Safety Data Sheet 2C AGP 2 KB - pss-interservice.ch
Safety Data Sheet 2C AGP 2 KB - pss-interservice.ch
Safety Data Sheet 2C AGP 2 KB - pss-interservice.ch
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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 Page 1 of 6<br />
Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />
"*" alterations as compared to previous version; n.ap. = not applicable; n.av. = not available<br />
1 Identification of Substance / Preparation and Company<br />
Identification of Substance or Preparation<br />
Trade Name: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />
Use: Component B (Hardener) for Faceal <strong>2C</strong> <strong>AGP</strong> 2 - component A ,<br />
antigraffiti protection for beton - See product bulletin for detailed information<br />
Company / Undertaking Identification<br />
Address of the Company / Undertaking:<br />
PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />
Telephone: +41 44 749 24 24, Fax: +41 44 749 24 25<br />
Contact person: Mr. Bu<strong>ch</strong>li; eMail: info@<strong>pss</strong>-te<strong>ch</strong>nology.com<br />
Responsible:<br />
CHEMCO123 ® – Chemical Consultancy, graduate <strong>ch</strong>emist, R. Fe<strong>ch</strong>ner, + 49 5254 9575 05<br />
eMail: info@<strong>ch</strong>emco123.de<br />
Emergency - Telephone<br />
Swiss Toxicological<br />
Emergency – Telephone<br />
Information Centre:<br />
of Company / Undertaking:<br />
Telephone: +41 44 251 51 51 Telephone:+41 44 749 24 24<br />
2 Hazards Identification<br />
For Humans<br />
Classification:<br />
R 43 - May cause sensitization by skin contact.<br />
R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic<br />
environment.<br />
Additional advice:<br />
Irritating to eyes. May cause sensitization by inhalation. Harmful by inhalation. May cause skin irritation.<br />
For the Environment:<br />
Slightly water endangering Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic<br />
environment.<br />
3 Composition / Information on Ingredients<br />
Chemical Characterisation:<br />
Aliphatic polyisocyanate, dissolved in Propylene carbonate<br />
Dangerous Ingredients:<br />
CAS - No. Index - No. EC - No. Material m% - range Symbol R - phrases<br />
Trade secret Aliphatic polyisocyanate > 75 % Xi R 43-52/53<br />
822-06-0 615-011-00-1 212-485-8 Hexamethylene-1,6-diisocyanate 0,1 < C < 0,5 % T R 23-36/37/38-<br />
42/43<br />
108-32-7 607-194-00-1 203-572-1 Propylene Carbonate 12,5 < C < 17,5 % Xi R 36<br />
Remarks:<br />
Classification and labelling of a product is indicated under item 15.<br />
Exposure Controls / Personal Protection under item 8<br />
R -phrase(s) under item 16<br />
4 First Aid Measures<br />
General advice:<br />
Show this safety data sheet to the doctor in attendance.<br />
Inhalation:<br />
Move to fresh air in case of accidental inhalation of vapours or decomposition products.<br />
Consult a physician. Symptoms may be delayed.
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 2 of 6<br />
Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />
Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />
Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />
Skin Contact:<br />
Wash off immediately with soap and plenty of water.<br />
In the case of skin irritation or allergic reactions see a physician.<br />
Eye Contact:<br />
Immediately flush eye(s) with plenty of water.<br />
If eye irritation persists, consult a specialist.<br />
Ingestion:<br />
Do not induce vomiting. Clean mouth with water and drink afterwards plenty of water.<br />
Consult a physician.<br />
Note to Physician:<br />
Symptoms may be delayed.<br />
Special Equipment:<br />
None.<br />
5 Fire Fighting Measures<br />
Suitable Extinguishing Media: Use dry <strong>ch</strong>emical, CO2, water spray or "alcohol" foam.<br />
Extinguishing Media to Avoid: None.<br />
Fire and Explosion Hazards:<br />
In the event of fire the following can be released: Carbon oxides, nitrogen oxides, isocyanates (vapours) and<br />
hydrogen cyanide (hydrocyanic acid).<br />
Additional Information: Cool containers / tanks with water spray. Prevent product from entering drains.<br />
Special Protective Equipment:<br />
Wear positive pressure self-contained breathing apparatus.<br />
Wear full protective clothing.<br />
6 Accidental Release Measures<br />
Personal Precautions:<br />
Use personal protective equipment. Ensure adequate ventilation.<br />
Environmental Precautions:<br />
Do not flush into surface water or sanitary sewer system. Contact the proper local authorities. Soak up with inert<br />
absorbent material and dispose of as hazardous waste. Take up me<strong>ch</strong>anically and collect in suitable container for<br />
disposal.<br />
Methods for Cleaning up:<br />
Clean-up methods - large spillage:<br />
Soak up with inert absorbent material and dispose of as hazardous waste. Take up me<strong>ch</strong>anically and collect in<br />
suitable container for disposal.<br />
Clean-up methods - small spillage:<br />
Soak up with inert absorbent material and dispose of as hazardous waste. Take up me<strong>ch</strong>anically and collect in<br />
suitable container for disposal.<br />
Further Information:<br />
Use personal protective equipment.<br />
7 Handling and Storage<br />
Handling<br />
Precautions for Safe Handling:<br />
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should<br />
not work with isocyanates. Avoid contact with skin and eyes. Do not breathe vapours or spray mist.<br />
Provide for appropriate exhaust ventilation at ma<strong>ch</strong>inery. Ensure adequate ventilation, especially in confined areas.<br />
Precautions in Case of Fire and Explosion:<br />
The product is flammable. Normal measures for preventive fire protection.
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 3 of 6<br />
Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />
Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />
Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />
Storage<br />
Storage Instructions:<br />
Keep container tightly closed in a cool, well-ventilated place.<br />
Store away from:<br />
Do not store together with strong oxidizing agents<br />
Further Information on Storage Conditions:<br />
Conditions to avoid: Exposure to moisture<br />
8 Exposure Controls and Personal Protection<br />
Information on System Design:<br />
Provide for appropriate exhaust ventilation at ma<strong>ch</strong>inery. Provide personal protective equipment.<br />
Exposure Limits:<br />
CAS / Material Limit Value according to TRGS 900/ EC Guidline 2000/39:<br />
822-06-0 / Hexamethylene-1,6-diisocyanate 0,005 ppm, 0,035 mg /m 3<br />
Personal Protective Equipment<br />
General Protection and Hygiene:<br />
Remove and wash contaminated clothing before re-use. Do not breathe vapours or spray mist.<br />
Avoid contact with skin and eyes. When using do not eat or drink. When using do not smoke.<br />
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment.<br />
Respirator with filter A2-P2<br />
Hand Protection:<br />
Excessive exposure: Protective gloves (butyl rubber) according to EN 374.<br />
Break through time: > 480 Min. Glove thickness: 0,7 mm / Level 6.<br />
Short time exposure: Protective gloves according to EN 374. (butyl rubber).<br />
Break through time: > 30 Min. Glove thickness: 0,4 mm / Level 2.<br />
Refer to manufacturer of gloves for detailed information.<br />
Eye Protection: Tightly fitting safety goggles.<br />
Skin Protection:<br />
Further Information:<br />
9 Physical and Chemical Properties<br />
Appearance<br />
Form: viscous liquid<br />
Colour: colourless<br />
Odour: none<br />
Impervious clothing.<br />
Choose body protection according to the amount and concentration of the dangerous<br />
substance at the work place.<br />
<strong>Safety</strong> Relevant <strong>Data</strong><br />
pH-value, undiluted: 6,5 - 7,5<br />
Boiling point / Boiling - range (°C): Decomposes on heating. (~ 80 C)<br />
Melting point / Melting range (°C): no data available<br />
Flash point (°C): > 250<br />
Flammability:<br />
The product is flammable<br />
Ignition temperature (°C):<br />
no data available<br />
Autoflammability:<br />
not applicable<br />
Oxidising properties:<br />
not applicable<br />
Explosion hazard:<br />
not applicable<br />
Explosion limits (Vol.%) lower: not applicable, upper: not applicable<br />
Vapour pressure:<br />
no data available<br />
Density (g/ml): 1,15<br />
Solubility (in Water): Reacts with water. Soluble in: ketones, toluene, xylene
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 4 of 6<br />
Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />
Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />
Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />
Partition coefficient, n-Octanol/Water: no data available<br />
Viscosity:<br />
no data available<br />
Solvent content (m %): 15<br />
COV content (g / kg) 150<br />
Fat solubility:<br />
Further <strong>Data</strong><br />
Thermal decomposition (°C): no data available<br />
Vapour density (Air = 1):<br />
no data available<br />
Evaporation rate:<br />
no data available<br />
10 Stability and Reactivity<br />
Conditions to Avoid:<br />
Stable at normal conditions.<br />
Materials to Avoid:<br />
Reacts with amines, alcohols and water.<br />
Hazardous Decomposition Products:<br />
Formation of carbon dioxide.<br />
Further Information:<br />
None.<br />
11 Toxicological Information<br />
Toxicological Tests:<br />
Acute Health Effects of the preparation:<br />
Inhalation, LC50 rat, (mg/l/4h): no data available<br />
Ingestion, LD50 rat, (mg/kg): > 2000<br />
Skin - contact, LD50 rat, (mg/kg): no data available<br />
Irritation (to skin / eye): May cause skin irritation. Irritating to eyes.<br />
Sensitisation:<br />
May cause sensitization by skin contact.<br />
Subacute / Chronic Toxicity of the preparation:<br />
Carcinogenicity:<br />
None known<br />
Mutagenicity:<br />
None known<br />
Teratogenicity:<br />
None known<br />
Narcotic Effects:<br />
None known<br />
Practical Experience<br />
Observations relevant for classification:<br />
None.<br />
Further Observations:<br />
None.<br />
General Remarks:<br />
Classification of the preparation has been done by calculation in accordance with directives 1999/45/EC<br />
and 2006/8/EC.<br />
12 Environmental Information<br />
Elimination (Persistence and Degradability):<br />
Not readily biodegradable ( 2 %) The product can be degraded by abiotic (e.g. <strong>ch</strong>emical or photolytic) processes.<br />
Reacts with water to insoluble polyurea.<br />
Behaviour in Sewage Works:<br />
Mobility and Accumulation Potential:<br />
Does not bioaccumulate.<br />
Ecotoxic Effects, Aquatic Toxicity:<br />
Slightly water endangering. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic<br />
environment.
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 5 of 6<br />
Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />
Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />
Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />
Other Ecological Information<br />
COD-Value, mg/g: no data available<br />
BOD 5 -Value, mg/g: no data available<br />
AOX-Remarks: Product does not contain any organic halogens.<br />
Persistent, bioaccumulative and toxic substances (PBT-substances: Hexamethylene-1,6-diisocyanate.<br />
Very persistent and very bioaccumulative substances (vPvB-substances): None<br />
13 Disposal Considerations<br />
Residues<br />
Recommendation: D 10<br />
Waste - Code - No.: 08 05 01 - Isocyanatabfälle<br />
In addition comply with the regional authorities.<br />
Safe Handling: See item 7 and 15.<br />
Contaminated Packaging<br />
Recommendation: Wash with suitable cleaner. Otherwise as described under Residues.<br />
Safe Handling: As described under Residues.<br />
14 Transport Information<br />
Transportation by Road or Railway according to ADR/GGVS and RID/GGVE<br />
Transportation by Vessels according to IMDG/GGVSee<br />
Transportation by Aeroplane according to IATA-DGR/ICAO-TI<br />
Remarks: Not dangerous goods<br />
15 Regulatory Information<br />
Classification according to directive 1999/45/EC:<br />
Hazard Identification: Irritant and Dangerous for the environment<br />
Contains: Aliphatic polyisocyanate and Hexamethylene-1,6-diisocyanate<br />
R-Phrases:<br />
R 43 - May cause sensitization by skin contact.<br />
R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in<br />
the aquatic environment.<br />
S-Phrases:<br />
S 23 - Do not breathe vapour /spray.<br />
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.<br />
S 37/39 - Wear suitable gloves and eye/face protection.<br />
S 45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).<br />
S 51 - Use only in well ventilated areas.<br />
S 60 - This material and its container must be disposed of as hazardous waste.<br />
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheets.<br />
Further EC – regulations:<br />
Regulation (EC) No 648/2004 of the European Parlament and of the Council of 31 Mar<strong>ch</strong> 2004 on detergents.<br />
not applicable<br />
Additional advice:<br />
Contains isocyanates. See information supplied by the manufacturer.<br />
The above mentioned classification is valid for distribution to: Professional use.<br />
Labelling (formats, exemptions, additional markings) has to be done according to respective regulations.
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 6 of 6<br />
Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />
Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />
Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />
16 Other Information<br />
Text of R phrases:<br />
R 23 - Toxic by inhalation.<br />
R 43 - May cause sensitization by skin contact.<br />
R 42/43 - May cause sensitization by inhalation and skin contact.<br />
R 36/37/38 - Irritating to eyes, respiratory system and skin.<br />
R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
Further information to work out the <strong>Data</strong> sheet:<br />
<strong>Data</strong> of the producer.<br />
The statements in this Material <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> were made to the best of our knowledge (2009/2/EC) and are as accurate<br />
as possible. They are given for information only. They do not constitute a contractual guarantee of a product’s properties. They<br />
must neither be altered nor transferred to other products.<br />
<strong>pss</strong>068