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Acetals

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L A M B I O T T E & C I E S. A.<br />

E T H Y L A L<br />

ETHYLAL<br />

Molecular formula C 5<br />

H 12<br />

O 2<br />

Chemical structure CH 3<br />

-CH 2<br />

-O-CH 2<br />

-O-CH 2<br />

-CH 3<br />

Synonym<br />

Diethoxymethane (DEM)<br />

CAS N° 462-95-3<br />

EINECS N° 207-330-6<br />

Physical Properties<br />

Molecular weight 104.15<br />

Density (g/cm 3 ) 20°C 0.830<br />

Vapour density 3.6<br />

Boiling point (°C) 101 325 Pa 88<br />

Freezing point (°C) - 66<br />

Flash point (°C)<br />

Closed cup (Pensky-Martens) - 7<br />

Open cup (Cleveland) 6<br />

Vapour pressure (bar) 20°C (ASTM D 323 modified) 0.17<br />

Kinematic viscosity (10 -7 m 2 /s) 25°C 5.07<br />

Refractory index η 20 D 1.3725<br />

Explosion limits (Vol%)<br />

LEL : 2.1<br />

UEL : 20<br />

Autoignition temperature (°C) (ASTM E 659) 174<br />

Surface tension (mN/m) 25°C 21.62<br />

Evaporation rate compared to<br />

Diethyl ether (=1) 3<br />

(Following DIN 53170)<br />

Butyl acetate (=1) 0.25<br />

Solubility of the acetal in water (%) 6.33<br />

Solubility of water in the acetal (%) 1.21<br />

Solvent power<br />

Kauri-butanol index (ASTM D 1133-90) measured with gum 4938 92<br />

gum 4939 120<br />

Solubility parameters (MPa 1/2 )<br />

Hildebrand: Total δ 17.06<br />

Hansen: Dispersion δ d 14.87<br />

Polarity δ p 4.67<br />

Hydrogen bond δ h 6.95

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