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Worksheet Electrons

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Chemistry <strong>Worksheet</strong>: Light : Chapt 13 : p. 372-375 Page 2<br />

1. Arrange the following electromagnetic radiations in order of decreasing wavelength.<br />

a. Infrared radiation from a heat lamp, (b) ultraviolet radiation from the sun, (c) dental X-rays,<br />

(d) the signal from a short wave radio station, (e) green light _______________<br />

2. Arrange the radiation from prob. 1 in order of increasing energy. ________________<br />

Constants and Equations you will need:<br />

!= “nu” = frequency of radiation, Hz, 1/sec or sec –1 " = “lambda”= wavelength of radiation<br />

h = Planck’s constant = 6.63 x 10 –34 Joules–sec c = 3.00 x 10 8 m/sec (speed of light)<br />

c = ! " (Relationship between E = h ! or E = h c (Energy of a photon of light)<br />

frequency and wavelength) "<br />

Metric conversions: 1 x 10 9 nm = 1 m 1 x 10 6 µm = 1 m 1 x 10 3 Hz = 1 kHz<br />

3. a. What is the wavelength in m of radiation whose frequency is 1.5 x 10 15 sec –1 (2x10 –7 m)<br />

b. Convert this wavelength to nm. (200 nm)<br />

c. In what part of the EM spectrum is this radiation ________<br />

d. Does this radiation have a longer or shorter wavelength than red light ________<br />

4. What is the frequency of green light with a wavelength of 5.20 x 10 –7 meters (5.77x10 14 Hz)<br />

What part of the EM spectrum is this radiation<br />

5. Radio Station WTIC AM in Hartford, CT, broadcasts at a frequency of 1080 KiloHz.<br />

a. What is this frequency in Hz (1.08 x10 6 Hz)<br />

b. What is the wavelength in m of these radio waves (278 m)<br />

c. Convert this wavelength to cm. (2.78x10 4 cm)<br />

6. What is the energy of a photon of microwave radiation with frequency = 7.6 x 10 11 sec –1 <br />

(5.04x10 –22 J)<br />

7. What is the energy of a photon of radiation with a wavelength of 6.0 x 10 –5 m Is this more or<br />

less energy than that of Question 6 (3.32 x 10 –21 J)<br />

8. What is the energy of a photon of light with a wavelength of 4.5 x 10 –2 nm What part of the<br />

EM Spectrum is this photon (hint: change nm to m first). (4.42 x10 –15 J)


Electron configurations and notations: p. 367-370 Page 3<br />

Fill in this chart for the electron configuration of these elements<br />

Symbol Atomic Electron configuration Orbital notation (do to Ar only)<br />

_________number_____________________________________________________________________<br />

N 7 1s 2 2s 2 2p 3 #$ #$ # # # (7 arrows)<br />

(7 electrons) (superscripts total 7) 1s 2s 2p<br />

_________________________________________________________________________________<br />

H 1<br />

_________________________________________________________________________________<br />

He 2<br />

_________________________________________________________________________________<br />

Be 4<br />

_________________________________________________________________________________<br />

C 6<br />

_________________________________________________________________________________<br />

O 8<br />

_________________________________________________________________________________<br />

*Ne 10<br />

_________________________________________________________________________________<br />

Mg 12 [Ne]<br />

_________________________________________________________________________________<br />

Al 13 [Ne]<br />

_________________________________________________________________________________<br />

P 15 [Ne]<br />

_________________________________________________________________________________<br />

*Ar 18 [Ne]<br />

_________________________________________________________________________________<br />

1. How many electrons are in the 2nd energy level of : (Add 2s and 2p together!)<br />

Be N O Ne Mg Ar<br />

2. How many electron pairs ( #$ ) are in :<br />

Be N O Ne<br />

You may use the "core method" for the following. Be sure to start with the previous *Noble<br />

Gas. Omit the orbital notation!<br />

Sym. Atomic Electron config. Symbol Atomic Electron config.<br />

number (omit orbitals) number (omit orbitals)<br />

_________________________________________________________________________________<br />

K 19 [ Ar ] 4s 1 Co 27<br />

_________________________________________________________________________________<br />

Ca 20 Br 35<br />

________________________________________________________________________<br />

Sc 21 *Kr 36


Electron configurations and notations: continued Page 4<br />

Sym. Atomic Electron config. Symbol Atomic Electron config.<br />

number (omit orbitals) number (omit orbitals)<br />

_____________________________________________________________________________________<br />

Rb 37 [Kr] Nd 60<br />

__________________________________________________________________________________<br />

Zr 40 Er 68<br />

_________________________________________________________________________________<br />

Sn 50 Ir 77<br />

__________________________________________________________________________________<br />

*Xe 54 Bi 83<br />

__________________________________________________________________________________<br />

Ba 56 [Xe] *Rn 86<br />

_________________________________________________________________________________<br />

Cr 24 (Exception to rule: Will be done in class: Pay attention!)<br />

__________________________________________________________________________________<br />

Questions with Electron configurations<br />

Use your answers from above and the previous worksheet to help you answer Q. 1 – 5<br />

1. How many electrons are in the outside, or highest occupied energy level of the following: (Hint:<br />

Add together the highest s and p sublevels!) Example: Kr has 8 (2 in 4s, 6 in 4p)<br />

C P Sc Br Rb Xe<br />

2. Which of these has an octet (s 2 p 6 ) as its outer electron configuration<br />

Mg Ar Sc Kr Sn Xe<br />

3. Which of these has its 3rd energy level completely filled (Hint: 3s 2 3p 6 3d 10 )<br />

P Ar Ca Co Br Kr Rb<br />

4. Which of these has its 4th energy level completely filled(What sublevels are in 4th level)<br />

Kr Sn Xe Nd Er Ir Bi<br />

5. How many energy levels are occupied in each of the following (Short cut: Row number on<br />

periodic table)<br />

C Mg Ar K Br Rb Zr Xe Nd Bi<br />

6. Which of these orbital notations is a correct, ground state configuration What rule do the<br />

others violate<br />

a. # # #$ # # # c. # $# #$ # # #<br />

1s 2s 2p 1s 2s 2p<br />

b. # $ #$ # # d. # $ #$ # $ #<br />

1s 2s 2p 1s 2s 2p<br />

1) 4, 5, 2, 7, 1, 8; 2) Ar, Kr, Xe (noble gases); 3) Br, Kr, Rb; 4) Ir, Bi; 5) 2, 3, 3, 4, 4, 5, 5, 5, 6, 6) b correct; a& c violate<br />

Pauli Prin. ; d violate Hund's rule


Review questions: <strong>Electrons</strong> : p. 361-383 Page 5<br />

1. What is the wavelength in meters and cm of waves with a frequency of 5 x 10 6 sec –1 . What<br />

part of the EM spectrum is this<br />

(60 m, 6000 cm)<br />

2. What is the wavelength and energy of a photon of with a frequency of 5.80 x 10 14 sec -1 <br />

What color is the photon (3.85 x 10 -19 J)<br />

3. Consider the orbital notation for Oxygen: #$ #$ #$ # #<br />

1s 2s 2p<br />

The "2" in 2s and 2p stands for the ___________, the "p" and "s" stand for the ________<br />

the lines above the "2p" stand for the _____________, and the arrows _____________.<br />

4. Consider the 4th energy level: What sublevels are found there _______________<br />

How many orbitals of each type of sublevel are there ________________________<br />

How many electrons can occupy each of these sublevels___________________<br />

How many electrons are needed to completely fill the 4th energy level _____<br />

5. Circle the correct filling order for the sublevels for elements in the 4th series (K - Kr).<br />

4s 4p 4d 4s 3p 4d 4s 4d 4p 4s 3d 4p<br />

6. Give the electron configuration (1s 2 ) and orbital notation (arrows) for the following:<br />

B _____________ ______________ S<br />

Ni<br />

Omit orbital ______________________<br />

___________ _______________<br />

Calculatrivia for electron configurations: Solve the following.<br />

a. Number of 4s electrons in Sc ______ b. Number of electrons in H ______<br />

c. Highest energy level occupied in Neodymium (Nd) ______<br />

d. Atomic number of the lowest element with an octet ______<br />

e. Atomic weight of element with configuration 1s 2 2s 2 2p 6 3s 1 ______<br />

f. Number of electrons in the highest energy level of Br ______<br />

g. Number of electron pairs in oxygen ______<br />

h. Number of orbitals in the entire 3rd energy level ______<br />

j. Theoretical maximum number of electrons in the 5th energy level (2n 2) ______<br />

k. Theoretical number of sublevels in the 7th energy level ______<br />

m. Lowest energy level with a d sublevel ______<br />

Substitute your answers into the following equation. Then show me the element with this<br />

atomic number<br />

g<br />

(( h m ) – e ) ( d – b) + ( j – ( k f ))<br />

c a<br />

Ans to calculatrivia: a. 2; b. 1; c. 6; d. 10; e. 23; f. 7; g. 3; h. 9; j. 50; k . 7; m. 3

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