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Toroidal configuration of the orbit of the electron of the hydrogen ...

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Energy E, a.u.-4-5-6-70 200 400 600 800 1000bFigure 12: Variational ground state energy <strong>of</strong> <strong>the</strong> <strong>hydrogen</strong> atom in <strong>the</strong>magnetic field, Eq. (3.38), as a function <strong>of</strong> <strong>the</strong> magnetic field intensity;b = B/B 0 , B 0 = 2.4 · 10 9 Gauss, 1 a.u. = 27.2 eV.4 DiscussionIn a physical context, <strong>the</strong> used adiabatic approximation implies that <strong>the</strong>position <strong>of</strong> <strong>the</strong> nucleus is not ”fixed” in <strong>the</strong> (r, ϕ) plane. Indeed, <strong>the</strong>re is noreason for <strong>the</strong> nucleus to stay ”exactly” at <strong>the</strong> center <strong>of</strong> <strong>the</strong> <strong>orbit</strong> when <strong>the</strong>Coulomb force in <strong>the</strong> transverse plane is totally ignored.In contrast, in <strong>the</strong> z direction, we have more complicated situation,namely, <strong>the</strong> magnetic field leads to <strong>the</strong> effective interaction potential C(z),which is finite at z = 0 and is Coulomb-like in <strong>the</strong> long-range asymptotic.Hence, <strong>the</strong> position <strong>of</strong> <strong>the</strong> nucleus remains to be fixed in <strong>the</strong> z directionrelative to <strong>the</strong> <strong>orbit</strong> <strong>of</strong> <strong>the</strong> <strong>electron</strong> (bound state).Due to <strong>the</strong> (crude) Coulomb approximation <strong>of</strong> Sect. 3.1.1, <strong>the</strong> <strong>electron</strong>probability density <strong>of</strong> <strong>the</strong> <strong>hydrogen</strong> atom under very intense magnetic field,at n = 1, appears to be <strong>of</strong> ra<strong>the</strong>r nontrivial form schematically depicted inFig. 6.More accurate approach may yield some different <strong>electron</strong> charge distributionsbut we expect that <strong>the</strong> symmetry requirements (namely, <strong>the</strong> axialsymmetry and <strong>the</strong> (anti)symmetry under inversion z → −z) would lead againto a toroidal <strong>orbit</strong>, which is splitted into two identical coaxial <strong>orbit</strong>s (<strong>the</strong> toriiare separated) similar to that shown in Fig. 6, or to an unsplitted one (<strong>the</strong>two torii are superimposed) as shown in Fig. 8.Accurate analytic calculation <strong>of</strong> <strong>the</strong> ground and excited <strong>hydrogen</strong> wave25

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