moretusburg<br />

60


Rehabilitation of historically polluted areas<br />

After 6 mio € clean-up costs: 2001 ><br />

< 1998: Before the clean-up<br />

61


Health & safety<br />

43<br />

38<br />

33<br />

28<br />

23<br />

18<br />

Lead <strong>in</strong> blood [µg/dl]<br />

40 = norm UPMR<br />

95 96 97 98 99 00 01 02 03 04 05<br />

UPMR cont<strong>in</strong>uously improves its occupational<br />

health & safety performance<br />

§ Occupational health monitor<strong>in</strong>g:<br />

q Bio-monitor<strong>in</strong>g<br />

q Workplace analysis<br />

q Vacc<strong>in</strong>ation<br />

§ Health:<br />

q Own medical service<br />

q Reduction program for lead <strong>in</strong> blood of<br />

employees<br />

§ Comfort:<br />

q Ergonomics<br />

q Advice & tra<strong>in</strong><strong>in</strong>g for use of computers<br />

§ Well-be<strong>in</strong>g:<br />

q Alcohol & drug policy / smok<strong>in</strong>g policy<br />

q Stress management<br />

62


Health & safety<br />

1,6<br />

1,4<br />

1,2<br />

1<br />

0,8<br />

0,6<br />

0,4<br />

0,2<br />

0<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

Severity<br />

97 98 99 00 01 02 03 04 05<br />

Frequency<br />

97 98 99 00 01 02 03 04 05<br />

UPMR has a safety policy focussed on three ma<strong>in</strong> areas:<br />

1. Technique:<br />

- Risk analysis of <strong>in</strong>stallations (via HAZOP:<br />

Hazard & Operability Study)<br />

- Identification & follow up of critical components.<br />

- Reliability of safety circles (via SIL:<br />

Safety Integrated Level)<br />

- Fire & explosion restriction (via ATEX:<br />

Atmosphères Explosives)<br />

2. Organization:<br />

Set up & audit of safety procedures (contractors,<br />

licenses, …).<br />

3. Human:<br />

Sensitivity & motivation of all employees <strong>in</strong> order<br />

to work <strong>in</strong> a safe environment.<br />

63


A Total Quality approach<br />

Our Total Quality system is driven by the<br />

European Foundation of Quality Management<br />

(EFQM) model. The EFQM approach is<br />

formalized <strong>in</strong> one <strong>in</strong>tegrated management<br />

system certified aga<strong>in</strong>st <strong>in</strong>ternational<br />

standards.<br />

§ Environmental care system certified<br />

accord<strong>in</strong>g to ISO14001: “… very well<br />

designed and implemented …”<br />

§ ISO 9001: Quality management.<br />

§ Safety certificate OSHAS 18001: due for<br />

October 2006.<br />

64


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

65


www.preciousmetals.umicore.com<br />

www.electronicscrap.umicore.com<br />

www.autocatalyst-recycl<strong>in</strong>g.umicore.com<br />

www.<strong>in</strong>dustrialcatalyst-recycl<strong>in</strong>g.umicore.com


Electronic Scrap Recycl<strong>in</strong>g<br />

www.electronicscrap.umicore.com<br />

67


Recycl<strong>in</strong>g is more complex than it appears on the<br />

1st look: Several cha<strong>in</strong> l<strong>in</strong>ks have to cooperate<br />

E-scrap<br />

Collection<br />

Dismantl<strong>in</strong>g<br />

Preprocess<strong>in</strong>g<br />

Separated components & fractions<br />

Materials<br />

recovery<br />

Recycled<br />

metals/<br />

elements<br />

reuse<br />

Handl<strong>in</strong>g of<br />

f<strong>in</strong>al waste<br />

• The entire cha<strong>in</strong> has to be considered. All steps are closely <strong>in</strong>terl<strong>in</strong>ked.<br />

• Dismantl<strong>in</strong>g & preprocess<strong>in</strong>g (often called „recycl<strong>in</strong>g“ by itself) is important, but only<br />

an <strong>in</strong>termediate step.<br />

• Endprocess<strong>in</strong>g (physical materials recovery) is a crucial step <strong>in</strong> value generation &<br />

toxic control.<br />

• Reuse is only an <strong>in</strong>terim solution and f<strong>in</strong>ally will lead to EOL-material.<br />

• In every process some f<strong>in</strong>al waste streams will occur, they have to be considered<br />

both <strong>in</strong> the environmental and economic process evaluation.<br />

68


E-waste: structure of recycl<strong>in</strong>g cha<strong>in</strong> and<br />

potential losses<br />

typical numbers of participants per country<br />

some 1.000<br />

(local)<br />

some 100 (local)<br />

Ma<strong>in</strong>ly<br />

Some 10 locally<br />

(partly <strong>in</strong>ternational)<br />

< 5 globally<br />

(3 <strong>in</strong> Europe)<br />

Entire EOL-devices<br />

Collection<br />

Sort<strong>in</strong>g/dismantl<strong>in</strong>g/component pick<strong>in</strong>g<br />

Ma<strong>in</strong>ly<br />

globally<br />

Large scale metallurgical<br />

& chemical technologies<br />

Stripped equipment & components<br />

Mechanical preprocess<strong>in</strong>g<br />

Circuit boards & highly<br />

complex materials<br />

Complex metals<br />

ref<strong>in</strong><strong>in</strong>g<br />

Magnitude of losses <strong>in</strong> materials and value<br />

Not collected<br />

Landfill, <strong>in</strong>c<strong>in</strong>eration<br />

or other losses<br />

Lost <strong>in</strong> sidestreams<br />

and wrong fractions<br />

(e.g. Au <strong>in</strong> Al-fraction)<br />

Transfer <strong>in</strong> slags or<br />

other sidestreams<br />

69


Significant losses of valuable raw materials still<br />

occur due to non-collection and exports to Asia<br />

About 40% of WEEE from<br />

Europe (on all levels) is<br />

exported, ma<strong>in</strong>ly to Asia, and<br />

treated <strong>in</strong> the <strong>in</strong>formal sector*<br />

Bulk collected<br />

(white, brown,<br />

grey):<br />

≈ 1,200 kt/y<br />

Total EOL-Waste Electronical<br />

and Electronic Equipment<br />

(WEEE) ≈ 5,000 kt/y <strong>in</strong> the EU<br />

Dismantl<strong>in</strong>g<br />

Pre-process<strong>in</strong>g<br />

Collection (communities,<br />

schemes, others)<br />

... Of which bulk<br />

with circuit boards<br />

≈ 450 kt/y<br />

Integrated metal<br />

smelters & ref<strong>in</strong>ers<br />

Precious Metals<br />

bear<strong>in</strong>g WEEE-parts:<br />

» 45 kt/y<br />

Total amount of Waste Electrical and Electronic Equipment ( WEEE) <strong>in</strong> the EU: » 5 million t/y (14 kg/person) but:<br />

- only some 25% of WEEE is collected so far<br />

- if collected, a substantial part is exported to Asia & Africa (ma<strong>in</strong>ly computers and telecommunication scrap)<br />

- white goods – free of precious metals (PM) - represent biggest quantity of WEEE-collected<br />

- only grey goods and brown goods bear PM’s and are of <strong>in</strong>terest for <strong>in</strong>tegrated metal smelters & ref<strong>in</strong>ers<br />

- WEEE usually requires adequate pre-process<strong>in</strong>g to separate it <strong>in</strong>to different fractions<br />

- PM-bear<strong>in</strong>g fractions <strong>in</strong> grey and brown goods only make up 5 – 10 % of the total weight.<br />

*exports often falsely labelled as<br />

„reuse“. Very low environmental<br />

standard and <strong>in</strong>efficient processes.<br />

Lack of control on exports and local<br />

operations.<br />

70


Material composition of e-scrap:<br />

not too sexy on a closer look<br />

E- scrap, a complex mix of:<br />

w Ag, Au, Pd, … (precious metals)<br />

w Cu, Al, Ni, Sn, Zn, Fe, … (base metals)<br />

w Hg, Be, Pb, Cd, As, Sb, Bi, … (metals of concern!)<br />

w Halogens (Br, F, Cl, ...)<br />

w combustibles (plastics)<br />

high risk of environmental damage if landfilled or if not treated<br />

<strong>in</strong> an environmentally sound way<br />

e-scrap conta<strong>in</strong>s valuable metals & resources and as such<br />

represents a true surface m<strong>in</strong>e, which must not be wasted<br />

Most toxic & most valuable metals are conta<strong>in</strong>ed <strong>in</strong> the circuit boards<br />

71


Examples: Material composition of<br />

circuit boards and some small<br />

electrical devices<br />

TV-boards<br />

Cu<br />

10%<br />

Calculator (without battery)<br />

Fe<br />

3%<br />

Al<br />

10%<br />

Al<br />

5%<br />

Others<br />

18%<br />

Plastics conta<strong>in</strong> halogenated<br />

flame retardants and/or Sb<br />

Cu<br />

3%<br />

Glass<br />

13%<br />

Ag [ppm] 280<br />

Au [ppm] 17<br />

Pd [ppm] 10<br />

Ni [%] 0,3<br />

Pb [%]<br />

Sn [%]<br />

1,0<br />

1,4 PC-boards<br />

Others<br />

15%<br />

Fe<br />

28%<br />

Plastics<br />

28%<br />

Glass<br />

6%<br />

Ag [ppm] 260<br />

Au [ppm] 50<br />

Pd [ppm] 5<br />

Ni [%] 0,5<br />

Pb [%] 0,1<br />

Sn [%] 0,2<br />

Plastics<br />

61%<br />

Others<br />

27%<br />

Cu<br />

20%<br />

Al<br />

5%<br />

Cell Phone 1999<br />

Cu<br />

13%<br />

Others<br />

22%<br />

Al<br />

1% Fe<br />

5%<br />

Glass<br />

2%<br />

Note: <strong>in</strong>dicative numbers only; value can differ significantly also with<strong>in</strong> one category!<br />

Ag [ppm] 1000<br />

Au [ppm] 250<br />

Pd [ppm] 110<br />

Ni [%] 1<br />

Pb [%] 1,5<br />

Sn [%] 2,9<br />

Fe<br />

7%<br />

Plastics<br />

23%<br />

Glass<br />

18%<br />

Ag [ppm] 1340<br />

Au [ppm] 350<br />

Pd [ppm] 210<br />

Ni [%] 0,1<br />

Pb [%] 0,3<br />

Sn [%] 0,5<br />

Plastics<br />

57%<br />

72


Plastics & steel contribute most to the weight, but<br />

precious metals usually dom<strong>in</strong>ate the material<br />

content value<br />

Note: <strong>in</strong>dicative numbers only; value can differ significantly also with<strong>in</strong> one category!<br />

weight-% plastics Fe Al Cu Ag [ppm] Au [ppm] Pd [ppm]<br />

TV-board 28% 28% 10% 10% 280 20 10<br />

PC-board 23% 7% 5% 20% 1000 250 110<br />

mobile phone 56% 5% 1% 13% 1380 350 210<br />

calculator 61% 4% 5% 3% 260 50 5<br />

value-share Fe Al Cu Ag Au Pd sum PM<br />

TV-board 4% 12% 43% 7% 27% 7% 41%<br />

PC-board 0% 1% 15% 4% 68% 12% 84%<br />

mobile phone 0% 0% 7% 4% 71% 18% 93%<br />

calculator 0% 6% 11% 6% 74% 3% 83%<br />

70%<br />

A high recovery of precious metals (PM) is crucial for maximis<strong>in</strong>g value<br />

return. Any PM-losses <strong>in</strong> dismantl<strong>in</strong>g and preprocess<strong>in</strong>g should be<br />

avoided, and metallurgical ref<strong>in</strong><strong>in</strong>g processes must show high recovery<br />

efficiencies and a well controlled handl<strong>in</strong>g of hazardous substances.<br />

73


Metal prices can be extremely volatile and heavily<br />

impact the <strong>in</strong>tr<strong>in</strong>sic metal value of e-scrap<br />

USD / tonne<br />

4500<br />

4000<br />

3500<br />

3000<br />

2500<br />

2000<br />

1500<br />

1000<br />

500<br />

1985<br />

1986<br />

USD / troz<br />

1987<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

Cu<br />

0<br />

1988<br />

1989<br />

1990<br />

1991<br />

1992<br />

Pd<br />

1993<br />

1994<br />

1995<br />

1996<br />

88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05<br />

1997<br />

1998<br />

1999<br />

2000<br />

2001<br />

2002<br />

2003<br />

2004<br />

2005<br />

USD/troz<br />

US cents/troz<br />

500<br />

450<br />

400<br />

350<br />

300<br />

250<br />

800<br />

750<br />

700<br />

650<br />

600<br />

550<br />

500<br />

450<br />

400<br />

350<br />

300<br />

1988<br />

1988<br />

1989<br />

1989<br />

1990<br />

1991<br />

Ag<br />

1990<br />

1991<br />

Au<br />

1992<br />

1992<br />

1993<br />

1993<br />

1994<br />

1994<br />

1995<br />

1995<br />

1996<br />

1996<br />

1997<br />

1997<br />

1998<br />

1998<br />

1999<br />

1999<br />

2000<br />

2000<br />

2001<br />

2001<br />

2002<br />

2002<br />

2003<br />

2003<br />

2004<br />

2004<br />

2005<br />

2005<br />

74


Some observations and conclusions<br />

• Toxic or other harmful substances are usually concentrated <strong>in</strong> the circuit<br />

boards, the same applies for the material content value.<br />

• Any major loss of precious metals (PM) decreases drastically the net<br />

recoverable value from electronic goods.<br />

• Material composition can have a significant impact on recycl<strong>in</strong>g<br />

requirements and adequate technical processes (<strong>in</strong>cl. emission control).<br />

• Mix<strong>in</strong>g different qualities <strong>in</strong> collection/preprocess<strong>in</strong>g can negatively<br />

<strong>in</strong>fluence recycl<strong>in</strong>g returns (dilution, technical constra<strong>in</strong>ts).<br />

• Legislation impacts material composition (and recycl<strong>in</strong>g requirements),<br />

e.g. ROHS → ban on Pb, <strong>in</strong>stead more Sn, Cu, Bi, Ag.<br />

• M<strong>in</strong>iaturisation & technological progress impact material composition.<br />

Tendency of decrease of absolute precious metals content <strong>in</strong> new models<br />

(m<strong>in</strong>iaturisation), but relative PM-% (per tonne) often more stable.<br />

• New products can br<strong>in</strong>g new compositions (e.g. MP 3 players, digital<br />

cameras).<br />

• New product generations can drastically change recycl<strong>in</strong>g requirements<br />

(e.g. CRT glass → flat screens; video recorders → DVD recorders).<br />

75


Electronic scrap <strong>in</strong> a global environment<br />

• Today, large quantities of old cell phones, computers and other IT-equipment are<br />

exported from Europe, North-America and Japan to Asia and <strong>in</strong>creas<strong>in</strong>gly also to<br />

Africa.<br />

• Many of these exports are falsely labelled as “reuse” (to circumvent restrictions<br />

on waste exports). Controls of real physical streams are low.<br />

• Every reuse is a temporary solution only and f<strong>in</strong>ally will lead to electronic-scrap<br />

that needs to be recycled.<br />

• Recycl<strong>in</strong>g requires awareness, an adequate <strong>in</strong>frastructure and some m<strong>in</strong>imum<br />

technology & experience. If this is not available, exports of electronics even for<br />

”real reuse” <strong>in</strong> such regions can be environmentally counterproductive.<br />

• More control and enforcement is needed to make sure that such exports are<br />

really recycled <strong>in</strong> the import<strong>in</strong>g country under high ESM standards.<br />

• Small scale, “backyard” metals recovery from computer scrap us<strong>in</strong>g open sky<br />

<strong>in</strong>c<strong>in</strong>eration and acid stripp<strong>in</strong>g methods release toxic<br />

substances while yield<strong>in</strong>g only low metal recoveries.<br />

They impose considerable damage to the environment<br />

and the health of local workers and neighbourhood.<br />

• Transparency of material flows until the f<strong>in</strong>al dest<strong>in</strong>ation is a key element.<br />

76


Sampl<strong>in</strong>g of electronic scrap at Umicore<br />

Example: the value of circuit<br />

boards can differ significantly:<br />

high grade: Au > 400 g/t<br />

medium grade Au 200 - 400 g/t<br />

low grade Au 100 - 200 g/t<br />

very low grade Au < 100 g/t<br />

Other precious metals conta<strong>in</strong>ed: Ag, Pd, (Pt)<br />

77


Digest<strong>in</strong>g the element cocktail <strong>in</strong> a complex<br />

separation process, us<strong>in</strong>g a unique metallurgy<br />

...<br />

Zn Ir HC Rh Fe<br />

Hg Pt Ni SiO2 Te Se<br />

Ru<br />

AgCo<br />

Au Cu<br />

As<br />

Pb<br />

S Bi Sn Pd<br />

Sb C Cd In Al2O3 Clean off gas Clean waste water<br />

Sulfuric<br />

Acid<br />

Base & Special Metals<br />

Pb, Cu, Ni,<br />

Sb, Sn, Bi, Se, In, Te, As<br />

Umicore Process<br />

Recovery of<br />

Metals & Energy<br />

Precious Metals<br />

Ag, Au,<br />

Pt, Pd, Rh, Ir, , Ru ,<br />

Dykefill<br />

Betogr<strong>in</strong>d<br />

… to turn a difficult feed systematically <strong>in</strong>to<br />

recycled, useful products, while safely<br />

recover<strong>in</strong>g or isolat<strong>in</strong>g toxic substances<br />

Controlled<br />

depot<br />

In<br />

Bi<br />

Ag<br />

Pb<br />

Sn<br />

Au<br />

Te<br />

Pd<br />

Cu<br />

Sb<br />

As<br />

Se<br />

Pt<br />

Ni<br />

Ir<br />

Rh<br />

Ru<br />

78


Umicore’s IsaSmelt process can efficiently cope<br />

with complex mixes of metals and plastics.<br />

Stack<br />

Bag<br />

house<br />

filter<br />

Monthly<br />

measurement of<br />

dust, metals,<br />

SO 2 , NO X , CO,<br />

C tot<br />

Filter dust Dust<br />

HygienicIsaSmelt<br />

Process Radiation<br />

gasses furnace gasses chambre<br />

Heat recovery:<br />

High pressure<br />

steam for <strong>in</strong>ternal<br />

use<br />

Adiabatic<br />

cooler<br />

Electrostatic<br />

precipitator<br />

Quench<strong>in</strong>g<br />

Water to Water<br />

Treatment Plant<br />

Sulphuric<br />

Acid<br />

Plant<br />

Stack<br />

Cont<strong>in</strong>uous<br />

measurement<br />

of SO 2 , NO X<br />

Cont<strong>in</strong>uous<br />

sampl<strong>in</strong>g for<br />

diox<strong>in</strong><br />

detection<br />

Periodic<br />

measurement of<br />

dust, metals,<br />

H 2 SO 4 , NO X , CO,<br />

C tot, , HF, HCl<br />

Plastics <strong>in</strong> the smelter feed can partially substitute<br />

coke & fuel (feedstock recycl<strong>in</strong>g), an extensive offgas<br />

treatment safely prevents any emission of diox<strong>in</strong>es.<br />

79


The scope for recycl<strong>in</strong>g optimisation is the<br />

entire WEEE recycl<strong>in</strong>g cha<strong>in</strong><br />

WEEE<br />

maximise<br />

ecoefficiency<br />

awareness<br />

optimise<br />

environmental<br />

balance<br />

optimise<br />

economical<br />

balance<br />

Process technologies<br />

Material composition<br />

Information/<br />

communication<br />

Bus<strong>in</strong>ess ethics<br />

legislation<br />

Reuse,<br />

Recycled materials,<br />

energy recovery<br />

w maximise material recycl<strong>in</strong>g (ga<strong>in</strong> 1)<br />

w m<strong>in</strong>imise environmental damage (burden)<br />

w consider environmental f<strong>in</strong>gerpr<strong>in</strong>t of material (ga<strong>in</strong> 2)<br />

(Fe < Al < Au)<br />

w maximise revenues from material recycl<strong>in</strong>g<br />

w m<strong>in</strong>imise total recycl<strong>in</strong>g costs (<strong>in</strong>cl. sidestreams)<br />

80


Interface optimisation to cope with technical<br />

conflicts <strong>in</strong> metal recycl<strong>in</strong>g<br />

Dismantl<strong>in</strong>g<br />

& preprocess<strong>in</strong>g<br />

Concentration rate* %<br />

Smelt<strong>in</strong>g &<br />

ref<strong>in</strong><strong>in</strong>g<br />

Investigate<br />

for optimisation<br />

The “concentration dilemma”<br />

e.g. separat<strong>in</strong>g Cu + PM<br />

from feed <strong>in</strong>to own fraction<br />

Recovery rate %<br />

* <strong>in</strong> output stream<br />

highest value & environmental impact for WEEE:<br />

circuit boards with Au, Pd, Ag, Cu, (special metals)<br />

=> m<strong>in</strong>imise total cha<strong>in</strong> losses of these metals<br />

<strong>in</strong>tegrated smelters recover Cu, PM, NF- & special metals,<br />

but Al is lost<br />

Al-smelters recover Al, but Cu & PM are lost<br />

all (NF-) metals are lost <strong>in</strong> landfill, <strong>in</strong>c<strong>in</strong>eration, plastic<br />

recycl<strong>in</strong>g and steel plants<br />

For complex, <strong>in</strong>tensely <strong>in</strong>terl<strong>in</strong>ked „high grade“ materials, metallurgical<br />

processes offer advantages over mechancial separation <strong>in</strong> efficiently<br />

extract<strong>in</strong>g precious & special metals as well as toxics<br />

81


Avoid deep mechanical treatment of<br />

“high grade” materials<br />

PM-loss %<br />

Fe Al<br />

Recovery rate per<br />

plastics<br />

<strong>in</strong>dividually separated material %<br />

100% 100% 100%<br />

Every separation step bears the risk of coseparat<strong>in</strong>g<br />

(los<strong>in</strong>g) precious metals. This can<br />

add up to significant PM-losses.<br />

Accept<strong>in</strong>g higher impurities of Fe, Al and<br />

plastics <strong>in</strong> the Cu/PM-fraction generated <strong>in</strong><br />

pre-process<strong>in</strong>g can boost the overall precious<br />

metal recovery and thus the generated value.<br />

High & medium grade boards, mobile phone<br />

handsets etc. should directly enter <strong>in</strong>to an<br />

efficient, <strong>in</strong>tegrated metals smelter process.<br />

Plastics conta<strong>in</strong>ed there<strong>in</strong> can be utilised as<br />

coke substitute (feedstock recycl<strong>in</strong>g).<br />

Mutual <strong>in</strong>terface optimisations by pre-processors and <strong>in</strong>tegrated smelters<br />

leads to w<strong>in</strong>/w<strong>in</strong>-situations and an <strong>in</strong>creased eco-efficiency<br />

82


F<strong>in</strong>d out the right w<strong>in</strong>dow of optimisation<br />

between preprocess<strong>in</strong>g and smelt<strong>in</strong>g/ref<strong>in</strong><strong>in</strong>g<br />

Costs<br />

Area of optimisation<br />

smelt<strong>in</strong>g costs<br />

preprocess<strong>in</strong>g costs (<strong>in</strong>cl. landfill)<br />

Preprocess<strong>in</strong>g Intensity<br />

precious<br />

metal losses<br />

83


Impact of metal losses along the<br />

recycl<strong>in</strong>g cha<strong>in</strong><br />

USD/t<br />

8000<br />

7000<br />

6000<br />

5000<br />

4000<br />

3000<br />

2000<br />

1000<br />

0<br />

TVboards<br />

PCboards<br />

cellphone<br />

1999<br />

cordless<br />

phone<br />

Metal prices for calculation (Oct. 2005, rounded)<br />

Ag $/troz 7,4 = $/kg 238<br />

Au $/troz 460 = $/kg 14789<br />

Pd $/troz 190 = $/kg 6109<br />

Cu $/mt 4000 = $/kg 4,00<br />

Al $/mt 1100 = $/kg 1,10<br />

Fe $/mt 140 = $/kg 0,14<br />

* gross metal value without consider<strong>in</strong>g<br />

any losses dur<strong>in</strong>g recycl<strong>in</strong>g nor any<br />

recycl<strong>in</strong>g costs. The more efficient the<br />

recycl<strong>in</strong>g cha<strong>in</strong> is, the more of this value<br />

can be recovered → net value.<br />

Fe<br />

Al<br />

Cu<br />

Pd<br />

Au<br />

Ag<br />

Assumption: loss of 20% of Ag, Au, Pd, Cu, Al, Fe<br />

Note: <strong>in</strong>dicative numbers only; value can differ significantly also with<strong>in</strong> one category!<br />

gross <strong>in</strong>tr<strong>in</strong>sic<br />

value*<br />

value share per metal<br />

USD/tonne Ag/Au/Pd Cu Al Fe<br />

TV boards 900 41% 43% 12% 4%<br />

PC-boards 5400 84% 15% 1% 0%<br />

cell phones 6400 93% 7% 0% 0%<br />

metal loss<br />

20% total loss loss per metal <strong>in</strong> USD / tonne<br />

USD/tonne Ag/Au/Pd Cu Al Fe<br />

TV boards 180 74 77 22 7<br />

PC-boards 1080 907 162 11 0<br />

cell phones 1280 1190 90 0 0<br />

For many electronic devices, los<strong>in</strong>g Al or Fe has only a marg<strong>in</strong>al impact on net<br />

value. Highest attention has to be placed on avoid<strong>in</strong>g losses of precious metals!<br />

84


How realistic is a 20% (precious) metal<br />

loss along the e-scrap recycl<strong>in</strong>g cha<strong>in</strong> ?<br />

E-scrap / circuit boards - a highly complex material, especially valid with respect to<br />

precious metals distribution.<br />

Occurrence of PMs with:<br />

• metallics: contacts, connector, solders, hard disk drives,...<br />

• ceramics: Multi layer capacitors (MLCC), ICs, hybrid ceramics, ...<br />

• plastics: ICs, PCB-tracks, <strong>in</strong>ter-board layers, ...<br />

→ Most of the PM conta<strong>in</strong><strong>in</strong>g parts on circuit boards and small devices (cell phones etc.) are<br />

closely <strong>in</strong>terl<strong>in</strong>ked with one another and PMs are highly dissem<strong>in</strong>ated.<br />

→ Shredd<strong>in</strong>g cannot really liberalise the different materials/metals. Shredded parts still are a<br />

partial mix of plastics, Fe, Al, Cu and PMs.<br />

→ Sort<strong>in</strong>g of these shredded parts by traditional separation technics (magnetic, eddy current,<br />

etc.) leads automatically to often substantial losses of PMs <strong>in</strong> the Fe-, Al-or plastic fractions.<br />

→ F<strong>in</strong>e shredd<strong>in</strong>g can improve the liberalisation but generates even more dust which is difficult<br />

to handle and also carries PM.<br />

If circuit boards or small devices are preprocessed by shredd<strong>in</strong>g & sort<strong>in</strong>g, a loss of 20% PMs<br />

is realistic, also higher losses do occur.<br />

If shredd<strong>in</strong>g cannot be avoided (low grade materials), a coarse shredd<strong>in</strong>g process followed by<br />

manual or optical sort<strong>in</strong>g could be a valid alternative.<br />

85


Example:<br />

Eco-efficiency of mobile phone recycl<strong>in</strong>g<br />

The „direct smelter route“ was proven<br />

to be the most eco-efficient solution<br />

(source: J. Huisman, TU Delft)<br />

Environmental weight: how much<br />

environmental impact/burden by<br />

produc<strong>in</strong>g 1 kg of a metal?<br />

86


An example for Umicore’s solution<br />

for complex materials recycl<strong>in</strong>g<br />

Umicore output<br />

Recovered as<br />

metal<br />

Chemical use<br />

as process<br />

additive<br />

Transfer <strong>in</strong>to<br />

an <strong>in</strong>ert slag<br />

(product)<br />

Neutralised<br />

<strong>in</strong> effluents<br />

Isolation and<br />

safe deposit<br />

87


Some observations and conclusions<br />

• Dismantl<strong>in</strong>g, mechanical preprocess<strong>in</strong>g and smelt<strong>in</strong>g/ref<strong>in</strong><strong>in</strong>g of e-scrap are<br />

highly <strong>in</strong>terdependent.<br />

• Interface optimisation is needed to m<strong>in</strong>imise value losses (= PM-losses).<br />

Metallurgical liberalisation and sort<strong>in</strong>g (=smelt<strong>in</strong>g) is a valid alternative to deep<br />

mechanical preprocess<strong>in</strong>g of circuit boards and small “high grade” devices.<br />

• Economies of scale are the more important the more one goes downstream <strong>in</strong><br />

the recycl<strong>in</strong>g cha<strong>in</strong>.<br />

• State-of-the-art technology requires considerable <strong>in</strong>vestments <strong>in</strong> equipment,<br />

process and <strong>in</strong>frastructure, aga<strong>in</strong> the higher the more downstream it is.<br />

• Specialisation and expertise is key to a successful operation. Investment risks<br />

and technical risks are high.<br />

• An (<strong>in</strong>ternational) share of labour has<br />

resulted thereof, emphasis<strong>in</strong>g <strong>in</strong>dividual<br />

core competencies. While collection,<br />

dismantl<strong>in</strong>g, preprocess<strong>in</strong>g usually takes<br />

place on a national/regional level, smelt<strong>in</strong>g<br />

& ref<strong>in</strong><strong>in</strong>g is conducted globally by a<br />

handful of specialised companies.<br />

Ma<strong>in</strong>ly<br />

locally<br />

Sort<strong>in</strong>g/dismantl<strong>in</strong>g/component pick<strong>in</strong>g<br />

Ma<strong>in</strong>ly<br />

globally<br />

Large scale metallurgical<br />

& chemical technologies<br />

Collection<br />

Entire EOL-devices<br />

Stripped equipment & components<br />

Mechanical preprocess<strong>in</strong>g<br />

Circuit boards & highly<br />

complex materials<br />

Complex metals<br />

ref<strong>in</strong><strong>in</strong>g<br />

88


It needs a global network of partners ...<br />

... to offer much more than just technical solutions.<br />

We <strong>in</strong>vite other market participants to jo<strong>in</strong> us <strong>in</strong> the development of<br />

appropriate measures to further <strong>in</strong>crease recycl<strong>in</strong>g efficiency, promot<strong>in</strong>g<br />

best-practice quality standards and environmentally sound operations.<br />

89


Conclusion<br />

• Integrated smelters offer unique, eco-efficient possibilities to recover precious, base<br />

and special metals, while us<strong>in</strong>g organic residues as substitute for coke & fuel, and<br />

safely handl<strong>in</strong>g toxic elements. Sufficient capacity is available.<br />

• For such plants high <strong>in</strong>vestments, state-of-the-art technology and extensive efforts <strong>in</strong><br />

offgas- & waste water treatment are required. Umicore’s Hoboken plant has been<br />

developed to the most advanced processor of precious metals conta<strong>in</strong><strong>in</strong>g WEEE.<br />

• Not any „copper smelter“ can treat e-scrap - only a handful of <strong>in</strong>tegrated smelters<br />

worldwide have all the necessary <strong>in</strong>stallations.<br />

• Integrated smelters can contribute significantly to further optimise the WEEE recycl<strong>in</strong>g<br />

cha<strong>in</strong>, <strong>in</strong> close cooperation with pre-processors (<strong>in</strong>terface optimisation).<br />

• Grow<strong>in</strong>g exports of WEEE and its fractions are a threat to the European recycl<strong>in</strong>g<br />

<strong>in</strong>dustry - valuable recourses are lost and often exported materials are treated <strong>in</strong><br />

environmentally non-compliant ways.<br />

• Future availabilties of e-scrap <strong>in</strong> Europe will be much lower than expected due to large<br />

WEEE-export streams to Asia and Africa.<br />

• Monitor<strong>in</strong>g & control of material streams, transparency and bus<strong>in</strong>ess ethics are key.<br />

90


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

91


Spent Auto Catalysts Recycl<strong>in</strong>g<br />

www.autocatalyst-recycl<strong>in</strong>g.umicore.com<br />

92


Spent automotive catalysts: Scope<br />

Umicore Precious Metals Ref<strong>in</strong><strong>in</strong>g has been active <strong>in</strong> spent<br />

autocatalyst recovery for many years.<br />

It is currently process<strong>in</strong>g material from all over the world.<br />

Transactions may imply “as is” purchase or toll ref<strong>in</strong><strong>in</strong>g.<br />

A state-of-the-art weigh<strong>in</strong>g and sampl<strong>in</strong>g comb<strong>in</strong>ed with a<br />

unique smelt<strong>in</strong>g and ref<strong>in</strong><strong>in</strong>g process guarantees optimum yield<br />

to the supplier.<br />

Additional services such as forward pric<strong>in</strong>g, f<strong>in</strong>anc<strong>in</strong>g etc can<br />

be offered as well.<br />

93


Some history<br />

For more than 20 years, Umicore Precious Metals has been active <strong>in</strong><br />

the recovery of autocatalysts from North America, where the first<br />

mandatory use of catalytic converters was implemented <strong>in</strong> 1975.<br />

S<strong>in</strong>ce 1991, Umicore’s supply also <strong>in</strong>cludes material from its own<br />

subsidiary, Umicore Bowden (Cov<strong>in</strong>gton, TN).<br />

In Europe, first volumes showed up at the end of the 80ies<br />

(Germany, Scand<strong>in</strong>avia) and have cont<strong>in</strong>uously grown s<strong>in</strong>ce<br />

then.<br />

By the late n<strong>in</strong>eties, volumes have started to emerge from<br />

other cont<strong>in</strong>ents as well.<br />

94


Modes of operation<br />

or<br />

“AS IS” basis<br />

= outright sale of converters or monolith material<br />

(per piece, per kg, …)<br />

“ASSAY” basis<br />

= precious metal recovery on toll ref<strong>in</strong><strong>in</strong>g transaction<br />

95


“AS IS” - Fundamentals<br />

Pric<strong>in</strong>g (spot) per unit converter or unit weight,<br />

as a function of estimated weight of monolith,<br />

precious metal assay,<br />

precious metal prices,<br />

costs.<br />

In practice, use of a regularly updated price list, with<br />

or without brand/size/type differentiation.<br />

96


“AS IS” - Pros and Cons<br />

+ Very simple formula: price/unit<br />

+ Easy adm<strong>in</strong>istration<br />

+ Immediate payment: no fluid assets problems<br />

+ No price risk<br />

+ No expertise necessary for sale of precious metals<br />

- The supplier has to develop an expertise on his own<br />

regard<strong>in</strong>g the quality of the various converters.<br />

- Little transparency: the supplier has no real idea of the<br />

different components <strong>in</strong>fluenc<strong>in</strong>g the price offered.<br />

- There is more than just the price ...<br />

97


“ASSAY” - Fundamentals<br />

Recovery of Pt, Pd, Rh on toll treatment :<br />

weigh<strong>in</strong>g / count<strong>in</strong>g+decann<strong>in</strong>g+weigh<strong>in</strong>g,<br />

crush<strong>in</strong>g,<br />

sampl<strong>in</strong>g,<br />

assay<strong>in</strong>g,<br />

allow<strong>in</strong>g actual determ<strong>in</strong>ation of Pt, Pd, Rh content.<br />

This is followed by credit to metal account,<br />

for subsequent account-to-account transfer,<br />

sale to Umicore Precious Metals,<br />

physical delivery,<br />

subject to payment of contractual process<strong>in</strong>g costs.<br />

98


“ASSAY” - Pros and Cons<br />

+ Transparency: customer knows the exact metal content and<br />

receives correspond<strong>in</strong>g return.<br />

+ Potential for highest yield: no cushion for cover<strong>in</strong>g aga<strong>in</strong>st<br />

quality and price risks, s<strong>in</strong>ce the settlement is based on the<br />

actual weight and precious metal assay.<br />

- Wait<strong>in</strong>g for metal credit means long f<strong>in</strong>anc<strong>in</strong>g period.<br />

- Market<strong>in</strong>g the precious metals requires some expertise.<br />

- Price risk until actual sale of the recovered metals, unless<br />

estimated metals content have been hedged.<br />

- More complicated formulas and adm<strong>in</strong>istration.<br />

99


Converter reception & decann<strong>in</strong>g<br />

Weigh<strong>in</strong>g (if required)<br />

Count<strong>in</strong>g<br />

Grad<strong>in</strong>g (full, half, empty)<br />

Sort<strong>in</strong>g (if required)<br />

Decann<strong>in</strong>g,<br />

with proper attention to safety and<br />

dust collection<br />

100


Weigh<strong>in</strong>g & Sampl<strong>in</strong>g<br />

Tailor-made, dedicated weigh<strong>in</strong>g<br />

and sampl<strong>in</strong>g l<strong>in</strong>e for broken<br />

honeycomb<br />

A thorough sampl<strong>in</strong>g procedure to<br />

guarantee maximum representativity<br />

of the reta<strong>in</strong>ed sample.<br />

Presence of customer representative<br />

or <strong>in</strong>dependent witness<br />

ISO 9001 certified<br />

Generally recognised as ‘first <strong>in</strong> class’<br />

Weigh<strong>in</strong>g<br />

Empty<strong>in</strong>g &<br />

separation of waste<br />

Shredder 6 mm<br />

< 6 mm<br />

Primary Sampler<br />

7 - 10%<br />

Secondary Sampler<br />

1 – 2%<br />

101


Process<br />

2<br />

1<br />

3<br />

Cu-smelter (1):<br />

collection of precious<br />

metals on Cu<br />

LEW (2):<br />

Leach<strong>in</strong>g and ElectroW<strong>in</strong>n<strong>in</strong>g of Cu<br />

Precious Metals ref<strong>in</strong>ery (3)<br />

High flexibility <strong>in</strong> terms of<br />

- quality (PGM, carrier, impurities)<br />

- quantity<br />

102


Spent autocatalyst operations with<strong>in</strong> UPMR<br />

Who<br />

Where 1<br />

Where 2<br />

Cycleon SA Asnières France X<br />

Contract<strong>in</strong>g<br />

Umicore Autocatalyst Recycl<strong>in</strong>g Belgium NV Hoboken Belgium X X<br />

Umicore Autocatalyst Recycl<strong>in</strong>g USA Cov<strong>in</strong>gton, TN USA X X<br />

Decann<strong>in</strong>g<br />

Umicore Autocatalyst Recycl<strong>in</strong>g GmbH Alzenau Germany X X<br />

UPMR Hanau (Umicore AG & Co KG) Hanau Germany X X<br />

UPMR Brasil (Umicore Brasil Ltda) Sao Paulo Brasil X X X<br />

UPMR Hoboken (Umicore NV) Hoboken Belgium X X X X<br />

W&S<br />

Smelt<strong>in</strong>g<br />

PGM Ref<strong>in</strong><strong>in</strong>g<br />

103


Umicore serves the complete PGM life-cycle<br />

PGM Compounds<br />

Precious Metal<br />

Management<br />

New Catalyst Production<br />

PGM Ref<strong>in</strong><strong>in</strong>g<br />

New Vehicle Production<br />

End of life Scrap<br />

Catalyst Collection<br />

104


Additional services<br />

Precious Metals Management :<br />

metal accounts<br />

geographical metal swaps<br />

leas<strong>in</strong>g (early metal outturn)<br />

purchase<br />

forward pric<strong>in</strong>g<br />

f<strong>in</strong>anc<strong>in</strong>g<br />

Assistance with <strong>in</strong>-bound shipp<strong>in</strong>g<br />

Global presence<br />

105


Conclusion: Why us ?<br />

General<br />

“AS IS”<br />

“ASSAY”<br />

Committed - Long term vision<br />

Flexible<br />

Reliable<br />

F<strong>in</strong>ancially stable<br />

Fair grad<strong>in</strong>g<br />

Fair price<br />

Transparent<br />

State-of-the-art weigh<strong>in</strong>g and sampl<strong>in</strong>g<br />

Best overall value<br />

106


Contact: Philippe Van Maele<br />

Manager Raw Materials Supply, Spent Catalysts<br />

address: Adolf Gre<strong>in</strong>erstraat 14<br />

2660 Hoboken<br />

Belgium<br />

Tel: +32 3 821.79.85<br />

Fax: + 32 3 821 78 07<br />

Mobile: +32 475 64.47.12<br />

e-mail: philippe.vanmaele@umicore.com


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

108


Spent Industrial catalysts Recycl<strong>in</strong>g<br />

www.<strong>in</strong>dustrialcatalyst-recycl<strong>in</strong>g.umicore.com<br />

109


Spent Industrial catalysts: Scope<br />

Umicore’s unique smelt<strong>in</strong>g and ref<strong>in</strong><strong>in</strong>g capabilities allow the<br />

recovery of precious metals from a wide variety of <strong>in</strong>dustrial<br />

spent catalysts.<br />

Its high flexibility makes it possible to cope with any type of<br />

carrier and with unregenerated catalysts, conta<strong>in</strong><strong>in</strong>g a high<br />

level of impurities.<br />

Additional services can be offered <strong>in</strong> the form of a package.<br />

110


Process<br />

2<br />

1<br />

3<br />

Cu-smelter (1):<br />

collection of precious metals on Cu<br />

LEW (2):<br />

Leach<strong>in</strong>g and Electrow<strong>in</strong>n<strong>in</strong>g of Cu<br />

Precious Metals ref<strong>in</strong>ery (3)<br />

High flexibility <strong>in</strong> terms of<br />

- quality (impurities, carriers, PM)<br />

- quantity<br />

111


Acceptable Spent Catalyst Properties<br />

Include<br />

A high presence of coke (no trashburn) and/or hydrocarbons<br />

Nuisance elements<br />

F<strong>in</strong>es<br />

Support balls<br />

by catalyst design, eg Cl -<br />

caused by process contam<strong>in</strong>ation, eg Fe, As<br />

Base metal catalyst fractions<br />

Any type of carrier<br />

112


Weigh<strong>in</strong>g & Sampl<strong>in</strong>g<br />

113


Weigh<strong>in</strong>g & Sampl<strong>in</strong>g<br />

A thorough sampl<strong>in</strong>g procedure to guarantee maximum<br />

representatively of the reta<strong>in</strong>ed sample.<br />

Presence of customer representative or <strong>in</strong>dependent<br />

witness<br />

No pretreatment losses<br />

ISO 9001 & ISO 14001 certified<br />

Generally recognised as ‘first <strong>in</strong> class’<br />

114


Additional Services<br />

Precious Metals Management:<br />

metal accounts<br />

Assistance with Transfrontier Movement of Waste<br />

Global presence<br />

geographical metal swaps<br />

leas<strong>in</strong>g possibilities (early metal outturn; bridge lease…)<br />

forward pric<strong>in</strong>g<br />

115


Conclusion<br />

Flexible<br />

complex multiple precious metal catalysts<br />

unscreened & unregenerated ‘polluted’ catalysts<br />

Process Reliability<br />

fast, efficient & representative sampl<strong>in</strong>g<br />

adequate assay<strong>in</strong>g<br />

possible to use umpire laboratory <strong>in</strong> case of discrepancies<br />

116


Conclusion<br />

F<strong>in</strong>ancial Reliability<br />

Service<br />

Competitive<br />

sound balance sheet<br />

long tradition<br />

a wide variety of precious metal related services<br />

117


Contact: Frank Bastenie<br />

Michel Verhelst<br />

Address: Adolf Gre<strong>in</strong>erstraat 14<br />

2660 Hoboken<br />

Belgium<br />

Tel: +32 3 821.74.13 / +32 3 821.73.06<br />

e-mail: frank.bastenie@umicore.com<br />

michel.verhelst@umicore.com


Industrial by-products<br />

Tankhouse slimes from the copper, lead and t<strong>in</strong> <strong>in</strong>dustry<br />

Dross, matte & speiss from the lead <strong>in</strong>dustry<br />

Lead sulphate and copper cement from the z<strong>in</strong>c <strong>in</strong>dustry<br />

Flue dust from the nickel and precious metals <strong>in</strong>dustry<br />

119


Our Core Bus<strong>in</strong>ess<br />

Sampl<strong>in</strong>g &<br />

Assay<strong>in</strong>g<br />

Metals Sales<br />

Recycl<strong>in</strong>g & Ref<strong>in</strong><strong>in</strong>g<br />

Raw Materials<br />

Supply<br />

Customer Support<br />

SUSTAINABLE<br />

DEVELOPMENT<br />

120


Tree Structure Bus<strong>in</strong>ess Presentation<br />

Level<br />

0.<br />

Umicore<br />

1.<br />

UPMR general &<br />

core bus<strong>in</strong>ess<br />

2.<br />

Sub bus<strong>in</strong>ess<br />

3.<br />

Details<br />

Byprod.<br />

1<br />

A. Supply<br />

Ind.<br />

cats<br />

Auto<br />

cats<br />

B. Sales<br />

Escrap<br />

1 1 1<br />

Homepage<br />

Explor<strong>in</strong>g Umicore<br />

Explor<strong>in</strong>g UPMR<br />

Our core bus<strong>in</strong>ess<br />

C. Customer<br />

Support<br />

D. Recycl<strong>in</strong>g<br />

& Ref<strong>in</strong><strong>in</strong>g<br />

Flow<br />

sheet 1<br />

E. Sampl<strong>in</strong>g<br />

& Assay<strong>in</strong>g<br />

F. Susta<strong>in</strong>able<br />

Development<br />

1 1 1<br />

1<br />

1 1<br />

PM<br />

2<br />

BM &<br />

SM 1<br />

Additional <strong>in</strong>fo<br />

121


Detailed structure Bus<strong>in</strong>ess Presentation (1)<br />

Base presentation<br />

(pages)<br />

1<br />

2 to 5<br />

6 to 7<br />

8 to 13<br />

14<br />

Sub presentation<br />

(pages)<br />

5.1 to 5.4<br />

Content<br />

Homepage<br />

Explor<strong>in</strong>g Umicore, part 1<br />

Additional <strong>in</strong>fo Umicore<br />

Explor<strong>in</strong>g Umicore, part 2<br />

Explor<strong>in</strong>g UPMR<br />

Pivot page “Core<br />

Bus<strong>in</strong>ess” for further<br />

presentation<br />

Comments<br />

By click<strong>in</strong>g on the “additional <strong>in</strong>fo” button of slide 5<br />

you will turn up at the additional <strong>in</strong>fo. Once this<br />

sub-presentation comes to an end you will arrive to<br />

part 2 of Explor<strong>in</strong>g Umicore.<br />

By click<strong>in</strong>g on the grey boxes of the specific<br />

presentations (and on the green text for Susta<strong>in</strong>able<br />

Development) you will turn up at right presentation.<br />

There is no particular order to follow <strong>in</strong> het choice<br />

of the presentations. Once a specific presentation<br />

comes to an end, you will automatically return to the<br />

122<br />

pivot page “Core Bus<strong>in</strong>ess”.


Detailed structure Bus<strong>in</strong>ess Presentation (2)<br />

Base presentation<br />

(pages)<br />

A1<br />

A2<br />

A3<br />

Sub presentation<br />

(pages)<br />

A. RAW MATERIAL SUPPLY<br />

A2.BP.1<br />

A2.IC.1-?<br />

A2.ES.1-?<br />

A2.AC.1-?<br />

Content<br />

Home page<br />

Types of raw materials<br />

Add. <strong>in</strong>fo By-products<br />

Add. <strong>in</strong>fo Industrial cats<br />

Add. <strong>in</strong>fo E-scrap<br />

Add. iInfo auto cats<br />

Supply distribution<br />

Comments<br />

By click<strong>in</strong>g on one of the pictures you will turn up at<br />

the right sub-presentation and automatically return<br />

to the pivot page “Core Bus<strong>in</strong>ess” once the specific<br />

presentation comes to an end.<br />

123


Detailed structure Bus<strong>in</strong>ess Presentation (3)<br />

Base presentation<br />

(pages)<br />

B. METALS SALES<br />

B1<br />

B2 to B3<br />

B4<br />

C1<br />

C2 – C4<br />

Sub presentation<br />

(pages)<br />

B3.PM.1-3<br />

B4.BM.1-3<br />

C. CUSTOMER SUPPORT<br />

Content<br />

Home page<br />

Precious Metals<br />

Add. <strong>in</strong>fo Precious Metals<br />

Base & Special Metals<br />

Add. Info Base & Special<br />

Metals<br />

Home page<br />

Info Customer Support<br />

Comments<br />

By click<strong>in</strong>g on the “additional <strong>in</strong>fo” button you will<br />

turn up at the specific presentation.<br />

By click<strong>in</strong>g on the “additional <strong>in</strong>fo” button you will<br />

turn up at the specific presentation.<br />

124


Detailed structure Bus<strong>in</strong>ess Presentation (4)<br />

Base presentation<br />

(pages)<br />

D1<br />

D2<br />

E1<br />

E2 – E6<br />

F1<br />

F2 – F10<br />

Sub presentation<br />

(pages)<br />

D. RECYCLING & REFINING<br />

D2.FS.1-6<br />

E. SAMPLING & ASSAYING<br />

F. SUSTAINABLE DEVELOPMENT<br />

Content<br />

Home page<br />

Flow sheet<br />

Add. <strong>in</strong>fo Flow sheet<br />

Home page<br />

Info Sampl<strong>in</strong>g & Assay<strong>in</strong>g<br />

Home page<br />

Info susta<strong>in</strong>able Development<br />

Comments<br />

By click<strong>in</strong>g on the “additional <strong>in</strong>fo” button you will<br />

turn up at the specific presentation. Be aware that<br />

you will not return to the flow sheet, but to the pivot<br />

page “Core Bus<strong>in</strong>ess”.<br />

125

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