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March 2011 - Career Point

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37. Two blocks are connected by a massless string<br />

through an ideal pulley as shown. A force of 22N is<br />

applied on block B when initially the blocks are at<br />

rest. Then speed of centre of mass of block A and<br />

block B, 2 sec, after the application of force is<br />

(masses of A and B are 4 kg and 6 kg respectively<br />

and surfaces are smooth) –<br />

A<br />

4kg<br />

B<br />

6kg<br />

(A) 1.4 m/s 2 (B) 1 m/s 2<br />

(C) 2 m/s 2<br />

(D) None of these<br />

F = 22 N<br />

38. A chain of length 1.5 πR and mass ‘m’ is put on a<br />

mounted half cylinder as shown in figure. Chain is<br />

pulled by vertically downward force 2 mg. Assuming<br />

surfaces to be friction less, acceleration of chain is –<br />

R<br />

θ<br />

1.0 m<br />

O<br />

<br />

(A) 10.2 N upwards (B) 4.2 N downwards<br />

(C) 8.3 N downwards (D) 6.2 N upwards<br />

CHEMISTRY<br />

1. According to Bohr’s theory, angular momentum of<br />

an electron in fourth orbit is -<br />

h h 2h<br />

4h<br />

(A) (B) (C) (D)<br />

2π 4π π<br />

π<br />

2. 1.25g of a solid dibasic acid is completely neutralized<br />

by 25 ml. of 0.25 molar Ba(OH) 2 solution. Molecular<br />

mass of the acid is -<br />

(A) 100 (B) 150 (C) 120 (D) 200<br />

3. Rates of effusion of hydrogen and deuterium under<br />

similar conditions are in the ratio -<br />

(A) 1 : 1 (B) 2 : 1 (C) 2 : 1 (D) 1 : 4<br />

(A) 2g<br />

(B)<br />

2g<br />

3<br />

(C) 2<br />

g<br />

F = 2mg<br />

5g<br />

(D) 3<br />

4. For equilibrium NH 4 HS(s) NH 3 (g) + H 2 S(g)<br />

K C = 1.8 × 10 –4 at 298 K. The value of K p at 298 K<br />

is-<br />

(A) 0.108 (B) 4.4 × 10 –3<br />

(C) 1.8 × 10 –4 (D) 4.4 × 10 –4<br />

39. In hydraulic press radii of connecting pipes r 1 and r 2<br />

are in ratio 1 : 2. In order to lift a heavy mass M on<br />

larger piston, the small piston must be pressed<br />

through a minimum force f equal to -<br />

f<br />

M<br />

(A) Mg<br />

(C) Mg/4<br />

(B) Mg/2<br />

(D) Mg/8<br />

40. A uniform rod of length 2.0 m specific gravity<br />

0.5 and mass 2 kg is hinged atone end to the bottom<br />

of a tank of water (specific gravity = 1.0) filled upto a<br />

height of 1.0 m as shown in figure. Taking the case<br />

θ ≠ 0º the force exerted by the hinge on the rod is :<br />

(g = 10 m/s 2 ) –<br />

5. Given that H 2 O (l) → H 2 O(g) ; ∆H = + 43.7 kJ<br />

H 2 O (s) → H 2 O (l) ; ∆H = + 6.05 kJ<br />

∆H sublimation of ice is -<br />

(A) 49.75 kJ mol –1 (B) 37.65 kJ mol –1<br />

(C) 43.7 kJ mol –1 (D) – 43.67 kJ mol –1<br />

6. Which of the following is a Lewis base ?<br />

(A) CO 2 (B) BF 3<br />

(C) Al 3+ (D) CH 3 NH 2<br />

7. The solubility product K sp of sparingly soluble salt<br />

Ag 2 CrO 4 is 4 × 10 –12 . The solubility of the salt is -<br />

(A) 1 × 10 –12 M (B) 2 × 10 –6 M<br />

(C) 1 × 10 –6 M (D) 1 × 10 –4 M<br />

8. Which of the following chemical reactions depicts<br />

the oxidising behaviour of H 2 SO 4 ?<br />

(A) 2HI + H 2 SO 4 → I 2 + SO 2 + 2H 2 O<br />

(B) Ca(OH) 2 + H 2 SO 4 → CaSO 4 + 2H 2 O<br />

(C) NaCl + H 2 SO 4 → NaHSO 4 + HCl<br />

(D) 2PCl 5 + H 2 SO 4 → 2POCl 3 + 2HCl + SO 2 Cl 2<br />

XtraEdge for IIT-JEE 83<br />

MARCH <strong>2011</strong>

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