19.11.2014 Views

Phase-Sensitive (Quadrature) Detection i NMR n NMR Phase ...

Phase-Sensitive (Quadrature) Detection i NMR n NMR Phase ...

Phase-Sensitive (Quadrature) Detection i NMR n NMR Phase ...

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

<strong>Phase</strong>-<strong>Sensitive</strong> (<strong>Quadrature</strong>) <strong>Detection</strong><br />

Procedure is optimized by phase-cycling.<br />

Scans collected in sets of four pulses.<br />

and then two more, -x(-cos, -sin) and -y(-sin, cos).<br />

Gradient-Enhanced COSY (gCOSY)<br />

<strong>Quadrature</strong><br />

detection<br />

lengthens time<br />

(x4) of 2D <strong>NMR</strong>.<br />

Can solve this by<br />

using pulsed-field<br />

gradient—vertical<br />

range of B 0 field,<br />

applied via RF<br />

coil.<br />

<strong>NMR</strong> tube

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!