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Fusible Polyvinyl Chloride Pipe Provides Owner with a Monolithic ...

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Research indicates that HDPE can be degraded by<br />

common water disinfectants leading to Stage III<br />

“end of life failure”<br />

• Polyethylene is a polyolefin family<br />

plastic – which oxidizes <strong>with</strong>out<br />

the aid of antioxidants that are<br />

added to the HDPE formulation<br />

• Over 20 research papers published<br />

since 2004 document the failure of<br />

HDPE (PE80, PE100) pipe in the<br />

presence of water disinfectants –<br />

Stage III failure resulting from<br />

oxidation (rapid antioxidant<br />

consumption) and polymer chain<br />

scission<br />

i<br />

• North American standards (ASTM<br />

and AWWA) do not give guidance<br />

on a design factor to account for<br />

this newly documented<br />

phenomenon<br />

• Life expectancies do not consider<br />

Stage III failure<br />

• Safety factors do not consider<br />

oxidative failure mode<br />

• PVC has been demonstrated to be<br />

resistant to oxidation due to water<br />

disinfectants<br />

Hoop Stress<br />

Stage III oxidative induced cracking polyolefin family pipe – Choi 2008<br />

Chemical Aging<br />

Premature Stage<br />

III Failure<br />

Time<br />

Hydroperoxide decomposition of polyethylene under<br />

attack by chlorine dioxide – L. Audouin et al. 2007

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