Sustainable Vineyard Management and Herbicide ... - Lodi Wine
Sustainable Vineyard Management and Herbicide ... - Lodi Wine
Sustainable Vineyard Management and Herbicide ... - Lodi Wine
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<strong>Lodi</strong> <strong>Wine</strong>grape Commission<br />
May 24, 2011, <strong>Lodi</strong>, Ca.<br />
John Roncoroni<br />
Weed Science Farm Advisor<br />
& Affiliate IPM Advisor<br />
UCCE Napa County
Work as contact herbicide<br />
Usually need warm to hot weather<br />
to work well<br />
Work better on small weedsbetter<br />
on broadleaves
Sunflower cultivation<br />
approximately 2 weeks prior to<br />
first application<br />
Applications made on December<br />
11. <strong>and</strong> February 15.<br />
Weather on both days clear <strong>and</strong><br />
sunny- but not hot.
untreated
Acetic Acid 20% + Nufilm P<br />
Not registered for crop use<br />
2/28/08
GreenMatch O 15%
Matran 10%
Matran 5%
Registration of compounds as<br />
pesticides<br />
Costs<br />
Must use high gallonage
In the right situation animals can<br />
do a good job of weed control
In the wrong situation animals<br />
can cause compaction, <strong>and</strong> crop<br />
damage‐<br />
Can be expensive‐ do you rent or<br />
buy?
Goats?<br />
No!
1. Weed Spectrum
Common groundsel Asparagus 1981 triazine (atrazine)<br />
Perennial ryegrass Roadside, railways 1989 sulfonylurea<br />
Smallflower umbrella sedge Rice 1993 sulfonylurea<br />
California arrowhead Rice 1993 sulfonylurea<br />
Russian thistle Roadside 1994 sulfonylurea<br />
Wild oat Barley, wheat 1996 pyrazolium (difenzoquat)<br />
Redstem Rice 1997 sulfonylurea<br />
Ricefield bulrush Rice 1997 sulfonylurea<br />
Late watergrass Rice 1998 fops & thiocarbamates<br />
Rigid ryegrass Almonds, roadsides 1998 glyphosate<br />
Long‐leaved loosestrife Rice 2000 sulfonylurea<br />
Barnyardgrass Rice 2000 fops & thiocarbamates<br />
Early watergrass Rice 2000 fops & thiocarbamates<br />
Small‐seeded canarygrass Sugar beets, onions 2001, 03 fops <strong>and</strong> dims<br />
Smooth crabgrass Rice 2002 synthetic auxins<br />
Horseweed Roadsides 2005 glyphosate<br />
Italian ryegrass Roadsides 2005 glyphosate<br />
Hairy fleabane Roadsides 2007 glyphosate<br />
Hairy fleabane Roadsides, vines 2009 glyphosate & paraquat<br />
www.weedscience.org
Common groundsel Asparagus 1981 triazine (atrazine)<br />
Perennial ryegrass Roadside, railways 1989 sulfonylurea<br />
Smallflower umbrella sedge Rice 1993 sulfonylurea<br />
California arrowhead Rice 1993 sulfonylurea<br />
Russian thistle Roadside 1994 sulfonylurea<br />
Wild oat Barley, wheat 1996 pyrazolium (difenzoquat)<br />
Redstem Rice 1997 sulfonylurea<br />
Ricefield bulrush Rice 1997 sulfonylurea<br />
Late watergrass Rice 1998 fops & thiocarbamates<br />
Rigid ryegrass Almonds, roadsides 1998 glyphosate<br />
Long‐leaved loosestrife Rice 2000 sulfonylurea<br />
Barnyardgrass Rice 2000 fops & thiocarbamates<br />
Early watergrass Rice 2000 fops & thiocarbamates<br />
Small‐seeded canarygrass Sugar beets, onions 2001, 03 fops <strong>and</strong> dims<br />
Smooth crabgrass Rice 2002 synthetic auxins<br />
Horseweed Roadsides 2005 glyphosate<br />
Italian ryegrass Roadsides 2005 glyphosate<br />
Hairy fleabane Roadsides 2007 glyphosate<br />
Hairy fleabane Roadsides, vines 2009 glyphosate & paraquat<br />
www.weedscience.org
‣ <strong>Herbicide</strong> tolerance: the inherent ability of a species<br />
to survive <strong>and</strong> reproduce after herbicide treatment;<br />
implies no selection or genetic manipulation to make<br />
the plant tolerant<br />
“We’ve never gotten dependable control of this weed with<br />
this herbicide…”<br />
‣ <strong>Herbicide</strong> resistance: the inherited ability of a plant<br />
to survive <strong>and</strong> reproduce following exposure to a dose<br />
of herbicide normally lethal to the wild type<br />
“We used to be able to control this weed with this<br />
treatment but it doesn’t work as well anymore…”
‣ Often co‐exist (swarm)<br />
‣ Annual grass<br />
‣ Obligate outcrossers<br />
‣ Throughout CA but<br />
more common weed in<br />
northern Central Valley<br />
‣ 2 to 15‐fold resistance<br />
‣ Usually target site mutation
Italian Ryegrass<br />
Figure 1. Map of California showing the<br />
geographical distribution of Italian<br />
ryegrass populations sampled for this study.<br />
Closed circles indicate populations<br />
with more than 20% seedlings surviving<br />
treatment with glyphosate t 866 g ae / ha;<br />
open circles indicate populations with 5%<br />
(two populations) or no surviving<br />
seedlings. Forty seedlings from each<br />
population were tested for<br />
glyphosate response.<br />
From Jasieniuk et al. 2008.<br />
Weed Sci 56:496-502
• AKA mare’s tail<br />
• Annual weed<br />
• Prolific seed producer<br />
• Wind‐blown seed<br />
• Early colonizer<br />
• Doesn’t tolerate disturbance<br />
• 6‐fold resistance (whole plant)<br />
• 4‐8 fold resistance (in vivo)<br />
• Mechanism not know. Suspected<br />
translocation mutation
• AKA mare’s tail<br />
• Annual weed<br />
• Prolific seed producer<br />
• Wind‐blown seed<br />
• Early colonizer<br />
• Doesn’t tolerate disturbance<br />
• 6‐fold resistance (whole plant)<br />
• 4‐8 fold resistance (in vivo)<br />
• Mechanism not know. Suspected<br />
translocation mutation
Results<br />
718 plants at 144 sites<br />
-62% GR<br />
-15% Intermediate<br />
-23% GS<br />
Hanson et al. 2009<br />
Weed Sci 57:48-53
‣ AKA flaxleaf fleabane<br />
‣ Annual weed<br />
‣ Wind‐blown seed<br />
‣ Early colonizer<br />
‣ Doesn’t tolerate<br />
disturbance<br />
‣ 3 to 10‐fold resistance<br />
(whole plant screening)<br />
‣ ~ 4‐fold resistance in vivo<br />
‣ Mechanism not known
Hairy Fleabane Survey ‐ 2009<br />
Prelim Results<br />
75 populations<br />
-27% GR<br />
-52% Mixed<br />
-21% GS<br />
Zozaya et al. 2010<br />
CWSS poster session
Large Horseweed treated with glyphosate
Glyphosate Rate (ai) Mortality (%)<br />
5 to 8 leaves 1 lb 2 lbs 4 lbs<br />
Susceptible 100 100 100<br />
Resistant 0 50 100<br />
From Shrestha, Hembree <strong>and</strong> Va, California Agriculture 61(2) 67-70
Glyphosate Rate (ai) Mortality (%)<br />
6.1 to 12 inches 1 lb 2 lbs 4 lbs<br />
Susceptible 30 80 100<br />
Resistant 0 0 0<br />
From Shrestha, Hembree <strong>and</strong> Va, California Agriculture 61(2) 67-70
‣ AKA flaxleaf fleabane<br />
‣ Annual weed<br />
‣ Wind‐blown seed<br />
‣ Early colonizer<br />
‣ Doesn’t tolerate<br />
disturbance<br />
‣ 3 to 10‐fold resistance<br />
(whole plant screening)<br />
‣ ~ 4‐fold resistance in vivo<br />
‣ Mechanism not known
<strong>Herbicide</strong> Tolerant Weeds<br />
Malva<br />
Willowherb<br />
Filaree
Malva
Tall annual willowherb<br />
Epilobium brachycarpum C. Presl
Willowherb growing in vineyard
Willowherb skeletons at time of treating at Laguna
Roundup on willowherb
Filaree<br />
C139-06<br />
C139-08
<strong>Herbicide</strong>s Registered<br />
for use in Grapes<br />
Surflan<br />
Chateau<br />
Princep<br />
Goal<br />
Solicam<br />
Kerb<br />
Visor*<br />
Casoron<br />
Karmex<br />
Devrinol<br />
Gallery<br />
Prowl<br />
Matrix<br />
Glyphosate<br />
Gramoxone<br />
Rely<br />
Goal<br />
Shark<br />
Fusilade<br />
2,4-D<br />
Poast<br />
Venue<br />
Prism*<br />
* Registered for non-bearing grapes only
Compound Acreage sprayed % of total<br />
Glyphosate 10,837 38.8<br />
Simizine 6,918 24.8<br />
Oxyfluorfen 6,225 22.3<br />
Total for top 3 85.9<br />
Oryzalin 1,719 6.2<br />
Paraquat 1,536 5.5<br />
Methyl Bromide 458 1.6<br />
Diuron 116 0.4<br />
2,4‐D 68 0.2<br />
Norflurazon 20 0.1<br />
Total (all herbicides) 27,896 100<br />
Total Acre for Grapes 32,261 0.86
Compound Acreage sprayed % of total<br />
Glyphosate 35,667 54.8<br />
Flumioxazin 9,935 15.3<br />
Oxyfluorfen 7,583 11.6<br />
Total for top 3 81.7<br />
Glufosinate 6,454 9.9<br />
Oryzalin 1,270 1.9<br />
Simizine 1,190 1.8<br />
Pendimethalin 750 1.2<br />
Rimsulfuron 732 1.1<br />
Total for top 8 63,581/65,144 97.6<br />
Total Acres for Grapes 45,942 1.42
1. Weed Spectrum<br />
2. Germination Time
Fillaree, which grows early in the<br />
season may ‘hide’ willowherb seedlings<br />
from herbicide applications
Fluvellin germination continues late into the<br />
growing season<br />
C236-05
February 28<br />
November 28
Horseweed<br />
Young plant<br />
Rosette<br />
Adult<br />
Pictures taken Sept 19
Sharp-point Fluvellin
Fall ‘variation’ of fluvellin<br />
There is a milk carton under this plant!<br />
Fluvellin competing with newly planted grapes
1. Weed Spectrum<br />
2. Germination time‐<br />
3. Leaf or duff cover
8 sets of paired treatments- either leaves<br />
raked or leaves left.<br />
Plots raked at 11:30 AM 12/19/07<br />
Plots treated 12:30 PM 12/19/07<br />
Treated with 10 oz Chateau +24 oz<br />
Roundup with OC nozzles sprayed from<br />
both sides of row.<br />
Each plot 4 vines (24 feet) long<br />
Merlot grapes
Unraked plot<br />
Raked plots
60% Leaf Cover<br />
Raked pre-treatment<br />
Raked post treatment<br />
Unraked pre-treatment<br />
Unraked post treatment
% Leaf<br />
Cover<br />
2/29/2008 6/12/2008<br />
%Fillaree Cover<br />
Willowherb control<br />
0-10 scale<br />
Raked Not Raked Not<br />
60 5 50 10 7<br />
50 7 30 10 5<br />
50 15 40 9 4<br />
40 3 20 9 5<br />
40 5 10 10 7<br />
33 1 15 9 7<br />
25 5 20 10 7<br />
Ave 8.30% 28% 9.6 6.0
Willowherb
•Raked<br />
•Unraked
Jan 20/Mar 21 Sept 11 09 Sept 11 09<br />
Raked<br />
Unraked<br />
overall wh fluv overall wh fluv<br />
UTC 2.75 2.75 8.75 1.50 1.50 6.50<br />
Rely 200 2 Qt/ 2Qt 2.75 10.00 2.75 5.25 10.00 5.25<br />
Rely 200 ‐ / 3Qt 2.75 9.50 2.75 3.50 9.25 3.75<br />
Roundup WM 1 Qt/ 1Qt 2.50 5.00 3.33 3.00 3.00 7.25<br />
Roundup WM ‐ / 2Qt 6.25 7.75 6.50 4.25 5.00 5.25<br />
Rely 200+ Chateau 2 Qt + 6oz 7.00 10.00 6.88 8.00 9.38 8.38<br />
Rely 200+ Chateau 2 Qt + 12oz 7.88 10.00 7.88 7.75 8.75 8.00<br />
Roundup + Chateau 1 Qt + 6 oz 6.50 9.75 6.50 6.50 8.75 7.00<br />
Roundup + Chateau 1 Qt + 12 oz 9.13 9.88 9.13 8.88 9.00 9.13<br />
Rely 200 + Matrix 2 Qt + 2oz 6.00 9.75 6.13 6.00 9.00 6.00<br />
Rely 200 + Matrix 2 Qt + 4 oz 8.88 10.00 8.50 7.75 9.75 7.75<br />
Roundup + Matrix 1 Qt + 2oz 6.25 8.75 7.00 6.00 7.75 7.00<br />
Roundup + Matrix 1 Qt + 4oz 7.50 9.00 8.00 6.25 6.75 8.50
Jan 20/Mar 21 Sept 11 09 Sept 11 09<br />
Raked<br />
Unraked<br />
overall wh fluv overall wh fluv<br />
UTC 2.75 2.75 8.75 1.50 1.50 6.50<br />
Rely 200 2 Qt/ 2Qt 2.75 10.00 2.75 5.25 10.00 5.25<br />
Rely 200 ‐ / 3Qt 2.75 9.50 2.75 3.50 9.25 3.75<br />
Roundup WM 1 Qt/ 1Qt 2.50 5.00 3.33 3.00 3.00 7.25<br />
Roundup WM ‐ / 2Qt 6.25 7.75 6.50 4.25 5.00 5.25<br />
Rely 200+ Chateau 2 Qt + 6oz 7.00 10.00 6.88 8.00 9.38 8.38<br />
Rely 200+ Chateau 2 Qt + 12oz 7.88 10.00 7.88 7.75 8.75 8.00<br />
Roundup + Chateau 1 Qt + 6 oz 6.50 9.75 6.50 6.50 8.75 7.00<br />
Roundup + Chateau 1 Qt + 12 oz 9.13 9.88 9.13 8.88 9.00 9.13<br />
Rely 200 + Matrix 2 Qt + 2oz 6.00 9.75 6.13 6.00 9.00 6.00<br />
Rely 200 + Matrix 2 Qt + 4 oz 8.88 10.00 8.50 7.75 9.75 7.75<br />
Roundup + Matrix 1 Qt + 2oz 6.25 8.75 7.00 6.00 7.75 7.00<br />
Roundup + Matrix 1 Qt + 4oz 7.50 9.00 8.00 6.25 6.75 8.50
Jan 20/Mar 21 Sept 11 09 Sept 11 09<br />
Raked<br />
Unraked<br />
overall wh fluv overall wh fluv<br />
UTC 2.75 2.75 8.75 1.50 1.50 6.50<br />
Rely 200 2 Qt/ 2Qt 2.75 10.00 2.75 5.25 10.00 5.25<br />
Rely 200 ‐ / 3Qt 2.75 9.50 2.75 3.50 9.25 3.75<br />
Roundup WM 1 Qt/ 1Qt 2.50 5.00 3.33 3.00 3.00 7.25<br />
Roundup WM ‐ / 2Qt 6.25 7.75 6.50 4.25 5.00 5.25<br />
Rely 200+ Chateau 2 Qt + 6oz 7.00 10.00 6.88 8.00 9.38 8.38<br />
Rely 200+ Chateau 2 Qt + 12oz 7.88 10.00 7.88 7.75 8.75 8.00<br />
Roundup + Chateau 1 Qt + 6 oz 6.50 9.75 6.50 6.50 8.75 7.00<br />
Roundup + Chateau 1 Qt + 12 oz 9.13 9.88 9.13 8.88 9.00 9.13<br />
Rely 200 + Matrix 2 Qt + 2oz 6.00 9.75 6.13 6.00 9.00 6.00<br />
Rely 200 + Matrix 2 Qt + 4 oz 8.88 10.00 8.50 7.75 9.75 7.75<br />
Roundup + Matrix 1 Qt + 2oz 6.25 8.75 7.00 6.00 7.75 7.00<br />
Roundup + Matrix 1 Qt + 4oz 7.50 9.00 8.00 6.25 6.75 8.50
1. Weed Spectrum<br />
2. Germination time<br />
3. Leaf or duff cover<br />
4. Rainfall timing
1. Weed Spectrum<br />
2. Germination time<br />
3. Leaf or duff cover<br />
4. Rainfall timing<br />
5. Rainfall amount
1. Weed Spectrum<br />
2. Germination time<br />
3. Leaf or duff cover<br />
4. Rainfall timing<br />
5. Rainfall amount<br />
6. Duration of control
Jan 20/Mar 21 Sept 11 09 Sept 11 09<br />
Raked<br />
Unraked<br />
overall wh fluv overall wh fluv<br />
UTC 2.75 2.75 8.75 1.50 1.50 6.50<br />
Rely 200 2 Qt/ 2Qt 2.75 10.00 2.75 5.25 10.00 5.25<br />
Rely 200 ‐ / 3Qt 2.75 9.50 2.75 3.50 9.25 3.75<br />
Roundup WM 1 Qt/ 1Qt 2.50 5.00 3.33 3.00 3.00 7.25<br />
Roundup WM ‐ / 2Qt 6.25 7.75 6.50 4.25 5.00 5.25<br />
Rely 200+ Chateau 2 Qt + 6oz 7.00 10.00 6.88 8.00 9.38 8.38<br />
Rely 200+ Chateau 2 Qt + 12oz 7.88 10.00 7.88 7.75 8.75 8.00<br />
Roundup + Chateau 1 Qt + 6 oz 6.50 9.75 6.50 6.50 8.75 7.00<br />
Roundup + Chateau 1 Qt + 12 oz 9.13 9.88 9.13 8.88 9.00 9.13<br />
Rely 200 + Matrix 2 Qt + 2oz 6.00 9.75 6.13 6.00 9.00 6.00<br />
Rely 200 + Matrix 2 Qt + 4 oz 8.88 10.00 8.50 7.75 9.75 7.75<br />
Roundup + Matrix 1 Qt + 2oz 6.25 8.75 7.00 6.00 7.75 7.00<br />
Roundup + Matrix 1 Qt + 4oz 7.50 9.00 8.00 6.25 6.75 8.50
1. Weed Spectrum<br />
2. Germination time<br />
3. Leaf or duff cover<br />
4. Rainfall timing<br />
5. Rainfall amount<br />
6. Duration of control<br />
7. Coverage
Large willowherb treated with Rely- application missed top of plant
Droplet size classification<br />
(droplets
Kurt Hembree – UCCE, Fresno County<br />
Spray nozzle choices for herbicide application,<br />
drift management, <strong>and</strong> herbicide performance.
Untreated<br />
30 DAT<br />
XR11004VS<br />
Kurt Hembree – UCCE, Fresno County<br />
TJ60-11004VS<br />
TTJ60-11004VP
Twin Turbo Turbo Jet Flat Fan
Treatment Rate nozzle type Nozzle Gallonage<br />
1 56 oz Flat Fan 8002 VS 25<br />
2 82 oz Flat Fan 8002 VS 25<br />
3 56 oz Flat Fan 8004 VS 50<br />
4 82 oz Flat Fan 8004 VS 50<br />
5 56 oz Turbo Turbo 02 25<br />
6 82 oz Turbo Turbo 02 25<br />
7 56 oz Turbo Turbo 04 50<br />
8 82 oz Turbo Turbo 04 50<br />
9 56 oz Twin Turbo TT 02 25<br />
10 82 oz Twin Turbo TT 02 25<br />
11 56 oz Twin Turbo TT 04 50<br />
12 82 oz Twin Turbo TT 04 50<br />
13 Untreated Control
Flumioxazin‐ Chateau<br />
Rimsulfuron‐Matrix, others<br />
Oxyflurofen‐ GoalTender<br />
Pendimethalin‐Prowl H2O<br />
Glufosinate –Rely 200, Rely 280<br />
Carfentrazone –Shark
Flumioxazin‐ PPO inhibitor<br />
Taken up by roots in Preemergent treatment<br />
Little systemic movement<br />
Primary loss by microbial degradation<br />
Not persistent in soil‐ Low potential for leaching<br />
Not susceptible to volatility once on soil<br />
Must have ¼inch of rain to activate<br />
Clean tank thoroughly<br />
Application rate of 6 to 12 oz<br />
“2 oz per month” of control
Treated 12/14/07
Rimsulfuron‐ALS inhibitor‐ Sulfonylurea<br />
Plants rapidly stop growing‐followed by chlorosis<br />
<strong>and</strong> necrosis <strong>and</strong> plant death<br />
Resistance due to altered binding site<br />
Chemical degradation most important<br />
Low potential for leaching<br />
Use rate 4 oz per acre‐ only rate<br />
Control is very moisture dependant
Treated 12/14/07
Treated 12/14/07
Oxyflurofen<br />
Pre <strong>and</strong> postemergence control<br />
No odor<br />
Water‐based flowable<br />
Increased crop safety due to reduced potential for lift‐off<br />
or co‐distillation<br />
Formulated at 2x strength of Goal 2 XL<br />
Preemergence: 2.5–3 pt Goaltender/ac<br />
Postemergence: 1–3 pt Goaltender/ac<br />
Weeds controled including annual morning glory, annual<br />
sowthistle, common cocklebur, common purslane,<br />
London rocket, prickly lettuce, pigweed, <strong>and</strong> others.<br />
Labeled for control of weeds prior to bud swell. Do not<br />
use if bud swell occurs.
Pendimenthalin<br />
Pre‐emergent<br />
New encapsulated formulation‐lasts longer without<br />
incorporation<br />
Tank mix to add pre grass control<br />
Use rate 2‐6.3 quarts/ac<br />
Controls most annual grasses <strong>and</strong> certain broadleaf<br />
weeds as they germinate.<br />
Remarks: Prowl H2O is labeled for nonbearing <strong>and</strong><br />
bearing trees. Pre‐harvest interval of 60 days. Do not<br />
apply more than 6.3 qt of Prowl H2O per acre per year.<br />
Do not graze livestock in treated orchards.
Less Binding to Crop <strong>and</strong> Weed Residue<br />
Efficacy of Pendimethalin Formulations as<br />
Affected by Mulch<br />
HARDWOOD MULCH (shredded)<br />
21 DAT<br />
UNTREATED<br />
Pendimethalin EC
Carfentrazone‐ethyl<br />
PPO inhibitor<br />
Contact, non residual for the control of broadleaf<br />
weeds<br />
Rapid burndown<br />
Very limited movement in plant<br />
Non‐volatile<br />
Use rate 1‐2oz
Pyraflufen<br />
PPO inhibitor<br />
Contact, non residual for the control of broadleaf<br />
weeds<br />
Rapid burndown<br />
Very limited movement in plant<br />
Non‐volatile<br />
Low toxicity to honeybees
Glufosinate<br />
Postemergent<br />
Contact only<br />
Strong on some glyphosate resistant weeds such as<br />
Horseweed <strong>and</strong> fleabane <strong>and</strong> on Willowherb‐<br />
Not strong on Grass<br />
New formulation Rely 280 more active<br />
Rely 200‐ 57.5 ‐115 oz per acre‐ usually 2‐3 quarts<br />
Rely 280‐48‐82 oz per acre
Indaziflam‐ Pre‐emergence herbicide<br />
Formulated as 200 SC<br />
3 to 6 months or more of residual control<br />
Will need to be mixed with glyphosate or glufosinate if<br />
weeds are present<br />
Registration expected on Tree Nuts for next seasonother<br />
crops to follow<br />
Use Rate 5‐6.5 oz per acre
Saflufenacil<br />
Chemical Family: Pyrimidinedione.<br />
Only herbicide technology in the pyrimidinedione class<br />
of chemistry available in the North American market.<br />
Similar to flumioxazin<br />
Readily absorbed by foliage, root <strong>and</strong> shoot tissue of<br />
plants.<br />
A process of membrane disruption which is initiated by<br />
the inhibition of the enzyme protoporphyrinogenoxidase<br />
(PPO) interferes with the chlorophyll biosynthetic pathway.
Combination of 2 herbicides‐ Penoxsulam(Pindar) <strong>and</strong><br />
Oxyflurofen (Goaltender)<br />
Penoxsulam is an ALS inhibitor like Rimsulfuron‐<br />
Goaltender added to help with burndown <strong>and</strong><br />
broader‐ weed control spectrum<br />
Labeled for nuts only<br />
4lbs of GoalTender per gallon<br />
Use rate: 1.5‐3 pints per acre<br />
May need burndown or grass herbicide added