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NASA Emissions Reduction and Alternative Fuels Research UTIAS ...

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Electron Microscopy, Spectroscopy <strong>and</strong><br />

Chemical Analysis of Aircraft Engine Particulate<br />

Microstructure - morphology<br />

Low resolution TEM<br />

provides aggregate<br />

size <strong>and</strong> shape for<br />

particles captured<br />

on netmesh TEM grids<br />

Chemical Composition<br />

Nanostructure - carbon organization<br />

High resolution TEM<br />

provides direct<br />

visualization of<br />

graphitic, fullerenic<br />

<strong>and</strong> amorphous<br />

contents of soot.<br />

Surface Chemistry<br />

Defective<br />

sp3<br />

Carboxylic<br />

-C-OOH<br />

Phenolic<br />

-C-OH<br />

Graphitic<br />

sp2<br />

Survey XPS scans provide elemental content High res. XPS scans provide surface chemistry<br />

PI: Dr. R<strong>and</strong>y L. V<strong>and</strong>er Wal (USRA @ <strong>NASA</strong>-Glenn) Support: <strong>NASA</strong> Aero2007 NRA<br />

31

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