10.07.2015 Views

International Paint Ltd. Safety Data Sheet EMB117 INTERGARD 410 ...

International Paint Ltd. Safety Data Sheet EMB117 INTERGARD 410 ...

International Paint Ltd. Safety Data Sheet EMB117 INTERGARD 410 ...

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Page 1 of 10<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><strong>EMB117</strong> <strong>INTERGARD</strong> <strong>410</strong> YELLOWVersion No. 3 Date Last Revised 29/11/11<strong>International</strong> <strong>Paint</strong> <strong>Ltd</strong>.Conforms to the requirements of Regulation (EC) No.1907/2006 (REACH), Annex II and Regulation (EC)No.1272/2008SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifier <strong>INTERGARD</strong> <strong>410</strong> YELLOWProduct Code <strong>EMB117</strong>Registration Number1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended use See Technical <strong>Data</strong> <strong>Sheet</strong>.Application Method See Technical <strong>Data</strong> <strong>Sheet</strong>.1.3. Details of the supplier of the safety data sheetManufacturer <strong>International</strong> <strong>Paint</strong> <strong>Ltd</strong>.Stoneygate LaneFelling GatesheadTyne and WearNE10 0JY UKTelephone No. +44 (0)191 469 6111Fax No. +44 (0)191 438 37111.4. Emergency telephone numberManufacturer +44 (0)191 469 6111 24hrOfficial Advisory Body Telephone No.:Advice for Doctors and HospitalsEmail+44 (0)844 892 0111sdsfellinguk@akzonobel.comSECTION 2: Hazards identification2.1. Classification of the substance or mixtureMixture NOT yet classified according to Regulation (EC) No. 1272/2008Classification according to 67/548/EEC or 1999/45/EC.XiIrritant.R10Flammable.R36/38 Irritating to eyes and skin.R43May cause sensitisation by skin contact.R52/53Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.2.2. Label elements


Page 2 of 10According to 1999/45/ECIrritantContains: Epoxy resin (MW 700 - 1000),R10 Flammable.R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.S23 Do not breathe vapour/spray.S24 Avoid contact with skin.S37 Wear suitable gloves.S51 Use only in well-ventilated areas.P. Phrases;2.3. Other hazardsThis product contains no PBT/vPvB chemicals.SECTION 3: Composition/information on ingredientsIf the product contains substances that present a health hazard within the meaning of the DangerousSubstances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substancesare listed below.Ingredient/Chemical Designations Weight %Epoxy resin (MW 700 - 1000)CAS Number: 0025036-25-3EC No.Index No.:REACH Reg. No.:XyleneCAS Number: 0001330-20-7EC No. 215-535-7Index No.: 601-022-00-9REACH Reg. No.:Solvent naphtha (petroleum), lightaromaticCAS Number: 0064742-95-6EC No. 265-199-0Index No.: 649-356-00-4REACH Reg. No.:1-methoxypropan-2-olCAS Number: 0000107-98-2EC No. 203-539-1Index No.: 603-064-00-3REACH Reg. No.: 01-2119457435-35-xxxx1,2,4-trimethylbenzeneCAS Number: 0000095-63-6EC No. 202-436-9Index No.: 601-043-00-3REACH Reg. No.:67/548/EECClassificationEC No. 1272/2008Classification10 - < 25 Xi;R36/38 R43 Eye Irrit. 2;H319Skin Irrit. 2;H315,Skin Sens. 1;H3172.5 - < 10 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226Acute Tox. 4;H332Acute Tox. 4;H312Skin Irrit. 2;H315[1]C[1][2]2.5 - < 10 Xn;R65 Asp. Tox. 1;H304 H; P[1]2.5 - < 10 R10 R67 Flam. Liq. 3;H226STOT SE 3;H336 [1][2]2.5 - < 10 R10 Xn;R20Xi;R36/37/38 N;R51-53Flam. Liq. 3;H226Acute Tox. 4;H332Eye Irrit. 2;H319STOT SE 3;H335Skin Irrit. 2;H315Aquatic Chronic[1][2]Notes


Page 3 of 101,3,5-trimethylbenzeneCAS Number: 0000108-67-8EC No. 203-604-4Index No.: 601-025-00-5REACH Reg. No.:2;H4111 - < 2.5 R10 Xi;R37 N;R51-53 Flam. Liq. 3;H226STOT SE 3;H335Aquatic Chronic2;H411[1] Substance classified with a health or environmental hazard.[2] Substance with a workplace exposure limit.[3] PBT-substance or vPvB-substance.[1]*The full texts of the phrases are shown in Section 16.SECTION 4: First aid measures4.1. Description of first aid measuresGeneralIn all cases of doubt, or when symptoms persist, seek medical attention.Never give anything by mouth to an unconscious person.InhalationRemove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificialrespiration. If unconscious place in the recovery position and obtain immediate medical attention. Givenothing by mouth.SkinRemove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skincleanser. Do NOT use solvents or thinners.EyeIrrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medicalattention.IngestionIf accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.4.2. Most important symptoms and effects, both acute and delayedNo data available4.3. Indication of any immediate medical attention and special treatment neededNo data availableSECTION 5: Fire-fighting measures5.1. Extinguishing mediaRecommended extinguishing media; alcohol resistant foam, CO 2 . powder, water spray.Do not use; water jet.5.2. Special hazards arising from the substance or mixtureFire will produce dense black smoke. Decomposition products may include the following materials: carbonmonoxide, carbon dioxide, smoke, oxides of nitrogen.Avoid exposure and use breathing apparatus as appropriate.5.3. Advice for fire-fightersCool closed containers exposed to fire by spraying them with water. Do not allow run off water andcontaminants from fire fighting to enter drains or water courses.


Page 4 of 10SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresRemove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of amajor spill or spillage in a confined space evacuate the area and check that solvent vapour levels arebelow the Lower Explosive Limit before re-entering.6.2. Environmental precautionsDo not allow spills to enter drains or watercourses.6.3. Methods and material for containment and cleaning upVentilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closedcontainers outside buildings and dispose of according to the Waste Regulations. (See section 13).Clean, preferably with a detergent. Do not use solvents.Do not allow spills to enter drains or watercourses.If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In thecase of contamination of rivers, streams or lakes the Environmental Protection Agency should also beinformed.SECTION 7: Handling and storage7.1. Precautions for safe handlingHandlingThis coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapoursmay form explosive mixtures with air. Areas of storage, preparation and application should be ventilated toprevent the creation of flammable or explosive concentrations of vapour in air and avoid vapourconcentrations higher than the occupational exposure limits.In StorageHandle containers carefully to prevent damage and spillage.Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucksand electrical equipment are protected to the appropriate standard.7.2. Conditions for safe storage, including any incompatibilitiesKeep away from the following materials: oxidising agents, strong alkalis, strong acids.Avoid skin and eye contact. Avoid inhalation of vapours and spray mists. Observe label precautions. Usepersonal protection as shown in section 8.Smoking, eating and drinking should be prohibited in all preparation and application areas.Never use pressure to empty a container; containers are not pressure vessels.Store in a well ventilated, dry place away from sources of heat and direct sunlight.Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stackmore than 3 pallets high.Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright toprevent leakage. Keep in the original container or one of the same material.Prevent unauthorised access.7.3. Specific end use(s)There are no exposure scenarios, see details in section 1.


IT? WAS IT MEGALOMANIA, DID HE HAVEDID SOMEBODY SET HIM UP TO DO IT?steadily built up. As Mr. Raju saidin his ‘confession’ letter, he wasriding a tiger which he couldn’t getoff, because he had built the story;and the more he built on it, the morehe had to do to keep it going.“This was a huge fraud in which,apparently, little or no money hadbeen taken out. Maybe that willcome out later, that money has gone,but we don’t know right now. Tillthe time I was there, we were notable to trace any money going intoMr. Raju’s or anyone else’s pocket.There might have been wheelswithin wheels, but nothing apparently.“It was just an accounting thing –high revenues, high profits, falsebank deposits – none of which existed.One of our jobs was to unravelthis. We got an accountingfirm... they are on the job even today;some people have been arrestedand jailed.”Finally, Mr. Karnik turned to the“Why?” of the whole story and saidthat it was still a great mystery tohim.He admitted that he knew Mr.Raju professionally from the timethat he (Mr. Karnik) enteredNasscom in 2002. Mr. Raju was theChairman of Nasscom which was arotating one-year position. He travelledextensively with Mr. Raju bothin the country and outside.Mr. Raju did a tremendousamount of social work, including thecreation of a state-of-the-art ambulanceservice called “108” which ranin many states, other thanMaharashtra. It was a very successfulventure. He had hired McKenzieto look at the metrics and it wasfound to be truly world-class. Heput a lot of money in it.In other words, Mr. Raju was asuccessful man who had a greatimage, who had built himself up;he was well known in the countryand even won a number ofawards for corporate governance,entrepreneurship and so on.He seemed to have his heart inthe right place and invested in socialcauses; he gave not trivial amountsbut huge sums of money for projectsthat did some very good work.“So why did he do this? I have noanswers. Maybe it was megalomania,maybe there was somethingwrong, maybe he had a Jekyll andHyde personality, or it may be thatsomebody set him up to do it.It was a huge fraud, no doubt. But there was no real money involved,says Mr. Kiran Karnik, former Nasscom chief. Till today, he does notknow whether anybody made any money. Nor is he sure whether themystery will ever be solved“But to me the ultimate fraud isthis, that the human character, inthe person you know, is not reallythere. If somebody had asked meon January 2 or 3, 2009, I can saytruthfully that I would have givenMr. Raju a character certificate.Now, suddenly, you lose confidencein your ability to assess a humanbeing. When you look at somebodywho’s doing good, it’s likely thatthis thought will be there at the backof your mind, that everything is notright.“The seed of doubt has beenplanted in your mind. And that, tome, is the biggest fraud. Can youtrust people? Suddenly, you will besaying, whom can you trust? Nobody.It’s very sad, but those of uswho knew him thought highly of himtill January 3 or 4.”Mr. Karnik took the opportunityto point out that even if one had thebest of systems in place (as didSatyam), even if rigorous reviewsand audits were conducted, even ifthere were eminent independent directorssitting on the board, therewas something else that was farmore important than all these puttogether. And that was a sense ofethics and values.“If there are no ethics and values,then all talk of good governance,systems and processes,checks and balances, work onlyup to a point. They are necessaryand they must be there, but theyare not enough, they are not sufficient.“Ethics and values must comeinto play. These should be (inculcated)early, from school, maybecollege, but certainly in places likebusiness schools; entry jobs in thecorporate world must emphasiseethics and values,” Mr. Karnik concluded.The first question was asked byAshwin Ramesh who wanted toknow how the competitors ofSatyam had behaved after the fraudwas discovered. Were they like vulturesor like friends?Mr. Karnik said that one of thefirst things Nasscom did was to arrangea teleconference of all theNasscom board members and to suggestthat they refrained from anypredatory action with regard to employees(trying to poach them) orcustomers. And apart from a few aberrations,the IT industry followedthe suggestion and showed restraint.The second question was posedby Mehul Sampat (which has beenreported extensively at the beginningof this report).And then it was the turn of PDGManibhai Doshi who asked aboutthe role played by Mr. DeepakParekh, an Honorary member of theRotary Club of Bombay, in rescuingSatyam.Mr. Karnik said he had not mentionedany individual names, but thefact remained that Mr. Parekh hadplayed a crucial role. There were sixmembers on the board and eachpulled his own weight, but Mr.Parekh was extremely helpful.“I was a retired man but Deepakhad a full-time operational job runninga huge corporation with greatresponsibility; yet, he was therewithout fail at every meeting in thefirst three or four months, adjustingto the others’ time, making sure hecame the previous evening, becausewe used to have an informal meetingfrom 10 to midnight. And he wasthere for every meeting. His contributionwas huge... it was a matter ofpride.”Finally, Sitaram Shah asked whenthe IT industry would become userfriendly for the common man. Hesaid that when someone got stuckwith something on a computer, serviceproviders were not available;one system never worked with another...and so on.Mr. Karnik said he shared the feelingof frustration for he had alsofaced the same problems. But computershad now become more userfriendly when compared to the situationa few years back. With time,they would become simpler, thanksto voice command, thanks to systemsthat would not break down frequentlyand so on.“You’ll reach a stage where youwon’t have to cope with the machine,but the machine will haveto cope with you. That’s the ultimate.We’re not there yet, ofcourse... but things are changingand ultimately we will get to thatpoint.“People like me have difficultycoping with the keyboard. I neverlearned typing so I keep searchingfor the keys. I have the same problemwith my Blackberry and someof the new smart phones. Qwertykeyboards are of no use to me becauseI don’t know where the lettersare located... an ABC keyboardmakes better sense for me. Butpeople are learning...“There is some good softwaresuch as voice-to-text. It’s a bit expensivebut it’s a great investmentfor someone who uses the computerfrequently; you can just read and itwill type; it’s self-learning and it getsused to your pronunciation. Theonly drawback is that it’s for a singleuser. It adjusts to your pronunciationand your (particular) speed. Ifyou buy one, your spouse and kidsmay not be able to use it,” Mr.Karnik added.The vote of thanks was proposedby Shailesh Haribhakti.August 17 to August 23, 2010 THE GATEWAY, The Bulletin of the Rotary Club of Bombay Page 5


Page 6 of 10Respiratory protectionIf workers are exposed to concentrations above the exposure limit they must use the appropriate,certifiedrespirators.For maximum protection when spraying this product it is recommended that a multi layercombination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh airrespiratory equipment.Thermal hazardsNo <strong>Data</strong> AvailableSECTION 9: Physical and chemical propertiesAppearance Coloured LiquidOdour Smell of SolventOdour thresholdNot MeasuredpHNot MeasuredMelting point / freezing point (°C)Not MeasuredInitial boiling point and boiling range (°C) 108Flash point (°C) 30Evaporation rate (Ether = 1)Not MeasuredFlammability (solid, gas)Not ApplicableUpper/lower flammability or explosive limits Lower Explosive Limit: Not MeasuredUpper Explosive Limit: Not MeasuredVapour pressure (Pa)Not MeasuredVapour densityHeavier than air.Relative density 1.57Solubility(ies)ImmisciblePartition coefficient n-octanol/water (Log Kow) Not MeasuredAuto-ignition temperature (°C)Not MeasuredDecomposition temperature (°C)Not MeasuredViscosity (cSt) 1529.2. Other informationNo further informationSECTION 10: Stability and reactivity10.1. ReactivityNo data available10.2. Chemical stabilityStable under recommended storage and handling conditions (see section 7).When exposed to hightemperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,oxides of nitrogen and smoke.Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possibleexothermic reactions.10.3. Possibility of hazardous reactionsMay react exothermically with: oxidising agents, strong alkalis, strong acids.10.4. Conditions to avoidStable under recommended storage and handling conditions (see section 7).10.5. Incompatible materialsKeep away from the following materials: oxidising agents, strong alkalis, strong acids.10.6. Hazardous decomposition products


Page 7 of 10Fire will produce dense black smoke. Decomposition products may include the following materials: carbonmonoxide, carbon dioxide, smoke, oxides of nitrogen.Avoid exposure and use breathing apparatus as appropriate.SECTION 11: Toxicological informationAcute toxicityExposure to solvent vapour concentrations from the component solvents in excess of the statedoccupational exposure limits may result in adverse health effects such as mucous membrane andrespiratory system irritation and adverse effects on the kidneys, liver and central nervous system.Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extremecases, loss of consciousness.Repeated or prolonged contact with the preparation may cause removal of natural fat from the skinresulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbedthrough the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversibledamage.IngredientOral LD50,mg/kgSkin LD50,mg/kgInhalationVapour LD50,mg/L/4hrInhalationDust/Mist LD50,mg/L/4hr1,2,4-trimethylbenzene - (95-63-6) 3,400.00, Rat 3,160.00, Rabbit 18.00, Rat Not Available1,3,5-trimethylbenzene - (108-67-8) Not Available Not Available 24.00, Rat Not Available1-methoxypropan-2-ol - (107-98-2) 5,000.00, Rat 13,000.00, Rabbit Not Available Not AvailableEpoxy resin (MW 700 - 1000) - (25036- Not Available Not Available Not Available Not Available25-3)Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not Availablearomatic - (64742-95-6)Xylene - (1330-20-7) 4,299.00, Rat 1,548.00, Rabbit 20.00, Rat Not AvailableSECTION 12: Ecological information12.1. ToxicityThe preparation has been assessed following the conventional method of the Dangerous PreparationsDirective 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3for details.There are no data available on the product itself.The product should not be allowed to enter drains or water courses.Aquatic Ecotoxicity96 hr LC50 fish,Ingredientmg/lEpoxy resin (MW 700 - 1000) -(25036-25-3)Xylene - (1330-20-7) 3.30, Oncorhynchusmykiss48 hr EC50 crustacea,mg/lErC50 algae,mg/lNot Available Not Available Not Available8.50, Palaemonetespugio100.00 (72 hr), ChlorococcalesSolvent naphtha (petroleum), lightaromatic - (64742-95-6)9.22, Oncorhynchusmykiss1-methoxypropan-2-ol - (107-98-2) 1,000.00, Oncorhynchus6.14, Daphnia magna 19.00 (72 hr), Selenastrumcapricornutum500.00, Daphniamagna1,000.00 (96 hr), Selenastrumcapricornutum


Page 9 of 1014.6. Special precautions for userNo further information14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeNot ApplicableSECTION 15: Regulatory informationEU LegislationREGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL onclassification, labelling and packaging of substances and mixtures, amending and repealing Directives67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCILconcerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishinga European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC)No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC andCommission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/ECNational LegislationUKSI 2009 No. 716 CHEMICALS (HAZARD INFORMATION AND PACKAGING FOR SUPPLY)REGULATIONS 2009.SECTION 16: Other informationIMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) isnot intended to be exhaustive and is presented in good faith and believed to be correct as of the date onwhich it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using theproduct to which it relates.Persons using the information must make their own determinations as to the suitability of the relevantproduct for their purposes prior to use. Where those purposes are other than as specifically recommendedin this safety data sheet, then the user uses the product at their own risk.MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,application, use and disposal of the product are not under the control and knowledge of the manufacturer.Therefore the manufacturer does not assume responsibility for any adverse events which may occur in thehandling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicablelaw, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arisingout of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,storage, use and disposal are the responsibility of the users. Users must comply with all applicable healthand safety laws.Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms andconditions of business, which include limitations of liability. Please make sure to refer to these and / or therelevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).© AkzoNobelThe information in this Health & <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> is required pursuant to EC Regulation 1907(2006) andthe Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.Key to 'Comments' column in Section 8.(+) There is a risk of absorption through unbroken skin.(C) Capable of causing cancer and/or heritable genetic damage.(R) Suppliers recommended limit.(S) Capable of causing occupational asthma.The full text of the R, H & EUH phrases appearing in section 3 is:


Page 10 of 10H226 Flammable liquid and vapour.H304 May be fatal if swallowed and enters airways.H312 Harmful in contact with skin.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H332 Harmful if inhaled.H335 May cause respiratory irritation.H336 May cause drowsiness and dizziness.H411 Toxic to aquatic life with long lasting effects.R10 Flammable.R20 Harmful by inhalation.R20/21 Harmful by inhalation and in contact with skin.R36/37/38 Irritating to eyes, respiratory system and skin.R36/38 Irritating to eyes and skin.R37 Irritating to respiratory system.R38 Irritating to skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R65 Harmful: may cause lung damage if swallowed.R67 Vapours may cause drowsiness and dizziness.The following sections have changed since the previous revision.SECTION 11: Toxicological informationSECTION 12: Ecological informationEnd of documentYour attention is drawn to the disclaimer on the Product <strong>Data</strong> <strong>Sheet</strong> which with this <strong>Safety</strong> <strong>Data</strong><strong>Sheet</strong> and the package labelling comprise an integral information system about this product. Copiesof the Product <strong>Data</strong> <strong>Sheet</strong> are available from <strong>International</strong> <strong>Paint</strong> on request or from our Internetsites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!