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<strong>Lewis</strong> <strong>Dot</strong> 6 - Resonance<br />

Two or more equivalent structures with double bonds<br />

Index:<br />

A Rule 6 - Resonance<br />

B<br />

C<br />

Example 1 - HCO 2 G<br />

Example 2 - C 6 H 6<br />

©copyright by James B. Condon (2013) all rights reserved.<br />

©Some of the graphics are supplied by Corel Corporation with their permission.<br />

Use of these materials by others is encouraged provided these notices are not<br />

altered. Donations to the Roane State Foundations would be appreciated in<br />

order to support the development of these presentations.<br />

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1


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are two or more equivalent ways to place<br />

a double bond in a molecule, this is an indication<br />

of resonance. This is shown by drawing all<br />

possibilities and writing a double arrow (ø)<br />

between them.<br />

2


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 1: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the HCO 2 G ion?<br />

3


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 1: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the HCO 2 G ion?<br />

Here is the structure using rules 1 - 6:<br />

H–C<br />

O<br />

O:<br />

4


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 1: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the HCO 2 G ion?<br />

Here is the structure using rules 1 - 6:<br />

H–C<br />

O<br />

O:<br />

H–C<br />

O<br />

O:<br />

But why is the “=” to top and not bottom “O”?<br />

5


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 1: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the HCO 2 G ion?<br />

Here is the structure using rules 1 - 6:<br />

H–C<br />

O<br />

O:<br />

H–C<br />

O<br />

O:<br />

The answer: “They are both correct.”<br />

6


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 1: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the HCO 2 G ion?<br />

Here is the structure using rules 1 - 6:<br />

H–C<br />

O<br />

O:<br />

ø<br />

H–C<br />

O<br />

O:<br />

Therefore, show both with a “ø” between them.<br />

7


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 2: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the C 6 H 6 molecule (a ring molecule)?<br />

8


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 2: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the C 6 H 6 molecule (a ring molecule)?<br />

Here is the structure using rules 1 - 6:<br />

H<br />

H<br />

H<br />

C<br />

C C<br />

C C<br />

C<br />

H<br />

H<br />

H<br />

9


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 2: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the C 6 H 6 molecule (a ring molecule)?<br />

Here is the structure using rules 1 - 6:<br />

H<br />

H<br />

H<br />

C<br />

C C<br />

C C<br />

C<br />

H<br />

H But, why<br />

not this? !<br />

H<br />

H<br />

H<br />

H<br />

C<br />

C C<br />

C C<br />

C<br />

H<br />

H<br />

H<br />

10


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 2: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the C 6 H 6 molecule (a ring molecule)?<br />

Here is the structure using rules 1 - 6:<br />

H<br />

H<br />

There is no<br />

H<br />

C<br />

C C<br />

H difference, H<br />

C<br />

C C<br />

C C<br />

so insert<br />

C C<br />

H H “ø” H C<br />

C<br />

H<br />

H<br />

H<br />

H<br />

11


<strong>Lewis</strong> <strong>Dot</strong> 6: Resonance<br />

If there are 2 or more equivalent ways to place a double<br />

bond, this indicates resonance. show all possibilities and<br />

writing a”ø” between them.<br />

Example 2: What is the <strong>Lewis</strong> <strong>Dot</strong> structure of<br />

the C 6 H 6 molecule (a ring molecule)?<br />

Here is the structure using rules 1 - 6:<br />

H<br />

H<br />

H<br />

C<br />

C C<br />

C C<br />

C<br />

H<br />

H<br />

H<br />

ø<br />

H<br />

H<br />

H<br />

C<br />

C C<br />

C C<br />

C<br />

H<br />

H<br />

H<br />

12


<strong>Lewis</strong> <strong>Dot</strong> 6 - Resonance<br />

Two or more equivalent structures with double bonds<br />

THE END<br />

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13

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