14.05.2015 Views

(E) PDF here - Petron

(E) PDF here - Petron

(E) PDF here - Petron

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 1 of 7<br />

CHEMICAL SAFETY DATA SHEET<br />

SECTION 1:<br />

PRODUCT AND COMPANY IDENTIFICATION<br />

As of the revision date above, this CSDS meets the regulations in Malaysia.<br />

PRODUCT<br />

Product Name:<br />

Product Description:<br />

Intended Use:<br />

COMPANY IDENTIFICATION<br />

Supplier:<br />

HYDROTUR R<br />

Mineral Base Oil and Additives<br />

Circulating Oil<br />

<strong>Petron</strong> Fuel International Sdn Bhd (4527-V)<br />

Menara I&P (Tower 1), Level 12A,<br />

No. 46, Jalan Dungun<br />

Damansara Heights<br />

50490 Kuala Lumpur<br />

General Contact: 03-2082 8400<br />

SECTION 2:<br />

COMPOSITION / INFORMATION ON INGREDIENTS<br />

“Petroleum Hydrocarbons and Additives”<br />

The composition of this product is proprietary information. In general, the product contain components<br />

that may be a significant health and safety hazard thus proper handling petroleum products and observing<br />

precautions must be observed and good standards of industrial and personal hygiene must be maintained.<br />

SECTION 3:<br />

PHYSICAL AND CHEMICAL PROPERTIES<br />

Note: Physical and chemical properties are provided for safety, health and environmental considerations<br />

only and may not fully represent product specifications. Contact the Supplier for additional information.<br />

Hydrotur R 32 46 68 100 150 220 320 400<br />

Specific Gravity at 60 o F 0.8705 0.8686 0.8735 0.8883 0.8951 0.8985 0.9024 0.9042<br />

Appearance Clear Clear Clear Clear Clear Clear Clear Clear<br />

Odor --------------------------- Characteristic of petroleum product --------------------<br />

Flash Point, COC, o C 210 218 230 254 260 272 280 290<br />

Viscosity at 40 o C, cSt 31.10 45.00 65.20 105.0 149.0 220.0 320.0 407.0<br />

Viscosity at 100 o C, cSt 5.40 6.82 8.61 11.51 14.50 18.81 23.96 27.80<br />

pH - - - - - - - -<br />

Boiling Point, °C - - - - - - - -


Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 2 of 7<br />

Pour Point, °C - - - - - - - -<br />

Vapor Pressure, kPa - - - - - - - -<br />

Vapor Density - - - - - - - -<br />

Solubility in Water ---------------------- Not soluble /Immiscible ----------------------<br />

Evaporation Rate - - - - - - - -<br />

Partition Coefficient - - - - - - - -<br />

SECTION 4:<br />

HAZARDS IDENTIFICATION<br />

This material is not considered to be hazardous according to regulatory guidelines (see CSDS Section 15).<br />

HEALTH HAZARDS<br />

Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory<br />

irritation. High-pressure injection under skin may cause serious damage.<br />

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without<br />

expert advice. Health studies have shown that chemical exposure may cause potential human health risks<br />

which may vary from person to person.<br />

SECTION 5:<br />

INHALATION<br />

SKIN CONTACT<br />

EYE CONTACT<br />

INGESTION<br />

FIRST AID MEASURES<br />

This product is not expected to present an inhalation problem at ambient<br />

temperature. However, if overexposed to oil mist, using proper respiratory<br />

protection, immediately remove the affected person immediately to fresh air.<br />

Administer artificial respiration if breathing is stopped. Keep at rest. Call for<br />

prompt medical attention.<br />

Immediately flush with large amount of water; use soap if available. Remove<br />

contaminated clothing and shoes, and launder before reuse.<br />

Immediately flush eyes with large amount of water for at least 15 minutes or until<br />

irritation subsides. If irritation persists, get prompt medical attention.<br />

If swallowed, DO NOT induce vomiting. If individual is conscious, give milk or<br />

water to dilute stomach contents. Keep warm and quiet. Get immediate medical<br />

attention. DO NOT attempt to give anything by mouth to an unconscious person.<br />

SECTION 6:<br />

FIRE FIGHTING MEASURES<br />

EXTINGUISHING MEDIA<br />

In case of fire use foam, carbon dioxide or dry chemical extinguishers.<br />

FIRE FIGHTING PROCEDURES<br />

Special Fire-fighting Procedures: Water jets should not be used directly on igniting products. Avoid<br />

spraying water directly into storage containers due to danger of boil-over.<br />

However, water may be used to cool exposed containers, structures and


Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 3 of 7<br />

equipment adjacent to fire. Respiratory and eye protection required for firefighting<br />

personnel.<br />

Hazardous Combustion Products: Fumes, smoke, oxides of sulfur, nitrogen, carbon and other toxic<br />

gases may be formed.<br />

FLAMMABILITY PROPERTIES<br />

Flash Point,°C (COC): Hyd R 32 (210); Hyd R46 (218); Hyd R 68 (230); Hyd R 100 (254); Hyd R 150 (260);<br />

Hyd R 220 (272); Hyd R 320 (280); Hyd R 400 (290)<br />

Auto-ignition Temperature: N/D<br />

SECTION 7:<br />

ACCIDENTAL RELEASE MEASURES<br />

NOTIFICATION PROCEDURES<br />

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable<br />

regulations.<br />

PROTECTIVE MEASURES<br />

Avoid contact with spilled material. See Section 6 for fire-fighting information. See the Hazard<br />

Identification Section for Significant Hazards. See Section 5 for First Aid Advice. See Section 8 for advice<br />

on the minimum requirements for personal protective equipment. Additional protective measures may be<br />

necessary, depending on the specific circumstances and/or the expert judgment of the emergency<br />

responders. For emergency responders: Respiratory protection: respiratory protection will be necessary<br />

only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic<br />

vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and<br />

potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient<br />

atmosp<strong>here</strong> is possible or anticipated, SCBA is recommended. Work gloves that are resistant to<br />

hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are<br />

not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is<br />

possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of<br />

chemical resistant, antistatic material is recommended.<br />

SPILL MANAGEMENT<br />

Land Spill:<br />

Taking normal safety precaution, eliminate sources of ignition. Prevent additional<br />

discharge of material, if possible to do so without hazard. For small spills,<br />

implement cleanup procedures. For large spills, implement clean-up procedures<br />

and, if in public area, keep public away and advise authorities. Prevent liquid from<br />

entering sewers, water courses, or low areas. Contain spilled liquid with sand or<br />

earth. Recover by pumping or with a suitable absorbent. If liquid is too viscous for<br />

pumping, scrape up. Consult an expert on disposal of recovered material and<br />

ensure conformity to local disposal regulations.


Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 4 of 7<br />

Water Spill:<br />

Use booms to confine spills immediately. Remove from water surface by skimming<br />

or with suitable adsorbents. If allowed by local authorities and environmental<br />

agencies, sinking and/or suitable dispersants may be used in non-confined waters.<br />

Consult an expert on disposal of recovered material and ensure conformity to<br />

local disposal regulations.<br />

SECTION 8:<br />

Handling<br />

Storage<br />

HANDLING AND STORAGE<br />

Keep away from potential sources of ignition. Open container in a well- ventilated<br />

area. Avoid breathing vapors. Keep containers closed when not in use. Wash<br />

thoroughly after handling. “Empty” containers with retained product residue<br />

(liquid or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder,<br />

drill, grind or expose containers to heat, flame, sparks, static electricity or other<br />

sources of ignition; they may explode and cause death or injury. Empty drums<br />

should be completely drained, properly bunged and promptly returned to a drum<br />

re-conditioner, or properly disposed off.<br />

Do not store near potential sources of ignition. Store in well-ventilated area.<br />

Odorous and toxic fumes may form from the decomposition of this product if<br />

stored at temperatures in excess of 60 o C for extended periods of time or if heat<br />

sources in excess of 70 o C are used.<br />

SECTION 9:<br />

EXPOSURE CONTROLS/ PERSONAL PROTECTION<br />

Exposure limits/standards for materials that can be formed when handling this product<br />

Components Source Value<br />

Petroleum Hydrocarbons and additives ACGIH<br />

OSHA<br />

5mg/m 3<br />

10 mg/m 3 (STEL)<br />

5mg/m 3<br />

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.<br />

ENGINEERING CONTROLS<br />

PERSONAL PROTECTION<br />

Respiratory Protection:<br />

The level of protection and types of controls necessary will vary<br />

depending upon potential exposure conditions. No special requirements<br />

under ordinary conditions of use and with adequate ventilation.<br />

Personal protective equipment selections vary based on potential<br />

exposure conditions such as applications, handling practices,<br />

concentration and ventilation. Information on the selection of protective<br />

equipment for use with this material, as provided below, is based upon<br />

intended, normal usage.<br />

Use self-contained breathing apparatus for entry into confined space, for


Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 5 of 7<br />

other poorly ventilated areas and for large spill clean-up sites. The use of<br />

local exhaust ventilation is recommended to control mists or vapors.<br />

Additional ventilation or exhaust may be required to maintain air<br />

concentrations below exposure limits.<br />

Hand Protection:<br />

Eye Protection:<br />

Skin and Body Protection:<br />

ENVIRONMENTAL CONTROLS<br />

Use chemical resistant gloves.<br />

W<strong>here</strong> contact may occur, wear safety glasses with side shields.<br />

Wear either a chemical protective suit or apron when potential for<br />

contact with material exists. Use neoprene or nitrile rubber boots when<br />

necessary to avoid contaminating shoes. Do not wear rings, watches or<br />

similar apparel that could entrap the material and cause a skin reaction.<br />

Comply with applicable environmental regulations limiting discharge to<br />

air, water and soil. Protect the environment by applying appropriate<br />

control measures to prevent or limit emissions.<br />

SECTION 10:<br />

Stability:<br />

Incompatibility:<br />

STABILITY AND REACTIVITY<br />

This product is stable and hazardous polymerization will not occur. However, the<br />

product should not be heated above 70 o C to avoid possible release of highly toxic<br />

hydrogen sulfide and odorous alkyl mercaptans.<br />

Strong oxidizing agents<br />

Hazardous Decomposition Products: Hydrogen Sulfide (toxic)<br />

Polymerization:<br />

Not Applicable<br />

SECTION 11:<br />

TOXICOLOGICAL INFORMATION<br />

Route of Exposure<br />

Ingestion<br />

Petroleum Hydrocarbons: Oral, LD50: >5000 mg/kg<br />

Inhalation<br />

Petroleum Hydrocarbons: Inhalation, LC50: 2.18 mg/L<br />

Conclusion / Remarks<br />

Ingestion is an unlikely event. However, if more<br />

than several mouthfuls are swallowed, abdominal<br />

discomfort, nausea, and diarrhea may occur.<br />

Minimal Toxicity.<br />

Skin<br />

Petroleum Hydrocarbons: Dermal, LD50: >2000 mg/kg<br />

Low order of toxicity. Frequent or prolonged<br />

contact may cause mild skin discomfort.


Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 6 of 7<br />

Eye<br />

Specific Target Organ Toxicity<br />

Will cause eye discomfort; may injure eye tissue if<br />

not removed promptly.<br />

Negligible hazard under ambient temperature<br />

conditions (-18 to 38°C; 0 to 100 o F). If overheated<br />

especially in the presence of water, hydrogen<br />

sulfide may be released. This can cause respiratory<br />

collapse, coma, even death without necessarily any<br />

odor being sensed. Avoid breathing vapor or mists.<br />

Repeated and prolonged over-exposure to oil mists<br />

may result in droplet deposition, inflammation and<br />

increased incidence of infection.<br />

SECTION 12:<br />

ECOLOGICAL INFORMATION<br />

The information given is based on data available for the material, the components of the material, and<br />

similar materials.<br />

ECOTOXICITY<br />

MOBILITY<br />

No data<br />

Oil component of this product floats and can migrate from water to land.<br />

PERSISTENCE AND DEGRADABILITY<br />

Biodegradation:<br />

Data have not been determined specifically for this product, but it is not expected<br />

that it will be “readily” biodegradable.<br />

BIOACCUMULATION POTENTIAL<br />

Data have not been determined specifically for this product, but it is expected to<br />

be harmful to aquatic organisms.<br />

SECTION 13:<br />

DISPOSAL INFORMATION<br />

Material, if discarded, is expected to be hazardous waste due to toxicity. Waste management should be in<br />

compliance with local and national regulations.<br />

SECTION 14:<br />

LAND<br />

SEA<br />

TRANSPORT INFORMATION<br />

This product is not regulated for road/rail transport.<br />

IMDG (Packaged Goods and BLCs). This product is not regulated for sea transport.


Product Name: HYDROTUR R<br />

Revision Date: 04 September 2012<br />

Page 7 of 7<br />

AIR<br />

(ICAO/IATA). This product is not regulated for air transport.<br />

SECTION 15:<br />

REGULATORY INFORMATION<br />

Material is not hazardous as defined by the Occupational Safety and Health (Classification, Packaging, and<br />

Labeling of Hazardous Chemicals) Regulations.<br />

CLASSIFICATION<br />

LABELING<br />

Not regulated<br />

Not regulated<br />

REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS<br />

Complies with the following national/regional chemical inventory requirements:<br />

KECI, ENCS, TSCA, AICS, DSL, IECSC, PICCS<br />

Special Cases:<br />

Inventory<br />

ELINCS<br />

Status<br />

Restrictions Apply<br />

If, however, the formulation of the lubricant does contain hazardous ingredients, then the hazardous<br />

ingredients must be declared in Section 4, and appropriate Classification clauses ( Risk (R) & Safety (S)<br />

clauses), and Labeling diagrams need to be declared in Section 15 as per Malaysian DOSH guidelines. In<br />

addition, the labeling diagrams will also need to be placed on the lubricant packing (drum, pail) to alert<br />

users on the hazardous nature of the product.<br />

SECTION 16:<br />

OTHER INFORMATION<br />

This is a computer-generated form and does not require a signature.<br />

------------------------------------------------------------------------------------------------------------------------------------------<br />

The information presented <strong>here</strong>in has been compiled from sources considered to be dependable and is accurate to the best of<br />

<strong>Petron</strong> Fuel International Sdn Bhd’s knowledge. This information relates only to the specific material designated and may not be<br />

valid when this material is combined with any other material or in any process. However, <strong>Petron</strong> Fuel International Sdn Bhd<br />

makes no warranty or guarantee as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to<br />

the suitability and completeness of such information for his own particular use. <strong>Petron</strong> Fuel International Sdn Bhd assumes no<br />

responsibility for injury to recipient or to third persons or for any damage to any property that may occur from the use of this<br />

information.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!