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Status of 2G HTS Wire for Electric Power Applications - SuperPower

Status of 2G HTS Wire for Electric Power Applications - SuperPower

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superior per<strong>for</strong>mance. powerful technology.<br />

<strong>Status</strong> <strong>of</strong> <strong>2G</strong> <strong>HTS</strong> <strong>Wire</strong> <strong>for</strong> <strong>Electric</strong> <strong>Power</strong><br />

<strong>Applications</strong><br />

Drew Hazelton, Principal Engineer<br />

CIGRÉ SC D1 WG38 Workshop on High Temperature Superconductors (<strong>HTS</strong>) <strong>for</strong> Utility <strong>Applications</strong><br />

Beijing, China • 26 April 2013<br />

Super<strong>Power</strong> Inc. is a subsidiary <strong>of</strong> Furukawa <strong>Electric</strong> Co. Ltd.


Outline<br />

• Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> conductor<br />

• <strong>Electric</strong> power applications requirements<br />

• Summary<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

2


Super<strong>Power</strong> ® <strong>2G</strong> <strong>HTS</strong> wire: Thin film<br />

deposition on robust, flexible substrate<br />

• Automated processes<br />

• Reel-to-reel systems<br />

• High throughput, fast processes<br />

• Modular and scalable systems<br />

• Quality assurance throughout<br />

• Rigorous testing, product certification<br />

with each delivery<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

3


Each layer serves a function….<br />

• Substrate (Hastelloy ® C-276) provides mechanical strength,<br />

electropolished base <strong>for</strong> subsequent layer growth<br />

• Buffer stack provides:<br />

– Diffusion barrier between substrate and superconductor<br />

– IBAD MgO layer provides texture template <strong>for</strong> growing aligned<br />

superconductor, necessary <strong>for</strong> high current density<br />

– Final buffer layer provides lattice match between buffer stack and<br />

superconductor<br />

• <strong>HTS</strong> superconductor layer – (RE)BCO superconductor with BZO<br />

based pinning sites <strong>for</strong> high current carrying capability in background<br />

magnetic field.<br />

• Ag layer – provides good current transfer to <strong>HTS</strong> layer while providing<br />

ready path oxygen diffusion during final anneal.<br />

• Cu layer – provides stabilization (parallel path) during operation and<br />

quench conditions.<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

4


Microstructure <strong>of</strong> production MOCVD <strong>HTS</strong> wires with<br />

standard 7.5% Zr doping<br />

5 nm sized, few hundred nanometer long BZO nanocolumns with<br />

~ 35 nm spacing created during in situ MOCVD process with 7.5% Zr<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

5


<strong>2G</strong> <strong>HTS</strong> wire produced in manufacturing facility<br />

at Super<strong>Power</strong> since 2006<br />

Substrate<br />

Electropolishing<br />

MOCVD<br />

IBAD<br />

Buffer Sputtering<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

6


<strong>2G</strong> <strong>HTS</strong> <strong>Wire</strong> Specifications<br />

• Robust, high-per<strong>for</strong>mance wire; several architectures, incl.<br />

variations <strong>of</strong> width, substrate thickness, stabilizer, and<br />

insulation<br />

– Insulated wire: Kapton wrapped - 30% overlap or butt-wrap available<br />

• Two chemical <strong>for</strong>mulations:<br />

– AP (Advanced Pinning) – <strong>for</strong> enhanced in-field per<strong>for</strong>mance in<br />

motors, generators, trans<strong>for</strong>mers, SMES, high field magnets, etc.<br />

– CF (Cable Formulation) – <strong>for</strong> cable or FCL<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

7


Outline<br />

• Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> conductor<br />

• <strong>Electric</strong> power applications requirements<br />

• Summary<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

8


<strong>2G</strong> <strong>HTS</strong> is ready to serve a diverse range <strong>of</strong><br />

applications<br />

Energy Defense Transportation Industrial Medical Science/<br />

Research<br />

• FCL<br />

• Cable<br />

• Generators<br />

• Trans<strong>for</strong>mers,<br />

incl. FCL<br />

• Storage<br />

–SMES<br />

–Flywheels<br />

• Motors<br />

• Cables<br />

• Directed<br />

energy<br />

weapons<br />

• Maglev<br />

• Motors<br />

• Rail engines<br />

• Induction<br />

heaters<br />

• Motors<br />

• Generators<br />

• Magnetic<br />

separation<br />

• Bearings<br />

• Current<br />

leads<br />

• NMR<br />

•MRI<br />

• HF magnets<br />

• Space<br />

exploration<br />

•SQUIDS<br />

• High energy<br />

physics<br />

• Electronics<br />

• Cell tower<br />

base station<br />

filters<br />

Courtesy <strong>of</strong><br />

Super<strong>Power</strong><br />

and Furukawa<br />

Courtesy <strong>of</strong><br />

SPX<br />

Key:<br />

• Near-Term addressable: 1-5 years<br />

• Mid-Term: 3-7 years<br />

• Longer term: 5-10 years<br />

Courtesy <strong>of</strong> Oswald<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

9


Key per<strong>for</strong>mance requirements <strong>for</strong> electric<br />

power applications<br />

• Long piece length<br />

• Uni<strong>for</strong>m and consistent properties<br />

• High mechanical strength<br />

• Low ac losses<br />

• Sufficient production capacity<br />

• High operating current density (magnets)<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

10


J e<br />

(KA/cm 2 )<br />

Excellent in-field per<strong>for</strong>mance makes a wide range <strong>of</strong><br />

real-world applications possible<br />

250<br />

25<br />

2.5<br />

0.25<br />

0.025<br />

Low Field<br />

4.2 K B⊥Tape<br />

Medium Field<br />

77K B⊥Tape<br />

High Field<br />

50 K B⊥Tape<br />

65 K B⊥Tape<br />

4.2 K B//Tape<br />

30 K B⊥Tape<br />

1E-3<br />

0 5 10 15 20 25 30 35<br />

Magnetic Field B (Tesla)<br />

Ultra-High Field<br />

J E floor <strong>for</strong> practicality<br />

Ic(B//ab)/Ic(77K,0T) - 4.2K<br />

Ic(B//c)/Ic(77K,0T) - 4.2 K<br />

Ic(B//c)/Ic(77K,0T) - 14 K<br />

Ic(B//c)/Ic(77K,0T) - 22 K<br />

Ic(B//c)/Ic(77K,0T) - 33K<br />

Ic(B//c)/Ic(77K,0T) - 50K<br />

Ic(B//c)/Ic(77K,0T) - 65 K<br />

Ic(B//c)/Ic(77K,0T) - 72K<br />

Ic(B//c)/Ic(77K,0T) - 77K<br />

* J e is calculated based on I c (77 K, 0T) = 100 A/4 mm (surr. copper stabilized, (SmY)BCO) and scaling<br />

factors measured by D. Larbalestier, et al at FSU and E. Barzi, et al. <strong>of</strong> Fermi Lab.<br />

High Temp,<br />

Low Fields:<br />

• Cable<br />

•SFCL<br />

• Trans<strong>for</strong>mer<br />

• Motor/generator<br />

• Propulsion motor<br />

• Plasma confinement<br />

• Crystal growth magnet<br />

• Magnetic separation<br />

Medium Temp,<br />

Medium Fields:<br />

• Motor/generator<br />

• Propulsion motor<br />

• Plasma confinement<br />

• Crystal growth magnet<br />

• Magnetic separation<br />

•Maglev<br />

•SMES<br />

Low Temp,<br />

High Fields:<br />

•SMES<br />

• High-field MRI<br />

• High-field Insert<br />

•NMR<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

11<br />

10<br />

1<br />

0.1<br />

0.01<br />

I c<br />

(B)/I c<br />

(77K,0T)


Critical current vs. temperature and magnetic field <strong>of</strong><br />

recent AP production material<br />

Small cross-section <strong>of</strong> Super<strong>Power</strong><strong>2G</strong> <strong>HTS</strong> translates into high operational<br />

current density<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

12


Significant improvement in lift factor at targeted<br />

operating conditions <strong>for</strong> motor / generator<br />

demonstrated<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

13


Long piece lengths now routinely being<br />

manufactured<br />

Example <strong>of</strong> >200m<br />

piece length<br />

delivered to ARPA-E<br />

SMES project<br />

(Tapestar data)<br />

• 12mm wide<br />

• 65 micron Cu<br />

stabilizer<br />

• 77K Ic ~ 400A<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

14


Alternative configurations <strong>for</strong> compact high<br />

amperage windings demonstrated<br />

Compact cable – Advanced Conductor Technologies<br />

ROEBEL cable – General Cable Superconductors, KIT<br />

• Bonded conductors <strong>for</strong> kA class conductors<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

15


Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> wire has high tensile<br />

strength<br />

1200<br />

Copper thickness<br />

1000<br />

40 µm<br />

800<br />

60 µm<br />

stress (MPa)<br />

600<br />

400<br />

100 µm<br />

4K and 77K<br />

data from<br />

NHMFL<br />

200<br />

0<br />

0.000 0.002 0.004 0.006 0.008 0.010 0.012<br />

strain<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

16


Outline<br />

• Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> conductor<br />

• <strong>Electric</strong> power applications requirements<br />

• Summary<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

17


Super<strong>Power</strong> is driving price down on two fronts: Improving<br />

manufacturing process and increasing in-field per<strong>for</strong>mance<br />

Time<br />

Standard<br />

Per<strong>for</strong>mance<br />

at 77 K,<br />

zero field*<br />

Lift Factor<br />

at device<br />

operating<br />

condition<br />

(30K, 2T)<br />

Per<strong>for</strong>mance<br />

at device<br />

operating<br />

condition<br />

Average<br />

<strong>Wire</strong><br />

price<br />

($/m)<br />

<strong>Wire</strong> price<br />

($/kA-m)<br />

at device<br />

operating<br />

condition<br />

Now 100 A 2 200 A $ 45 $225<br />

2 years 150 A 4 600 A $ 40 $ 67<br />

4 years 200 A 6 1200 A $ 35 $ 30<br />

* Based 4mm width<br />

Improving wire per<strong>for</strong>mance is key to success<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

1<br />

8


Continually improving large-scale production <strong>of</strong><br />

robust, high-per<strong>for</strong>mance wire<br />

• High critical current:<br />

– 100A standard; 110-140 + A premium (4 mm width)<br />

• Uni<strong>for</strong>m critical current over long lengths: +/- 10% standard deviation<br />

• Single piece lengths <strong>of</strong> 50-300 m (without splices); up to 1 km and<br />

longer with high quality splices<br />

• Excellent joints & solderability:<br />

– No degradation in Ic even when joint is bent over 1” diameter and thermal<br />

cycled<br />

– Joint resistance ~ 40 nohm-cm 2<br />

– No issues with soldering to our <strong>2G</strong> <strong>HTS</strong> <strong>Wire</strong><br />

• Manufacturing volume steadily increasing<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

1<br />

9


Thank you <strong>for</strong> your attention!<br />

• For further in<strong>for</strong>mation, please visit www.superpower-inc.com<br />

All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />

Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />

20

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