color+ wu016 flushing solution - FUJIFILM Australia

FUJIFILM SOLVENT FLUSHING SOLUTION WU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 2-Sep-2010 CHEMWATCH 24-6698XC9317SCVersion No:2.0CD 2010/2 Page 1 of 6Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM SOLVENT FLUSHING SOLUTION WU016SYNONYMS"printing ink cleaner"PRODUCT USEInk jet printing ink cleaner.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel:+61 1800 039 008Emergency Tel:+61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Irritating to eyes.■ HARMFUL- May cause lung damage ifswallowed.■ May produce discomfort of therespiratory system and skin*.■ Limited evidence of a carcinogeniceffect*.SAFETY■ Do not breathe gas/fumes/vapour/spray.■ Avoid contact with eyes.■ Wear suitable protective clothing.■ To clean the floor and all objects contaminated by thismaterial, use water and detergent.* (limited evidence). ■ Keep away from food, drink and animal feeding stuffs.■ In case of contact with eyes, rinse with plenty of waterand contact Doctor or Poisons Information Centre.■ If swallowed, IMMEDIATELY contact Doctor or PoisonsInformation Centre. (show this container or label).continued...

FUJIFILM SOLVENT FLUSHING SOLUTION WU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 2-Sep-2010 CHEMWATCH 24-6698XC9317SCVersion No:2.0CD 2010/2 Page 3 of 6Section 5 - FIRE FIGHTING MEASURESPERSONAL PROTECTIONGlasses: Gloves: Respirator:Safety Glasses. PVC chemical resistant type. Type A- P Filter of sufficient capacitySection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Remove all ignition sources.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact by using protective equipment.MAJOR SPILLS■ Moderate hazard.• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• DO NOT allow clothing wet with material to stay in contact with skin.The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treated to concentrate theperoxides. The substance may concentrate around the container opening for example.Purchases of peroxidisable chemicals should be restricted to ensure that the chemical is used completely before it can become peroxidised.• A responsible person should maintain an inventory of peroxidisable chemicals or annotate the general chemical inventory to indicate which chemicalsare subject to peroxidation. An expiration date should be determined. The chemical should either be treated to remove peroxides or disposed ofbefore this date.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.SUITABLE CONTAINER• Metal can or drum• Packaging as recommended by manufacturer.• Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY• The unhindered oxygen atom found on cyclic ethers such as the epoxides, oxetanes, furans, dioxanes and pyrans, carries two unshared pairs ofelectrons - a structure which favors the formation of coordination complexes and the solvation of cations.• Cyclic ethers are used as important solvents, as chemical intermediate and as monomers for ring-opening polymerization.• They are unstable at room temperature due to possibility of peroxide formation; stabiliser is sometimes needed for storage and transportation.NOTE: Ethers lacking non-methyl hydrogen atoms adjacent to the ether link are thought to be relatively safe.• Avoid reaction with oxidising agents.STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• No smoking, naked lights or ignition sources.• Store in a cool, dry, well-ventilated area.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• propylene carbonate: CAS:108- 32- 7PERSONAL PROTECTIONcontinued...

FUJIFILM SOLVENT FLUSHING SOLUTION WU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 2-Sep-2010 CHEMWATCH 24-6698XC9317SCVersion No:2.0CD 2010/2 Page 4 of 6Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONRESPIRATORType A-P Filter of sufficient capacityEYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing thewearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity.• Neoprene rubber gloves.OTHER• Overalls.• P.V.C. apron.• Barrier cream.• Skin cleansing cream.ENGINEERING CONTROLS■ Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEColoured liquid with a characteristic odour; does not mix with water.PHYSICAL PROPERTIESLiquid.Does not mix with water.Sinks in water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) - 54 Viscosity Not AvailableBoiling Range (°C) 242 Solubility in water (g/L) ImmiscibleFlash Point (°C) 135 pH (1% solution) Not ApplicableDecomposition Temp (°C) Not Available pH (as supplied) Not AvailableAutoignition Temp (°C) Not Available Vapour Pressure (kPa) 0.004 @ 20CUpper Explosive Limit (%) Not Available Specific Gravity (water=1) 1.205Lower Explosive Limit (%) Not Available Relative Vapour Density Not Available(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not AvailableSection 10 - CHEMICAL STABILITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.continued...

FUJIFILM SOLVENT FLUSHING SOLUTION WU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 2-Sep-2010 CHEMWATCH 24-6698XC9317SCVersion No:2.0CD 2010/2 Page 5 of 6Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTS■ Irritating to eyes.■ HARMFUL- May cause lung damage if swallowed.■ May produce discomfort of the respiratory system andskin*.■ * (limited evidence).CHRONIC HEALTH EFFECTS■ Limited evidence of a carcinogeniceffect*.■ * (limited evidence).TOXICITY AND IRRITATION■ The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form ofdermatitis is often characterised by skin redness (erythema) and swelling the epidermis.for propylene carbonate:Numerous adequate and reliable acute toxicity tests are available on propylene carbonate. Oral and dermal tests meet OECD and EPA test guidelines.Section 12 - ECOLOGICAL INFORMATIONNo dataEcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilpropylene carbonate HIGH LOW HIGHSection 13 - DISPOSAL CONSIDERATIONS■ Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in theirarea.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible or consult manufacturer for recycling options.• Consult State Land Waste Authority for disposal.• Bury or incinerate residue at an approved site.• Recycle containers if possible, or dispose of in an authorised landfill.Section 14 - TRANSPORTATION INFORMATIONLabels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.HAZCHEM:None (ADG7)NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDGcontinued...

FUJIFILM SOLVENT FLUSHING SOLUTION WU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 2-Sep-2010 CHEMWATCH 24-6698XC9317SCVersion No:2.0CD 2010/2 Page 6 of 6Section 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientspropylene carbonate (CAS: 108-32-7) is found on the following regulatory lists;"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBCCode Chapter 18: List of products to which the Code does not apply","International Council of Chemical Associations (ICCA) - High Production VolumeList","OECD Representative List of High Production Volume (HPV) Chemicals"No data for Fujifilm Solvent Flushing Solution WU016 (CW: 24-6698)Section 16 - OTHER INFORMATION■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review bythe Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 2-Sep-2010Print Date: 10-Sep-2010This is the end of the MSDS.