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Published by<br />

<strong>Pan</strong> <strong>Stanford</strong> <strong>Publishing</strong> Pte. Ltd.<br />

Penthouse Level, Suntec Tower 3<br />

8 Temasek Boulevard<br />

Singapore 038988<br />

Email: editorial@panstanford.com<br />

Web: www.panstanford.com<br />

British Library Cataloguing-in-Publication Data<br />

A catalogue record for this book is available from the British Library.<br />

Nanotechnology and Energy: Science, Promises, and Limits<br />

Copyright c○ 2013 <strong>Pan</strong> <strong>Stanford</strong> <strong>Publishing</strong> Pte. Ltd.<br />

All rights reserved. This book, or parts thereof, may not be reproduced in any<br />

form or by any means, electronic or mechanical, including photocopying,<br />

recording or any information storage and retrieval system now known or to<br />

be invented, without written permission from the publisher.<br />

For photocopying of material in this volume, please pay a copying<br />

fee through the Copyright Clearance Center, Inc., 222 Rosewood Drive,<br />

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required from the publisher.<br />

ISBN 978-981-4310-81-9 (Hardcover)<br />

ISBN 978-981-4364-06-5 (eBook)<br />

PrintedintheUSA


Contents<br />

Notes on the Contributors<br />

Foreword<br />

xiii<br />

xxi<br />

1. Challenges in the Energy Sector and Future Role of<br />

Nanotechnology 1<br />

Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß<br />

1.1 The Energy Sector in Germany and Its Future<br />

Challenges 1<br />

1.1.1 Demographic and Economic Development 2<br />

1.1.2 Development of Prices for Fossil Energy<br />

Sources 2<br />

1.1.3 Primary Energy Consumption 3<br />

1.1.4 Electricity Generation 6<br />

1.1.5 Final Energy Consumption 9<br />

1.1.6 Energy Productivity and Energy Intensity 9<br />

1.1.7 Emissions 12<br />

1.2 Nanotechnology and Energy 15<br />

2. Principles of Nanotechnology 21<br />

2.1 Definition and Classification 21<br />

Jochen Lambauer, Dr. Ulrich Fahl, and<br />

Prof. Dr. Alfred Voß<br />

2.2 Scientific and Technical Background 25<br />

Jochen Lambauer, Dr. Ulrich Fahl, and<br />

Prof. Dr. Alfred Voß<br />

2.2.1 Nanomaterials 25<br />

2.2.1.1 Point-shaped structures 25<br />

2.2.1.2 Line-shaped structures 27<br />

2.2.1.3 Layer structures 28


vi<br />

Contents<br />

2.2.1.4 Pore structures 29<br />

2.2.1.5 Complex structures 30<br />

2.2.2 Top-Down and Bottom-Up Strategy 31<br />

2.2.3 Tools and Production Processes 33<br />

2.2.3.1 Vapour deposition 37<br />

2.2.3.2 Manufacturing from liquid or<br />

dissolved raw materials 38<br />

2.2.3.3 Manufacturing from solid raw<br />

materials 38<br />

2.2.3.4 Lithography 39<br />

2.2.3.5 Self-organisation 40<br />

2.2.3.6 Nanoanalytics 40<br />

2.3 Innovation and Economic Potential 42<br />

Dr. Wolfgang Luther<br />

2.3.1 Nanotechnology as a Cross-Cutting<br />

Innovation Field 42<br />

2.3.2 Economic Relevance of Nanotechnology 47<br />

2.3.3 Nanotechnology Companies in the<br />

Value-Added Chain 50<br />

2.4 Risk and Safety Issues 54<br />

Niels Boeing<br />

2.4.1 The Image of Nanotechnology: Three Phases 54<br />

2.4.1.1 Pre-2000: the futuristic phase 55<br />

2.4.1.2 2000–2006: the nanomarkets phase 55<br />

2.4.1.3 Since 2006: the sceptical phase 56<br />

2.4.2 A Systematic Approach to Nanotechnology<br />

Risks 57<br />

2.4.2.1 Primary nanorisks: impacts on<br />

health and the environment 58<br />

2.4.2.2 Secondary nanorisks: impacts on<br />

society and the economy 63<br />

2.4.3 Conclusion 63<br />

2.5 Public Perception of Nanotechnologies: Challenges<br />

and Recommendations for Communication<br />

Strategies and Dialogue Concepts 68<br />

Dr. Antje Grobe and Nico Kreinberger<br />

2.5.1 Introduction 68<br />

2.5.2 Psychological, Social, and Cultural Factors of<br />

Risk Perception 69


Contents<br />

vii<br />

2.5.3 Public Perception of Nanotechnologies: an<br />

International Comparison 71<br />

2.5.4 Consumer’s Perception of Nanotechnologies<br />

in German Language Areas 76<br />

2.5.5 Attitudes Towards Nanotechnologies in the<br />

Energy Sector 82<br />

2.5.6 Requirements for Consumer Communication 83<br />

2.5.7 Conclusions: Recommendations for<br />

Communication Strategies and Dialogue<br />

Concepts 85<br />

3. Examples for Nanotechnological Applications in<br />

the Energy Sector 89<br />

3.1 Aerogels: Porous Sol-Gel-Derived Solids for<br />

Applications in Energy Technologies 90<br />

Dr. Gudrun Reichenauer<br />

3.1.1 Aerogels–Synthesis and Properties 90<br />

3.1.1.1 Synthesis 90<br />

3.1.1.2 Structural properties 93<br />

3.1.2 Properties Meeting Applications 94<br />

3.1.2.1 Thermal insulation 94<br />

3.1.2.2 Components for energy storage 102<br />

3.1.2.3 Catalysts supports 106<br />

3.1.2.4 Other energy-related fields of<br />

application 107<br />

3.1.3 Problems to be Solved for a Broad<br />

Introduction of Aerogels in Energy-Related<br />

Applications 107<br />

3.1.4 Conclusions 109<br />

3.2 Energy Sources and Conversion 114<br />

3.2.1 Dye Solar Cells 114<br />

Dr. Claus Lang-Koetz, Dr. Andreas Hinsch,<br />

and Dr. Severin Beucker<br />

3.2.1.1 DSC technology and its application 115<br />

3.2.1.2 Characteristics of DSC modules 116<br />

3.2.1.3 Manufacturing steps for DSC<br />

modules 118<br />

3.2.1.4 Industrial production for DSC<br />

modules 119


viii<br />

Contents<br />

3.2.1.5 Application scenarios for future DSC<br />

products 122<br />

3.2.1.6 Environmental impact 123<br />

3.2.1.7 Conclusions and outlook 125<br />

3.2.2 Nanoscale Thermoelectrics – a Concept for<br />

Higher Energy Efficiency? 128<br />

Dr. Harald Böttner and Jan König<br />

3.2.2.1 Introduction 129<br />

3.2.2.2 Initial concepts of nanoscale<br />

thermoelectrics 130<br />

3.2.2.3 Current concepts of nanoscale<br />

thermoelectrics 131<br />

3.2.2.4 Nanocomposite bulk materials 138<br />

3.2.2.5 Summary and outlook 142<br />

3.2.3 Nanostructured Ceramic Membranes for<br />

Carbon Capture and Storage 144<br />

Dr.MartinBram,Dr.TimvanGestel,<br />

Dr. Wilhelm Albert Meulenberg,<br />

and Prof. Dr. Detlev Stöver<br />

3.2.3.1 Requirements of membranes for gas<br />

separation in post- and<br />

pre-combustion power plants 144<br />

3.2.3.2 Gas separation with microporous<br />

ceramic membranes 147<br />

3.2.3.3 Membrane materials 149<br />

3.2.3.4 Performance of microporous<br />

ceramic membranes 153<br />

3.2.3.5 Summary and conclusion 159<br />

3.3 Energy Storage and Distribution 162<br />

3.3.1 Materials for Energy Storage 162<br />

Dr. Wiebke Lohstroh<br />

3.3.1.1 Materials for hydrogen storage 165<br />

3.3.1.2 Physiorption materials 166<br />

3.3.1.3 Chemisorption materials 167<br />

3.3.1.4 Materials for energy storage in<br />

batteries 176<br />

3.3.1.5 ‘New’ battery materials 180<br />

3.3.1.6 Conclusions 184


Contents<br />

ix<br />

3.4 Energy Use 190<br />

3.4.1 Nanotechnology in Construction 190<br />

Dr. Wenzhong Zhu<br />

3.4.1.1 General development 190<br />

3.4.1.2 Application areas 193<br />

3.4.1.3 Future prospect 200<br />

3.4.2 Active Windows for Daylight-Guiding<br />

Applications 203<br />

Andreas Jäkel, Qingdang Li,<br />

Jörg Clobes, Volker Viereck,<br />

and Prof. Dr. Hartmut Hillmer<br />

3.4.2.1 Introduction and basics 203<br />

3.4.2.2 Complete active window 208<br />

3.4.2.3 Regulation concepts for active<br />

windows 211<br />

3.4.2.4 Production of micromirror arrays 212<br />

3.4.3 Energy Efficiency Potential of<br />

Nanotechnology in Production Processes 215<br />

Dr. Karl-Heinz Haas<br />

3.4.3.1 Introduction 215<br />

3.4.3.2 Types and properties of nanoscaled<br />

materials 216<br />

3.4.3.3 Production processes of<br />

nanomaterials 217<br />

3.4.3.4 Nanotechnologies in production<br />

processes 220<br />

3.4.3.5 The vision of molecular<br />

manufacturing 231<br />

3.4.3.6 Conclusion, summary, and outlook 232<br />

4. Potential Analysis and Assessment of the Impact of<br />

Nanotechnology on the Energy Sector Until 2030 241<br />

4.1 Methodological Approach 241<br />

Jochen Lambauer, Dr. Ulrich Fahl, and<br />

Prof. Dr. Alfred Voß<br />

4.2 Environmental Impact and Energy Demand of<br />

Nanotechnology 247<br />

Michael Steinfeldt


x<br />

Contents<br />

4.2.1 Environmental Reliefs Potentials of<br />

Nanotechnology 248<br />

4.2.2 Evaluation of Specific Application Contexts:<br />

Life Cycle Assessment 249<br />

4.2.3 Evaluation of Specific Manufactured<br />

Nanoparticles 255<br />

4.3 Potentials of Nanotechnology for Improvements in<br />

Energy Efficiency and Emission Reduction 265<br />

Jochen Lambauer, Dr. Ulrich Fahl, and<br />

Prof. Dr. Alfred Voß<br />

4.3.1 Energy Sources and Conversion 266<br />

4.3.1.1 Solar heat and photovoltaics 266<br />

4.3.1.2 Fuel cells 271<br />

4.3.1.3 Fuel additives 271<br />

4.3.1.4 Nanostructured membranes 272<br />

4.3.1.5 Thermoelectric generators 272<br />

4.3.2 Energy Storage and Distribution 273<br />

4.3.3 Energy Use 274<br />

4.3.3.1 LED and OLED in illumination 274<br />

4.3.3.2 New display technologies 276<br />

4.3.3.3 Ultra-high-performance concrete 279<br />

4.3.3.4 Insulation with vacuum-insulation<br />

panels 281<br />

4.3.3.5 Polycarbonates for automotive glazing 282<br />

4.3.3.6 Nano-lacquers 282<br />

4.3.3.7 Nanocatalysts 283<br />

4.3.3.8 Nanoparticles in synthetic production 284<br />

4.3.3.9 Nanpoarticles in tyre compounds 284<br />

4.3.3.10 Nano-based coatings to reduce friction 285<br />

4.3.4 Theoretical Potentials of<br />

Nanotechnology 286<br />

4.4 Scenario and Sensitivity Analyses for Impacts of<br />

Nanotechnological Applications 296<br />

Jochen Lambauer, Dr. Ulrich Fahl, and<br />

Prof. Dr. Alfred Voß<br />

4.4.1 Energy Sources and Conversion 298<br />

4.4.1.1 Solar heat and photovoltaics 298<br />

4.4.1.2 Fuel cells 302


Contents<br />

xi<br />

4.4.1.3 Fuel additives 306<br />

4.4.1.4 Nano-based membranes for carbon<br />

capture and storage 307<br />

4.4.1.5 Thermoelectric generators 309<br />

4.4.2 Energy Storage and Distribution 310<br />

4.4.3 Energy Use 311<br />

4.4.3.1 LED and OLED in illumination 311<br />

4.4.3.2 New display technologies 314<br />

4.4.3.3 Ultra-high-performance concrete 316<br />

4.4.3.4 Insulation with vacuum-insulation<br />

panels 317<br />

4.4.3.5 Polycarbonates for automotive glazing 319<br />

4.4.3.6 Nano-lacquers 320<br />

4.4.3.7 Nanocatalysts for styrene<br />

manufacturing 322<br />

4.4.3.8 Nanoparticles in synthetic production 323<br />

4.4.3.9 Nanoparticles in tyre compounds 324<br />

4.4.3.10 Nano-based coatings to reduce friction 325<br />

4.5 Comprehensive Subsumption of Nanotechnology in<br />

the Energy Sector 330<br />

Jochen Lambauer, Dr. Ulrich Fahl, and<br />

Prof. Dr. Alfred Voß<br />

Index 341


Notes on the Contributors<br />

Severin Beucker is co-founder of and senior researcher at the<br />

Borderstep Institute for Innovation and Sustainability, Berlin. His<br />

research focuses on innovation and technology analyses for new<br />

technologies. In the project ColorSol, he was responsible for the<br />

analysis of market potentials and the development of application<br />

scenarios for dye solar cells.<br />

Niels Boeing graduated in physics and science theory at Technische<br />

Universität Berlin. Since 2002 he has been working as a freelance<br />

science writer for major German publications, including Die Zeit<br />

and MIT Technology Review (German edition). In 2004 he published<br />

the popular-science introduction to nanotechnology Nano?! Die<br />

Technik des 21. Jahrhunderts (Rowohlt, Berlin). He lives in Hamburg,<br />

Germany.<br />

Harald Böttner is head of the Thermoelectric and Integrated<br />

Sensor Systems department of the Fraunhofer Institute for Physical<br />

Measurement Techniques, Freiburg, Germany. He graduated with<br />

a diploma in chemistry from the University of Münster, Germany,<br />

in 1974 and received his Ph.D. in 1977 at the same university for<br />

his thesis on diffusion and solid state reaction in the quaternary<br />

semiconductor II–VI/IV–VI materials system. In 1978 he joined the<br />

Fraunhofer Institut für Silicatforschung, Würzburg, Germany, and<br />

in 1980 he changed to the present appointment at the Fraunhofer<br />

Institute for Physical Measurement Techniques, Freiburg, Germany.<br />

From 1980 to 1995 he developed IV–VI infrared semiconductor<br />

lasers, while being active in thin film thermoelectrics based on PbTe.<br />

He was one of the main inventors of the worldwide first waferscale<br />

technology for vertical thermoelectric known under “Micropelt.” He<br />

is a board member of the International Thermoelectric Society, of


xiv<br />

Notes on the Contributors<br />

the European Thermoelectric Society, and co-founder of the German<br />

Thermoelectric Society.<br />

Martin Bram graduated as a materials scientist from the Friedrich<br />

Alexander University of Erlangen-Nürnberg in 1995 and received<br />

his Ph.D. from the University of Saarbrücken in 1999. After joining<br />

Forschungszentrum Jülich in 1999, the main topic of his research<br />

has been materials in energy systems. He is currently head of<br />

a research group Powder Metallurgy and Composite Materials.<br />

Dr. Bram is continuously looking for new solutions if metals or<br />

ceramics or even composites are required with defined functional<br />

porosity. His expertise in materials science and technology enables<br />

him to fruitfully combine materials synthesis, phase composition,<br />

heat treatment, grain growth, and chemical interaction during<br />

processing, as well as during operation.<br />

Ulrich Fahl studied economics at the University of Freiburg from<br />

1978 to 1983 and received his Ph.D. in 1990 from the University<br />

of Stuttgart on a decision support system for energy economy and<br />

energy policy. Since 1990 he heads the Energy Economics and<br />

Systems Analysis department at the Institute of Energy Economics<br />

and the Rational Use of Energy (IER) (staff of 20 researchers). He is<br />

responsible for national and international research activities in the<br />

field of energy and electricity demand and supply analysis, energy<br />

and electricity modelling, energy and environmental management<br />

in industry and commerce, sustainable development of energy<br />

systems, energy and transport issues, and energy and climate.<br />

Regine Geerk-Hedderich is a physicist. She studied solid state<br />

physics at the Central Institute for Solid State Physics and Material<br />

Research of the TU Dresden (Dr. rer. nat.) and at the Friedrich-<br />

Schiller-Universität Jena (Dr. sc.). Between 1980 and 1989 she<br />

worked as visiting scientist for several months at the Kapitza<br />

Institute at the Academy of Science in Moscow and the High<br />

Field Magnet Laboratory in Wroclaw. During 1990–91 Dr. Geerk-<br />

Hedderich held a research position at the high field magnet<br />

laboratory in Grenoble. Since 1991 she is employed at the Karlsruhe<br />

Institute of Technology (Forschungszentrum Karlsruhe). From 1992<br />

to 1993 she held a guest scientist position at the international


Notes on the Contributors<br />

xv<br />

superconducting laboratory in Tokyo. Since 1998 she is director<br />

the network NanoMat (supra-regional network for nanomaterials,<br />

www.nanomat.de), which has 29 partners from industry and<br />

academia.<br />

Antje Grobe obtained her M.A. from the University of Stuttgart,<br />

Germany, where she gives lectures on dialogue management and<br />

leads several national and EU-funded research projects on risk<br />

assessment and risk perception with an emphasis on nanotechnologies<br />

and climate change issues. Grobe is managing director<br />

of DialogBasis, a science-based think-tank and dialogue platform.<br />

Since more than 15 years, she has been facilitating stakeholder<br />

dialogues and citizen participation exercises in Europe on behalf<br />

of governmental bodies, academia, industry, and civil society<br />

organizations. She serves as an expert on nanotechnologies for the<br />

European Commission and the Swiss Confederation and was with<br />

the German government’s NanoKommission from 2006 to 2011.<br />

Karl-Heinz Haas studied chemistry and obtained his Ph.D. from the<br />

University of Karlsruhe, Germany, in 1983. He joined Fraunhofer ISC<br />

(sol-gel, materials, hybrid polymers) and worked for BASF in the<br />

central polymer research lab from 1988 to 1995. In 1995 Dr. Haas<br />

became head of the hybrid polymer department at ISC. Since 2004 he<br />

is managing director of the Fraunhofer Alliance Nanotechnology and<br />

is currently also head of the New Business Development department<br />

at ISC.<br />

Hartmut Hillmer received his Ph.D. in physics from Stuttgart<br />

University in 1989, after which he joined the Research Center<br />

German Telekom, Darmstadt. In 1991 he became a guest scientist at<br />

NTT Optoelectronic Laboratories, Japan. Since 1999 he is professor<br />

of technological electronics at the Institute of Nanostructure<br />

Technologies and Analytics, University of Kassel, Germany. In 2006<br />

he received the Grand Prix Europeen for Innovation Award for the<br />

patent “Micro Mirror Array.” Dr. Hillmer’s research interests include<br />

networked sensors and actuators for smart personal environments,<br />

micromirror arrays in intelligent windows, non-invasive optical<br />

biomarker detection in breath and tissue, semiconductor lasers, and<br />

optical filters for telecommunication.


xvi<br />

Notes on the Contributors<br />

Andreas Hinsch is a physicist who has been working as a researcher<br />

for many years. He is responsible for the dye solar cell activities<br />

of Fraunhofer Institute for Solar Energy Systems (ISE), Freiburg,<br />

Germany. For the project ColorSol, he was in charge of technology<br />

research and development and the technology transfer to the<br />

companies involved.<br />

Andreas Jäkel studied physics at the University of Kassel, Germany,<br />

from 2001 to 2008. In May 2008 he joined the Department of<br />

Technological Electronics, University of Kassel, where he worked<br />

on his Ph.D. in micro-optical and electromechanical systems with a<br />

focus on micromirror applications. He is one of the project leaders<br />

at the Institute of Nanostructure Technologies and Analytics and<br />

responsible for the development of micromirror arrays for active<br />

windows.<br />

Jan D. König is group leader for the Thermoelectric Energy<br />

Conversion branch in the Thermoelectric Systems department of<br />

the Fraunhofer Institute for Physical Measurement Techniques<br />

(IPM), Freiburg, Germany. He is project manager in different<br />

projects regarding thermoelectric materials research, measurement<br />

systems, and thermoelectric generator development. Some of<br />

his remarkable projects include the design and fabrication of<br />

a fully automated material measurement setup, standardization<br />

of thermoelectric metrology, and the development of a smallscale<br />

production of thermoelectric generator for high-temperature<br />

application. König’s current activities cover nanoscale bulk and thinfilm<br />

research on Bi 2 Te 3 , PbTe, and silicide-based materials as well<br />

as the development of a high-temperature generator for automotive<br />

applications. Since 2009 he is executive board member of the<br />

German Thermoelectric Society.<br />

Nico Kreinberger has a B.A. from University of Stuttgart, Germany,<br />

where he studied politics, sociology, and empirical social research.<br />

In the EU-FP 7–funded NanoCode project he conducted an international<br />

survey and several conferences on the responsible research<br />

of nanotechnologies. At the Switzerland-based Risk Dialogue Foundation<br />

he works in the fields of nanotechnologies, microsystem<br />

technologies, and climate change in several stakeholder dialogues.


Notes on the Contributors<br />

xvii<br />

Jochen Lambauer has studied environmental engineering (Dipl.-<br />

Ing., B.Sc.) at the University of Stuttgart, Germany, and the University<br />

of Iceland (Háskolí Islands, Reykjavík), Iceland. Since 2005 he is a<br />

research associate at the Institute for Energy Economics and the<br />

Rational Use of Energy (IER) at the University of Stuttgart. Lambauer<br />

is responsible for research activities in the fields of rational<br />

use of energy, energy efficiency, virtual power plants, demand<br />

response, and energy impacts of innovations (e.g., nanotechnology).<br />

In addition, he is managing director and scientific coordinator of<br />

the Graduate and Research School, Efficient Use of Energy, Stuttgart<br />

(GREES).<br />

Claus Lang-Koetz is an environmental engineer. He obtained his<br />

doctorate degree from the University of Stuttgart. He was the<br />

manager of the group “Innovative Technologies” at the Fraunhofer<br />

Institute for Industrial Engineering IAO, Stuttgart, Germany, and<br />

coordinator of the research project ColorSol. He is now working<br />

in the machine and plant manufacturing industry as an innovation<br />

manager.<br />

Qingdang Li studied electronics engineering at the Wuhan University<br />

of Technology, China, from 1993 to 1997, economics at<br />

the Harbin Institute of Technology, China, from 2000 to 2002, and<br />

mechanical engineering at the University of Paderborn from 2003<br />

to 2005. In August 2006 Li joined the Department of Technological<br />

Electronics, University of Kassel, Germany, where he worked on his<br />

Ph.D. in micro-optical and electromechanical systems with a focus<br />

on micromirror applications.<br />

Wiebke Lohstroh received her doctorate in physics in 1999<br />

at the Georg-August Universität, Göttingen, Germany. During her<br />

stay as postdoctoral fellow at Oxford University (UK) and at<br />

Vrije Universiteit, Amsterdam (the Netherlands), she investigated<br />

structural and optical properties of thin films during hydrogen<br />

uptake. From 2005 to 2011 she worked at the Institute of<br />

Nanotechnology, Karlsruhe Institute of Technology (KIT), Germany.<br />

In 2011, she joined the Forschungsneutronenquelle Heinz Maier-<br />

Leibnitz (FRM II), TU München, Germany. Her work focuses on


xviii<br />

Notes on the Contributors<br />

materials development for energy storage, i.e., solid state hydrogen<br />

storage systems and electrode materials for secondary batteries.<br />

Wolfgang Luther works as a consultant and project manager at<br />

the VDI Technologiezentrum GmbH in Duesseldorf, Germany, since<br />

1999. He holds a degree in chemistry, a degree in economics,<br />

and a Ph.D. in analytical chemistry. Dr. Luther’s specific field<br />

of competence is the socioeconomic assessment of emerging<br />

technologies, in particular nanotechnology. His current main field of<br />

activity is the coordination of innovation accompanying measures<br />

for nanotechnology within the funding programme of the Federal<br />

Ministry of Research and Education.<br />

Gudrun Reichenauer works in the field of materials science and<br />

physics, with a particular focus on the synthesis and characterization<br />

of aerogels and xerogels since more than 20 years. During<br />

1999–2000 she was a research assistant in the group of Prof.<br />

G. W. Scherer at Princeton University and the Princeton Materials<br />

Institute, NJ, USA. On her return to Germany she became the head of<br />

the Nanomaterials group of the Bavarian Center for Applied Energy<br />

Research (Division: Functional Materials for Energy Technology).<br />

Her current research is focussed on the synthesis and characterization<br />

of nanoporous materials in general, with special emphasis<br />

on sol-gel-derived materials and nanofibres synthesized by chemical<br />

vapour deposition. Application-directed activities concern, in particular,<br />

thermal insulations, electrodes in electrochemical devices, IR<br />

opacifiers, and materials for gas separation and gas storage.<br />

Michael Steinfeldt, a diploma’d engineer, is senior scientist at the<br />

Faculty of Production Engineering, University of Bremen, Germany,<br />

since 2005. His main focus of research is environmental valuation<br />

and methods of technology assessment and life cycle assessment.<br />

Current research themes are green and sustainable nanotechnology.<br />

After some years as a process engineer in an industrial enterprise<br />

he worked as senior researcher and project manager at the Institute<br />

for Ecological Economy Research (IÖW) gGmbH, Berlin, in the field<br />

corporate environmental management (1992–2004).<br />

Volker Viereck studied physics at the Humboldt University, Berlin,<br />

and at the University of Kassel, Germany, from 1997 to 2004. He


Notes on the Contributors<br />

xix<br />

worked out his diploma thesis at the Volkswagen Konzernforschung,<br />

Wolfsburg, on nanoparticle measurement in 2003. In June 2004 he<br />

joined the Department of Technological Electronics, University of<br />

Kassel, where he worked on his Ph.D. in micro-optical and electromechanical<br />

systems with a focus on micromirror applications. He is<br />

now leader of the Optical MEMS Technologies group there.<br />

Alfred Voß received his Dipl.-Ing. degree in energy engineering<br />

from the Technical University of Aachen in 1970 and a Ph.D.<br />

(Dr.-Ing.) in 1973. In 1990 the University of Stuttgart appointed<br />

him director of the Institute of Energy Economics and the Rational<br />

Use of Energy. His areas of expertise are new energy technologies,<br />

including renewable energy; energy systems and energy modeling;<br />

rational use of energy; and energy and sustainability.<br />

Wenzhong Zhu is lecturer at and manager of the Scottish Centre<br />

of Nanotechnology in Construction Materials, School of Engineering,<br />

University of the West of Scotland. His main interests and expertise<br />

are in technology and properties of self-compacting concrete and<br />

special concretes, nanotechnology in construction, and particularly<br />

nano- and micromechanical characterization of materials.


Foreword<br />

Heat, light, and mobility are essential for our modern lifestyle.<br />

However, some of these resources, such as oil and therefore gas<br />

and diesel, are not indefinitely available. Experts on energy expect<br />

a further increase in the worldwide energy demand in the next few<br />

years. For instance, we can expect the actual numbers to double<br />

by 2050. At the same time it seems as if global oil production<br />

has already reached its maximum capacity. In order to counter the<br />

growing energy shortage, research on energy is being fostered the<br />

world over. Nanomaterials play an important role in that matter, as<br />

many of the macroscopic properties of energy materials derive from<br />

the nanoscale.<br />

Compared with the big technological revolutions in the past,<br />

it is the small but creative ideas that nowadays spur important<br />

innovations. Knowledge gained in and through the world of<br />

nanotechnology allows us to ameliorate many existing technologies<br />

and to make them more reliable, efficient, and resource friendly.<br />

Nanotechnology will break into many different sectors, and the<br />

energy industry will see new materials with better properties come<br />

up or notice a decrease in the need of materials: high-efficiency<br />

accumulators, photovoltaics, compact fuel cells, surface coating.<br />

In the car industry we will find light-weight construction, tires<br />

with optimal adherence, self-healing varnishes, LEDs, and electromobility.<br />

The construction industry and process technology are two<br />

sectors that will also profit from the benefits of nanotechnology.<br />

This book provides an interdisciplinary approach to the presentation<br />

of research results in various energy applications of<br />

nanomaterials. We look at individual technologies in their global<br />

context and deal with the resulting scientific and technological<br />

questions, commercial implementation, and ecological, ethical, and


xxii<br />

Foreword<br />

social aspects. Not only are physical-chemical basics examined, but<br />

subjects and questions concerning communication risks, protection<br />

of the environment, health, regulation or science requirements, as<br />

well as economic and social implementing are also addressed.<br />

Storing electricity in huge quantities is one of the future<br />

challenges we will face, especially with the massive expansion of<br />

renewable energies.<br />

To get a more precise idea of these quantities, we take a<br />

hypothetical look at the year 2030. Supposing that until then, 30%<br />

of Germany’s entire electricity will be provided by wind, a storage<br />

or buffer capacity of about 3000 GWh will be necessary to make up<br />

for the energy lost during an almost wind-free week. This is more<br />

than 70 times the capacity of our actual pump storage capacity of<br />

40 GWh. A similar problem arises in the face of a temporary energy<br />

excess. Along with pump storage plants and air pressure storages,<br />

developments in stationary storing solutions are necessary in order<br />

to store energy intelligently and to be able to feed the network<br />

when needed. Electro-chemical storage options are described in the<br />

chapter 3.3.1, “Materials for Energy Storage.”<br />

Chapter 3.4.1, “Nanotechnology in Construction,” provides an<br />

overview on nanotechnology applications within the construction<br />

sector.<br />

All over the world, scientists look for new processes in order<br />

to enhance energy and ecological assets in the cement production.<br />

CO 2 emissions in cement production are three to four times higher<br />

than, for instance, the entire air traffic’s discharges. Scientists<br />

at the Karlsruhe Institute of Technology (KIT) fabricated a new<br />

adhesive agent with Celitement, which is comparable to the<br />

adhesive in Portland cement (OPC), based on the still unidentified<br />

hydraulically active calcium hydro-silicates. Compared with the<br />

standard fabrication of Portland cement, 50% of energy and CO 2<br />

emissions can be saved during its production.<br />

How to use lost heat efficiently with the help of the thermoelectric<br />

effect and adequate materials is the subject dealt with in chapter<br />

3.2.2, “Nanoscale Thermoelectrics”. Nanoscalic thermoelectric materials<br />

with high Seebeck coefficients show excellent characteristics<br />

for technical use — for instance, in the car industry.


Foreword<br />

xxiii<br />

Light is an elemental aspect of work quality and influences our<br />

well-being. Approximately 10% of power requirements are used<br />

for lighting appliances, half of which are employed by trade and<br />

craft businesses while 25% are used by the industry and another<br />

25% by private households. Energy-saving lighting facilities not only<br />

aim to reduce electricity costs but set important ecological accents,<br />

a subject that is described in detail in the chapter 3.4.2, “Active<br />

Windows for Daylight Guiding Applications.”<br />

The further development of coal power plants is focused on<br />

the elimination of CO 2 by storage below the ground or below<br />

the sea level. Chapter 3.2.3, dealing with nanostructured ceramic<br />

membranes for carbon capture and storage (CCS), describes an<br />

option for technological enhancement of CO 2 elimination in power<br />

plants.<br />

Chapter 4, on the potential analysis and assessment of the<br />

impacts of nanotechnology on the energy sector until 2030, does<br />

not only cover very interesting subjects, but completes the other<br />

chapters.<br />

All subjects treated in this book are very important for us today,<br />

as the prevailing ecological and societal problems concern all of us.<br />

With help of new technologies and common efforts, we can create<br />

more awareness and encourage our future generations.<br />

Dr. Regine Geerk-Hedderich<br />

Managing Director, NanoMat

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