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Published by<br />
<strong>Pan</strong> <strong>Stanford</strong> <strong>Publishing</strong> Pte. Ltd.<br />
Penthouse Level, Suntec Tower 3<br />
8 Temasek Boulevard<br />
Singapore 038988<br />
Email: editorial@panstanford.com<br />
Web: www.panstanford.com<br />
British Library Cataloguing-in-Publication Data<br />
A catalogue record for this book is available from the British Library.<br />
Nanotechnology and Energy: Science, Promises, and Limits<br />
Copyright c○ 2013 <strong>Pan</strong> <strong>Stanford</strong> <strong>Publishing</strong> Pte. Ltd.<br />
All rights reserved. This book, or parts thereof, may not be reproduced in any<br />
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ISBN 978-981-4310-81-9 (Hardcover)<br />
ISBN 978-981-4364-06-5 (eBook)<br />
PrintedintheUSA
Contents<br />
Notes on the Contributors<br />
Foreword<br />
xiii<br />
xxi<br />
1. Challenges in the Energy Sector and Future Role of<br />
Nanotechnology 1<br />
Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß<br />
1.1 The Energy Sector in Germany and Its Future<br />
Challenges 1<br />
1.1.1 Demographic and Economic Development 2<br />
1.1.2 Development of Prices for Fossil Energy<br />
Sources 2<br />
1.1.3 Primary Energy Consumption 3<br />
1.1.4 Electricity Generation 6<br />
1.1.5 Final Energy Consumption 9<br />
1.1.6 Energy Productivity and Energy Intensity 9<br />
1.1.7 Emissions 12<br />
1.2 Nanotechnology and Energy 15<br />
2. Principles of Nanotechnology 21<br />
2.1 Definition and Classification 21<br />
Jochen Lambauer, Dr. Ulrich Fahl, and<br />
Prof. Dr. Alfred Voß<br />
2.2 Scientific and Technical Background 25<br />
Jochen Lambauer, Dr. Ulrich Fahl, and<br />
Prof. Dr. Alfred Voß<br />
2.2.1 Nanomaterials 25<br />
2.2.1.1 Point-shaped structures 25<br />
2.2.1.2 Line-shaped structures 27<br />
2.2.1.3 Layer structures 28
vi<br />
Contents<br />
2.2.1.4 Pore structures 29<br />
2.2.1.5 Complex structures 30<br />
2.2.2 Top-Down and Bottom-Up Strategy 31<br />
2.2.3 Tools and Production Processes 33<br />
2.2.3.1 Vapour deposition 37<br />
2.2.3.2 Manufacturing from liquid or<br />
dissolved raw materials 38<br />
2.2.3.3 Manufacturing from solid raw<br />
materials 38<br />
2.2.3.4 Lithography 39<br />
2.2.3.5 Self-organisation 40<br />
2.2.3.6 Nanoanalytics 40<br />
2.3 Innovation and Economic Potential 42<br />
Dr. Wolfgang Luther<br />
2.3.1 Nanotechnology as a Cross-Cutting<br />
Innovation Field 42<br />
2.3.2 Economic Relevance of Nanotechnology 47<br />
2.3.3 Nanotechnology Companies in the<br />
Value-Added Chain 50<br />
2.4 Risk and Safety Issues 54<br />
Niels Boeing<br />
2.4.1 The Image of Nanotechnology: Three Phases 54<br />
2.4.1.1 Pre-2000: the futuristic phase 55<br />
2.4.1.2 2000–2006: the nanomarkets phase 55<br />
2.4.1.3 Since 2006: the sceptical phase 56<br />
2.4.2 A Systematic Approach to Nanotechnology<br />
Risks 57<br />
2.4.2.1 Primary nanorisks: impacts on<br />
health and the environment 58<br />
2.4.2.2 Secondary nanorisks: impacts on<br />
society and the economy 63<br />
2.4.3 Conclusion 63<br />
2.5 Public Perception of Nanotechnologies: Challenges<br />
and Recommendations for Communication<br />
Strategies and Dialogue Concepts 68<br />
Dr. Antje Grobe and Nico Kreinberger<br />
2.5.1 Introduction 68<br />
2.5.2 Psychological, Social, and Cultural Factors of<br />
Risk Perception 69
Contents<br />
vii<br />
2.5.3 Public Perception of Nanotechnologies: an<br />
International Comparison 71<br />
2.5.4 Consumer’s Perception of Nanotechnologies<br />
in German Language Areas 76<br />
2.5.5 Attitudes Towards Nanotechnologies in the<br />
Energy Sector 82<br />
2.5.6 Requirements for Consumer Communication 83<br />
2.5.7 Conclusions: Recommendations for<br />
Communication Strategies and Dialogue<br />
Concepts 85<br />
3. Examples for Nanotechnological Applications in<br />
the Energy Sector 89<br />
3.1 Aerogels: Porous Sol-Gel-Derived Solids for<br />
Applications in Energy Technologies 90<br />
Dr. Gudrun Reichenauer<br />
3.1.1 Aerogels–Synthesis and Properties 90<br />
3.1.1.1 Synthesis 90<br />
3.1.1.2 Structural properties 93<br />
3.1.2 Properties Meeting Applications 94<br />
3.1.2.1 Thermal insulation 94<br />
3.1.2.2 Components for energy storage 102<br />
3.1.2.3 Catalysts supports 106<br />
3.1.2.4 Other energy-related fields of<br />
application 107<br />
3.1.3 Problems to be Solved for a Broad<br />
Introduction of Aerogels in Energy-Related<br />
Applications 107<br />
3.1.4 Conclusions 109<br />
3.2 Energy Sources and Conversion 114<br />
3.2.1 Dye Solar Cells 114<br />
Dr. Claus Lang-Koetz, Dr. Andreas Hinsch,<br />
and Dr. Severin Beucker<br />
3.2.1.1 DSC technology and its application 115<br />
3.2.1.2 Characteristics of DSC modules 116<br />
3.2.1.3 Manufacturing steps for DSC<br />
modules 118<br />
3.2.1.4 Industrial production for DSC<br />
modules 119
viii<br />
Contents<br />
3.2.1.5 Application scenarios for future DSC<br />
products 122<br />
3.2.1.6 Environmental impact 123<br />
3.2.1.7 Conclusions and outlook 125<br />
3.2.2 Nanoscale Thermoelectrics – a Concept for<br />
Higher Energy Efficiency? 128<br />
Dr. Harald Böttner and Jan König<br />
3.2.2.1 Introduction 129<br />
3.2.2.2 Initial concepts of nanoscale<br />
thermoelectrics 130<br />
3.2.2.3 Current concepts of nanoscale<br />
thermoelectrics 131<br />
3.2.2.4 Nanocomposite bulk materials 138<br />
3.2.2.5 Summary and outlook 142<br />
3.2.3 Nanostructured Ceramic Membranes for<br />
Carbon Capture and Storage 144<br />
Dr.MartinBram,Dr.TimvanGestel,<br />
Dr. Wilhelm Albert Meulenberg,<br />
and Prof. Dr. Detlev Stöver<br />
3.2.3.1 Requirements of membranes for gas<br />
separation in post- and<br />
pre-combustion power plants 144<br />
3.2.3.2 Gas separation with microporous<br />
ceramic membranes 147<br />
3.2.3.3 Membrane materials 149<br />
3.2.3.4 Performance of microporous<br />
ceramic membranes 153<br />
3.2.3.5 Summary and conclusion 159<br />
3.3 Energy Storage and Distribution 162<br />
3.3.1 Materials for Energy Storage 162<br />
Dr. Wiebke Lohstroh<br />
3.3.1.1 Materials for hydrogen storage 165<br />
3.3.1.2 Physiorption materials 166<br />
3.3.1.3 Chemisorption materials 167<br />
3.3.1.4 Materials for energy storage in<br />
batteries 176<br />
3.3.1.5 ‘New’ battery materials 180<br />
3.3.1.6 Conclusions 184
Contents<br />
ix<br />
3.4 Energy Use 190<br />
3.4.1 Nanotechnology in Construction 190<br />
Dr. Wenzhong Zhu<br />
3.4.1.1 General development 190<br />
3.4.1.2 Application areas 193<br />
3.4.1.3 Future prospect 200<br />
3.4.2 Active Windows for Daylight-Guiding<br />
Applications 203<br />
Andreas Jäkel, Qingdang Li,<br />
Jörg Clobes, Volker Viereck,<br />
and Prof. Dr. Hartmut Hillmer<br />
3.4.2.1 Introduction and basics 203<br />
3.4.2.2 Complete active window 208<br />
3.4.2.3 Regulation concepts for active<br />
windows 211<br />
3.4.2.4 Production of micromirror arrays 212<br />
3.4.3 Energy Efficiency Potential of<br />
Nanotechnology in Production Processes 215<br />
Dr. Karl-Heinz Haas<br />
3.4.3.1 Introduction 215<br />
3.4.3.2 Types and properties of nanoscaled<br />
materials 216<br />
3.4.3.3 Production processes of<br />
nanomaterials 217<br />
3.4.3.4 Nanotechnologies in production<br />
processes 220<br />
3.4.3.5 The vision of molecular<br />
manufacturing 231<br />
3.4.3.6 Conclusion, summary, and outlook 232<br />
4. Potential Analysis and Assessment of the Impact of<br />
Nanotechnology on the Energy Sector Until 2030 241<br />
4.1 Methodological Approach 241<br />
Jochen Lambauer, Dr. Ulrich Fahl, and<br />
Prof. Dr. Alfred Voß<br />
4.2 Environmental Impact and Energy Demand of<br />
Nanotechnology 247<br />
Michael Steinfeldt
x<br />
Contents<br />
4.2.1 Environmental Reliefs Potentials of<br />
Nanotechnology 248<br />
4.2.2 Evaluation of Specific Application Contexts:<br />
Life Cycle Assessment 249<br />
4.2.3 Evaluation of Specific Manufactured<br />
Nanoparticles 255<br />
4.3 Potentials of Nanotechnology for Improvements in<br />
Energy Efficiency and Emission Reduction 265<br />
Jochen Lambauer, Dr. Ulrich Fahl, and<br />
Prof. Dr. Alfred Voß<br />
4.3.1 Energy Sources and Conversion 266<br />
4.3.1.1 Solar heat and photovoltaics 266<br />
4.3.1.2 Fuel cells 271<br />
4.3.1.3 Fuel additives 271<br />
4.3.1.4 Nanostructured membranes 272<br />
4.3.1.5 Thermoelectric generators 272<br />
4.3.2 Energy Storage and Distribution 273<br />
4.3.3 Energy Use 274<br />
4.3.3.1 LED and OLED in illumination 274<br />
4.3.3.2 New display technologies 276<br />
4.3.3.3 Ultra-high-performance concrete 279<br />
4.3.3.4 Insulation with vacuum-insulation<br />
panels 281<br />
4.3.3.5 Polycarbonates for automotive glazing 282<br />
4.3.3.6 Nano-lacquers 282<br />
4.3.3.7 Nanocatalysts 283<br />
4.3.3.8 Nanoparticles in synthetic production 284<br />
4.3.3.9 Nanpoarticles in tyre compounds 284<br />
4.3.3.10 Nano-based coatings to reduce friction 285<br />
4.3.4 Theoretical Potentials of<br />
Nanotechnology 286<br />
4.4 Scenario and Sensitivity Analyses for Impacts of<br />
Nanotechnological Applications 296<br />
Jochen Lambauer, Dr. Ulrich Fahl, and<br />
Prof. Dr. Alfred Voß<br />
4.4.1 Energy Sources and Conversion 298<br />
4.4.1.1 Solar heat and photovoltaics 298<br />
4.4.1.2 Fuel cells 302
Contents<br />
xi<br />
4.4.1.3 Fuel additives 306<br />
4.4.1.4 Nano-based membranes for carbon<br />
capture and storage 307<br />
4.4.1.5 Thermoelectric generators 309<br />
4.4.2 Energy Storage and Distribution 310<br />
4.4.3 Energy Use 311<br />
4.4.3.1 LED and OLED in illumination 311<br />
4.4.3.2 New display technologies 314<br />
4.4.3.3 Ultra-high-performance concrete 316<br />
4.4.3.4 Insulation with vacuum-insulation<br />
panels 317<br />
4.4.3.5 Polycarbonates for automotive glazing 319<br />
4.4.3.6 Nano-lacquers 320<br />
4.4.3.7 Nanocatalysts for styrene<br />
manufacturing 322<br />
4.4.3.8 Nanoparticles in synthetic production 323<br />
4.4.3.9 Nanoparticles in tyre compounds 324<br />
4.4.3.10 Nano-based coatings to reduce friction 325<br />
4.5 Comprehensive Subsumption of Nanotechnology in<br />
the Energy Sector 330<br />
Jochen Lambauer, Dr. Ulrich Fahl, and<br />
Prof. Dr. Alfred Voß<br />
Index 341
Notes on the Contributors<br />
Severin Beucker is co-founder of and senior researcher at the<br />
Borderstep Institute for Innovation and Sustainability, Berlin. His<br />
research focuses on innovation and technology analyses for new<br />
technologies. In the project ColorSol, he was responsible for the<br />
analysis of market potentials and the development of application<br />
scenarios for dye solar cells.<br />
Niels Boeing graduated in physics and science theory at Technische<br />
Universität Berlin. Since 2002 he has been working as a freelance<br />
science writer for major German publications, including Die Zeit<br />
and MIT Technology Review (German edition). In 2004 he published<br />
the popular-science introduction to nanotechnology Nano?! Die<br />
Technik des 21. Jahrhunderts (Rowohlt, Berlin). He lives in Hamburg,<br />
Germany.<br />
Harald Böttner is head of the Thermoelectric and Integrated<br />
Sensor Systems department of the Fraunhofer Institute for Physical<br />
Measurement Techniques, Freiburg, Germany. He graduated with<br />
a diploma in chemistry from the University of Münster, Germany,<br />
in 1974 and received his Ph.D. in 1977 at the same university for<br />
his thesis on diffusion and solid state reaction in the quaternary<br />
semiconductor II–VI/IV–VI materials system. In 1978 he joined the<br />
Fraunhofer Institut für Silicatforschung, Würzburg, Germany, and<br />
in 1980 he changed to the present appointment at the Fraunhofer<br />
Institute for Physical Measurement Techniques, Freiburg, Germany.<br />
From 1980 to 1995 he developed IV–VI infrared semiconductor<br />
lasers, while being active in thin film thermoelectrics based on PbTe.<br />
He was one of the main inventors of the worldwide first waferscale<br />
technology for vertical thermoelectric known under “Micropelt.” He<br />
is a board member of the International Thermoelectric Society, of
xiv<br />
Notes on the Contributors<br />
the European Thermoelectric Society, and co-founder of the German<br />
Thermoelectric Society.<br />
Martin Bram graduated as a materials scientist from the Friedrich<br />
Alexander University of Erlangen-Nürnberg in 1995 and received<br />
his Ph.D. from the University of Saarbrücken in 1999. After joining<br />
Forschungszentrum Jülich in 1999, the main topic of his research<br />
has been materials in energy systems. He is currently head of<br />
a research group Powder Metallurgy and Composite Materials.<br />
Dr. Bram is continuously looking for new solutions if metals or<br />
ceramics or even composites are required with defined functional<br />
porosity. His expertise in materials science and technology enables<br />
him to fruitfully combine materials synthesis, phase composition,<br />
heat treatment, grain growth, and chemical interaction during<br />
processing, as well as during operation.<br />
Ulrich Fahl studied economics at the University of Freiburg from<br />
1978 to 1983 and received his Ph.D. in 1990 from the University<br />
of Stuttgart on a decision support system for energy economy and<br />
energy policy. Since 1990 he heads the Energy Economics and<br />
Systems Analysis department at the Institute of Energy Economics<br />
and the Rational Use of Energy (IER) (staff of 20 researchers). He is<br />
responsible for national and international research activities in the<br />
field of energy and electricity demand and supply analysis, energy<br />
and electricity modelling, energy and environmental management<br />
in industry and commerce, sustainable development of energy<br />
systems, energy and transport issues, and energy and climate.<br />
Regine Geerk-Hedderich is a physicist. She studied solid state<br />
physics at the Central Institute for Solid State Physics and Material<br />
Research of the TU Dresden (Dr. rer. nat.) and at the Friedrich-<br />
Schiller-Universität Jena (Dr. sc.). Between 1980 and 1989 she<br />
worked as visiting scientist for several months at the Kapitza<br />
Institute at the Academy of Science in Moscow and the High<br />
Field Magnet Laboratory in Wroclaw. During 1990–91 Dr. Geerk-<br />
Hedderich held a research position at the high field magnet<br />
laboratory in Grenoble. Since 1991 she is employed at the Karlsruhe<br />
Institute of Technology (Forschungszentrum Karlsruhe). From 1992<br />
to 1993 she held a guest scientist position at the international
Notes on the Contributors<br />
xv<br />
superconducting laboratory in Tokyo. Since 1998 she is director<br />
the network NanoMat (supra-regional network for nanomaterials,<br />
www.nanomat.de), which has 29 partners from industry and<br />
academia.<br />
Antje Grobe obtained her M.A. from the University of Stuttgart,<br />
Germany, where she gives lectures on dialogue management and<br />
leads several national and EU-funded research projects on risk<br />
assessment and risk perception with an emphasis on nanotechnologies<br />
and climate change issues. Grobe is managing director<br />
of DialogBasis, a science-based think-tank and dialogue platform.<br />
Since more than 15 years, she has been facilitating stakeholder<br />
dialogues and citizen participation exercises in Europe on behalf<br />
of governmental bodies, academia, industry, and civil society<br />
organizations. She serves as an expert on nanotechnologies for the<br />
European Commission and the Swiss Confederation and was with<br />
the German government’s NanoKommission from 2006 to 2011.<br />
Karl-Heinz Haas studied chemistry and obtained his Ph.D. from the<br />
University of Karlsruhe, Germany, in 1983. He joined Fraunhofer ISC<br />
(sol-gel, materials, hybrid polymers) and worked for BASF in the<br />
central polymer research lab from 1988 to 1995. In 1995 Dr. Haas<br />
became head of the hybrid polymer department at ISC. Since 2004 he<br />
is managing director of the Fraunhofer Alliance Nanotechnology and<br />
is currently also head of the New Business Development department<br />
at ISC.<br />
Hartmut Hillmer received his Ph.D. in physics from Stuttgart<br />
University in 1989, after which he joined the Research Center<br />
German Telekom, Darmstadt. In 1991 he became a guest scientist at<br />
NTT Optoelectronic Laboratories, Japan. Since 1999 he is professor<br />
of technological electronics at the Institute of Nanostructure<br />
Technologies and Analytics, University of Kassel, Germany. In 2006<br />
he received the Grand Prix Europeen for Innovation Award for the<br />
patent “Micro Mirror Array.” Dr. Hillmer’s research interests include<br />
networked sensors and actuators for smart personal environments,<br />
micromirror arrays in intelligent windows, non-invasive optical<br />
biomarker detection in breath and tissue, semiconductor lasers, and<br />
optical filters for telecommunication.
xvi<br />
Notes on the Contributors<br />
Andreas Hinsch is a physicist who has been working as a researcher<br />
for many years. He is responsible for the dye solar cell activities<br />
of Fraunhofer Institute for Solar Energy Systems (ISE), Freiburg,<br />
Germany. For the project ColorSol, he was in charge of technology<br />
research and development and the technology transfer to the<br />
companies involved.<br />
Andreas Jäkel studied physics at the University of Kassel, Germany,<br />
from 2001 to 2008. In May 2008 he joined the Department of<br />
Technological Electronics, University of Kassel, where he worked<br />
on his Ph.D. in micro-optical and electromechanical systems with a<br />
focus on micromirror applications. He is one of the project leaders<br />
at the Institute of Nanostructure Technologies and Analytics and<br />
responsible for the development of micromirror arrays for active<br />
windows.<br />
Jan D. König is group leader for the Thermoelectric Energy<br />
Conversion branch in the Thermoelectric Systems department of<br />
the Fraunhofer Institute for Physical Measurement Techniques<br />
(IPM), Freiburg, Germany. He is project manager in different<br />
projects regarding thermoelectric materials research, measurement<br />
systems, and thermoelectric generator development. Some of<br />
his remarkable projects include the design and fabrication of<br />
a fully automated material measurement setup, standardization<br />
of thermoelectric metrology, and the development of a smallscale<br />
production of thermoelectric generator for high-temperature<br />
application. König’s current activities cover nanoscale bulk and thinfilm<br />
research on Bi 2 Te 3 , PbTe, and silicide-based materials as well<br />
as the development of a high-temperature generator for automotive<br />
applications. Since 2009 he is executive board member of the<br />
German Thermoelectric Society.<br />
Nico Kreinberger has a B.A. from University of Stuttgart, Germany,<br />
where he studied politics, sociology, and empirical social research.<br />
In the EU-FP 7–funded NanoCode project he conducted an international<br />
survey and several conferences on the responsible research<br />
of nanotechnologies. At the Switzerland-based Risk Dialogue Foundation<br />
he works in the fields of nanotechnologies, microsystem<br />
technologies, and climate change in several stakeholder dialogues.
Notes on the Contributors<br />
xvii<br />
Jochen Lambauer has studied environmental engineering (Dipl.-<br />
Ing., B.Sc.) at the University of Stuttgart, Germany, and the University<br />
of Iceland (Háskolí Islands, Reykjavík), Iceland. Since 2005 he is a<br />
research associate at the Institute for Energy Economics and the<br />
Rational Use of Energy (IER) at the University of Stuttgart. Lambauer<br />
is responsible for research activities in the fields of rational<br />
use of energy, energy efficiency, virtual power plants, demand<br />
response, and energy impacts of innovations (e.g., nanotechnology).<br />
In addition, he is managing director and scientific coordinator of<br />
the Graduate and Research School, Efficient Use of Energy, Stuttgart<br />
(GREES).<br />
Claus Lang-Koetz is an environmental engineer. He obtained his<br />
doctorate degree from the University of Stuttgart. He was the<br />
manager of the group “Innovative Technologies” at the Fraunhofer<br />
Institute for Industrial Engineering IAO, Stuttgart, Germany, and<br />
coordinator of the research project ColorSol. He is now working<br />
in the machine and plant manufacturing industry as an innovation<br />
manager.<br />
Qingdang Li studied electronics engineering at the Wuhan University<br />
of Technology, China, from 1993 to 1997, economics at<br />
the Harbin Institute of Technology, China, from 2000 to 2002, and<br />
mechanical engineering at the University of Paderborn from 2003<br />
to 2005. In August 2006 Li joined the Department of Technological<br />
Electronics, University of Kassel, Germany, where he worked on his<br />
Ph.D. in micro-optical and electromechanical systems with a focus<br />
on micromirror applications.<br />
Wiebke Lohstroh received her doctorate in physics in 1999<br />
at the Georg-August Universität, Göttingen, Germany. During her<br />
stay as postdoctoral fellow at Oxford University (UK) and at<br />
Vrije Universiteit, Amsterdam (the Netherlands), she investigated<br />
structural and optical properties of thin films during hydrogen<br />
uptake. From 2005 to 2011 she worked at the Institute of<br />
Nanotechnology, Karlsruhe Institute of Technology (KIT), Germany.<br />
In 2011, she joined the Forschungsneutronenquelle Heinz Maier-<br />
Leibnitz (FRM II), TU München, Germany. Her work focuses on
xviii<br />
Notes on the Contributors<br />
materials development for energy storage, i.e., solid state hydrogen<br />
storage systems and electrode materials for secondary batteries.<br />
Wolfgang Luther works as a consultant and project manager at<br />
the VDI Technologiezentrum GmbH in Duesseldorf, Germany, since<br />
1999. He holds a degree in chemistry, a degree in economics,<br />
and a Ph.D. in analytical chemistry. Dr. Luther’s specific field<br />
of competence is the socioeconomic assessment of emerging<br />
technologies, in particular nanotechnology. His current main field of<br />
activity is the coordination of innovation accompanying measures<br />
for nanotechnology within the funding programme of the Federal<br />
Ministry of Research and Education.<br />
Gudrun Reichenauer works in the field of materials science and<br />
physics, with a particular focus on the synthesis and characterization<br />
of aerogels and xerogels since more than 20 years. During<br />
1999–2000 she was a research assistant in the group of Prof.<br />
G. W. Scherer at Princeton University and the Princeton Materials<br />
Institute, NJ, USA. On her return to Germany she became the head of<br />
the Nanomaterials group of the Bavarian Center for Applied Energy<br />
Research (Division: Functional Materials for Energy Technology).<br />
Her current research is focussed on the synthesis and characterization<br />
of nanoporous materials in general, with special emphasis<br />
on sol-gel-derived materials and nanofibres synthesized by chemical<br />
vapour deposition. Application-directed activities concern, in particular,<br />
thermal insulations, electrodes in electrochemical devices, IR<br />
opacifiers, and materials for gas separation and gas storage.<br />
Michael Steinfeldt, a diploma’d engineer, is senior scientist at the<br />
Faculty of Production Engineering, University of Bremen, Germany,<br />
since 2005. His main focus of research is environmental valuation<br />
and methods of technology assessment and life cycle assessment.<br />
Current research themes are green and sustainable nanotechnology.<br />
After some years as a process engineer in an industrial enterprise<br />
he worked as senior researcher and project manager at the Institute<br />
for Ecological Economy Research (IÖW) gGmbH, Berlin, in the field<br />
corporate environmental management (1992–2004).<br />
Volker Viereck studied physics at the Humboldt University, Berlin,<br />
and at the University of Kassel, Germany, from 1997 to 2004. He
Notes on the Contributors<br />
xix<br />
worked out his diploma thesis at the Volkswagen Konzernforschung,<br />
Wolfsburg, on nanoparticle measurement in 2003. In June 2004 he<br />
joined the Department of Technological Electronics, University of<br />
Kassel, where he worked on his Ph.D. in micro-optical and electromechanical<br />
systems with a focus on micromirror applications. He is<br />
now leader of the Optical MEMS Technologies group there.<br />
Alfred Voß received his Dipl.-Ing. degree in energy engineering<br />
from the Technical University of Aachen in 1970 and a Ph.D.<br />
(Dr.-Ing.) in 1973. In 1990 the University of Stuttgart appointed<br />
him director of the Institute of Energy Economics and the Rational<br />
Use of Energy. His areas of expertise are new energy technologies,<br />
including renewable energy; energy systems and energy modeling;<br />
rational use of energy; and energy and sustainability.<br />
Wenzhong Zhu is lecturer at and manager of the Scottish Centre<br />
of Nanotechnology in Construction Materials, School of Engineering,<br />
University of the West of Scotland. His main interests and expertise<br />
are in technology and properties of self-compacting concrete and<br />
special concretes, nanotechnology in construction, and particularly<br />
nano- and micromechanical characterization of materials.
Foreword<br />
Heat, light, and mobility are essential for our modern lifestyle.<br />
However, some of these resources, such as oil and therefore gas<br />
and diesel, are not indefinitely available. Experts on energy expect<br />
a further increase in the worldwide energy demand in the next few<br />
years. For instance, we can expect the actual numbers to double<br />
by 2050. At the same time it seems as if global oil production<br />
has already reached its maximum capacity. In order to counter the<br />
growing energy shortage, research on energy is being fostered the<br />
world over. Nanomaterials play an important role in that matter, as<br />
many of the macroscopic properties of energy materials derive from<br />
the nanoscale.<br />
Compared with the big technological revolutions in the past,<br />
it is the small but creative ideas that nowadays spur important<br />
innovations. Knowledge gained in and through the world of<br />
nanotechnology allows us to ameliorate many existing technologies<br />
and to make them more reliable, efficient, and resource friendly.<br />
Nanotechnology will break into many different sectors, and the<br />
energy industry will see new materials with better properties come<br />
up or notice a decrease in the need of materials: high-efficiency<br />
accumulators, photovoltaics, compact fuel cells, surface coating.<br />
In the car industry we will find light-weight construction, tires<br />
with optimal adherence, self-healing varnishes, LEDs, and electromobility.<br />
The construction industry and process technology are two<br />
sectors that will also profit from the benefits of nanotechnology.<br />
This book provides an interdisciplinary approach to the presentation<br />
of research results in various energy applications of<br />
nanomaterials. We look at individual technologies in their global<br />
context and deal with the resulting scientific and technological<br />
questions, commercial implementation, and ecological, ethical, and
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Foreword<br />
social aspects. Not only are physical-chemical basics examined, but<br />
subjects and questions concerning communication risks, protection<br />
of the environment, health, regulation or science requirements, as<br />
well as economic and social implementing are also addressed.<br />
Storing electricity in huge quantities is one of the future<br />
challenges we will face, especially with the massive expansion of<br />
renewable energies.<br />
To get a more precise idea of these quantities, we take a<br />
hypothetical look at the year 2030. Supposing that until then, 30%<br />
of Germany’s entire electricity will be provided by wind, a storage<br />
or buffer capacity of about 3000 GWh will be necessary to make up<br />
for the energy lost during an almost wind-free week. This is more<br />
than 70 times the capacity of our actual pump storage capacity of<br />
40 GWh. A similar problem arises in the face of a temporary energy<br />
excess. Along with pump storage plants and air pressure storages,<br />
developments in stationary storing solutions are necessary in order<br />
to store energy intelligently and to be able to feed the network<br />
when needed. Electro-chemical storage options are described in the<br />
chapter 3.3.1, “Materials for Energy Storage.”<br />
Chapter 3.4.1, “Nanotechnology in Construction,” provides an<br />
overview on nanotechnology applications within the construction<br />
sector.<br />
All over the world, scientists look for new processes in order<br />
to enhance energy and ecological assets in the cement production.<br />
CO 2 emissions in cement production are three to four times higher<br />
than, for instance, the entire air traffic’s discharges. Scientists<br />
at the Karlsruhe Institute of Technology (KIT) fabricated a new<br />
adhesive agent with Celitement, which is comparable to the<br />
adhesive in Portland cement (OPC), based on the still unidentified<br />
hydraulically active calcium hydro-silicates. Compared with the<br />
standard fabrication of Portland cement, 50% of energy and CO 2<br />
emissions can be saved during its production.<br />
How to use lost heat efficiently with the help of the thermoelectric<br />
effect and adequate materials is the subject dealt with in chapter<br />
3.2.2, “Nanoscale Thermoelectrics”. Nanoscalic thermoelectric materials<br />
with high Seebeck coefficients show excellent characteristics<br />
for technical use — for instance, in the car industry.
Foreword<br />
xxiii<br />
Light is an elemental aspect of work quality and influences our<br />
well-being. Approximately 10% of power requirements are used<br />
for lighting appliances, half of which are employed by trade and<br />
craft businesses while 25% are used by the industry and another<br />
25% by private households. Energy-saving lighting facilities not only<br />
aim to reduce electricity costs but set important ecological accents,<br />
a subject that is described in detail in the chapter 3.4.2, “Active<br />
Windows for Daylight Guiding Applications.”<br />
The further development of coal power plants is focused on<br />
the elimination of CO 2 by storage below the ground or below<br />
the sea level. Chapter 3.2.3, dealing with nanostructured ceramic<br />
membranes for carbon capture and storage (CCS), describes an<br />
option for technological enhancement of CO 2 elimination in power<br />
plants.<br />
Chapter 4, on the potential analysis and assessment of the<br />
impacts of nanotechnology on the energy sector until 2030, does<br />
not only cover very interesting subjects, but completes the other<br />
chapters.<br />
All subjects treated in this book are very important for us today,<br />
as the prevailing ecological and societal problems concern all of us.<br />
With help of new technologies and common efforts, we can create<br />
more awareness and encourage our future generations.<br />
Dr. Regine Geerk-Hedderich<br />
Managing Director, NanoMat