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Physics Graduate Brochure - Physics - North Carolina State University

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structure in films determines the energies of electronic<br />

transport states. In addition, the group has developed<br />

the capability to carry out spin polarized STM/STS for<br />

the purpose of understanding the interaction between<br />

magnetic surfaces and adsorbed molecules. These<br />

fundamental experiments provide the scientific<br />

foundation for optimizing applications of organic<br />

molecular materials in electronic and spintronic<br />

devices. (dan_dougherty@ncsu.edu)<br />

J. E. (Jack) Rowe<br />

Prof. Rowe’s group uses measurements that include<br />

scanning tunneling microscopy (STM), atomic force<br />

microscopy (AFM), low energy electron diffraction<br />

(LEED); soft X-ray photoemission spectroscopy<br />

(SXPS) including results with synchrotron radiation<br />

(SR-SXPS) and with spin detection. A major goal of<br />

this research program is to study the initial surface and<br />

buried-interface processes of electronic materials at<br />

the nanoscale. Photoemission-based methods can<br />

measure threshold energy barriers (sometimes these<br />

are spatially resolved). One example of these studies<br />

is the organic-molecule system of a nickel<br />

phthalocyanine (NiPc) film on a Au(001) surface.<br />

SR-SXPS results from these studies are shown in the<br />

figure below. The HOMO (2a 1u ) shifts between 1.4<br />

and 3 Å indicates that the barrier is not fully formed<br />

until ~3 Å. Future experiments will also measure XPS<br />

levels such as C-1s, Ni-2p, and Au-4f.<br />

(rowe@ncsu.edu)<br />

Constant current tunneling spectrum (tip displacement<br />

versus gap voltage) showing the π* derived resonance<br />

of a single Alq3 molecule on Cu(110). Inset is a quantum<br />

mechanical calculation of the π* orbital shape.<br />

Self assembled monolayer of benzoate on Cu(110)<br />

ARUPS valence orbitals of NiPc on a Au(001) surface at<br />

~300 K. Bottom vertical lines show gas-phase data IP’s.<br />

Further Information<br />

We encourage interested applicants to learn more by visiting the faculty web pages. Prospective students can contact<br />

any faculty member directly (see email addresses above) or the <strong>Graduate</strong> Program office at py-gradprogram@ncsu.edu.<br />

.NC STATE <strong>Physics</strong>.<br />

www.physics.ncsu.edu

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