Safety data sheet - Lex doo

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Safety data sheet
According to regulation (EC) N o . 1907/2006
ALCOHOL BENZYLICUS
Revision date (edition 13): 06.05.2013
Replace version: 16.11.2012
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product code:
Product name:
1.2 Relevant identified uses of the substance or
mixture and uses advised against
1.3 Details of the supplier of the safety data sheet
Tel.:
Fax:
e-mail:
1.4 Emergency telephone number
0966
BENZYL ALCOHOL
No information available.
Lex, d.o.o., Vanganelska c. 26, 6000 Koper
05 625-18-10
05 625-18-12
info@lex.si
In case of poisoning consult your doctor or call Emergency, phone: 112.
2. Hazards identification
2.1 Classification of the substance or mixture
Classification GHS ((EC) No. 1272/2008): Acute Tox. 4
Acute Tox. 4
H302 Harmful if swallowed.
H332 Harmful if inhaled.
Classification ES (67/548/EEC, 1999/45/EC): Xn Harmful R20/22 Harmful by inhalation and if swallowed.
2.2 Label elements
Labelling GHS ((EC) No. 1272/2008):
Hazard pictograms:
Signal word:
Hazard statements:
Precautionary statements:
Warning
H302
H332
P280
P301+P313
2.3 Other hazards None known.
Harmful if swallowed.
Harmful if inhaled.
Wear protective gloves/protective clothing/eye protection/
face protection.
IF SWALLOWED:Get medical advice/attention.
3. Composition/Information on ingredients
3.1 Substance
Chemical formula:
C7H8O BENZYL ALCOHOL
Molar mass:
108,1 g/mol
CAS: 100-51-6
EINECS: 202-859-9
Index: 603-057-00-5
3.2 Mixtures No information available.
4. First aid measures
4.1 Description of first aid measures
Inhalation:
Skin contact:
Eye contact:
Bring the person out of the contaminated area to fresh air, assure medical help immediately.
Show product label or this MSDS.
Take off contaminated clothes and shoes, wash immediately with plenty of water and soap.
Rinse out with plenty of water with the eyelid wide open. Call in ophthalmologist.
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
ALCOHOL BENZYLICUS
product code: 0966
Ingestion:
4.2 Most important symptoms and effects, both
acute and delayed
4.3 Indication of immediate medical attention and
special treatment needed
Drink plenty of water. Avoid vomiting. Danger of aspiration! Get medical advice.
No information available. See also chapter 11.
Medical advice: gastrolavage.
5. Fire-fighting measures
5.1 Extinguishing media All regular extinguishing media can be used. Select fire fighting measures suitable to
surrounding environment.
5.2 Special hazards arising from the substance or
mixture
5.3 Advice for fire-fighters
Special protective equipment for fire-fighters:
Additional information:
6. Accidental release measures
Combustible. Vapours heavier/denser than air. With air explosive mixtures can be formed.
Suitable protective clothes and respiratory protection
Prevent fire-extinguishing water from contaminating surface water, the ground water system or
soil. Residues must be deposited according to local regulations.
6.1 Personal precautions: Avoid contact with substance. Do not inhale vapours. Good ventilation of working place.
6.2 Environmental precautions Prevent from entering into surface water, the ground water system or soil.
6.3 Methods and materials for containment and
cleaning up
Absorb with liquid-binding material: sand, silica gel, acid binder, universal binder, saw dust.
Disposal according to section 13 of this MSDS.
6.4 Reference to other sections Any information regarding personal protection and disposal can be found in sections 8 and 13.
7. Handling and storage
7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Handling corresponding to laboratory
safety guidelines. Keep away from ignition sources. Do not smoke.
7.2 Conditions for safe storage, including any
incompatibilities
Requirements for storage areas and containers:
Advices on common storage:
VCI storage class:
Keep container tightly closed. Store at a good ventilated place. Keep away from heat and
ignition sources. Store at a cool place (+2 to +8 °C).
Not required.
7.3 Specific end uses No information available.
8. Exposure controls/personal protection
8.1 Control parameters No information available.
8.2 Exposure controls
General protective and hygiene measures:
Respiratory protection:
Hand protection:
Eye protection:
9. Physical and chemical properties
3 B
9.1 Information on basic physical and chemical properties
Form:
Colour:
Odour:
The usual precaution measures during handling of chemicals are to observe.
Only required if aerosols or vapours are generated.
Protection gloves of rubber or latex or PVC, for full contact 15 minutes maximum: neopren.
Suitable gloves for enduring contact, material: nitrile rubber/nitrile latex, penetration time >
480 min., thickness: 0,35 mm.
Safety glasses
liquid
colourless
characteristic
Melting point: -15,3 °C
Boiling point: 205,4 °C
Flash point:
Explosion hazard:
101 ˚C
Explosion limits: lower: 1,3 vol. %
upper: 13 vol. %
Vapour pressure: (20 ˚C) 0,13 hPa
The product is not explosive, but explosive mixtures of vapour with air can be formed.
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
ALCOHOL BENZYLICUS
product code: 0966
Density: (20 ˚C) 1,04 g/cm 3
Solubility in water: (20 ˚C) 39 g/l
9.2 Other data No information available.
10. Stability and reactivity
10.1 Reactivity No information available.
10.2 Chemical stability No information available.
10.3 Possibility of hazardous reactions No information available.
10.4 Conditions to avoid No information available.
10.5 Incompatible materials Oxidizing agents, non-metal halogenides, concentrated sulphuric acid, polymerisation initiators.
Unsuitable materials: some plastics.
10.6 Hazardous decomposition products No information available.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity:
Carcinogenicity:
Other information:
12. Ecological information
12.1 Toxicity
Aquatic toxicity:
Draize test, rabbit, skin: 100 mg/24 h moderate
LC50 (inhalation, mouse): > 500 mg/m 3
LC50 (inhalation, rat): > 500 mg/m 3
LD50 (oral, mouse): 1360 mg/kg
LD50 (oral, rabbit): 1040 mg/kg
LD50 (skin, rabbit): 2000 mg/kg
LD50 (skin, rat): 100 pph/90M
According to ACGIH, IARC, NTP, or CA Prop 65 not classified as carcinogene.
See actual entry in RTECS for complete information.
Fish toxicity (LC50): Leuciscus idus 646 mg/l/48h
Daphnia toxicity (EC50): Daphnia magna 400 mg/l
Bacteria toxicity (EC50): Pseudomonas putida > 658 mg/l
Algea l toxicity (EC50): Scenedesmus quadrica 640 mg/l/96h
Behaviour in sewage plants: Activated sludge bacteria in a model sewage plant are not harmed by concentrations of 100
mg/l.
General advices:
12.2 Persistence and degradability Elimination: > 90 %
12.3 Bioaccumulative potential No information available.
12.4 Mobility in soil No information available.
12.5 Results of PBT and vPvB assessment No information available.
12.6 Other adverse effects No information available.
13. Disposal considerations
13.1 Waste treatment methods
Product:
Packaging:
14. Transport information
Not classified as dangerous in the meaning of transport regulations.
15. Regulatory information
Water hazard class (German regulation) 1 (VwVwS): slightly hazardous for water. Prevent from
leaking into ground water, environment waters or drainage.
Reuse, if possible. The residues of the product are to be considered special hazardous waste.
Lex product packaging must be disposed of in compliance with the country specific regulations
or must be passed to a packaging return system. Under www.slopak.si you will find special
information on the respective national conditions.
Chemicals must be disposed of in compliance with the respective national regulations. Under
www.slopak.si you will find country and substance specific information for disposal.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Classification GHS ((EC) No. 1272/2008)
NIOSH -Registry of toxic effects of chemicals substances (1983)
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
ALCOHOL BENZYLICUS
product code: 0966
I.N.R.S. -Fiche toxicologique
15.2 Chemical Safety Assessment No chemical safety assessment has been processed for the mixture and the substances it
contains.
16. Other information
Full text of H-Statements referred to under section 2.
H302 Harmful if swallowed.
H332 Harmful if inhaled.
Full text of R-phrases referred to under section 2.
R20/22 Harmful by inhalation and if swallowed.
Further information
Other information: This version replaces all previous versions.
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si