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Safety Data Sheet 2C AGP 2 KB - pss-interservice.ch

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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 Page 1 of 6<br />

Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />

"*" alterations as compared to previous version; n.ap. = not applicable; n.av. = not available<br />

1 Identification of Substance / Preparation and Company<br />

Identification of Substance or Preparation<br />

Trade Name: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />

Use: Component B (Hardener) for Faceal <strong>2C</strong> <strong>AGP</strong> 2 - component A ,<br />

antigraffiti protection for beton - See product bulletin for detailed information<br />

Company / Undertaking Identification<br />

Address of the Company / Undertaking:<br />

PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />

Telephone: +41 44 749 24 24, Fax: +41 44 749 24 25<br />

Contact person: Mr. Bu<strong>ch</strong>li; eMail: info@<strong>pss</strong>-te<strong>ch</strong>nology.com<br />

Responsible:<br />

CHEMCO123 ® – Chemical Consultancy, graduate <strong>ch</strong>emist, R. Fe<strong>ch</strong>ner, + 49 5254 9575 05<br />

eMail: info@<strong>ch</strong>emco123.de<br />

Emergency - Telephone<br />

Swiss Toxicological<br />

Emergency – Telephone<br />

Information Centre:<br />

of Company / Undertaking:<br />

Telephone: +41 44 251 51 51 Telephone:+41 44 749 24 24<br />

2 Hazards Identification<br />

For Humans<br />

Classification:<br />

R 43 - May cause sensitization by skin contact.<br />

R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic<br />

environment.<br />

Additional advice:<br />

Irritating to eyes. May cause sensitization by inhalation. Harmful by inhalation. May cause skin irritation.<br />

For the Environment:<br />

Slightly water endangering Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic<br />

environment.<br />

3 Composition / Information on Ingredients<br />

Chemical Characterisation:<br />

Aliphatic polyisocyanate, dissolved in Propylene carbonate<br />

Dangerous Ingredients:<br />

CAS - No. Index - No. EC - No. Material m% - range Symbol R - phrases<br />

Trade secret Aliphatic polyisocyanate > 75 % Xi R 43-52/53<br />

822-06-0 615-011-00-1 212-485-8 Hexamethylene-1,6-diisocyanate 0,1 < C < 0,5 % T R 23-36/37/38-<br />

42/43<br />

108-32-7 607-194-00-1 203-572-1 Propylene Carbonate 12,5 < C < 17,5 % Xi R 36<br />

Remarks:<br />

Classification and labelling of a product is indicated under item 15.<br />

Exposure Controls / Personal Protection under item 8<br />

R -phrase(s) under item 16<br />

4 First Aid Measures<br />

General advice:<br />

Show this safety data sheet to the doctor in attendance.<br />

Inhalation:<br />

Move to fresh air in case of accidental inhalation of vapours or decomposition products.<br />

Consult a physician. Symptoms may be delayed.


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 2 of 6<br />

Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />

Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />

Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />

Skin Contact:<br />

Wash off immediately with soap and plenty of water.<br />

In the case of skin irritation or allergic reactions see a physician.<br />

Eye Contact:<br />

Immediately flush eye(s) with plenty of water.<br />

If eye irritation persists, consult a specialist.<br />

Ingestion:<br />

Do not induce vomiting. Clean mouth with water and drink afterwards plenty of water.<br />

Consult a physician.<br />

Note to Physician:<br />

Symptoms may be delayed.<br />

Special Equipment:<br />

None.<br />

5 Fire Fighting Measures<br />

Suitable Extinguishing Media: Use dry <strong>ch</strong>emical, CO2, water spray or "alcohol" foam.<br />

Extinguishing Media to Avoid: None.<br />

Fire and Explosion Hazards:<br />

In the event of fire the following can be released: Carbon oxides, nitrogen oxides, isocyanates (vapours) and<br />

hydrogen cyanide (hydrocyanic acid).<br />

Additional Information: Cool containers / tanks with water spray. Prevent product from entering drains.<br />

Special Protective Equipment:<br />

Wear positive pressure self-contained breathing apparatus.<br />

Wear full protective clothing.<br />

6 Accidental Release Measures<br />

Personal Precautions:<br />

Use personal protective equipment. Ensure adequate ventilation.<br />

Environmental Precautions:<br />

Do not flush into surface water or sanitary sewer system. Contact the proper local authorities. Soak up with inert<br />

absorbent material and dispose of as hazardous waste. Take up me<strong>ch</strong>anically and collect in suitable container for<br />

disposal.<br />

Methods for Cleaning up:<br />

Clean-up methods - large spillage:<br />

Soak up with inert absorbent material and dispose of as hazardous waste. Take up me<strong>ch</strong>anically and collect in<br />

suitable container for disposal.<br />

Clean-up methods - small spillage:<br />

Soak up with inert absorbent material and dispose of as hazardous waste. Take up me<strong>ch</strong>anically and collect in<br />

suitable container for disposal.<br />

Further Information:<br />

Use personal protective equipment.<br />

7 Handling and Storage<br />

Handling<br />

Precautions for Safe Handling:<br />

Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should<br />

not work with isocyanates. Avoid contact with skin and eyes. Do not breathe vapours or spray mist.<br />

Provide for appropriate exhaust ventilation at ma<strong>ch</strong>inery. Ensure adequate ventilation, especially in confined areas.<br />

Precautions in Case of Fire and Explosion:<br />

The product is flammable. Normal measures for preventive fire protection.


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 3 of 6<br />

Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />

Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />

Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />

Storage<br />

Storage Instructions:<br />

Keep container tightly closed in a cool, well-ventilated place.<br />

Store away from:<br />

Do not store together with strong oxidizing agents<br />

Further Information on Storage Conditions:<br />

Conditions to avoid: Exposure to moisture<br />

8 Exposure Controls and Personal Protection<br />

Information on System Design:<br />

Provide for appropriate exhaust ventilation at ma<strong>ch</strong>inery. Provide personal protective equipment.<br />

Exposure Limits:<br />

CAS / Material Limit Value according to TRGS 900/ EC Guidline 2000/39:<br />

822-06-0 / Hexamethylene-1,6-diisocyanate 0,005 ppm, 0,035 mg /m 3<br />

Personal Protective Equipment<br />

General Protection and Hygiene:<br />

Remove and wash contaminated clothing before re-use. Do not breathe vapours or spray mist.<br />

Avoid contact with skin and eyes. When using do not eat or drink. When using do not smoke.<br />

Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment.<br />

Respirator with filter A2-P2<br />

Hand Protection:<br />

Excessive exposure: Protective gloves (butyl rubber) according to EN 374.<br />

Break through time: > 480 Min. Glove thickness: 0,7 mm / Level 6.<br />

Short time exposure: Protective gloves according to EN 374. (butyl rubber).<br />

Break through time: > 30 Min. Glove thickness: 0,4 mm / Level 2.<br />

Refer to manufacturer of gloves for detailed information.<br />

Eye Protection: Tightly fitting safety goggles.<br />

Skin Protection:<br />

Further Information:<br />

9 Physical and Chemical Properties<br />

Appearance<br />

Form: viscous liquid<br />

Colour: colourless<br />

Odour: none<br />

Impervious clothing.<br />

Choose body protection according to the amount and concentration of the dangerous<br />

substance at the work place.<br />

<strong>Safety</strong> Relevant <strong>Data</strong><br />

pH-value, undiluted: 6,5 - 7,5<br />

Boiling point / Boiling - range (°C): Decomposes on heating. (~ 80 C)<br />

Melting point / Melting range (°C): no data available<br />

Flash point (°C): > 250<br />

Flammability:<br />

The product is flammable<br />

Ignition temperature (°C):<br />

no data available<br />

Autoflammability:<br />

not applicable<br />

Oxidising properties:<br />

not applicable<br />

Explosion hazard:<br />

not applicable<br />

Explosion limits (Vol.%) lower: not applicable, upper: not applicable<br />

Vapour pressure:<br />

no data available<br />

Density (g/ml): 1,15<br />

Solubility (in Water): Reacts with water. Soluble in: ketones, toluene, xylene


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 4 of 6<br />

Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />

Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />

Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />

Partition coefficient, n-Octanol/Water: no data available<br />

Viscosity:<br />

no data available<br />

Solvent content (m %): 15<br />

COV content (g / kg) 150<br />

Fat solubility:<br />

Further <strong>Data</strong><br />

Thermal decomposition (°C): no data available<br />

Vapour density (Air = 1):<br />

no data available<br />

Evaporation rate:<br />

no data available<br />

10 Stability and Reactivity<br />

Conditions to Avoid:<br />

Stable at normal conditions.<br />

Materials to Avoid:<br />

Reacts with amines, alcohols and water.<br />

Hazardous Decomposition Products:<br />

Formation of carbon dioxide.<br />

Further Information:<br />

None.<br />

11 Toxicological Information<br />

Toxicological Tests:<br />

Acute Health Effects of the preparation:<br />

Inhalation, LC50 rat, (mg/l/4h): no data available<br />

Ingestion, LD50 rat, (mg/kg): > 2000<br />

Skin - contact, LD50 rat, (mg/kg): no data available<br />

Irritation (to skin / eye): May cause skin irritation. Irritating to eyes.<br />

Sensitisation:<br />

May cause sensitization by skin contact.<br />

Subacute / Chronic Toxicity of the preparation:<br />

Carcinogenicity:<br />

None known<br />

Mutagenicity:<br />

None known<br />

Teratogenicity:<br />

None known<br />

Narcotic Effects:<br />

None known<br />

Practical Experience<br />

Observations relevant for classification:<br />

None.<br />

Further Observations:<br />

None.<br />

General Remarks:<br />

Classification of the preparation has been done by calculation in accordance with directives 1999/45/EC<br />

and 2006/8/EC.<br />

12 Environmental Information<br />

Elimination (Persistence and Degradability):<br />

Not readily biodegradable ( 2 %) The product can be degraded by abiotic (e.g. <strong>ch</strong>emical or photolytic) processes.<br />

Reacts with water to insoluble polyurea.<br />

Behaviour in Sewage Works:<br />

Mobility and Accumulation Potential:<br />

Does not bioaccumulate.<br />

Ecotoxic Effects, Aquatic Toxicity:<br />

Slightly water endangering. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic<br />

environment.


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 5 of 6<br />

Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />

Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />

Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />

Other Ecological Information<br />

COD-Value, mg/g: no data available<br />

BOD 5 -Value, mg/g: no data available<br />

AOX-Remarks: Product does not contain any organic halogens.<br />

Persistent, bioaccumulative and toxic substances (PBT-substances: Hexamethylene-1,6-diisocyanate.<br />

Very persistent and very bioaccumulative substances (vPvB-substances): None<br />

13 Disposal Considerations<br />

Residues<br />

Recommendation: D 10<br />

Waste - Code - No.: 08 05 01 - Isocyanatabfälle<br />

In addition comply with the regional authorities.<br />

Safe Handling: See item 7 and 15.<br />

Contaminated Packaging<br />

Recommendation: Wash with suitable cleaner. Otherwise as described under Residues.<br />

Safe Handling: As described under Residues.<br />

14 Transport Information<br />

Transportation by Road or Railway according to ADR/GGVS and RID/GGVE<br />

Transportation by Vessels according to IMDG/GGVSee<br />

Transportation by Aeroplane according to IATA-DGR/ICAO-TI<br />

Remarks: Not dangerous goods<br />

15 Regulatory Information<br />

Classification according to directive 1999/45/EC:<br />

Hazard Identification: Irritant and Dangerous for the environment<br />

Contains: Aliphatic polyisocyanate and Hexamethylene-1,6-diisocyanate<br />

R-Phrases:<br />

R 43 - May cause sensitization by skin contact.<br />

R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in<br />

the aquatic environment.<br />

S-Phrases:<br />

S 23 - Do not breathe vapour /spray.<br />

S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.<br />

S 37/39 - Wear suitable gloves and eye/face protection.<br />

S 45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).<br />

S 51 - Use only in well ventilated areas.<br />

S 60 - This material and its container must be disposed of as hazardous waste.<br />

S 61 - Avoid release to the environment. Refer to special instructions/safety data sheets.<br />

Further EC – regulations:<br />

Regulation (EC) No 648/2004 of the European Parlament and of the Council of 31 Mar<strong>ch</strong> 2004 on detergents.<br />

not applicable<br />

Additional advice:<br />

Contains isocyanates. See information supplied by the manufacturer.<br />

The above mentioned classification is valid for distribution to: Professional use.<br />

Labelling (formats, exemptions, additional markings) has to be done according to respective regulations.


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> in Accordance with Regulation (EC) No 1907/2006 page 6 of 6<br />

Tradename: Faceal <strong>2C</strong> <strong>AGP</strong> 2 - Component B<br />

Company / Distributor: PSS INTERSERVICE Ltd., P.O. Box 315, Poststr. 1, 8954 Geroldswil, Switzerland<br />

Telephone: +41 44 749 24 24, Date of issue: 29.12.2009 Replaces <strong>Data</strong> <strong>Sheet</strong> of:<br />

16 Other Information<br />

Text of R phrases:<br />

R 23 - Toxic by inhalation.<br />

R 43 - May cause sensitization by skin contact.<br />

R 42/43 - May cause sensitization by inhalation and skin contact.<br />

R 36/37/38 - Irritating to eyes, respiratory system and skin.<br />

R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

Further information to work out the <strong>Data</strong> sheet:<br />

<strong>Data</strong> of the producer.<br />

The statements in this Material <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> were made to the best of our knowledge (2009/2/EC) and are as accurate<br />

as possible. They are given for information only. They do not constitute a contractual guarantee of a product’s properties. They<br />

must neither be altered nor transferred to other products.<br />

<strong>pss</strong>068

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