Status of 2G HTS Wire for Electric Power Applications - SuperPower
Status of 2G HTS Wire for Electric Power Applications - SuperPower
Status of 2G HTS Wire for Electric Power Applications - SuperPower
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superior per<strong>for</strong>mance. powerful technology.<br />
<strong>Status</strong> <strong>of</strong> <strong>2G</strong> <strong>HTS</strong> <strong>Wire</strong> <strong>for</strong> <strong>Electric</strong> <strong>Power</strong><br />
<strong>Applications</strong><br />
Drew Hazelton, Principal Engineer<br />
CIGRÉ SC D1 WG38 Workshop on High Temperature Superconductors (<strong>HTS</strong>) <strong>for</strong> Utility <strong>Applications</strong><br />
Beijing, China • 26 April 2013<br />
Super<strong>Power</strong> Inc. is a subsidiary <strong>of</strong> Furukawa <strong>Electric</strong> Co. Ltd.
Outline<br />
• Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> conductor<br />
• <strong>Electric</strong> power applications requirements<br />
• Summary<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
2
Super<strong>Power</strong> ® <strong>2G</strong> <strong>HTS</strong> wire: Thin film<br />
deposition on robust, flexible substrate<br />
• Automated processes<br />
• Reel-to-reel systems<br />
• High throughput, fast processes<br />
• Modular and scalable systems<br />
• Quality assurance throughout<br />
• Rigorous testing, product certification<br />
with each delivery<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
3
Each layer serves a function….<br />
• Substrate (Hastelloy ® C-276) provides mechanical strength,<br />
electropolished base <strong>for</strong> subsequent layer growth<br />
• Buffer stack provides:<br />
– Diffusion barrier between substrate and superconductor<br />
– IBAD MgO layer provides texture template <strong>for</strong> growing aligned<br />
superconductor, necessary <strong>for</strong> high current density<br />
– Final buffer layer provides lattice match between buffer stack and<br />
superconductor<br />
• <strong>HTS</strong> superconductor layer – (RE)BCO superconductor with BZO<br />
based pinning sites <strong>for</strong> high current carrying capability in background<br />
magnetic field.<br />
• Ag layer – provides good current transfer to <strong>HTS</strong> layer while providing<br />
ready path oxygen diffusion during final anneal.<br />
• Cu layer – provides stabilization (parallel path) during operation and<br />
quench conditions.<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
4
Microstructure <strong>of</strong> production MOCVD <strong>HTS</strong> wires with<br />
standard 7.5% Zr doping<br />
5 nm sized, few hundred nanometer long BZO nanocolumns with<br />
~ 35 nm spacing created during in situ MOCVD process with 7.5% Zr<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
5
<strong>2G</strong> <strong>HTS</strong> wire produced in manufacturing facility<br />
at Super<strong>Power</strong> since 2006<br />
Substrate<br />
Electropolishing<br />
MOCVD<br />
IBAD<br />
Buffer Sputtering<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
6
<strong>2G</strong> <strong>HTS</strong> <strong>Wire</strong> Specifications<br />
• Robust, high-per<strong>for</strong>mance wire; several architectures, incl.<br />
variations <strong>of</strong> width, substrate thickness, stabilizer, and<br />
insulation<br />
– Insulated wire: Kapton wrapped - 30% overlap or butt-wrap available<br />
• Two chemical <strong>for</strong>mulations:<br />
– AP (Advanced Pinning) – <strong>for</strong> enhanced in-field per<strong>for</strong>mance in<br />
motors, generators, trans<strong>for</strong>mers, SMES, high field magnets, etc.<br />
– CF (Cable Formulation) – <strong>for</strong> cable or FCL<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
7
Outline<br />
• Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> conductor<br />
• <strong>Electric</strong> power applications requirements<br />
• Summary<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
8
<strong>2G</strong> <strong>HTS</strong> is ready to serve a diverse range <strong>of</strong><br />
applications<br />
Energy Defense Transportation Industrial Medical Science/<br />
Research<br />
• FCL<br />
• Cable<br />
• Generators<br />
• Trans<strong>for</strong>mers,<br />
incl. FCL<br />
• Storage<br />
–SMES<br />
–Flywheels<br />
• Motors<br />
• Cables<br />
• Directed<br />
energy<br />
weapons<br />
• Maglev<br />
• Motors<br />
• Rail engines<br />
• Induction<br />
heaters<br />
• Motors<br />
• Generators<br />
• Magnetic<br />
separation<br />
• Bearings<br />
• Current<br />
leads<br />
• NMR<br />
•MRI<br />
• HF magnets<br />
• Space<br />
exploration<br />
•SQUIDS<br />
• High energy<br />
physics<br />
• Electronics<br />
• Cell tower<br />
base station<br />
filters<br />
Courtesy <strong>of</strong><br />
Super<strong>Power</strong><br />
and Furukawa<br />
Courtesy <strong>of</strong><br />
SPX<br />
Key:<br />
• Near-Term addressable: 1-5 years<br />
• Mid-Term: 3-7 years<br />
• Longer term: 5-10 years<br />
Courtesy <strong>of</strong> Oswald<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
9
Key per<strong>for</strong>mance requirements <strong>for</strong> electric<br />
power applications<br />
• Long piece length<br />
• Uni<strong>for</strong>m and consistent properties<br />
• High mechanical strength<br />
• Low ac losses<br />
• Sufficient production capacity<br />
• High operating current density (magnets)<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
10
J e<br />
(KA/cm 2 )<br />
Excellent in-field per<strong>for</strong>mance makes a wide range <strong>of</strong><br />
real-world applications possible<br />
250<br />
25<br />
2.5<br />
0.25<br />
0.025<br />
Low Field<br />
4.2 K B⊥Tape<br />
Medium Field<br />
77K B⊥Tape<br />
High Field<br />
50 K B⊥Tape<br />
65 K B⊥Tape<br />
4.2 K B//Tape<br />
30 K B⊥Tape<br />
1E-3<br />
0 5 10 15 20 25 30 35<br />
Magnetic Field B (Tesla)<br />
Ultra-High Field<br />
J E floor <strong>for</strong> practicality<br />
Ic(B//ab)/Ic(77K,0T) - 4.2K<br />
Ic(B//c)/Ic(77K,0T) - 4.2 K<br />
Ic(B//c)/Ic(77K,0T) - 14 K<br />
Ic(B//c)/Ic(77K,0T) - 22 K<br />
Ic(B//c)/Ic(77K,0T) - 33K<br />
Ic(B//c)/Ic(77K,0T) - 50K<br />
Ic(B//c)/Ic(77K,0T) - 65 K<br />
Ic(B//c)/Ic(77K,0T) - 72K<br />
Ic(B//c)/Ic(77K,0T) - 77K<br />
* J e is calculated based on I c (77 K, 0T) = 100 A/4 mm (surr. copper stabilized, (SmY)BCO) and scaling<br />
factors measured by D. Larbalestier, et al at FSU and E. Barzi, et al. <strong>of</strong> Fermi Lab.<br />
High Temp,<br />
Low Fields:<br />
• Cable<br />
•SFCL<br />
• Trans<strong>for</strong>mer<br />
• Motor/generator<br />
• Propulsion motor<br />
• Plasma confinement<br />
• Crystal growth magnet<br />
• Magnetic separation<br />
Medium Temp,<br />
Medium Fields:<br />
• Motor/generator<br />
• Propulsion motor<br />
• Plasma confinement<br />
• Crystal growth magnet<br />
• Magnetic separation<br />
•Maglev<br />
•SMES<br />
Low Temp,<br />
High Fields:<br />
•SMES<br />
• High-field MRI<br />
• High-field Insert<br />
•NMR<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
11<br />
10<br />
1<br />
0.1<br />
0.01<br />
I c<br />
(B)/I c<br />
(77K,0T)
Critical current vs. temperature and magnetic field <strong>of</strong><br />
recent AP production material<br />
Small cross-section <strong>of</strong> Super<strong>Power</strong><strong>2G</strong> <strong>HTS</strong> translates into high operational<br />
current density<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013 Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
12
Significant improvement in lift factor at targeted<br />
operating conditions <strong>for</strong> motor / generator<br />
demonstrated<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
13
Long piece lengths now routinely being<br />
manufactured<br />
Example <strong>of</strong> >200m<br />
piece length<br />
delivered to ARPA-E<br />
SMES project<br />
(Tapestar data)<br />
• 12mm wide<br />
• 65 micron Cu<br />
stabilizer<br />
• 77K Ic ~ 400A<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
14
Alternative configurations <strong>for</strong> compact high<br />
amperage windings demonstrated<br />
Compact cable – Advanced Conductor Technologies<br />
ROEBEL cable – General Cable Superconductors, KIT<br />
• Bonded conductors <strong>for</strong> kA class conductors<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
15
Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> wire has high tensile<br />
strength<br />
1200<br />
Copper thickness<br />
1000<br />
40 µm<br />
800<br />
60 µm<br />
stress (MPa)<br />
600<br />
400<br />
100 µm<br />
4K and 77K<br />
data from<br />
NHMFL<br />
200<br />
0<br />
0.000 0.002 0.004 0.006 0.008 0.010 0.012<br />
strain<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
16
Outline<br />
• Super<strong>Power</strong> <strong>2G</strong> <strong>HTS</strong> conductor<br />
• <strong>Electric</strong> power applications requirements<br />
• Summary<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
17
Super<strong>Power</strong> is driving price down on two fronts: Improving<br />
manufacturing process and increasing in-field per<strong>for</strong>mance<br />
Time<br />
Standard<br />
Per<strong>for</strong>mance<br />
at 77 K,<br />
zero field*<br />
Lift Factor<br />
at device<br />
operating<br />
condition<br />
(30K, 2T)<br />
Per<strong>for</strong>mance<br />
at device<br />
operating<br />
condition<br />
Average<br />
<strong>Wire</strong><br />
price<br />
($/m)<br />
<strong>Wire</strong> price<br />
($/kA-m)<br />
at device<br />
operating<br />
condition<br />
Now 100 A 2 200 A $ 45 $225<br />
2 years 150 A 4 600 A $ 40 $ 67<br />
4 years 200 A 6 1200 A $ 35 $ 30<br />
* Based 4mm width<br />
Improving wire per<strong>for</strong>mance is key to success<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
1<br />
8
Continually improving large-scale production <strong>of</strong><br />
robust, high-per<strong>for</strong>mance wire<br />
• High critical current:<br />
– 100A standard; 110-140 + A premium (4 mm width)<br />
• Uni<strong>for</strong>m critical current over long lengths: +/- 10% standard deviation<br />
• Single piece lengths <strong>of</strong> 50-300 m (without splices); up to 1 km and<br />
longer with high quality splices<br />
• Excellent joints & solderability:<br />
– No degradation in Ic even when joint is bent over 1” diameter and thermal<br />
cycled<br />
– Joint resistance ~ 40 nohm-cm 2<br />
– No issues with soldering to our <strong>2G</strong> <strong>HTS</strong> <strong>Wire</strong><br />
• Manufacturing volume steadily increasing<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
1<br />
9
Thank you <strong>for</strong> your attention!<br />
• For further in<strong>for</strong>mation, please visit www.superpower-inc.com<br />
All Rights Reserved. Copyright Super<strong>Power</strong> ® Inc. 2013<br />
Cigré WG38 Workshop • Beijing, China • 26 April 2013<br />
20