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National Biomethane Summit - Low Carbon Fuels Conference Series

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The Potential of <strong>Biomethane</strong> from<br />

Municipal Solid Waste Resources<br />

<strong>National</strong> <strong>Biomethane</strong> <strong>Summit</strong><br />

June 23, 2009<br />

Sacramento, CA<br />

Fernando Berton


Biomass Resources in California<br />

• Gross resources are 80<br />

million bone dry tons<br />

annually<br />

• Three principal resources are<br />

agriculture, forestry, and<br />

waste<br />

• Forestry in northern and<br />

central mountains<br />

• Agriculture in Central Valley<br />

• Waste in Los Angeles and San<br />

Francisco Bay Area


Disposal Vs Diversion<br />

45<br />

70<br />

40<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

17<br />

5 7.8<br />

60<br />

58<br />

54 50<br />

52<br />

48<br />

47<br />

48<br />

44<br />

40<br />

42<br />

37<br />

31<br />

32<br />

33<br />

30<br />

28<br />

24<br />

25<br />

20<br />

20<br />

21<br />

10<br />

7.1 6.8 6.4 6.3 6.2 6 6 6.1 6.1 6.1 6 5.9 6.1 6.2 6.3 6.2 5.8<br />

Disposal (millions)<br />

Population (millions)<br />

Per Capita Disposal<br />

(lb/person/day)<br />

Estimated Statewide<br />

Diversion Rate (% of<br />

Generation)<br />

0<br />

0


Potential Feedstock<br />

Waste Management & Energy<br />

Production<br />

39 Million TPY Disposed<br />

Reduce Reliance on Landfills<br />

Alternatives to Natural Gas<br />

Achieve 33% Threshold of<br />

Renewable Energy by 2020<br />

<strong>Low</strong> <strong>Carbon</strong> Fuel Standard


California Waste Characterization<br />

(2008 Preliminary)<br />

Lumber<br />

Food<br />

Remainder/Composite Inerts<br />

and Other<br />

Remainder/Composite Paper<br />

Uncoated Corrugated Cardboard<br />

Remainder/Composite Organic<br />

Bulky Items<br />

Rock, Soil and Fines<br />

• 39.7 million tons<br />

disposed in 2008<br />

• 25.3 million tons<br />

organics<br />

• Food waste ~ 5.7<br />

million tons<br />

Leaves and Grass<br />

Carpet


Energy Potential<br />

Source: Rob Williams, California Biomass Collaborative


Anaerobic Digestion Feedstocks<br />

<strong>Biomethane</strong> Potential (BMP) of some feedstocks<br />

Energy in Biogas per wet pound of feedstock<br />

CH 4 Generated<br />

(BTU/lb input)<br />

Vegetable oil 16024<br />

Office paper 5609<br />

Corrugated paper 4389<br />

MSW C 2586<br />

MSW B 2466<br />

MSW D 2387<br />

Food waste 1969<br />

MSW A 1918<br />

Newspaper 1534<br />

Branches 1519<br />

Grass 1161<br />

Blend of grass, leaves, branches 1130<br />

Leaves 1123<br />

Sources:<br />

Chynoweth, et.al., (1993)<br />

Owens and Chynoweth (1993)<br />

Eleaser, et.al., (1997)<br />

Tchobanoglous, et.al.., (1993)


Biogas and Methane Yield<br />

Biogas Yield Methane Yield Methane<br />

Waste Type<br />

Retention in<br />

drum (days)<br />

ml/g VS ft 3 /dry ton ft 3 /dry ton<br />

Content<br />

of biogas<br />

(%)<br />

1 474 12666 7223 60<br />

A: MSW and Biosolids<br />

2 456 11892 7148 60<br />

3 413 10480 6415 60<br />

B: MSW, Paper Cardboard<br />

and Biosolids<br />

1 435 11118 6478 60<br />

2 481 11750 7085 59<br />

3 469 12455 7510 59<br />

1 485 12123 6822 63<br />

C: MSW<br />

2 474 12224 7308 61<br />

3 448 12019 7276 60<br />

D: MSW and Paper &<br />

Cardboard<br />

Food Waste<br />

1 395 10458 5872 62<br />

2 454 12316 7337 59<br />

3 457 12895 7839 61<br />

- 511 17383 9630 64<br />

Source: Zang, et.al. Anaerobic Digestion of Municipal Solid Waste for Biogas Energy and Compost Production: Evaluation of Biomixer<br />

Process as a Pretreatment Technology, UC Davis, May 2007


Biogas Production<br />

160<br />

140<br />

1day 2days 3days<br />

____ Daily Biogas Yield<br />

_ _ _ Cumulative Biogas Yield<br />

700<br />

600<br />

160<br />

140<br />

1day 2days 3days<br />

____ Daily Biogas Yield<br />

_ _ _ Cumulative Biogas Yield<br />

700<br />

600<br />

Daily Biogas Yield (ml/gVS • day)<br />

120<br />

100<br />

80<br />

60<br />

40<br />

500<br />

400<br />

300<br />

200<br />

Cumulative Biogas Yield (ml/gVS)<br />

Daily Biogas Yield (ml/gVS • day)<br />

120<br />

100<br />

80<br />

60<br />

40<br />

500<br />

400<br />

300<br />

200<br />

Cumulative Biogas Yield (ml/gVS)<br />

20<br />

100<br />

20<br />

100<br />

0<br />

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20<br />

Digestion Time (day)<br />

0<br />

0<br />

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20<br />

Digestion Time (day)<br />

0<br />

MSW/Biosolids Mix (2:1)<br />

MSW Alone<br />

Source: Zang et.al. - Anaerobic Digestion of Municipal Solid Waste for Biogas Energy and Compost Production: Evaluation of Biomixer Process as<br />

a Pretreatment Technology, UC Davis, 2007


Biogas Energy Potential<br />

1 m 3 of biogas<br />

Equals 1 lb of LPG<br />

Calorific value ~ 24 MJ/m3 (5.5 to<br />

6.5 kWh/m 3 )<br />

Contains 65% CH 4 & 35% CO 2<br />

Source: 1) Government of Alberta, Agriculture and Rural Development<br />

2) Senederra, et.al. University of Adelaide


AD Capacity in Europe<br />

Source: Contractor Report to the CIWMB: Current Anaerobic Digestion Technologies Used for Treatment of Municipal Organic<br />

Solid Waste; Zang, et.al. UC Davis, March 2008


Lifecycle Analysis<br />

Source: Contractor Report to the CIWMB: Current Anaerobic Digestion Technologies Used for Treatment of Municipal Organic<br />

Solid Waste; Zang, et.al. UC Davis, March 2008


What About California<br />

Los Angeles County<br />

City of Los Angeles<br />

East Bay Municipal Utility District<br />

Sacramento Municipal Utility District


Conclusions<br />

Materials being landfilled have energy value<br />

Technologies exist to harness value<br />

Creates energy or biofuels<br />

Can meet multiple policy goals<br />

Overall positive LCA benefits


Contact Information<br />

Fernando Berton<br />

fberton@ciwmb.ca.gov<br />

(916) 341-6607

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