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US MSDS - Myriant

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Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

* * *Section 1 - IDENTIFICATION* * *<br />

Product Identifier<br />

Myrifilm<br />

Chemical Family<br />

Ester<br />

Recommended Use<br />

Laboratory chemicals, chemical intermediate.<br />

Restrictions on Use<br />

None known.<br />

Manufacturer Information<br />

<strong>Myriant</strong> Corporation Telephone No : +1 617-657-5200<br />

3 Batterymarch Park Email : productsafety@myriant.com<br />

3 rd Floor Emergency Phone No : CHEMTREC: 800-424-9300<br />

Quincy, MA 02169<br />

* * *Section 2 - HAZARD(S) IDENTIFICATION* * *<br />

Classification in accordance with 29 CFR 1910.1200.<br />

No classification is assigned, based on classification criteria. Review the entire data sheet for any additional<br />

information which did not result in a GHS classification.<br />

GHS LABEL ELEMENTS<br />

Symbol(s)<br />

None needed according to classification criteria.<br />

Signal Word<br />

None needed according to classification criteria.<br />

Hazard Statement(s)<br />

None needed according to classification criteria.<br />

Precautionary Statement(s)<br />

Prevention<br />

None needed according to classification criteria.<br />

Response<br />

None needed according to classification criteria.<br />

Storage<br />

None needed according to classification criteria.<br />

Disposal<br />

Dispose in accordance with all applicable regulations.<br />

____________________________________________________________<br />

Page 1 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

5/3/2013


Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

* * *Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS* * *<br />

CAS Component Percent<br />

Trade secret Proprietary >99<br />

* * *Section 4 - FIRST-AID MEASURES* * *<br />

Description of Necessary Measures<br />

Inhalation<br />

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate<br />

medical attention.<br />

Skin Contact<br />

Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get<br />

medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.<br />

Eye Contact<br />

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.<br />

Ingestion<br />

Get medical attention, if needed.<br />

Most Important Symptoms/Effects<br />

Acute<br />

No information on significant adverse effects.<br />

Delayed<br />

No information on significant adverse effects.<br />

Indication of Immediate Medical Attention and Special Treatment Needed, If Needed<br />

Provide general supportive measures and treat symptomatically.<br />

* * *Section 5 - FIRE-FIGHTING MEASURES* * *<br />

Suitable Extinguishing Media<br />

Dry chemical, carbon dioxide, foam, water spray.<br />

Unsuitable Extinguishing Media<br />

None known.<br />

Special Hazards Arising from the Chemical<br />

Negligible fire and explosion hazard in bulk form. Upon decomposition, this product emits carbon monoxide,<br />

carbon dioxide and/or low molecular weight hydrocarbons.<br />

Special Protective Equipment and Precautions for Firefighters<br />

Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against<br />

possible exposure.<br />

Fire Fighting Measures<br />

Move container from fire area if it can be done without risk. Keep unnecessary people away, isolate hazard area<br />

and deny entry. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or<br />

combustion by-products. Stay upwind and keep out of low areas.<br />

____________________________________________________________<br />

Page 2 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

5/3/2013


Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

* * *Section 6 - ACCIDENTAL RELEASE MEASURES* * *<br />

Personal Precautions, Protective Equipment and Emergency Procedures<br />

Wear personal protective clothing and equipment, see Section 8. Keep unnecessary people away, isolate hazard<br />

area and deny entry. Collect spillage. In case of spillage, stop the flow of material and block any potential routes<br />

to water systems. Avoid release to the environment. Only personnel trained for the hazards of this material should<br />

perform clean up and disposal.<br />

Methods and Materials for Containment and Cleaning Up<br />

Keep out of water supplies, sewers and soil. In case of spillage, stop the flow of material and block any potential<br />

routes to water systems. Keep container tightly closed.<br />

* * *Section 7 - HANDLING AND STORAGE* * *<br />

Precautions for Safe Handling<br />

Do not handle until all safety precautions have been read and understood. Keep away from all ignition sources.<br />

Always wear recommended personal protective equipment. Wear personal protective clothing and equipment,<br />

see Section 8.<br />

Conditions for Safe Storage, including any Incompatibilities<br />

Store in a cool, dry place. Store in a well-ventilated area. Keep separated from incompatible substances. Keep<br />

separated from incompatible substances. Store and handle in accordance with all current regulations and<br />

standards.<br />

Incompatibilities: oxidizing materials.<br />

* * *Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION* * *<br />

Component Exposure Limits<br />

ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product's components.<br />

Appropriate Engineering Controls<br />

Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.<br />

Individual Protection Measures, such as Personal Protective Equipment<br />

Eyes/Face Protection<br />

Wear splash resistant safety goggles.<br />

Skin Protection<br />

Wear appropriate chemical resistant clothing.<br />

Glove Recommendations<br />

Wear appropriate chemical resistant gloves.<br />

Respiratory Protection<br />

A NIOSH approved air-purifying respirator with an appropriate cartridge or canister may be appropriate under<br />

certain circumstances where airborne concentrations are expected to exceed exposure limits.<br />

____________________________________________________________<br />

Page 3 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

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Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

* * *Section 9 - PHYSICAL AND CHEMICAL PROPERTIES* * *<br />

Physical State:<br />

Color :<br />

Slightly viscous liquid<br />

Colorless<br />

Appearance:<br />

Odor :<br />

Not available<br />

Low odor<br />

Odor Threshold: Not available Melting Point: Not available<br />

pH: not available Boiling Point: 358.9 °C<br />

Flash Point: 158 °C Decomposition: Not available<br />

Evaporation Rate: Not available OSHA Flammability Class: Not Flammable<br />

LEL: Not available UEL: Not available<br />

Vapor Pressure: Not available Vapor Density(air = 1): Not available<br />

Density : Not availablle Specific Gravity (water = 1): 0.934<br />

Water Solubility: Not available KOW: Not available<br />

Log KOW: Not available Coeff. Water/Oil Dist: Not available<br />

KOC: Not available VOC: Not available<br />

Molecular Weight: 342.51 Molecular Formula: Proprietary<br />

* * *Section 10 - STABILITY AND REACTIVITY* * *<br />

Reactivity<br />

No reactivity hazard is expected.<br />

Chemical Stability<br />

Stable at normal temperatures and pressure.<br />

Possibility of Hazardous Reactions<br />

Will not polymerize.<br />

Conditions to Avoid<br />

Avoid generating dust.<br />

Incompatible Materials<br />

Oxidizing materials.<br />

Hazardous Decomposition Products<br />

Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight<br />

hydrocarbons.<br />

* * *Section 11 - TOXICOLOGICAL INFORMATION* * *<br />

Acute Toxicity<br />

Component Analysis - LD50/LC50<br />

The components of this material have been reviewed in various sources and no selected endpoints have been<br />

identified.<br />

Information on Likely Routes of Exposure<br />

Inhalation<br />

No information available for the product.<br />

Ingestion<br />

No information available for the product.<br />

Skin Contact<br />

No information available for the product.<br />

____________________________________________________________<br />

Page 4 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

5/3/2013


Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

Eye Contact<br />

Irritation<br />

Immediate Effects<br />

No information on significant adverse effects<br />

Delayed Effects<br />

No information on significant adverse effects.<br />

Medical Conditions Aggravated by Exposure<br />

None known.<br />

Irritation/Corrosivity Data<br />

Non-irritating to rabbit skin.<br />

Respiratory Sensitization<br />

No data available.<br />

Dermal Sensitization<br />

No data available.<br />

Germ Cell Mutagenicity<br />

No data available.<br />

Carcinogenicity<br />

Component Carcinogenicity<br />

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA.<br />

Reproductive Toxicity<br />

No data available.<br />

Specific Target Organ Toxicity - Single Exposure<br />

No data available.<br />

Specific Target Organ Toxicity - Repeated Exposure<br />

No data available.<br />

Aspiration Hazard<br />

No data available.<br />

* * *Section 12 - ECOLOGICAL INFORMATION* * *<br />

Ecotoxicity<br />

No information available for the product.<br />

Component Analysis - Aquatic Toxicity<br />

No LOLI ecotoxicity data are available for this product's components.<br />

Persistence and Degradability<br />

No data available.<br />

Bioaccumulation<br />

No information available for the product.<br />

Mobility<br />

No information available for the product.<br />

Other Toxicity<br />

No additional information is available.<br />

____________________________________________________________<br />

Page 5 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

5/3/2013


Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

* * *Section 13 - DISPOSAL CONSIDERATIONS* * *<br />

Disposal Methods<br />

Dispose in accordance with all applicable regulations. Regulations vary. Consult local authorities before disposal.<br />

Disposal of Contaminated Packaging<br />

Dispose in accordance with all applicable regulations.<br />

Component Waste Numbers<br />

The U.S. EPA has not published waste numbers for this product's components.<br />

* * *Section 14 - TRANSPORT INFORMATION* * *<br />

<strong>US</strong> DOT Information<br />

Not regulated.<br />

TDG Information<br />

No Classification assigned.<br />

* * *Section 15 - REGULATORY INFORMATION* * *<br />

U.S. Federal Regulations<br />

None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section<br />

311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require<br />

an OSHA process safety plan.<br />

Acute Health: No<br />

Chronic Health: No<br />

Fire: No<br />

Pressure: No<br />

Reactive: No<br />

U.S. State Regulations<br />

None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA.<br />

Not regulated under California Proposition 65<br />

Canadian Regulations<br />

Canadian WHMIS Classification of Substances<br />

WHMIS CLASSIFICATION: Not classified.<br />

Canadian WHMIS Ingredient Disclosure List (IDL)<br />

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The<br />

List is composed of chemicals which must be identified on <strong>MSDS</strong>s if they are included in products which fall under<br />

WHMIS criteria specified in the Controlled Products Regulations and present above the threshold limits listed on<br />

the IDL.<br />

Not listed<br />

____________________________________________________________<br />

Page 6 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

5/3/2013


Safety Data Sheet<br />

Product Identifier: Myrifilm SDS ID: M-004<br />

Chemical Inventory Listings<br />

Component Analysis - Inventory<br />

Component CAS <strong>US</strong> CA EU AU PH JP KR CN NZ<br />

Proprietary Trade secret Yes DSL EIN Yes Yes Yes Yes Yes Yes<br />

* * *Section 16 - OTHER INFORMATION* * *<br />

Summary of Changes<br />

NFPA Ratings: Health: 0 Fire: 1 Reactivity: 0<br />

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe<br />

Key / Legend<br />

ACGIH =American Conference of Governmental Industrial Hygienists; AU = Australia; BOD = Biochemical<br />

Oxygen Demand; C = Celsius; CA = California; CA = Canada; CAS = Chemical Abstract Service; CERCLA =<br />

Comprehensive Environmental Response, Compensation and Liability Act; CFR = Code of Federal Regulations;<br />

CN = China; DOT = Department of Transportation; DSL = Canadian Domestic Substance List; EPA =<br />

Environmental Protection Agency; EU = European Union; IARC = International Agency for Research on Cancer;<br />

IDL = Ingredient Disclose List; IDLH = Immediately Danger to Life and Health; JP = Japan; KR = Korea; LC50 =<br />

Lethal Concentration; LD50 = Lethal Dose; LEL = Lower Explosive Limit; NIOSH = National Institute of<br />

Occupational Safety and Health; NJTSR = New Jersey Trade Secret Registry; NTP = National Toxicology<br />

Program; NZ = New Zealand; OEL = Occupational Exposure Limit; OSHA = Occupational Safety and Health<br />

Administration; PEL = Permissible Exposure Limit; PH = Philippines; RQ = Reportable Quantity; SARA =<br />

Superfund Amendments Act; SDS = Safety Data Sheet; STEL = Short-term Exposure Limit; TDG =<br />

Transportation of Dangerous Goods; TLV = Threshold Limit Value; TSCA = Toxic Substance Control Act; TWA =<br />

Time Weighted Average; UEL = Upper Explosive Limit; UN = United Nations; <strong>US</strong> = United State; WHMIS =<br />

Workplace Hazardous Materials Information System<br />

Other Information<br />

The information contained in this document express our current knowledge and experience, however cannot<br />

imply guarantee of any nature. Considering the variety of factors that can affect their process or application, the<br />

information on this sheet does not exempt the processors from the responsibility of executing their own tests and<br />

experiments.<br />

____________________________________________________________<br />

Page 7 of 7 Issue Date: 08/06/12 Revision 1.0000 Print Date:<br />

5/3/2013

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